# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_zx12a_zxl_5b_0m
_database_code_depnum_ccdc_archive 'CCDC 2102566'
loop_
_audit_author_name
_audit_author_address
'Xiaolin Zhu'
;Shaanxi Normal University
China
;
_audit_update_record             
;
2021-08-11 deposited with the CCDC.	2022-02-09 downloaded from the CCDC.
;
_audit_creation_date             2019-07-16
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C50 H32 N2'
_chemical_formula_sum            'C50 H32 N2'
_chemical_formula_weight         660.77
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.501(6)
_cell_length_b                   21.209(9)
_cell_length_c                   13.563(6)
_cell_angle_alpha                90
_cell_angle_beta                 98.118(14)
_cell_angle_gamma                90
_cell_volume                     3560(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    8874
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      31.32
_cell_measurement_theta_min      2.29
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.071
_exptl_absorpt_correction_T_max  0.9608
_exptl_absorpt_correction_T_min  0.8571
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0871 before and 0.0485 after correction.
The Ratio of minimum to maximum transmission is 0.8921.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.233
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1384
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0334
_diffrn_reflns_av_unetI/netI     0.0199
_diffrn_reflns_Laue_measured_fraction_full 0.983
_diffrn_reflns_Laue_measured_fraction_max 0.984
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            93709
_diffrn_reflns_point_group_measured_fraction_full 0.983
_diffrn_reflns_point_group_measured_fraction_max 0.984
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.731
_diffrn_reflns_theta_min         1.795
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5978
_reflns_number_total             7437
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'XS (Sheldrick, 2008)'
_refine_diff_density_max         0.300
_refine_diff_density_min         -0.238
_refine_diff_density_rms         0.044
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     469
_refine_ls_number_reflns         7437
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0596
_refine_ls_R_factor_gt           0.0452
_refine_ls_restrained_S_all      1.026
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0588P)²+1.8747P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1167
_refine_ls_wR_factor_ref         0.1250
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Ternary CH refined with riding coordinates:
 C20(H20), C29(H29)
2.b Aromatic/amide H refined with riding coordinates:
 C11(H11), C15(H15), C17(H17), C18(H18), C23(H23), C25(H25), C27(H27),
 C28(H28), C30(H30), C31(H31), C32(H32), C33(H33), C34(H34), C35(H35), C36(H36),
  C38(H38), C39(H39), C40(H40), C41(H41), C42(H42), C43(H43), C44(H44),
 C45(H45), C46(H46), C47(H47), C48(H48), C49(H49), C50(H50), C51(H51), C52(H52)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
N1 N 0.78069(9) 0.16549(6) 0.97504(9) 0.0203(3) Uani 1 1 d . . . . .
N2 N 1.00024(9) 0.20636(6) 1.29758(9) 0.0196(3) Uani 1 1 d . . . . .
C3 C 0.81660(11) 0.27730(7) 1.02842(11) 0.0181(3) Uani 1 1 d . . . . .
C4 C 1.04057(11) 0.24819(7) 1.36641(11) 0.0186(3) Uani 1 1 d . . . . .
C5 C 0.97653(11) 0.34245(7) 1.27063(11) 0.0180(3) Uani 1 1 d . . . . .
C6 C 0.72036(11) 0.18897(7) 0.89362(11) 0.0205(3) Uani 1 1 d . . . . .
C7 C 0.83061(11) 0.20995(7) 1.04416(11) 0.0184(3) Uani 1 1 d . . . . .
C8 C 0.73597(11) 0.36905(7) 0.91641(11) 0.0206(3) Uani 1 1 d . . . . .
C9 C 0.94262(11) 0.23114(7) 1.20886(11) 0.0184(3) Uani 1 1 d . . . . .
C10 C 0.96164(11) 0.41230(7) 1.25521(11) 0.0189(3) Uani 1 1 d . . . . .
C11 C 0.89437(11) 0.18880(7) 1.13355(11) 0.0192(3) Uani 1 1 d . . . . .
