# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Eu-MOF
_database_code_depnum_ccdc_archive 'CCDC 2008758'
loop_
_audit_author_name
_audit_author_address
'haihuan Yu'
;Changchun University of Science and Technology
China
;
_audit_update_record             
;
2020-06-09 deposited with the CCDC.	2020-11-17 downloaded from the CCDC.
;
_audit_creation_date             2020-06-04
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C24 H10 Eu F6 N2 O7'
_chemical_formula_sum            'C24 H10 Eu F6 N2 O7'
_chemical_formula_weight         704.30
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   19.7306(15)
_cell_length_b                   21.3391(17)
_cell_length_c                   11.5617(9)
_cell_angle_alpha                90
_cell_angle_beta                 102.206(3)
_cell_angle_gamma                90
_cell_volume                     4757.8(6)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9226
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.127
_cell_measurement_theta_min      1.628
_shelx_estimated_absorpt_T_max   25.0915?
_shelx_estimated_absorpt_T_min   2.8473
_exptl_absorpt_coefficient_mu    2.734
_exptl_absorpt_correction_T_max  0.87
_exptl_absorpt_correction_T_min  0.86
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Krause et al., 2015) was used for absorption correction.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            green
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    1.966
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2728
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0301
_diffrn_reflns_av_unetI/netI     0.0175
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            29607
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.106
_diffrn_reflns_theta_max         25.106
_diffrn_reflns_theta_min         2.625
_diffrn_ambient_temperature      293.15
_diffrn_detector                 'charge-coupled device (CCD) area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'Bruker APEX II'
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker APEX II Quazar'
_diffrn_measurement_method       '0.5° ω and 0.5° φ scans'
_diffrn_radiation_collimation    'focusing mirrors'
_diffrn_radiation_detector       'Bruker APEX II'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_type              'Incoatec I\ms'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3664
_reflns_number_total             4251
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT+ Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_data_collection       'APEX3 Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT+ Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XT (Sheldrick, 2015a)'
_refine_diff_density_max         1.372
_refine_diff_density_min         -1.488
_refine_diff_density_rms         0.135
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     362
_refine_ls_number_reflns         4251
_refine_ls_number_restraints     1218
_refine_ls_R_factor_all          0.0433
_refine_ls_R_factor_gt           0.0347
_refine_ls_restrained_S_all      1.179
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0411P)²+64.1270P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0848
_refine_ls_wR_factor_ref         0.0933
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
F3 \\sim F4 \\sim F6 \\sim F5 \\sim F1 \\sim F2: within 3.8A with sigma of
0.005 and sigma for terminal atoms of 0.01
F5 \\sim F6 \\sim F4 \\sim F3 \\sim F1 \\sim F2: within 3.8A with sigma of
0.005 and sigma for terminal atoms of 0.01
O2 \\sim F3 \\sim F5 \\sim C4 \\sim F6 \\sim C3 \\sim C5 \\sim O6 \\sim N1
\\sim C6 \\sim F2 \\sim Eu1 \\sim F1 \\sim O4 \\sim O5 \\sim O7 \\sim F4 \\sim
C1 \\sim C2 \\sim O3 \\sim O1 \\sim C21 \\sim C24 \\sim C22 \\sim C20 \\sim C23
\\sim C11 \\sim C9 \\sim C7 \\sim C12 \\sim C13 \\sim C15 \\sim C17 \\sim C8
\\sim C18 \\sim C16 \\sim C14 \\sim C10 \\sim C19 \\sim N2: within 3.8A with
sigma of 0.005 and sigma for terminal atoms of 0.01
3.a Rotating group:
 O6(H6A,H6B)
3.b Aromatic/amide H refined with riding coordinates:
 C9(H9), C15(H15), C18(H18), C20(H20), C21(H21), C22(H22), C23(H23), C24(H24)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.69640(2) 0.25503(2) 0.64461(2) 0.01627(10) Uani 1 1 d . U . . .
F1 F 0.56809(17) 0.31198(14) 0.2934(3) 0.0382(7) Uani 1 1 d . U . . .
O1 O 0.7270(2) 0.33118(16) 0.3510(3) 0.0259(6) Uani 1 1 d . U . . .
F2 F 0.56843(17) 0.09147(15) 0.2938(3) 0.0422(8) Uani 1 1 d . U . . .
O2 O 0.6861(2) 0.34300(16) 0.5161(3) 0.0272(6) Uani 1 1 d . U . . .
O3 O 0.68806(19) 0.20012(17) 0.2704(3) 0.0296(7) Uani 1 1 d . U . . .
