# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_kgacup
_database_code_depnum_ccdc_archive 'CCDC 2068489'
loop_
_audit_author_name
_audit_author_address
'Jin-Xiao Mi'
;Xiamen University
China
;
_audit_update_record             
;
2021-03-07 deposited with the CCDC.	2021-04-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
#=============================================================================== 

_chemical_name_systematic        KGaCu(PO4)2
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'Cu Ga K O8 P2'
_chemical_formula_weight         362.30

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   4.977(3)
_cell_length_b                   14.025(8)
_cell_length_c                   9.376(5)
_cell_angle_alpha                90
_cell_angle_beta                 101.906(8)
_cell_angle_gamma                90
_cell_volume                     640.4(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    203(2)
_cell_measurement_reflns_used    3895
_cell_measurement_theta_min      2.653
_cell_measurement_theta_max      28.872

_exptl_crystal_description       prism
_exptl_crystal_colour            'light blue'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    3.758
_exptl_crystal_F_000             692
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.300
_exptl_absorpt_coefficient_mu    8.689
_shelx_estimated_absorpt_T_min   0.098
_shelx_estimated_absorpt_T_max   0.180
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.756
_exptl_absorpt_correction_T_max  0.879
_exptl_absorpt_process_details   'SMART (Bruker, 2001)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      203(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_measurement_device_type  'Bruker Diffraction CCD area-detector'
_diffrn_measurement_method       
'1265 images,φ=0, 90, 180 degree, and Δω=0.3 degree, χ= 54.74 degree'
_diffrn_detector_area_resol_mean .
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_interval_time  .
_diffrn_standards_decay_%        .
_diffrn_reflns_number            3895
_diffrn_reflns_av_unetI/netI     0.0572
_diffrn_reflns_av_R_equivalents  0.0424
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       7
_diffrn_reflns_theta_min         2.653
_diffrn_reflns_theta_max         28.872
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.910
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.910
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.910
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             1536
_reflns_number_gt                1355
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'SMART (Bruker, 2001)'
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_reduction        'SAINT (Bruker, 2001)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2015)'
_computing_molecular_graphics    
'DIAMOND (Brandenburg, 2011) and ATOMS (Dowty, 2004)'
_computing_publication_material  'SHELXL-2013 (Sheldrick, 2015)'


_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0261P)²+14.5723P]
 where P=(Fo²+2Fc²)/3
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         1536
_refine_ls_number_parameters     118
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0691
_refine_ls_R_factor_gt           0.0580
_refine_ls_wR_factor_ref         0.1280
_refine_ls_wR_factor_gt          0.1211
_refine_ls_goodness_of_fit_ref   1.179
_refine_ls_restrained_S_all      1.178
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ga1 Ga 0.25135(18) 0.62902(6) 0.38667(10) 0.0049(2) Uani 1 1 d . . . . .
Cu1 Cu 0.2429(2) 0.45452(8) 0.95873(13) 0.0129(3) Uani 1 1 d . . . . .
P1 P 0.2588(4) 0.67351(15) 0.0417(2) 0.0062(4) Uani 1 1 d . . . . .
P2 P 0.2829(4) 0.49163(15) 0.6717(2) 0.0045(4) Uani 1 1 d . . . . .
K K 0.1891(4) 0.17215(15) 0.8020(2) 0.0199(5) Uani 1 1 d . . . . .
O1 O 0.2298(12) 0.6903(4) 0.1973(6) 0.0073(11) Uani 1 1 d . . . . .
O2 O 0.4427(13) 0.3341(4) 0.9729(7) 0.0121(13) Uani 1 1 d . . . . .
O3 O 0.1240(12) 0.7425(4) 0.4491(7) 0.0093(12) Uani 1 1 d . . . . .
O4 O 0.0885(12) 0.5854(4) 0.9776(6) 0.0090(12) Uani 1 1 d . . . . .
O5 O 0.2737(13) 0.5848(4) 0.5898(7) 0.0111(12) Uani 1 1 d . . . . .
