# Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics.
# This journal is © the Owner Societies 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_eup
_database_code_depnum_ccdc_archive 'CCDC 2081275'
loop_
_audit_author_name
_audit_author_address
'Mikhail Kiskin'
;Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2021-04-30 deposited with the CCDC.	2021-10-25 downloaded from the CCDC.
;
_audit_creation_date             2021-01-29
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C36 H29 Eu N2 O6 S3'
_chemical_formula_sum            'C36 H29 Eu N2 O6 S3'
_chemical_formula_weight         833.75
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.1817(5)
_cell_length_b                   13.0615(7)
_cell_length_c                   15.0182(8)
_cell_angle_alpha                96.107(2)
_cell_angle_beta                 92.850(2)
_cell_angle_gamma                104.079(2)
_cell_volume                     1731.72(16)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9837
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      30.51
_cell_measurement_theta_min      2.45
_shelx_estimated_absorpt_T_max   0.887
_shelx_estimated_absorpt_T_min   0.750
_exptl_absorpt_coefficient_mu    2.040
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6023
_exptl_absorpt_correction_type   'multi scan'
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1124 before and 0.0390 after correction.
The Ratio of minimum to maximum transmission is 0.8073.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.599
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       parallelepiped
_exptl_crystal_F_000             836
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1447
_diffrn_reflns_av_unetI/netI     0.0904
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            23879
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.366
_diffrn_reflns_theta_min         2.455
_diffrn_ambient_temperature      150.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6560
_reflns_number_total             7066
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         2.057
_refine_diff_density_min         -2.021
_refine_diff_density_rms         0.148
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     436
_refine_ls_number_reflns         7066
_refine_ls_number_restraints     15
_refine_ls_R_factor_all          0.0508
_refine_ls_R_factor_gt           0.0484
_refine_ls_restrained_S_all      1.054
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0562P)²+2.1583P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1215
_refine_ls_wR_factor_ref         0.1233
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Rigid body (RIGU) restrains
 C20, C21, C21, C22, C22, C23
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.008
3.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C5(H5), C6(H6), C7(H7), C10(H10), C13(H13), C14(H14), C15(H15),
 C18(H18), C21(H21), C22(H22), C23(H23), C25(H25), C26(H26), C27(H27), C30(H30),
  C31(H31), C32(H32), C35(H35), C36(H36)
3.b Idealised Me refined as rotating group:
 C8(H8A,H8B,H8C), C16(H16A,H16B,H16C), C24(H24A,H24B,H24C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.59281(2) 0.77717(2) 0.24974(2) 0.02557(10) Uani 1 1 d . . . . .
N1 N 0.3424(4) 0.8355(3) 0.2396(2) 0.0293(8) Uani 1 1 d . . . . .
N2 N 0.5850(4) 0.9403(3) 0.1611(2) 0.0300(8) Uani 1 1 d . . . . .
O1 O 0.5023(3) 0.7932(3) 0.39279(19) 0.0334(7) Uani 1 1 d . . . . .
O2 O 0.7483(3) 0.9309(3) 0.3346(2) 0.0326(7) Uani 1 1 d . . . . .
O3 O 0.4509(3) 0.6068(3) 0.2691(2) 0.0328(7) Uani 1 1 d . . . . .
O4 O 0.7518(3) 0.6974(3) 0.3326(2) 0.0343(7) Uani 1 1 d . . . . .
O5 O 0.4750(3) 0.6974(3) 0.10694(19) 0.0330(7) Uani 1 1 d . . . . .
O6 O 0.7820(3) 0.7764(3) 0.1506(2) 0.0330(7) Uani 1 1 d . . . . .
C1 C 0.5468(5) 0.8458(4) 0.4678(3) 0.0268(9) Uani 1 1 d . . . . .
C2 C 0.6713(5) 0.9331(4) 0.4826(3) 0.0390(12) Uani 1 1 d . . . . .
H2 H 0.6952 0.9682 0.5422 0.047 Uiso 1 1 calc R . . . .
C3 C 0.7627(5) 0.9725(4) 0.4170(3) 0.0337(10) Uani 1 1 d . . . . .
C4 C 0.4548(5) 0.8084(4) 0.5419(3) 0.0326(10) Uani 1 1 d . . . . .
C5 C 0.4760(5) 0.8536(4) 0.6408(3) 0.0352(11) Uani 1 1 d . . . . .
H5 H 0.5488 0.9141 0.6699 0.042 Uiso 1 1 calc R . . . .
C6 C 0.3530(7) 0.7784(6) 0.6804(4) 0.0587(17) Uani 1 1 d . . . . .
H6 H 0.3378 0.7870 0.7426 0.070 Uiso 1 1 calc R . . . .
C7 C 0.2651(6) 0.6981(5) 0.6234(4) 0.0507(14) Uani 1 1 d . . . . .
H7 H 0.1844 0.6463 0.6421 0.061 Uiso 1 1 calc R . . . .
C8 C 0.8883(6) 1.0713(4) 0.4402(4) 0.0461(13) Uani 1 1 d . . . . .
H8A H 0.9851 1.0541 0.4313 0.069 Uiso 1 1 calc GR . . . .
H8B H 0.8864 1.0997 0.5031 0.069 Uiso 1 1 calc GR . . . .
H8C H 0.8754 1.1246 0.4012 0.069 Uiso 1 1 calc GR . . . .
C9 C 0.4640(5) 0.5416(4) 0.3230(3) 0.0304(10) Uani 1 1 d . . . . .
C10 C 0.5903(5) 0.5481(4) 0.3830(3) 0.0352(10) Uani 1 1 d . . . . .
H10 H 0.5822 0.4988 0.4257 0.042 Uiso 1 1 calc R . . . .
C11 C 0.7274(5) 0.6245(4) 0.3822(3) 0.0344(10) Uani 1 1 d . . . . .
C12 C 0.3367(5) 0.4452(4) 0.3180(3) 0.0362(11) Uani 1 1 d . . . . .
C13 C 0.3196(6) 0.3533(5) 0.3556(4) 0.0506(14) Uani 1 1 d . . . . .
H13 H 0.3950 0.3401 0.3953 0.061 Uiso 1 1 calc R . . . .
C14 C 0.1802(7) 0.2792(5) 0.3307(5) 0.0642(19) Uani 1 1 d . . . . .
H14 H 0.1507 0.2118 0.3519 0.077 Uiso 1 1 calc R . . . .
C15 C 0.0926(6) 0.3168(5) 0.2719(5) 0.0587(18) Uani 1 1 d . . . . .
H15 H -0.0054 0.2784 0.2476 0.070 Uiso 1 1 calc R . . . .
C16 C 0.8627(6) 0.6148(5) 0.4405(4) 0.0502(14) Uani 1 1 d . . . . .
H16A H 0.9343 0.5906 0.4023 0.075 Uiso 1 1 calc GR . . . .
H16B H 0.8291 0.5633 0.4828 0.075 Uiso 1 1 calc GR . . . .
H16C H 0.9119 0.6843 0.4740 0.075 Uiso 1 1 calc GR . . . .
C17 C 0.5174(5) 0.6611(4) 0.0347(3) 0.0282(9) Uani 1 1 d . . . . .
C18 C 0.6684(5) 0.6752(4) 0.0141(3) 0.0324(10) Uani 1 1 d . . . . .
H18 H 0.6879 0.6429 -0.0423 0.039 Uiso 1 1 calc R . . . .
C19 C 0.7902(5) 0.7334(4) 0.0715(3) 0.0305(9) Uani 1 1 d . . . . .
C20 C 0.3958(5) 0.6040(4) -0.0341(3) 0.0312(10) Uani 1 1 d . U . . .
C21 C 0.4043(4) 0.5605(3) -0.1288(3) 0.0264(9) Uani 1 1 d . U . . .
H21 H 0.4927 0.5624 -0.1595 0.032 Uiso 1 1 calc R . . . .
C22 C 0.2490(7) 0.5143(5) -0.1647(4) 0.0540(15) Uani 1 1 d . U . . .
H22 H 0.2237 0.4799 -0.2244 0.065 Uiso 1 1 calc R . . . .
C23 C 0.1433(6) 0.5240(5) -0.1067(4) 0.0517(14) Uani 1 1 d . U . . .
H23 H 0.0381 0.4979 -0.1221 0.062 Uiso 1 1 calc R . . . .
C24 C 0.9463(6) 0.7525(5) 0.0386(4) 0.0481(14) Uani 1 1 d . . . . .
H24A H 0.9782 0.8256 0.0241 0.072 Uiso 1 1 calc GR . . . .
H24B H 0.9451 0.7028 -0.0153 0.072 Uiso 1 1 calc GR . . . .
H24C H 1.0168 0.7415 0.0856 0.072 Uiso 1 1 calc GR . . . .
C25 C 0.2240(5) 0.7850(4) 0.2804(3) 0.0388(12) Uani 1 1 d . . . . .
H25 H 0.2293 0.7222 0.3056 0.047 Uiso 1 1 calc R . . . .
C26 C 0.0932(5) 0.8210(5) 0.2873(4) 0.0466(14) Uani 1 1 d . . . . .
H26 H 0.0114 0.7829 0.3167 0.056 Uiso 1 1 calc R . . . .
C27 C 0.0833(5) 0.9111(5) 0.2519(4) 0.0473(14) Uani 1 1 d . . . . .
H27 H -0.0045 0.9368 0.2573 0.057 Uiso 1 1 calc R . . . .
C28 C 0.2043(5) 0.9660(4) 0.2071(3) 0.0381(11) Uani 1 1 d . . . . .
C29 C 0.3318(5) 0.9237(4) 0.2036(3) 0.0293(9) Uani 1 1 d . . . . .
C30 C 0.7025(6) 0.9918(4) 0.1207(3) 0.0377(11) Uani 1 1 d . . . . .
H30 H 0.7902 0.9654 0.1206 0.045 Uiso 1 1 calc R . . . .
C31 C 0.7039(6) 1.0813(4) 0.0791(4) 0.0462(13) Uani 1 1 d . . . . .
H31 H 0.7910 1.1150 0.0517 0.055 Uiso 1 1 calc R . . . .
C32 C 0.5789(7) 1.1212(4) 0.0773(3) 0.0468(13) Uani 1 1 d . . . . .
H32 H 0.5778 1.1823 0.0485 0.056 Uiso 1 1 calc R . . . .
C33 C 0.4517(6) 1.0694(4) 0.1192(3) 0.0410(12) Uani 1 1 d . . . . .
C34 C 0.4607(5) 0.9799(4) 0.1592(3) 0.0305(10) Uani 1 1 d . . . . .
C35 C 0.2011(6) 1.0587(5) 0.1663(4) 0.0514(14) Uani 1 1 d . . . . .
H35 H 0.1147 1.0864 0.1694 0.062 Uiso 1 1 calc R . . . .
C36 C 0.3206(7) 1.1091(5) 0.1225(4) 0.0528(14) Uani 1 1 d . . . . .
H36 H 0.3159 1.1702 0.0945 0.063 Uiso 1 1 calc R . . . .
S1 S 0.31099(16) 0.69755(12) 0.51572(9) 0.0483(3) Uani 1 1 d . . . . .
S2 S 0.18074(15) 0.44157(13) 0.24748(11) 0.0535(4) Uani 1 1 d . . . . .
S3 S 0.21645(15) 0.58649(13) -0.00582(10) 0.0499(4) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 N1 2.595(4) . ?
Eu1 N2 2.643(4) . ?
Eu1 O1 2.349(3) . ?
Eu1 O2 2.361(3) . ?
Eu1 O3 2.345(3) . ?
Eu1 O4 2.367(4) . ?
Eu1 O5 2.367(3) . ?
Eu1 O6 2.344(3) . ?
N1 C25 1.340(5) . ?
N1 C29 1.345(7) . ?
N2 C30 1.335(6) . ?
N2 C34 1.363(6) . ?
O1 C1 1.249(5) . ?
O2 C3 1.285(5) . ?
O3 C9 1.257(6) . ?
O4 C11 1.255(6) . ?
O5 C17 1.255(5) . ?
O6 C19 1.274(5) . ?
C1 C2 1.394(6) . ?
C1 C4 1.483(6) . ?
C2 H2 0.9500 . ?
C2 C3 1.386(7) . ?
C3 C8 1.503(6) . ?
C4 C5 1.523(6) . ?
C4 S1 1.700(5) . ?
C5 H5 0.9500 . ?
C5 C6 1.498(7) . ?
C6 H6 0.9500 . ?
C6 C7 1.346(8) . ?
C7 H7 0.9500 . ?
C7 S1 1.691(5) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 C10 1.413(7) . ?
C9 C12 1.488(6) . ?
C10 H10 0.9500 . ?
C10 C11 1.405(6) . ?
C11 C16 1.523(7) . ?
C12 C13 1.360(9) . ?
C12 S2 1.726(5) . ?
C13 H13 0.9500 . ?
C13 C14 1.410(8) . ?
C14 H14 0.9500 . ?
C14 C15 1.371(11) . ?
C15 H15 0.9500 . ?
C15 S2 1.721(7) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.407(6) . ?
C17 C20 1.479(6) . ?
C18 H18 0.9500 . ?
C18 C19 1.386(6) . ?
C19 C24 1.510(6) . ?
C20 C21 1.487(5) . ?
C20 S3 1.689(5) . ?
C21 H21 0.9500 . ?
C21 C22 1.457(6) . ?
C22 H22 0.9500 . ?
C22 C23 1.355(8) . ?
C23 H23 0.9500 . ?
C23 S3 1.668(6) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25 0.9500 . ?
C25 C26 1.398(7) . ?
C26 H26 0.9500 . ?
C26 C27 1.362(9) . ?
C27 H27 0.9500 . ?
C27 C28 1.411(7) . ?
C28 C29 1.412(7) . ?
C28 C35 1.419(9) . ?
C29 C34 1.465(6) . ?
C30 H30 0.9500 . ?
C30 C31 1.381(8) . ?
C31 H31 0.9500 . ?
C31 C32 1.371(9) . ?
C32 H32 0.9500 . ?
C32 C33 1.413(7) . ?
C33 C34 1.388(8) . ?
C33 C36 1.422(8) . ?
C35 H35 0.9500 . ?
C35 C36 1.371(9) . ?
C36 H36 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Eu1 N2 62.31(12) . . ?
O1 Eu1 N1 70.02(12) . . ?
O1 Eu1 N2 113.00(12) . . ?
O1 Eu1 O2 71.95(10) . . ?
O1 Eu1 O4 78.98(12) . . ?
O1 Eu1 O5 132.69(10) . . ?
O2 Eu1 N1 99.41(11) . . ?
O2 Eu1 N2 72.58(12) . . ?
O2 Eu1 O4 80.52(12) . . ?
O2 Eu1 O5 146.51(12) . . ?
O3 Eu1 N1 87.97(13) . . ?
O3 Eu1 N2 141.72(11) . . ?
O3 Eu1 O1 74.06(11) . . ?
O3 Eu1 O2 140.09(11) . . ?
O3 Eu1 O4 72.97(11) . . ?
O3 Eu1 O5 73.35(11) . . ?
O4 Eu1 N1 147.15(11) . . ?
O4 Eu1 N2 144.38(11) . . ?
O4 Eu1 O5 121.70(12) . . ?
O5 Eu1 N1 75.46(11) . . ?
O5 Eu1 N2 75.99(12) . . ?
O6 Eu1 N1 132.88(12) . . ?
O6 Eu1 N2 77.12(12) . . ?
O6 Eu1 O1 153.92(11) . . ?
O6 Eu1 O2 89.67(10) . . ?
O6 Eu1 O3 113.71(12) . . ?
O6 Eu1 O4 79.87(12) . . ?
O6 Eu1 O5 72.17(10) . . ?
C25 N1 Eu1 119.9(4) . . ?
C25 N1 C29 117.6(4) . . ?
C29 N1 Eu1 121.9(3) . . ?
C30 N2 Eu1 122.9(3) . . ?
C30 N2 C34 116.5(4) . . ?
C34 N2 Eu1 120.5(3) . . ?
C1 O1 Eu1 137.5(3) . . ?
C3 O2 Eu1 135.7(3) . . ?
C9 O3 Eu1 133.7(3) . . ?
C11 O4 Eu1 133.4(3) . . ?
C17 O5 Eu1 135.7(3) . . ?
C19 O6 Eu1 136.4(3) . . ?
O1 C1 C2 124.0(4) . . ?
O1 C1 C4 114.4(4) . . ?
C2 C1 C4 121.6(4) . . ?
C1 C2 H2 117.5 . . ?
C3 C2 C1 124.9(4) . . ?
C3 C2 H2 117.5 . . ?
O2 C3 C2 124.6(4) . . ?
O2 C3 C8 115.4(4) . . ?
C2 C3 C8 120.0(4) . . ?
C1 C4 C5 128.4(4) . . ?
C1 C4 S1 116.8(3) . . ?
C5 C4 S1 114.7(3) . . ?
C4 C5 H5 128.8 . . ?
C6 C5 C4 102.3(4) . . ?
C6 C5 H5 128.8 . . ?
C5 C6 H6 121.7 . . ?
C7 C6 C5 116.7(5) . . ?
C7 C6 H6 121.7 . . ?
C6 C7 H7 123.0 . . ?
C6 C7 S1 114.1(4) . . ?
S1 C7 H7 123.0 . . ?
C3 C8 H8A 109.5 . . ?
C3 C8 H8B 109.5 . . ?
C3 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
O3 C9 C10 126.5(4) . . ?
O3 C9 C12 115.8(4) . . ?
C10 C9 C12 117.6(5) . . ?
C9 C10 H10 118.6 . . ?
C11 C10 C9 122.8(5) . . ?
C11 C10 H10 118.6 . . ?
O4 C11 C10 125.4(5) . . ?
O4 C11 C16 116.0(4) . . ?
C10 C11 C16 118.4(5) . . ?
C9 C12 S2 116.7(4) . . ?
C13 C12 C9 132.3(5) . . ?
C13 C12 S2 110.9(4) . . ?
C12 C13 H13 123.0 . . ?
C12 C13 C14 114.1(6) . . ?
C14 C13 H13 123.0 . . ?
C13 C14 H14 124.3 . . ?
C15 C14 C13 111.5(6) . . ?
C15 C14 H14 124.3 . . ?
C14 C15 H15 124.0 . . ?
C14 C15 S2 112.1(4) . . ?
S2 C15 H15 124.0 . . ?
C11 C16 H16A 109.5 . . ?
C11 C16 H16B 109.5 . . ?
C11 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O5 C17 C18 125.2(4) . . ?
O5 C17 C20 115.6(4) . . ?
C18 C17 C20 119.2(4) . . ?
C17 C18 H18 118.1 . . ?
C19 C18 C17 123.7(4) . . ?
C19 C18 H18 118.1 . . ?
O6 C19 C18 125.1(4) . . ?
O6 C19 C24 115.7(4) . . ?
C18 C19 C24 119.1(4) . . ?
C17 C20 C21 130.1(4) . . ?
C17 C20 S3 117.6(3) . . ?
C21 C20 S3 112.3(3) . . ?
C20 C21 H21 127.1 . . ?
C22 C21 C20 105.8(4) . . ?
C22 C21 H21 127.1 . . ?
C21 C22 H22 122.4 . . ?
C23 C22 C21 115.2(4) . . ?
C23 C22 H22 122.4 . . ?
C22 C23 H23 123.4 . . ?
C22 C23 S3 113.2(4) . . ?
S3 C23 H23 123.4 . . ?
C19 C24 H24A 109.5 . . ?
C19 C24 H24B 109.5 . . ?
C19 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
N1 C25 H25 118.7 . . ?
N1 C25 C26 122.6(5) . . ?
C26 C25 H25 118.7 . . ?
C25 C26 H26 120.2 . . ?
C27 C26 C25 119.7(5) . . ?
C27 C26 H26 120.2 . . ?
C26 C27 H27 120.2 . . ?
C26 C27 C28 119.7(5) . . ?
C28 C27 H27 120.2 . . ?
C27 C28 C29 116.5(5) . . ?
C27 C28 C35 123.1(5) . . ?
C29 C28 C35 120.4(5) . . ?
N1 C29 C28 123.8(4) . . ?
N1 C29 C34 118.1(4) . . ?
C28 C29 C34 118.0(5) . . ?
N2 C30 H30 118.1 . . ?
N2 C30 C31 123.8(5) . . ?
C31 C30 H30 118.1 . . ?
C30 C31 H31 120.1 . . ?
C32 C31 C30 119.7(5) . . ?
C32 C31 H31 120.1 . . ?
C31 C32 H32 120.7 . . ?
C31 C32 C33 118.6(5) . . ?
C33 C32 H32 120.7 . . ?
C32 C33 C36 121.3(6) . . ?
C34 C33 C32 117.5(5) . . ?
C34 C33 C36 121.1(5) . . ?
N2 C34 C29 116.6(4) . . ?
N2 C34 C33 123.9(4) . . ?
C33 C34 C29 119.5(5) . . ?
C28 C35 H35 119.4 . . ?
C36 C35 C28 121.2(5) . . ?
C36 C35 H35 119.4 . . ?
C33 C36 H36 120.1 . . ?
C35 C36 C33 119.8(6) . . ?
C35 C36 H36 120.1 . . ?
C7 S1 C4 92.2(2) . . ?
C15 S2 C12 91.4(3) . . ?
C23 S3 C20 93.6(3) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_eup_CCDC1
_database_code_depnum_ccdc_archive 'CCDC 2081276'
loop_
_audit_author_name
_audit_author_address
'Mikhail Kiskin'
;Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2021-04-30 deposited with the CCDC.	2021-10-25 downloaded from the CCDC.
;

# start Validation Reply Form
_vrf_PLAT973_eup                 
;
PROBLEM: Check Calcd Positive Resid. Density on Eu1 1.90 eA-3  
RESPONSE: These are the ripples (residual density) features that arevery 
closed to the heavy atom and are typically more pronounced forheavier atoms, 
for example element Eu in this case.
;

_audit_creation_date             2021-01-29
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'C35.67 H22.67 Eu F6 N2 O6 S2.67, 0.33(C), 0.33(S)'
_chemical_formula_sum            'C36 H23 Eu F6 N2 O6 S3'
_chemical_formula_weight         941.70
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.4489(7)
_cell_length_b                   13.2007(11)
_cell_length_c                   14.8576(11)
_cell_angle_alpha                90.152(4)
_cell_angle_beta                 94.059(3)
_cell_angle_gamma                102.044(3)
_cell_volume                     1807.6(2)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    3417
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      30.37
_cell_measurement_theta_min      2.43
_shelx_estimated_absorpt_T_max   0.961
_shelx_estimated_absorpt_T_min   0.857
_exptl_absorpt_coefficient_mu    1.988
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6330
_exptl_absorpt_correction_type   'multi scan'
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1295 before and 0.0486 after correction.
The Ratio of minimum to maximum transmission is 0.8484.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.730
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       parallelepiped
_exptl_crystal_F_000             932
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0689
_diffrn_reflns_av_unetI/netI     0.1282
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            16459
_diffrn_reflns_point_group_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.877
_diffrn_reflns_theta_min         1.374
_diffrn_ambient_temperature      150.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6035
_reflns_number_total             8489
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         1.482
_refine_diff_density_min         -1.910
_refine_diff_density_rms         0.173
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     494
_refine_ls_number_reflns         8489
_refine_ls_number_restraints     21
_refine_ls_R_factor_all          0.0968
_refine_ls_R_factor_gt           0.0640
_refine_ls_restrained_S_all      1.178
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0487P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1188
_refine_ls_wR_factor_ref         0.1310
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Restrained distances
 S3-C20 = S3-C22
 1.7 with sigma of 0.02
 S3A-C20 = S3A-C23
 1.7 with sigma of 0.02
 C21-C22 = C21A-C23
 1.46 with sigma of 0.01
 C20-C21 = C20-C21A
 1.44 with sigma of 0.01
 C22-C23
 1.35 with sigma of 0.01
 C20-C22 = C20-C23
 2.4 with sigma of 0.02
 C21-S3 = C21A-S3A
 2.6 with sigma of 0.02
 C21-C23 = C21A-C22
 2.35 with sigma of 0.02
 S3-C22 = S3A-C23
 2.5 with sigma of 0.02
3. Restrained planarity
 C20, C21, C22, C23, S3
 with sigma of 0.01
 C20, C21A, C22, C23, S3A
 with sigma of 0.01
4. Uiso/Uaniso restraints and constraints
Uanis(C21) = Uanis(C21A)
Uanis(S3) = Uanis(S3A)
5. Others
 Sof(C21A)=Sof(S3A)=1-FVAR(1)
 Sof(C21)=Sof(H21)=Sof(S3)=FVAR(1)
6.a Ternary CH refined with riding coordinates:
 C8(H8), C16(H16), C24(H24)
6.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C5(H5), C6(H6), C7(H7), C10(H10), C13(H13), C14(H14), C15(H15),
 C18(H18), C21(H21), C22(H22), C23(H23), C25(H25), C26(H26), C27(H27), C30(H30),
  C31(H31), C32(H32), C35(H35), C36(H36)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.39795(3) 0.24999(3) 0.25988(2) 0.01967(10) Uani 1 1 d . . . . .
N1 N 0.4162(5) 0.0832(4) 0.3475(3) 0.0237(12) Uani 1 1 d . . . . .
N2 N 0.6493(5) 0.2013(4) 0.2746(3) 0.0251(13) Uani 1 1 d . . . . .
O1 O 0.5162(4) 0.3259(3) 0.3979(3) 0.0267(11) Uani 1 1 d . . . . .
O2 O 0.2217(4) 0.2509(3) 0.3623(3) 0.0263(11) Uani 1 1 d . . . . .
O3 O 0.5349(4) 0.4125(3) 0.2237(3) 0.0251(10) Uani 1 1 d . . . . .
O4 O 0.2435(4) 0.3364(4) 0.1708(3) 0.0292(11) Uani 1 1 d . . . . .
O5 O 0.4707(4) 0.2161(4) 0.1161(3) 0.0282(11) Uani 1 1 d . . . . .
O6 O 0.2272(4) 0.1093(3) 0.1938(3) 0.0256(10) Uani 1 1 d . . . . .
C1 C 0.4824(7) 0.3500(5) 0.4739(4) 0.0232(14) Uani 1 1 d . . . . .
C2 C 0.3380(6) 0.3330(5) 0.4991(4) 0.0242(15) Uani 1 1 d . . . . .
H2 H 0.3201 0.3557 0.5571 0.029 Uiso 1 1 calc R . . . .
C3 C 0.2232(6) 0.2850(5) 0.4426(4) 0.0243(14) Uani 1 1 d . . . . .
C4 C 0.6036(6) 0.3961(5) 0.5395(4) 0.0252(15) Uani 1 1 d . . . . .
C5 C 0.6030(6) 0.4292(5) 0.6315(4) 0.0253(15) Uani 1 1 d . . . . .
H5 H 0.5196 0.4267 0.6642 0.030 Uiso 1 1 calc R . . . .
C6 C 0.7498(9) 0.4665(6) 0.6651(5) 0.046(2) Uani 1 1 d . . . . .
H6 H 0.7757 0.4952 0.7242 0.056 Uiso 1 1 calc R . . . .
C7 C 0.8472(8) 0.4580(6) 0.6073(5) 0.041(2) Uani 1 1 d . . . . .
H7 H 0.9488 0.4786 0.6217 0.050 Uiso 1 1 calc R . . . .
C8 C 0.0697(7) 0.2619(6) 0.4770(5) 0.0337(17) Uani 1 1 d . . . . .
H8 H 0.0015 0.2879 0.4327 0.040 Uiso 1 1 calc R . . . .
C9 C 0.5239(7) 0.4808(5) 0.1668(4) 0.0272(15) Uani 1 1 d . . . . .
C10 C 0.3983(7) 0.4777(6) 0.1082(5) 0.0355(18) Uani 1 1 d . . . . .
H10 H 0.4036 0.5263 0.0608 0.043 Uiso 1 1 calc R . . . .
C11 C 0.2685(7) 0.4083(6) 0.1156(5) 0.0317(17) Uani 1 1 d . . . . .
C12 C 0.6445(7) 0.5693(6) 0.1673(5) 0.0314(16) Uani 1 1 d . . . . .
C13 C 0.6655(9) 0.6554(6) 0.1163(6) 0.054(2) Uani 1 1 d . . . . .
H13 H 0.5997 0.6665 0.0678 0.065 Uiso 1 1 calc R . . . .
C14 C 0.7955(9) 0.7271(7) 0.1426(7) 0.060(3) Uani 1 1 d . . . . .
H14 H 0.8259 0.7917 0.1143 0.073 Uiso 1 1 calc R . . . .
C15 C 0.8710(8) 0.6934(6) 0.2122(6) 0.050(2) Uani 1 1 d . . . . .
H15 H 0.9609 0.7314 0.2387 0.060 Uiso 1 1 calc R . . . .
C16 C 0.1386(8) 0.4301(7) 0.0551(6) 0.051(2) Uani 1 1 d . . . . .
H16 H 0.1704 0.4691 -0.0001 0.061 Uiso 1 1 calc R . . . .
C17 C 0.4290(7) 0.1514(5) 0.0517(4) 0.0268(15) Uani 1 1 d . . . . .
C18 C 0.3045(7) 0.0723(6) 0.0512(5) 0.039(2) Uani 1 1 d . . . . .
H18 H 0.2807 0.0266 0.0003 0.047 Uiso 1 1 calc R . . . .
C19 C 0.2161(7) 0.0582(5) 0.1209(5) 0.0304(17) Uani 1 1 d . . . . .
C20 C 0.5208(6) 0.1650(5) -0.0240(4) 0.0346(18) Uani 1 1 d D . . A 1
C21 C 0.4881(10) 0.1154(6) -0.1117(7) 0.114(11) Uani 0.671(5) 1 d D . P A 1
H21 H 0.4056 0.0645 -0.1328 0.137 Uiso 0.671(5) 1 calc R . P A 1
S3 S 0.6810(3) 0.2531(3) -0.0120(2) 0.0440(11) Uani 0.671(5) 1 d D . P A 1
C22 C 0.6167(8) 0.1642(6) -0.1613(5) 0.069(3) Uani 1 1 d D . . A 1
H22 H 0.6277 0.1473 -0.2222 0.083 Uiso 1 1 calc R . . A 1
C23 C 0.7114(7) 0.2314(5) -0.1137(5) 0.064(3) Uani 1 1 d D . . A 1
H23 H 0.7973 0.2671 -0.1386 0.077 Uiso 1 1 calc R . . A 1
C21A C 0.6597(11) 0.2386(7) -0.0213(7) 0.114(11) Uani 0.329(5) 1 d D . P A 2
S3A S 0.4832(6) 0.1075(5) -0.1259(6) 0.0440(11) Uani 0.329(5) 1 d D . P A 2
C24 C 0.0846(8) -0.0325(6) 0.1133(6) 0.046(2) Uani 1 1 d . . . . .
