# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 2089885'
loop_
_audit_author_name
_audit_author_address
'Alexander Goloveshkin'
;Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2021-06-14 deposited with the CCDC.	2021-08-09 downloaded from the CCDC.
;
_audit_creation_date             2021-06-14
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C39 H37 Eu N2 O6'
_chemical_formula_sum            'C39 H37 Eu N2 O6'
_chemical_formula_weight         781.66
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.925(2)
_cell_length_b                   12.023(2)
_cell_length_c                   14.135(3)
_cell_angle_alpha                95.16(3)
_cell_angle_beta                 105.55(3)
_cell_angle_gamma                110.74(3)
_cell_volume                     1787.0(8)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    7505
_cell_measurement_temperature    120
_cell_measurement_theta_max      33.01
_cell_measurement_theta_min      2.73
_shelx_estimated_absorpt_T_max   0.737
_shelx_estimated_absorpt_T_min   0.571
_exptl_absorpt_coefficient_mu    1.803
_exptl_absorpt_correction_T_max  0.7466
_exptl_absorpt_correction_T_min  0.6086
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0842 before and 0.0337 after correction.
The Ratio of minimum to maximum transmission is 0.8152.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.453
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             792
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.18
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0242
_diffrn_reflns_av_unetI/netI     0.0443
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            14155
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.279
_diffrn_reflns_theta_min         1.851
_diffrn_ambient_temperature      120
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7886
_reflns_number_total             8790
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    ?
_refine_diff_density_max         1.830
_refine_diff_density_min         -0.954
_refine_diff_density_rms         0.101
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     439
_refine_ls_number_reflns         8790
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0346
_refine_ls_R_factor_gt           0.0288
_refine_ls_restrained_S_all      1.044
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0317P)²+0.6528P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0665
_refine_ls_wR_factor_ref         0.0691
_refine_special_details          ?
_olex2_refinement_description    
;
1. Others
 Fixed Uiso: H16(0.02) H18(0.034) H19(0.03) H21(0.023) H22(0.023) H24(0.022)
 H28(0.02) H30(0.025) H31(0.028) H32(0.036) H35(0.04) H36(0.025) H38(0.027)
 H40A(0.048) H40B(0.048) H40C(0.048) H42(0.027) H44A(0.045) H44B(0.045)
 H44C(0.045) H47(0.037) H2(0.032) H3(0.027) H4A(0.038) H4B(0.038) H4C(0.038)
 H5A(0.037) H5B(0.037) H5C(0.037) H6(0.031) H7A(0.053) H7B(0.053) H7C(0.053)
 H8(0.033) H9A(0.042) H9B(0.042) H9C(0.042)
 Fixed X: H16(0.14379) H18(0.566046) H19(0.574499) H21(0.46607) H22(0.018649)
 H24(0.545336) H28(0.307589) H30(0.12564) H31(0.075986) H32(0.629333) H35(-
 0.310035) H36(-0.08361) H38(0.040908) H40A(-0.099158) H40B(-0.076582) H40C(-
 0.152259) H42(0.391143) H44A(-0.187921) H44B(-0.148625) H44C(-0.140626) H47(-
 0.191749) H2(-0.210521) H3(0.545783) H4A(0.299912) H4B(0.223102) H4C(0.359824)
 H5A(0.70133) H5B(0.690304) H5C(0.630705) H6(0.025319) H7A(0.344214)
 H7B(0.20996) H7C(0.281514) H8(0.444161) H9A(0.293635) H9B(0.429519) H9C(0.3076)
 Fixed Y: H16(1.45261) H18(1.643195) H19(1.561439) H21(1.080141) H22(1.036126)
 H24(1.23087) H28(1.468557) H30(1.524881) H31(0.763051) H32(1.704909)
 H35(1.384685) H36(1.168724) H38(0.633803) H40A(0.924457) H40B(0.858434)
 H40C(0.779286) H42(1.294578) H44A(0.684043) H44B(0.655284) H44C(0.788647)
 H47(1.591451) H2(1.247713) H3(1.06056) H4A(0.667875) H4B(0.677452)
 H4C(0.78093) H5A(1.062586) H5B(1.021275) H5C(0.922029) H6(1.660797)
 H7A(0.687539) H7B(0.579497) H7C(0.583894) H8(1.438219) H9A(1.012627)
 H9B(1.123209) H9C(1.145106)
 Fixed Z: H16(0.426472) H18(0.924246) H19(0.642477) H21(0.504647)
 H22(0.129505) H24(0.649795) H28(0.563234) H30(0.262986) H31(0.523047)
 H32(0.788476) H35(0.212818) H36(0.119431) H38(-0.019952) H40A(0.406673)
 H40B(0.499165) H40C(0.387724) H42(0.768637) H44A(0.036506) H44B(-0.059723)
 H44C(-0.023373) H47(0.22649) H2(0.223433) H3(0.113197) H4A(0.488023)
 H4B(0.56334) H4C(0.580597) H5A(0.343853) H5B(0.229749) H5C(0.29001)
 H6(0.250083) H7A(0.062978) H7B(0.004126) H7C(0.118591) H8(0.913836) H9A(-
 0.051141) H9B(-0.013501) H9C(-0.004684)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.23643(2) 0.94654(2) 0.27383(2) 0.01329(4) Uani 1 1 d . . . . .
O49 O 0.25671(18) 0.77935(17) 0.18827(14) 0.0215(4) Uani 1 1 d . . . . .
O50 O 0.04444(18) 0.83879(17) 0.14198(15) 0.0219(4) Uani 1 1 d . . . . .
C51 C 0.4757(2) 1.4137(2) 0.69066(19) 0.0157(5) Uani 1 1 d . . . . .
O52 O 0.27597(17) 0.84248(17) 0.40480(14) 0.0192(4) Uani 1 1 d . . . . .
C53 C 0.2928(2) 1.2225(2) 0.42578(18) 0.0134(5) Uani 1 1 d . . . . .
C54 C 0.3376(2) 1.3181(2) 0.50985(19) 0.0142(5) Uani 1 1 d . . . . .
O55 O 0.07366(18) 0.91294(18) 0.34849(15) 0.0235(4) Uani 1 1 d . . . . .
O56 O 0.45827(17) 1.00778(17) 0.30457(14) 0.0189(4) Uani 1 1 d . . . . .
C10 C 0.1978(3) 0.7076(2) 0.1036(2) 0.0208(5) Uani 1 1 d . . . . .
O11 O 0.28354(18) 1.04179(18) 0.14090(14) 0.0215(4) Uani 1 1 d . . . . .
C12 C 0.4340(2) 1.3208(2) 0.59679(18) 0.0144(5) Uani 1 1 d . . . . .
C13 C 0.0055(3) 0.7531(2) 0.0657(2) 0.0195(5) Uani 1 1 d . . . . .
