# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 2103757'
loop_
_audit_author_name
_audit_author_address
'Wei Jiang'
;Jilin Normal University
China
;
_audit_update_record             
;
2021-08-17 deposited with the CCDC.	2021-09-20 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        JLNU-91
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C42 H43 Ag3 N6 O8'
_chemical_formula_sum            'C42 H43 Ag3 N6 O8'
_chemical_formula_weight         1083.43

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_H-M_alt        'P 1'
_space_group_name_Hall           'P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'

_cell_length_a                   9.702(5)
_cell_length_b                   10.763(5)
_cell_length_c                   11.435(5)
_cell_angle_alpha                75.894(6)
_cell_angle_beta                 84.943(7)
_cell_angle_gamma                69.928(8)
_cell_volume                     1087.7(9)
_cell_formula_units_Z            1
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    5937
_cell_measurement_theta_min      0.846
_cell_measurement_theta_max      0.846

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.654
_exptl_crystal_F_000             542
_exptl_transmission_factor_min   0.4719
_exptl_transmission_factor_max   0.7455
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.11
_exptl_absorpt_coefficient_mu    1.394
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'Enhance (Mo) X-ray Source'
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scan'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            7266
_diffrn_reflns_av_unetI/netI     0.0394
_diffrn_reflns_av_R_equivalents  0.0204
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         1.836
_diffrn_reflns_theta_max         27.216
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             5937
_reflns_number_gt                5401
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         1.000
_reflns_Friedel_fraction_max     0.987
_reflns_Friedel_fraction_full    0.998

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_reduction        'Bruker XSCANS'
_computing_structure_solution    'SHELXS-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          
'Refined as a 2-component inversion twin.,SQUEEZE'
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0842P)²+0.2529P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.37(4)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         5937
_refine_ls_number_parameters     395
_refine_ls_number_restraints     9
_refine_ls_R_factor_all          0.0457
_refine_ls_R_factor_gt           0.0421
_refine_ls_wR_factor_ref         0.1225
_refine_ls_wR_factor_gt          0.1194
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_restrained_S_all      1.068
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C -0.3515(10) 0.0725(10) -1.0090(6) 0.0435(19) Uani 1 1 d . . . . .
C2 C -0.5088(10) 0.0757(10) -1.0059(8) 0.052(2) Uani 1 1 d . . . . .
H2A H -0.5706 0.1667 -1.0438 0.062 Uiso 1 1 calc R U . . .
H2B H -0.5401 0.0559 -0.9226 0.062 Uiso 1 1 calc R U . . .
C3 C -0.6864(9) -0.0370(10) -1.0381(7) 0.0445(19) Uani 1 1 d . . . . .
C4 C -0.5149(6) 0.0064(5) -1.2079(3) 0.0375(14) Uani 1 1 d G . . . .
C5 C -0.4934(6) -0.0990(4) -1.2650(4) 0.0468(17) Uani 1 1 d G . . . .
H5 H -0.4833 -0.1860 -1.2194 0.056 Uiso 1 1 calc R U . . .
C6 C -0.4871(7) -0.0745(5) -1.3901(4) 0.059(2) Uani 1 1 d G . . . .
H6 H -0.4728 -0.1451 -1.4283 0.071 Uiso 1 1 calc R U . . .
C7 C -0.5023(7) 0.0554(6) -1.4582(3) 0.055(2) Uani 1 1 d G . . . .
H7 H -0.4981 0.0718 -1.5419 0.066 Uiso 1 1 calc R U . . .
C8 C -0.5237(8) 0.1609(4) -1.4011(4) 0.059(2) Uani 1 1 d G . . . .
H8 H -0.5339 0.2478 -1.4466 0.071 Uiso 1 1 calc R U . . .
C9 C -0.5300(7) 0.1364(4) -1.2760(4) 0.0494(18) Uani 1 1 d G . . . .
H9 H -0.5444 0.2069 -1.2378 0.059 Uiso 1 1 calc R U . . .
N1 N -1.0561(6) 0.2047(6) -1.2545(3) 0.0424(17) Uani 1 1 d G . . . .
C10 C -1.1882(4) 0.2509(7) -1.3157(4) 0.042(2) Uani 1 1 d G . . . .