O4 O 0.67156(19) 0.21382(17) 0.4513(3) 0.0284(6) Uani 1 1 d . U . . .
O5 O 0.6722(2) 0.65711(16) 0.2570(3) 0.0300(7) Uani 1 1 d . U . . .
O6 O 0.7155(2) 0.22137(17) 0.8460(3) 0.0336(9) Uani 1 1 d . U . . .
H6A H 0.685178 0.193035 0.854693 0.050 Uiso 1 1 d GR . . . .
H6B H 0.707224 0.251953 0.890963 0.050 Uiso 1 1 d GR . . . .
O7 O 0.7175(3) 0.66802(18) 0.4474(4) 0.0438(10) Uani 1 1 d . U . . .
F3 F 0.7719(3) 0.44992(18) 0.5918(4) 0.0646(11) Uani 1 1 d . U . . .
F4 F 0.7700(3) 0.57083(18) 0.5628(4) 0.0667(11) Uani 1 1 d . U . . .
C1 C 0.5725(3) 0.2017(2) 0.2959(5) 0.0231(8) Uani 1 1 d . U . . .
C2 C 0.5352(3) 0.1469(2) 0.2731(5) 0.0261(8) Uani 1 1 d . U . . .
C3 C 0.5359(3) 0.2570(2) 0.2726(5) 0.0293(8) Uani 1 1 d . U . . .
F5 F 0.6305(3) 0.42384(17) 0.2153(4) 0.0686(11) Uani 1 1 d . U . . .
C4 C 0.6503(3) 0.2047(2) 0.3431(5) 0.0236(8) Uani 1 1 d . U . . .
F6 F 0.6246(3) 0.54512(18) 0.1852(4) 0.0732(12) Uani 1 1 d . U . . .
C5 C 0.6951(3) 0.6359(2) 0.3579(5) 0.0287(9) Uani 1 1 d . U . . .
N1 N 0.6209(2) 0.1544(2) 0.6529(4) 0.0291(7) Uani 1 1 d . U . . .
C6 C 0.7038(3) 0.3622(2) 0.4259(5) 0.0250(8) Uani 1 1 d . U . . .
N2 N 0.5637(2) 0.2677(2) 0.5879(4) 0.0308(7) Uani 1 1 d . U . . .
C7 C 0.6951(3) 0.5654(2) 0.3741(5) 0.0317(9) Uani 1 1 d . U . . .
C8 C 0.6994(3) 0.4325(2) 0.4060(5) 0.0304(8) Uani 1 1 d . U . . .
C9 C 0.4226(3) 0.2793(3) 0.4865(6) 0.0375(9) Uani 1 1 d . U . . .
H9 H 0.375936 0.283657 0.450856 0.045 Uiso 1 1 calc R . . . .
C10 C 0.5215(3) 0.2162(3) 0.5704(5) 0.0305(7) Uani 1 1 d . U . . .
C11 C 0.5518(3) 0.1564(3) 0.6059(5) 0.0305(7) Uani 1 1 d . U . . .
C12 C 0.7317(3) 0.5371(3) 0.4750(5) 0.0354(9) Uani 1 1 d . U . . .
C13 C 0.7334(3) 0.4728(3) 0.4914(5) 0.0347(9) Uani 1 1 d . U . . .
C14 C 0.6641(3) 0.4599(3) 0.3034(5) 0.0369(9) Uani 1 1 d . U . . .
C15 C 0.6484(3) 0.0990(3) 0.6910(5) 0.0309(8) Uani 1 1 d . U . . .
H15 H 0.695479 0.097509 0.724983 0.037 Uiso 1 1 calc R . . . .
C16 C 0.5099(3) 0.1023(3) 0.5926(5) 0.0332(8) Uani 1 1 d . U . . .
C17 C 0.4503(3) 0.2199(3) 0.5199(5) 0.0344(8) Uani 1 1 d . U . . .
C18 C 0.4092(3) 0.1636(3) 0.5053(6) 0.0379(9) Uani 1 1 d . U . . .
H18 H 0.362209 0.165865 0.470743 0.046 Uiso 1 1 calc R . . . .
C19 C 0.6616(4) 0.5242(3) 0.2875(5) 0.0381(9) Uani 1 1 d . U . . .
C20 C 0.4375(3) 0.1082(3) 0.5406(5) 0.0375(9) Uani 1 1 d . U . . .
H20 H 0.409620 0.072634 0.531257 0.045 Uiso 1 1 calc R . . . .
C21 C 0.4644(3) 0.3306(3) 0.5066(6) 0.0402(9) Uani 1 1 d . U . . .