C16 C 0.1812(2) 1.3948(2) 0.4258(2) 0.0171(5) Uani 1 1 d . . . . .
H16 H 0.143790 1.452610 0.426472 0.020 Uiso 1 1 calc R U . . .
N17 N 0.3407(2) 1.13466(19) 0.42435(16) 0.0147(4) Uani 1 1 d . . . . .
C18 C 0.5430(3) 1.5851(3) 0.8649(2) 0.0280(7) Uani 1 1 d . . . . .
H18 H 0.566046 1.643195 0.924246 0.034 Uiso 1 1 calc R U . . .
C19 C 0.5478(3) 1.5361(3) 0.6974(2) 0.0252(6) Uani 1 1 d . . . . .
H19 H 0.574499 1.561439 0.642477 0.030 Uiso 1 1 calc R U . . .
C20 C -0.0321(2) 1.3722(2) 0.24529(19) 0.0170(5) Uani 1 1 d . . . . .
C21 C 0.4320(3) 1.1405(2) 0.5057(2) 0.0189(5) Uani 1 1 d . . . . .
H21 H 0.466070 1.080141 0.504647 0.023 Uiso 1 1 calc R U . . .
C22 C 0.0493(3) 1.1037(2) 0.1833(2) 0.0194(5) Uani 1 1 d . . . . .
H22 H 0.018649 1.036126 0.129505 0.023 Uiso 1 1 calc R U . . .
C23 C 0.2197(3) 0.7937(2) 0.4647(2) 0.0193(5) Uani 1 1 d . . . . .
C24 C 0.4807(3) 1.2313(2) 0.5934(2) 0.0187(5) Uani 1 1 d . . . . .
H24 H 0.545336 1.230870 0.649795 0.022 Uiso 1 1 calc R U . . .
C25 C 0.1903(2) 1.2129(2) 0.33904(18) 0.0136(5) Uani 1 1 d . . . . .
C27 C 0.0298(2) 1.2842(2) 0.25305(19) 0.0164(5) Uani 1 1 d . . . . .
C28 C 0.2782(2) 1.4041(2) 0.50702(19) 0.0166(5) Uani 1 1 d . . . . .
H28 H 0.307589 1.468557 0.563234 0.020 Uiso 1 1 calc R U . . .
N29 N 0.1486(2) 1.11699(19) 0.26077(16) 0.0161(4) Uani 1 1 d . . . . .
C30 C 0.0373(3) 1.4961(2) 0.2528(2) 0.0204(5) Uani 1 1 d . . . . .
H30 H 0.125640 1.524881 0.262986 0.025 Uiso 1 1 calc R U . . .
C31 C 0.1082(3) 0.8003(3) 0.4741(2) 0.0232(6) Uani 1 1 d . . . . .
H31 H 0.075986 0.763051 0.523047 0.028 Uiso 1 1 calc R U . . .
C32 C 0.5808(3) 1.6216(3) 0.7845(2) 0.0296(7) Uani 1 1 d . . . . .
H32 H 0.629333 1.704909 0.788476 0.036 Uiso 1 1 calc R U . . .
C33 C 0.1340(2) 1.2990(2) 0.33856(19) 0.0150(5) Uani 1 1 d . . . . .
C34 C 0.3724(3) 1.0576(2) 0.1031(2) 0.0200(5) Uani 1 1 d . . . . .
C35 C -0.2217(3) 1.4130(3) 0.2229(3) 0.0333(7) Uani 1 1 d . . . . .
H35 H -0.310035 1.384685 0.212818 0.040 Uiso 1 1 calc R U . . .
C36 C -0.0125(3) 1.1834(2) 0.1765(2) 0.0206(5) Uani 1 1 d . . . . .
H36 H -0.083610 1.168724 0.119431 0.025 Uiso 1 1 calc R U . . .
C37 C 0.5230(2) 1.0211(2) 0.2450(2) 0.0185(5) Uani 1 1 d . . . . .
C38 C 0.0766(3) 0.6910(3) 0.0419(2) 0.0227(6) Uani 1 1 d . . . . .
H38 H 0.040908 0.633803 -0.019952 0.027 Uiso 1 1 calc R U . . .
C40 C -0.0828(3) 0.8549(3) 0.4283(3) 0.0317(7) Uani 1 1 d . . . . .
H40A H -0.099158 0.924457 0.406673 0.048 Uiso 1 1 calc R U . . .
H40B H -0.076582 0.858434 0.499165 0.048 Uiso 1 1 calc R U . . .
H40C H -0.152259 0.779286 0.387724 0.048 Uiso 1 1 calc R U . . .
C42 C 0.4388(3) 1.3779(3) 0.7721(2) 0.0226(6) Uani 1 1 d . . . . .
H42 H 0.391143 1.294578 0.768637 0.027 Uiso 1 1 calc R U . . .
C44 C -0.1299(3) 0.7171(3) -0.0011(2) 0.0301(7) Uani 1 1 d . . . . .
H44A H -0.187921 0.684043 0.036506 0.045 Uiso 1 1 calc R U . . .
H44B H -0.148625 0.655284 -0.059723 0.045 Uiso 1 1 calc R U . . .
H44C H -0.140626 0.788647 -0.023373 0.045 Uiso 1 1 calc R U . . .
C47 C -0.1514(3) 1.5358(3) 0.2309(2) 0.0308(7) Uani 1 1 d . . . . .
H47 H -0.191749 1.591451 0.226490 0.037 Uiso 1 1 calc R U . . .
C1 C 0.0410(3) 0.8590(2) 0.4150(2) 0.0213(6) Uani 1 1 d . . . . .
C2 C -0.1622(3) 1.3316(3) 0.2296(2) 0.0266(6) Uani 1 1 d . . . . .
H2 H -0.210521 1.247713 0.223433 0.032 Uiso 1 1 calc R U . . .
C3 C 0.4872(3) 1.0479(3) 0.1494(2) 0.0225(6) Uani 1 1 d . . . . .
H3 H 0.545783 1.060560 0.113197 0.027 Uiso 1 1 calc R U . . .
C4 C 0.2811(3) 0.7238(3) 0.5300(2) 0.0252(6) Uani 1 1 d . . . . .
H4A H 0.299912 0.667875 0.488023 0.038 Uiso 1 1 calc R U . . .
H4B H 0.223102 0.677452 0.563340 0.038 Uiso 1 1 calc R U . . .
H4C H 0.359824 0.780930 0.580597 0.038 Uiso 1 1 calc R U . . .
C5 C 0.6473(3) 1.0053(3) 0.2803(2) 0.0248(6) Uani 1 1 d . . . . .
H5A H 0.701330 1.062586 0.343853 0.037 Uiso 1 1 calc R U . . .
H5B H 0.690304 1.021275 0.229749 0.037 Uiso 1 1 calc R U . . .
