# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_namiko232
_database_code_depnum_ccdc_archive 'CCDC 2071492'
loop_
_audit_author_name
_audit_author_address
'Namik Ozdemir'
;Ondokuz Mayis University
Turkey
;
_audit_update_record             
;
2021-03-18 deposited with the CCDC.	2021-09-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C22 H26 Ag Cl N2'
_chemical_formula_sum            'C22 H26 Ag Cl N2'
_chemical_formula_weight         461.77

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.3151(13)
_cell_length_b                   13.7666(11)
_cell_length_c                   13.7491(15)
_cell_angle_alpha                90
_cell_angle_beta                 95.702(9)
_cell_angle_gamma                90
_cell_volume                     2131.1(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    17201
_cell_measurement_theta_min      2.34
_cell_measurement_theta_max      28.10

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.439
_exptl_crystal_F_000             944
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.660
_exptl_crystal_size_mid          0.650
_exptl_crystal_size_min          0.320
_exptl_absorpt_coefficient_mu    1.079
_shelx_estimated_absorpt_T_min   0.536
_shelx_estimated_absorpt_T_max   0.724
_exptl_absorpt_correction_type   integration
_exptl_absorpt_correction_T_min  0.5094
_exptl_absorpt_correction_T_max  0.7142
_exptl_absorpt_process_details   'X-RED32 (Stoe & Cie, 2002)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_monochromator  'plane graphite'
_diffrn_radiation_collimation    '0.8 mm diameter, multiple pinhole'
_diffrn_source                   
'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 6.67
_diffrn_reflns_number            16396
_diffrn_reflns_av_unetI/netI     0.0545
_diffrn_reflns_av_R_equivalents  0.0624
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.454
_diffrn_reflns_theta_max         27.917
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             5041
_reflns_number_gt                3319
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'X-AREA (Stoe & Cie, 2002)'
_computing_cell_refinement       X-AREA
_computing_data_reduction        'X-RED32 (Stoe & Cie, 2002)'
_computing_structure_solution    'SUPERFLIP (Palatinus & Chapuis, 2007)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2015)'
_computing_molecular_graphics    'OLEX2 (Dolomanov et al., 2009)'
_computing_publication_material  
'OLEX2 (Dolomanov et al., 2009) and PLATON (Spek, 2009)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0362P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5041
_refine_ls_number_parameters     240
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0712
_refine_ls_R_factor_gt           0.0372
_refine_ls_wR_factor_ref         0.0816
_refine_ls_wR_factor_gt          0.0730
_refine_ls_goodness_of_fit_ref   0.925
_refine_ls_restrained_S_all      0.925
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.83104(2) 0.35061(2) 0.29918(2) 0.05949(9) Uani 1 1 d . . . . .
Cl1 Cl 0.80052(8) 0.30668(9) 0.13561(6) 0.0804(3) Uani 1 1 d . . . . .
N1 N 0.9700(2) 0.35133(19) 0.50138(16) 0.0507(5) Uani 1 1 d . . . . .
N2 N 0.8154(2) 0.44450(18) 0.50434(16) 0.0487(5) Uani 1 1 d . . . . .
C1 C 0.8727(3) 0.3851(2) 0.4455(2) 0.0508(7) Uani 1 1 d . . . . .
C2 C 0.9753(2) 0.3888(2) 0.59636(19) 0.0480(6) Uani 1 1 d . . . . .
C3 C 1.0547(3) 0.3747(2) 0.6789(2) 0.0525(7) Uani 1 1 d . . . . .
H3 H 1.119895 0.333809 0.677078 0.063 Uiso 1 1 calc R U . . .
C4 C 1.0341(3) 0.4234(2) 0.7645(2) 0.0541(7) Uani 1 1 d . . . . .
C5 C 1.1185(3) 0.4073(3) 0.8557(2) 0.0686(9) Uani 1 1 d . . . . .
H5A H 1.177691 0.360520 0.842294 0.103 Uiso 1 1 calc R U . . .
H5B H 1.074934 0.383656 0.907262 0.103 Uiso 1 1 calc R U . . .
H5C H 1.156403 0.467568 0.875315 0.103 Uiso 1 1 calc R U . . .
C6 C 0.9341(3) 0.4856(2) 0.7664(2) 0.0554(7) Uani 1 1 d . . . . .
C7 C 0.9099(3) 0.5357(3) 0.8602(2) 0.0776(11) Uani 1 1 d . . . . .
H7A H 0.839430 0.574561 0.848801 0.116 Uiso 1 1 calc R U . . .
H7B H 0.975996 0.576465 0.882107 0.116 Uiso 1 1 calc R U . . .
H7C H 0.898787 0.487772 0.909209 0.116 Uiso 1 1 calc R U . . .
C8 C 0.8552(3) 0.4986(2) 0.6829(2) 0.0537(7) Uani 1 1 d . . . . .
H8 H 0.789613 0.539166 0.683784 0.064 Uiso 1 1 calc R U . . .
C9 C 0.8771(2) 0.4495(2) 0.59826(19) 0.0473(6) Uani 1 1 d . . . . .
C10 C 1.0512(3) 0.2792(3) 0.4689(2) 0.0653(9) Uani 1 1 d . . . . .
H10A H 1.128420 0.288295 0.505239 0.078 Uiso 1 1 calc R U . . .
H10B H 1.060356 0.290639 0.400463 0.078 Uiso 1 1 calc R U . . .
C11 C 1.0140(4) 0.1768(3) 0.4806(3) 0.0890(13) Uani 1 1 d . . . . .
H11 H 1.070703 0.129761 0.471251 0.107 Uiso 1 1 calc R U . . .
C12 C 0.9132(5) 0.1453(4) 0.5020(3) 0.1072(15) Uani 1 1 d . . . . .
H12A H 0.852858 0.188904 0.512226 0.129 Uiso 1 1 calc R U . . .
H12B H 0.900395 0.078894 0.507315 0.129 Uiso 1 1 calc R U . . .
C13 C 0.7037(2) 0.4971(2) 0.4742(2) 0.0549(7) Uani 1 1 d . . . . .
H13A H 0.720361 0.548683 0.429405 0.066 Uiso 1 1 calc R U . . .
H13B H 0.675435 0.527081 0.531350 0.066 Uiso 1 1 calc R U . . .
C14 C 0.6056(2) 0.4328(2) 0.42497(19) 0.0482(6) Uani 1 1 d . . . . .
C15 C 0.5565(2) 0.3586(2) 0.4787(2) 0.0526(7) Uani 1 1 d . . . . .
C16 C 0.6025(3) 0.3367(3) 0.5834(2) 0.0711(10) Uani 1 1 d . . . . .
H16A H 0.549931 0.291842 0.610790 0.107 Uiso 1 1 calc R U . . .
