# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_1947_sq
_database_code_depnum_ccdc_archive 'CCDC 2077342'
loop_
_audit_author_name
_audit_author_address
'Mian HE'
;University of Sussex
United Kingdom
;
_audit_update_record             
;
2021-04-13 deposited with the CCDC.	2021-05-28 downloaded from the CCDC.
;
_audit_creation_date             2020-02-05
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C72 H122 B3 Dy3, 2(C3 H7)'
_chemical_formula_sum            'C78 H136 B3 Dy3'
_chemical_formula_weight         1593.79
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -9.8046 9.8477 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   14.14480(10)
_cell_length_b                   21.92880(10)
_cell_length_c                   26.0721(2)
_cell_angle_alpha                90
_cell_angle_beta                 98.3090(10)
_cell_angle_gamma                90
_cell_volume                     8002.11(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    22591
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      71.0270
_cell_measurement_theta_min      3.7940
_shelx_estimated_absorpt_T_max   0.315
_shelx_estimated_absorpt_T_min   0.315
_exptl_absorpt_coefficient_mu    15.012
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.323
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3268
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0814
_diffrn_reflns_av_unetI/netI     0.0644
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            55554
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         71.257
_diffrn_reflns_theta_min         3.426
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.1033
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -98.00 -59.00   1.00   12.00    --  -36.63-178.00 -60.00   39
  2  ω    -85.00 -38.00   1.00   12.00    --  -36.63 126.00  77.00   47
  3  ω   -101.00 -53.00   1.00   12.00    --  -36.63 145.00-114.00   48
  4  ω     78.00 106.00   1.00   12.00    --   36.63  38.00  30.00   28
  5  ω    -33.00  56.00   1.00   12.00    --   36.63 -38.00-150.00   89
  6  ω     11.00  66.00   1.00   12.00    --   36.63  19.00-150.00   55
  7  ω     81.00 108.00   1.00   12.00    --   36.63-178.00 -30.00   27
  8  ω     17.00  46.00   1.00   12.00    --   36.63 -38.00 120.00   29
  9  ω     20.00  95.00   1.00   12.00    --   36.63  57.00   0.00   75
 10  ω     33.00  75.00   1.00   12.00    --   36.63-178.00-180.00   42
 11  ω     40.00 121.00   1.00   50.00    --  107.00 -45.00 -90.00   81
 12  ω     91.00 122.00   1.00   50.00    --  107.00  45.00   0.00   31
 13  ω    147.00 173.00   1.00   50.00    --  107.00  45.00   0.00   26
 14  ω     41.00 123.00   1.00   50.00    --  107.00 -45.00  30.00   82
 15  ω     41.00 108.00   1.00   50.00    --  107.00 -45.00 120.00   67
 16  ω     90.00 147.00   1.00   50.00    --  107.00  45.00  60.00   57
 17  ω     38.00 142.00   1.00   50.00    --  107.00 -91.00 -61.44  104
 18  ω     43.00 112.00   1.00   50.00    --  107.00 -91.00-119.98   69
 19  ω     38.00 138.00   1.00   50.00    --  107.00 -91.00  73.92  100
 20  ω     38.00 117.00   1.00   50.00    --  107.00 -30.00-180.00   79
 21  ω    122.00 148.00   1.00   50.00    --  107.00  61.00 -60.00   26
 22  ω     83.00 109.00   1.00   50.00    --  107.00 -91.00 -11.91   26
 23  ω    113.00 138.00   1.00   50.00    --  107.00  45.00  90.00   25
 24  ω     70.00 171.00   1.00   50.00    --  107.00  15.00-180.00  101
 25  ω     73.00 101.00   1.00   50.00    --  107.00 -90.00 124.89   28
 26  ω     81.00 106.00   1.00   50.00    --  107.00 -91.00-149.79   25
 27  ω     82.00 107.00   1.00   50.00    --  107.00 -91.00 176.27   25
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0804535000
_diffrn_orient_matrix_UB_12      0.0059818000
_diffrn_orient_matrix_UB_13      0.0463281000
_diffrn_orient_matrix_UB_21      -0.0717174000
_diffrn_orient_matrix_UB_22      -0.0146885000
_diffrn_orient_matrix_UB_23      0.0374804000
_diffrn_orient_matrix_UB_31      0.0224259000
_diffrn_orient_matrix_UB_32      -0.0684197000
_diffrn_orient_matrix_UB_33      -0.0039620000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance Ultra (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                13632
_reflns_number_total             15365
_reflns_odcompleteness_completeness 99.97
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.758
_refine_diff_density_min         -0.878
_refine_diff_density_rms         0.114
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     856
_refine_ls_number_reflns         15365
_refine_ls_number_restraints     2213
_refine_ls_R_factor_all          0.0458
_refine_ls_R_factor_gt           0.0402
_refine_ls_restrained_S_all      1.015
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0499P)²+4.3708P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0999
_refine_ls_wR_factor_ref         0.1040
_refine_special_details          SQUEEZE
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All B(H,H,H,H) groups, All C(H,H,H) groups
2. Restrained distances
 C75-C74 = C74-C73
 1.55 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
C41 \\sim C8 \\sim C37 \\sim C1 \\sim C42 \\sim C5 \\sim C9 \\sim C43 \\sim C40
\\sim C38 \\sim C44 \\sim C39 \\sim C7 \\sim C45 \\sim C4 \\sim C2 \\sim C55
\\sim C10 \\sim C70 \\sim C47 \\sim C6 \\sim C63 \\sim C11 \\sim C65 \\sim C59
\\sim C67 \\sim C3 \\sim C19 \\sim C46 \\sim C62 \\sim C66 \\sim C23 \\sim C64
\\sim C15 \\sim C14 \\sim C20 \\sim C22 \\sim C49 \\sim C28 \\sim C60 \\sim C71
\\sim C69 \\sim C61 \\sim C13 \\sim C72 \\sim C21 \\sim C12 \\sim C27 \\sim C78
\\sim C48 \\sim C50 \\sim C51 \\sim C57 \\sim C29 \\sim C68 \\sim C31 \\sim C58
\\sim C18 \\sim C30 \\sim C77 \\sim C56 \\sim C16 \\sim C33 \\sim C17 \\sim C32
\\sim C34 \\sim C36 \\sim C35 \\sim C76 \\sim C25 \\sim C24 \\sim C26 \\sim
C24A \\sim C26A \\sim C25A \\sim C54 \\sim C53 \\sim C52 \\sim C74 \\sim C73
\\sim C75: within 3.8A with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C52) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C53) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C75) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C74) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C73) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
4. Rigid body (RIGU) restrains
 C73, C74, C75
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
5. Others
 Sof(C24A)=Sof(H24D)=Sof(H24E)=Sof(H24F)=Sof(C26A)=Sof(H26D)=Sof(H26E)=
 Sof(H26F)=Sof(C25A)=Sof(H25D)=Sof(H25E)=Sof(H25F)=1-FVAR(1)
 Sof(C25)=Sof(H25A)=Sof(H25B)=Sof(H25C)=Sof(C24)=Sof(H24A)=Sof(H24B)=Sof(H24C)=
 Sof(C26)=Sof(H26A)=Sof(H26B)=Sof(H26C)=FVAR(1)
6.a Riding coordinates:
 B3(H3A,H3B,H3C,H3D)
6.b Secondary CH2 refined with riding coordinates:
 C78(H78A,H78B), C77(H77A,H77B), C74(H74A,H74B), C73(H73A,H73B)
6.c Aromatic/amide H refined with riding coordinates:
 C41(H41), C5(H5), C9(H9), C43(H43), C39(H39), C7(H7), C45(H45), C3(H3)
6.d Idealised Me refined as rotating group:
 C70(H70A,H70B,H70C), C62(H62A,H62B,H62C), C14(H14A,H14B,H14C), C20(H20A,H20B,
 H20C), C22(H22A,H22B,H22C), C49(H49A,H49B,H49C), C60(H60A,H60B,H60C), C71(H71A,
 H71B,H71C), C69(H69A,H69B,H69C), C61(H61A,H61B,H61C), C13(H13A,H13B,H13C),
 C72(H72A,H72B,H72C), C21(H21A,H21B,H21C), C12(H12A,H12B,H12C), C48(H48A,H48B,
 H48C), C50(H50A,H50B,H50C), C57(H57A,H57B,H57C), C68(H68A,H68B,H68C), C58(H58A,
 H58B,H58C), C18(H18A,H18B,H18C), C56(H56A,H56B,H56C), C16(H16A,H16B,H16C),
 C33(H33A,H33B,H33C), C17(H17A,H17B,H17C), C32(H32A,H32B,H32C), C34(H34A,H34B,
 H34C), C36(H36A,H36B,H36C), C35(H35A,H35B,H35C), C76(H76A,H76B,H76C), C25(H25A,
 H25B,H25C), C24(H24A,H24B,H24C), C26(H26A,H26B,H26C), C24A(H24D,H24E,H24F),
 C26A(H26D,H26E,H26F), C25A(H25D,H25E,H25F), C54(H54A,H54B,H54C), C53(H53A,H53B,
 H53C), C52(H52A,H52B,H52C), C75(H75A,H75B,H75C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy2 Dy 0.49734(2) 0.68225(2) 0.63611(2) 0.01536(6) Uani 1 1 d . . . . .
Dy3 Dy 0.68577(2) 0.80033(2) 0.76323(2) 0.01876(6) Uani 1 1 d . . . . .
Dy1 Dy 0.37061(2) 0.64990(2) 0.79261(2) 0.02133(7) Uani 1 1 d . . . . .
C41 C 0.6419(3) 0.74155(16) 0.60757(14) 0.0184(6) Uani 1 1 d . U . . .
H41 H 0.638832 0.783491 0.612363 0.022 Uiso 1 1 calc R . . . .
C8 C 0.3583(3) 0.61266(17) 0.58468(14) 0.0205(7) Uani 1 1 d . U . . .
C37 C 0.6854(3) 0.69948(16) 0.64536(14) 0.0167(6) Uani 1 1 d . U . . .
C1 C 0.2810(3) 0.68891(17) 0.69947(14) 0.0194(6) Uani 1 1 d . U . . .
C42 C 0.7401(3) 0.71651(16) 0.69604(14) 0.0178(6) Uani 1 1 d . U . . .
C5 C 0.3070(3) 0.74066(17) 0.73064(14) 0.0204(7) Uani 1 1 d . U . . .
H5 H 0.354237 0.768491 0.725282 0.025 Uiso 1 1 calc R . . . .
C9 C 0.3409(3) 0.67236(18) 0.56469(14) 0.0218(7) Uani 1 1 d . U . . .
H9 H 0.348782 0.684642 0.531436 0.026 Uiso 1 1 calc R . . . .
C43 C 0.7309(3) 0.68776(16) 0.74391(14) 0.0181(6) Uani 1 1 d . U . . .
H43 H 0.682860 0.660492 0.749141 0.022 Uiso 1 1 calc R . . . .
C40 C 0.6044(3) 0.71065(18) 0.56207(14) 0.0214(7) Uani 1 1 d . U . . .
C38 C 0.6737(3) 0.63973(16) 0.62255(14) 0.0176(6) Uani 1 1 d . U . . .
C44 C 0.8060(3) 0.70693(17) 0.78245(14) 0.0201(7) Uani 1 1 d . U . . .
C39 C 0.6206(3) 0.64801(17) 0.57244(14) 0.0188(7) Uani 1 1 d . U . . .
H39 H 0.599490 0.616584 0.549679 0.023 Uiso 1 1 calc R . . . .
C7 C 0.3441(2) 0.61554(17) 0.63691(14) 0.0192(6) Uani 1 1 d . U . . .
H7 H 0.353173 0.583113 0.660088 0.023 Uiso 1 1 calc R . . . .
C45 C 0.8580(3) 0.75078(17) 0.75821(15) 0.0204(7) Uani 1 1 d . U . . .
H45 H 0.909837 0.772711 0.774880 0.024 Uiso 1 1 calc R . . . .
C4 C 0.2509(3) 0.74389(17) 0.77101(15) 0.0223(7) Uani 1 1 d . U . . .
C2 C 0.2095(3) 0.65640(17) 0.72216(15) 0.0222(7) Uani 1 1 d . U . . .
C55 C 0.8358(3) 0.67767(18) 0.83572(15) 0.0242(8) Uani 1 1 d . U . . .
C10 C 0.3094(3) 0.71094(17) 0.60303(15) 0.0208(7) Uani 1 1 d . U . . .
C70 C 0.7117(3) 0.8629(2) 0.89742(16) 0.0312(9) Uani 1 1 d . U . . .
H70A H 0.659365 0.835925 0.900459 0.047 Uiso 1 1 calc GR . . . .
H70B H 0.705147 0.899304 0.917077 0.047 Uiso 1 1 calc GR . . . .
H70C H 0.770782 0.843081 0.910487 0.047 Uiso 1 1 calc GR . . . .
C47 C 0.7288(3) 0.58013(16) 0.63615(15) 0.0205(7) Uani 1 1 d . U . . .
C6 C 0.3142(3) 0.67463(17) 0.64930(14) 0.0195(7) Uani 1 1 d . U . . .
C63 C 0.7633(3) 0.91231(18) 0.76746(17) 0.0290(8) Uani 1 1 d . U . . .
C11 C 0.1459(3) 0.60313(19) 0.70027(16) 0.0263(8) Uani 1 1 d . U . . .
C65 C 0.7114(3) 0.87921(16) 0.84165(16) 0.0234(7) Uani 1 1 d . U . . .
C59 C 0.8734(3) 0.78744(19) 0.66440(16) 0.0245(7) Uani 1 1 d . U . . .
C67 C 0.6634(3) 0.92172(17) 0.76211(16) 0.0271(8) Uani 1 1 d . U . . .
C3 C 0.1935(3) 0.69080(18) 0.76666(15) 0.0231(7) Uani 1 1 d . U . . .
H3 H 0.151529 0.679869 0.789444 0.028 Uiso 1 1 calc R . . . .
C19 C 0.3586(3) 0.55351(19) 0.55373(15) 0.0258(8) Uani 1 1 d . U . . .
C46 C 0.8202(3) 0.75675(17) 0.70468(15) 0.0199(7) Uani 1 1 d . U . . .
C62 C 0.8928(3) 0.7398(2) 0.62398(17) 0.0321(9) Uani 1 1 d . U . . .
H62A H 0.925628 0.705543 0.641210 0.048 Uiso 1 1 calc GR . . . .
H62B H 0.931627 0.757638 0.600628 0.048 Uiso 1 1 calc GR . . . .
H62C H 0.833295 0.726483 0.604845 0.048 Uiso 1 1 calc GR . . . .
C66 C 0.6318(3) 0.90219(16) 0.80807(16) 0.0239(7) Uani 1 1 d . U . . .
C23 C 0.2574(3) 0.77156(19) 0.58816(16) 0.0263(8) Uani 1 1 d . U . . .
C64 C 0.7932(3) 0.88541(17) 0.81638(16) 0.0260(8) Uani 1 1 d . U . . .
C15 C 0.2401(3) 0.80006(18) 0.80537(16) 0.0249(8) Uani 1 1 d . U . . .
C14 C 0.1027(3) 0.6162(2) 0.64384(18) 0.0350(9) Uani 1 1 d . U . . .
H14A H 0.066931 0.653527 0.642311 0.052 Uiso 1 1 calc GR . . . .
H14B H 0.061125 0.583315 0.630973 0.052 Uiso 1 1 calc GR . . . .
H14C H 0.153053 0.619944 0.622984 0.052 Uiso 1 1 calc GR . . . .
C20 C 0.4080(3) 0.5604(2) 0.50575(16) 0.0308(9) Uani 1 1 d . U . . .
H20A H 0.379753 0.593643 0.485037 0.046 Uiso 1 1 calc GR . . . .
H20B H 0.400586 0.523408 0.485826 0.046 Uiso 1 1 calc GR . . . .
H20C H 0.474742 0.568335 0.516191 0.046 Uiso 1 1 calc GR . . . .
C22 C 0.4019(4) 0.5009(2) 0.58708(19) 0.0393(10) Uani 1 1 d . U . . .
H22A H 0.467769 0.509532 0.599473 0.059 Uiso 1 1 calc GR . . . .
H22B H 0.397546 0.464163 0.566798 0.059 Uiso 1 1 calc GR . . . .
H22C H 0.367732 0.495638 0.616021 0.059 Uiso 1 1 calc GR . . . .
C49 C 0.7830(3) 0.57412(19) 0.68997(17) 0.0315(9) Uani 1 1 d . U . . .
H49A H 0.825025 0.608389 0.697259 0.047 Uiso 1 1 calc GR . . . .
H49B H 0.819762 0.537175 0.692395 0.047 Uiso 1 1 calc GR . . . .
H49C H 0.738727 0.572972 0.714615 0.047 Uiso 1 1 calc GR . . . .
C28 C 0.3013(4) 0.6052(2) 0.87483(18) 0.0380(9) Uani 1 1 d . U . . .
C60 C 0.9722(3) 0.8102(2) 0.69076(19) 0.0328(9) Uani 1 1 d . U . . .
H60A H 0.963489 0.840687 0.716114 0.049 Uiso 1 1 calc GR . . . .
H60B H 1.006530 0.827518 0.665093 0.049 Uiso 1 1 calc GR . . . .
H60C H 1.007744 0.776629 0.707413 0.049 Uiso 1 1 calc GR . . . .
C71 C 0.5335(3) 0.9128(2) 0.82199(19) 0.0325(9) Uani 1 1 d . U . . .
H71A H 0.486827 0.907997 0.791645 0.049 Uiso 1 1 calc GR . . . .
H71B H 0.529674 0.953387 0.835364 0.049 Uiso 1 1 calc GR . . . .
H71C H 0.521245 0.883830 0.847831 0.049 Uiso 1 1 calc GR . . . .
C69 C 0.8956(3) 0.8770(2) 0.8411(2) 0.0356(10) Uani 1 1 d . U . . .
H69A H 0.902122 0.838710 0.859095 0.053 Uiso 1 1 calc GR . . . .
H69B H 0.913424 0.909564 0.865194 0.053 Uiso 1 1 calc GR . . . .
H69C H 0.936514 0.877434 0.814741 0.053 Uiso 1 1 calc GR . . . .
C61 C 0.8191(3) 0.84138(19) 0.63528(18) 0.0313(9) Uani 1 1 d . U . . .
H61A H 0.774794 0.826044 0.606838 0.047 Uiso 1 1 calc GR . . . .
H61B H 0.863903 0.868152 0.622355 0.047 Uiso 1 1 calc GR . . . .
H61C H 0.784921 0.863401 0.658609 0.047 Uiso 1 1 calc GR . . . .
C13 C 0.1971(3) 0.5409(2) 0.70219(19) 0.0338(9) Uani 1 1 d . U . . .
H13A H 0.226732 0.535864 0.671586 0.051 Uiso 1 1 calc GR . . . .
H13B H 0.151376 0.508832 0.703914 0.051 Uiso 1 1 calc GR . . . .
H13C H 0.244943 0.539149 0.732278 0.051 Uiso 1 1 calc GR . . . .
C72 C 0.6026(4) 0.95488(19) 0.71827(18) 0.0373(10) Uani 1 1 d . U . . .
H72A H 0.631063 0.951048 0.687165 0.056 Uiso 1 1 calc GR . . . .
H72B H 0.598332 0.997218 0.727010 0.056 Uiso 1 1 calc GR . . . .
H72C H 0.539696 0.937383 0.712828 0.056 Uiso 1 1 calc GR . . . .
C21 C 0.2527(3) 0.5378(2) 0.53553(19) 0.0391(11) Uani 1 1 d . U . . .
H21A H 0.221262 0.530062 0.565150 0.059 Uiso 1 1 calc GR . . . .
H21B H 0.248763 0.502090 0.513978 0.059 Uiso 1 1 calc GR . . . .
H21C H 0.222119 0.571344 0.516129 0.059 Uiso 1 1 calc GR . . . .
C12 C 0.0608(3) 0.5970(2) 0.73090(19) 0.0347(10) Uani 1 1 d . U . . .
H12A H 0.084181 0.588534 0.766607 0.052 Uiso 1 1 calc GR . . . .
H12B H 0.020190 0.564237 0.716671 0.052 Uiso 1 1 calc GR . . . .
H12C H 0.025096 0.634361 0.728453 0.052 Uiso 1 1 calc GR . . . .
B1 B 0.5027(3) 0.61144(19) 0.73235(16) 0.0208(8) Uani 1 1 d . . . . .
