# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_namiko204
_database_code_depnum_ccdc_archive 'CCDC 2062835'
loop_
_audit_author_name
_audit_author_address
'Namik Ozdemir'
;Ondokuz Mayis University
Turkey
;
_audit_update_record             
;
2021-02-12 deposited with the CCDC.	2021-07-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C26 H30 Ag N9 O3, 2(N O3)'
_chemical_formula_sum            'C26 H30 Ag N11 O9'
_chemical_formula_weight         748.48

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   14.8453(6)
_cell_length_b                   15.1725(7)
_cell_length_c                   14.2740(6)
_cell_angle_alpha                90
_cell_angle_beta                 105.931(3)
_cell_angle_gamma                90
_cell_volume                     3091.6(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    18382
_cell_measurement_theta_min      1.96
_cell_measurement_theta_max      28.09

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.608
_exptl_crystal_F_000             1528
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.700
_exptl_crystal_size_mid          0.490
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    0.723
_shelx_estimated_absorpt_T_min   0.632
_shelx_estimated_absorpt_T_max   0.931
_exptl_absorpt_correction_type   integration
_exptl_absorpt_correction_T_min  0.8166
_exptl_absorpt_correction_T_max  0.9663
_exptl_absorpt_process_details   'X-RED32 (Stoe & Cie, 2002)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_monochromator  'plane graphite'
_diffrn_radiation_collimation    '0.8 mm diameter, multiple pinhole'
_diffrn_source                   
'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 6.67
_diffrn_reflns_number            25008
_diffrn_reflns_av_unetI/netI     0.0896
_diffrn_reflns_av_R_equivalents  0.0904
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.959
_diffrn_reflns_theta_max         27.677
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             7191
_reflns_number_gt                3818
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'X-AREA (Stoe & Cie, 2002)'
_computing_cell_refinement       X-AREA
_computing_data_reduction        'X-RED32 (Stoe & Cie, 2002)'
_computing_structure_solution    'SHELXT-2018/2 (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2015)'
_computing_molecular_graphics    'OLEX2 (Dolomanov et al., 2009)'
_computing_publication_material  
'OLEX2 (Dolomanov et al., 2009) and PLATON (Spek, 2009)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0570P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7191
_refine_ls_number_parameters     428
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1406
_refine_ls_R_factor_gt           0.0683
_refine_ls_wR_factor_ref         0.1411
_refine_ls_wR_factor_gt          0.1196
_refine_ls_goodness_of_fit_ref   0.994
_refine_ls_restrained_S_all      0.994
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.77227(3) 0.55855(3) 0.48186(3) 0.05956(16) Uani 1 1 d . . . . .
O1 O 0.3567(3) 0.8162(3) 0.2426(3) 0.0827(13) Uani 1 1 d . . . . .
O2 O 0.2594(3) 0.8610(3) 0.3187(3) 0.0731(12) Uani 1 1 d . . . . .
O3 O 0.3980(3) 0.8192(3) 0.3979(3) 0.0815(14) Uani 1 1 d . . . . .
O4 O 0.6941(4) 0.4073(5) 0.5480(6) 0.148(3) Uani 1 1 d . . . . .
O5 O 0.7348(5) 0.5094(4) 0.6485(4) 0.117(2) Uani 1 1 d . . . . .
O6 O 0.6862(7) 0.3903(5) 0.6903(7) 0.185(4) Uani 1 1 d . . . . .
O7 O 1.1288(4) 0.2714(3) 0.4494(4) 0.0956(15) Uani 1 1 d . . . . .
O8 O 1.0730(4) 0.1930(3) 0.5444(4) 0.0989(16) Uani 1 1 d . . . . .
O9 O 1.1996(3) 0.1535(3) 0.5112(4) 0.0916(15) Uani 1 1 d . . . . .
N1 N 0.6579(3) 0.6304(3) 0.3904(3) 0.0474(10) Uani 1 1 d . . . . .
N2 N 0.5293(3) 0.7081(3) 0.3367(3) 0.0583(12) Uani 1 1 d . . . . .
H2 H 0.485500 0.745231 0.336429 0.070 Uiso 1 1 calc R U . . .
N3 N 0.5953(4) 0.6812(4) 0.5800(4) 0.0751(16) Uani 1 1 d . . . . .
