# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_audit_block_doi                 10.25505/fiz.icsd.cc2665j4
_database_code_depnum_ccdc_archive 'CCDC 2031725'
loop_
_audit_author_name
_audit_author_address
'Simeon Ponou'
;UNIVERSITY STOCKHOLM
Sweden
;
_audit_update_record             
;
2021-01-07 deposited with the CCDC.	2021-02-19 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_EXPT005_shelx               
;
PROBLEM: _exptl_crystal_description is missing
RESPONSE: dark silver
;
# Added during the CSD deposition process: Thursday 07 January 2021 05:12 PM
# end Validation Reply Form


_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        'tricalcium cupper trigermanide'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'Ca3  Cu1  Ge3  Cd0'
_chemical_formula_sum            'Ca3 Cu Ge3'
_chemical_formula_weight         401.55

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ca Ca 0.2262 0.3064 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_H-M_alt        'C 2/m'
_space_group_name_Hall           '-C 2y'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'

_cell_length_a                   10.67010(10)
_cell_length_b                   4.44520(10)
_cell_length_c                   14.2961(2)
_cell_angle_alpha                90
_cell_angle_beta                 110.7290(10)
_cell_angle_gamma                90
_cell_volume                     634.179(18)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    0
_cell_measurement_theta_min      0
_cell_measurement_theta_max      0

_exptl_crystal_description       block
_exptl_crystal_colour            'dark silver'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    4.206
_exptl_crystal_F_000             740
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0
_exptl_crystal_size_mid          0
_exptl_crystal_size_min          0
_exptl_absorpt_coefficient_mu    19.673
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            15281
_diffrn_reflns_av_unetI/netI     0.0189
_diffrn_reflns_av_R_equivalents  0.0319
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.523
_diffrn_reflns_theta_max         36.528
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             1689
_reflns_number_gt                1549
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Ortep for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0351P)²+1.3603P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.0056(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         1689
_refine_ls_number_parameters     44
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0244
_refine_ls_R_factor_gt           0.0210
_refine_ls_wR_factor_ref         0.0599
_refine_ls_wR_factor_gt          0.0587
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.74971(4) 0.000000 0.10421(3) 0.01118(8) Uani 1 2 d S T P . .
Ge1 Ge 0.12930(3) 0.000000 0.04364(2) 0.00933(7) Uani 1 2 d S T P . .
Ge2 Ge 0.95816(3) 0.000000 0.26702(2) 0.00833(7) Uani 1 2 d S T P . .
Ge3 Ge 0.89122(3) 0.000000 0.42437(2) 0.00777(7) Uani 1 2 d S T P . .
Ca1 Ca 0.45711(6) 0.000000 0.11592(4) 0.01032(10) Uani 1 2 d S T P . .
Ca2 Ca 0.25305(5) 0.000000 0.27113(4) 0.00920(10) Uani 1 2 d S T P . .
Ca3 Ca 0.60004(5) 0.000000 0.42062(4) 0.00857(9) Uani 1 2 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 Ge1 2.5599(2) 3_545 ?
Cu1 Ge1 2.5599(2) 3 ?
Cu1 Ge2 2.5884(5) . ?
Cu1 Ge1 2.8399(5) 5_655 ?
Cu1 Ca1 3.0989(5) 3 ?
Cu1 Ca1 3.0989(5) 3_545 ?
Cu1 Ca1 3.1396(7) 5_655 ?
Cu1 Ca1 3.1852(7) . ?
Cu1 Ca2 3.2520(5) 3 ?
Cu1 Ca2 3.2520(5) 3_545 ?
Ge1 Ge1 2.5949(6) 5 ?
Ge1 Ca2 3.0463(6) . ?
Ge1 Ca1 3.0829(4) 7_545 ?
Ge1 Ca1 3.0829(4) 7 ?
Ge1 Ca1 3.2752(5) 3_445 ?
Ge1 Ca1 3.2752(5) 3_455 ?
Ge1 Ca1 3.2777(7) . ?
Ge2 Ge3 2.5899(4) . ?
Ge2 Ca1 3.0967(4) 3_545 ?
Ge2 Ca1 3.0967(4) 3 ?
Ge2 Ca3 3.1145(4) 3 ?
Ge2 Ca3 3.1145(4) 3_545 ?
Ge2 Ca2 3.1263(6) 1_655 ?
Ge2 Ca2 3.1343(4) 3_545 ?
Ge2 Ca2 3.1343(4) 3 ?
Ge3 Ge3 2.5518(6) 5_756 ?
Ge3 Ca3 3.0884(6) . ?
Ge3 Ca2 3.1027(4) 3_545 ?
Ge3 Ca2 3.1027(4) 3 ?
Ge3 Ca3 3.1166(4) 7_656 ?
Ge3 Ca3 3.1166(4) 7_646 ?
Ge3 Ca3 3.1610(4) 3 ?
Ge3 Ca3 3.1610(4) 3_545 ?
Ca1 Ca2 3.6173(8) . ?
Ca2 Ca3 3.5600(8) . ?
Ca2 Ca3 3.8266(7) 3_455 ?
Ca2 Ca3 3.8266(7) 3_445 ?
Ca3 Ca3 3.6248(11) 5_656 ?
Ca3 Ca3 3.8976(9) 7_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ge1 Cu1 Ge1 120.512(18) 3_545 3 ?
Ge1 Cu1 Ge2 118.217(9) 3_545 . ?
Ge1 Cu1 Ge2 118.217(9) 3 . ?
Ge1 Cu1 Ge1 93.107(12) 3_545 5_655 ?
Ge1 Cu1 Ge1 93.107(12) 3 5_655 ?
Ge2 Cu1 Ge1 101.363(15) . 5_655 ?
Ge1 Cu1 Ca1 154.734(18) 3_545 3 ?
Ge1 Cu1 Ca1 70.055(11) 3 3 ?
Ge2 Cu1 Ca1 65.262(12) . 3 ?
Ge1 Cu1 Ca1 62.366(12) 5_655 3 ?
Ge1 Cu1 Ca1 70.055(11) 3_545 3_545 ?
Ge1 Cu1 Ca1 154.734(18) 3 3_545 ?
Ge2 Cu1 Ca1 65.262(12) . 3_545 ?
Ge1 Cu1 Ca1 62.366(12) 5_655 3_545 ?
Ca1 Cu1 Ca1 91.652(18) 3 3_545 ?
Ge1 Cu1 Ca1 64.557(10) 3_545 5_655 ?
Ge1 Cu1 Ca1 64.557(10) 3 5_655 ?
Ge2 Cu1 Ca1 167.63(2) . 5_655 ?
Ge1 Cu1 Ca1 66.263(15) 5_655 5_655 ?
Ca1 Cu1 Ca1 106.819(15) 3 5_655 ?
Ca1 Cu1 Ca1 106.819(15) 3_545 5_655 ?
Ge1 Cu1 Ca1 68.520(11) 3_545 . ?
Ge1 Cu1 Ca1 68.520(11) 3 . ?
Ge2 Cu1 Ca1 119.932(18) . . ?
Ge1 Cu1 Ca1 138.706(17) 5_655 . ?
Ca1 Cu1 Ca1 133.764(10) 3 . ?
Ca1 Cu1 Ca1 133.763(10) 3_545 . ?
Ca1 Cu1 Ca1 72.443(18) 5_655 . ?
Ge1 Cu1 Ca2 135.679(18) 3_545 3 ?
Ge1 Cu1 Ca2 61.876(11) 3 3 ?
Ge2 Cu1 Ca2 63.729(12) . 3 ?
Ge1 Cu1 Ca2 131.020(11) 5_655 3 ?
Ca1 Cu1 Ca2 69.392(13) 3 3 ?
Ca1 Cu1 Ca2 128.933(17) 3_545 3 ?
Ca1 Cu1 Ca2 123.831(13) 5_655 3 ?
Ca1 Cu1 Ca2 73.608(14) . 3 ?
Ge1 Cu1 Ca2 61.876(11) 3_545 3_545 ?
Ge1 Cu1 Ca2 135.679(18) 3 3_545 ?
Ge2 Cu1 Ca2 63.729(12) . 3_545 ?
Ge1 Cu1 Ca2 131.020(11) 5_655 3_545 ?
Ca1 Cu1 Ca2 128.933(17) 3 3_545 ?
Ca1 Cu1 Ca2 69.392(13) 3_545 3_545 ?
Ca1 Cu1 Ca2 123.831(13) 5_655 3_545 ?
Ca1 Cu1 Ca2 73.608(14) . 3_545 ?
Ca2 Cu1 Ca2 86.229(16) 3 3_545 ?
Cu1 Ge1 Cu1 120.512(18) 3_455 3_445 ?
Cu1 Ge1 Ge1 118.922(9) 3_455 5 ?
Cu1 Ge1 Ge1 118.922(9) 3_445 5 ?
Cu1 Ge1 Cu1 86.893(12) 3_455 5_655 ?
Cu1 Ge1 Cu1 86.893(12) 3_445 5_655 ?
Ge1 Ge1 Cu1 109.160(18) 5 5_655 ?
Cu1 Ge1 Ca2 70.300(11) 3_455 . ?
Cu1 Ge1 Ca2 70.300(11) 3_445 . ?
Ge1 Ge1 Ca2 119.91(2) 5 . ?
Cu1 Ge1 Ca2 130.927(16) 5_655 . ?
Cu1 Ge1 Ca1 149.214(17) 3_455 7_545 ?
Cu1 Ge1 Ca1 66.870(11) 3_445 7_545 ?
Ge1 Ge1 Ca1 69.851(14) 5 7_545 ?
Cu1 Ge1 Ca1 62.937(12) 5_655 7_545 ?
Ca2 Ge1 Ca1 133.868(8) . 7_545 ?
Cu1 Ge1 Ca1 66.870(11) 3_455 7 ?
Cu1 Ge1 Ca1 149.214(17) 3_445 7 ?
Ge1 Ge1 Ca1 69.851(14) 5 7 ?
Cu1 Ge1 Ca1 62.937(12) 5_655 7 ?
Ca2 Ge1 Ca1 133.868(8) . 7 ?
Ca1 Ge1 Ca1 92.263(17) 7_545 7 ?
Cu1 Ge1 Ca1 138.846(16) 3_455 3_445 ?
Cu1 Ge1 Ca1 64.819(12) 3_445 3_445 ?
Ge1 Ge1 Ca1 62.091(13) 5 3_445 ?
Cu1 Ge1 Ca1 133.495(9) 5_655 3_445 ?
Ca2 Ge1 Ca1 75.096(13) . 3_445 ?
Ca1 Ge1 Ca1 71.935(17) 7_545 3_445 ?
Ca1 Ge1 Ca1 131.942(11) 7 3_445 ?
Cu1 Ge1 Ca1 64.819(12) 3_455 3_455 ?
Cu1 Ge1 Ca1 138.846(17) 3_445 3_455 ?
Ge1 Ge1 Ca1 62.091(13) 5 3_455 ?
Cu1 Ge1 Ca1 133.495(9) 5_655 3_455 ?
Ca2 Ge1 Ca1 75.096(13) . 3_455 ?
Ca1 Ge1 Ca1 131.942(11) 7_545 3_455 ?
Ca1 Ge1 Ca1 71.935(17) 7 3_455 ?
Ca1 Ge1 Ca1 85.472(16) 3_445 3_455 ?
Cu1 Ge1 Ca1 62.712(10) 3_455 . ?
Cu1 Ge1 Ca1 62.712(10) 3_445 . ?
Ge1 Ge1 Ca1 170.42(2) 5 . ?
Cu1 Ge1 Ca1 61.260(14) 5_655 . ?
Ca2 Ge1 Ca1 69.667(15) . . ?
Ca1 Ge1 Ca1 103.862(14) 7_545 . ?
Ca1 Ge1 Ca1 103.862(14) 7 . ?
Ca1 Ge1 Ca1 123.762(13) 3_445 . ?
Ca1 Ge1 Ca1 123.762(13) 3_455 . ?
Cu1 Ge2 Ge3 111.573(16) . . ?
Cu1 Ge2 Ca1 65.349(13) . 3_545 ?
Ge3 Ge2 Ca1 132.213(9) . 3_545 ?
Cu1 Ge2 Ca1 65.349(13) . 3 ?
Ge3 Ge2 Ca1 132.213(9) . 3 ?
Ca1 Ge2 Ca1 91.734(16) 3_545 3 ?
Cu1 Ge2 Ca3 133.041(9) . 3 ?
Ge3 Ge2 Ca3 66.566(12) . 3 ?
Ca1 Ge2 Ca3 152.233(19) 3_545 3 ?
Ca1 Ge2 Ca3 81.979(11) 3 3 ?
Cu1 Ge2 Ca3 133.041(9) . 3_545 ?
Ge3 Ge2 Ca3 66.566(12) . 3_545 ?
Ca1 Ge2 Ca3 81.979(11) 3_545 3_545 ?
Ca1 Ge2 Ca3 152.233(19) 3 3_545 ?
Ca3 Ge2 Ca3 91.062(16) 3 3_545 ?
Cu1 Ge2 Ca2 123.755(17) . 1_655 ?
Ge3 Ge2 Ca2 124.672(16) . 1_655 ?
Ca1 Ge2 Ca2 76.595(14) 3_545 1_655 ?
Ca1 Ge2 Ca2 76.595(14) 3 1_655 ?
Ca3 Ge2 Ca2 75.639(13) 3 1_655 ?
Ca3 Ge2 Ca2 75.639(13) 3_545 1_655 ?
Cu1 Ge2 Ca2 68.494(12) . 3_545 ?
Ge3 Ge2 Ca2 64.830(11) . 3_545 ?
Ca1 Ge2 Ca2 70.972(13) 3_545 3_545 ?
Ca1 Ge2 Ca2 133.779(16) 3 3_545 ?
Ca3 Ge2 Ca2 131.393(16) 3 3_545 ?
Ca3 Ge2 Ca2 69.459(13) 3_545 3_545 ?
Ca2 Ge2 Ca2 134.786(8) 1_655 3_545 ?
Cu1 Ge2 Ca2 68.494(12) . 3 ?
Ge3 Ge2 Ca2 64.830(11) . 3 ?
Ca1 Ge2 Ca2 133.779(16) 3_545 3 ?
Ca1 Ge2 Ca2 70.972(13) 3 3 ?
Ca3 Ge2 Ca2 69.459(13) 3 3 ?
Ca3 Ge2 Ca2 131.393(16) 3_545 3 ?
Ca2 Ge2 Ca2 134.786(8) 1_655 3 ?
Ca2 Ge2 Ca2 90.327(16) 3_545 3 ?
Ge3 Ge3 Ge2 106.749(18) 5_756 . ?
Ge3 Ge3 Ca3 128.50(2) 5_756 . ?
Ge2 Ge3 Ca3 124.747(16) . . ?
Ge3 Ge3 Ca2 131.356(10) 5_756 3_545 ?
Ge2 Ge3 Ca2 66.104(12) . 3_545 ?
Ca3 Ge3 Ca2 76.354(14) . 3_545 ?
Ge3 Ge3 Ca2 131.356(10) 5_756 3 ?
Ge2 Ge3 Ca2 66.104(12) . 3 ?
Ca3 Ge3 Ca2 76.354(14) . 3 ?
Ca2 Ge3 Ca2 91.508(16) 3_545 3 ?
Ge3 Ge3 Ca3 66.929(12) 5_756 7_656 ?
Ge2 Ge3 Ca3 132.030(9) . 7_656 ?
Ca3 Ge3 Ca3 77.825(14) . 7_656 ?
Ca2 Ge3 Ca3 154.171(18) 3_545 7_656 ?
Ca2 Ge3 Ca3 83.014(11) 3 7_656 ?
Ge3 Ge3 Ca3 66.929(12) 5_756 7_646 ?
Ge2 Ge3 Ca3 132.030(9) . 7_646 ?
Ca3 Ge3 Ca3 77.825(14) . 7_646 ?
Ca2 Ge3 Ca3 83.014(11) 3_545 7_646 ?
Ca2 Ge3 Ca3 154.171(18) 3 7_646 ?
Ca3 Ge3 Ca3 90.983(16) 7_656 7_646 ?
Ge3 Ge3 Ca3 65.108(12) 5_756 3 ?
Ge2 Ge3 Ca3 64.692(12) . 3 ?
Ca3 Ge3 Ca3 135.278(8) . 3 ?
Ca2 Ge3 Ca3 130.793(16) 3_545 3 ?
Ca2 Ge3 Ca3 69.264(13) 3 3 ?
Ca3 Ge3 Ca3 70.532(17) 7_656 3 ?
Ca3 Ge3 Ca3 132.037(11) 7_646 3 ?
Ge3 Ge3 Ca3 65.108(12) 5_756 3_545 ?
Ge2 Ge3 Ca3 64.692(12) . 3_545 ?
Ca3 Ge3 Ca3 135.278(8) . 3_545 ?
Ca2 Ge3 Ca3 69.264(13) 3_545 3_545 ?
Ca2 Ge3 Ca3 130.793(16) 3 3_545 ?
Ca3 Ge3 Ca3 132.037(11) 7_656 3_545 ?
Ca3 Ge3 Ca3 70.532(16) 7_646 3_545 ?
Ca3 Ge3 Ca3 89.358(16) 3 3_545 ?
Ge1 Ca1 Ge1 92.264(17) 7_545 7 ?
Ge1 Ca1 Ge2 163.71(2) 7_545 3_455 ?
Ge1 Ca1 Ge2 85.698(6) 7 3_455 ?
Ge1 Ca1 Ge2 85.698(6) 7_545 3_445 ?
Ge1 Ca1 Ge2 163.71(2) 7 3_445 ?
Ge2 Ca1 Ge2 91.734(16) 3_455 3_445 ?
Ge1 Ca1 Cu1 54.697(10) 7_545 3_445 ?
Ge1 Ca1 Cu1 117.15(2) 7 3_445 ?
Ge2 Ca1 Cu1 112.249(19) 3_455 3_445 ?
Ge2 Ca1 Cu1 49.389(10) 3_445 3_445 ?
Ge1 Ca1 Cu1 117.15(2) 7_545 3_455 ?
Ge1 Ca1 Cu1 54.697(10) 7 3_455 ?
Ge2 Ca1 Cu1 49.389(10) 3_455 3_455 ?
Ge2 Ca1 Cu1 112.249(19) 3_445 3_455 ?
Cu1 Ca1 Cu1 91.653(18) 3_445 3_455 ?
Ge1 Ca1 Cu1 48.573(9) 7_545 5_655 ?
Ge1 Ca1 Cu1 48.573(9) 7 5_655 ?
Ge2 Ca1 Cu1 121.797(14) 3_455 5_655 ?
Ge2 Ca1 Cu1 121.797(14) 3_445 5_655 ?
Cu1 Ca1 Cu1 73.183(15) 3_445 5_655 ?
Cu1 Ca1 Cu1 73.183(15) 3_455 5_655 ?
Ge1 Ca1 Cu1 90.180(15) 7_545 . ?
Ge1 Ca1 Cu1 90.180(15) 7 . ?
Ge2 Ca1 Cu1 105.968(15) 3_455 . ?
Ge2 Ca1 Cu1 105.968(15) 3_445 . ?
Cu1 Ca1 Cu1 133.763(10) 3_445 . ?
Cu1 Ca1 Cu1 133.763(10) 3_455 . ?
Cu1 Ca1 Cu1 107.556(18) 5_655 . ?
Ge1 Ca1 Ge1 108.064(17) 7_545 3 ?
Ge1 Ca1 Ge1 48.057(11) 7 3 ?
Ge2 Ca1 Ge1 82.479(8) 3_455 3 ?
Ge2 Ca1 Ge1 147.48(2) 3_445 3 ?
Cu1 Ca1 Ge1 159.93(2) 3_445 3 ?
Cu1 Ca1 Ge1 88.043(8) 3_455 3 ?
Cu1 Ca1 Ge1 87.568(14) 5_655 3 ?
Cu1 Ca1 Ge1 46.661(9) . 3 ?
Ge1 Ca1 Ge1 48.057(11) 7_545 3_545 ?
Ge1 Ca1 Ge1 108.064(17) 7 3_545 ?
Ge2 Ca1 Ge1 147.48(2) 3_455 3_545 ?
Ge2 Ca1 Ge1 82.479(8) 3_445 3_545 ?
Cu1 Ca1 Ge1 88.043(7) 3_445 3_545 ?
Cu1 Ca1 Ge1 159.93(2) 3_455 3_545 ?
Cu1 Ca1 Ge1 87.568(14) 5_655 3_545 ?
Cu1 Ca1 Ge1 46.661(9) . 3_545 ?
Ge1 Ca1 Ge1 85.471(16) 3 3_545 ?
Ge1 Ca1 Ge1 76.139(14) 7_545 . ?
Ge1 Ca1 Ge1 76.139(14) 7 . ?
Ge2 Ca1 Ge1 87.699(14) 3_455 . ?
Ge2 Ca1 Ge1 87.699(14) 3_445 . ?
Cu1 Ca1 Ge1 47.234(9) 3_445 . ?
Cu1 Ca1 Ge1 47.234(9) 3_455 . ?
Cu1 Ca1 Ge1 52.480(13) 5_655 . ?
Cu1 Ca1 Ge1 160.04(2) . . ?
Ge1 Ca1 Ge1 123.762(13) 3 . ?
Ge1 Ca1 Ge1 123.762(13) 3_545 . ?
Ge1 Ca1 Ca2 111.502(16) 7_545 . ?
Ge1 Ca1 Ca2 111.502(16) 7 . ?
Ge2 Ca1 Ca2 54.999(11) 3_455 . ?
Ge2 Ca1 Ca2 54.999(11) 3_445 . ?
Cu1 Ca1 Ca2 57.298(12) 3_445 . ?
Cu1 Ca1 Ca2 57.298(12) 3_455 . ?
Cu1 Ca1 Ca2 104.64(2) 5_655 . ?
Cu1 Ca1 Ca2 147.81(2) . . ?
Ge1 Ca1 Ca2 136.071(9) 3 . ?
Ge1 Ca1 Ca2 136.071(9) 3_545 . ?
Ge1 Ca1 Ca2 52.156(13) . . ?
Ge1 Ca2 Ge3 132.213(10) . 3_455 ?
Ge1 Ca2 Ge3 132.213(10) . 3_445 ?
Ge3 Ca2 Ge3 91.508(16) 3_455 3_445 ?
Ge1 Ca2 Ge2 85.808(15) . 1_455 ?
Ge3 Ca2 Ge2 103.697(14) 3_455 1_455 ?
Ge3 Ca2 Ge2 103.697(14) 3_445 1_455 ?
Ge1 Ca2 Ge2 91.243(14) . 3_455 ?
Ge3 Ca2 Ge2 49.067(9) 3_455 3_455 ?
Ge3 Ca2 Ge2 111.148(17) 3_445 3_455 ?
Ge2 Ca2 Ge2 134.785(8) 1_455 3_455 ?
Ge1 Ca2 Ge2 91.243(14) . 3_445 ?
Ge3 Ca2 Ge2 111.148(17) 3_455 3_445 ?
Ge3 Ca2 Ge2 49.067(9) 3_445 3_445 ?
Ge2 Ca2 Ge2 134.785(8) 1_455 3_445 ?
Ge2 Ca2 Ge2 90.327(16) 3_455 3_445 ?
Ge1 Ca2 Cu1 47.825(9) . 3_445 ?
Ge3 Ca2 Cu1 152.47(2) 3_455 3_445 ?
Ge3 Ca2 Cu1 84.698(8) 3_445 3_445 ?
Ge2 Ca2 Cu1 103.692(14) 1_455 3_445 ?
Ge2 Ca2 Cu1 107.295(17) 3_455 3_445 ?
Ge2 Ca2 Cu1 47.777(9) 3_445 3_445 ?
Ge1 Ca2 Cu1 47.825(9) . 3_455 ?
Ge3 Ca2 Cu1 84.698(8) 3_455 3_455 ?
Ge3 Ca2 Cu1 152.47(2) 3_445 3_455 ?
Ge2 Ca2 Cu1 103.692(14) 1_455 3_455 ?
Ge2 Ca2 Cu1 47.777(9) 3_455 3_455 ?
Ge2 Ca2 Cu1 107.294(17) 3_445 3_455 ?
Cu1 Ca2 Cu1 86.229(16) 3_445 3_455 ?
Ge1 Ca2 Ca3 127.34(2) . . ?
Ge3 Ca2 Ca3 56.141(11) 3_455 . ?
Ge3 Ca2 Ca3 56.141(11) 3_445 . ?
Ge2 Ca2 Ca3 146.85(2) 1_455 . ?
Ge2 Ca2 Ca3 55.008(10) 3_455 . ?
Ge2 Ca2 Ca3 55.008(10) 3_445 . ?
Cu1 Ca2 Ca3 100.338(15) 3_445 . ?
Cu1 Ca2 Ca3 100.338(15) 3_455 . ?
Ge1 Ca2 Ca1 58.177(14) . . ?
Ge3 Ca2 Ca1 101.209(15) 3_455 . ?
Ge3 Ca2 Ca1 101.209(15) 3_445 . ?
Ge2 Ca2 Ca1 143.98(2) 1_455 . ?
Ge2 Ca2 Ca1 54.029(10) 3_455 . ?
Ge2 Ca2 Ca1 54.029(10) 3_445 . ?
Cu1 Ca2 Ca1 53.309(11) 3_445 . ?
Cu1 Ca2 Ca1 53.309(11) 3_455 . ?
Ca3 Ca2 Ca1 69.166(16) . . ?
Ge1 Ca2 Ca3 119.132(16) . 3_455 ?
Ge3 Ca2 Ca3 51.655(11) 3_455 3_455 ?
Ge3 Ca2 Ca3 102.225(17) 3_445 3_455 ?
Ge2 Ca2 Ca3 52.042(11) 1_455 3_455 ?
Ge2 Ca2 Ca3 92.141(9) 3_455 3_455 ?
Ge2 Ca2 Ca3 149.440(19) 3_445 3_455 ?
Cu1 Ca2 Ca3 155.61(2) 3_445 3_455 ?
Cu1 Ca2 Ca3 96.709(9) 3_455 3_455 ?
Ca3 Ca2 Ca3 102.908(17) . 3_455 ?
Ca1 Ca2 Ca3 144.198(7) . 3_455 ?
Ge1 Ca2 Ca3 119.132(16) . 3_445 ?
Ge3 Ca2 Ca3 102.225(17) 3_455 3_445 ?
Ge3 Ca2 Ca3 51.655(11) 3_445 3_445 ?
Ge2 Ca2 Ca3 52.042(11) 1_455 3_445 ?
Ge2 Ca2 Ca3 149.440(19) 3_455 3_445 ?
Ge2 Ca2 Ca3 92.141(9) 3_445 3_445 ?
Cu1 Ca2 Ca3 96.709(9) 3_445 3_445 ?
Cu1 Ca2 Ca3 155.61(2) 3_455 3_445 ?
Ca3 Ca2 Ca3 102.908(17) . 3_445 ?
Ca1 Ca2 Ca3 144.198(7) . 3_445 ?
Ca3 Ca2 Ca3 71.017(14) 3_455 3_445 ?
Ge3 Ca3 Ge2 104.312(14) . 3_445 ?
Ge3 Ca3 Ge2 104.312(14) . 3_455 ?
Ge2 Ca3 Ge2 91.062(16) 3_445 3_455 ?
Ge3 Ca3 Ge3 102.175(14) . 7_656 ?
Ge2 Ca3 Ge3 153.51(2) 3_445 7_656 ?
Ge2 Ca3 Ge3 82.943(7) 3_455 7_656 ?
Ge3 Ca3 Ge3 102.175(14) . 7_646 ?
Ge2 Ca3 Ge3 82.943(7) 3_445 7_646 ?
Ge2 Ca3 Ge3 153.51(2) 3_455 7_646 ?
Ge3 Ca3 Ge3 90.983(16) 7_656 7_646 ?
Ge3 Ca3 Ge3 135.279(8) . 3_445 ?
Ge2 Ca3 Ge3 48.742(9) 3_445 3_445 ?
Ge2 Ca3 Ge3 110.127(17) 3_455 3_445 ?
Ge3 Ca3 Ge3 109.466(16) 7_656 3_445 ?
Ge3 Ca3 Ge3 47.963(11) 7_646 3_445 ?
Ge3 Ca3 Ge3 135.279(8) . 3_455 ?
Ge2 Ca3 Ge3 110.127(17) 3_445 3_455 ?
Ge2 Ca3 Ge3 48.742(9) 3_455 3_455 ?
Ge3 Ca3 Ge3 47.963(11) 7_656 3_455 ?
Ge3 Ca3 Ge3 109.466(16) 7_646 3_455 ?
Ge3 Ca3 Ge3 89.357(16) 3_445 3_455 ?
Ge3 Ca3 Ca2 146.77(2) . . ?
Ge2 Ca3 Ca2 55.532(10) 3_445 . ?
Ge2 Ca3 Ca2 55.532(10) 3_455 . ?
Ge3 Ca3 Ca2 100.947(15) 7_656 . ?
Ge3 Ca3 Ca2 100.947(15) 7_646 . ?
Ge3 Ca3 Ca2 54.595(10) 3_445 . ?
Ge3 Ca3 Ca2 54.595(10) 3_455 . ?
Ge3 Ca3 Ca3 143.22(3) . 5_656 ?
Ge2 Ca3 Ca3 101.212(17) 3_445 5_656 ?
Ge2 Ca3 Ca3 101.212(17) 3_455 5_656 ?
Ge3 Ca3 Ca3 55.306(11) 7_656 5_656 ?
Ge3 Ca3 Ca3 55.306(11) 7_646 5_656 ?
Ge3 Ca3 Ca3 54.160(11) 3_445 5_656 ?
Ge3 Ca3 Ca3 54.160(11) 3_455 5_656 ?
Ca2 Ca3 Ca3 70.004(18) . 5_656 ?
Ge3 Ca3 Ca2 51.992(11) . 3_545 ?
Ge2 Ca3 Ca2 52.321(11) 3_445 3_545 ?
Ge2 Ca3 Ca2 102.577(17) 3_455 3_545 ?
Ge3 Ca3 Ca2 154.160(19) 7_656 3_545 ?
Ge3 Ca3 Ca2 94.105(8) 7_646 3_545 ?
Ge3 Ca3 Ca2 92.507(9) 3_445 3_545 ?
Ge3 Ca3 Ca2 149.38(2) 3_455 3_545 ?
Ca2 Ca3 Ca2 102.908(17) . 3_545 ?
Ca3 Ca3 Ca2 144.290(7) 5_656 3_545 ?
Ge3 Ca3 Ca2 51.992(11) . 3 ?
Ge2 Ca3 Ca2 102.577(17) 3_445 3 ?
Ge2 Ca3 Ca2 52.321(11) 3_455 3 ?
Ge3 Ca3 Ca2 94.105(8) 7_656 3 ?
Ge3 Ca3 Ca2 154.160(19) 7_646 3 ?
Ge3 Ca3 Ca2 149.38(2) 3_445 3 ?
Ge3 Ca3 Ca2 92.507(9) 3_455 3 ?
Ca2 Ca3 Ca2 102.908(17) . 3 ?
Ca3 Ca3 Ca2 144.290(7) 5_656 3 ?
Ca2 Ca3 Ca2 71.017(14) 3_545 3 ?
Ge3 Ca3 Ca3 51.411(13) . 7_656 ?
Ge2 Ca3 Ca3 155.72(2) 3_445 7_656 ?
Ge2 Ca3 Ca3 95.603(7) 3_455 7_656 ?
Ge3 Ca3 Ca3 50.764(10) 7_656 7_656 ?
Ge3 Ca3 Ca3 100.42(2) 7_646 7_656 ?
Ge3 Ca3 Ca3 146.05(2) 3_445 7_656 ?
Ge3 Ca3 Ca3 91.580(9) 3_455 7_656 ?
Ca2 Ca3 Ca3 144.556(10) . 7_656 ?
Ca3 Ca3 Ca3 100.34(2) 5_656 7_656 ?
Ca2 Ca3 Ca3 103.40(2) 3_545 7_656 ?
Ca2 Ca3 Ca3 64.489(13) 3 7_656 ?

