# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_2101301167
_database_code_depnum_ccdc_archive 'CCDC 2080916'
loop_
_audit_author_name
_audit_author_address
'ketaochen Guo'
;Nanjing Tech University
China
;
_audit_update_record             
;
2021-04-29 deposited with the CCDC.	2021-06-22 downloaded from the CCDC.
;
_audit_creation_date             2021-02-03
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C33 H24 Br2 F3 N O5'
_chemical_formula_sum            'C33 H24 Br2 F3 N O5'
_chemical_formula_weight         731.35
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0148 0.0070 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.9502 1.0410 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0599 0.0411 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0253 0.0136 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0412 0.0250 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.3047(2)
_cell_length_b                   9.9702(2)
_cell_length_c                   17.0352(4)
_cell_angle_alpha                73.9880(10)
_cell_angle_beta                 80.7730(10)
_cell_angle_gamma                80.4190(10)
_cell_volume                     1486.89(6)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    6862
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      54.824
_cell_measurement_theta_min      4.048
_shelx_estimated_absorpt_T_max   0.922
_shelx_estimated_absorpt_T_min   0.811
_exptl_absorpt_coefficient_mu    2.736
_exptl_absorpt_correction_T_max  0.7508
_exptl_absorpt_correction_T_min  0.5632
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1284 before and 0.0615 after correction. The Ratio of minimum to maximum transmission is 0.7501. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.634
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             732
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.03
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0541
_diffrn_reflns_av_unetI/netI     0.0557
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            17604
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         54.932
_diffrn_reflns_theta_min         4.047
_diffrn_ambient_temperature      193.01
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34139
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4156
_reflns_number_total             5621
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.879
_refine_diff_density_min         -0.815
_refine_diff_density_rms         0.084
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     397
_refine_ls_number_reflns         5621
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0723
_refine_ls_R_factor_gt           0.0465
_refine_ls_restrained_S_all      1.032
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0325P)²+2.5409P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0957
_refine_ls_wR_factor_ref         0.1098
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Ternary CH refined with riding coordinates:
 C8(H8)
2.b Secondary CH2 refined with riding coordinates:
 C6(H6A,H6B), C22(H22A,H22B), C23(H23A,H23B)
2.c Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C11(H11), C12(H12), C14(H14), C15(H15), C17(H17), C18(H18),
 C19(H19), C20(H20), C21(H21), C26(H26), C27(H27), C29(H29), C30(H30), C32(H32),
  C33(H33)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Br1 Br 1.03830(6) 1.48382(5) 0.15166(3) 0.05359(17) Uani 1 1 d . . . . .
Br2 Br 0.68247(5) -0.02307(5) 0.05230(3) 0.04223(15) Uani 1 1 d . . . . .
F1 F 0.6905(3) 0.7964(2) 0.41549(14) 0.0433(6) Uani 1 1 d . . . . .
F2 F 0.5884(3) 0.6099(3) 0.47043(14) 0.0532(7) Uani 1 1 d . . . . .
F3 F 0.8194(3) 0.5934(3) 0.42643(16) 0.0548(7) Uani 1 1 d . . . . .
O1 O 0.8050(3) 0.8402(3) 0.24998(15) 0.0300(6) Uani 1 1 d . . . . .
O2 O 0.5206(3) 0.7532(3) 0.31089(15) 0.0301(6) Uani 1 1 d . . . . .
O3 O 0.4445(3) 0.5958(3) 0.15464(16) 0.0365(7) Uani 1 1 d . . . . .
O4 O 0.6352(4) 0.6649(3) 0.0617(2) 0.0532(8) Uani 1 1 d . . . . .
O5 O 1.0055(3) 0.7978(3) 0.16306(18) 0.0392(7) Uani 1 1 d . . . . .
N1 N 0.6264(3) 0.5194(3) 0.33191(18) 0.0292(7) Uani 1 1 d . . . . .
C1 C 1.0024(5) 1.2972(4) 0.1654(3) 0.0362(10) Uani 1 1 d . . . . .
C2 C 0.8802(4) 1.2510(4) 0.2175(2) 0.0331(9) Uani 1 1 d . . . . .
H2 H 0.815793 1.312469 0.245084 0.040 Uiso 1 1 calc R . . . .
C3 C 0.8528(4) 1.1137(4) 0.2289(2) 0.0298(9) Uani 1 1 d . . . . .
H3 H 0.769565 1.080490 0.264641 0.036 Uiso 1 1 calc R . . . .
C4 C 0.9474(4) 1.0253(4) 0.1880(2) 0.0277(8) Uani 1 1 d . . . . .
C5 C 0.9252(4) 0.8772(4) 0.1974(2) 0.0303(9) Uani 1 1 d . . . . .