H21 H 0.446382 0.370374 0.486464 0.048 Uiso 1 1 calc R . . . .
C22 C 0.5413(3) 0.0452(3) 0.6333(5) 0.0359(9) Uani 1 1 d . U . . .
H22 H 0.515037 0.008646 0.626671 0.043 Uiso 1 1 calc R . . . .
C23 C 0.5349(3) 0.3231(3) 0.5580(5) 0.0346(8) Uani 1 1 d . U . . .
H23 H 0.562807 0.358603 0.571819 0.041 Uiso 1 1 calc R . . . .
C24 C 0.6107(3) 0.0434(3) 0.6828(5) 0.0354(9) Uani 1 1 d . U . . .
H24 H 0.632241 0.005884 0.710363 0.043 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.375(3) 7_656 ?
Eu1 O2 2.376(3) . ?
Eu1 O3 2.476(4) 7_656 ?
Eu1 O4 3.111(4) 7_656 ?
Eu1 O5 2.386(3) 6_566 ?
Eu1 O6 2.389(4) . ?
Eu1 H6A 2.8153 . ?
Eu1 H6B 2.8116 . ?
Eu1 N1 2.626(4) . ?
Eu1 N2 2.575(5) . ?
F1 C3 1.332(6) . ?
O1 C6 1.251(6) . ?
F2 C2 1.348(6) . ?
O2 C6 1.238(6) . ?
O3 C4 1.239(7) . ?
O4 C4 1.247(6) . ?
O5 C5 1.243(6) . ?
O6 H6A 0.8705 . ?
O6 H6B 0.8706 . ?
O7 C5 1.242(7) . ?
F3 C13 1.338(6) . ?
F4 C12 1.340(7) . ?
C1 C2 1.378(7) . ?
C1 C3 1.379(7) . ?
C1 C4 1.519(7) . ?
C2 C2 1.379(10) 2_655 ?
C3 C3 1.403(11) 2_655 ?
F5 C14 1.335(7) . ?
F6 C19 1.329(7) . ?
C5 C7 1.517(7) . ?
N1 C11 1.358(7) . ?
N1 C15 1.335(7) . ?
C6 C8 1.517(7) . ?
N2 C10 1.368(7) . ?
N2 C23 1.325(7) . ?
C7 C12 1.375(8) . ?
C7 C19 1.390(8) . ?
C8 C13 1.372(8) . ?
C8 C14 1.373(8) . ?
C9 H9 0.9300 . ?
C9 C17 1.403(9) . ?
C9 C21 1.361(9) . ?
C10 C11 1.431(8) . ?
C10 C17 1.405(8) . ?
C11 C16 1.410(8) . ?
C12 C13 1.384(8) . ?
C14 C19 1.384(8) . ?
C15 H15 0.9300 . ?
C15 C24 1.393(8) . ?
C16 C20 1.434(9) . ?
C16 C22 1.402(9) . ?
C17 C18 1.440(8) . ?
C18 H18 0.9300 . ?
C18 C20 1.333(9) . ?
C20 H20 0.9300 . ?
C21 H21 0.9300 . ?
C21 C23 1.402(8) . ?
C22 H22 0.9300 . ?
C22 C24 1.369(9) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O2 126.53(13) 7_656 . ?
O1 Eu1 O3 76.24(12) 7_656 7_656 ?
O1 Eu1 O4 66.15(11) 7_656 7_656 ?
O1 Eu1 O5 142.82(13) 7_656 6_566 ?
O1 Eu1 O6 77.18(13) 7_656 . ?
O1 Eu1 H6A 77.5 7_656 . ?
O1 Eu1 H6B 92.8 7_656 . ?
O1 Eu1 N1 74.30(14) 7_656 . ?
O1 Eu1 N2 134.06(14) 7_656 . ?
O2 Eu1 O3 83.83(13) . 7_656 ?
O2 Eu1 O4 64.90(11) . 7_656 ?
O2 Eu1 O5 73.69(13) . 6_566 ?
O2 Eu1 O6 145.27(13) . . ?
O2 Eu1 H6A 154.0 . . ?
O2 Eu1 H6B 129.0 . . ?
O2 Eu1 N1 133.99(14) . . ?
O2 Eu1 N2 79.03(14) . . ?
O3 Eu1 O4 44.66(11) 7_656 7_656 ?
O3 Eu1 H6A 94.2 7_656 . ?
O3 Eu1 H6B 75.0 7_656 . ?
O3 Eu1 N1 141.55(14) 7_656 . ?
O3 Eu1 N2 149.49(14) 7_656 . ?