H11 H 0.904953 0.145713 1.143199 0.023 Uiso 1 1 calc R . . . .
C12 C 0.92848(11) 0.29838(7) 1.19258(11) 0.0177(3) Uani 1 1 d . . . . .
C13 C 0.65159(11) 0.15269(7) 0.81276(11) 0.0218(3) Uani 1 1 d . . . . .
C14 C 0.75174(11) 0.29998(7) 0.93623(11) 0.0187(3) Uani 1 1 d . . . . .
C15 C 0.86606(11) 0.31911(7) 1.10263(11) 0.0188(3) Uani 1 1 d . . . . .
H15 H 0.857287 0.362233 1.091995 0.023 Uiso 1 1 calc R . . . .
C16 C 1.03199(11) 0.31634(7) 1.35701(11) 0.0182(3) Uani 1 1 d . . . . .
C17 C 0.90910(12) 0.44790(7) 1.32234(11) 0.0221(3) Uani 1 1 d . . . . .
H17 H 0.884862 0.428384 1.376472 0.026 Uiso 1 1 calc R . . . .
C18 C 0.63364(12) 0.08760(7) 0.80091(12) 0.0246(3) Uani 1 1 d . . . . .
H18 H 0.669628 0.058932 0.845761 0.029 Uiso 1 1 calc R . . . .
C19 C 0.70502(11) 0.25523(7) 0.86950(11) 0.0206(3) Uani 1 1 d . . . . .
C20 C 1.09111(11) 0.34792(7) 1.45329(11) 0.0194(3) Uani 1 1 d . . . . .
H20 H 1.039108 0.372316 1.485428 0.023 Uiso 1 1 calc R . . . .
C21 C 1.12993(11) 0.29056(7) 1.51888(11) 0.0201(3) Uani 1 1 d . . . . .
C22 C 1.18635(12) 0.39049(7) 1.43611(11) 0.0213(3) Uani 1 1 d . . . . .
C23 C 0.98227(12) 0.50793(7) 1.15778(12) 0.0266(3) Uani 1 1 d . . . . .
H23 H 1.005952 0.527635 1.103546 0.032 Uiso 1 1 calc R . . . .
C24 C 1.10248(11) 0.23358(7) 1.46729(11) 0.0198(3) Uani 1 1 d . . . . .
C25 C 0.89374(13) 0.51302(7) 1.30667(12) 0.0272(3) Uani 1 1 d . . . . .
H25 H 0.858648 0.536412 1.350456 0.033 Uiso 1 1 calc R . . . .
C26 C 0.59592(12) 0.19587(7) 0.74310(11) 0.0230(3) Uani 1 1 d . . . . .
C27 C 0.93085(13) 0.54322(7) 1.22548(13) 0.0274(3) Uani 1 1 d . . . . .
H27 H 0.921423 0.586443 1.216574 0.033 Uiso 1 1 calc R . . . .
C28 C 0.52041(12) 0.17488(8) 0.66227(12) 0.0265(3) Uani 1 1 d . . . . .
H28 H 0.483145 0.203469 0.618087 0.032 Uiso 1 1 calc R . . . .
C29 C 0.62713(12) 0.26422(7) 0.77058(11) 0.0230(3) Uani 1 1 d . . . . .
H29 H 0.666883 0.282206 0.719954 0.028 Uiso 1 1 calc R . . . .
C30 C 0.77442(13) 0.39668(8) 0.83341(13) 0.0309(4) Uani 1 1 d . . . . .
H30 H 0.810559 0.372006 0.792008 0.037 Uiso 1 1 calc R . . . .
C31 C 0.99751(12) 0.44315(7) 1.17252(12) 0.0236(3) Uani 1 1 d . . . . .
H31 H 1.031499 0.419888 1.127778 0.028 Uiso 1 1 calc R . . . .
C32 C 0.50325(13) 0.11009(8) 0.65053(12) 0.0287(4) Uani 1 1 d . . . . .