H10 H -1.2766 0.2747 -1.2739 0.051 Uiso 1 1 calc R U . . .
C11 C -1.1884(4) 0.2617(6) -1.4393(4) 0.047(2) Uani 1 1 d G . . . .
H11 H -1.2768 0.2927 -1.4802 0.057 Uiso 1 1 calc R U . . .
C12 C -1.0564(6) 0.2263(6) -1.5017(3) 0.0312(16) Uani 1 1 d G . . . .
C13 C -0.9242(4) 0.1800(7) -1.4405(5) 0.0455(19) Uani 1 1 d G . . . .
H13 H -0.8358 0.1563 -1.4823 0.055 Uiso 1 1 calc R U . . .
C14 C -0.9240(4) 0.1692(7) -1.3169(5) 0.070(4) Uani 1 1 d G . . . .
H14 H -0.8356 0.1383 -1.2760 0.084 Uiso 1 1 calc R U . . .
C15 C -1.0569(6) 0.2320(6) -1.6369(3) 0.0337(16) Uani 1 1 d G . . . .
C16 C -1.1882(5) 0.2748(8) -1.6987(4) 0.062(3) Uani 1 1 d G . . . .
H16 H -1.2770 0.3065 -1.6593 0.074 Uiso 1 1 calc R U . . .
C17 C -1.1869(5) 0.2702(8) -1.8192(4) 0.062(3) Uani 1 1 d G . . . .
H17 H -1.2748 0.2988 -1.8605 0.074 Uiso 1 1 calc R U . . .
N2 N -1.0542(6) 0.2228(7) -1.8779(3) 0.0441(17) Uani 1 1 d G . . . .
C18 C -0.9229(5) 0.1800(8) -1.8162(5) 0.078(4) Uani 1 1 d G . . . .
H18 H -0.8341 0.1483 -1.8555 0.094 Uiso 1 1 calc R U . . .
C19 C -0.9242(5) 0.1846(8) -1.6956(5) 0.069(4) Uani 1 1 d G . . . .
H19 H -0.8363 0.1560 -1.6543 0.083 Uiso 1 1 calc R U . . .
N3 N -0.9570(6) -0.1570(6) -1.1702(3) 0.0420(18) Uani 1 1 d G . . . .
C20 C -1.0911(4) -0.1187(7) -1.2269(4) 0.0381(18) Uani 1 1 d G . . . .
H20 H -1.1779 -0.0961 -1.1830 0.046 Uiso 1 1 calc R U . . .
C21 C -1.0953(4) -0.1142(7) -1.3491(4) 0.046(2) Uani 1 1 d G . . . .
H21 H -1.1849 -0.0886 -1.3870 0.056 Uiso 1 1 calc R U . . .
C22 C -0.9654(6) -0.1480(6) -1.4146(3) 0.0317(16) Uani 1 1 d G . . . .
C23 C -0.8314(4) -0.1862(7) -1.3579(4) 0.049(2) Uani 1 1 d G . . . .
H23 H -0.7445 -0.2088 -1.4017 0.059 Uiso 1 1 calc R U . . .
C24 C -0.8272(4) -0.1907(7) -1.2357(5) 0.061(3) Uani 1 1 d G . . . .
H24 H -0.7375 -0.2164 -1.1977 0.073 Uiso 1 1 calc R U . . .
C25 C -0.9644(6) -0.1466(7) -1.5464(3) 0.0369(19) Uani 1 1 d G . . . .
C26 C -1.0953(5) -0.0953(7) -1.6100(4) 0.043(2) Uani 1 1 d G . . . .
H26 H -1.1838 -0.0610 -1.5711 0.052 Uiso 1 1 calc R U . . .
C27 C -1.0940(4) -0.0953(7) -1.7316(4) 0.038(2) Uani 1 1 d G . . . .
H27 H -1.1816 -0.0609 -1.7742 0.045 Uiso 1 1 calc R U . . .
N4 N -0.9619(5) -0.1465(6) -1.7897(3) 0.0369(16) Uani 1 1 d G . . . .
C28 C -0.8310(4) -0.1977(7) -1.7261(4) 0.073(4) Uani 1 1 d G . . . .
H28 H -0.7426 -0.2320 -1.7649 0.087 Uiso 1 1 calc R U . . .
