# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_123
_database_code_depnum_ccdc_archive 'CCDC 2054600'
loop_
_audit_author_name
_audit_author_address
'Yan-Qin Wang'
;Inner Mongolia University
China
;
_audit_update_record             
;
2021-01-08 deposited with the CCDC.	2021-02-15 downloaded from the CCDC.
;
_audit_creation_date             2020-09-29
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.06.28 svn.raecde09e for OlexSys, GUI svn.r6132)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C19 H17 Eu N2 O10'
_chemical_formula_sum            'C19 H17 Eu N2 O10'
_chemical_formula_weight         585.30
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'

_cell_length_a                   17.898(2)
_cell_length_b                   15.3388(17)
_cell_length_c                   18.208(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     4998.7(10)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    7258
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.59
_cell_measurement_theta_min      2.24
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.560
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6787
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0753 before and 0.0330 after correction.
The Ratio of minimum to maximum transmission is 0.9103.
The λ/2 correction factor is 0.00150.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.555
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2304
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0410
_diffrn_reflns_av_unetI/netI     0.0277
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            24333
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        24.999
_diffrn_reflns_theta_max         24.999
_diffrn_reflns_theta_min         2.510
_diffrn_ambient_temperature      293
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_special_details          ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3508
_reflns_number_total             4393
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         2.099
_refine_diff_density_min         -1.034
_refine_diff_density_rms         0.175
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     368
_refine_ls_number_reflns         4393
_refine_ls_number_restraints     188
_refine_ls_R_factor_all          0.0577
_refine_ls_R_factor_gt           0.0445
_refine_ls_restrained_S_all      1.114
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0801P)²+28.4471P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1315
_refine_ls_wR_factor_ref         0.1388
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2. Restrained distances
 C19-N1
 1.4 with sigma of 0.02
 N4-C15
 1.4 with sigma of 0.02
 O12-N4
 1.2 with sigma of 0.02
 C22-C23 = N2-C21
 1.4 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(N2) \\sim Ueq, Uanis(C20) \\sim Ueq, Uanis(C22) \\sim Ueq, Uanis(C21)
\\sim Ueq, Uanis(C23) \\sim Ueq: with sigma of 0.005 and sigma for terminal
atoms of 0.01
Uanis(O8) \\sim Ueq, Uanis(N1) \\sim Ueq, Uanis(C16) \\sim Ueq, Uanis(C17)
\\sim Ueq, Uanis(C19) \\sim Ueq, Uanis(C18) \\sim Ueq: with sigma of 0.01 and
sigma for terminal atoms of 0.02
Uanis(C19) \\sim Ueq, Uanis(N1) \\sim Ueq, Uanis(C16) \\sim Ueq, Uanis(C18)
\\sim Ueq, Uanis(C17) \\sim Ueq: with sigma of 0.01 and sigma for terminal
atoms of 0.02
Uanis(O12) \\sim Ueq, Uanis(N4) \\sim Ueq, Uanis(O11) \\sim Ueq: with sigma of
0.005 and sigma for terminal atoms of 0.01
4. Rigid body (RIGU) restrains
 O7, C22, N2, C21, C20, C23
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 O8, N1, C16, C17, C19, C18
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 O8, N1, C16, C17, C19, C18
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 O11, N4, O12, C15, C8, C13
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
5. Others
 Sof(H7A)=Sof(H7B)=Sof(N1)=Sof(H15)=Sof(C16)=Sof(C17)=Sof(H17A)=Sof(H17B)=
 Sof(H17C)=Sof(C19)=Sof(H19A)=Sof(H19B)=Sof(H19C)=Sof(C18)=Sof(H18A)=Sof(H18B)=
 Sof(H18C)=Sof(O9)=Sof(N3)=Sof(O10)=1-FVAR(1)
 Sof(H8A)=Sof(H8B)=Sof(N2)=Sof(C20)=Sof(H20A)=Sof(H20B)=Sof(H20C)=Sof(H9)=
 Sof(C21)=Sof(H21A)=Sof(H21B)=Sof(H21C)=Sof(C22)=Sof(C23)=Sof(H23A)=Sof(H23B)=
 Sof(H23C)=Sof(O11)=Sof(N4)=Sof(O12)=FVAR(1)
6.a Riding coordinates:
 O7(H7A,H7B), O8(H8A,H8B)
6.b Aromatic/amide H refined with riding coordinates:
 C6(H6), C3(H3), C4(H4), C15(H15), C13(H13), C10(H10), C9(H9)
6.c Idealised Me refined as rotating group:
 C20(H20A,H20B,H20C), C21(H21A,H21B,H21C), C17(H17A,H17B,H17C), C19(H19A,H19B,
 H19C), C18(H18A,H18B,H18C), C23(H23A,H23B,H23C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.43160(2) 0.59105(2) 0.43123(2) 0.01331(15) Uani 1 1 d . . . . .