H5C H 0.630705 0.922029 0.290010 0.037 Uiso 1 1 calc R U . . .
C6 C -0.0223(3) 1.5771(3) 0.2453(2) 0.0259(6) Uani 1 1 d . . . . .
H6 H 0.025319 1.660797 0.250083 0.031 Uiso 1 1 calc R U . . .
C7 C 0.2642(3) 0.6330(3) 0.0693(2) 0.0351(8) Uani 1 1 d . . . . .
H7A H 0.344214 0.687539 0.062978 0.053 Uiso 1 1 calc R U . . .
H7B H 0.209960 0.579497 0.004126 0.053 Uiso 1 1 calc R U . . .
H7C H 0.281514 0.583894 0.118591 0.053 Uiso 1 1 calc R U . . .
C8 C 0.4711(3) 1.4632(3) 0.8590(2) 0.0275(6) Uani 1 1 d . . . . .
H8 H 0.444161 1.438219 0.913836 0.033 Uiso 1 1 calc R U . . .
C9 C 0.3487(3) 1.0873(3) -0.0008(2) 0.0281(6) Uani 1 1 d . . . . .
H9A H 0.293635 1.012627 -0.051141 0.042 Uiso 1 1 calc R U . . .
H9B H 0.429519 1.123209 -0.013501 0.042 Uiso 1 1 calc R U . . .
H9C H 0.307600 1.145106 -0.004684 0.042 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O49 2.3718(19) . ?
Eu1 O50 2.360(2) . ?
Eu1 O52 2.3623(19) . ?
Eu1 O55 2.380(2) . ?
Eu1 O56 2.3825(19) . ?
Eu1 O11 2.378(2) . ?
Eu1 N17 2.629(2) . ?
Eu1 N29 2.611(2) . ?
O49 C10 1.266(3) . ?
O50 C13 1.277(3) . ?
C51 C12 1.497(3) . ?
C51 C19 1.396(4) . ?
C51 C42 1.389(4) . ?
O52 C23 1.276(3) . ?
C53 C54 1.413(3) . ?
C53 N17 1.368(3) . ?
C53 C25 1.443(3) . ?
C54 C12 1.429(3) . ?
C54 C28 1.443(3) . ?
O55 C1 1.259(3) . ?
O56 C37 1.271(3) . ?
C10 C38 1.406(4) . ?
C10 C7 1.516(4) . ?
O11 C34 1.274(3) . ?
C12 C24 1.379(4) . ?
C13 C38 1.396(4) . ?
C13 C44 1.517(4) . ?
C16 H16 0.9500 . ?
C16 C28 1.357(4) . ?
C16 C33 1.442(4) . ?
N17 C21 1.332(3) . ?
C18 H18 0.9500 . ?
C18 C32 1.383(5) . ?
C18 C8 1.392(4) . ?
C19 H19 0.9500 . ?
C19 C32 1.398(4) . ?
C20 C27 1.485(4) . ?
C20 C30 1.402(4) . ?
C20 C2 1.398(4) . ?
C21 H21 0.9500 . ?
C21 C24 1.410(4) . ?
C22 H22 0.9500 . ?
C22 N29 1.328(3) . ?
C22 C36 1.396(4) . ?
C23 C31 1.400(4) . ?
C23 C4 1.519(4) . ?
C24 H24 0.9500 . ?
C25 N29 1.368(3) . ?
C25 C33 1.419(3) . ?
C27 C33 1.427(4) . ?
C27 C36 1.390(4) . ?
C28 H28 0.9500 . ?
C30 H30 0.9500 . ?
C30 C6 1.390(4) . ?
C31 H31 0.9500 . ?
C31 C1 1.409(4) . ?
C32 H32 0.9500 . ?
C34 C3 1.401(4) . ?
C34 C9 1.518(4) . ?
C35 H35 0.9500 . ?
C35 C47 1.392(5) . ?
C35 C2 1.393(4) . ?
C36 H36 0.9500 . ?
C37 C3 1.407(4) . ?
C37 C5 1.517(4) . ?
C38 H38 0.9500 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C40 C1 1.522(4) . ?
C42 H42 0.9500 . ?
C42 C8 1.396(4) . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C47 H47 0.9500 . ?
C47 C6 1.389(5) . ?
C2 H2 0.9500 . ?
C3 H3 0.9500 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6 0.9500 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8 0.9500 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O49 Eu1 O55 120.11(7) . . ?
O49 Eu1 O56 75.21(7) . . ?
O49 Eu1 O11 84.95(7) . . ?
O49 Eu1 N17 147.03(7) . . ?
O49 Eu1 N29 147.26(7) . . ?
O50 Eu1 O49 72.47(7) . . ?
O50 Eu1 O52 114.69(7) . . ?
O50 Eu1 O55 74.34(7) . . ?
O50 Eu1 O56 139.06(7) . . ?
O50 Eu1 O11 79.54(7) . . ?
O50 Eu1 N17 140.43(7) . . ?
O50 Eu1 N29 81.09(7) . . ?
O52 Eu1 O49 79.05(7) . . ?
O52 Eu1 O55 71.68(7) . . ?
O52 Eu1 O56 82.46(7) . . ?
O52 Eu1 O11 153.60(7) . . ?
O52 Eu1 N17 82.18(7) . . ?
O52 Eu1 N29 130.73(7) . . ?
O55 Eu1 O56 145.37(7) . . ?
O55 Eu1 N17 78.30(7) . . ?
O55 Eu1 N29 68.58(7) . . ?
O56 Eu1 N17 75.64(7) . . ?
O56 Eu1 N29 116.80(7) . . ?
O11 Eu1 O55 134.71(7) . . ?
O11 Eu1 O56 73.17(7) . . ?
O11 Eu1 N17 101.01(7) . . ?
O11 Eu1 N29 71.33(7) . . ?
N29 Eu1 N17 62.40(7) . . ?
C10 O49 Eu1 135.02(17) . . ?
C13 O50 Eu1 135.94(18) . . ?
C19 C51 C12 121.6(2) . . ?
C42 C51 C12 119.3(2) . . ?
C42 C51 C19 119.1(2) . . ?
C23 O52 Eu1 137.02(17) . . ?
C54 C53 C25 120.0(2) . . ?
N17 C53 C54 122.2(2) . . ?
N17 C53 C25 117.8(2) . . ?
C53 C54 C12 118.5(2) . . ?
C53 C54 C28 118.7(2) . . ?
C12 C54 C28 122.6(2) . . ?
C1 O55 Eu1 137.38(18) . . ?
C37 O56 Eu1 131.31(17) . . ?
O49 C10 C38 125.1(3) . . ?
O49 C10 C7 116.1(3) . . ?
C38 C10 C7 118.8(3) . . ?