C29 C -0.8323(5) -0.1978(8) -1.6044(4) 0.059(3) Uani 1 1 d G . . . .
H29 H -0.7447 -0.2321 -1.5619 0.071 Uiso 1 1 calc R U . . .
N5 N -0.9926(6) -0.4751(6) -1.0039(3) 0.0428(18) Uani 1 1 d G . . . .
C30 C -1.1251(5) -0.4460(7) -1.0599(4) 0.053(2) Uani 1 1 d G U . . .
H30 H -1.2126 -0.4243 -1.0167 0.063 Uiso 1 1 calc R U . . .
C31 C -1.1269(5) -0.4493(7) -1.1805(4) 0.055(2) Uani 1 1 d G . . . .
H31 H -1.2156 -0.4298 -1.2180 0.066 Uiso 1 1 calc R U . . .
C32 C -0.9962(6) -0.4817(6) -1.2451(3) 0.0329(17) Uani 1 1 d G . . . .
C33 C -0.8637(5) -0.5108(8) -1.1891(5) 0.058(2) Uani 1 1 d G . . . .
H33 H -0.7763 -0.5324 -1.2324 0.069 Uiso 1 1 calc R U . . .
C34 C -0.8619(5) -0.5075(8) -1.0685(5) 0.076(4) Uani 1 1 d G . . . .
H34 H -0.7732 -0.5270 -1.0311 0.091 Uiso 1 1 calc R U . . .
C35 C -0.9961(6) -0.4753(6) -1.3814(3) 0.0324(16) Uani 1 1 d G . . . .
C36 C -1.1273(4) -0.4254(6) -1.4444(4) 0.0414(19) Uani 1 1 d G . . . .
H36 H -1.2160 -0.3961 -1.4044 0.050 Uiso 1 1 calc R U . . .
C37 C -1.1259(4) -0.4194(6) -1.5673(4) 0.0405(19) Uani 1 1 d G . . . .
H37 H -1.2137 -0.3861 -1.6095 0.049 Uiso 1 1 calc R U . . .
N6 N -0.9933(5) -0.4632(6) -1.6272(3) 0.0338(14) Uani 1 1 d G . . . .
C38 C -0.8621(4) -0.5131(7) -1.5642(4) 0.061(3) Uani 1 1 d G . . . .
H38 H -0.7734 -0.5424 -1.6043 0.073 Uiso 1 1 calc R U . . .
C39 C -0.8635(4) -0.5191(7) -1.4413(4) 0.047(2) Uani 1 1 d G . . . .
H39 H -0.7757 -0.5525 -1.3992 0.057 Uiso 1 1 calc R U . . .
C40 C -0.5313(8) -0.0245(8) -1.0691(7) 0.0408(16) Uani 1 1 d . . . . .
O1 O -0.6940(9) -0.1562(9) -0.9995(7) 0.070(2) Uani 1 1 d . . . . .
O2 O -0.7877(7) 0.0661(9) -1.0529(7) 0.073(2) Uani 1 1 d . . . . .
O3 O -0.2539(8) -0.0435(8) -0.9850(6) 0.0608(17) Uani 1 1 d . . . . .
O4 O -0.3256(11) 0.1770(9) -1.0307(8) 0.081(2) Uani 1 1 d . . . . .
Ag1 Ag -1.06426(7) 0.18298(7) -1.05769(5) 0.05228(19) Uani 1 1 d . . . . .
Ag2 Ag -0.96324(6) -0.13171(6) -0.98421(4) 0.04837(18) Uani 1 1 d . . . . .
Ag3 Ag -1.00353(8) -0.45209(7) -0.81928(5) 0.0567(2) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O4 1.199(12) . ?
C1 O3 1.264(12) . ?
C1 C2 1.512(12) . ?
C2 C40 1.517(11) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 O2 1.190(12) . ?
C3 O1 1.277(12) . ?
C3 C40 1.559(11) . ?
C4 C5 1.3900 . ?
C4 C9 1.3900 . ?
C4 C40 1.546(9) . ?
C5 C6 1.3900 . ?
C5 H5 0.9300 . ?
C6 C7 1.3900 . ?
C6 H6 0.9300 . ?
C7 C8 1.3900 . ?
C7 H7 0.9300 . ?
C8 C9 1.3900 . ?
C8 H8 0.9300 . ?