H16B H 0.606401 0.395796 0.620708 0.107 Uiso 1 1 calc R U . . .
H16C H 0.680350 0.308666 0.585252 0.107 Uiso 1 1 calc R U . . .
C17 C 0.4622(3) 0.3030(3) 0.4354(2) 0.0597(8) Uani 1 1 d . . . . .
H17 H 0.429773 0.254479 0.471660 0.072 Uiso 1 1 calc R U . . .
C18 C 0.4159(3) 0.3187(2) 0.3392(2) 0.0608(8) Uani 1 1 d . . . . .
C19 C 0.3140(3) 0.2565(3) 0.2945(3) 0.0876(13) Uani 1 1 d . . . . .
H19A H 0.244193 0.296012 0.281753 0.131 Uiso 1 1 calc R U . . .
H19B H 0.298581 0.205488 0.339129 0.131 Uiso 1 1 calc R U . . .
H19C H 0.334559 0.228790 0.234422 0.131 Uiso 1 1 calc R U . . .
C20 C 0.4663(3) 0.3909(3) 0.2876(2) 0.0651(9) Uani 1 1 d . . . . .
H20 H 0.436622 0.401367 0.222900 0.078 Uiso 1 1 calc R U . . .
C21 C 0.5596(3) 0.4492(2) 0.3276(2) 0.0576(8) Uani 1 1 d . . . . .
C22 C 0.6079(4) 0.5270(3) 0.2644(3) 0.0849(12) Uani 1 1 d . . . . .
H22A H 0.590302 0.589903 0.289298 0.127 Uiso 1 1 calc R U . . .
H22B H 0.571648 0.520714 0.198509 0.127 Uiso 1 1 calc R U . . .
H22C H 0.692349 0.519528 0.265207 0.127 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C1 2.075(3) . ?
Ag1 Cl1 2.3212(8) . ?
N1 C1 1.360(3) . ?
N1 C2 1.400(3) . ?
N1 C10 1.454(4) . ?
N2 C1 1.360(4) . ?
N2 C9 1.407(3) . ?
N2 C13 1.479(3) . ?
C2 C3 1.390(4) . ?
C2 C9 1.392(4) . ?
C3 C4 1.394(4) . ?
C3 H3 0.9300 . ?
C4 C6 1.422(4) . ?
C4 C5 1.515(4) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 C8 1.394(4) . ?
C6 C7 1.511(4) . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C8 C9 1.389(4) . ?
C8 H8 0.9300 . ?
C10 C11 1.484(6) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.281(7) . ?
C11 H11 0.9300 . ?
C12 H12A 0.9300 . ?
C12 H12B 0.9300 . ?
C13 C14 1.525(4) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C21 1.406(4) . ?
C14 C15 1.407(4) . ?
C15 C17 1.397(4) . ?
C15 C16 1.512(4) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C18 1.391(5) . ?
C17 H17 0.9300 . ?
C18 C20 1.378(5) . ?
C18 C19 1.516(5) . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 C21 1.395(5) . ?
C20 H20 0.9300 . ?
C21 C22 1.515(5) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag1 Cl1 175.15(9) . . ?
C1 N1 C2 111.0(2) . . ?
C1 N1 C10 124.1(2) . . ?
C2 N1 C10 124.7(2) . . ?
C1 N2 C9 110.7(2) . . ?
C1 N2 C13 124.9(2) . . ?
C9 N2 C13 124.4(2) . . ?
N2 C1 N1 106.0(2) . . ?
N2 C1 Ag1 129.68(19) . . ?
N1 C1 Ag1 124.3(2) . . ?
C3 C2 C9 121.4(3) . . ?
C3 C2 N1 132.4(3) . . ?
C9 C2 N1 106.2(2) . . ?
C2 C3 C4 118.2(3) . . ?
C2 C3 H3 120.9 . . ?
C4 C3 H3 120.9 . . ?
C3 C4 C6 120.4(3) . . ?
C3 C4 C5 118.9(3) . . ?
C6 C4 C5 120.7(3) . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C8 C6 C4 120.5(3) . . ?
C8 C6 C7 119.3(3) . . ?
C4 C6 C7 120.2(3) . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C9 C8 C6 118.3(3) . . ?
C9 C8 H8 120.8 . . ?
C6 C8 H8 120.8 . . ?
C8 C9 C2 121.1(2) . . ?
C8 C9 N2 132.8(3) . . ?
C2 C9 N2 106.1(2) . . ?
N1 C10 C11 114.8(3) . . ?
N1 C10 H10A 108.6 . . ?
C11 C10 H10A 108.6 . . ?
N1 C10 H10B 108.6 . . ?
C11 C10 H10B 108.6 . . ?
H10A C10 H10B 107.5 . . ?
C12 C11 C10 128.0(4) . . ?
C12 C11 H11 116.0 . . ?
C10 C11 H11 116.0 . . ?
C11 C12 H12A 120.0 . . ?
C11 C12 H12B 120.0 . . ?
H12A C12 H12B 120.0 . . ?
N2 C13 C14 113.8(2) . . ?
N2 C13 H13A 108.8 . . ?
C14 C13 H13A 108.8 . . ?
N2 C13 H13B 108.8 . . ?
C14 C13 H13B 108.8 . . ?
H13A C13 H13B 107.7 . . ?
C21 C14 C15 119.2(3) . . ?
C21 C14 C13 120.9(3) . . ?
C15 C14 C13 119.8(2) . . ?
C17 C15 C14 119.9(3) . . ?
C17 C15 C16 118.2(3) . . ?
C14 C15 C16 121.9(3) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 C15 121.3(3) . . ?
C18 C17 H17 119.4 . . ?
C15 C17 H17 119.4 . . ?
C20 C18 C17 117.8(3) . . ?
C20 C18 C19 122.4(3) . . ?
C17 C18 C19 119.8(4) . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C18 C20 C21 123.2(3) . . ?
C18 C20 H20 118.4 . . ?
C21 C20 H20 118.4 . . ?
C20 C21 C14 118.6(3) . . ?
C20 C21 C22 118.8(3) . . ?
C14 C21 C22 122.6(3) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C9 N2 C1 N1 0.6(3) . . . . ?
C13 N2 C1 N1 -179.6(3) . . . . ?
C9 N2 C1 Ag1 -178.0(2) . . . . ?
C13 N2 C1 Ag1 1.7(4) . . . . ?
C2 N1 C1 N2 0.1(3) . . . . ?
C10 N1 C1 N2 174.9(3) . . . . ?
C2 N1 C1 Ag1 178.8(2) . . . . ?
C10 N1 C1 Ag1 -6.3(4) . . . . ?
C1 N1 C2 C3 178.6(3) . . . . ?