_refine_diff_density_max         1.475
_refine_diff_density_min         -0.706
_refine_diff_density_rms         0.195


_exptl_crystal_recrystallization_method 'From the Melt'
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx_CCDC1
_audit_block_doi                 10.25505/fiz.icsd.cc2665k5
_database_code_depnum_ccdc_archive 'CCDC 2031726'
loop_
_audit_author_name
_audit_author_address
'Simeon Ponou'
;Department of Chemistry, Lund University 
Sweden
;
_audit_update_record             
;
2020-09-13 deposited with the CCDC.	2021-02-19 downloaded from the CCDC.
;

_audit_creation_date             2020-08-31T16:45:13-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4.5
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic

#----------------------------------------------------------------------------#
#                   CHEMICAL INFORMATION                                     #
#----------------------------------------------------------------------------#

_chemical_formula_moiety         'Ca5  Ge5  Ag1  Mn1'
_chemical_formula_sum            'Ag1.41 Ca5 Ge4.94 Mn0.64'
_chemical_formula_weight         746.98

#----------------------------------------------------------------------------#
#                   UNIT CELL INFORMATION                                    #
#----------------------------------------------------------------------------#

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P n m a'
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_Int_Tables_number      62
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   22.9432(9)
_cell_length_b                   4.4763(2)
_cell_length_c                   10.8109(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     1110.29(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    0
_cell_measurement_theta_min      0
_cell_measurement_theta_max      0
_cell_measurement_wavelength     0.71073

#----------------------------------------------------------------------------#
#                   CRYSTAL INFORMATION                                      #
#----------------------------------------------------------------------------#

_exptl_crystal_size_max          0
_exptl_crystal_size_mid          0
_exptl_crystal_size_min          0
_exptl_crystal_density_diffrn    4.469
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1363

#----------------------------------------------------------------------------#
#                   ABSORPTION CORRECTION                                    #
#----------------------------------------------------------------------------#

_exptl_absorpt_coefficient_mu    18.589
_exptl_absorpt_correction_type   none

#----------------------------------------------------------------------------#
#                   DATA COLLECTION                                          #
#----------------------------------------------------------------------------#

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_probe          x-ray
_diffrn_standards_number         0
_diffrn_standards_interval_time  .
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?
_diffrn_reflns_av_R_equivalents  0.036
_diffrn_reflns_av_unetI/netI     0.0324
_diffrn_reflns_number            12853
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         3.769
_diffrn_reflns_theta_max         32.302
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.938
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.938
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.938
_reflns_Friedel_coverage         0
_reflns_number_total             2068
_reflns_number_gt                1598
_reflns_threshold_expression     'I > 2σ(I)'

#----------------------------------------------------------------------------#
#                   COMPUTER PROGRAMS USED                                   #
#----------------------------------------------------------------------------#

_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Ortep for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'

#----------------------------------------------------------------------------#
#                   STRUCTURE SOLUTION                                       #
#----------------------------------------------------------------------------#


#----------------------------------------------------------------------------#
#                   REFINEMENT INFORMATION                                   #
#----------------------------------------------------------------------------#

_shelx_SHELXL_version_number     2018/3
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0250P)²+0.7090P] where P=(Fo²+2Fc²)/3'
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_coef       0.00262(11)
_refine_ls_number_reflns         2068
_refine_ls_number_parameters     77
_refine_ls_number_restraints     0
_refine_ls_number_constraints    0
_refine_ls_R_factor_all          0.0453
_refine_ls_R_factor_gt           0.0289
_refine_ls_wR_factor_ref         0.06
_refine_ls_wR_factor_gt          0.0576
_refine_ls_goodness_of_fit_ref   1.11
_refine_ls_restrained_S_all      1.11
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_diff_density_max         1.486
_refine_diff_density_min         -1.031
_refine_diff_density_rms         0.307

#----------------------------------------------------------------------------#
#                   CONSTRAINTS AND RESTRAINTS                               #
#----------------------------------------------------------------------------#


#----------------------------------------------------------------------------#
#                   ATOMIC TYPES, COORDINATES AND THERMAL PARAMETERS         #
#----------------------------------------------------------------------------#

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ca Ca 0.2262 0.3064 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.97463(2) 0.25 0.34373(5) 0.01037(14) Uani 1 2 d S T P . .
Ge2 Ge 0.92393(2) 0.25 0.95477(5) 0.01054(17) Uani 0.943(6) 2 d S T P . .
Ag' Ag 0.92393(2) 0.25 0.95477(5) 0.01054(17) Uani 0.057(6) 2 d S T P . .
Ge3 Ge 0.83494(2) 0.25 0.09700(5) 0.00837(13) Uani 1 2 d S T P . .
Ge4 Ge 0.74769(2) 0.25 0.94975(5) 0.00832(13) Uani 1 2 d S T P . .
Ge5 Ge 0.65723(2) 0.25 0.08989(5) 0.00935(13) Uani 1 2 d S T P . .
Mn1 Mn 0.02136(2) 0.25 0.11273(4) 0.01461(15) Uani 0.170(4) 2 d S T P . .
Ag1 Ag 0.02136(2) 0.25 0.11273(4) 0.01461(15) Uani 0.830(4) 2 d S T P . .
Ag2 Ag 0.55503(2) 0.25 0.96294(4) 0.01472(18) Uani 0.530(4) 2 d S T P . .
Mn2 Mn 0.55503(2) 0.25 0.96294(4) 0.01472(18) Uani 0.470(4) 2 d S T P . .
Ca1 Ca 0.07209(4) 0.25 0.83804(9) 0.0112(2) Uani 1 2 d S T P . .
Ca2 Ca 0.92922(4) 0.25 0.67001(9) 0.0113(2) Uani 1 2 d S T P . .
Ca3 Ca 0.16338(4) 0.25 0.11759(9) 0.0094(2) Uani 1 2 d S T P . .
Ca4 Ca 0.34188(4) 0.25 0.11440(9) 0.0100(2) Uani 1 2 d S T P . .
Ca5 Ca 0.25376(4) 0.25 0.83953(9) 0.0097(2) Uani 1 2 d S T P . .



#----------------------------------------------------------------------------#
#                   MOLECULAR GEOMETRY                                       #
#----------------------------------------------------------------------------#