N4 N 0.5874(5) 0.6166(4) 0.7100(5) 0.0890(19) Uani 1 1 d . . . . .
N5 N 0.8899(3) 0.4729(3) 0.5362(3) 0.0461(10) Uani 1 1 d . . . . .
N6 N 0.9818(3) 0.3568(3) 0.5578(3) 0.0551(11) Uani 1 1 d . . . . .
H6 H 1.003796 0.306401 0.547365 0.066 Uiso 1 1 calc R U . . .
N7 N 0.8305(3) 0.2611(3) 0.4236(3) 0.0504(11) Uani 1 1 d . . . . .
N8 N 0.8427(4) 0.1220(3) 0.4132(3) 0.0620(13) Uani 1 1 d . . . . .
N9 N 0.3370(4) 0.8325(3) 0.3194(4) 0.0567(12) Uani 1 1 d . . . . .
N10 N 0.7037(4) 0.4348(4) 0.6291(5) 0.0790(16) Uani 1 1 d . . . . .
N11 N 1.1340(4) 0.2057(3) 0.5012(4) 0.0628(13) Uani 1 1 d . . . . .
C1 C 0.6028(4) 0.6900(3) 0.4128(4) 0.0512(13) Uani 1 1 d . . . . .
C2 C 0.6175(4) 0.6087(3) 0.2938(4) 0.0454(12) Uani 1 1 d . . . . .
C3 C 0.6479(4) 0.5515(4) 0.2333(4) 0.0565(14) Uani 1 1 d . . . . .
H3 H 0.702472 0.518616 0.255686 0.068 Uiso 1 1 calc R U . . .
C4 C 0.5937(5) 0.5457(4) 0.1387(4) 0.0652(16) Uani 1 1 d . . . . .
H4 H 0.612146 0.508140 0.095867 0.078 Uiso 1 1 calc R U . . .
C5 C 0.5118(5) 0.5946(4) 0.1052(4) 0.0739(19) Uani 1 1 d . . . . .
H5 H 0.476546 0.587915 0.040857 0.089 Uiso 1 1 calc R U . . .
C6 C 0.4816(4) 0.6518(4) 0.1637(5) 0.0660(17) Uani 1 1 d . . . . .
H6A H 0.427597 0.685234 0.140388 0.079 Uiso 1 1 calc R U . . .
C7 C 0.5357(4) 0.6576(3) 0.2598(4) 0.0501(13) Uani 1 1 d . . . . .
C8 C 0.6190(5) 0.7362(4) 0.5075(4) 0.0628(16) Uani 1 1 d . . . . .
H8A H 0.684333 0.753221 0.530391 0.075 Uiso 1 1 calc R U . . .
H8B H 0.581394 0.789394 0.498596 0.075 Uiso 1 1 calc R U . . .
C9 C 0.5025(5) 0.6374(6) 0.5571(7) 0.093(2) Uani 1 1 d . . . . .
H9 H 0.456494 0.638803 0.497874 0.112 Uiso 1 1 calc R U . . .
C10 C 0.4980(6) 0.5986(6) 0.6321(7) 0.097(3) Uani 1 1 d . . . . .
H10 H 0.448189 0.564433 0.638977 0.116 Uiso 1 1 calc R U . . .
C11 C 0.6061(6) 0.5760(4) 0.8028(5) 0.087(2) Uani 1 1 d . . . . .
H11A H 0.626378 0.516458 0.798444 0.130 Uiso 1 1 calc R U . . .
H11B H 0.550194 0.575948 0.824220 0.130 Uiso 1 1 calc R U . . .
H11C H 0.654397 0.608167 0.848563 0.130 Uiso 1 1 calc R U . . .
C12 C 0.6334(6) 0.6630(4) 0.6684(7) 0.082(2) Uani 1 1 d . . . . .
C13 C 0.7289(4) 0.6949(5) 0.7205(6) 0.095(3) Uani 1 1 d . . . . .
H13A H 0.723848 0.746066 0.758292 0.143 Uiso 1 1 calc R U . . .
H13B H 0.762407 0.709814 0.673958 0.143 Uiso 1 1 calc R U . . .