H24 H 0.0925 -0.0806 0.0627 0.055 Uiso 1 1 calc R . . . .
C25 C 0.3036(7) 0.0249(6) 0.3838(4) 0.0312(17) Uani 1 1 d . . . . .
H25 H 0.2171 0.0506 0.3856 0.037 Uiso 1 1 calc R . . . .
C26 C 0.3061(7) -0.0723(6) 0.4195(5) 0.0347(18) Uani 1 1 d . . . . .
H26 H 0.2227 -0.1116 0.4447 0.042 Uiso 1 1 calc R . . . .
C27 C 0.4282(8) -0.1100(6) 0.4179(5) 0.0369(18) Uani 1 1 d . . . . .
H27 H 0.4311 -0.1761 0.4423 0.044 Uiso 1 1 calc R . . . .
C28 C 0.5500(8) -0.0523(6) 0.3803(5) 0.0328(17) Uani 1 1 d . . . . .
C29 C 0.5397(7) 0.0446(5) 0.3459(4) 0.0236(14) Uani 1 1 d . . . . .
C30 C 0.7617(7) 0.2612(6) 0.2405(5) 0.0322(17) Uani 1 1 d . . . . .
H30 H 0.7519 0.3268 0.2179 0.039 Uiso 1 1 calc R . . . .
C31 C 0.8961(7) 0.2314(6) 0.2362(5) 0.0342(18) Uani 1 1 d . . . . .
H31 H 0.9758 0.2765 0.2121 0.041 Uiso 1 1 calc R . . . .
C32 C 0.9094(7) 0.1358(6) 0.2675(5) 0.0327(17) Uani 1 1 d . . . . .
H32 H 0.9980 0.1133 0.2639 0.039 Uiso 1 1 calc R . . . .
C33 C 0.7920(7) 0.0722(6) 0.3046(5) 0.0303(16) Uani 1 1 d . . . . .
C34 C 0.6627(6) 0.1089(5) 0.3076(4) 0.0209(14) Uani 1 1 d . . . . .
C35 C 0.6826(8) -0.0886(6) 0.3746(5) 0.042(2) Uani 1 1 d . . . . .
H35 H 0.6891 -0.1552 0.3962 0.051 Uiso 1 1 calc R . . . .
C36 C 0.7978(8) -0.0282(6) 0.3386(6) 0.045(2) Uani 1 1 d . . . . .
H36 H 0.8848 -0.0531 0.3358 0.054 Uiso 1 1 calc R . . . .
S1 S 0.7755(2) 0.40736(17) 0.50643(14) 0.0434(5) Uani 1 1 d . . . . .
S2 S 0.7867(2) 0.57469(16) 0.24751(14) 0.0431(5) Uani 1 1 d . . . . .
F1 F 0.0654(4) 0.3055(4) 0.5594(3) 0.0578(15) Uani 1 1 d . . . . .
F2 F 0.0254(4) 0.1590(4) 0.4850(3) 0.0551(13) Uani 1 1 d . . . . .
F3 F 0.0453(5) 0.3361(5) 0.0338(4) 0.0833(19) Uani 1 1 d . . . . .
F4 F 0.0616(6) 0.4806(5) 0.1049(4) 0.087(2) Uani 1 1 d . . . . .
F5 F 0.0744(5) -0.0839(4) 0.1932(3) 0.0641(15) Uani 1 1 d . . . . .
F6 F -0.0371(5) 0.0050(4) 0.1002(4) 0.0735(18) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 N1 2.591(6) . ?
Eu1 N2 2.582(5) . ?
Eu1 O1 2.378(4) . ?
Eu1 O2 2.335(4) . ?
Eu1 O3 2.348(4) . ?
Eu1 O4 2.369(5) . ?
Eu1 O5 2.359(4) . ?
Eu1 O6 2.351(4) . ?
N1 C25 1.325(8) . ?
N1 C29 1.369(8) . ?
N2 C30 1.318(8) . ?
N2 C34 1.343(8) . ?
O1 C1 1.254(7) . ?
O2 C3 1.272(7) . ?
O3 C9 1.252(8) . ?
O4 C11 1.251(8) . ?
O5 C17 1.266(7) . ?
O6 C19 1.262(7) . ?
C1 C2 1.413(8) . ?
C1 C4 1.476(8) . ?
C2 H2 0.9500 . ?
C2 C3 1.366(8) . ?
C3 C8 1.543(8) . ?
C4 C5 1.434(8) . ?
C4 S1 1.708(6) . ?
C5 H5 0.9500 . ?
C5 C6 1.425(9) . ?
C6 H6 0.9500 . ?
C6 C7 1.323(10) . ?
C7 H7 0.9500 . ?
C7 S1 1.677(7) . ?
C8 H8 1.0000 . ?
C8 F1 1.358(7) . ?
C8 F2 1.343(8) . ?
C9 C10 1.416(9) . ?
C9 C12 1.452(9) . ?
C10 H10 0.9500 . ?
C10 C11 1.381(9) . ?
C11 C16 1.547(10) . ?
C12 C13 1.356(10) . ?
C12 S2 1.721(7) . ?
C13 H13 0.9500 . ?
C13 C14 1.415(10) . ?
C14 H14 0.9500 . ?
C14 C15 1.344(11) . ?
C15 H15 0.9500 . ?
C15 S2 1.706(8) . ?
C16 H16 1.0000 . ?
C16 F3 1.385(9) . ?
C16 F4 1.341(10) . ?
C17 C18 1.400(9) . ?
C17 C20 1.457(8) . ?
C18 H18 0.9500 . ?
C18 C19 1.365(9) . ?
C19 C24 1.532(9) . ?
C20 C21 1.441(9) . ?
C20 S3 1.704(7) . ?
C21 H21 0.9500 . ?
C21 C22 1.496(9) . ?
S3 C23 1.594(8) . ?
C22 H22 0.9500 . ?
C22 C23 1.289(7) . ?
C23 H23 0.9500 . ?
C24 H24 1.0000 . ?
C24 F5 1.369(9) . ?
C24 F6 1.347(9) . ?
C25 H25 0.9500 . ?
C25 C26 1.394(10) . ?
C26 H26 0.9500 . ?
C26 C27 1.351(10) . ?
C27 H27 0.9500 . ?
C27 C28 1.395(10) . ?
C28 C29 1.398(9) . ?
C28 C35 1.439(10) . ?
C29 C34 1.442(8) . ?
C30 H30 0.9500 . ?
C30 C31 1.412(9) . ?
C31 H31 0.9500 . ?
C31 C32 1.372(10) . ?
C32 H32 0.9500 . ?
C32 C33 1.393(9) . ?
C33 C34 1.409(9) . ?
C33 C36 1.430(10) . ?
C35 H35 0.9500 . ?
C35 C36 1.353(11) . ?
C36 H36 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Eu1 N1 63.31(17) . . ?
O1 Eu1 N1 80.54(16) . . ?
O1 Eu1 N2 73.40(15) . . ?
O2 Eu1 N1 80.06(16) . . ?
O2 Eu1 N2 132.67(16) . . ?
O2 Eu1 O1 71.82(14) . . ?
O2 Eu1 O3 116.14(15) . . ?
O2 Eu1 O4 81.40(16) . . ?
O2 Eu1 O5 152.35(14) . . ?
O2 Eu1 O6 83.77(14) . . ?
O3 Eu1 N1 142.18(15) . . ?
O3 Eu1 N2 82.83(16) . . ?
O3 Eu1 O1 73.68(15) . . ?
O3 Eu1 O4 72.32(15) . . ?
O3 Eu1 O5 78.29(15) . . ?
O3 Eu1 O6 140.98(15) . . ?
O4 Eu1 N1 145.49(15) . . ?
O4 Eu1 N2 144.96(17) . . ?
O4 Eu1 O1 120.38(16) . . ?
O5 Eu1 N1 103.18(16) . . ?
O5 Eu1 N2 69.73(15) . . ?
O5 Eu1 O1 135.80(14) . . ?
O5 Eu1 O4 81.12(16) . . ?
O6 Eu1 N1 70.65(15) . . ?
O6 Eu1 N2 108.84(15) . . ?
O6 Eu1 O1 145.02(15) . . ?
O6 Eu1 O4 78.63(15) . . ?
O6 Eu1 O5 71.88(14) . . ?
C25 N1 Eu1 122.6(5) . . ?
C25 N1 C29 117.4(6) . . ?
C29 N1 Eu1 119.4(4) . . ?
C30 N2 Eu1 120.4(5) . . ?
C30 N2 C34 119.2(6) . . ?
C34 N2 Eu1 119.9(4) . . ?
C1 O1 Eu1 138.2(4) . . ?
C3 O2 Eu1 134.8(4) . . ?
C9 O3 Eu1 136.6(4) . . ?
C11 O4 Eu1 132.4(4) . . ?
C17 O5 Eu1 138.1(4) . . ?
C19 O6 Eu1 134.5(4) . . ?
O1 C1 C2 123.6(6) . . ?
O1 C1 C4 116.3(5) . . ?
C2 C1 C4 120.1(6) . . ?
C1 C2 H2 119.0 . . ?
C3 C2 C1 122.1(6) . . ?
C3 C2 H2 119.0 . . ?
O2 C3 C2 129.4(6) . . ?
O2 C3 C8 111.3(5) . . ?
C2 C3 C8 119.2(6) . . ?
C1 C4 S1 117.4(5) . . ?
C5 C4 C1 130.5(6) . . ?
C5 C4 S1 112.1(4) . . ?
C4 C5 H5 126.0 . . ?
C6 C5 C4 107.9(6) . . ?
C6 C5 H5 126.0 . . ?
C5 C6 H6 122.7 . . ?
C7 C6 C5 114.5(6) . . ?
C7 C6 H6 122.7 . . ?
C6 C7 H7 123.0 . . ?
C6 C7 S1 114.1(6) . . ?
S1 C7 H7 123.0 . . ?
C3 C8 H8 109.3 . . ?
F1 C8 C3 112.7(5) . . ?
F1 C8 H8 109.3 . . ?
F2 C8 C3 108.9(6) . . ?
F2 C8 H8 109.3 . . ?
F2 C8 F1 107.2(6) . . ?
O3 C9 C10 123.2(6) . . ?
O3 C9 C12 116.5(6) . . ?
C10 C9 C12 120.2(7) . . ?
C9 C10 H10 118.0 . . ?
C11 C10 C9 123.9(7) . . ?
C11 C10 H10 118.0 . . ?
O4 C11 C10 126.9(6) . . ?
O4 C11 C16 117.6(6) . . ?
C10 C11 C16 115.2(7) . . ?
C9 C12 S2 118.1(5) . . ?
C13 C12 C9 131.1(7) . . ?
C13 C12 S2 110.8(5) . . ?
C12 C13 H13 123.4 . . ?
C12 C13 C14 113.1(8) . . ?
C14 C13 H13 123.4 . . ?
C13 C14 H14 123.9 . . ?
C15 C14 C13 112.3(8) . . ?
C15 C14 H14 123.9 . . ?
C14 C15 H15 123.9 . . ?
C14 C15 S2 112.2(6) . . ?
S2 C15 H15 123.9 . . ?
C11 C16 H16 112.0 . . ?
F3 C16 C11 107.9(7) . . ?
F3 C16 H16 112.0 . . ?
F4 C16 C11 108.3(7) . . ?
F4 C16 H16 112.0 . . ?
F4 C16 F3 104.1(7) . . ?
O5 C17 C18 123.7(6) . . ?
O5 C17 C20 114.9(6) . . ?
C18 C17 C20 121.4(6) . . ?
C17 C18 H18 118.7 . . ?
C19 C18 C17 122.6(6) . . ?
C19 C18 H18 118.7 . . ?
O6 C19 C18 129.1(6) . . ?
O6 C19 C24 113.1(6) . . ?
C18 C19 C24 117.8(6) . . ?
C17 C20 S3 118.0(5) . . ?
C21 C20 C17 127.0(7) . . ?
C21 C20 S3 114.9(6) . . ?
C20 C21 H21 128.7 . . ?
C20 C21 C22 102.5(7) . . ?
C22 C21 H21 128.7 . . ?
C23 S3 C20 90.3(3) . . ?
C21 C22 H22 123.1 . . ?
C23 C22 C21 113.8(6) . . ?
C23 C22 H22 123.1 . . ?
S3 C23 H23 120.8 . . ?
C22 C23 S3 118.5(6) . . ?
C22 C23 H23 120.8 . . ?
C19 C24 H24 110.6 . . ?
F5 C24 C19 109.7(6) . . ?
F5 C24 H24 110.6 . . ?
F6 C24 C19 109.0(7) . . ?
F6 C24 H24 110.6 . . ?
F6 C24 F5 106.2(6) . . ?
N1 C25 H25 118.4 . . ?
N1 C25 C26 123.1(7) . . ?
C26 C25 H25 118.4 . . ?
C25 C26 H26 120.3 . . ?
C27 C26 C25 119.3(7) . . ?
C27 C26 H26 120.3 . . ?
C26 C27 H27 120.0 . . ?
C26 C27 C28 120.1(7) . . ?
C28 C27 H27 120.0 . . ?
C27 C28 C29 117.4(7) . . ?
C27 C28 C35 123.1(7) . . ?
C29 C28 C35 119.5(7) . . ?
N1 C29 C28 122.7(6) . . ?
N1 C29 C34 117.2(6) . . ?
C28 C29 C34 120.1(6) . . ?
N2 C30 H30 118.8 . . ?
N2 C30 C31 122.4(7) . . ?
C31 C30 H30 118.8 . . ?
C30 C31 H31 120.7 . . ?
C32 C31 C30 118.7(6) . . ?
C32 C31 H31 120.7 . . ?
C31 C32 H32 120.2 . . ?
C31 C32 C33 119.5(6) . . ?
C33 C32 H32 120.2 . . ?
C32 C33 C34 118.0(7) . . ?
C32 C33 C36 122.6(7) . . ?
C34 C33 C36 119.4(6) . . ?
N2 C34 C29 118.8(6) . . ?
N2 C34 C33 122.1(6) . . ?
C33 C34 C29 119.1(6) . . ?
C28 C35 H35 119.9 . . ?
C36 C35 C28 120.3(7) . . ?
C36 C35 H35 119.9 . . ?
C33 C36 H36 119.2 . . ?
C35 C36 C33 121.6(7) . . ?
C35 C36 H36 119.2 . . ?
C7 S1 C4 91.3(3) . . ?
C15 S2 C12 91.6(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 N1 C25 C26 170.4(5) . . . . ?
Eu1 N1 C29 C28 -170.6(5) . . . . ?
Eu1 N1 C29 C34 10.1(7) . . . . ?
Eu1 N2 C30 C31 -171.4(5) . . . . ?
Eu1 N2 C34 C29 -8.6(7) . . . . ?
Eu1 N2 C34 C33 170.4(4) . . . . ?
Eu1 O1 C1 C2 0.7(11) . . . . ?
Eu1 O1 C1 C4 179.1(4) . . . . ?
Eu1 O2 C3 C2 -2.0(12) . . . . ?
Eu1 O2 C3 C8 -179.5(4) . . . . ?
Eu1 O3 C9 C10 7.5(11) . . . . ?
Eu1 O3 C9 C12 -176.6(4) . . . . ?
Eu1 O4 C11 C10 -19.0(11) . . . . ?
Eu1 O4 C11 C16 167.6(5) . . . . ?
Eu1 O5 C17 C18 2.0(11) . . . . ?
Eu1 O5 C17 C20 -178.2(4) . . . . ?
Eu1 O6 C19 C18 -2.6(12) . . . . ?
Eu1 O6 C19 C24 176.4(5) . . . . ?
N1 C25 C26 C27 0.2(10) . . . . ?
N1 C29 C34 N2 -1.0(8) . . . . ?
N1 C29 C34 C33 180.0(5) . . . . ?
N2 C30 C31 C32 1.0(10) . . . . ?
O1 C1 C2 C3 2.4(11) . . . . ?
O1 C1 C4 C5 -178.2(7) . . . . ?
O1 C1 C4 S1 -2.2(9) . . . . ?
O2 C3 C8 F1 -174.4(6) . . . . ?
O2 C3 C8 F2 66.8(8) . . . . ?
O3 C9 C10 C11 9.5(12) . . . . ?
O3 C9 C12 C13 -179.2(8) . . . . ?
O3 C9 C12 S2 -2.3(9) . . . . ?
O4 C11 C16 F3 -35.8(10) . . . . ?
O4 C11 C16 F4 76.3(9) . . . . ?
O5 C17 C18 C19 0.2(12) . . . . ?
O5 C17 C20 C21 -168.6(5) . . . . ?
O5 C17 C20 S3 7.8(8) . . . . ?
O6 C19 C24 F5 -44.1(9) . . . . ?
O6 C19 C24 F6 71.8(8) . . . . ?
C1 C2 C3 O2 -1.8(12) . . . . ?
C1 C2 C3 C8 175.6(6) . . . . ?
C1 C4 C5 C6 179.0(7) . . . . ?
C1 C4 S1 C7 -178.6(6) . . . . ?
C2 C1 C4 C5 0.3(11) . . . . ?
C2 C1 C4 S1 176.3(5) . . . . ?
C2 C3 C8 F1 7.8(10) . . . . ?
C2 C3 C8 F2 -111.0(7) . . . . ?
C4 C1 C2 C3 -176.0(6) . . . . ?
C4 C5 C6 C7 -2.6(10) . . . . ?
C5 C4 S1 C7 -1.9(6) . . . . ?
C5 C6 C7 S1 1.3(10) . . . . ?
C6 C7 S1 C4 0.4(7) . . . . ?
C9 C10 C11 O4 -3.4(13) . . . . ?
C9 C10 C11 C16 170.2(7) . . . . ?
C9 C12 C13 C14 176.0(8) . . . . ?
C9 C12 S2 C15 -176.7(6) . . . . ?
C10 C9 C12 C13 -3.1(13) . . . . ?
C10 C9 C12 S2 173.8(6) . . . . ?
C10 C11 C16 F3 150.0(7) . . . . ?
C10 C11 C16 F4 -97.8(8) . . . . ?
C12 C9 C10 C11 -166.3(7) . . . . ?
C12 C13 C14 C15 0.7(13) . . . . ?
C13 C12 S2 C15 0.8(7) . . . . ?
C13 C14 C15 S2 -0.1(11) . . . . ?
C14 C15 S2 C12 -0.4(8) . . . . ?
C17 C18 C19 O6 0.2(14) . . . . ?
C17 C18 C19 C24 -178.8(7) . . . . ?
C17 C20 C21 C22 176.5(7) . . . . ?
C17 C20 S3 C23 -176.8(6) . . . . ?
C18 C17 C20 C21 11.2(9) . . . . ?
C18 C17 C20 S3 -172.3(6) . . . . ?
C18 C19 C24 F5 135.0(8) . . . . ?
C18 C19 C24 F6 -109.0(8) . . . . ?
C20 C17 C18 C19 -179.6(7) . . . . ?
C20 C21 C22 C23 0.0(2) . . . . ?
C20 S3 C23 C22 -0.1(4) . . . . ?
C21 C20 S3 C23 0.0(3) . . . . ?
C21 C22 C23 S3 0.1(4) . . . . ?
S3 C20 C21 C22 -0.01(17) . . . . ?
C25 N1 C29 C28 0.2(9) . . . . ?
C25 N1 C29 C34 -179.1(5) . . . . ?
C25 C26 C27 C28 -0.3(11) . . . . ?
C26 C27 C28 C29 0.4(10) . . . . ?
C26 C27 C28 C35 -178.7(7) . . . . ?
C27 C28 C29 N1 -0.4(10) . . . . ?
C27 C28 C29 C34 178.9(6) . . . . ?
C27 C28 C35 C36 -179.0(7) . . . . ?
C28 C29 C34 N2 179.7(6) . . . . ?
C28 C29 C34 C33 0.6(9) . . . . ?
C28 C35 C36 C33 -0.5(12) . . . . ?
C29 N1 C25 C26 -0.1(9) . . . . ?
C29 C28 C35 C36 1.9(11) . . . . ?
C30 N2 C34 C29 179.1(6) . . . . ?
C30 N2 C34 C33 -1.8(9) . . . . ?
C30 C31 C32 C33 -1.6(10) . . . . ?
C31 C32 C33 C34 0.6(10) . . . . ?
C31 C32 C33 C36 180.0(6) . . . . ?
C32 C33 C34 N2 1.2(9) . . . . ?
C32 C33 C34 C29 -179.8(6) . . . . ?
C32 C33 C36 C35 179.8(7) . . . . ?
C34 N2 C30 C31 0.7(10) . . . . ?
C34 C33 C36 C35 -0.8(11) . . . . ?
C35 C28 C29 N1 178.7(6) . . . . ?
C35 C28 C29 C34 -2.0(9) . . . . ?
C36 C33 C34 N2 -178.2(6) . . . . ?
C36 C33 C34 C29 0.8(9) . . . . ?
S1 C4 C5 C6 2.8(8) . . . . ?
S2 C12 C13 C14 -1.0(10) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_b_a
_database_code_depnum_ccdc_archive 'CCDC 2088575'
loop_
_audit_author_name
_audit_author_address
'Konstantin Lyssenko'
;Chemical Department MSU
Russia
;
_audit_update_record             
;
2021-06-07 deposited with the CCDC.	2021-10-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C42 H20 Eu F21 N2 O6 S3'
_chemical_formula_sum            'C42 H20 Eu F21 N2 O6 S3'
_chemical_formula_weight         1295.74

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   20.6112(6)
_cell_length_b                   17.9832(5)
_cell_length_c                   25.1758(8)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     9331.5(5)
_cell_formula_units_Z            8
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    8932
_cell_measurement_theta_min      2.25
_cell_measurement_theta_max      28.2

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.845
_exptl_crystal_F_000             5072
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.372
_exptl_crystal_size_mid          0.314
_exptl_crystal_size_min          0.158
_exptl_absorpt_coefficient_mu    1.612
_shelx_estimated_absorpt_T_min   0.585
_shelx_estimated_absorpt_T_max   0.785
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.495
_exptl_absorpt_correction_T_max  0.658
_exptl_absorpt_process_details   
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_measurement_device_type  'Bruker D8 Quest with Photon III detector'
_diffrn_measurement_method       'φ and ω shutterless scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            78170
_diffrn_reflns_av_unetI/netI     0.0209
_diffrn_reflns_av_R_equivalents  0.0368
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_theta_min         1.976
_diffrn_reflns_theta_max         27.499
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             10719
_reflns_number_gt                9531
_reflns_threshold_expression     I>2σ(I)
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX3 (Bruker, 2019)'
_computing_cell_refinement       'SAINT (Bruker, 2019)'
_computing_data_reduction        'SAINT (Bruker, 2019)'
_computing_structure_solution    
'SHELXT, SHELXS-2013 (Sheldrick, Acta Cryst., 2015, A71, 3-8)'
_computing_structure_refinement  
'SHELXL-2018 (Sheldrick, Acta Cryst., 2015, C71, 3-8)'
_computing_molecular_graphics    
'SHELXTL (Sheldrick, Acta Cryst., 2008, A64, 112-122)'
_computing_publication_material  
'SHELXTL (Sheldrick, Acta Cryst., 2008, A64, 112-122)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0524P)²+78.8996P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10719
_refine_ls_number_parameters     743
_refine_ls_number_restraints     128
_refine_ls_R_factor_all          0.0778
_refine_ls_R_factor_gt           0.0704
_refine_ls_wR_factor_ref         0.1631
_refine_ls_wR_factor_gt          0.1583
_refine_ls_goodness_of_fit_ref   1.100
_refine_ls_restrained_S_all      1.100
_refine_ls_shift/su_max          0.035
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.61916(2) 0.67468(2) 0.58264(2) 0.03080(10) Uani 1 1 d . . . . .
O1A O 0.6906(2) 0.5774(2) 0.56054(18) 0.0337(9) Uani 1 1 d . . . . .
O2A O 0.6259(2) 0.5929(3) 0.6554(2) 0.0426(11) Uani 1 1 d . . . . .
S1A S 0.77956(9) 0.51459(10) 0.48774(8) 0.0486(4) Uani 1 1 d . . . . .
F1A F 0.5953(2) 0.4881(3) 0.7289(2) 0.0695(14) Uani 1 1 d D . . . .
F2A F 0.6963(3) 0.4595(3) 0.73779(18) 0.0688(14) Uani 1 1 d D . . . .
C9Z C 0.6591(11) 0.5759(14) 0.7593(6) 0.058(3) Uani 0.336(5) 1 d D . P A 2
C10Z C 0.6684(7) 0.5551(8) 0.8188(5) 0.070(4) Uani 0.336(5) 1 d D . P A 2
F3Z F 0.7052(9) 0.6272(11) 0.7500(8) 0.086(2) Uani 0.336(5) 1 d D . P A 2
F4Z F 0.6096(16) 0.6246(16) 0.7572(8) 0.125(4) Uani 0.336(5) 1 d D . P A 2
F5Z F 0.6622(8) 0.6150(7) 0.8505(6) 0.083(2) Uani 0.336(5) 1 d D . P A 2
F6Z F 0.7264(6) 0.5245(9) 0.8301(7) 0.090(3) Uani 0.336(5) 1 d D . P A 2
F7Z F 0.6230(7) 0.5059(9) 0.8345(8) 0.103(3) Uani 0.336(5) 1 d D . P A 2
C9A C 0.6669(5) 0.5697(8) 0.7754(4) 0.058(3) Uani 0.664(5) 1 d D . P A 1
C10A C 0.6281(4) 0.6391(5) 0.7760(3) 0.070(4) Uani 0.664(5) 1 d D . P A 1
F3A F 0.7299(4) 0.5897(6) 0.7726(4) 0.086(2) Uani 0.664(5) 1 d D . P A 1
F4A F 0.6512(8) 0.5321(7) 0.8200(4) 0.125(4) Uani 0.664(5) 1 d D . P A 1
F5A F 0.6493(4) 0.6896(4) 0.7406(2) 0.083(2) Uani 0.664(5) 1 d D . P A 1
F6A F 0.5645(4) 0.6291(6) 0.7665(3) 0.090(3) Uani 0.664(5) 1 d D . P A 1
F7A F 0.6328(5) 0.6708(6) 0.8243(2) 0.103(3) Uani 0.664(5) 1 d D . P A 1
C1A C 0.7220(3) 0.5273(3) 0.5840(3) 0.0321(12) Uani 1 1 d . . . . .
C2A C 0.7140(3) 0.5105(3) 0.6382(3) 0.0364(13) Uani 1 1 d . . . . .
H2AA H 0.742157 0.475325 0.654397 0.044 Uiso 1 1 calc R U . . .
C3A C 0.6665(3) 0.5433(3) 0.6684(3) 0.0374(14) Uani 1 1 d . . . . .
C4A C 0.7667(3) 0.4837(3) 0.5506(3) 0.0332(13) Uani 1 1 d . . . . .
C5A C 0.7973(3) 0.4100(3) 0.5607(3) 0.0353(7) Uani 1 1 d . U . . .
H5AA H 0.795532 0.381717 0.592483 0.042 Uiso 1 1 calc R U . . .
C6A C 0.8297(3) 0.3909(4) 0.5130(2) 0.0353(7) Uani 1 1 d . U . . .
H6AA H 0.853850 0.346068 0.509687 0.042 Uiso 1 1 calc R U . . .
C7A C 0.8245(3) 0.4399(3) 0.4723(3) 0.0353(7) Uani 1 1 d . . . . .
H7AA H 0.844177 0.432663 0.438522 0.042 Uiso 1 1 calc R U . . .
C8A C 0.6558(2) 0.5157(3) 0.7254(3) 0.0495(18) Uani 1 1 d D . . . .
O1 O 0.68170(19) 0.7124(2) 0.50769(17) 0.0311(9) Uani 1 1 d . . . . .
O2 O 0.7181(2) 0.7209(3) 0.61466(19) 0.0461(12) Uani 1 1 d . . . . .
S1 S 0.70757(14) 0.70736(19) 0.39575(10) 0.0679(10) Uani 0.859(8) 1 d D . P B 1
C5 C 0.8283(4) 0.6886(10) 0.4245(5) 0.055(3) Uani 0.859(8) 1 d D . P B 1
H5A H 0.866234 0.682156 0.445333 0.066 Uiso 0.859(8) 1 calc R U P B 1
S1' S 0.8404(7) 0.690(3) 0.4237(11) 0.0679(10) Uani 0.141(8) 1 d D . P B 2
C5' C 0.734(2) 0.726(3) 0.3938(4) 0.055(3) Uani 0.141(8) 1 d D . P B 2
H5'A H 0.697712 0.758812 0.390925 0.066 Uiso 0.141(8) 1 calc R U P B 2
C1 C 0.7415(3) 0.7121(3) 0.4995(3) 0.0328(12) Uani 1 1 d . . . . .
C2 C 0.7892(3) 0.7164(4) 0.5400(3) 0.0386(14) Uani 1 1 d . . . . .
H2A H 0.833668 0.715268 0.530137 0.046 Uiso 1 1 calc R U . . .
C3 C 0.7737(3) 0.7220(5) 0.5927(3) 0.0498(18) Uani 1 1 d D . . . .
C4 C 0.7635(3) 0.7061(4) 0.4449(2) 0.0403(14) Uani 1 1 d D . . . .
C6 C 0.8249(5) 0.6829(5) 0.3673(4) 0.073(3) Uani 1 1 d D . . . .
H6A H 0.859002 0.671551 0.342662 0.088 Uiso 1 1 d R U . B .
C7 C 0.7646(6) 0.6919(6) 0.3481(4) 0.078(3) Uani 1 1 d D . . . .
H7A H 0.747279 0.680899 0.313550 0.093 Uiso 1 1 d R U . B .