_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 Ag2 2.6709(4) 2_664 ?
Ge1 Ag2 2.6709(4) 2_654 ?
Ge1 Mn1 2.7177(7) 1_655 ?
Ge1 Ag2 2.7876(7) 6_657 ?
Ge1 Ca4 3.0792(12) 6_656 ?
Ge1 Ca2 3.1460(8) 5_766 ?
Ge1 Ca2 3.1460(8) 5_756 ?
Ge1 Ca1 3.1654(8) 5_656 ?
Ge1 Ca1 3.1654(8) 5_666 ?
Ge1 Ca2 3.6781(11) . ?
Ge2 Ge3 2.5560(7) 1_556 ?
Ge2 Mn1 2.6678(4) 5_666 ?
Ge2 Mn1 2.6678(4) 5_656 ?
Ge2 Mn1 2.8130(7) 1_656 ?
Ge2 Ca2 3.0810(11) . ?
Ge2 Ca3 3.1038(8) 5_656 ?
Ge2 Ca3 3.1038(8) 5_666 ?
Ge2 Ca1 3.1677(8) 5_667 ?
Ge2 Ca1 3.1677(8) 5_657 ?
Ge2 Ca1 3.6258(12) 1_655 ?
Ge3 Ge4 2.5576(7) 1_554 ?
Ge3 Ca5 3.1018(8) 5_656 ?
Ge3 Ca5 3.1018(8) 5_666 ?
Ge3 Ca4 3.1240(11) 6_656 ?
Ge3 Ca1 3.1707(8) 5_666 ?
Ge3 Ca1 3.1707(8) 5_656 ?
Ge3 Ca3 3.2238(8) 5_655 ?
Ge3 Ca3 3.2238(8) 5_665 ?
Ge4 Ge5 2.5696(7) 1_556 ?
Ge4 Ca3 3.1150(8) 5_666 ?
Ge4 Ca3 3.1150(8) 5_656 ?
Ge4 Ca4 3.1166(8) 5_656 ?
Ge4 Ca4 3.1166(8) 5_666 ?
Ge4 Ca5 3.1304(11) 6_657 ?
Ge4 Ca5 3.1938(8) 5_667 ?
Ge4 Ca5 3.1938(8) 5_657 ?
Ge5 Ag2 2.7169(7) 1_554 ?
Ge5 Ca2 3.1134(8) 2_654 ?
Ge5 Ca2 3.1134(8) 2_664 ?
Ge5 Ca5 3.1244(8) 5_666 ?
Ge5 Ca5 3.1244(8) 5_656 ?
Ge5 Ca4 3.1445(8) 5_655 ?
Ge5 Ca4 3.1445(8) 5_665 ?
Ge5 Ca3 3.1656(11) 6_656 ?
Mn1 Ca1 3.1447(8) 5_556 ?
Mn1 Ca1 3.1447(8) 5_566 ?
Mn1 Ca1 3.1894(11) 1_554 ?
Mn1 Ca3 3.2587(11) . ?
Mn1 Ca2 3.4368(8) 5_666 ?
Mn1 Ca2 3.4368(8) 5_656 ?
Mn2 Ca2 3.1860(8) 2_665 ?
Mn2 Ca2 3.1860(8) 2_655 ?
Mn2 Ca2 3.2245(11) 6_557 ?
Mn2 Ca1 3.2774(11) 6_657 ?
Mn2 Ca4 3.3619(8) 5_666 ?
Mn2 Ca4 3.3619(8) 5_656 ?
Ca1 Ca3 3.6770(14) 1_556 ?
Ca2 Ca4 3.6701(14) 6_656 ?
Ca3 Ca5 3.6519(14) 1_554 ?
Ca3 Ca5 3.7922(11) 2_564 ?
Ca4 Ca5 3.5941(14) 1_554 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ge1 Ag2 113.85(3) 2_664 2_654 ?
Ag2 Ge1 Mn1 122.952(13) 2_664 1_655 ?
Ag2 Ge1 Mn1 122.952(13) 2_654 1_655 ?
Ag2 Ge1 Ag2 78.862(19) 2_664 6_657 ?
Ag2 Ge1 Ag2 78.862(19) 2_654 6_657 ?
Mn1 Ge1 Ag2 115.34(2) 1_655 6_657 ?
Ag2 Ge1 Ca4 71.156(18) 2_664 6_656 ?
Ag2 Ge1 Ca4 71.156(18) 2_654 6_656 ?
Mn1 Ge1 Ca4 121.69(3) 1_655 6_656 ?
Ag2 Ge1 Ca4 122.98(3) 6_657 6_656 ?
Ag2 Ge1 Ca2 66.752(19) 2_664 5_766 ?
Ag2 Ge1 Ca2 142.90(3) 2_654 5_766 ?
Mn1 Ge1 Ca2 71.34(2) 1_655 5_766 ?
Ag2 Ge1 Ca2 64.62(2) 6_657 5_766 ?
Ca4 Ge1 Ca2 134.466(15) 6_656 5_766 ?
Ag2 Ge1 Ca2 142.90(3) 2_664 5_756 ?
Ag2 Ge1 Ca2 66.752(19) 2_654 5_756 ?
Mn1 Ge1 Ca2 71.34(2) 1_655 5_756 ?
Ag2 Ge1 Ca2 64.62(2) 6_657 5_756 ?
Ca4 Ge1 Ca2 134.466(15) 6_656 5_756 ?
Ca2 Ge1 Ca2 90.70(3) 5_766 5_756 ?
Ag2 Ge1 Ca1 143.69(3) 2_664 5_656 ?
Ag2 Ge1 Ca1 67.714(18) 2_654 5_656 ?
Mn1 Ge1 Ca1 64.09(2) 1_655 5_656 ?
Ag2 Ge1 Ca1 133.592(16) 6_657 5_656 ?
Ca4 Ge1 Ca1 75.90(3) 6_656 5_656 ?
Ca2 Ge1 Ca1 135.33(3) 5_766 5_656 ?
Ca2 Ge1 Ca1 72.85(2) 5_756 5_656 ?
Ag2 Ge1 Ca1 67.714(18) 2_664 5_666 ?
Ag2 Ge1 Ca1 143.69(3) 2_654 5_666 ?
Mn1 Ge1 Ca1 64.09(2) 1_655 5_666 ?
Ag2 Ge1 Ca1 133.592(16) 6_657 5_666 ?
Ca4 Ge1 Ca1 75.90(3) 6_656 5_666 ?
Ca2 Ge1 Ca1 72.85(2) 5_766 5_666 ?
Ca2 Ge1 Ca1 135.33(3) 5_756 5_666 ?
Ca1 Ge1 Ca1 89.99(3) 5_656 5_666 ?
Ag2 Ge1 Ca2 57.658(14) 2_664 . ?
Ag2 Ge1 Ca2 57.658(14) 2_654 . ?
Mn1 Ge1 Ca2 173.22(3) 1_655 . ?
Ag2 Ge1 Ca2 57.89(2) 6_657 . ?
Ca4 Ge1 Ca2 65.09(3) 6_656 . ?
Ca2 Ge1 Ca2 104.12(2) 5_766 . ?
Ca2 Ge1 Ca2 104.12(2) 5_756 . ?
Ca1 Ge1 Ca2 119.96(2) 5_656 . ?
Ca1 Ge1 Ca2 119.96(2) 5_666 . ?
Ge3 Ge2 Mn1 122.709(12) 1_556 5_666 ?
Ge3 Ge2 Mn1 122.709(12) 1_556 5_656 ?
Mn1 Ge2 Mn1 114.06(2) 5_666 5_656 ?
Ge3 Ge2 Mn1 105.64(2) 1_556 1_656 ?
Mn1 Ge2 Mn1 78.004(16) 5_666 1_656 ?
Mn1 Ge2 Mn1 78.004(16) 5_656 1_656 ?
Ge3 Ge2 Ca2 129.24(3) 1_556 . ?
Mn1 Ge2 Ca2 73.031(17) 5_666 . ?
Mn1 Ge2 Ca2 73.031(17) 5_656 . ?
Mn1 Ge2 Ca2 125.12(3) 1_656 . ?
Ge3 Ge2 Ca3 68.66(2) 1_556 5_656 ?
Mn1 Ge2 Ca3 147.10(3) 5_666 5_656 ?
Mn1 Ge2 Ca3 68.268(18) 5_656 5_656 ?
Mn1 Ge2 Ca3 131.747(16) 1_656 5_656 ?
Ca2 Ge2 Ca3 76.91(2) . 5_656 ?
Ge3 Ge2 Ca3 68.66(2) 1_556 5_666 ?
Mn1 Ge2 Ca3 68.268(18) 5_666 5_666 ?
Mn1 Ge2 Ca3 147.10(3) 5_656 5_666 ?
Mn1 Ge2 Ca3 131.747(16) 1_656 5_666 ?
Ca2 Ge2 Ca3 76.91(2) . 5_666 ?
Ca3 Ge2 Ca3 92.29(3) 5_656 5_666 ?
Ge3 Ge2 Ca1 66.28(2) 1_556 5_667 ?
Mn1 Ge2 Ca1 65.610(18) 5_666 5_667 ?
Mn1 Ge2 Ca1 140.58(3) 5_656 5_667 ?
Mn1 Ge2 Ca1 63.12(2) 1_656 5_667 ?
Ca2 Ge2 Ca1 134.861(14) . 5_667 ?
Ca3 Ge2 Ca1 134.94(3) 5_656 5_667 ?
Ca3 Ge2 Ca1 71.78(2) 5_666 5_667 ?
Ge3 Ge2 Ca1 66.28(2) 1_556 5_657 ?
Mn1 Ge2 Ca1 140.58(3) 5_666 5_657 ?
Mn1 Ge2 Ca1 65.611(18) 5_656 5_657 ?
Mn1 Ge2 Ca1 63.12(2) 1_656 5_657 ?
Ca2 Ge2 Ca1 134.861(14) . 5_657 ?
Ca3 Ge2 Ca1 71.78(2) 5_656 5_657 ?
Ca3 Ge2 Ca1 134.94(3) 5_666 5_657 ?
Ca1 Ge2 Ca1 89.91(3) 5_667 5_657 ?
Ge3 Ge2 Ca1 163.39(3) 1_556 1_655 ?
Mn1 Ge2 Ca1 57.570(12) 5_666 1_655 ?
Mn1 Ge2 Ca1 57.570(12) 5_656 1_655 ?
Mn1 Ge2 Ca1 57.74(2) 1_656 1_655 ?
Ca2 Ge2 Ca1 67.37(3) . 1_655 ?
Ca3 Ge2 Ca1 121.15(2) 5_656 1_655 ?
Ca3 Ge2 Ca1 121.15(2) 5_666 1_655 ?
Ca1 Ge2 Ca1 102.65(2) 5_667 1_655 ?
Ca1 Ge2 Ca1 102.65(2) 5_657 1_655 ?
Ge2 Ge3 Ge4 104.52(2) 1_554 1_554 ?
Ge2 Ge3 Ca5 131.082(17) 1_554 5_656 ?
Ge4 Ge3 Ca5 67.93(2) 1_554 5_656 ?
Ge2 Ge3 Ca5 131.082(17) 1_554 5_666 ?
Ge4 Ge3 Ca5 67.93(2) 1_554 5_666 ?
Ca5 Ge3 Ca5 92.37(3) 5_656 5_666 ?
Ge2 Ge3 Ca4 124.06(3) 1_554 6_656 ?
Ge4 Ge3 Ca4 131.42(3) 1_554 6_656 ?
Ca5 Ge3 Ca4 79.20(2) 5_656 6_656 ?
Ca5 Ge3 Ca4 79.20(2) 5_666 6_656 ?
Ge2 Ge3 Ca1 66.16(2) 1_554 5_666 ?
Ge4 Ge3 Ca1 131.639(17) 1_554 5_666 ?
Ca5 Ge3 Ca1 154.39(3) 5_656 5_666 ?
Ca5 Ge3 Ca1 83.29(2) 5_666 5_666 ?
Ca4 Ge3 Ca1 75.20(2) 6_656 5_666 ?
Ge2 Ge3 Ca1 66.16(2) 1_554 5_656 ?
Ge4 Ge3 Ca1 131.639(16) 1_554 5_656 ?
Ca5 Ge3 Ca1 83.29(2) 5_656 5_656 ?
Ca5 Ge3 Ca1 154.39(3) 5_666 5_656 ?
Ca4 Ge3 Ca1 75.20(2) 6_656 5_656 ?
Ca1 Ge3 Ca1 89.80(3) 5_666 5_656 ?
Ge2 Ge3 Ca3 63.74(2) 1_554 5_655 ?
Ge4 Ge3 Ca3 63.99(2) 1_554 5_655 ?
Ca5 Ge3 Ca3 70.49(2) 5_656 5_655 ?
Ca5 Ge3 Ca3 131.91(3) 5_666 5_655 ?
Ca4 Ge3 Ca3 135.895(14) 6_656 5_655 ?
Ca1 Ge3 Ca3 129.89(3) 5_666 5_655 ?
Ca1 Ge3 Ca3 70.20(2) 5_656 5_655 ?
Ge2 Ge3 Ca3 63.74(2) 1_554 5_665 ?
Ge4 Ge3 Ca3 63.99(2) 1_554 5_665 ?
Ca5 Ge3 Ca3 131.91(3) 5_656 5_665 ?
Ca5 Ge3 Ca3 70.49(2) 5_666 5_665 ?
Ca4 Ge3 Ca3 135.895(14) 6_656 5_665 ?
Ca1 Ge3 Ca3 70.20(2) 5_666 5_665 ?
Ca1 Ge3 Ca3 129.89(3) 5_656 5_665 ?
Ca3 Ge3 Ca3 87.94(3) 5_655 5_665 ?
Ge3 Ge4 Ge5 105.38(2) 1_556 1_556 ?
Ge3 Ge4 Ca3 68.45(2) 1_556 5_666 ?
Ge5 Ge4 Ca3 131.826(16) 1_556 5_666 ?
Ge3 Ge4 Ca3 68.45(2) 1_556 5_656 ?
Ge5 Ge4 Ca3 131.826(16) 1_556 5_656 ?
Ca3 Ge4 Ca3 91.86(3) 5_666 5_656 ?
Ge3 Ge4 Ca4 130.887(17) 1_556 5_656 ?
Ge5 Ge4 Ca4 66.34(2) 1_556 5_656 ?
Ca3 Ge4 Ca4 153.63(3) 5_666 5_656 ?
Ca3 Ge4 Ca4 82.18(2) 5_656 5_656 ?
Ge3 Ge4 Ca4 130.887(17) 1_556 5_666 ?
Ge5 Ge4 Ca4 66.34(2) 1_556 5_666 ?
Ca3 Ge4 Ca4 82.18(2) 5_666 5_666 ?
Ca3 Ge4 Ca4 153.63(3) 5_656 5_666 ?
Ca4 Ge4 Ca4 91.80(3) 5_656 5_666 ?
Ge3 Ge4 Ca5 125.94(3) 1_556 6_657 ?
Ge5 Ge4 Ca5 128.68(3) 1_556 6_657 ?
Ca3 Ge4 Ca5 74.77(2) 5_666 6_657 ?
Ca3 Ge4 Ca5 74.77(2) 5_656 6_657 ?
Ca4 Ge4 Ca5 78.88(2) 5_656 6_657 ?
Ca4 Ge4 Ca5 78.88(2) 5_666 6_657 ?
Ge3 Ge4 Ca5 64.16(2) 1_556 5_667 ?
Ge5 Ge4 Ca5 64.60(2) 1_556 5_667 ?
Ca3 Ge4 Ca5 70.73(2) 5_666 5_667 ?
Ca3 Ge4 Ca5 132.61(3) 5_656 5_667 ?
Ca4 Ge4 Ca5 130.93(3) 5_656 5_667 ?
Ca4 Ge4 Ca5 69.43(2) 5_666 5_667 ?
Ca5 Ge4 Ca5 135.484(14) 6_657 5_667 ?
Ge3 Ge4 Ca5 64.16(2) 1_556 5_657 ?
Ge5 Ge4 Ca5 64.60(2) 1_556 5_657 ?
Ca3 Ge4 Ca5 132.61(3) 5_666 5_657 ?
Ca3 Ge4 Ca5 70.73(2) 5_656 5_657 ?
Ca4 Ge4 Ca5 69.43(2) 5_656 5_657 ?
Ca4 Ge4 Ca5 130.93(3) 5_666 5_657 ?
Ca5 Ge4 Ca5 135.484(14) 6_657 5_657 ?
Ca5 Ge4 Ca5 88.98(3) 5_667 5_657 ?
Ge4 Ge5 Ag2 113.53(2) 1_554 1_554 ?
Ge4 Ge5 Ca2 132.731(16) 1_554 2_654 ?
Ag2 Ge5 Ca2 65.84(2) 1_554 2_654 ?
Ge4 Ge5 Ca2 132.731(16) 1_554 2_664 ?
Ag2 Ge5 Ca2 65.84(2) 1_554 2_664 ?
Ca2 Ge5 Ca2 91.92(3) 2_654 2_664 ?
Ge4 Ge5 Ca5 67.42(2) 1_554 5_666 ?
Ag2 Ge5 Ca5 133.429(15) 1_554 5_666 ?
Ca2 Ge5 Ca5 149.70(3) 2_654 5_666 ?
Ca2 Ge5 Ca5 80.42(2) 2_664 5_666 ?
Ge4 Ge5 Ca5 67.42(2) 1_554 5_656 ?
Ag2 Ge5 Ca5 133.428(15) 1_554 5_656 ?
Ca2 Ge5 Ca5 80.42(2) 2_654 5_656 ?
Ca2 Ge5 Ca5 149.70(3) 2_664 5_656 ?
Ca5 Ge5 Ca5 91.51(3) 5_666 5_656 ?
Ge4 Ge5 Ca4 65.20(2) 1_554 5_655 ?
Ag2 Ge5 Ca4 69.56(2) 1_554 5_655 ?
Ca2 Ge5 Ca4 71.81(2) 2_654 5_655 ?
Ca2 Ge5 Ca4 135.33(3) 2_664 5_655 ?
Ca5 Ge5 Ca4 132.62(3) 5_666 5_655 ?
Ca5 Ge5 Ca4 69.97(2) 5_656 5_655 ?
Ge4 Ge5 Ca4 65.20(2) 1_554 5_665 ?
Ag2 Ge5 Ca4 69.56(2) 1_554 5_665 ?
Ca2 Ge5 Ca4 135.33(3) 2_654 5_665 ?
Ca2 Ge5 Ca4 71.81(2) 2_664 5_665 ?
Ca5 Ge5 Ca4 69.97(2) 5_666 5_665 ?
Ca5 Ge5 Ca4 132.62(3) 5_656 5_665 ?
Ca4 Ge5 Ca4 90.76(3) 5_655 5_665 ?
Ge4 Ge5 Ca3 123.58(3) 1_554 6_656 ?
Ag2 Ge5 Ca3 122.89(3) 1_554 6_656 ?
Ca2 Ge5 Ca3 75.55(2) 2_654 6_656 ?
Ca2 Ge5 Ca3 75.55(2) 2_664 6_656 ?
Ca5 Ge5 Ca3 74.15(2) 5_666 6_656 ?
Ca5 Ge5 Ca3 74.15(2) 5_656 6_656 ?
Ca4 Ge5 Ca3 134.539(15) 5_655 6_656 ?
Ca4 Ge5 Ca3 134.539(15) 5_665 6_656 ?
Ge2 Mn1 Ge2 114.06(2) 5_666 5_656 ?
Ge2 Mn1 Ge1 115.910(14) 5_666 1_455 ?
Ge2 Mn1 Ge1 115.910(14) 5_656 1_455 ?
Ge2 Mn1 Ge2 101.997(16) 5_666 1_454 ?
Ge2 Mn1 Ge2 101.997(16) 5_656 1_454 ?
Ge1 Mn1 Ge2 104.14(2) 1_455 1_454 ?
Ge2 Mn1 Ca1 164.61(2) 5_666 5_556 ?
Ge2 Mn1 Ca1 76.701(17) 5_656 5_556 ?
Ge1 Mn1 Ca1 64.883(19) 1_455 5_556 ?
Ge2 Mn1 Ca1 63.957(19) 1_454 5_556 ?
Ge2 Mn1 Ca1 76.702(17) 5_666 5_566 ?
Ge2 Mn1 Ca1 164.61(2) 5_656 5_566 ?
Ge1 Mn1 Ca1 64.883(19) 1_455 5_566 ?
Ge2 Mn1 Ca1 63.957(19) 1_454 5_566 ?
Ca1 Mn1 Ca1 90.75(3) 5_556 5_566 ?
Ge2 Mn1 Ca1 64.765(14) 5_666 1_554 ?
Ge2 Mn1 Ca1 64.765(14) 5_656 1_554 ?
Ge1 Mn1 Ca1 178.16(3) 1_455 1_554 ?
Ge2 Mn1 Ca1 74.02(2) 1_454 1_554 ?
Ca1 Mn1 Ca1 113.97(2) 5_556 1_554 ?
Ca1 Mn1 Ca1 113.97(2) 5_566 1_554 ?
Ge2 Mn1 Ca3 62.223(14) 5_666 . ?
Ge2 Mn1 Ca3 62.223(14) 5_656 . ?
Ge1 Mn1 Ca3 112.31(3) 1_455 . ?
Ge2 Mn1 Ca3 143.55(2) 1_454 . ?
Ca1 Mn1 Ca3 132.762(16) 5_556 . ?
Ca1 Mn1 Ca3 132.762(16) 5_566 . ?
Ca1 Mn1 Ca3 69.53(3) 1_554 . ?
Ge2 Mn1 Ca2 59.029(18) 5_666 5_666 ?
Ge2 Mn1 Ca2 125.31(2) 5_656 5_666 ?
Ge1 Mn1 Ca2 60.141(19) 1_455 5_666 ?
Ge2 Mn1 Ca2 132.611(17) 1_454 5_666 ?
Ca1 Mn1 Ca2 124.94(3) 5_556 5_666 ?
Ca1 Mn1 Ca2 69.25(2) 5_566 5_666 ?
Ca1 Mn1 Ca2 121.06(2) 1_554 5_666 ?
Ca3 Mn1 Ca2 70.07(2) . 5_666 ?
Ge2 Mn1 Ca2 125.31(2) 5_666 5_656 ?
Ge2 Mn1 Ca2 59.029(18) 5_656 5_656 ?
Ge1 Mn1 Ca2 60.141(19) 1_455 5_656 ?
Ge2 Mn1 Ca2 132.611(17) 1_454 5_656 ?
Ca1 Mn1 Ca2 69.25(2) 5_556 5_656 ?
Ca1 Mn1 Ca2 124.94(3) 5_566 5_656 ?
Ca1 Mn1 Ca2 121.06(2) 1_554 5_656 ?
Ca3 Mn1 Ca2 70.07(2) . 5_656 ?
Ca2 Mn1 Ca2 81.27(2) 5_666 5_656 ?
Ge1 Mn2 Ge1 113.86(3) 2_655 2_665 ?
Ge1 Mn2 Ge5 117.625(16) 2_655 1_556 ?
Ge1 Mn2 Ge5 117.625(16) 2_665 1_556 ?
Ge1 Mn2 Ge1 101.138(19) 2_655 6_557 ?
Ge1 Mn2 Ge1 101.138(19) 2_665 6_557 ?
Ge5 Mn2 Ge1 101.09(2) 1_556 6_557 ?
Ge1 Mn2 Ca2 163.06(3) 2_655 2_665 ?
Ge1 Mn2 Ca2 77.248(16) 2_665 2_665 ?
Ge5 Mn2 Ca2 63.08(2) 1_556 2_665 ?
Ge1 Mn2 Ca2 63.14(2) 6_557 2_665 ?
Ge1 Mn2 Ca2 77.248(16) 2_655 2_655 ?
Ge1 Mn2 Ca2 163.06(3) 2_665 2_655 ?
Ge5 Mn2 Ca2 63.08(2) 1_556 2_655 ?
Ge1 Mn2 Ca2 63.14(2) 6_557 2_655 ?
Ca2 Mn2 Ca2 89.25(3) 2_665 2_655 ?
Ge1 Mn2 Ca2 63.692(16) 2_655 6_557 ?
Ge1 Mn2 Ca2 63.692(16) 2_665 6_557 ?
Ge5 Mn2 Ca2 176.13(3) 1_556 6_557 ?
Ge1 Mn2 Ca2 75.04(2) 6_557 6_557 ?
Ca2 Mn2 Ca2 114.50(2) 2_665 6_557 ?
Ca2 Mn2 Ca2 114.50(2) 2_655 6_557 ?
Ge1 Mn2 Ca1 63.341(16) 2_655 6_657 ?
Ge1 Mn2 Ca1 63.341(16) 2_665 6_657 ?
Ge5 Mn2 Ca1 113.49(3) 1_556 6_657 ?
Ge1 Mn2 Ca1 145.42(3) 6_557 6_657 ?
Ca2 Mn2 Ca1 133.161(16) 2_665 6_657 ?
Ca2 Mn2 Ca1 133.161(16) 2_655 6_657 ?
Ca2 Mn2 Ca1 70.38(3) 6_557 6_657 ?
Ge1 Mn2 Ca4 128.11(3) 2_655 5_666 ?
Ge1 Mn2 Ca4 60.091(19) 2_665 5_666 ?
Ge5 Mn2 Ca4 61.22(2) 1_556 5_666 ?
Ge1 Mn2 Ca4 130.693(17) 6_557 5_666 ?
Ca2 Mn2 Ca4 68.12(2) 2_665 5_666 ?
Ca2 Mn2 Ca4 124.24(3) 2_655 5_666 ?
Ca2 Mn2 Ca4 121.26(2) 6_557 5_666 ?
Ca1 Mn2 Ca4 70.68(2) 6_657 5_666 ?
Ge1 Mn2 Ca4 60.091(19) 2_655 5_656 ?
Ge1 Mn2 Ca4 128.11(3) 2_665 5_656 ?
Ge5 Mn2 Ca4 61.22(2) 1_556 5_656 ?
Ge1 Mn2 Ca4 130.693(17) 6_557 5_656 ?
Ca2 Mn2 Ca4 124.24(3) 2_665 5_656 ?
Ca2 Mn2 Ca4 68.12(2) 2_655 5_656 ?
Ca2 Mn2 Ca4 121.26(2) 6_557 5_656 ?
Ca1 Mn2 Ca4 70.68(2) 6_657 5_656 ?
Ca4 Mn2 Ca4 83.48(3) 5_666 5_656 ?
Mn1 Ca1 Mn1 90.75(3) 5_556 5_566 ?
Mn1 Ca1 Ge1 51.023(15) 5_556 5_656 ?
Mn1 Ca1 Ge1 112.18(3) 5_566 5_656 ?
Mn1 Ca1 Ge1 112.18(3) 5_556 5_666 ?
Mn1 Ca1 Ge1 51.023(15) 5_566 5_666 ?
Ge1 Ca1 Ge1 89.99(3) 5_656 5_666 ?
Mn1 Ca1 Ge2 113.76(3) 5_556 5_667 ?
Mn1 Ca1 Ge2 52.926(16) 5_566 5_667 ?
Ge1 Ca1 Ge2 161.50(4) 5_656 5_667 ?
Ge1 Ca1 Ge2 87.086(12) 5_666 5_667 ?
Mn1 Ca1 Ge2 52.926(16) 5_556 5_657 ?
Mn1 Ca1 Ge2 113.76(3) 5_566 5_657 ?
Ge1 Ca1 Ge2 87.086(12) 5_656 5_657 ?
Ge1 Ca1 Ge2 161.50(4) 5_666 5_657 ?
Ge2 Ca1 Ge2 89.91(3) 5_667 5_657 ?
Mn1 Ca1 Ge3 157.46(4) 5_556 5_666 ?
Mn1 Ca1 Ge3 85.343(11) 5_566 5_666 ?
Ge1 Ca1 Ge3 149.82(4) 5_656 5_666 ?
Ge1 Ca1 Ge3 82.311(14) 5_666 5_666 ?
Ge2 Ca1 Ge3 47.562(15) 5_667 5_666 ?
Ge2 Ca1 Ge3 108.83(3) 5_657 5_666 ?
Mn1 Ca1 Ge3 85.343(11) 5_556 5_656 ?
Mn1 Ca1 Ge3 157.46(4) 5_566 5_656 ?
Ge1 Ca1 Ge3 82.311(14) 5_656 5_656 ?
Ge1 Ca1 Ge3 149.82(4) 5_666 5_656 ?
Ge2 Ca1 Ge3 108.83(3) 5_667 5_656 ?
Ge2 Ca1 Ge3 47.562(15) 5_657 5_656 ?
Ge3 Ca1 Ge3 89.80(3) 5_666 5_656 ?
Mn1 Ca1 Mn1 66.02(2) 5_556 1_556 ?
Mn1 Ca1 Mn1 66.02(2) 5_566 1_556 ?
Ge1 Ca1 Mn1 117.03(3) 5_656 1_556 ?
Ge1 Ca1 Mn1 117.03(3) 5_666 1_556 ?
Ge2 Ca1 Mn1 49.624(16) 5_667 1_556 ?
Ge2 Ca1 Mn1 49.624(16) 5_657 1_556 ?
Ge3 Ca1 Mn1 92.25(2) 5_666 1_556 ?
Ge3 Ca1 Mn1 92.25(2) 5_656 1_556 ?
Mn1 Ca1 Ag2 94.97(2) 5_556 6_557 ?
Mn1 Ca1 Ag2 94.97(2) 5_566 6_557 ?
Ge1 Ca1 Ag2 48.945(15) 5_656 6_557 ?
Ge1 Ca1 Ag2 48.945(15) 5_666 6_557 ?
Ge2 Ca1 Ag2 134.868(14) 5_667 6_557 ?
Ge2 Ca1 Ag2 134.868(14) 5_657 6_557 ?
Ge3 Ca1 Ag2 107.47(3) 5_666 6_557 ?
Ge3 Ca1 Ag2 107.47(2) 5_656 6_557 ?
Mn1 Ca1 Ag2 151.74(4) 1_556 6_557 ?
Mn1 Ca1 Ge2 45.729(14) 5_556 1_455 ?
Mn1 Ca1 Ge2 45.729(14) 5_566 1_455 ?
Ge1 Ca1 Ge2 84.18(2) 5_656 1_455 ?
Ge1 Ca1 Ge2 84.18(2) 5_666 1_455 ?
Ge2 Ca1 Ge2 77.35(2) 5_667 1_455 ?
Ge2 Ca1 Ge2 77.35(2) 5_657 1_455 ?
Ge3 Ca1 Ge2 123.62(2) 5_666 1_455 ?
Ge3 Ca1 Ge2 123.62(2) 5_656 1_455 ?
Mn1 Ca1 Ge2 48.232(18) 1_556 1_455 ?
Ag2 Ca1 Ge2 103.51(3) 6_557 1_455 ?
Mn1 Ca1 Ca3 104.43(2) 5_556 1_556 ?
Mn1 Ca1 Ca3 104.43(2) 5_566 1_556 ?
Ge1 Ca1 Ca3 134.678(15) 5_656 1_556 ?
Ge1 Ca1 Ca3 134.678(15) 5_666 1_556 ?
Ge2 Ca1 Ca3 53.301(18) 5_667 1_556 ?
Ge2 Ca1 Ca3 53.301(18) 5_657 1_556 ?
Ge3 Ca1 Ca3 55.578(19) 5_666 1_556 ?
Ge3 Ca1 Ca3 55.578(19) 5_656 1_556 ?
Mn1 Ca1 Ca3 56.12(2) 1_556 1_556 ?
Ag2 Ca1 Ca3 152.13(4) 6_557 1_556 ?
Ge2 Ca1 Ca3 104.36(3) 1_455 1_556 ?
Ge2 Ca2 Ge5 104.65(3) . 2_655 ?
Ge2 Ca2 Ge5 104.65(3) . 2_665 ?
Ge5 Ca2 Ge5 91.92(3) 2_655 2_665 ?
Ge2 Ca2 Ge1 94.29(3) . 5_766 ?
Ge5 Ca2 Ge1 160.91(4) 2_655 5_766 ?
Ge5 Ca2 Ge1 85.534(12) 2_665 5_766 ?
Ge2 Ca2 Ge1 94.29(3) . 5_756 ?
Ge5 Ca2 Ge1 85.534(12) 2_655 5_756 ?
Ge5 Ca2 Ge1 160.91(4) 2_665 5_756 ?
Ge1 Ca2 Ge1 90.70(3) 5_766 5_756 ?
Ge2 Ca2 Ag2 134.954(15) . 2_654 ?
Ge5 Ca2 Ag2 51.082(16) 2_655 2_654 ?
Ge5 Ca2 Ag2 112.44(3) 2_665 2_654 ?
Ge1 Ca2 Ag2 112.77(3) 5_766 2_654 ?
Ge1 Ca2 Ag2 52.234(16) 5_756 2_654 ?
Ge2 Ca2 Ag2 134.954(15) . 2_664 ?
Ge5 Ca2 Ag2 112.44(3) 2_655 2_664 ?
Ge5 Ca2 Ag2 51.082(16) 2_665 2_664 ?
Ge1 Ca2 Ag2 52.234(16) 5_766 2_664 ?
Ge1 Ca2 Ag2 112.77(3) 5_756 2_664 ?
Ag2 Ca2 Ag2 89.25(3) 2_654 2_664 ?
Ge2 Ca2 Ag2 118.73(3) . 6_657 ?
Ge5 Ca2 Ag2 116.50(2) 2_655 6_657 ?
Ge5 Ca2 Ag2 116.50(2) 2_665 6_657 ?
Ge1 Ca2 Ag2 49.557(16) 5_766 6_657 ?
Ge1 Ca2 Ag2 49.557(16) 5_756 6_657 ?
Ag2 Ca2 Ag2 65.50(2) 2_654 6_657 ?
Ag2 Ca2 Ag2 65.50(2) 2_664 6_657 ?
Ge2 Ca2 Mn1 47.940(15) . 5_666 ?
Ge5 Ca2 Mn1 150.28(3) 2_655 5_666 ?
Ge5 Ca2 Mn1 86.108(13) 2_665 5_666 ?
Ge1 Ca2 Mn1 48.521(15) 5_766 5_666 ?
Ge1 Ca2 Mn1 105.32(3) 5_756 5_666 ?
Ag2 Ca2 Mn1 154.19(4) 2_654 5_666 ?
Ag2 Ca2 Mn1 89.158(12) 2_664 5_666 ?
Ag2 Ca2 Mn1 90.54(2) 6_657 5_666 ?
Ge2 Ca2 Mn1 47.940(15) . 5_656 ?
Ge5 Ca2 Mn1 86.108(13) 2_655 5_656 ?
Ge5 Ca2 Mn1 150.28(3) 2_665 5_656 ?
Ge1 Ca2 Mn1 105.32(3) 5_766 5_656 ?
Ge1 Ca2 Mn1 48.521(15) 5_756 5_656 ?
Ag2 Ca2 Mn1 89.158(12) 2_654 5_656 ?
Ag2 Ca2 Mn1 154.19(4) 2_664 5_656 ?
Ag2 Ca2 Mn1 90.54(2) 6_657 5_656 ?
Mn1 Ca2 Mn1 81.27(2) 5_666 5_656 ?
Ge2 Ca2 Ca4 144.65(4) . 6_656 ?
Ge5 Ca2 Ca4 54.487(18) 2_655 6_656 ?
Ge5 Ca2 Ca4 54.487(18) 2_665 6_656 ?
Ge1 Ca2 Ca4 110.08(3) 5_766 6_656 ?
Ge1 Ca2 Ca4 110.08(3) 5_756 6_656 ?
Ag2 Ca2 Ca4 58.22(2) 2_654 6_656 ?
Ag2 Ca2 Ca4 58.22(2) 2_664 6_656 ?
Ag2 Ca2 Ca4 96.62(3) 6_657 6_656 ?
Mn1 Ca2 Ca4 138.824(13) 5_666 6_656 ?
Mn1 Ca2 Ca4 138.824(13) 5_656 6_656 ?
Ge2 Ca3 Ge2 92.29(3) 5_656 5_666 ?
Ge2 Ca3 Ge4 151.88(4) 5_656 5_666 ?
Ge2 Ca3 Ge4 81.124(13) 5_666 5_666 ?
Ge2 Ca3 Ge4 81.124(13) 5_656 5_656 ?
Ge2 Ca3 Ge4 151.88(4) 5_666 5_656 ?
Ge4 Ca3 Ge4 91.87(3) 5_666 5_656 ?
Ge2 Ca3 Ge5 102.89(3) 5_656 6_556 ?
Ge2 Ca3 Ge5 102.89(3) 5_666 6_556 ?
Ge4 Ca3 Ge5 105.23(3) 5_666 6_556 ?
Ge4 Ca3 Ge5 105.23(3) 5_656 6_556 ?
Ge2 Ca3 Ge3 47.602(15) 5_656 5_655 ?
Ge2 Ca3 Ge3 109.09(3) 5_666 5_655 ?
Ge4 Ca3 Ge3 108.83(3) 5_666 5_655 ?
Ge4 Ca3 Ge3 47.556(15) 5_656 5_655 ?
Ge5 Ca3 Ge3 136.008(14) 6_556 5_655 ?
Ge2 Ca3 Ge3 109.09(3) 5_656 5_665 ?
Ge2 Ca3 Ge3 47.602(15) 5_666 5_665 ?
Ge4 Ca3 Ge3 47.556(15) 5_666 5_665 ?
Ge4 Ca3 Ge3 108.83(3) 5_656 5_665 ?
Ge5 Ca3 Ge3 136.008(14) 6_556 5_665 ?
Ge3 Ca3 Ge3 87.94(3) 5_655 5_665 ?
Ge2 Ca3 Mn1 49.508(16) 5_656 . ?
Ge2 Ca3 Mn1 49.508(16) 5_666 . ?
Ge4 Ca3 Mn1 130.632(18) 5_666 . ?
Ge4 Ca3 Mn1 130.632(18) 5_656 . ?
Ge5 Ca3 Mn1 88.37(3) 6_556 . ?
Ge3 Ca3 Mn1 90.02(2) 5_655 . ?
Ge3 Ca3 Mn1 90.02(2) 5_665 . ?
Ge2 Ca3 Ca5 99.15(3) 5_656 1_554 ?
Ge2 Ca3 Ca5 99.15(3) 5_666 1_554 ?
Ge4 Ca3 Ca5 55.645(18) 5_666 1_554 ?
Ge4 Ca3 Ca5 55.645(18) 5_656 1_554 ?
Ge5 Ca3 Ca5 147.96(4) 6_556 1_554 ?
Ge3 Ca3 Ca5 53.191(18) 5_655 1_554 ?
Ge3 Ca3 Ca5 53.191(18) 5_665 1_554 ?
Mn1 Ca3 Ca5 123.68(3) . 1_554 ?
Ge2 Ca3 Ca1 54.916(18) 5_656 1_554 ?
Ge2 Ca3 Ca1 54.916(18) 5_666 1_554 ?
Ge4 Ca3 Ca1 100.43(3) 5_666 1_554 ?
Ge4 Ca3 Ca1 100.43(3) 5_656 1_554 ?
Ge5 Ca3 Ca1 142.72(4) 6_556 1_554 ?
Ge3 Ca3 Ca1 54.224(18) 5_655 1_554 ?
Ge3 Ca3 Ca1 54.224(18) 5_665 1_554 ?
Mn1 Ca3 Ca1 54.35(2) . 1_554 ?
Ca5 Ca3 Ca1 69.32(3) 1_554 1_554 ?
Ge2 Ca3 Ca5 155.31(3) 5_656 2_564 ?
Ge2 Ca3 Ca5 93.291(15) 5_666 2_564 ?
Ge4 Ca3 Ca5 52.799(19) 5_666 2_564 ?
Ge4 Ca3 Ca5 104.10(3) 5_656 2_564 ?
Ge5 Ca3 Ca5 52.43(2) 6_556 2_564 ?
Ge3 Ca3 Ca5 149.21(3) 5_655 2_564 ?
Ge3 Ca3 Ca5 92.267(16) 5_665 2_564 ?
Mn1 Ca3 Ca5 120.76(3) . 2_564 ?
Ca5 Ca3 Ca5 103.66(2) 1_554 2_564 ?
Ca1 Ca3 Ca5 143.669(13) 1_554 2_564 ?
Ge1 Ca4 Ge4 133.229(16) 6_556 5_656 ?
Ge1 Ca4 Ge4 133.229(16) 6_556 5_666 ?
Ge4 Ca4 Ge4 91.80(3) 5_656 5_666 ?
Ge1 Ca4 Ge3 84.47(3) 6_556 6_556 ?
Ge4 Ca4 Ge3 100.87(3) 5_656 6_556 ?
Ge4 Ca4 Ge3 100.87(3) 5_666 6_556 ?
Ge1 Ca4 Ge5 95.55(3) 6_556 5_655 ?
Ge4 Ca4 Ge5 48.461(15) 5_656 5_655 ?
Ge4 Ca4 Ge5 111.05(3) 5_666 5_655 ?
Ge3 Ca4 Ge5 134.572(15) 6_556 5_655 ?
Ge1 Ca4 Ge5 95.55(3) 6_556 5_665 ?
Ge4 Ca4 Ge5 111.05(3) 5_656 5_665 ?
Ge4 Ca4 Ge5 48.461(15) 5_666 5_665 ?
Ge3 Ca4 Ge5 134.572(15) 6_556 5_665 ?
Ge5 Ca4 Ge5 90.76(3) 5_655 5_665 ?
Ge1 Ca4 Ag2 48.752(16) 6_556 5_666 ?
Ge4 Ca4 Ag2 152.45(4) 5_656 5_666 ?
Ge4 Ca4 Ag2 86.012(13) 5_666 5_666 ?
Ge3 Ca4 Ag2 106.51(3) 6_556 5_666 ?
Ge5 Ca4 Ag2 107.13(3) 5_655 5_666 ?
Ge5 Ca4 Ag2 49.222(16) 5_665 5_666 ?
Ge1 Ca4 Ag2 48.752(16) 6_556 5_656 ?
Ge4 Ca4 Ag2 86.012(13) 5_656 5_656 ?
Ge4 Ca4 Ag2 152.45(4) 5_666 5_656 ?
Ge3 Ca4 Ag2 106.51(3) 6_556 5_656 ?
Ge5 Ca4 Ag2 49.222(16) 5_655 5_656 ?
Ge5 Ca4 Ag2 107.13(3) 5_665 5_656 ?
Ag2 Ca4 Ag2 83.48(3) 5_666 5_656 ?
Ge1 Ca4 Ca5 132.68(4) 6_556 1_554 ?
Ge4 Ca4 Ca5 56.298(19) 5_656 1_554 ?
Ge4 Ca4 Ca5 56.298(19) 5_666 1_554 ?
Ge3 Ca4 Ca5 142.85(4) 6_556 1_554 ?
Ge5 Ca4 Ca5 54.756(19) 5_655 1_554 ?
Ge5 Ca4 Ca5 54.756(19) 5_665 1_554 ?
Ag2 Ca4 Ca5 100.96(3) 5_666 1_554 ?
Ag2 Ca4 Ca5 100.96(3) 5_656 1_554 ?
Ge1 Ca4 Ca2 65.36(3) 6_556 6_556 ?
Ge4 Ca4 Ca2 100.00(3) 5_656 6_556 ?
Ge4 Ca4 Ca2 100.00(3) 5_666 6_556 ?
Ge3 Ca4 Ca2 149.83(4) 6_556 6_556 ?
Ge5 Ca4 Ca2 53.701(19) 5_655 6_556 ?
Ge5 Ca4 Ca2 53.701(19) 5_665 6_556 ?
Ag2 Ca4 Ca2 53.665(18) 5_666 6_556 ?
Ag2 Ca4 Ca2 53.665(18) 5_656 6_556 ?
Ca5 Ca4 Ca2 67.32(3) 1_554 6_556 ?
Ge1 Ca4 Ca1 53.06(2) 6_556 2_564 ?
Ge4 Ca4 Ca1 153.82(3) 5_656 2_564 ?
Ge4 Ca4 Ca1 93.467(15) 5_666 2_564 ?
Ge3 Ca4 Ca1 52.95(2) 6_556 2_564 ?
Ge5 Ca4 Ca1 148.60(4) 5_655 2_564 ?
Ge5 Ca4 Ca1 91.377(16) 5_665 2_564 ?
Ag2 Ca4 Ca1 53.633(19) 5_666 2_564 ?
Ag2 Ca4 Ca1 100.54(3) 5_656 2_564 ?
Ca5 Ca4 Ca1 144.054(13) 1_554 2_564 ?
Ca2 Ca4 Ca1 104.29(3) 6_556 2_564 ?
Ge1 Ca4 Ca1 53.06(2) 6_556 2_554 ?
Ge4 Ca4 Ca1 93.467(15) 5_656 2_554 ?
Ge4 Ca4 Ca1 153.82(3) 5_666 2_554 ?
Ge3 Ca4 Ca1 52.95(2) 6_556 2_554 ?
Ge5 Ca4 Ca1 91.377(16) 5_655 2_554 ?
Ge5 Ca4 Ca1 148.60(4) 5_665 2_554 ?
Ag2 Ca4 Ca1 100.54(3) 5_666 2_554 ?
Ag2 Ca4 Ca1 53.633(19) 5_656 2_554 ?
Ca5 Ca4 Ca1 144.054(13) 1_554 2_554 ?
Ca2 Ca4 Ca1 104.29(3) 6_556 2_554 ?
Ca1 Ca4 Ca1 71.29(2) 2_564 2_554 ?
Ge3 Ca5 Ge3 92.37(3) 5_656 5_666 ?
Ge3 Ca5 Ge5 153.09(4) 5_656 5_666 ?
Ge3 Ca5 Ge5 81.833(14) 5_666 5_666 ?
Ge3 Ca5 Ge5 81.833(14) 5_656 5_656 ?
Ge3 Ca5 Ge5 153.09(4) 5_666 5_656 ?
Ge5 Ca5 Ge5 91.50(3) 5_666 5_656 ?
Ge3 Ca5 Ge4 101.06(3) 5_656 6_557 ?
Ge3 Ca5 Ge4 101.06(3) 5_666 6_557 ?
Ge5 Ca5 Ge4 105.84(3) 5_666 6_557 ?
Ge5 Ca5 Ge4 105.84(3) 5_656 6_557 ?
Ge3 Ca5 Ge4 109.94(3) 5_656 5_667 ?
Ge3 Ca5 Ge4 47.912(15) 5_666 5_667 ?
Ge5 Ca5 Ge4 47.981(15) 5_666 5_667 ?
Ge5 Ca5 Ge4 109.55(3) 5_656 5_667 ?
Ge4 Ca5 Ge4 135.408(14) 6_557 5_667 ?
Ge3 Ca5 Ge4 47.912(15) 5_656 5_657 ?
Ge3 Ca5 Ge4 109.94(3) 5_666 5_657 ?
Ge5 Ca5 Ge4 109.55(3) 5_666 5_657 ?
Ge5 Ca5 Ge4 47.981(15) 5_656 5_657 ?
Ge4 Ca5 Ge4 135.408(14) 6_557 5_657 ?
Ge4 Ca5 Ge4 88.98(3) 5_667 5_657 ?
Ge3 Ca5 Ca4 100.73(3) 5_656 1_556 ?
Ge3 Ca5 Ca4 100.73(3) 5_666 1_556 ?
Ge5 Ca5 Ca4 55.279(19) 5_666 1_556 ?
Ge5 Ca5 Ca4 55.279(19) 5_656 1_556 ?
Ge4 Ca5 Ca4 148.32(4) 6_557 1_556 ?
Ge4 Ca5 Ca4 54.275(18) 5_667 1_556 ?
Ge4 Ca5 Ca4 54.275(18) 5_657 1_556 ?
Ge3 Ca5 Ca3 56.316(19) 5_656 1_556 ?
Ge3 Ca5 Ca3 56.316(19) 5_666 1_556 ?
Ge5 Ca5 Ca3 99.80(3) 5_666 1_556 ?
Ge5 Ca5 Ca3 99.80(3) 5_656 1_556 ?
Ge4 Ca5 Ca3 142.85(4) 6_557 1_556 ?
Ge4 Ca5 Ca3 53.627(18) 5_667 1_556 ?
Ge4 Ca5 Ca3 53.627(18) 5_657 1_556 ?
Ca4 Ca5 Ca3 68.83(3) 1_556 1_556 ?
Ge3 Ca5 Ca3 92.465(15) 5_656 2 ?
Ge3 Ca5 Ca3 153.47(3) 5_666 2 ?
Ge5 Ca5 Ca3 104.45(3) 5_666 2 ?
Ge5 Ca5 Ca3 53.418(19) 5_656 2 ?
Ge4 Ca5 Ca3 52.43(2) 6_557 2 ?
Ge4 Ca5 Ca3 150.47(3) 5_667 2 ?
Ge4 Ca5 Ca3 92.461(15) 5_657 2 ?
Ca4 Ca5 Ca3 103.95(3) 1_556 2 ?
Ca3 Ca5 Ca3 143.659(14) 1_556 2 ?
Ge3 Ca5 Ca3 153.47(3) 5_656 2_565 ?
Ge3 Ca5 Ca3 92.465(15) 5_666 2_565 ?
Ge5 Ca5 Ca3 53.418(19) 5_666 2_565 ?
Ge5 Ca5 Ca3 104.45(3) 5_656 2_565 ?
Ge4 Ca5 Ca3 52.43(2) 6_557 2_565 ?
Ge4 Ca5 Ca3 92.461(15) 5_667 2_565 ?
Ge4 Ca5 Ca3 150.47(3) 5_657 2_565 ?
Ca4 Ca5 Ca3 103.95(3) 1_556 2_565 ?
Ca3 Ca5 Ca3 143.659(14) 1_556 2_565 ?
Ca3 Ca5 Ca3 72.34(2) 2 2_565 ?
Ge3 Ca5 Ca4 50.650(18) 5_656 2 ?
Ge3 Ca5 Ca4 100.36(3) 5_666 2 ?
Ge5 Ca5 Ca4 156.23(3) 5_666 2 ?
Ge5 Ca5 Ca4 96.153(14) 5_656 2 ?
Ge4 Ca5 Ca4 50.409(19) 6_557 2 ?
Ge4 Ca5 Ca4 145.79(3) 5_667 2 ?
Ge4 Ca5 Ca4 92.091(16) 5_657 2 ?
Ca4 Ca5 Ca4 144.897(15) 1_556 2 ?
Ca3 Ca5 Ca4 101.00(3) 1_556 2 ?
Ca3 Ca5 Ca4 63.66(2) 2 2 ?
Ca3 Ca5 Ca4 102.83(3) 2_565 2 ?