C34 O11 Eu1 132.60(18) . . ?
C54 C12 C51 120.3(2) . . ?
C24 C12 C51 121.4(2) . . ?
C24 C12 C54 118.2(2) . . ?
O50 C13 C38 125.1(2) . . ?
O50 C13 C44 115.7(3) . . ?
C38 C13 C44 119.2(2) . . ?
C28 C16 H16 119.4 . . ?
C28 C16 C33 121.2(2) . . ?
C33 C16 H16 119.4 . . ?
C53 N17 Eu1 120.52(16) . . ?
C21 N17 Eu1 121.04(17) . . ?
C21 N17 C53 118.0(2) . . ?
C32 C18 H18 120.0 . . ?
C32 C18 C8 120.1(3) . . ?
C8 C18 H18 120.0 . . ?
C51 C19 H19 119.8 . . ?
C51 C19 C32 120.3(3) . . ?
C32 C19 H19 119.8 . . ?
C30 C20 C27 121.3(2) . . ?
C2 C20 C27 119.9(2) . . ?
C2 C20 C30 118.8(2) . . ?
N17 C21 H21 118.2 . . ?
N17 C21 C24 123.6(2) . . ?
C24 C21 H21 118.2 . . ?
N29 C22 H22 118.1 . . ?
N29 C22 C36 123.8(2) . . ?
C36 C22 H22 118.1 . . ?
O52 C23 C31 125.2(3) . . ?
O52 C23 C4 115.9(2) . . ?
C31 C23 C4 118.9(2) . . ?
C12 C24 C21 119.5(2) . . ?
C12 C24 H24 120.3 . . ?
C21 C24 H24 120.3 . . ?
N29 C25 C53 117.6(2) . . ?
N29 C25 C33 122.5(2) . . ?
C33 C25 C53 119.9(2) . . ?
C33 C27 C20 121.9(2) . . ?
C36 C27 C20 120.8(2) . . ?
C36 C27 C33 117.4(2) . . ?
C54 C28 H28 119.3 . . ?
C16 C28 C54 121.4(2) . . ?
C16 C28 H28 119.3 . . ?
C22 N29 Eu1 120.28(17) . . ?
C22 N29 C25 117.7(2) . . ?
C25 N29 Eu1 121.30(16) . . ?
C20 C30 H30 119.7 . . ?
C6 C30 C20 120.5(3) . . ?
C6 C30 H30 119.7 . . ?
C23 C31 H31 118.2 . . ?
C23 C31 C1 123.7(3) . . ?
C1 C31 H31 118.2 . . ?
C18 C32 C19 120.1(3) . . ?
C18 C32 H32 120.0 . . ?
C19 C32 H32 120.0 . . ?
C25 C33 C16 118.7(2) . . ?
C25 C33 C27 118.5(2) . . ?
C27 C33 C16 122.8(2) . . ?
O11 C34 C3 125.0(3) . . ?
O11 C34 C9 116.3(2) . . ?
C3 C34 C9 118.7(2) . . ?
C47 C35 H35 120.1 . . ?
C47 C35 C2 119.8(3) . . ?
C2 C35 H35 120.1 . . ?
C22 C36 H36 119.9 . . ?
C27 C36 C22 120.1(2) . . ?
C27 C36 H36 119.9 . . ?
O56 C37 C3 124.9(3) . . ?
O56 C37 C5 116.9(2) . . ?
C3 C37 C5 118.2(2) . . ?
C10 C38 H38 117.9 . . ?
C13 C38 C10 124.1(3) . . ?
C13 C38 H38 117.9 . . ?
H40A C40 H40B 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C1 C40 H40A 109.5 . . ?
C1 C40 H40B 109.5 . . ?
C1 C40 H40C 109.5 . . ?
C51 C42 H42 119.7 . . ?
C51 C42 C8 120.7(3) . . ?
C8 C42 H42 119.7 . . ?
C13 C44 H44A 109.5 . . ?
C13 C44 H44B 109.5 . . ?
C13 C44 H44C 109.5 . . ?
H44A C44 H44B 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C35 C47 H47 120.0 . . ?
C6 C47 C35 120.1(3) . . ?
C6 C47 H47 120.0 . . ?
O55 C1 C31 124.8(3) . . ?
O55 C1 C40 116.2(3) . . ?
C31 C1 C40 119.0(3) . . ?
C20 C2 H2 119.7 . . ?
C35 C2 C20 120.7(3) . . ?
C35 C2 H2 119.7 . . ?
C34 C3 C37 125.4(3) . . ?
C34 C3 H3 117.3 . . ?
C37 C3 H3 117.3 . . ?
C23 C4 H4A 109.5 . . ?
C23 C4 H4B 109.5 . . ?
C23 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C37 C5 H5A 109.5 . . ?
C37 C5 H5B 109.5 . . ?
C37 C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C30 C6 H6 119.9 . . ?
C47 C6 C30 120.1(3) . . ?
C47 C6 H6 119.9 . . ?
C10 C7 H7A 109.5 . . ?
C10 C7 H7B 109.5 . . ?
C10 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C18 C8 C42 119.8(3) . . ?
C18 C8 H8 120.1 . . ?
C42 C8 H8 120.1 . . ?
C34 C9 H9A 109.5 . . ?
C34 C9 H9B 109.5 . . ?
C34 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O49 C10 C38 -16.4(5) . . . . ?
Eu1 O49 C10 C7 165.1(2) . . . . ?
Eu1 O50 C13 C38 3.5(4) . . . . ?
Eu1 O50 C13 C44 -177.87(19) . . . . ?
Eu1 O52 C23 C31 -6.7(4) . . . . ?
Eu1 O52 C23 C4 173.32(18) . . . . ?
Eu1 O55 C1 C31 3.6(5) . . . . ?
Eu1 O55 C1 C40 -174.3(2) . . . . ?
Eu1 O56 C37 C3 26.3(4) . . . . ?
Eu1 O56 C37 C5 -153.10(18) . . . . ?
Eu1 O11 C34 C3 -17.6(4) . . . . ?
Eu1 O11 C34 C9 161.48(19) . . . . ?
Eu1 N17 C21 C24 -172.1(2) . . . . ?
O49 C10 C38 C13 0.8(5) . . . . ?
O50 C13 C38 C10 5.6(5) . . . . ?
C51 C12 C24 C21 175.4(2) . . . . ?
C51 C19 C32 C18 0.5(5) . . . . ?
C51 C42 C8 C18 -1.2(4) . . . . ?
O52 C23 C31 C1 2.3(5) . . . . ?
C53 C54 C12 C51 -174.4(2) . . . . ?
C53 C54 C12 C24 1.5(4) . . . . ?
C53 C54 C28 C16 -0.1(4) . . . . ?
C53 N17 C21 C24 0.7(4) . . . . ?