O1 O 0.3002(3) 0.5955(3) 0.3852(3) 0.0328(13) Uani 1 1 d . . . . .
O2 O 0.3849(3) 0.5477(4) 0.3081(3) 0.0328(12) Uani 1 1 d . . . . .
O3 O 0.1238(3) 0.4265(3) 0.0491(3) 0.0241(11) Uani 1 1 d . . . . .
O4 O 0.0384(3) 0.5122(3) 0.1005(3) 0.0241(10) Uani 1 1 d . . . . .
O5 O 0.1051(3) 0.9415(3) 0.4401(3) 0.0286(12) Uani 1 1 d . . . . .
O6 O 0.0247(3) 0.8482(3) 0.4919(3) 0.0299(12) Uani 1 1 d . . . . .
O7 O 0.4881(3) 0.6879(3) 0.3460(3) 0.0382(13) Uani 1 1 d . . . . .
H7A H 0.514463 0.732663 0.355138 0.057 Uiso 0.442(6) 1 d R U P A 2
H7B H 0.486563 0.685403 0.299348 0.057 Uiso 0.442(6) 1 d R U P A 2
O8 O 0.3843(3) 0.7339(4) 0.4593(4) 0.0439(14) Uani 1 1 d . U . . .
H8A H 0.382776 0.774237 0.427312 0.066 Uiso 0.558(6) 1 d R U P A 1
H8B H 0.419746 0.748787 0.487852 0.066 Uiso 0.558(6) 1 d R U P A 1
N1 N 0.3323(10) 0.8642(11) 0.4770(11) 0.059(4) Uani 0.442(6) 1 d D U P A 2
N2 N 0.4924(8) 0.8078(9) 0.2823(8) 0.054(3) Uani 0.558(6) 1 d D U P A 1
C11 C 0.1014(4) 0.4780(4) 0.0984(3) 0.0207(14) Uani 1 1 d . . . . .
C5 C 0.1558(4) 0.4984(4) 0.1592(3) 0.0214(14) Uani 1 1 d . . . . .
C6 C 0.1389(4) 0.5625(4) 0.2103(3) 0.0193(14) Uani 1 1 d . . . . .
H6 H 0.093226 0.591297 0.207256 0.023 Uiso 1 1 calc R U . . .
C7 C 0.1889(4) 0.5850(4) 0.2664(4) 0.0212(15) Uani 1 1 d . . . . .
C2 C 0.2588(4) 0.5444(4) 0.2683(3) 0.0233(15) Uani 1 1 d . . . . .
C3 C 0.2755(4) 0.4804(5) 0.2157(4) 0.0343(19) Uani 1 1 d . . . . .
H3 H 0.322028 0.453342 0.216875 0.041 Uiso 1 1 calc R U . . .
C4 C 0.2247(4) 0.4567(5) 0.1624(4) 0.0309(17) Uani 1 1 d . . . . .
H4 H 0.236370 0.413074 0.128850 0.037 Uiso 1 1 calc R U . . .
C1 C 0.3180(4) 0.5648(5) 0.3243(4) 0.0235(15) Uani 1 1 d . . . . .