C10 N1 C2 C3 3.8(5) . . . . ?
C1 N1 C2 C9 -0.7(3) . . . . ?
C10 N1 C2 C9 -175.6(3) . . . . ?
C9 C2 C3 C4 -0.3(4) . . . . ?
N1 C2 C3 C4 -179.5(3) . . . . ?
C2 C3 C4 C6 0.1(4) . . . . ?
C2 C3 C4 C5 178.8(3) . . . . ?
C3 C4 C6 C8 0.0(5) . . . . ?
C5 C4 C6 C8 -178.6(3) . . . . ?
C3 C4 C6 C7 178.0(3) . . . . ?
C5 C4 C6 C7 -0.7(5) . . . . ?
C4 C6 C8 C9 0.0(5) . . . . ?
C7 C6 C8 C9 -178.0(3) . . . . ?
C6 C8 C9 C2 -0.2(5) . . . . ?
C6 C8 C9 N2 178.2(3) . . . . ?
C3 C2 C9 C8 0.3(5) . . . . ?
N1 C2 C9 C8 179.7(3) . . . . ?
C3 C2 C9 N2 -178.4(3) . . . . ?
N1 C2 C9 N2 1.0(3) . . . . ?
C1 N2 C9 C8 -179.6(3) . . . . ?
C13 N2 C9 C8 0.7(5) . . . . ?
C1 N2 C9 C2 -1.1(3) . . . . ?
C13 N2 C9 C2 179.2(3) . . . . ?
C1 N1 C10 C11 -84.5(4) . . . . ?
C2 N1 C10 C11 89.7(4) . . . . ?
N1 C10 C11 C12 10.9(6) . . . . ?
C1 N2 C13 C14 50.8(4) . . . . ?
C9 N2 C13 C14 -129.5(3) . . . . ?
N2 C13 C14 C21 -117.6(3) . . . . ?
N2 C13 C14 C15 65.2(4) . . . . ?
C21 C14 C15 C17 -0.7(4) . . . . ?
C13 C14 C15 C17 176.5(3) . . . . ?
C21 C14 C15 C16 179.6(3) . . . . ?
C13 C14 C15 C16 -3.3(4) . . . . ?
C14 C15 C17 C18 0.6(4) . . . . ?
C16 C15 C17 C18 -179.6(3) . . . . ?
C15 C17 C18 C20 0.2(5) . . . . ?
C15 C17 C18 C19 179.7(3) . . . . ?
C17 C18 C20 C21 -0.9(5) . . . . ?
C19 C18 C20 C21 179.6(3) . . . . ?
C18 C20 C21 C14 0.8(5) . . . . ?
C18 C20 C21 C22 -179.7(3) . . . . ?
C15 C14 C21 C20 0.0(4) . . . . ?
C13 C14 C21 C20 -177.2(3) . . . . ?
C15 C14 C21 C22 -179.5(3) . . . . ?
C13 C14 C21 C22 3.4(5) . . . . ?

_refine_diff_density_max         0.489
_refine_diff_density_min         -0.335
_refine_diff_density_rms         0.055



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_namiko230
_database_code_depnum_ccdc_archive 'CCDC 2071494'
loop_
_audit_author_name
_audit_author_address
'Namik Ozdemir'
;Ondokuz Mayis University
Turkey
;
_audit_update_record             
;
2021-03-18 deposited with the CCDC.	2021-09-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C24 H30 Ag Cl N2'
_chemical_formula_sum            'C24 H30 Ag Cl N2'
_chemical_formula_weight         489.82

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.1956(9)
_cell_length_b                   15.9222(9)
_cell_length_c                   12.9237(10)
_cell_angle_alpha                90
_cell_angle_beta                 99.791(6)
_cell_angle_gamma                90
_cell_volume                     2270.2(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    18377
_cell_measurement_theta_min      2.24
_cell_measurement_theta_max      28.08

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.433
_exptl_crystal_F_000             1008
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.780
_exptl_crystal_size_mid          0.670
_exptl_crystal_size_min          0.410
_exptl_absorpt_coefficient_mu    1.017
_shelx_estimated_absorpt_T_min   0.504
_shelx_estimated_absorpt_T_max   0.681
_exptl_absorpt_correction_type   integration
_exptl_absorpt_correction_T_min  0.5673
_exptl_absorpt_correction_T_max  0.7017
_exptl_absorpt_process_details   'X-RED32 (Stoe & Cie, 2002)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_monochromator  'plane graphite'
_diffrn_radiation_collimation    '0.8 mm diameter, multiple pinhole'
_diffrn_source                   
'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 6.67
_diffrn_reflns_number            16149
_diffrn_reflns_av_unetI/netI     0.0319
_diffrn_reflns_av_R_equivalents  0.0355
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         2.246
_diffrn_reflns_theta_max         27.783
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             5310
_reflns_number_gt                4037
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'X-AREA (Stoe & Cie, 2002)'
_computing_cell_refinement       X-AREA
_computing_data_reduction        'X-RED32 (Stoe & Cie, 2002)'
_computing_structure_solution    'SUPERFLIP (Palatinus & Chapuis, 2007)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2015)'
_computing_molecular_graphics    'OLEX2 (Dolomanov et al., 2009)'
_computing_publication_material  
'OLEX2 (Dolomanov et al., 2009) and PLATON (Spek, 2009)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0477P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5310
_refine_ls_number_parameters     274
_refine_ls_number_restraints     58
_refine_ls_R_factor_all          0.0512
_refine_ls_R_factor_gt           0.0335
_refine_ls_wR_factor_ref         0.0847
_refine_ls_wR_factor_gt          0.0794
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_restrained_S_all      1.023
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.80564(2) 0.28847(2) 0.34035(2) 0.05352(8) Uani 1 1 d . . . . .
Cl1 Cl 0.80182(7) 0.14387(4) 0.30337(6) 0.06523(18) Uani 1 1 d . . . . .
N1 N 0.90444(18) 0.47123(12) 0.34240(15) 0.0468(4) Uani 1 1 d D . . . .
N2 N 0.78183(17) 0.45828(12) 0.45392(15) 0.0439(4) Uani 1 1 d . . . . .
C1 C 0.8311(2) 0.41568(15) 0.38059(19) 0.0476(5) Uani 1 1 d . . . . .
C2 C 0.9027(2) 0.54942(14) 0.39063(17) 0.0425(5) Uani 1 1 d . . . . .
C3 C 0.9594(2) 0.62554(15) 0.37639(18) 0.0467(5) Uani 1 1 d . . . . .
H3 H 1.010258 0.630907 0.326843 0.056 Uiso 1 1 calc R U . . .
C4 C 0.9376(2) 0.69303(15) 0.4386(2) 0.0468(5) Uani 1 1 d . . . . .
