# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_i17488
_database_code_depnum_ccdc_archive 'CCDC 2009510'
loop_
_audit_author_name
_audit_author_address
'Wen Yuh Sheng'
;X ray Lab, Institute of Chemistry, Academia Sinica
Taiwan
;
_audit_update_record             
;
2020-06-12 deposited with the CCDC.	2020-12-08 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C160 H140 N20 O4 Pt4'
_chemical_formula_weight         3187.27

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   7.8030(18)
_cell_length_b                   13.819(3)
_cell_length_c                   29.561(7)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     3187.4(12)
_cell_formula_units_Z            1
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9910
_cell_measurement_theta_min      2.54
_cell_measurement_theta_max      24.57

_exptl_crystal_description       niddle
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      none
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.660
_exptl_crystal_F_000             1584
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.322
_exptl_crystal_size_mid          0.049
_exptl_crystal_size_min          0.035
_exptl_absorpt_coefficient_mu    4.444
_shelx_estimated_absorpt_T_min   0.329
_shelx_estimated_absorpt_T_max   0.860
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.8545
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_process_details   'Bruker SADABS, 1996'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            81866
_diffrn_reflns_av_unetI/netI     0.0628
_diffrn_reflns_av_R_equivalents  0.1518
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_theta_min         1.627
_diffrn_reflns_theta_max         27.097
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             6999
_reflns_number_gt                6615
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.767
_reflns_Friedel_fraction_max     0.998
_reflns_Friedel_fraction_full    1.000

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker Instrument Service v2012.12.0.3'
_computing_cell_refinement       'APEX3 v2015.9-0 (Bruker AXS)'
_computing_data_reduction        'SAINT V8.35A (Bruker AXS Inc., 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    'shelXle (C.B. Huebschle, rev 740)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2014)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     'w=1/[σ²(Fo²)] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 2731 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.007(5)
_chemical_absolute_configuration unk
_refine_ls_number_reflns         6999
_refine_ls_number_parameters     428
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0278
_refine_ls_R_factor_gt           0.0238
_refine_ls_wR_factor_ref         0.0462
_refine_ls_wR_factor_gt          0.0450
_refine_ls_goodness_of_fit_ref   0.860
_refine_ls_restrained_S_all      0.860
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.73609(2) 0.23680(2) 0.34774(2) 0.00961(5) Uani 1 1 d . . . . .
O1 O 0.7694(4) 0.0952(2) 0.32548(11) 0.0139(8) Uani 1 1 d . . . . .
N1 N 0.9750(4) 0.2496(3) 0.31976(13) 0.0113(9) Uani 1 1 d . . . . .
N2 N 1.2245(5) 0.0677(3) 0.25450(13) 0.0165(10) Uani 1 1 d . . . . .
N3 N 1.4465(4) 0.2371(4) 0.24924(14) 0.0191(11) Uani 1 1 d . . . . .
N4 N 0.5092(5) 0.2108(3) 0.37684(14) 0.0109(10) Uani 1 1 d . . . . .
N5 N 0.2941(4) 0.2548(3) 0.42132(13) 0.0102(9) Uani 1 1 d . . . . .
C1 C 0.9095(6) 0.0849(4) 0.30154(18) 0.0118(11) Uani 1 1 d . . . . .
C2 C 0.9521(6) 0.0015(4) 0.27848(18) 0.0141(12) Uani 1 1 d . . . . .
H2 H 0.875097 -0.051773 0.277668 0.017 Uiso 1 1 calc R U . . .
C3 C 1.1102(6) -0.0035(4) 0.25633(18) 0.0164(12) Uani 1 1 d . . . . .
H3 H 1.138119 -0.062390 0.241444 0.020 Uiso 1 1 calc R U . . .
C4 C 1.1843(6) 0.1524(4) 0.27531(18) 0.0143(12) Uani 1 1 d . . . . .
C5 C 1.2969(5) 0.2353(4) 0.27280(16) 0.0153(12) Uani 1 1 d . . . . .
C6 C 1.2439(7) 0.3183(4) 0.29680(16) 0.0171(11) Uani 1 1 d . . . . .
H6 H 1.317094 0.373224 0.297816 0.021 Uiso 1 1 calc R U . . .
C7 C 1.0868(6) 0.3215(4) 0.31903(18) 0.0136(12) Uani 1 1 d . . . . .
