# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_362
_audit_block_doi                 10.25505/fiz.icsd.cc277q6f
_database_code_depnum_ccdc_archive 'CCDC 2062994'
loop_
_audit_author_name
_audit_author_address
'Xiaoming Wang'
;Shaanxi Normal University
China
;
_audit_update_record             
;
2021-02-16 deposited with the CCDC.	2021-03-10 downloaded from the CCDC.
;
_audit_creation_date             2020-12-17
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'La2.31 N10.31 O1.69 Si5 Sr3.69'
_chemical_formula_sum            'La2.31 N10.31 O1.69 Si5 Sr3.69'
_chemical_formula_weight         956.13
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
La La -1.4094 9.0376 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sr Sr -0.3528 1.8200 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   14.9017(2)
_cell_length_b                   5.47450(10)
_cell_length_c                   16.0571(2)
_cell_angle_alpha                90
_cell_angle_beta                 98.8730(10)
_cell_angle_gamma                90
_cell_volume                     1294.25(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    5264
_cell_measurement_temperature    120.00(10)
_cell_measurement_theta_max      75.6610
_cell_measurement_theta_min      3.7680
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    81.445
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.55405
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.19a (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    4.907
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1710
_exptl_crystal_preparation       Luminescent
_exptl_crystal_recrystallization_method 'From the Melt'
_exptl_crystal_size_max          0.06
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.04
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0514
_diffrn_reflns_av_unetI/netI     0.0404
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            11318
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         74.479
_diffrn_reflns_theta_min         3.768
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      120.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean ?
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.994

_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.1015864000
_diffrn_orient_matrix_UB_12      0.0571441000
_diffrn_orient_matrix_UB_13      0.0268570000
_diffrn_orient_matrix_UB_21      0.0083111000
_diffrn_orient_matrix_UB_22      -0.2182931000
_diffrn_orient_matrix_UB_23      0.0612510000
_diffrn_orient_matrix_UB_31      0.0237472000
_diffrn_orient_matrix_UB_32      -0.1681577000
_diffrn_orient_matrix_UB_33      -0.0703684000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'PhotonJet R (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2225
_reflns_number_total             2628
_reflns_odcompleteness_completeness 98.10
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     77.17
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.19a (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.40.19a (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.40.19a (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2017/1 (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.982
_refine_diff_density_min         -1.883
_refine_diff_density_rms         0.362
_refine_ls_extinction_coef       0.000054(17)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2017/1 (Sheldrick 2017)'
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     187
_refine_ls_number_reflns         2628
_refine_ls_number_restraints     5
_refine_ls_R_factor_all          0.0440
_refine_ls_R_factor_gt           0.0354
_refine_ls_restrained_S_all      1.071
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0595P)²+2.7445P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0913
_refine_ls_wR_factor_ref         0.0956
_refine_special_details          ?

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sr5 Sr 0.94578(4) 1.24556(9) 0.04968(3) 0.00503(15) Uiso 0.4 1 d D . P A 6
Sr2 Sr 0.33231(3) -0.31232(10) 0.28396(3) 0.00470(15) Uani 0.5 1 d D . P B 4
Sr3 Sr 0.73056(4) 0.27022(10) 0.50838(3) 0.00404(16) Uiso 0.64 1 d . . P C 10
La1 La 0.07292(4) 0.71309(10) 0.33994(3) 0.00879(16) Uani 0.5 1 d . . P D 7
Sr4 Sr 0.82566(4) 0.75858(10) 0.22178(4) 0.00684(17) Uani 0.65 1 d D . P A 11
Sr6 Sr 0.41514(4) 0.74584(11) 0.01509(4) 0.00304(17) Uani 1 1 d . . . . .
Si1 Si 0.27395(14) 0.2307(4) 0.40030(13) 0.0065(4) Uani 1 1 d D . . . .
Si2 Si 0.75366(15) 1.2625(4) 0.11260(13) 0.0068(4) Uani 1 1 d . . . . .
Si3 Si 0.54189(15) 0.7551(4) 0.26167(13) 0.0059(4) Uani 1 1 d . . . . .
Si4 Si 0.48210(15) 0.2458(4) 0.35734(13) 0.0070(4) Uani 1 1 d . . . . .
Si5 Si 0.62199(15) 0.7568(4) 0.10369(13) 0.0065(4) Uani 1 1 d . . . . .
N2 N 0.2026(4) 0.4525(12) 0.3601(4) 0.0155(14) Uani 0.5775 1 d D . P E 13
N7 N 0.5016(4) 0.4663(12) 0.2837(4) 0.0095(13) Uani 1 1 d . . . . .
N11 N 0.5300(5) 0.8082(13) 0.1553(4) 0.0099(13) Uani 1 1 d . . . . .
N12 N 0.6810(5) 1.4904(13) 0.1340(4) 0.0111(10) Uani 1 1 d . . . . .
N3 N 0.5648(5) 0.2380(12) 0.4445(4) 0.0151(10) Uani 0.5775 1 d . . P F 15
N6 N 0.4719(5) -0.0318(13) 0.3049(4) 0.0111(10) Uani 1 1 d D . . . .
N9 N 0.7744(5) 1.2832(13) 0.0091(5) 0.0109(14) Uani 1 1 d D . . . .
N8 N 0.7038(5) 0.9856(14) 0.1237(4) 0.0122(14) Uani 1 1 d . . . . .
N4 N 0.5825(5) 0.7485(12) -0.0049(4) 0.0153(15) Uani 0.5775 1 d . . P G 19
N10 N 0.8484(5) 1.2797(13) 0.1861(4) 0.0120(15) Uani 1 1 d D . . . .
N1 N 0.2367(5) -0.0332(13) 0.3524(4) 0.0206(15) Uani 0.5775 1 d . . P E 18
N5 N 0.3804(5) 0.3301(15) 0.3889(5) 0.0151(10) Uani 1 1 d . . . . .
La2 La 0.33231(3) -0.31232(10) 0.28396(3) 0.00470(15) Uani 0.5 1 d D . P B 3
La5 La 0.94578(4) 1.24556(9) 0.04968(3) 0.00503(15) Uiso 0.6 1 d D . P A 5
Sr1 Sr 0.07292(4) 0.71309(10) 0.33994(3) 0.00879(16) Uani 0.5 1 d . . P H 8
La3 La 0.73056(4) 0.27022(10) 0.50838(3) 0.00404(16) Uiso 0.36 1 d . . P I 9
La4 La 0.82566(4) 0.75858(10) 0.22178(4) 0.00684(17) Uani 0.35 1 d D . P A 12
O2 O 0.2026(4) 0.4525(12) 0.3601(4) 0.0155(14) Uani 0.4225 1 d D . P E 14
O3 O 0.5648(5) 0.2380(12) 0.4445(4) 0.0151(10) Uani 0.4225 1 d . . P F 16
O1 O 0.2367(5) -0.0332(13) 0.3524(4) 0.0206(15) Uani 0.4225 1 d . . P E 17
O4 O 0.5825(5) 0.7485(12) -0.0049(4) 0.0153(15) Uani 0.4225 1 d . . P G 20