H13C H 0.762013 0.649363 0.762912 0.143 Uiso 1 1 calc R U . . .
C14 C 0.9049(4) 0.3962(4) 0.5008(4) 0.0481(12) Uani 1 1 d . . . . .
C15 C 0.9607(4) 0.4843(3) 0.6220(4) 0.0458(12) Uani 1 1 d . . . . .
C16 C 0.9766(4) 0.5509(4) 0.6908(4) 0.0602(14) Uani 1 1 d . . . . .
H16 H 0.937790 0.600094 0.682605 0.072 Uiso 1 1 calc R U . . .
C17 C 1.0515(5) 0.5418(5) 0.7714(5) 0.0745(18) Uani 1 1 d . . . . .
H17 H 1.063699 0.585703 0.818733 0.089 Uiso 1 1 calc R U . . .
C18 C 1.1091(5) 0.4691(5) 0.7839(5) 0.080(2) Uani 1 1 d . . . . .
H18 H 1.159194 0.465253 0.839644 0.096 Uiso 1 1 calc R U . . .
C19 C 1.0948(4) 0.4023(5) 0.7168(5) 0.0710(17) Uani 1 1 d . . . . .
H19 H 1.134098 0.353416 0.725497 0.085 Uiso 1 1 calc R U . . .
C20 C 1.0188(4) 0.4112(3) 0.6355(4) 0.0506(13) Uani 1 1 d . . . . .
C21 C 0.8422(5) 0.3559(4) 0.4122(4) 0.0626(16) Uani 1 1 d . . . . .
H21A H 0.781423 0.384279 0.397753 0.075 Uiso 1 1 calc R U . . .
H21B H 0.867907 0.365890 0.357566 0.075 Uiso 1 1 calc R U . . .
C22 C 0.7885(4) 0.2245(4) 0.4881(4) 0.0665(16) Uani 1 1 d . . . . .
H22 H 0.759889 0.254810 0.528754 0.080 Uiso 1 1 calc R U . . .
C23 C 0.7960(5) 0.1385(5) 0.4821(4) 0.0705(18) Uani 1 1 d . . . . .
H23 H 0.773805 0.096613 0.517813 0.085 Uiso 1 1 calc R U . . .
C24 C 0.8689(6) 0.0340(4) 0.3862(6) 0.101(3) Uani 1 1 d . . . . .
H24A H 0.840001 0.023910 0.318163 0.152 Uiso 1 1 calc R U . . .
H24B H 0.847905 -0.009862 0.423913 0.152 Uiso 1 1 calc R U . . .
H24C H 0.935697 0.030553 0.398895 0.152 Uiso 1 1 calc R U . . .
C25 C 0.8626(4) 0.1979(4) 0.3780(4) 0.0492(13) Uani 1 1 d . . . . .
C26 C 0.9099(5) 0.2080(4) 0.3008(5) 0.0721(17) Uani 1 1 d . . . . .
H26A H 0.870852 0.241626 0.248121 0.108 Uiso 1 1 calc R U . . .
H26B H 0.921268 0.150910 0.277407 0.108 Uiso 1 1 calc R U . . .
H26C H 0.968364 0.238077 0.326333 0.108 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.135(4) . ?
Ag1 N5 2.144(4) . ?
Ag1 O5 2.692(6) . ?
Ag1 O4 2.847(8) . ?
O1 N9 1.235(6) . ?
O2 N9 1.228(6) . ?
O3 N9 1.248(6) . ?
O4 N10 1.202(7) . ?
O5 N10 1.224(7) . ?
O6 N10 1.188(8) . ?
O7 N11 1.232(6) . ?
O8 N11 1.242(6) . ?
O9 N11 1.233(6) . ?
N1 C1 1.316(6) . ?
N1 C2 1.384(6) . ?
N2 C1 1.339(7) . ?
N2 C7 1.363(7) . ?
N2 H2 0.8600 . ?
N3 C12 1.264(9) . ?
N3 C8 1.446(8) . ?
N3 C9 1.483(9) . ?
N4 C12 1.241(9) . ?
N4 C11 1.417(9) . ?
N4 C10 1.504(10) . ?
N5 C14 1.311(6) . ?
N5 C15 1.388(6) . ?
N6 C14 1.347(6) . ?