C6 C 0.7763(4) 0.6995(4) 0.2578(2) 0.0308(9) Uani 1 1 d . . . . .
H6A H 0.865976 0.632524 0.270307 0.037 Uiso 1 1 calc R . . . .
H6B H 0.749075 0.692863 0.205304 0.037 Uiso 1 1 calc R . . . .
C7 C 0.6527(4) 0.6618(4) 0.3260(2) 0.0281(8) Uani 1 1 d . . . . .
C8 C 0.4040(4) 0.6693(4) 0.3189(2) 0.0280(8) Uani 1 1 d . . . . .
H8 H 0.337750 0.672708 0.370922 0.034 Uiso 1 1 calc R . . . .
C9 C 0.4885(4) 0.5226(4) 0.3285(2) 0.0270(8) Uani 1 1 d . . . . .
C10 C 0.4214(4) 0.3933(4) 0.3423(2) 0.0270(8) Uani 1 1 d . . . . .
C11 C 0.5093(4) 0.2632(4) 0.3522(2) 0.0317(9) Uani 1 1 d . . . . .
H11 H 0.613137 0.259682 0.345026 0.038 Uiso 1 1 calc R . . . .
C12 C 0.4475(4) 0.1396(4) 0.3721(2) 0.0339(9) Uani 1 1 d . . . . .
H12 H 0.509536 0.052331 0.378419 0.041 Uiso 1 1 calc R . . . .
C13 C 0.2958(4) 0.1408(4) 0.3831(2) 0.0291(9) Uani 1 1 d . . . . .
C14 C 0.2086(4) 0.2709(4) 0.3702(2) 0.0373(10) Uani 1 1 d . . . . .
H14 H 0.105032 0.274548 0.374770 0.045 Uiso 1 1 calc R . . . .
C15 C 0.2704(4) 0.3954(4) 0.3508(2) 0.0345(9) Uani 1 1 d . . . . .
H15 H 0.208547 0.482829 0.343260 0.041 Uiso 1 1 calc R . . . .
C16 C 0.2284(4) 0.0088(4) 0.4111(2) 0.0306(9) Uani 1 1 d . . . . .
C17 C 0.2862(5) -0.1054(4) 0.4699(2) 0.0377(10) Uani 1 1 d . . . . .
H17 H 0.373252 -0.100419 0.490931 0.045 Uiso 1 1 calc R . . . .
C18 C 0.2189(5) -0.2262(5) 0.4983(3) 0.0402(10) Uani 1 1 d . . . . .
H18 H 0.259273 -0.302534 0.539223 0.048 Uiso 1 1 calc R . . . .
C19 C 0.0946(5) -0.2372(5) 0.4682(3) 0.0417(11) Uani 1 1 d . . . . .
H19 H 0.048879 -0.320533 0.487834 0.050 Uiso 1 1 calc R . . . .
C20 C 0.0371(5) -0.1259(5) 0.4091(3) 0.0478(12) Uani 1 1 d . . . . .
H20 H -0.048609 -0.132818 0.387433 0.057 Uiso 1 1 calc R . . . .
C21 C 0.1028(5) -0.0039(5) 0.3808(3) 0.0444(11) Uani 1 1 d . . . . .
H21 H 0.061323 0.072206 0.340199 0.053 Uiso 1 1 calc R . . . .
C22 C 0.3169(4) 0.7310(4) 0.2464(2) 0.0340(9) Uani 1 1 d . . . . .
H22A H 0.236682 0.673730 0.252232 0.041 Uiso 1 1 calc R . . . .
H22B H 0.271206 0.827243 0.248405 0.041 Uiso 1 1 calc R . . . .
C23 C 0.4050(5) 0.7380(4) 0.1640(2) 0.0367(10) Uani 1 1 d . . . . .
H23A H 0.346571 0.795662 0.119846 0.044 Uiso 1 1 calc R . . . .
H23B H 0.494718 0.781904 0.160153 0.044 Uiso 1 1 calc R . . . .
C24 C 0.5620(5) 0.5751(4) 0.0994(2) 0.0369(10) Uani 1 1 d . . . . .
C25 C 0.5876(4) 0.4278(4) 0.0913(2) 0.0328(9) Uani 1 1 d . . . . .
C26 C 0.4964(5) 0.3276(4) 0.1335(2) 0.0360(9) Uani 1 1 d . . . . .
H26 H 0.414020 0.351461 0.170165 0.043 Uiso 1 1 calc R . . . .
C27 C 0.5253(4) 0.1928(4) 0.1222(2) 0.0365(10) Uani 1 1 d . . . . .
H27 H 0.463184 0.123693 0.150839 0.044 Uiso 1 1 calc R . . . .
