# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_m5014_0m
_database_code_depnum_ccdc_archive 'CCDC 2093916'
loop_
_audit_author_name
_audit_author_address
'Zhen Liu'
;HENU
China
;
_audit_update_record             
;
2021-08-19 deposited with the CCDC.	2021-08-24 downloaded from the CCDC.
;
_audit_creation_date             2021-08-19
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'0.25(C32 H72 As8 N8 Na8 O336 Rh8 W88), 8(C2 H8 N), 7(O)'
_chemical_formula_sum            'C24 H82 As2 N10 Na2 O91 Rh2 W22'
_chemical_formula_weight         6413.33
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   40.0469(11)
_cell_length_b                   12.2563(4)
_cell_length_c                   23.2462(6)
_cell_angle_alpha                90
_cell_angle_beta                 108.0590(10)
_cell_angle_gamma                90
_cell_volume                     10847.8(5)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9656
_cell_measurement_temperature    150.0
_cell_measurement_theta_max      28.268
_cell_measurement_theta_min      2.352
_shelx_estimated_absorpt_T_max   0.324
_shelx_estimated_absorpt_T_min   0.113
_exptl_absorpt_coefficient_mu    24.238
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.4000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1049 before and 0.0587 after correction. The Ratio of minimum to maximum transmission is 0.5364. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    3.927
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             11320
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0343
_diffrn_reflns_av_unetI/netI     0.0329
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       47
_diffrn_reflns_limit_h_min       -47
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            35713
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.100
_diffrn_reflns_theta_max         25.100
_diffrn_reflns_theta_min         2.295
_diffrn_ambient_temperature      150
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker D8 VENTURE PHOTON II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  'Helios multilayer optic'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_source            'Incoatc Ius 3.0 '
_diffrn_source_type              Microfocus
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8520
_reflns_number_total             9618
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         2.409
_refine_diff_density_min         -1.660
_refine_diff_density_rms         0.235
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     724
_refine_ls_number_reflns         9618
_refine_ls_number_restraints     24
_refine_ls_R_factor_all          0.0324
_refine_ls_R_factor_gt           0.0265
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0173P)²+291.2592P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0554
_refine_ls_wR_factor_ref         0.0579
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All N(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(N5) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(O4W) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(O3W) \\sim Ueq, Uanis(O5W) \\sim Ueq: with sigma of 0.001 and sigma for
terminal atoms of 0.002
3. Others
 Fixed Sof: Na2(0.5) O3W(0.5) O4W(0.5) O5W(0.5) O8W(0.5)
4.a Secondary CH2 refined with riding coordinates:
 N2(H2D,H2E), N3(H3D,H3E), N4(H4A,H4B), N5(H5D,H5E)
4.b Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C2(H2A,H2B,H2C), C3(H3A,H3B,H3C), C5(H5A,H5B,H5C), C6(H6A,
 H6B,H6C), C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C9(H9A,H9B,H9C), C10(H10A,H10B,
 H10C), C11(H11A,H11B,H11C), C12(H12A,H12B,H12C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
As1 As 0.61617(2) 0.70982(7) 0.75117(4) 0.01173(18) Uani 1 1 d . . . . .
C1 C 0.5698(3) 1.1150(9) 0.6989(6) 0.043(3) Uani 1 1 d . . . . .
H1A H 0.546908 1.097454 0.701113 0.065 Uiso 1 1 calc GR . . . .
H1B H 0.572661 1.084111 0.662721 0.065 Uiso 1 1 calc GR . . . .
H1C H 0.572394 1.192836 0.698097 0.065 Uiso 1 1 calc GR . . . .
C2 C 0.5947(3) 1.1135(9) 0.8089(5) 0.036(3) Uani 1 1 d . . . . .
H2A H 0.594826 1.191849 0.807828 0.054 Uiso 1 1 calc GR . . . .
H2B H 0.614787 1.088293 0.840805 0.054 Uiso 1 1 calc GR . . . .
H2C H 0.573649 1.088566 0.815998 0.054 Uiso 1 1 calc GR . . . .
C3 C 0.4561(3) 0.5748(9) 0.5007(5) 0.030(2) Uani 1 1 d . . . . .
H3A H 0.466276 0.589227 0.469144 0.045 Uiso 1 1 calc GR . . . .
H3B H 0.431158 0.566132 0.483423 0.045 Uiso 1 1 calc GR . . . .
H3C H 0.466033 0.509134 0.521592 0.045 Uiso 1 1 calc GR . . . .
C4 C 0.4636(2) 0.6676(8) 0.5441(4) 0.019(2) Uani 1 1 d . . . . .
C5 C 0.7789(3) 0.6272(10) 0.7437(6) 0.044(3) Uani 1 1 d . . . . .
H5A H 0.766566 0.607972 0.702541 0.066 Uiso 1 1 calc GR . . . .
H5B H 0.777931 0.567369 0.769791 0.066 Uiso 1 1 calc GR . . . .
H5C H 0.802964 0.643107 0.747491 0.066 Uiso 1 1 calc GR . . . .
C6 C 0.7672(3) 0.8249(10) 0.7327(6) 0.045(3) Uani 1 1 d . . . . .