# END of CIF
_exptl_crystal_colour            silver
_exptl_crystal_description       block
_exptl_crystal_recrystallization_method 'From the Melt'
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx_CCDC2
_database_code_depnum_ccdc_archive 'CCDC 2055289'
loop_
_audit_author_name
_audit_author_address
'Simeon Ponou'
;Department of Environmental and Materials Chemistry, Stockholm University 
Sweden
;
_audit_update_record             
;
2021-01-11 deposited with the CCDC.	2021-02-19 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Ag1.33 Ca5 Ge4.96 Mn0.71'
_chemical_formula_weight         742.74

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ca Ca 0.2262 0.3064 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_H-M_alt        'P n m a'
_space_group_name_Hall           '-P 2ac 2n'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'x+1/2, -y+1/2, -z+1/2'
'-x, y+1/2, -z'
'-x+1/2, -y, z+1/2'
'-x, -y, -z'
'-x-1/2, y-1/2, z-1/2'
'x, -y-1/2, z'
'x-1/2, y, -z-1/2'

_cell_length_a                   23.0029(7)
_cell_length_b                   4.47440(10)
_cell_length_c                   10.8489(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     1116.61(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    10697
_cell_measurement_theta_min      2.075
_cell_measurement_theta_max      42.856

_exptl_crystal_description       'block shape'
_exptl_crystal_colour            'dark silver'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    4.418
_exptl_crystal_F_000             1356
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.06
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.02
_exptl_absorpt_coefficient_mu    18.454
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.124
_exptl_absorpt_correction_T_max  0.226
_exptl_absorpt_process_details   
;
 Reference: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker D8 QUEST'
_diffrn_measurement_method       'ω and π scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            27200
_diffrn_reflns_av_unetI/netI     0.0278
_diffrn_reflns_av_R_equivalents  0.0371
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_h_max       43
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_k_max       4
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         2.075
_diffrn_reflns_theta_max         42.856
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.966
_diffrn_measured_fraction_theta_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.966
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.966
_diffrn_reflns_point_group_measured_fraction_full 0.989
_reflns_number_total             4313
_reflns_number_gt                3610
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       
;
APEX3, Bruker AXS Inc.: Madison, WI, 2015
;
_computing_cell_refinement       
;
APEX3, Bruker AXS Inc.: Madison, WI, 2015
;
_computing_data_reduction        
;
APEX3, Bruker AXS Inc.: Madison, WI, 2015
;
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0097P)²+1.2192P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.00165(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         4313
_refine_ls_number_parameters     77
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0342
_refine_ls_R_factor_gt           0.0235
_refine_ls_wR_factor_ref         0.0442
_refine_ls_wR_factor_gt          0.0408
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_restrained_S_all      1.016
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.97467(2) 0.250000 0.34305(2) 0.01199(5) Uani 1 2 d S T P . .
Ge2 Ge 0.92363(2) 0.250000 0.95475(2) 0.01150(6) Uani 0.965(3) 2 d S T P . .
Ag' Ag 0.92363(2) 0.250000 0.95475(2) 0.01150(6) Uani 0.035(3) 2 d S T P . .
Ge3 Ge 0.83476(2) 0.250000 0.09713(2) 0.00962(4) Uani 1 2 d S T P . .
Ge4 Ge 0.74756(2) 0.250000 0.94970(2) 0.00940(4) Uani 1 2 d S T P . .
Ge5 Ge 0.65693(2) 0.250000 0.08948(2) 0.01040(4) Uani 1 2 d S T P . .
Mn1 Mn 0.02113(2) 0.250000 0.11150(2) 0.01560(5) Uani 0.194(2) 2 d S T P . .
Ag1 Ag 0.02113(2) 0.250000 0.11150(2) 0.01560(5) Uani 0.806(2) 2 d S T P . .
Ag2 Ag 0.55418(2) 0.250000 0.96359(2) 0.01589(6) Uani 0.4816(19) 2 d S T P . .
Mn2 Mn 0.55418(2) 0.250000 0.96359(2) 0.01589(6) Uani 0.5184(19) 2 d S T P . .
Ca1 Ca 0.07236(2) 0.250000 0.83745(4) 0.01239(7) Uani 1 2 d S T P . .
Ca2 Ca 0.92913(2) 0.250000 0.67087(4) 0.01258(7) Uani 1 2 d S T P . .
Ca3 Ca 0.16343(2) 0.250000 0.11771(4) 0.01026(6) Uani 1 2 d S T P . .
Ca4 Ca 0.34210(2) 0.250000 0.11452(4) 0.01073(6) Uani 1 2 d S T P . .
Ca5 Ca 0.25391(2) 0.250000 0.83987(4) 0.01041(6) Uani 1 2 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 Ag2 2.67505(18) 6_765 ?
Ge1 Ag2 2.67505(18) 6_755 ?
Ge1 Mn1 2.7299(3) 1_655 ?
Ge1 Ag2 2.7832(3) 2_556 ?
Ge1 Ca4 3.0840(5) 2 ?
Ge1 Ca2 3.1503(3) 5_766 ?
Ge1 Ca2 3.1503(3) 5_756 ?
Ge1 Ca1 3.1639(3) 5_656 ?
Ge1 Ca1 3.1639(3) 5_666 ?
Ge2 Ge3 2.5622(3) 1_556 ?
Ge2 Mn1 2.67141(16) 5_666 ?
Ge2 Mn1 2.67141(16) 5_656 ?
Ge2 Mn1 2.8145(3) 1_656 ?
Ge2 Ca2 3.0824(5) . ?
Ge2 Ca3 3.1038(3) 5_656 ?
Ge2 Ca3 3.1038(3) 5_666 ?
Ge2 Ca1 3.1774(3) 5_667 ?
Ge2 Ca1 3.1774(3) 5_657 ?
Ge2 Ca1 3.6501(5) 1_655 ?
Ge3 Ge4 2.5655(3) 1_554 ?
Ge3 Ca5 3.1036(3) 5_656 ?
Ge3 Ca5 3.1036(3) 5_666 ?
Ge3 Ca4 3.1328(4) 2 ?
Ge3 Ca1 3.1739(3) 5_666 ?
Ge3 Ca1 3.1739(3) 5_656 ?
Ge3 Ca3 3.2310(3) 5_655 ?
Ge3 Ca3 3.2310(3) 5_665 ?
Ge4 Ge5 2.5779(3) 1_556 ?
Ge4 Ca3 3.1197(3) 5_666 ?
Ge4 Ca3 3.1197(3) 5_656 ?
Ge4 Ca4 3.1216(3) 5_656 ?
Ge4 Ca4 3.1216(3) 5_666 ?
Ge4 Ca5 3.1449(4) 2_556 ?
Ge4 Ca5 3.1966(3) 5_667 ?
Ge4 Ca5 3.1965(3) 5_657 ?
Ge5 Ag2 2.7297(3) 1_554 ?
Ge5 Ca2 3.1151(3) 6_755 ?
Ge5 Ca2 3.1151(3) 6_765 ?
Ge5 Ca5 3.1304(3) 5_666 ?
Ge5 Ca5 3.1304(3) 5_656 ?
Ge5 Ca4 3.1470(3) 5_655 ?
Ge5 Ca4 3.1470(3) 5_665 ?
Ge5 Ca3 3.1802(4) 2 ?
Mn1 Ca1 3.1522(3) 5_556 ?
Mn1 Ca1 3.1522(3) 5_566 ?
Mn1 Ca1 3.1981(5) 1_554 ?
Mn1 Ca3 3.2741(5) . ?
Mn1 Ca2 3.4480(3) 5_666 ?
Mn1 Ca2 3.4480(3) 5_656 ?
Mn2 Ca2 3.1952(3) 6_766 ?
Mn2 Ca2 3.1952(3) 6_756 ?
Mn2 Ca2 3.2253(5) 2_456 ?
Mn2 Ca1 3.2927(5) 2_556 ?
Mn2 Ca4 3.3786(4) 5_666 ?
Mn2 Ca4 3.3786(4) 5_656 ?
Ca1 Ca3 3.6923(6) 1_556 ?
Ca2 Ca4 3.6871(6) 2 ?
Ca3 Ca5 3.6629(6) 1_554 ?
Ca3 Ca5 3.7986(4) 6_665 ?
Ca4 Ca5 3.6048(6) 1_554 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Ge1 Ag2 113.508(11) 6_765 6_755 ?
Ag2 Ge1 Mn1 123.161(6) 6_765 1_655 ?
Ag2 Ge1 Mn1 123.161(6) 6_755 1_655 ?
Ag2 Ge1 Ag2 78.146(8) 6_765 2_556 ?
Ag2 Ge1 Ag2 78.146(8) 6_755 2_556 ?
Mn1 Ge1 Ag2 115.870(10) 1_655 2_556 ?
Ag2 Ge1 Ca4 71.440(8) 6_765 2 ?
Ag2 Ge1 Ca4 71.440(8) 6_755 2 ?
Mn1 Ge1 Ca4 121.628(12) 1_655 2 ?
Ag2 Ge1 Ca4 122.502(12) 2_556 2 ?
Ag2 Ge1 Ca2 66.659(8) 6_765 5_766 ?
Ag2 Ge1 Ca2 142.337(12) 6_755 5_766 ?
Mn1 Ge1 Ca2 71.394(9) 1_655 5_766 ?
Ag2 Ge1 Ca2 64.818(9) 2_556 5_766 ?
Ca4 Ge1 Ca2 134.564(6) 2 5_766 ?
Ag2 Ge1 Ca2 142.337(12) 6_765 5_756 ?
Ag2 Ge1 Ca2 66.659(8) 6_755 5_756 ?
Mn1 Ge1 Ca2 71.394(9) 1_655 5_756 ?
Ag2 Ge1 Ca2 64.818(9) 2_556 5_756 ?
Ca4 Ge1 Ca2 134.564(6) 2 5_756 ?
Ca2 Ge1 Ca2 90.493(12) 5_766 5_756 ?
Ag2 Ge1 Ca1 144.011(13) 6_765 5_656 ?
Ag2 Ge1 Ca1 68.061(8) 6_755 5_656 ?
Mn1 Ge1 Ca1 64.169(9) 1_655 5_656 ?
Ag2 Ge1 Ca1 133.726(7) 2_556 5_656 ?
Ca4 Ge1 Ca1 75.777(10) 2 5_656 ?
Ca2 Ge1 Ca1 135.451(13) 5_766 5_656 ?
Ca2 Ge1 Ca1 73.043(10) 5_756 5_656 ?
Ag2 Ge1 Ca1 68.061(8) 6_765 5_666 ?
Ag2 Ge1 Ca1 144.011(13) 6_755 5_666 ?
Mn1 Ge1 Ca1 64.169(9) 1_655 5_666 ?
Ag2 Ge1 Ca1 133.726(7) 2_556 5_666 ?
Ca4 Ge1 Ca1 75.777(10) 2 5_666 ?
Ca2 Ge1 Ca1 73.043(10) 5_766 5_666 ?
Ca2 Ge1 Ca1 135.451(13) 5_756 5_666 ?
Ca1 Ge1 Ca1 90.001(12) 5_656 5_666 ?
Ge3 Ge2 Mn1 122.800(5) 1_556 5_666 ?
Ge3 Ge2 Mn1 122.800(5) 1_556 5_656 ?
Mn1 Ge2 Mn1 113.746(10) 5_666 5_656 ?
Ge3 Ge2 Mn1 105.752(10) 1_556 1_656 ?
Mn1 Ge2 Mn1 77.496(7) 5_666 1_656 ?
Mn1 Ge2 Mn1 77.496(7) 5_656 1_656 ?
Ge3 Ge2 Ca2 129.431(13) 1_556 . ?
Mn1 Ge2 Ca2 73.242(7) 5_666 . ?
Mn1 Ge2 Ca2 73.242(7) 5_656 . ?
Mn1 Ge2 Ca2 124.817(12) 1_656 . ?
Ge3 Ge2 Ca3 68.771(9) 1_556 5_656 ?
Mn1 Ge2 Ca3 147.399(11) 5_666 5_656 ?
Mn1 Ge2 Ca3 68.602(7) 5_656 5_656 ?
Mn1 Ge2 Ca3 131.847(7) 1_656 5_656 ?
Ca2 Ge2 Ca3 76.907(10) . 5_656 ?
Ge3 Ge2 Ca3 68.771(9) 1_556 5_666 ?
Mn1 Ge2 Ca3 68.602(7) 5_666 5_666 ?
Mn1 Ge2 Ca3 147.399(11) 5_656 5_666 ?
Mn1 Ge2 Ca3 131.847(7) 1_656 5_666 ?
Ca2 Ge2 Ca3 76.907(10) . 5_666 ?
Ca3 Ge2 Ca3 92.242(12) 5_656 5_666 ?
Ge3 Ge2 Ca1 66.136(9) 1_556 5_667 ?
Mn1 Ge2 Ca1 65.631(8) 5_666 5_667 ?
Mn1 Ge2 Ca1 140.059(11) 5_656 5_667 ?
Mn1 Ge2 Ca1 63.138(8) 1_656 5_667 ?
Ca2 Ge2 Ca1 135.049(6) . 5_667 ?
Ca3 Ge2 Ca1 134.907(12) 5_656 5_667 ?
Ca3 Ge2 Ca1 71.996(9) 5_666 5_667 ?
Ge3 Ge2 Ca1 66.136(9) 1_556 5_657 ?
Mn1 Ge2 Ca1 140.059(11) 5_666 5_657 ?
Mn1 Ge2 Ca1 65.631(8) 5_656 5_657 ?
Mn1 Ge2 Ca1 63.138(8) 1_656 5_657 ?
Ca2 Ge2 Ca1 135.049(6) . 5_657 ?
Ca3 Ge2 Ca1 71.996(9) 5_656 5_657 ?
Ca3 Ge2 Ca1 134.907(12) 5_666 5_657 ?
Ca1 Ge2 Ca1 89.514(11) 5_667 5_657 ?
Ge3 Ge2 Ca1 163.326(11) 1_556 1_655 ?
Mn1 Ge2 Ca1 57.341(5) 5_666 1_655 ?
Mn1 Ge2 Ca1 57.341(5) 5_656 1_655 ?
Mn1 Ge2 Ca1 57.574(8) 1_656 1_655 ?
Ca2 Ge2 Ca1 67.243(11) . 1_655 ?
Ca3 Ge2 Ca1 121.095(9) 5_656 1_655 ?
Ca3 Ge2 Ca1 121.095(9) 5_666 1_655 ?
Ca1 Ge2 Ca1 102.715(10) 5_667 1_655 ?
Ca1 Ge2 Ca1 102.715(10) 5_657 1_655 ?
Ge2 Ge3 Ge4 104.358(10) 1_554 1_554 ?
Ge2 Ge3 Ca5 131.079(7) 1_554 5_656 ?
Ge4 Ge3 Ca5 67.881(9) 1_554 5_656 ?
Ge2 Ge3 Ca5 131.079(7) 1_554 5_666 ?
Ge4 Ge3 Ca5 67.881(9) 1_554 5_666 ?
Ca5 Ge3 Ca5 92.249(12) 5_656 5_666 ?
Ge2 Ge3 Ca4 123.985(12) 1_554 2 ?
Ge4 Ge3 Ca4 131.657(12) 1_554 2 ?
Ca5 Ge3 Ca4 79.369(10) 5_656 2 ?
Ca5 Ge3 Ca4 79.369(10) 5_666 2 ?
Ge2 Ge3 Ca1 66.279(9) 1_554 5_666 ?
Ge4 Ge3 Ca1 131.739(7) 1_554 5_666 ?
Ca5 Ge3 Ca1 154.323(12) 5_656 5_666 ?
Ca5 Ge3 Ca1 83.399(9) 5_666 5_666 ?
Ca4 Ge3 Ca1 74.956(10) 2 5_666 ?
Ge2 Ge3 Ca1 66.279(9) 1_554 5_656 ?
Ge4 Ge3 Ca1 131.739(7) 1_554 5_656 ?
Ca5 Ge3 Ca1 83.399(9) 5_656 5_656 ?
Ca5 Ge3 Ca1 154.323(12) 5_666 5_656 ?
Ca4 Ge3 Ca1 74.956(10) 2 5_656 ?
Ca1 Ge3 Ca1 89.639(12) 5_666 5_656 ?
Ge2 Ge3 Ca3 63.565(8) 1_554 5_655 ?
Ge4 Ge3 Ca3 63.919(8) 1_554 5_655 ?
Ca5 Ge3 Ca3 70.623(9) 5_656 5_655 ?
Ca5 Ge3 Ca3 131.796(12) 5_666 5_655 ?
Ca4 Ge3 Ca3 136.024(5) 2 5_655 ?
Ca1 Ge3 Ca3 129.843(12) 5_666 5_655 ?
Ca1 Ge3 Ca3 70.400(9) 5_656 5_655 ?
Ge2 Ge3 Ca3 63.565(8) 1_554 5_665 ?
Ge4 Ge3 Ca3 63.919(8) 1_554 5_665 ?
Ca5 Ge3 Ca3 131.796(12) 5_656 5_665 ?
Ca5 Ge3 Ca3 70.623(9) 5_666 5_665 ?
Ca4 Ge3 Ca3 136.024(5) 2 5_665 ?
Ca1 Ge3 Ca3 70.400(9) 5_666 5_665 ?
Ca1 Ge3 Ca3 129.843(12) 5_656 5_665 ?
Ca3 Ge3 Ca3 87.645(11) 5_655 5_665 ?
Ge3 Ge4 Ge5 105.402(10) 1_556 1_556 ?
Ge3 Ge4 Ca3 68.467(9) 1_556 5_666 ?
Ge5 Ge4 Ca3 131.965(7) 1_556 5_666 ?
Ge3 Ge4 Ca3 68.467(9) 1_556 5_656 ?
Ge5 Ge4 Ca3 131.965(7) 1_556 5_656 ?
Ca3 Ge4 Ca3 91.635(12) 5_666 5_656 ?
Ge3 Ge4 Ca4 130.977(7) 1_556 5_656 ?
Ge5 Ge4 Ca4 66.234(9) 1_556 5_656 ?
Ca3 Ge4 Ca4 153.543(13) 5_666 5_656 ?
Ca3 Ge4 Ca4 82.378(9) 5_656 5_656 ?
Ge3 Ge4 Ca4 130.977(7) 1_556 5_666 ?
Ge5 Ge4 Ca4 66.234(9) 1_556 5_666 ?
Ca3 Ge4 Ca4 82.378(9) 5_666 5_666 ?
Ca3 Ge4 Ca4 153.543(13) 5_656 5_666 ?
Ca4 Ge4 Ca4 91.564(12) 5_656 5_666 ?
Ge3 Ge4 Ca5 125.904(12) 1_556 2_556 ?
Ge5 Ge4 Ca5 128.693(12) 1_556 2_556 ?
Ca3 Ge4 Ca5 74.654(9) 5_666 2_556 ?
Ca3 Ge4 Ca5 74.654(9) 5_656 2_556 ?
Ca4 Ge4 Ca5 78.913(10) 5_656 2_556 ?
Ca4 Ge4 Ca5 78.913(10) 5_666 2_556 ?
Ge3 Ge4 Ca5 64.087(8) 1_556 5_667 ?
Ge5 Ge4 Ca5 64.620(8) 1_556 5_667 ?
Ca3 Ge4 Ca5 70.879(9) 5_666 5_667 ?
Ca3 Ge4 Ca5 132.550(12) 5_656 5_667 ?
Ca4 Ge4 Ca5 130.849(12) 5_656 5_667 ?
Ca4 Ge4 Ca5 69.566(9) 5_666 5_667 ?
Ca5 Ge4 Ca5 135.553(5) 2_556 5_667 ?
Ge3 Ge4 Ca5 64.087(8) 1_556 5_657 ?
Ge5 Ge4 Ca5 64.620(8) 1_556 5_657 ?
Ca3 Ge4 Ca5 132.550(12) 5_666 5_657 ?
Ca3 Ge4 Ca5 70.879(9) 5_656 5_657 ?
Ca4 Ge4 Ca5 69.566(9) 5_656 5_657 ?
Ca4 Ge4 Ca5 130.849(12) 5_666 5_657 ?
Ca5 Ge4 Ca5 135.553(5) 2_556 5_657 ?
Ca5 Ge4 Ca5 88.835(11) 5_667 5_657 ?
Ge4 Ge5 Ag2 113.948(11) 1_554 1_554 ?
Ge4 Ge5 Ca2 132.896(7) 1_554 6_755 ?
Ag2 Ge5 Ca2 65.895(9) 1_554 6_755 ?
Ge4 Ge5 Ca2 132.896(7) 1_554 6_765 ?
Ag2 Ge5 Ca2 65.895(9) 1_554 6_765 ?
Ca2 Ge5 Ca2 91.810(12) 6_755 6_765 ?
Ge4 Ge5 Ca5 67.305(9) 1_554 5_666 ?
Ag2 Ge5 Ca5 133.615(6) 1_554 5_666 ?
Ca2 Ge5 Ca5 149.343(13) 6_755 5_666 ?
Ca2 Ge5 Ca5 80.428(9) 6_765 5_666 ?
Ge4 Ge5 Ca5 67.305(9) 1_554 5_656 ?
Ag2 Ge5 Ca5 133.615(6) 1_554 5_656 ?
Ca2 Ge5 Ca5 80.428(9) 6_755 5_656 ?
Ca2 Ge5 Ca5 149.343(13) 6_765 5_656 ?
Ca5 Ge5 Ca5 91.232(12) 5_666 5_656 ?
Ge4 Ge5 Ca4 65.203(9) 1_554 5_655 ?
Ag2 Ge5 Ca4 69.774(9) 1_554 5_655 ?
Ca2 Ge5 Ca4 72.139(9) 6_755 5_655 ?
Ca2 Ge5 Ca4 135.594(13) 6_765 5_655 ?
Ca5 Ge5 Ca4 132.502(12) 5_666 5_655 ?
Ca5 Ge5 Ca4 70.093(9) 5_656 5_655 ?
Ge4 Ge5 Ca4 65.203(9) 1_554 5_665 ?
Ag2 Ge5 Ca4 69.774(9) 1_554 5_665 ?
Ca2 Ge5 Ca4 135.594(13) 6_755 5_665 ?
Ca2 Ge5 Ca4 72.139(9) 6_765 5_665 ?
Ca5 Ge5 Ca4 70.093(9) 5_666 5_665 ?
Ca5 Ge5 Ca4 132.502(12) 5_656 5_665 ?
Ca4 Ge5 Ca4 90.615(11) 5_655 5_665 ?
Ge4 Ge5 Ca3 123.336(12) 1_554 2 ?
Ag2 Ge5 Ca3 122.717(12) 1_554 2 ?
Ca2 Ge5 Ca3 75.329(10) 6_755 2 ?
Ca2 Ge5 Ca3 75.329(10) 6_765 2 ?
Ca5 Ge5 Ca3 74.014(9) 5_666 2 ?
Ca5 Ge5 Ca3 74.014(9) 5_656 2 ?
Ca4 Ge5 Ca3 134.600(6) 5_655 2 ?
Ca4 Ge5 Ca3 134.600(6) 5_665 2 ?
Ge2 Mn1 Ge2 113.748(10) 5_666 5_656 ?
Ge2 Mn1 Ge1 115.707(6) 5_666 1_455 ?
Ge2 Mn1 Ge1 115.707(6) 5_656 1_455 ?
Ge2 Mn1 Ge2 102.503(7) 5_666 1_454 ?
Ge2 Mn1 Ge2 102.503(7) 5_656 1_454 ?
Ge1 Mn1 Ge2 104.125(9) 1_455 1_454 ?
Ge2 Mn1 Ca1 165.051(10) 5_666 5_556 ?
Ge2 Mn1 Ca1 77.138(7) 5_656 5_556 ?
Ge1 Mn1 Ca1 64.613(8) 1_455 5_556 ?
Ge2 Mn1 Ca1 64.058(8) 1_454 5_556 ?
Ge2 Mn1 Ca1 77.138(7) 5_666 5_566 ?
Ge2 Mn1 Ca1 165.051(10) 5_656 5_566 ?
Ge1 Mn1 Ca1 64.613(8) 1_455 5_566 ?
Ge2 Mn1 Ca1 64.058(8) 1_454 5_566 ?
Ca1 Mn1 Ca1 90.426(12) 5_556 5_566 ?
Ge2 Mn1 Ca1 64.826(6) 5_666 1_554 ?
Ge2 Mn1 Ca1 64.826(6) 5_656 1_554 ?
Ge1 Mn1 Ca1 178.575(12) 1_455 1_554 ?
Ge2 Mn1 Ca1 74.451(10) 1_454 1_554 ?
Ca1 Mn1 Ca1 114.501(9) 5_556 1_554 ?
Ca1 Mn1 Ca1 114.501(9) 5_566 1_554 ?