C5 C 0.9933(3) 0.77753(16) 0.4208(3) 0.0612(7) Uani 1 1 d . . . . .
H5A H 1.042182 0.772318 0.366895 0.092 Uiso 1 1 calc R U . . .
H5B H 1.043007 0.795935 0.484775 0.092 Uiso 1 1 calc R U . . .
H5C H 0.930111 0.817804 0.399587 0.092 Uiso 1 1 calc R U . . .
C6 C 0.8617(2) 0.68425(16) 0.51478(19) 0.0472(5) Uani 1 1 d . . . . .
C7 C 0.8396(3) 0.75797(19) 0.5833(3) 0.0690(8) Uani 1 1 d . . . . .
H7A H 0.915252 0.776323 0.623318 0.104 Uiso 1 1 calc R U . . .
H7B H 0.786089 0.741075 0.630187 0.104 Uiso 1 1 calc R U . . .
H7C H 0.803368 0.803195 0.539785 0.104 Uiso 1 1 calc R U . . .
C8 C 0.8042(2) 0.60824(15) 0.52650(19) 0.0460(5) Uani 1 1 d . . . . .
H8 H 0.752672 0.602639 0.575460 0.055 Uiso 1 1 calc R U . . .
C9 C 0.8251(2) 0.54094(14) 0.46368(17) 0.0421(5) Uani 1 1 d . . . . .
C10 C 0.9696(3) 0.45420(18) 0.2558(2) 0.0624(7) Uani 1 1 d D U . . .
H10A H 0.987207 0.394591 0.254689 0.075 Uiso 0.622(7) 1 calc R U P A 1
H10B H 1.046300 0.483922 0.268552 0.075 Uiso 0.622(7) 1 calc R U P A 1
H10C H 1.002841 0.397855 0.263471 0.075 Uiso 0.378(7) 1 calc R U P A 2
H10D H 1.036770 0.493178 0.259605 0.075 Uiso 0.378(7) 1 calc R U P A 2
C11A C 0.9026(6) 0.4790(5) 0.1516(3) 0.0800(13) Uani 0.622(7) 1 d D U P A 1
H11A H 0.951304 0.488397 0.101193 0.096 Uiso 0.622(7) 1 calc R U P A 1
C12A C 0.7954(6) 0.4893(4) 0.1208(5) 0.0972(17) Uani 0.622(7) 1 d D U P A 1
H12A H 0.740318 0.481246 0.166230 0.117 Uiso 0.622(7) 1 calc R U P A 1
H12B H 0.768004 0.505252 0.051558 0.117 Uiso 0.622(7) 1 calc R U P A 1
C11B C 0.8913(7) 0.4619(7) 0.1509(3) 0.0771(15) Uani 0.378(7) 1 d D U P A 2
H11B H 0.826347 0.424688 0.138864 0.093 Uiso 0.378(7) 1 calc R U P A 2
C12B C 0.8992(10) 0.5091(6) 0.0789(5) 0.092(2) Uani 0.378(7) 1 d D U P A 2
H12C H 0.961886 0.548122 0.085160 0.111 Uiso 0.378(7) 1 calc R U P A 2
H12D H 0.842622 0.506401 0.017319 0.111 Uiso 0.378(7) 1 calc R U P A 2
C13 C 0.6905(2) 0.42479(17) 0.51324(19) 0.0517(6) Uani 1 1 d . . . . .
H13A H 0.651852 0.471068 0.543526 0.062 Uiso 1 1 calc R U . . .
H13B H 0.730470 0.389872 0.570298 0.062 Uiso 1 1 calc R U . . .
C14 C 0.5944(2) 0.37321(16) 0.44315(18) 0.0458(5) Uani 1 1 d . . . . .
C15 C 0.5232(2) 0.41348(16) 0.35640(19) 0.0495(6) Uani 1 1 d . . . . .
C16 C 0.5354(3) 0.50740(18) 0.3403(2) 0.0637(7) Uani 1 1 d . . . . .
H16A H 0.592293 0.530383 0.397253 0.096 Uiso 1 1 d R U . . .
H16B H 0.563665 0.517333 0.275313 0.096 Uiso 1 1 d R U . . .
H16C H 0.457940 0.533829 0.338194 0.096 Uiso 1 1 d R U . . .
C17 C 0.4449(2) 0.36570(19) 0.2835(2) 0.0574(6) Uani 1 1 d . . . . .
C18 C 0.3702(4) 0.4091(3) 0.1884(3) 0.0935(12) Uani 1 1 d . . . . .
H18A H 0.387696 0.468163 0.190976 0.140 Uiso 1 1 d R U . . .
H18B H 0.390462 0.385688 0.125174 0.140 Uiso 1 1 d R U . . .
H18C H 0.285441 0.400667 0.189303 0.140 Uiso 1 1 d R U . . .
C19 C 0.4373(2) 0.27854(19) 0.2966(2) 0.0600(7) Uani 1 1 d . . . . .
C20 C 0.3619(4) 0.2259(2) 0.2107(3) 0.0914(12) Uani 1 1 d . . . . .
H20A H 0.324327 0.261978 0.155083 0.137 Uiso 1 1 d R U . . .
H20B H 0.413477 0.186336 0.183623 0.137 Uiso 1 1 d R U . . .
H20C H 0.300439 0.196178 0.239466 0.137 Uiso 1 1 d R U . . .
C21 C 0.5010(2) 0.23979(17) 0.3864(2) 0.0550(6) Uani 1 1 d . . . . .
C22 C 0.4900(3) 0.14537(19) 0.4033(3) 0.0799(9) Uani 1 1 d . . . . .
H22A H 0.435616 0.121416 0.345320 0.120 Uiso 1 1 d R U . . .
H22B H 0.568272 0.119633 0.408281 0.120 Uiso 1 1 d R U . . .
H22C H 0.458970 0.135753 0.467102 0.120 Uiso 1 1 d R U . . .
C23 C 0.5807(2) 0.28720(16) 0.4604(2) 0.0505(6) Uani 1 1 d . . . . .
C24 C 0.6505(3) 0.2428(2) 0.5562(3) 0.0729(8) Uani 1 1 d . . . . .
H24A H 0.628874 0.184453 0.554224 0.109 Uiso 1 1 d R U . . .
H24B H 0.735867 0.248225 0.555881 0.109 Uiso 1 1 d R U . . .
H24C H 0.631200 0.267947 0.618824 0.109 Uiso 1 1 d R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C1 2.099(2) . ?
Ag1 Cl1 2.3503(7) . ?
N1 C1 1.356(3) . ?
N1 C2 1.394(3) . ?
N1 C10 1.462(3) . ?
N2 C1 1.357(3) . ?