H7 H 1.057855 0.379229 0.334729 0.016 Uiso 1 1 calc R U . . .
C8 C 1.0257(6) 0.1643(4) 0.29897(18) 0.0130(12) Uani 1 1 d . . . . .
C9 C 1.5411(7) 0.1523(5) 0.2337(2) 0.0278(16) Uani 1 1 d . . . . .
H9A H 1.522585 0.098610 0.254804 0.042 Uiso 1 1 calc R U . . .
H9B H 1.663628 0.167628 0.232358 0.042 Uiso 1 1 calc R U . . .
H9C H 1.500672 0.133772 0.203547 0.042 Uiso 1 1 calc R U . . .
C10 C 1.5298(7) 0.3305(5) 0.2406(2) 0.0279(16) Uani 1 1 d . . . . .
H10A H 1.608504 0.324188 0.214932 0.042 Uiso 1 1 calc R U . . .
H10B H 1.593963 0.350576 0.267505 0.042 Uiso 1 1 calc R U . . .
H10C H 1.442466 0.379257 0.233566 0.042 Uiso 1 1 calc R U . . .
C11 C 0.4447(5) 0.2820(4) 0.40120(17) 0.0109(11) Uani 1 1 d . . . . .
C12 C 0.3984(6) 0.1319(4) 0.37992(18) 0.0113(12) Uani 1 1 d . . . . .
C13 C 0.4072(6) 0.0391(4) 0.36184(17) 0.0120(11) Uani 1 1 d . . . . .
H13 H 0.499286 0.019590 0.342890 0.014 Uiso 1 1 calc R U . . .
C14 C 0.2748(6) -0.0236(4) 0.37287(17) 0.0155(11) Uani 1 1 d . . . . .
H14 H 0.275971 -0.087368 0.360816 0.019 Uiso 1 1 calc R U . . .
C15 C 0.1395(6) 0.0039(4) 0.40118(19) 0.0174(13) Uani 1 1 d . . . . .
H15 H 0.052448 -0.041756 0.408225 0.021 Uiso 1 1 calc R U . . .
C16 C 0.1299(6) 0.0967(4) 0.41920(18) 0.0142(12) Uani 1 1 d . . . . .
H16 H 0.037697 0.115966 0.438144 0.017 Uiso 1 1 calc R U . . .
C17 C 0.2612(7) 0.1593(3) 0.40815(16) 0.0123(10) Uani 1 1 d . . . . .
C18 C 0.5289(6) 0.3751(4) 0.39849(18) 0.0097(11) Uani 1 1 d . . . . .
C19 C 0.6761(6) 0.3714(4) 0.36916(16) 0.0101(11) Uani 1 1 d . . . . .
C20 C 0.7493(6) 0.4600(3) 0.35796(14) 0.0117(10) Uani 1 1 d . . . . .
H20 H 0.845211 0.461621 0.338174 0.014 Uiso 1 1 calc R U . . .
C21 C 0.6841(6) 0.5470(4) 0.37537(17) 0.0115(11) Uani 1 1 d . . . . .
C22 C 0.7392(7) 0.6472(3) 0.36776(16) 0.0123(10) Uani 1 1 d . . . . .
C23 C 0.8692(6) 0.6847(4) 0.34075(19) 0.0151(12) Uani 1 1 d . . . . .
H23 H 0.941024 0.642949 0.323640 0.018 Uiso 1 1 calc R U . . .
C24 C 0.8918(6) 0.7845(4) 0.33927(19) 0.0168(13) Uani 1 1 d . . . . .
H24 H 0.981184 0.811008 0.321305 0.020 Uiso 1 1 calc R U . . .
C25 C 0.7858(6) 0.8458(4) 0.36368(19) 0.0167(12) Uani 1 1 d . . . . .
H25 H 0.801915 0.913851 0.361840 0.020 Uiso 1 1 calc R U . . .
C26 C 0.6558(7) 0.8085(4) 0.39086(19) 0.0170(13) Uani 1 1 d . . . . .
H26 H 0.583379 0.850610 0.407577 0.020 Uiso 1 1 calc R U . . .
C27 C 0.6333(6) 0.7084(4) 0.39324(18) 0.0114(11) Uani 1 1 d . . . . .
C28 C 0.4999(6) 0.6512(4) 0.41965(18) 0.0128(12) Uani 1 1 d . . . . .