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sr5 Sr5 3.7031(10) 3_785 ?
Sr5 Sr5 3.6306(10) 3_775 ?
Sr5 Si1 3.230(2) 4_675 ?
Sr5 Si3 3.007(2) 2_655 ?
Sr5 Si4 3.217(2) 4_675 ?
Sr5 Si4 3.221(2) 2_655 ?
Sr5 Si4 3.223(2) 2_665 ?
Sr5 N7 3.076(7) 2_655 ?
Sr5 N6 2.749(7) 2_665 ?
Sr5 N9 2.545(7) . ?
Sr5 N10 2.814(7) . ?
Sr5 N5 2.648(7) 4_675 ?
Sr2 Sr2 3.7248(7) 2_545 ?
Sr2 Sr2 3.7248(7) 2 ?
Sr2 Sr6 4.6807(8) 1_545 ?
Sr2 Si1 3.318(2) 1_545 ?
Sr2 Si1 3.686(2) . ?
Sr2 Si1 3.142(2) 2_545 ?
Sr2 Si3 3.219(2) 1_545 ?
Sr2 Si4 3.378(2) 1_545 ?
Sr2 N7 2.799(6) 1_545 ?
Sr2 N6 2.566(7) . ?
Sr2 N5 2.610(8) 1_545 ?
Sr3 Sr6 3.9330(8) 4_666 ?
Sr3 Sr6 3.8086(8) 4_676 ?
Sr3 Si1 3.106(2) 3_666 ?
Sr3 Si1 3.115(2) 3_656 ?
Sr3 Si2 3.420(2) 2_635 ?
Sr3 Si2 3.352(2) 2_645 ?
Sr3 Si5 3.048(2) 2_645 ?
Sr3 N12 3.200(7) 2_635 ?
Sr3 N9 2.681(7) 2_635 ?
Sr3 N9 2.822(7) 2_645 ?
Sr3 N8 2.736(7) 2_645 ?
Sr3 N5 3.329(8) 3_666 ?
La1 Sr6 3.9404(9) 4_576 ?
La1 Sr6 3.4447(8) 2_545 ?
La1 Sr6 3.7188(8) 2 ?
La1 Si3 3.319(2) 2_545 ?
La1 Si4 3.152(2) 2 ?
La1 N7 2.533(7) 2 ?
La1 N11 2.703(7) 2_545 ?
La1 N6 2.678(7) 2 ?
Sr4 Si2 3.320(2) 1_545 ?
Sr4 Si2 3.072(2) 2_645 ?
Sr4 Si3 3.346(2) 2_655 ?
Sr4 Si3 3.377(2) 2_645 ?
Sr4 Si4 3.309(2) 2_655 ?
Sr4 N7 2.828(7) 2_655 ?
Sr4 N12 2.656(7) 2_645 ?
Sr4 N12 2.802(7) 1_545 ?
Sr4 N8 2.986(7) 2_645 ?
Sr4 N10 2.716(7) 1_545 ?
Sr4 N10 2.940(7) . ?
Sr4 N10 3.180(7) 2_645 ?
Sr6 Si1 3.313(2) 2 ?
Sr6 Si2 2.990(2) 3_675 ?
Sr6 Si5 3.321(2) 3_675 ?
Sr6 N2 3.076(7) 2 ?
Sr6 N11 2.631(7) . ?
Sr6 N12 2.898(7) 3_675 ?
Sr6 N9 2.795(7) 3_675 ?
Sr6 N8 3.008(7) 3_675 ?
Sr6 N4 2.712(7) 3_665 ?
Sr6 N4 2.564(7) . ?
Sr6 N4 2.773(7) 3_675 ?
Sr6 O4 2.564(7) . ?
Si1 N2 1.676(7) . ?
Si1 N9 1.748(7) 4_576 ?
Si1 N1 1.689(7) . ?
Si1 N5 1.713(8) . ?
Si1 O2 1.676(7) . ?
Si1 O1 1.689(7) . ?
Si2 N12 1.721(7) . ?
Si2 N9 1.740(7) . ?
Si2 N8 1.710(8) . ?
Si2 N10 1.698(7) . ?
Si2 La4 3.355(2) . ?
Si3 N7 1.747(7) . ?
Si3 N11 1.715(7) . ?
Si3 N6 1.775(7) 1_565 ?
Si3 N10 1.723(7) 2_645 ?
Si4 N7 1.745(7) . ?
Si4 N3 1.716(7) . ?
Si4 N6 1.733(7) . ?
Si4 N5 1.733(8) . ?
Si4 O3 1.716(7) . ?
Si5 N11 1.731(7) . ?
Si5 N12 1.733(7) 1_545 ?
Si5 N8 1.743(8) . ?
Si5 N4 1.753(7) . ?
Si5 La4 3.321(2) . ?
Si5 O4 1.753(7) . ?
N6 La2 2.566(7) . ?
N9 La5 2.545(7) . ?
N8 La4 2.538(7) . ?
N10 La5 2.814(7) . ?
N10 La4 2.940(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si1 Sr5 Sr5 89.91(4) 4_675 3_785 ?
Si1 Sr5 Sr5 93.39(4) 4_675 3_775 ?
Si3 Sr5 Sr5 117.26(5) 2_655 3_785 ?
Si3 Sr5 Sr5 119.56(5) 2_655 3_775 ?
Si3 Sr5 Si1 131.74(6) 2_655 4_675 ?
Si3 Sr5 Si4 65.39(5) 2_655 2_655 ?
Si3 Sr5 Si4 166.84(6) 2_655 4_675 ?
Si3 Sr5 Si4 63.54(6) 2_655 2_665 ?
Si3 Sr5 N7 33.35(13) 2_655 2_655 ?
Si4 Sr5 Sr5 133.91(4) 2_665 3_775 ?
Si4 Sr5 Sr5 134.59(4) 2_655 3_785 ?
Si4 Sr5 Sr5 54.98(4) 4_675 3_785 ?
Si4 Sr5 Sr5 55.72(4) 4_675 3_775 ?
Si4 Sr5 Sr5 54.82(4) 2_665 3_785 ?
Si4 Sr5 Sr5 55.62(4) 2_655 3_775 ?
Si4 Sr5 Si1 118.64(5) 2_665 4_675 ?
Si4 Sr5 Si1 61.18(6) 4_675 4_675 ?
Si4 Sr5 Si1 123.23(5) 2_655 4_675 ?
Si4 Sr5 Si4 109.80(4) 4_675 2_665 ?
Si4 Sr5 Si4 111.34(4) 4_675 2_655 ?
Si4 Sr5 Si4 116.32(7) 2_655 2_665 ?
N7 Sr5 Sr5 86.74(13) 2_655 3_775 ?
N7 Sr5 Sr5 132.76(12) 2_655 3_785 ?
N7 Sr5 Si1 137.09(13) 2_655 4_675 ?
N7 Sr5 Si4 89.85(13) 2_655 2_665 ?
N7 Sr5 Si4 32.08(13) 2_655 2_655 ?
N7 Sr5 Si4 141.65(13) 2_655 4_675 ?
N6 Sr5 Sr5 82.26(14) 2_665 3_785 ?
N6 Sr5 Sr5 122.08(15) 2_665 3_775 ?
N6 Sr5 Si1 144.25(16) 2_665 4_675 ?
N6 Sr5 Si3 35.57(15) 2_665 2_655 ?
N6 Sr5 Si4 133.62(15) 2_665 4_675 ?
N6 Sr5 Si4 32.52(15) 2_665 2_665 ?
N6 Sr5 Si4 84.81(15) 2_665 2_655 ?
N6 Sr5 N7 57.4(2) 2_665 2_655 ?
N6 Sr5 N10 61.7(2) 2_665 . ?
N9 Sr5 Sr5 108.44(16) . 3_785 ?
N9 Sr5 Sr5 116.39(16) . 3_775 ?
N9 Sr5 Si1 32.57(17) . 4_675 ?
N9 Sr5 Si3 99.18(17) . 2_655 ?
N9 Sr5 Si4 107.44(17) . 2_665 ?
N9 Sr5 Si4 93.66(17) . 4_675 ?
N9 Sr5 Si4 115.93(16) . 2_655 ?
N9 Sr5 N7 112.0(2) . 2_655 ?
N9 Sr5 N6 118.7(2) . 2_665 ?
N9 Sr5 N10 64.9(2) . . ?
N9 Sr5 N5 63.8(2) . 4_675 ?
N10 Sr5 Sr5 126.66(14) . 3_785 ?
N10 Sr5 Sr5 135.16(14) . 3_775 ?
N10 Sr5 Si1 97.50(15) . 4_675 ?
N10 Sr5 Si3 34.24(15) . 2_655 ?
N10 Sr5 Si4 76.00(15) . 2_665 ?
N10 Sr5 Si4 82.58(15) . 2_655 ?
N10 Sr5 Si4 158.38(15) . 4_675 ?
N10 Sr5 N7 56.55(19) . 2_655 ?
N5 Sr5 Sr5 65.01(17) 4_675 3_775 ?
N5 Sr5 Sr5 79.46(17) 4_675 3_785 ?
N5 Sr5 Si1 31.97(16) 4_675 4_675 ?
N5 Sr5 Si3 160.24(17) 4_675 2_655 ?
N5 Sr5 Si4 129.11(18) 4_675 2_665 ?
N5 Sr5 Si4 32.58(16) 4_675 4_675 ?
N5 Sr5 Si4 111.44(18) 4_675 2_655 ?
N5 Sr5 N7 140.9(2) 4_675 2_655 ?
N5 Sr5 N6 161.2(2) 4_675 2_665 ?
N5 Sr5 N10 127.8(2) 4_675 . ?
Si1 Sr2 Sr2 120.07(4) 1_545 2 ?
Si1 Sr2 Sr2 57.02(4) 2_545 2 ?
Si1 Sr2 Sr2 52.60(4) 1_545 2_545 ?
Si1 Sr2 Sr2 50.17(3) . 2 ?
Si1 Sr2 Sr2 123.02(4) . 2_545 ?
Si1 Sr2 Sr2 64.27(4) 2_545 2_545 ?
Si1 Sr2 Sr6 134.43(4) 1_545 1_545 ?
Si1 Sr2 Sr6 121.94(4) . 1_545 ?
Si1 Sr2 Sr6 44.98(4) 2_545 1_545 ?
Si1 Sr2 Si1 116.68(6) 2_545 1_545 ?
Si1 Sr2 Si1 107.03(6) 2_545 . ?
Si1 Sr2 Si1 102.71(6) 1_545 . ?
Si1 Sr2 Si3 104.08(6) 2_545 1_545 ?
Si1 Sr2 Si4 126.30(5) 2_545 1_545 ?
Si1 Sr2 Si4 58.67(5) 1_545 1_545 ?
Si3 Sr2 Sr2 119.31(4) 1_545 2 ?
Si3 Sr2 Sr2 131.16(4) 1_545 2_545 ?
Si3 Sr2 Sr6 59.42(4) 1_545 1_545 ?
Si3 Sr2 Si1 105.82(5) 1_545 . ?
Si3 Sr2 Si1 119.48(5) 1_545 1_545 ?
Si3 Sr2 Si4 61.36(5) 1_545 1_545 ?
Si4 Sr2 Sr2 176.63(4) 1_545 2 ?
Si4 Sr2 Sr2 86.89(4) 1_545 2_545 ?
Si4 Sr2 Sr6 96.68(4) 1_545 1_545 ?
Si4 Sr2 Si1 126.56(5) 1_545 . ?
N7 Sr2 Sr2 150.54(14) 1_545 2 ?
N7 Sr2 Sr2 103.56(14) 1_545 2_545 ?
N7 Sr2 Sr6 70.26(13) 1_545 1_545 ?
N7 Sr2 Si1 110.77(14) 1_545 2_545 ?
N7 Sr2 Si1 129.27(14) 1_545 . ?
N7 Sr2 Si1 89.37(14) 1_545 1_545 ?
N7 Sr2 Si3 32.80(15) 1_545 1_545 ?
N7 Sr2 Si4 31.06(14) 1_545 1_545 ?
N6 Sr2 Sr2 164.19(15) . 2_545 ?
N6 Sr2 Sr2 94.74(15) . 2 ?
N6 Sr2 Sr6 75.89(15) . 1_545 ?
N6 Sr2 Si1 111.05(15) . 2_545 ?
N6 Sr2 Si1 130.94(15) . 1_545 ?
N6 Sr2 Si1 72.60(15) . . ?
N6 Sr2 Si3 33.38(16) . 1_545 ?
N6 Sr2 Si4 84.49(16) . 1_545 ?
N6 Sr2 N7 63.0(2) . 1_545 ?
N6 Sr2 N5 103.2(2) . 1_545 ?
N5 Sr2 Sr2 74.96(16) 1_545 2_545 ?
N5 Sr2 Sr2 147.45(17) 1_545 2 ?
N5 Sr2 Sr6 124.15(17) 1_545 1_545 ?
N5 Sr2 Si1 109.91(17) 1_545 . ?
N5 Sr2 Si1 30.74(16) 1_545 1_545 ?
N5 Sr2 Si1 135.43(17) 1_545 2_545 ?
N5 Sr2 Si3 89.06(16) 1_545 1_545 ?
N5 Sr2 Si4 30.34(17) 1_545 1_545 ?
N5 Sr2 N7 61.2(2) 1_545 1_545 ?
