# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
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data_200903dyf_qsiidt_4f_0m
_database_code_depnum_ccdc_archive 'CCDC 2039335'
loop_
_audit_author_name
_audit_author_address
QSiIDTF
; The Cambridge Crystallographic Data Centre
China
;
_audit_update_record             
;
2020-10-19 deposited with the CCDC.	2021-01-10 downloaded from the CCDC.
;
_audit_creation_date             2020-09-04
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C28 H30 F2 O2 S Si'
_chemical_formula_sum            'C28 H30 F2 O2 S Si'
_chemical_formula_weight         496.67
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0148 0.0070 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0599 0.0411 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0412 0.0250 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.2924 0.4247 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2148 0.2488 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   15.4494(9)
_cell_length_b                   5.8637(3)
_cell_length_c                   28.4818(16)
_cell_angle_alpha                90
_cell_angle_beta                 93.615(4)
_cell_angle_gamma                90
_cell_volume                     2575.1(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    4729
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      52.426
_cell_measurement_theta_min      2.76
_shelx_estimated_absorpt_T_max   0.976
_shelx_estimated_absorpt_T_min   0.888
_exptl_absorpt_coefficient_mu    1.216
_exptl_absorpt_correction_T_max  0.7508
_exptl_absorpt_correction_T_min  0.5606
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1745 before and 0.1048 after correction. The Ratio of minimum to maximum transmission is 0.7146. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.281
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             1048
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1768
_diffrn_reflns_av_unetI/netI     0.1382
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            24964
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         54.958
_diffrn_reflns_theta_min         2.760
_diffrn_ambient_temperature      193.02
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34139
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2300
_reflns_number_total             4880
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.712
_refine_diff_density_min         -0.417
_refine_diff_density_rms         0.079
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     309
_refine_ls_number_reflns         4880
_refine_ls_number_restraints     28
_refine_ls_R_factor_all          0.1908
_refine_ls_R_factor_gt           0.0928
_refine_ls_restrained_S_all      1.050
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1391P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2214
_refine_ls_wR_factor_ref         0.2818
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C27-C28 = C27-C26 = C26-C25 = C25-C24
 1.53 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
C24 \\sim C25 \\sim C26 \\sim C27 \\sim C28: within 2A with sigma of 0.01 and
sigma for terminal atoms of 0.02
4.a Secondary CH2 refined with riding coordinates:
 C17(H17A,H17B), C18(H18A,H18B), C19(H19A,H19B), C20(H20A,H20B), C21(H21A,
 H21B), C23(H23A,H23B), C24(H24A,H24B), C25(H25A,H25B), C26(H26A,H26B),
 C27(H27A,H27B)
4.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C6(H6), C11(H11), C14(H14)
4.c Idealised Me refined as rotating group:
 C22(H22A,H22B,H22C), C28(H28A,H28B,H28C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
S1 S 0.36055(9) 0.4522(2) 0.44212(5) 0.0520(5) Uani 1 1 d . . . . .
Si1 Si 0.64090(10) 1.1843(3) 0.42673(5) 0.0483(5) Uani 1 1 d . . . . .
F1 F 0.0932(2) -0.6736(6) 0.35090(13) 0.0799(11) Uani 1 1 d . . . . .
F2 F -0.0102(2) -0.6382(6) 0.42096(12) 0.0752(11) Uani 1 1 d . . . . .
O1 O 0.3011(3) 0.0628(7) 0.38365(14) 0.0699(12) Uani 1 1 d . . . . .
O2 O 0.1151(2) 0.1118(7) 0.50850(14) 0.0619(11) Uani 1 1 d . . . . .
C1 C 0.5586(3) 1.0554(9) 0.46470(18) 0.0449(13) Uani 1 1 d . . . . .
C2 C 0.5003(3) 0.8806(9) 0.45729(19) 0.0495(14) Uani 1 1 d . . . . .
H2 H 0.499250 0.798092 0.428550 0.059 Uiso 1 1 calc R . . . .
C3 C 0.4420(3) 0.8205(8) 0.49141(19) 0.0453(14) Uani 1 1 d . . . . .
C4 C 0.3790(3) 0.6488(9) 0.48696(19) 0.0465(14) Uani 1 1 d . . . . .
C5 C 0.3194(4) 0.6265(9) 0.52338(18) 0.0477(14) Uani 1 1 d . . . . .