C9 H9 0.9300 . ?
N1 C10 1.3900 . ?
N1 C14 1.3900 . ?
N1 Ag1 2.202(4) . ?
C10 C11 1.3900 . ?
C10 H10 0.9300 . ?
C11 C12 1.3900 . ?
C11 H11 0.9300 . ?
C12 C13 1.3900 . ?
C12 C15 1.532(5) . ?
C13 C14 1.3900 . ?
C13 H13 0.9300 . ?
C14 H14 0.9300 . ?
C15 C16 1.3900 . ?
C15 C19 1.3900 . ?
C16 C17 1.3900 . ?
C16 H16 0.9300 . ?
C17 N2 1.3900 . ?
C17 H17 0.9300 . ?
N2 C18 1.3900 . ?
N2 Ag1 2.216(4) 1_554 ?
C18 C19 1.3900 . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
N3 C20 1.3900 . ?
N3 C24 1.3900 . ?
N3 Ag2 2.202(3) . ?
C20 C21 1.3900 . ?
C20 H20 0.9300 . ?
C21 C22 1.3900 . ?
C21 H21 0.9300 . ?
C22 C23 1.3900 . ?
C22 C25 1.503(4) . ?
C23 C24 1.3900 . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C26 1.3900 . ?
C25 C29 1.3900 . ?
C26 C27 1.3900 . ?
C26 H26 0.9300 . ?
C27 N4 1.3900 . ?
C27 H27 0.9300 . ?
N4 C28 1.3900 . ?
N4 Ag2 2.192(3) 1_554 ?
C28 C29 1.3900 . ?
C28 H28 0.9300 . ?
C29 H29 0.9300 . ?
N5 C30 1.3900 . ?
N5 C34 1.3900 . ?
N5 Ag3 2.174(3) . ?
C30 C31 1.3900 . ?
C30 H30 0.9300 . ?
C31 C32 1.3900 . ?
C31 H31 0.9300 . ?
C32 C33 1.3900 . ?
C32 C35 1.543(4) . ?
C33 C34 1.3900 . ?
C33 H33 0.9300 . ?
C34 H34 0.9300 . ?
C35 C36 1.3900 . ?
C35 C39 1.3900 . ?
C36 C37 1.3900 . ?
C36 H36 0.9300 . ?
C37 N6 1.3900 . ?
C37 H37 0.9300 . ?
N6 C38 1.3900 . ?
N6 Ag3 2.179(3) 1_554 ?
C38 C39 1.3900 . ?
C38 H38 0.9300 . ?
C39 H39 0.9300 . ?
O1 Ag2 2.528(8) . ?
O2 Ag1 2.542(7) . ?
O4 Ag1 2.548(9) 1_655 ?
Ag1 N2 2.216(8) 1_556 ?
Ag1 O4 2.548(9) 1_455 ?
Ag1 Ag2 3.1013(18) . ?
Ag2 N4 2.192(4) 1_556 ?
Ag3 N6 2.179(3) 1_556 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 C1 O3 123.7(9) . . ?
O4 C1 C2 119.7(9) . . ?
O3 C1 C2 116.6(8) . . ?
C1 C2 C40 113.5(7) . . ?
C1 C2 H2A 108.9 . . ?
C40 C2 H2A 108.9 . . ?
C1 C2 H2B 108.9 . . ?
C40 C2 H2B 108.9 . . ?
H2A C2 H2B 107.7 . . ?
O2 C3 O1 125.7(9) . . ?
O2 C3 C40 116.8(8) . . ?
O1 C3 C40 117.5(8) . . ?
C5 C4 C9 120.0 . . ?
C5 C4 C40 117.8(4) . . ?
C9 C4 C40 122.1(4) . . ?
C6 C5 C4 120.0 . . ?
C6 C5 H5 120.0 . . ?
C4 C5 H5 120.0 . . ?
C7 C6 C5 120.0 . . ?
C7 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C6 C7 C8 120.0 . . ?
C6 C7 H7 120.0 . . ?
C8 C7 H7 120.0 . . ?
C9 C8 C7 120.0 . . ?
C9 C8 H8 120.0 . . ?
C7 C8 H8 120.0 . . ?
C8 C9 C4 120.0 . . ?
C8 C9 H9 120.0 . . ?