C27 C 0.3195(4) 0.5537(2) 0.84638(19) 0.0410(10) Uani 1 1 d . U . . .
C78 C 0.4885(3) 0.9686(2) 1.00940(18) 0.0404(11) Uani 1 1 d . U . . .
H78A H 0.428596 0.970639 1.023310 0.048 Uiso 1 1 calc R . . . .
H78B H 0.537884 0.956928 1.037452 0.048 Uiso 1 1 calc R . . . .
C48 C 0.6611(3) 0.52519(19) 0.62659(17) 0.0303(9) Uani 1 1 d . U . . .
H48A H 0.618444 0.524839 0.652089 0.046 Uiso 1 1 calc GR . . . .
H48B H 0.697728 0.488193 0.629085 0.046 Uiso 1 1 calc GR . . . .
H48C H 0.624726 0.528235 0.592616 0.046 Uiso 1 1 calc GR . . . .
C50 C 0.8016(3) 0.5743(2) 0.59748(19) 0.0351(9) Uani 1 1 d . U . . .
H50A H 0.768432 0.576029 0.562676 0.053 Uiso 1 1 calc GR . . . .
H50B H 0.834714 0.536156 0.602867 0.053 Uiso 1 1 calc GR . . . .
H50C H 0.846694 0.607227 0.602896 0.053 Uiso 1 1 calc GR . . . .
C51 C 0.5823(3) 0.7401(2) 0.50898(16) 0.0334(9) Uani 1 1 d . U . . .
B2 B 0.5251(3) 0.79919(19) 0.68758(18) 0.0230(9) Uani 1 1 d . . . . .
C57 C 0.8104(4) 0.7161(2) 0.88072(16) 0.0339(9) Uani 1 1 d . U . . .
H57A H 0.841180 0.755146 0.880625 0.051 Uiso 1 1 calc GR . . . .
H57B H 0.831779 0.695670 0.912866 0.051 Uiso 1 1 calc GR . . . .
H57C H 0.742475 0.721698 0.876919 0.051 Uiso 1 1 calc GR . . . .
C29 C 0.3871(4) 0.6325(2) 0.89414(19) 0.0446(11) Uani 1 1 d . U . . .
C68 C 0.8289(4) 0.9432(2) 0.7352(2) 0.0421(11) Uani 1 1 d . U . . .
H68A H 0.885996 0.919470 0.735738 0.063 Uiso 1 1 calc GR . . . .
H68B H 0.845050 0.983058 0.749015 0.063 Uiso 1 1 calc GR . . . .
H68C H 0.797434 0.946930 0.700130 0.063 Uiso 1 1 calc GR . . . .
C31 C 0.4195(5) 0.5492(2) 0.8474(2) 0.0472(11) Uani 1 1 d . U . . .
C58 C 0.9436(4) 0.6683(3) 0.8439(2) 0.0505(13) Uani 1 1 d . U . . .
H58A H 0.960945 0.642345 0.817118 0.076 Uiso 1 1 calc GR . . . .
H58B H 0.962995 0.649630 0.877084 0.076 Uiso 1 1 calc GR . . . .
H58C H 0.974940 0.707008 0.842731 0.076 Uiso 1 1 calc GR . . . .
C18 C 0.1512(4) 0.7945(2) 0.8312(2) 0.0400(11) Uani 1 1 d . U . . .
H18A H 0.095845 0.793029 0.805227 0.060 Uiso 1 1 calc GR . . . .
H18B H 0.146852 0.829089 0.853337 0.060 Uiso 1 1 calc GR . . . .
H18C H 0.154726 0.757834 0.851557 0.060 Uiso 1 1 calc GR . . . .
C30 C 0.4606(4) 0.5983(3) 0.8774(2) 0.0510(12) Uani 1 1 d . U . . .
C77 C 0.4807(4) 0.9197(3) 0.9680(2) 0.0534(13) Uani 1 1 d . U . . .
H77A H 0.429684 0.930526 0.940481 0.064 Uiso 1 1 calc R . . . .
H77B H 0.539748 0.918537 0.953179 0.064 Uiso 1 1 calc R . . . .
C56 C 0.7870(5) 0.6160(2) 0.8377(2) 0.0505(14) Uani 1 1 d . U . . .
H56A H 0.718986 0.621531 0.832366 0.076 Uiso 1 1 calc GR . . . .
H56B H 0.806388 0.597615 0.870989 0.076 Uiso 1 1 calc GR . . . .
H56C H 0.804973 0.590084 0.811089 0.076 Uiso 1 1 calc GR . . . .
C16 C 0.2285(5) 0.8555(2) 0.7707(2) 0.0529(14) Uani 1 1 d . U . . .
H16A H 0.284092 0.860079 0.753798 0.079 Uiso 1 1 calc GR . . . .
H16B H 0.220955 0.891098 0.791109 0.079 Uiso 1 1 calc GR . . . .
H16C H 0.173088 0.850537 0.745032 0.079 Uiso 1 1 calc GR . . . .
C33 C 0.2038(5) 0.6210(3) 0.8897(2) 0.0577(14) Uani 1 1 d . U . . .
H33A H 0.199120 0.664289 0.893905 0.087 Uiso 1 1 calc GR . . . .
H33B H 0.196406 0.601000 0.921615 0.087 Uiso 1 1 calc GR . . . .
H33C H 0.154559 0.607490 0.862827 0.087 Uiso 1 1 calc GR . . . .
C17 C 0.3257(4) 0.8071(3) 0.8471(3) 0.0618(17) Uani 1 1 d . U . . .
H17A H 0.327874 0.773595 0.870859 0.093 Uiso 1 1 calc GR . . . .
H17B H 0.320377 0.844685 0.865368 0.093 Uiso 1 1 calc GR . . . .
H17C H 0.383080 0.807643 0.831403 0.093 Uiso 1 1 calc GR . . . .
C32 C 0.2487(6) 0.5026(3) 0.8310(3) 0.0675(17) Uani 1 1 d . U . . .
H32A H 0.188498 0.519538 0.816002 0.101 Uiso 1 1 calc GR . . . .
H32B H 0.240347 0.479211 0.861179 0.101 Uiso 1 1 calc GR . . . .
H32C H 0.272668 0.476601 0.806184 0.101 Uiso 1 1 calc GR . . . .
C34 C 0.4057(7) 0.6825(3) 0.9336(2) 0.0703(18) Uani 1 1 d . U . . .
H34A H 0.443021 0.714003 0.920634 0.105 Uiso 1 1 calc GR . . . .
H34B H 0.439949 0.666341 0.965178 0.105 Uiso 1 1 calc GR . . . .
H34C H 0.345982 0.699264 0.940376 0.105 Uiso 1 1 calc GR . . . .
C36 C 0.4687(6) 0.4950(3) 0.8261(3) 0.0743(19) Uani 1 1 d . U . . .
H36A H 0.433881 0.483271 0.793266 0.111 Uiso 1 1 calc GR . . . .
H36B H 0.470479 0.461493 0.849930 0.111 Uiso 1 1 calc GR . . . .
H36C H 0.532668 0.506164 0.821803 0.111 Uiso 1 1 calc GR . . . .
C35 C 0.5662(5) 0.6061(4) 0.8938(3) 0.080(2) Uani 1 1 d . U . . .
H35A H 0.600219 0.577063 0.875863 0.120 Uiso 1 1 calc GR . . . .
H35B H 0.581120 0.599525 0.930521 0.120 Uiso 1 1 calc GR . . . .
H35C H 0.584628 0.646644 0.885616 0.120 Uiso 1 1 calc GR . . . .
C76 C 0.4611(7) 0.8568(4) 0.9877(3) 0.082(2) Uani 1 1 d . U . . .
H76A H 0.457015 0.828068 0.959678 0.124 Uiso 1 1 calc GR . . . .
H76B H 0.401889 0.857169 1.001623 0.124 Uiso 1 1 calc GR . . . .
H76C H 0.512045 0.845177 1.014348 0.124 Uiso 1 1 calc GR . . . .
C25 C 0.3045(6) 0.8282(3) 0.6111(3) 0.0308(16) Uani 0.565(7) 1 d . U P A 1
H25A H 0.316231 0.824338 0.648188 0.046 Uiso 0.565(7) 1 calc GR . P A 1
H25B H 0.263662 0.862536 0.601795 0.046 Uiso 0.565(7) 1 calc GR . P A 1
H25C H 0.364084 0.833971 0.598182 0.046 Uiso 0.565(7) 1 calc GR . P A 1
C24 C 0.2328(6) 0.7783(4) 0.5295(3) 0.0343(17) Uani 0.565(7) 1 d . U P A 1
H24A H 0.290437 0.777717 0.514128 0.052 Uiso 0.565(7) 1 calc GR . P A 1
H24B H 0.200154 0.816321 0.521613 0.052 Uiso 0.565(7) 1 calc GR . P A 1
H24C H 0.192233 0.745262 0.515966 0.052 Uiso 0.565(7) 1 calc GR . P A 1
C26 C 0.1560(6) 0.7666(4) 0.6076(3) 0.0335(16) Uani 0.565(7) 1 d . U P A 1
H26A H 0.124414 0.730041 0.594023 0.050 Uiso 0.565(7) 1 calc GR . P A 1
H26B H 0.117828 0.801362 0.595624 0.050 Uiso 0.565(7) 1 calc GR . P A 1
H26C H 0.164720 0.765389 0.644758 0.050 Uiso 0.565(7) 1 calc GR . P A 1
C24A C 0.3180(8) 0.8091(5) 0.5509(4) 0.034(2) Uani 0.435(7) 1 d . U P A 2
H24D H 0.383374 0.811901 0.566838 0.051 Uiso 0.435(7) 1 calc GR . P A 2
H24E H 0.291807 0.849377 0.545320 0.051 Uiso 0.435(7) 1 calc GR . P A 2
H24F H 0.314830 0.788457 0.518190 0.051 Uiso 0.435(7) 1 calc GR . P A 2
C26A C 0.1641(7) 0.7566(5) 0.5564(4) 0.033(2) Uani 0.435(7) 1 d . U P A 2
H26D H 0.175093 0.734022 0.526279 0.049 Uiso 0.435(7) 1 calc GR . P A 2
H26E H 0.130731 0.793693 0.545811 0.049 Uiso 0.435(7) 1 calc GR . P A 2
H26F H 0.126396 0.732590 0.576596 0.049 Uiso 0.435(7) 1 calc GR . P A 2
C25A C 0.2447(8) 0.8148(5) 0.6314(4) 0.031(2) Uani 0.435(7) 1 d . U P A 2
H25D H 0.216583 0.793491 0.657609 0.047 Uiso 0.435(7) 1 calc GR . P A 2
H25E H 0.203661 0.847723 0.618038 0.047 Uiso 0.435(7) 1 calc GR . P A 2
H25F H 0.305793 0.830770 0.646197 0.047 Uiso 0.435(7) 1 calc GR . P A 2
C54 C 0.5184(3) 0.7016(2) 0.46953(16) 0.0328(9) Uani 1 1 d . U . . .
H54A H 0.544377 0.661161 0.468832 0.049 Uiso 1 1 calc GR . . . .
H54B H 0.515212 0.719723 0.435818 0.049 Uiso 1 1 calc GR . . . .
H54C H 0.455430 0.699501 0.479049 0.049 Uiso 1 1 calc GR . . . .
C53 C 0.5365(7) 0.8021(3) 0.5122(3) 0.081(2) Uani 1 1 d . U . . .
H53A H 0.474912 0.797446 0.523099 0.121 Uiso 1 1 calc GR . . . .
H53B H 0.529276 0.821318 0.478775 0.121 Uiso 1 1 calc GR . . . .
H53C H 0.576326 0.827007 0.536820 0.121 Uiso 1 1 calc GR . . . .
C52 C 0.6786(5) 0.7463(4) 0.4893(2) 0.078(2) Uani 1 1 d . U . . .
H52A H 0.719091 0.773197 0.511680 0.117 Uiso 1 1 calc GR . . . .
H52B H 0.668776 0.762567 0.454765 0.117 Uiso 1 1 calc GR . . . .
H52C H 0.708227 0.706906 0.489087 0.117 Uiso 1 1 calc GR . . . .
H2A H 0.488(3) 0.7873(17) 0.6492(15) 0.004(8) Uiso 1 1 d . . . . .
H2B H 0.597(4) 0.829(2) 0.6872(19) 0.026(12) Uiso 1 1 d . . . . .
H2C H 0.545(4) 0.748(3) 0.704(2) 0.041(15) Uiso 1 1 d . . . . .
H1A H 0.477(4) 0.661(2) 0.7314(19) 0.026(12) Uiso 1 1 d . . . . .
H2D H 0.480(4) 0.825(2) 0.707(2) 0.030(13) Uiso 1 1 d . . . . .
H1B H 0.561(4) 0.604(2) 0.763(2) 0.034(13) Uiso 1 1 d . . . . .
H1C H 0.525(4) 0.602(2) 0.692(2) 0.031(13) Uiso 1 1 d . . . . .
H1D H 0.429(4) 0.590(3) 0.732(2) 0.041(15) Uiso 1 1 d . . . . .
B3 B 0.5501(3) 0.7496(2) 0.82428(18) 0.0260(9) Uani 1 1 d . . . . .
H3A H 0.558490 0.764622 0.868587 0.039 Uiso 1 1 d R . . . .
H3B H 0.485340 0.714712 0.823107 0.039 Uiso 1 1 d R . . . .
H3C H 0.537390 0.795752 0.800207 0.039 Uiso 1 1 d R . . . .
H3D H 0.631860 0.736962 0.824307 0.039 Uiso 1 1 d R . . . .
C74 C 0.6305(12) 0.5054(8) 1.0155(6) 0.182(5) Uani 1 1 d D U . . .
H74A H 0.639454 0.494397 1.051932 0.219 Uiso 1 1 calc R . . . .
H74B H 0.633570 0.549373 1.012082 0.219 Uiso 1 1 calc R . . . .
C73 C 0.5359(11) 0.4787(7) 0.9858(6) 0.170(5) Uani 1 1 d D U . . .
H73A H 0.528426 0.435579 0.992565 0.204 Uiso 1 1 calc R . . . .
H73B H 0.529490 0.485877 0.948736 0.204 Uiso 1 1 calc R . . . .
C75 C 0.7033(14) 0.4723(8) 0.9854(6) 0.213(6) Uani 1 1 d D U . . .
H75A H 0.676165 0.467971 0.949626 0.320 Uiso 1 1 calc GR . . . .
H75B H 0.717558 0.432657 1.000195 0.320 Uiso 1 1 calc GR . . . .
H75C H 0.761033 0.495797 0.987776 0.320 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy2 C41 2.621(4) . ?
Dy2 C8 2.690(4) . ?
Dy2 C37 2.663(4) . ?
Dy2 C9 2.687(4) . ?
Dy2 C40 2.693(4) . ?
Dy2 C38 2.733(4) . ?
Dy2 C39 2.683(4) . ?
Dy2 C7 2.617(3) . ?
Dy2 C10 2.746(4) . ?
Dy2 C6 2.668(4) . ?
Dy3 C42 2.725(4) . ?
Dy3 C43 2.617(4) . ?
Dy3 C44 2.663(4) . ?
Dy3 C45 2.689(4) . ?
Dy3 C63 2.685(4) . ?
Dy3 C65 2.663(4) . ?
Dy3 C67 2.680(4) . ?
Dy3 C46 2.775(4) . ?
Dy3 C66 2.683(4) . ?
Dy3 C64 2.665(4) . ?
Dy1 C1 2.710(4) . ?
Dy1 C5 2.638(4) . ?
Dy1 C4 2.675(4) . ?
Dy1 C2 2.716(4) . ?
Dy1 C3 2.655(4) . ?
Dy1 C28 2.669(4) . ?
Dy1 C27 2.688(5) . ?
Dy1 C29 2.651(5) . ?
Dy1 C31 2.667(5) . ?
Dy1 C30 2.642(5) . ?
C41 C37 1.423(5) . ?
C41 C40 1.402(5) . ?
C8 C9 1.417(6) . ?
C8 C7 1.406(5) . ?
C8 C19 1.528(5) . ?
C37 C42 1.479(5) . ?
C37 C38 1.439(5) . ?
C1 C5 1.413(5) . ?
C1 C2 1.433(5) . ?
C1 C6 1.485(5) . ?
C42 C43 1.421(5) . ?
C42 C46 1.428(5) . ?
C5 C4 1.409(5) . ?
C9 C10 1.429(5) . ?
C43 C44 1.416(5) . ?
C40 C39 1.412(5) . ?
C40 C51 1.518(5) . ?
C38 C39 1.421(5) . ?
C38 C47 1.537(5) . ?
C44 C45 1.414(6) . ?
C44 C55 1.533(5) . ?
C7 C6 1.415(5) . ?
C45 C46 1.427(5) . ?
C4 C3 1.415(5) . ?
C4 C15 1.543(5) . ?
C2 C11 1.533(5) . ?
C2 C3 1.429(5) . ?
C55 C57 1.529(6) . ?
C55 C58 1.524(6) . ?
C55 C56 1.521(6) . ?
C10 C6 1.439(5) . ?
C10 C23 1.542(5) . ?
C70 C65 1.496(6) . ?
C47 C49 1.504(6) . ?
C47 C48 1.537(5) . ?
C47 C50 1.546(6) . ?
C63 C67 1.414(6) . ?
C63 C64 1.413(6) . ?
C63 C68 1.501(6) . ?
C11 C14 1.536(6) . ?
C11 C13 1.543(6) . ?
C11 C12 1.544(6) . ?
C65 C66 1.415(6) . ?
C65 C64 1.419(6) . ?
C59 C46 1.533(5) . ?
C59 C62 1.536(6) . ?
C59 C60 1.548(5) . ?
C59 C61 1.548(6) . ?
C67 C66 1.405(6) . ?
C67 C72 1.514(6) . ?
C19 C20 1.526(6) . ?
C19 C22 1.520(6) . ?
C19 C21 1.544(6) . ?
C66 C71 1.505(6) . ?
C23 C25 1.493(9) . ?
C23 C24 1.525(9) . ?
C23 C26 1.591(9) . ?
C23 C24A 1.613(12) . ?
C23 C26A 1.489(10) . ?
C23 C25A 1.504(11) . ?
C64 C69 1.510(6) . ?
C15 C18 1.515(6) . ?
C15 C16 1.510(7) . ?
C15 C17 1.513(6) . ?
C28 C27 1.395(7) . ?
C28 C29 1.381(8) . ?
C28 C33 1.524(8) . ?
C27 C31 1.415(8) . ?
C27 C32 1.518(8) . ?
C78 C78 1.511(11) 3_677 ?
C78 C77 1.516(7) . ?
C51 C54 1.523(6) . ?
C51 C53 1.515(8) . ?
C51 C52 1.529(8) . ?
C29 C30 1.402(9) . ?
C29 C34 1.502(8) . ?
C31 C30 1.406(9) . ?
C31 C36 1.521(7) . ?
C30 C35 1.502(9) . ?
C77 C76 1.511(10) . ?
C74 C73 1.560(9) . ?
C74 C75 1.562(9) . ?
C73 C73 1.63(3) 3_667 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C41 Dy2 C8 133.20(11) . . ?
C41 Dy2 C37 31.23(11) . . ?
C41 Dy2 C9 116.21(12) . . ?
C41 Dy2 C40 30.56(11) . . ?
C41 Dy2 C38 50.83(11) . . ?
C41 Dy2 C39 50.17(11) . . ?
C41 Dy2 C10 123.83(11) . . ?
C41 Dy2 C6 151.65(11) . . ?
C8 Dy2 C40 102.73(11) . . ?
C8 Dy2 C38 110.93(11) . . ?
C8 Dy2 C10 50.84(11) . . ?
C37 Dy2 C8 140.77(11) . . ?
C37 Dy2 C9 141.82(11) . . ?
C37 Dy2 C40 51.26(11) . . ?
C37 Dy2 C38 30.89(10) . . ?
C37 Dy2 C39 50.63(11) . . ?
C37 Dy2 C10 154.78(11) . . ?
C37 Dy2 C6 166.73(11) . . ?
C9 Dy2 C8 30.57(12) . . ?
C9 Dy2 C40 90.81(12) . . ?
C9 Dy2 C38 123.95(11) . . ?
C9 Dy2 C10 30.46(11) . . ?
C40 Dy2 C38 50.80(11) . . ?
C40 Dy2 C10 109.93(11) . . ?