N2 C9 1.401(3) . ?
N2 C13 1.478(3) . ?
C2 C9 1.394(3) . ?
C2 C3 1.395(3) . ?
C3 C4 1.389(3) . ?
C3 H3 0.9300 . ?
C4 C6 1.412(4) . ?
C4 C5 1.517(3) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 C8 1.391(3) . ?
C6 C7 1.516(4) . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C8 C9 1.388(3) . ?
C8 H8 0.9300 . ?
C10 C11A 1.479(5) . ?
C10 C11B 1.488(5) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C10 H10C 0.9700 . ?
C10 H10D 0.9700 . ?
C11A C12A 1.210(7) . ?
C11A H11A 0.9300 . ?
C12A H12A 0.9300 . ?
C12A H12B 0.9300 . ?
C11B C12B 1.212(8) . ?
C11B H11B 0.9300 . ?
C12B H12C 0.9300 . ?
C12B H12D 0.9300 . ?
C13 C14 1.524(3) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C23 1.400(3) . ?
C14 C15 1.414(3) . ?
C15 C17 1.398(4) . ?
C15 C16 1.519(4) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C19 1.402(4) . ?
C17 C18 1.529(4) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 C21 1.398(4) . ?
C19 C20 1.527(4) . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 C23 1.411(3) . ?
C21 C22 1.527(4) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 C24 1.521(4) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag1 Cl1 173.15(7) . . ?
C1 N1 C2 111.37(19) . . ?
C1 N1 C10 124.7(2) . . ?
C2 N1 C10 123.7(2) . . ?
C1 N2 C9 110.9(2) . . ?
C1 N2 C13 125.6(2) . . ?
C9 N2 C13 123.47(19) . . ?
N1 C1 N2 105.8(2) . . ?
N1 C1 Ag1 127.20(17) . . ?
N2 C1 Ag1 126.97(18) . . ?
C9 C2 N1 105.92(19) . . ?
C9 C2 C3 121.6(2) . . ?
N1 C2 C3 132.5(2) . . ?
C4 C3 C2 117.8(2) . . ?
C4 C3 H3 121.1 . . ?
C2 C3 H3 121.1 . . ?
C3 C4 C6 120.9(2) . . ?
C3 C4 C5 118.7(2) . . ?
C6 C4 C5 120.4(2) . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C8 C6 C4 120.4(2) . . ?
C8 C6 C7 119.0(2) . . ?
C4 C6 C7 120.5(2) . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C9 C8 C6 118.7(2) . . ?
C9 C8 H8 120.6 . . ?
C6 C8 H8 120.6 . . ?
C8 C9 C2 120.5(2) . . ?
C8 C9 N2 133.5(2) . . ?
C2 C9 N2 106.01(19) . . ?
N1 C10 C11A 113.9(3) . . ?
N1 C10 C11B 112.9(3) . . ?
N1 C10 H10A 108.8 . . ?
C11A C10 H10A 108.8 . . ?
N1 C10 H10B 108.8 . . ?
C11A C10 H10B 108.8 . . ?
H10A C10 H10B 107.7 . . ?
N1 C10 H10C 109.0 . . ?
C11B C10 H10C 109.0 . . ?
N1 C10 H10D 109.0 . . ?
C11B C10 H10D 109.0 . . ?
H10C C10 H10D 107.8 . . ?
C12A C11A C10 131.1(6) . . ?
C12A C11A H11A 114.5 . . ?
C10 C11A H11A 114.5 . . ?
C11A C12A H12A 120.0 . . ?
C11A C12A H12B 120.0 . . ?
H12A C12A H12B 120.0 . . ?
C12B C11B C10 129.9(8) . . ?
C12B C11B H11B 115.0 . . ?
C10 C11B H11B 115.0 . . ?
C11B C12B H12C 120.0 . . ?
C11B C12B H12D 120.0 . . ?
H12C C12B H12D 120.0 . . ?
N2 C13 C14 111.54(19) . . ?
N2 C13 H13A 109.3 . . ?
C14 C13 H13A 109.3 . . ?
N2 C13 H13B 109.3 . . ?
C14 C13 H13B 109.3 . . ?
H13A C13 H13B 108.0 . . ?
C23 C14 C15 120.5(2) . . ?
C23 C14 C13 121.2(2) . . ?
C15 C14 C13 118.2(2) . . ?
C17 C15 C14 119.5(2) . . ?
C17 C15 C16 120.3(2) . . ?
C14 C15 C16 120.2(2) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.4 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 C19 120.0(2) . . ?
C15 C17 C18 119.4(3) . . ?
C19 C17 C18 120.6(3) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.4 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C21 C19 C17 120.3(2) . . ?
C21 C19 C20 120.1(3) . . ?
C17 C19 C20 119.5(3) . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.4 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C21 C23 120.1(2) . . ?
C19 C21 C22 120.7(3) . . ?
C23 C21 C22 119.2(3) . . ?
C21 C22 H22A 109.6 . . ?
C21 C22 H22B 109.6 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.2 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C14 C23 C21 119.3(2) . . ?
C14 C23 C24 121.9(2) . . ?
C21 C23 C24 118.8(2) . . ?
C23 C24 H24A 109.6 . . ?
C23 C24 H24B 109.2 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.6 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 N1 C1 N2 0.0(3) . . . . ?
C10 N1 C1 N2 -175.3(2) . . . . ?
C2 N1 C1 Ag1 -177.25(17) . . . . ?
C10 N1 C1 Ag1 7.5(3) . . . . ?
C9 N2 C1 N1 -0.8(3) . . . . ?
C13 N2 C1 N1 176.6(2) . . . . ?
C9 N2 C1 Ag1 176.37(16) . . . . ?
C13 N2 C1 Ag1 -6.2(3) . . . . ?
C1 N1 C2 C9 0.9(3) . . . . ?
C10 N1 C2 C9 176.2(2) . . . . ?
C1 N1 C2 C3 -178.2(3) . . . . ?
C10 N1 C2 C3 -2.9(4) . . . . ?
C9 C2 C3 C4 0.8(3) . . . . ?
N1 C2 C3 C4 179.8(2) . . . . ?
C2 C3 C4 C6 0.9(3) . . . . ?
C2 C3 C4 C5 -177.0(2) . . . . ?
C3 C4 C6 C8 -2.1(4) . . . . ?
C5 C4 C6 C8 175.8(2) . . . . ?
C3 C4 C6 C7 179.2(2) . . . . ?
C5 C4 C6 C7 -2.9(4) . . . . ?
C4 C6 C8 C9 1.5(4) . . . . ?
C7 C6 C8 C9 -179.8(2) . . . . ?
C6 C8 C9 C2 0.2(3) . . . . ?