Ge2 Mn1 Ca3 61.964(6) 5_666 . ?
Ge2 Mn1 Ca3 61.964(6) 5_656 . ?
Ge1 Mn1 Ca3 111.866(11) 1_455 . ?
Ge2 Mn1 Ca3 144.009(10) 1_454 . ?
Ca1 Mn1 Ca3 132.723(7) 5_556 . ?
Ca1 Mn1 Ca3 132.723(7) 5_566 . ?
Ca1 Mn1 Ca3 69.558(11) 1_554 . ?
Ge2 Mn1 Ca2 58.869(8) 5_666 5_666 ?
Ge2 Mn1 Ca2 124.733(10) 5_656 5_666 ?
Ge1 Mn1 Ca2 59.986(8) 1_455 5_666 ?
Ge2 Mn1 Ca2 132.699(7) 1_454 5_666 ?
Ca1 Mn1 Ca2 124.511(11) 5_556 5_666 ?
Ca1 Mn1 Ca2 69.242(9) 5_566 5_666 ?
Ca1 Mn1 Ca2 120.952(9) 1_554 5_666 ?
Ca3 Mn1 Ca2 69.766(9) . 5_666 ?
Ge2 Mn1 Ca2 124.733(10) 5_666 5_656 ?
Ge2 Mn1 Ca2 58.869(8) 5_656 5_656 ?
Ge1 Mn1 Ca2 59.986(8) 1_455 5_656 ?
Ge2 Mn1 Ca2 132.699(7) 1_454 5_656 ?
Ca1 Mn1 Ca2 69.242(9) 5_556 5_656 ?
Ca1 Mn1 Ca2 124.511(11) 5_566 5_656 ?
Ca1 Mn1 Ca2 120.952(9) 1_554 5_656 ?
Ca3 Mn1 Ca2 69.766(9) . 5_656 ?
Ca2 Mn1 Ca2 80.907(10) 5_666 5_656 ?
Ge1 Mn2 Ge1 113.508(11) 6_756 6_766 ?
Ge1 Mn2 Ge5 117.349(7) 6_756 1_556 ?
Ge1 Mn2 Ge5 117.349(7) 6_766 1_556 ?
Ge1 Mn2 Ge1 101.855(8) 6_756 2_456 ?
Ge1 Mn2 Ge1 101.855(8) 6_766 2_456 ?
Ge5 Mn2 Ge1 101.064(10) 1_556 2_456 ?
Ge1 Mn2 Ca2 163.628(11) 6_756 6_766 ?
Ge1 Mn2 Ca2 77.778(7) 6_766 6_766 ?
Ge5 Mn2 Ca2 62.862(8) 1_556 6_766 ?
Ge1 Mn2 Ca2 63.159(9) 2_456 6_766 ?
Ge1 Mn2 Ca2 77.778(7) 6_756 6_756 ?
Ge1 Mn2 Ca2 163.628(11) 6_766 6_756 ?
Ge5 Mn2 Ca2 62.862(8) 1_556 6_756 ?
Ge1 Mn2 Ca2 63.159(9) 2_456 6_756 ?
Ca2 Mn2 Ca2 88.883(12) 6_766 6_756 ?
Ge1 Mn2 Ca2 63.744(7) 6_756 2_456 ?
Ge1 Mn2 Ca2 63.744(7) 6_766 2_456 ?
Ge5 Mn2 Ca2 176.869(13) 1_556 2_456 ?
Ge1 Mn2 Ca2 75.806(11) 2_456 2_456 ?
Ca2 Mn2 Ca2 115.180(9) 6_766 2_456 ?
Ca2 Mn2 Ca2 115.180(9) 6_756 2_456 ?
Ge1 Mn2 Ca1 63.037(7) 6_756 2_556 ?
Ge1 Mn2 Ca1 63.037(7) 6_766 2_556 ?
Ge5 Mn2 Ca1 112.727(12) 1_556 2_556 ?
Ge1 Mn2 Ca1 146.210(12) 2_456 2_556 ?
Ca2 Mn2 Ca1 133.066(7) 6_766 2_556 ?
Ca2 Mn2 Ca1 133.066(7) 6_756 2_556 ?
Ca2 Mn2 Ca1 70.404(11) 2_456 2_556 ?
Ge1 Mn2 Ca4 127.326(11) 6_756 5_666 ?
Ge1 Mn2 Ca4 59.919(8) 6_766 5_666 ?
Ge5 Mn2 Ca4 60.928(8) 1_556 5_666 ?
Ge1 Mn2 Ca4 130.777(7) 2_456 5_666 ?
Ca2 Mn2 Ca4 68.165(9) 6_766 5_666 ?
Ca2 Mn2 Ca4 123.734(12) 6_756 5_666 ?
Ca2 Mn2 Ca4 121.087(9) 2_456 5_666 ?
Ca1 Mn2 Ca4 70.217(9) 2_556 5_666 ?
Ge1 Mn2 Ca4 59.919(8) 6_756 5_656 ?
Ge1 Mn2 Ca4 127.326(11) 6_766 5_656 ?
Ge5 Mn2 Ca4 60.928(8) 1_556 5_656 ?
Ge1 Mn2 Ca4 130.777(7) 2_456 5_656 ?
Ca2 Mn2 Ca4 123.734(12) 6_766 5_656 ?
Ca2 Mn2 Ca4 68.165(9) 6_756 5_656 ?
Ca2 Mn2 Ca4 121.087(9) 2_456 5_656 ?
Ca1 Mn2 Ca4 70.217(9) 2_556 5_656 ?
Ca4 Mn2 Ca4 82.930(11) 5_666 5_656 ?
Mn1 Ca1 Mn1 90.428(12) 5_556 5_566 ?
Mn1 Ca1 Ge1 51.217(7) 5_556 5_656 ?
Mn1 Ca1 Ge1 112.171(14) 5_566 5_656 ?
Mn1 Ca1 Ge1 112.171(14) 5_556 5_666 ?
Mn1 Ca1 Ge1 51.217(7) 5_566 5_666 ?
Ge1 Ca1 Ge1 90.001(12) 5_656 5_666 ?
Mn1 Ca1 Ge3 156.958(15) 5_556 5_666 ?
Mn1 Ca1 Ge3 85.391(5) 5_566 5_666 ?
Ge1 Ca1 Ge3 150.111(16) 5_656 5_666 ?
Ge1 Ca1 Ge3 82.538(6) 5_666 5_666 ?
Mn1 Ca1 Ge3 85.391(5) 5_556 5_656 ?
Mn1 Ca1 Ge3 156.958(15) 5_566 5_656 ?
Ge1 Ca1 Ge3 82.538(6) 5_656 5_656 ?
Ge1 Ca1 Ge3 150.111(16) 5_666 5_656 ?
Ge3 Ca1 Ge3 89.640(12) 5_666 5_656 ?
Mn1 Ca1 Ge2 113.259(13) 5_556 5_667 ?
Mn1 Ca1 Ge2 52.802(7) 5_566 5_667 ?
Ge1 Ca1 Ge2 161.254(17) 5_656 5_667 ?
Ge1 Ca1 Ge2 87.203(5) 5_666 5_667 ?
Ge3 Ca1 Ge2 47.583(6) 5_666 5_667 ?
Ge3 Ca1 Ge2 108.548(12) 5_656 5_667 ?
Mn1 Ca1 Ge2 52.802(7) 5_556 5_657 ?
Mn1 Ca1 Ge2 113.259(13) 5_566 5_657 ?
Ge1 Ca1 Ge2 87.203(5) 5_656 5_657 ?
Ge1 Ca1 Ge2 161.254(17) 5_666 5_657 ?
Ge3 Ca1 Ge2 108.548(12) 5_666 5_657 ?
Ge3 Ca1 Ge2 47.583(6) 5_656 5_657 ?
Ge2 Ca1 Ge2 89.514(11) 5_667 5_657 ?
Mn1 Ca1 Mn1 65.498(9) 5_556 1_556 ?
Mn1 Ca1 Mn1 65.498(9) 5_566 1_556 ?
Ge1 Ca1 Mn1 116.705(11) 5_656 1_556 ?
Ge1 Ca1 Mn1 116.705(11) 5_666 1_556 ?
Ge3 Ca1 Mn1 92.302(10) 5_666 1_556 ?
Ge3 Ca1 Mn1 92.302(10) 5_656 1_556 ?
Ge2 Ca1 Mn1 49.543(7) 5_667 1_556 ?
Ge2 Ca1 Mn1 49.543(7) 5_657 1_556 ?
Mn1 Ca1 Ag2 95.030(10) 5_556 2_456 ?
Mn1 Ca1 Ag2 95.030(10) 5_566 2_456 ?
Ge1 Ca1 Ag2 48.903(6) 5_656 2_456 ?
Ge1 Ca1 Ag2 48.903(6) 5_666 2_456 ?
Ge3 Ca1 Ag2 107.894(11) 5_666 2_456 ?
Ge3 Ca1 Ag2 107.894(11) 5_656 2_456 ?
Ge2 Ca1 Ag2 135.028(6) 5_667 2_456 ?
Ge2 Ca1 Ag2 135.028(6) 5_657 2_456 ?
Mn1 Ca1 Ag2 151.084(16) 1_556 2_456 ?
Mn1 Ca1 Ge2 45.521(6) 5_556 1_455 ?
Mn1 Ca1 Ge2 45.521(6) 5_566 1_455 ?
Ge1 Ca1 Ge2 83.991(10) 5_656 1_455 ?
Ge1 Ca1 Ge2 83.991(10) 5_666 1_455 ?
Ge3 Ca1 Ge2 123.571(9) 5_666 1_455 ?
Ge3 Ca1 Ge2 123.571(9) 5_656 1_455 ?
Ge2 Ca1 Ge2 77.284(10) 5_667 1_455 ?
Ge2 Ca1 Ge2 77.284(10) 5_657 1_455 ?
Mn1 Ca1 Ge2 47.974(8) 1_556 1_455 ?
Ag2 Ca1 Ge2 103.110(12) 2_456 1_455 ?
Mn1 Ca1 Ca3 104.027(10) 5_556 1_556 ?
Mn1 Ca1 Ca3 104.027(10) 5_566 1_556 ?
Ge1 Ca1 Ca3 134.722(6) 5_656 1_556 ?
Ge1 Ca1 Ca3 134.722(6) 5_666 1_556 ?
Ge3 Ca1 Ca3 55.523(8) 5_666 1_556 ?
Ge3 Ca1 Ca3 55.524(8) 5_656 1_556 ?
Ge2 Ca1 Ca3 53.078(7) 5_667 1_556 ?
Ge2 Ca1 Ca3 53.078(7) 5_657 1_556 ?
Mn1 Ca1 Ca3 56.190(10) 1_556 1_556 ?
Ag2 Ca1 Ca3 152.726(16) 2_456 1_556 ?
Ge2 Ca1 Ca3 104.164(12) 1_455 1_556 ?
Ge2 Ca2 Ge5 104.899(11) . 6_756 ?
Ge2 Ca2 Ge5 104.899(11) . 6_766 ?
Ge5 Ca2 Ge5 91.808(12) 6_756 6_766 ?
Ge2 Ca2 Ge1 94.401(11) . 5_766 ?
Ge5 Ca2 Ge1 160.531(16) 6_756 5_766 ?
Ge5 Ca2 Ge1 85.571(5) 6_766 5_766 ?
Ge2 Ca2 Ge1 94.401(11) . 5_756 ?
Ge5 Ca2 Ge1 85.571(6) 6_756 5_756 ?
Ge5 Ca2 Ge1 160.531(16) 6_766 5_756 ?
Ge1 Ca2 Ge1 90.496(13) 5_766 5_756 ?
Ge2 Ca2 Ag2 135.083(6) . 6_755 ?
Ge5 Ca2 Ag2 51.243(7) 6_756 6_755 ?
Ge5 Ca2 Ag2 112.314(13) 6_766 6_755 ?
Ge1 Ca2 Ag2 112.281(14) 5_766 6_755 ?
Ge1 Ca2 Ag2 52.024(7) 5_756 6_755 ?
Ge2 Ca2 Ag2 135.083(6) . 6_765 ?
Ge5 Ca2 Ag2 112.314(13) 6_756 6_765 ?
Ge5 Ca2 Ag2 51.243(7) 6_766 6_765 ?
Ge1 Ca2 Ag2 52.024(7) 5_766 6_765 ?
Ge1 Ca2 Ag2 112.281(14) 5_756 6_765 ?
Ag2 Ca2 Ag2 88.884(12) 6_755 6_765 ?
Ge2 Ca2 Ag2 119.245(14) . 2_556 ?
Ge5 Ca2 Ag2 116.014(11) 6_756 2_556 ?
Ge5 Ca2 Ag2 116.014(11) 6_766 2_556 ?
Ge1 Ca2 Ag2 49.599(7) 5_766 2_556 ?
Ge1 Ca2 Ag2 49.599(7) 5_756 2_556 ?
Ag2 Ca2 Ag2 64.822(9) 6_755 2_556 ?
Ag2 Ca2 Ag2 64.822(9) 6_765 2_556 ?
Ge2 Ca2 Mn1 47.890(6) . 5_666 ?
Ge5 Ca2 Mn1 150.570(15) 6_756 5_666 ?
Ge5 Ca2 Mn1 86.503(6) 6_766 5_666 ?
Ge1 Ca2 Mn1 48.621(6) 5_766 5_666 ?
Ge1 Ca2 Mn1 105.100(12) 5_756 5_666 ?
Ag2 Ca2 Mn1 153.686(15) 6_755 5_666 ?
Ag2 Ca2 Mn1 89.300(6) 6_765 5_666 ?
Ag2 Ca2 Mn1 90.789(10) 2_556 5_666 ?
Ge2 Ca2 Mn1 47.890(6) . 5_656 ?
Ge5 Ca2 Mn1 86.503(6) 6_756 5_656 ?
Ge5 Ca2 Mn1 150.570(15) 6_766 5_656 ?
Ge1 Ca2 Mn1 105.100(12) 5_766 5_656 ?
Ge1 Ca2 Mn1 48.621(6) 5_756 5_656 ?
Ag2 Ca2 Mn1 89.300(6) 6_755 5_656 ?
Ag2 Ca2 Mn1 153.686(15) 6_765 5_656 ?
Ag2 Ca2 Mn1 90.789(10) 2_556 5_656 ?
Mn1 Ca2 Mn1 80.907(10) 5_666 5_656 ?
Ge2 Ca2 Ca4 144.759(16) . 2 ?
Ge5 Ca2 Ca4 54.331(8) 6_756 2 ?
Ge5 Ca2 Ca4 54.331(7) 6_766 2 ?
Ge1 Ca2 Ca4 109.947(11) 5_766 2 ?
Ge1 Ca2 Ca4 109.947(11) 5_756 2 ?
Ag2 Ca2 Ca4 58.278(8) 6_755 2 ?
Ag2 Ca2 Ca4 58.278(8) 6_765 2 ?
Ag2 Ca2 Ca4 95.996(13) 2_556 2 ?
Mn1 Ca2 Ca4 139.044(5) 5_666 2 ?
Mn1 Ca2 Ca4 139.044(5) 5_656 2 ?
Ge2 Ca3 Ge2 92.239(12) 5_656 5_666 ?
Ge2 Ca3 Ge4 151.763(15) 5_656 5_666 ?
Ge2 Ca3 Ge4 81.211(6) 5_666 5_666 ?
Ge2 Ca3 Ge4 81.211(6) 5_656 5_656 ?
Ge2 Ca3 Ge4 151.763(15) 5_666 5_656 ?
Ge4 Ca3 Ge4 91.637(12) 5_666 5_656 ?
Ge2 Ca3 Ge5 102.864(10) 5_656 2_455 ?
Ge2 Ca3 Ge5 102.864(10) 5_666 2_455 ?
Ge4 Ca3 Ge5 105.370(10) 5_666 2_455 ?
Ge4 Ca3 Ge5 105.370(10) 5_656 2_455 ?
Ge2 Ca3 Ge3 47.663(6) 5_656 5_655 ?
Ge2 Ca3 Ge3 108.946(12) 5_666 5_655 ?
Ge4 Ca3 Ge3 108.602(12) 5_666 5_655 ?
Ge4 Ca3 Ge3 47.614(6) 5_656 5_655 ?
Ge5 Ca3 Ge3 136.152(5) 2_455 5_655 ?
Ge2 Ca3 Ge3 108.946(12) 5_656 5_665 ?
Ge2 Ca3 Ge3 47.663(6) 5_666 5_665 ?
Ge4 Ca3 Ge3 47.614(6) 5_666 5_665 ?
Ge4 Ca3 Ge3 108.602(12) 5_656 5_665 ?
Ge5 Ca3 Ge3 136.152(5) 2_455 5_665 ?
Ge3 Ca3 Ge3 87.644(11) 5_655 5_665 ?
Ge2 Ca3 Mn1 49.435(6) 5_656 . ?
Ge2 Ca3 Mn1 49.435(6) 5_666 . ?
Ge4 Ca3 Mn1 130.644(7) 5_666 . ?
Ge4 Ca3 Mn1 130.644(7) 5_656 . ?
Ge5 Ca3 Mn1 88.484(11) 2_455 . ?
Ge3 Ca3 Mn1 89.885(10) 5_655 . ?
Ge3 Ca3 Mn1 89.885(10) 5_665 . ?
Ge2 Ca3 Ca5 99.101(10) 5_656 1_554 ?
Ge2 Ca3 Ca5 99.101(10) 5_666 1_554 ?
Ge4 Ca3 Ca5 55.540(7) 5_666 1_554 ?
Ge4 Ca3 Ca5 55.540(7) 5_656 1_554 ?
Ge5 Ca3 Ca5 148.073(15) 2_455 1_554 ?
Ge3 Ca3 Ca5 53.063(7) 5_655 1_554 ?
Ge3 Ca3 Ca5 53.063(7) 5_665 1_554 ?
Mn1 Ca3 Ca5 123.443(13) . 1_554 ?
Ge2 Ca3 Ca1 54.925(8) 5_656 1_554 ?
Ge2 Ca3 Ca1 54.925(8) 5_666 1_554 ?
Ge4 Ca3 Ca1 100.331(10) 5_666 1_554 ?
Ge4 Ca3 Ca1 100.331(10) 5_656 1_554 ?
Ge5 Ca3 Ca1 142.736(15) 2_455 1_554 ?
Ge3 Ca3 Ca1 54.075(7) 5_655 1_554 ?
Ge3 Ca3 Ca1 54.075(7) 5_665 1_554 ?
Mn1 Ca3 Ca1 54.252(10) . 1_554 ?
Ca5 Ca3 Ca1 69.191(12) 1_554 1_554 ?
Ge2 Ca3 Ca5 155.255(14) 5_656 6_665 ?
Ge2 Ca3 Ca5 93.392(6) 5_666 6_665 ?
Ge4 Ca3 Ca5 52.977(8) 5_666 6_665 ?
Ge4 Ca3 Ca5 104.039(12) 5_656 6_665 ?
Ge5 Ca3 Ca5 52.393(8) 2_455 6_665 ?
Ge3 Ca3 Ca5 149.212(14) 5_655 6_665 ?
Ge3 Ca3 Ca5 92.491(6) 5_665 6_665 ?
Mn1 Ca3 Ca5 120.899(11) . 6_665 ?
Ca5 Ca3 Ca5 103.752(9) 1_554 6_665 ?
Ca1 Ca3 Ca5 143.754(5) 1_554 6_665 ?
Ge1 Ca4 Ge4 133.362(6) 2_455 5_656 ?
Ge1 Ca4 Ge4 133.362(6) 2_455 5_666 ?
Ge4 Ca4 Ge4 91.565(12) 5_656 5_666 ?
Ge1 Ca4 Ge3 84.504(11) 2_455 2_455 ?
Ge4 Ca4 Ge3 100.797(10) 5_656 2_455 ?
Ge4 Ca4 Ge3 100.797(10) 5_666 2_455 ?
Ge1 Ca4 Ge5 95.620(10) 2_455 5_655 ?
Ge4 Ca4 Ge5 48.564(6) 5_656 5_655 ?
Ge4 Ca4 Ge5 110.929(13) 5_666 5_655 ?
Ge3 Ca4 Ge5 134.638(6) 2_455 5_655 ?
Ge1 Ca4 Ge5 95.620(10) 2_455 5_665 ?
Ge4 Ca4 Ge5 110.929(13) 5_656 5_665 ?
Ge4 Ca4 Ge5 48.564(6) 5_666 5_665 ?
Ge3 Ca4 Ge5 134.638(6) 2_455 5_665 ?
Ge5 Ca4 Ge5 90.615(11) 5_655 5_665 ?
Ge1 Ca4 Ag2 48.639(6) 2_455 5_666 ?
Ge4 Ca4 Ag2 152.265(14) 5_656 5_666 ?
Ge4 Ca4 Ag2 86.329(6) 5_666 5_666 ?
Ge3 Ca4 Ag2 106.768(10) 2_455 5_666 ?
Ge5 Ca4 Ag2 106.816(12) 5_655 5_666 ?
Ge5 Ca4 Ag2 49.297(7) 5_665 5_666 ?
Ge1 Ca4 Ag2 48.639(7) 2_455 5_656 ?
Ge4 Ca4 Ag2 86.329(6) 5_656 5_656 ?
Ge4 Ca4 Ag2 152.265(14) 5_666 5_656 ?
Ge3 Ca4 Ag2 106.768(10) 2_455 5_656 ?
Ge5 Ca4 Ag2 49.297(7) 5_655 5_656 ?
Ge5 Ca4 Ag2 106.816(12) 5_665 5_656 ?
Ag2 Ca4 Ag2 82.929(11) 5_666 5_656 ?
Ge1 Ca4 Ca5 132.832(15) 2_455 1_554 ?
Ge4 Ca4 Ca5 56.196(8) 5_656 1_554 ?
Ge4 Ca4 Ca5 56.196(8) 5_666 1_554 ?
Ge3 Ca4 Ca5 142.664(15) 2_455 1_554 ?
Ge5 Ca4 Ca5 54.738(7) 5_655 1_554 ?
Ge5 Ca4 Ca5 54.738(7) 5_665 1_554 ?
Ag2 Ca4 Ca5 100.956(10) 5_666 1_554 ?
Ag2 Ca4 Ca5 100.956(10) 5_656 1_554 ?
Ge1 Ca4 Ca2 65.697(11) 2_455 2_455 ?
Ge4 Ca4 Ca2 99.862(10) 5_656 2_455 ?
Ge4 Ca4 Ca2 99.862(10) 5_666 2_455 ?
Ge3 Ca4 Ca2 150.201(15) 2_455 2_455 ?
Ge5 Ca4 Ca2 53.528(7) 5_655 2_455 ?
Ge5 Ca4 Ca2 53.528(7) 5_665 2_455 ?
Ag2 Ca4 Ca2 53.555(7) 5_666 2_455 ?
Ag2 Ca4 Ca2 53.555(7) 5_656 2_455 ?
Ca5 Ca4 Ca2 67.135(12) 1_554 2_455 ?
Ge1 Ca4 Ca1 53.052(8) 2_455 6_665 ?
Ge4 Ca4 Ca1 153.805(14) 5_656 6_665 ?
Ge4 Ca4 Ca1 93.535(6) 5_666 6_665 ?
Ge3 Ca4 Ca1 53.008(8) 2_455 6_665 ?
Ge5 Ca4 Ca1 148.651(15) 5_655 6_665 ?
Ge5 Ca4 Ca1 91.441(7) 5_665 6_665 ?
Ag2 Ca4 Ca1 53.841(8) 5_666 6_665 ?
Ag2 Ca4 Ca1 100.487(12) 5_656 6_665 ?
Ca5 Ca4 Ca1 144.051(5) 1_554 6_665 ?
Ca2 Ca4 Ca1 104.526(12) 2_455 6_665 ?
Ge1 Ca4 Ca1 53.052(8) 2_455 6_655 ?
Ge4 Ca4 Ca1 93.535(6) 5_656 6_655 ?
Ge4 Ca4 Ca1 153.805(14) 5_666 6_655 ?
Ge3 Ca4 Ca1 53.008(8) 2_455 6_655 ?
Ge5 Ca4 Ca1 91.441(7) 5_655 6_655 ?
Ge5 Ca4 Ca1 148.651(15) 5_665 6_655 ?
Ag2 Ca4 Ca1 100.487(12) 5_666 6_655 ?
Ag2 Ca4 Ca1 53.841(8) 5_656 6_655 ?
Ca5 Ca4 Ca1 144.051(5) 1_554 6_655 ?
Ca2 Ca4 Ca1 104.526(12) 2_455 6_655 ?
Ca1 Ca4 Ca1 71.321(10) 6_665 6_655 ?
Ge3 Ca5 Ge3 92.247(12) 5_656 5_666 ?
Ge3 Ca5 Ge5 153.103(15) 5_656 5_666 ?
Ge3 Ca5 Ge5 82.039(6) 5_666 5_666 ?
Ge3 Ca5 Ge5 82.039(6) 5_656 5_656 ?
Ge3 Ca5 Ge5 153.103(15) 5_666 5_656 ?
Ge5 Ca5 Ge5 91.232(12) 5_666 5_656 ?
Ge3 Ca5 Ge4 100.922(10) 5_656 2_456 ?
Ge3 Ca5 Ge4 100.922(10) 5_666 2_456 ?
Ge5 Ca5 Ge4 105.963(10) 5_666 2_456 ?
Ge5 Ca5 Ge4 105.963(10) 5_656 2_456 ?
Ge3 Ca5 Ge4 109.895(12) 5_656 5_667 ?
Ge3 Ca5 Ge4 48.032(6) 5_666 5_667 ?
Ge5 Ca5 Ge4 48.075(6) 5_666 5_667 ?
Ge5 Ca5 Ge4 109.404(12) 5_656 5_667 ?
Ge4 Ca5 Ge4 135.473(6) 2_456 5_667 ?
Ge3 Ca5 Ge4 48.032(6) 5_656 5_657 ?
Ge3 Ca5 Ge4 109.895(12) 5_666 5_657 ?
Ge5 Ca5 Ge4 109.404(12) 5_666 5_657 ?
Ge5 Ca5 Ge4 48.075(6) 5_656 5_657 ?
Ge4 Ca5 Ge4 135.473(6) 2_456 5_657 ?
Ge4 Ca5 Ge4 88.836(11) 5_667 5_657 ?
Ge3 Ca5 Ca4 100.826(10) 5_656 1_556 ?
Ge3 Ca5 Ca4 100.826(10) 5_666 1_556 ?
Ge5 Ca5 Ca4 55.170(7) 5_666 1_556 ?
Ge5 Ca5 Ca4 55.170(7) 5_656 1_556 ?
Ge4 Ca5 Ca4 148.412(15) 2_456 1_556 ?
Ge4 Ca5 Ca4 54.239(7) 5_667 1_556 ?
Ge4 Ca5 Ca4 54.239(7) 5_657 1_556 ?
Ge3 Ca5 Ca3 56.315(8) 5_656 1_556 ?
Ge3 Ca5 Ca3 56.315(8) 5_666 1_556 ?
Ge5 Ca5 Ca3 99.833(10) 5_666 1_556 ?
Ge5 Ca5 Ca3 99.833(10) 5_656 1_556 ?
Ge4 Ca5 Ca3 142.714(15) 2_456 1_556 ?
Ge4 Ca5 Ca3 53.581(7) 5_667 1_556 ?
Ge4 Ca5 Ca3 53.581(7) 5_657 1_556 ?
Ca4 Ca5 Ca3 68.873(12) 1_556 1_556 ?
Ge3 Ca5 Ca3 92.532(6) 5_656 6_656 ?
Ge3 Ca5 Ca3 153.282(14) 5_666 6_656 ?
Ge5 Ca5 Ca3 104.376(12) 5_666 6_656 ?
Ge5 Ca5 Ca3 53.593(8) 5_656 6_656 ?
Ge4 Ca5 Ca3 52.370(8) 2_456 6_656 ?
Ge4 Ca5 Ca3 150.529(14) 5_667 6_656 ?
Ge4 Ca5 Ca3 92.649(6) 5_657 6_656 ?
Ca4 Ca5 Ca3 104.049(12) 1_556 6_656 ?
Ca3 Ca5 Ca3 143.759(5) 1_556 6_656 ?
Ge3 Ca5 Ca3 153.282(14) 5_656 6_666 ?
Ge3 Ca5 Ca3 92.532(6) 5_666 6_666 ?
Ge5 Ca5 Ca3 53.593(8) 5_666 6_666 ?
Ge5 Ca5 Ca3 104.376(12) 5_656 6_666 ?
Ge4 Ca5 Ca3 52.370(8) 2_456 6_666 ?
Ge4 Ca5 Ca3 92.649(6) 5_667 6_666 ?
Ge4 Ca5 Ca3 150.529(14) 5_657 6_666 ?
Ca4 Ca5 Ca3 104.049(12) 1_556 6_666 ?
Ca3 Ca5 Ca3 143.759(5) 1_556 6_666 ?
Ca3 Ca5 Ca3 72.164(10) 6_656 6_666 ?
Ge3 Ca5 Ca4 50.639(8) 5_656 6_656 ?
Ge3 Ca5 Ca4 100.119(11) 5_666 6_656 ?
Ge5 Ca5 Ca4 156.228(13) 5_666 6_656 ?
Ge5 Ca5 Ca4 96.441(6) 5_656 6_656 ?
Ge4 Ca5 Ca4 50.284(7) 2_456 6_656 ?
Ge4 Ca5 Ca4 145.665(13) 5_667 6_656 ?
Ge4 Ca5 Ca4 92.258(7) 5_657 6_656 ?
Ca4 Ca5 Ca4 145.039(6) 1_556 6_656 ?
Ca3 Ca5 Ca4 100.957(11) 1_556 6_656 ?
Ca3 Ca5 Ca4 63.720(9) 6_656 6_656 ?
Ca3 Ca5 Ca4 102.647(12) 6_666 6_656 ?