C38 Dy2 C10 153.82(11) . . ?
C39 Dy2 C8 91.52(11) . . ?
C39 Dy2 C9 95.30(11) . . ?
C39 Dy2 C40 30.46(11) . . ?
C39 Dy2 C38 30.41(11) . . ?
C39 Dy2 C10 123.77(11) . . ?
C7 Dy2 C41 163.88(11) . . ?
C7 Dy2 C8 30.69(12) . . ?
C7 Dy2 C37 153.64(11) . . ?
C7 Dy2 C9 50.24(12) . . ?
C7 Dy2 C40 133.39(11) . . ?
C7 Dy2 C38 125.63(11) . . ?
C7 Dy2 C39 117.48(11) . . ?
C7 Dy2 C10 50.62(12) . . ?
C7 Dy2 C6 31.04(11) . . ?
C6 Dy2 C8 51.30(11) . . ?
C6 Dy2 C9 50.68(11) . . ?
C6 Dy2 C40 139.83(11) . . ?
C6 Dy2 C38 156.46(11) . . ?
C6 Dy2 C39 142.41(11) . . ?
C6 Dy2 C10 30.78(11) . . ?
C42 Dy3 C46 30.07(11) . . ?
C43 Dy3 C42 30.77(11) . . ?
C43 Dy3 C44 31.10(11) . . ?
C43 Dy3 C45 50.30(11) . . ?
C43 Dy3 C63 139.56(13) . . ?
C43 Dy3 C65 138.65(11) . . ?
C43 Dy3 C67 165.11(13) . . ?
C43 Dy3 C46 50.47(11) . . ?
C43 Dy3 C66 164.16(12) . . ?
C43 Dy3 C64 128.60(12) . . ?
C44 Dy3 C42 50.98(11) . . ?
C44 Dy3 C45 30.64(12) . . ?
C44 Dy3 C63 116.73(13) . . ?
C44 Dy3 C67 146.81(12) . . ?
C44 Dy3 C46 50.86(11) . . ?
C44 Dy3 C66 140.59(12) . . ?
C44 Dy3 C64 98.05(12) . . ?
C45 Dy3 C42 49.78(11) . . ?
C45 Dy3 C46 30.22(11) . . ?
C63 Dy3 C42 119.45(12) . . ?
C63 Dy3 C45 90.23(13) . . ?
C63 Dy3 C46 91.68(12) . . ?
C65 Dy3 C42 155.79(12) . . ?
C65 Dy3 C44 110.05(11) . . ?
C65 Dy3 C45 106.04(12) . . ?
C65 Dy3 C63 50.57(13) . . ?
C65 Dy3 C67 50.64(12) . . ?
C65 Dy3 C46 128.19(12) . . ?
C65 Dy3 C66 30.70(12) . . ?
C65 Dy3 C64 30.89(13) . . ?
C67 Dy3 C42 134.95(12) . . ?
C67 Dy3 C45 120.47(13) . . ?
C67 Dy3 C63 30.56(13) . . ?
C67 Dy3 C46 115.16(12) . . ?
C67 Dy3 C66 30.38(13) . . ?
C66 Dy3 C42 165.04(12) . . ?
C66 Dy3 C45 132.43(12) . . ?
C66 Dy3 C63 50.27(13) . . ?
C66 Dy3 C46 141.94(12) . . ?
C64 Dy3 C42 127.86(12) . . ?
C64 Dy3 C45 81.69(12) . . ?
C64 Dy3 C63 30.63(13) . . ?
C64 Dy3 C67 50.78(12) . . ?
C64 Dy3 C46 98.20(12) . . ?
C64 Dy3 C66 50.75(12) . . ?
C1 Dy1 C2 30.63(11) . . ?
C5 Dy1 C1 30.60(11) . . ?
C5 Dy1 C4 30.74(12) . . ?
C5 Dy1 C2 50.79(12) . . ?
C5 Dy1 C3 50.47(12) . . ?
C5 Dy1 C28 129.52(14) . . ?
C5 Dy1 C27 144.82(15) . . ?
C5 Dy1 C29 133.89(15) . . ?
C5 Dy1 C31 172.71(17) . . ?
C5 Dy1 C30 156.40(17) . . ?
C4 Dy1 C1 50.83(11) . . ?
C4 Dy1 C2 51.21(11) . . ?
C4 Dy1 C27 120.28(15) . . ?
C3 Dy1 C1 50.44(12) . . ?
C3 Dy1 C4 30.78(12) . . ?
C3 Dy1 C2 30.83(11) . . ?
C3 Dy1 C28 83.45(14) . . ?
C3 Dy1 C27 94.74(15) . . ?
C3 Dy1 C31 125.33(16) . . ?
C28 Dy1 C1 131.07(14) . . ?
C28 Dy1 C4 99.03(14) . . ?
C28 Dy1 C2 101.11(15) . . ?
C28 Dy1 C27 30.19(16) . . ?
C27 Dy1 C1 126.05(14) . . ?
C27 Dy1 C2 97.53(15) . . ?
C29 Dy1 C1 154.48(16) . . ?
C29 Dy1 C4 106.44(15) . . ?
C29 Dy1 C2 128.83(16) . . ?
C29 Dy1 C3 104.30(16) . . ?
C29 Dy1 C28 30.10(17) . . ?
C29 Dy1 C27 50.05(16) . . ?
C29 Dy1 C31 50.73(17) . . ?
C31 Dy1 C1 142.47(16) . . ?
C31 Dy1 C4 149.10(15) . . ?
C31 Dy1 C2 122.21(17) . . ?
C31 Dy1 C28 50.40(15) . . ?
C31 Dy1 C27 30.63(18) . . ?
C30 Dy1 C1 172.59(17) . . ?
C30 Dy1 C4 136.08(17) . . ?
C30 Dy1 C2 147.60(16) . . ?
C30 Dy1 C3 132.92(16) . . ?
C30 Dy1 C28 50.14(17) . . ?
C30 Dy1 C27 50.27(18) . . ?
C30 Dy1 C29 30.71(19) . . ?
C30 Dy1 C31 30.71(19) . . ?
C37 C41 Dy2 76.0(2) . . ?
C40 C41 Dy2 77.6(2) . . ?
C40 C41 C37 110.2(3) . . ?
C9 C8 Dy2 74.6(2) . . ?
C9 C8 C19 127.1(3) . . ?
C7 C8 Dy2 71.8(2) . . ?
C7 C8 C9 105.8(3) . . ?
C7 C8 C19 124.1(4) . . ?
C19 C8 Dy2 133.4(2) . . ?
C41 C37 Dy2 72.7(2) . . ?
C41 C37 C42 124.9(3) . . ?
C41 C37 C38 107.0(3) . . ?
C42 C37 Dy2 120.2(2) . . ?
C38 C37 Dy2 77.3(2) . . ?
C38 C37 C42 127.8(3) . . ?
C5 C1 Dy1 71.9(2) . . ?
C5 C1 C2 107.6(3) . . ?
C5 C1 C6 125.9(3) . . ?
C2 C1 Dy1 74.9(2) . . ?
C2 C1 C6 126.2(3) . . ?
C6 C1 Dy1 123.8(2) . . ?
C37 C42 Dy3 125.8(2) . . ?
C43 C42 Dy3 70.4(2) . . ?
C43 C42 C37 124.7(3) . . ?
C43 C42 C46 107.9(3) . . ?
C46 C42 Dy3 76.9(2) . . ?
C46 C42 C37 126.7(3) . . ?
C1 C5 Dy1 77.5(2) . . ?
C4 C5 Dy1 76.1(2) . . ?
C4 C5 C1 110.0(3) . . ?
C8 C9 Dy2 74.8(2) . . ?
C8 C9 C10 110.2(3) . . ?
C10 C9 Dy2 77.1(2) . . ?
C42 C43 Dy3 78.8(2) . . ?
C44 C43 Dy3 76.3(2) . . ?
C44 C43 C42 109.7(3) . . ?
C41 C40 Dy2 71.9(2) . . ?
C41 C40 C39 106.1(3) . . ?
C41 C40 C51 124.7(4) . . ?
C39 C40 Dy2 74.4(2) . . ?
C39 C40 C51 126.5(4) . . ?
C51 C40 Dy2 133.5(3) . . ?
C37 C38 Dy2 71.9(2) . . ?
C37 C38 C47 130.9(3) . . ?
C39 C38 Dy2 72.8(2) . . ?
C39 C38 C37 106.1(3) . . ?
C39 C38 C47 120.3(3) . . ?
C47 C38 Dy2 134.6(2) . . ?
C43 C44 Dy3 72.6(2) . . ?
C43 C44 C55 126.8(3) . . ?
C45 C44 Dy3 75.7(2) . . ?
C45 C44 C43 105.7(3) . . ?
C45 C44 C55 126.6(3) . . ?
C55 C44 Dy3 125.2(2) . . ?
C40 C39 Dy2 75.2(2) . . ?
C40 C39 C38 110.5(3) . . ?
C38 C39 Dy2 76.8(2) . . ?
C8 C7 Dy2 77.5(2) . . ?
C8 C7 C6 110.6(3) . . ?
C6 C7 Dy2 76.4(2) . . ?
C44 C45 Dy3 73.7(2) . . ?
C44 C45 C46 110.7(3) . . ?
C46 C45 Dy3 78.2(2) . . ?
C5 C4 Dy1 73.2(2) . . ?
C5 C4 C3 106.1(3) . . ?
C5 C4 C15 126.0(3) . . ?
C3 C4 Dy1 73.8(2) . . ?
C3 C4 C15 126.8(4) . . ?
C15 C4 Dy1 127.2(3) . . ?
C1 C2 Dy1 74.5(2) . . ?
C1 C2 C11 129.5(3) . . ?
C11 C2 Dy1 127.0(3) . . ?
C3 C2 Dy1 72.2(2) . . ?
C3 C2 C1 106.0(3) . . ?
C3 C2 C11 123.5(4) . . ?
C57 C55 C44 113.6(3) . . ?
C58 C55 C44 108.8(4) . . ?
C58 C55 C57 107.9(4) . . ?
C56 C55 C44 109.7(3) . . ?
C56 C55 C57 107.8(4) . . ?
C56 C55 C58 109.0(4) . . ?
C9 C10 Dy2 72.5(2) . . ?
C9 C10 C6 106.1(3) . . ?
C9 C10 C23 121.4(3) . . ?
C6 C10 Dy2 71.6(2) . . ?
C6 C10 C23 130.6(3) . . ?
C23 C10 Dy2 133.0(3) . . ?
C38 C47 C48 110.2(3) . . ?
C38 C47 C50 106.4(3) . . ?
C49 C47 C38 117.6(3) . . ?
C49 C47 C48 107.7(3) . . ?
C49 C47 C50 107.7(3) . . ?
C48 C47 C50 106.7(3) . . ?
C1 C6 Dy2 122.4(2) . . ?
C7 C6 Dy2 72.5(2) . . ?
C7 C6 C1 122.5(3) . . ?
C7 C6 C10 107.1(3) . . ?
C10 C6 Dy2 77.6(2) . . ?
C10 C6 C1 129.7(3) . . ?
C67 C63 Dy3 74.5(2) . . ?
C67 C63 C68 124.6(4) . . ?
C64 C63 Dy3 73.9(2) . . ?
C64 C63 C67 108.3(4) . . ?
C64 C63 C68 124.5(4) . . ?
C68 C63 Dy3 132.2(3) . . ?
C2 C11 C14 110.2(4) . . ?
C2 C11 C13 114.5(3) . . ?
C2 C11 C12 109.5(3) . . ?
C14 C11 C13 108.4(4) . . ?
C14 C11 C12 106.2(4) . . ?
C13 C11 C12 107.6(4) . . ?
C70 C65 Dy3 124.9(3) . . ?
C66 C65 Dy3 75.4(2) . . ?
C66 C65 C70 125.2(4) . . ?
C66 C65 C64 107.9(4) . . ?
C64 C65 Dy3 74.6(2) . . ?
C64 C65 C70 125.9(4) . . ?
C46 C59 C62 109.0(3) . . ?
C46 C59 C60 109.8(3) . . ?
C46 C59 C61 114.4(3) . . ?
C62 C59 C60 106.6(3) . . ?
C62 C59 C61 108.0(4) . . ?
C60 C59 C61 108.8(3) . . ?
C63 C67 Dy3 74.9(2) . . ?
C63 C67 C72 126.5(4) . . ?
C66 C67 Dy3 74.9(2) . . ?
C66 C67 C63 108.0(4) . . ?
C66 C67 C72 125.0(4) . . ?
C72 C67 Dy3 122.6(3) . . ?
C4 C3 Dy1 75.4(2) . . ?
C4 C3 C2 110.1(3) . . ?
C2 C3 Dy1 77.0(2) . . ?
C8 C19 C21 106.0(3) . . ?
C20 C19 C8 112.7(3) . . ?
C20 C19 C21 108.0(3) . . ?
C22 C19 C8 112.0(3) . . ?
C22 C19 C20 110.5(4) . . ?
C22 C19 C21 107.4(4) . . ?
C42 C46 Dy3 73.1(2) . . ?
C42 C46 C59 128.3(3) . . ?
C45 C46 Dy3 71.6(2) . . ?
C45 C46 C42 105.9(3) . . ?
C45 C46 C59 123.9(3) . . ?
C59 C46 Dy3 132.0(2) . . ?
C65 C66 Dy3 73.9(2) . . ?
C65 C66 C71 125.9(4) . . ?
C67 C66 Dy3 74.7(2) . . ?
C67 C66 C65 108.3(4) . . ?
C67 C66 C71 125.3(4) . . ?
C71 C66 Dy3 124.4(3) . . ?
C10 C23 C26 106.3(4) . . ?
C10 C23 C24A 108.4(5) . . ?
C25 C23 C10 116.5(4) . . ?
C25 C23 C24 110.2(5) . . ?
C25 C23 C26 107.5(5) . . ?
C24 C23 C10 111.6(4) . . ?
C24 C23 C26 103.9(5) . . ?
C26A C23 C10 107.6(5) . . ?
C26A C23 C24A 106.4(6) . . ?
C26A C23 C25A 111.3(6) . . ?
C25A C23 C10 117.4(5) . . ?
C25A C23 C24A 105.2(6) . . ?
C63 C64 Dy3 75.5(2) . . ?
C63 C64 C65 107.5(4) . . ?
C63 C64 C69 125.4(4) . . ?
C65 C64 Dy3 74.5(2) . . ?
C65 C64 C69 125.9(4) . . ?
C69 C64 Dy3 125.2(3) . . ?
C18 C15 C4 110.6(3) . . ?
C16 C15 C4 107.8(4) . . ?
C16 C15 C18 107.8(4) . . ?
C16 C15 C17 110.8(5) . . ?
C17 C15 C4 111.3(3) . . ?
C17 C15 C18 108.5(4) . . ?
C27 C28 Dy1 75.7(3) . . ?
C27 C28 C33 124.1(5) . . ?
C29 C28 Dy1 74.2(3) . . ?
C29 C28 C27 108.9(5) . . ?
C29 C28 C33 126.1(5) . . ?
C33 C28 Dy1 124.9(3) . . ?
C28 C27 Dy1 74.1(3) . . ?
C28 C27 C31 107.9(5) . . ?
C28 C27 C32 125.0(6) . . ?
C31 C27 Dy1 73.9(3) . . ?
C31 C27 C32 124.9(6) . . ?
C32 C27 Dy1 131.2(4) . . ?
C78 C78 C77 114.3(5) 3_677 . ?
C40 C51 C54 113.9(4) . . ?
C40 C51 C52 105.5(4) . . ?
C54 C51 C52 107.0(5) . . ?
C53 C51 C40 111.4(4) . . ?
C53 C51 C54 108.6(4) . . ?
C53 C51 C52 110.3(6) . . ?
C28 C29 Dy1 75.7(3) . . ?
C28 C29 C30 107.9(5) . . ?
C28 C29 C34 128.5(6) . . ?
C30 C29 Dy1 74.3(3) . . ?
C30 C29 C34 122.7(6) . . ?
C34 C29 Dy1 124.1(4) . . ?
C27 C31 Dy1 75.5(3) . . ?
C27 C31 C36 123.8(6) . . ?
C30 C31 Dy1 73.7(3) . . ?
C30 C31 C27 106.8(5) . . ?
C30 C31 C36 128.8(7) . . ?
C36 C31 Dy1 123.2(3) . . ?
C29 C30 Dy1 75.0(3) . . ?
C29 C30 C31 108.5(5) . . ?
C29 C30 C35 127.0(7) . . ?
C31 C30 Dy1 75.6(3) . . ?
C31 C30 C35 124.1(7) . . ?
C35 C30 Dy1 121.9(4) . . ?
C76 C77 C78 113.7(6) . . ?
C73 C74 C75 99.0(14) . . ?
C74 C73 C73 96.0(15) . 3_667 ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
;
_oxdiff_exptl_absorpt_empirical_full_max 1.390
_oxdiff_exptl_absorpt_empirical_full_min 0.782
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Heat-sensitive,Oxygen-sensitive
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_2012
_database_code_depnum_ccdc_archive 'CCDC 2077343'
loop_
_audit_author_name
_audit_author_address
'Mian HE'
;University of Sussex
United Kingdom
;
_audit_update_record             
;
2021-04-13 deposited with the CCDC.	2021-05-28 downloaded from the CCDC.
;
_audit_creation_date             2020-12-11
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C72 H118 B2 Dy3, B C24 F20, C6 H14'
_chemical_formula_sum            'C102 H132 B3 Dy3 F20'
_chemical_formula_weight         2258.00
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -9.8046 9.8477 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.2955(5)
_cell_length_b                   17.6222(7)
_cell_length_c                   19.9866(6)
_cell_angle_alpha                80.945(3)
_cell_angle_beta                 88.122(3)
_cell_angle_gamma                88.861(3)
_cell_volume                     4969.0(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    12860
_cell_measurement_temperature    100.00(11)
_cell_measurement_theta_max      70.9080
_cell_measurement_theta_min      3.9680
_shelx_estimated_absorpt_T_max   0.787
_shelx_estimated_absorpt_T_min   0.254
_exptl_absorpt_coefficient_mu    12.576
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.69295
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'light yellow'
_exptl_crystal_colour_lustre     .