C4 C9 H9 120.0 . . ?
C10 N1 C14 120.0 . . ?
C10 N1 Ag1 118.0(3) . . ?
C14 N1 Ag1 122.0(3) . . ?
C11 C10 N1 120.0 . . ?
C11 C10 H10 120.0 . . ?
N1 C10 H10 120.0 . . ?
C10 C11 C12 120.0 . . ?
C10 C11 H11 120.0 . . ?
C12 C11 H11 120.0 . . ?
C13 C12 C11 120.0 . . ?
C13 C12 C15 120.1(4) . . ?
C11 C12 C15 119.9(4) . . ?
C12 C13 C14 120.0 . . ?
C12 C13 H13 120.0 . . ?
C14 C13 H13 120.0 . . ?
C13 C14 N1 120.0 . . ?
C13 C14 H14 120.0 . . ?
N1 C14 H14 120.0 . . ?
C16 C15 C19 120.0 . . ?
C16 C15 C12 120.7(4) . . ?
C19 C15 C12 119.1(4) . . ?
C17 C16 C15 120.0 . . ?
C17 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
C16 C17 N2 120.0 . . ?
C16 C17 H17 120.0 . . ?
N2 C17 H17 120.0 . . ?
C18 N2 C17 120.0 . . ?
C18 N2 Ag1 122.0(3) . 1_554 ?
C17 N2 Ag1 117.0(3) . 1_554 ?
N2 C18 C19 120.0 . . ?
N2 C18 H18 120.0 . . ?
C19 C18 H18 120.0 . . ?
C18 C19 C15 120.0 . . ?
C18 C19 H19 120.0 . . ?
C15 C19 H19 120.0 . . ?
C20 N3 C24 120.0 . . ?
C20 N3 Ag2 117.0(3) . . ?
C24 N3 Ag2 122.4(3) . . ?
N3 C20 C21 120.0 . . ?
N3 C20 H20 120.0 . . ?
C21 C20 H20 120.0 . . ?
C22 C21 C20 120.0 . . ?
C22 C21 H21 120.0 . . ?
C20 C21 H21 120.0 . . ?
C21 C22 C23 120.0 . . ?
C21 C22 C25 121.9(3) . . ?
C23 C22 C25 118.1(3) . . ?
C24 C23 C22 120.0 . . ?
C24 C23 H23 120.0 . . ?
C22 C23 H23 120.0 . . ?
C23 C24 N3 120.0 . . ?
C23 C24 H24 120.0 . . ?
N3 C24 H24 120.0 . . ?
C26 C25 C29 120.0 . . ?
C26 C25 C22 120.2(3) . . ?
C29 C25 C22 119.8(3) . . ?
C27 C26 C25 120.0 . . ?
C27 C26 H26 120.0 . . ?
C25 C26 H26 120.0 . . ?
N4 C27 C26 120.0 . . ?
N4 C27 H27 120.0 . . ?
C26 C27 H27 120.0 . . ?
C27 N4 C28 120.0 . . ?
C27 N4 Ag2 118.8(3) . 1_554 ?
C28 N4 Ag2 121.1(3) . 1_554 ?
C29 C28 N4 120.0 . . ?
C29 C28 H28 120.0 . . ?
N4 C28 H28 120.0 . . ?
C28 C29 C25 120.0 . . ?
C28 C29 H29 120.0 . . ?
C25 C29 H29 120.0 . . ?
C30 N5 C34 120.0 . . ?
C30 N5 Ag3 116.9(3) . . ?
C34 N5 Ag3 122.9(3) . . ?
N5 C30 C31 120.0 . . ?
N5 C30 H30 120.0 . . ?
C31 C30 H30 120.0 . . ?
C32 C31 C30 120.0 . . ?
C32 C31 H31 120.0 . . ?
C30 C31 H31 120.0 . . ?
C31 C32 C33 120.0 . . ?
C31 C32 C35 121.0(4) . . ?
C33 C32 C35 118.8(4) . . ?
C34 C33 C32 120.0 . . ?
C34 C33 H33 120.0 . . ?
C32 C33 H33 120.0 . . ?
C33 C34 N5 120.0 . . ?
C33 C34 H34 120.0 . . ?
N5 C34 H34 120.0 . . ?
C36 C35 C39 120.0 . . ?