O6 O 0.4573(12) 0.5033(4) 0.8241(6) 0.0072(11) Uani 1 1 d . U . . .
O7 O 0.6157(12) 0.5925(4) 0.4076(7) 0.0084(12) Uani 1 1 d . . . . .
O8 O 0.0091(12) 0.5332(4) 0.3086(7) 0.0091(12) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ga1 O3 1.852(6) . ?
Ga1 O8 1.853(6) . ?
Ga1 O7 1.855(6) . ?
Ga1 O1 1.955(6) . ?
Ga1 O5 1.984(6) . ?
Ga1 K 3.645(3) 2_656 ?
Ga1 K 3.757(3) 3_566 ?
Cu1 O6 1.938(6) . ?
Cu1 O4 1.948(6) 3_567 ?
Cu1 O2 1.950(6) . ?
Cu1 O4 2.012(6) . ?
Cu1 O6 2.339(6) 3_667 ?
Cu1 P2 2.789(3) . ?
Cu1 Cu1 2.821(3) 3_667 ?
Cu1 Cu1 2.973(2) 3_567 ?
Cu1 K 3.734(3) 4_566 ?
P1 O1 1.514(6) . ?
P1 O2 1.524(7) 3_666 ?
P1 O3 1.534(6) 4_575 ?
P1 O4 1.548(6) 1_554 ?
P1 K 3.521(3) 2 ?
P1 K 3.567(3) 3_666 ?
P1 K 3.626(3) 3_566 ?
P2 O5 1.511(6) . ?
P2 O6 1.520(6) . ?
P2 O7 1.534(6) 3_666 ?
P2 O8 1.542(6) 3_566 ?
P2 K 3.497(3) 2_556 ?
P2 K 3.620(3) 2_656 ?
K O3 2.810(7) 3_566 ?
K O1 2.841(6) 3_566 ?
K O2 2.913(7) . ?
K O7 2.918(6) 2_646 ?
K O5 2.926(7) 2_646 ?
K O4 2.961(7) 2_546 ?
K O5 2.966(7) 2_546 ?
K O8 3.020(6) 4_566 ?
K O3 3.217(7) 2_546 ?
K O6 3.311(6) 2_646 ?
K P2 3.497(3) 2_546 ?
K P1 3.521(3) 2_545 ?
O1 K 2.841(6) 3_566 ?
O2 P1 1.524(7) 3_666 ?
O3 P1 1.534(6) 4_576 ?
O3 K 2.810(7) 3_566 ?
O3 K 3.217(7) 2_556 ?
O4 P1 1.548(6) 1_556 ?
O4 Cu1 1.948(6) 3_567 ?
O4 K 2.961(7) 2_556 ?
O5 K 2.926(7) 2_656 ?
O5 K 2.966(7) 2_556 ?
O6 Cu1 2.339(6) 3_667 ?
O6 K 3.311(6) 2_656 ?
O7 P2 1.534(6) 3_666 ?
O7 K 2.918(6) 2_656 ?
O8 P2 1.542(6) 3_566 ?
O8 K 3.021(6) 4_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Ga1 O8 120.7(3) . . ?
O3 Ga1 O7 126.5(3) . . ?
O8 Ga1 O7 112.6(3) . . ?
O3 Ga1 O1 87.2(3) . . ?
O8 Ga1 O1 92.9(3) . . ?
O7 Ga1 O1 95.0(3) . . ?
O3 Ga1 O5 85.4(3) . . ?
O8 Ga1 O5 93.2(3) . . ?
O7 Ga1 O5 87.3(3) . . ?
O1 Ga1 O5 172.1(3) . . ?
O3 Ga1 K 81.89(19) . 2_656 ?
O8 Ga1 K 139.8(2) . 2_656 ?
O7 Ga1 K 52.60(19) . 2_656 ?
O1 Ga1 K 122.95(19) . 2_656 ?
O5 Ga1 K 53.21(19) . 2_656 ?