C29 C 0.5435(6) 0.5480(4) 0.40537(17) 0.0107(11) Uani 1 1 d . . . . .
C30 C 0.4652(6) 0.4617(4) 0.41636(18) 0.0137(12) Uani 1 1 d . . . . .
H30 H 0.368687 0.461101 0.435935 0.016 Uiso 1 1 calc R U . . .
C31 C 0.1930(5) 0.3097(3) 0.45336(17) 0.0104(11) Uani 1 1 d . . . . .
C32 C 0.2615(6) 0.3309(3) 0.49575(15) 0.0135(10) Uani 1 1 d . . . . .
H32 H 0.369811 0.305888 0.504609 0.016 Uiso 1 1 calc R U . . .
C33 C 0.1680(6) 0.3890(4) 0.52452(18) 0.0155(12) Uani 1 1 d . . . . .
H33 H 0.213421 0.404903 0.553398 0.019 Uiso 1 1 calc R U . . .
C34 C 0.0089(6) 0.4247(4) 0.51205(19) 0.0156(12) Uani 1 1 d . . . . .
H34 H -0.052656 0.466025 0.531935 0.019 Uiso 1 1 calc R U . . .
C35 C -0.0604(6) 0.3997(4) 0.47027(19) 0.0162(13) Uani 1 1 d . . . . .
H35 H -0.170666 0.422644 0.461874 0.019 Uiso 1 1 calc R U . . .
C36 C 0.0320(6) 0.3412(4) 0.44089(18) 0.0138(12) Uani 1 1 d . . . . .
H36 H -0.015088 0.323070 0.412494 0.017 Uiso 1 1 calc R U . . .
C37 C 0.5245(6) 0.6651(4) 0.47121(17) 0.0156(12) Uani 1 1 d . . . . .
H37A H 0.499211 0.733338 0.478874 0.019 Uiso 1 1 calc R U . . .
H37B H 0.439992 0.624156 0.487265 0.019 Uiso 1 1 calc R U . . .
C38 C 0.7030(7) 0.6404(4) 0.4887(2) 0.0253(14) Uani 1 1 d . . . . .
H38A H 0.728021 0.572179 0.482347 0.038 Uiso 1 1 calc R U . . .
H38B H 0.707827 0.651659 0.521359 0.038 Uiso 1 1 calc R U . . .
H38C H 0.787881 0.681311 0.473482 0.038 Uiso 1 1 calc R U . . .
C39 C 0.3177(6) 0.6843(4) 0.40562(18) 0.0159(12) Uani 1 1 d . . . . .
H39A H 0.309882 0.754954 0.410767 0.019 Uiso 1 1 calc R U . . .
H39B H 0.305474 0.673387 0.372684 0.019 Uiso 1 1 calc R U . . .
C40 C 0.1656(6) 0.6368(4) 0.4291(2) 0.0229(14) Uani 1 1 d . . . . .
H40A H 0.060495 0.671930 0.421333 0.034 Uiso 1 1 calc R U . . .
H40B H 0.182831 0.638587 0.461893 0.034 Uiso 1 1 calc R U . . .
H40C H 0.155705 0.569472 0.419048 0.034 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N4 2.001(4) . ?
Pt1 C19 2.019(5) . ?
Pt1 N1 2.047(3) . ?
Pt1 O1 2.080(3) . ?
O1 C1 1.310(6) . ?
N1 C7 1.322(6) . ?
N1 C8 1.387(6) . ?
N2 C3 1.329(6) . ?
N2 C4 1.360(6) . ?
N3 C5 1.359(5) . ?
N3 C9 1.459(7) . ?
N3 C10 1.468(7) . ?
N4 C11 1.319(6) . ?
N4 C12 1.394(6) . ?
N5 C11 1.370(5) . ?
N5 C17 1.399(6) . ?
N5 C31 1.448(6) . ?
C1 C2 1.380(7) . ?
C1 C8 1.426(7) . ?
C2 C3 1.399(6) . ?
C2 H2 0.9500 . ?
C3 H3 0.9500 . ?
C4 C8 1.431(7) . ?
C4 C5 1.445(7) . ?
C5 C6 1.411(7) . ?
C6 C7 1.392(7) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C18 1.447(7) . ?
C12 C13 1.392(7) . ?