Sr6 Sr3 Sr6 89.993(18) 4_676 4_666 ?
Si1 Sr3 Sr6 131.83(4) 3_656 4_676 ?
Si1 Sr3 Sr6 56.15(4) 3_666 4_676 ?
Si1 Sr3 Sr6 133.22(4) 3_666 4_666 ?
Si1 Sr3 Sr6 54.59(4) 3_656 4_666 ?
Si1 Sr3 Si1 123.26(7) 3_666 3_656 ?
Si1 Sr3 Si2 172.46(6) 3_666 2_635 ?
Si1 Sr3 Si2 171.56(6) 3_656 2_645 ?
Si1 Sr3 Si2 64.84(5) 3_666 2_645 ?
Si1 Sr3 Si2 63.92(5) 3_656 2_635 ?
Si1 Sr3 N12 87.48(13) 3_656 2_635 ?
Si1 Sr3 N12 143.09(13) 3_666 2_635 ?
Si1 Sr3 N5 107.28(14) 3_656 3_666 ?
Si1 Sr3 N5 30.62(13) 3_666 3_666 ?
Si2 Sr3 Sr6 117.95(4) 2_635 4_676 ?
Si2 Sr3 Sr6 48.86(4) 2_645 4_676 ?
Si2 Sr3 Sr6 47.36(4) 2_635 4_666 ?
Si2 Sr3 Sr6 118.83(4) 2_645 4_666 ?
Si2 Sr3 Si2 107.89(6) 2_645 2_635 ?
Si5 Sr3 Sr6 55.53(4) 2_645 4_666 ?
Si5 Sr3 Sr6 56.65(4) 2_645 4_676 ?
Si5 Sr3 Si1 109.05(6) 2_645 3_656 ?
Si5 Sr3 Si1 111.71(6) 2_645 3_666 ?
Si5 Sr3 Si2 61.71(5) 2_645 2_635 ?
Si5 Sr3 Si2 63.63(5) 2_645 2_645 ?
Si5 Sr3 N12 32.10(13) 2_645 2_635 ?
Si5 Sr3 N5 140.05(14) 2_645 3_666 ?
N12 Sr3 Sr6 46.55(12) 2_635 4_666 ?
N12 Sr3 Sr6 88.74(12) 2_635 4_676 ?
N12 Sr3 Si2 84.11(13) 2_635 2_645 ?
N12 Sr3 Si2 29.90(13) 2_635 2_635 ?
N12 Sr3 N5 163.61(19) 2_635 3_666 ?
N9 Sr3 Sr6 134.65(15) 2_635 4_676 ?
N9 Sr3 Sr6 136.46(14) 2_645 4_666 ?
N9 Sr3 Sr6 45.26(15) 2_635 4_666 ?
N9 Sr3 Sr6 47.01(14) 2_645 4_676 ?
N9 Sr3 Si1 157.02(15) 2_645 3_656 ?
N9 Sr3 Si1 33.86(15) 2_645 3_666 ?
N9 Sr3 Si1 157.21(16) 2_635 3_666 ?
N9 Sr3 Si1 34.06(16) 2_635 3_656 ?
N9 Sr3 Si2 30.16(16) 2_635 2_635 ?
N9 Sr3 Si2 139.05(15) 2_645 2_635 ?
N9 Sr3 Si2 31.27(15) 2_645 2_645 ?
N9 Sr3 Si2 137.93(16) 2_635 2_645 ?
N9 Sr3 Si5 88.59(15) 2_645 2_645 ?
N9 Sr3 Si5 85.68(16) 2_635 2_645 ?
N9 Sr3 N12 114.37(19) 2_645 2_635 ?
N9 Sr3 N12 57.1(2) 2_635 2_635 ?
N9 Sr3 N9 168.4(3) 2_635 2_645 ?
N9 Sr3 N8 110.8(2) 2_635 2_645 ?
N9 Sr3 N5 134.3(2) 2_635 3_666 ?
N9 Sr3 N5 52.3(2) 2_645 3_666 ?
N8 Sr3 Sr6 89.92(15) 2_645 4_666 ?
N8 Sr3 Sr6 51.61(15) 2_645 4_676 ?
N8 Sr3 Si1 91.33(16) 2_645 3_666 ?
N8 Sr3 Si1 141.30(16) 2_645 3_656 ?
N8 Sr3 Si2 81.13(16) 2_645 2_635 ?
N8 Sr3 Si2 30.54(15) 2_645 2_645 ?
N8 Sr3 Si5 34.53(15) 2_645 2_645 ?
N8 Sr3 N12 54.3(2) 2_645 2_635 ?
N8 Sr3 N9 60.1(2) 2_645 2_645 ?
N8 Sr3 N5 111.4(2) 2_645 3_666 ?
N5 Sr3 Sr6 86.58(13) 3_666 4_676 ?
N5 Sr3 Sr6 149.01(12) 3_666 4_666 ?
N5 Sr3 Si2 153.98(13) 3_666 2_635 ?
N5 Sr3 Si2 80.98(14) 3_666 2_645 ?
Sr6 La1 Sr6 62.247(19) 2_545 4_576 ?
Sr6 La1 Sr6 58.981(18) 2 4_576 ?
Sr6 La1 Sr6 99.61(2) 2_545 2 ?
Si3 La1 Sr6 150.63(4) 2_545 2 ?
Si3 La1 Sr6 94.29(4) 2_545 4_576 ?
Si3 La1 Sr6 74.94(4) 2_545 2_545 ?
Si4 La1 Sr6 124.36(4) 2 2 ?
Si4 La1 Sr6 134.39(4) 2 2_545 ?
Si4 La1 Sr6 128.51(4) 2 4_576 ?
Si4 La1 Si3 60.95(5) 2 2_545 ?
N7 La1 Sr6 106.89(15) 2 4_576 ?
N7 La1 Sr6 91.96(15) 2 2 ?
N7 La1 Sr6 155.06(15) 2 2_545 ?
N7 La1 Si3 84.13(15) 2 2_545 ?
N7 La1 Si4 33.56(16) 2 2 ?
N7 La1 N11 106.8(2) 2 2_545 ?
N7 La1 N6 64.7(2) 2 2 ?
N11 La1 Sr6 48.88(15) 2_545 2_545 ?
N11 La1 Sr6 126.73(15) 2_545 2 ?
N11 La1 Sr6 67.86(15) 2_545 4_576 ?
N11 La1 Si3 30.98(15) 2_545 2_545 ?
N11 La1 Si4 90.82(15) 2_545 2 ?
N6 La1 Sr6 101.24(15) 2 2_545 ?
N6 La1 Sr6 123.49(15) 2 4_576 ?
N6 La1 Sr6 156.58(15) 2 2 ?
N6 La1 Si3 32.25(15) 2 2_545 ?
N6 La1 Si4 33.34(15) 2 2 ?
N6 La1 N11 63.1(2) 2 2_545 ?
Si2 Sr4 Si2 109.07(6) 2_645 1_545 ?
Si2 Sr4 Si3 60.74(5) 1_545 2_645 ?
Si2 Sr4 Si3 103.64(6) 2_645 2_645 ?
Si2 Sr4 Si3 147.71(6) 1_545 2_655 ?
Si2 Sr4 Si3 103.09(6) 2_645 2_655 ?
Si2 Sr4 Si4 143.51(6) 2_645 2_655 ?
Si2 Sr4 N10 31.45(13) 2_645 2_645 ?
Si3 Sr4 Si3 109.05(6) 2_655 2_645 ?
Si4 Sr4 Si2 90.48(5) 2_655 1_545 ?
Si4 Sr4 Si3 58.86(5) 2_655 2_645 ?
Si4 Sr4 Si3 60.83(5) 2_655 2_655 ?
N7 Sr4 Si2 119.85(14) 2_655 2_645 ?
N7 Sr4 Si2 122.29(14) 2_655 1_545 ?
N7 Sr4 Si3 78.87(15) 2_655 2_645 ?
N7 Sr4 Si3 31.47(14) 2_655 2_655 ?
N7 Sr4 Si4 31.83(14) 2_655 2_655 ?
N7 Sr4 N8 118.57(19) 2_655 2_645 ?
N7 Sr4 N10 58.0(2) 2_655 . ?
N7 Sr4 N10 144.25(18) 2_655 2_645 ?
N12 Sr4 Si2 33.98(15) 2_645 2_645 ?
N12 Sr4 Si2 31.21(15) 1_545 1_545 ?
N12 Sr4 Si2 94.04(15) 1_545 2_645 ?
N12 Sr4 Si2 143.02(15) 2_645 1_545 ?
N12 Sr4 Si3 114.93(16) 2_645 2_645 ?
N12 Sr4 Si3 149.79(15) 1_545 2_655 ?
N12 Sr4 Si3 69.12(15) 2_645 2_655 ?
N12 Sr4 Si3 90.39(15) 1_545 2_645 ?
N12 Sr4 Si4 119.73(15) 2_645 2_655 ?
N12 Sr4 Si4 116.11(14) 1_545 2_655 ?
N12 Sr4 N7 145.92(19) 1_545 2_655 ?
N12 Sr4 N7 89.5(2) 2_645 2_655 ?
N12 Sr4 N12 124.03(11) 2_645 1_545 ?
N12 Sr4 N8 59.0(2) 2_645 2_645 ?
N12 Sr4 N8 87.5(2) 1_545 2_645 ?
N12 Sr4 N10 74.2(2) 2_645 . ?
N12 Sr4 N10 68.51(19) 1_545 2_645 ?
N12 Sr4 N10 131.9(2) 2_645 1_545 ?
N12 Sr4 N10 120.88(19) 1_545 . ?
N12 Sr4 N10 55.54(19) 2_645 2_645 ?
N8 Sr4 Si2 87.28(14) 2_645 1_545 ?
N8 Sr4 Si2 32.74(14) 2_645 2_645 ?
N8 Sr4 Si3 71.64(14) 2_645 2_645 ?
N8 Sr4 Si3 120.07(14) 2_645 2_655 ?
N8 Sr4 Si4 123.73(14) 2_645 2_655 ?
N8 Sr4 N10 52.91(19) 2_645 2_645 ?
N10 Sr4 Si2 30.64(15) 1_545 1_545 ?
N10 Sr4 Si2 136.77(14) . 1_545 ?
N10 Sr4 Si2 103.48(15) . 2_645 ?
N10 Sr4 Si2 93.15(13) 2_645 1_545 ?
N10 Sr4 Si2 105.46(16) 1_545 2_645 ?
N10 Sr4 Si3 116.55(13) 2_645 2_655 ?
N10 Sr4 Si3 120.13(13) 2_645 2_645 ?
N10 Sr4 Si3 135.21(16) 1_545 2_655 ?
N10 Sr4 Si3 30.47(15) 1_545 2_645 ?
N10 Sr4 Si3 30.98(14) . 2_655 ?
N10 Sr4 Si3 136.38(15) . 2_645 ?
N10 Sr4 Si4 75.82(16) 1_545 2_655 ?
N10 Sr4 Si4 174.86(13) 2_645 2_655 ?
N10 Sr4 Si4 79.22(15) . 2_655 ?
N10 Sr4 N7 103.8(2) 1_545 2_655 ?
N10 Sr4 N12 60.0(2) 1_545 1_545 ?
N10 Sr4 N8 133.1(2) . 2_645 ?
N10 Sr4 N8 74.4(2) 1_545 2_645 ?
N10 Sr4 N10 105.7(2) 1_545 2_645 ?
N10 Sr4 N10 100.5(2) . 2_645 ?
N10 Sr4 N10 150.9(3) 1_545 . ?
Si1 Sr6 Si5 100.32(6) 2 3_675 ?
Si2 Sr6 Si1 66.55(5) 3_675 2 ?
Si2 Sr6 Si5 64.58(6) 3_675 3_675 ?
Si2 Sr6 N2 87.03(13) 3_675 2 ?
Si2 Sr6 N8 33.12(14) 3_675 3_675 ?
N11 Sr6 Si1 97.71(15) . 2 ?
N11 Sr6 Si2 162.89(15) . 3_675 ?
N11 Sr6 Si5 114.43(16) . 3_675 ?
N11 Sr6 N2 75.87(19) . 2 ?
N11 Sr6 N12 159.7(2) . 3_675 ?
N11 Sr6 N9 129.5(2) . 3_675 ?
N11 Sr6 N8 143.3(2) . 3_675 ?
N11 Sr6 N4 99.7(2) . 3_665 ?
N11 Sr6 N4 84.8(2) . 3_675 ?
N12 Sr6 Si1 89.09(14) 3_675 2 ?
N12 Sr6 Si2 33.94(14) 3_675 3_675 ?
N12 Sr6 Si5 82.78(14) 3_675 3_675 ?
N12 Sr6 N2 116.31(18) 3_675 2 ?
N12 Sr6 N8 56.4(2) 3_675 3_675 ?
N9 Sr6 Si1 31.84(15) 3_675 2 ?
N9 Sr6 Si2 34.81(15) 3_675 3_675 ?
N9 Sr6 Si5 83.77(15) 3_675 3_675 ?
N9 Sr6 N2 56.33(19) 3_675 2 ?
N9 Sr6 N12 60.0(2) 3_675 3_675 ?
N9 Sr6 N8 57.2(2) 3_675 3_675 ?