H6A H 0.756096 0.820256 0.689795 0.067 Uiso 1 1 calc GR . . . .
H6B H 0.791759 0.839420 0.740994 0.067 Uiso 1 1 calc GR . . . .
H6C H 0.756616 0.882872 0.748871 0.067 Uiso 1 1 calc GR . . . .
C7 C 0.5190(3) 0.2460(11) 0.8299(5) 0.047(3) Uani 1 1 d . . . . .
H7A H 0.536656 0.269259 0.812654 0.071 Uiso 1 1 calc GR . . . .
H7B H 0.497911 0.287595 0.812637 0.071 Uiso 1 1 calc GR . . . .
H7C H 0.514079 0.169962 0.821563 0.071 Uiso 1 1 calc GR . . . .
C8 C 0.5077(3) 0.2085(10) 0.9269(5) 0.039(3) Uani 1 1 d . . . . .
H8A H 0.484089 0.233487 0.908617 0.059 Uiso 1 1 calc GR . . . .
H8B H 0.515183 0.226176 0.969261 0.059 Uiso 1 1 calc GR . . . .
H8C H 0.508672 0.130882 0.922082 0.059 Uiso 1 1 calc GR . . . .
C9 C 0.3158(3) 0.2782(11) 0.5886(5) 0.047(3) Uani 1 1 d . . . . .
H9A H 0.308252 0.224841 0.556959 0.070 Uiso 1 1 calc GR . . . .
H9B H 0.296248 0.298585 0.602023 0.070 Uiso 1 1 calc GR . . . .
H9C H 0.334060 0.247964 0.621854 0.070 Uiso 1 1 calc GR . . . .
C10 C 0.3552(3) 0.3520(12) 0.5345(6) 0.052(4) Uani 1 1 d . . . . .
H10A H 0.344768 0.308161 0.499332 0.077 Uiso 1 1 calc GR . . . .
H10B H 0.374790 0.313752 0.561423 0.077 Uiso 1 1 calc GR . . . .
H10C H 0.363166 0.419716 0.522594 0.077 Uiso 1 1 calc GR . . . .
C11 C 0.3672(5) 0.8846(14) 0.4394(10) 0.096(6) Uani 1 1 d . . . . .
H11A H 0.347325 0.886960 0.403328 0.144 Uiso 1 1 calc GR . . . .
H11B H 0.385233 0.932170 0.434746 0.144 Uiso 1 1 calc GR . . . .
H11C H 0.360152 0.907996 0.473293 0.144 Uiso 1 1 calc GR . . . .
C12 C 0.3856(5) 0.7227(18) 0.4005(7) 0.097(7) Uani 1 1 d . . . . .
H12A H 0.371379 0.753070 0.362808 0.146 Uiso 1 1 calc GR . . . .
H12B H 0.379614 0.647368 0.402703 0.146 Uiso 1 1 calc GR . . . .
H12C H 0.409968 0.728344 0.402993 0.146 Uiso 1 1 calc GR . . . .
N1 N 0.59622(19) 1.0709(6) 0.7511(3) 0.0195(17) Uani 1 1 d . . . . .
N2 N 0.7626(2) 0.7226(8) 0.7607(4) 0.035(2) Uani 1 1 d . . . . .
H2D H 0.739725 0.709780 0.751840 0.042 Uiso 1 1 calc R . . . .
H2E H 0.771219 0.730561 0.800663 0.042 Uiso 1 1 calc R . . . .
N3 N 0.5318(2) 0.2635(8) 0.8968(4) 0.032(2) Uani 1 1 d . . . . .
H3D H 0.532662 0.334737 0.904664 0.039 Uiso 1 1 calc R . . . .
H3E H 0.553364 0.236628 0.911834 0.039 Uiso 1 1 calc R . . . .
N4 N 0.3290(2) 0.3742(8) 0.5657(4) 0.033(2) Uani 1 1 d . . . . .
H4A H 0.338492 0.419041 0.596527 0.040 Uiso 1 1 calc R . . . .
H4B H 0.310872 0.408905 0.540085 0.040 Uiso 1 1 calc R . . . .
N5 N 0.3797(4) 0.7805(13) 0.4489(6) 0.083(4) Uani 1 1 d . U . . .
H5D H 0.364758 0.741709 0.461946 0.100 Uiso 1 1 calc R . . . .
H5E H 0.399956 0.782501 0.478845 0.100 Uiso 1 1 calc R . . . .
Na1 Na 0.500000 0.6737(4) 0.750000 0.0207(11) Uani 1 2 d S T P . .
Na2 Na 0.7155(2) 0.9549(8) 0.5428(5) 0.054(3) Uani 0.5 1 d . . . . .
O1 O 0.74094(15) 0.5053(6) 0.8607(3) 0.0215(15) Uani 1 1 d . . . . .
O1W O 0.500000 1.0075(9) 0.750000 0.037(3) Uani 1 2 d S T P . .
O2 O 0.70130(15) 0.4988(6) 0.6418(3) 0.0223(15) Uani 1 1 d . . . . .
O2W O 0.4055(2) 1.1242(7) 0.5410(4) 0.046(2) Uani 1 1 d . . . . .