H32 H 0.454596 0.095266 0.597365 0.034 Uiso 1 1 calc R . . . .
C33 C 0.55907(13) 0.06669(8) 0.71863(12) 0.0275(3) Uani 1 1 d . . . . .
H33 H 0.546686 0.023720 0.709311 0.033 Uiso 1 1 calc R . . . .
C34 C 0.68222(14) 0.40648(8) 0.97975(14) 0.0318(4) Uani 1 1 d . . . . .
H34 H 0.657506 0.388714 1.035018 0.038 Uiso 1 1 calc R . . . .
C35 C 1.13397(12) 0.17539(7) 1.51282(12) 0.0240(3) Uani 1 1 d . . . . .
H35 H 1.115851 0.137593 1.479891 0.029 Uiso 1 1 calc R . . . .
C36 C 1.18965(12) 0.29051(8) 1.61606(12) 0.0246(3) Uani 1 1 d . . . . .
H36 H 1.207273 0.328244 1.649347 0.029 Uiso 1 1 calc R . . . .
C37 C 0.53016(12) 0.30595(7) 0.78211(13) 0.0276(4) Uani 1 1 d . . . . .
C38 C 0.75858(14) 0.46053(9) 0.81320(16) 0.0410(5) Uani 1 1 d . . . . .
H38 H 0.784074 0.478626 0.758558 0.049 Uiso 1 1 calc R . . . .
C39 C 1.18229(14) 0.45592(8) 1.44967(12) 0.0275(3) Uani 1 1 d . . . . .
H39 H 1.119121 0.474465 1.464634 0.033 Uiso 1 1 calc R . . . .
C40 C 0.70450(15) 0.49701(9) 0.87510(19) 0.0474(5) Uani 1 1 d . . . . .
H40 H 0.693223 0.539622 0.861142 0.057 Uiso 1 1 calc R . . . .
C41 C 1.22171(12) 0.23260(8) 1.66117(12) 0.0279(4) Uani 1 1 d . . . . .
H41 H 1.261181 0.231844 1.724644 0.033 Uiso 1 1 calc R . . . .
C42 C 0.47043(13) 0.29534(9) 0.86186(14) 0.0367(4) Uani 1 1 d . . . . .
H42 H 0.489004 0.262304 0.906062 0.044 Uiso 1 1 calc R . . . .
C43 C 1.36674(15) 0.46623(10) 1.41632(14) 0.0406(5) Uani 1 1 d . . . . .
H43 H 1.426766 0.491166 1.410664 0.049 Uiso 1 1 calc R . . . .
C44 C 1.37079(14) 0.40132(9) 1.40022(14) 0.0369(4) Uani 1 1 d . . . . .
H44 H 1.432965 0.383132 1.382342 0.044 Uiso 1 1 calc R . . . .
C45 C 1.19410(12) 0.17569(8) 1.61030(12) 0.0274(3) Uani 1 1 d . . . . .
H45 H 1.215505 0.137605 1.640886 0.033 Uiso 1 1 calc R . . . .
C46 C 1.28150(13) 0.36368(8) 1.41097(12) 0.0288(4) Uani 1 1 d . . . . .
H46 H 1.285140 0.320363 1.401349 0.035 Uiso 1 1 calc R . . . .
C47 C 0.49989(15) 0.35527(8) 0.71373(16) 0.0407(5) Uani 1 1 d . . . . .
H47 H 0.538865 0.361746 0.661064 0.049 Uiso 1 1 calc R . . . .
C48 C 1.27253(16) 0.49369(9) 1.44091(13) 0.0377(4) Uani 1 1 d . . . . .
H48 H 1.269612 0.536947 1.451459 0.045 Uiso 1 1 calc R . . . .
C49 C 0.66637(16) 0.47058(9) 0.95877(17) 0.0446(5) Uani 1 1 d . . . . .