C20 C 0.5093(9) 0.8947(9) 0.2571(9) 0.039(3) Uani 0.558(6) 1 d . U P A 1
H20A H 0.553137 0.893276 0.226675 0.059 Uiso 0.558(6) 1 calc R U P A 1
H20B H 0.518120 0.931955 0.298553 0.059 Uiso 0.558(6) 1 calc R U P A 1
H20C H 0.467940 0.916815 0.229147 0.059 Uiso 0.558(6) 1 calc R U P A 1
C15 C 0.1086(7) 0.6443(7) 0.3664(7) 0.076(4) Uani 1 1 d D . . . .
H15 H 0.087220 0.589229 0.370415 0.091 Uiso 0.442(6) 1 calc R U P A 2
C13 C 0.0812(7) 0.7128(7) 0.4113(7) 0.071(4) Uani 1 1 d . . . . .
H13 H 0.043438 0.701872 0.445226 0.085 Uiso 1 1 calc R U . . .
C12 C 0.1100(4) 0.7942(4) 0.4047(4) 0.0226(14) Uani 1 1 d . . . . .
C10 C 0.1659(6) 0.8079(5) 0.3569(5) 0.051(3) Uani 1 1 d . . . . .
H10 H 0.187025 0.863047 0.352697 0.061 Uiso 1 1 calc R U . . .
C9 C 0.1922(6) 0.7401(5) 0.3140(5) 0.052(3) Uani 1 1 d . . . . .
H9 H 0.230262 0.751973 0.280713 0.063 Uiso 0.558(6) 1 calc R U P A 1
C14 C 0.0769(4) 0.8683(5) 0.4490(4) 0.0242(15) Uani 1 1 d . . . . .
C16 C 0.3388(9) 0.7813(10) 0.4904(9) 0.027(3) Uani 0.442(6) 1 d . U P A 2
C21 C 0.4375(13) 0.7602(17) 0.2324(13) 0.094(6) Uani 0.558(6) 1 d D U P A 1
H21A H 0.422493 0.798153 0.193108 0.140 Uiso 0.558(6) 1 calc R U P A 1
H21B H 0.394318 0.743231 0.260229 0.140 Uiso 0.558(6) 1 calc R U P A 1
H21C H 0.461004 0.709235 0.212314 0.140 Uiso 0.558(6) 1 calc R U P A 1
C17 C 0.2689(10) 0.7379(13) 0.5232(9) 0.036(4) Uani 0.442(6) 1 d . U P A 2
H17A H 0.261048 0.682366 0.500114 0.054 Uiso 0.442(6) 1 calc R U P A 2
H17B H 0.226186 0.774458 0.514944 0.054 Uiso 0.442(6) 1 calc R U P A 2
H17C H 0.275800 0.729681 0.575040 0.054 Uiso 0.442(6) 1 calc R U P A 2
C19 C 0.379(2) 0.907(2) 0.425(2) 0.113(11) Uani 0.442(6) 1 d D U P A 2
H19A H 0.423985 0.926649 0.449404 0.169 Uiso 0.442(6) 1 calc R U P A 2
H19B H 0.353375 0.956669 0.405179 0.169 Uiso 0.442(6) 1 calc R U P A 2
H19C H 0.392032 0.867684 0.386484 0.169 Uiso 0.442(6) 1 calc R U P A 2
C18 C 0.2820(14) 0.9235(14) 0.5118(15) 0.065(6) Uani 0.442(6) 1 d . U P A 2
H18A H 0.242047 0.891495 0.534305 0.098 Uiso 0.442(6) 1 calc R U P A 2
H18B H 0.261929 0.962777 0.475781 0.098 Uiso 0.442(6) 1 calc R U P A 2
H18C H 0.308311 0.956141 0.548602 0.098 Uiso 0.442(6) 1 calc R U P A 2
C22 C 0.5084(8) 0.7645(9) 0.3266(8) 0.042(3) Uani 0.558(6) 1 d D U P A 1
C23 C 0.5729(11) 0.8049(14) 0.3671(11) 0.073(5) Uani 0.558(6) 1 d D U P A 1
H23A H 0.590514 0.765133 0.403917 0.109 Uiso 0.558(6) 1 calc R U P A 1
H23B H 0.556793 0.858013 0.390061 0.109 Uiso 0.558(6) 1 calc R U P A 1
H23C H 0.612464 0.817329 0.333108 0.109 Uiso 0.558(6) 1 calc R U P A 1
C8 C 0.1653(4) 0.6565(5) 0.3176(4) 0.0240(14) Uani 1 1 d . . . . .