O4 Eu1 H6A 129.2 7_656 . ?
O4 Eu1 H6B 118.4 7_656 . ?
O5 Eu1 O3 75.76(13) 6_566 7_656 ?
O5 Eu1 O4 107.79(12) 6_566 7_656 ?
O5 Eu1 O6 73.37(13) 6_566 . ?
O5 Eu1 H6A 80.7 6_566 . ?
O5 Eu1 H6B 56.5 6_566 . ?
O5 Eu1 N1 116.23(14) 6_566 . ?
O5 Eu1 N2 75.29(14) 6_566 . ?
O6 Eu1 O3 77.73(14) . 7_656 ?
O6 Eu1 O4 116.13(13) . 7_656 ?
O6 Eu1 H6A 16.8 . . ?
O6 Eu1 H6B 16.9 . . ?
O6 Eu1 N1 72.09(14) . . ?
O6 Eu1 N2 102.82(15) . . ?
H6A Eu1 H6B 28.1 . . ?
N1 Eu1 O4 135.37(12) . 7_656 ?
N1 Eu1 H6A 55.7 . . ?
N1 Eu1 H6B 82.3 . . ?
N2 Eu1 O4 140.32(13) . 7_656 ?
N2 Eu1 H6A 90.5 . . ?
N2 Eu1 H6B 96.7 . . ?
N2 Eu1 N1 62.71(15) . . ?
C6 O1 Eu1 136.0(3) . 7_656 ?
C6 O2 Eu1 141.9(3) . . ?
C4 O3 Eu1 109.6(3) . 7_656 ?
C4 O4 Eu1 78.8(3) . 7_656 ?
C5 O5 Eu1 136.1(3) . 6_565 ?
Eu1 O6 H6A 110.5 . . ?
Eu1 O6 H6B 110.2 . . ?
H6A O6 H6B 103.5 . . ?
C2 C1 C3 116.9(5) . . ?
C2 C1 C4 124.3(5) . . ?
C3 C1 C4 118.8(5) . . ?
F2 C2 C1 119.4(5) . . ?
F2 C2 C2 118.8(3) . 2_655 ?
C1 C2 C2 121.8(3) . 2_655 ?
F1 C3 C1 120.6(5) . . ?
F1 C3 C3 118.2(3) . 2_655 ?
C1 C3 C3 121.2(3) . 2_655 ?
O3 C4 Eu1 48.4(3) . 7_656 ?
O3 C4 O4 124.8(5) . . ?
O3 C4 C1 117.4(5) . . ?
O4 C4 Eu1 78.1(3) . 7_656 ?
O4 C4 C1 117.8(5) . . ?
C1 C4 Eu1 157.7(3) . 7_656 ?
O5 C5 C7 117.9(5) . . ?
O7 C5 O5 125.2(5) . . ?
O7 C5 C7 116.9(5) . . ?
C11 N1 Eu1 119.2(4) . . ?
C15 N1 Eu1 122.8(4) . . ?
C15 N1 C11 117.6(5) . . ?
O1 C6 C8 115.8(5) . . ?
O2 C6 O1 128.1(5) . . ?
O2 C6 C8 116.0(5) . . ?
C10 N2 Eu1 120.5(4) . . ?
C23 N2 Eu1 121.1(4) . . ?
C23 N2 C10 117.7(5) . . ?
C12 C7 C5 121.9(5) . . ?
C12 C7 C19 114.7(5) . . ?
C19 C7 C5 123.4(5) . . ?
C13 C8 C6 120.5(5) . . ?
C13 C8 C14 115.9(5) . . ?
C14 C8 C6 123.6(5) . . ?
C17 C9 H9 120.2 . . ?
C21 C9 H9 120.2 . . ?
C21 C9 C17 119.5(6) . . ?
N2 C10 C11 118.0(5) . . ?
N2 C10 C17 122.7(5) . . ?
C17 C10 C11 119.3(5) . . ?
N1 C11 C10 117.8(5) . . ?
N1 C11 C16 122.2(5) . . ?
C16 C11 C10 120.0(5) . . ?
F4 C12 C7 121.1(5) . . ?
F4 C12 C13 115.8(5) . . ?
C7 C12 C13 123.0(5) . . ?
F3 C13 C8 119.8(5) . . ?
F3 C13 C12 118.3(5) . . ?
C8 C13 C12 121.9(5) . . ?
F5 C14 C8 119.6(5) . . ?
F5 C14 C19 118.2(5) . . ?
C8 C14 C19 122.2(5) . . ?
N1 C15 H15 118.0 . . ?
N1 C15 C24 123.9(6) . . ?