H49 H 0.630740 0.495715 0.999959 0.053 Uiso 1 1 calc R . . . .
C50 C 0.41290(16) 0.39415(9) 0.72402(19) 0.0503(6) Uani 1 1 d . . . . .
H50 H 0.392411 0.425984 0.678065 0.060 Uiso 1 1 calc R . . . .
C51 C 0.38330(15) 0.33474(11) 0.87397(17) 0.0524(6) Uani 1 1 d . . . . .
H51 H 0.343827 0.328314 0.926309 0.063 Uiso 1 1 calc R . . . .
C52 C 0.35621(16) 0.38447(10) 0.8054(2) 0.0597(7) Uani 1 1 d . . . . .
H52 H 0.299642 0.411395 0.814323 0.072 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N1 C6 1.342(2) . ?
N1 C7 1.4115(19) . ?
N2 C4 1.3342(19) . ?
N2 C9 1.4136(19) . ?
C3 C7 1.451(2) . ?
C3 C14 1.472(2) . ?
C3 C15 1.416(2) . ?
C4 C16 1.454(2) . ?
C4 C24 1.506(2) . ?
C5 C10 1.504(2) . ?
C5 C12 1.475(2) . ?
C5 C16 1.389(2) . ?
C6 C13 1.506(2) . ?
C6 C19 1.449(2) . ?
C7 C11 1.426(2) . ?
C8 C14 1.497(2) . ?
C8 C30 1.412(2) . ?
C8 C34 1.408(2) . ?
C9 C11 1.428(2) . ?
C9 C12 1.450(2) . ?
C10 C17 1.414(2) . ?
C10 C31 1.424(2) . ?
C12 C15 1.422(2) . ?
C13 C18 1.404(2) . ?
C13 C26 1.425(2) . ?
C14 C19 1.383(2) . ?
C16 C20 1.558(2) . ?
C17 C25 1.407(2) . ?
C18 C33 1.420(2) . ?
C19 C29 1.554(2) . ?
C20 C21 1.544(2) . ?
C20 C22 1.538(2) . ?
C21 C24 1.414(2) . ?
C21 C36 1.420(2) . ?
C22 C39 1.402(2) . ?
C22 C46 1.403(2) . ?
C23 C27 1.408(2) . ?
C23 C31 1.398(2) . ?
C24 C35 1.411(2) . ?
C25 C27 1.408(2) . ?
C26 C28 1.414(2) . ?
C26 C29 1.533(2) . ?
C28 C32 1.396(2) . ?
C29 C37 1.527(2) . ?
C30 C38 1.390(3) . ?
C32 C33 1.416(2) . ?
C34 C49 1.397(2) . ?
C35 C45 1.426(2) . ?
C36 C41 1.405(2) . ?
C37 C42 1.416(3) . ?
C37 C47 1.414(3) . ?
C38 C40 1.386(3) . ?
C39 C48 1.402(2) . ?
C40 C49 1.408(3) . ?
C41 C45 1.409(2) . ?
C42 C51 1.401(3) . ?
C43 C44 1.396(3) . ?
C43 C48 1.396(3) . ?
C44 C46 1.397(2) . ?
C47 C50 1.387(3) . ?
C50 C52 1.409(4) . ?
C51 C52 1.415(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 N1 C7 116.29(12) . . ?
C4 N2 C9 116.43(12) . . ?
C7 C3 C14 119.16(12) . . ?
C15 C3 C7 118.70(13) . . ?
C15 C3 C14 122.14(13) . . ?
N2 C4 C16 125.73(13) . . ?
N2 C4 C24 126.43(13) . . ?
C16 C4 C24 107.84(12) . . ?
C12 C5 C10 119.63(12) . . ?
C16 C5 C10 123.16(13) . . ?
C16 C5 C12 117.18(13) . . ?
N1 C6 C13 127.32(14) . . ?
N1 C6 C19 125.92(13) . . ?
C19 C6 C13 106.70(13) . . ?