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.509
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2274
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0429
_diffrn_reflns_av_unetI/netI     0.0635
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            34352
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        67.076
_diffrn_reflns_theta_max         67.076
_diffrn_reflns_theta_min         3.641
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(11)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.1033
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -101.00 -74.00   1.00   10.00    --  -36.75 -57.00-150.00   27
  2  ω     35.00 104.00   1.00   10.00    --   36.75 178.00  60.00   69
  3  ω     39.00  97.00   1.00   10.00    --   36.75  77.00 150.00   58
  4  ω     21.00  99.00   1.00   10.00    --   36.75  57.00 120.00   78
  5  ω     10.00 104.00   1.00   10.00    --   36.75  77.00-120.00   94
  6  ω     46.00  76.00   1.00   10.00    --   36.75 -99.00 120.00   30
  7  ω     36.00 109.00   1.00   10.00    --   36.75 178.00 120.00   73
  8  ω     41.00  74.00   1.00   10.00    --   36.75 -99.00 -30.00   33
  9  ω     90.00 129.00   1.00   50.00    --  107.00  45.00 -90.00   39
 10  ω     43.00 135.00   1.00   50.00    --  107.00 -91.00 -15.05   92
 11  ω     39.00  65.00   1.00   50.00    --  107.00 -91.00 -84.02   26
 12  ω     91.00 116.00   1.00   50.00    --  107.00 -91.00 -84.02   25
 13  ω     79.00 105.00   1.00   50.00    --  107.00 -90.00 -64.13   26
 14  ω     40.00  65.00   1.00   50.00    --  107.00 -84.00 123.87   25
 15  ω     37.00 128.00   1.00   50.00    --  107.00 -30.00 -90.00   91
 16  ω     37.00  87.00   1.00   50.00    --  107.00-111.00 -30.00   50
 17  ω     43.00 136.00   1.00   50.00    --  107.00 -91.00 150.20   93
 18  ω     43.00 122.00   1.00   50.00    --  107.00 -45.00 120.00   79
 19  ω     76.00 101.00   1.00   50.00    --  107.00 -91.00  51.93   25
 20  ω     40.00 116.00   1.00   50.00    --  107.00 -45.00   0.00   76
 21  ω     51.00  77.00   1.00   50.00    --  107.00 178.00 -30.00   26
 22  ω    109.00 134.00   1.00   50.00    --  107.00 178.00 -30.00   25
 23  ω    149.00 175.00   1.00   50.00    --  107.00  45.00 -90.00   26
 24  ω     85.00 122.00   1.00   50.00    --  107.00 -91.00-154.50   37
 25  ω     82.00 107.00   1.00   50.00    --  107.00 -91.00  87.12   25
 26  ω     69.00 177.00   1.00   50.00    --  107.00  15.00-150.00  108
 27  ω     84.00 111.00   1.00   50.00    --  107.00 -61.00 -60.00   27
 28  ω     93.00 174.00   1.00   50.00    --  107.00  45.00  90.00   81
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0071610000
_diffrn_orient_matrix_UB_12      0.0870133000
_diffrn_orient_matrix_UB_13      0.0017514000
_diffrn_orient_matrix_UB_21      -0.1063899000
_diffrn_orient_matrix_UB_22      -0.0020691000
_diffrn_orient_matrix_UB_23      -0.0094494000
_diffrn_orient_matrix_UB_31      -0.0160729000
_diffrn_orient_matrix_UB_32      -0.0162114000
_diffrn_orient_matrix_UB_33      0.0774940000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance Ultra (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                14469
_reflns_number_total             17677
_reflns_odcompleteness_completeness 99.73
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         2.916
_refine_diff_density_min         -1.709
_refine_diff_density_rms         0.106
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.015
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1221
_refine_ls_number_reflns         17677
_refine_ls_number_restraints     29
_refine_ls_R_factor_all          0.0611
_refine_ls_R_factor_gt           0.0474
_refine_ls_restrained_S_all      1.018
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0598P)²+6.8249P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1141
_refine_ls_wR_factor_ref         0.1225
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C101-C102
 1.55 with sigma of 0.02
 C101-C100
 1.55 with sigma of 0.02
3. Rigid body (RIGU) restrains
 C99, C100, C101, C98, C102, C97
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
4.a Secondary CH2 refined with riding coordinates:
 C100(H10A,H10B), C98(H98A,H98B), C99(H99A,H99B), C101(H10F,H10G)
4.b Aromatic/amide H refined with riding coordinates:
 C41(H41), C3(H3), C45(H45), C9(H9), C43(H43), C7(H7), C5(H5), C39(H39)
4.c Idealised Me refined as rotating group:
 C21(H21A,H21B,H21C), C61(H61A,H61B,H61C), C68(H68A,H68B,H68C), C13(H13A,H13B,
 H13C), C50(H50A,H50B,H50C), C17(H17A,H17B,H17C), C16(H16A,H16B,H16C), C35(H35A,
 H35B,H35C), C14(H14A,H14B,H14C), C72(H72A,H72B,H72C), C62(H62A,H62B,H62C),
 C48(H48A,H48B,H48C), C36(H36A,H36B,H36C), C60(H60A,H60B,H60C), C32(H32A,H32B,
 H32C), C54(H54A,H54B,H54C), C20(H20A,H20B,H20C), C53(H53A,H53B,H53C), C70(H70A,
 H70B,H70C), C18(H18A,H18B,H18C), C69(H69A,H69B,H69C), C12(H12A,H12B,H12C),
 C49(H49A,H49B,H49C), C71(H71A,H71B,H71C), C33(H33A,H33B,H33C), C52(H52A,H52B,
 H52C), C22(H22A,H22B,H22C), C34(H34A,H34B,H34C), C24(H24A,H24B,H24C), C25(H25A,
 H25B,H25C), C26(H26A,H26B,H26C), C56(H56A,H56B,H56C), C97(H97A,H97B,H97C),
 C57(H57A,H57B,H57C), C58(H58A,H58B,H58C), C102(H10C,H10D,H10E)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy2 Dy 0.15946(2) 0.71074(2) 0.24948(2) 0.02084(8) Uani 1 1 d . . . . .
Dy1 Dy -0.12967(2) 0.81874(2) 0.14834(2) 0.02575(8) Uani 1 1 d . . . . .
Dy3 Dy 0.19469(2) 0.80552(2) 0.46311(2) 0.02828(8) Uani 1 1 d . . . . .
F4 F 0.6970(2) 0.87034(16) 0.60969(15) 0.0276(6) Uani 1 1 d . . . . .
F8 F 0.7509(2) 0.91662(16) 0.73675(15) 0.0294(6) Uani 1 1 d . . . . .
F14 F 0.6517(2) 0.83078(17) 0.84878(15) 0.0308(6) Uani 1 1 d . . . . .
F18 F 0.7402(2) 0.68285(17) 0.87050(15) 0.0312(6) Uani 1 1 d . . . . .
F9 F 0.8209(2) 0.65060(17) 0.74771(16) 0.0336(7) Uani 1 1 d . . . . .
F5 F 0.7177(2) 0.84579(18) 0.48162(15) 0.0325(7) Uani 1 1 d . . . . .
F13 F 0.5073(2) 0.83250(18) 0.63834(16) 0.0338(7) Uani 1 1 d . . . . .
F3 F 0.6612(3) 0.60274(17) 0.67984(15) 0.0373(8) Uani 1 1 d . . . . .
F7 F 0.9287(2) 0.9420(2) 0.75587(17) 0.0381(7) Uani 1 1 d . . . . .
F19 F 0.4970(2) 0.67940(19) 0.71595(17) 0.0369(7) Uani 1 1 d . . . . .
F15 F 0.5261(3) 0.9331(2) 0.88037(18) 0.0421(8) Uani 1 1 d . . . . .
F10 F 1.0002(2) 0.6782(2) 0.76688(19) 0.0448(9) Uani 1 1 d . . . . .
F20 F 0.4167(2) 0.5656(2) 0.79985(19) 0.0423(8) Uani 1 1 d . . . . .
F2 F 0.6762(3) 0.58087(18) 0.55217(16) 0.0449(9) Uani 1 1 d . . . . .
F1 F 0.7065(3) 0.7014(2) 0.45097(16) 0.0436(8) Uani 1 1 d . . . . .
F17 F 0.6553(3) 0.5744(2) 0.95494(16) 0.0425(8) Uani 1 1 d . . . . .
F6 F 1.0567(2) 0.8247(2) 0.77057(18) 0.0446(9) Uani 1 1 d . . . . .
F12 F 0.3843(2) 0.9350(2) 0.6715(2) 0.0456(9) Uani 1 1 d . . . . .
F11 F 0.3901(3) 0.9874(2) 0.7919(2) 0.0512(10) Uani 1 1 d . . . . .
F16 F 0.4936(3) 0.5118(2) 0.92116(18) 0.0479(9) Uani 1 1 d . . . . .
C81 C 0.8086(4) 0.8545(3) 0.7443(2) 0.0259(10) Uani 1 1 d . . . . .
C6 C 0.0256(4) 0.6478(3) 0.1823(3) 0.0261(10) Uani 1 1 d . . . . .
C76 C 0.6738(3) 0.7385(3) 0.6520(3) 0.0239(10) Uani 1 1 d . . . . .
C82 C 0.7750(3) 0.7811(3) 0.7438(2) 0.0229(10) Uani 1 1 d . . . . .
C41 C 0.2747(3) 0.8223(3) 0.2635(3) 0.0238(10) Uani 1 1 d . . . . .
H41 H 0.243418 0.865372 0.277773 0.029 Uiso 1 1 calc R U . . .
C37 C 0.3129(3) 0.7588(3) 0.3080(3) 0.0255(10) Uani 1 1 d . . . . .
C3 C -0.1606(3) 0.7250(3) 0.0616(3) 0.0246(10) Uani 1 1 d . . . . .
H3 H -0.221008 0.728222 0.042814 0.030 Uiso 1 1 calc R U . . .
C80 C 0.9014(4) 0.8695(3) 0.7535(2) 0.0279(11) Uani 1 1 d . . . . .
C77 C 0.6905(3) 0.7968(3) 0.5980(3) 0.0234(10) Uani 1 1 d . . . . .
C45 C 0.3703(4) 0.7711(3) 0.4870(3) 0.0273(10) Uani 1 1 d . . . . .
H45 H 0.395743 0.792561 0.523078 0.033 Uiso 1 1 calc R U . . .
C75 C 0.6718(4) 0.6666(3) 0.6330(3) 0.0288(11) Uani 1 1 d . . . . .
C9 C 0.1326(4) 0.5645(3) 0.2382(3) 0.0259(10) Uani 1 1 d . . . . .
H9 H 0.186352 0.532299 0.247061 0.031 Uiso 1 1 calc R U . . .
C43 C 0.2946(4) 0.6914(3) 0.4305(3) 0.0294(11) Uani 1 1 d . . . . .
H43 H 0.260011 0.649220 0.420707 0.035 Uiso 1 1 calc R U . . .
C42 C 0.3229(4) 0.7550(3) 0.3822(3) 0.0276(11) Uani 1 1 d . . . . .
C7 C 0.0027(4) 0.6348(3) 0.2531(3) 0.0250(10) Uani 1 1 d . . . . .
H7 H -0.047187 0.659338 0.274317 0.030 Uiso 1 1 calc R U . . .
C46 C 0.3724(4) 0.8063(3) 0.4179(3) 0.0262(10) Uani 1 1 d . . . . .
C8 C 0.0657(4) 0.5796(3) 0.2872(3) 0.0254(10) Uani 1 1 d . . . . .
C83 C 0.8440(4) 0.7239(3) 0.7505(3) 0.0286(11) Uani 1 1 d . . . . .
C1 C -0.0372(4) 0.6897(3) 0.1310(3) 0.0267(10) Uani 1 1 d . . . . .
C27 C -0.2791(4) 0.9056(3) 0.1292(3) 0.0329(12) Uani 1 1 d . . . . .
C87 C 0.5232(4) 0.9085(3) 0.8203(3) 0.0318(12) Uani 1 1 d . . . . .
C10 C 0.1088(4) 0.6044(3) 0.1726(3) 0.0276(11) Uani 1 1 d . . . . .
C31 C -0.3042(4) 0.8430(3) 0.1816(3) 0.0298(11) Uani 1 1 d . . . . .
C40 C 0.2901(4) 0.8121(3) 0.1954(3) 0.0269(10) Uani 1 1 d . . . . .
C5 C -0.0100(4) 0.7500(3) 0.0796(3) 0.0273(11) Uani 1 1 d . . . . .
H5 H 0.049830 0.773185 0.075402 0.033 Uiso 1 1 calc R U . . .
C85 C 0.5891(3) 0.8272(3) 0.7411(3) 0.0241(10) Uani 1 1 d . . . . .
C2 C -0.1339(4) 0.6727(3) 0.1205(3) 0.0277(11) Uani 1 1 d . . . . .
C4 C -0.0839(4) 0.7711(3) 0.0355(3) 0.0255(10) Uani 1 1 d . . . . .
C30 C -0.2519(4) 0.8512(3) 0.2385(3) 0.0297(11) Uani 1 1 d . . . . .
C74 C 0.6818(4) 0.6528(3) 0.5670(3) 0.0318(12) Uani 1 1 d . . . . .
C86 C 0.5876(4) 0.8559(3) 0.8022(3) 0.0271(10) Uani 1 1 d . . . . .
C79 C 0.9664(4) 0.8102(4) 0.7614(3) 0.0338(12) Uani 1 1 d . . . . .
C96 C 0.6605(4) 0.6564(3) 0.8489(3) 0.0288(11) Uani 1 1 d . . . . .
C38 C 0.3503(3) 0.7054(3) 0.2663(3) 0.0254(10) Uani 1 1 d . . . . .
C28 C -0.2136(4) 0.9506(3) 0.1564(3) 0.0347(12) Uani 1 1 d . . . . .
C19 C 0.0472(4) 0.5303(3) 0.3566(3) 0.0270(10) Uani 1 1 d . . . . .
C90 C 0.5170(4) 0.8554(3) 0.6990(3) 0.0284(11) Uani 1 1 d . . . . .
C51 C 0.2873(4) 0.8741(3) 0.1329(3) 0.0278(11) Uani 1 1 d . . . . .
C59 C 0.4249(4) 0.8803(3) 0.3907(3) 0.0321(12) Uani 1 1 d . . . . .
C65 C 0.0640(4) 0.8334(3) 0.5503(3) 0.0328(12) Uani 1 1 d . . . . .
C73 C 0.6968(4) 0.7134(3) 0.5152(3) 0.0320(12) Uani 1 1 d . . . . .
C15 C -0.0793(4) 0.8338(3) -0.0259(3) 0.0297(11) Uani 1 1 d . . . . .
C39 C 0.3331(4) 0.7388(3) 0.1981(3) 0.0287(11) Uani 1 1 d . . . . .
H39 H 0.348338 0.714929 0.159609 0.034 Uiso 1 1 calc R U . . .
C91 C 0.6249(4) 0.6853(3) 0.7864(3) 0.0256(10) Uani 1 1 d . . . . .
C78 C 0.7019(4) 0.7862(3) 0.5317(3) 0.0261(10) Uani 1 1 d . . . . .
C21 C -0.0301(5) 0.5655(3) 0.3979(3) 0.0391(13) Uani 1 1 d . . . . .
H21A H -0.010344 0.615791 0.406850 0.059 Uiso 1 1 calc R U . . .
H21B H -0.041589 0.531463 0.441013 0.059 Uiso 1 1 calc R U . . .
H21C H -0.087740 0.571666 0.372237 0.059 Uiso 1 1 calc R U . . .
C61 C 0.3567(4) 0.9469(3) 0.3677(3) 0.0316(11) Uani 1 1 d . . . . .
H61A H 0.322206 0.935807 0.328905 0.047 Uiso 1 1 calc R U . . .
H61B H 0.391777 0.994411 0.354614 0.047 Uiso 1 1 calc R U . . .
H61C H 0.312447 0.953076 0.405093 0.047 Uiso 1 1 calc R U . . .
C95 C 0.6179(5) 0.5994(3) 0.8941(3) 0.0345(13) Uani 1 1 d . . . . .
C89 C 0.4517(4) 0.9092(3) 0.7157(3) 0.0348(12) Uani 1 1 d . . . . .
C67 C 0.1127(4) 0.9382(3) 0.4740(3) 0.0317(12) Uani 1 1 d . . . . .
C88 C 0.4544(4) 0.9359(3) 0.7761(3) 0.0360(13) Uani 1 1 d . . . . .
C92 C 0.5407(4) 0.6530(3) 0.7737(3) 0.0293(11) Uani 1 1 d . . . . .
C44 C 0.3249(4) 0.6995(3) 0.4944(3) 0.0307(11) Uani 1 1 d . . . . .
C29 C -0.1967(4) 0.9167(3) 0.2232(3) 0.0333(12) Uani 1 1 d . . . . .
C64 C 0.1479(4) 0.8596(3) 0.5735(3) 0.0314(11) Uani 1 1 d . . . . .
C84 C 0.9367(4) 0.7363(4) 0.7598(3) 0.0331(12) Uani 1 1 d . . . . .
C63 C 0.1782(4) 0.9241(3) 0.5258(3) 0.0292(11) Uani 1 1 d . . . . .
C68 C 0.2587(4) 0.9741(3) 0.5377(3) 0.0361(13) Uani 1 1 d . . . . .
H68A H 0.314640 0.941925 0.548218 0.054 Uiso 1 1 calc R U . . .
H68B H 0.242504 1.001245 0.575790 0.054 Uiso 1 1 calc R U . . .
H68C H 0.271173 1.011557 0.496842 0.054 Uiso 1 1 calc R U . . .
C11 C -0.1932(4) 0.6050(3) 0.1532(3) 0.0321(12) Uani 1 1 d . . . . .
C13 C -0.2252(4) 0.6094(4) 0.2266(3) 0.0411(14) Uani 1 1 d . . . . .
H13A H -0.171596 0.599429 0.256189 0.062 Uiso 1 1 calc R U . . .
H13B H -0.273255 0.570915 0.241088 0.062 Uiso 1 1 calc R U . . .
H13C H -0.251177 0.660790 0.229270 0.062 Uiso 1 1 calc R U . . .
C50 C 0.4942(4) 0.6587(3) 0.3299(3) 0.0338(12) Uani 1 1 d . . . . .
H50A H 0.525728 0.704483 0.306090 0.051 Uiso 1 1 calc R U . . .
H50B H 0.539775 0.616326 0.339003 0.051 Uiso 1 1 calc R U . . .
H50C H 0.466524 0.669871 0.372891 0.051 Uiso 1 1 calc R U . . .
C17 C -0.1674(4) 0.8354(3) -0.0669(3) 0.0336(12) Uani 1 1 d . . . . .
H17A H -0.172649 0.786479 -0.083932 0.050 Uiso 1 1 calc R U . . .
H17B H -0.164022 0.877555 -0.105139 0.050 Uiso 1 1 calc R U . . .
H17C H -0.222338 0.843009 -0.037896 0.050 Uiso 1 1 calc R U . . .
C16 C 0.0057(4) 0.8178(4) -0.0708(3) 0.0395(13) Uani 1 1 d . . . . .
H16A H 0.062846 0.817361 -0.044964 0.059 Uiso 1 1 calc R U . . .
H16B H 0.009696 0.858111 -0.110601 0.059 Uiso 1 1 calc R U . . .
H16C H -0.001174 0.767810 -0.085541 0.059 Uiso 1 1 calc R U . . .
C94 C 0.5359(4) 0.5677(3) 0.8783(3) 0.0339(12) Uani 1 1 d . . . . .
C35 C -0.2578(4) 0.7994(4) 0.3069(3) 0.0429(14) Uani 1 1 d . . . . .
H35A H -0.296115 0.754807 0.303352 0.064 Uiso 1 1 calc R U . . .
H35B H -0.286401 0.828073 0.340710 0.064 Uiso 1 1 calc R U . . .
H35C H -0.194764 0.782065 0.320587 0.064 Uiso 1 1 calc R U . . .
C47 C 0.4174(4) 0.6360(3) 0.2861(3) 0.0299(11) Uani 1 1 d . . . . .
C14 C -0.2814(5) 0.6012(4) 0.1127(3) 0.0428(14) Uani 1 1 d . . . . .
H14A H -0.321118 0.646475 0.115964 0.064 Uiso 1 1 calc R U . . .
H14B H -0.315823 0.554595 0.131002 0.064 Uiso 1 1 calc R U . . .
H14C H -0.263689 0.600009 0.065043 0.064 Uiso 1 1 calc R U . . .
C66 C 0.0422(4) 0.8809(3) 0.4888(3) 0.0351(12) Uani 1 1 d . . . . .
C72 C 0.1114(4) 1.0012(4) 0.4136(3) 0.0401(14) Uani 1 1 d . . . . .
H72A H 0.166331 1.033533 0.413791 0.060 Uiso 1 1 calc R U . . .
H72B H 0.054354 1.032524 0.415789 0.060 Uiso 1 1 calc R U . . .
H72C H 0.112741 0.978385 0.371876 0.060 Uiso 1 1 calc R U . . .
C93 C 0.4972(4) 0.5952(3) 0.8168(3) 0.0328(12) Uani 1 1 d . . . . .
C62 C 0.4891(4) 0.8673(4) 0.3301(4) 0.0440(15) Uani 1 1 d . . . . .
H62A H 0.535016 0.826521 0.344912 0.066 Uiso 1 1 calc R U . . .
H62B H 0.521871 0.914916 0.312444 0.066 Uiso 1 1 calc R U . . .
H62C H 0.451433 0.852101 0.294489 0.066 Uiso 1 1 calc R U . . .
C23 C 0.1542(4) 0.5789(3) 0.1085(3) 0.0313(11) Uani 1 1 d . . . . .
C48 C 0.4655(4) 0.6135(3) 0.2216(3) 0.0371(13) Uani 1 1 d . . . . .
H48A H 0.417858 0.599692 0.191641 0.056 Uiso 1 1 calc R U . . .
H48B H 0.507751 0.569443 0.234209 0.056 Uiso 1 1 calc R U . . .
H48C H 0.501405 0.657015 0.197980 0.056 Uiso 1 1 calc R U . . .
C36 C -0.3819(4) 0.7885(4) 0.1771(3) 0.0414(14) Uani 1 1 d . . . . .
H36A H -0.387284 0.780441 0.129923 0.062 Uiso 1 1 calc R U . . .
H36B H -0.440899 0.810028 0.192710 0.062 Uiso 1 1 calc R U . . .
H36C H -0.368457 0.739213 0.205601 0.062 Uiso 1 1 calc R U . . .