C53 C25 N29 Eu1 5.5(3) . . . . ?
C53 C25 N29 C22 176.1(2) . . . . ?
C53 C25 C33 C16 0.0(4) . . . . ?
C53 C25 C33 C27 -177.8(2) . . . . ?
C54 C53 N17 Eu1 173.24(18) . . . . ?
C54 C53 N17 C21 0.4(4) . . . . ?
C54 C53 C25 N29 -178.4(2) . . . . ?
C54 C53 C25 C33 -0.4(4) . . . . ?
C54 C12 C24 C21 -0.5(4) . . . . ?
O56 C37 C3 C34 -3.7(5) . . . . ?
O11 C34 C3 C37 -0.9(5) . . . . ?
C12 C51 C19 C32 177.2(3) . . . . ?
C12 C51 C42 C8 -176.9(3) . . . . ?
C12 C54 C28 C16 -175.7(2) . . . . ?
N17 C53 C54 C12 -1.5(4) . . . . ?
N17 C53 C54 C28 -177.3(2) . . . . ?
N17 C53 C25 N29 -0.5(3) . . . . ?
N17 C53 C25 C33 177.4(2) . . . . ?
N17 C21 C24 C12 -0.7(4) . . . . ?
C19 C51 C12 C54 -71.8(3) . . . . ?
C19 C51 C12 C24 112.5(3) . . . . ?
C19 C51 C42 C8 1.2(4) . . . . ?
C20 C27 C33 C16 4.2(4) . . . . ?
C20 C27 C33 C25 -178.2(2) . . . . ?
C20 C27 C36 C22 177.8(3) . . . . ?
C20 C30 C6 C47 0.3(4) . . . . ?
C23 C31 C1 O55 -0.9(5) . . . . ?
C23 C31 C1 C40 177.0(3) . . . . ?
C25 C53 C54 C12 176.3(2) . . . . ?
C25 C53 C54 C28 0.5(4) . . . . ?
C25 C53 N17 Eu1 -4.6(3) . . . . ?
C25 C53 N17 C21 -177.4(2) . . . . ?
C27 C20 C30 C6 180.0(2) . . . . ?
C27 C20 C2 C35 179.5(3) . . . . ?
C28 C54 C12 C51 1.2(4) . . . . ?
C28 C54 C12 C24 177.1(2) . . . . ?
C28 C16 C33 C25 0.4(4) . . . . ?
C28 C16 C33 C27 178.1(3) . . . . ?
N29 C22 C36 C27 0.6(4) . . . . ?
N29 C25 C33 C16 177.8(2) . . . . ?
N29 C25 C33 C27 0.1(4) . . . . ?
C30 C20 C27 C33 56.8(4) . . . . ?
C30 C20 C27 C36 -123.3(3) . . . . ?
C30 C20 C2 C35 -0.9(4) . . . . ?
C32 C18 C8 C42 0.8(5) . . . . ?
C33 C16 C28 C54 -0.4(4) . . . . ?
C33 C25 N29 Eu1 -172.42(17) . . . . ?
C33 C25 N29 C22 -1.9(4) . . . . ?
C33 C27 C36 C22 -2.3(4) . . . . ?
C35 C47 C6 C30 -0.6(5) . . . . ?
C36 C22 N29 Eu1 172.2(2) . . . . ?
C36 C22 N29 C25 1.5(4) . . . . ?
C36 C27 C33 C16 -175.7(2) . . . . ?
C36 C27 C33 C25 2.0(4) . . . . ?
C42 C51 C12 C54 106.3(3) . . . . ?
C42 C51 C12 C24 -69.5(3) . . . . ?
C42 C51 C19 C32 -0.8(4) . . . . ?
C44 C13 C38 C10 -173.0(3) . . . . ?
C47 C35 C2 C20 0.6(5) . . . . ?
C2 C20 C27 C33 -123.6(3) . . . . ?
C2 C20 C27 C36 56.2(4) . . . . ?
C2 C20 C30 C6 0.4(4) . . . . ?
C2 C35 C47 C6 0.2(5) . . . . ?
C4 C23 C31 C1 -177.7(3) . . . . ?
C5 C37 C3 C34 175.7(3) . . . . ?
C7 C10 C38 C13 179.3(3) . . . . ?
C8 C18 C32 C19 -0.5(5) . . . . ?
C9 C34 C3 C37 -180.0(3) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a_CCDC1
_database_code_depnum_ccdc_archive 'CCDC 2089887'
loop_
_audit_author_name
_audit_author_address
'Alexander Goloveshkin'
;Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2021-06-14 deposited with the CCDC.	2021-08-09 downloaded from the CCDC.
;
_audit_creation_date             2021-06-14
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         '2(C24 H16 N2), C60 H50 Eu2 N4 O12, 2(C2 H5 O)'
_chemical_formula_sum            'C112 H92 Eu2 N8 O14'
_chemical_formula_weight         2077.86
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'

_cell_length_a                   9.849(2)
_cell_length_b                   10.323(2)
_cell_length_c                   24.422(5)
_cell_angle_alpha                97.899(5)
_cell_angle_beta                 99.011(5)
_cell_angle_gamma                105.648(4)
_cell_volume                     2318.9(8)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    3108
_cell_measurement_temperature    120
_cell_measurement_theta_max      30.52
_cell_measurement_theta_min      2.19
_exptl_absorpt_coefficient_mu    1.413
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6239
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2008/1 (Bruker,2008) was used for absorption correction. wR2(int) was 0.0939 before and 0.0660 after correction. The Ratio of minimum to maximum transmission is 0.8362. The λ/2 correction factor is 0.0015.'
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.488
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1058
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.15
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.1103
_diffrn_reflns_av_unetI/netI     0.1584
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            26763
_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         1.72
_diffrn_ambient_temperature      120
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         0
_reflns_number_gt                7472
_reflns_number_total             11424
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XH  (Sheldrick, 2008)'
_computing_structure_solution    'XS n/a (Sheldrick, 2008)'
_refine_diff_density_max         3.205
_refine_diff_density_min         -4.336
_refine_diff_density_rms         0.211
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     618
_refine_ls_number_reflns         11424
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1275
_refine_ls_R_factor_gt           0.0798
_refine_ls_restrained_S_all      1.034
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0950P)²+1.8368P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1817
_refine_ls_wR_factor_ref         0.2020
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description    
;
1.a Aromatic/amide H refined with riding coordinates:
 C8(H8), C35(H35), C48(H48), C69(H69), C77(H77), C80(H80), C85(H85), C89(H89),
 C91(H91), C93(H93), C98(H98), C110(H110), C112(H112), C114(H114), C119(H119),
 C129(H129), C11(H11), C24(H24), C44(H44), C52(H52), C56(H56), C65(H65),
 C70(H70), C74(H74), C76(H76), C78(H78), C84(H84), C87(H87), C95(H95), C96(H96),
  C97(H97), C113(H113), C3(H3)
1.b Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C12(H12A,H12B,H12C), C81(H81A,H81B,H81C), C7(H7A,H7B,H7C)
1.c Idealised tetrahedral OH refined as rotating group:
 O23(H23)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C8 C 0.4584(10) 0.1522(9) -0.4980(4) 0.0291(19) Uani 1 1 d . . .