O9 O 0.2672(9) 0.7366(10) 0.2116(7) 0.056(4) Uani 0.442(6) 1 d . . P A 2
N3 N 0.2655(9) 0.7632(12) 0.2780(10) 0.049(5) Uani 0.442(6) 1 d . . P A 2
O10 O 0.3122(9) 0.8086(12) 0.3054(10) 0.074(5) Uani 0.442(6) 1 d . . P A 2
O11 O 0.1196(10) 0.4939(9) 0.3757(8) 0.080(4) Uani 0.558(6) 1 d . U P A 1
N4 N 0.0734(9) 0.5606(10) 0.3798(10) 0.070(3) Uani 0.558(6) 1 d D U P A 1
O12 O 0.0073(10) 0.5601(13) 0.3997(13) 0.116(5) Uani 0.558(6) 1 d D U P A 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Eu1 4.4797(7) 5_666 ?
Eu1 O1 2.498(5) . ?
Eu1 O2 2.483(5) . ?
Eu1 O3 2.379(5) 2_565 ?
Eu1 O4 2.335(5) 6_656 ?
Eu1 O5 2.392(5) 7_655 ?
Eu1 O6 2.366(4) 3_566 ?
Eu1 O7 2.375(5) . ?
Eu1 O8 2.404(5) . ?
Eu1 H8B 2.6386 . ?
O1 C1 1.245(8) . ?
O2 C1 1.261(8) . ?
O3 C11 1.262(8) . ?
O4 C11 1.244(8) . ?
O5 C14 1.242(9) . ?
O6 C14 1.257(8) . ?
O7 H7A 0.8500 . ?
O7 H7B 0.8500 . ?
O7 C22 1.279(15) . ?
O8 H8A 0.8509 . ?
O8 H8B 0.8505 . ?
O8 C16 1.231(16) . ?
N1 C16 1.30(2) . ?
N1 C19 1.425(18) . ?
N1 C18 1.43(3) . ?
N2 C20 1.442(17) . ?
N2 C21 1.526(17) . ?
N2 C22 1.084(18) . ?
C11 C5 1.506(9) . ?
C5 C6 1.387(9) . ?
C5 C4 1.391(10) . ?
C6 H6 0.9300 . ?
C6 C7 1.403(9) . ?
C7 C2 1.397(9) . ?
C7 C8 1.500(9) . ?
C2 C3 1.402(9) . ?
C2 C1 1.504(9) . ?
C3 H3 0.9300 . ?
C3 C4 1.380(10) . ?
C4 H4 0.9300 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C15 H15 0.9300 . ?
C15 C13 1.420(13) . ?
C15 C8 1.361(12) . ?
C15 N4 1.451(14) . ?
C13 H13 0.9300 . ?
C13 C12 1.357(12) . ?
C12 C10 1.343(11) . ?
C12 C14 1.513(10) . ?
C10 H10 0.9300 . ?
C10 C9 1.383(11) . ?
C9 H9 0.9300 . ?
C9 C8 1.372(11) . ?
C9 N3 1.508(18) . ?
C16 C17 1.54(2) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C22 C23 1.503(16) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
O9 N3 1.28(2) . ?
N3 O10 1.20(2) . ?
O11 N4 1.32(2) . ?
N4 O12 1.237(15) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Eu1 Eu1 H8B 113.4 5_666 . ?
O1 Eu1 Eu1 135.99(13) . 5_666 ?
O1 Eu1 H8B 91.7 . . ?
O2 Eu1 Eu1 121.44(13) . 5_666 ?
O2 Eu1 O1 52.22(16) . . ?