C6 C8 C9 N2 -178.8(2) . . . . ?
N1 C2 C9 C8 179.4(2) . . . . ?
C3 C2 C9 C8 -1.4(3) . . . . ?
N1 C2 C9 N2 -1.3(2) . . . . ?
C3 C2 C9 N2 177.8(2) . . . . ?
C1 N2 C9 C8 -179.5(3) . . . . ?
C13 N2 C9 C8 3.0(4) . . . . ?
C1 N2 C9 C2 1.4(3) . . . . ?
C13 N2 C9 C2 -176.1(2) . . . . ?
C1 N1 C10 C11A 92.3(5) . . . . ?
C2 N1 C10 C11A -82.4(5) . . . . ?
C1 N1 C10 C11B 79.7(6) . . . . ?
C2 N1 C10 C11B -95.0(6) . . . . ?
N1 C10 C11A C12A -22.7(11) . . . . ?
N1 C10 C11B C12B 118.3(10) . . . . ?
C1 N2 C13 C14 -41.3(3) . . . . ?
C9 N2 C13 C14 135.8(2) . . . . ?
N2 C13 C14 C23 116.0(2) . . . . ?
N2 C13 C14 C15 -60.6(3) . . . . ?
C23 C14 C15 C17 -4.5(4) . . . . ?
C13 C14 C15 C17 172.2(2) . . . . ?
C23 C14 C15 C16 177.9(2) . . . . ?
C13 C14 C15 C16 -5.5(3) . . . . ?
C14 C15 C17 C19 0.0(4) . . . . ?
C16 C15 C17 C19 177.7(3) . . . . ?
C14 C15 C17 C18 -178.7(3) . . . . ?
C16 C15 C17 C18 -1.0(4) . . . . ?
C15 C17 C19 C21 4.7(4) . . . . ?
C18 C17 C19 C21 -176.6(3) . . . . ?
C15 C17 C19 C20 -173.6(3) . . . . ?
C18 C17 C19 C20 5.1(4) . . . . ?
C17 C19 C21 C23 -5.0(4) . . . . ?
C20 C19 C21 C23 173.2(3) . . . . ?
C17 C19 C21 C22 177.9(3) . . . . ?
C20 C19 C21 C22 -3.9(4) . . . . ?
C15 C14 C23 C21 4.2(4) . . . . ?
C13 C14 C23 C21 -172.3(2) . . . . ?
C15 C14 C23 C24 -176.5(3) . . . . ?
C13 C14 C23 C24 7.0(4) . . . . ?
C19 C21 C23 C14 0.5(4) . . . . ?
C22 C21 C23 C14 177.7(3) . . . . ?
C19 C21 C23 C24 -178.8(3) . . . . ?
C22 C21 C23 C24 -1.7(4) . . . . ?

_refine_diff_density_max         0.289
_refine_diff_density_min         -0.339
_refine_diff_density_rms         0.056



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_namiko231
_database_code_depnum_ccdc_archive 'CCDC 2071493'
loop_
_audit_author_name
_audit_author_address
'Namik Ozdemir'
;Ondokuz Mayis University
Turkey
;
_audit_update_record             
;
2021-03-18 deposited with the CCDC.	2021-09-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C23 H28 Ag Cl N2'
_chemical_formula_sum            'C23 H28 Ag Cl N2'
_chemical_formula_weight         475.79

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.1252(6)
_cell_length_b                   10.6418(6)
_cell_length_c                   11.6214(7)
_cell_angle_alpha                90.879(5)
_cell_angle_beta                 104.275(5)
_cell_angle_gamma                115.012(4)
_cell_volume                     1089.49(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    38289
_cell_measurement_theta_min      2.35
_cell_measurement_theta_max      28.16

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.450
_exptl_crystal_F_000             488
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.780
_exptl_crystal_size_mid          0.270
_exptl_crystal_size_min          0.230
_exptl_absorpt_coefficient_mu    1.057
_shelx_estimated_absorpt_T_min   0.493
_shelx_estimated_absorpt_T_max   0.793
_exptl_absorpt_correction_type   integration
_exptl_absorpt_correction_T_min  0.5265
_exptl_absorpt_correction_T_max  0.8276
_exptl_absorpt_process_details   'X-RED32 (Stoe & Cie, 2002)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_monochromator  'plane graphite'
_diffrn_radiation_collimation    '0.8 mm diameter, multiple pinhole'
_diffrn_source                   
'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 6.67
_diffrn_reflns_number            23139
_diffrn_reflns_av_unetI/netI     0.0271
_diffrn_reflns_av_R_equivalents  0.0488
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         2.356
_diffrn_reflns_theta_max         27.867
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             5131
_reflns_number_gt                4559
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'X-AREA (Stoe & Cie, 2002)'
_computing_cell_refinement       X-AREA
_computing_data_reduction        'X-RED32 (Stoe & Cie, 2002)'
_computing_structure_solution    'SUPERFLIP (Palatinus & Chapuis, 2007)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2015)'
_computing_molecular_graphics    'OLEX2 (Dolomanov et al., 2009)'
_computing_publication_material  
'OLEX2 (Dolomanov et al., 2009) and PLATON (Spek, 2009)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0337P)²+0.3007P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5131
_refine_ls_number_parameters     246
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0319
_refine_ls_R_factor_gt           0.0267
_refine_ls_wR_factor_ref         0.0725
_refine_ls_wR_factor_gt          0.0697
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_restrained_S_all      1.045
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.48000(2) 0.81032(2) 0.33798(2) 0.05349(7) Uani 1 1 d . . . . .
Cl1 Cl 0.35536(8) 0.94841(7) 0.27487(6) 0.06740(15) Uani 1 1 d . . . . .
N1 N 0.67850(19) 0.68982(16) 0.50108(14) 0.0442(3) Uani 1 1 d . . . . .
N2 N 0.56180(18) 0.56161(16) 0.32779(14) 0.0425(3) Uani 1 1 d . . . . .
C1 C 0.5823(2) 0.6793(2) 0.39265(18) 0.0450(4) Uani 1 1 d . . . . .
C2 C 0.7195(2) 0.57947(18) 0.50553(16) 0.0414(4) Uani 1 1 d . . . . .
C3 C 0.8190(2) 0.5478(2) 0.59298(17) 0.0454(4) Uani 1 1 d . . . . .
H3 H 0.872659 0.605517 0.665882 0.054 Uiso 1 1 calc R U . . .
C4 C 0.8358(2) 0.4282(2) 0.56838(18) 0.0458(4) Uani 1 1 d . . . . .
C5 C 0.9489(3) 0.3952(3) 0.6587(2) 0.0581(5) Uani 1 1 d . . . . .
H5A H 0.896929 0.305629 0.682880 0.087 Uiso 1 1 calc R U . . .