C6 C 0.2587(3) 0.4640(8) 0.51244(18) 0.0450(13) Uani 1 1 d . . . . .
H6 H 0.211637 0.434058 0.531456 0.054 Uiso 1 1 calc R . . . .
C7 C 0.2714(3) 0.3420(9) 0.47011(19) 0.0481(14) Uani 1 1 d . . . . .
C8 C 0.2247(3) 0.1561(9) 0.45221(18) 0.0492(14) Uani 1 1 d . . . . .
C9 C 0.1500(4) 0.0532(10) 0.4731(2) 0.0495(14) Uani 1 1 d . . . . .
C10 C 0.1249(4) -0.1473(9) 0.44345(19) 0.0488(14) Uani 1 1 d . . . . .
C11 C 0.0592(4) -0.3011(10) 0.4491(2) 0.0567(16) Uani 1 1 d . . . . .
H11 H 0.021272 -0.286860 0.473897 0.068 Uiso 1 1 calc R . . . .
C12 C 0.0509(4) -0.4750(10) 0.4173(2) 0.0592(16) Uani 1 1 d . . . . .
C13 C 0.1052(4) -0.4930(10) 0.3805(2) 0.0608(17) Uani 1 1 d . . . . .
C14 C 0.1698(4) -0.3384(10) 0.3739(2) 0.0574(16) Uani 1 1 d . . . . .
H14 H 0.206319 -0.351271 0.348470 0.069 Uiso 1 1 calc R . . . .
C15 C 0.1791(4) -0.1637(9) 0.4061(2) 0.0511(15) Uani 1 1 d . . . . .
C16 C 0.2440(4) 0.0246(9) 0.4102(2) 0.0514(15) Uani 1 1 d . . . . .
C17 C 0.7203(3) 0.9824(9) 0.40452(19) 0.0502(14) Uani 1 1 d . . . . .
H17A H 0.744216 0.888400 0.431147 0.060 Uiso 1 1 calc R . . . .
H17B H 0.689600 0.878598 0.381667 0.060 Uiso 1 1 calc R . . . .
C18 C 0.7955(4) 1.0936(10) 0.3808(2) 0.0627(17) Uani 1 1 d . . . . .
H18A H 0.824761 1.202064 0.403258 0.075 Uiso 1 1 calc R . . . .
H18B H 0.771748 1.182476 0.353420 0.075 Uiso 1 1 calc R . . . .
C19 C 0.8630(4) 0.9260(11) 0.3642(2) 0.0704(18) Uani 1 1 d . . . . .
H19A H 0.913270 1.013907 0.354084 0.085 Uiso 1 1 calc R . . . .
H19B H 0.883699 0.829818 0.391189 0.085 Uiso 1 1 calc R . . . .
C20 C 0.8309(4) 0.7731(10) 0.3245(2) 0.0629(17) Uani 1 1 d . . . . .
H20A H 0.778569 0.692381 0.334044 0.075 Uiso 1 1 calc R . . . .
H20B H 0.813259 0.869521 0.297035 0.075 Uiso 1 1 calc R . . . .
C21 C 0.8947(4) 0.5992(11) 0.3095(2) 0.0696(18) Uani 1 1 d . . . . .
H21A H 0.909928 0.496448 0.336313 0.084 Uiso 1 1 calc R . . . .
H21B H 0.948315 0.678426 0.301368 0.084 Uiso 1 1 calc R . . . .
C22 C 0.8616(4) 0.4575(12) 0.2680(2) 0.087(2) Uani 1 1 d . . . . .
H22A H 0.850588 0.556431 0.240500 0.130 Uiso 1 1 calc GR . . . .
H22B H 0.807703 0.381334 0.275346 0.130 Uiso 1 1 calc GR . . . .
H22C H 0.905160 0.342768 0.261057 0.130 Uiso 1 1 calc GR . . . .
C23 C 0.5869(4) 1.3559(9) 0.37831(19) 0.0550(15) Uani 1 1 d . . . . .
H23A H 0.551454 1.476025 0.392176 0.066 Uiso 1 1 calc R . . . .
H23B H 0.632016 1.432372 0.360758 0.066 Uiso 1 1 calc R . . . .
C24 C 0.5287(4) 1.2149(11) 0.3437(2) 0.0752(19) Uani 1 1 d D U . . .
H24A H 0.561839 1.081049 0.333580 0.090 Uiso 1 1 calc R . . . .