C36 C35 C32 120.5(4) . . ?
C39 C35 C32 119.5(4) . . ?
C35 C36 C37 120.0 . . ?
C35 C36 H36 120.0 . . ?
C37 C36 H36 120.0 . . ?
C36 C37 N6 120.0 . . ?
C36 C37 H37 120.0 . . ?
N6 C37 H37 120.0 . . ?
C38 N6 C37 120.0 . . ?
C38 N6 Ag3 122.9(3) . 1_554 ?
C37 N6 Ag3 117.1(3) . 1_554 ?
N6 C38 C39 120.0 . . ?
N6 C38 H38 120.0 . . ?
C39 C38 H38 120.0 . . ?
C38 C39 C35 120.0 . . ?
C38 C39 H39 120.0 . . ?
C35 C39 H39 120.0 . . ?
C2 C40 C4 116.5(6) . . ?
C2 C40 C3 109.9(6) . . ?
C4 C40 C3 107.6(5) . . ?
C3 O1 Ag2 107.1(6) . . ?
C3 O2 Ag1 148.3(7) . . ?
C1 O4 Ag1 122.0(8) . 1_655 ?
N1 Ag1 N2 161.2(10) . 1_556 ?
N1 Ag1 O2 88.6(2) . . ?
N2 Ag1 O2 89.5(7) 1_556 . ?
N1 Ag1 O4 95.7(3) . 1_455 ?
N2 Ag1 O4 94.8(8) 1_556 1_455 ?
O2 Ag1 O4 151.8(3) . 1_455 ?
N1 Ag1 Ag2 97.59(17) . . ?
N2 Ag1 Ag2 98.5(9) 1_556 . ?
O2 Ag1 Ag2 65.3(2) . . ?
O4 Ag1 Ag2 86.5(2) 1_455 . ?
N4 Ag2 N3 169.6(10) 1_556 . ?
N4 Ag2 O1 90.8(8) 1_556 . ?
N3 Ag2 O1 89.9(2) . . ?
N4 Ag2 Ag1 95.7(10) 1_556 . ?
N3 Ag2 Ag1 94.64(16) . . ?
O1 Ag2 Ag1 93.28(19) . . ?
N5 Ag3 N6 170.9(8) . 1_556 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O4 C1 C2 C40 136.5(9) . . . . ?
O3 C1 C2 C40 -45.2(10) . . . . ?
C9 C4 C5 C6 0.0 . . . . ?
C40 C4 C5 C6 176.0(5) . . . . ?
C4 C5 C6 C7 0.0 . . . . ?
C5 C6 C7 C8 0.0 . . . . ?
C6 C7 C8 C9 0.0 . . . . ?
C7 C8 C9 C4 0.0 . . . . ?
C5 C4 C9 C8 0.0 . . . . ?
C40 C4 C9 C8 -175.9(5) . . . . ?
C14 N1 C10 C11 0.0 . . . . ?
Ag1 N1 C10 C11 -177.8(4) . . . . ?
N1 C10 C11 C12 0.0 . . . . ?
C10 C11 C12 C13 0.0 . . . . ?
C10 C11 C12 C15 177.2(6) . . . . ?
C11 C12 C13 C14 0.0 . . . . ?
C15 C12 C13 C14 -177.2(6) . . . . ?
C12 C13 C14 N1 0.0 . . . . ?
C10 N1 C14 C13 0.0 . . . . ?
Ag1 N1 C14 C13 177.7(4) . . . . ?
C13 C12 C15 C16 178.4(4) . . . . ?
C11 C12 C15 C16 1.2(7) . . . . ?
C13 C12 C15 C19 2.9(7) . . . . ?
C11 C12 C15 C19 -174.2(4) . . . . ?
C19 C15 C16 C17 0.0 . . . . ?
C12 C15 C16 C17 -175.4(6) . . . . ?
C15 C16 C17 N2 0.0 . . . . ?
C16 C17 N2 C18 0.0 . . . . ?
C16 C17 N2 Ag1 168.8(4) . . . 1_554 ?
C17 N2 C18 C19 0.0 . . . . ?
Ag1 N2 C18 C19 -168.3(5) 1_554 . . . ?
N2 C18 C19 C15 0.0 . . . . ?
C16 C15 C19 C18 0.0 . . . . ?