O3 O 0.64083(16) 0.2695(5) 0.7533(3) 0.0213(14) Uani 1 1 d . . . . .
O3W O 0.7226(3) 0.7633(10) 0.5724(5) 0.014(2) Uani 0.5 1 d . U . . .
O4 O 0.69888(15) 0.5919(5) 0.7511(3) 0.0186(14) Uani 1 1 d . . . . .
O4W O 0.7284(5) 1.1585(17) 0.5281(7) 0.058(5) Uani 0.5 1 d . U . . .
O5 O 0.66805(15) 0.4681(5) 0.8119(3) 0.0176(14) Uani 1 1 d . . . . .
O5W O 0.7362(4) 0.5664(12) 0.5262(6) 0.035(3) Uani 0.5 1 d . U . . .
O6 O 0.64762(15) 0.4662(5) 0.6951(3) 0.0182(14) Uani 1 1 d . . . . .
O6W O 0.7033(2) 0.2673(10) 0.6175(4) 0.072(3) Uani 1 1 d . . . . .
O7 O 0.72021(14) 0.7230(5) 0.8469(3) 0.0191(14) Uani 1 1 d . . . . .
O7W O 0.5507(2) 1.0691(9) 0.5366(4) 0.063(3) Uani 1 1 d . . . . .
O8 O 0.68631(15) 0.7191(5) 0.6560(3) 0.0193(14) Uani 1 1 d . . . . .
O8W O 0.3407(4) 1.0237(12) 0.5433(7) 0.036(4) Uani 0.5 1 d . . . . .
O9 O 0.63451(15) 0.5843(5) 0.5947(3) 0.0184(14) Uani 1 1 d . . . . .
O10 O 0.60546(14) 0.4003(5) 0.8138(3) 0.0170(13) Uani 1 1 d . . . . .
O11 O 0.58334(14) 0.3973(5) 0.6936(3) 0.0158(13) Uani 1 1 d . . . . .
O12 O 0.55988(16) 0.4617(5) 0.8788(3) 0.0211(14) Uani 1 1 d . . . . .
O13 O 0.59998(14) 0.5791(5) 0.7517(2) 0.0136(13) Uani 1 1 d . . . . .
O14 O 0.65388(15) 0.6983(5) 0.8130(2) 0.0156(13) Uani 1 1 d . . . . .
O15 O 0.50690(16) 0.9196(6) 0.5776(3) 0.0218(15) Uani 1 1 d . . . . .
O16 O 0.68812(15) 0.8416(5) 0.7507(3) 0.0189(14) Uani 1 1 d . . . . .
O17 O 0.71893(16) 0.9520(6) 0.8630(3) 0.0260(16) Uani 1 1 d . . . . .
O18 O 0.67968(16) 0.9448(6) 0.6381(3) 0.0265(16) Uani 1 1 d . . . . .
O19 O 0.62509(15) 0.9230(5) 0.6890(3) 0.0152(13) Uani 1 1 d . . . . .
O20 O 0.64681(15) 0.9243(5) 0.8111(3) 0.0164(13) Uani 1 1 d . . . . .
O21 O 0.62479(15) 0.7995(5) 0.5900(3) 0.0159(13) Uani 1 1 d . . . . .
O22 O 0.57612(16) 0.6644(6) 0.5088(3) 0.0219(15) Uani 1 1 d . . . . .
O23 O 0.63169(14) 0.6966(5) 0.6891(2) 0.0130(13) Uani 1 1 d . . . . .
O24 O 0.51465(15) 0.4567(5) 0.6273(3) 0.0175(14) Uani 1 1 d . . . . .
O25 O 0.54306(14) 0.4880(5) 0.7531(3) 0.0141(13) Uani 1 1 d . . . . .
O26 O 0.57410(15) 0.5651(5) 0.6197(3) 0.0163(13) Uani 1 1 d . . . . .
O27 O 0.56078(15) 0.7702(5) 0.6018(3) 0.0167(13) Uani 1 1 d . . . . .
O28 O 0.53555(14) 0.6640(5) 0.6780(2) 0.0153(13) Uani 1 1 d . . . . .
O29 O 0.56322(14) 0.6660(5) 0.8265(2) 0.0152(13) Uani 1 1 d . . . . .
O30 O 0.49472(15) 0.7005(5) 0.5634(3) 0.0203(14) Uani 1 1 d . . . . .
O31 O 0.55189(15) 0.8887(5) 0.6913(3) 0.0164(13) Uani 1 1 d . . . . .
O32 O 0.37709(15) 0.5686(5) 0.6153(3) 0.0177(14) Uani 1 1 d . . . . .
O33 O 0.30819(16) 0.5917(5) 0.5910(3) 0.0205(14) Uani 1 1 d . . . . .
O34 O 0.33626(16) 0.6638(6) 0.5047(3) 0.0266(16) Uani 1 1 d . . . . .
O35 O 0.31775(15) 0.8061(5) 0.5875(3) 0.0204(14) Uani 1 1 d . . . . .
O36 O 0.38520(15) 0.7743(5) 0.5957(3) 0.0208(14) Uani 1 1 d . . . . .
O37 O 0.43163(15) 0.9234(6) 0.5771(3) 0.0220(15) Uani 1 1 d . . . . .