N6 C20 1.370(7) . ?
N6 H6 0.8600 . ?
N7 C25 1.319(6) . ?
N7 C22 1.363(7) . ?
N7 C21 1.462(7) . ?
N8 C25 1.322(7) . ?
N8 C23 1.373(8) . ?
N8 C24 1.471(8) . ?
C1 C8 1.482(7) . ?
C2 C3 1.385(7) . ?
C2 C7 1.391(7) . ?
C3 C4 1.372(8) . ?
C3 H3 0.9300 . ?
C4 C5 1.392(9) . ?
C4 H4 0.9300 . ?
C5 C6 1.362(9) . ?
C5 H5 0.9300 . ?
C6 C7 1.390(8) . ?
C6 H6A 0.9300 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C10 1.239(10) . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 C13 1.489(10) . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 C21 1.481(8) . ?
C15 C16 1.384(7) . ?
C15 C20 1.386(7) . ?
C16 C17 1.371(8) . ?
C16 H16 0.9300 . ?
C17 C18 1.377(9) . ?
C17 H17 0.9300 . ?
C18 C19 1.371(10) . ?
C18 H18 0.9300 . ?
C19 C20 1.386(8) . ?
C19 H19 0.9300 . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 C23 1.315(9) . ?
C22 H22 0.9300 . ?
C23 H23 0.9300 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C25 C26 1.468(8) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N5 164.33(15) . . ?
N1 Ag1 O5 111.03(18) . . ?
N5 Ag1 O5 81.82(17) . . ?
N1 Ag1 O4 106.63(19) . . ?
N5 Ag1 O4 75.94(19) . . ?
O5 Ag1 O4 44.10(18) . . ?
N10 O4 Ag1 95.0(5) . . ?
N10 O5 Ag1 102.3(4) . . ?
C1 N1 C2 106.1(4) . . ?
C1 N1 Ag1 130.2(4) . . ?
C2 N1 Ag1 122.8(3) . . ?
C1 N2 C7 108.5(4) . . ?
C1 N2 H2 125.8 . . ?
C7 N2 H2 125.8 . . ?
C12 N3 C8 135.2(7) . . ?
C12 N3 C9 104.9(7) . . ?
C8 N3 C9 119.7(6) . . ?
C12 N4 C11 134.6(8) . . ?
C12 N4 C10 103.8(7) . . ?
C11 N4 C10 121.3(7) . . ?
C14 N5 C15 106.4(4) . . ?
C14 N5 Ag1 127.3(4) . . ?
C15 N5 Ag1 126.0(3) . . ?
C14 N6 C20 107.8(4) . . ?
C14 N6 H6 126.1 . . ?
C20 N6 H6 126.1 . . ?
C25 N7 C22 109.3(5) . . ?
C25 N7 C21 126.1(5) . . ?
C22 N7 C21 124.5(5) . . ?
C25 N8 C23 108.8(5) . . ?
C25 N8 C24 126.1(6) . . ?
C23 N8 C24 125.0(6) . . ?
O2 N9 O1 120.9(5) . . ?
O2 N9 O3 120.8(5) . . ?
O1 N9 O3 118.3(5) . . ?
O6 N10 O4 121.2(8) . . ?
O6 N10 O5 120.3(7) . . ?
O4 N10 O5 118.4(7) . . ?
O7 N11 O9 120.5(6) . . ?
O7 N11 O8 119.3(5) . . ?
O9 N11 O8 120.2(5) . . ?
N1 C1 N2 111.5(5) . . ?
N1 C1 C8 126.1(5) . . ?
N2 C1 C8 122.4(5) . . ?
N1 C2 C3 130.1(5) . . ?
N1 C2 C7 108.5(4) . . ?
C3 C2 C7 121.3(5) . . ?
C4 C3 C2 116.8(5) . . ?
C4 C3 H3 121.6 . . ?
C2 C3 H3 121.6 . . ?
C3 C4 C5 121.6(6) . . ?
C3 C4 H4 119.2 . . ?
C5 C4 H4 119.2 . . ?
C6 C5 C4 122.2(6) . . ?
C6 C5 H5 118.9 . . ?
C4 C5 H5 118.9 . . ?
C5 C6 C7 116.5(6) . . ?