C12 C17 1.409(7) . ?
C13 C14 1.387(6) . ?
C13 H13 0.9500 . ?
C14 C15 1.400(7) . ?
C14 H14 0.9500 . ?
C15 C16 1.390(7) . ?
C15 H15 0.9500 . ?
C16 C17 1.381(7) . ?
C16 H16 0.9500 . ?
C18 C30 1.400(7) . ?
C18 C19 1.440(6) . ?
C19 C20 1.391(6) . ?
C20 C21 1.404(6) . ?
C20 H20 0.9500 . ?
C21 C29 1.410(6) . ?
C21 C22 1.466(6) . ?
C22 C23 1.391(7) . ?
C22 C27 1.402(7) . ?
C23 C24 1.392(7) . ?
C23 H23 0.9500 . ?
C24 C25 1.387(7) . ?
C24 H24 0.9500 . ?
C25 C26 1.393(7) . ?
C25 H25 0.9500 . ?
C26 C27 1.396(7) . ?
C26 H26 0.9500 . ?
C27 C28 1.522(7) . ?
C28 C29 1.526(7) . ?
C28 C37 1.548(7) . ?
C28 C39 1.550(6) . ?
C29 C30 1.378(7) . ?
C30 H30 0.9500 . ?
C31 C36 1.379(6) . ?
C31 C32 1.393(6) . ?
C32 C33 1.379(7) . ?
C32 H32 0.9500 . ?
C33 C34 1.386(7) . ?
C33 H33 0.9500 . ?
C34 C35 1.391(7) . ?
C34 H34 0.9500 . ?
C35 C36 1.389(7) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
C37 C38 1.524(6) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C40 1.523(6) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Pt1 C19 79.96(18) . . ?
N4 Pt1 N1 174.26(17) . . ?
C19 Pt1 N1 104.96(18) . . ?
N4 Pt1 O1 94.45(15) . . ?
C19 Pt1 O1 173.78(17) . . ?
N1 Pt1 O1 80.77(16) . . ?
C1 O1 Pt1 112.2(3) . . ?
C7 N1 C8 116.3(4) . . ?
C7 N1 Pt1 132.2(4) . . ?
C8 N1 Pt1 111.5(3) . . ?
C3 N2 C4 117.7(4) . . ?
C5 N3 C9 125.5(5) . . ?
C5 N3 C10 119.0(5) . . ?
C9 N3 C10 115.3(4) . . ?
C11 N4 C12 108.1(4) . . ?
C11 N4 Pt1 116.0(3) . . ?
C12 N4 Pt1 135.8(3) . . ?
C11 N5 C17 107.2(4) . . ?
C11 N5 C31 127.4(4) . . ?
C17 N5 C31 125.2(4) . . ?
O1 C1 C2 123.9(5) . . ?
O1 C1 C8 118.4(5) . . ?
C2 C1 C8 117.6(5) . . ?
C1 C2 C3 119.0(5) . . ?
C1 C2 H2 120.5 . . ?
C3 C2 H2 120.5 . . ?
N2 C3 C2 125.1(5) . . ?
N2 C3 H3 117.5 . . ?
C2 C3 H3 117.5 . . ?
N2 C4 C8 121.3(5) . . ?
N2 C4 C5 121.3(4) . . ?
C8 C4 C5 117.4(5) . . ?
N3 C5 C6 119.6(5) . . ?
N3 C5 C4 124.2(5) . . ?
C6 C5 C4 116.1(4) . . ?
C7 C6 C5 121.4(5) . . ?
C7 C6 H6 119.3 . . ?
C5 C6 H6 119.3 . . ?
N1 C7 C6 124.4(5) . . ?
N1 C7 H7 117.8 . . ?
C6 C7 H7 117.8 . . ?
N1 C8 C1 116.7(4) . . ?
N1 C8 C4 124.1(5) . . ?
C1 C8 C4 119.2(5) . . ?
N3 C9 H9A 109.5 . . ?
N3 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
N3 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N3 C10 H10A 109.5 . . ?
N3 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
N3 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
N4 C11 N5 111.1(4) . . ?
N4 C11 C18 117.3(4) . . ?
N5 C11 C18 131.2(5) . . ?
C13 C12 N4 131.7(5) . . ?
C13 C12 C17 120.8(5) . . ?
N4 C12 C17 107.5(5) . . ?