N8 Sr6 Si1 82.82(14) 3_675 2 ?
N8 Sr6 Si5 31.47(14) 3_675 3_675 ?
N8 Sr6 N2 88.45(19) 3_675 2 ?
N4 Sr6 N11 65.8(2) . . ?
O4 Sr6 N11 65.8(2) . . ?
Sr6 Si1 Sr2 121.70(6) 2_545 1_565 ?
N2 Si1 N5 105.7(4) . . ?
N9 Si1 Sr5 51.6(2) 4_576 4_576 ?
N9 Si1 Sr2 129.4(2) 4_576 1_565 ?
N9 Si1 Sr2 149.5(2) 4_576 2 ?
N9 Si1 Sr3 59.2(2) 4_576 3_656 ?
N9 Si1 Sr3 64.1(2) 4_576 3_666 ?
N9 Si1 Sr6 57.5(2) 4_576 2_545 ?
N1 Si1 N5 117.8(4) . . ?
N5 Si1 Sr5 55.0(2) . 4_576 ?
N5 Si1 Sr2 105.3(3) . 2 ?
N5 Si1 Sr2 51.2(3) . 1_565 ?
N5 Si1 Sr3 114.7(3) . 3_656 ?
N5 Si1 Sr3 81.9(3) . 3_666 ?
N5 Si1 Sr6 153.6(3) . 2_545 ?
N5 Si1 N9 105.1(3) . 4_576 ?
O2 Si1 N5 105.7(4) . . ?
O1 Si1 N5 117.8(4) . . ?
Sr6 Si2 Sr3 73.57(5) 3_675 2_655 ?
Sr6 Si2 Sr3 75.36(5) 3_675 2_665 ?
Sr6 Si2 Sr4 101.43(7) 3_675 2_655 ?
Sr6 Si2 La4 120.87(7) 3_675 . ?
N12 Si2 Sr3 67.9(2) . 2_665 ?
N12 Si2 Sr3 143.2(3) . 2_655 ?
N12 Si2 Sr4 59.6(2) . 2_655 ?
N12 Si2 Sr6 70.1(2) . 3_675 ?
N12 Si2 N9 110.7(3) . . ?
N12 Si2 La4 130.7(2) . . ?
N9 Si2 Sr3 50.7(2) . 2_665 ?
N9 Si2 Sr3 57.3(2) . 2_655 ?
N9 Si2 Sr4 167.3(3) . 2_655 ?
N9 Si2 Sr6 66.4(2) . 3_675 ?
N9 Si2 La4 117.6(2) . . ?
N8 Si2 Sr3 54.4(2) . 2_655 ?
N8 Si2 Sr3 148.1(3) . 2_665 ?
N8 Si2 Sr4 70.8(2) . 2_655 ?
N8 Si2 Sr6 74.0(2) . 3_675 ?
N8 Si2 N12 109.0(4) . . ?
N8 Si2 N9 107.5(3) . . ?
N8 Si2 La4 47.6(2) . . ?
N10 Si2 Sr3 108.8(3) . 2_655 ?
N10 Si2 Sr3 103.1(3) . 2_665 ?
N10 Si2 Sr4 77.8(3) . 2_655 ?
N10 Si2 Sr6 177.6(3) . 3_675 ?
N10 Si2 N12 107.6(4) . . ?
N10 Si2 N9 114.2(4) . . ?
N10 Si2 N8 107.8(3) . . ?
N10 Si2 La4 61.2(2) . . ?
N7 Si3 Sr5 75.5(2) . 2_645 ?
N7 Si3 Sr2 60.3(2) . 1_565 ?
N7 Si3 La1 128.0(2) . 2 ?
N7 Si3 Sr4 159.7(2) . 2_655 ?
N7 Si3 Sr4 57.7(2) . 2_645 ?
N7 Si3 N6 105.9(3) . 1_565 ?
N11 Si3 Sr5 170.9(3) . 2_645 ?
N11 Si3 Sr2 100.2(2) . 1_565 ?
N11 Si3 La1 54.2(2) . 2 ?
N11 Si3 Sr4 84.8(3) . 2_655 ?
N11 Si3 Sr4 100.7(2) . 2_645 ?
N11 Si3 N7 111.7(3) . . ?
N11 Si3 N6 107.5(3) . 1_565 ?
N11 Si3 N10 114.6(4) . 2_645 ?
N6 Si3 Sr5 64.3(2) 1_565 2_645 ?
N6 Si3 Sr2 52.7(2) 1_565 1_565 ?
N6 Si3 La1 53.6(2) 1_565 2 ?
N6 Si3 Sr4 78.7(2) 1_565 2_655 ?
N6 Si3 Sr4 151.3(2) 1_565 2_645 ?
N10 Si3 Sr5 66.7(3) 2_645 2_645 ?
N10 Si3 Sr2 144.9(3) 2_645 1_565 ?
N10 Si3 La1 124.0(3) 2_645 2 ?
N10 Si3 Sr4 53.1(2) 2_645 2_655 ?
N10 Si3 Sr4 61.4(2) 2_645 2_645 ?
N10 Si3 N7 107.6(3) 2_645 . ?
N10 Si3 N6 109.2(3) 2_645 1_565 ?
N7 Si4 Sr5 135.3(2) . 4_576 ?
N7 Si4 Sr5 145.4(2) . 2_635 ?
N7 Si4 Sr5 69.4(2) . 2_645 ?
N7 Si4 Sr2 55.8(2) . 1_565 ?
N7 Si4 La1 53.4(2) . 2_545 ?
N7 Si4 Sr4 58.7(2) . 2_645 ?
N3 Si4 N7 113.3(3) . . ?
N3 Si4 N6 111.8(3) . . ?
N3 Si4 N5 108.6(4) . . ?
N6 Si4 Sr5 117.7(2) . 4_576 ?
N6 Si4 Sr5 58.5(2) . 2_635 ?
N6 Si4 Sr5 165.5(3) . 2_645 ?
N6 Si4 Sr2 117.1(2) . 1_565 ?
N6 Si4 La1 58.1(2) . 2_545 ?
N6 Si4 Sr4 81.2(2) . 2_645 ?
N6 Si4 N7 106.8(3) . . ?
N6 Si4 N5 111.1(4) . . ?
N5 Si4 Sr5 109.6(3) . 2_635 ?
N5 Si4 Sr5 55.3(2) . 4_576 ?
N5 Si4 Sr5 83.3(3) . 2_645 ?
N5 Si4 Sr2 49.5(3) . 1_565 ?
N5 Si4 La1 101.8(2) . 2_545 ?
N5 Si4 Sr4 162.7(3) . 2_645 ?
N5 Si4 N7 105.0(4) . . ?
O3 Si4 N7 113.3(3) . . ?
O3 Si4 N6 111.8(3) . . ?
O3 Si4 N5 108.6(4) . . ?
Sr6 Si5 Sr6 110.41(6) 3_675 3_665 ?
N11 Si5 Sr3 167.2(3) . 2_655 ?
N11 Si5 Sr6 93.9(2) . 3_675 ?
N11 Si5 Sr6 109.5(2) . 3_665 ?
N11 Si5 N12 114.1(3) . 1_545 ?
N11 Si5 N8 112.2(4) . . ?
N11 Si5 N4 108.1(3) . . ?
N11 Si5 La4 116.6(2) . . ?
N11 Si5 O4 108.1(3) . . ?
N12 Si5 Sr3 78.8(2) 1_545 2_655 ?
N12 Si5 Sr6 60.0(2) 1_545 3_665 ?
N12 Si5 Sr6 152.0(3) 1_545 3_675 ?
N12 Si5 N8 104.1(4) 1_545 . ?
N12 Si5 N4 109.6(3) 1_545 . ?
N12 Si5 La4 57.5(2) 1_545 . ?
N12 Si5 O4 109.6(3) 1_545 . ?
N8 Si5 Sr3 62.9(2) . 2_655 ?
N8 Si5 Sr6 64.3(2) . 3_675 ?
N8 Si5 Sr6 138.3(3) . 3_665 ?
N8 Si5 N4 108.7(3) . . ?
N8 Si5 La4 48.8(2) . . ?
N8 Si5 O4 108.7(3) . . ?
Si1 N2 Sr6 82.8(3) . 2_545 ?
Si3 N7 Sr5 71.2(2) . 2_645 ?
Si3 N7 Sr2 86.9(3) . 1_565 ?
Si3 N7 La1 117.3(3) . 2_545 ?
Si3 N7 Sr4 90.8(3) . 2_645 ?
Si4 N7 Sr5 78.5(2) . 2_645 ?
Si4 N7 Sr2 93.1(3) . 1_565 ?
Si4 N7 La1 93.1(3) . 2_545 ?
Si4 N7 Sr4 89.5(3) . 2_645 ?
Si4 N7 Si3 149.5(4) . . ?
Sr6 N11 La1 80.44(19) . 2 ?
Si3 N11 La1 94.8(3) . 2 ?
Si3 N11 Sr6 141.6(4) . . ?
Si3 N11 Si5 118.8(4) . . ?
Si5 N11 La1 129.9(4) . 2 ?
Si5 N11 Sr6 91.6(3) . . ?
Sr6 N12 Sr3 80.17(16) 3_675 2_665 ?
Si2 N12 Sr3 82.2(3) . 2_665 ?
Si2 N12 Sr4 91.2(3) . 1_565 ?
Si2 N12 Sr4 86.4(3) . 2_655 ?
Si2 N12 Sr6 76.0(2) . 3_675 ?
Si2 N12 Si5 149.5(4) . 1_565 ?
Si5 N12 Sr3 69.1(2) 1_565 2_665 ?
Si5 N12 Sr4 124.1(3) 1_565 2_655 ?
Si5 N12 Sr4 91.0(3) 1_565 1_565 ?
Si5 N12 Sr6 88.8(3) 1_565 3_675 ?
Si3 N6 Sr5 80.2(2) 1_545 2_635 ?
Si3 N6 Sr2 93.9(3) 1_545 . ?
Si3 N6 La1 94.2(3) 1_545 2_545 ?
Si3 N6 La2 93.9(3) 1_545 . ?
Si4 N6 Sr5 89.0(3) . 2_635 ?
Si4 N6 Sr2 126.6(3) . . ?
Si4 N6 La1 88.5(3) . 2_545 ?
Si4 N6 Si3 138.9(4) . 1_545 ?
Si4 N6 La2 126.6(3) . . ?
Sr6 N9 Sr3 85.4(2) 3_675 2_655 ?
Si1 N9 Sr5 95.8(3) 4_675 . ?
Si1 N9 Sr3 82.0(3) 4_675 2_655 ?
Si1 N9 Sr3 86.7(3) 4_675 2_665 ?
Si1 N9 Sr6 90.6(3) 4_675 3_675 ?
Si1 N9 La5 95.8(3) 4_675 . ?
Si2 N9 Sr5 94.0(3) . . ?
Si2 N9 Sr3 99.1(3) . 2_665 ?
Si2 N9 Sr3 91.4(3) . 2_655 ?
Si2 N9 Sr6 78.7(3) . 3_675 ?
Si2 N9 Si1 168.0(5) . 4_675 ?
Si2 N9 La5 94.0(3) . . ?
Si2 N8 Sr3 95.0(3) . 2_655 ?
Si2 N8 Sr4 76.4(3) . 2_655 ?
Si2 N8 Sr6 72.9(2) . 3_675 ?
Si2 N8 Si5 157.1(5) . . ?
Si2 N8 La4 102.6(3) . . ?
Si5 N8 Sr3 82.6(3) . 2_655 ?
Si5 N8 Sr4 109.0(3) . 2_655 ?
Si5 N8 Sr6 84.2(3) . 3_675 ?
Si5 N8 La4 100.1(3) . . ?
Sr6 N4 Sr6 92.0(2) . 3_675 ?
Sr6 N4 Sr6 172.8(3) 3_665 3_675 ?
Sr6 N4 Sr6 91.3(2) . 3_665 ?
Si5 N4 Sr6 93.4(3) . . ?
Si5 N4 Sr6 91.6(3) . 3_675 ?
Si5 N4 Sr6 94.6(3) . 3_665 ?
Sr4 N10 Sr4 150.9(3) 1_565 . ?
Si2 N10 Sr5 85.9(3) . . ?
Si2 N10 Sr4 94.7(3) . 1_565 ?
Si2 N10 Sr4 88.5(3) . . ?
Si2 N10 Sr4 70.8(3) . 2_655 ?
Si2 N10 Si3 163.5(5) . 2_655 ?
Si2 N10 La5 85.9(3) . . ?
Si2 N10 La4 88.5(3) . . ?
Si3 N10 Sr5 79.0(3) 2_655 . ?
Si3 N10 Sr4 96.5(3) 2_655 1_565 ?
Si3 N10 Sr4 87.6(3) 2_655 . ?
Si3 N10 Sr4 123.5(3) 2_655 2_655 ?
Si3 N10 La5 79.0(3) 2_655 . ?
Si3 N10 La4 87.6(3) 2_655 . ?
Si1 N5 Sr5 93.1(3) . 4_576 ?
Si1 N5 Sr2 98.1(3) . 1_565 ?
Si1 N5 Sr3 67.5(2) . 3_666 ?
Si1 N5 Si4 144.4(5) . . ?
Si4 N5 Sr5 92.1(3) . 4_576 ?
Si4 N5 Sr2 100.1(3) . 1_565 ?
Si4 N5 Sr3 147.5(4) . 3_666 ?
Si1 La2 Si1 116.68(6) 2_545 1_545 ?
Si1 La2 Si3 104.08(6) 2_545 1_545 ?