_refine_diff_density_max         1.374
_refine_diff_density_min         -1.949
_refine_diff_density_rms         0.206

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_global
_audit_block_doi                 10.25505/fiz.icsd.cc2665l6
_database_code_depnum_ccdc_archive 'CCDC 2031727'
loop_
_audit_author_name
_audit_author_address
'Simeon Ponou'
;Department of Chemistry, Lund University 
Sweden
;
_audit_update_record             
;
2020-09-13 deposited with the CCDC.	2021-02-19 downloaded from the CCDC.
;


#==============================================================================

_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.03

_chemical_formula_sum            'Ag1.79 Ca6 Ge5.54 Mn0.67'
_chemical_formula_weight         872.53

#==============================================================================

# CRYSTAL DATA

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/m'
_symmetry_space_group_name_Hall  '-P 2yb'
_cell_length_a                   10.8208(3)
_cell_length_b                   4.49790(10)
_cell_length_c                   14.3546(4)
_cell_angle_alpha                90
_cell_angle_beta                 110.008(3)
_cell_angle_gamma                90
_cell_volume                     656.48(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    3188
_cell_measurement_theta_min      3.7516
_cell_measurement_theta_max      31.9518
_cell_measurement_temperature    293(2)
_exptl_crystal_density_diffrn    4.414
_exptl_crystal_F_000             796
_exptl_absorpt_coefficient_mu    18.026
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
        CrysAlis RED, Oxford Diffraction Ltd.,
        Version 1.171.32.24 (release 21-04-2008 CrysAlis171 .NET)
        (compiled Apr 21 2008,18:23:10)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_correction_T_min  0.17273
_exptl_absorpt_correction_T_max  1

#==============================================================================

# EXPERIMENTAL DATA

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_monochromator  graphite
_diffrn_detector_area_resol_mean 16.5467
_diffrn_reflns_number            6027
_diffrn_reflns_av_R_equivalents  0.0285
_diffrn_reflns_av_unetI/netI     0.0546
_diffrn_reflns_theta_min         3.769
_diffrn_reflns_theta_max         32.138
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.917
_diffrn_measured_fraction_theta_full 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.987
_diffrn_reflns_Laue_measured_fraction_max 0.917
_diffrn_reflns_point_group_measured_fraction_full 0.987
_diffrn_reflns_point_group_measured_fraction_max 0.917
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_limit_l_max       19

#==============================================================================

# STRUCTURE SOLUTION
_computing_structure_solution    
;
SUPERFLIP: Palatinus, L. & Chapuis, G. (2007) J. Appl. Cryst. 40, 786-790.
;


#==============================================================================

# REFINEMENT DATA

_reflns_number_total             2349
_reflns_number_gt                1819
_reflns_threshold_expression     'I > 2σ(I)'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_R_factor_all          0.0642
_refine_ls_R_factor_gt           0.0508
_refine_ls_wR_factor_ref         0.137
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_restrained_S_all      1.058
_refine_ls_number_reflns         2349
_refine_ls_number_parameters     89
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment    undef
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0691P)²+5.2963P] where P=(Fo²+2Fc²)/3'
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_diff_density_max         3.009
_refine_diff_density_min         -1.963
_refine_diff_density_rms         0.463
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.0084(7)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ca Ca 0.2262 0.3064 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_computing_data_collection       
;
        CrysAlis CCD, Oxford Diffraction Ltd.,
        Version 1.171.32.24 (release 21-04-2008 CrysAlis171 .NET)
        (compiled Apr 21 2008,18:23:10)
;
_computing_cell_refinement       
;
        CrysAlis RED, Oxford Diffraction Ltd.,
        Version 1.171.32.24 (release 21-04-2008 CrysAlis171 .NET)
        (compiled Apr 21 2008,18:23:10)
;
_computing_data_reduction        
;
        CrysAlis RED, Oxford Diffraction Ltd.,
        Version 1.171.32.24 (release 21-04-2008 CrysAlis171 .NET)
        (compiled Apr 21 2008,18:23:10)
;
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'

#==============================================================================

# ATOMIC COORDINATES AND DISPLACEMENT PARAMETERS

loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
Ge1 0.12964(9) 0.25 0.95619(7) 0.0105(2) Uani d 1 . . Ge
Ge2 0.49029(8) 0.25 0.88136(8) 0.0210(3) Uani d 0.542(14) . . Ge
Ag2 0.49029(8) 0.25 0.88136(8) 0.0210(3) Uani d 0.458(14) . . Ag
Ge3 0.27635(8) 0.25 0.72302(7) 0.0103(2) Uani d 1 . . Ge
Ge4 0.35515(8) 0.25 0.57257(6) 0.0094(2) Uani d 1 . . Ge
Ge5 0.14261(8) 0.25 0.42370(6) 0.0097(2) Uani d 1 . . Ge
Ge6 0.21618(9) 0.25 0.27043(7) 0.0109(2) Uani d 1 . . Ge
Mn1 0.39081(10) 0.25 0.04043(7) 0.0243(3) Uani d 0.317(8) . . Mn
Ag1 0.39081(10) 0.25 0.04043(7) 0.0243(3) Uani d 0.683(8) . . Ag
Ag3 0.00630(8) 0.25 0.10171(8) 0.0202(3) Uani d 0.649(9) . . Ag
Mn3 0.00630(8) 0.25 0.10171(8) 0.0202(3) Uani d 0.351(9) . . Mn
Ca1 0.78112(18) 0.25 0.88005(13) 0.0138(3) Uani d 1 . . Ca
Ca2 0.85418(16) 0.25 0.42501(13) 0.0104(3) Uani d 1 . . Ca
Ca3 0.50979(16) 0.25 0.27671(13) 0.0108(3) Uani d 1 . . Ca
Ca4 0.71539(17) 0.25 0.12088(13) 0.0123(3) Uani d 1 . . Ca
Ca5 0.99054(16) 0.25 0.72794(13) 0.0108(3) Uani d 1 . . Ca
Ca6 0.64816(16) 0.25 0.57933(13) 0.0104(3) Uani d 1 . . Ca