C24 C15 H15 118.0 . . ?
C11 C16 C20 118.8(6) . . ?
C22 C16 C11 118.0(5) . . ?
C22 C16 C20 123.2(5) . . ?
C9 C17 C10 117.6(6) . . ?
C9 C17 C18 123.0(6) . . ?
C10 C17 C18 119.4(6) . . ?
C17 C18 H18 119.5 . . ?
C20 C18 C17 121.0(6) . . ?
C20 C18 H18 119.5 . . ?
F6 C19 C7 121.1(5) . . ?
F6 C19 C14 116.6(5) . . ?
C14 C19 C7 122.2(5) . . ?
C16 C20 H20 119.3 . . ?
C18 C20 C16 121.5(6) . . ?
C18 C20 H20 119.3 . . ?
C9 C21 H21 120.3 . . ?
C9 C21 C23 119.5(6) . . ?
C23 C21 H21 120.3 . . ?
C16 C22 H22 120.1 . . ?
C24 C22 C16 119.7(5) . . ?
C24 C22 H22 120.1 . . ?
N2 C23 C21 123.0(6) . . ?
N2 C23 H23 118.5 . . ?
C21 C23 H23 118.5 . . ?
C15 C24 H24 120.8 . . ?
C22 C24 C15 118.5(6) . . ?
C22 C24 H24 120.8 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Gd-MOF
_database_code_depnum_ccdc_archive 'CCDC 2008759'
loop_
_audit_author_name
_audit_author_address
'haihuan Yu'
;Changchun University of Science and Technology
China
;
_audit_update_record             
;
2020-06-09 deposited with the CCDC.	2020-11-17 downloaded from the CCDC.
;
_audit_creation_date             2020-01-07
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C24 H10 F6 Gd N2 O7'
_chemical_formula_sum            'C24 H10 F6 Gd N2 O7'
_chemical_formula_weight         709.59
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   19.697(9)
_cell_length_b                   21.234(9)
_cell_length_c                   11.532(6)
_cell_angle_alpha                90
_cell_angle_beta                 101.866(16)
_cell_angle_gamma                90
_cell_volume                     4720(4)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    5598
_cell_measurement_temperature    293.15(2)
_cell_measurement_theta_max      24.8250
_cell_measurement_theta_min      2.8544
_shelx_estimated_absorpt_T_max   0.594
_shelx_estimated_absorpt_T_min   0.542
_exptl_absorpt_coefficient_mu    2.908
_exptl_absorpt_correction_T_max  0.87
_exptl_absorpt_correction_T_min  0.86
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Krause et al., 2015) was used for absorption correction.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.997
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2736
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0918
_diffrn_reflns_av_unetI/netI     0.0592
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            27148
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.107
_diffrn_reflns_theta_max         25.107
_diffrn_reflns_theta_min         2.634
_diffrn_ambient_temperature      293.15
_diffrn_detector                 'charge-coupled device (CCD) area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'Bruker APEX II'
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker APEX II Quazar'
_diffrn_measurement_method       '0.5° ω and 0.5° φ scans'
_diffrn_radiation_collimation    'focusing mirrors'
_diffrn_radiation_detector       'Bruker APEX II'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_type              'Incoatec I\ms'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3018
_reflns_number_total             4207
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT+ Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_data_collection       'APEX3 Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT+ Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XT (Sheldrick, 2015a)'
_refine_diff_density_max         1.439
_refine_diff_density_min         -1.630
_refine_diff_density_rms         0.178
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     362
_refine_ls_number_reflns         4207
_refine_ls_number_restraints     1231
_refine_ls_R_factor_all          0.0816
_refine_ls_R_factor_gt           0.0504
_refine_ls_restrained_S_all      6.048
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0580P)²+96.0002P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1137
_refine_ls_wR_factor_ref         0.1291
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Restrained distances
 O3-O4
 2.8 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
C12 \\sim C22 \\sim F6 \\sim C10 \\sim C16 \\sim C20 \\sim C23 \\sim C5 \\sim
F5 \\sim C17 \\sim C11 \\sim C24 \\sim C18 \\sim C19 \\sim C13 \\sim C6 \\sim
C7 \\sim C14 \\sim C9 \\sim C15 \\sim C21 \\sim C8 \\sim O6 \\sim O3 \\sim C3
\\sim C1 \\sim N2 \\sim F1 \\sim O4 \\sim N1 \\sim F4 \\sim O7 \\sim C4 \\sim
C2 \\sim O2 \\sim O5 \\sim F3 \\sim O1 \\sim F2 \\sim Gd1: within 3.8A with
sigma of 0.005 and sigma for terminal atoms of 0.01
4.a Rotating group:
 O6(H6A,H6B)
4.b Aromatic/amide H refined with riding coordinates:
 C12(H12), C16(H16), C18(H18), C20(H20), C21(H21), C22(H22), C23(H23), C24(H24)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Gd1 Gd 0.69597(2) 0.24497(2) 0.64561(4) 0.01609(15) Uani 1 1 d . U . . .