O38 O 0.42592(15) 0.8897(5) 0.6893(3) 0.0189(14) Uani 1 1 d . . . . .
O39 O 0.43823(15) 0.7067(5) 0.5590(3) 0.0190(14) Uani 1 1 d . . . . .
O40 O 0.48358(15) 0.8069(5) 0.6599(3) 0.0161(13) Uani 1 1 d . . . . .
Rh1 Rh 0.59972(2) 0.90152(6) 0.75041(3) 0.01370(15) Uani 1 1 d . . . . .
W1 W 0.67245(2) 0.57365(3) 0.66674(2) 0.01582(8) Uani 1 1 d . . . . .
W2 W 0.62752(2) 0.40177(3) 0.75254(2) 0.01474(8) Uani 1 1 d . . . . .
W3 W 0.70282(2) 0.57884(3) 0.83441(2) 0.01690(9) Uani 1 1 d . . . . .
W4 W 0.59432(2) 0.67896(3) 0.58478(2) 0.01460(8) Uani 1 1 d . . . . .
W5 W 0.65876(2) 0.84829(3) 0.66766(2) 0.01619(9) Uani 1 1 d . . . . .
W6 W 0.68865(2) 0.85175(3) 0.83423(2) 0.01742(9) Uani 1 1 d . . . . .
W7 W 0.57746(2) 0.52413(3) 0.82864(2) 0.01312(8) Uani 1 1 d . . . . .
W8 W 0.54985(2) 0.52294(3) 0.67487(2) 0.01238(8) Uani 1 1 d . . . . .
W9 W 0.52301(2) 0.81681(3) 0.62966(2) 0.01313(8) Uani 1 1 d . . . . .
W10 W 0.43338(2) 0.81862(3) 0.62795(2) 0.01427(8) Uani 1 1 d . . . . .
W11 W 0.34548(2) 0.68191(3) 0.58127(2) 0.01716(9) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
As1 O13 1.730(6) . ?
As1 O14 1.737(6) . ?
As1 O23 1.746(5) . ?
As1 Rh1 2.4388(11) . ?
C1 N1 1.445(13) . ?
C2 N1 1.460(12) . ?
C3 C4 1.488(13) . ?
C4 O30 1.254(11) . ?
C4 O39 1.264(11) . ?
C5 N2 1.452(14) . ?
C6 N2 1.450(14) . ?
C7 N3 1.494(14) . ?
C8 N3 1.513(13) . ?
C9 N4 1.457(14) . ?
C10 N4 1.474(13) . ?
C11 N5 1.36(2) . ?
C12 N5 1.410(19) . ?
N1 Rh1 2.081(8) . ?
Na1 O25 2.843(7) 2_656 ?
Na1 O25 2.843(7) . ?
Na1 O28 2.513(5) 2_656 ?
Na1 O28 2.513(5) . ?
Na1 O29 2.606(6) . ?
Na1 O29 2.606(6) 2_656 ?
Na1 O40 2.575(7) . ?
Na1 O40 2.575(7) 2_656 ?
Na1 W7 3.579(3) . ?
Na1 W7 3.579(3) 2_656 ?
Na1 W8 3.551(3) 2_656 ?
Na1 W8 3.551(3) . ?
Na2 O1 2.457(11) 4_656 ?
Na2 O3W 2.440(15) . ?
Na2 O4W 2.59(2) . ?
Na2 O5W 2.882(19) 7_666 ?
Na2 O8W 2.520(18) 5_676 ?
Na2 O18 2.992(13) . ?
O1 W3 1.714(6) . ?
O2 W1 1.710(6) . ?
O3 W2 1.705(7) . ?
O4 W1 1.931(6) . ?
O4 W3 1.900(6) . ?
O5 W2 1.951(6) . ?
O5 W3 1.898(6) . ?
O6 W1 1.889(6) . ?
O6 W2 1.928(6) . ?
O7 W3 1.888(6) . ?
O7 W6 1.986(6) . ?
O8 W1 1.906(6) . ?
O8 W5 1.996(6) . ?
O9 W1 1.886(6) . ?
O9 W4 1.939(6) . ?
O10 W2 1.894(6) . ?
O10 W7 1.980(6) . ?
O11 W2 1.873(6) . ?
O11 W8 1.999(6) . ?
O12 W7 1.718(6) . ?
O13 W2 2.434(6) . ?
O13 W7 2.339(5) . ?
O13 W8 2.339(6) . ?
O14 W3 2.372(6) . ?
O14 W6 2.301(6) . ?
O14 W11 2.459(5) 2_656 ?
O15 W9 1.728(6) . ?
O16 W5 1.926(6) . ?
O16 W6 1.939(6) . ?
O17 W6 1.710(6) . ?
O18 W5 1.712(6) . ?
O19 Rh1 2.009(5) . ?
O19 W5 1.822(6) . ?
O20 Rh1 1.994(6) . ?
O20 W6 1.824(6) . ?
O21 W4 1.896(6) . ?
O21 W5 1.985(6) . ?
O22 W4 1.698(6) . ?
O23 W1 2.394(6) . ?
O23 W4 2.433(6) . ?