#==============================================================================

# MOLECULAR GEOMETRY

_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ge1 Ag3 3_556 2.6600(7) ?
Ge1 Ag3 3_566 2.6600(7) ?
Ge1 Mn1 1_556 2.6665(14) ?
Ge1 Ag3 1_556 2.8377(13) ?
Ge1 Ca5 1_455 3.103(2) ?
Ge1 Ca1 3_667 3.1564(14) ?
Ge1 Ca1 3_657 3.1564(14) ?
Ge1 Ca4 3_666 3.2192(13) ?
Ge1 Ca4 3_656 3.2192(13) ?
Ge1 Ca1 1_455 3.549(2) ?
Ag2 Ge3 . 2.6315(13) ?
Ag2 Mn1 3_666 2.6430(7) ?
Ag2 Mn1 3_656 2.6429(7) ?
Ag2 Mn1 1_556 2.8380(14) ?
Ag2 Ca1 . 3.1535(19) ?
Ag2 Ca4 3_656 3.1564(13) ?
Ag2 Ca4 3_666 3.1564(13) ?
Ag2 Ca3 3_656 3.1945(14) ?
Ag2 Ca3 3_666 3.1945(14) ?
Ag2 Ca4 1_556 3.467(2) ?
Ge3 Ge4 . 2.5791(12) ?
Ge3 Ca2 3_656 3.0845(13) ?
Ge3 Ca2 3_666 3.0845(13) ?
Ge3 Ca5 1_455 3.1176(18) ?
Ge3 Ca4 3_666 3.1543(14) ?
Ge3 Ca4 3_656 3.1543(14) ?
Ge3 Ca3 3_666 3.2260(13) ?
Ge3 Ca3 3_656 3.2260(13) ?
Ge4 Ge5 . 2.5481(13) ?
Ge4 Ca3 3_666 3.1162(13) ?
Ge4 Ca3 3_656 3.1162(13) ?
Ge4 Ca6 3_656 3.1241(13) ?
Ge4 Ca6 3_666 3.1241(13) ?
Ge4 Ca6 . 3.1387(18) ?
Ge4 Ca2 3_656 3.2006(13) ?
Ge4 Ca2 3_666 3.2006(13) ?
Ge5 Ge6 . 2.5832(12) ?
Ge5 Ca2 3_666 3.1183(13) ?
Ge5 Ca2 3_656 3.1183(13) ?
Ge5 Ca5 3_656 3.1185(13) ?
Ge5 Ca5 3_666 3.1185(13) ?
Ge5 Ca2 1_455 3.1275(18) ?
Ge5 Ca6 3_666 3.2021(13) ?
Ge5 Ca6 3_656 3.2021(13) ?
Ge6 Ag3 . 2.6944(13) ?
Ge6 Ca6 3_666 3.1140(14) ?
Ge6 Ca6 3_656 3.1140(14) ?
Ge6 Ca1 3_656 3.1253(13) ?
Ge6 Ca1 3_666 3.1253(13) ?
Ge6 Ca3 . 3.1474(18) ?
Ge6 Ca5 3_656 3.1777(13) ?
Ge6 Ca5 3_666 3.1777(13) ?
Ag1 Ca4 3_655 3.1495(14) ?
Ag1 Ca4 3_665 3.1495(14) ?
Ag1 Ca3 . 3.190(2) ?
Ag1 Ca4 . 3.3005(19) ?
Ag1 Ca1 3_656 3.3578(15) ?
Ag1 Ca1 3_666 3.3578(15) ?
Ag3 Ca1 3_666 3.1632(14) ?
Ag3 Ca1 3_656 3.1632(14) ?
Ag3 Ca4 1_455 3.2524(18) ?
Ag3 Ca1 1_454 3.280(2) ?
Ag3 Ca5 3_666 3.3138(14) ?
Ag3 Ca5 3_656 3.3138(14) ?
Ca2 Ca3 . 3.604(2) ?
Ca2 Ca6 . 3.641(2) ?
Ca2 Ca2 3_766 3.873(3) ?
Ca2 Ca2 3_756 3.873(3) ?
Ca2 Ca5 3_756 3.9020(19) ?
Ca3 Ca4 . 3.655(2) ?
Ca3 Ca6 3_666 3.8296(19) ?
Ca5 Ca6 . 3.587(2) ?
Ca6 Ca6 3_656 3.941(3) ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag3 Ge1 Ag3 115.44(4) 3_556 3_566 ?
Ag3 Ge1 Mn1 121.92(2) 3_556 1_556 ?
Ag3 Ge1 Mn1 121.92(2) 3_566 1_556 ?
Ag3 Ge1 Ag3 83.16(3) 3_556 1_556 ?
Ag3 Ge1 Ag3 83.16(3) 3_566 1_556 ?
Mn1 Ge1 Ag3 111.02(4) 1_556 1_556 ?
Ag3 Ge1 Ca5 69.72(3) 3_556 1_455 ?
Ag3 Ge1 Ca5 69.72(3) 3_566 1_455 ?
Mn1 Ge1 Ca5 122.33(5) 1_556 1_455 ?
Ag3 Ge1 Ca5 126.65(5) 1_556 1_455 ?
Ag3 Ge1 Ca1 146.17(5) 3_556 3_667 ?
Ag3 Ge1 Ca1 68.03(3) 3_566 3_667 ?
Mn1 Ge1 Ca1 69.85(4) 1_556 3_667 ?
Ag3 Ge1 Ca1 63.44(3) 1_556 3_667 ?
Ca5 Ge1 Ca1 134.49(3) 1_455 3_667 ?
Ag3 Ge1 Ca1 68.03(3) 3_556 3_657 ?
Ag3 Ge1 Ca1 146.17(5) 3_566 3_657 ?
Mn1 Ge1 Ca1 69.85(4) 1_556 3_657 ?
Ag3 Ge1 Ca1 63.44(3) 1_556 3_657 ?
Ca5 Ge1 Ca1 134.49(3) 1_455 3_657 ?
Ca1 Ge1 Ca1 90.88(5) 3_667 3_657 ?
Ag3 Ge1 Ca4 141.32(5) 3_556 3_666 ?
Ag3 Ge1 Ca4 66.38(3) 3_566 3_666 ?
Mn1 Ge1 Ca4 63.89(4) 1_556 3_666 ?
Ag3 Ge1 Ca4 133.19(3) 1_556 3_666 ?
Ca5 Ge1 Ca4 76.03(4) 1_455 3_666 ?
Ca1 Ge1 Ca4 72.28(4) 3_667 3_666 ?
Ca1 Ge1 Ca4 133.72(5) 3_657 3_666 ?
Ag3 Ge1 Ca4 66.38(3) 3_556 3_656 ?
Ag3 Ge1 Ca4 141.32(5) 3_566 3_656 ?
Mn1 Ge1 Ca4 63.89(4) 1_556 3_656 ?
Ag3 Ge1 Ca4 133.19(3) 1_556 3_656 ?
Ca5 Ge1 Ca4 76.03(4) 1_455 3_656 ?
Ca1 Ge1 Ca4 133.72(5) 3_667 3_656 ?
Ca1 Ge1 Ca4 72.28(4) 3_657 3_656 ?
Ca4 Ge1 Ca4 88.63(5) 3_666 3_656 ?
Ag3 Ge1 Ca1 59.21(2) 3_556 1_455 ?
Ag3 Ge1 Ca1 59.21(2) 3_566 1_455 ?
Mn1 Ge1 Ca1 171.60(5) 1_556 1_455 ?
Ag3 Ge1 Ca1 60.59(4) 1_556 1_455 ?
Ca5 Ge1 Ca1 66.07(4) 1_455 1_455 ?
Ca1 Ge1 Ca1 104.56(4) 3_667 1_455 ?
Ca1 Ge1 Ca1 104.56(4) 3_657 1_455 ?
Ca4 Ge1 Ca1 121.18(4) 3_666 1_455 ?
Ca4 Ge1 Ca1 121.18(4) 3_656 1_455 ?
Ge3 Ag2 Mn1 121.56(2) . 3_666 ?
Ge3 Ag2 Mn1 121.56(3) . 3_656 ?
Mn1 Ag2 Mn1 116.62(5) 3_666 3_656 ?
Ge3 Ag2 Mn1 103.37(4) . 1_556 ?
Mn1 Ag2 Mn1 85.51(4) 3_666 1_556 ?
Mn1 Ag2 Mn1 85.51(4) 3_656 1_556 ?
Ge3 Ag2 Ca1 125.42(5) . . ?
Mn1 Ag2 Ca1 70.17(3) 3_666 . ?
Mn1 Ag2 Ca1 70.17(3) 3_656 . ?
Mn1 Ag2 Ca1 131.21(5) 1_556 . ?
Ge3 Ag2 Ca4 65.31(4) . 3_656 ?
Mn1 Ag2 Ca4 148.18(5) 3_666 3_656 ?
Mn1 Ag2 Ca4 68.72(3) 3_656 3_656 ?
Mn1 Ag2 Ca4 63.13(3) 1_556 3_656 ?
Ca1 Ag2 Ca4 134.55(2) . 3_656 ?
Ge3 Ag2 Ca4 65.31(4) . 3_666 ?
Mn1 Ag2 Ca4 68.72(3) 3_666 3_666 ?
Mn1 Ag2 Ca4 148.18(5) 3_656 3_666 ?
Mn1 Ag2 Ca4 63.13(3) 1_556 3_666 ?
Ca1 Ag2 Ca4 134.55(2) . 3_666 ?
Ca4 Ag2 Ca4 90.88(5) 3_656 3_666 ?
Ge3 Ag2 Ca3 66.43(4) . 3_656 ?
Mn1 Ag2 Ca3 141.50(5) 3_666 3_656 ?
Mn1 Ag2 Ca3 65.45(3) 3_656 3_656 ?
Mn1 Ag2 Ca3 131.57(3) 1_556 3_656 ?
Ca1 Ag2 Ca3 75.73(4) . 3_656 ?
Ca4 Ag2 Ca3 70.27(4) 3_656 3_656 ?
Ca4 Ag2 Ca3 131.72(5) 3_666 3_656 ?
Ge3 Ag2 Ca3 66.43(4) . 3_666 ?
Mn1 Ag2 Ca3 65.45(3) 3_666 3_666 ?
Mn1 Ag2 Ca3 141.50(5) 3_656 3_666 ?
Mn1 Ag2 Ca3 131.57(3) 1_556 3_666 ?
Ca1 Ag2 Ca3 75.73(4) . 3_666 ?
Ca4 Ag2 Ca3 131.72(5) 3_656 3_666 ?
Ca4 Ag2 Ca3 70.27(4) 3_666 3_666 ?
Ca3 Ag2 Ca3 89.50(5) 3_656 3_666 ?
Ge3 Ag2 Ca4 165.55(5) . 1_556 ?
Mn1 Ag2 Ca4 60.27(3) 3_666 1_556 ?
Mn1 Ag2 Ca4 60.27(3) 3_656 1_556 ?
Mn1 Ag2 Ca4 62.18(4) 1_556 1_556 ?
Ca1 Ag2 Ca4 69.03(5) . 1_556 ?
Ca4 Ag2 Ca4 105.29(4) 3_656 1_556 ?
Ca4 Ag2 Ca4 105.29(4) 3_666 1_556 ?
Ca3 Ag2 Ca4 122.25(4) 3_656 1_556 ?
Ca3 Ag2 Ca4 122.25(4) 3_666 1_556 ?
Ge4 Ge3 Ag2 106.15(4) . . ?
Ge4 Ge3 Ca2 68.15(4) . 3_656 ?
Ag2 Ge3 Ca2 130.93(3) . 3_656 ?
Ge4 Ge3 Ca2 68.15(4) . 3_666 ?
Ag2 Ge3 Ca2 130.93(3) . 3_666 ?
Ca2 Ge3 Ca2 93.62(5) 3_656 3_666 ?
Ge4 Ge3 Ca5 129.33(5) . 1_455 ?
Ag2 Ge3 Ca5 124.53(5) . 1_455 ?
Ca2 Ge3 Ca5 77.97(4) 3_656 1_455 ?
Ca2 Ge3 Ca5 77.97(4) 3_666 1_455 ?
Ge4 Ge3 Ca4 131.13(3) . 3_666 ?
Ag2 Ge3 Ca4 65.40(4) . 3_666 ?
Ca2 Ge3 Ca4 154.72(5) 3_656 3_666 ?
Ca2 Ge3 Ca4 82.21(3) 3_666 3_666 ?
Ca5 Ge3 Ca4 76.77(4) 1_455 3_666 ?
Ge4 Ge3 Ca4 131.13(3) . 3_656 ?
Ag2 Ge3 Ca4 65.40(4) . 3_656 ?
Ca2 Ge3 Ca4 82.21(3) 3_656 3_656 ?
Ca2 Ge3 Ca4 154.72(5) 3_666 3_656 ?
Ca5 Ge3 Ca4 76.77(4) 1_455 3_656 ?
Ca4 Ge3 Ca4 90.95(5) 3_666 3_656 ?
Ge4 Ge3 Ca3 63.80(3) . 3_666 ?
Ag2 Ge3 Ca3 65.18(4) . 3_666 ?
Ca2 Ge3 Ca3 131.94(5) 3_656 3_666 ?
Ca2 Ge3 Ca3 69.62(4) 3_666 3_666 ?
Ca5 Ge3 Ca3 135.79(2) 1_455 3_666 ?
Ca4 Ge3 Ca3 69.89(4) 3_666 3_666 ?
Ca4 Ge3 Ca3 130.56(5) 3_656 3_666 ?
Ge4 Ge3 Ca3 63.80(3) . 3_656 ?
Ag2 Ge3 Ca3 65.18(4) . 3_656 ?
Ca2 Ge3 Ca3 69.62(4) 3_656 3_656 ?
Ca2 Ge3 Ca3 131.94(5) 3_666 3_656 ?
Ca5 Ge3 Ca3 135.79(2) 1_455 3_656 ?
Ca4 Ge3 Ca3 130.56(5) 3_666 3_656 ?
Ca4 Ge3 Ca3 69.89(4) 3_656 3_656 ?
Ca3 Ge3 Ca3 88.40(4) 3_666 3_656 ?
Ge5 Ge4 Ge3 103.89(4) . . ?
Ge5 Ge4 Ca3 131.04(3) . 3_666 ?
Ge3 Ge4 Ca3 68.25(3) . 3_666 ?
Ge5 Ge4 Ca3 131.04(3) . 3_656 ?
Ge3 Ge4 Ca3 68.25(3) . 3_656 ?
Ca3 Ge4 Ca3 92.39(5) 3_666 3_656 ?
Ge5 Ge4 Ca6 67.86(4) . 3_656 ?
Ge3 Ge4 Ca6 131.02(3) . 3_656 ?
Ca3 Ge4 Ca6 153.48(5) 3_666 3_656 ?
Ca3 Ge4 Ca6 81.70(3) 3_656 3_656 ?
Ge5 Ge4 Ca6 67.86(4) . 3_666 ?
Ge3 Ge4 Ca6 131.02(3) . 3_666 ?
Ca3 Ge4 Ca6 81.70(3) 3_666 3_666 ?
Ca3 Ge4 Ca6 153.48(5) 3_656 3_666 ?
Ca6 Ge4 Ca6 92.09(5) 3_656 3_666 ?
Ge5 Ge4 Ca6 129.66(5) . . ?
Ge3 Ge4 Ca6 126.44(5) . . ?
Ca3 Ge4 Ca6 75.51(4) 3_666 . ?
Ca3 Ge4 Ca6 75.51(4) 3_656 . ?
Ca6 Ge4 Ca6 77.98(4) 3_656 . ?
Ca6 Ge4 Ca6 77.98(4) 3_666 . ?
Ge5 Ge4 Ca2 64.54(4) . 3_656 ?
Ge3 Ge4 Ca2 63.44(3) . 3_656 ?
Ca3 Ge4 Ca2 131.69(5) 3_666 3_656 ?
Ca3 Ge4 Ca2 69.57(4) 3_656 3_656 ?
Ca6 Ge4 Ca2 70.28(4) 3_656 3_656 ?
Ca6 Ge4 Ca2 132.40(5) 3_666 3_656 ?
Ca6 Ge4 Ca2 135.30(2) . 3_656 ?
Ge5 Ge4 Ca2 64.54(4) . 3_666 ?
Ge3 Ge4 Ca2 63.44(3) . 3_666 ?
Ca3 Ge4 Ca2 69.57(4) 3_666 3_666 ?
Ca3 Ge4 Ca2 131.69(5) 3_656 3_666 ?
Ca6 Ge4 Ca2 132.40(5) 3_656 3_666 ?
Ca6 Ge4 Ca2 70.28(4) 3_666 3_666 ?
Ca6 Ge4 Ca2 135.30(2) . 3_666 ?
Ca2 Ge4 Ca2 89.28(4) 3_656 3_666 ?
Ge4 Ge5 Ge6 105.16(4) . . ?
Ge4 Ge5 Ca2 67.92(4) . 3_666 ?
Ge6 Ge5 Ca2 131.29(3) . 3_666 ?
Ge4 Ge5 Ca2 67.92(4) . 3_656 ?
Ge6 Ge5 Ca2 131.29(3) . 3_656 ?
Ca2 Ge5 Ca2 92.31(5) 3_666 3_656 ?
Ge4 Ge5 Ca5 130.86(3) . 3_656 ?
Ge6 Ge5 Ca5 66.98(3) . 3_656 ?
Ca2 Ge5 Ca5 153.97(5) 3_666 3_656 ?
Ca2 Ge5 Ca5 81.86(3) 3_656 3_656 ?
Ge4 Ge5 Ca5 130.86(3) . 3_666 ?
Ge6 Ge5 Ca5 66.98(3) . 3_666 ?
Ca2 Ge5 Ca5 81.86(3) 3_666 3_666 ?
Ca2 Ge5 Ca5 153.97(5) 3_656 3_666 ?
Ca5 Ge5 Ca5 92.30(5) 3_656 3_666 ?
Ge4 Ge5 Ca2 127.67(5) . 1_455 ?
Ge6 Ge5 Ca2 127.17(5) . 1_455 ?
Ca2 Ge5 Ca2 76.65(4) 3_666 1_455 ?
Ca2 Ge5 Ca2 76.65(4) 3_656 1_455 ?
Ca5 Ge5 Ca2 77.32(4) 3_656 1_455 ?
Ca5 Ge5 Ca2 77.32(4) 3_666 1_455 ?
Ge4 Ge5 Ca6 64.65(4) . 3_666 ?
Ge6 Ge5 Ca6 64.09(3) . 3_666 ?
Ca2 Ge5 Ca6 70.33(4) 3_666 3_666 ?
Ca2 Ge5 Ca6 132.57(5) 3_656 3_666 ?
Ca5 Ge5 Ca6 131.07(5) 3_656 3_666 ?
Ca5 Ge5 Ca6 69.14(4) 3_666 3_666 ?
Ca2 Ge5 Ca6 135.38(2) 1_455 3_666 ?
Ge4 Ge5 Ca6 64.65(4) . 3_656 ?
Ge6 Ge5 Ca6 64.09(3) . 3_656 ?
Ca2 Ge5 Ca6 132.57(5) 3_666 3_656 ?
Ca2 Ge5 Ca6 70.33(4) 3_656 3_656 ?
Ca5 Ge5 Ca6 69.14(4) 3_656 3_656 ?
Ca5 Ge5 Ca6 131.07(5) 3_666 3_656 ?
Ca2 Ge5 Ca6 135.38(2) 1_455 3_656 ?
Ca6 Ge5 Ca6 89.23(5) 3_666 3_656 ?
Ge5 Ge6 Ag3 110.79(4) . . ?
Ge5 Ge6 Ca6 67.65(4) . 3_666 ?
Ag3 Ge6 Ca6 132.47(3) . 3_666 ?
Ge5 Ge6 Ca6 67.65(4) . 3_656 ?
Ag3 Ge6 Ca6 132.47(3) . 3_656 ?
Ca6 Ge6 Ca6 92.47(5) 3_666 3_656 ?
Ge5 Ge6 Ca1 131.85(3) . 3_656 ?
Ag3 Ge6 Ca1 65.36(4) . 3_656 ?
Ca6 Ge6 Ca1 152.21(5) 3_666 3_656 ?
Ca6 Ge6 Ca1 81.10(4) 3_656 3_656 ?
Ge5 Ge6 Ca1 131.85(3) . 3_666 ?
Ag3 Ge6 Ca1 65.36(4) . 3_666 ?
Ca6 Ge6 Ca1 81.10(4) 3_666 3_666 ?
Ca6 Ge6 Ca1 152.21(5) 3_656 3_666 ?
Ca1 Ge6 Ca1 92.04(5) 3_656 3_666 ?
Ge5 Ge6 Ca3 125.30(5) . . ?
Ag3 Ge6 Ca3 123.91(5) . . ?
Ca6 Ge6 Ca3 75.41(4) 3_666 . ?
Ca6 Ge6 Ca3 75.41(4) 3_656 . ?
Ca1 Ge6 Ca3 76.80(4) 3_656 . ?
Ca1 Ge6 Ca3 76.80(4) 3_666 . ?
Ge5 Ge6 Ca5 64.59(3) . 3_656 ?
Ag3 Ge6 Ca5 68.14(4) . 3_656 ?
Ca6 Ge6 Ca5 132.24(5) 3_666 3_656 ?
Ca6 Ge6 Ca5 69.51(4) 3_656 3_656 ?
Ca1 Ge6 Ca5 70.66(4) 3_656 3_656 ?
Ca1 Ge6 Ca5 133.43(5) 3_666 3_656 ?
Ca3 Ge6 Ca5 134.91(2) . 3_656 ?
Ge5 Ge6 Ca5 64.59(3) . 3_666 ?
Ag3 Ge6 Ca5 68.14(4) . 3_666 ?
Ca6 Ge6 Ca5 69.51(4) 3_666 3_666 ?
Ca6 Ge6 Ca5 132.24(5) 3_656 3_666 ?
Ca1 Ge6 Ca5 133.43(5) 3_656 3_666 ?
Ca1 Ge6 Ca5 70.66(4) 3_666 3_666 ?
Ca3 Ge6 Ca5 134.91(2) . 3_666 ?
Ca5 Ge6 Ca5 90.10(5) 3_656 3_666 ?
Ge2 Ag1 Ge2 116.63(5) 3_666 3_656 ?
Ge2 Ag1 Ge1 118.62(3) 3_666 1_554 ?
Ge2 Ag1 Ge1 118.62(3) 3_656 1_554 ?
Ge2 Ag1 Ge2 94.49(4) 3_666 1_554 ?
Ge2 Ag1 Ge2 94.49(4) 3_656 1_554 ?
Ge1 Ag1 Ge2 105.67(4) 1_554 1_554 ?
Ge2 Ag1 Ca4 157.23(5) 3_666 3_655 ?
Ge2 Ag1 Ca4 72.95(3) 3_656 3_655 ?
Ge1 Ag1 Ca4 66.62(4) 1_554 3_655 ?
Ge2 Ag1 Ca4 63.38(3) 1_554 3_655 ?
Ge2 Ag1 Ca4 72.95(3) 3_666 3_665 ?
Ge2 Ag1 Ca4 157.23(5) 3_656 3_665 ?
Ge1 Ag1 Ca4 66.62(4) 1_554 3_665 ?
Ge2 Ag1 Ca4 63.38(3) 1_554 3_665 ?
Ca4 Ag1 Ca4 91.13(5) 3_655 3_665 ?
Ge2 Ag1 Ca3 65.64(3) 3_666 . ?
Ge2 Ag1 Ca3 65.64(3) 3_656 . ?
Ge1 Ag1 Ca3 117.50(5) 1_554 . ?
Ge2 Ag1 Ca3 136.83(5) 1_554 . ?
Ca4 Ag1 Ca3 134.01(3) 3_655 . ?
Ca4 Ag1 Ca3 134.01(3) 3_665 . ?
Ge2 Ag1 Ca4 63.02(3) 3_666 . ?
Ge2 Ag1 Ca4 63.02(3) 3_656 . ?
Ge1 Ag1 Ca4 173.97(5) 1_554 . ?
Ge2 Ag1 Ca4 68.31(4) 1_554 . ?
Ca4 Ag1 Ca4 109.52(4) 3_655 . ?
Ca4 Ag1 Ca4 109.52(4) 3_665 . ?
Ca3 Ag1 Ca4 68.52(4) . . ?
Ge2 Ag1 Ca1 132.17(5) 3_666 3_656 ?
Ge2 Ag1 Ca1 62.06(3) 3_656 3_656 ?
Ge1 Ag1 Ca1 61.94(4) 1_554 3_656 ?
Ge2 Ag1 Ca1 132.87(3) 1_554 3_656 ?
Ca4 Ag1 Ca1 70.52(4) 3_655 3_656 ?
Ca4 Ag1 Ca1 128.53(5) 3_665 3_656 ?
Ca3 Ag1 Ca1 72.99(4) . 3_656 ?
Ca4 Ag1 Ca1 121.87(4) . 3_656 ?
Ge2 Ag1 Ca1 62.06(3) 3_666 3_666 ?
Ge2 Ag1 Ca1 132.17(5) 3_656 3_666 ?
Ge1 Ag1 Ca1 61.94(4) 1_554 3_666 ?
Ge2 Ag1 Ca1 132.87(3) 1_554 3_666 ?
Ca4 Ag1 Ca1 128.53(5) 3_655 3_666 ?
Ca4 Ag1 Ca1 70.52(4) 3_665 3_666 ?
Ca3 Ag1 Ca1 72.99(4) . 3_666 ?
Ca4 Ag1 Ca1 121.87(4) . 3_666 ?
Ca1 Ag1 Ca1 84.10(5) 3_656 3_666 ?
Ge1 Ag3 Ge1 115.44(4) 3_556 3_566 ?
Ge1 Ag3 Ge6 119.13(3) 3_556 . ?
Ge1 Ag3 Ge6 119.13(3) 3_566 . ?
Ge1 Ag3 Ge1 96.84(3) 3_556 1_554 ?
Ge1 Ag3 Ge1 96.84(3) 3_566 1_554 ?
Ge6 Ag3 Ge1 101.40(4) . 1_554 ?
Ge1 Ag3 Ca1 159.34(5) 3_556 3_666 ?
Ge1 Ag3 Ca1 74.54(3) 3_566 3_666 ?
Ge6 Ag3 Ca1 63.90(4) . 3_666 ?
Ge1 Ag3 Ca1 63.20(3) 1_554 3_666 ?
Ge1 Ag3 Ca1 74.54(3) 3_556 3_656 ?
Ge1 Ag3 Ca1 159.34(5) 3_566 3_656 ?
Ge6 Ag3 Ca1 63.90(4) . 3_656 ?
Ge1 Ag3 Ca1 63.20(3) 1_554 3_656 ?
Ca1 Ag3 Ca1 90.63(5) 3_666 3_656 ?
Ge1 Ag3 Ca4 65.08(3) 3_556 1_455 ?
Ge1 Ag3 Ca4 65.08(3) 3_566 1_455 ?
Ge6 Ag3 Ca4 117.81(5) . 1_455 ?
Ge1 Ag3 Ca4 140.79(5) 1_554 1_455 ?
Ca1 Ag3 Ca4 133.67(3) 3_666 1_455 ?
Ca1 Ag3 Ca4 133.67(3) 3_656 1_455 ?
Ge1 Ag3 Ca1 63.19(3) 3_556 1_454 ?
Ge1 Ag3 Ca1 63.19(3) 3_566 1_454 ?
Ge6 Ag3 Ca1 171.90(5) . 1_454 ?
Ge1 Ag3 Ca1 70.50(4) 1_554 1_454 ?
Ca1 Ag3 Ca1 110.99(4) 3_666 1_454 ?
Ca1 Ag3 Ca1 110.99(4) 3_656 1_454 ?
Ca4 Ag3 Ca1 70.29(5) 1_455 1_454 ?
Ge1 Ag3 Ca5 132.02(4) 3_556 3_666 ?
Ge1 Ag3 Ca5 61.43(3) 3_566 3_666 ?
Ge6 Ag3 Ca5 62.87(3) . 3_666 ?
Ge1 Ag3 Ca5 130.88(3) 1_554 3_666 ?
Ca1 Ag3 Ca5 68.46(4) 3_666 3_666 ?
Ca1 Ag3 Ca5 126.71(5) 3_656 3_666 ?
Ca4 Ag3 Ca5 72.75(4) 1_455 3_666 ?