O1 O 0.6704(3) 0.2865(3) 0.4539(6) 0.0287(8) Uani 1 1 d . U . . .
O2 O 0.7727(3) 0.3304(3) 0.6493(6) 0.0286(9) Uani 1 1 d . U . . .
O3 O 0.8135(3) 0.3451(3) 0.4858(6) 0.0305(9) Uani 1 1 d D U . . .
O4 O 0.8278(4) 0.6543(3) 0.7402(6) 0.0323(11) Uani 1 1 d D U . . .
F1 F 0.5679(3) 0.1878(2) 0.2943(5) 0.0365(12) Uani 1 1 d . U . . .
F2 F 0.5690(3) 0.4085(2) 0.2948(5) 0.0392(12) Uani 1 1 d . U . . .
O5 O 0.6889(3) 0.2993(3) 0.2724(6) 0.0305(10) Uani 1 1 d . U . . .
C1 C 0.5522(5) 0.3437(4) 0.6078(8) 0.0294(9) Uani 1 1 d . U . . .
F3 F 0.7293(4) 0.5705(3) 0.4373(6) 0.0596(15) Uani 1 1 d . U . . .
N1 N 0.6212(4) 0.3454(3) 0.6551(7) 0.0288(9) Uani 1 1 d . U . . .
C2 C 0.8007(6) 0.4319(4) 0.5932(9) 0.0337(10) Uani 1 1 d . U . . .
O6 O 0.7143(4) 0.2777(3) 0.8463(5) 0.0308(14) Uani 1 1 d . U . . .
H6A H 0.688181 0.310474 0.852070 0.046 Uiso 1 1 d GR . . . .
H6B H 0.756752 0.291792 0.869140 0.046 Uiso 1 1 d GR . . . .
F4 F 0.7268(4) 0.4493(3) 0.4091(6) 0.0533(13) Uani 1 1 d . U . . .
O7 O 0.7825(4) 0.6675(3) 0.5527(6) 0.0425(15) Uani 1 1 d . U . . .
C3 C 0.5728(5) 0.2981(4) 0.2961(8) 0.0273(11) Uani 1 1 d . U . . .
N2 N 0.5640(4) 0.2320(3) 0.5901(7) 0.0301(9) Uani 1 1 d . U . . .
C4 C 0.6498(5) 0.2952(4) 0.3447(8) 0.0270(10) Uani 1 1 d . U . . .
C5 C 0.5206(5) 0.2829(4) 0.5704(9) 0.0296(8) Uani 1 1 d . U . . .
C6 C 0.5350(5) 0.3533(4) 0.2722(9) 0.0273(12) Uani 1 1 d . U . . .
F5 F 0.8764(4) 0.5445(3) 0.8135(6) 0.0628(15) Uani 1 1 d . U . . .
F6 F 0.8699(4) 0.4233(3) 0.7835(6) 0.0588(14) Uani 1 1 d . U . . .
C7 C 0.8050(6) 0.5651(4) 0.6241(9) 0.0358(11) Uani 1 1 d . U . . .
C8 C 0.7961(5) 0.3618(4) 0.5733(9) 0.0289(9) Uani 1 1 d . U . . .
C9 C 0.8054(6) 0.6357(4) 0.6424(9) 0.0352(13) Uani 1 1 d . U . . .
C10 C 0.7687(6) 0.5371(4) 0.5241(9) 0.0363(11) Uani 1 1 d . U . . .
C11 C 0.5355(5) 0.2437(4) 0.2733(9) 0.0293(9) Uani 1 1 d . U . . .
C12 C 0.6488(5) 0.4014(4) 0.6923(8) 0.0298(9) Uani 1 1 d . U . . .
H12 H 0.697037 0.403905 0.725757 0.036 Uiso 1 1 calc R . . . .
C13 C 0.8363(6) 0.4595(4) 0.6959(9) 0.0364(11) Uani 1 1 d . U . . .
C14 C 0.5098(5) 0.3978(4) 0.5944(9) 0.0317(10) Uani 1 1 d . U . . .
C15 C 0.4502(5) 0.2792(4) 0.5205(9) 0.0326(10) Uani 1 1 d . U . . .