O23 W5 2.284(6) . ?
O24 W8 1.704(6) . ?
O25 W7 1.918(6) . ?
O25 W8 1.967(5) . ?
O26 W4 1.916(6) . ?
O26 W8 1.904(5) . ?
O27 W4 1.882(6) . ?
O27 W9 1.908(6) . ?
O28 W8 1.830(6) . ?
O28 W9 2.161(6) . ?
O29 W7 1.826(6) . ?
O29 W10 2.133(6) 2_656 ?
O30 W9 2.146(6) . ?
O31 Rh1 1.988(6) . ?
O31 W9 1.771(6) . ?
O32 W7 1.959(6) 2_656 ?
O32 W11 1.881(6) . ?
O33 W3 1.924(6) 2_656 ?
O33 W11 1.927(6) . ?
O34 W11 1.715(6) . ?
O35 W6 1.994(6) 2_656 ?
O35 W11 1.916(6) . ?
O36 W10 1.919(6) . ?
O36 W11 1.896(6) . ?
O37 W10 1.732(6) . ?
O38 Rh1 1.983(6) 2_656 ?
O38 W10 1.773(6) . ?
O39 W10 2.164(6) . ?
O40 W9 1.922(5) . ?
O40 W10 1.920(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O13 As1 O14 98.7(3) . . ?
O13 As1 O23 98.6(3) . . ?
O13 As1 Rh1 142.32(19) . . ?
O14 As1 O23 103.6(3) . . ?
O14 As1 Rh1 104.4(2) . . ?
O23 As1 Rh1 104.4(2) . . ?
O30 C4 C3 117.2(8) . . ?
O30 C4 O39 125.1(9) . . ?
O39 C4 C3 117.7(8) . . ?
C1 N1 C2 114.3(9) . . ?
C1 N1 Rh1 113.6(6) . . ?
C2 N1 Rh1 112.7(6) . . ?
C6 N2 C5 116.5(9) . . ?
C7 N3 C8 110.8(9) . . ?
C9 N4 C10 115.2(10) . . ?
C11 N5 C12 119.0(16) . . ?
O25 Na1 O25 73.6(3) . 2_656 ?
O25 Na1 W7 91.49(17) 2_656 . ?
O25 Na1 W7 91.49(17) . 2_656 ?
O25 Na1 W7 32.24(12) 2_656 2_656 ?
O25 Na1 W7 32.24(12) . . ?
O25 Na1 W8 33.58(11) 2_656 2_656 ?
O25 Na1 W8 90.01(17) . 2_656 ?
O25 Na1 W8 33.58(11) . . ?
O25 Na1 W8 90.01(17) 2_656 . ?
O28 Na1 O25 60.98(19) . . ?
O28 Na1 O25 60.98(19) 2_656 2_656 ?
O28 Na1 O25 114.2(2) . 2_656 ?
O28 Na1 O25 114.2(2) 2_656 . ?
O28 Na1 O28 174.6(4) . 2_656 ?
O28 Na1 O29 100.08(17) 2_656 . ?
O28 Na1 O29 79.73(17) 2_656 2_656 ?
O28 Na1 O29 79.73(17) . . ?
O28 Na1 O29 100.08(17) . 2_656 ?
O28 Na1 O40 62.81(19) 2_656 2_656 ?
O28 Na1 O40 121.1(2) . 2_656 ?
O28 Na1 O40 62.81(19) . . ?
O28 Na1 O40 121.1(2) 2_656 . ?
O28 Na1 W7 74.68(14) . . ?
O28 Na1 W7 102.48(16) 2_656 . ?
O28 Na1 W7 74.69(14) 2_656 2_656 ?
O28 Na1 W7 102.48(16) . 2_656 ?
O28 Na1 W8 29.23(15) . . ?
O28 Na1 W8 145.5(2) 2_656 . ?
O28 Na1 W8 145.5(2) . 2_656 ?
O28 Na1 W8 29.23(15) 2_656 2_656 ?
O29 Na1 O25 60.03(18) . . ?
O29 Na1 O25 116.2(2) . 2_656 ?
O29 Na1 O25 116.2(2) 2_656 . ?
O29 Na1 O25 60.03(19) 2_656 2_656 ?
O29 Na1 O29 175.9(4) 2_656 . ?
O29 Na1 W7 146.6(2) . 2_656 ?
O29 Na1 W7 29.31(14) 2_656 2_656 ?
O29 Na1 W7 146.6(2) 2_656 . ?
O29 Na1 W7 29.31(14) . . ?
O29 Na1 W8 102.77(15) 2_656 . ?
O29 Na1 W8 102.77(15) . 2_656 ?
O29 Na1 W8 75.02(13) . . ?
O29 Na1 W8 75.02(13) 2_656 2_656 ?
O40 Na1 O25 121.90(17) 2_656 2_656 ?
O40 Na1 O25 119.16(18) . 2_656 ?
O40 Na1 O25 121.90(17) . . ?
O40 Na1 O25 119.16(18) 2_656 . ?
O40 Na1 O29 61.23(18) 2_656 . ?
O40 Na1 O29 121.8(2) 2_656 2_656 ?