C8' C 0.8227(6) 0.7663(9) 0.6274(5) 0.0399(19) Uani 0.287(4) 1 d D . P C 2
C9' C 0.8368(8) 0.7157(12) 0.6762(7) 0.043(2) Uani 0.287(4) 1 d D . P C 2
C10' C 0.8985(6) 0.7374(8) 0.7081(5) 0.052(3) Uani 0.287(4) 1 d D . P C 2
F1' F 0.8825(6) 0.7771(11) 0.6072(7) 0.0550(16) Uani 0.287(4) 1 d D . P C 2
F2' F 0.810(2) 0.8312(9) 0.6519(10) 0.076(3) Uani 0.287(4) 1 d D . P C 2
F3' F 0.7907(16) 0.7510(19) 0.7044(13) 0.067(2) Uani 0.287(4) 1 d D . P C 2
F4' F 0.840(2) 0.6424(13) 0.6545(13) 0.065(3) Uani 0.287(4) 1 d . . P C 2
F5' F 0.9001(8) 0.7004(8) 0.7544(5) 0.0695(19) Uani 0.287(4) 1 d D . P C 2
F6' F 0.9539(7) 0.7212(10) 0.6823(5) 0.071(2) Uani 0.287(4) 1 d D . P C 2
F7' F 0.9005(9) 0.8103(7) 0.7199(7) 0.075(2) Uani 0.287(4) 1 d D . P C 2
C8 C 0.8316(3) 0.7123(4) 0.6318(2) 0.0399(19) Uani 0.713(4) 1 d D . P C 1
C9 C 0.8227(3) 0.7671(4) 0.6790(2) 0.043(2) Uani 0.713(4) 1 d D . P C 1
C10 C 0.8883(3) 0.7818(3) 0.7074(2) 0.052(3) Uani 0.713(4) 1 d D . P C 1
F1 F 0.8884(2) 0.7292(4) 0.6080(3) 0.0550(16) Uani 0.713(4) 1 d D . P C 1
F2 F 0.8373(9) 0.6458(6) 0.6561(6) 0.076(3) Uani 0.713(4) 1 d D . P C 1
F3 F 0.7825(6) 0.7364(7) 0.7151(4) 0.067(2) Uani 0.713(4) 1 d D . P C 1
F4 F 0.8038(7) 0.8328(4) 0.6584(4) 0.065(3) Uani 0.713(4) 1 d D . P C 1
F5 F 0.9290(3) 0.8258(3) 0.6799(2) 0.0695(19) Uani 0.713(4) 1 d D . P C 1
F6 F 0.8770(3) 0.8162(4) 0.7539(2) 0.071(2) Uani 0.713(4) 1 d D . P C 1
F7 F 0.9211(3) 0.7190(3) 0.7184(3) 0.075(2) Uani 0.713(4) 1 d D . P C 1
O1B O 0.55631(18) 0.7638(2) 0.53524(18) 0.0327(9) Uani 1 1 d . . . . .
O2B O 0.5834(2) 0.7646(2) 0.64270(18) 0.0377(10) Uani 1 1 d . . . . .
S1B S 0.52071(10) 0.83423(11) 0.43681(8) 0.0530(5) Uani 1 1 d . . . . .
F1B F 0.5327(3) 0.8110(3) 0.7329(2) 0.0865(19) Uani 1 1 d D . . . .
F2B F 0.4858(2) 0.9046(3) 0.6944(2) 0.0772(16) Uani 1 1 d D . . . .
F3B F 0.6166(14) 0.9509(14) 0.6620(8) 0.082(5) Uani 0.408(7) 1 d D U P D 1
F4B F 0.6438(6) 0.8637(7) 0.7246(5) 0.064(2) Uani 0.408(7) 1 d D U P D 1
F5B F 0.5630(6) 0.9385(9) 0.7876(8) 0.117(4) Uani 0.408(7) 1 d D U P D 1
F7B F 0.5547(6) 1.0292(9) 0.7320(6) 0.120(4) Uani 0.408(7) 1 d D U P D 1
C10B C 0.5913(5) 0.9701(7) 0.7452(6) 0.097(6) Uani 0.408(7) 1 d D . P D 1
F3H F 0.5952(9) 0.9678(8) 0.6701(6) 0.082(5) Uani 0.592(7) 1 d D U P D 2
F4H F 0.6567(3) 0.8768(6) 0.6960(4) 0.064(2) Uani 0.592(7) 1 d D U P D 2
F5H F 0.5474(6) 0.9734(9) 0.7766(7) 0.117(4) Uani 0.592(7) 1 d D U P D 2
F7H F 0.6201(7) 0.8966(8) 0.7948(5) 0.120(4) Uani 0.592(7) 1 d D U P D 2
C10H C 0.6059(7) 0.9506(11) 0.7596(6) 0.097(6) Uani 0.592(7) 1 d D . P D 2
F6B F 0.6491(3) 0.9966(5) 0.7613(3) 0.125(3) Uani 1 1 d D . . . .
C1B C 0.5230(2) 0.8206(3) 0.5451(3) 0.0308(12) Uani 1 1 d . . . . .
C2B C 0.5140(3) 0.8492(3) 0.5969(3) 0.0367(14) Uani 1 1 d . . . . .
H2BA H 0.485332 0.889930 0.601904 0.044 Uiso 1 1 calc R U . . .
C3B C 0.5456(3) 0.8197(4) 0.6403(3) 0.0365(13) Uani 1 1 d . . . . .
C4B C 0.4961(3) 0.8605(3) 0.4994(3) 0.0318(12) Uani 1 1 d . . . . .
C5B C 0.4508(3) 0.9236(3) 0.4996(3) 0.0440(17) Uani 1 1 d . . . . .
H5BA H 0.430608 0.945749 0.529575 0.053 Uiso 1 1 calc R U . . .
C6B C 0.4436(4) 0.9448(4) 0.4448(4) 0.0518(19) Uani 1 1 d . . . . .
H6BA H 0.417037 0.985523 0.434490 0.062 Uiso 1 1 calc R U . . .
C7B C 0.4766(4) 0.9037(4) 0.4089(3) 0.0511(18) Uani 1 1 d . . . . .
H7BA H 0.475274 0.912825 0.371769 0.061 Uiso 1 1 calc R U . . .
C8B C 0.5389(3) 0.8611(4) 0.6935(3) 0.0527(19) Uani 1 1 d D . . . .
C9B C 0.5996(3) 0.9117(4) 0.7054(3) 0.060(2) Uani 1 1 d D . . . .
N1 N 0.4996(3) 0.6349(3) 0.5995(3) 0.0445(14) Uani 1 1 d . . . . .
N2 N 0.5617(2) 0.6046(3) 0.5075(2) 0.0339(11) Uani 1 1 d . . . . .
C1P C 0.4698(4) 0.6439(4) 0.6460(4) 0.057(2) Uani 1 1 d . . . . .
H1PA H 0.495154 0.652924 0.676856 0.068 Uiso 1 1 calc R U . . .
C2P C 0.4015(4) 0.6402(5) 0.6508(5) 0.075(3) Uani 1 1 d . . . . .
H2PA H 0.381646 0.643991 0.684776 0.090 Uiso 1 1 calc R U . . .
C3P C 0.3649(4) 0.6315(5) 0.6073(5) 0.075(3) Uani 1 1 d . . . . .
H3PA H 0.318905 0.632280 0.610009 0.089 Uiso 1 1 calc R U . . .
C4P C 0.3942(3) 0.6212(4) 0.5580(4) 0.060(2) Uani 1 1 d . . . . .
C5P C 0.3602(4) 0.6101(5) 0.5089(5) 0.077(3) Uani 1 1 d . . . . .
H5PA H 0.314217 0.614029 0.508930 0.092 Uiso 1 1 calc R U . . .
C6P C 0.3901(4) 0.5945(4) 0.4635(5) 0.069(3) Uani 1 1 d . . . . .
H6PA H 0.365231 0.586161 0.432288 0.083 Uiso 1 1 calc R U . . .
C7P C 0.4598(4) 0.5902(3) 0.4612(4) 0.051(2) Uani 1 1 d . . . . .
C8P C 0.4934(5) 0.5698(4) 0.4162(4) 0.065(3) Uani 1 1 d . . . . .
H8PA H 0.470412 0.558541 0.384522 0.078 Uiso 1 1 calc R U . . .
C9P C 0.5598(4) 0.5658(4) 0.4170(3) 0.056(2) Uani 1 1 d . . . . .
H9PA H 0.583325 0.550415 0.386423 0.067 Uiso 1 1 calc R U . . .
C10P C 0.5920(3) 0.5850(3) 0.4643(3) 0.0428(16) Uani 1 1 d . . . . .
H10A H 0.638114 0.583606 0.464727 0.051 Uiso 1 1 calc R U . . .
C11P C 0.4633(3) 0.6218(3) 0.5558(4) 0.0465(18) Uani 1 1 d . . . . .
C12P C 0.4961(3) 0.6057(3) 0.5077(3) 0.0417(16) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O2B 2.333(4) . ?
Eu1 O2 2.345(4) . ?
Eu1 O1A 2.353(4) . ?
Eu1 O2A 2.353(5) . ?
Eu1 O1B 2.381(4) . ?
Eu1 O1 2.384(4) . ?
Eu1 N2 2.562(5) . ?
Eu1 N1 2.602(5) . ?
O1A C1A 1.257(7) . ?
O2A C3A 1.266(7) . ?
S1A C7A 1.678(6) . ?
S1A C4A 1.697(7) . ?
F1A C8A 1.346(4) . ?
F2A C8A 1.349(4) . ?
C9Z F4Z 1.346(5) . ?
C9Z F3Z 1.346(5) . ?
C9Z C8A 1.38(3) . ?
C9Z C10Z 1.555(7) . ?
C10Z F7Z 1.345(5) . ?
C10Z F5Z 1.346(5) . ?
C10Z F6Z 1.346(5) . ?
C9A F3A 1.349(5) . ?
C9A F4A 1.350(5) . ?
C9A C10A 1.482(18) . ?
C9A C8A 1.607(15) . ?
C10A F6A 1.345(5) . ?
C10A F5A 1.345(5) . ?
C10A F7A 1.346(5) . ?
C1A C2A 1.409(9) . ?
C1A C4A 1.473(8) . ?
C2A C3A 1.372(9) . ?
C2A H2AA 0.9500 . ?
C3A C8A 1.533(9) . ?
C4A C5A 1.490(8) . ?
C5A C6A 1.416(9) . ?
C5A H5AA 0.9500 . ?
C6A C7A 1.356(9) . ?
C6A H6AA 0.9500 . ?
C7A H7AA 0.9500 . ?
O1 C1 1.251(7) . ?
O2 C3 1.272(8) . ?
S1 C4 1.692(4) . ?
S1 C7 1.703(10) . ?
C5 C6 1.444(10) . ?
C5 C4 1.464(4) . ?
C5 H5A 0.9500 . ?
S1' C6 1.46(4) . ?
S1' C4 1.696(5) . ?
C5' C7 1.452(10) . ?
C5' C4 1.471(4) . ?
C5' H5'A 0.9500 . ?
C1 C2 1.417(9) . ?
C1 C4 1.451(8) . ?
C2 C3 1.369(10) . ?
C2 H2A 0.9500 . ?
C3 C8' 1.557(7) . ?
C3 C8 1.557(6) . ?
C6 C7 1.343(15) . ?
C6 H6A 0.9599 . ?
C7 H7A 0.9599 . ?
C8' F2' 1.347(5) . ?
C8' F1' 1.347(5) . ?
C8' C9' 1.554(7) . ?
C9' F3' 1.346(4) . ?
C9' F4' 1.43(3) . ?
C9' C10' 1.553(7) . ?
C10' F5' 1.344(5) . ?
C10' F6' 1.344(5) . ?
C10' F7' 1.345(5) . ?
C8 F2 1.348(4) . ?
C8 F1 1.351(4) . ?
C8 C9 1.554(6) . ?
C9 F3 1.348(4) . ?
C9 F4 1.347(4) . ?
C9 C10 1.553(6) . ?
C10 F6 1.343(3) . ?
C10 F7 1.344(3) . ?
C10 F5 1.345(3) . ?
O1B C1B 1.256(7) . ?
O2B C3B 1.262(7) . ?
S1B C7B 1.697(7) . ?
S1B C4B 1.721(7) . ?
F1B C8B 1.345(4) . ?
F2B C8B 1.347(4) . ?
F3B C9B 1.346(5) . ?
F4B C9B 1.346(5) . ?
F5B C10B 1.344(5) . ?
F7B C10B 1.344(5) . ?
C10B F6B 1.346(5) . ?
C10B C9B 1.462(15) . ?
F3H C9B 1.348(5) . ?
F4H C9B 1.355(4) . ?
F5H C10H 1.343(5) . ?
F7H C10H 1.346(5) . ?
C10H F6B 1.22(2) . ?
C10H C9B 1.54(2) . ?
C1B C2B 1.413(9) . ?
C1B C4B 1.465(9) . ?
C2B C3B 1.378(9) . ?
C2B H2BA 0.9500 . ?
C3B C8B 1.539(10) . ?
C4B C5B 1.469(8) . ?
C5B C6B 1.438(11) . ?
C5B H5BA 0.9500 . ?
C6B C7B 1.352(11) . ?
C6B H6BA 0.9500 . ?
C7B H7BA 0.9500 . ?
C8B C9B 1.576(12) . ?
N1 C1P 1.332(10) . ?
N1 C11P 1.351(10) . ?
N2 C10P 1.305(9) . ?
N2 C12P 1.352(8) . ?
C1P C2P 1.414(11) . ?
C1P H1PA 0.9500 . ?
C2P C3P 1.340(15) . ?
C2P H2PA 0.9500 . ?
C3P C4P 1.392(15) . ?
C3P H3PA 0.9500 . ?
C4P C11P 1.425(9) . ?
C4P C5P 1.435(14) . ?
C5P C6P 1.329(15) . ?
C5P H5PA 0.9500 . ?
C6P C7P 1.440(11) . ?
C6P H6PA 0.9500 . ?
C7P C8P 1.377(13) . ?
C7P C12P 1.416(10) . ?
C8P C9P 1.371(12) . ?
C8P H8PA 0.9500 . ?
C9P C10P 1.407(10) . ?
C9P H9PA 0.9500 . ?
C10P H10A 0.9500 . ?
C11P C12P 1.416(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2B Eu1 O2 78.83(16) . . ?
O2B Eu1 O1A 150.01(15) . . ?
O2 Eu1 O1A 78.52(16) . . ?
O2B Eu1 O2A 86.99(16) . . ?
O2 Eu1 O2A 84.43(17) . . ?
O1A Eu1 O2A 71.48(15) . . ?
O2B Eu1 O1B 71.73(15) . . ?
O2 Eu1 O1B 114.00(16) . . ?
O1A Eu1 O1B 136.23(15) . . ?
O2A Eu1 O1B 147.44(15) . . ?
O2B Eu1 O1 119.12(14) . . ?
O2 Eu1 O1 72.60(16) . . ?
O1A Eu1 O1 71.72(14) . . ?
O2A Eu1 O1 139.65(14) . . ?
O1B Eu1 O1 72.90(14) . . ?
O2B Eu1 N2 132.29(15) . . ?
O2 Eu1 N2 146.10(17) . . ?
O1A Eu1 N2 75.47(15) . . ?
O2A Eu1 N2 107.10(17) . . ?
O1B Eu1 N2 73.12(14) . . ?
O1 Eu1 N2 78.80(16) . . ?
O2B Eu1 N1 77.60(17) . . ?
O2 Eu1 N1 149.92(19) . . ?
O1A Eu1 N1 115.27(16) . . ?
O2A Eu1 N1 75.94(17) . . ?
O1B Eu1 N1 75.59(16) . . ?
O1 Eu1 N1 136.03(17) . . ?
N2 Eu1 N1 63.08(19) . . ?
C1A O1A Eu1 138.1(4) . . ?
C3A O2A Eu1 132.9(4) . . ?
C7A S1A C4A 92.4(3) . . ?
F4Z C9Z F3Z 95(2) . . ?
F4Z C9Z C8A 116.6(18) . . ?
F3Z C9Z C8A 117.7(18) . . ?
F4Z C9Z C10Z 106.7(19) . . ?
F3Z C9Z C10Z 104.2(17) . . ?
C8A C9Z C10Z 114.5(15) . . ?
F7Z C10Z F5Z 106.7(5) . . ?
F7Z C10Z F6Z 106.7(5) . . ?
F5Z C10Z F6Z 106.6(5) . . ?
F7Z C10Z C9Z 110.8(14) . . ?
F5Z C10Z C9Z 111.5(15) . . ?
F6Z C10Z C9Z 114.2(15) . . ?
F3A C9A F4A 114.0(12) . . ?
F3A C9A C10A 107.2(10) . . ?
F4A C9A C10A 106.5(11) . . ?
F3A C9A C8A 104.9(9) . . ?
F4A C9A C8A 108.3(10) . . ?
C10A C9A C8A 116.1(7) . . ?
F6A C10A F5A 106.8(5) . . ?
F6A C10A F7A 106.7(5) . . ?
F5A C10A F7A 106.8(5) . . ?
F6A C10A C9A 114.3(8) . . ?
F5A C10A C9A 112.7(7) . . ?
F7A C10A C9A 109.1(8) . . ?
O1A C1A C2A 123.3(6) . . ?
O1A C1A C4A 115.8(6) . . ?
C2A C1A C4A 120.9(5) . . ?
C3A C2A C1A 121.9(6) . . ?
C3A C2A H2AA 119.1 . . ?
C1A C2A H2AA 119.1 . . ?
O2A C3A C2A 129.1(6) . . ?
O2A C3A C8A 112.0(6) . . ?
C2A C3A C8A 118.8(5) . . ?
C1A C4A C5A 129.9(6) . . ?
C1A C4A S1A 117.1(4) . . ?
C5A C4A S1A 112.5(5) . . ?
C6A C5A C4A 105.8(6) . . ?
C6A C5A H5AA 127.1 . . ?
C4A C5A H5AA 127.1 . . ?
C7A C6A C5A 116.4(6) . . ?
C7A C6A H6AA 121.8 . . ?
C5A C6A H6AA 121.8 . . ?
C6A C7A S1A 112.9(5) . . ?
C6A C7A H7AA 123.6 . . ?
S1A C7A H7AA 123.6 . . ?
F1A C8A F2A 106.3(5) . . ?
F1A C8A C9Z 107.2(11) . . ?
F2A C8A C9Z 114.4(10) . . ?
F1A C8A C3A 108.4(5) . . ?
F2A C8A C3A 111.7(6) . . ?
C9Z C8A C3A 108.6(7) . . ?
F1A C8A C9A 107.7(6) . . ?
F2A C8A C9A 100.5(6) . . ?
C3A C8A C9A 121.1(5) . . ?
C1 O1 Eu1 131.5(4) . . ?
C3 O2 Eu1 129.7(4) . . ?
C4 S1 C7 92.5(4) . . ?
C6 C5 C4 108.8(9) . . ?
C6 C5 H5A 125.6 . . ?
C4 C5 H5A 125.6 . . ?
C6 S1' C4 96.7(13) . . ?
C7 C5' C4 114.0(10) . . ?
C7 C5' H5'A 123.0 . . ?
C4 C5' H5'A 123.0 . . ?
O1 C1 C2 124.4(6) . . ?
O1 C1 C4 117.6(5) . . ?
C2 C1 C4 118.0(5) . . ?
C3 C2 C1 122.6(6) . . ?
C3 C2 H2A 118.7 . . ?
C1 C2 H2A 118.7 . . ?
O2 C3 C2 129.1(6) . . ?
O2 C3 C8' 110.4(7) . . ?
C2 C3 C8' 115.5(8) . . ?
O2 C3 C8 114.4(6) . . ?
C2 C3 C8 115.2(6) . . ?
C1 C4 C5 129.3(7) . . ?
C1 C4 C5' 132.9(10) . . ?
C1 C4 S1 118.6(4) . . ?
C5 C4 S1 111.5(7) . . ?
C1 C4 S1' 127.0(11) . . ?
C5' C4 S1' 98.9(17) . . ?
C7 C6 C5 113.3(9) . . ?
C7 C6 S1' 122.8(8) . . ?
C7 C6 H6A 118.1 . . ?
C5 C6 H6A 128.6 . . ?
S1' C6 H6A 119.1 . . ?
C6 C7 C5' 99.7(15) . . ?
C6 C7 S1 113.8(8) . . ?
C6 C7 H7A 130.2 . . ?
C5' C7 H7A 130.0 . . ?
S1 C7 H7A 114.5 . . ?
F2' C8' F1' 103(2) . . ?
F2' C8' C9' 100.6(16) . . ?
F1' C8' C9' 102.2(15) . . ?
F2' C8' C3 125(2) . . ?
F1' C8' C3 117.1(11) . . ?
C9' C8' C3 105.4(9) . . ?
F3' C9' F4' 132(3) . . ?
F3' C9' C10' 101(2) . . ?
F4' C9' C10' 113(2) . . ?
F3' C9' C8' 90.5(17) . . ?
F4' C9' C8' 104.3(18) . . ?
C10' C9' C8' 114.5(12) . . ?
F5' C10' F6' 106.9(5) . . ?
F5' C10' F7' 106.9(5) . . ?
F6' C10' F7' 106.9(5) . . ?
F5' C10' C9' 110.1(12) . . ?
F6' C10' C9' 113.0(13) . . ?
F7' C10' C9' 112.6(14) . . ?
F2 C8 F1 109.0(10) . . ?
F2 C8 C9 103.2(9) . . ?
F1 C8 C9 107.4(5) . . ?
F2 C8 C3 116.9(9) . . ?
F1 C8 C3 111.0(5) . . ?
C9 C8 C3 108.8(6) . . ?
F3 C9 F4 116.2(10) . . ?
F3 C9 C10 107.0(8) . . ?
F4 C9 C10 106.3(7) . . ?
F3 C9 C8 109.2(7) . . ?
F4 C9 C8 107.3(5) . . ?
C10 C9 C8 110.9(6) . . ?
F6 C10 F7 107.1(4) . . ?
F6 C10 F5 106.6(4) . . ?
F7 C10 F5 106.7(4) . . ?
F6 C10 C9 109.2(6) . . ?
F7 C10 C9 112.9(5) . . ?
F5 C10 C9 113.9(5) . . ?
C1B O1B Eu1 138.2(4) . . ?
C3B O2B Eu1 135.1(4) . . ?
C7B S1B C4B 91.1(4) . . ?
F5B C10B F7B 106.8(6) . . ?
F5B C10B F6B 107.1(6) . . ?
F7B C10B F6B 107.0(6) . . ?
F5B C10B C9B 106.9(13) . . ?
F7B C10B C9B 117.6(11) . . ?
F6B C10B C9B 111.0(9) . . ?
F6B C10H F5H 116.0(17) . . ?
F6B C10H F7H 108.0(14) . . ?
F5H C10H F7H 101.9(13) . . ?
F6B C10H C9B 113.7(10) . . ?
F5H C10H C9B 110.1(14) . . ?
F7H C10H C9B 105.9(13) . . ?
O1B C1B C2B 123.4(6) . . ?
O1B C1B C4B 116.7(6) . . ?
C2B C1B C4B 119.8(5) . . ?
C3B C2B C1B 122.0(5) . . ?
C3B C2B H2BA 119.0 . . ?
C1B C2B H2BA 119.0 . . ?
O2B C3B C2B 129.2(6) . . ?
O2B C3B C8B 113.1(6) . . ?
C2B C3B C8B 117.6(5) . . ?
C1B C4B C5B 128.0(6) . . ?
C1B C4B S1B 118.2(4) . . ?
C5B C4B S1B 113.7(5) . . ?
C6B C5B C4B 105.5(7) . . ?
C6B C5B H5BA 127.2 . . ?
C4B C5B H5BA 127.2 . . ?
C7B C6B C5B 116.3(6) . . ?
C7B C6B H6BA 121.8 . . ?
C5B C6B H6BA 121.8 . . ?
C6B C7B S1B 113.3(6) . . ?
C6B C7B H7BA 123.3 . . ?
S1B C7B H7BA 123.3 . . ?
F1B C8B F2B 107.4(6) . . ?
F1B C8B C3B 109.1(6) . . ?
F2B C8B C3B 111.5(6) . . ?
F1B C8B C9B 108.8(6) . . ?
F2B C8B C9B 107.9(6) . . ?
C3B C8B C9B 111.9(5) . . ?
F4B C9B F3B 116.9(13) . . ?
F3H C9B F4H 106.9(10) . . ?
F4B C9B C10B 107.1(9) . . ?
F3B C9B C10B 102.1(16) . . ?
F3H C9B C10H 104.5(11) . . ?
F4H C9B C10H 106.9(7) . . ?
F4B C9B C8B 103.6(8) . . ?
F3B C9B C8B 110.8(15) . . ?
F3H C9B C8B 104.7(10) . . ?
F4H C9B C8B 112.9(7) . . ?
C10B C9B C8B 116.9(6) . . ?
C10H C9B C8B 119.9(8) . . ?
C1P N1 C11P 118.9(6) . . ?
C1P N1 Eu1 123.1(5) . . ?
C11P N1 Eu1 116.0(5) . . ?
C10P N2 C12P 119.0(6) . . ?
C10P N2 Eu1 121.8(4) . . ?
C12P N2 Eu1 117.0(4) . . ?
N1 C1P C2P 121.9(9) . . ?
N1 C1P H1PA 119.1 . . ?
C2P C1P H1PA 119.1 . . ?
C3P C2P C1P 119.7(10) . . ?
C3P C2P H2PA 120.1 . . ?
C1P C2P H2PA 120.1 . . ?
C2P C3P C4P 120.0(8) . . ?
C2P C3P H3PA 120.0 . . ?
C4P C3P H3PA 120.0 . . ?
C3P C4P C11P 118.0(9) . . ?
C3P C4P C5P 124.9(8) . . ?
C11P C4P C5P 117.1(9) . . ?
C6P C5P C4P 122.9(8) . . ?
C6P C5P H5PA 118.5 . . ?
C4P C5P H5PA 118.5 . . ?
C5P C6P C7P 120.6(8) . . ?
C5P C6P H6PA 119.7 . . ?
C7P C6P H6PA 119.7 . . ?
C8P C7P C12P 117.7(7) . . ?
C8P C7P C6P 123.3(8) . . ?
C12P C7P C6P 118.9(9) . . ?
C9P C8P C7P 120.4(7) . . ?
C9P C8P H8PA 119.8 . . ?
C7P C8P H8PA 119.8 . . ?
C8P C9P C10P 118.0(9) . . ?
C8P C9P H9PA 121.0 . . ?
C10P C9P H9PA 121.0 . . ?
N2 C10P C9P 123.1(7) . . ?
N2 C10P H10A 118.4 . . ?
C9P C10P H10A 118.4 . . ?
N1 C11P C12P 118.0(6) . . ?
N1 C11P C4P 121.4(8) . . ?
C12P C11P C4P 120.6(8) . . ?
N2 C12P C11P 118.8(6) . . ?
N2 C12P C7P 121.6(7) . . ?
C11P C12P C7P 119.6(7) . . ?

_refine_diff_density_max         2.020
_refine_diff_density_min         -1.503
_refine_diff_density_rms         0.131


_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_3_a
_database_code_depnum_ccdc_archive 'CCDC 2081277'
loop_
_audit_author_name
_audit_author_address
'Mikhail Kiskin'
;Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2021-04-30 deposited with the CCDC.	2021-10-25 downloaded from the CCDC.
;
_audit_creation_date             2021-02-23
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'0.5(C36 H20 Eu F9 N2 O6 S2.78), 0.5(C36 H19 Eu F9 N2 O6 S2.614), C3 H6 O, 0.303(S)'
_chemical_formula_sum            'C39 H26 Eu F9 N2 O7 S3'
_chemical_formula_weight         1053.76
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 1 21 1'
_space_group_name_Hall           'P 2yb'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   9.8914(5)
_cell_length_b                   10.6986(5)
_cell_length_c                   38.1886(18)
_cell_angle_alpha                90
_cell_angle_beta                 89.992(2)
_cell_angle_gamma                90
_cell_volume                     4041.3(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9918
_cell_measurement_temperature    296.15
_cell_measurement_theta_max      29.42
_cell_measurement_theta_min      2.18
_shelx_estimated_absorpt_T_max   0.915
_shelx_estimated_absorpt_T_min   0.662
_exptl_absorpt_coefficient_mu    1.801
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.5868
_exptl_absorpt_correction_type   'multi scan'
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0980 before and 0.0667 after correction.
The Ratio of minimum to maximum transmission is 0.7865.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.732
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       parallelepiped
_exptl_crystal_F_000             2088
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0442
_diffrn_reflns_av_unetI/netI     0.0813
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       49
_diffrn_reflns_limit_l_min       -50
_diffrn_reflns_number            42018
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.281
_diffrn_reflns_theta_min         1.600
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.887
_reflns_Friedel_fraction_full    0.988
_reflns_Friedel_fraction_max     0.986
_reflns_number_gt                16463
_reflns_number_total             19911
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_refine_diff_density_max         1.291
_refine_diff_density_min         -2.857
_refine_diff_density_rms         0.122
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.018(12)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.105
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1116
_refine_ls_number_reflns         19911
_refine_ls_number_restraints     170
_refine_ls_R_factor_all          0.0709
_refine_ls_R_factor_gt           0.0556
_refine_ls_restrained_S_all      1.110
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+7.3898P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0914
_refine_ls_wR_factor_ref         0.0965
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.982(12)
 0.018(12)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3. Restrained distances
 S2-C12 = S2-C15
 1.7 with sigma of 0.01
 S2A-C12 = S2A-C14
 1.7 with sigma of 0.01
 S5-C48 = S5-C51
 1.7 with sigma of 0.01
 S5A-C48 = S5A-C50
 1.7 with sigma of 0.01
 S4-C40 = S4-C43
 1.7 with sigma of 0.01
 S4A-C40 = S4A-C42
 1.7 with sigma of 0.01
 C41-C42 = C42-C43
 1.39 with sigma of 0.01
 C40-C41
 1.34 with sigma of 0.01
 C13-C14 = C14-C15
 1.39 with sigma of 0.01
 C12-C13
 1.34 with sigma of 0.01
 C49-C50 = C50-C51
 1.39 with sigma of 0.01
 C48-C49
 1.34 with sigma of 0.01
4. Restrained planarity
 S4, C40, C41, C42, C43
 with sigma of 0.01
 S5, C48, C49, C50, C51
 with sigma of 0.01
5. Uiso/Uaniso restraints and constraints
Uanis(C13) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(C21) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(C41) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(C49) \\sim Ueq: with sigma of 0.003 and sigma for terminal atoms of 0.006
Uanis(S2) = Uanis(S2A)
Uanis(S4) = Uanis(S4A)
Uanis(S5) = Uanis(S5A)
6. Rigid body (RIGU) restrains
 C21, C20, C21, C22
 with sigma for 1-2 distances of 0.005 and sigma for 1-3 distances of 0.01
 C41, C42, C41, C40
 with sigma for 1-2 distances of 0.005 and sigma for 1-3 distances of 0.01
 C16, F4, C16, F5, C16, F6
 with sigma for 1-2 distances of 0.008 and sigma for 1-3 distances of 0.016
 C26, C25, C26, C27
 with sigma for 1-2 distances of 0.008 and sigma for 1-3 distances of 0.016
 C52, F13, C52, F14, C52, F15
 with sigma for 1-2 distances of 0.008 and sigma for 1-3 distances of 0.016
 C44, F10, C44, F11, C44, F12
 with sigma for 1-2 distances of 0.008 and sigma for 1-3 distances of 0.016
 C24, F7, C24, F8, C24, F9
 with sigma for 1-2 distances of 0.008 and sigma for 1-3 distances of 0.016
 C13, C12, C13, C14
 with sigma for 1-2 distances of 0.003 and sigma for 1-3 distances of 0.006
 C48, C49, C49, C50
 with sigma for 1-2 distances of 0.008 and sigma for 1-3 distances of 0.016
 C63, C62, C63, C64
 with sigma for 1-2 distances of 0.008 and sigma for 1-3 distances of 0.016
7. Others
 Sof(S5A)=1-FVAR(1)
 Sof(S5)=FVAR(1)
 Sof(S4A)=1-FVAR(2)
 Sof(S4)=FVAR(2)
 Sof(S2A)=1-FVAR(3)
 Sof(S2)=FVAR(3)
8.a Aromatic/amide H refined with riding coordinates:
 C26(H26), C38(H38), C43(H43), C62(H62), C57(H57), C21(H21), C54(H54),
 C78(H78), C23(H23), C61(H61), C25(H25), C15(H15), C2(H2), C36(H36), C32(H32),
 C02D(H02D), C51(H51), C67(H67), C35(H35), C66(H66), C7(H7), C6(H6), C30(H30),
 C63(H63), C59(H59), C27(H27), C31(H31), C71(H71), C46(H46), C58(H58), C42(H42),
  C41(H41), C50(H50), C72(H72), C13(H13), C22(H22), C18(H18), C10(H10), C14(H14)
8.b Idealised Me refined as rotating group:
 C5S(H5SA,H5SB,H5SC), C3S(H3SA,H3SB,H3SC), C2S(H2SA,H2SB,H2SC), C6S(H6SA,H6SB,
 H6SC)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.71853(3) -0.64254(6) 0.36670(2) 0.01732(9) Uani 1 1 d . . . . .