Si1 La2 Si4 58.67(5) 1_545 1_545 ?
Si1 La2 Si4 126.30(5) 2_545 1_545 ?
Si3 La2 Si1 119.48(5) 1_545 1_545 ?
Si3 La2 Si4 61.36(5) 1_545 1_545 ?
N7 La2 Si1 110.77(14) 1_545 2_545 ?
N7 La2 Si1 89.37(14) 1_545 1_545 ?
N7 La2 Si3 32.80(15) 1_545 1_545 ?
N7 La2 Si4 31.06(14) 1_545 1_545 ?
N6 La2 Si1 111.05(15) . 2_545 ?
N6 La2 Si1 130.94(15) . 1_545 ?
N6 La2 Si3 33.38(16) . 1_545 ?
N6 La2 Si4 84.49(16) . 1_545 ?
N6 La2 N7 63.0(2) . 1_545 ?
N6 La2 N5 103.2(2) . 1_545 ?
N5 La2 Si1 135.43(17) 1_545 2_545 ?
N5 La2 Si1 30.74(16) 1_545 1_545 ?
N5 La2 Si3 89.06(16) 1_545 1_545 ?
N5 La2 Si4 30.34(17) 1_545 1_545 ?
N5 La2 N7 61.2(2) 1_545 1_545 ?
Si3 La5 Si1 131.74(6) 2_655 4_675 ?
Si3 La5 Si4 65.39(5) 2_655 2_655 ?
Si3 La5 Si4 166.84(6) 2_655 4_675 ?
Si3 La5 Si4 63.54(6) 2_655 2_665 ?
Si4 La5 Si1 118.64(5) 2_665 4_675 ?
Si4 La5 Si1 123.23(5) 2_655 4_675 ?
Si4 La5 Si1 61.18(6) 4_675 4_675 ?
Si4 La5 Si4 116.32(7) 2_655 2_665 ?
Si4 La5 Si4 111.34(4) 4_675 2_655 ?
Si4 La5 Si4 109.80(4) 4_675 2_665 ?
N6 La5 Si1 144.25(16) 2_665 4_675 ?
N6 La5 Si3 35.57(15) 2_665 2_655 ?
N6 La5 Si4 133.62(15) 2_665 4_675 ?
N6 La5 Si4 84.81(15) 2_665 2_655 ?
N6 La5 Si4 32.52(15) 2_665 2_665 ?
N6 La5 N10 61.7(2) 2_665 . ?
N9 La5 Si1 32.57(17) . 4_675 ?
N9 La5 Si3 99.18(17) . 2_655 ?
N9 La5 Si4 115.93(16) . 2_655 ?
N9 La5 Si4 93.66(17) . 4_675 ?
N9 La5 Si4 107.44(17) . 2_665 ?
N9 La5 N6 118.7(2) . 2_665 ?
N9 La5 N10 64.9(2) . . ?
N9 La5 N5 63.8(2) . 4_675 ?
N10 La5 Si1 97.50(15) . 4_675 ?
N10 La5 Si3 34.24(15) . 2_655 ?
N10 La5 Si4 158.38(15) . 4_675 ?
N10 La5 Si4 82.58(15) . 2_655 ?
N10 La5 Si4 76.00(15) . 2_665 ?
N5 La5 Si1 31.97(16) 4_675 4_675 ?
N5 La5 Si3 160.24(17) 4_675 2_655 ?
N5 La5 Si4 129.11(18) 4_675 2_665 ?
N5 La5 Si4 32.58(16) 4_675 4_675 ?
N5 La5 Si4 111.44(18) 4_675 2_655 ?
N5 La5 N6 161.2(2) 4_675 2_665 ?
N5 La5 N10 127.8(2) 4_675 . ?
Sr6 Sr1 Sr6 58.981(18) 2 4_576 ?
Sr6 Sr1 Sr6 62.247(19) 2_545 4_576 ?
Sr6 Sr1 Sr6 99.61(2) 2_545 2 ?
Sr6 Sr1 Si3 150.54(4) 2_545 2 ?
Si3 Sr1 Sr6 94.29(4) 2_545 4_576 ?
Si3 Sr1 Sr6 89.00(4) 2 4_576 ?
Si3 Sr1 Sr6 67.61(4) 2 2 ?
Si3 Sr1 Sr6 150.63(4) 2_545 2 ?
Si3 Sr1 Sr6 74.94(4) 2_545 2_545 ?
Si3 Sr1 Si3 102.83(6) 2_545 2 ?
Si4 Sr1 Sr6 124.36(4) 2 2 ?
Si4 Sr1 Sr6 134.39(4) 2 2_545 ?
Si4 Sr1 Sr6 128.51(4) 2 4_576 ?
Si4 Sr1 Si3 60.95(5) 2 2_545 ?
Si4 Sr1 Si3 58.49(5) 2 2 ?
N7 Sr1 Sr6 91.96(15) 2 2 ?
N7 Sr1 Sr6 155.06(15) 2 2_545 ?
N7 Sr1 Sr6 106.89(15) 2 4_576 ?
N7 Sr1 Si3 24.94(15) 2 2 ?
N7 Sr1 Si3 84.13(15) 2 2_545 ?
N7 Sr1 Si4 33.56(16) 2 2 ?
N7 Sr1 N11 106.8(2) 2 2_545 ?
N7 Sr1 N6 64.7(2) 2 2 ?
N11 Sr1 Sr6 126.73(15) 2_545 2 ?
N11 Sr1 Sr6 48.88(15) 2_545 2_545 ?
N11 Sr1 Sr6 67.86(15) 2_545 4_576 ?
N11 Sr1 Si3 30.98(15) 2_545 2_545 ?
N11 Sr1 Si3 116.55(15) 2_545 2 ?
N11 Sr1 Si4 90.82(15) 2_545 2 ?
N6 Sr1 Sr6 156.58(15) 2 2 ?
N6 Sr1 Sr6 123.49(15) 2 4_576 ?
N6 Sr1 Sr6 101.24(15) 2 2_545 ?
N6 Sr1 Si3 88.97(16) 2 2 ?
N6 Sr1 Si3 32.25(15) 2 2_545 ?
N6 Sr1 Si4 33.34(15) 2 2 ?
N6 Sr1 N11 63.1(2) 2 2_545 ?
Sr6 La3 Sr6 89.993(18) 4_676 4_666 ?
Si1 La3 Sr6 131.83(4) 3_656 4_676 ?
Si1 La3 Sr6 133.22(4) 3_666 4_666 ?
Si1 La3 Sr6 54.59(4) 3_656 4_666 ?
Si1 La3 Sr6 56.15(4) 3_666 4_676 ?
Si1 La3 Si1 123.26(7) 3_666 3_656 ?
Si1 La3 Si2 172.46(6) 3_666 2_635 ?
Si1 La3 Si2 171.56(6) 3_656 2_645 ?
Si1 La3 Si2 63.92(5) 3_656 2_635 ?
Si1 La3 Si2 64.84(5) 3_666 2_645 ?
Si2 La3 Sr6 117.95(4) 2_635 4_676 ?
Si2 La3 Sr6 47.36(4) 2_635 4_666 ?
Si2 La3 Sr6 118.83(4) 2_645 4_666 ?
Si2 La3 Sr6 48.86(4) 2_645 4_676 ?
Si2 La3 Si2 107.89(6) 2_645 2_635 ?
Si5 La3 Sr6 56.65(4) 2_645 4_676 ?
Si5 La3 Sr6 55.53(4) 2_645 4_666 ?
Si5 La3 Si1 111.71(6) 2_645 3_666 ?
Si5 La3 Si1 109.05(6) 2_645 3_656 ?
Si5 La3 Si2 61.71(5) 2_645 2_635 ?
Si5 La3 Si2 63.63(5) 2_645 2_645 ?
N9 La3 Sr6 136.46(14) 2_645 4_666 ?
N9 La3 Sr6 45.26(15) 2_635 4_666 ?
N9 La3 Sr6 47.01(14) 2_645 4_676 ?
N9 La3 Sr6 134.65(15) 2_635 4_676 ?
N9 La3 Si1 157.21(16) 2_635 3_666 ?
N9 La3 Si1 34.06(16) 2_635 3_656 ?
N9 La3 Si1 33.86(15) 2_645 3_666 ?
N9 La3 Si1 157.02(15) 2_645 3_656 ?
N9 La3 Si2 30.16(16) 2_635 2_635 ?
N9 La3 Si2 31.27(15) 2_645 2_645 ?
N9 La3 Si2 137.93(16) 2_635 2_645 ?
N9 La3 Si2 139.05(15) 2_645 2_635 ?
N9 La3 Si5 85.68(16) 2_635 2_645 ?
N9 La3 Si5 88.59(15) 2_645 2_645 ?
N9 La3 N9 168.4(3) 2_635 2_645 ?
N9 La3 N8 110.8(2) 2_635 2_645 ?
N8 La3 Sr6 51.61(15) 2_645 4_676 ?
N8 La3 Sr6 89.92(15) 2_645 4_666 ?
N8 La3 Si1 141.30(16) 2_645 3_656 ?
N8 La3 Si1 91.33(16) 2_645 3_666 ?
N8 La3 Si2 30.54(15) 2_645 2_645 ?
N8 La3 Si2 81.13(16) 2_645 2_635 ?
N8 La3 Si5 34.53(15) 2_645 2_645 ?
N8 La3 N9 60.1(2) 2_645 2_645 ?
Si2 La4 Si2 109.07(6) 2_645 1_545 ?
Si2 La4 Si3 147.71(6) 1_545 2_655 ?
Si2 La4 Si3 103.09(6) 2_645 2_655 ?
Si2 La4 Si4 143.51(6) 2_645 2_655 ?
Si2 La4 Si5 93.12(6) 2_645 . ?
Si2 La4 Si5 60.24(5) 1_545 . ?
Si4 La4 Si2 90.48(5) 2_655 1_545 ?
Si4 La4 Si3 60.83(5) 2_655 2_655 ?
Si4 La4 Si5 123.35(5) 2_655 . ?
Si5 La4 Si3 121.58(5) . 2_655 ?
N7 La4 Si2 119.85(14) 2_655 2_645 ?
N7 La4 Si2 122.29(14) 2_655 1_545 ?
N7 La4 Si3 31.47(14) 2_655 2_655 ?
N7 La4 Si4 31.83(14) 2_655 2_655 ?
N7 La4 Si5 137.68(14) 2_655 . ?
N7 La4 N8 118.57(19) 2_655 2_645 ?
N7 La4 N10 58.0(2) 2_655 . ?
N12 La4 Si2 31.21(15) 1_545 1_545 ?
N12 La4 Si2 143.02(15) 2_645 1_545 ?
N12 La4 Si2 94.04(15) 1_545 2_645 ?
N12 La4 Si2 33.98(15) 2_645 2_645 ?
N12 La4 Si3 149.79(15) 1_545 2_655 ?
N12 La4 Si3 69.12(15) 2_645 2_655 ?
N12 La4 Si4 119.73(15) 2_645 2_655 ?
N12 La4 Si4 116.11(14) 1_545 2_655 ?
N12 La4 Si5 31.45(15) 1_545 . ?
N12 La4 Si5 110.20(16) 2_645 . ?
N12 La4 N7 145.92(19) 1_545 2_655 ?
N12 La4 N7 89.5(2) 2_645 2_655 ?
N12 La4 N12 124.03(11) 2_645 1_545 ?
N12 La4 N8 87.5(2) 1_545 2_645 ?
N12 La4 N8 59.0(2) 2_645 2_645 ?
N12 La4 N10 120.88(19) 1_545 . ?
N12 La4 N10 131.9(2) 2_645 1_545 ?
N12 La4 N10 74.2(2) 2_645 . ?
N8 La4 Si2 101.51(16) . 2_645 ?
N8 La4 Si2 86.04(17) . 1_545 ?
N8 La4 Si2 32.74(14) 2_645 2_645 ?
N8 La4 Si2 87.28(14) 2_645 1_545 ?
N8 La4 Si3 90.48(17) . 2_655 ?
N8 La4 Si3 120.07(14) 2_645 2_655 ?
N8 La4 Si4 123.73(14) 2_645 2_655 ?
N8 La4 Si4 110.57(16) . 2_655 ?
N8 La4 Si5 103.56(14) 2_645 . ?
N8 La4 Si5 31.10(17) . . ?
N8 La4 N7 110.6(2) . 2_655 ?
N8 La4 N12 61.5(2) . 1_545 ?
N8 La4 N12 100.8(2) . 2_645 ?
N8 La4 N8 125.29(12) . 2_645 ?
N8 La4 N10 116.3(2) . 1_545 ?
N8 La4 N10 59.8(2) . . ?
N10 La4 Si2 30.64(15) 1_545 1_545 ?