H24B H 0.478630 1.157521 0.360276 0.090 Uiso 1 1 calc R . . . .
C25 C 0.4948(5) 1.3477(14) 0.3000(2) 0.101(2) Uani 1 1 d D U . . .
H25A H 0.544524 1.426605 0.286887 0.121 Uiso 1 1 calc R . . . .
H25B H 0.472111 1.236521 0.276169 0.121 Uiso 1 1 calc R . . . .
C26 C 0.4278(6) 1.5149(17) 0.3068(3) 0.131(3) Uani 1 1 d D U . . .
H26A H 0.451685 1.641239 0.326717 0.157 Uiso 1 1 calc R . . . .
H26B H 0.379730 1.443638 0.322898 0.157 Uiso 1 1 calc R . . . .
C27 C 0.3932(7) 1.610(2) 0.2577(4) 0.164(4) Uani 1 1 d D U . . .
H27A H 0.441976 1.678293 0.241652 0.197 Uiso 1 1 calc R . . . .
H27B H 0.369830 1.482115 0.237986 0.197 Uiso 1 1 calc R . . . .
C28 C 0.3309(9) 1.768(2) 0.2614(4) 0.227(6) Uani 1 1 d D U . . .
H28A H 0.275242 1.705998 0.248726 0.341 Uiso 1 1 calc GR . . . .
H28B H 0.345306 1.904101 0.243701 0.341 Uiso 1 1 calc GR . . . .
H28C H 0.326600 1.807416 0.294621 0.341 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
S1 C4 1.731(5) . ?
S1 C7 1.757(5) . ?
Si1 C1 1.879(5) . ?
Si1 C5 1.875(5) 3_676 ?
Si1 C17 1.845(5) . ?
Si1 C23 1.861(5) . ?
F1 C13 1.359(6) . ?
F2 C12 1.353(6) . ?
O1 C16 1.218(6) . ?
O2 C9 1.221(6) . ?
C1 C2 1.371(7) . ?
C1 C3 1.447(7) 3_676 ?
C2 H2 0.9500 . ?
C2 C3 1.411(7) . ?
C3 C4 1.400(7) . ?
C4 C5 1.435(7) . ?
C5 C6 1.360(7) . ?
C6 H6 0.9500 . ?
C6 C7 1.426(7) . ?
C7 C8 1.386(7) . ?
C8 C9 1.463(8) . ?
C8 C16 1.471(7) . ?
C9 C10 1.486(7) . ?
C10 C11 1.375(7) . ?
C10 C15 1.400(8) . ?
C11 H11 0.9500 . ?
C11 C12 1.363(7) . ?
C12 C13 1.389(9) . ?
C13 C14 1.369(8) . ?
C14 H14 0.9500 . ?
C14 C15 1.375(7) . ?
C15 C16 1.491(8) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C17 C18 1.526(7) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C18 C19 1.530(8) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C19 C20 1.502(8) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C20 C21 1.499(8) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C21 C22 1.508(8) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C23 C24 1.533(8) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C24 C25 1.532(8) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C25 C26 1.448(9) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C26 C27 1.568(10) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C27 C28 1.344(12) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C4 S1 C7 90.4(3) . . ?
C5 Si1 C1 90.1(2) 3_676 . ?
C17 Si1 C1 115.3(2) . . ?
C17 Si1 C5 116.6(2) . 3_676 ?
C17 Si1 C23 111.7(3) . . ?
C23 Si1 C1 110.9(2) . . ?
C23 Si1 C5 110.6(2) . 3_676 ?
C2 C1 Si1 132.3(4) . . ?
C2 C1 C3 118.0(5) . 3_676 ?
C3 C1 Si1 109.6(4) 3_676 . ?
C1 C2 H2 119.3 . . ?
C1 C2 C3 121.5(5) . . ?
C3 C2 H2 119.3 . . ?
C2 C3 C1 120.5(5) . 3_676 ?
C4 C3 C1 113.4(5) . 3_676 ?
C4 C3 C2 126.0(5) . . ?
C3 C4 S1 128.8(4) . . ?
C3 C4 C5 118.3(5) . . ?
C5 C4 S1 112.9(4) . . ?
C4 C5 Si1 107.5(4) . 3_676 ?
C6 C5 Si1 140.9(4) . 3_676 ?
C6 C5 C4 111.3(5) . . ?
C5 C6 H6 122.7 . . ?
C5 C6 C7 114.5(5) . . ?