C12 C15 C19 C18 175.5(6) . . . . ?
C24 N3 C20 C21 0.0 . . . . ?
Ag2 N3 C20 C21 171.2(4) . . . . ?
N3 C20 C21 C22 0.0 . . . . ?
C20 C21 C22 C23 0.0 . . . . ?
C20 C21 C22 C25 179.1(6) . . . . ?
C21 C22 C23 C24 0.0 . . . . ?
C25 C22 C23 C24 -179.1(5) . . . . ?
C22 C23 C24 N3 0.0 . . . . ?
C20 N3 C24 C23 0.0 . . . . ?
Ag2 N3 C24 C23 -170.7(4) . . . . ?
C21 C22 C25 C26 7.8(7) . . . . ?
C23 C22 C25 C26 -173.1(4) . . . . ?
C21 C22 C25 C29 -171.7(4) . . . . ?
C23 C22 C25 C29 7.4(6) . . . . ?
C29 C25 C26 C27 0.0 . . . . ?
C22 C25 C26 C27 -179.5(6) . . . . ?
C25 C26 C27 N4 0.0 . . . . ?
C26 C27 N4 C28 0.0 . . . . ?
C26 C27 N4 Ag2 -175.9(4) . . . 1_554 ?
C27 N4 C28 C29 0.0 . . . . ?
Ag2 N4 C28 C29 175.8(4) 1_554 . . . ?
N4 C28 C29 C25 0.0 . . . . ?
C26 C25 C29 C28 0.0 . . . . ?
C22 C25 C29 C28 179.5(6) . . . . ?
C34 N5 C30 C31 0.0 . . . . ?
Ag3 N5 C30 C31 175.5(4) . . . . ?
N5 C30 C31 C32 0.0 . . . . ?
C30 C31 C32 C33 0.0 . . . . ?
C30 C31 C32 C35 -175.3(6) . . . . ?
C31 C32 C33 C34 0.0 . . . . ?
C35 C32 C33 C34 175.4(6) . . . . ?
C32 C33 C34 N5 0.0 . . . . ?
C30 N5 C34 C33 0.0 . . . . ?
Ag3 N5 C34 C33 -175.2(4) . . . . ?
C31 C32 C35 C36 5.7(7) . . . . ?
C33 C32 C35 C36 -169.6(4) . . . . ?
C31 C32 C35 C39 -174.7(4) . . . . ?
C33 C32 C35 C39 10.0(6) . . . . ?
C39 C35 C36 C37 0.0 . . . . ?
C32 C35 C36 C37 179.6(5) . . . . ?
C35 C36 C37 N6 0.0 . . . . ?
C36 C37 N6 C38 0.0 . . . . ?
C36 C37 N6 Ag3 179.2(4) . . . 1_554 ?
C37 N6 C38 C39 0.0 . . . . ?
Ag3 N6 C38 C39 -179.1(4) 1_554 . . . ?
N6 C38 C39 C35 0.0 . . . . ?
C36 C35 C39 C38 0.0 . . . . ?
C32 C35 C39 C38 -179.6(5) . . . . ?
C1 C2 C40 C4 -69.5(9) . . . . ?
C1 C2 C40 C3 167.8(8) . . . . ?
C5 C4 C40 C2 162.2(5) . . . . ?
C9 C4 C40 C2 -21.8(8) . . . . ?
C5 C4 C40 C3 -73.9(7) . . . . ?
C9 C4 C40 C3 102.0(6) . . . . ?
O2 C3 C40 C2 51.6(9) . . . . ?
O1 C3 C40 C2 -128.5(8) . . . . ?
O2 C3 C40 C4 -76.2(8) . . . . ?
O1 C3 C40 C4 103.7(8) . . . . ?
O2 C3 O1 Ag2 6.4(10) . . . . ?
C40 C3 O1 Ag2 -173.5(5) . . . . ?
O1 C3 O2 Ag1 -7.8(17) . . . . ?
C40 C3 O2 Ag1 172.1(8) . . . . ?
O3 C1 O4 Ag1 7.8(12) . . . 1_655 ?
C2 C1 O4 Ag1 -174.1(5) . . . 1_655 ?

_refine_diff_density_max         1.815
_refine_diff_density_min         -0.936
_refine_diff_density_rms         0.115