O40 Na1 O29 121.8(2) . . ?
O40 Na1 O29 61.22(18) . 2_656 ?
O40 Na1 O40 101.3(3) 2_656 . ?
O40 Na1 W7 86.96(13) . 2_656 ?
O40 Na1 W7 86.96(13) 2_656 . ?
O40 Na1 W7 134.64(12) 2_656 2_656 ?
O40 Na1 W7 134.64(12) . . ?
O40 Na1 W8 88.33(13) . . ?
O40 Na1 W8 88.33(13) 2_656 2_656 ?
O40 Na1 W8 133.56(12) 2_656 . ?
O40 Na1 W8 133.56(12) . 2_656 ?
W7 Na1 W7 118.40(15) 2_656 . ?
W8 Na1 W7 90.74(9) 2_656 . ?
W8 Na1 W7 56.94(5) 2_656 2_656 ?
W8 Na1 W7 56.94(5) . . ?
W8 Na1 W7 90.73(9) . 2_656 ?
W8 Na1 W8 117.31(15) 2_656 . ?
O1 Na2 O4W 76.4(5) 4_656 . ?
O1 Na2 O5W 97.0(4) 4_656 7_666 ?
O1 Na2 O8W 155.0(6) 4_656 5_676 ?
O1 Na2 O18 72.6(4) 4_656 . ?
O3W Na2 O1 89.8(4) . 4_656 ?
O3W Na2 O4W 162.5(6) . . ?
O3W Na2 O5W 91.8(5) . 7_666 ?
O3W Na2 O8W 108.7(5) . 5_676 ?
O3W Na2 O18 77.9(4) . . ?
O4W Na2 O5W 79.6(6) . 7_666 ?
O4W Na2 O18 107.3(6) . . ?
O5W Na2 O18 165.2(5) 7_666 . ?
O8W Na2 O4W 87.8(6) 5_676 . ?
O8W Na2 O5W 98.9(6) 5_676 7_666 ?
O8W Na2 O18 94.4(4) 5_676 . ?
W3 O1 Na2 139.4(4) . 4_646 ?
W3 O4 W1 150.6(3) . . ?
W3 O5 W2 150.6(3) . . ?
W1 O6 W2 154.9(4) . . ?
W3 O7 W6 122.2(3) . . ?
W1 O8 W5 121.9(3) . . ?
W1 O9 W4 123.9(3) . . ?
W2 O10 W7 123.1(3) . . ?
W2 O11 W8 123.7(3) . . ?
As1 O13 W2 131.1(3) . . ?
As1 O13 W7 120.4(3) . . ?
As1 O13 W8 120.1(3) . . ?
W7 O13 W2 91.0(2) . . ?
W7 O13 W8 93.20(19) . . ?
W8 O13 W2 91.3(2) . . ?
As1 O14 W3 132.3(3) . . ?
As1 O14 W6 115.1(3) . . ?
As1 O14 W11 124.8(3) . 2_656 ?
W3 O14 W11 89.29(19) . 2_656 ?
W6 O14 W3 93.1(2) . . ?
W6 O14 W11 91.9(2) . 2_656 ?
W5 O16 W6 144.6(3) . . ?
W5 O18 Na2 137.1(4) . . ?
W5 O19 Rh1 135.0(3) . . ?
W6 O20 Rh1 136.2(3) . . ?
W4 O21 W5 122.6(3) . . ?
As1 O23 W1 132.8(3) . . ?
As1 O23 W4 124.4(3) . . ?
As1 O23 W5 114.8(3) . . ?
W1 O23 W4 88.73(18) . . ?
W5 O23 W1 93.62(18) . . ?
W5 O23 W4 92.4(2) . . ?
W7 O25 Na1 95.5(2) . . ?
W7 O25 W8 122.0(3) . . ?
W8 O25 Na1 93.4(2) . . ?
W8 O26 W4 148.7(3) . . ?
W4 O27 W9 160.4(4) . . ?
W8 O28 Na1 108.7(3) . . ?
W8 O28 W9 145.4(3) . . ?
W9 O28 Na1 102.6(2) . . ?
W7 O29 Na1 106.4(3) . . ?
W7 O29 W10 148.3(3) . 2_656 ?
W10 O29 Na1 101.9(2) 2_656 . ?
C4 O30 W9 135.7(6) . . ?
W9 O31 Rh1 147.8(3) . . ?
W11 O32 W7 148.3(4) . 2_656 ?
W3 O33 W11 123.7(3) 2_656 . ?
W11 O35 W6 122.3(3) . 2_656 ?
W11 O36 W10 157.7(4) . . ?
W10 O38 Rh1 149.0(4) . 2_656 ?
C4 O39 W10 135.0(6) . . ?
W9 O40 Na1 107.8(2) . . ?
W10 O40 Na1 109.6(2) . . ?
W10 O40 W9 137.2(3) . . ?
N1 Rh1 As1 168.4(2) . . ?
O19 Rh1 As1 86.37(17) . . ?
O19 Rh1 N1 85.7(3) . . ?
O20 Rh1 As1 86.30(18) . . ?
O20 Rh1 N1 84.6(3) . . ?
O20 Rh1 O19 84.8(2) . . ?