N10 La4 Si2 105.46(16) 1_545 2_645 ?
N10 La4 Si2 136.77(14) . 1_545 ?
N10 La4 Si2 103.48(15) . 2_645 ?
N10 La4 Si3 30.98(14) . 2_655 ?
N10 La4 Si3 135.21(16) 1_545 2_655 ?
N10 La4 Si4 75.82(16) 1_545 2_655 ?
N10 La4 Si4 79.22(15) . 2_655 ?
N10 La4 Si5 90.82(14) . . ?
N10 La4 Si5 90.55(15) 1_545 . ?
N10 La4 N7 103.8(2) 1_545 2_655 ?
N10 La4 N12 60.0(2) 1_545 1_545 ?
N10 La4 N8 74.4(2) 1_545 2_645 ?
N10 La4 N8 133.1(2) . 2_645 ?
N10 La4 N10 150.9(3) 1_545 . ?
Si1 O2 Sr6 82.8(3) . 2_545 ?
Sr6 O4 Sr6 172.8(3) 3_665 3_675 ?
Sr6 O4 Sr6 92.0(2) . 3_675 ?
Sr6 O4 Sr6 91.3(2) . 3_665 ?
Si5 O4 Sr6 91.6(3) . 3_675 ?
Si5 O4 Sr6 94.6(3) . 3_665 ?
Si5 O4 Sr6 93.4(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Sr5 Si1 N5 Si4 97.9(8) 4_576 . . . ?
Sr5 Si3 N7 Si4 -6.4(8) 2_645 . . . ?
Sr5 Si4 N7 Sr5 -106.8(4) 2_635 . . 2_645 ?
Sr5 Si4 N7 Sr5 21.2(3) 4_576 . . 2_645 ?
Sr5 Si4 N7 Si3 -100.6(8) 2_635 . . . ?
Sr5 Si4 N7 Si3 6.2(7) 2_645 . . . ?
Sr5 Si4 N7 Si3 27.3(10) 4_576 . . . ?
Sr5 Si4 N6 Sr5 73.1(10) 2_645 . . 2_635 ?
Sr5 Si4 N6 Sr5 -39.7(3) 4_576 . . 2_635 ?
Sr5 Si4 N6 Si3 -0.6(15) 2_645 . . 1_545 ?
Sr5 Si4 N6 Si3 -113.4(6) 4_576 . . 1_545 ?
Sr5 Si4 N6 Si3 -73.7(6) 2_635 . . 1_545 ?
Sr5 Si4 N5 Sr5 46.9(3) 2_635 . . 4_576 ?
Sr5 Si4 N5 Sr5 -68.66(17) 2_645 . . 4_576 ?
Sr5 Si4 N5 Si1 -51.3(8) 2_635 . . . ?
Sr5 Si4 N5 Si1 -166.9(8) 2_645 . . . ?
Sr5 Si4 N5 Si1 -98.2(8) 4_576 . . . ?
Sr2 Si1 N5 Sr2 48.2(3) 2 . . 1_565 ?
Sr2 Si1 N5 Si4 -120.3(9) 1_565 . . . ?
Sr2 Si1 N5 Si4 -72.1(8) 2 . . . ?
Sr2 Si3 N7 Si4 -90.9(8) 1_565 . . . ?
Sr2 Si3 N11 Sr6 -20.4(6) 1_565 . . . ?
Sr2 Si3 N11 Si5 -158.6(4) 1_565 . . . ?
Sr2 Si4 N7 Si3 89.2(8) 1_565 . . . ?
Sr2 Si4 N6 Sr2 -59.0(4) 1_565 . . . ?
Sr2 Si4 N6 Si3 131.4(5) 1_565 . . 1_545 ?
Sr2 Si4 N5 Si1 119.7(9) 1_565 . . . ?
Sr3 Si1 N5 Sr3 -122.97(14) 3_656 . . 3_666 ?
Sr3 Si1 N5 Si4 171.2(8) 3_666 . . . ?
Sr3 Si1 N5 Si4 48.2(9) 3_656 . . . ?
Sr3 Si2 N12 Sr3 -90.7(4) 2_655 . . 2_665 ?
Sr3 Si2 N12 Sr6 -8.9(4) 2_655 . . 3_675 ?
Sr3 Si2 N12 Sr6 81.76(11) 2_665 . . 3_675 ?
Sr3 Si2 N12 Si5 19.6(8) 2_665 . . 1_565 ?
Sr3 Si2 N12 Si5 -71.1(11) 2_655 . . 1_565 ?
Sr3 Si2 N9 Sr3 175.0(3) 2_655 . . 2_665 ?
Sr3 Si2 N9 Sr3 -175.0(3) 2_665 . . 2_655 ?
Sr3 Si2 N9 Sr6 -90.0(2) 2_665 . . 3_675 ?
Sr3 Si2 N9 Sr6 85.01(18) 2_655 . . 3_675 ?
Sr3 Si2 N9 Si1 -118(2) 2_665 . . 4_675 ?
Sr3 Si2 N9 Si1 57(2) 2_655 . . 4_675 ?
Sr3 Si2 N8 Sr3 64.2(5) 2_665 . . 2_655 ?
Sr3 Si2 N8 Sr6 -80.97(17) 2_655 . . 3_675 ?
Sr3 Si2 N8 Sr6 -16.7(5) 2_665 . . 3_675 ?
Sr3 Si2 N8 Si5 -18.6(16) 2_665 . . . ?
Sr3 Si2 N8 Si5 -82.8(12) 2_655 . . . ?
Sr3 Si2 N10 Si3 28.8(17) 2_655 . . 2_655 ?
Sr3 Si2 N10 Si3 -85.6(16) 2_665 . . 2_655 ?
Sr3 Si5 N11 Sr6 64.3(12) 2_655 . . . ?
Sr3 Si5 N11 Si3 -140.2(9) 2_655 . . . ?
Sr3 Si5 N8 Sr6 83.57(15) 2_655 . . 3_675 ?
Sr3 Si5 N8 Si2 85.3(12) 2_655 . . . ?
La1 Si3 N7 La1 56.6(4) 2 . . 2_545 ?
La1 Si3 N7 Si4 -119.6(7) 2 . . . ?
La1 Si3 N11 Sr6 -80.6(5) 2 . . . ?
La1 Si3 N11 Si5 141.3(5) 2 . . . ?
La1 Si4 N7 Si3 176.6(10) 2_545 . . . ?
La1 Si4 N6 Si3 94.6(6) 2_545 . . 1_545 ?
La1 Si4 N5 Si1 71.7(8) 2_545 . . . ?
Sr4 Si2 N12 Sr4 86.53(18) 2_655 . . 1_565 ?
Sr4 Si2 N12 Sr6 -117.2(2) 2_655 . . 3_675 ?
Sr4 Si2 N12 Si5 -179.3(10) 2_655 . . 1_565 ?
Sr4 Si2 N9 Sr6 -17.5(12) 2_655 . . 3_675 ?
Sr4 Si2 N9 Si1 -46(3) 2_655 . . 4_675 ?
Sr4 Si2 N8 Sr6 108.52(13) 2_655 . . 3_675 ?
Sr4 Si2 N8 Si5 106.7(12) 2_655 . . . ?
Sr4 Si2 N10 Sr4 75.02(14) 2_655 . . . ?
Sr4 Si2 N10 Sr4 -76.01(17) 2_655 . . 1_565 ?
Sr4 Si2 N10 Si3 151.4(17) 2_655 . . 2_655 ?
Sr4 Si3 N7 Sr4 -53.4(7) 2_655 . . 2_645 ?
Sr4 Si3 N7 Si4 37.0(14) 2_655 . . . ?
Sr4 Si3 N7 Si4 90.4(8) 2_645 . . . ?
Sr4 Si3 N11 Sr6 -150.8(6) 2_655 . . . ?
Sr4 Si3 N11 Sr6 100.8(5) 2_645 . . . ?
Sr4 Si3 N11 Si5 -37.3(5) 2_645 . . . ?
Sr4 Si3 N11 Si5 71.1(4) 2_655 . . . ?
Sr4 Si4 N7 Si3 -90.7(8) 2_645 . . . ?
Sr4 Si4 N6 Si3 18.3(6) 2_645 . . 1_545 ?
Sr4 Si4 N5 Si1 145.3(6) 2_645 . . . ?
Sr6 Si1 N5 Sr5 57.9(7) 2_545 . . 4_576 ?
Sr6 Si1 N5 Sr2 -83.9(6) 2_545 . . 1_565 ?
Sr6 Si1 N5 Sr3 -15.4(6) 2_545 . . 3_666 ?
Sr6 Si1 N5 Si4 155.8(4) 2_545 . . . ?
Sr6 Si2 N12 Sr3 -81.76(11) 3_675 . . 2_665 ?
Sr6 Si2 N12 Sr4 117.2(2) 3_675 . . 2_655 ?
Sr6 Si2 N12 Sr4 -156.3(2) 3_675 . . 1_565 ?
Sr6 Si2 N12 Si5 -62.2(9) 3_675 . . 1_565 ?
Sr6 Si2 N9 Sr5 -172.5(3) 3_675 . . . ?
Sr6 Si2 N9 Sr3 90.0(2) 3_675 . . 2_665 ?
Sr6 Si2 N9 Sr3 -85.01(18) 3_675 . . 2_655 ?
Sr6 Si2 N9 Si1 -28(2) 3_675 . . 4_675 ?
Sr6 Si2 N9 La5 -172.5(3) 3_675 . . . ?
Sr6 Si2 N8 Sr3 80.97(17) 3_675 . . 2_655 ?
Sr6 Si2 N8 Sr4 -108.52(13) 3_675 . . 2_655 ?
Sr6 Si2 N8 Si5 -1.8(11) 3_675 . . . ?
Sr6 Si2 N8 La4 169.9(3) 3_675 . . . ?
Sr6 Si5 N11 La1 -13.5(4) 3_675 . . 2 ?
Sr6 Si5 N11 La1 -126.7(3) 3_665 . . 2 ?
Sr6 Si5 N11 Sr6 -47.9(2) 3_665 . . . ?
Sr6 Si5 N11 Sr6 65.38(17) 3_675 . . . ?
Sr6 Si5 N11 Si3 107.7(4) 3_665 . . . ?
Sr6 Si5 N11 Si3 -139.1(4) 3_675 . . . ?
Sr6 Si5 N8 Sr3 -83.57(15) 3_675 . . 2_655 ?
Sr6 Si5 N8 Sr3 8.8(4) 3_665 . . 2_655 ?
Sr6 Si5 N8 Sr4 -165.74(13) 3_665 . . 2_655 ?
Sr6 Si5 N8 Sr4 101.8(3) 3_675 . . 2_655 ?
Sr6 Si5 N8 Sr6 92.4(3) 3_665 . . 3_675 ?
Sr6 Si5 N8 Si2 94.2(12) 3_665 . . . ?
Sr6 Si5 N8 Si2 1.8(11) 3_675 . . . ?
Sr6 Si5 N8 La4 -170.0(3) 3_675 . . . ?
Sr6 Si5 N8 La4 -77.6(4) 3_665 . . . ?
Sr6 Si5 N4 Sr6 91.6(2) 3_665 . . . ?
Sr6 Si5 N4 Sr6 -92.1(2) 3_675 . . . ?
Sr6 Si5 N4 Sr6 176.3(3) 3_675 . . 3_665 ?
Sr6 Si5 N4 Sr6 -176.3(3) 3_665 . . 3_675 ?
Sr6 Si5 O4 Sr6 -176.3(3) 3_665 . . 3_675 ?
Sr6 Si5 O4 Sr6 91.6(2) 3_665 . . . ?
Sr6 Si5 O4 Sr6 176.3(3) 3_675 . . 3_665 ?
Sr6 Si5 O4 Sr6 -92.1(2) 3_675 . . . ?
N2 Si1 N5 Si4 -134.2(8) . . . . ?
N7 Si3 N11 La1 122.1(3) . . . 2 ?
N7 Si3 N11 Sr6 41.5(7) . . . . ?
N7 Si3 N11 Si5 -96.7(5) . . . . ?
N7 Si4 N6 Sr5 145.4(3) . . . 2_635 ?
N7 Si4 N6 Sr2 -118.7(4) . . . . ?
N7 Si4 N6 La1 -22.9(3) . . . 2_545 ?
N7 Si4 N6 Si3 71.7(7) . . . 1_545 ?
N7 Si4 N6 La2 -118.7(4) . . . . ?
N7 Si4 N5 Sr5 -135.2(3) . . . 4_576 ?
N7 Si4 N5 Sr2 6.9(4) . . . 1_565 ?
N7 Si4 N5 Sr3 -68.6(7) . . . 3_666 ?
N7 Si4 N5 Si1 126.6(8) . . . . ?
N11 Si3 N7 Sr5 -174.1(3) . . . 2_645 ?
N11 Si3 N7 Sr2 -89.5(3) . . . 1_565 ?
N11 Si3 N7 La1 -4.3(5) . . . 2_545 ?
N11 Si3 N7 Sr4 89.2(3) . . . 2_645 ?
N11 Si3 N7 Si4 179.5(8) . . . . ?
N11 Si5 N8 Sr3 -166.9(3) . . . 2_655 ?
N11 Si5 N8 Sr4 18.5(4) . . . 2_655 ?
N11 Si5 N8 Sr6 -83.4(3) . . . 3_675 ?
N11 Si5 N8 Si2 -81.6(12) . . . . ?