H5B H 0.997317 0.465895 0.727453 0.087 Uiso 1 1 calc R U . . .
H5C H 1.024025 0.393174 0.622932 0.087 Uiso 1 1 calc R U . . .
C6 C 0.7518(2) 0.33947(19) 0.45776(18) 0.0451(4) Uani 1 1 d . . . . .
C7 C 0.7682(3) 0.2072(2) 0.4325(2) 0.0619(5) Uani 1 1 d . . . . .
H7A H 0.737958 0.146337 0.490882 0.093 Uiso 1 1 calc R U . . .
H7B H 0.872174 0.231173 0.436818 0.093 Uiso 1 1 calc R U . . .
H7C H 0.704978 0.160363 0.353834 0.093 Uiso 1 1 calc R U . . .
C8 C 0.6543(2) 0.37254(19) 0.37041(18) 0.0443(4) Uani 1 1 d . . . . .
H8 H 0.599139 0.314633 0.297762 0.053 Uiso 1 1 calc R U . . .
C9 C 0.6419(2) 0.49576(18) 0.39528(16) 0.0401(4) Uani 1 1 d . . . . .
C10 C 0.7343(3) 0.8032(2) 0.6000(2) 0.0547(5) Uani 1 1 d . . . . .
H10A H 0.728809 0.763556 0.674260 0.066 Uiso 1 1 calc R U . . .
H10B H 0.669338 0.850387 0.586181 0.066 Uiso 1 1 calc R U . . .
C11 C 0.8933(3) 0.9069(3) 0.6123(3) 0.0796(8) Uani 1 1 d . . . . .
H11 H 0.910057 0.948582 0.544171 0.095 Uiso 1 1 calc R U . . .
C12 C 1.0063(5) 0.9460(5) 0.6995(4) 0.1251(15) Uani 1 1 d . . . . .
H12A H 0.998070 0.908826 0.770700 0.150 Uiso 1 1 calc R U . . .
H12B H 1.099662 1.012554 0.693948 0.150 Uiso 1 1 calc R U . . .
C13 C 0.4679(2) 0.5091(2) 0.20255(18) 0.0502(4) Uani 1 1 d . . . . .
H13A H 0.361988 0.463141 0.201700 0.060 Uiso 1 1 calc R U . . .
H13B H 0.492446 0.439358 0.170817 0.060 Uiso 1 1 calc R U . . .
C14 C 0.4886(2) 0.62208(19) 0.12022(16) 0.0439(4) Uani 1 1 d . . . . .
C15 C 0.6296(2) 0.6909(2) 0.09493(17) 0.0470(4) Uani 1 1 d . . . . .
C16 C 0.7604(3) 0.6584(3) 0.1530(2) 0.0620(5) Uani 1 1 d . . . . .
H16A H 0.846991 0.714655 0.126169 0.093 Uiso 1 1 d R U . . .
H16B H 0.785245 0.678489 0.238500 0.093 Uiso 1 1 d R U . . .
H16C H 0.731826 0.561120 0.131132 0.093 Uiso 1 1 d R U . . .
C17 C 0.6475(3) 0.7912(2) 0.01521(18) 0.0526(5) Uani 1 1 d . . . . .
C18 C 0.7945(3) 0.8665(3) -0.0193(3) 0.0748(7) Uani 1 1 d . . . . .
H18A H 0.782876 0.927936 -0.076346 0.112 Uiso 1 1 d R U . . .
H18B H 0.875554 0.919953 0.050766 0.112 Uiso 1 1 d R U . . .
H18C H 0.817726 0.798723 -0.054267 0.112 Uiso 1 1 d R U . . .
C19 C 0.5259(3) 0.8196(2) -0.03609(18) 0.0561(5) Uani 1 1 d . . . . .
H19 H 0.538533 0.886442 -0.088284 0.067 Uiso 1 1 calc R U . . .
C20 C 0.3858(3) 0.7525(2) -0.01290(18) 0.0531(5) Uani 1 1 d . . . . .
C21 C 0.2589(3) 0.7899(3) -0.0728(2) 0.0769(7) Uani 1 1 d . . . . .
H21A H 0.294206 0.860472 -0.123038 0.115 Uiso 1 1 d R U . . .
H21B H 0.174241 0.708092 -0.120717 0.115 Uiso 1 1 d R U . . .
H21C H 0.227932 0.824921 -0.012837 0.115 Uiso 1 1 d R U . . .
C22 C 0.3659(2) 0.6515(2) 0.06624(17) 0.0484(4) Uani 1 1 d . . . . .
C23 C 0.2125(3) 0.5776(3) 0.0902(3) 0.0693(6) Uani 1 1 d . . . . .
H23A H 0.144824 0.612220 0.045243 0.104 Uiso 1 1 d R U . . .
H23B H 0.171722 0.478713 0.066292 0.104 Uiso 1 1 d R U . . .
H23C H 0.223844 0.595131 0.174142 0.104 Uiso 1 1 d R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C1 2.0838(18) . ?
Ag1 Cl1 2.3313(6) . ?
N1 C1 1.359(3) . ?
N1 C2 1.399(2) . ?
N1 C10 1.469(3) . ?
N2 C1 1.362(2) . ?
N2 C9 1.396(2) . ?
N2 C13 1.476(2) . ?
C2 C9 1.389(3) . ?
C2 C3 1.398(3) . ?
C3 C4 1.388(3) . ?
C3 H3 0.9300 . ?
C4 C6 1.418(3) . ?
C4 C5 1.514(3) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 C8 1.392(3) . ?
C6 C7 1.519(3) . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C8 C9 1.402(3) . ?
C8 H8 0.9300 . ?
C10 C11 1.486(4) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.233(5) . ?
C11 H11 0.9300 . ?
C12 H12A 0.9300 . ?
C12 H12B 0.9300 . ?
C13 C14 1.525(3) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C22 1.409(3) . ?
C14 C15 1.410(3) . ?
C15 C17 1.407(3) . ?
C15 C16 1.510(3) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C19 1.386(3) . ?
C17 C18 1.521(3) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 C20 1.390(3) . ?
C19 H19 0.9300 . ?
C20 C22 1.408(3) . ?
C20 C21 1.515(3) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 C23 1.515(3) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag1 Cl1 177.51(5) . . ?
C1 N1 C2 111.08(15) . . ?
C1 N1 C10 124.59(17) . . ?
C2 N1 C10 124.33(17) . . ?
C1 N2 C9 111.11(15) . . ?
C1 N2 C13 125.13(16) . . ?
C9 N2 C13 123.77(16) . . ?
N1 C1 N2 105.50(15) . . ?
N1 C1 Ag1 127.66(14) . . ?