O3 Ga1 K 46.1(2) . 3_566 ?
O8 Ga1 K 94.8(2) . 3_566 ?
O7 Ga1 K 135.83(19) . 3_566 ?
O1 Ga1 K 47.83(18) . 3_566 ?
O5 Ga1 K 126.57(18) . 3_566 ?
K Ga1 K 121.95(4) 2_656 3_566 ?
O6 Cu1 O4 156.3(3) . 3_567 ?
O6 Cu1 O2 90.5(3) . . ?
O4 Cu1 O2 100.5(3) 3_567 . ?
O6 Cu1 O4 90.4(2) . . ?
O4 Cu1 O4 82.7(3) 3_567 . ?
O2 Cu1 O4 169.3(3) . . ?
O6 Cu1 O6 98.0(2) . 3_667 ?
O4 Cu1 O6 103.6(2) 3_567 3_667 ?
O2 Cu1 O6 86.3(2) . 3_667 ?
O4 Cu1 O6 83.1(2) . 3_667 ?
O6 Cu1 P2 31.45(18) . . ?
O4 Cu1 P2 125.66(19) 3_567 . ?
O2 Cu1 P2 95.2(2) . . ?
O4 Cu1 P2 91.11(18) . . ?
O6 Cu1 P2 129.30(15) 3_667 . ?
O6 Cu1 Cu1 55.17(18) . 3_667 ?
O4 Cu1 Cu1 145.42(19) 3_567 3_667 ?
O2 Cu1 Cu1 87.2(2) . 3_667 ?
O4 Cu1 Cu1 84.52(18) . 3_667 ?
O6 Cu1 Cu1 42.86(14) 3_667 3_667 ?
P2 Cu1 Cu1 86.50(7) . 3_667 ?
O6 Cu1 Cu1 127.20(19) . 3_567 ?
O4 Cu1 Cu1 42.16(18) 3_567 3_567 ?
O2 Cu1 Cu1 141.7(2) . 3_567 ?
O4 Cu1 Cu1 40.53(17) . 3_567 ?
O6 Cu1 Cu1 94.12(15) 3_667 3_567 ?
P2 Cu1 Cu1 113.26(7) . 3_567 ?
Cu1 Cu1 Cu1 118.35(8) 3_667 3_567 ?
O6 Cu1 K 151.20(18) . 4_566 ?
O4 Cu1 K 51.93(18) 3_567 4_566 ?
O2 Cu1 K 69.9(2) . 4_566 ?
O4 Cu1 K 105.17(18) . 4_566 ?
O6 Cu1 K 61.06(15) 3_667 4_566 ?
P2 Cu1 K 162.34(7) . 4_566 ?
Cu1 Cu1 K 101.59(7) 3_667 4_566 ?
Cu1 Cu1 K 76.89(6) 3_567 4_566 ?
O1 P1 O2 112.7(4) . 3_666 ?
O1 P1 O3 108.0(3) . 4_575 ?
O2 P1 O3 108.9(3) 3_666 4_575 ?
O1 P1 O4 110.2(3) . 1_554 ?
O2 P1 O4 112.0(3) 3_666 1_554 ?
O3 P1 O4 104.6(3) 4_575 1_554 ?
O1 P1 K 135.6(3) . 2 ?
O2 P1 K 111.2(3) 3_666 2 ?
O3 P1 K 50.6(2) 4_575 2 ?
O4 P1 K 56.5(2) 1_554 2 ?
O1 P1 K 74.2(2) . 3_666 ?
O2 P1 K 52.9(2) 3_666 3_666 ?
O3 P1 K 88.6(2) 4_575 3_666 ?
O4 P1 K 163.3(3) 1_554 3_666 ?
K P1 K 131.91(8) 2 3_666 ?
O1 P1 K 47.9(2) . 3_566 ?
O2 P1 K 140.4(3) 3_666 3_566 ?
O3 P1 K 62.4(3) 4_575 3_566 ?
O4 P1 K 107.5(2) 1_554 3_566 ?