N11 Si5 N8 La4 106.6(3) . . . . ?
N11 Si5 N4 Sr6 82.5(3) . . . 3_675 ?
N11 Si5 N4 Sr6 -9.6(4) . . . . ?
N11 Si5 N4 Sr6 -101.2(3) . . . 3_665 ?
N11 Si5 O4 Sr6 82.5(3) . . . 3_675 ?
N11 Si5 O4 Sr6 -101.2(3) . . . 3_665 ?
N11 Si5 O4 Sr6 -9.6(4) . . . . ?
N12 Si2 N9 Sr5 131.7(3) . . . . ?
N12 Si2 N9 Sr3 34.2(4) . . . 2_665 ?
N12 Si2 N9 Sr3 -140.8(3) . . . 2_655 ?
N12 Si2 N9 Sr6 -55.8(3) . . . 3_675 ?
N12 Si2 N9 Si1 -84(2) . . . 4_675 ?
N12 Si2 N9 La5 131.7(3) . . . . ?
N12 Si2 N8 Sr3 142.7(3) . . . 2_655 ?
N12 Si2 N8 Sr4 -46.8(3) . . . 2_655 ?
N12 Si2 N8 Sr6 61.8(3) . . . 3_675 ?
N12 Si2 N8 Si5 59.9(13) . . . . ?
N12 Si2 N8 La4 -128.3(3) . . . . ?
N12 Si2 N10 Sr5 -132.4(3) . . . . ?
N12 Si2 N10 Sr4 52.3(3) . . . 2_655 ?
N12 Si2 N10 Sr4 -23.7(4) . . . 1_565 ?
N12 Si2 N10 Sr4 127.3(3) . . . . ?
N12 Si2 N10 Si3 -156.3(16) . . . 2_655 ?
N12 Si2 N10 La5 -132.4(3) . . . . ?
N12 Si2 N10 La4 127.3(3) . . . . ?
N12 Si5 N11 La1 168.3(4) 1_545 . . 2 ?
N12 Si5 N11 Sr6 -112.8(3) 1_545 . . . ?
N12 Si5 N11 Si3 42.7(6) 1_545 . . . ?
N12 Si5 N8 Sr3 69.3(3) 1_545 . . 2_655 ?
N12 Si5 N8 Sr4 -105.3(3) 1_545 . . 2_655 ?
N12 Si5 N8 Sr6 152.8(3) 1_545 . . 3_675 ?
N12 Si5 N8 Si2 154.6(11) 1_545 . . . ?
N12 Si5 N8 La4 -17.2(4) 1_545 . . . ?
N12 Si5 N4 Sr6 115.3(3) 1_545 . . . ?
N12 Si5 N4 Sr6 23.6(4) 1_545 . . 3_665 ?
N12 Si5 N4 Sr6 -152.7(3) 1_545 . . 3_675 ?
N12 Si5 O4 Sr6 -152.7(3) 1_545 . . 3_675 ?
N12 Si5 O4 Sr6 115.3(3) 1_545 . . . ?
N12 Si5 O4 Sr6 23.6(4) 1_545 . . 3_665 ?
N3 Si4 N7 Si3 -35.5(9) . . . . ?
N3 Si4 N6 Si3 -52.8(7) . . . 1_545 ?
N3 Si4 N5 Si1 -111.9(8) . . . . ?
N6 Si3 N7 Sr5 -57.3(3) 1_565 . . 2_645 ?
N6 Si3 N7 Sr2 27.2(3) 1_565 . . 1_565 ?
N6 Si3 N7 La1 112.5(4) 1_565 . . 2_545 ?
N6 Si3 N7 Sr4 -154.1(3) 1_565 . . 2_645 ?
N6 Si3 N7 Si4 -63.7(9) 1_565 . . . ?
N6 Si3 N11 La1 6.3(4) 1_565 . . 2 ?
N6 Si3 N11 Sr6 -74.3(6) 1_565 . . . ?
N6 Si3 N11 Si5 147.5(4) 1_565 . . . ?
N6 Si4 N7 Sr5 -165.2(3) . . . 2_645 ?
N6 Si4 N7 Sr2 111.7(3) . . . 1_565 ?
N6 Si4 N7 La1 24.3(3) . . . 2_545 ?
N6 Si4 N7 Sr4 -68.3(3) . . . 2_645 ?
N6 Si4 N7 Si3 -159.1(8) . . . . ?
N6 Si4 N5 Sr5 109.8(3) . . . 4_576 ?
N6 Si4 N5 Sr2 -108.1(3) . . . 1_565 ?
N6 Si4 N5 Sr3 176.3(6) . . . 3_666 ?
N6 Si4 N5 Si1 11.6(9) . . . . ?
N9 Si1 N2 Sr6 -40.7(3) 4_576 . . 2_545 ?
N9 Si1 N5 Sr5 13.0(4) 4_576 . . 4_576 ?
N9 Si1 N5 Sr2 -128.8(3) 4_576 . . 1_565 ?
N9 Si1 N5 Sr3 -60.3(3) 4_576 . . 3_666 ?
N9 Si1 N5 Si4 110.9(8) 4_576 . . . ?
N9 Si1 O2 Sr6 -40.7(3) 4_576 . . 2_545 ?
N9 Si2 N12 Sr3 -28.0(3) . . . 2_665 ?
N9 Si2 N12 Sr4 170.9(3) . . . 2_655 ?
N9 Si2 N12 Sr4 -102.5(3) . . . 1_565 ?
N9 Si2 N12 Sr6 53.8(3) . . . 3_675 ?
N9 Si2 N12 Si5 -8.4(10) . . . 1_565 ?
N9 Si2 N8 Sr3 22.7(4) . . . 2_655 ?
N9 Si2 N8 Sr4 -166.8(3) . . . 2_655 ?
N9 Si2 N8 Sr6 -58.2(3) . . . 3_675 ?
N9 Si2 N8 Si5 -60.1(12) . . . . ?
N9 Si2 N8 La4 111.7(3) . . . . ?
N9 Si2 N10 Sr5 -9.1(4) . . . . ?
N9 Si2 N10 Sr4 99.6(3) . . . 1_565 ?
N9 Si2 N10 Sr4 -109.4(3) . . . . ?
N9 Si2 N10 Sr4 175.6(3) . . . 2_655 ?
N9 Si2 N10 Si3 -33.1(18) . . . 2_655 ?
N9 Si2 N10 La5 -9.1(4) . . . . ?
N9 Si2 N10 La4 -109.4(3) . . . . ?
N8 Si2 N12 Sr3 -146.0(3) . . . 2_665 ?
N8 Si2 N12 Sr4 139.4(3) . . . 1_565 ?
N8 Si2 N12 Sr4 52.9(3) . . . 2_655 ?
N8 Si2 N12 Sr6 -64.3(3) . . . 3_675 ?
N8 Si2 N12 Si5 -126.4(9) . . . 1_565 ?
N8 Si2 N9 Sr5 -109.4(3) . . . . ?
N8 Si2 N9 Sr3 -21.9(3) . . . 2_655 ?
N8 Si2 N9 Sr3 153.1(3) . . . 2_665 ?
N8 Si2 N9 Sr6 63.1(3) . . . 3_675 ?
N8 Si2 N9 Si1 35(2) . . . 4_675 ?
N8 Si2 N9 La5 -109.4(3) . . . . ?
N8 Si2 N10 Sr5 110.3(3) . . . . ?
N8 Si2 N10 Sr4 -65.0(3) . . . 2_655 ?
N8 Si2 N10 Sr4 10.0(3) . . . . ?
N8 Si2 N10 Sr4 -141.1(3) . . . 1_565 ?
N8 Si2 N10 Si3 86.3(17) . . . 2_655 ?
N8 Si2 N10 La5 110.3(3) . . . . ?
N8 Si2 N10 La4 10.0(3) . . . . ?
N8 Si5 N11 La1 50.3(5) . . . 2 ?
N8 Si5 N11 Sr6 129.2(3) . . . . ?
N8 Si5 N11 Si3 -75.3(5) . . . . ?
N8 Si5 N4 Sr6 136.7(3) . . . 3_665 ?
N8 Si5 N4 Sr6 -39.6(4) . . . 3_675 ?
N8 Si5 N4 Sr6 -131.6(3) . . . . ?
N8 Si5 O4 Sr6 -39.6(4) . . . 3_675 ?
N8 Si5 O4 Sr6 -131.6(3) . . . . ?
N8 Si5 O4 Sr6 136.7(3) . . . 3_665 ?
N4 Si5 N11 Sr6 9.4(3) . . . . ?
N4 Si5 N11 Si3 164.9(4) . . . . ?
N4 Si5 N8 Sr6 36.1(3) . . . 3_675 ?
N4 Si5 N8 Si2 37.9(13) . . . . ?
N10 Si2 N12 Sr3 97.4(3) . . . 2_665 ?
N10 Si2 N12 Sr4 22.8(3) . . . 1_565 ?
N10 Si2 N12 Sr4 -63.7(3) . . . 2_655 ?
N10 Si2 N12 Sr6 179.2(3) . . . 3_675 ?
N10 Si2 N12 Si5 117.0(9) . . . 1_565 ?
N10 Si2 N9 Sr5 10.1(4) . . . . ?
N10 Si2 N9 Sr3 -87.4(4) . . . 2_665 ?
N10 Si2 N9 Sr3 97.6(3) . . . 2_655 ?
N10 Si2 N9 Sr6 -177.4(3) . . . 3_675 ?
N10 Si2 N9 Si1 154(2) . . . 4_675 ?
N10 Si2 N9 La5 10.1(4) . . . . ?
N10 Si2 N8 Sr3 -100.8(3) . . . 2_655 ?
N10 Si2 N8 Sr4 69.7(3) . . . 2_655 ?
N10 Si2 N8 Sr6 178.2(3) . . . 3_675 ?
N10 Si2 N8 Si5 176.4(11) . . . . ?
N10 Si2 N8 La4 -11.9(4) . . . . ?
N10 Si3 N7 Sr5 59.4(3) 2_645 . . 2_645 ?
N10 Si3 N7 Sr2 143.9(3) 2_645 . . 1_565 ?
N10 Si3 N7 La1 -130.8(4) 2_645 . . 2_545 ?
N10 Si3 N7 Sr4 -37.4(3) 2_645 . . 2_645 ?
N10 Si3 N7 Si4 53.0(9) 2_645 . . . ?
N10 Si3 N11 La1 -115.3(3) 2_645 . . 2 ?
N10 Si3 N11 Sr6 164.1(5) 2_645 . . . ?
N10 Si3 N11 Si5 26.0(6) 2_645 . . . ?
N1 Si1 N5 Si4 -14.1(10) . . . . ?
N5 Si1 N2 Sr6 -153.1(3) . . . 2_545 ?
N5 Si1 O2 Sr6 -153.1(3) . . . 2_545 ?
N5 Si4 N7 Sr5 76.7(3) . . . 2_645 ?
N5 Si4 N7 Sr2 -6.4(3) . . . 1_565 ?
N5 Si4 N7 La1 -93.8(3) . . . 2_545 ?
N5 Si4 N7 Sr4 173.6(3) . . . 2_645 ?
N5 Si4 N7 Si3 82.9(8) . . . . ?
N5 Si4 N6 Sr5 -100.6(3) . . . 2_635 ?
N5 Si4 N6 Sr2 -4.8(5) . . . . ?
N5 Si4 N6 La1 91.1(3) . . . 2_545 ?
N5 Si4 N6 Si3 -174.3(6) . . . 1_545 ?
N5 Si4 N6 La2 -4.8(5) . . . . ?
La4 Si2 N12 Sr6 -114.1(2) . . . 3_675 ?
La4 Si2 N12 Si5 -176.3(7) . . . 1_565 ?
La4 Si2 N9 Sr6 113.82(14) . . . 3_675 ?
La4 Si2 N9 Si1 85(2) . . . 4_675 ?
La4 Si2 N8 Sr6 -169.9(3) . . . 3_675 ?
La4 Si2 N8 Si5 -171.7(14) . . . . ?
La4 Si2 N10 Si3 76.3(16) . . . 2_655 ?
La4 Si5 N11 Sr6 -177.10(9) . . . . ?
La4 Si5 N11 Si3 -21.6(5) . . . . ?
La4 Si5 N8 Sr6 170.0(3) . . . 3_675 ?
La4 Si5 N8 Si2 171.8(14) . . . . ?
O2 Si1 N5 Si4 -134.2(8) . . . . ?
O3 Si4 N7 Si3 -35.5(9) . . . . ?
O3 Si4 N6 Si3 -52.8(7) . . . 1_545 ?
O3 Si4 N5 Si1 -111.9(8) . . . . ?
O1 Si1 N5 Si4 -14.1(10) . . . . ?
O4 Si5 N11 Sr6 9.4(3) . . . . ?
O4 Si5 N11 Si3 164.9(4) . . . . ?
O4 Si5 N8 Sr6 36.1(3) . . . 3_675 ?
O4 Si5 N8 Si2 37.9(13) . . . . ?