Eu2 Eu 0.71852(3) 0.85746(6) 0.13331(2) 0.01721(9) Uani 1 1 d . . . . .
S1 S 0.4155(3) -0.5858(3) 0.46944(7) 0.0327(6) Uani 1 1 d . . . . .
S3 S 0.4045(3) -0.8761(3) 0.28623(9) 0.0434(7) Uani 1 1 d . . . . .
S6 S 0.4153(3) 0.9141(3) 0.03062(7) 0.0326(6) Uani 1 1 d . . . . .
S2 S 0.4053(3) -1.0067(3) 0.40030(12) 0.0427(11) Uani 0.780(6) 1 d D . P A 5
S4 S 0.4049(3) 0.6244(3) 0.21387(9) 0.0297(8) Uani 0.838(6) 1 d D . P B 3
S5 S 0.4052(3) 0.4926(3) 0.09959(12) 0.0426(11) Uani 0.776(6) 1 d D . P C 1
C49 C 0.5889(10) 0.3259(8) 0.0897(2) 0.015(3) Uani 1 1 d D U . C 1
F3 F 1.1081(6) -0.4141(7) 0.4321(2) 0.064(2) Uani 1 1 d . . . . .
F16 F 1.1085(6) 1.0859(7) 0.0683(2) 0.065(2) Uani 1 1 d . . . . .
O4 O 0.8959(6) -0.7895(6) 0.36774(19) 0.0275(16) Uani 1 1 d . . . . .
O11 O 0.6479(6) 0.8986(5) 0.07556(16) 0.0221(14) Uani 1 1 d . . . . .
O1 O 0.6476(6) -0.6011(5) 0.42435(16) 0.0217(14) Uani 1 1 d . . . . .
O2 O 0.8803(6) -0.5108(6) 0.39333(16) 0.0201(13) Uani 1 1 d . . . . .
O12 O 0.8806(6) 0.9884(6) 0.10669(17) 0.0213(14) Uani 1 1 d . . . . .
F1 F 1.0220(7) -0.2952(7) 0.39301(17) 0.052(2) Uani 1 1 d . . . . .
O8 O 0.8574(6) 0.8940(5) 0.18439(16) 0.0224(14) Uani 1 1 d . . . . .
F10 F 1.0195(8) 0.7868(9) 0.2597(2) 0.084(3) Uani 1 1 d . . . . .
O6 O 0.8582(6) -0.6056(5) 0.31563(16) 0.0228(15) Uani 1 1 d . . . . .
F15 F 1.0798(8) 0.5959(7) 0.1729(2) 0.074(3) Uani 1 1 d . . . . .
F13 F 1.0233(7) 0.4174(6) 0.1551(2) 0.074(3) Uani 1 1 d . . . . .
F8 F 0.9987(9) -0.5267(8) 0.2575(3) 0.103(4) Uani 1 1 d . . . . .
O10 O 0.8966(6) 0.7095(6) 0.13232(18) 0.0255(15) Uani 1 1 d . . . . .
F9 F 1.1113(5) -0.6545(12) 0.28677(16) 0.070(2) Uani 1 1 d . . . . .
F4 F 1.0227(7) -1.0831(6) 0.3447(2) 0.074(3) Uani 1 1 d . . . . .
F11 F 1.1113(5) 0.8477(13) 0.21343(16) 0.073(2) Uani 1 1 d . . . . .
F5 F 1.0795(8) -0.9036(7) 0.3270(2) 0.074(3) Uani 1 1 d . . . . .
C44 C 1.0010(9) 0.8550(16) 0.2318(2) 0.034(2) Uani 1 1 d . . . . .
F17 F 1.0216(8) 1.2042(7) 0.10684(18) 0.056(2) Uani 1 1 d . . . . .
O7 O 0.6186(6) 0.7604(6) 0.18183(17) 0.0245(15) Uani 1 1 d . . . . .
C69 C 0.4815(9) 1.2241(8) 0.1746(2) 0.0216(19) Uani 1 1 d . . . . .
C24 C 1.0010(9) -0.6482(15) 0.2685(2) 0.033(2) Uani 1 1 d . . . . .
C26 C 0.2366(8) -0.6430(16) 0.3733(2) 0.031(2) Uani 1 1 d . . . . .
H26 H 0.173861 -0.702466 0.382037 0.037 Uiso 1 1 calc R U . . .
N3 N 0.4645(7) 0.9127(7) 0.13403(19) 0.0196(16) Uani 1 1 d . . . . .
C8 C 0.9962(10) -0.3511(10) 0.4235(3) 0.033(2) Uani 1 1 d . . . . .
C38 C 0.7922(9) 0.7304(9) 0.2236(3) 0.026(2) Uani 1 1 d . . . . .
H38 H 0.824141 0.679822 0.242258 0.031 Uiso 1 1 calc R U . . .
F7 F 1.0185(8) -0.7114(9) 0.2402(2) 0.078(3) Uani 1 1 d . . . . .
C60 C 0.9962(10) 1.1496(10) 0.0766(3) 0.033(2) Uani 1 1 d . . . . .
F12 F 0.9969(9) 0.9708(8) 0.2427(3) 0.106(4) Uani 1 1 d . . . . .
C19 C 0.8736(8) -0.6753(7) 0.2895(2) 0.018(2) Uani 1 1 d . . . . .
C12 C 0.5695(8) -1.0464(7) 0.3993(2) 0.0200(19) Uani 1 1 d D . . A 5
C43 C 0.3608(10) 0.5167(7) 0.2437(2) 0.036(3) Uani 1 1 d D . . B 3
H43 H 0.271143 0.486364 0.246393 0.043 Uiso 1 1 calc R U . B 3
C62 C 0.2350(8) 0.8551(15) 0.1268(2) 0.030(2) Uani 1 1 d . . . . .
H62 H 0.172121 0.794619 0.118660 0.036 Uiso 1 1 calc R U . . .
F6 F 1.1224(7) -0.9555(9) 0.3793(2) 0.078(3) Uani 1 1 d . . . . .
C53 C 0.6646(9) 0.9865(8) 0.0537(2) 0.0194(19) Uani 1 1 d . . . . .
C20 C 0.5699(9) -0.8773(8) 0.2734(2) 0.0185(18) Uani 1 1 d . . . . .
C48 C 0.5694(8) 0.4534(7) 0.1004(2) 0.0204(19) Uani 1 1 d D . . C 1
F18 F 0.9814(7) 1.2372(7) 0.0531(2) 0.063(2) Uani 1 1 d . . . . .
C57 C 0.5509(10) 1.0892(10) 0.0005(3) 0.028(2) Uani 1 1 d . . . . .
H57 H 0.620106 1.147076 -0.005348 0.033 Uiso 1 1 calc R U . . .
C17 C 0.6618(9) -0.7926(8) 0.2909(2) 0.021(2) Uani 1 1 d . . . . .
C37 C 0.6631(9) 0.7069(8) 0.2092(2) 0.0172(18) Uani 1 1 d . . . . .
C21 C 0.5969(7) -0.9691(6) 0.24367(18) 0.0050(14) Uani 1 1 d . U . . .
H21 H 0.680680 -0.986152 0.232513 0.006 Uiso 1 1 calc R U . . .
C33 C 0.4811(9) -0.2761(8) 0.3254(2) 0.0202(19) Uani 1 1 d . . . . .
C54 C 0.7781(9) 1.0675(9) 0.0545(2) 0.024(2) Uani 1 1 d . . . . .
H54 H 0.786971 1.128821 0.036617 0.029 Uiso 1 1 calc R U . . .
O5 O 0.6183(6) -0.7393(6) 0.31805(16) 0.0235(14) Uani 1 1 d . . . . .
O1S O 1.1522(8) 0.2454(8) 0.4777(2) 0.060(3) Uani 1 1 d . . . . .
O9 O 0.6293(6) 0.6634(6) 0.11180(17) 0.0227(14) Uani 1 1 d . . . . .
O3 O 0.6296(6) -0.8357(6) 0.38857(17) 0.0240(15) Uani 1 1 d . . . . .
N2 N 0.6549(7) -0.4216(7) 0.34427(19) 0.0181(16) Uani 1 1 d . . . . .
C9 C 0.6672(9) -0.9505(8) 0.3878(2) 0.022(2) Uani 1 1 d . . . . .
F2 F 0.9813(7) -0.2636(7) 0.4473(2) 0.061(2) Uani 1 1 d . . . . .
N1 N 0.4639(7) -0.5875(7) 0.3660(2) 0.0192(16) Uani 1 1 d . . . . .
C78 C 0.5822(10) 1.3062(9) 0.1857(2) 0.028(2) Uani 1 1 d . . . . .
H78 H 0.558921 1.384186 0.195937 0.033 Uiso 1 1 calc R U . . .
C47 C 0.8962(9) 0.5908(9) 0.1331(3) 0.025(2) Uani 1 1 d . . . . .
C1S C 1.0542(11) 0.1857(11) 0.4699(3) 0.035(3) Uani 1 1 d . . . . .
N4 N 0.6534(7) 1.0786(7) 0.15562(19) 0.0189(16) Uani 1 1 d . . . . .
C23 C 0.3615(11) -0.9825(10) 0.2562(3) 0.044(3) Uani 1 1 d . . . . .
H23 H 0.271360 -1.011453 0.253353 0.052 Uiso 1 1 calc R U . . .
C45 C 0.6668(9) 0.5502(8) 0.1118(2) 0.0201(19) Uani 1 1 d . . . . .
O2S O 1.1520(8) 1.7453(9) 0.0225(3) 0.064(3) Uani 1 1 d . . . . .
C61 C 0.3709(9) 0.8332(8) 0.1233(3) 0.028(3) Uani 1 1 d . . . . .
H61 H 0.399156 0.757307 0.112654 0.034 Uiso 1 1 calc R U . . .
C25 C 0.3699(9) -0.6678(7) 0.3771(3) 0.028(2) Uani 1 1 d . . . . .
H25 H 0.397102 -0.743827 0.387825 0.034 Uiso 1 1 calc R U . . .
C15 C 0.3567(9) -1.1485(10) 0.4137(3) 0.042(2) Uani 1 1 d D . . A 5
H15 H 0.265181 -1.171242 0.417725 0.051 Uiso 1 1 calc R U . A 5
C2 C 0.7781(9) -0.4323(9) 0.4456(3) 0.025(2) Uani 1 1 d . . . . .
H2 H 0.786527 -0.370979 0.463419 0.030 Uiso 1 1 calc R U . . .
C36 C 0.3382(10) -0.2519(10) 0.3209(3) 0.032(2) Uani 1 1 d . . . . .
H36 H 0.309981 -0.175536 0.310572 0.038 Uiso 1 1 calc R U . . .
C32 C 0.5828(10) -0.1940(9) 0.3141(2) 0.026(2) Uani 1 1 d . . . . .
H32 H 0.559436 -0.116093 0.303787 0.031 Uiso 1 1 calc R U . . .
C4 C 0.5598(9) -0.4973(9) 0.4727(2) 0.021(2) Uani 1 1 d . . . . .
C55 C 0.8754(8) 1.0608(8) 0.0798(2) 0.0179(18) Uani 1 1 d . . . . .
C40 C 0.5686(8) 0.6216(7) 0.2274(2) 0.023(2) Uani 1 1 d D . . B 3
C34 C 0.5226(9) -0.3903(8) 0.3404(2) 0.0175(18) Uani 1 1 d . . . . .
C70 C 0.5217(9) 1.1093(8) 0.1597(2) 0.0173(18) Uani 1 1 d . . . . .
C5S C 1.0590(12) 1.5446(12) 0.0325(4) 0.053(3) Uani 1 1 d . . . . .
H5SA H 1.006631 1.508934 0.013178 0.080 Uiso 1 1 calc R U . . .
H5SB H 1.021028 1.516311 0.054866 0.080 Uiso 1 1 calc R U . . .
H5SC H 1.153277 1.517215 0.030722 0.080 Uiso 1 1 calc R U . . .
C02D C 0.5507(9) -0.4107(9) 0.4994(3) 0.026(2) Uani 1 1 d . . . . .
H02D H 0.619694 -0.352120 0.504872 0.031 Uiso 1 1 calc R U . . .
C1 C 0.6648(9) -0.5146(9) 0.4462(2) 0.021(2) Uani 1 1 d . . . . .
C51 C 0.3571(9) 0.3520(10) 0.0861(2) 0.042(2) Uani 1 1 d D . . C 1
H51 H 0.265528 0.329890 0.081919 0.051 Uiso 1 1 calc R U . C 1
C67 C 0.7149(10) 1.2732(9) 0.1817(3) 0.028(2) Uani 1 1 d . . . . .
H67 H 0.784212 1.328666 0.189103 0.033 Uiso 1 1 calc R U . . .
C35 C 0.2462(9) -0.3341(9) 0.3310(3) 0.030(2) Uani 1 1 d . . . . .
H35 H 0.153131 -0.315938 0.327587 0.036 Uiso 1 1 calc R U . . .
C16 C 1.0295(10) -0.9638(9) 0.3540(3) 0.037(3) Uani 1 1 d . . . . .
C65 C 0.4217(8) 1.0219(8) 0.1483(2) 0.0181(18) Uani 1 1 d . . . . .
C39 C 0.8726(8) 0.8253(8) 0.2109(2) 0.021(2) Uani 1 1 d . . . . .
C3 C 0.8752(8) -0.4387(8) 0.4200(2) 0.0187(18) Uani 1 1 d . . . . .
F14 F 1.1223(7) 0.5445(9) 0.1212(3) 0.086(3) Uani 1 1 d . . . . .
C4S C 1.0529(11) 1.6864(11) 0.0307(3) 0.038(3) Uani 1 1 d . . . . .
C66 C 0.7491(9) 1.1576(8) 0.1667(2) 0.0194(19) Uani 1 1 d . . . . .
H66 H 0.841557 1.135155 0.164431 0.023 Uiso 1 1 calc R U . . .
C64 C 0.2844(9) 1.0517(9) 0.1533(3) 0.026(2) Uani 1 1 d . . . . .
C56 C 0.5599(9) 1.0043(9) 0.0276(2) 0.0203(19) Uani 1 1 d . . . . .
C7 C 0.3461(11) -0.5098(11) 0.5040(3) 0.037(3) Uani 1 1 d . . . . .
H7 H 0.259048 -0.528506 0.513079 0.045 Uiso 1 1 calc R U . . .
C6 C 0.4277(11) -0.4194(11) 0.5174(3) 0.040(3) Uani 1 1 d . . . . .
H6 H 0.403908 -0.367955 0.536688 0.047 Uiso 1 1 calc R U . . .
C30 C 0.7485(9) -0.3418(8) 0.3333(2) 0.0213(19) Uani 1 1 d . . . . .
H30 H 0.841079 -0.363204 0.336064 0.026 Uiso 1 1 calc R U . . .
C63 C 0.1894(9) 0.9610(10) 0.1416(3) 0.030(2) Uani 1 1 d . . . . .
H63 H 0.095112 0.975049 0.144266 0.036 Uiso 1 1 calc R U . . .
C11 C 0.8964(9) -0.9089(9) 0.3669(3) 0.026(2) Uani 1 1 d . . . . .
C59 C 0.3451(11) 0.9882(11) -0.0040(3) 0.039(3) Uani 1 1 d . . . . .
H59 H 0.258343 0.968714 -0.013166 0.046 Uiso 1 1 calc R U . . .
C27 C 0.1866(10) -0.5389(10) 0.3578(3) 0.030(2) Uani 1 1 d . . . . .
H27 H 0.092475 -0.525878 0.354360 0.036 Uiso 1 1 calc R U . . .
C3S C 0.9211(13) 0.2444(11) 0.4624(4) 0.057(4) Uani 1 1 d . . . . .
H3SA H 0.858284 0.225964 0.481580 0.085 Uiso 1 1 calc R U . . .
H3SB H 0.884901 0.210879 0.440460 0.085 Uiso 1 1 calc R U . . .
H3SC H 0.932383 0.335109 0.460298 0.085 Uiso 1 1 calc R U . . .
C31 C 0.7155(10) -0.2268(9) 0.3179(2) 0.027(2) Uani 1 1 d . . . . .
H31 H 0.784916 -0.172149 0.310085 0.033 Uiso 1 1 calc R U . . .
C71 C 0.2458(9) 1.1672(10) 0.1689(3) 0.033(2) Uani 1 1 d . . . . .
H71 H 0.152786 1.186164 0.172046 0.040 Uiso 1 1 calc R U . . .
C52 C 1.0289(10) 0.5373(10) 0.1457(3) 0.034(2) Uani 1 1 d . . . . .
C2S C 1.0597(13) 0.0431(12) 0.4676(4) 0.054(3) Uani 1 1 d . . . . .
H2SA H 1.153272 0.014928 0.470504 0.081 Uiso 1 1 calc R U . . .
H2SB H 1.025866 0.016052 0.444682 0.081 Uiso 1 1 calc R U . . .
H2SC H 1.003352 0.006815 0.486100 0.081 Uiso 1 1 calc R U . . .
C46 C 0.7986(10) 0.5098(9) 0.1232(3) 0.029(2) Uani 1 1 d . . . . .
H46 H 0.817681 0.422762 0.123753 0.034 Uiso 1 1 calc R U . . .
C58 C 0.4277(11) 1.0800(10) -0.0174(3) 0.034(2) Uani 1 1 d . . . . .
H58 H 0.403825 1.131590 -0.036672 0.041 Uiso 1 1 calc R U . . .
C42 C 0.4658(10) 0.4774(9) 0.2635(2) 0.035(3) Uani 1 1 d D . . B 3
H42 H 0.458354 0.416074 0.281400 0.042 Uiso 1 1 calc R U . B 3
C41 C 0.5877(13) 0.5380(9) 0.2546(3) 0.031(4) Uani 1 1 d D U . B 3
H41 H 0.671950 0.523192 0.265773 0.037 Uiso 1 1 calc R U . B 3
C6S C 0.9205(11) 1.7429(12) 0.0378(4) 0.052(4) Uani 1 1 d . . . . .
H6SA H 0.932230 1.831620 0.043409 0.078 Uiso 1 1 calc R U . . .
H6SB H 0.877831 1.700140 0.057582 0.078 Uiso 1 1 calc R U . . .
H6SC H 0.862909 1.734776 0.016999 0.078 Uiso 1 1 calc R U . . .
C50 C 0.4616(10) 0.2722(9) 0.0817(2) 0.038(3) Uani 1 1 d D . . C 1
H50 H 0.450842 0.188302 0.074054 0.046 Uiso 1 1 calc R U . C 1
C72 C 0.3403(10) 1.2490(9) 0.1790(3) 0.031(2) Uani 1 1 d . . . . .
H72 H 0.313010 1.325658 0.189361 0.037 Uiso 1 1 calc R U . . .
C13 C 0.5896(11) -1.1736(9) 0.4101(3) 0.021(3) Uani 1 1 d D U . A 5
H13 H 0.674354 -1.215027 0.411612 0.025 Uiso 1 1 calc R U . A 5
C29 C 0.4221(9) -0.4795(8) 0.3515(2) 0.0170(18) Uani 1 1 d . . . . .
C22 C 0.4660(11) -1.0246(9) 0.2362(3) 0.031(2) Uani 1 1 d . . . . .
H22 H 0.454116 -1.086069 0.218489 0.037 Uiso 1 1 calc R U . . .
C18 C 0.7929(9) -0.7707(9) 0.2766(3) 0.027(2) Uani 1 1 d . . . . .
H18 H 0.825194 -0.821854 0.258071 0.032 Uiso 1 1 calc R U . . .
C10 C 0.7976(9) -0.9898(9) 0.3767(3) 0.029(2) Uani 1 1 d . . . . .
H10 H 0.816609 -1.076784 0.376141 0.034 Uiso 1 1 calc R U . . .
C28 C 0.2848(9) -0.4514(10) 0.3470(2) 0.025(2) Uani 1 1 d . . . . .
C14 C 0.4621(9) -1.2273(9) 0.4180(3) 0.033(2) Uani 1 1 d D . . A 5
H14 H 0.451826 -1.311199 0.425778 0.040 Uiso 1 1 calc R U . A 5
S5A S 0.6206(17) 0.3127(17) 0.0875(6) 0.0426(11) Uani 0.224(6) 1 d . . P C 2
S4A S 0.612(2) 0.521(2) 0.2581(7) 0.0297(8) Uani 0.162(6) 1 d . . P B 4
S2A S 0.6139(17) -1.1881(17) 0.4131(7) 0.0427(11) Uani 0.220(6) 1 d . . P A 6


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O4 2.356(6) . ?
Eu1 O1 2.353(6) . ?
Eu1 O2 2.362(6) . ?
Eu1 O6 2.422(6) . ?
Eu1 O5 2.347(6) . ?
Eu1 O3 2.396(6) . ?
Eu1 N2 2.592(7) . ?
Eu1 N1 2.586(7) . ?
Eu2 O11 2.355(6) . ?
Eu2 O12 2.359(6) . ?
Eu2 O8 2.418(6) . ?
Eu2 O10 2.369(6) . ?
Eu2 O7 2.343(6) . ?
Eu2 N3 2.581(7) . ?
Eu2 O9 2.400(6) . ?
Eu2 N4 2.596(7) . ?
S1 C4 1.717(9) . ?
S1 C7 1.695(11) . ?
S3 C20 1.708(9) . ?
S3 C23 1.671(12) . ?
S6 C56 1.729(9) . ?
S6 C59 1.691(11) . ?
S2 C12 1.679(8) . ?
S2 C15 1.672(10) . ?
S4 C43 1.678(8) . ?
S4 C40 1.701(8) . ?
S5 C48 1.678(8) . ?
S5 C51 1.659(10) . ?
C49 C48 1.436(10) . ?
C49 C50 1.417(10) . ?
F3 C8 1.338(12) . ?
F16 C60 1.340(12) . ?
O4 C11 1.278(11) . ?
O11 C53 1.269(10) . ?
O1 C1 1.258(10) . ?
O2 C3 1.280(10) . ?
O12 C55 1.286(10) . ?
F1 C8 1.333(12) . ?
O8 C39 1.259(10) . ?
F10 C44 1.304(13) . ?
O6 C19 1.255(10) . ?
F15 C52 1.314(13) . ?
F13 C52 1.333(12) . ?
F8 C24 1.366(17) . ?
O10 C47 1.270(11) . ?
F9 C24 1.296(10) . ?
F4 C16 1.326(12) . ?
F11 C44 1.299(10) . ?
F5 C16 1.311(13) . ?
C44 F12 1.309(17) . ?
C44 C39 1.534(12) . ?
F17 C60 1.320(12) . ?
O7 C37 1.271(10) . ?
C69 C78 1.394(13) . ?
C69 C70 1.410(12) . ?
C69 C72 1.431(13) . ?
C24 F7 1.289(12) . ?
C24 C19 1.521(11) . ?
C26 H26 0.9500 . ?
C26 C25 1.353(12) . ?
C26 C27 1.354(18) . ?
N3 C61 1.322(11) . ?
N3 C65 1.357(11) . ?
C8 F2 1.314(11) . ?
C8 C3 1.526(12) . ?
C38 H38 0.9500 . ?
C38 C37 1.412(12) . ?
C38 C39 1.378(12) . ?
C60 F18 1.305(12) . ?
C60 C55 1.533(12) . ?
C19 C18 1.386(12) . ?
C12 C9 1.476(11) . ?
C12 C13 1.436(10) . ?
C43 H43 0.9500 . ?
C43 C42 1.352(10) . ?
C62 H62 0.9500 . ?
C62 C61 1.372(11) . ?
C62 C63 1.344(17) . ?
F6 C16 1.338(13) . ?
C53 C54 1.418(12) . ?
C53 C56 1.452(12) . ?
C20 C17 1.447(12) . ?
C20 C21 1.525(11) . ?
C48 C45 1.480(11) . ?
C57 H57 0.9500 . ?
C57 C56 1.379(13) . ?
C57 C58 1.400(14) . ?
C17 O5 1.258(10) . ?
C17 C18 1.428(12) . ?
C37 C40 1.480(11) . ?
C21 H21 0.9500 . ?
C21 C22 1.453(12) . ?
C33 C36 1.447(13) . ?
C33 C32 1.404(12) . ?
C33 C34 1.410(12) . ?
C54 H54 0.9500 . ?
C54 C55 1.367(12) . ?
O1S C1S 1.198(12) . ?
O9 C45 1.267(10) . ?
O3 C9 1.284(11) . ?
N2 C34 1.359(10) . ?
N2 C30 1.327(10) . ?
C9 C10 1.421(12) . ?
N1 C25 1.336(10) . ?
N1 C29 1.346(11) . ?
C78 H78 0.9500 . ?
C78 C67 1.368(13) . ?
C47 C52 1.511(14) . ?
C47 C46 1.352(13) . ?
C1S C3S 1.486(15) . ?
C1S C2S 1.530(16) . ?
N4 C70 1.353(10) . ?
N4 C66 1.337(11) . ?
C23 H23 0.9500 . ?
C23 C22 1.363(15) . ?
C45 C46 1.441(12) . ?
O2S C4S 1.206(13) . ?
C61 H61 0.9500 . ?
C25 H25 0.9500 . ?
C15 H15 0.9500 . ?
C15 C14 1.351(10) . ?
C2 H2 0.9500 . ?
C2 C1 1.425(13) . ?
C2 C3 1.371(12) . ?
C36 H36 0.9500 . ?
C36 C35 1.322(13) . ?
C32 H32 0.9500 . ?
C32 C31 1.367(13) . ?
C4 C02D 1.380(13) . ?
C4 C1 1.460(12) . ?
C40 C41 1.382(11) . ?
C34 C29 1.442(11) . ?
C70 C65 1.429(12) . ?
C5S H5SA 0.9800 . ?
C5S H5SB 0.9800 . ?
C5S H5SC 0.9800 . ?
C5S C4S 1.520(16) . ?
C02D H02D 0.9500 . ?
C02D C6 1.401(13) . ?
C51 H51 0.9500 . ?
C51 C50 1.351(10) . ?
C67 H67 0.9500 . ?
C67 C66 1.403(12) . ?
C35 H35 0.9500 . ?
C35 C28 1.448(13) . ?
C16 C11 1.524(13) . ?
C65 C64 1.408(12) . ?
F14 C52 1.318(12) . ?
C4S C6S 1.468(15) . ?
C66 H66 0.9500 . ?
C64 C63 1.423(13) . ?
C64 C71 1.422(14) . ?
C7 H7 0.9500 . ?
C7 C6 1.359(16) . ?
C6 H6 0.9500 . ?
C30 H30 0.9500 . ?
C30 C31 1.403(13) . ?
C63 H63 0.9500 . ?
C11 C10 1.358(13) . ?
C59 H59 0.9500 . ?
C59 C58 1.376(15) . ?
C27 H27 0.9500 . ?
C27 C28 1.410(13) . ?
C3S H3SA 0.9800 . ?
C3S H3SB 0.9800 . ?
C3S H3SC 0.9800 . ?
C31 H31 0.9500 . ?
C71 H71 0.9500 . ?
C71 C72 1.338(14) . ?
C2S H2SA 0.9800 . ?
C2S H2SB 0.9800 . ?
C2S H2SC 0.9800 . ?
C46 H46 0.9500 . ?
C58 H58 0.9500 . ?
C42 H42 0.9500 . ?
C42 C41 1.410(11) . ?
C41 H41 0.9500 . ?
C6S H6SA 0.9800 . ?
C6S H6SB 0.9800 . ?
C6S H6SC 0.9800 . ?
C50 H50 0.9500 . ?
C72 H72 0.9500 . ?
C13 H13 0.9500 . ?
C13 C14 1.419(11) . ?
C29 C28 1.401(12) . ?
C22 H22 0.9500 . ?
C18 H18 0.9500 . ?
C10 H10 0.9500 . ?
C14 H14 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Eu1 O2 83.5(2) . . ?
O4 Eu1 O6 72.4(2) . . ?
O4 Eu1 O3 72.1(2) . . ?
O4 Eu1 N2 142.7(2) . . ?
O4 Eu1 N1 151.3(2) . . ?
O1 Eu1 O4 109.4(2) . . ?
O1 Eu1 O2 71.7(2) . . ?
O1 Eu1 O6 153.2(2) . . ?
O1 Eu1 O3 74.2(2) . . ?
O1 Eu1 N2 93.7(2) . . ?
O1 Eu1 N1 71.2(2) . . ?
O2 Eu1 O6 82.1(2) . . ?
O2 Eu1 O3 127.8(2) . . ?
O2 Eu1 N2 76.3(2) . . ?
O2 Eu1 N1 121.9(2) . . ?
O6 Eu1 N2 74.0(2) . . ?
O6 Eu1 N1 120.6(2) . . ?
O5 Eu1 O4 91.9(2) . . ?
O5 Eu1 O1 134.3(2) . . ?
O5 Eu1 O2 152.9(2) . . ?
O5 Eu1 O6 71.1(2) . . ?
O5 Eu1 O3 74.9(2) . . ?
O5 Eu1 N2 92.2(2) . . ?
O5 Eu1 N1 71.4(2) . . ?
O3 Eu1 O6 129.1(2) . . ?
O3 Eu1 N2 144.4(2) . . ?
O3 Eu1 N1 81.0(2) . . ?
N1 Eu1 N2 63.4(2) . . ?
O11 Eu2 O12 71.8(2) . . ?
O11 Eu2 O8 153.39(19) . . ?
O11 Eu2 O10 109.3(2) . . ?
O11 Eu2 N3 71.2(2) . . ?
O11 Eu2 O9 74.5(2) . . ?
O11 Eu2 N4 93.6(2) . . ?