O2 Eu1 H8B 124.8 . . ?
O3 Eu1 Eu1 69.71(11) 2_565 5_666 ?
O3 Eu1 O1 85.02(17) 2_565 . ?
O3 Eu1 O2 130.06(18) 2_565 . ?
O3 Eu1 O5 73.52(17) 2_565 7_655 ?
O3 Eu1 O8 76.36(19) 2_565 . ?
O3 Eu1 H8B 73.6 2_565 . ?
O4 Eu1 Eu1 50.79(12) 6_656 5_666 ?
O4 Eu1 O1 134.58(16) 6_656 . ?
O4 Eu1 O2 85.03(17) 6_656 . ?
O4 Eu1 O3 120.40(16) 6_656 2_565 ?
O4 Eu1 O5 75.21(17) 6_656 7_655 ?
O4 Eu1 O6 76.93(17) 6_656 3_566 ?
O4 Eu1 O7 79.28(18) 6_656 . ?
O4 Eu1 O8 144.40(18) 6_656 . ?
O4 Eu1 H8B 129.6 6_656 . ?
O5 Eu1 Eu1 60.96(12) 7_655 5_666 ?
O5 Eu1 O1 77.87(18) 7_655 . ?
O5 Eu1 O2 73.23(18) 7_655 . ?
O5 Eu1 O8 139.7(2) 7_655 . ?
O5 Eu1 H8B 146.2 7_655 . ?
O6 Eu1 Eu1 61.97(12) 3_566 5_666 ?
O6 Eu1 O1 148.28(16) 3_566 . ?
O6 Eu1 O2 151.18(17) 3_566 . ?
O6 Eu1 O3 78.74(18) 3_566 2_565 ?
O6 Eu1 O5 122.08(17) 3_566 7_655 ?
O6 Eu1 O7 80.84(19) 3_566 . ?
O6 Eu1 O8 76.30(19) 3_566 . ?
O6 Eu1 H8B 57.6 3_566 . ?
O7 Eu1 Eu1 121.54(14) . 5_666 ?
O7 Eu1 O1 99.45(19) . . ?
O7 Eu1 O2 73.77(19) . . ?
O7 Eu1 O3 146.90(18) . 2_565 ?
O7 Eu1 O5 139.56(18) . 7_655 ?
O7 Eu1 O8 73.7(2) . . ?
O7 Eu1 H8B 73.5 . . ?
O8 Eu1 Eu1 129.91(15) . 5_666 ?
O8 Eu1 O1 73.46(18) . . ?
O8 Eu1 O2 108.5(2) . . ?
O8 Eu1 H8B 18.7 . . ?
C1 O1 Eu1 92.7(4) . . ?
C1 O2 Eu1 93.1(4) . . ?
C11 O3 Eu1 125.5(4) . 2_564 ?
C11 O4 Eu1 162.3(4) . 6_556 ?
C14 O5 Eu1 139.9(5) . 7_665 ?
C14 O6 Eu1 142.7(5) . 3_466 ?
Eu1 O7 H7A 127.8 . . ?
Eu1 O7 H7B 127.7 . . ?
H7A O7 H7B 104.5 . . ?
C22 O7 Eu1 151.1(8) . . ?
Eu1 O8 H8A 121.9 . . ?
Eu1 O8 H8B 96.5 . . ?
H8A O8 H8B 104.3 . . ?
C16 O8 Eu1 150.4(9) . . ?
C16 N1 C19 122(2) . . ?
C16 N1 C18 127(2) . . ?
C19 N1 C18 112(2) . . ?
C20 N2 C21 112.8(15) . . ?
C22 N2 C20 138.5(17) . . ?
C22 N2 C21 108.7(16) . . ?
O3 C11 C5 116.6(6) . . ?
O4 C11 O3 125.0(6) . . ?
O4 C11 C5 118.3(6) . . ?
C6 C5 C11 120.0(6) . . ?
C6 C5 C4 119.4(6) . . ?
C4 C5 C11 120.5(6) . . ?
C5 C6 H6 119.2 . . ?