C7 C6 H6 122.7 . . ?
C6 C7 S1 110.7(4) . . ?
C8 C7 S1 121.8(4) . . ?
C8 C7 C6 127.5(5) . . ?
C7 C8 C9 125.5(5) . . ?
C7 C8 C16 125.8(5) . . ?
C9 C8 C16 108.7(5) . . ?
O2 C9 C8 128.4(5) . . ?
O2 C9 C10 125.3(5) . . ?
C8 C9 C10 106.2(5) . . ?
C11 C10 C9 128.4(6) . . ?
C11 C10 C15 121.7(5) . . ?
C15 C10 C9 109.9(5) . . ?
C10 C11 H11 121.5 . . ?
C12 C11 C10 116.9(6) . . ?
C12 C11 H11 121.5 . . ?
F2 C12 C11 121.0(6) . . ?
F2 C12 C13 117.5(6) . . ?
C11 C12 C13 121.5(6) . . ?
F1 C13 C12 117.6(6) . . ?
F1 C13 C14 120.3(6) . . ?
C14 C13 C12 122.2(6) . . ?
C13 C14 H14 121.6 . . ?
C13 C14 C15 116.7(6) . . ?
C15 C14 H14 121.6 . . ?
C10 C15 C16 108.7(5) . . ?
C14 C15 C10 121.0(5) . . ?
C14 C15 C16 130.2(6) . . ?
O1 C16 C8 126.9(5) . . ?
O1 C16 C15 126.7(5) . . ?
C8 C16 C15 106.4(5) . . ?
Si1 C17 H17A 108.6 . . ?
Si1 C17 H17B 108.6 . . ?
H17A C17 H17B 107.6 . . ?
C18 C17 Si1 114.7(4) . . ?
C18 C17 H17A 108.6 . . ?
C18 C17 H17B 108.6 . . ?
C17 C18 H18A 108.6 . . ?
C17 C18 H18B 108.6 . . ?
C17 C18 C19 114.5(5) . . ?
H18A C18 H18B 107.6 . . ?
C19 C18 H18A 108.6 . . ?
C19 C18 H18B 108.6 . . ?
C18 C19 H19A 108.6 . . ?
C18 C19 H19B 108.6 . . ?
H19A C19 H19B 107.6 . . ?
C20 C19 C18 114.7(5) . . ?
C20 C19 H19A 108.6 . . ?
C20 C19 H19B 108.6 . . ?
C19 C20 H20A 108.4 . . ?
C19 C20 H20B 108.4 . . ?
H20A C20 H20B 107.5 . . ?
C21 C20 C19 115.5(5) . . ?
C21 C20 H20A 108.4 . . ?
C21 C20 H20B 108.4 . . ?
C20 C21 H21A 108.8 . . ?
C20 C21 H21B 108.8 . . ?
C20 C21 C22 113.8(5) . . ?
H21A C21 H21B 107.7 . . ?
C22 C21 H21A 108.8 . . ?
C22 C21 H21B 108.8 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si1 C23 H23A 108.8 . . ?
Si1 C23 H23B 108.8 . . ?
H23A C23 H23B 107.7 . . ?
C24 C23 Si1 113.7(4) . . ?
C24 C23 H23A 108.8 . . ?
C24 C23 H23B 108.8 . . ?
C23 C24 H24A 108.8 . . ?
C23 C24 H24B 108.8 . . ?
H24A C24 H24B 107.7 . . ?
C25 C24 C23 113.9(6) . . ?
C25 C24 H24A 108.8 . . ?
C25 C24 H24B 108.8 . . ?
C24 C25 H25A 108.2 . . ?
C24 C25 H25B 108.2 . . ?
H25A C25 H25B 107.3 . . ?
C26 C25 C24 116.5(7) . . ?
C26 C25 H25A 108.2 . . ?
C26 C25 H25B 108.2 . . ?
C25 C26 H26A 109.8 . . ?
C25 C26 H26B 109.8 . . ?
C25 C26 C27 109.2(8) . . ?
H26A C26 H26B 108.3 . . ?
C27 C26 H26A 109.8 . . ?
C27 C26 H26B 109.8 . . ?
C26 C27 H27A 109.2 . . ?
C26 C27 H27B 109.2 . . ?
H27A C27 H27B 107.9 . . ?
C28 C27 C26 112.2(11) . . ?
C28 C27 H27A 109.2 . . ?
C28 C27 H27B 109.2 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