K P1 K 92.71(8) 2 3_566 ?
K P1 K 87.56(8) 3_666 3_566 ?
O5 P2 O6 109.6(4) . . ?
O5 P2 O7 113.4(4) . 3_666 ?
O6 P2 O7 110.9(3) . 3_666 ?
O5 P2 O8 109.0(4) . 3_566 ?
O6 P2 O8 106.3(3) . 3_566 ?
O7 P2 O8 107.3(3) 3_666 3_566 ?
O5 P2 Cu1 130.6(3) . . ?
O6 P2 Cu1 41.7(2) . . ?
O7 P2 Cu1 114.8(2) 3_666 . ?
O8 P2 Cu1 65.5(2) 3_566 . ?
O5 P2 K 57.3(2) . 2_556 ?
O6 P2 K 96.7(2) . 2_556 ?
O7 P2 K 152.1(2) 3_666 2_556 ?
O8 P2 K 59.4(2) 3_566 2_556 ?
Cu1 P2 K 83.35(7) . 2_556 ?
O5 P2 K 51.4(3) . 2_656 ?
O6 P2 K 66.1(2) . 2_656 ?
O7 P2 K 105.3(2) 3_666 2_656 ?
O8 P2 K 147.0(2) 3_566 2_656 ?
Cu1 P2 K 105.08(8) . 2_656 ?
K P2 K 88.71(8) 2_556 2_656 ?
O3 K O1 55.39(17) 3_566 3_566 ?
O3 K O2 103.35(19) 3_566 . ?
O1 K O2 72.79(18) 3_566 . ?
O3 K O7 164.92(19) 3_566 2_646 ?
O1 K O7 111.16(18) 3_566 2_646 ?
O2 K O7 76.25(18) . 2_646 ?
O3 K O5 141.11(19) 3_566 2_646 ?
O1 K O5 154.44(19) 3_566 2_646 ?
O2 K O5 82.81(18) . 2_646 ?
O7 K O5 53.97(17) 2_646 2_646 ?
O3 K O4 49.91(17) 3_566 2_546 ?
O1 K O4 94.14(18) 3_566 2_546 ?
O2 K O4 151.32(19) . 2_546 ?
O7 K O4 132.36(18) 2_646 2_546 ?
O5 K O4 111.16(18) 2_646 2_546 ?
O3 K O5 97.30(19) 3_566 2_546 ?
O1 K O5 70.00(18) 3_566 2_546 ?
O2 K O5 114.40(19) . 2_546 ?
O7 K O5 69.83(18) 2_646 2_546 ?
O5 K O5 115.3(2) 2_646 2_546 ?
O4 K O5 83.09(18) 2_546 2_546 ?
O3 K O8 107.92(18) 3_566 4_566 ?
O1 K O8 115.24(18) 3_566 4_566 ?
O2 K O8 146.01(19) . 4_566 ?
O7 K O8 70.07(17) 2_646 4_566 ?
O5 K O8 81.22(17) 2_646 4_566 ?
O4 K O8 62.62(17) 2_546 4_566 ?
O5 K O8 49.05(17) 2_546 4_566 ?
O3 K O3 102.08(16) 3_566 2_546 ?
O1 K O3 47.52(16) 3_566 2_546 ?
O2 K O3 65.27(17) . 2_546 ?
O7 K O3 63.79(17) 2_646 2_546 ?
O5 K O3 114.95(18) 2_646 2_546 ?
O4 K O3 124.12(18) 2_546 2_546 ?
O5 K O3 49.62(16) 2_546 2_546 ?
O8 K O3 95.02(17) 4_566 2_546 ?
O3 K O6 104.43(18) 3_566 2_646 ?
O1 K O6 158.54(17) 3_566 2_646 ?
O2 K O6 123.53(18) . 2_646 ?
O7 K O6 87.73(16) 2_646 2_646 ?
O5 K O6 46.31(16) 2_646 2_646 ?
O4 K O6 64.86(16) 2_546 2_646 ?