C60 C 0.4845(4) 0.9038(3) 0.4458(4) 0.0427(15) Uani 1 1 d . . . . .
H60A H 0.443808 0.915056 0.483475 0.064 Uiso 1 1 calc R U . . .
H60B H 0.520066 0.949674 0.427066 0.064 Uiso 1 1 calc R U . . .
H60C H 0.527974 0.861735 0.462089 0.064 Uiso 1 1 calc R U . . .
C55 C 0.3141(5) 0.6388(3) 0.5583(3) 0.0393(13) Uani 1 1 d . . . . .
C32 C -0.3294(4) 0.9265(4) 0.0633(3) 0.0451(15) Uani 1 1 d . . . . .
H32A H -0.286954 0.954508 0.029022 0.068 Uiso 1 1 calc R U . . .
H32B H -0.384113 0.959103 0.070404 0.068 Uiso 1 1 calc R U . . .
H32C H -0.349857 0.879613 0.047896 0.068 Uiso 1 1 calc R U . . .
C54 C 0.2410(5) 0.9478(3) 0.1501(4) 0.0466(16) Uani 1 1 d . . . . .
H54A H 0.175188 0.938089 0.163453 0.070 Uiso 1 1 calc R U . . .
H54B H 0.244708 0.988085 0.110368 0.070 Uiso 1 1 calc R U . . .
H54C H 0.273372 0.964430 0.187677 0.070 Uiso 1 1 calc R U . . .
C20 C 0.0119(5) 0.4534(3) 0.3419(3) 0.0412(14) Uani 1 1 d . . . . .
H20A H -0.043636 0.462265 0.314091 0.062 Uiso 1 1 calc R U . . .
H20B H -0.004184 0.420266 0.384639 0.062 Uiso 1 1 calc R U . . .
H20C H 0.061090 0.428365 0.317377 0.062 Uiso 1 1 calc R U . . .
C53 C 0.3901(4) 0.8916(3) 0.1101(3) 0.0369(13) Uani 1 1 d . . . . .
H53A H 0.422866 0.909633 0.146794 0.055 Uiso 1 1 calc R U . . .
H53B H 0.391543 0.931433 0.069923 0.055 Uiso 1 1 calc R U . . .
H53C H 0.421043 0.844762 0.099120 0.055 Uiso 1 1 calc R U . . .
C70 C 0.0021(5) 0.7712(4) 0.5866(3) 0.0476(16) Uani 1 1 d . . . . .
H70A H -0.017261 0.738169 0.554545 0.071 Uiso 1 1 calc R U . . .
H70B H -0.053424 0.794461 0.605705 0.071 Uiso 1 1 calc R U . . .
H70C H 0.036562 0.740370 0.623156 0.071 Uiso 1 1 calc R U . . .
C18 C -0.0677(4) 0.9118(3) -0.0026(3) 0.0350(12) Uani 1 1 d . . . . .
H18A H -0.121847 0.922316 0.026052 0.053 Uiso 1 1 calc R U . . .
H18B H -0.063284 0.952227 -0.042302 0.053 Uiso 1 1 calc R U . . .
H18C H -0.010534 0.910842 0.023288 0.053 Uiso 1 1 calc R U . . .
B3 B 0.6658(4) 0.7575(3) 0.7306(3) 0.0240(11) Uani 1 1 d . . . . .
C69 C 0.1922(5) 0.8350(4) 0.6407(3) 0.0429(15) Uani 1 1 d . . . . .
H69A H 0.170211 0.783767 0.660471 0.064 Uiso 1 1 calc R U . . .
H69B H 0.174769 0.871666 0.671310 0.064 Uiso 1 1 calc R U . . .
H69C H 0.260383 0.833542 0.634293 0.064 Uiso 1 1 calc R U . . .
C12 C -0.1366(5) 0.5296(3) 0.1524(4) 0.0448(15) Uani 1 1 d . . . . .
H12A H -0.119141 0.524236 0.105486 0.067 Uiso 1 1 calc R U . . .
H12B H -0.174783 0.485859 0.172719 0.067 Uiso 1 1 calc R U . . .
H12C H -0.079827 0.530705 0.178400 0.067 Uiso 1 1 calc R U . . .
C49 C 0.3692(4) 0.5648(3) 0.3230(3) 0.0385(13) Uani 1 1 d . . . . .
H49A H 0.340144 0.576158 0.365510 0.058 Uiso 1 1 calc R U . . .
H49B H 0.415289 0.523019 0.332927 0.058 Uiso 1 1 calc R U . . .
H49C H 0.320857 0.549343 0.294407 0.058 Uiso 1 1 calc R U . . .
C71 C -0.0465(4) 0.8798(4) 0.4506(4) 0.0498(16) Uani 1 1 d . . . . .
H71A H -0.033246 0.895991 0.402069 0.075 Uiso 1 1 calc R U . . .
H71B H -0.092776 0.915045 0.466745 0.075 Uiso 1 1 calc R U . . .
H71C H -0.071411 0.827604 0.457981 0.075 Uiso 1 1 calc R U . . .
B2 B 0.0814(5) 0.7482(4) 0.3791(3) 0.0323(13) Uani 1 1 d . . . . .
C33 C -0.1745(5) 1.0268(3) 0.1228(4) 0.0501(17) Uani 1 1 d . . . . .
H33A H -0.109048 1.030133 0.134980 0.075 Uiso 1 1 calc R U . . .
H33B H -0.210999 1.068806 0.138233 0.075 Uiso 1 1 calc R U . . .
H33C H -0.178198 1.030842 0.073509 0.075 Uiso 1 1 calc R U . . .
C52 C 0.2365(5) 0.8468(4) 0.0745(3) 0.0503(17) Uani 1 1 d . . . . .
H52A H 0.260848 0.795994 0.068065 0.076 Uiso 1 1 calc R U . . .
H52B H 0.247103 0.883355 0.032794 0.076 Uiso 1 1 calc R U . . .
H52C H 0.169272 0.843681 0.085564 0.076 Uiso 1 1 calc R U . . .
C22 C 0.1348(5) 0.5155(5) 0.3971(3) 0.0511(18) Uani 1 1 d . . . . .
H22A H 0.184917 0.496839 0.369004 0.077 Uiso 1 1 calc R U . . .
H22B H 0.122282 0.476790 0.437116 0.077 Uiso 1 1 calc R U . . .
H22C H 0.154060 0.563351 0.411575 0.077 Uiso 1 1 calc R U . . .
B1 B 0.0287(5) 0.8429(4) 0.2103(3) 0.0329(13) Uani 1 1 d . . . . .
C34 C -0.1411(5) 0.9507(4) 0.2738(4) 0.0492(16) Uani 1 1 d . . . . .
H34A H -0.113734 0.909188 0.306067 0.074 Uiso 1 1 calc R U . . .
H34B H -0.182474 0.982634 0.298241 0.074 Uiso 1 1 calc R U . . .
H34C H -0.090989 0.982282 0.249944 0.074 Uiso 1 1 calc R U . . .
C24 C 0.2604(5) 0.5778(5) 0.1113(4) 0.060(2) Uani 1 1 d . . . . .
H24A H 0.282450 0.630235 0.110621 0.090 Uiso 1 1 calc R U . . .
H24B H 0.287303 0.557161 0.072094 0.090 Uiso 1 1 calc R U . . .
H24C H 0.279748 0.545346 0.153123 0.090 Uiso 1 1 calc R U . . .
C25 C 0.1242(5) 0.4956(4) 0.1063(4) 0.0498(16) Uani 1 1 d . . . . .
H25A H 0.145478 0.461978 0.146899 0.075 Uiso 1 1 calc R U . . .
H25B H 0.152229 0.478184 0.065835 0.075 Uiso 1 1 calc R U . . .
H25C H 0.055831 0.493814 0.104722 0.075 Uiso 1 1 calc R U . . .
C26 C 0.1274(7) 0.6250(5) 0.0407(4) 0.075(3) Uani 1 1 d . . . . .
H26A H 0.059201 0.625174 0.036879 0.112 Uiso 1 1 calc R U . . .
H26B H 0.156842 0.601629 0.003777 0.112 Uiso 1 1 calc R U . . .
H26C H 0.148826 0.677946 0.037806 0.112 Uiso 1 1 calc R U . . .
C56 C 0.2088(6) 0.6354(6) 0.5757(4) 0.073(3) Uani 1 1 d . . . . .
H56A H 0.186892 0.685151 0.586691 0.109 Uiso 1 1 calc R U . . .
H56B H 0.197143 0.595285 0.614798 0.109 Uiso 1 1 calc R U . . .
H56C H 0.175241 0.623566 0.536746 0.109 Uiso 1 1 calc R U . . .
C100 C 0.3922(7) 0.7306(5) 0.9195(5) 0.075(3) Uani 1 1 d D . . . .
H10A H 0.358879 0.682079 0.935548 0.089 Uiso 1 1 calc R U . . .
H10B H 0.441852 0.717831 0.887206 0.089 Uiso 1 1 calc R U . . .
C97 C 0.2312(7) 0.6895(5) 0.8194(6) 0.079(3) Uani 1 1 d . . . . .
H97A H 0.217950 0.686624 0.772081 0.118 Uiso 1 1 calc R U . . .
H97B H 0.172339 0.688091 0.846075 0.118 Uiso 1 1 calc R U . . .
H97C H 0.271127 0.645761 0.837665 0.118 Uiso 1 1 calc R U . . .
C57 C 0.3649(8) 0.6611(5) 0.6142(4) 0.074(3) Uani 1 1 d . . . . .
H57A H 0.432051 0.662911 0.602469 0.111 Uiso 1 1 calc R U . . .
H57B H 0.354051 0.623318 0.655138 0.111 Uiso 1 1 calc R U . . .
H57C H 0.342864 0.711842 0.622512 0.111 Uiso 1 1 calc R U . . .
C58 C 0.3475(9) 0.5624(5) 0.5423(5) 0.087(3) Uani 1 1 d . . . . .
H58A H 0.309854 0.547823 0.506423 0.131 Uiso 1 1 calc R U . . .
H58B H 0.341214 0.523593 0.583062 0.131 Uiso 1 1 calc R U . . .
H58C H 0.413389 0.565759 0.527097 0.131 Uiso 1 1 calc R U . . .
C98 C 0.2792(10) 0.7609(7) 0.8230(7) 0.108(4) Uani 1 1 d . . . . .
H98A H 0.325378 0.767410 0.784590 0.130 Uiso 1 1 calc R U . . .
H98B H 0.231740 0.802429 0.812361 0.130 Uiso 1 1 calc R U . . .
C102 C 0.5077(9) 0.7012(8) 1.0140(5) 0.111(5) Uani 1 1 d D . . . .
H10C H 0.570411 0.718837 0.998297 0.166 Uiso 1 1 calc R U . . .
H10D H 0.501030 0.647530 1.007713 0.166 Uiso 1 1 calc R U . . .
H10E H 0.498932 0.705111 1.062202 0.166 Uiso 1 1 calc R U . . .
C99 C 0.3269(9) 0.7784(6) 0.8792(6) 0.097(3) Uani 1 1 d . . . . .
H99A H 0.277402 0.791654 0.911399 0.116 Uiso 1 1 calc R U . . .
H99B H 0.360280 0.826704 0.862536 0.116 Uiso 1 1 calc R U . . .
C101 C 0.4399(10) 0.7472(8) 0.9765(7) 0.124(5) Uani 1 1 d D . . . .
H10F H 0.470175 0.797258 0.961235 0.148 Uiso 1 1 calc R U . . .
H10G H 0.390247 0.756821 1.009928 0.148 Uiso 1 1 calc R U . . .
H2A H 0.124(3) 0.702(3) 0.355(2) 0.010(11) Uiso 1 1 d . . . . .
H1A H -0.040(4) 0.800(4) 0.240(3) 0.030(15) Uiso 1 1 d . . . . .
H1B H 0.090(4) 0.809(4) 0.188(3) 0.034(16) Uiso 1 1 d . . . . .
H1C H -0.001(4) 0.875(3) 0.161(3) 0.023(14) Uiso 1 1 d . . . . .
H2B H 0.077(4) 0.726(4) 0.436(3) 0.030(16) Uiso 1 1 d . . . . .
H2C H 0.121(6) 0.802(5) 0.366(4) 0.06(2) Uiso 1 1 d . . . . .
H1D H 0.055(6) 0.869(5) 0.247(4) 0.06(2) Uiso 1 1 d . . . . .
H2D H 0.011(7) 0.753(5) 0.358(5) 0.08(3) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy2 C6 2.723(5) . ?
Dy2 C41 2.645(5) . ?
Dy2 C37 2.730(5) . ?
Dy2 C9 2.659(5) . ?
Dy2 C7 2.626(5) . ?
Dy2 C8 2.686(5) . ?
Dy2 C10 2.726(5) . ?
Dy2 C40 2.691(5) . ?
Dy2 C38 2.757(5) . ?
Dy2 C39 2.680(5) . ?
Dy2 B2 2.951(6) . ?
Dy2 B1 2.980(6) . ?
Dy2 H2A 2.13(5) . ?
Dy2 H1B 2.19(6) . ?
Dy1 C3 2.629(5) . ?
Dy1 C1 2.672(5) . ?
Dy1 C27 2.606(5) . ?
Dy1 C31 2.606(5) . ?
Dy1 C5 2.562(5) . ?
Dy1 C2 2.719(5) . ?
Dy1 C4 2.587(5) . ?
Dy1 C30 2.590(5) . ?
Dy1 C28 2.620(5) . ?
Dy1 C29 2.605(5) . ?
Dy1 B1 2.688(7) . ?
Dy1 H1A 2.24(6) . ?
Dy1 H1C 2.15(6) . ?
Dy3 C45 2.613(5) . ?
Dy3 C43 2.598(5) . ?
Dy3 C42 2.639(5) . ?
Dy3 C46 2.668(5) . ?
Dy3 C65 2.606(5) . ?
Dy3 C67 2.630(5) . ?
Dy3 C44 2.630(5) . ?
Dy3 C64 2.601(5) . ?
Dy3 C63 2.603(5) . ?
Dy3 C66 2.609(6) . ?
Dy3 B2 2.691(6) . ?
Dy3 H2B 2.34(6) . ?
Dy3 H2C 2.26(8) . ?
F4 C77 1.359(6) . ?
F8 C81 1.349(6) . ?
F14 C86 1.346(6) . ?
F18 C96 1.348(7) . ?
F9 C83 1.349(6) . ?
F5 C78 1.348(6) . ?
F13 C90 1.349(6) . ?
F3 C75 1.354(6) . ?
F7 C80 1.351(6) . ?
F19 C92 1.343(6) . ?
F15 C87 1.341(7) . ?
F10 C84 1.349(7) . ?
F20 C93 1.348(7) . ?
F2 C74 1.351(6) . ?
F1 C73 1.336(6) . ?
F17 C95 1.349(7) . ?
F6 C79 1.345(7) . ?
F12 C89 1.353(7) . ?
F11 C88 1.344(6) . ?
F16 C94 1.341(7) . ?
C81 C82 1.391(7) . ?
C81 C80 1.382(8) . ?
C6 C7 1.426(7) . ?
C6 C1 1.482(7) . ?
C6 C10 1.425(7) . ?
C76 C77 1.386(7) . ?
C76 C75 1.380(7) . ?
C76 B3 1.656(7) . ?
C82 C83 1.390(7) . ?
C82 B3 1.664(7) . ?
C41 H41 0.9500 . ?
C41 C37 1.427(7) . ?
C41 C40 1.411(7) . ?
C37 C42 1.485(8) . ?
C37 C38 1.435(7) . ?
C3 H3 0.9500 . ?
C3 C2 1.433(7) . ?
C3 C4 1.414(7) . ?
C80 C79 1.378(8) . ?
C77 C78 1.371(7) . ?
C45 H45 0.9500 . ?
C45 C46 1.423(7) . ?
C45 C44 1.415(8) . ?
C75 C74 1.381(8) . ?
C9 H9 0.9500 . ?
C9 C8 1.399(7) . ?
C9 C10 1.435(7) . ?
C43 H43 0.9500 . ?
C43 C42 1.415(8) . ?
C43 C44 1.391(8) . ?
C42 C46 1.445(7) . ?
C7 H7 0.9500 . ?
C7 C8 1.419(7) . ?
C46 C59 1.533(7) . ?
C8 C19 1.535(7) . ?
C83 C84 1.371(8) . ?
C1 C5 1.409(8) . ?
C1 C2 1.449(8) . ?
C27 C31 1.438(8) . ?
C27 C28 1.414(9) . ?
C27 C32 1.512(8) . ?
C87 C86 1.374(8) . ?
C87 C88 1.373(9) . ?
C10 C23 1.543(7) . ?
C31 C30 1.411(8) . ?
C31 C36 1.497(8) . ?
C40 C51 1.525(7) . ?
C40 C39 1.414(7) . ?
C5 H5 0.9500 . ?
C5 C4 1.405(8) . ?
C85 C86 1.394(7) . ?
C85 C90 1.386(8) . ?
C85 B3 1.663(7) . ?
C2 C11 1.526(7) . ?
C4 C15 1.518(7) . ?
C30 C29 1.399(8) . ?
C30 C35 1.519(8) . ?
C74 C73 1.380(8) . ?
C79 C84 1.383(9) . ?
C96 C91 1.381(8) . ?
C96 C95 1.379(8) . ?
C38 C39 1.425(8) . ?
C38 C47 1.549(7) . ?
C28 C29 1.401(9) . ?
C28 C33 1.512(8) . ?
C19 C21 1.537(8) . ?
C19 C20 1.530(7) . ?
C19 C22 1.510(8) . ?
C90 C89 1.388(8) . ?
C51 C54 1.529(8) . ?
C51 C53 1.547(7) . ?
C51 C52 1.538(8) . ?
C59 C61 1.535(8) . ?
C59 C62 1.538(8) . ?
C59 C60 1.526(8) . ?
C65 C64 1.411(9) . ?
C65 C66 1.413(9) . ?
C65 C70 1.502(8) . ?
C73 C78 1.378(8) . ?
C15 C17 1.522(8) . ?
C15 C16 1.535(8) . ?
C15 C18 1.533(8) . ?
C39 H39 0.9500 . ?
C91 C92 1.390(8) . ?
C91 B3 1.658(7) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C95 C94 1.375(9) . ?
C89 C88 1.363(9) . ?
C67 C63 1.408(8) . ?
C67 C66 1.432(8) . ?
C67 C72 1.507(8) . ?
C92 C93 1.372(8) . ?
C44 C55 1.536(8) . ?
C29 C34 1.508(8) . ?
C64 C63 1.428(7) . ?
C64 C69 1.502(8) . ?
C63 C68 1.511(8) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C11 C13 1.535(8) . ?
C11 C14 1.528(8) . ?
C11 C12 1.545(8) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C50 C47 1.524(8) . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C94 C93 1.377(9) . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C47 C48 1.545(8) . ?
C47 C49 1.518(8) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C66 C71 1.504(9) . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C23 C24 1.520(9) . ?
C23 C25 1.545(9) . ?
C23 C26 1.522(9) . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C55 C56 1.534(11) . ?
C55 C57 1.459(10) . ?
C55 C58 1.498(11) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C69 H69A 0.9800 . ?
C69 H69B 0.9800 . ?
C69 H69C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
B2 H2A 1.17(5) . ?
B2 H2B 1.14(6) . ?
B2 H2C 1.11(8) . ?
B2 H2D 1.10(9) . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
B1 H1A 1.31(6) . ?
B1 H1B 1.17(6) . ?
B1 H1C 1.15(6) . ?
B1 H1D 1.01(8) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C100 H10A 0.9900 . ?
C100 H10B 0.9900 . ?
C100 C99 1.426(12) . ?
C100 C101 1.420(12) . ?
C97 H97A 0.9800 . ?
C97 H97B 0.9800 . ?
C97 H97C 0.9800 . ?
C97 C98 1.458(14) . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C58 H58A 0.9800 . ?
C58 H58B 0.9800 . ?
C58 H58C 0.9800 . ?
C98 H98A 0.9900 . ?
C98 H98B 0.9900 . ?
C98 C99 1.410(14) . ?
C102 H10C 0.9800 . ?
C102 H10D 0.9800 . ?
C102 H10E 0.9800 . ?
C102 C101 1.409(12) . ?
C99 H99A 0.9900 . ?
C99 H99B 0.9900 . ?
C101 H10F 0.9900 . ?
C101 H10G 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 Dy2 C37 170.92(15) . . ?