O31 Rh1 As1 97.41(18) . . ?
O31 Rh1 N1 91.8(3) . . ?
O31 Rh1 O19 96.3(2) . . ?
O31 Rh1 O20 176.2(3) . . ?
O38 Rh1 As1 97.04(19) 2_656 . ?
O38 Rh1 N1 91.0(3) 2_656 . ?
O38 Rh1 O19 176.6(3) 2_656 . ?
O38 Rh1 O20 95.3(2) 2_656 . ?
O38 Rh1 O31 83.3(2) 2_656 . ?
O2 W1 O4 101.0(3) . . ?
O2 W1 O6 103.2(3) . . ?
O2 W1 O8 101.7(3) . . ?
O2 W1 O9 100.3(3) . . ?
O2 W1 O23 171.3(3) . . ?
O4 W1 O23 84.4(2) . . ?
O6 W1 O4 84.7(3) . . ?
O6 W1 O8 154.7(3) . . ?
O6 W1 O23 84.0(2) . . ?
O8 W1 O4 86.2(3) . . ?
O8 W1 O23 71.7(2) . . ?
O9 W1 O4 158.7(2) . . ?
O9 W1 O6 89.6(3) . . ?
O9 W1 O8 90.3(3) . . ?
O9 W1 O23 74.5(2) . . ?
O3 W2 O5 101.5(3) . . ?
O3 W2 O6 101.6(3) . . ?
O3 W2 O10 101.6(3) . . ?
O3 W2 O11 101.6(3) . . ?
O3 W2 O13 171.3(2) . . ?
O5 W2 O13 84.8(2) . . ?
O6 W2 O5 83.4(2) . . ?
O6 W2 O13 85.1(2) . . ?
O10 W2 O5 87.3(2) . . ?
O10 W2 O6 156.4(3) . . ?
O10 W2 O13 72.5(2) . . ?
O11 W2 O5 156.8(3) . . ?
O11 W2 O6 90.5(2) . . ?
O11 W2 O10 89.7(2) . . ?
O11 W2 O13 72.4(2) . . ?
O1 W3 O4 101.0(3) . . ?
O1 W3 O5 102.6(3) . . ?
O1 W3 O7 101.1(3) . . ?
O1 W3 O14 170.4(3) . . ?
O1 W3 O33 98.6(3) . 2_656 ?
O4 W3 O14 86.1(2) . . ?
O4 W3 O33 160.4(3) . 2_656 ?
O5 W3 O4 87.5(3) . . ?
O5 W3 O14 84.0(2) . . ?
O5 W3 O33 87.4(3) . 2_656 ?
O7 W3 O4 89.3(3) . . ?
O7 W3 O5 156.3(2) . . ?
O7 W3 O14 72.3(2) . . ?
O7 W3 O33 87.8(3) . 2_656 ?
O33 W3 O14 74.6(2) 2_656 . ?
O9 W4 O23 72.8(2) . . ?
O21 W4 O9 88.0(3) . . ?
O21 W4 O23 71.4(2) . . ?
O21 W4 O26 152.7(2) . . ?
O22 W4 O9 97.7(3) . . ?
O22 W4 O21 102.1(3) . . ?
O22 W4 O23 168.3(2) . . ?
O22 W4 O26 105.3(3) . . ?
O22 W4 O27 100.2(3) . . ?
O26 W4 O9 87.6(2) . . ?
O26 W4 O23 81.5(2) . . ?
O27 W4 O9 162.0(2) . . ?
O27 W4 O21 90.6(3) . . ?
O27 W4 O23 89.8(2) . . ?
O27 W4 O26 85.4(3) . . ?
O8 W5 O23 72.7(2) . . ?
O16 W5 O8 84.9(3) . . ?
O16 W5 O21 158.7(3) . . ?
O16 W5 O23 86.0(2) . . ?
O18 W5 O8 97.7(3) . . ?
O18 W5 O16 102.1(3) . . ?
O18 W5 O19 104.9(3) . . ?
O18 W5 O21 97.2(3) . . ?
O18 W5 O23 167.1(3) . . ?
O19 W5 O8 157.3(2) . . ?
O19 W5 O16 91.2(3) . . ?
O19 W5 O21 92.5(2) . . ?
O19 W5 O23 84.7(2) . . ?
O21 W5 O8 83.7(2) . . ?
O21 W5 O23 73.5(2) . . ?
O7 W6 O14 72.4(2) . . ?
O7 W6 O35 84.1(3) . 2_656 ?
O16 W6 O7 84.6(3) . . ?
O16 W6 O14 85.1(2) . . ?
O16 W6 O35 158.5(3) . 2_656 ?
O17 W6 O7 99.9(3) . . ?
O17 W6 O14 168.5(3) . . ?
O17 W6 O16 102.9(3) . . ?
O17 W6 O20 103.9(3) . . ?
O17 W6 O35 97.0(3) . 2_656 ?
O20 W6 O7 156.2(3) . . ?
O20 W6 O14 84.0(2) . . ?
O20 W6 O16 90.7(3) . . ?
O20 W6 O35 92.3(2) . 2_656 ?
O35 W6 O14 74.1(2) 2_656 . ?