C16 C 0.5348(5) 0.1766(4) 0.5607(9) 0.0316(11) Uani 1 1 d . U . . .
H16 H 0.562970 0.140059 0.577256 0.038 Uiso 1 1 calc R . . . .
C17 C 0.7667(5) 0.4720(4) 0.5089(9) 0.0349(10) Uani 1 1 d . U . . .
C18 C 0.6085(5) 0.4562(4) 0.6830(9) 0.0328(12) Uani 1 1 d . U . . .
H18 H 0.629459 0.494788 0.712656 0.039 Uiso 1 1 calc R . . . .
C19 C 0.8389(6) 0.5239(4) 0.7108(9) 0.0384(11) Uani 1 1 d . U . . .
C20 C 0.4089(5) 0.3358(4) 0.5044(9) 0.0345(11) Uani 1 1 d . U . . .
H20 H 0.361175 0.333579 0.467630 0.041 Uiso 1 1 calc R . . . .
C21 C 0.4228(5) 0.2202(4) 0.4869(9) 0.0344(11) Uani 1 1 d . U . . .
H21 H 0.375242 0.215615 0.450484 0.041 Uiso 1 1 calc R . . . .
C22 C 0.5409(5) 0.4550(4) 0.6330(9) 0.0321(11) Uani 1 1 d . U . . .
H22 H 0.514466 0.492710 0.623989 0.039 Uiso 1 1 calc R . . . .
C23 C 0.4375(5) 0.3913(4) 0.5408(9) 0.0341(11) Uani 1 1 d . U . . .
H23 H 0.408953 0.427774 0.531043 0.041 Uiso 1 1 calc R . . . .
C24 C 0.4652(5) 0.1687(4) 0.5070(9) 0.0353(11) Uani 1 1 d . U . . .
H24 H 0.447479 0.127871 0.484536 0.042 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Gd1 O1 2.337(6) . ?
Gd1 O2 2.356(6) . ?
Gd1 O3 2.423(6) 7_656 ?
Gd1 O4 2.431(6) 4_646 ?
Gd1 O5 2.458(6) 7_656 ?
Gd1 N1 2.608(7) . ?
Gd1 O6 2.372(6) . ?
Gd1 N2 2.561(8) . ?
O1 C4 1.254(11) . ?
O2 C8 1.261(11) . ?
O3 C8 1.186(11) . ?
O4 C9 1.192(11) . ?
F1 C11 1.347(10) . ?
F2 C6 1.348(10) . ?
O5 C4 1.249(11) . ?
C1 N1 1.356(12) . ?
C1 C5 1.460(13) . ?
C1 C14 1.410(13) . ?
F3 C10 1.337(11) . ?
N1 C12 1.339(11) . ?
C2 C8 1.506(12) . ?
C2 C13 1.376(13) . ?
C2 C17 1.360(13) . ?
F4 C17 1.343(11) . ?
O7 C9 1.241(11) . ?
C3 C4 1.507(13) . ?
C3 C6 1.386(12) . ?
C3 C11 1.364(12) . ?
N2 C5 1.368(12) . ?
N2 C16 1.321(12) . ?
C5 C15 1.390(14) . ?
C6 C6 1.369(18) 2_655 ?
F5 C19 1.334(11) . ?
F6 C13 1.332(11) . ?
C7 C9 1.513(12) . ?
C7 C10 1.363(13) . ?
C7 C19 1.392(13) . ?
C10 C17 1.392(12) . ?
C11 C11 1.391(18) 2_655 ?
C12 C18 1.401(13) . ?
C13 C19 1.378(12) . ?
C14 C22 1.391(13) . ?
C14 C23 1.438(14) . ?
C15 C20 1.441(13) . ?
C15 C21 1.389(14) . ?
C16 C24 1.393(13) . ?
C18 C22 1.338(13) . ?
C20 C23 1.336(13) . ?
C21 C24 1.367(13) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Gd1 O2 74.9(2) . . ?
O1 Gd1 O3 74.5(2) . 7_656 ?
O1 Gd1 O4 141.5(2) . 4_646 ?
O1 Gd1 O5 120.7(2) . 7_656 ?
O1 Gd1 N1 73.6(2) . . ?
O1 Gd1 O6 140.6(2) . . ?
O1 Gd1 N2 78.1(2) . . ?
O2 Gd1 O3 125.9(2) . 7_656 ?
O2 Gd1 O4 142.6(2) . 4_646 ?
O2 Gd1 O5 75.5(2) . 7_656 ?
O2 Gd1 N1 74.6(2) . . ?