C6 Dy2 C10 30.32(15) . . ?
C6 Dy2 C38 140.62(15) . . ?
C6 Dy2 B2 110.25(16) . . ?
C6 Dy2 B1 77.38(17) . . ?
C6 Dy2 H2A 111.5(13) . . ?
C6 Dy2 H1B 74.8(17) . . ?
C41 Dy2 C6 152.31(15) . . ?
C41 Dy2 C37 30.75(15) . . ?
C41 Dy2 C9 149.56(15) . . ?
C41 Dy2 C8 156.43(15) . . ?
C41 Dy2 C10 147.02(15) . . ?
C41 Dy2 C40 30.65(16) . . ?
C41 Dy2 C38 50.35(15) . . ?
C41 Dy2 C39 49.98(15) . . ?
C41 Dy2 B2 81.72(16) . . ?
C41 Dy2 B1 82.10(17) . . ?
C41 Dy2 H2A 88.1(13) . . ?
C41 Dy2 H1B 79.6(17) . . ?
C37 Dy2 C38 30.30(15) . . ?
C37 Dy2 B2 77.38(16) . . ?
C37 Dy2 B1 109.99(16) . . ?
C37 Dy2 H2A 74.0(13) . . ?
C37 Dy2 H1B 110.2(17) . . ?
C9 Dy2 C6 50.37(15) . . ?
C9 Dy2 C37 122.88(15) . . ?
C9 Dy2 C8 30.35(16) . . ?
C9 Dy2 C10 30.88(16) . . ?
C9 Dy2 C40 132.25(16) . . ?
C9 Dy2 C38 99.24(15) . . ?
C9 Dy2 C39 104.04(16) . . ?
C9 Dy2 B2 111.73(17) . . ?
C9 Dy2 B1 127.04(17) . . ?
C9 Dy2 H2A 97.3(13) . . ?
C9 Dy2 H1B 124.3(17) . . ?
C7 Dy2 C6 30.85(16) . . ?
C7 Dy2 C41 159.14(15) . . ?
C7 Dy2 C37 152.84(16) . . ?
C7 Dy2 C9 50.38(15) . . ?
C7 Dy2 C8 30.97(16) . . ?
C7 Dy2 C10 50.67(15) . . ?
C7 Dy2 C40 155.94(16) . . ?
C7 Dy2 C38 147.71(15) . . ?
C7 Dy2 C39 149.78(16) . . ?
C7 Dy2 B2 82.04(16) . . ?
C7 Dy2 B1 81.14(17) . . ?
C7 Dy2 H2A 80.7(13) . . ?
C7 Dy2 H1B 88.6(17) . . ?
C8 Dy2 C6 51.00(15) . . ?
C8 Dy2 C37 127.49(15) . . ?
C8 Dy2 C10 50.95(15) . . ?
C8 Dy2 C40 162.21(16) . . ?
C8 Dy2 C38 117.26(15) . . ?
C8 Dy2 B2 83.10(17) . . ?
C8 Dy2 B1 111.17(17) . . ?
C8 Dy2 H2A 72.1(13) . . ?
C8 Dy2 H1B 119.4(17) . . ?
C10 Dy2 C37 140.65(15) . . ?
C10 Dy2 C38 110.57(15) . . ?
C10 Dy2 B2 131.26(17) . . ?
C10 Dy2 B1 104.18(17) . . ?
C10 Dy2 H2A 123.0(13) . . ?
C10 Dy2 H1B 95.6(17) . . ?
C40 Dy2 C6 127.07(16) . . ?
C40 Dy2 C37 50.88(16) . . ?
C40 Dy2 C10 116.88(16) . . ?
C40 Dy2 C38 50.77(15) . . ?
C40 Dy2 B2 111.47(17) . . ?
C40 Dy2 B1 83.30(17) . . ?
C40 Dy2 H2A 118.7(13) . . ?
C40 Dy2 H1B 71.2(17) . . ?
C38 Dy2 B2 104.07(16) . . ?
C38 Dy2 B1 131.15(16) . . ?
C38 Dy2 H2A 94.9(13) . . ?
C38 Dy2 H1B 121.9(17) . . ?
C39 Dy2 C6 122.86(16) . . ?
C39 Dy2 C37 50.01(16) . . ?
C39 Dy2 C8 132.17(16) . . ?
C39 Dy2 C10 99.15(16) . . ?
C39 Dy2 C40 30.53(16) . . ?
C39 Dy2 C38 30.34(16) . . ?
C39 Dy2 B2 126.82(17) . . ?
C39 Dy2 B1 112.29(17) . . ?
C39 Dy2 H2A 123.1(13) . . ?
C39 Dy2 H1B 97.0(17) . . ?
B2 Dy2 B1 75.13(19) . . ?
B2 Dy2 H2A 19.1(13) . . ?
B2 Dy2 H1B 94.0(17) . . ?
B1 Dy2 H2A 93.8(13) . . ?
B1 Dy2 H1B 19.6(17) . . ?
H2A Dy2 H1B 113(2) . . ?
C3 Dy1 C1 51.33(15) . . ?
C3 Dy1 C2 31.03(15) . . ?
C3 Dy1 B1 129.71(18) . . ?
C3 Dy1 H1A 128.9(16) . . ?
C3 Dy1 H1C 127.3(15) . . ?
C1 Dy1 C2 31.18(16) . . ?
C1 Dy1 B1 81.46(18) . . ?
C1 Dy1 H1A 78.6(16) . . ?
C1 Dy1 H1C 91.4(15) . . ?
C27 Dy1 C3 98.87(17) . . ?
C27 Dy1 C1 149.11(18) . . ?
C27 Dy1 C2 118.93(18) . . ?
C27 Dy1 C28 31.40(19) . . ?
C27 Dy1 B1 129.4(2) . . ?
C27 Dy1 H1A 127.8(15) . . ?
C27 Dy1 H1C 116.7(15) . . ?
C31 Dy1 C3 96.98(17) . . ?
C31 Dy1 C1 131.15(17) . . ?
C31 Dy1 C27 32.03(17) . . ?
C31 Dy1 C2 101.84(17) . . ?
C31 Dy1 C28 52.20(17) . . ?
C31 Dy1 B1 130.72(19) . . ?
C31 Dy1 H1A 111.5(15) . . ?
C31 Dy1 H1C 133.9(15) . . ?
C5 Dy1 C3 51.56(16) . . ?
C5 Dy1 C1 31.13(16) . . ?
C5 Dy1 C27 139.32(17) . . ?
C5 Dy1 C31 148.52(18) . . ?
C5 Dy1 C2 51.65(16) . . ?
C5 Dy1 C4 31.65(17) . . ?
C5 Dy1 C30 164.12(17) . . ?
C5 Dy1 C28 144.28(17) . . ?
C5 Dy1 C29 158.98(17) . . ?
C5 Dy1 B1 79.49(19) . . ?
C5 Dy1 H1A 91.8(16) . . ?
C5 Dy1 H1C 77.0(15) . . ?
C2 Dy1 H1A 99.9(16) . . ?
C2 Dy1 H1C 122.5(15) . . ?
C4 Dy1 C3 31.45(16) . . ?
C4 Dy1 C1 52.05(16) . . ?
C4 Dy1 C27 108.24(17) . . ?
C4 Dy1 C31 121.11(17) . . ?
C4 Dy1 C2 52.10(16) . . ?
C4 Dy1 C30 152.17(17) . . ?
C4 Dy1 C28 124.13(18) . . ?
C4 Dy1 C29 155.17(18) . . ?
C4 Dy1 B1 108.06(19) . . ?
C4 Dy1 H1A 123.4(16) . . ?
C4 Dy1 H1C 97.7(15) . . ?
C30 Dy1 C3 123.90(17) . . ?
C30 Dy1 C1 133.00(17) . . ?
C30 Dy1 C27 52.19(17) . . ?
C30 Dy1 C31 31.51(17) . . ?
C30 Dy1 C2 115.51(17) . . ?
C30 Dy1 C28 51.59(18) . . ?
C30 Dy1 C29 31.25(18) . . ?
C30 Dy1 B1 99.68(19) . . ?
C30 Dy1 H1A 80.9(15) . . ?
C30 Dy1 H1C 108.8(15) . . ?
C28 Dy1 C3 127.35(18) . . ?
C28 Dy1 C1 175.41(17) . . ?
C28 Dy1 C2 150.28(18) . . ?
C28 Dy1 B1 98.2(2) . . ?
C28 Dy1 H1A 103.4(16) . . ?
C28 Dy1 H1C 86.6(15) . . ?
C29 Dy1 C3 148.38(16) . . ?
C29 Dy1 C1 152.51(18) . . ?
C29 Dy1 C27 52.02(18) . . ?
C29 Dy1 C31 52.16(18) . . ?
C29 Dy1 C2 146.57(17) . . ?
C29 Dy1 C28 31.11(19) . . ?
C29 Dy1 B1 81.80(19) . . ?
C29 Dy1 H1A 76.2(16) . . ?
C29 Dy1 H1C 82.0(15) . . ?
B1 Dy1 C2 111.01(18) . . ?
B1 Dy1 H1A 29.1(16) . . ?
B1 Dy1 H1C 24.3(15) . . ?
H1A Dy1 H1C 53(2) . . ?
C45 Dy3 C42 51.59(16) . . ?
C45 Dy3 C46 31.24(16) . . ?
C45 Dy3 C67 125.29(17) . . ?
C45 Dy3 C44 31.32(17) . . ?
C45 Dy3 B2 128.38(18) . . ?
C45 Dy3 H2B 128.4(15) . . ?
C45 Dy3 H2C 127(2) . . ?
C43 Dy3 C45 51.15(16) . . ?
C43 Dy3 C42 31.35(17) . . ?
C43 Dy3 C46 51.87(16) . . ?
C43 Dy3 C65 140.01(18) . . ?
C43 Dy3 C67 167.76(18) . . ?
C43 Dy3 C44 30.86(17) . . ?
C43 Dy3 C64 136.93(18) . . ?
C43 Dy3 C63 149.61(17) . . ?
C43 Dy3 C66 156.68(18) . . ?
C43 Dy3 B2 78.11(19) . . ?
C43 Dy3 H2B 79.3(15) . . ?
C43 Dy3 H2C 85(2) . . ?
C42 Dy3 C46 31.61(16) . . ?
C42 Dy3 B2 80.93(18) . . ?
C42 Dy3 H2B 94.5(15) . . ?
C42 Dy3 H2C 75(2) . . ?
C46 Dy3 B2 111.34(18) . . ?
C46 Dy3 H2B 125.9(15) . . ?
C46 Dy3 H2C 100(2) . . ?
C65 Dy3 C45 127.28(18) . . ?
C65 Dy3 C42 171.26(17) . . ?
C65 Dy3 C46 152.34(18) . . ?
C65 Dy3 C67 52.23(17) . . ?
C65 Dy3 C44 121.82(18) . . ?
C65 Dy3 C66 31.45(19) . . ?
C65 Dy3 B2 96.3(2) . . ?
C65 Dy3 H2B 80.1(15) . . ?
C65 Dy3 H2C 105(2) . . ?
C67 Dy3 C42 136.41(17) . . ?
C67 Dy3 C46 118.10(17) . . ?
C67 Dy3 B2 102.1(2) . . ?
C67 Dy3 H2B 106.2(15) . . ?
C67 Dy3 H2C 90(2) . . ?
C44 Dy3 C42 51.84(17) . . ?
C44 Dy3 C46 52.12(16) . . ?
C44 Dy3 C67 152.32(18) . . ?
C44 Dy3 B2 105.53(19) . . ?
C44 Dy3 H2B 98.2(15) . . ?
C44 Dy3 H2C 116(2) . . ?
C64 Dy3 C45 99.45(18) . . ?
C64 Dy3 C42 150.66(18) . . ?
C64 Dy3 C46 120.89(17) . . ?
C64 Dy3 C65 31.46(19) . . ?
C64 Dy3 C67 52.17(18) . . ?
C64 Dy3 C44 107.17(18) . . ?
C64 Dy3 C63 31.84(16) . . ?
C64 Dy3 C66 52.09(19) . . ?
C64 Dy3 B2 127.75(19) . . ?
C64 Dy3 H2B 110.2(15) . . ?
C64 Dy3 H2C 133(2) . . ?
C63 Dy3 C45 98.58(17) . . ?
C63 Dy3 C42 135.04(17) . . ?
C63 Dy3 C46 104.87(17) . . ?
C63 Dy3 C65 52.27(17) . . ?
C63 Dy3 C67 31.22(18) . . ?
C63 Dy3 C44 121.35(17) . . ?
C63 Dy3 C66 52.10(18) . . ?
C63 Dy3 B2 132.17(19) . . ?
C63 Dy3 H2B 128.6(15) . . ?
C63 Dy3 H2C 121(2) . . ?
C66 Dy3 C45 149.64(17) . . ?
C66 Dy3 C42 153.97(18) . . ?
C66 Dy3 C46 149.54(17) . . ?
C66 Dy3 C67 31.72(18) . . ?
C66 Dy3 C44 153.12(18) . . ?
C66 Dy3 B2 81.9(2) . . ?
C66 Dy3 H2B 77.5(15) . . ?
C66 Dy3 H2C 81(2) . . ?
B2 Dy3 H2B 25.1(15) . . ?
B2 Dy3 H2C 24(2) . . ?
H2B Dy3 H2C 48(3) . . ?
F8 C81 C82 121.4(5) . . ?
F8 C81 C80 115.2(5) . . ?
C80 C81 C82 123.4(5) . . ?
C7 C6 Dy2 70.8(3) . . ?
C7 C6 C1 123.2(5) . . ?
C1 C6 Dy2 126.3(3) . . ?
C10 C6 Dy2 74.9(3) . . ?
C10 C6 C7 107.0(5) . . ?
C10 C6 C1 129.2(5) . . ?
C77 C76 B3 120.5(4) . . ?
C75 C76 C77 113.1(5) . . ?
C75 C76 B3 126.2(5) . . ?
C81 C82 B3 127.0(4) . . ?
C83 C82 C81 114.0(5) . . ?
C83 C82 B3 118.9(4) . . ?
Dy2 C41 H41 112.8 . . ?
C37 C41 Dy2 77.9(3) . . ?
C37 C41 H41 124.9 . . ?
C40 C41 Dy2 76.5(3) . . ?
C40 C41 H41 124.9 . . ?
C40 C41 C37 110.3(4) . . ?
C41 C37 Dy2 71.3(3) . . ?
C41 C37 C42 125.3(4) . . ?
C41 C37 C38 107.0(5) . . ?
C42 C37 Dy2 124.3(3) . . ?
C38 C37 Dy2 75.9(3) . . ?
C38 C37 C42 127.2(5) . . ?
Dy1 C3 H3 116.2 . . ?
C2 C3 Dy1 78.0(3) . . ?
C2 C3 H3 125.0 . . ?
C4 C3 Dy1 72.7(3) . . ?
C4 C3 H3 125.0 . . ?
C4 C3 C2 110.0(5) . . ?
F7 C80 C81 120.4(5) . . ?
F7 C80 C79 119.7(5) . . ?
C79 C80 C81 120.0(5) . . ?
F4 C77 C76 119.4(4) . . ?
F4 C77 C78 115.8(4) . . ?
C78 C77 C76 124.7(5) . . ?
Dy3 C45 H45 115.5 . . ?
C46 C45 Dy3 76.5(3) . . ?
C46 C45 H45 124.9 . . ?
C44 C45 Dy3 75.0(3) . . ?
C44 C45 H45 124.9 . . ?
C44 C45 C46 110.2(5) . . ?
F3 C75 C76 120.9(5) . . ?
F3 C75 C74 114.6(4) . . ?
C76 C75 C74 124.5(5) . . ?
Dy2 C9 H9 114.1 . . ?
C8 C9 Dy2 75.9(3) . . ?
C8 C9 H9 124.8 . . ?
C8 C9 C10 110.4(4) . . ?
C10 C9 Dy2 77.1(3) . . ?
C10 C9 H9 124.8 . . ?
Dy3 C43 H43 115.3 . . ?
C42 C43 Dy3 75.9(3) . . ?
C42 C43 H43 124.9 . . ?
C44 C43 Dy3 75.8(3) . . ?
C44 C43 H43 124.9 . . ?
C44 C43 C42 110.3(5) . . ?
C37 C42 Dy3 124.0(3) . . ?
C43 C42 Dy3 72.7(3) . . ?
C43 C42 C37 123.5(5) . . ?
C43 C42 C46 107.3(5) . . ?
C46 C42 Dy3 75.3(3) . . ?
C46 C42 C37 128.7(5) . . ?
Dy2 C7 H7 111.9 . . ?
C6 C7 Dy2 78.4(3) . . ?
C6 C7 H7 125.1 . . ?
C8 C7 Dy2 76.8(3) . . ?
C8 C7 C6 109.9(4) . . ?
C8 C7 H7 125.1 . . ?
C45 C46 Dy3 72.2(3) . . ?
C45 C46 C42 105.6(5) . . ?
C45 C46 C59 124.1(5) . . ?
C42 C46 Dy3 73.1(3) . . ?
C42 C46 C59 130.1(5) . . ?
C59 C46 Dy3 123.0(3) . . ?
C9 C8 Dy2 73.8(3) . . ?
C9 C8 C7 105.9(4) . . ?
C9 C8 C19 126.2(5) . . ?
C7 C8 Dy2 72.2(3) . . ?
C7 C8 C19 125.7(5) . . ?
C19 C8 Dy2 132.2(3) . . ?
F9 C83 C82 119.6(5) . . ?
F9 C83 C84 116.1(5) . . ?
C84 C83 C82 124.3(5) . . ?
C6 C1 Dy1 123.1(3) . . ?
C5 C1 Dy1 70.2(3) . . ?
C5 C1 C6 125.1(5) . . ?
C5 C1 C2 107.5(5) . . ?
C2 C1 Dy1 76.2(3) . . ?
C2 C1 C6 127.2(5) . . ?
C31 C27 Dy1 74.0(3) . . ?
C31 C27 C32 124.5(6) . . ?
C28 C27 Dy1 74.8(3) . . ?
C28 C27 C31 107.4(5) . . ?
C28 C27 C32 126.9(6) . . ?
C32 C27 Dy1 126.2(4) . . ?
F15 C87 C86 121.2(5) . . ?
F15 C87 C88 119.6(5) . . ?
C88 C87 C86 119.2(5) . . ?
C6 C10 Dy2 74.7(3) . . ?
C6 C10 C9 106.5(4) . . ?
C6 C10 C23 131.5(5) . . ?
C9 C10 Dy2 72.0(3) . . ?
C9 C10 C23 119.5(5) . . ?
C23 C10 Dy2 131.9(4) . . ?
C27 C31 Dy1 74.0(3) . . ?
C27 C31 C36 124.4(5) . . ?
C30 C31 Dy1 73.6(3) . . ?
C30 C31 C27 106.7(5) . . ?
C30 C31 C36 128.3(5) . . ?
C36 C31 Dy1 124.6(4) . . ?
C41 C40 Dy2 72.9(3) . . ?
C41 C40 C51 127.0(5) . . ?
C41 C40 C39 105.6(5) . . ?
C51 C40 Dy2 130.3(3) . . ?
C39 C40 Dy2 74.3(3) . . ?
C39 C40 C51 125.4(5) . . ?
Dy1 C5 H5 113.3 . . ?
C1 C5 Dy1 78.7(3) . . ?
C1 C5 H5 124.8 . . ?
C4 C5 Dy1 75.1(3) . . ?
C4 C5 C1 110.3(5) . . ?
C4 C5 H5 124.8 . . ?
C86 C85 B3 118.3(4) . . ?
C90 C85 C86 113.7(5) . . ?
C90 C85 B3 127.6(5) . . ?
C3 C2 Dy1 71.0(3) . . ?
C3 C2 C1 105.6(5) . . ?
C3 C2 C11 123.6(5) . . ?
C1 C2 Dy1 72.6(3) . . ?
C1 C2 C11 129.8(5) . . ?
C11 C2 Dy1 129.8(4) . . ?
C3 C4 Dy1 75.9(3) . . ?
C3 C4 C15 128.7(5) . . ?
C5 C4 Dy1 73.2(3) . . ?
C5 C4 C3 106.5(5) . . ?
C5 C4 C15 124.8(5) . . ?
C15 C4 Dy1 114.6(3) . . ?
C31 C30 Dy1 74.9(3) . . ?
C31 C30 C35 125.5(5) . . ?
C29 C30 Dy1 75.0(3) . . ?