O12 Eu2 O8 82.3(2) . . ?
O12 Eu2 O10 83.4(2) . . ?
O12 Eu2 N3 122.0(2) . . ?
O12 Eu2 O9 128.0(2) . . ?
O12 Eu2 N4 76.6(2) . . ?
O8 Eu2 N3 120.5(2) . . ?
O8 Eu2 N4 74.3(2) . . ?
O10 Eu2 O8 72.4(2) . . ?
O10 Eu2 N3 151.3(2) . . ?
O10 Eu2 O9 71.9(2) . . ?
O10 Eu2 N4 143.0(2) . . ?
O7 Eu2 O11 134.3(2) . . ?
O7 Eu2 O12 153.0(2) . . ?
O7 Eu2 O8 70.9(2) . . ?
O7 Eu2 O10 91.7(2) . . ?
O7 Eu2 N3 71.5(2) . . ?
O7 Eu2 O9 74.5(2) . . ?
O7 Eu2 N4 92.3(2) . . ?
N3 Eu2 N4 63.0(2) . . ?
O9 Eu2 O8 128.7(2) . . ?
O9 Eu2 N3 81.0(2) . . ?
O9 Eu2 N4 144.0(2) . . ?
C7 S1 C4 90.9(5) . . ?
C23 S3 C20 92.4(5) . . ?
C59 S6 C56 91.4(5) . . ?
C15 S2 C12 93.2(4) . . ?
C43 S4 C40 91.6(5) . . ?
C51 S5 C48 93.2(5) . . ?
C50 C49 C48 109.1(8) . . ?
C11 O4 Eu1 132.0(6) . . ?
C53 O11 Eu2 135.7(6) . . ?
C1 O1 Eu1 136.1(5) . . ?
C3 O2 Eu1 132.5(5) . . ?
C55 O12 Eu2 132.4(5) . . ?
C39 O8 Eu2 128.4(5) . . ?
C19 O6 Eu1 127.8(5) . . ?
C47 O10 Eu2 131.7(6) . . ?
F10 C44 F12 105.8(10) . . ?
F10 C44 C39 115.2(10) . . ?
F11 C44 F10 106.8(11) . . ?
F11 C44 F12 104.8(12) . . ?
F11 C44 C39 113.7(8) . . ?
F12 C44 C39 109.7(10) . . ?
C37 O7 Eu2 134.8(6) . . ?
C78 C69 C70 118.0(9) . . ?
C78 C69 C72 123.0(9) . . ?
C70 C69 C72 119.0(8) . . ?
F8 C24 C19 109.2(9) . . ?
F9 C24 F8 103.2(12) . . ?
F9 C24 C19 113.9(8) . . ?
F7 C24 F8 104.1(10) . . ?
F7 C24 F9 108.2(10) . . ?
F7 C24 C19 117.0(10) . . ?
C25 C26 H26 117.8 . . ?
C25 C26 C27 124.4(11) . . ?
C27 C26 H26 117.8 . . ?
C61 N3 Eu2 122.1(6) . . ?
C61 N3 C65 117.4(7) . . ?
C65 N3 Eu2 120.3(5) . . ?
F3 C8 C3 111.1(9) . . ?
F1 C8 F3 106.5(8) . . ?
F1 C8 C3 110.5(8) . . ?
F2 C8 F3 106.3(9) . . ?
F2 C8 F1 107.8(9) . . ?
F2 C8 C3 114.2(8) . . ?
C37 C38 H38 119.4 . . ?
C39 C38 H38 119.4 . . ?
C39 C38 C37 121.1(9) . . ?
F16 C60 C55 110.5(9) . . ?
F17 C60 F16 105.9(9) . . ?
F17 C60 C55 110.6(8) . . ?
F18 C60 F16 107.2(9) . . ?
F18 C60 F17 107.8(9) . . ?
F18 C60 C55 114.4(8) . . ?
O6 C19 C24 113.9(8) . . ?
O6 C19 C18 130.6(8) . . ?
C18 C19 C24 115.5(9) . . ?
C9 C12 S2 117.7(6) . . ?
C13 C12 S2 111.5(7) . . ?
C13 C12 C9 130.8(8) . . ?
S4 C43 H43 123.4 . . ?
C42 C43 S4 113.2(8) . . ?
C42 C43 H43 123.4 . . ?
C61 C62 H62 119.5 . . ?
C63 C62 H62 119.5 . . ?
C63 C62 C61 120.9(11) . . ?
O11 C53 C54 122.9(8) . . ?
O11 C53 C56 117.2(8) . . ?
C54 C53 C56 119.9(8) . . ?
C17 C20 S3 117.7(7) . . ?
C17 C20 C21 129.6(8) . . ?
C21 C20 S3 112.7(6) . . ?
C49 C48 S5 111.2(7) . . ?
C49 C48 C45 131.3(8) . . ?
C45 C48 S5 117.5(6) . . ?
C56 C57 H57 124.0 . . ?
C56 C57 C58 112.1(9) . . ?
C58 C57 H57 124.0 . . ?
O5 C17 C20 116.7(8) . . ?
O5 C17 C18 123.5(9) . . ?
C18 C17 C20 119.8(8) . . ?
O7 C37 C38 123.5(8) . . ?
O7 C37 C40 116.5(8) . . ?
C38 C37 C40 119.9(8) . . ?
C20 C21 H21 127.6 . . ?
C22 C21 C20 104.8(7) . . ?
C22 C21 H21 127.6 . . ?
C32 C33 C36 123.5(8) . . ?
C32 C33 C34 117.3(9) . . ?
C34 C33 C36 119.2(8) . . ?
C53 C54 H54 118.7 . . ?
C55 C54 C53 122.6(8) . . ?
C55 C54 H54 118.7 . . ?
C17 O5 Eu1 135.0(6) . . ?
C45 O9 Eu2 136.0(6) . . ?
C9 O3 Eu1 135.4(6) . . ?
C34 N2 Eu1 119.7(5) . . ?
C30 N2 Eu1 121.4(6) . . ?
C30 N2 C34 118.6(8) . . ?
O3 C9 C12 118.0(8) . . ?
O3 C9 C10 123.5(8) . . ?
C10 C9 C12 118.5(8) . . ?
C25 N1 Eu1 121.9(6) . . ?
C25 N1 C29 117.9(7) . . ?
C29 N1 Eu1 120.0(6) . . ?
C69 C78 H78 120.4 . . ?
C67 C78 C69 119.3(9) . . ?
C67 C78 H78 120.4 . . ?
O10 C47 C52 112.6(8) . . ?
O10 C47 C46 129.6(9) . . ?
C46 C47 C52 117.8(9) . . ?
O1S C1S C3S 122.7(12) . . ?
O1S C1S C2S 121.1(11) . . ?
C3S C1S C2S 116.2(10) . . ?
C70 N4 Eu2 119.9(5) . . ?
C66 N4 Eu2 120.3(6) . . ?
C66 N4 C70 119.4(7) . . ?
S3 C23 H23 122.7 . . ?
C22 C23 S3 114.7(8) . . ?
C22 C23 H23 122.7 . . ?
O9 C45 C48 118.6(8) . . ?
O9 C45 C46 123.5(8) . . ?
C46 C45 C48 117.9(8) . . ?
N3 C61 C62 123.1(10) . . ?
N3 C61 H61 118.4 . . ?
C62 C61 H61 118.4 . . ?
C26 C25 H25 119.4 . . ?
N1 C25 C26 121.2(10) . . ?
N1 C25 H25 119.4 . . ?
S2 C15 H15 123.8 . . ?
C14 C15 S2 112.5(7) . . ?
C14 C15 H15 123.8 . . ?
C1 C2 H2 118.9 . . ?
C3 C2 H2 118.9 . . ?
C3 C2 C1 122.2(9) . . ?
C33 C36 H36 119.4 . . ?
C35 C36 C33 121.3(9) . . ?
C35 C36 H36 119.4 . . ?
C33 C32 H32 120.2 . . ?
C31 C32 C33 119.7(9) . . ?
C31 C32 H32 120.2 . . ?
C02D C4 S1 111.7(7) . . ?
C02D C4 C1 129.9(8) . . ?
C1 C4 S1 118.1(7) . . ?
O12 C55 C60 114.0(8) . . ?
O12 C55 C54 128.7(8) . . ?
C54 C55 C60 117.3(8) . . ?
C37 C40 S4 116.6(6) . . ?
C41 C40 S4 111.7(7) . . ?
C41 C40 C37 131.7(9) . . ?
C33 C34 C29 119.5(8) . . ?
N2 C34 C33 122.6(8) . . ?
N2 C34 C29 118.0(8) . . ?
C69 C70 C65 119.8(8) . . ?
N4 C70 C69 122.0(8) . . ?
N4 C70 C65 118.2(7) . . ?
H5SA C5S H5SB 109.5 . . ?
H5SA C5S H5SC 109.5 . . ?
H5SB C5S H5SC 109.5 . . ?
C4S C5S H5SA 109.5 . . ?
C4S C5S H5SB 109.5 . . ?
C4S C5S H5SC 109.5 . . ?
C4 C02D H02D 124.0 . . ?
C4 C02D C6 112.0(9) . . ?
C6 C02D H02D 124.0 . . ?
O1 C1 C2 123.2(8) . . ?
O1 C1 C4 117.2(8) . . ?
C2 C1 C4 119.6(8) . . ?
S5 C51 H51 123.5 . . ?
C50 C51 S5 113.1(7) . . ?
C50 C51 H51 123.5 . . ?
C78 C67 H67 119.9 . . ?
C78 C67 C66 120.3(9) . . ?
C66 C67 H67 119.9 . . ?
C36 C35 H35 119.4 . . ?
C36 C35 C28 121.2(9) . . ?
C28 C35 H35 119.4 . . ?
F4 C16 F6 106.9(10) . . ?
F4 C16 C11 114.4(9) . . ?
F5 C16 F4 106.4(10) . . ?
F5 C16 F6 106.1(9) . . ?
F5 C16 C11 113.0(9) . . ?
F6 C16 C11 109.4(10) . . ?
N3 C65 C70 118.0(7) . . ?
N3 C65 C64 123.4(8) . . ?
C64 C65 C70 118.6(8) . . ?
O8 C39 C44 113.3(8) . . ?
O8 C39 C38 130.1(9) . . ?
C38 C39 C44 116.6(9) . . ?
O2 C3 C8 114.1(8) . . ?
O2 C3 C2 128.7(8) . . ?
C2 C3 C8 117.2(8) . . ?
O2S C4S C5S 120.0(11) . . ?
O2S C4S C6S 123.9(12) . . ?
C6S C4S C5S 116.0(10) . . ?
N4 C66 C67 121.0(8) . . ?
N4 C66 H66 119.5 . . ?
C67 C66 H66 119.5 . . ?
C65 C64 C63 116.1(9) . . ?
C65 C64 C71 120.8(9) . . ?
C63 C64 C71 123.1(9) . . ?
C53 C56 S6 118.1(7) . . ?
C57 C56 S6 111.4(7) . . ?
C57 C56 C53 130.4(9) . . ?
S1 C7 H7 123.4 . . ?
C6 C7 S1 113.2(8) . . ?
C6 C7 H7 123.4 . . ?
C02D C6 H6 123.9 . . ?
C7 C6 C02D 112.2(10) . . ?
C7 C6 H6 123.9 . . ?
N2 C30 H30 118.9 . . ?
N2 C30 C31 122.3(8) . . ?
C31 C30 H30 118.9 . . ?
C62 C63 C64 119.0(8) . . ?
C62 C63 H63 120.5 . . ?
C64 C63 H63 120.5 . . ?
O4 C11 C16 113.4(8) . . ?
O4 C11 C10 128.9(9) . . ?
C10 C11 C16 117.7(9) . . ?
S6 C59 H59 123.8 . . ?
C58 C59 S6 112.4(8) . . ?
C58 C59 H59 123.8 . . ?
C26 C27 H27 122.6 . . ?
C26 C27 C28 114.9(9) . . ?
C28 C27 H27 122.6 . . ?
C1S C3S H3SA 109.5 . . ?
C1S C3S H3SB 109.5 . . ?
C1S C3S H3SC 109.5 . . ?
H3SA C3S H3SB 109.5 . . ?
H3SA C3S H3SC 109.5 . . ?
H3SB C3S H3SC 109.5 . . ?
C32 C31 C30 119.6(9) . . ?
C32 C31 H31 120.2 . . ?
C30 C31 H31 120.2 . . ?
C64 C71 H71 120.0 . . ?
C72 C71 C64 120.1(9) . . ?
C72 C71 H71 120.0 . . ?
F15 C52 F13 105.2(10) . . ?
F15 C52 C47 113.9(9) . . ?
F15 C52 F14 105.4(10) . . ?
F13 C52 C47 114.5(9) . . ?
F14 C52 F13 106.1(9) . . ?
F14 C52 C47 111.1(10) . . ?
C1S C2S H2SA 109.5 . . ?
C1S C2S H2SB 109.5 . . ?
C1S C2S H2SC 109.5 . . ?
H2SA C2S H2SB 109.5 . . ?
H2SA C2S H2SC 109.5 . . ?
H2SB C2S H2SC 109.5 . . ?
C47 C46 C45 122.6(9) . . ?
C47 C46 H46 118.7 . . ?
C45 C46 H46 118.7 . . ?
C57 C58 H58 123.7 . . ?
C59 C58 C57 112.7(10) . . ?
C59 C58 H58 123.7 . . ?
C43 C42 H42 123.9 . . ?
C43 C42 C41 112.2(10) . . ?
C41 C42 H42 123.9 . . ?
C40 C41 C42 111.2(10) . . ?
C40 C41 H41 124.4 . . ?
C42 C41 H41 124.4 . . ?
C4S C6S H6SA 109.5 . . ?
C4S C6S H6SB 109.5 . . ?
C4S C6S H6SC 109.5 . . ?
H6SA C6S H6SB 109.5 . . ?
H6SA C6S H6SC 109.5 . . ?
H6SB C6S H6SC 109.5 . . ?
C49 C50 H50 123.3 . . ?
C51 C50 C49 113.4(9) . . ?
C51 C50 H50 123.3 . . ?
C69 C72 H72 119.1 . . ?
C71 C72 C69 121.7(9) . . ?
C71 C72 H72 119.1 . . ?
C12 C13 H13 125.6 . . ?
C14 C13 C12 108.8(8) . . ?
C14 C13 H13 125.6 . . ?
N1 C29 C34 118.5(8) . . ?
N1 C29 C28 122.2(8) . . ?
C28 C29 C34 119.4(8) . . ?
C21 C22 H22 122.3 . . ?
C23 C22 C21 115.5(9) . . ?
C23 C22 H22 122.3 . . ?
C19 C18 C17 120.5(9) . . ?
C19 C18 H18 119.7 . . ?
C17 C18 H18 119.7 . . ?
C9 C10 H10 118.4 . . ?
C11 C10 C9 123.2(9) . . ?
C11 C10 H10 118.4 . . ?
C27 C28 C35 121.1(9) . . ?
C29 C28 C35 119.6(8) . . ?
C29 C28 C27 119.4(9) . . ?
C15 C14 C13 114.0(9) . . ?
C15 C14 H14 123.0 . . ?
C13 C14 H14 123.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O4 C11 C16 157.4(7) . . . . ?
Eu1 O4 C11 C10 -24.5(17) . . . . ?
Eu1 O1 C1 C2 -24.2(14) . . . . ?
Eu1 O1 C1 C4 153.8(6) . . . . ?
Eu1 O2 C3 C8 -168.4(6) . . . . ?
Eu1 O2 C3 C2 12.9(14) . . . . ?
Eu1 O6 C19 C24 -160.0(7) . . . . ?
Eu1 O6 C19 C18 21.1(13) . . . . ?
Eu1 O3 C9 C12 -169.1(6) . . . . ?
Eu1 O3 C9 C10 11.1(15) . . . . ?
Eu1 N2 C34 C33 -174.2(6) . . . . ?
Eu1 N2 C34 C29 4.4(10) . . . . ?
Eu1 N2 C30 C31 173.5(7) . . . . ?
Eu1 N1 C25 C26 -173.2(7) . . . . ?
Eu1 N1 C29 C34 -7.2(10) . . . . ?
Eu1 N1 C29 C28 173.0(6) . . . . ?
Eu2 O11 C53 C54 25.7(13) . . . . ?
Eu2 O11 C53 C56 -153.0(6) . . . . ?
Eu2 O12 C55 C60 167.6(6) . . . . ?
Eu2 O12 C55 C54 -12.6(14) . . . . ?
Eu2 O8 C39 C44 160.5(7) . . . . ?
Eu2 O8 C39 C38 -19.9(13) . . . . ?
Eu2 O10 C47 C52 -158.0(7) . . . . ?
Eu2 O10 C47 C46 24.8(16) . . . . ?
Eu2 O7 C37 C38 23.5(13) . . . . ?
Eu2 O7 C37 C40 -160.1(6) . . . . ?
Eu2 N3 C61 C62 173.0(7) . . . . ?
Eu2 N3 C65 C70 5.8(11) . . . . ?
Eu2 N3 C65 C64 -172.4(7) . . . . ?
Eu2 O9 C45 C48 170.1(5) . . . . ?
Eu2 O9 C45 C46 -8.2(14) . . . . ?
Eu2 N4 C70 C69 174.4(6) . . . . ?
Eu2 N4 C70 C65 -6.0(10) . . . . ?
Eu2 N4 C66 C67 -174.4(7) . . . . ?
S1 C4 C02D C6 1.4(12) . . . . ?
S1 C4 C1 O1 -5.8(12) . . . . ?
S1 C4 C1 C2 172.3(7) . . . . ?
S1 C7 C6 C02D -0.2(14) . . . . ?
S3 C20 C17 O5 11.3(11) . . . . ?
S3 C20 C17 C18 -166.9(7) . . . . ?
S3 C20 C21 C22 0.6(8) . . . . ?
S3 C23 C22 C21 -0.9(12) . . . . ?
S6 C59 C58 C57 0.8(13) . . . . ?
S2 C12 C9 O3 18.7(12) . . . . ?
S2 C12 C9 C10 -161.5(8) . . . . ?
S2 C12 C13 C14 0.6(12) . . . . ?
S2 C15 C14 C13 -0.7(14) . . . . ?
S4 C43 C42 C41 0.8(6) . . . . ?
S4 C40 C41 C42 0.2(3) . . . . ?
S5 C48 C45 O9 -17.6(11) . . . . ?
S5 C48 C45 C46 160.8(7) . . . . ?
S5 C51 C50 C49 0.2(6) . . . . ?
C49 C48 C45 O9 163.2(6) . . . . ?
C49 C48 C45 C46 -18.4(11) . . . . ?
F3 C8 C3 O2 -70.3(11) . . . . ?
F3 C8 C3 C2 108.6(10) . . . . ?
F16 C60 C55 O12 70.0(11) . . . . ?
F16 C60 C55 C54 -109.8(10) . . . . ?
O4 C11 C10 C9 4.7(18) . . . . ?
O11 C53 C54 C55 -3.2(14) . . . . ?
O11 C53 C56 S6 5.6(11) . . . . ?
O11 C53 C56 C57 -178.8(9) . . . . ?
F1 C8 C3 O2 47.7(12) . . . . ?
F1 C8 C3 C2 -133.4(9) . . . . ?
F10 C44 C39 O8 179.2(10) . . . . ?
F10 C44 C39 C38 -0.4(15) . . . . ?
O6 C19 C18 C17 8.1(16) . . . . ?
F8 C24 C19 O6 -58.1(11) . . . . ?
F8 C24 C19 C18 121.1(11) . . . . ?
O10 C47 C52 F15 43.2(13) . . . . ?
O10 C47 C52 F13 164.3(10) . . . . ?
O10 C47 C52 F14 -75.6(12) . . . . ?
O10 C47 C46 C45 -5.0(17) . . . . ?
F9 C24 C19 O6 56.7(15) . . . . ?
F9 C24 C19 C18 -124.2(13) . . . . ?
F4 C16 C11 O4 -164.3(10) . . . . ?
F4 C16 C11 C10 17.3(16) . . . . ?
F11 C44 C39 O8 -57.1(16) . . . . ?
F11 C44 C39 C38 123.3(13) . . . . ?
F5 C16 C11 O4 -42.2(14) . . . . ?
F5 C16 C11 C10 139.4(10) . . . . ?
F17 C60 C55 O12 -47.0(11) . . . . ?
F17 C60 C55 C54 133.3(9) . . . . ?
O7 C37 C40 S4 -10.2(10) . . . . ?
O7 C37 C40 C41 170.6(6) . . . . ?
C69 C78 C67 C66 -0.3(14) . . . . ?
C69 C70 C65 N3 179.8(8) . . . . ?
C69 C70 C65 C64 -1.9(13) . . . . ?
C24 C19 C18 C17 -170.9(9) . . . . ?
C26 C27 C28 C35 -178.3(10) . . . . ?
C26 C27 C28 C29 2.9(14) . . . . ?
N3 C65 C64 C63 -1.5(14) . . . . ?
N3 C65 C64 C71 179.2(9) . . . . ?
C38 C37 C40 S4 166.4(7) . . . . ?
C38 C37 C40 C41 -12.8(11) . . . . ?
F7 C24 C19 O6 -175.8(10) . . . . ?
F7 C24 C19 C18 3.3(15) . . . . ?
F12 C44 C39 O8 60.0(11) . . . . ?
F12 C44 C39 C38 -119.6(11) . . . . ?
C12 S2 C15 C14 0.9(10) . . . . ?
C12 C9 C10 C11 -177.6(9) . . . . ?
C12 C13 C14 C15 0.1(15) . . . . ?
C43 S4 C40 C37 -179.1(7) . . . . ?
C43 S4 C40 C41 0.2(2) . . . . ?
C43 C42 C41 C40 -0.6(5) . . . . ?
F6 C16 C11 O4 75.8(12) . . . . ?
F6 C16 C11 C10 -102.6(11) . . . . ?
C53 C54 C55 O12 -2.6(15) . . . . ?
C53 C54 C55 C60 177.1(9) . . . . ?
C20 S3 C23 C22 1.1(9) . . . . ?
C20 C17 O5 Eu1 159.0(6) . . . . ?
C20 C17 C18 C19 169.3(9) . . . . ?
C20 C21 C22 C23 0.2(11) . . . . ?
C48 S5 C51 C50 -0.2(4) . . . . ?
C48 C49 C50 C51 -0.1(5) . . . . ?
C48 C45 C46 C47 178.0(9) . . . . ?
F18 C60 C55 O12 -168.9(9) . . . . ?
F18 C60 C55 C54 11.3(13) . . . . ?
C17 C20 C21 C22 -177.9(9) . . . . ?
C37 C38 C39 O8 -8.4(15) . . . . ?
C37 C38 C39 C44 171.2(9) . . . . ?
C37 C40 C41 C42 179.4(9) . . . . ?
C21 C20 C17 O5 -170.2(8) . . . . ?
C21 C20 C17 C18 11.6(14) . . . . ?
C33 C36 C35 C28 0.3(16) . . . . ?
C33 C32 C31 C30 -0.5(14) . . . . ?
C33 C34 C29 N1 -179.5(8) . . . . ?
C33 C34 C29 C28 0.3(12) . . . . ?
C54 C53 C56 S6 -173.2(7) . . . . ?
C54 C53 C56 C57 2.4(15) . . . . ?
O5 C17 C18 C19 -8.8(15) . . . . ?
O9 C45 C46 C47 -3.7(15) . . . . ?
O3 C9 C10 C11 2.3(16) . . . . ?
N2 C34 C29 N1 1.8(12) . . . . ?
N2 C34 C29 C28 -178.4(8) . . . . ?
N2 C30 C31 C32 0.7(14) . . . . ?
C9 C12 C13 C14 -179.2(10) . . . . ?
F2 C8 C3 O2 169.4(9) . . . . ?
F2 C8 C3 C2 -11.7(14) . . . . ?
N1 C29 C28 C35 -179.4(9) . . . . ?
N1 C29 C28 C27 -0.5(13) . . . . ?
C78 C69 C70 N4 -0.9(13) . . . . ?
C78 C69 C70 C65 179.4(8) . . . . ?
C78 C69 C72 C71 -178.4(10) . . . . ?
C78 C67 C66 N4 1.0(14) . . . . ?
N4 C70 C65 N3 0.1(12) . . . . ?
N4 C70 C65 C64 178.4(8) . . . . ?
C23 S3 C20 C17 177.7(8) . . . . ?
C23 S3 C20 C21 -1.0(7) . . . . ?
C61 N3 C65 C70 -179.4(8) . . . . ?
C61 N3 C65 C64 2.4(13) . . . . ?
C61 C62 C63 C64 0.9(15) . . . . ?
C25 C26 C27 C28 -3.3(16) . . . . ?
C25 N1 C29 C34 178.1(8) . . . . ?
C25 N1 C29 C28 -1.6(13) . . . . ?
C15 S2 C12 C9 179.0(8) . . . . ?
C15 S2 C12 C13 -0.8(9) . . . . ?
C36 C33 C32 C31 -176.9(9) . . . . ?
C36 C33 C34 N2 177.5(8) . . . . ?
C36 C33 C34 C29 -1.1(13) . . . . ?
C36 C35 C28 C27 180.0(10) . . . . ?
C36 C35 C28 C29 -1.2(15) . . . . ?
C32 C33 C36 C35 177.6(10) . . . . ?
C32 C33 C34 N2 0.6(13) . . . . ?
C32 C33 C34 C29 -178.1(8) . . . . ?
C4 S1 C7 C6 0.8(9) . . . . ?
C4 C02D C6 C7 -0.8(15) . . . . ?
C40 S4 C43 C42 -0.6(4) . . . . ?
C34 C33 C36 C35 0.8(15) . . . . ?
C34 C33 C32 C31 -0.1(13) . . . . ?
C34 N2 C30 C31 -0.2(13) . . . . ?
C34 C29 C28 C35 0.9(13) . . . . ?
C34 C29 C28 C27 179.7(8) . . . . ?
C70 C69 C78 C67 0.2(14) . . . . ?
C70 C69 C72 C71 -1.0(15) . . . . ?
C70 N4 C66 C67 -1.7(13) . . . . ?
C70 C65 C64 C63 -179.6(8) . . . . ?
C70 C65 C64 C71 1.0(14) . . . . ?
C02D C4 C1 O1 -179.2(10) . . . . ?
C02D C4 C1 C2 -1.1(16) . . . . ?
C1 C2 C3 O2 2.6(16) . . . . ?
C1 C2 C3 C8 -176.2(9) . . . . ?
C1 C4 C02D C6 175.1(10) . . . . ?
C51 S5 C48 C49 0.1(2) . . . . ?
C51 S5 C48 C45 -179.3(7) . . . . ?
C16 C11 C10 C9 -177.2(10) . . . . ?
C65 N3 C61 C62 -1.7(14) . . . . ?
C65 C64 C63 C62 -0.2(14) . . . . ?
C65 C64 C71 C72 -0.1(15) . . . . ?
C39 C38 C37 O7 8.1(14) . . . . ?
C39 C38 C37 C40 -168.3(8) . . . . ?
C3 C2 C1 O1 2.3(15) . . . . ?
C3 C2 C1 C4 -175.6(9) . . . . ?
C66 N4 C70 C69 1.7(13) . . . . ?
C66 N4 C70 C65 -178.7(8) . . . . ?
C64 C71 C72 C69 0.1(16) . . . . ?
C56 S6 C59 C58 -0.7(9) . . . . ?
C56 C53 C54 C55 175.5(8) . . . . ?
C56 C57 C58 C59 -0.4(14) . . . . ?
C7 S1 C4 C02D -1.3(8) . . . . ?
C7 S1 C4 C1 -175.8(8) . . . . ?
C30 N2 C34 C33 -0.4(13) . . . . ?
C30 N2 C34 C29 178.2(8) . . . . ?
C63 C62 C61 N3 0.1(16) . . . . ?
C63 C64 C71 C72 -179.4(10) . . . . ?
C59 S6 C56 C53 176.9(8) . . . . ?
C59 S6 C56 C57 0.5(8) . . . . ?
C27 C26 C25 N1 1.3(17) . . . . ?
C71 C64 C63 C62 179.2(10) . . . . ?
C52 C47 C46 C45 178.0(9) . . . . ?
C46 C47 C52 F15 -139.2(10) . . . . ?
C46 C47 C52 F13 -18.2(15) . . . . ?
C46 C47 C52 F14 102.0(11) . . . . ?
C58 C57 C56 S6 -0.1(11) . . . . ?
C58 C57 C56 C53 -176.0(9) . . . . ?
C50 C49 C48 S5 0.0(3) . . . . ?
C50 C49 C48 C45 179.2(9) . . . . ?
C72 C69 C78 C67 177.6(9) . . . . ?
C72 C69 C70 N4 -178.4(8) . . . . ?
C72 C69 C70 C65 1.9(13) . . . . ?
C13 C12 C9 O3 -161.6(11) . . . . ?
C13 C12 C9 C10 18.3(16) . . . . ?
C29 N1 C25 C26 1.4(14) . . . . ?
C18 C17 O5 Eu1 -22.9(14) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.982(12)
2 0.018(12)

_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_thio
_database_code_depnum_ccdc_archive 'CCDC 2088576'
loop_
_audit_author_name
_audit_author_address
'Konstantin Lyssenko'
;Chemical Department MSU
Russia
;
_audit_update_record             
;
2021-06-07 deposited with the CCDC.	2021-10-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C45 H20 Eu F27 N2 O6 S3'
_chemical_formula_weight         1445.77

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.2499(8)
_cell_length_b                   15.6839(8)
_cell_length_c                   22.6048(11)
_cell_angle_alpha                78.9390(10)
_cell_angle_beta                 89.6640(10)
_cell_angle_gamma                79.5320(10)
_cell_volume                     5215.5(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9982
_cell_measurement_theta_min      2.252
_cell_measurement_theta_max      27.42

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.841
_exptl_crystal_F_000             2824
_exptl_transmission_factor_min   0.545
_exptl_transmission_factor_max   0.788
_exptl_crystal_size_max          0.395
_exptl_crystal_size_mid          0.274
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    1.469
_shelx_estimated_absorpt_T_min   0.595
_shelx_estimated_absorpt_T_max   0.758
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.495
_exptl_absorpt_correction_T_max  0.658
_exptl_absorpt_process_details   
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_measurement_device_type  'Bruker D8 Quest with Photon III detector'
_diffrn_measurement_method       'φ and ω shutterless scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            66431
_diffrn_reflns_av_unetI/netI     0.0450
_diffrn_reflns_av_R_equivalents  0.0381
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_theta_min         1.346
_diffrn_reflns_theta_max         26.999
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             22729
_reflns_number_gt                16695
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'APEX3 (Bruker, 2019)'
_computing_cell_refinement       'SAINT (Bruker, 2019)'
_computing_data_reduction        'SAINT (Bruker, 2019)'
_computing_structure_solution    
'SHELXT, SHELXS-2013 (Sheldrick, Acta Cryst., 2015, A71, 3-8)'
_computing_structure_refinement  
'SHELXL-2018 (Sheldrick, Acta Cryst., 2015, C71, 3-8)'
_computing_molecular_graphics    
'SHELXTL (Sheldrick, Acta Cryst., 2008, A64, 112-122)'
_computing_publication_material  
'SHELXTL (Sheldrick, Acta Cryst., 2008, A64, 112-122)'

_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0813P)²+49.6280P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         22729
_refine_ls_number_parameters     1594
_refine_ls_number_restraints     1199
_refine_ls_R_factor_all          0.0999
_refine_ls_R_factor_gt           0.0745
_refine_ls_wR_factor_ref         0.2021
_refine_ls_wR_factor_gt          0.1831
_refine_ls_goodness_of_fit_ref   0.997
_refine_ls_restrained_S_all      1.001
_refine_ls_shift/su_max          0.026
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.65559(2) 0.19027(2) 0.64559(2) 0.03780(11) Uani 1 1 d . U . . .