C5 C6 H6A 121.7 . . ?
C7 C6 H6A 121.7 . . ?
N2 C7 C6 133.0(5) . . ?
N2 C7 C2 105.4(4) . . ?
C6 C7 C2 121.5(5) . . ?
N3 C8 C1 111.7(5) . . ?
N3 C8 H8A 109.3 . . ?
C1 C8 H8A 109.3 . . ?
N3 C8 H8B 109.3 . . ?
C1 C8 H8B 109.3 . . ?
H8A C8 H8B 108.0 . . ?
C10 C9 N3 106.8(8) . . ?
C10 C9 H9 126.6 . . ?
N3 C9 H9 126.6 . . ?
C9 C10 N4 107.8(7) . . ?
C9 C10 H10 126.1 . . ?
N4 C10 H10 126.1 . . ?
N4 C11 H11A 109.5 . . ?
N4 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
N4 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N4 C12 N3 116.6(8) . . ?
N4 C12 C13 121.2(9) . . ?
N3 C12 C13 122.2(8) . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
N5 C14 N6 111.5(5) . . ?
N5 C14 C21 124.2(5) . . ?
N6 C14 C21 124.2(5) . . ?
C16 C15 C20 120.5(5) . . ?
C16 C15 N5 131.1(5) . . ?
C20 C15 N5 108.3(5) . . ?
C17 C16 C15 117.6(6) . . ?
C17 C16 H16 121.2 . . ?
C15 C16 H16 121.2 . . ?
C16 C17 C18 121.4(6) . . ?
C16 C17 H17 119.3 . . ?
C18 C17 H17 119.3 . . ?
C19 C18 C17 122.1(6) . . ?
C19 C18 H18 119.0 . . ?
C17 C18 H18 119.0 . . ?
C18 C19 C20 116.5(6) . . ?
C18 C19 H19 121.7 . . ?
C20 C19 H19 121.7 . . ?
N6 C20 C15 105.9(5) . . ?
N6 C20 C19 132.2(5) . . ?
C15 C20 C19 121.8(6) . . ?
N7 C21 C14 112.2(4) . . ?
N7 C21 H21A 109.2 . . ?
C14 C21 H21A 109.2 . . ?
N7 C21 H21B 109.2 . . ?
C14 C21 H21B 109.2 . . ?
H21A C21 H21B 107.9 . . ?
C23 C22 N7 107.4(6) . . ?
C23 C22 H22 126.3 . . ?
N7 C22 H22 126.3 . . ?
C22 C23 N8 107.2(6) . . ?
C22 C23 H23 126.4 . . ?
N8 C23 H23 126.4 . . ?
N8 C24 H24A 109.5 . . ?
N8 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
N8 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
N7 C25 N8 107.3(5) . . ?
N7 C25 C26 127.3(5) . . ?
N8 C25 C26 125.3(5) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 O4 N10 O6 -174.5(8) . . . . ?
Ag1 O4 N10 O5 3.4(7) . . . . ?
Ag1 O5 N10 O6 174.3(7) . . . . ?
Ag1 O5 N10 O4 -3.6(8) . . . . ?
C2 N1 C1 N2 0.1(6) . . . . ?
Ag1 N1 C1 N2 -169.1(4) . . . . ?
C2 N1 C1 C8 -177.3(5) . . . . ?
Ag1 N1 C1 C8 13.6(8) . . . . ?
C7 N2 C1 N1 0.3(6) . . . . ?
C7 N2 C1 C8 177.7(5) . . . . ?
C1 N1 C2 C3 177.9(5) . . . . ?
Ag1 N1 C2 C3 -11.9(8) . . . . ?
C1 N1 C2 C7 -0.3(6) . . . . ?
Ag1 N1 C2 C7 169.8(3) . . . . ?
N1 C2 C3 C4 -177.9(5) . . . . ?
C7 C2 C3 C4 0.1(8) . . . . ?
C2 C3 C4 C5 -0.3(8) . . . . ?
C3 C4 C5 C6 1.1(9) . . . . ?
C4 C5 C6 C7 -1.5(9) . . . . ?
C1 N2 C7 C6 -177.3(6) . . . . ?
C1 N2 C7 C2 -0.4(6) . . . . ?