C29 C30 C31 109.2(5) . . ?
C29 C30 C35 125.3(5) . . ?
C35 C30 Dy1 118.9(4) . . ?
F2 C74 C75 121.0(5) . . ?
F2 C74 C73 119.4(5) . . ?
C73 C74 C75 119.7(5) . . ?
F14 C86 C87 115.6(5) . . ?
F14 C86 C85 119.6(4) . . ?
C87 C86 C85 124.7(5) . . ?
F6 C79 C80 120.0(5) . . ?
F6 C79 C84 121.2(5) . . ?
C80 C79 C84 118.7(5) . . ?
F18 C96 C91 121.9(5) . . ?
F18 C96 C95 114.7(5) . . ?
C95 C96 C91 123.3(5) . . ?
C37 C38 Dy2 73.8(3) . . ?
C37 C38 C47 128.5(5) . . ?
C39 C38 Dy2 71.8(3) . . ?
C39 C38 C37 106.2(4) . . ?
C39 C38 C47 123.7(5) . . ?
C47 C38 Dy2 130.5(3) . . ?
C27 C28 Dy1 73.8(3) . . ?
C27 C28 C33 126.8(6) . . ?
C29 C28 Dy1 73.9(3) . . ?
C29 C28 C27 108.5(5) . . ?
C29 C28 C33 124.5(6) . . ?
C33 C28 Dy1 122.9(4) . . ?
C8 C19 C21 111.9(4) . . ?
C20 C19 C8 105.8(4) . . ?
C20 C19 C21 107.6(5) . . ?
C22 C19 C8 112.4(4) . . ?
C22 C19 C21 110.4(5) . . ?
C22 C19 C20 108.5(5) . . ?
F13 C90 C85 121.3(5) . . ?
F13 C90 C89 115.9(5) . . ?
C85 C90 C89 122.7(5) . . ?
C40 C51 C54 110.8(5) . . ?
C40 C51 C53 106.8(4) . . ?
C40 C51 C52 111.8(5) . . ?
C54 C51 C53 108.4(5) . . ?
C54 C51 C52 110.0(5) . . ?
C52 C51 C53 108.9(5) . . ?
C46 C59 C61 111.2(4) . . ?
C46 C59 C62 109.7(4) . . ?
C61 C59 C62 109.0(5) . . ?
C60 C59 C46 110.3(5) . . ?
C60 C59 C61 107.7(5) . . ?
C60 C59 C62 108.9(5) . . ?
C64 C65 Dy3 74.1(3) . . ?
C64 C65 C66 108.2(5) . . ?
C64 C65 C70 127.0(6) . . ?
C66 C65 Dy3 74.4(3) . . ?
C66 C65 C70 124.6(6) . . ?
C70 C65 Dy3 121.9(4) . . ?
F1 C73 C74 120.7(5) . . ?
F1 C73 C78 121.1(5) . . ?
C78 C73 C74 118.2(5) . . ?
C4 C15 C17 110.9(5) . . ?
C4 C15 C16 108.6(4) . . ?
C4 C15 C18 109.4(4) . . ?
C17 C15 C16 109.0(5) . . ?
C17 C15 C18 109.7(5) . . ?
C18 C15 C16 109.2(5) . . ?
Dy2 C39 H39 114.2 . . ?
C40 C39 Dy2 75.2(3) . . ?
C40 C39 C38 110.8(5) . . ?
C40 C39 H39 124.6 . . ?
C38 C39 Dy2 77.9(3) . . ?
C38 C39 H39 124.6 . . ?
C96 C91 C92 114.0(5) . . ?
C96 C91 B3 127.5(5) . . ?
C92 C91 B3 118.3(5) . . ?
F5 C78 C77 121.5(4) . . ?
F5 C78 C73 118.8(5) . . ?
C77 C78 C73 119.8(5) . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C59 C61 H61A 109.5 . . ?
C59 C61 H61B 109.5 . . ?
C59 C61 H61C 109.5 . . ?
H61A C61 H61B 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
F17 C95 C96 120.6(6) . . ?
F17 C95 C94 119.0(5) . . ?
C94 C95 C96 120.4(5) . . ?
F12 C89 C90 119.3(6) . . ?
F12 C89 C88 119.8(5) . . ?
C88 C89 C90 120.9(5) . . ?
C63 C67 Dy3 73.3(3) . . ?
C63 C67 C66 107.4(5) . . ?
C63 C67 C72 128.9(5) . . ?
C66 C67 Dy3 73.3(3) . . ?
C66 C67 C72 123.7(6) . . ?
C72 C67 Dy3 119.7(4) . . ?
F11 C88 C87 120.9(6) . . ?
F11 C88 C89 120.3(6) . . ?
C89 C88 C87 118.8(5) . . ?
F19 C92 C91 119.3(5) . . ?
F19 C92 C93 116.4(5) . . ?
C93 C92 C91 124.3(5) . . ?
C45 C44 Dy3 73.7(3) . . ?
C45 C44 C55 128.3(5) . . ?
C43 C44 Dy3 73.3(3) . . ?
C43 C44 C45 106.5(5) . . ?
C43 C44 C55 125.1(5) . . ?
C55 C44 Dy3 120.8(4) . . ?
C30 C29 Dy1 73.8(3) . . ?
C30 C29 C28 108.1(5) . . ?
C30 C29 C34 124.9(6) . . ?
C28 C29 Dy1 75.0(3) . . ?
C28 C29 C34 126.3(6) . . ?
C34 C29 Dy1 124.5(4) . . ?
C65 C64 Dy3 74.5(3) . . ?
C65 C64 C63 107.8(5) . . ?
C65 C64 C69 128.0(5) . . ?
C63 C64 Dy3 74.2(3) . . ?
C63 C64 C69 123.5(5) . . ?
C69 C64 Dy3 124.5(4) . . ?
F10 C84 C83 121.6(5) . . ?
F10 C84 C79 118.9(5) . . ?
C83 C84 C79 119.5(5) . . ?
C67 C63 Dy3 75.5(3) . . ?
C67 C63 C64 108.4(5) . . ?
C67 C63 C68 127.5(5) . . ?
C64 C63 Dy3 74.0(3) . . ?
C64 C63 C68 123.4(5) . . ?
C68 C63 Dy3 124.2(4) . . ?
C63 C68 H68A 109.5 . . ?
C63 C68 H68B 109.5 . . ?
C63 C68 H68C 109.5 . . ?
H68A C68 H68B 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C2 C11 C13 113.8(5) . . ?
C2 C11 C14 109.8(5) . . ?
C2 C11 C12 109.2(5) . . ?
C13 C11 C12 108.5(5) . . ?
C14 C11 C13 107.2(5) . . ?
C14 C11 C12 108.2(5) . . ?
C11 C13 H13A 109.5 . . ?
C11 C13 H13B 109.5 . . ?
C11 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
H50A C50 H50B 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C47 C50 H50A 109.5 . . ?
C47 C50 H50B 109.5 . . ?
C47 C50 H50C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
F16 C94 C95 121.5(5) . . ?
F16 C94 C93 120.1(6) . . ?
C95 C94 C93 118.4(5) . . ?
C30 C35 H35A 109.5 . . ?
C30 C35 H35B 109.5 . . ?
C30 C35 H35C 109.5 . . ?
H35A C35 H35B 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C50 C47 C38 109.6(4) . . ?
C50 C47 C48 107.3(5) . . ?
C48 C47 C38 109.6(5) . . ?
C49 C47 C38 113.9(4) . . ?
C49 C47 C50 109.3(5) . . ?
C49 C47 C48 107.0(5) . . ?
C11 C14 H14A 109.5 . . ?
C11 C14 H14B 109.5 . . ?
C11 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C65 C66 Dy3 74.1(3) . . ?
C65 C66 C67 108.2(5) . . ?
C65 C66 C71 126.3(6) . . ?
C67 C66 Dy3 75.0(3) . . ?
C67 C66 C71 124.9(6) . . ?
C71 C66 Dy3 123.9(4) . . ?
C67 C72 H72A 109.5 . . ?
C67 C72 H72B 109.5 . . ?
C67 C72 H72C 109.5 . . ?
H72A C72 H72B 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
F20 C93 C92 120.7(5) . . ?
F20 C93 C94 119.8(5) . . ?
C92 C93 C94 119.5(6) . . ?
C59 C62 H62A 109.5 . . ?
C59 C62 H62B 109.5 . . ?
C59 C62 H62C 109.5 . . ?
H62A C62 H62B 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C10 C23 C25 108.0(5) . . ?
C24 C23 C10 111.1(5) . . ?
C24 C23 C25 107.0(5) . . ?
C24 C23 C26 107.8(6) . . ?
C26 C23 C10 116.7(5) . . ?
C26 C23 C25 105.7(6) . . ?
C47 C48 H48A 109.5 . . ?
C47 C48 H48B 109.5 . . ?
C47 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C31 C36 H36A 109.5 . . ?
C31 C36 H36B 109.5 . . ?
C31 C36 H36C 109.5 . . ?
H36A C36 H36B 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C59 C60 H60A 109.5 . . ?
C59 C60 H60B 109.5 . . ?
C59 C60 H60C 109.5 . . ?
H60A C60 H60B 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C56 C55 C44 105.7(6) . . ?
C57 C55 C44 110.8(6) . . ?
C57 C55 C56 110.3(7) . . ?
C57 C55 C58 111.4(7) . . ?
C58 C55 C44 109.2(6) . . ?
C58 C55 C56 109.3(7) . . ?
C27 C32 H32A 109.5 . . ?
C27 C32 H32B 109.5 . . ?
C27 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C51 C54 H54A 109.5 . . ?
C51 C54 H54B 109.5 . . ?
C51 C54 H54C 109.5 . . ?
H54A C54 H54B 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C51 C53 H53A 109.5 . . ?
C51 C53 H53B 109.5 . . ?
C51 C53 H53C 109.5 . . ?
H53A C53 H53B 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C65 C70 H70A 109.5 . . ?
C65 C70 H70B 109.5 . . ?
C65 C70 H70C 109.5 . . ?
H70A C70 H70B 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
C15 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
C15 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C76 B3 C82 102.1(4) . . ?
C76 B3 C85 113.9(4) . . ?
C76 B3 C91 113.7(4) . . ?
C85 B3 C82 112.4(4) . . ?
C91 B3 C82 113.9(4) . . ?
C91 B3 C85 101.4(4) . . ?
C64 C69 H69A 109.5 . . ?
C64 C69 H69B 109.5 . . ?
C64 C69 H69C 109.5 . . ?
H69A C69 H69B 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C47 C49 H49A 109.5 . . ?
C47 C49 H49B 109.5 . . ?
C47 C49 H49C 109.5 . . ?
H49A C49 H49B 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C66 C71 H71A 109.5 . . ?
C66 C71 H71B 109.5 . . ?
C66 C71 H71C 109.5 . . ?
H71A C71 H71B 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
Dy2 B2 H2A 36(2) . . ?
Dy2 B2 H2B 142(3) . . ?
Dy2 B2 H2C 85(4) . . ?
Dy2 B2 H2D 90(5) . . ?
Dy3 B2 Dy2 119.2(2) . . ?
Dy3 B2 H2A 108(2) . . ?
Dy3 B2 H2B 60(3) . . ?
Dy3 B2 H2C 55(4) . . ?
Dy3 B2 H2D 144(5) . . ?
H2A B2 H2B 106(4) . . ?
H2A B2 H2C 106(5) . . ?
H2A B2 H2D 109(5) . . ?
H2B B2 H2C 114(5) . . ?
H2B B2 H2D 111(6) . . ?
H2C B2 H2D 112(6) . . ?
C28 C33 H33A 109.5 . . ?
C28 C33 H33B 109.5 . . ?
C28 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52B 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C19 C22 H22A 109.5 . . ?
C19 C22 H22B 109.5 . . ?
C19 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Dy2 B1 H1A 88(3) . . ?
Dy2 B1 H1B 39(3) . . ?
Dy2 B1 H1C 137(3) . . ?
Dy2 B1 H1D 89(5) . . ?
Dy1 B1 Dy2 118.8(2) . . ?
Dy1 B1 H1A 56(3) . . ?
Dy1 B1 H1B 109(3) . . ?
Dy1 B1 H1C 50(3) . . ?
Dy1 B1 H1D 144(5) . . ?
H1A B1 H1B 114(4) . . ?
H1A B1 H1C 105(4) . . ?
H1A B1 H1D 106(5) . . ?
H1B B1 H1C 100(4) . . ?
H1B B1 H1D 107(5) . . ?
H1C B1 H1D 124(5) . . ?
C29 C34 H34A 109.5 . . ?
C29 C34 H34B 109.5 . . ?
C29 C34 H34C 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C23 C25 H25A 109.5 . . ?
C23 C25 H25B 109.5 . . ?
C23 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C23 C26 H26A 109.5 . . ?
C23 C26 H26B 109.5 . . ?
C23 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C55 C56 H56A 109.5 . . ?
C55 C56 H56B 109.5 . . ?
C55 C56 H56C 109.5 . . ?
H56A C56 H56B 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
H10A C100 H10B 106.0 . . ?
C99 C100 H10A 105.3 . . ?
C99 C100 H10B 105.3 . . ?
C101 C100 H10A 105.3 . . ?
C101 C100 H10B 105.3 . . ?
C101 C100 C99 127.8(9) . . ?
H97A C97 H97B 109.5 . . ?
H97A C97 H97C 109.5 . . ?
H97B C97 H97C 109.5 . . ?
C98 C97 H97A 109.5 . . ?
C98 C97 H97B 109.5 . . ?
C98 C97 H97C 109.5 . . ?
C55 C57 H57A 109.5 . . ?
C55 C57 H57B 109.5 . . ?
C55 C57 H57C 109.5 . . ?
H57A C57 H57B 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C55 C58 H58A 109.5 . . ?
C55 C58 H58B 109.5 . . ?
C55 C58 H58C 109.5 . . ?
H58A C58 H58B 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
C97 C98 H98A 105.8 . . ?
C97 C98 H98B 105.8 . . ?
H98A C98 H98B 106.2 . . ?
C99 C98 C97 126.0(11) . . ?
C99 C98 H98A 105.8 . . ?
C99 C98 H98B 105.8 . . ?
H10C C102 H10D 109.5 . . ?
H10C C102 H10E 109.5 . . ?
H10D C102 H10E 109.5 . . ?
C101 C102 H10C 109.5 . . ?
C101 C102 H10D 109.5 . . ?
C101 C102 H10E 109.5 . . ?
C100 C99 H99A 105.5 . . ?
C100 C99 H99B 105.5 . . ?
C98 C99 C100 127.3(11) . . ?
C98 C99 H99A 105.5 . . ?
C98 C99 H99B 105.5 . . ?
H99A C99 H99B 106.1 . . ?
C100 C101 H10F 105.4 . . ?
C100 C101 H10G 105.4 . . ?
C102 C101 C100 127.5(12) . . ?
C102 C101 H10F 105.4 . . ?
C102 C101 H10G 105.4 . . ?
H10F C101 H10G 106.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy2 C6 C7 C8 -71.2(4) . . . . ?
Dy2 C6 C1 Dy1 -46.6(6) . . . . ?
Dy2 C6 C1 C5 41.2(7) . . . . ?
Dy2 C6 C1 C2 -144.5(4) . . . . ?
Dy2 C6 C10 C9 65.5(4) . . . . ?
Dy2 C6 C10 C23 -133.0(6) . . . . ?
Dy2 C41 C37 C42 -119.3(5) . . . . ?
Dy2 C41 C37 C38 68.2(3) . . . . ?
Dy2 C41 C40 C51 127.9(5) . . . . ?
Dy2 C41 C40 C39 -67.6(4) . . . . ?
Dy2 C37 C42 Dy3 -49.3(5) . . . . ?
Dy2 C37 C42 C43 41.7(6) . . . . ?
Dy2 C37 C42 C46 -147.8(4) . . . . ?
Dy2 C37 C38 C39 65.0(4) . . . . ?
Dy2 C37 C38 C47 -129.2(5) . . . . ?
Dy2 C9 C8 C7 65.5(3) . . . . ?
Dy2 C9 C8 C19 -130.8(5) . . . . ?
Dy2 C9 C10 C6 -67.4(4) . . . . ?
Dy2 C9 C10 C23 128.5(5) . . . . ?
Dy2 C7 C8 C9 -66.6(4) . . . . ?
Dy2 C7 C8 C19 129.6(5) . . . . ?
Dy2 C8 C19 C21 77.4(6) . . . . ?
Dy2 C8 C19 C20 -165.6(4) . . . . ?
Dy2 C8 C19 C22 -47.4(7) . . . . ?
Dy2 C10 C23 C24 37.2(7) . . . . ?
Dy2 C10 C23 C25 154.2(4) . . . . ?
Dy2 C10 C23 C26 -86.9(7) . . . . ?
Dy2 C40 C51 C54 84.4(6) . . . . ?
Dy2 C40 C51 C53 -157.8(4) . . . . ?
Dy2 C40 C51 C52 -38.8(7) . . . . ?
Dy2 C40 C39 C38 -70.5(4) . . . . ?
Dy2 C38 C39 C40 68.8(4) . . . . ?
Dy2 C38 C47 C50 -144.7(4) . . . . ?
Dy2 C38 C47 C48 97.8(5) . . . . ?
Dy2 C38 C47 C49 -21.9(7) . . . . ?
Dy1 C3 C2 C1 -64.9(3) . . . . ?
Dy1 C3 C2 C11 125.7(5) . . . . ?
Dy1 C3 C4 C5 67.4(3) . . . . ?
Dy1 C3 C4 C15 -110.4(5) . . . . ?
Dy1 C1 C5 C4 -69.3(4) . . . . ?
Dy1 C1 C2 C3 63.8(3) . . . . ?
Dy1 C1 C2 C11 -127.7(6) . . . . ?
Dy1 C27 C31 C30 66.9(4) . . . . ?
Dy1 C27 C31 C36 -121.3(5) . . . . ?
Dy1 C27 C28 C29 -66.2(4) . . . . ?
Dy1 C27 C28 C33 119.3(6) . . . . ?
Dy1 C31 C30 C29 67.7(4) . . . . ?
Dy1 C31 C30 C35 -114.9(5) . . . . ?
Dy1 C5 C4 C3 -69.2(3) . . . . ?
Dy1 C5 C4 C15 108.7(5) . . . . ?
Dy1 C2 C11 C13 -25.9(7) . . . . ?
Dy1 C2 C11 C14 94.2(6) . . . . ?
Dy1 C2 C11 C12 -147.3(4) . . . . ?
Dy1 C4 C15 C17 -100.4(4) . . . . ?
Dy1 C4 C15 C16 139.8(4) . . . . ?
Dy1 C4 C15 C18 20.7(5) . . . . ?
Dy1 C30 C29 C28 67.8(4) . . . . ?
Dy1 C30 C29 C34 -121.1(6) . . . . ?
Dy1 C28 C29 C30 -67.0(4) . . . . ?
Dy1 C28 C29 C34 122.1(6) . . . . ?
Dy3 C45 C46 C42 -66.0(3) . . . . ?
Dy3 C45 C46 C59 118.3(5) . . . . ?
Dy3 C45 C44 C43 66.5(4) . . . . ?
Dy3 C45 C44 C55 -116.7(6) . . . . ?
Dy3 C43 C42 C37 -119.8(5) . . . . ?
Dy3 C43 C42 C46 68.0(3) . . . . ?
Dy3 C43 C44 C45 -66.7(4) . . . . ?
Dy3 C43 C44 C55 116.3(6) . . . . ?
Dy3 C42 C46 C45 65.4(3) . . . . ?
Dy3 C42 C46 C59 -119.2(5) . . . . ?
Dy3 C46 C59 C61 -21.6(6) . . . . ?
Dy3 C46 C59 C62 -142.2(4) . . . . ?
Dy3 C46 C59 C60 97.8(5) . . . . ?
Dy3 C65 C64 C63 67.2(4) . . . . ?
Dy3 C65 C64 C69 -121.9(6) . . . . ?
Dy3 C65 C66 C67 -67.8(4) . . . . ?
Dy3 C65 C66 C71 120.7(6) . . . . ?
Dy3 C67 C63 C64 -67.2(4) . . . . ?
Dy3 C67 C63 C68 122.2(5) . . . . ?
Dy3 C67 C66 C65 67.3(4) . . . . ?
Dy3 C67 C66 C71 -121.1(6) . . . . ?
Dy3 C44 C55 C56 22.0(7) . . . . ?