_olex2_submission_original_sample_id La2.3Sr3.7Si5N10.3O1.7
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 4.360
_oxdiff_exptl_absorpt_empirical_full_min 0.303
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_C
_audit_block_doi                 10.25505/fiz.icsd.cc277tt4
_database_code_depnum_ccdc_archive 'CCDC 2063106'
loop_
_audit_author_name
_audit_author_address
'Xiaoming Wang'
;Shaanxi Normal University
China
;
_audit_update_record             
;
2021-02-15 deposited with the CCDC.	2021-03-10 downloaded from the CCDC.
;
#==============================================================================

# 2. CHEMICAL DATA

_chemical_name_systematic        
;

;
_chemical_name_common            ?
_chemical_formula_moiety         Ce2.44Sr3.56Si5N10.44O1.56
_chemical_formula_structural     ?
_chemical_formula_analytical     ?
_chemical_formula_weight         965.495
_chemical_formula_sum            'Ce2.44 N10.44 O1.56 Si5 Sr3.56'
_chemical_melting_point          ?
#==============================================================================

# 3. POWDER SPECIMEN AND CRYSTAL DATA

_space_group_crystal_system      Monoclinic
_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_symmetry_space_group_name_hall  '-P 2yn'
_symmetry_int_tables_number      14
_chemical_absolute_configuration ?

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z '
'-x+1/2, y+1/2, -z+1/2 '
'-x, -y, -z '
'x+1/2, -y+1/2, z+1/2 '

_cell_length_a                   14.90289(12)
_cell_length_b                   5.46328(5)
_cell_length_c                   16.00855(13)
_cell_angle_alpha                90
_cell_angle_beta                 98.9959(5)
_cell_angle_gamma                90
_cell_volume                     1287.362(18)
_cell_formula_units_Z            4
_cell_measurement_temperature    297
_exptl_crystal_density_diffrn    4.98072(7)
_exptl_absorpt_coefficient_mu    88.545
_cell_special_details            
; ?
;
#==============================================================================

# 4. EXPERIMENTAL DATA

_exptl_special_details           
; ?
;
_exptl_crystal_description       block
_pd_char_colour                  black
_diffrn_ambient_temperature      297
_diffrn_radiation_probe          ?
_diffrn_radiation_type           'Cu K\a'
# The following six items are used for angular dispersive measurements only.
loop_
_diffrn_radiation_wavelength
1.5418
_diffrn_source                   ?
_diffrn_source_type              ?
_diffrn_source_target            Cu
_diffrn_measurement_device_type  'Rigaku MiniFlex 600'
_diffrn_detector                 ?
_diffrn_detector_type            ? # make or model of detector

_pd_meas_scan_method             step # options are 'step', 'cont',
# 'tof', 'fixed' or
# 'disp' (= dispersive)
_pd_meas_special_details         ?


#  The following four items give details of the measured (not processed)
#  powder pattern.  Angles are in degrees.

_pd_meas_number_of_points        11501
_pd_meas_2theta_range_min        5
_pd_meas_2theta_range_max        120
_pd_meas_2theta_range_inc        0.01

# The following three items are used for time-of-flight measurements only.

_pd_instr_dist_src/spec          ?
_pd_instr_dist_spec/detc         ?
_pd_meas_2theta_fixed            ?

#==============================================================================

# 5. REFINEMENT DATA

# Use the next field to give any special details about the fitting of the
# powder pattern.

_pd_proc_ls_special_details      
; ?
;

# The next three items are given as text.

_pd_proc_ls_profile_function     PV_TCHZ
_pd_proc_ls_background_function  '20 Legendre polynoms'

_pd_proc_ls_prof_R_factor        0.0395
_pd_proc_ls_prof_wR_factor       0.0543
_pd_proc_ls_prof_wR_expected     0.0272
_refine_ls_R_I_expected          ?
_refine_ls_R_Fsqd_factor         ?
_refine_ls_R_factor_all          0.0395

_refine_special_details          
; ?
;
_refine_ls_matrix_type           ?
_refine_ls_weighting_scheme      sigma
_refine_ls_weighting_details     1/[Yi]
_refine_ls_hydrogen_treatment    ?
_refine_ls_extinction_method     ?
_refine_ls_extinction_coef       ?
_refine_ls_number_independent_parameters 104
_refine_ls_number_restraints     0
# The following item is the same as CHI, the square root of 'CHI squared'
_refine_ls_goodness_of_fit_all   2.00



#==============================================================================

# 6. ATOMIC COORDINATES AND DISPLACEMENT PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_B_iso_or_equiv
Sr5 Sr+2 4 0.94486(14) 1.2493(7) 0.04896(13) 0.4 1.07(6)
Sr2 Sr+2 4 0.33240(16) -0.3117(5) 0.28459(14) 0.4 1.07(6)
Sr3 Sr+2 4 0.72895(14) 0.2735(6) 0.50736(14) 0.56 1.07(6)
Ce1 Ce+3 4 0.07366(16) 0.7068(6) 0.33981(14) 0.48 1.23(7)
Sr4 Sr+2 4 0.82776(16) 0.7576(7) 0.22151(14) 0.78 1.07(6)
Sr6 Sr+2 4 0.41442(17) 0.7494(7) 0.01322(15) 0.9 1.07(6)
Si1 Si+4 4 0.2772(5) 0.235(2) 0.3976(5) 1 1.41(10)
Si2 Si+4 4 0.7533(5) 1.267(3) 0.1137(5) 1 1.41(10)
Si3 Si+4 4 0.54189 0.7552(5) 0.2574(5) 1 1.41(10)
Si4 Si+4 4 0.4822(5) 0.250(3) 0.35734(13) 1 1.41(10)
Si5 Si+4 4 0.6239(6) 0.7568(4) 0.10369(14) 1 1.41(10)
N2 N 4 0.2073(17) 0.4525(12) 0.3601(6) 0.61 3.1(3)
N7 N 4 0.5016(4) 0.4663(12) 0.2890(15) 1 0.8(2)
N11 N 4 0.5300(5) 0.8082(5) 0.1553(4) 1 0.8(2)
N12 N 4 0.6698(19) 1.4904(6) 0.1311(17) 1 0.8(2)
N3 N 4 0.5648(7) 0.2381(2) 0.4508(12) 0.61 3.1(3)
N6 N 4 0.4687(17) -0.0319(13) 0.3099(2) 1 0.8(2)
N9 N 4 0.7744(5) 1.281(5) 0.0097(12) 1 0.8(2)
N8 N 4 0.706(2) 0.9856(7) 0.124(2) 1 0.8(2)
N4 N 4 0.5826(5) 0.7486(12) -0.0049(4) 0.61 3.1(3)
N10 N 4 0.8566(13) 1.2798(5) 0.1901(5) 1 0.8(2)
N1 N 4 0.2416(17) -0.0331(15) 0.3455(5) 0.61 3.1(3)
N5 N 4 0.3804(1) 0.3301(7) 0.3889(3) 1 0.8(2)
Ce2 Ce+3 4 0.33240(16) -0.3117(5) 0.28459(14) 0.6 1.23(7)
Ce5 Ce+3 4 0.94487(14) 1.2493(7) 0.04896(13) 0.6 1.23(7)
Sr1 Sr+2 4 0.07366(16) 0.7068(6) 0.33981(14) 0.52 1.07(6)
Ce3 Ce+3 4 0.72895(14) 0.2735(6) 0.50736(14) 0.44 1.23(7)
Ce4 Ce+3 4 0.82776(16) 0.7576(7) 0.22151(14) 0.22 1.23(7)
O2 O-2 4 0.2073(17) 0.4525(12) 0.3601(6) 0.39 3.1(3)
O3 O-2 4 0.5648(7) 0.2381(2) 0.4508(12) 0.39 3.1(3)
O1 O-2 4 0.2416(17) -0.0331(15) 0.3455(5) 0.39 3.1(3)
O4 O-2 4 0.5826(5) 0.7486(12) -0.0049(4) 0.39 3.1(3)
Ce6 Ce+3 4 0.41442(17) 0.7494(7) 0.01322(15) 0.1 1.07(6)


#==============================================================================

# 6. MOLECULAR GEOMETRY

_geom_special_details            ?

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag

Si1 N1 1.728(13) ? ? ?
Si1 N2 1.630(18) . . .
Si1 N5 1.650(8) . . .
Si1 N9 11.854(19) . . .
Si2 N10 1.812(16) . . .
Si2 N12 1.80(2) . . .
Si2 N8 1.707(19) . . .
Si2 N9 1.74(2) . . .
Si3 N10 1.617(17) . 2_645 .
Si3 N11 1.642(8) . . .
Si3 N6 1.880(17) . 1_565 .
Si3 N7 1.789(9) . . .
Si4 N3 1.784(17) . . .
Si4 N5 1.733(8) . . .
Si4 N6 1.713(13) . . .
Si4 N7 1.668(19) . . .
Si5 N11 1.755(7) . . .
Si5 N12 1.639(13) . 1_545 .
Si5 N4 1.7523(19) . . .
Si5 N8 1.75(2) . . .

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag

Si2 N10 Si3 167.1(8) ? ? 2_655 ?
Si3 N11 Si5 118.1(4) . . . .
Si2 N12 Si5 146.4(17) . . 1_565 .
Si1 N5 Si4 144.4(5) . . . .
Si4 N6 Si3 135.8(14) . . 1_545 .
Si4 N7 Si3 155.7(14) . . . .
Si2 N8 Si5 157.1(5) . . . .
Si2 N9 Si1 63.4(5) . . 4_675 .
N1 Si1 N5 116.5(10) . . . .
N2 Si1 N5 106.8(9) . . . .
N5 Si1 N9 58.0(3) . . 4_576 .
N10 Si2 N9 112.5(7) . . . .
N10 Si2 N8 107.8(3) . . . .
N12 Si2 N9 110.7(3) . . . .
N10 Si3 N7 104.7(6) 2_645 . . .
N11 Si3 N7 116.6(8) . . . .
N11 Si3 N6 110.9(4) . . 1_565 .
N3 Si4 N7 113.3(3) . . . .
N3 Si4 N6 111.8(3) . . . .
N5 Si4 N6 108.0(10) . . . .
N11 Si5 N8 112.2(4) . . . .
N12 Si5 N4 108.1(9) 1_545 . . .
N8 Si5 N4 108.6(3) . . . .




#==============================================================================
# Additional structures (sections 5-10 and associated data_? identifiers)
# may be added at this point.
#==============================================================================
_exptl_crystal_colour            Black
_exptl_crystal_recrystallization_method 'From the Melt'
_chemical_properties_physical    Air-sensitive
_exptl_crystal_preparation       'Magnetic properties'