H8 H 0.5358 0.2177 -0.5052 0.035 Uiso 1 1 calc R . .
N33 N 0.1603(7) -0.0860(7) -0.6312(3) 0.0241(15) Uani 1 1 d . . .
C35 C -0.1775(9) -0.5240(8) -0.5878(3) 0.0211(17) Uani 1 1 d . . .
H35 H -0.0861 -0.5196 -0.5690 0.025 Uiso 1 1 calc R . .
C39 C 0.2313(8) -0.0376(8) -0.4754(3) 0.0195(16) Uani 1 1 d . . .
C40 C 0.2467(8) -0.0175(8) -0.5307(3) 0.0207(17) Uani 1 1 d . . .
C48 C 0.1089(8) -0.1406(8) -0.4678(3) 0.0201(16) Uani 1 1 d . . .
H48 H 0.0965 -0.1513 -0.4315 0.024 Uiso 1 1 calc R . .
N59 N 0.3578(7) 0.0765(7) -0.5417(3) 0.0246(15) Uani 1 1 d . . .
C63 C 0.0245(8) -0.2120(8) -0.5700(3) 0.0201(16) Uani 1 1 d . . .
C64 C -0.0730(8) -0.3002(8) -0.6178(3) 0.0215(17) Uani 1 1 d . . .
C68 C -0.1968(8) -0.4156(8) -0.6135(3) 0.0190(16) Uani 1 1 d . . .
C69 C -0.0527(9) -0.2778(8) -0.6705(3) 0.0216(17) Uani 1 1 d . . .
H69 H -0.1154 -0.3333 -0.7029 0.026 Uiso 1 1 calc R . .
C77 C 0.0110(9) -0.2225(8) -0.5130(3) 0.0218(17) Uani 1 1 d . . .
H77 H -0.0680 -0.2880 -0.5069 0.026 Uiso 1 1 calc R . .
C80 C 0.4852(10) 0.0108(9) -0.2813(4) 0.032(2) Uani 1 1 d . . .
H80 H 0.5686 0.0003 -0.2612 0.038 Uiso 1 1 calc R . .
C85 C -0.4298(10) -0.6442(9) -0.6163(4) 0.0281(19) Uani 1 1 d . . .
H85 H -0.5071 -0.7205 -0.6175 0.034 Uiso 1 1 calc R . .
C88 C 0.1409(8) -0.1074(8) -0.5789(3) 0.0191(16) Uani 1 1 d . . .
C89 C 0.4558(9) 0.1401(9) -0.4420(4) 0.0259(18) Uani 1 1 d . . .
H89 H 0.5303 0.1962 -0.4132 0.031 Uiso 1 1 calc R . .
C91 C 0.2362(9) 0.0405(8) -0.3413(4) 0.0240(18) Uani 1 1 d . . .
H91 H 0.1523 0.0504 -0.3613 0.029 Uiso 1 1 calc R . .
C93 C 0.2488(9) 0.0363(8) -0.2845(4) 0.0252(18) Uani 1 1 d . . .
H93 H 0.1744 0.0444 -0.2663 0.030 Uiso 1 1 calc R . .
C98 C -0.3365(9) -0.4233(9) -0.6400(3) 0.0244(18) Uani 1 1 d . . .
H98 H -0.3517 -0.3518 -0.6571 0.029 Uiso 1 1 calc R . .
C110 C -0.4515(9) -0.5350(9) -0.6410(4) 0.030(2) Uani 1 1 d . . .
H110 H -0.5437 -0.5380 -0.6583 0.036 Uiso 1 1 calc R . .
C112 C 0.4728(9) 0.0171(9) -0.3379(4) 0.0261(18) Uani 1 1 d . . .
H112 H 0.5490 0.0126 -0.3555 0.031 Uiso 1 1 calc R . .
C114 C 0.3733(10) 0.0200(9) -0.2547(4) 0.0286(19) Uani 1 1 d . . .
H114 H 0.3815 0.0153 -0.2166 0.034 Uiso 1 1 calc R . .
C116 C 0.3427(9) 0.0449(9) -0.4294(4) 0.0240(18) Uani 1 1 d . . .
C119 C 0.0655(9) -0.1686(9) -0.6744(3) 0.0256(18) Uani 1 1 d . . .
H119 H 0.0772 -0.1539 -0.7104 0.031 Uiso 1 1 calc R . .
C129 C -0.2921(9) -0.6376(9) -0.5900(3) 0.0235(18) Uani 1 1 d . . .
H129 H -0.2770 -0.7101 -0.5736 0.028 Uiso 1 1 calc R . .
C131 C 0.3469(9) 0.0302(9) -0.3690(4) 0.0245(18) Uani 1 1 d . . .
Eu1 Eu 0.10777(4) -0.01299(4) -0.060893(17) 0.01644(13) Uani 1 1 d . . .
O18 O 0.2127(6) 0.1812(6) -0.1034(2) 0.0271(13) Uani 1 1 d . . .
O118 O -0.0157(6) -0.2603(6) -0.0798(2) 0.0241(13) Uani 1 1 d . . .
O121 O 0.0929(6) 0.1466(5) 0.0147(2) 0.0204(12) Uani 1 1 d . . .
O122 O 0.2174(6) -0.0801(6) 0.0196(2) 0.0207(12) Uani 1 1 d . . .
O124 O 0.3578(6) 0.1445(6) -0.0340(2) 0.0225(12) Uani 1 1 d . . .
O126 O -0.1059(6) 0.0439(6) -0.0910(2) 0.0235(13) Uani 1 1 d . . .
N13 N 0.0369(7) -0.1001(7) -0.1709(3) 0.0199(14) Uani 1 1 d . . .
N15 N 0.2685(7) -0.1378(7) -0.1060(3) 0.0178(13) Uani 1 1 d . . .
C1 C 0.4455(10) 0.3446(10) -0.0728(4) 0.036(2) Uani 1 1 d . . .
H1A H 0.4740 0.3351 -0.1086 0.055 Uiso 1 1 calc R . .
H1B H 0.5278 0.3609 -0.0430 0.055 Uiso 1 1 calc R . .
H1C H 0.4064 0.4203 -0.0685 0.055 Uiso 1 1 calc R . .
C11 C 0.3853(9) -0.1520(9) -0.0750(3) 0.0236(18) Uani 1 1 d . . .