O10 W7 Na1 138.71(18) . . ?
O10 W7 O13 73.4(2) . . ?
O12 W7 Na1 95.9(2) . . ?
O12 W7 O10 98.7(3) . . ?
O12 W7 O13 169.8(3) . . ?
O12 W7 O25 100.9(3) . . ?
O12 W7 O29 104.6(3) . . ?
O12 W7 O32 99.5(3) . 2_656 ?
O13 W7 Na1 86.59(14) . . ?
O25 W7 Na1 52.25(19) . . ?
O25 W7 O10 87.0(2) . . ?
O25 W7 O13 72.8(2) . . ?
O25 W7 O32 158.3(2) . 2_656 ?
O29 W7 Na1 44.31(19) . . ?
O29 W7 O10 156.1(2) . . ?
O29 W7 O13 84.0(2) . . ?
O29 W7 O25 93.8(3) . . ?
O29 W7 O32 88.3(3) . 2_656 ?
O32 W7 Na1 132.6(2) 2_656 . ?
O32 W7 O10 82.5(2) 2_656 . ?
O32 W7 O13 86.0(2) 2_656 . ?
O11 W8 Na1 137.32(17) . . ?
O11 W8 O13 72.6(2) . . ?
O13 W8 Na1 87.25(14) . . ?
O24 W8 Na1 95.1(2) . . ?
O24 W8 O11 98.0(3) . . ?
O24 W8 O13 167.8(3) . . ?
O24 W8 O25 100.0(3) . . ?
O24 W8 O26 100.6(3) . . ?
O24 W8 O28 105.7(3) . . ?
O25 W8 Na1 53.06(18) . . ?
O25 W8 O11 84.6(2) . . ?
O25 W8 O13 72.0(2) . . ?
O26 W8 Na1 132.2(2) . . ?
O26 W8 O11 84.7(2) . . ?
O26 W8 O13 86.4(2) . . ?
O26 W8 O25 157.9(2) . . ?
O28 W8 Na1 42.12(19) . . ?
O28 W8 O11 156.4(2) . . ?
O28 W8 O13 84.1(2) . . ?
O28 W8 O25 92.0(2) . . ?
O28 W8 O26 90.1(3) . . ?
O15 W9 Na1 139.3(2) . . ?
O15 W9 O27 98.2(3) . . ?
O15 W9 O28 166.5(3) . . ?
O15 W9 O30 89.0(3) . . ?
O15 W9 O31 102.3(3) . . ?
O15 W9 O40 97.6(3) . . ?
O27 W9 Na1 122.05(19) . . ?
O27 W9 O28 80.6(2) . . ?
O27 W9 O30 81.7(2) . . ?
O27 W9 O40 159.0(3) . . ?
O28 W9 Na1 42.17(16) . . ?
O30 W9 Na1 91.64(17) . . ?
O30 W9 O28 77.5(2) . . ?
O31 W9 Na1 82.88(19) . . ?
O31 W9 O27 92.0(3) . . ?
O31 W9 O28 91.3(3) . . ?
O31 W9 O30 167.9(3) . . ?
O31 W9 O40 98.0(3) . . ?
O40 W9 Na1 42.13(18) . . ?
O40 W9 O28 80.8(2) . . ?
O40 W9 O30 84.9(2) . . ?
O29 W10 Na1 43.68(16) 2_656 . ?
O29 W10 O39 78.8(2) 2_656 . ?
O36 W10 Na1 124.3(2) . . ?
O36 W10 O29 81.2(2) . 2_656 ?
O36 W10 O39 80.9(2) . . ?
O36 W10 O40 159.2(3) . . ?
O37 W10 Na1 138.4(2) . . ?
O37 W10 O29 166.4(3) . 2_656 ?
O37 W10 O36 96.9(3) . . ?
O37 W10 O38 101.7(3) . . ?
O37 W10 O39 87.6(3) . . ?
O37 W10 O40 97.8(3) . . ?
O38 W10 Na1 83.1(2) . . ?
O38 W10 O29 91.9(3) . 2_656 ?
O38 W10 O36 93.1(3) . . ?
O38 W10 O39 169.5(3) . . ?
O38 W10 O40 98.2(3) . . ?
O39 W10 Na1 93.14(17) . . ?
O40 W10 Na1 41.07(18) . . ?
O40 W10 O29 81.0(2) . 2_656 ?
O40 W10 O39 85.2(2) . . ?
O32 W11 O14 80.9(2) . 2_656 ?
O32 W11 O33 88.4(3) . . ?
O32 W11 O35 152.2(2) . . ?
O32 W11 O36 87.0(3) . . ?
O33 W11 O14 72.4(2) . 2_656 ?
O34 W11 O14 168.4(2) . 2_656 ?
O34 W11 O32 104.0(3) . . ?
O34 W11 O33 97.0(3) . . ?
O34 W11 O35 103.8(3) . . ?
O34 W11 O36 99.2(3) . . ?
O35 W11 O14 71.7(2) . 2_656 ?
O35 W11 O33 87.6(3) . . ?
O36 W11 O14 91.5(2) . 2_656 ?
O36 W11 O33 163.8(3) . . ?
O36 W11 O35 89.2(3) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