Dy3 C44 C55 C57 -97.5(7) . . . . ?
Dy3 C44 C55 C58 139.4(6) . . . . ?
Dy3 C64 C63 C67 68.2(4) . . . . ?
Dy3 C64 C63 C68 -120.7(5) . . . . ?
F4 C77 C78 F5 -0.6(7) . . . . ?
F4 C77 C78 C73 179.8(5) . . . . ?
F8 C81 C82 C83 178.5(4) . . . . ?
F8 C81 C82 B3 3.3(8) . . . . ?
F8 C81 C80 F7 1.2(7) . . . . ?
F8 C81 C80 C79 -179.6(4) . . . . ?
F18 C96 C91 C92 -178.0(4) . . . . ?
F18 C96 C91 B3 -4.1(8) . . . . ?
F18 C96 C95 F17 0.7(7) . . . . ?
F18 C96 C95 C94 179.8(5) . . . . ?
F9 C83 C84 F10 -1.1(7) . . . . ?
F9 C83 C84 C79 178.3(4) . . . . ?
F13 C90 C89 F12 -0.3(7) . . . . ?
F13 C90 C89 C88 179.4(5) . . . . ?
F3 C75 C74 F2 3.2(8) . . . . ?
F3 C75 C74 C73 -177.5(5) . . . . ?
F7 C80 C79 F6 -0.7(7) . . . . ?
F7 C80 C79 C84 179.1(4) . . . . ?
F19 C92 C93 F20 2.2(8) . . . . ?
F19 C92 C93 C94 -177.2(5) . . . . ?
F15 C87 C86 F14 0.8(7) . . . . ?
F15 C87 C86 C85 179.6(5) . . . . ?
F15 C87 C88 F11 0.4(8) . . . . ?
F15 C87 C88 C89 -178.9(5) . . . . ?
F2 C74 C73 F1 -0.6(9) . . . . ?
F2 C74 C73 C78 179.8(5) . . . . ?
F1 C73 C78 F5 -0.4(8) . . . . ?
F1 C73 C78 C77 179.2(5) . . . . ?
F17 C95 C94 F16 -1.4(8) . . . . ?
F17 C95 C94 C93 178.3(5) . . . . ?
F6 C79 C84 F10 -0.8(8) . . . . ?
F6 C79 C84 C83 179.8(5) . . . . ?
F12 C89 C88 F11 0.5(8) . . . . ?
F12 C89 C88 C87 179.7(5) . . . . ?
F16 C94 C93 F20 0.0(8) . . . . ?
F16 C94 C93 C92 179.3(5) . . . . ?
C81 C82 C83 F9 -177.1(4) . . . . ?
C81 C82 C83 C84 2.6(7) . . . . ?
C81 C82 B3 C76 104.5(5) . . . . ?
C81 C82 B3 C85 -18.0(7) . . . . ?
C81 C82 B3 C91 -132.5(5) . . . . ?
C81 C80 C79 F6 -179.8(4) . . . . ?
C81 C80 C79 C84 0.0(8) . . . . ?
C6 C7 C8 Dy2 72.2(4) . . . . ?
C6 C7 C8 C9 5.6(6) . . . . ?
C6 C7 C8 C19 -158.2(5) . . . . ?
C6 C1 C5 Dy1 -117.1(5) . . . . ?
C6 C1 C5 C4 173.6(5) . . . . ?
C6 C1 C2 Dy1 121.3(5) . . . . ?
C6 C1 C2 C3 -175.0(5) . . . . ?
C6 C1 C2 C11 -6.5(9) . . . . ?
C6 C10 C23 C24 146.0(6) . . . . ?
C6 C10 C23 C25 -97.0(7) . . . . ?
C6 C10 C23 C26 21.9(10) . . . . ?
C76 C77 C78 F5 179.8(5) . . . . ?
C76 C77 C78 C73 0.1(8) . . . . ?
C76 C75 C74 F2 -178.0(5) . . . . ?
C76 C75 C74 C73 1.4(10) . . . . ?
C82 C81 C80 F7 -177.7(4) . . . . ?
C82 C81 C80 C79 1.4(8) . . . . ?
C82 C83 C84 F10 179.1(5) . . . . ?
C82 C83 C84 C79 -1.5(8) . . . . ?
C41 C37 C42 Dy3 41.2(7) . . . . ?
C41 C37 C42 C43 132.2(5) . . . . ?
C41 C37 C42 C46 -57.3(8) . . . . ?
C41 C37 C38 Dy2 -65.1(3) . . . . ?
C41 C37 C38 C39 -0.1(6) . . . . ?
C41 C37 C38 C47 165.7(5) . . . . ?
C41 C40 C51 C54 -14.5(8) . . . . ?
C41 C40 C51 C53 103.3(6) . . . . ?
C41 C40 C51 C52 -137.7(6) . . . . ?
C41 C40 C39 Dy2 66.7(3) . . . . ?
C41 C40 C39 C38 -3.9(6) . . . . ?
C37 C41 C40 Dy2 71.4(4) . . . . ?
C37 C41 C40 C51 -160.7(5) . . . . ?
C37 C41 C40 C39 3.8(6) . . . . ?
C37 C42 C46 Dy3 122.1(5) . . . . ?
C37 C42 C46 C45 -172.5(5) . . . . ?
C37 C42 C46 C59 2.9(9) . . . . ?
C37 C38 C39 Dy2 -66.3(4) . . . . ?
C37 C38 C39 C40 2.5(6) . . . . ?
C37 C38 C47 C50 -42.6(7) . . . . ?
C37 C38 C47 C48 -160.0(5) . . . . ?
C37 C38 C47 C49 80.2(7) . . . . ?
C3 C2 C11 C13 -118.5(6) . . . . ?
C3 C2 C11 C14 1.6(7) . . . . ?
C3 C2 C11 C12 120.1(6) . . . . ?
C3 C4 C15 C17 -9.1(7) . . . . ?
C3 C4 C15 C16 -128.8(6) . . . . ?
C3 C4 C15 C18 112.1(6) . . . . ?
C80 C81 C82 C83 -2.6(7) . . . . ?
C80 C81 C82 B3 -177.9(5) . . . . ?
C80 C79 C84 F10 179.4(5) . . . . ?
C80 C79 C84 C83 0.0(8) . . . . ?
C77 C76 C75 F3 176.5(5) . . . . ?
C77 C76 C75 C74 -2.3(8) . . . . ?
C77 C76 B3 C82 -68.5(6) . . . . ?
C77 C76 B3 C85 52.9(6) . . . . ?
C77 C76 B3 C91 168.4(4) . . . . ?
C45 C46 C59 C61 -111.6(6) . . . . ?
C45 C46 C59 C62 127.7(6) . . . . ?
C45 C46 C59 C60 7.8(7) . . . . ?
C45 C44 C55 C56 115.1(7) . . . . ?
C45 C44 C55 C57 -4.4(10) . . . . ?
C45 C44 C55 C58 -127.5(8) . . . . ?
C75 C76 C77 F4 -178.1(4) . . . . ?
C75 C76 C77 C78 1.5(8) . . . . ?
C75 C76 B3 C82 106.8(6) . . . . ?
C75 C76 B3 C85 -131.8(5) . . . . ?
C75 C76 B3 C91 -16.4(7) . . . . ?
C75 C74 C73 F1 -179.9(5) . . . . ?
C75 C74 C73 C78 0.5(9) . . . . ?
C9 C8 C19 C21 178.7(5) . . . . ?
C9 C8 C19 C20 -64.4(7) . . . . ?
C9 C8 C19 C22 53.9(7) . . . . ?
C9 C10 C23 C24 -54.5(7) . . . . ?
C9 C10 C23 C25 62.5(7) . . . . ?
C9 C10 C23 C26 -178.6(7) . . . . ?
C43 C42 C46 Dy3 -66.2(3) . . . . ?
C43 C42 C46 C45 -0.8(5) . . . . ?
C43 C42 C46 C59 174.5(5) . . . . ?
C43 C44 C55 C56 -68.6(8) . . . . ?
C43 C44 C55 C57 171.9(7) . . . . ?
C43 C44 C55 C58 48.8(9) . . . . ?
C42 C37 C38 Dy2 122.6(5) . . . . ?
C42 C37 C38 C39 -172.4(5) . . . . ?
C42 C37 C38 C47 -6.6(9) . . . . ?
C42 C43 C44 Dy3 68.9(4) . . . . ?
C42 C43 C44 C45 2.1(6) . . . . ?
C42 C43 C44 C55 -174.9(5) . . . . ?
C42 C46 C59 C61 73.8(7) . . . . ?
C42 C46 C59 C62 -46.8(8) . . . . ?
C42 C46 C59 C60 -166.8(5) . . . . ?
C7 C6 C1 Dy1 42.9(7) . . . . ?
C7 C6 C1 C5 130.8(6) . . . . ?
C7 C6 C1 C2 -54.9(8) . . . . ?
C7 C6 C10 Dy2 -64.0(3) . . . . ?
C7 C6 C10 C9 1.5(6) . . . . ?
C7 C6 C10 C23 163.0(5) . . . . ?
C7 C8 C19 C21 -20.8(7) . . . . ?
C7 C8 C19 C20 96.2(6) . . . . ?
C7 C8 C19 C22 -145.6(6) . . . . ?
C46 C45 C44 Dy3 -69.2(4) . . . . ?
C46 C45 C44 C43 -2.7(6) . . . . ?
C46 C45 C44 C55 174.2(5) . . . . ?
C8 C9 C10 Dy2 69.4(4) . . . . ?
C8 C9 C10 C6 2.0(6) . . . . ?
C8 C9 C10 C23 -162.1(5) . . . . ?
C83 C82 B3 C76 -70.6(5) . . . . ?
C83 C82 B3 C85 167.0(4) . . . . ?
C83 C82 B3 C91 52.4(6) . . . . ?
C1 C6 C7 Dy2 -121.5(5) . . . . ?
C1 C6 C7 C8 167.3(5) . . . . ?
C1 C6 C10 Dy2 124.9(5) . . . . ?
C1 C6 C10 C9 -169.6(5) . . . . ?
C1 C6 C10 C23 -8.1(9) . . . . ?
C1 C5 C4 Dy1 71.7(4) . . . . ?
C1 C5 C4 C3 2.5(6) . . . . ?
C1 C5 C4 C15 -179.6(5) . . . . ?
C1 C2 C11 C13 74.9(7) . . . . ?
C1 C2 C11 C14 -165.0(5) . . . . ?
C1 C2 C11 C12 -46.5(8) . . . . ?
C27 C31 C30 Dy1 -67.2(4) . . . . ?
C27 C31 C30 C29 0.6(6) . . . . ?
C27 C31 C30 C35 177.9(5) . . . . ?
C27 C28 C29 Dy1 66.2(4) . . . . ?
C27 C28 C29 C30 -0.8(6) . . . . ?
C27 C28 C29 C34 -171.7(5) . . . . ?
C10 C6 C7 Dy2 66.8(4) . . . . ?
C10 C6 C7 C8 -4.5(6) . . . . ?
C10 C6 C1 Dy1 -147.3(4) . . . . ?
C10 C6 C1 C5 -59.4(8) . . . . ?
C10 C6 C1 C2 114.9(6) . . . . ?
C10 C9 C8 Dy2 -70.2(4) . . . . ?
C10 C9 C8 C7 -4.7(6) . . . . ?
C10 C9 C8 C19 159.0(5) . . . . ?
C31 C27 C28 Dy1 67.4(4) . . . . ?
C31 C27 C28 C29 1.1(6) . . . . ?
C31 C27 C28 C33 -173.4(5) . . . . ?
C31 C30 C29 Dy1 -67.7(4) . . . . ?
C31 C30 C29 C28 0.1(6) . . . . ?
C31 C30 C29 C34 171.2(5) . . . . ?
C40 C41 C37 Dy2 -70.5(4) . . . . ?
C40 C41 C37 C42 170.2(5) . . . . ?
C40 C41 C37 C38 -2.3(6) . . . . ?
C5 C1 C2 Dy1 -63.6(3) . . . . ?
C5 C1 C2 C3 0.2(6) . . . . ?
C5 C1 C2 C11 168.6(5) . . . . ?
C5 C4 C15 C17 173.5(5) . . . . ?
C5 C4 C15 C16 53.7(7) . . . . ?
C5 C4 C15 C18 -65.4(7) . . . . ?
C85 C90 C89 F12 178.8(5) . . . . ?
C85 C90 C89 C88 -1.4(8) . . . . ?
C2 C3 C4 Dy1 -69.7(4) . . . . ?
C2 C3 C4 C5 -2.4(6) . . . . ?
C2 C3 C4 C15 179.8(5) . . . . ?
C2 C1 C5 Dy1 67.7(4) . . . . ?
C2 C1 C5 C4 -1.6(6) . . . . ?
C4 C3 C2 Dy1 66.3(4) . . . . ?
C4 C3 C2 C1 1.4(6) . . . . ?
C4 C3 C2 C11 -168.0(5) . . . . ?
C74 C73 C78 F5 179.2(5) . . . . ?
C74 C73 C78 C77 -1.2(8) . . . . ?
C86 C87 C88 F11 180.0(5) . . . . ?
C86 C87 C88 C89 0.7(8) . . . . ?
C86 C85 C90 F13 -178.9(4) . . . . ?
C86 C85 C90 C89 1.9(7) . . . . ?
C86 C85 B3 C76 -170.0(4) . . . . ?
C86 C85 B3 C82 -54.5(6) . . . . ?
C86 C85 B3 C91 67.5(5) . . . . ?
C96 C91 C92 F19 176.7(4) . . . . ?
C96 C91 C92 C93 -2.9(8) . . . . ?
C96 C91 B3 C76 133.2(5) . . . . ?
C96 C91 B3 C82 16.7(7) . . . . ?
C96 C91 B3 C85 -104.2(6) . . . . ?
C96 C95 C94 F16 179.5(5) . . . . ?
C96 C95 C94 C93 -0.8(8) . . . . ?
C38 C37 C42 Dy3 -147.8(4) . . . . ?
C38 C37 C42 C43 -56.8(8) . . . . ?
C38 C37 C42 C46 113.6(6) . . . . ?
C28 C27 C31 Dy1 -67.9(4) . . . . ?
C28 C27 C31 C30 -1.0(6) . . . . ?
C28 C27 C31 C36 170.7(5) . . . . ?
C90 C85 C86 F14 177.5(4) . . . . ?
C90 C85 C86 C87 -1.3(8) . . . . ?
C90 C85 B3 C76 18.2(7) . . . . ?
C90 C85 B3 C82 133.7(5) . . . . ?
C90 C85 B3 C91 -104.3(6) . . . . ?
C90 C89 C88 F11 -179.3(5) . . . . ?
C90 C89 C88 C87 -0.1(8) . . . . ?
C51 C40 C39 Dy2 -128.6(5) . . . . ?
C51 C40 C39 C38 160.9(5) . . . . ?
C65 C64 C63 Dy3 -67.4(4) . . . . ?
C65 C64 C63 C67 0.8(6) . . . . ?
C65 C64 C63 C68 171.8(5) . . . . ?
C39 C40 C51 C54 -176.1(5) . . . . ?
C39 C40 C51 C53 -58.2(7) . . . . ?
C39 C40 C51 C52 60.8(7) . . . . ?
C39 C38 C47 C50 121.0(6) . . . . ?
C39 C38 C47 C48 3.5(7) . . . . ?
C39 C38 C47 C49 -116.2(6) . . . . ?
C91 C96 C95 F17 -178.9(5) . . . . ?
C91 C96 C95 C94 0.2(8) . . . . ?
C91 C92 C93 F20 -178.2(5) . . . . ?
C91 C92 C93 C94 2.4(8) . . . . ?
C95 C96 C91 C92 1.5(7) . . . . ?
C95 C96 C91 B3 175.4(5) . . . . ?
C95 C94 C93 F20 -179.8(5) . . . . ?
C95 C94 C93 C92 -0.4(8) . . . . ?
C88 C87 C86 F14 -178.8(5) . . . . ?
C88 C87 C86 C85 0.0(8) . . . . ?
C92 C91 B3 C76 -53.2(6) . . . . ?
C92 C91 B3 C82 -169.6(4) . . . . ?
C92 C91 B3 C85 69.4(6) . . . . ?
C44 C45 C46 Dy3 68.2(4) . . . . ?
C44 C45 C46 C42 2.2(6) . . . . ?
C44 C45 C46 C59 -173.5(5) . . . . ?
C44 C43 C42 Dy3 -68.8(4) . . . . ?
C44 C43 C42 C37 171.4(5) . . . . ?
C44 C43 C42 C46 -0.8(6) . . . . ?
C64 C65 C66 Dy3 67.0(4) . . . . ?
C64 C65 C66 C67 -0.9(6) . . . . ?
C64 C65 C66 C71 -172.4(6) . . . . ?
C63 C67 C66 Dy3 -65.9(4) . . . . ?
C63 C67 C66 C65 1.4(6) . . . . ?
C63 C67 C66 C71 173.0(5) . . . . ?
C35 C30 C29 Dy1 115.0(5) . . . . ?
C35 C30 C29 C28 -177.2(5) . . . . ?
C35 C30 C29 C34 -6.1(9) . . . . ?
C47 C38 C39 Dy2 127.0(5) . . . . ?
C47 C38 C39 C40 -164.2(5) . . . . ?
C66 C65 C64 Dy3 -67.2(4) . . . . ?
C66 C65 C64 C63 0.1(6) . . . . ?
C66 C65 C64 C69 170.9(6) . . . . ?
C66 C67 C63 Dy3 65.9(4) . . . . ?
C66 C67 C63 C64 -1.3(6) . . . . ?
C66 C67 C63 C68 -171.9(5) . . . . ?
C72 C67 C63 Dy3 -115.1(6) . . . . ?
C72 C67 C63 C64 177.7(5) . . . . ?
C72 C67 C63 C68 7.1(9) . . . . ?
C72 C67 C66 Dy3 115.0(5) . . . . ?
C72 C67 C66 C65 -177.7(5) . . . . ?
C72 C67 C66 C71 -6.1(9) . . . . ?
C36 C31 C30 Dy1 121.5(6) . . . . ?
C36 C31 C30 C29 -170.8(5) . . . . ?
C36 C31 C30 C35 6.6(9) . . . . ?
C32 C27 C31 Dy1 123.3(5) . . . . ?
C32 C27 C31 C30 -169.8(5) . . . . ?
C32 C27 C31 C36 1.9(9) . . . . ?
C32 C27 C28 Dy1 -124.2(5) . . . . ?
C32 C27 C28 C29 169.6(5) . . . . ?
C32 C27 C28 C33 -4.9(9) . . . . ?
C70 C65 C64 Dy3 118.3(6) . . . . ?
C70 C65 C64 C63 -174.5(5) . . . . ?
C70 C65 C64 C69 -3.6(10) . . . . ?
C70 C65 C66 Dy3 -118.3(5) . . . . ?
C70 C65 C66 C67 173.8(5) . . . . ?
C70 C65 C66 C71 2.3(9) . . . . ?
B3 C76 C77 F4 -2.3(7) . . . . ?
B3 C76 C77 C78 177.3(5) . . . . ?
B3 C76 C75 F3 1.0(8) . . . . ?
B3 C76 C75 C74 -177.8(5) . . . . ?
B3 C82 C83 F9 -1.4(7) . . . . ?
B3 C82 C83 C84 178.3(5) . . . . ?
B3 C85 C86 F14 4.5(7) . . . . ?
B3 C85 C86 C87 -174.2(5) . . . . ?
B3 C85 C90 F13 -6.8(8) . . . . ?
B3 C85 C90 C89 174.1(5) . . . . ?
B3 C91 C92 F19 2.2(7) . . . . ?
B3 C91 C92 C93 -177.4(5) . . . . ?
C69 C64 C63 Dy3 121.2(6) . . . . ?
C69 C64 C63 C67 -170.5(5) . . . . ?
C69 C64 C63 C68 0.5(9) . . . . ?
C33 C28 C29 Dy1 -119.2(5) . . . . ?
C33 C28 C29 C30 173.9(5) . . . . ?
C33 C28 C29 C34 2.9(9) . . . . ?
C97 C98 C99 C100 46(2) . . . . ?
C99 C100 C101 C102 -176.7(15) . . . . ?
C101 C100 C99 C98 -179.4(15) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.479
_oxdiff_exptl_absorpt_empirical_full_min 0.804
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Heat-sensitive,Oxygen-sensitive