C5 C6 C7 121.6(6) . . ?
C7 C6 H6 119.2 . . ?
C6 C7 C8 116.9(6) . . ?
C2 C7 C6 118.7(6) . . ?
C2 C7 C8 124.3(6) . . ?
C7 C2 C3 119.1(6) . . ?
C7 C2 C1 123.6(6) . . ?
C3 C2 C1 117.3(6) . . ?
C2 C3 H3 119.2 . . ?
C4 C3 C2 121.5(7) . . ?
C4 C3 H3 119.2 . . ?
C5 C4 H4 120.2 . . ?
C3 C4 C5 119.6(6) . . ?
C3 C4 H4 120.2 . . ?
O1 C1 O2 121.9(6) . . ?
O1 C1 C2 120.2(6) . . ?
O2 C1 C2 117.8(6) . . ?
N2 C20 H20A 109.5 . . ?
N2 C20 H20B 109.5 . . ?
N2 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C13 C15 H15 118.9 . . ?
C13 C15 N4 114.0(10) . . ?
C8 C15 H15 118.9 . . ?
C8 C15 C13 122.2(9) . . ?
C8 C15 N4 123.8(10) . . ?
C15 C13 H13 120.0 . . ?
C12 C13 C15 119.9(9) . . ?
C12 C13 H13 120.0 . . ?
C13 C12 C14 119.7(7) . . ?
C10 C12 C13 119.0(7) . . ?
C10 C12 C14 121.3(7) . . ?
C12 C10 H10 119.9 . . ?
C12 C10 C9 120.2(7) . . ?
C9 C10 H10 119.9 . . ?
C10 C9 H9 118.1 . . ?
C10 C9 N3 111.4(10) . . ?
C8 C9 C10 123.8(8) . . ?
C8 C9 H9 118.1 . . ?
C8 C9 N3 123.0(9) . . ?
O5 C14 O6 127.2(7) . . ?
O5 C14 C12 116.8(6) . . ?
O6 C14 C12 116.0(6) . . ?
O8 C16 N1 123.4(17) . . ?
O8 C16 C17 117.5(14) . . ?
N1 C16 C17 115.1(15) . . ?
N2 C21 H21A 109.5 . . ?
N2 C21 H21B 109.5 . . ?
N2 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
N1 C19 H19A 109.5 . . ?
N1 C19 H19B 109.5 . . ?
N1 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
N1 C18 H18A 109.5 . . ?
N1 C18 H18B 109.5 . . ?
N1 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
O7 C22 C23 117.5(13) . . ?
N2 C22 O7 133.9(16) . . ?
N2 C22 C23 108.3(16) . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C15 C8 C7 121.0(7) . . ?
C15 C8 C9 114.9(7) . . ?
C9 C8 C7 123.7(7) . . ?
O9 N3 C9 111.0(15) . . ?
O10 N3 C9 124.2(16) . . ?
O10 N3 O9 124.3(18) . . ?
O11 N4 C15 113.8(13) . . ?
O12 N4 C15 118.1(17) . . ?
O12 N4 O11 127.7(16) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1 C1 O2 -2.2(8) . . . . ?
Eu1 O1 C1 C2 175.9(6) . . . . ?
Eu1 O2 C1 O1 2.2(8) . . . . ?
Eu1 O2 C1 C2 -175.9(6) . . . . ?
Eu1 O3 C11 O4 17.8(9) 2_564 . . . ?
Eu1 O3 C11 C5 -162.8(4) 2_564 . . . ?
Eu1 O4 C11 O3 -56.3(18) 6_556 . . . ?
Eu1 O4 C11 C5 124.2(13) 6_556 . . . ?
Eu1 O5 C14 O6 -40.5(12) 7_665 . . . ?
Eu1 O5 C14 C12 141.0(6) 7_665 . . . ?
Eu1 O6 C14 O5 11.4(13) 3_466 . . . ?
Eu1 O6 C14 C12 -170.1(5) 3_466 . . . ?
Eu1 O7 C22 N2 -116(2) . . . . ?