H11 H 0.4132 -0.1073 -0.0375 0.028 Uiso 1 1 calc R . .
C12 C -0.3170(10) 0.1149(11) -0.1091(4) 0.036(2) Uani 1 1 d . . .
H12A H -0.3956 0.1185 -0.0908 0.054 Uiso 1 1 calc R . .
H12B H -0.3519 0.0481 -0.1435 0.054 Uiso 1 1 calc R . .
H12C H -0.2743 0.2032 -0.1175 0.054 Uiso 1 1 calc R . .
C17 C 0.0570(8) -0.2550(8) -0.2520(3) 0.0153(15) Uani 1 1 d . . .
C21 C -0.0702(8) -0.2421(8) -0.2836(3) 0.0182(16) Uani 1 1 d . . .
C24 C -0.1305(9) -0.1482(8) -0.2593(3) 0.0213(17) Uani 1 1 d . . .
H24 H -0.2090 -0.1307 -0.2800 0.026 Uiso 1 1 calc R . .
C25 C 0.1045(8) -0.1853(8) -0.1949(3) 0.0160(15) Uani 1 1 d . . .
C26 C 0.3334(9) 0.2156(8) -0.0700(3) 0.0211(17) Uani 1 1 d . . .
C29 C 0.4293(8) -0.2999(8) -0.1508(3) 0.0186(16) Uani 1 1 d . . .
C37 C 0.0922(8) 0.2606(8) 0.0437(3) 0.0192(16) Uani 1 1 d . . .
C43 C 0.5133(8) -0.3883(8) -0.1739(3) 0.0180(16) Uani 1 1 d . . .
C44 C 0.1451(8) -0.3285(8) -0.2755(3) 0.0201(17) Uani 1 1 d . . .
H44 H 0.1184 -0.3698 -0.3135 0.024 Uiso 1 1 calc R . .
C46 C 0.3086(8) -0.2825(8) -0.1853(3) 0.0188(16) Uani 1 1 d . . .
C47 C -0.1376(8) -0.3271(8) -0.3406(3) 0.0173(16) Uani 1 1 d . . .
C50 C -0.2052(8) 0.0752(8) -0.0705(3) 0.0197(16) Uani 1 1 d . . .
C51 C 0.2305(8) -0.2023(8) -0.1611(3) 0.0164(15) Uani 1 1 d . . .
C52 C -0.1559(8) -0.4671(8) -0.3487(3) 0.0202(16) Uani 1 1 d . . .
H52 H -0.1227 -0.5054 -0.3190 0.024 Uiso 1 1 calc R . .
C56 C -0.1896(8) -0.2713(9) -0.3847(3) 0.0220(17) Uani 1 1 d . . .
H56 H -0.1802 -0.1781 -0.3795 0.026 Uiso 1 1 calc R . .
C65 C 0.4685(9) -0.2302(9) -0.0956(3) 0.0227(17) Uani 1 1 d . . .
H65 H 0.5502 -0.2352 -0.0722 0.027 Uiso 1 1 calc R . .
C70 C 0.6621(9) -0.3379(9) -0.1670(3) 0.0235(18) Uani 1 1 d . . .
H70 H 0.7101 -0.2490 -0.1477 0.028 Uiso 1 1 calc R . .
C74 C -0.2238(8) -0.5504(9) -0.4010(4) 0.0246(19) Uani 1 1 d . . .
H74 H -0.2358 -0.6441 -0.4065 0.029 Uiso 1 1 calc R . .
C76 C -0.2727(9) -0.4924(9) -0.4445(4) 0.0270(19) Uani 1 1 d . . .
H76 H -0.3178 -0.5473 -0.4796 0.032 Uiso 1 1 calc R . .
C78 C 0.2646(9) -0.3395(8) -0.2445(3) 0.0212(17) Uani 1 1 d . . .
H78 H 0.3207 -0.3853 -0.2618 0.025 Uiso 1 1 calc R . .
C81 C 0.1827(10) 0.3926(9) 0.0322(4) 0.035(2) Uani 1 1 d . . .
H81A H 0.1274 0.4228 0.0033 0.052 Uiso 1 1 calc R . .
H81B H 0.2663 0.3785 0.0198 0.052 Uiso 1 1 calc R . .
H81C H 0.2121 0.4610 0.0661 0.052 Uiso 1 1 calc R . .
C84 C 0.7393(9) -0.4198(9) -0.1889(4) 0.0258(19) Uani 1 1 d . . .
H84 H 0.8385 -0.3854 -0.1851 0.031 Uiso 1 1 calc R . .
C87 C -0.0733(9) -0.0796(8) -0.2036(3) 0.0213(17) Uani 1 1 d . . .
H87 H -0.1150 -0.0158 -0.1886 0.026 Uiso 1 1 calc R . .
C95 C -0.2558(9) -0.3553(9) -0.4367(3) 0.0262(19) Uani 1 1 d . . .
H95 H -0.2891 -0.3176 -0.4666 0.031 Uiso 1 1 calc R . .
C96 C 0.6675(9) -0.5533(9) -0.2164(4) 0.0276(19) Uani 1 1 d . . .
H96 H 0.7187 -0.6087 -0.2310 0.033 Uiso 1 1 calc R . .
C97 C 0.4435(9) -0.5231(9) -0.2014(3) 0.0234(17) Uani 1 1 d . . .
H97 H 0.3443 -0.5587 -0.2057 0.028 Uiso 1 1 calc R . .
C113 C 0.5224(9) -0.6035(8) -0.2222(4) 0.0261(18) Uani 1 1 d . . .
H113 H 0.4755 -0.6935 -0.2404 0.031 Uiso 1 1 calc R . .
C3 C 0.0148(13) -0.6483(14) -0.1802(5) 0.056(3) Uani 1 1 d . . .
H3 H -0.0706 -0.6542 -0.2043 0.067 Uiso 1 1 calc R . .
C7 C 0.0579(16) -0.5647(14) -0.1249(5) 0.068(4) Uani 1 1 d . . .
H7A H 0.1502 -0.4992 -0.1215 0.102 Uiso 1 1 calc R . .
H7B H 0.0640 -0.6216 -0.0971 0.102 Uiso 1 1 calc R . .
H7C H -0.0117 -0.5175 -0.1189 0.102 Uiso 1 1 calc R . .
O23 O 0.1089(7) -0.7211(7) -0.1962(3) 0.0349(15) Uani 1 1 d . . .
H23 H 0.1539 -0.7368 -0.1679 0.052 Uiso 1 1 calc R . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C8 H8 0.9300 . ?
C8 N59 1.324(11) . ?
C8 C89 1.394(12) . ?
N33 C88 1.359(10) . ?
N33 C119 1.314(11) . ?
C35 H35 0.9300 . ?
C35 C68 1.398(11) . ?