O2 Gd1 O6 77.8(2) . . ?
O2 Gd1 N2 134.6(2) . . ?
O3 Gd1 O4 73.5(2) 7_656 4_646 ?
O3 Gd1 O5 83.4(2) 7_656 7_656 ?
O3 Gd1 N1 134.4(2) 7_656 . ?
O3 Gd1 N2 79.3(2) 7_656 . ?
O4 Gd1 O5 75.7(2) 4_646 7_656 ?
O4 Gd1 N1 116.8(2) 4_646 . ?
O4 Gd1 N2 75.6(2) 4_646 . ?
O5 Gd1 N1 141.4(2) 7_656 . ?
O5 Gd1 N2 149.7(2) 7_656 . ?
O6 Gd1 O3 144.9(2) . 7_656 ?
O6 Gd1 O4 73.2(2) . 4_646 ?
O6 Gd1 O5 78.1(2) . 7_656 ?
O6 Gd1 N1 72.1(2) . . ?
O6 Gd1 N2 102.6(3) . . ?
N2 Gd1 N1 63.0(2) . . ?
C4 O1 Gd1 165.3(6) . . ?
C8 O2 Gd1 136.0(6) . . ?
C8 O3 Gd1 140.4(6) . 7_656 ?
C9 O4 Gd1 134.5(6) . 4_656 ?
C4 O5 Gd1 111.2(6) . 7_656 ?
N1 C1 C5 118.3(8) . . ?
N1 C1 C14 122.9(9) . . ?
C14 C1 C5 118.8(9) . . ?
C1 N1 Gd1 119.3(6) . . ?
C12 N1 Gd1 122.8(6) . . ?
C12 N1 C1 117.4(8) . . ?
C13 C2 C8 123.7(8) . . ?
C17 C2 C8 120.3(9) . . ?
C17 C2 C13 115.9(8) . . ?
C6 C3 C4 124.6(8) . . ?
C11 C3 C4 119.9(8) . . ?
C11 C3 C6 115.6(9) . . ?
C5 N2 Gd1 121.6(6) . . ?
C16 N2 Gd1 121.7(6) . . ?
C16 N2 C5 115.9(8) . . ?
O1 C4 C3 118.2(9) . . ?
O5 C4 O1 124.4(9) . . ?
O5 C4 C3 117.4(8) . . ?
N2 C5 C1 115.9(9) . . ?
N2 C5 C15 124.1(9) . . ?
C15 C5 C1 120.0(8) . . ?
F2 C6 C3 118.2(8) . . ?
F2 C6 C6 119.6(4) . 2_655 ?
C6 C6 C3 122.2(5) 2_655 . ?
C10 C7 C9 122.5(8) . . ?
C10 C7 C19 115.1(8) . . ?
C19 C7 C9 122.3(9) . . ?
O2 C8 C2 115.8(9) . . ?
O3 C8 O2 130.1(8) . . ?
O3 C8 C2 114.1(9) . . ?
O4 C9 O7 127.4(8) . . ?
O4 C9 C7 116.9(8) . . ?
O7 C9 C7 115.7(8) . . ?
F3 C10 C7 121.6(8) . . ?
F3 C10 C17 115.8(8) . . ?
C7 C10 C17 122.4(9) . . ?
F1 C11 C3 119.7(8) . . ?
F1 C11 C11 118.1(5) . 2_655 ?
C3 C11 C11 122.2(5) . 2_655 ?
N1 C12 C18 121.6(9) . . ?
C2 C13 C19 121.9(9) . . ?
F6 C13 C2 119.6(8) . . ?
F6 C13 C19 118.5(9) . . ?
C1 C14 C23 118.7(9) . . ?
C22 C14 C1 117.6(9) . . ?
C22 C14 C23 123.6(9) . . ?
C5 C15 C20 119.7(9) . . ?
C21 C15 C5 117.6(9) . . ?
C21 C15 C20 122.7(9) . . ?
N2 C16 C24 123.9(9) . . ?
C2 C17 C10 122.3(9) . . ?
F4 C17 C2 120.2(8) . . ?
F4 C17 C10 117.4(8) . . ?
C22 C18 C12 121.1(9) . . ?
F5 C19 C7 121.9(8) . . ?
F5 C19 C13 115.9(8) . . ?
C13 C19 C7 122.2(9) . . ?
C23 C20 C15 120.3(10) . . ?
C24 C21 C15 119.1(9) . . ?
C18 C22 C14 119.2(9) . . ?
C20 C23 C14 122.4(9) . . ?
C21 C24 C16 119.3(9) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