N1 C7 C3 121.81(13) . . ?
N1 C7 C11 119.75(13) . . ?
C11 C7 C3 118.43(12) . . ?
C30 C8 C14 119.87(14) . . ?
C34 C8 C14 120.27(14) . . ?
C34 C8 C30 119.85(15) . . ?
N2 C9 C11 119.20(13) . . ?
N2 C9 C12 122.13(12) . . ?
C11 C9 C12 118.65(13) . . ?
C17 C10 C5 119.73(13) . . ?
C17 C10 C31 119.23(14) . . ?
C31 C10 C5 121.02(13) . . ?
C7 C11 C9 122.63(13) . . ?
C9 C12 C5 119.03(13) . . ?
C15 C12 C5 122.58(13) . . ?
C15 C12 C9 118.36(12) . . ?
C18 C13 C6 130.65(14) . . ?
C18 C13 C26 120.05(14) . . ?
C26 C13 C6 109.24(13) . . ?
C3 C14 C8 121.00(12) . . ?
C19 C14 C3 117.57(13) . . ?
C19 C14 C8 121.43(13) . . ?
C3 C15 C12 123.21(13) . . ?
C4 C16 C20 109.49(12) . . ?
C5 C16 C4 119.48(13) . . ?
C5 C16 C20 131.03(13) . . ?
C25 C17 C10 119.53(14) . . ?
C13 C18 C33 118.27(15) . . ?
C6 C19 C29 111.13(12) . . ?
C14 C19 C6 119.19(13) . . ?
C14 C19 C29 129.50(14) . . ?
C21 C20 C16 102.55(12) . . ?
C22 C20 C16 114.28(12) . . ?
C22 C20 C21 111.27(12) . . ?
C24 C21 C20 110.71(13) . . ?
C24 C21 C36 121.17(14) . . ?
C36 C21 C20 128.06(13) . . ?
C39 C22 C20 121.21(14) . . ?
C39 C22 C46 118.73(14) . . ?
C46 C22 C20 119.99(14) . . ?
C31 C23 C27 119.66(15) . . ?
C21 C24 C4 109.35(12) . . ?
C35 C24 C4 130.80(13) . . ?
C35 C24 C21 119.85(14) . . ?
C17 C25 C27 120.79(15) . . ?
C13 C26 C29 111.27(13) . . ?
C28 C26 C13 121.47(14) . . ?
C28 C26 C29 127.24(14) . . ?
C25 C27 C23 119.96(14) . . ?
C32 C28 C26 118.24(15) . . ?
C26 C29 C19 101.58(12) . . ?
C37 C29 C19 113.10(13) . . ?
C37 C29 C26 113.24(12) . . ?
C38 C30 C8 120.41(17) . . ?
C23 C31 C10 120.82(14) . . ?
C28 C32 C33 120.78(14) . . ?
C32 C33 C18 121.19(15) . . ?
C49 C34 C8 119.37(16) . . ?
C24 C35 C45 118.68(14) . . ?
C41 C36 C21 119.02(14) . . ?
C42 C37 C29 119.86(15) . . ?
C47 C37 C29 120.31(16) . . ?
C47 C37 C42 119.83(16) . . ?
C40 C38 C30 119.50(17) . . ?
C22 C39 C48 120.67(16) . . ?
C38 C40 C49 121.04(17) . . ?
C36 C41 C45 120.03(14) . . ?
C51 C42 C37 119.8(2) . . ?
C48 C43 C44 119.96(16) . . ?
C43 C44 C46 120.01(17) . . ?
C41 C45 C35 121.24(14) . . ?
C44 C46 C22 120.74(16) . . ?
C50 C47 C37 121.0(2) . . ?
C43 C48 C39 119.86(17) . . ?
C34 C49 C40 119.81(18) . . ?
C47 C50 C52 118.7(2) . . ?
C42 C51 C52 119.0(2) . . ?
C50 C52 C51 121.56(18) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