C14 C13 C12 116.7(5) . . ?
C14 C13 H13 121.7 . . ?
C12 C13 H13 121.7 . . ?
C13 C14 C15 122.2(5) . . ?
C13 C14 H14 118.9 . . ?
C15 C14 H14 118.9 . . ?
C16 C15 C14 121.3(5) . . ?
C16 C15 H15 119.3 . . ?
C14 C15 H15 119.3 . . ?
C17 C16 C15 116.6(5) . . ?
C17 C16 H16 121.7 . . ?
C15 C16 H16 121.7 . . ?
C16 C17 N5 131.4(5) . . ?
C16 C17 C12 122.4(5) . . ?
N5 C17 C12 106.2(4) . . ?
C30 C18 C19 122.7(5) . . ?
C30 C18 C11 125.3(4) . . ?
C19 C18 C11 111.4(4) . . ?
C20 C19 C18 116.1(5) . . ?
C20 C19 Pt1 129.9(4) . . ?
C18 C19 Pt1 114.0(4) . . ?
C19 C20 C21 121.2(4) . . ?
C19 C20 H20 119.4 . . ?
C21 C20 H20 119.4 . . ?
C20 C21 C29 121.4(5) . . ?
C20 C21 C22 130.2(5) . . ?
C29 C21 C22 108.4(5) . . ?
C23 C22 C27 120.9(5) . . ?
C23 C22 C21 130.8(5) . . ?
C27 C22 C21 108.3(5) . . ?
C22 C23 C24 118.7(5) . . ?
C22 C23 H23 120.7 . . ?
C24 C23 H23 120.7 . . ?
C25 C24 C23 120.9(5) . . ?
C25 C24 H24 119.5 . . ?
C23 C24 H24 119.5 . . ?
C24 C25 C26 120.5(5) . . ?
C24 C25 H25 119.7 . . ?
C26 C25 H25 119.7 . . ?
C25 C26 C27 119.2(5) . . ?
C25 C26 H26 120.4 . . ?
C27 C26 H26 120.4 . . ?
C26 C27 C22 119.8(5) . . ?
C26 C27 C28 128.8(5) . . ?
C22 C27 C28 111.4(5) . . ?
C27 C28 C29 101.0(4) . . ?
C27 C28 C37 110.9(4) . . ?
C29 C28 C37 111.1(4) . . ?
C27 C28 C39 109.7(4) . . ?
C29 C28 C39 114.0(4) . . ?
C37 C28 C39 109.9(4) . . ?
C30 C29 C21 119.0(5) . . ?
C30 C29 C28 130.1(5) . . ?
C21 C29 C28 110.8(5) . . ?
C29 C30 C18 119.6(5) . . ?
C29 C30 H30 120.2 . . ?
C18 C30 H30 120.2 . . ?
C36 C31 C32 121.5(5) . . ?
C36 C31 N5 119.1(4) . . ?
C32 C31 N5 119.3(4) . . ?
C33 C32 C31 118.3(5) . . ?
C33 C32 H32 120.8 . . ?
C31 C32 H32 120.8 . . ?
C32 C33 C34 121.1(5) . . ?
C32 C33 H33 119.4 . . ?
C34 C33 H33 119.4 . . ?
C33 C34 C35 119.7(5) . . ?
C33 C34 H34 120.1 . . ?
C35 C34 H34 120.1 . . ?
C36 C35 C34 119.9(5) . . ?
C36 C35 H35 120.1 . . ?
C34 C35 H35 120.1 . . ?
C31 C36 C35 119.3(5) . . ?
C31 C36 H36 120.3 . . ?
C35 C36 H36 120.3 . . ?
C38 C37 C28 114.8(4) . . ?
C38 C37 H37A 108.6 . . ?
C28 C37 H37A 108.6 . . ?
C38 C37 H37B 108.6 . . ?
C28 C37 H37B 108.6 . . ?
H37A C37 H37B 107.6 . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C40 C39 C28 117.8(4) . . ?
C40 C39 H39A 107.9 . . ?
C28 C39 H39A 107.9 . . ?
C40 C39 H39B 107.9 . . ?
C28 C39 H39B 107.9 . . ?
H39A C39 H39B 107.2 . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?

_refine_diff_density_max         0.655
_refine_diff_density_min         -0.728
_refine_diff_density_rms         0.103