C28 C 0.6459(5) 0.1604(4) 0.0685(2) 0.0341(9) Uani 1 1 d . . . . .
C29 C 0.7384(5) 0.2586(4) 0.0265(2) 0.0371(10) Uani 1 1 d . . . . .
H29 H 0.821208 0.234916 -0.009912 0.045 Uiso 1 1 calc R . . . .
C30 C 0.7075(5) 0.3915(4) 0.0388(2) 0.0377(10) Uani 1 1 d . . . . .
H30 H 0.770384 0.460044 0.010496 0.045 Uiso 1 1 calc R . . . .
C31 C 0.6879(5) 0.6661(4) 0.4098(3) 0.0388(10) Uani 1 1 d . . . . .
C32 C 1.0680(5) 1.0748(4) 0.1357(3) 0.0388(10) Uani 1 1 d . . . . .
H32 H 1.132310 1.014116 0.107518 0.047 Uiso 1 1 calc R . . . .
C33 C 1.0962(5) 1.2109(4) 0.1240(3) 0.0415(11) Uani 1 1 d . . . . .
H33 H 1.178971 1.244347 0.087910 0.050 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Br1 C1 1.890(4) . ?
Br2 C28 1.892(4) . ?
F1 C31 1.334(5) . ?
F2 C31 1.336(5) . ?
F3 C31 1.344(5) . ?
O1 C5 1.350(4) . ?
O1 C6 1.438(4) . ?
O2 C7 1.417(4) . ?
O2 C8 1.445(4) . ?
O3 C23 1.451(4) . ?
O3 C24 1.351(5) . ?
O4 C24 1.193(5) . ?
O5 C5 1.202(4) . ?
N1 C7 1.454(4) . ?
N1 C9 1.289(5) . ?
C1 C2 1.385(5) . ?
C1 C33 1.374(6) . ?
C2 H2 0.9500 . ?
C2 C3 1.389(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.386(5) . ?
C4 C5 1.487(5) . ?
C4 C32 1.385(5) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C6 C7 1.513(5) . ?
C7 C31 1.527(5) . ?
C8 H8 1.0000 . ?
C8 C9 1.520(5) . ?
C8 C22 1.516(5) . ?
C9 C10 1.470(5) . ?
C10 C11 1.397(5) . ?
C10 C15 1.386(5) . ?
C11 H11 0.9500 . ?
C11 C12 1.381(5) . ?
C12 H12 0.9500 . ?
C12 C13 1.392(5) . ?
C13 C14 1.392(6) . ?
C13 C16 1.479(5) . ?
C14 H14 0.9500 . ?
C14 C15 1.390(5) . ?
C15 H15 0.9500 . ?
C16 C17 1.389(6) . ?
C16 C21 1.388(5) . ?
C17 H17 0.9500 . ?
C17 C18 1.382(6) . ?
C18 H18 0.9500 . ?
C18 C19 1.370(6) . ?
C19 H19 0.9500 . ?
C19 C20 1.375(6) . ?
C20 H20 0.9500 . ?
C20 C21 1.384(6) . ?
C21 H21 0.9500 . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C22 C23 1.498(5) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 C25 1.489(5) . ?
C25 C26 1.388(5) . ?
C25 C30 1.377(5) . ?
C26 H26 0.9500 . ?
C26 C27 1.387(5) . ?
C27 H27 0.9500 . ?
C27 C28 1.384(5) . ?
C28 C29 1.380(6) . ?
C29 H29 0.9500 . ?
C29 C30 1.375(6) . ?
C30 H30 0.9500 . ?
C32 H32 0.9500 . ?
C32 C33 1.379(6) . ?
C33 H33 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C5 O1 C6 114.0(3) . . ?
C7 O2 C8 108.6(3) . . ?
C24 O3 C23 116.3(3) . . ?
C9 N1 C7 107.7(3) . . ?
C2 C1 Br1 118.5(3) . . ?
C33 C1 Br1 120.0(3) . . ?
C33 C1 C2 121.5(4) . . ?
C1 C2 H2 120.4 . . ?
C1 C2 C3 119.3(4) . . ?
C3 C2 H2 120.4 . . ?
C2 C3 H3 120.1 . . ?
C4 C3 C2 119.7(4) . . ?
C4 C3 H3 120.1 . . ?
C3 C4 C5 122.7(3) . . ?
C32 C4 C3 119.8(3) . . ?
C32 C4 C5 117.6(3) . . ?
O1 C5 C4 112.4(3) . . ?
O5 C5 O1 123.3(3) . . ?
O5 C5 C4 124.3(3) . . ?
O1 C6 H6A 109.7 . . ?
O1 C6 H6B 109.7 . . ?
O1 C6 C7 109.8(3) . . ?
H6A C6 H6B 108.2 . . ?