N1A N 0.6259(4) 0.1404(5) 0.5471(3) 0.0458(16) Uani 1 1 d . U . . .
N2A N 0.6262(4) 0.3131(5) 0.5501(3) 0.0489(16) Uani 1 1 d . U . . .
O1A O 0.6828(4) 0.1454(3) 0.7512(3) 0.0434(12) Uani 1 1 d . U . . .
O2A O 0.6422(4) 0.3169(3) 0.6895(3) 0.0530(15) Uani 1 1 d . U . . .
O3A O 0.7698(3) 0.0662(3) 0.6463(3) 0.0401(12) Uani 1 1 d . U . . .
O4A O 0.7896(3) 0.2392(3) 0.6162(3) 0.0427(12) Uani 1 1 d . U . . .
O5A O 0.5863(3) 0.0671(3) 0.6779(3) 0.0447(13) Uani 1 1 d . U . . .
O6A O 0.4989(3) 0.2381(3) 0.6351(3) 0.0475(13) Uani 1 1 d . U . . .
S1 S 0.69470(16) 0.00516(15) 0.85575(11) 0.0566(5) Uani 1 1 d . U . . .
S2 S 0.82967(14) -0.12246(14) 0.67185(14) 0.0611(7) Uani 1 1 d . U . . .
S3 S 0.60025(14) -0.11668(14) 0.72925(12) 0.0540(5) Uani 1 1 d . U . . .
C1A C 0.6684(5) 0.1782(5) 0.7980(4) 0.0432(17) Uani 1 1 d . U . . .
C2A C 0.6454(6) 0.2703(5) 0.7960(4) 0.051(2) Uani 1 1 d . U . . .
H2AA H 0.636468 0.291103 0.832734 0.061 Uiso 1 1 calc R U . . .
C3A C 0.6356(5) 0.3307(5) 0.7423(4) 0.0474(19) Uani 1 1 d . U . . .
C4A C 0.6729(5) 0.1165(5) 0.8560(4) 0.0461(18) Uani 1 1 d . U . . .
C5A C 0.6545(5) 0.1331(5) 0.9145(4) 0.0407(17) Uani 1 1 d . U . . .
H5AA H 0.641110 0.190185 0.924371 0.049 Uiso 1 1 calc R U . . .
C6A C 0.6589(6) 0.0531(7) 0.9561(4) 0.060(2) Uani 1 1 d . U . . .
H6AA H 0.648664 0.050142 0.997845 0.072 Uiso 1 1 calc R U . . .
C7A C 0.6795(6) -0.0199(7) 0.9304(5) 0.060(2) Uani 1 1 d . U . . .
H7AA H 0.684603 -0.078696 0.952493 0.072 Uiso 1 1 calc R U . . .
C8A C 0.6165(5) 0.4307(5) 0.7457(3) 0.068(3) Uani 1 1 d D U . . .
C9A C 0.7052(4) 0.4643(5) 0.7489(3) 0.062(2) Uani 1 1 d D U . . .
C10A C 0.6945(7) 0.5625(5) 0.7523(5) 0.079(3) Uani 1 1 d D U . . .
C11A C 0.7817(6) 0.5975(6) 0.7560(5) 0.109(5) Uani 1 1 d D U . . .
C12A C 0.8508(5) 0.0486(4) 0.6344(3) 0.0328(14) Uani 1 1 d . U . . .
C13A C 0.9023(5) 0.1146(5) 0.6123(3) 0.0357(15) Uani 1 1 d . U . . .
H13A H 0.962699 0.096812 0.602476 0.043 Uiso 1 1 calc R U . . .
C14A C 0.8675(5) 0.2025(5) 0.6048(3) 0.0412(17) Uani 1 1 d . U . . .
C15A C 0.8930(5) -0.0445(5) 0.6451(3) 0.0367(15) Uani 1 1 d . U . . .
C16A C 0.9808(5) -0.0820(5) 0.6394(4) 0.048(2) Uani 1 1 d . U . . .
H16A H 1.026721 -0.049740 0.626242 0.058 Uiso 1 1 calc R U . . .
C17A C 0.9934(6) -0.1768(6) 0.6563(5) 0.061(3) Uani 1 1 d . U . . .
H17A H 1.049145 -0.214976 0.655170 0.073 Uiso 1 1 calc R U . . .
C18A C 0.9178(6) -0.2053(6) 0.6737(5) 0.066(3) Uani 1 1 d . U . . .
H18A H 0.914267 -0.265960 0.685762 0.079 Uiso 1 1 calc R U . . .
C19A C 0.9270(6) 0.2698(5) 0.5805(4) 0.0460(18) Uani 1 1 d . U . . .
C20A C 0.9093(8) 0.3062(7) 0.5110(4) 0.062(3) Uani 1 1 d . U . . .
C21A C 0.9352(10) 0.3940(7) 0.4855(5) 0.076(3) Uani 1 1 d . U . . .
C22A C 0.9255(5) 0.4241(5) 0.4150(4) 0.093(4) Uani 1 1 d D U . . .
C23A C 0.5094(5) 0.0502(5) 0.6847(3) 0.0391(16) Uani 1 1 d . U . . .
C24A C 0.4312(6) 0.1129(6) 0.6663(5) 0.067(3) Uani 1 1 d . U . . .
H24A H 0.375155 0.094447 0.670861 0.080 Uiso 1 1 calc R U . . .
C25A C 0.4332(6) 0.1993(7) 0.6422(5) 0.064(3) Uani 1 1 d . U . . .
C26A C 0.5027(5) -0.0415(5) 0.7106(3) 0.0371(15) Uani 1 1 d . U . . .
C27A C 0.4263(5) -0.0796(5) 0.7243(3) 0.0391(16) Uani 1 1 d . U . . .
H27A H 0.366167 -0.049384 0.718157 0.047 Uiso 1 1 calc R U . . .
C28A C 0.4547(6) -0.1719(6) 0.7491(4) 0.0484(19) Uani 1 1 d . U . . .
H28A H 0.414029 -0.210703 0.761507 0.058 Uiso 1 1 calc R U . . .
C29A C 0.5440(6) -0.1989(6) 0.7533(4) 0.051(2) Uani 1 1 d . U . . .
H29A H 0.572170 -0.258305 0.768376 0.061 Uiso 1 1 calc R U . . .
C34A C 0.6003(5) 0.2035(7) 0.4957(4) 0.052(2) Uani 1 1 d . U . . .
C35A C 0.6265(6) 0.0576(7) 0.5443(5) 0.057(2) Uani 1 1 d . U . . .
H35A H 0.644446 0.013767 0.579439 0.068 Uiso 1 1 calc R U . . .
C36A C 0.6019(7) 0.0304(8) 0.4920(6) 0.074(3) Uani 1 1 d . U . . .
H36A H 0.603692 -0.030444 0.491774 0.089 Uiso 1 1 calc R U . . .
C37A C 0.5755(7) 0.0926(10) 0.4418(5) 0.080(4) Uani 1 1 d . U . . .
H37A H 0.557705 0.075128 0.406443 0.096 Uiso 1 1 calc R U . . .
C38A C 0.5741(6) 0.1802(9) 0.4414(5) 0.068(3) Uani 1 1 d . U . . .
C39A C 0.5499(8) 0.2523(8) 0.3892(6) 0.078(3) Uani 1 1 d . U . . .
H39A H 0.529807 0.239233 0.352791 0.094 Uiso 1 1 calc R U . . .
C40A C 0.5549(9) 0.3332(9) 0.3910(6) 0.085(3) Uani 1 1 d . U . . .
H40A H 0.539478 0.377238 0.355639 0.102 Uiso 1 1 calc R U . . .
C41A C 0.5827(7) 0.3591(9) 0.4442(5) 0.076(3) Uani 1 1 d . U . . .
C42A C 0.5911(8) 0.4444(9) 0.4476(7) 0.088(4) Uani 1 1 d . U . . .
H42A H 0.580138 0.489874 0.412698 0.106 Uiso 1 1 calc R U . . .
C43A C 0.6142(9) 0.4628(8) 0.4990(7) 0.092(4) Uani 1 1 d . U . . .
H43A H 0.619155 0.521561 0.501220 0.110 Uiso 1 1 calc R U . . .
C44A C 0.6315(7) 0.3955(6) 0.5506(5) 0.066(3) Uani 1 1 d . U . . .
H44A H 0.647680 0.410323 0.587354 0.079 Uiso 1 1 calc R U . . .
C45A C 0.6032(5) 0.2927(6) 0.4976(4) 0.053(2) Uani 1 1 d . U . . .
F1A' F 0.5765(7) 0.4420(6) 0.7977(4) 0.084(3) Uani 0.782(9) 1 d D U P A 1
F2A' F 0.5587(7) 0.4753(7) 0.7016(5) 0.089(3) Uani 0.782(9) 1 d D U P A 1
F3A' F 0.7565(6) 0.4188(5) 0.7967(4) 0.075(2) Uani 0.782(9) 1 d D U P A 1
F4A' F 0.7532(6) 0.4517(6) 0.7002(4) 0.075(2) Uani 0.782(9) 1 d D U P A 1
F1A F 0.5427(12) 0.445(2) 0.7774(11) 0.058(8) Uani 0.218(9) 1 d D U P A 2
F2A F 0.5901(16) 0.4743(15) 0.6894(6) 0.034(5) Uani 0.218(9) 1 d D U P A 2
F3A F 0.699(2) 0.4502(19) 0.8093(4) 0.075(2) Uani 0.218(9) 1 d D U P A 2
F4A F 0.7844(11) 0.4191(17) 0.7368(15) 0.075(2) Uani 0.218(9) 1 d D U P A 2
F5A F 0.6502(6) 0.6111(5) 0.7037(4) 0.114(3) Uani 1 1 d . U . . .
F6A F 0.6486(6) 0.5777(6) 0.7990(4) 0.120(3) Uani 1 1 d . U . . .
F7A F 0.8319(7) 0.5530(7) 0.8044(5) 0.133(3) Uani 1 1 d D U . . .
F8A F 0.7615(6) 0.6829(5) 0.7590(5) 0.128(3) Uani 1 1 d D U . . .
F9A F 0.8355(7) 0.5837(7) 0.7107(5) 0.130(3) Uani 1 1 d D U . . .
F10A F 1.0144(3) 0.2338(3) 0.5899(3) 0.0632(14) Uani 1 1 d . U . . .
F11A F 0.9105(4) 0.3392(3) 0.6082(2) 0.0535(12) Uani 1 1 d . U . . .
F13A F 0.9513(5) 0.2427(4) 0.4822(3) 0.0807(19) Uani 1 1 d . U . . .
F12A F 0.8184(5) 0.3145(5) 0.4959(3) 0.0821(18) Uani 1 1 d . U . . .
F15F F 0.8777(6) 0.4572(4) 0.5057(3) 0.100(2) Uani 1 1 d . U . . .
F14A F 1.0176(4) 0.3903(4) 0.5074(3) 0.0749(17) Uani 1 1 d . U . . .
F15' F 0.9417(6) 0.5067(4) 0.4028(4) 0.104(3) Uani 0.799(8) 1 d D U P B 1
F16' F 0.9884(5) 0.3691(5) 0.3918(4) 0.095(3) Uani 0.799(8) 1 d D U P B 1
F17' F 0.8439(5) 0.4212(6) 0.3940(4) 0.100(3) Uani 0.799(8) 1 d D U P B 1
F15A F 0.8488(12) 0.4807(16) 0.4170(15) 0.104(3) Uani 0.201(8) 1 d D U P B 2
F16A F 0.9925(15) 0.4665(18) 0.3961(14) 0.095(3) Uani 0.201(8) 1 d D U P B 2
F17A F 0.917(2) 0.3627(15) 0.3831(13) 0.100(3) Uani 0.201(8) 1 d D U P B 2
Eu2 Eu 0.77979(2) 0.16037(2) 0.15638(2) 0.03601(11) Uani 1 1 d . U . . .
S4 S 0.80397(15) -0.00650(15) 0.37068(11) 0.0526(5) Uani 1 1 d . U . . .
S5 S 0.94970(14) -0.14903(14) 0.23472(11) 0.0517(5) Uani 1 1 d . U . . .
O1B O 0.7661(3) 0.1241(3) 0.2622(2) 0.0381(11) Uani 1 1 d . U . . .
O2B O 0.7383(4) 0.2924(3) 0.1936(2) 0.0418(12) Uani 1 1 d . U . . .
O3B O 0.8939(3) 0.0376(3) 0.1916(2) 0.0389(11) Uani 1 1 d . U . . .
O4B O 0.9169(3) 0.2096(3) 0.1577(2) 0.0403(11) Uani 1 1 d . U . . .
O5B O 0.7085(3) 0.0381(4) 0.1623(3) 0.0467(13) Uani 1 1 d . U . . .
O6B O 0.6315(4) 0.2107(4) 0.1177(3) 0.0531(14) Uani 1 1 d . U . . .
N1B N 0.8310(4) 0.0946(4) 0.0628(3) 0.0435(15) Uani 1 1 d . U . . .
N2B N 0.7859(5) 0.2721(5) 0.0573(3) 0.0481(16) Uani 1 1 d . U . . .
C1B C 0.7702(5) 0.1616(5) 0.3065(3) 0.0351(15) Uani 1 1 d . U . . .
C2B C 0.7589(5) 0.2540(5) 0.3004(3) 0.0419(17) Uani 1 1 d . U . . .
H2BA H 0.761780 0.278170 0.335688 0.050 Uiso 1 1 calc R U . . .
C3B C 0.7435(5) 0.3114(5) 0.2447(4) 0.0405(16) Uani 1 1 d . U . . .
C4B C 0.7883(5) 0.1054(5) 0.3652(3) 0.0398(16) Uani 1 1 d . U . . .
C5B C 0.8042(4) 0.1262(5) 0.4240(3) 0.0349(15) Uani 1 1 d . U . . .
H5BA H 0.798884 0.184257 0.431855 0.042 Uiso 1 1 calc R U . . .
C6B C 0.8285(6) 0.0486(7) 0.4670(4) 0.058(2) Uani 1 1 d . U . . .
H6BA H 0.841930 0.048577 0.507927 0.069 Uiso 1 1 calc R U . . .
C7B C 0.8312(6) -0.0268(7) 0.4455(4) 0.062(3) Uani 1 1 d . U . . .
H7BA H 0.846569 -0.084355 0.469546 0.075 Uiso 1 1 calc R U . . .
C12B C 0.9777(5) 0.0197(5) 0.2006(3) 0.0360(15) Uani 1 1 d . U . . .
C13B C 1.0320(5) 0.0855(5) 0.1877(3) 0.0389(16) Uani 1 1 d . U . . .
H13B H 1.094804 0.068100 0.193885 0.047 Uiso 1 1 calc R U . . .
C14B C 0.9969(5) 0.1735(5) 0.1665(3) 0.0389(16) Uani 1 1 d . U . . .
C15B C 1.0180(5) -0.0718(5) 0.2227(3) 0.0358(15) Uani 1 1 d . U . . .
C16B C 1.1082(5) -0.1104(5) 0.2350(3) 0.0360(15) Uani 1 1 d . U . . .
H16B H 1.156330 -0.079113 0.231486 0.043 Uiso 1 1 calc R U . . .
C17B C 1.1165(5) -0.2041(5) 0.2538(3) 0.0443(18) Uani 1 1 d . U . . .
H17B H 1.172046 -0.242715 0.264312 0.053 Uiso 1 1 calc R U . . .
C18B C 1.0378(6) -0.2323(6) 0.2551(4) 0.052(2) Uani 1 1 d . U . . .
H18B H 1.032502 -0.292665 0.266225 0.062 Uiso 1 1 calc R U . . .
C23B C 0.6355(5) 0.0211(6) 0.1474(5) 0.058(3) Uani 1 1 d . U . . .
C24B C 0.5623(6) 0.0858(7) 0.1204(5) 0.068(3) Uani 1 1 d . U . . .
H24B H 0.509693 0.067511 0.109321 0.082 Uiso 1 1 calc R U . . .
C25B C 0.5655(6) 0.1737(7) 0.1101(5) 0.060(2) Uani 1 1 d . U . . .
S6' S 0.7082(13) -0.1384(10) 0.1908(11) 0.075(3) Uani 0.5 1 d . U P C 2
C26' C 0.6261(10) -0.0612(10) 0.1497(7) 0.036(2) Uani 0.5 1 d . U P C 2
C27' C 0.5541(12) -0.1022(11) 0.1388(8) 0.048(3) Uani 0.5 1 d . U P C 2
H27B H 0.498376 -0.070391 0.121189 0.058 Uiso 0.5 1 calc R U P C 2
C28' C 0.5728(14) -0.1925(14) 0.1562(10) 0.066(4) Uani 0.5 1 d . U P C 2
H28B H 0.533049 -0.229493 0.148516 0.079 Uiso 0.5 1 calc R U P C 2
C29' C 0.6521(13) -0.2241(14) 0.1849(10) 0.061(3) Uani 0.5 1 d . U P C 2
H29B H 0.674701 -0.284881 0.200045 0.073 Uiso 0.5 1 calc R U P C 2
S6 S 0.7163(13) -0.1574(10) 0.2098(11) 0.075(3) Uani 0.5 1 d . U P C 1
C26B C 0.6234(10) -0.0787(10) 0.1773(7) 0.036(2) Uani 0.5 1 d . U P C 1
C27B C 0.5477(12) -0.1175(11) 0.1778(8) 0.048(3) Uani 0.5 1 d . U P C 1
H27C H 0.490107 -0.086836 0.162976 0.058 Uiso 0.5 1 calc R U P C 1
C28B C 0.5684(14) -0.2067(14) 0.2027(10) 0.066(4) Uani 0.5 1 d . U P C 1
H28C H 0.525667 -0.244306 0.204547 0.079 Uiso 0.5 1 calc R U P C 1
C29B C 0.6526(13) -0.2370(14) 0.2242(10) 0.061(3) Uani 0.5 1 d . U P C 1
H29C H 0.673924 -0.295762 0.244886 0.073 Uiso 0.5 1 calc R U P C 1
C34B C 0.8445(5) 0.1497(6) 0.0098(3) 0.0436(17) Uani 1 1 d . U . . .
C35B C 0.8502(5) 0.0075(6) 0.0651(4) 0.0480(19) Uani 1 1 d . U . . .
H35B H 0.841355 -0.031180 0.101598 0.058 Uiso 1 1 calc R U . . .
C36B C 0.8828(5) -0.0288(6) 0.0157(4) 0.053(2) Uani 1 1 d . U . . .
H36B H 0.894652 -0.091159 0.018809 0.064 Uiso 1 1 calc R U . . .
C37B C 0.8976(6) 0.0244(7) -0.0363(4) 0.056(2) Uani 1 1 d . U . . .
H37B H 0.920144 -0.000322 -0.069751 0.067 Uiso 1 1 calc R U . . .
C38B C 0.8794(5) 0.1166(7) -0.0408(4) 0.052(2) Uani 1 1 d . U . . .
C39B C 0.8942(7) 0.1784(7) -0.0934(4) 0.061(2) Uani 1 1 d . U . . .
H39B H 0.920463 0.157254 -0.127267 0.073 Uiso 1 1 calc R U . . .
C40B C 0.8718(7) 0.2657(8) -0.0960(4) 0.066(3) Uani 1 1 d . U . . .
H40B H 0.881185 0.304989 -0.132014 0.080 Uiso 1 1 calc R U . . .
C41B C 0.8342(7) 0.3009(7) -0.0462(4) 0.059(2) Uani 1 1 d . U . . .
C42B C 0.8089(8) 0.3917(7) -0.0471(4) 0.069(3) Uani 1 1 d . U . . .
H42B H 0.816575 0.433014 -0.082609 0.082 Uiso 1 1 calc R U . . .
C43B C 0.7731(9) 0.4216(7) 0.0027(5) 0.077(3) Uani 1 1 d . U . . .
H43B H 0.756103 0.483019 0.002596 0.093 Uiso 1 1 calc R U . . .
C44B C 0.7626(7) 0.3575(6) 0.0543(4) 0.058(2) Uani 1 1 d . U . . .
H44B H 0.737233 0.377559 0.088758 0.069 Uiso 1 1 calc R U . . .
C45B C 0.8213(5) 0.2425(5) 0.0076(3) 0.0444(18) Uani 1 1 d . U . . .
F1B F 0.6747(4) 0.4568(4) 0.2028(3) 0.0763(17) Uani 1 1 d . U . . .
F2B F 0.7182(5) 0.4299(4) 0.2983(3) 0.0817(19) Uani 1 1 d . U . . .
F3B F 0.8926(4) 0.3949(3) 0.2651(3) 0.0670(15) Uani 1 1 d . U . . .
F4B F 0.8516(4) 0.4180(4) 0.1716(3) 0.0733(16) Uani 1 1 d . U . . .
F5B F 0.7974(7) 0.5653(5) 0.2676(4) 0.123(3) Uani 1 1 d . U . . .
F6B F 0.7802(6) 0.5835(5) 0.1710(4) 0.114(3) Uani 1 1 d . U . . .
F9B F 0.9670(6) 0.5299(5) 0.1675(4) 0.112(3) Uani 1 1 d . U . . .
F8B F 0.9725(7) 0.5365(5) 0.2598(4) 0.120(3) Uani 1 1 d . U . . .
F7B F 0.9138(8) 0.6509(5) 0.1959(4) 0.134(3) Uani 1 1 d . U . . .
C8B C 0.7391(7) 0.4102(6) 0.2438(4) 0.057(2) Uani 1 1 d . U . . .
C9B C 0.8293(7) 0.4402(6) 0.2252(4) 0.055(2) Uani 1 1 d . U . . .
C10B C 0.8328(10) 0.5373(7) 0.2197(6) 0.085(4) Uani 1 1 d . U . . .
F10B F 1.1483(4) 0.1975(4) 0.1616(3) 0.085(2) Uani 1 1 d . U . . .
F11B F 1.0440(4) 0.3040(4) 0.1776(3) 0.0753(17) Uani 1 1 d . U . . .
F12B F 0.9792(4) 0.3386(5) 0.0688(3) 0.088(2) Uani 1 1 d . U . . .
F13B F 1.0351(5) 0.2065(4) 0.0469(2) 0.0715(17) Uani 1 1 d . U . . .
F14B F 1.1957(7) 0.2385(6) 0.0451(5) 0.135(3) Uani 1 1 d . U . . .
F15B F 1.1502(7) 0.3633(5) 0.0833(4) 0.120(3) Uani 1 1 d . U . . .
F16B F 1.0548(8) 0.4330(8) -0.0195(5) 0.153(4) Uani 1 1 d . U . . .
F17B F 1.0797(8) 0.3134(7) -0.0499(5) 0.146(3) Uani 1 1 d . U . . .
F18B F 1.1849(8) 0.3824(7) -0.0405(5) 0.143(4) Uani 1 1 d . U . . .
C19B C 1.0621(6) 0.2371(6) 0.1481(5) 0.058(2) Uani 1 1 d . U . . .
C20B C 1.0540(8) 0.2718(7) 0.0753(6) 0.080(3) Uani 1 1 d . U . . .
C21B C 1.1314(10) 0.3094(9) 0.0468(7) 0.093(4) Uani 1 1 d . U . . .
C22B C 1.1208(13) 0.3614(13) -0.0160(8) 0.114(4) Uani 1 1 d . U . . .
C30A C 0.3444(7) 0.2556(8) 0.6107(5) 0.091(4) Uani 1 1 d D U . . .
C31A C 0.3384(6) 0.2614(6) 0.5428(5) 0.072(3) Uani 1 1 d D U . . .
C32A C 0.2501(7) 0.3067(10) 0.5109(6) 0.102(4) Uani 1 1 d D U . . .
C33A C 0.2487(16) 0.3350(16) 0.4427(6) 0.147(4) Uani 1 1 d D U . . .
C31B C 0.4627(9) 0.2930(8) 0.0224(4) 0.081(5) Uani 0.575(5) 1 d D U P D 1
C32B C 0.5277(7) 0.3518(8) -0.0047(5) 0.116(8) Uani 0.575(5) 1 d D U P D 1
F23B F 0.5496(10) 0.3975(9) 0.0357(6) 0.112(4) Uani 0.575(5) 1 d D U P D 1
F24B F 0.6049(8) 0.2989(8) -0.0121(5) 0.085(3) Uani 0.575(5) 1 d D U P D 1
C33B C 0.5009(9) 0.4168(8) -0.0636(5) 0.116(8) Uani 0.575(5) 1 d D U P D 1
F21B F 0.3848(10) 0.3491(11) 0.0089(8) 0.114(4) Uani 0.575(5) 1 d D U P D 1
F22B F 0.4650(11) 0.2285(10) -0.0091(7) 0.101(4) Uani 0.575(5) 1 d D U P D 1
F25B F 0.4324(10) 0.4826(11) -0.0605(9) 0.157(5) Uani 0.575(5) 1 d D U P D 1
F26B F 0.5710(9) 0.4525(11) -0.0850(8) 0.140(5) Uani 0.575(5) 1 d D U P D 1
F27B F 0.4763(10) 0.3686(9) -0.1014(7) 0.113(4) Uani 0.575(5) 1 d D U P D 1
C30B C 0.4781(7) 0.2413(7) 0.0868(4) 0.066(3) Uani 1 1 d D U . . .
F19B F 0.4046(4) 0.2036(4) 0.1004(3) 0.0797(17) Uani 1 1 d . U . . .
F20B F 0.4689(4) 0.3087(4) 0.1155(3) 0.0732(16) Uani 1 1 d . U . . .
F19A F 0.3413(5) 0.3394(5) 0.6230(4) 0.094(2) Uani 1 1 d . U . . .
F21A F 0.3980(4) 0.3150(5) 0.5168(3) 0.0852(19) Uani 1 1 d . U . . .
F20A F 0.3727(5) 0.1832(4) 0.5293(3) 0.095(2) Uani 1 1 d . U . . .
F18A F 0.2730(5) 0.2201(5) 0.6345(4) 0.109(2) Uani 1 1 d . U . . .
F22A F 0.2145(7) 0.3683(7) 0.5401(5) 0.131(3) Uani 1 1 d . U . . .
F23A F 0.1968(8) 0.2417(8) 0.5221(6) 0.162(4) Uani 1 1 d . U . . .
F26A F 0.1670(8) 0.3579(8) 0.4190(5) 0.158(4) Uani 1 1 d . U . . .
F25A F 0.2971(8) 0.2646(8) 0.4199(6) 0.160(4) Uani 1 1 d . U . . .
C11B C 0.9219(10) 0.5646(9) 0.2097(7) 0.086(3) Uani 1 1 d . U . . .
F24A F 0.2859(9) 0.3997(9) 0.4283(6) 0.181(4) Uani 1 1 d . U . . .
F21X F 0.4770(15) 0.1790(13) 0.0002(10) 0.114(4) Uani 0.425(5) 1 d D U P D 2
F22X F 0.5571(13) 0.2830(14) 0.0046(10) 0.101(4) Uani 0.425(5) 1 d D U P D 2
C31X C 0.4805(12) 0.2546(11) 0.0185(4) 0.081(5) Uani 0.425(5) 1 d D U P D 2
C32X C 0.4146(11) 0.3373(12) -0.0094(6) 0.116(8) Uani 0.425(5) 1 d D U P D 2
F23X F 0.4381(14) 0.4113(12) 0.0015(9) 0.112(4) Uani 0.425(5) 1 d D U P D 2
F24X F 0.3421(11) 0.3488(11) 0.0241(6) 0.085(3) Uani 0.425(5) 1 d D U P D 2
C33X C 0.3907(11) 0.3487(11) -0.0759(6) 0.116(8) Uani 0.425(5) 1 d D U P D 2
F25X F 0.3463(14) 0.4315(11) -0.0942(12) 0.157(5) Uani 0.425(5) 1 d D U P D 2
F26X F 0.3388(13) 0.2899(12) -0.0805(11) 0.140(5) Uani 0.425(5) 1 d D U P D 2
F27X F 0.4650(10) 0.3329(13) -0.1070(10) 0.113(4) Uani 0.425(5) 1 d D U P D 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O4A 2.359(5) . ?
Eu1 O5A 2.361(5) . ?
Eu1 O2A 2.361(6) . ?
Eu1 O3A 2.362(5) . ?
Eu1 O6A 2.370(5) . ?
Eu1 O1A 2.372(6) . ?
Eu1 N1A 2.567(7) . ?
Eu1 N2A 2.584(7) . ?
N1A C35A 1.310(11) . ?
N1A C34A 1.380(12) . ?
N2A C44A 1.313(12) . ?
N2A C45A 1.349(12) . ?
O1A C1A 1.264(10) . ?
O2A C3A 1.254(11) . ?
O3A C12A 1.256(8) . ?
O4A C14A 1.271(10) . ?
O5A C23A 1.250(9) . ?
O6A C25A 1.257(10) . ?
S1 C7A 1.683(10) . ?
S1 C4A 1.718(8) . ?
S2 C18A 1.685(9) . ?
S2 C15A 1.712(7) . ?
S3 C29A 1.680(9) . ?
S3 C26A 1.721(7) . ?
C1A C2A 1.414(11) . ?
C1A C4A 1.467(12) . ?
C2A C3A 1.379(13) . ?
C2A H2AA 0.9500 . ?
C3A C8A 1.559(11) . ?
C4A C5A 1.414(12) . ?
C5A C6A 1.407(13) . ?
C5A H5AA 0.9500 . ?
C6A C7A 1.366(14) . ?
C6A H6AA 0.9500 . ?
C7A H7AA 0.9500 . ?
C8A F2A' 1.335(5) . ?
C8A F1A 1.338(5) . ?
C8A F1A' 1.347(5) . ?
C8A F2A 1.350(5) . ?
C8A C9A 1.544(4) . ?
C9A F4A 1.340(5) . ?
C9A F3A' 1.342(5) . ?
C9A F4A' 1.344(5) . ?