O5 K O6 109.51(17) 2_546 2_646 ?
O8 K O6 60.46(16) 4_566 2_646 ?
O3 K O6 148.34(16) 2_546 2_646 ?
O3 K P2 95.92(14) 3_566 2_546 ?
O1 K P2 89.29(14) 3_566 2_546 ?
O2 K P2 138.33(16) . 2_546 ?
O7 K P2 75.89(13) 2_646 2_546 ?
O5 K P2 104.56(14) 2_646 2_546 ?
O4 K P2 64.38(13) 2_546 2_546 ?
O5 K P2 25.38(12) 2_546 2_546 ?
O8 K P2 26.08(11) 4_566 2_546 ?
O3 K P2 74.80(12) 2_546 2_546 ?
O6 K P2 85.50(12) 2_646 2_546 ?
O3 K P1 24.95(13) 3_566 2_545 ?
O1 K P1 70.85(13) 3_566 2_545 ?
O2 K P1 128.31(15) . 2_545 ?
O7 K P1 151.94(14) 2_646 2_545 ?
O5 K P1 132.87(15) 2_646 2_545 ?
O4 K P1 25.83(12) 2_546 2_545 ?
O5 K P1 85.74(14) 2_546 2_545 ?
O8 K P1 83.64(13) 4_566 2_545 ?
O3 K P1 110.64(13) 2_546 2_545 ?
O6 K P1 87.69(12) 2_646 2_545 ?
P2 K P1 76.16(7) 2_546 2_545 ?
P1 O1 Ga1 143.9(4) . . ?
P1 O1 K 108.9(3) . 3_566 ?
Ga1 O1 K 101.5(2) . 3_566 ?
P1 O2 Cu1 123.2(4) 3_666 . ?
P1 O2 K 102.5(3) 3_666 . ?
Cu1 O2 K 118.7(3) . . ?
P1 O3 Ga1 134.5(4) 4_576 . ?
P1 O3 K 104.4(3) 4_576 3_566 ?
Ga1 O3 K 105.5(3) . 3_566 ?
P1 O3 K 92.6(3) 4_576 2_556 ?
Ga1 O3 K 102.4(2) . 2_556 ?
K O3 K 118.1(2) 3_566 2_556 ?
P1 O4 Cu1 122.7(4) 1_556 3_567 ?
P1 O4 Cu1 125.0(4) 1_556 . ?
Cu1 O4 Cu1 97.3(3) 3_567 . ?
P1 O4 K 97.7(3) 1_556 2_556 ?
Cu1 O4 K 96.9(2) 3_567 2_556 ?
Cu1 O4 K 114.4(2) . 2_556 ?
P2 O5 Ga1 138.4(4) . . ?
P2 O5 K 104.8(3) . 2_656 ?
Ga1 O5 K 93.9(2) . 2_656 ?
P2 O5 K 97.4(3) . 2_556 ?
Ga1 O5 K 107.8(2) . 2_556 ?
K O5 K 115.3(2) 2_656 2_556 ?
P2 O6 Cu1 106.9(3) . . ?
P2 O6 Cu1 169.7(4) . 3_667 ?
Cu1 O6 Cu1 82.0(2) . 3_667 ?
P2 O6 K 89.1(3) . 2_656 ?
Cu1 O6 K 152.8(3) . 2_656 ?
Cu1 O6 K 80.76(17) 3_667 2_656 ?
P2 O7 Ga1 125.0(4) 3_666 . ?
P2 O7 K 131.8(3) 3_666 2_656 ?
Ga1 O7 K 97.1(2) . 2_656 ?
P2 O8 Ga1 132.0(4) 3_566 . ?
P2 O8 K 94.5(3) 3_566 4_565 ?
Ga1 O8 K 121.9(3) . 4_565 ?

_refine_diff_density_max         1.433
_refine_diff_density_min         -1.761
_refine_diff_density_rms         0.299

_shelxl_version_number           2013-2



_chemical_compound_source        Synthetic