C5 C6 C7 N2 177.8(6) . . . . ?
C5 C6 C7 C2 1.3(8) . . . . ?
N1 C2 C7 N2 0.5(6) . . . . ?
C3 C2 C7 N2 -178.0(5) . . . . ?
N1 C2 C7 C6 177.8(5) . . . . ?
C3 C2 C7 C6 -0.7(8) . . . . ?
C12 N3 C8 C1 134.8(7) . . . . ?
C9 N3 C8 C1 -51.4(7) . . . . ?
N1 C1 C8 N3 -78.4(7) . . . . ?
N2 C1 C8 N3 104.5(6) . . . . ?
C12 N3 C9 C10 -1.1(9) . . . . ?
C8 N3 C9 C10 -176.5(7) . . . . ?
N3 C9 C10 N4 1.4(9) . . . . ?
C12 N4 C10 C9 -1.3(9) . . . . ?
C11 N4 C10 C9 -175.5(7) . . . . ?
C11 N4 C12 N3 173.7(7) . . . . ?
C10 N4 C12 N3 0.6(8) . . . . ?
C11 N4 C12 C13 -6.1(11) . . . . ?
C10 N4 C12 C13 -179.2(6) . . . . ?
C8 N3 C12 N4 174.6(6) . . . . ?
C9 N3 C12 N4 0.2(8) . . . . ?
C8 N3 C12 C13 -5.6(11) . . . . ?
C9 N3 C12 C13 -180.0(6) . . . . ?
C15 N5 C14 N6 -0.4(6) . . . . ?
Ag1 N5 C14 N6 -174.7(3) . . . . ?
C15 N5 C14 C21 176.4(5) . . . . ?
Ag1 N5 C14 C21 2.1(7) . . . . ?
C20 N6 C14 N5 0.3(6) . . . . ?
C20 N6 C14 C21 -176.5(5) . . . . ?
C14 N5 C15 C16 -176.6(5) . . . . ?
Ag1 N5 C15 C16 -2.2(8) . . . . ?
C14 N5 C15 C20 0.4(5) . . . . ?
Ag1 N5 C15 C20 174.8(3) . . . . ?
C20 C15 C16 C17 0.4(8) . . . . ?
N5 C15 C16 C17 177.1(5) . . . . ?
C15 C16 C17 C18 -0.1(9) . . . . ?
C16 C17 C18 C19 0.0(10) . . . . ?
C17 C18 C19 C20 -0.3(10) . . . . ?
C14 N6 C20 C15 0.0(6) . . . . ?
C14 N6 C20 C19 177.5(6) . . . . ?
C16 C15 C20 N6 177.1(5) . . . . ?
N5 C15 C20 N6 -0.2(5) . . . . ?
C16 C15 C20 C19 -0.7(8) . . . . ?
N5 C15 C20 C19 -178.1(5) . . . . ?
C18 C19 C20 N6 -176.6(6) . . . . ?
C18 C19 C20 C15 0.6(9) . . . . ?
C25 N7 C21 C14 -111.3(6) . . . . ?
C22 N7 C21 C14 64.8(7) . . . . ?
N5 C14 C21 N7 -139.1(5) . . . . ?
N6 C14 C21 N7 37.3(8) . . . . ?
C25 N7 C22 C23 0.6(7) . . . . ?
C21 N7 C22 C23 -176.1(5) . . . . ?
N7 C22 C23 N8 -0.2(7) . . . . ?
C25 N8 C23 C22 -0.3(7) . . . . ?
C24 N8 C23 C22 177.7(6) . . . . ?
C22 N7 C25 N8 -0.7(6) . . . . ?
C21 N7 C25 N8 175.9(5) . . . . ?
C22 N7 C25 C26 178.0(6) . . . . ?
C21 N7 C25 C26 -5.4(9) . . . . ?
C23 N8 C25 N7 0.6(6) . . . . ?
C24 N8 C25 N7 -177.4(6) . . . . ?
C23 N8 C25 C26 -178.1(6) . . . . ?
C24 N8 C25 C26 3.9(9) . . . . ?

_refine_diff_density_max         0.867
_refine_diff_density_min         -0.267
_refine_diff_density_rms         0.078