C9A F3A 1.346(5) . ?
C9A C10A 1.537(4) . ?
C10A F6A 1.300(13) . ?
C10A F5A 1.321(13) . ?
C10A C11A 1.537(4) . ?
C11A F8A 1.333(5) . ?
C11A F9A 1.334(5) . ?
C11A F7A 1.339(5) . ?
C12A C13A 1.426(9) . ?
C12A C15A 1.459(10) . ?
C13A C14A 1.362(11) . ?
C13A H13A 0.9500 . ?
C14A C19A 1.536(10) . ?
C15A C16A 1.378(10) . ?
C16A C17A 1.440(11) . ?
C16A H16A 0.9500 . ?
C17A C18A 1.341(12) . ?
C17A H17A 0.9500 . ?
C18A H18A 0.9500 . ?
C19A F11A 1.342(10) . ?
C19A F10A 1.350(10) . ?
C19A C20A 1.571(12) . ?
C20A F13A 1.357(11) . ?
C20A F12A 1.406(13) . ?
C20A C21A 1.509(14) . ?
C21A F14A 1.340(14) . ?
C21A F15F 1.346(14) . ?
C21A C22A 1.572(14) . ?
C22A F17A 1.333(5) . ?
C22A F15A 1.341(5) . ?
C22A F15' 1.340(5) . ?
C22A F16A 1.341(5) . ?
C22A F16' 1.343(5) . ?
C22A F17' 1.347(5) . ?
C23A C24A 1.408(11) . ?
C23A C26A 1.467(10) . ?
C24A C25A 1.367(13) . ?
C24A H24A 0.9500 . ?
C25A C30A 1.568(14) . ?
C26A C27A 1.411(10) . ?
C27A C28A 1.435(11) . ?
C27A H27A 0.9500 . ?
C28A C29A 1.349(12) . ?
C28A H28A 0.9500 . ?
C29A H29A 0.9500 . ?
C34A C45A 1.417(13) . ?
C34A C38A 1.425(13) . ?
C35A C36A 1.408(14) . ?
C35A H35A 0.9500 . ?
C36A C37A 1.355(18) . ?
C36A H36A 0.9500 . ?
C37A C38A 1.368(17) . ?
C37A H37A 0.9500 . ?
C38A C39A 1.467(16) . ?
C39A C40A 1.294(16) . ?
C39A H39A 0.9500 . ?
C40A C41A 1.431(17) . ?
C40A H40A 0.9500 . ?
C41A C42A 1.384(18) . ?
C41A C45A 1.429(14) . ?
C42A C43A 1.312(19) . ?
C42A H42A 0.9500 . ?
C43A C44A 1.405(15) . ?
C43A H43A 0.9500 . ?
C44A H44A 0.9500 . ?
Eu2 O5B 2.353(5) . ?
Eu2 O4B 2.358(5) . ?
Eu2 O3B 2.362(5) . ?
Eu2 O2B 2.363(5) . ?
Eu2 O1B 2.367(5) . ?
Eu2 O6B 2.369(6) . ?
Eu2 N2B 2.578(7) . ?
Eu2 N1B 2.584(6) . ?
S4 C7B 1.699(10) . ?
S4 C4B 1.708(8) . ?
S5 C18B 1.692(9) . ?
S5 C15B 1.719(7) . ?
O1B C1B 1.261(8) . ?
O2B C3B 1.254(9) . ?
O3B C12B 1.267(9) . ?
O4B C14B 1.249(9) . ?
O5B C23B 1.252(9) . ?
O6B C25B 1.277(11) . ?
N1B C35B 1.335(10) . ?
N1B C34B 1.374(11) . ?
N2B C44B 1.311(11) . ?
N2B C45B 1.367(10) . ?
C1B C2B 1.409(10) . ?
C1B C4B 1.442(11) . ?
C2B C3B 1.395(11) . ?
C2B H2BA 0.9500 . ?
C3B C8B 1.534(11) . ?
C4B C5B 1.460(10) . ?
C5B C6B 1.397(12) . ?
C5B H5BA 0.9500 . ?
C6B C7B 1.354(14) . ?
C6B H6BA 0.9500 . ?
C7B H7BA 0.9500 . ?
C12B C13B 1.424(10) . ?
C12B C15B 1.447(10) . ?
C13B C14B 1.379(11) . ?
C13B H13B 0.9500 . ?
C14B C19B 1.533(11) . ?
C15B C16B 1.405(10) . ?
C16B C17B 1.431(11) . ?
C16B H16B 0.9500 . ?
C17B C18B 1.350(12) . ?
C17B H17B 0.9500 . ?
C18B H18B 0.9500 . ?
C23B C26' 1.316(17) . ?
C23B C24B 1.417(13) . ?
C23B C26B 1.624(18) . ?
C24B C25B 1.363(14) . ?
C24B H24B 0.9500 . ?
C25B C30B 1.568(13) . ?
S6' C26' 1.710(19) . ?
S6' C29' 1.74(3) . ?
C26' C27' 1.41(2) . ?
C27' C28' 1.37(3) . ?
C27' H27B 0.9500 . ?
C28' C29' 1.34(3) . ?
C28' H28B 0.9500 . ?
C29' H29B 0.9500 . ?
S6 C29B 1.70(3) . ?
S6 C26B 1.76(2) . ?
C26B C27B 1.40(2) . ?
C27B C28B 1.38(3) . ?
C27B H27C 0.9500 . ?
C28B C29B 1.34(3) . ?
C28B H28C 0.9500 . ?
C29B H29C 0.9500 . ?
C34B C38B 1.409(11) . ?
C34B C45B 1.425(11) . ?
C35B C36B 1.397(11) . ?
C35B H35B 0.9500 . ?
C36B C37B 1.349(14) . ?
C36B H36B 0.9500 . ?
C37B C38B 1.406(13) . ?
C37B H37B 0.9500 . ?
C38B C39B 1.428(14) . ?
C39B C40B 1.338(15) . ?
C39B H39B 0.9500 . ?
C40B C41B 1.420(13) . ?
C40B H40B 0.9500 . ?
C41B C42B 1.403(14) . ?
C41B C45B 1.411(12) . ?
C42B C43B 1.376(14) . ?
C42B H42B 0.9500 . ?
C43B C44B 1.414(13) . ?
C43B H43B 0.9500 . ?
C44B H44B 0.9500 . ?
F1B C8B 1.359(11) . ?
F2B C8B 1.350(10) . ?
F3B C9B 1.329(10) . ?
F4B C9B 1.349(10) . ?
F5B C10B 1.322(14) . ?
F6B C10B 1.370(14) . ?
F9B C11B 1.319(15) . ?
F8B C11B 1.329(15) . ?
F7B C11B 1.312(15) . ?
C8B C9B 1.564(14) . ?
C9B C10B 1.514(14) . ?
C10B C11B 1.500(19) . ?
F10B C19B 1.358(10) . ?
F11B C19B 1.334(12) . ?
F12B C20B 1.389(13) . ?
F13B C20B 1.381(13) . ?
F14B C21B 1.349(15) . ?
F15B C21B 1.356(16) . ?
F16B C22B 1.356(19) . ?
F17B C22B 1.395(19) . ?
F18B C22B 1.188(19) . ?
C19B C20B 1.630(16) . ?
C20B C21B 1.501(17) . ?
C21B C22B 1.49(2) . ?
C30A F18A 1.372(12) . ?
C30A F19A 1.387(14) . ?
C30A C31A 1.522(2) . ?
C31A F20A 1.334(11) . ?
C31A F21A 1.401(12) . ?
C31A C32A 1.519(2) . ?
C32A F22A 1.308(16) . ?
C32A C33A 1.519(2) . ?
C32A F23A 1.402(17) . ?
C33A F24A 1.24(2) . ?
C33A F26A 1.32(2) . ?
C33A F25A 1.40(2) . ?
C31B F22B 1.341(2) . ?
C31B F21B 1.342(2) . ?
C31B C32B 1.521(2) . ?
C31B C30B 1.521(2) . ?
C32B F24B 1.341(2) . ?
C32B F23B 1.341(2) . ?
C32B C33B 1.522(2) . ?
C33B F27B 1.340(2) . ?
C33B F25B 1.341(2) . ?
C33B F26B 1.341(2) . ?
C30B F20B 1.329(12) . ?
C30B F19B 1.365(12) . ?
C30B C31X 1.519(2) . ?
F21X C31X 1.340(2) . ?
F22X C31X 1.340(2) . ?
C31X C32X 1.520(2) . ?
C32X F24X 1.340(2) . ?
C32X F23X 1.340(2) . ?
C32X C33X 1.519(2) . ?
C33X F25X 1.339(2) . ?
C33X F27X 1.339(2) . ?
C33X F26X 1.339(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4A Eu1 O5A 146.14(17) . . ?
O4A Eu1 O2A 79.0(2) . . ?
O5A Eu1 O2A 126.3(2) . . ?
O4A Eu1 O3A 70.94(17) . . ?
O5A Eu1 O3A 75.21(17) . . ?
O2A Eu1 O3A 133.77(19) . . ?
O4A Eu1 O6A 140.76(18) . . ?
O5A Eu1 O6A 71.42(18) . . ?
O2A Eu1 O6A 80.8(2) . . ?
O3A Eu1 O6A 142.74(18) . . ?
O4A Eu1 O1A 100.44(19) . . ?
O5A Eu1 O1A 72.78(19) . . ?
O2A Eu1 O1A 70.88(19) . . ?
O3A Eu1 O1A 80.82(18) . . ?
O6A Eu1 O1A 104.2(2) . . ?
O4A Eu1 N1A 96.2(2) . . ?
O5A Eu1 N1A 76.6(2) . . ?
O2A Eu1 N1A 142.4(2) . . ?
O3A Eu1 N1A 76.5(2) . . ?
O6A Eu1 N1A 80.1(2) . . ?
O1A Eu1 N1A 145.6(2) . . ?
O4A Eu1 N2A 70.26(19) . . ?
O5A Eu1 N2A 130.4(2) . . ?
O2A Eu1 N2A 79.8(2) . . ?
O3A Eu1 N2A 119.5(2) . . ?
O6A Eu1 N2A 73.2(2) . . ?
O1A Eu1 N2A 150.5(2) . . ?
N1A Eu1 N2A 63.8(2) . . ?
C35A N1A C34A 117.9(8) . . ?
C35A N1A Eu1 122.7(6) . . ?
C34A N1A Eu1 119.1(5) . . ?
C44A N2A C45A 118.2(8) . . ?
C44A N2A Eu1 122.4(7) . . ?
C45A N2A Eu1 119.3(6) . . ?
C1A O1A Eu1 138.1(5) . . ?
C3A O2A Eu1 134.8(5) . . ?
C12A O3A Eu1 139.6(4) . . ?
C14A O4A Eu1 135.5(5) . . ?
C23A O5A Eu1 138.9(5) . . ?
C25A O6A Eu1 134.2(6) . . ?
C7A S1 C4A 91.8(5) . . ?
C18A S2 C15A 91.8(4) . . ?
C29A S3 C26A 91.7(4) . . ?
O1A C1A C2A 122.8(8) . . ?
O1A C1A C4A 117.2(7) . . ?
C2A C1A C4A 119.9(8) . . ?
C3A C2A C1A 122.0(8) . . ?
C3A C2A H2AA 119.0 . . ?
C1A C2A H2AA 119.0 . . ?
O2A C3A C2A 128.9(8) . . ?
O2A C3A C8A 113.6(7) . . ?
C2A C3A C8A 117.5(8) . . ?
C5A C4A C1A 130.0(7) . . ?
C5A C4A S1 111.5(6) . . ?
C1A C4A S1 118.2(6) . . ?
C6A C5A C4A 110.3(8) . . ?
C6A C5A H5AA 124.8 . . ?
C4A C5A H5AA 124.8 . . ?
C7A C6A C5A 113.4(9) . . ?
C7A C6A H6AA 123.3 . . ?
C5A C6A H6AA 123.3 . . ?
C6A C7A S1 113.0(7) . . ?
C6A C7A H7AA 123.5 . . ?
S1 C7A H7AA 123.5 . . ?
F2A' C8A F1A' 106.0(9) . . ?
F1A C8A F2A 103.3(17) . . ?
F2A' C8A C9A 116.1(8) . . ?
F1A C8A C9A 129.8(14) . . ?
F1A' C8A C9A 104.8(7) . . ?
F2A C8A C9A 97.6(11) . . ?
F2A' C8A C3A 109.7(8) . . ?
F1A C8A C3A 107.4(14) . . ?
F1A' C8A C3A 110.0(7) . . ?
F2A C8A C3A 105.7(12) . . ?
C9A C8A C3A 110.0(6) . . ?
F3A' C9A F4A' 105.7(7) . . ?
F4A C9A F3A 107.3(19) . . ?
F4A C9A C10A 120.3(14) . . ?
F3A' C9A C10A 106.7(7) . . ?
F4A' C9A C10A 107.5(7) . . ?
F3A C9A C10A 85.6(14) . . ?
F4A C9A C8A 123.6(14) . . ?
F3A' C9A C8A 111.8(6) . . ?
F4A' C9A C8A 109.9(6) . . ?
F3A C9A C8A 88.0(13) . . ?
C10A C9A C8A 114.7(6) . . ?
F6A C10A F5A 107.9(9) . . ?
F6A C10A C9A 109.7(8) . . ?
F5A C10A C9A 109.4(8) . . ?
F6A C10A C11A 107.6(9) . . ?
F5A C10A C11A 106.2(8) . . ?
C9A C10A C11A 115.8(7) . . ?
F8A C11A F9A 112.0(10) . . ?
F8A C11A F7A 109.7(9) . . ?
F9A C11A F7A 102.4(9) . . ?
F8A C11A C10A 108.6(7) . . ?
F9A C11A C10A 112.8(9) . . ?
F7A C11A C10A 111.2(9) . . ?
O3A C12A C13A 123.2(6) . . ?
O3A C12A C15A 117.1(6) . . ?
C13A C12A C15A 119.6(6) . . ?
C14A C13A C12A 121.9(7) . . ?
C14A C13A H13A 119.0 . . ?
C12A C13A H13A 119.0 . . ?
O4A C14A C13A 128.4(7) . . ?
O4A C14A C19A 112.6(7) . . ?
C13A C14A C19A 118.9(7) . . ?
C16A C15A C12A 129.3(7) . . ?
C16A C15A S2 111.9(6) . . ?
C12A C15A S2 118.7(5) . . ?
C15A C16A C17A 110.5(7) . . ?
C15A C16A H16A 124.7 . . ?
C17A C16A H16A 124.7 . . ?
C18A C17A C16A 112.6(8) . . ?
C18A C17A H17A 123.7 . . ?
C16A C17A H17A 123.7 . . ?
C17A C18A S2 113.2(7) . . ?
C17A C18A H18A 123.4 . . ?
S2 C18A H18A 123.4 . . ?
F11A C19A F10A 107.6(7) . . ?
F11A C19A C14A 110.5(7) . . ?
F10A C19A C14A 111.5(6) . . ?
F11A C19A C20A 107.4(7) . . ?
F10A C19A C20A 108.5(7) . . ?
C14A C19A C20A 111.3(7) . . ?
F13A C20A F12A 104.4(8) . . ?
F13A C20A C21A 110.6(8) . . ?
F12A C20A C21A 106.7(9) . . ?
F13A C20A C19A 106.9(8) . . ?
F12A C20A C19A 110.4(7) . . ?
C21A C20A C19A 117.1(8) . . ?
F14A C21A F15F 109.7(9) . . ?
F14A C21A C20A 106.5(10) . . ?
F15F C21A C20A 107.8(10) . . ?
F14A C21A C22A 113.6(9) . . ?
F15F C21A C22A 103.3(9) . . ?
C20A C21A C22A 115.8(8) . . ?
F17A C22A F15A 112.1(6) . . ?
F17A C22A F16A 112.3(6) . . ?
F15A C22A F16A 111.7(6) . . ?
F15' C22A F16' 110.7(5) . . ?
F15' C22A F17' 110.9(5) . . ?
F16' C22A F17' 110.5(5) . . ?
F17A C22A C21A 117.3(14) . . ?
F15A C22A C21A 93.8(15) . . ?
F15' C22A C21A 105.9(8) . . ?
F16A C22A C21A 108.3(15) . . ?
F16' C22A C21A 106.6(8) . . ?
F17' C22A C21A 112.1(8) . . ?
O5A C23A C24A 123.6(7) . . ?
O5A C23A C26A 116.8(7) . . ?
C24A C23A C26A 119.6(7) . . ?
C25A C24A C23A 122.3(8) . . ?
C25A C24A H24A 118.9 . . ?
C23A C24A H24A 118.9 . . ?
O6A C25A C24A 129.1(9) . . ?
O6A C25A C30A 114.2(8) . . ?
C24A C25A C30A 116.0(8) . . ?
C27A C26A C23A 129.6(7) . . ?
C27A C26A S3 112.5(6) . . ?
C23A C26A S3 117.9(5) . . ?
C26A C27A C28A 108.4(7) . . ?
C26A C27A H27A 125.8 . . ?
C28A C27A H27A 125.8 . . ?
C29A C28A C27A 114.3(7) . . ?
C29A C28A H28A 122.8 . . ?
C27A C28A H28A 122.8 . . ?
C28A C29A S3 113.0(7) . . ?
C28A C29A H29A 123.5 . . ?
S3 C29A H29A 123.5 . . ?
N1A C34A C45A 118.1(8) . . ?
N1A C34A C38A 121.5(9) . . ?
C45A C34A C38A 120.4(10) . . ?
N1A C35A C36A 123.3(11) . . ?
N1A C35A H35A 118.4 . . ?
C36A C35A H35A 118.4 . . ?
C37A C36A C35A 118.7(11) . . ?
C37A C36A H36A 120.6 . . ?
C35A C36A H36A 120.6 . . ?
C36A C37A C38A 121.1(10) . . ?
C36A C37A H37A 119.5 . . ?
C38A C37A H37A 119.5 . . ?
C37A C38A C34A 117.5(11) . . ?
C37A C38A C39A 125.5(11) . . ?
C34A C38A C39A 116.9(11) . . ?
C40A C39A C38A 122.2(12) . . ?
C40A C39A H39A 118.9 . . ?
C38A C39A H39A 118.9 . . ?
C39A C40A C41A 122.6(13) . . ?
C39A C40A H40A 118.7 . . ?
C41A C40A H40A 118.7 . . ?
C42A C41A C45A 117.5(11) . . ?
C42A C41A C40A 124.4(12) . . ?
C45A C41A C40A 118.1(12) . . ?
C43A C42A C41A 120.2(11) . . ?
C43A C42A H42A 119.9 . . ?
C41A C42A H42A 119.9 . . ?
C42A C43A C44A 120.1(13) . . ?
C42A C43A H43A 120.0 . . ?
C44A C43A H43A 120.0 . . ?
N2A C44A C43A 122.6(12) . . ?
N2A C44A H44A 118.7 . . ?
C43A C44A H44A 118.7 . . ?
N2A C45A C34A 119.0(8) . . ?
N2A C45A C41A 121.3(10) . . ?
C34A C45A C41A 119.7(10) . . ?
O5B Eu2 O4B 146.37(18) . . ?
O5B Eu2 O3B 76.09(18) . . ?
O4B Eu2 O3B 71.11(17) . . ?
O5B Eu2 O2B 130.66(18) . . ?
O4B Eu2 O2B 78.12(18) . . ?
O3B Eu2 O2B 129.27(18) . . ?
O5B Eu2 O1B 80.57(19) . . ?
O4B Eu2 O1B 96.85(18) . . ?
O3B Eu2 O1B 73.56(18) . . ?
O2B Eu2 O1B 71.22(17) . . ?
O5B Eu2 O6B 71.1(2) . . ?
O4B Eu2 O6B 140.3(2) . . ?
O3B Eu2 O6B 146.84(19) . . ?
O2B Eu2 O6B 78.0(2) . . ?
O1B Eu2 O6B 104.9(2) . . ?
O5B Eu2 N2B 122.5(2) . . ?
O4B Eu2 N2B 72.7(2) . . ?
O3B Eu2 N2B 123.9(2) . . ?
O2B Eu2 N2B 81.3(2) . . ?
O1B Eu2 N2B 152.18(19) . . ?
O6B Eu2 N2B 72.7(2) . . ?
O5B Eu2 N1B 75.3(2) . . ?
O4B Eu2 N1B 88.67(19) . . ?
O3B Eu2 N1B 74.13(19) . . ?
O2B Eu2 N1B 144.9(2) . . ?
O1B Eu2 N1B 143.34(19) . . ?
O6B Eu2 N1B 93.0(2) . . ?
N2B Eu2 N1B 63.7(2) . . ?
C7B S4 C4B 92.9(5) . . ?
C18B S5 C15B 91.7(4) . . ?
C1B O1B Eu2 136.8(5) . . ?
C3B O2B Eu2 133.5(5) . . ?
C12B O3B Eu2 139.6(5) . . ?
C14B O4B Eu2 135.7(5) . . ?
C23B O5B Eu2 139.3(6) . . ?
C25B O6B Eu2 135.1(6) . . ?
C35B N1B C34B 118.3(7) . . ?
C35B N1B Eu2 121.8(6) . . ?
C34B N1B Eu2 119.7(5) . . ?
C44B N2B C45B 118.5(7) . . ?
C44B N2B Eu2 121.8(6) . . ?
C45B N2B Eu2 119.4(5) . . ?
O1B C1B C2B 122.9(7) . . ?
O1B C1B C4B 117.1(6) . . ?
C2B C1B C4B 120.0(7) . . ?
C3B C2B C1B 122.5(7) . . ?
C3B C2B H2BA 118.7 . . ?
C1B C2B H2BA 118.7 . . ?
O2B C3B C2B 128.1(7) . . ?
O2B C3B C8B 114.3(7) . . ?
C2B C3B C8B 117.3(7) . . ?
C1B C4B C5B 131.0(7) . . ?
C1B C4B S4 118.8(6) . . ?
C5B C4B S4 109.9(6) . . ?
C6B C5B C4B 110.3(7) . . ?
C6B C5B H5BA 124.9 . . ?
C4B C5B H5BA 124.9 . . ?
C7B C6B C5B 114.6(8) . . ?
C7B C6B H6BA 122.7 . . ?
C5B C6B H6BA 122.7 . . ?
C6B C7B S4 112.3(7) . . ?
C6B C7B H7BA 123.8 . . ?
S4 C7B H7BA 123.9 . . ?
O3B C12B C13B 122.3(7) . . ?
O3B C12B C15B 117.4(6) . . ?
C13B C12B C15B 120.3(6) . . ?
C14B C13B C12B 122.5(7) . . ?
C14B C13B H13B 118.8 . . ?
C12B C13B H13B 118.8 . . ?
O4B C14B C13B 128.3(7) . . ?
O4B C14B C19B 113.6(7) . . ?
C13B C14B C19B 118.0(7) . . ?
C16B C15B C12B 129.6(7) . . ?
C16B C15B S5 112.0(6) . . ?
C12B C15B S5 118.3(5) . . ?
C15B C16B C17B 109.7(7) . . ?
C15B C16B H16B 125.2 . . ?
C17B C16B H16B 125.2 . . ?
C18B C17B C16B 113.6(7) . . ?
C18B C17B H17B 123.2 . . ?
C16B C17B H17B 123.2 . . ?
C17B C18B S5 113.0(7) . . ?
C17B C18B H18B 123.5 . . ?
S5 C18B H18B 123.5 . . ?
O5B C23B C26' 120.4(10) . . ?
O5B C23B C24B 124.2(9) . . ?
C26' C23B C24B 114.9(10) . . ?
O5B C23B C26B 112.6(9) . . ?
C24B C23B C26B 121.4(9) . . ?
C25B C24B C23B 121.6(8) . . ?
C25B C24B H24B 119.2 . . ?
C23B C24B H24B 119.2 . . ?
O6B C25B C24B 128.5(8) . . ?
O6B C25B C30B 113.3(8) . . ?
C24B C25B C30B 118.2(8) . . ?
C26' S6' C29' 91.9(13) . . ?
C23B C26' C27' 134.5(14) . . ?
C23B C26' S6' 114.3(13) . . ?
C27' C26' S6' 109.2(14) . . ?
C28' C27' C26' 113.2(17) . . ?
C28' C27' H27B 123.4 . . ?
C26' C27' H27B 123.4 . . ?
C29' C28' C27' 114(2) . . ?
C29' C28' H28B 122.9 . . ?
C27' C28' H28B 122.9 . . ?
C28' C29' S6' 110.9(17) . . ?
C28' C29' H29B 124.6 . . ?
S6' C29' H29B 124.6 . . ?
C29B S6 C26B 90.8(13) . . ?
C27B C26B C23B 129.1(13) . . ?
C27B C26B S6 110.6(13) . . ?
C23B C26B S6 120.0(11) . . ?
C28B C27B C26B 110.6(17) . . ?
C28B C27B H27C 124.7 . . ?
C26B C27B H27C 124.7 . . ?
C29B C28B C27B 116(2) . . ?
C29B C28B H28C 122.1 . . ?
C27B C28B H28C 122.1 . . ?
C28B C29B S6 111.9(17) . . ?
C28B C29B H29C 124.0 . . ?
S6 C29B H29C 124.0 . . ?
N1B C34B C38B 121.7(8) . . ?
N1B C34B C45B 117.5(7) . . ?
C38B C34B C45B 120.7(8) . . ?
N1B C35B C36B 122.3(9) . . ?
N1B C35B H35B 118.9 . . ?
C36B C35B H35B 118.9 . . ?
C37B C36B C35B 120.1(9) . . ?
C37B C36B H36B 119.9 . . ?
C35B C36B H36B 119.9 . . ?
C36B C37B C38B 119.8(8) . . ?
C36B C37B H37B 120.1 . . ?
C38B C37B H37B 120.1 . . ?
C37B C38B C34B 117.7(9) . . ?
C37B C38B C39B 124.1(8) . . ?
C34B C38B C39B 118.2(9) . . ?
C40B C39B C38B 121.3(9) . . ?
C40B C39B H39B 119.3 . . ?
C38B C39B H39B 119.3 . . ?
C39B C40B C41B 121.6(9) . . ?
C39B C40B H40B 119.2 . . ?
C41B C40B H40B 119.2 . . ?
C42B C41B C45B 117.3(8) . . ?
C42B C41B C40B 123.5(9) . . ?
C45B C41B C40B 119.2(9) . . ?
C43B C42B C41B 120.6(9) . . ?
C43B C42B H42B 119.7 . . ?
C41B C42B H42B 119.7 . . ?
C42B C43B C44B 117.5(9) . . ?
C42B C43B H43B 121.3 . . ?
C44B C43B H43B 121.3 . . ?
N2B C44B C43B 123.9(9) . . ?
N2B C44B H44B 118.1 . . ?
C43B C44B H44B 118.1 . . ?
N2B C45B C41B 122.2(8) . . ?
N2B C45B C34B 119.0(7) . . ?
C41B C45B C34B 118.8(8) . . ?
F2B C8B F1B 108.6(8) . . ?
F2B C8B C3B 111.1(7) . . ?
F1B C8B C3B 108.3(8) . . ?
F2B C8B C9B 108.3(8) . . ?
F1B C8B C9B 108.3(7) . . ?
C3B C8B C9B 112.1(7) . . ?
F3B C9B F4B 106.9(8) . . ?
F3B C9B C10B 107.4(8) . . ?
F4B C9B C10B 107.7(8) . . ?
F3B C9B C8B 108.6(7) . . ?
F4B C9B C8B 108.3(7) . . ?
C10B C9B C8B 117.5(9) . . ?
F5B C10B F6B 106.7(11) . . ?
F5B C10B C11B 109.0(11) . . ?
F6B C10B C11B 105.4(11) . . ?
F5B C10B C9B 109.4(10) . . ?
F6B C10B C9B 108.0(10) . . ?
C11B C10B C9B 117.7(11) . . ?
F11B C19B F10B 107.4(8) . . ?
F11B C19B C14B 109.6(8) . . ?
F10B C19B C14B 112.4(7) . . ?
F11B C19B C20B 111.7(7) . . ?
F10B C19B C20B 106.9(8) . . ?
C14B C19B C20B 109.0(8) . . ?
F13B C20B F12B 107.8(10) . . ?
F13B C20B C21B 110.6(11) . . ?
F12B C20B C21B 108.9(9) . . ?
F13B C20B C19B 110.5(8) . . ?
F12B C20B C19B 102.3(9) . . ?
C21B C20B C19B 116.0(10) . . ?
F14B C21B F15B 115.1(14) . . ?
F14B C21B C22B 105.7(12) . . ?
F15B C21B C22B 107.7(12) . . ?
F14B C21B C20B 105.0(11) . . ?
F15B C21B C20B 104.6(11) . . ?
C22B C21B C20B 119.2(14) . . ?
F18B C22B F16B 110.1(17) . . ?
F18B C22B F17B 110.5(16) . . ?
F16B C22B F17B 98.9(15) . . ?
F18B C22B C21B 118.7(17) . . ?
F16B C22B C21B 110.3(15) . . ?
F17B C22B C21B 106.6(15) . . ?
F18A C30A F19A 111.0(10) . . ?
F18A C30A C31A 106.8(9) . . ?
F19A C30A C31A 109.6(8) . . ?
F18A C30A C25A 109.9(8) . . ?
F19A C30A C25A 104.9(9) . . ?
C31A C30A C25A 114.8(9) . . ?
F20A C31A F21A 102.7(9) . . ?
F20A C31A C32A 115.2(10) . . ?
F21A C31A C32A 103.2(9) . . ?
F20A C31A C30A 109.9(8) . . ?
F21A C31A C30A 107.2(8) . . ?
C32A C31A C30A 117.0(10) . . ?
F22A C32A C33A 115.3(14) . . ?
F22A C32A F23A 106.0(12) . . ?
C33A C32A F23A 105.2(14) . . ?
F22A C32A C31A 107.2(11) . . ?
C33A C32A C31A 118.1(14) . . ?
F23A C32A C31A 103.8(11) . . ?
F24A C33A F26A 107.3(19) . . ?
F24A C33A C32A 110.2(18) . . ?
F26A C33A C32A 112.6(16) . . ?
F24A C33A F25A 108.4(19) . . ?
F26A C33A F25A 111.0(18) . . ?
C32A C33A F25A 107.3(16) . . ?
F22B C31B F21B 107.6(14) . . ?
F22B C31B C32B 108.6(12) . . ?
F21B C31B C32B 100.6(11) . . ?
F22B C31B C30B 102.2(10) . . ?
F21B C31B C30B 117.5(12) . . ?
C32B C31B C30B 119.9(10) . . ?
F24B C32B F23B 103.4(12) . . ?
F24B C32B C31B 107.6(12) . . ?
F23B C32B C31B 110.0(11) . . ?
F24B C32B C33B 108.6(10) . . ?
F23B C32B C33B 107.7(11) . . ?
C31B C32B C33B 118.5(9) . . ?