N2 C1 Ag1 126.80(14) . . ?
C9 C2 C3 121.13(17) . . ?
C9 C2 N1 106.09(16) . . ?
C3 C2 N1 132.74(18) . . ?
C4 C3 C2 118.40(18) . . ?
C4 C3 H3 120.8 . . ?
C2 C3 H3 120.8 . . ?
C3 C4 C6 120.49(17) . . ?
C3 C4 C5 119.60(19) . . ?
C6 C4 C5 119.87(19) . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C8 C6 C4 120.82(17) . . ?
C8 C6 C7 118.97(19) . . ?
C4 C6 C7 120.21(18) . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C6 C8 C9 117.98(18) . . ?
C6 C8 H8 121.0 . . ?
C9 C8 H8 121.0 . . ?
C2 C9 N2 106.18(15) . . ?
C2 C9 C8 121.09(17) . . ?
N2 C9 C8 132.73(17) . . ?
N1 C10 C11 112.14(19) . . ?
N1 C10 H10A 109.2 . . ?
C11 C10 H10A 109.2 . . ?
N1 C10 H10B 109.2 . . ?
C11 C10 H10B 109.2 . . ?
H10A C10 H10B 107.9 . . ?
C12 C11 C10 129.5(4) . . ?
C12 C11 H11 115.2 . . ?
C10 C11 H11 115.2 . . ?
C11 C12 H12A 120.0 . . ?
C11 C12 H12B 120.0 . . ?
H12A C12 H12B 120.0 . . ?
N2 C13 C14 114.23(16) . . ?
N2 C13 H13A 108.7 . . ?
C14 C13 H13A 108.7 . . ?
N2 C13 H13B 108.7 . . ?
C14 C13 H13B 108.7 . . ?
H13A C13 H13B 107.6 . . ?
C22 C14 C15 121.06(18) . . ?
C22 C14 C13 120.01(18) . . ?
C15 C14 C13 118.85(17) . . ?
C17 C15 C14 119.12(18) . . ?
C17 C15 C16 120.2(2) . . ?
C14 C15 C16 120.67(18) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.4 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C19 C17 C15 119.0(2) . . ?
C19 C17 C18 118.9(2) . . ?
C15 C17 C18 122.1(2) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.6 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.3 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 C20 122.84(19) . . ?
C17 C19 H19 118.6 . . ?
C20 C19 H19 118.6 . . ?
C19 C20 C22 118.91(19) . . ?
C19 C20 C21 119.4(2) . . ?
C22 C20 C21 121.7(2) . . ?
C20 C21 H21A 109.3 . . ?
C20 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C20 C21 H21C 109.6 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C20 C22 C14 119.10(19) . . ?
C20 C22 C23 118.68(19) . . ?
C14 C22 C23 122.21(19) . . ?
C22 C23 H23A 109.4 . . ?
C22 C23 H23B 109.6 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 N1 C1 N2 0.1(2) . . . . ?
C10 N1 C1 N2 179.10(17) . . . . ?
C2 N1 C1 Ag1 177.91(13) . . . . ?
C10 N1 C1 Ag1 -3.1(3) . . . . ?
C9 N2 C1 N1 1.3(2) . . . . ?
C13 N2 C1 N1 -178.66(17) . . . . ?
C9 N2 C1 Ag1 -176.60(13) . . . . ?
C13 N2 C1 Ag1 3.5(3) . . . . ?
C1 N1 C2 C9 -1.3(2) . . . . ?
C10 N1 C2 C9 179.63(17) . . . . ?
C1 N1 C2 C3 176.51(19) . . . . ?
C10 N1 C2 C3 -2.5(3) . . . . ?
C9 C2 C3 C4 -1.6(3) . . . . ?
N1 C2 C3 C4 -179.22(18) . . . . ?
C2 C3 C4 C6 -1.0(3) . . . . ?
C2 C3 C4 C5 176.81(17) . . . . ?
C3 C4 C6 C8 1.9(3) . . . . ?
C5 C4 C6 C8 -175.94(18) . . . . ?
C3 C4 C6 C7 -178.72(18) . . . . ?
C5 C4 C6 C7 3.5(3) . . . . ?
C4 C6 C8 C9 -0.1(3) . . . . ?
C7 C6 C8 C9 -179.47(17) . . . . ?
C3 C2 C9 N2 -176.14(16) . . . . ?
N1 C2 C9 N2 2.01(19) . . . . ?
C3 C2 C9 C8 3.5(3) . . . . ?
N1 C2 C9 C8 -178.32(16) . . . . ?
C1 N2 C9 C2 -2.1(2) . . . . ?
C13 N2 C9 C2 177.83(17) . . . . ?
C1 N2 C9 C8 178.29(19) . . . . ?
C13 N2 C9 C8 -1.8(3) . . . . ?
C6 C8 C9 C2 -2.6(3) . . . . ?
C6 C8 C9 N2 176.96(18) . . . . ?
C1 N1 C10 C11 -103.2(3) . . . . ?
C2 N1 C10 C11 75.7(3) . . . . ?
N1 C10 C11 C12 -122.9(4) . . . . ?
C1 N2 C13 C14 43.9(3) . . . . ?
C9 N2 C13 C14 -136.05(18) . . . . ?
N2 C13 C14 C22 -116.5(2) . . . . ?
N2 C13 C14 C15 66.6(2) . . . . ?
C22 C14 C15 C17 0.6(3) . . . . ?
C13 C14 C15 C17 177.45(18) . . . . ?
C22 C14 C15 C16 -179.83(19) . . . . ?
C13 C14 C15 C16 -2.9(3) . . . . ?
C14 C15 C17 C19 0.1(3) . . . . ?
C16 C15 C17 C19 -179.5(2) . . . . ?
C14 C15 C17 C18 -178.1(2) . . . . ?
C16 C15 C17 C18 2.2(3) . . . . ?
C15 C17 C19 C20 -0.4(3) . . . . ?
C18 C17 C19 C20 177.8(2) . . . . ?
C17 C19 C20 C22 0.2(3) . . . . ?
C17 C19 C20 C21 180.0(2) . . . . ?
C19 C20 C22 C14 0.5(3) . . . . ?
C21 C20 C22 C14 -179.4(2) . . . . ?
C19 C20 C22 C23 -179.4(2) . . . . ?
C21 C20 C22 C23 0.8(3) . . . . ?
C15 C14 C22 C20 -0.8(3) . . . . ?
C13 C14 C22 C20 -177.69(18) . . . . ?
C15 C14 C22 C23 179.0(2) . . . . ?
C13 C14 C22 C23 2.1(3) . . . . ?

_refine_diff_density_max         0.312
_refine_diff_density_min         -0.446
_refine_diff_density_rms         0.058