Eu1 O7 C22 C23 71(2) . . . . ?
Eu1 O8 C16 N1 -168.7(13) . . . . ?
Eu1 O8 C16 C17 -12(3) . . . . ?
O3 C11 C5 C6 172.1(6) . . . . ?
O3 C11 C5 C4 -4.6(10) . . . . ?
O4 C11 C5 C6 -8.4(9) . . . . ?
O4 C11 C5 C4 174.9(7) . . . . ?
C11 C5 C6 C7 -178.2(6) . . . . ?
C11 C5 C4 C3 175.8(7) . . . . ?
C5 C6 C7 C2 3.1(10) . . . . ?
C5 C6 C7 C8 178.8(6) . . . . ?
C6 C5 C4 C3 -0.9(11) . . . . ?
C6 C7 C2 C3 -2.3(11) . . . . ?
C6 C7 C2 C1 178.2(6) . . . . ?
C6 C7 C8 C15 69.6(11) . . . . ?
C6 C7 C8 C9 -103.1(9) . . . . ?
C7 C2 C3 C4 0.0(12) . . . . ?
C7 C2 C1 O1 24.7(11) . . . . ?
C7 C2 C1 O2 -157.1(7) . . . . ?
C2 C7 C8 C15 -115.0(10) . . . . ?
C2 C7 C8 C9 72.3(11) . . . . ?
C2 C3 C4 C5 1.6(13) . . . . ?
C3 C2 C1 O1 -154.8(7) . . . . ?
C3 C2 C1 O2 23.3(10) . . . . ?
C4 C5 C6 C7 -1.5(11) . . . . ?
C1 C2 C3 C4 179.5(7) . . . . ?
C20 N2 C22 O7 177.4(16) . . . . ?
C20 N2 C22 C23 -9(3) . . . . ?
C15 C13 C12 C10 -1.9(17) . . . . ?
C15 C13 C12 C14 175.8(10) . . . . ?
C13 C15 C8 C7 -174.9(11) . . . . ?
C13 C15 C8 C9 -1.6(17) . . . . ?
C13 C15 N4 O11 -142.2(16) . . . . ?
C13 C15 N4 O12 32(3) . . . . ?
C13 C12 C10 C9 1.6(15) . . . . ?
C13 C12 C14 O5 -179.3(9) . . . . ?
C13 C12 C14 O6 2.1(11) . . . . ?
C12 C10 C9 C8 -1.3(17) . . . . ?
C12 C10 C9 N3 -166.6(11) . . . . ?
C10 C12 C14 O5 -1.6(11) . . . . ?
C10 C12 C14 O6 179.8(8) . . . . ?
C10 C9 C8 C7 174.3(9) . . . . ?
C10 C9 C8 C15 1.2(16) . . . . ?
C10 C9 N3 O9 -138.7(14) . . . . ?
C10 C9 N3 O10 34(2) . . . . ?
C14 C12 C10 C9 -176.2(9) . . . . ?
C21 N2 C22 O7 -4(3) . . . . ?
C21 N2 C22 C23 169.4(17) . . . . ?
C19 N1 C16 O8 -1(4) . . . . ?
C19 N1 C16 C17 -158(3) . . . . ?
C18 N1 C16 O8 -178.6(19) . . . . ?
C18 N1 C16 C17 25(3) . . . . ?
C8 C7 C2 C3 -177.6(7) . . . . ?
C8 C7 C2 C1 2.9(11) . . . . ?
C8 C15 C13 C12 2(2) . . . . ?
C8 C15 N4 O11 35(2) . . . . ?
C8 C15 N4 O12 -151.2(19) . . . . ?
C8 C9 N3 O9 55.8(19) . . . . ?
C8 C9 N3 O10 -131.9(19) . . . . ?
N3 C9 C8 C7 -22.0(16) . . . . ?
N3 C9 C8 C15 164.9(13) . . . . ?
N4 C15 C13 C12 179.4(13) . . . . ?
N4 C15 C8 C7 8.1(19) . . . . ?
N4 C15 C8 C9 -178.7(14) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