F27B C33B F25B 107.7(7) . . ?
F27B C33B F26B 110.4(7) . . ?
F25B C33B F26B 108.3(7) . . ?
F27B C33B C32B 105.3(12) . . ?
F25B C33B C32B 115.4(12) . . ?
F26B C33B C32B 109.7(12) . . ?
F20B C30B F19B 105.5(8) . . ?
F20B C30B C31X 122.0(10) . . ?
F19B C30B C31X 103.6(10) . . ?
F20B C30B C31B 99.0(9) . . ?
F19B C30B C31B 106.3(9) . . ?
F20B C30B C25B 109.7(8) . . ?
F19B C30B C25B 110.6(8) . . ?
C31X C30B C25B 105.0(10) . . ?
C31B C30B C25B 123.9(10) . . ?
F7B C11B F9B 108.8(12) . . ?
F7B C11B F8B 107.6(12) . . ?
F9B C11B F8B 105.8(12) . . ?
F7B C11B C10B 111.5(12) . . ?
F9B C11B C10B 113.0(11) . . ?
F8B C11B C10B 109.8(11) . . ?
F22X C31X F21X 112.4(17) . . ?
F22X C31X C30B 104.7(15) . . ?
F21X C31X C30B 110.6(14) . . ?
F22X C31X C32X 99.6(15) . . ?
F21X C31X C32X 118.7(16) . . ?
C30B C31X C32X 109.6(11) . . ?
F24X C32X F23X 91.5(16) . . ?
F24X C32X C33X 112.2(14) . . ?
F23X C32X C33X 109.7(16) . . ?
F24X C32X C31X 111.3(13) . . ?
F23X C32X C31X 112.6(16) . . ?
C33X C32X C31X 116.8(12) . . ?
F25X C33X F27X 111.5(8) . . ?
F25X C33X F26X 111.0(8) . . ?
F27X C33X F26X 110.1(7) . . ?
F25X C33X C32X 107.4(16) . . ?
F27X C33X C32X 109.9(15) . . ?
F26X C33X C32X 106.7(16) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1A C1A C2A -16.4(12) . . . . ?
Eu1 O1A C1A C4A 161.2(5) . . . . ?
O1A C1A C2A C3A 1.1(13) . . . . ?
C4A C1A C2A C3A -176.4(8) . . . . ?
Eu1 O2A C3A C2A 9.2(14) . . . . ?
Eu1 O2A C3A C8A -172.8(5) . . . . ?
C1A C2A C3A O2A 2.0(14) . . . . ?
C1A C2A C3A C8A -176.0(7) . . . . ?
O1A C1A C4A C5A -175.4(7) . . . . ?
C2A C1A C4A C5A 2.3(13) . . . . ?
O1A C1A C4A S1 -1.4(10) . . . . ?
C2A C1A C4A S1 176.3(6) . . . . ?
C7A S1 C4A C5A 0.4(6) . . . . ?
C7A S1 C4A C1A -174.6(7) . . . . ?
C1A C4A C5A C6A 174.0(8) . . . . ?
S1 C4A C5A C6A -0.3(8) . . . . ?
C4A C5A C6A C7A 0.0(10) . . . . ?
C5A C6A C7A S1 0.3(10) . . . . ?
C4A S1 C7A C6A -0.4(7) . . . . ?
O2A C3A C8A F2A' 39.7(10) . . . . ?
C2A C3A C8A F2A' -142.0(9) . . . . ?
O2A C3A C8A F1A 125.0(15) . . . . ?
C2A C3A C8A F1A -56.7(15) . . . . ?
O2A C3A C8A F1A' 155.9(8) . . . . ?
C2A C3A C8A F1A' -25.9(11) . . . . ?
O2A C3A C8A F2A 15.2(14) . . . . ?
C2A C3A C8A F2A -166.5(13) . . . . ?
O2A C3A C8A C9A -89.2(8) . . . . ?
C2A C3A C8A C9A 89.1(8) . . . . ?
F1A C8A C9A F4A 149(2) . . . . ?
F2A C8A C9A F4A -96(2) . . . . ?
C3A C8A C9A F4A 13.6(19) . . . . ?
F2A' C8A C9A F3A' 176.2(9) . . . . ?
F1A' C8A C9A F3A' 59.7(9) . . . . ?
C3A C8A C9A F3A' -58.5(8) . . . . ?
F2A' C8A C9A F4A' -66.7(10) . . . . ?
F1A' C8A C9A F4A' 176.8(8) . . . . ?
C3A C8A C9A F4A' 58.6(8) . . . . ?
F1A C8A C9A F3A 40(2) . . . . ?
F2A C8A C9A F3A 154.3(17) . . . . ?
C3A C8A C9A F3A -95.9(14) . . . . ?
F2A' C8A C9A C10A 54.6(11) . . . . ?
F1A C8A C9A C10A -44.3(19) . . . . ?
F1A' C8A C9A C10A -61.9(9) . . . . ?
F2A C8A C9A C10A 70.1(13) . . . . ?
C3A C8A C9A C10A 179.9(7) . . . . ?
F4A C9A C10A F6A -135.7(19) . . . . ?
F3A' C9A C10A F6A -66.7(10) . . . . ?
F4A' C9A C10A F6A -179.8(9) . . . . ?
F3A C9A C10A F6A -28.1(16) . . . . ?
C8A C9A C10A F6A 57.6(11) . . . . ?
F4A C9A C10A F5A 106.2(19) . . . . ?
F3A' C9A C10A F5A 175.1(9) . . . . ?
F4A' C9A C10A F5A 62.1(10) . . . . ?
F3A C9A C10A F5A -146.3(16) . . . . ?
C8A C9A C10A F5A -60.5(10) . . . . ?
F4A C9A C10A C11A -14(2) . . . . ?
F3A' C9A C10A C11A 55.2(11) . . . . ?
F4A' C9A C10A C11A -57.9(11) . . . . ?
F3A C9A C10A C11A 93.8(16) . . . . ?
C8A C9A C10A C11A 179.5(8) . . . . ?
F6A C10A C11A F8A -56.7(12) . . . . ?
F5A C10A C11A F8A 58.6(12) . . . . ?
C9A C10A C11A F8A -179.7(9) . . . . ?
F6A C10A C11A F9A 178.6(9) . . . . ?
F5A C10A C11A F9A -66.1(11) . . . . ?
C9A C10A C11A F9A 55.6(13) . . . . ?
F6A C10A C11A F7A 64.2(11) . . . . ?
F5A C10A C11A F7A 179.5(9) . . . . ?
C9A C10A C11A F7A -58.9(12) . . . . ?
Eu1 O3A C12A C13A -1.0(12) . . . . ?
Eu1 O3A C12A C15A 178.0(5) . . . . ?
O3A C12A C13A C14A 2.7(11) . . . . ?
C15A C12A C13A C14A -176.2(7) . . . . ?
Eu1 O4A C14A C13A -7.6(13) . . . . ?
Eu1 O4A C14A C19A 173.5(5) . . . . ?
C12A C13A C14A O4A 1.4(12) . . . . ?
C12A C13A C14A C19A -179.8(7) . . . . ?
O3A C12A C15A C16A -175.9(8) . . . . ?
C13A C12A C15A C16A 3.1(12) . . . . ?
O3A C12A C15A S2 0.9(9) . . . . ?
C13A C12A C15A S2 179.9(5) . . . . ?
C18A S2 C15A C16A -1.7(8) . . . . ?
C18A S2 C15A C12A -179.0(7) . . . . ?
C12A C15A C16A C17A 178.5(8) . . . . ?
S2 C15A C16A C17A 1.5(10) . . . . ?
C15A C16A C17A C18A -0.5(13) . . . . ?
C16A C17A C18A S2 -0.7(14) . . . . ?
C15A S2 C18A C17A 1.4(10) . . . . ?
O4A C14A C19A F11A 37.2(9) . . . . ?
C13A C14A C19A F11A -141.8(7) . . . . ?
O4A C14A C19A F10A 156.7(7) . . . . ?
C13A C14A C19A F10A -22.3(10) . . . . ?
O4A C14A C19A C20A -82.1(9) . . . . ?
C13A C14A C19A C20A 98.9(9) . . . . ?
F11A C19A C20A F13A 161.5(7) . . . . ?
F10A C19A C20A F13A 45.6(9) . . . . ?
C14A C19A C20A F13A -77.4(9) . . . . ?
F11A C19A C20A F12A -85.4(8) . . . . ?
F10A C19A C20A F12A 158.6(7) . . . . ?
C14A C19A C20A F12A 35.7(10) . . . . ?
F11A C19A C20A C21A 36.9(12) . . . . ?
F10A C19A C20A C21A -79.0(11) . . . . ?
C14A C19A C20A C21A 158.0(9) . . . . ?
F13A C20A C21A F14A -75.9(11) . . . . ?
F12A C20A C21A F14A 171.1(8) . . . . ?
C19A C20A C21A F14A 46.8(13) . . . . ?
F13A C20A C21A F15F 166.4(9) . . . . ?
F12A C20A C21A F15F 53.4(11) . . . . ?
C19A C20A C21A F15F -70.8(13) . . . . ?
F13A C20A C21A C22A 51.4(14) . . . . ?
F12A C20A C21A C22A -61.6(12) . . . . ?
C19A C20A C21A C22A 174.1(9) . . . . ?
F14A C21A C22A F17A 107.9(16) . . . . ?
F15F C21A C22A F17A -133.3(15) . . . . ?
C20A C21A C22A F17A -15.7(19) . . . . ?
F14A C21A C22A F15A -134.8(15) . . . . ?
F15F C21A C22A F15A -16.0(15) . . . . ?
C20A C21A C22A F15A 101.6(16) . . . . ?
F14A C21A C22A F15' -63.3(10) . . . . ?
F15F C21A C22A F15' 55.5(10) . . . . ?
C20A C21A C22A F15' 173.0(10) . . . . ?
F14A C21A C22A F16A -20.5(16) . . . . ?
F15F C21A C22A F16A 98.3(15) . . . . ?
C20A C21A C22A F16A -144.1(16) . . . . ?
F14A C21A C22A F16' 54.6(10) . . . . ?
F15F C21A C22A F16' 173.4(8) . . . . ?
C20A C21A C22A F16' -69.0(12) . . . . ?
F14A C21A C22A F17' 175.6(8) . . . . ?
F15F C21A C22A F17' -65.6(9) . . . . ?
C20A C21A C22A F17' 51.9(12) . . . . ?
Eu1 O5A C23A C24A 6.4(14) . . . . ?
Eu1 O5A C23A C26A -176.5(5) . . . . ?
O5A C23A C24A C25A -3.5(17) . . . . ?
C26A C23A C24A C25A 179.6(10) . . . . ?
Eu1 O6A C25A C24A 8.9(19) . . . . ?
Eu1 O6A C25A C30A -161.8(6) . . . . ?
C23A C24A C25A O6A -4(2) . . . . ?
C23A C24A C25A C30A 166.6(10) . . . . ?
O5A C23A C26A C27A 178.9(8) . . . . ?
C24A C23A C26A C27A -3.9(13) . . . . ?
O5A C23A C26A S3 0.0(10) . . . . ?
C24A C23A C26A S3 177.1(7) . . . . ?
C29A S3 C26A C27A 1.3(6) . . . . ?
C29A S3 C26A C23A -179.6(6) . . . . ?
C23A C26A C27A C28A 180.0(8) . . . . ?
S3 C26A C27A C28A -1.0(8) . . . . ?
C26A C27A C28A C29A 0.1(10) . . . . ?
C27A C28A C29A S3 0.9(10) . . . . ?
C26A S3 C29A C28A -1.2(7) . . . . ?
C35A N1A C34A C45A -177.4(7) . . . . ?
Eu1 N1A C34A C45A 8.3(9) . . . . ?
C35A N1A C34A C38A 0.9(11) . . . . ?
Eu1 N1A C34A C38A -173.4(6) . . . . ?
C34A N1A C35A C36A -0.5(12) . . . . ?
Eu1 N1A C35A C36A 173.6(7) . . . . ?
N1A C35A C36A C37A -0.5(14) . . . . ?
C35A C36A C37A C38A 1.1(15) . . . . ?
C36A C37A C38A C34A -0.7(15) . . . . ?
C36A C37A C38A C39A 177.7(10) . . . . ?
N1A C34A C38A C37A -0.3(13) . . . . ?
C45A C34A C38A C37A 177.9(8) . . . . ?
N1A C34A C38A C39A -178.9(8) . . . . ?
C45A C34A C38A C39A -0.7(12) . . . . ?
C37A C38A C39A C40A -176.0(12) . . . . ?
C34A C38A C39A C40A 2.5(16) . . . . ?
C38A C39A C40A C41A -1(2) . . . . ?
C39A C40A C41A C42A 178.3(12) . . . . ?
C39A C40A C41A C45A -1.8(18) . . . . ?
C45A C41A C42A C43A -2.2(18) . . . . ?
C40A C41A C42A C43A 177.7(12) . . . . ?
C41A C42A C43A C44A 1(2) . . . . ?
C45A N2A C44A C43A 0.0(15) . . . . ?
Eu1 N2A C44A C43A -179.0(9) . . . . ?
C42A C43A C44A N2A 0(2) . . . . ?
C44A N2A C45A C34A 177.7(8) . . . . ?
Eu1 N2A C45A C34A -3.3(10) . . . . ?
C44A N2A C45A C41A -1.7(12) . . . . ?
Eu1 N2A C45A C41A 177.4(6) . . . . ?
N1A C34A C45A N2A -3.3(11) . . . . ?
C38A C34A C45A N2A 178.4(7) . . . . ?
N1A C34A C45A C41A 176.0(8) . . . . ?
C38A C34A C45A C41A -2.3(12) . . . . ?
C42A C41A C45A N2A 2.8(14) . . . . ?
C40A C41A C45A N2A -177.2(9) . . . . ?
C42A C41A C45A C34A -176.6(9) . . . . ?
C40A C41A C45A C34A 3.5(14) . . . . ?
Eu2 O1B C1B C2B 20.4(11) . . . . ?
Eu2 O1B C1B C4B -159.0(5) . . . . ?
O1B C1B C2B C3B -1.0(12) . . . . ?
C4B C1B C2B C3B 178.3(7) . . . . ?
Eu2 O2B C3B C2B -15.7(12) . . . . ?
Eu2 O2B C3B C8B 159.4(6) . . . . ?
C1B C2B C3B O2B -0.7(13) . . . . ?
C1B C2B C3B C8B -175.7(7) . . . . ?
O1B C1B C4B C5B 174.5(7) . . . . ?
C2B C1B C4B C5B -4.9(12) . . . . ?
O1B C1B C4B S4 0.7(9) . . . . ?
C2B C1B C4B S4 -178.7(6) . . . . ?
C7B S4 C4B C1B 174.4(6) . . . . ?
C7B S4 C4B C5B -0.6(6) . . . . ?
C1B C4B C5B C6B -173.5(8) . . . . ?
S4 C4B C5B C6B 0.7(8) . . . . ?
C4B C5B C6B C7B -0.4(10) . . . . ?
C5B C6B C7B S4 0.0(11) . . . . ?
C4B S4 C7B C6B 0.3(8) . . . . ?
Eu2 O3B C12B C13B -0.7(11) . . . . ?
Eu2 O3B C12B C15B -178.5(5) . . . . ?
O3B C12B C13B C14B 2.3(11) . . . . ?
C15B C12B C13B C14B 180.0(7) . . . . ?
Eu2 O4B C14B C13B -10.2(13) . . . . ?
Eu2 O4B C14B C19B 167.0(6) . . . . ?
C12B C13B C14B O4B 3.0(13) . . . . ?
C12B C13B C14B C19B -174.0(7) . . . . ?
O3B C12B C15B C16B 178.2(7) . . . . ?
C13B C12B C15B C16B 0.4(12) . . . . ?
O3B C12B C15B S5 0.4(9) . . . . ?
C13B C12B C15B S5 -177.5(5) . . . . ?
C18B S5 C15B C16B -0.6(6) . . . . ?
C18B S5 C15B C12B 177.6(6) . . . . ?
C12B C15B C16B C17B -177.5(7) . . . . ?
S5 C15B C16B C17B 0.4(8) . . . . ?
C15B C16B C17B C18B 0.1(9) . . . . ?
C16B C17B C18B S5 -0.5(10) . . . . ?
C15B S5 C18B C17B 0.7(7) . . . . ?
Eu2 O5B C23B C26' 168.0(10) . . . . ?
Eu2 O5B C23B C24B -4.0(16) . . . . ?
Eu2 O5B C23B C26B -169.1(7) . . . . ?
O5B C23B C24B C25B -1.9(17) . . . . ?
C26' C23B C24B C25B -174.2(12) . . . . ?
C26B C23B C24B C25B 162.0(11) . . . . ?
Eu2 O6B C25B C24B -3.7(17) . . . . ?
Eu2 O6B C25B C30B 175.2(5) . . . . ?
C23B C24B C25B O6B 5.5(19) . . . . ?
C23B C24B C25B C30B -173.3(9) . . . . ?
O5B C23B C26' C27' 177.0(17) . . . . ?
C24B C23B C26' C27' -10(3) . . . . ?
O5B C23B C26' S6' 15(2) . . . . ?
C24B C23B C26' S6' -172.1(14) . . . . ?
C29' S6' C26' C23B 172.8(14) . . . . ?
C29' S6' C26' C27' 6.5(19) . . . . ?
C23B C26' C27' C28' -170.5(19) . . . . ?
S6' C26' C27' C28' -8(2) . . . . ?
C26' C27' C28' C29' 6(3) . . . . ?
C27' C28' C29' S6' 0(3) . . . . ?
C26' S6' C29' C28' -4(2) . . . . ?
O5B C23B C26B C27B 170.8(15) . . . . ?
C24B C23B C26B C27B 5(2) . . . . ?
O5B C23B C26B S6 -14.9(18) . . . . ?
C24B C23B C26B S6 179.5(14) . . . . ?
C29B S6 C26B C27B -1.2(19) . . . . ?
C29B S6 C26B C23B -176.5(13) . . . . ?
C23B C26B C27B C28B 173.7(15) . . . . ?
S6 C26B C27B C28B -1(2) . . . . ?
C26B C27B C28B C29B 4(3) . . . . ?
C27B C28B C29B S6 -5(3) . . . . ?
C26B S6 C29B C28B 3(2) . . . . ?
C35B N1B C34B C38B -1.3(11) . . . . ?
Eu2 N1B C34B C38B 174.7(6) . . . . ?
C35B N1B C34B C45B 178.3(7) . . . . ?
Eu2 N1B C34B C45B -5.8(9) . . . . ?
C34B N1B C35B C36B -0.4(11) . . . . ?
Eu2 N1B C35B C36B -176.2(6) . . . . ?
N1B C35B C36B C37B 1.2(13) . . . . ?
C35B C36B C37B C38B -0.4(13) . . . . ?
C36B C37B C38B C34B -1.1(12) . . . . ?
C36B C37B C38B C39B 178.9(9) . . . . ?
N1B C34B C38B C37B 2.0(12) . . . . ?
C45B C34B C38B C37B -177.5(8) . . . . ?
N1B C34B C38B C39B -178.0(8) . . . . ?
C45B C34B C38B C39B 2.5(12) . . . . ?
C37B C38B C39B C40B 176.9(9) . . . . ?
C34B C38B C39B C40B -3.1(14) . . . . ?
C38B C39B C40B C41B 1.5(16) . . . . ?
C39B C40B C41B C42B -179.3(11) . . . . ?
C39B C40B C41B C45B 0.8(16) . . . . ?
C45B C41B C42B C43B 0.1(17) . . . . ?
C40B C41B C42B C43B -179.8(11) . . . . ?
C41B C42B C43B C44B -0.4(18) . . . . ?
C45B N2B C44B C43B -0.9(15) . . . . ?
Eu2 N2B C44B C43B 173.5(9) . . . . ?
C42B C43B C44B N2B 0.8(18) . . . . ?
C44B N2B C45B C41B 0.6(13) . . . . ?
Eu2 N2B C45B C41B -174.0(7) . . . . ?
C44B N2B C45B C34B -178.3(8) . . . . ?
Eu2 N2B C45B C34B 7.2(10) . . . . ?
C42B C41B C45B N2B -0.2(14) . . . . ?
C40B C41B C45B N2B 179.7(9) . . . . ?
C42B C41B C45B C34B 178.7(9) . . . . ?
C40B C41B C45B C34B -1.4(13) . . . . ?
N1B C34B C45B N2B -0.9(11) . . . . ?
C38B C34B C45B N2B 178.6(7) . . . . ?
N1B C34B C45B C41B -179.8(8) . . . . ?
C38B C34B C45B C41B -0.3(12) . . . . ?
O2B C3B C8B F2B 161.5(8) . . . . ?
C2B C3B C8B F2B -22.8(11) . . . . ?
O2B C3B C8B F1B 42.3(10) . . . . ?
C2B C3B C8B F1B -142.1(8) . . . . ?
O2B C3B C8B C9B -77.2(9) . . . . ?
C2B C3B C8B C9B 98.5(9) . . . . ?
F2B C8B C9B F3B 62.3(9) . . . . ?
F1B C8B C9B F3B 179.9(7) . . . . ?
C3B C8B C9B F3B -60.6(9) . . . . ?
F2B C8B C9B F4B 178.0(7) . . . . ?
F1B C8B C9B F4B -64.3(9) . . . . ?
C3B C8B C9B F4B 55.2(9) . . . . ?
F2B C8B C9B C10B -59.8(10) . . . . ?
F1B C8B C9B C10B 57.8(10) . . . . ?
C3B C8B C9B C10B 177.3(8) . . . . ?
F3B C9B C10B F5B -75.4(13) . . . . ?
F4B C9B C10B F5B 169.7(10) . . . . ?
C8B C9B C10B F5B 47.3(14) . . . . ?
F3B C9B C10B F6B 168.7(10) . . . . ?
F4B C9B C10B F6B 53.9(13) . . . . ?
C8B C9B C10B F6B -68.6(12) . . . . ?
F3B C9B C10B C11B 49.7(13) . . . . ?
F4B C9B C10B C11B -65.2(13) . . . . ?
C8B C9B C10B C11B 172.4(10) . . . . ?
O4B C14B C19B F11B 56.8(10) . . . . ?
C13B C14B C19B F11B -125.7(8) . . . . ?
O4B C14B C19B F10B 176.1(8) . . . . ?
C13B C14B C19B F10B -6.5(12) . . . . ?
O4B C14B C19B C20B -65.6(10) . . . . ?
C13B C14B C19B C20B 111.8(9) . . . . ?
F11B C19B C20B F13B -154.6(8) . . . . ?
F10B C19B C20B F13B 88.2(10) . . . . ?
C14B C19B C20B F13B -33.4(12) . . . . ?
F11B C19B C20B F12B -40.0(10) . . . . ?
F10B C19B C20B F12B -157.2(8) . . . . ?
C14B C19B C20B F12B 81.2(9) . . . . ?
F11B C19B C20B C21B 78.4(12) . . . . ?
F10B C19B C20B C21B -38.8(12) . . . . ?
C14B C19B C20B C21B -160.4(9) . . . . ?
F13B C20B C21B F14B -50.7(14) . . . . ?
F12B C20B C21B F14B -169.0(11) . . . . ?
C19B C20B C21B F14B 76.3(14) . . . . ?
F13B C20B C21B F15B -172.2(10) . . . . ?
F12B C20B C21B F15B 69.4(13) . . . . ?
C19B C20B C21B F15B -45.3(14) . . . . ?
F13B C20B C21B C22B 67.4(16) . . . . ?
F12B C20B C21B C22B -51.0(17) . . . . ?
C19B C20B C21B C22B -165.6(12) . . . . ?
F14B C21B C22B F18B -54(2) . . . . ?
F15B C21B C22B F18B 69(2) . . . . ?
C20B C21B C22B F18B -171.7(15) . . . . ?
F14B C21B C22B F16B 177.8(14) . . . . ?
F15B C21B C22B F16B -58.7(19) . . . . ?
C20B C21B C22B F16B 60(2) . . . . ?
F14B C21B C22B F17B 71.4(17) . . . . ?
F15B C21B C22B F17B -165.1(13) . . . . ?
C20B C21B C22B F17B -46.3(19) . . . . ?
O6A C25A C30A F18A -162.6(10) . . . . ?
C24A C25A C30A F18A 25.5(15) . . . . ?
O6A C25A C30A F19A -43.2(12) . . . . ?
C24A C25A C30A F19A 144.8(10) . . . . ?
O6A C25A C30A C31A 77.1(13) . . . . ?
C24A C25A C30A C31A -94.9(12) . . . . ?
F18A C30A C31A F20A -82.1(11) . . . . ?
F19A C30A C31A F20A 157.6(9) . . . . ?
C25A C30A C31A F20A 39.9(13) . . . . ?
F18A C30A C31A F21A 166.9(8) . . . . ?
F19A C30A C31A F21A 46.7(10) . . . . ?
C25A C30A C31A F21A -71.0(10) . . . . ?
F18A C30A C31A C32A 51.7(14) . . . . ?
F19A C30A C31A C32A -68.6(13) . . . . ?
C25A C30A C31A C32A 173.7(10) . . . . ?
F20A C31A C32A F22A 163.4(11) . . . . ?
F21A C31A C32A F22A -85.5(12) . . . . ?
C30A C31A C32A F22A 32.0(16) . . . . ?
F20A C31A C32A C33A -64.4(19) . . . . ?
F21A C31A C32A C33A 46.7(18) . . . . ?
C30A C31A C32A C33A 164.2(15) . . . . ?
F20A C31A C32A F23A 51.5(14) . . . . ?
F21A C31A C32A F23A 162.6(10) . . . . ?
C30A C31A C32A F23A -79.9(14) . . . . ?
F22A C32A C33A F24A 56(2) . . . . ?
F23A C32A C33A F24A 172.5(17) . . . . ?
C31A C32A C33A F24A -72(2) . . . . ?
F22A C32A C33A F26A -64(2) . . . . ?
F23A C32A C33A F26A 53(2) . . . . ?
C31A C32A C33A F26A 167.9(16) . . . . ?
F22A C32A C33A F25A 174.0(14) . . . . ?
F23A C32A C33A F25A -69.7(18) . . . . ?
C31A C32A C33A F25A 45(2) . . . . ?
F22B C31B C32B F24B -47.8(14) . . . . ?
F21B C31B C32B F24B -160.6(13) . . . . ?
C30B C31B C32B F24B 69.0(15) . . . . ?
F22B C31B C32B F23B -159.7(12) . . . . ?
F21B C31B C32B F23B 87.5(14) . . . . ?
C30B C31B C32B F23B -43.0(15) . . . . ?
F22B C31B C32B C33B 75.8(14) . . . . ?
F21B C31B C32B C33B -37.0(15) . . . . ?
C30B C31B C32B C33B -167.4(11) . . . . ?
F24B C32B C33B F27B 71.2(14) . . . . ?
F23B C32B C33B F27B -177.5(11) . . . . ?
C31B C32B C33B F27B -51.9(13) . . . . ?
F24B C32B C33B F25B -170.2(12) . . . . ?
F23B C32B C33B F25B -58.9(13) . . . . ?
C31B C32B C33B F25B 66.8(14) . . . . ?
F24B C32B C33B F26B -47.6(15) . . . . ?
F23B C32B C33B F26B 63.8(13) . . . . ?
C31B C32B C33B F26B -170.6(11) . . . . ?
F22B C31B C30B F20B -175.9(11) . . . . ?
F21B C31B C30B F20B -58.4(15) . . . . ?
C32B C31B C30B F20B 64.1(13) . . . . ?
F22B C31B C30B F19B -66.8(13) . . . . ?
F21B C31B C30B F19B 50.7(16) . . . . ?
C32B C31B C30B F19B 173.3(10) . . . . ?
F22B C31B C30B C25B 62.9(15) . . . . ?
F21B C31B C30B C25B -179.6(13) . . . . ?
C32B C31B C30B C25B -57.1(16) . . . . ?
O6B C25B C30B F20B -41.5(11) . . . . ?
C24B C25B C30B F20B 137.5(10) . . . . ?
O6B C25B C30B F19B -157.5(9) . . . . ?
C24B C25B C30B F19B 21.5(13) . . . . ?
O6B C25B C30B C31X 91.4(12) . . . . ?
C24B C25B C30B C31X -89.7(13) . . . . ?
O6B C25B C30B C31B 74.6(13) . . . . ?
C24B C25B C30B C31B -106.4(13) . . . . ?
F5B C10B C11B F7B -65.1(15) . . . . ?
F6B C10B C11B F7B 49.1(14) . . . . ?
C9B C10B C11B F7B 169.5(10) . . . . ?
F5B C10B C11B F9B 171.9(11) . . . . ?
F6B C10B C11B F9B -73.9(13) . . . . ?
C9B C10B C11B F9B 46.5(16) . . . . ?
F5B C10B C11B F8B 54.0(14) . . . . ?
F6B C10B C11B F8B 168.2(10) . . . . ?
C9B C10B C11B F8B -71.3(14) . . . . ?
F20B C30B C31X F22X 67.8(17) . . . . ?
F19B C30B C31X F22X -173.8(13) . . . . ?
C25B C30B C31X F22X -57.7(16) . . . . ?
F20B C30B C31X F21X -170.9(14) . . . . ?
F19B C30B C31X F21X -52.5(17) . . . . ?
C25B C30B C31X F21X 63.6(18) . . . . ?
F20B C30B C31X C32X -38.2(19) . . . . ?
F19B C30B C31X C32X 80.2(15) . . . . ?
C25B C30B C31X C32X -163.7(13) . . . . ?
F22X C31X C32X F24X -143.8(17) . . . . ?
F21X C31X C32X F24X 94.0(19) . . . . ?
C30B C31X C32X F24X -34(2) . . . . ?
F22X C31X C32X F23X -42.7(18) . . . . ?
F21X C31X C32X F23X -164.9(17) . . . . ?
C30B C31X C32X F23X 66.7(18) . . . . ?
F22X C31X C32X C33X 85.5(19) . . . . ?
F21X C31X C32X C33X -37(2) . . . . ?
C30B C31X C32X C33X -165.0(14) . . . . ?
F24X C32X C33X F25X 61.2(18) . . . . ?
F23X C32X C33X F25X -39.0(18) . . . . ?
C31X C32X C33X F25X -168.6(15) . . . . ?
F24X C32X C33X F27X -177.3(15) . . . . ?
F23X C32X C33X F27X 82.5(17) . . . . ?
C31X C32X C33X F27X -47.1(19) . . . . ?
F24X C32X C33X F26X -57.9(18) . . . . ?
F23X C32X C33X F26X -158.1(15) . . . . ?
C31X C32X C33X F26X 72.3(18) . . . . ?

_refine_diff_density_max         2.407
_refine_diff_density_min         -1.507
_refine_diff_density_rms         0.159


_exptl_crystal_preparation       Luminescent