C7 C6 H6A 109.7 . . ?
C7 C6 H6B 109.7 . . ?
O2 C7 N1 108.4(3) . . ?
O2 C7 C6 112.2(3) . . ?
O2 C7 C31 106.9(3) . . ?
N1 C7 C6 108.3(3) . . ?
N1 C7 C31 108.0(3) . . ?
C6 C7 C31 112.9(3) . . ?
O2 C8 H8 109.1 . . ?
O2 C8 C9 101.7(3) . . ?
O2 C8 C22 108.7(3) . . ?
C9 C8 H8 109.1 . . ?
C22 C8 H8 109.1 . . ?
C22 C8 C9 118.8(3) . . ?
N1 C9 C8 113.0(3) . . ?
N1 C9 C10 121.8(3) . . ?
C10 C9 C8 124.8(3) . . ?
C11 C10 C9 120.1(3) . . ?
C15 C10 C9 121.6(3) . . ?
C15 C10 C11 118.2(3) . . ?
C10 C11 H11 119.5 . . ?
C12 C11 C10 121.0(4) . . ?
C12 C11 H11 119.5 . . ?
C11 C12 H12 119.5 . . ?
C11 C12 C13 121.1(4) . . ?
C13 C12 H12 119.5 . . ?
C12 C13 C16 121.4(4) . . ?
C14 C13 C12 117.9(3) . . ?
C14 C13 C16 120.7(3) . . ?
C13 C14 H14 119.4 . . ?
C15 C14 C13 121.2(4) . . ?
C15 C14 H14 119.4 . . ?
C10 C15 C14 120.7(4) . . ?
C10 C15 H15 119.7 . . ?
C14 C15 H15 119.7 . . ?
C17 C16 C13 121.3(3) . . ?
C21 C16 C13 121.0(4) . . ?
C21 C16 C17 117.7(4) . . ?
C16 C17 H17 119.5 . . ?
C18 C17 C16 120.9(4) . . ?
C18 C17 H17 119.5 . . ?
C17 C18 H18 119.6 . . ?
C19 C18 C17 120.8(4) . . ?
C19 C18 H18 119.6 . . ?
C18 C19 H19 120.5 . . ?
C18 C19 C20 119.1(4) . . ?
C20 C19 H19 120.5 . . ?
C19 C20 H20 119.7 . . ?
C19 C20 C21 120.6(4) . . ?
C21 C20 H20 119.7 . . ?
C16 C21 H21 119.5 . . ?
C20 C21 C16 120.9(4) . . ?
C20 C21 H21 119.5 . . ?
C8 C22 H22A 108.6 . . ?
C8 C22 H22B 108.6 . . ?
H22A C22 H22B 107.6 . . ?
C23 C22 C8 114.6(3) . . ?
C23 C22 H22A 108.6 . . ?
C23 C22 H22B 108.6 . . ?
O3 C23 C22 108.2(3) . . ?
O3 C23 H23A 110.1 . . ?
O3 C23 H23B 110.1 . . ?
C22 C23 H23A 110.1 . . ?
C22 C23 H23B 110.1 . . ?
H23A C23 H23B 108.4 . . ?
O3 C24 C25 111.8(3) . . ?
O4 C24 O3 123.6(4) . . ?
O4 C24 C25 124.5(4) . . ?
C26 C25 C24 123.0(4) . . ?
C30 C25 C24 117.6(4) . . ?
C30 C25 C26 119.4(4) . . ?
C25 C26 H26 119.9 . . ?
C27 C26 C25 120.1(4) . . ?
C27 C26 H26 119.9 . . ?
C26 C27 H27 120.5 . . ?
C28 C27 C26 118.9(4) . . ?
C28 C27 H27 120.5 . . ?
C27 C28 Br2 118.5(3) . . ?
C29 C28 Br2 119.8(3) . . ?
C29 C28 C27 121.7(4) . . ?
C28 C29 H29 120.8 . . ?
C30 C29 C28 118.3(4) . . ?
C30 C29 H29 120.8 . . ?
C25 C30 H30 119.2 . . ?
C29 C30 C25 121.6(4) . . ?
C29 C30 H30 119.2 . . ?
F1 C31 F2 106.5(3) . . ?
F1 C31 F3 106.9(3) . . ?
F1 C31 C7 113.0(3) . . ?
F2 C31 F3 107.1(3) . . ?
F2 C31 C7 111.4(3) . . ?
F3 C31 C7 111.7(3) . . ?
C4 C32 H32 119.5 . . ?
C33 C32 C4 121.0(4) . . ?
C33 C32 H32 119.5 . . ?
C1 C33 C32 118.8(4) . . ?
C1 C33 H33 120.6 . . ?
C32 C33 H33 120.6 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