Ca1 Ag3 Ca5 122.18(4) 1_454 3_666 ?
Ge1 Ag3 Ca5 61.43(3) 3_556 3_656 ?
Ge1 Ag3 Ca5 132.02(4) 3_566 3_656 ?
Ge6 Ag3 Ca5 62.87(3) . 3_656 ?
Ge1 Ag3 Ca5 130.88(3) 1_554 3_656 ?
Ca1 Ag3 Ca5 126.71(5) 3_666 3_656 ?
Ca1 Ag3 Ca5 68.46(4) 3_656 3_656 ?
Ca4 Ag3 Ca5 72.75(4) 1_455 3_656 ?
Ca1 Ag3 Ca5 122.18(4) 1_454 3_656 ?
Ca5 Ag3 Ca5 85.48(5) 3_666 3_656 ?
Ge6 Ca1 Ge6 92.04(5) 3_656 3_666 ?
Ge6 Ca1 Ag2 104.45(5) 3_656 . ?
Ge6 Ca1 Ag2 104.45(5) 3_666 . ?
Ge6 Ca1 Ge1 162.67(7) 3_656 3_667 ?
Ge6 Ca1 Ge1 85.94(2) 3_666 3_667 ?
Ag2 Ca1 Ge1 92.71(4) . 3_667 ?
Ge6 Ca1 Ge1 85.939(19) 3_656 3_657 ?
Ge6 Ca1 Ge1 162.67(7) 3_666 3_657 ?
Ag2 Ca1 Ge1 92.71(4) . 3_657 ?
Ge1 Ca1 Ge1 90.88(5) 3_667 3_657 ?
Ge6 Ca1 Ag3 112.97(5) 3_656 3_666 ?
Ge6 Ca1 Ag3 50.73(3) 3_666 3_666 ?
Ag2 Ca1 Ag3 134.30(3) . 3_666 ?
Ge1 Ca1 Ag3 53.36(3) 3_667 3_666 ?
Ge1 Ca1 Ag3 114.61(6) 3_657 3_666 ?
Ge6 Ca1 Ag3 50.73(3) 3_656 3_656 ?
Ge6 Ca1 Ag3 112.97(5) 3_666 3_656 ?
Ag2 Ca1 Ag3 134.30(3) . 3_656 ?
Ge1 Ca1 Ag3 114.61(6) 3_667 3_656 ?
Ge1 Ca1 Ag3 53.36(3) 3_657 3_656 ?
Ag3 Ca1 Ag3 90.63(5) 3_666 3_656 ?
Ge6 Ca1 Ag3 119.41(4) 3_656 1_656 ?
Ge6 Ca1 Ag3 119.41(4) 3_666 1_656 ?
Ag2 Ca1 Ag3 113.95(6) . 1_656 ?
Ge1 Ca1 Ag3 48.78(3) 3_667 1_656 ?
Ge1 Ca1 Ag3 48.78(3) 3_657 1_656 ?
Ag3 Ca1 Ag3 69.01(4) 3_666 1_656 ?
Ag3 Ca1 Ag3 69.01(4) 3_656 1_656 ?
Ge6 Ca1 Mn1 83.70(2) 3_656 3_656 ?
Ge6 Ca1 Mn1 148.67(7) 3_666 3_656 ?
Ag2 Ca1 Mn1 47.77(3) . 3_656 ?
Ge1 Ca1 Mn1 106.73(5) 3_667 3_656 ?
Ge1 Ca1 Mn1 48.20(3) 3_657 3_656 ?
Ag3 Ca1 Mn1 156.90(7) 3_666 3_656 ?
Ag3 Ca1 Mn1 88.14(2) 3_656 3_656 ?
Ag3 Ca1 Mn1 89.10(4) 1_656 3_656 ?
Ge6 Ca1 Mn1 148.67(7) 3_656 3_666 ?
Ge6 Ca1 Mn1 83.70(2) 3_666 3_666 ?
Ag2 Ca1 Mn1 47.77(3) . 3_666 ?
Ge1 Ca1 Mn1 48.20(3) 3_667 3_666 ?
Ge1 Ca1 Mn1 106.73(5) 3_657 3_666 ?
Ag3 Ca1 Mn1 88.14(2) 3_666 3_666 ?
Ag3 Ca1 Mn1 156.90(7) 3_656 3_666 ?
Ag3 Ca1 Mn1 89.10(4) 1_656 3_666 ?
Mn1 Ca1 Mn1 84.10(5) 3_656 3_666 ?
Ge6 Ca1 Ge1 87.29(4) 3_656 1_655 ?
Ge6 Ca1 Ge1 87.29(4) 3_666 1_655 ?
Ag2 Ca1 Ge1 162.86(6) . 1_655 ?
Ge1 Ca1 Ge1 75.44(4) 3_667 1_655 ?
Ge1 Ca1 Ge1 75.44(4) 3_657 1_655 ?
Ag3 Ca1 Ge1 46.25(3) 3_666 1_655 ?
Ag3 Ca1 Ge1 46.25(3) 3_656 1_655 ?
Ag3 Ca1 Ge1 48.91(3) 1_656 1_655 ?
Mn1 Ca1 Ge1 123.31(4) 3_656 1_655 ?
Mn1 Ca1 Ge1 123.31(4) 3_666 1_655 ?
Ge3 Ca2 Ge3 93.62(5) 3_656 3_666 ?
Ge3 Ca2 Ge5 154.03(6) 3_656 3_666 ?
Ge3 Ca2 Ge5 81.22(2) 3_666 3_666 ?
Ge3 Ca2 Ge5 81.22(2) 3_656 3_656 ?
Ge3 Ca2 Ge5 154.03(6) 3_666 3_656 ?
Ge5 Ca2 Ge5 92.31(5) 3_666 3_656 ?
Ge3 Ca2 Ge5 102.62(4) 3_656 1_655 ?
Ge3 Ca2 Ge5 102.62(4) 3_666 1_655 ?
Ge5 Ca2 Ge5 103.35(4) 3_666 1_655 ?
Ge5 Ca2 Ge5 103.35(4) 3_656 1_655 ?
Ge3 Ca2 Ge4 48.41(3) 3_656 3_656 ?
Ge3 Ca2 Ge4 111.15(5) 3_666 3_656 ?
Ge5 Ca2 Ge4 109.79(5) 3_666 3_656 ?
Ge5 Ca2 Ge4 47.54(3) 3_656 3_656 ?
Ge5 Ca2 Ge4 135.36(2) 1_655 3_656 ?
Ge3 Ca2 Ge4 111.15(5) 3_656 3_666 ?
Ge3 Ca2 Ge4 48.41(3) 3_666 3_666 ?
Ge5 Ca2 Ge4 47.54(3) 3_666 3_666 ?
Ge5 Ca2 Ge4 109.79(5) 3_656 3_666 ?
Ge5 Ca2 Ge4 135.36(2) 1_655 3_666 ?
Ge4 Ca2 Ge4 89.28(4) 3_656 3_666 ?
Ge3 Ca2 Ca3 57.04(3) 3_656 . ?
Ge3 Ca2 Ca3 57.04(3) 3_666 . ?
Ge5 Ca2 Ca3 100.03(4) 3_666 . ?
Ge5 Ca2 Ca3 100.03(4) 3_656 . ?
Ge5 Ca2 Ca3 145.97(6) 1_655 . ?
Ge4 Ca2 Ca3 54.12(3) 3_656 . ?
Ge4 Ca2 Ca3 54.12(3) 3_666 . ?
Ge3 Ca2 Ca6 100.82(4) 3_656 . ?
Ge3 Ca2 Ca6 100.82(4) 3_666 . ?
Ge5 Ca2 Ca6 55.91(3) 3_666 . ?
Ge5 Ca2 Ca6 55.91(3) 3_656 . ?
Ge5 Ca2 Ca6 145.46(7) 1_655 . ?
Ge4 Ca2 Ca6 53.87(3) 3_656 . ?
Ge4 Ca2 Ca6 53.87(3) 3_666 . ?
Ca3 Ca2 Ca6 68.58(5) . . ?
Ge3 Ca2 Ca2 154.18(7) 3_656 3_766 ?
Ge3 Ca2 Ca2 93.07(2) 3_666 3_766 ?
Ge5 Ca2 Ca2 51.78(3) 3_666 3_766 ?
Ge5 Ca2 Ca2 102.64(6) 3_656 3_766 ?
Ge5 Ca2 Ca2 51.57(4) 1_655 3_766 ?
Ge4 Ca2 Ca2 147.89(8) 3_656 3_766 ?
Ge4 Ca2 Ca2 91.78(3) 3_666 3_766 ?
Ca3 Ca2 Ca2 144.04(3) . 3_766 ?
Ca6 Ca2 Ca2 102.35(6) . 3_766 ?
Ge3 Ca2 Ca2 93.07(2) 3_656 3_756 ?
Ge3 Ca2 Ca2 154.18(7) 3_666 3_756 ?
Ge5 Ca2 Ca2 102.64(6) 3_666 3_756 ?
Ge5 Ca2 Ca2 51.78(3) 3_656 3_756 ?
Ge5 Ca2 Ca2 51.57(4) 1_655 3_756 ?
Ge4 Ca2 Ca2 91.78(3) 3_656 3_756 ?
Ge4 Ca2 Ca2 147.89(8) 3_666 3_756 ?
Ca3 Ca2 Ca2 144.04(3) . 3_756 ?
Ca6 Ca2 Ca2 102.35(6) . 3_756 ?
Ca2 Ca2 Ca2 70.99(6) 3_766 3_756 ?
Ge3 Ca2 Ca5 51.39(3) 3_656 3_756 ?
Ge3 Ca2 Ca5 102.50(5) 3_666 3_756 ?
Ge5 Ca2 Ca5 154.58(6) 3_666 3_756 ?
Ge5 Ca2 Ca5 94.12(2) 3_656 3_756 ?
Ge5 Ca2 Ca5 51.24(3) 1_655 3_756 ?
Ge4 Ca2 Ca5 92.51(3) 3_656 3_756 ?
Ge4 Ca2 Ca5 148.62(6) 3_666 3_756 ?
Ca3 Ca2 Ca5 103.00(5) . 3_756 ?
Ca6 Ca2 Ca5 144.44(2) . 3_756 ?
Ca2 Ca2 Ca5 102.80(6) 3_766 3_756 ?
Ca2 Ca2 Ca5 63.40(4) 3_756 3_756 ?
Ge4 Ca3 Ge4 92.39(5) 3_666 3_656 ?
Ge4 Ca3 Ge6 104.41(4) 3_666 . ?
Ge4 Ca3 Ge6 104.41(4) 3_656 . ?
Ge4 Ca3 Ag1 131.38(3) 3_666 . ?
Ge4 Ca3 Ag1 131.38(3) 3_656 . ?
Ge6 Ca3 Ag1 86.18(5) . . ?
Ge4 Ca3 Ge2 152.54(6) 3_666 3_656 ?
Ge4 Ca3 Ge2 82.60(2) 3_656 3_656 ?
Ge6 Ca3 Ge2 102.99(4) . 3_656 ?
Ag1 Ca3 Ge2 48.91(3) . 3_656 ?
Ge4 Ca3 Ge2 82.60(2) 3_666 3_666 ?
Ge4 Ca3 Ge2 152.54(6) 3_656 3_666 ?
Ge6 Ca3 Ge2 102.99(4) . 3_666 ?
Ag1 Ca3 Ge2 48.91(3) . 3_666 ?
Ge2 Ca3 Ge2 89.50(5) 3_656 3_666 ?
Ge4 Ca3 Ge3 47.95(3) 3_666 3_666 ?
Ge4 Ca3 Ge3 109.66(5) 3_656 3_666 ?
Ge6 Ca3 Ge3 135.78(2) . 3_666 ?
Ag1 Ca3 Ge3 91.70(4) . 3_666 ?
Ge2 Ca3 Ge3 108.51(5) 3_656 3_666 ?
Ge2 Ca3 Ge3 48.39(3) 3_666 3_666 ?
Ge4 Ca3 Ge3 109.66(5) 3_666 3_656 ?
Ge4 Ca3 Ge3 47.95(3) 3_656 3_656 ?
Ge6 Ca3 Ge3 135.78(2) . 3_656 ?
Ag1 Ca3 Ge3 91.70(4) . 3_656 ?
Ge2 Ca3 Ge3 48.39(3) 3_656 3_656 ?
Ge2 Ca3 Ge3 108.51(5) 3_666 3_656 ?
Ge3 Ca3 Ge3 88.40(4) 3_666 3_656 ?
Ge4 Ca3 Ca2 56.32(3) 3_666 . ?
Ge4 Ca3 Ca2 56.32(3) 3_656 . ?
Ge6 Ca3 Ca2 147.83(6) . . ?
Ag1 Ca3 Ca2 125.99(6) . . ?
Ge2 Ca3 Ca2 99.70(4) 3_656 . ?
Ge2 Ca3 Ca2 99.70(4) 3_666 . ?
Ge3 Ca3 Ca2 53.34(3) 3_666 . ?
Ge3 Ca3 Ca2 53.34(3) 3_656 . ?
Ge4 Ca3 Ca4 100.71(4) 3_666 . ?
Ge4 Ca3 Ca4 100.71(4) 3_656 . ?
Ge6 Ca3 Ca4 143.35(7) . . ?
Ag1 Ca3 Ca4 57.18(4) . . ?
Ge2 Ca3 Ca4 54.38(3) 3_656 . ?
Ge2 Ca3 Ca4 54.38(3) 3_666 . ?
Ge3 Ca3 Ca4 54.14(3) 3_666 . ?
Ge3 Ca3 Ca4 54.14(3) 3_656 . ?
Ca2 Ca3 Ca4 68.82(5) . . ?
Ge4 Ca3 Ca6 52.51(3) 3_666 3_666 ?
Ge4 Ca3 Ca6 103.83(5) 3_656 3_666 ?
Ge6 Ca3 Ca6 51.90(3) . 3_666 ?
Ag1 Ca3 Ca6 118.78(5) . 3_666 ?
Ge2 Ca3 Ca6 154.82(6) 3_656 3_666 ?
Ge2 Ca3 Ca6 94.48(2) 3_666 3_666 ?
Ge3 Ca3 Ca6 92.43(3) 3_666 3_666 ?
Ge3 Ca3 Ca6 149.45(6) 3_656 3_666 ?
Ca2 Ca3 Ca6 104.09(5) . 3_666 ?
Ca4 Ca3 Ca6 143.88(2) . 3_666 ?
Mn1 Ca4 Mn1 91.14(5) 3_655 3_665 ?
Mn1 Ca4 Ge3 161.07(6) 3_655 3_666 ?
Mn1 Ca4 Ge3 85.85(2) 3_665 3_666 ?
Mn1 Ca4 Ge3 85.85(2) 3_655 3_656 ?
Mn1 Ca4 Ge3 161.07(6) 3_665 3_656 ?
Ge3 Ca4 Ge3 90.96(5) 3_666 3_656 ?
Mn1 Ca4 Ge2 53.49(3) 3_655 3_656 ?
Mn1 Ca4 Ge2 115.00(6) 3_665 3_656 ?
Ge3 Ca4 Ge2 111.33(5) 3_666 3_656 ?
Ge3 Ca4 Ge2 49.29(3) 3_656 3_656 ?
Mn1 Ca4 Ge2 115.00(6) 3_655 3_666 ?
Mn1 Ca4 Ge2 53.49(3) 3_665 3_666 ?
Ge3 Ca4 Ge2 49.29(3) 3_666 3_666 ?
Ge3 Ca4 Ge2 111.33(5) 3_656 3_666 ?
Ge2 Ca4 Ge2 90.88(5) 3_656 3_666 ?
Mn1 Ca4 Ge1 110.37(5) 3_655 3_666 ?
Mn1 Ca4 Ge1 49.49(3) 3_665 3_666 ?
Ge3 Ca4 Ge1 81.64(2) 3_666 3_666 ?
Ge3 Ca4 Ge1 148.29(6) 3_656 3_666 ?
Ge2 Ca4 Ge1 160.50(7) 3_656 3_666 ?
Ge2 Ca4 Ge1 86.969(19) 3_666 3_666 ?
Mn1 Ca4 Ge1 49.49(3) 3_655 3_656 ?
Mn1 Ca4 Ge1 110.37(5) 3_665 3_656 ?
Ge3 Ca4 Ge1 148.29(6) 3_666 3_656 ?
Ge3 Ca4 Ge1 81.64(2) 3_656 3_656 ?
Ge2 Ca4 Ge1 86.969(19) 3_656 3_656 ?
Ge2 Ca4 Ge1 160.50(7) 3_666 3_656 ?
Ge1 Ca4 Ge1 88.63(4) 3_666 3_656 ?
Mn1 Ca4 Ag3 93.33(4) 3_655 1_655 ?
Mn1 Ca4 Ag3 93.33(4) 3_665 1_655 ?
Ge3 Ca4 Ag3 105.49(4) 3_666 1_655 ?
Ge3 Ca4 Ag3 105.49(4) 3_656 1_655 ?
Ge2 Ca4 Ag3 134.32(2) 3_656 1_655 ?
Ge2 Ca4 Ag3 134.32(2) 3_666 1_655 ?
Ge1 Ca4 Ag3 48.54(3) 3_666 1_655 ?
Ge1 Ca4 Ag3 48.54(3) 3_656 1_655 ?
Mn1 Ca4 Ag1 70.48(4) 3_655 . ?
Mn1 Ca4 Ag1 70.48(4) 3_665 . ?
Ge3 Ca4 Ag1 90.95(4) 3_666 . ?
Ge3 Ca4 Ag1 90.95(4) 3_656 . ?
Ge2 Ca4 Ag1 48.26(3) 3_656 . ?
Ge2 Ca4 Ag1 48.26(3) 3_666 . ?
Ge1 Ca4 Ag1 119.79(4) 3_666 . ?
Ge1 Ca4 Ag1 119.79(4) 3_656 . ?
Ag3 Ca4 Ag1 156.25(6) 1_655 . ?
Mn1 Ca4 Ge2 46.78(3) 3_655 1_554 ?
Mn1 Ca4 Ge2 46.78(3) 3_665 1_554 ?
Ge3 Ca4 Ge2 122.95(4) 3_666 1_554 ?
Ge3 Ca4 Ge2 122.95(4) 3_656 1_554 ?
Ge2 Ca4 Ge2 74.71(4) 3_656 1_554 ?
Ge2 Ca4 Ge2 74.71(4) 3_666 1_554 ?
Ge1 Ca4 Ge2 86.05(4) 3_666 1_554 ?
Ge1 Ca4 Ge2 86.05(4) 3_656 1_554 ?
Ag3 Ca4 Ge2 106.74(5) 1_655 1_554 ?
Ag1 Ca4 Ge2 49.51(3) . 1_554 ?
Ge1 Ca5 Ge3 84.11(5) 1_655 1_655 ?
Ge1 Ca5 Ge5 132.72(3) 1_655 3_656 ?
Ge3 Ca5 Ge5 102.08(4) 1_655 3_656 ?
Ge1 Ca5 Ge5 132.72(3) 1_655 3_666 ?
Ge3 Ca5 Ge5 102.08(4) 1_655 3_666 ?
Ge5 Ca5 Ge5 92.30(5) 3_656 3_666 ?
Ge1 Ca5 Ge6 94.62(4) 1_655 3_656 ?
Ge3 Ca5 Ge6 134.95(2) 1_655 3_656 ?
Ge5 Ca5 Ge6 48.43(3) 3_656 3_656 ?
Ge5 Ca5 Ge6 110.93(5) 3_666 3_656 ?
Ge1 Ca5 Ge6 94.62(4) 1_655 3_666 ?
Ge3 Ca5 Ge6 134.95(2) 1_655 3_666 ?
Ge5 Ca5 Ge6 110.93(5) 3_656 3_666 ?
Ge5 Ca5 Ge6 48.43(3) 3_666 3_666 ?
Ge6 Ca5 Ge6 90.10(5) 3_656 3_666 ?
Ge1 Ca5 Ag3 48.85(3) 1_655 3_666 ?
Ge3 Ca5 Ag3 104.88(4) 1_655 3_666 ?
Ge5 Ca5 Ag3 152.89(6) 3_656 3_666 ?
Ge5 Ca5 Ag3 84.91(2) 3_666 3_666 ?
Ge6 Ca5 Ag3 107.72(5) 3_656 3_666 ?
Ge6 Ca5 Ag3 48.99(3) 3_666 3_666 ?
Ge1 Ca5 Ag3 48.85(3) 1_655 3_656 ?
Ge3 Ca5 Ag3 104.88(4) 1_655 3_656 ?
Ge5 Ca5 Ag3 84.91(2) 3_656 3_656 ?
Ge5 Ca5 Ag3 152.89(6) 3_666 3_656 ?
Ge6 Ca5 Ag3 48.99(3) 3_656 3_656 ?
Ge6 Ca5 Ag3 107.72(5) 3_666 3_656 ?
Ag3 Ca5 Ag3 85.48(5) 3_666 3_656 ?
Ge1 Ca5 Ca6 131.08(6) 1_655 . ?
Ge3 Ca5 Ca6 144.81(6) 1_655 . ?
Ge5 Ca5 Ca6 56.53(3) 3_656 . ?
Ge5 Ca5 Ca6 56.53(3) 3_666 . ?
Ge6 Ca5 Ca6 54.41(3) 3_656 . ?
Ge6 Ca5 Ca6 54.41(3) 3_666 . ?
Ag3 Ca5 Ca6 100.75(4) 3_666 . ?
Ag3 Ca5 Ca6 100.75(4) 3_656 . ?
Ge1 Ca5 Ca1 62.86(4) 1_655 . ?
Ge3 Ca5 Ca1 146.97(7) 1_655 . ?
Ge5 Ca5 Ca1 100.64(4) 3_656 . ?
Ge5 Ca5 Ca1 100.64(4) 3_666 . ?
Ge6 Ca5 Ca1 54.00(3) 3_656 . ?
Ge6 Ca5 Ca1 54.00(3) 3_666 . ?
Ag3 Ca5 Ca1 53.81(3) 3_666 . ?
Ag3 Ca5 Ca1 53.81(3) 3_656 . ?
Ca6 Ca5 Ca1 68.22(5) . . ?
Ge1 Ca5 Ca4 53.34(3) 1_655 3_766 ?
Ge3 Ca5 Ca4 52.04(3) 1_655 3_766 ?
Ge5 Ca5 Ca4 154.11(5) 3_656 3_766 ?
Ge5 Ca5 Ca4 93.83(3) 3_666 3_766 ?
Ge6 Ca5 Ca4 147.95(6) 3_656 3_766 ?
Ge6 Ca5 Ca4 91.73(3) 3_666 3_766 ?
Ag3 Ca5 Ca4 52.90(3) 3_666 3_766 ?
Ag3 Ca5 Ca4 100.40(5) 3_656 3_766 ?
Ca6 Ca5 Ca4 144.30(2) . 3_766 ?
Ca1 Ca5 Ca4 102.89(5) . 3_766 ?
Ge1 Ca5 Ca4 53.34(3) 1_655 3_756 ?
Ge3 Ca5 Ca4 52.04(3) 1_655 3_756 ?
Ge5 Ca5 Ca4 93.83(3) 3_656 3_756 ?
Ge5 Ca5 Ca4 154.11(5) 3_666 3_756 ?
Ge6 Ca5 Ca4 91.73(3) 3_656 3_756 ?
Ge6 Ca5 Ca4 147.95(6) 3_666 3_756 ?
Ag3 Ca5 Ca4 100.40(5) 3_666 3_756 ?
Ag3 Ca5 Ca4 52.90(3) 3_656 3_756 ?
Ca6 Ca5 Ca4 144.30(2) . 3_756 ?
Ca1 Ca5 Ca4 102.89(5) . 3_756 ?
Ca4 Ca5 Ca4 70.54(4) 3_766 3_756 ?
Ge6 Ca6 Ge6 92.47(5) 3_666 3_656 ?
Ge6 Ca6 Ge4 153.30(6) 3_666 3_656 ?
Ge6 Ca6 Ge4 81.58(2) 3_656 3_656 ?
Ge6 Ca6 Ge4 81.58(2) 3_666 3_666 ?
Ge6 Ca6 Ge4 153.30(6) 3_656 3_666 ?
Ge4 Ca6 Ge4 92.09(5) 3_656 3_666 ?
Ge6 Ca6 Ge4 104.67(4) 3_666 . ?
Ge6 Ca6 Ge4 104.67(4) 3_656 . ?
Ge4 Ca6 Ge4 102.02(4) 3_656 . ?
Ge4 Ca6 Ge4 102.02(4) 3_666 . ?
Ge6 Ca6 Ge5 48.26(3) 3_666 3_666 ?
Ge6 Ca6 Ge5 110.41(5) 3_656 3_666 ?
Ge4 Ca6 Ge5 109.60(5) 3_656 3_666 ?
Ge4 Ca6 Ge5 47.49(3) 3_666 3_666 ?
Ge4 Ca6 Ge5 135.32(2) . 3_666 ?
Ge6 Ca6 Ge5 110.41(5) 3_666 3_656 ?
Ge6 Ca6 Ge5 48.26(3) 3_656 3_656 ?
Ge4 Ca6 Ge5 47.49(3) 3_656 3_656 ?
Ge4 Ca6 Ge5 109.60(5) 3_666 3_656 ?
Ge4 Ca6 Ge5 135.32(2) . 3_656 ?
Ge5 Ca6 Ge5 89.23(4) 3_666 3_656 ?
Ge6 Ca6 Ca5 56.08(3) 3_666 . ?
Ge6 Ca6 Ca5 56.08(3) 3_656 . ?
Ge4 Ca6 Ca5 100.25(4) 3_656 . ?
Ge4 Ca6 Ca5 100.25(4) 3_666 . ?
Ge4 Ca6 Ca5 147.69(6) . . ?
Ge5 Ca6 Ca5 54.33(3) 3_666 . ?
Ge5 Ca6 Ca5 54.33(3) 3_656 . ?
Ge6 Ca6 Ca2 100.35(4) 3_666 . ?
Ge6 Ca6 Ca2 100.35(4) 3_656 . ?
Ge4 Ca6 Ca2 55.84(3) 3_656 . ?
Ge4 Ca6 Ca2 55.84(3) 3_666 . ?
Ge4 Ca6 Ca2 143.47(7) . . ?
Ge5 Ca6 Ca2 53.76(3) 3_666 . ?
Ge5 Ca6 Ca2 53.76(3) 3_656 . ?
Ca5 Ca6 Ca2 68.84(5) . . ?
Ge6 Ca6 Ca3 52.69(3) 3_666 3_666 ?
Ge6 Ca6 Ca3 104.01(5) 3_656 3_666 ?
Ge4 Ca6 Ca3 153.99(6) 3_656 3_666 ?
Ge4 Ca6 Ca3 93.05(2) 3_666 3_666 ?
Ge4 Ca6 Ca3 51.98(3) . 3_666 ?
Ge5 Ca6 Ca3 92.47(3) 3_666 3_666 ?
Ge5 Ca6 Ca3 150.22(6) 3_656 3_666 ?
Ca5 Ca6 Ca3 103.88(5) . 3_666 ?
Ca2 Ca6 Ca3 143.85(2) . 3_666 ?
Ge6 Ca6 Ca3 104.01(5) 3_666 3_656 ?
Ge6 Ca6 Ca3 52.69(3) 3_656 3_656 ?
Ge4 Ca6 Ca3 93.05(2) 3_656 3_656 ?
Ge4 Ca6 Ca3 153.99(6) 3_666 3_656 ?
Ge4 Ca6 Ca3 51.98(3) . 3_656 ?
Ge5 Ca6 Ca3 150.22(6) 3_666 3_656 ?
Ge5 Ca6 Ca3 92.47(3) 3_656 3_656 ?
Ca5 Ca6 Ca3 103.88(5) . 3_656 ?
Ca2 Ca6 Ca3 143.85(2) . 3_656 ?
Ca3 Ca6 Ca3 71.92(4) 3_666 3_656 ?
Ge6 Ca6 Ca6 155.50(7) 3_666 3_656 ?
Ge6 Ca6 Ca6 94.91(2) 3_656 3_656 ?
Ge4 Ca6 Ca6 51.17(3) 3_656 3_656 ?
Ge4 Ca6 Ca6 101.23(6) 3_666 3_656 ?
Ge4 Ca6 Ca6 50.84(4) . 3_656 ?
Ge5 Ca6 Ca6 146.33(7) 3_666 3_656 ?
Ge5 Ca6 Ca6 91.75(3) 3_656 3_656 ?
Ca5 Ca6 Ca6 144.51(3) . 3_656 ?
Ca2 Ca6 Ca6 101.24(6) . 3_656 ?
Ca3 Ca6 Ca6 102.82(6) 3_666 3_656 ?
Ca3 Ca6 Ca6 63.36(4) 3_656 3_656 ?


# END of CIF