C35 C129 1.379(12) . ?
C39 C40 1.420(11) . ?
C39 C48 1.432(11) . ?
C39 C116 1.427(11) . ?
C40 N59 1.343(10) . ?
C40 C88 1.459(11) . ?
C48 H48 0.9300 . ?
C48 C77 1.354(11) . ?
C63 C64 1.414(11) . ?
C63 C77 1.434(11) . ?
C63 C88 1.415(11) . ?
C64 C68 1.485(11) . ?
C64 C69 1.375(11) . ?
C68 C98 1.402(11) . ?
C69 H69 0.9300 . ?
C69 C119 1.412(12) . ?
C77 H77 0.9300 . ?
C80 H80 0.9300 . ?
C80 C112 1.380(12) . ?
C80 C114 1.382(13) . ?
C85 H85 0.9300 . ?
C85 C110 1.399(13) . ?
C85 C129 1.386(12) . ?
C89 H89 0.9300 . ?
C89 C116 1.380(11) . ?
C91 H91 0.9300 . ?
C91 C93 1.382(11) . ?
C91 C131 1.391(11) . ?
C93 H93 0.9300 . ?
C93 C114 1.388(12) . ?
C98 H98 0.9300 . ?
C98 C110 1.375(12) . ?
C110 H110 0.9300 . ?
C112 H112 0.9300 . ?
C112 C131 1.398(12) . ?
C114 H114 0.9300 . ?
C116 C131 1.498(12) . ?
C119 H119 0.9300 . ?
C129 H129 0.9300 . ?
Eu1 Eu1 3.9357(10) 2 ?
Eu1 O18 2.440(6) . ?
Eu1 O118 2.456(6) . ?
Eu1 O121 2.596(5) 2 ?
Eu1 O121 2.350(5) . ?
Eu1 O122 2.372(5) . ?
Eu1 O124 2.486(5) . ?
Eu1 O126 2.370(5) . ?
Eu1 N13 2.631(6) . ?
Eu1 N15 2.576(6) . ?
Eu1 C26 2.833(8) . ?
Eu1 C37 2.903(8) 2 ?
O18 C26 1.263(10) . ?
O118 C37 1.245(9) 2 ?
O121 Eu1 2.596(5) 2 ?
O121 C37 1.289(9) . ?
O122 C50 1.262(9) 2 ?
O124 C26 1.255(10) . ?
O126 C50 1.262(9) . ?
N13 C25 1.364(9) . ?
N13 C87 1.327(10) . ?
N15 C11 1.329(10) . ?
N15 C51 1.363(9) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C1 C26 1.501(12) . ?
C11 H11 0.9300 . ?
C11 C65 1.397(11) . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C12 C50 1.514(11) . ?
C17 C21 1.413(10) . ?
C17 C25 1.420(10) . ?
C17 C44 1.431(10) . ?
C21 C24 1.381(10) . ?
C21 C47 1.485(10) . ?
C24 H24 0.9300 . ?
C24 C87 1.396(11) . ?
C25 C51 1.445(10) . ?
C29 C43 1.498(10) . ?
C29 C46 1.413(11) . ?
C29 C65 1.380(11) . ?
C37 Eu1 2.903(8) 2 ?
C37 O118 1.245(9) 2 ?
C37 C81 1.503(12) . ?
C43 C70 1.391(11) . ?
C43 C97 1.393(11) . ?
C44 H44 0.9300 . ?
C44 C78 1.338(11) . ?
C46 C51 1.406(10) . ?
C46 C78 1.434(10) . ?
C47 C52 1.389(11) . ?
C47 C56 1.383(11) . ?
C50 O122 1.262(9) 2 ?
C52 H52 0.9300 . ?
C52 C74 1.393(11) . ?
C56 H56 0.9300 . ?
C56 C95 1.387(11) . ?
C65 H65 0.9300 . ?
C70 H70 0.9300 . ?
C70 C84 1.390(10) . ?
C74 H74 0.9300 . ?
C74 C76 1.374(13) . ?
C76 H76 0.9300 . ?
C76 C95 1.362(12) . ?
C78 H78 0.9300 . ?
C81 H81A 0.9600 . ?
C81 H81B 0.9600 . ?
C81 H81C 0.9600 . ?
C84 H84 0.9300 . ?
C84 C96 1.386(12) . ?
C87 H87 0.9300 . ?
C95 H95 0.9300 . ?
C96 H96 0.9300 . ?
C96 C113 1.359(12) . ?
C97 H97 0.9300 . ?
C97 C113 1.381(11) . ?
C113 H113 0.9300 . ?
C3 H3 0.9300 . ?
C3 C7 1.434(16) . ?
C3 O23 1.408(11) . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
O23 H23 0.8200 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N59 C8 H8 117.9 . . ?
N59 C8 C89 124.3(8) . . ?
C89 C8 H8 117.9 . . ?
C119 N33 C88 116.9(7) . . ?
C68 C35 H35 119.6 . . ?
C129 C35 H35 119.6 . . ?
C129 C35 C68 120.9(8) . . ?
C40 C39 C48 119.6(7) . . ?
C40 C39 C116 117.6(7) . . ?
C116 C39 C48 122.8(7) . . ?
C39 C40 C88 119.1(7) . . ?
N59 C40 C39 123.6(7) . . ?
N59 C40 C88 117.2(7) . . ?
C39 C48 H48 119.7 . . ?
C77 C48 C39 120.5(7) . . ?
C77 C48 H48 119.7 . . ?
C8 N59 C40 117.1(7) . . ?
C64 C63 C77 123.4(7) . . ?
C64 C63 C88 118.2(7) . . ?
C88 C63 C77 118.4(7) . . ?
C63 C64 C68 122.9(7) . . ?
C69 C64 C63 118.5(8) . . ?
C69 C64 C68 118.5(7) . . ?
C35 C68 C64 121.8(7) . . ?
C35 C68 C98 118.3(8) . . ?
C98 C68 C64 119.7(7) . . ?
C64 C69 H69 120.8 . . ?
C64 C69 C119 118.4(8) . . ?
C119 C69 H69 120.8 . . ?
C48 C77 C63 122.5(8) . . ?
C48 C77 H77 118.8 . . ?
C63 C77 H77 118.8 . . ?
C112 C80 H80 120.1 . . ?
C112 C80 C114 119.8(9) . . ?
C114 C80 H80 120.1 . . ?
C110 C85 H85 120.3 . . ?
C129 C85 H85 120.3 . . ?
C129 C85 C110 119.4(8) . . ?
N33 C88 C40 117.3(7) . . ?
N33 C88 C63 122.9(7) . . ?
C63 C88 C40 119.8(7) . . ?
C8 C89 H89 120.1 . . ?
C116 C89 C8 119.9(8) . . ?
C116 C89 H89 120.1 . . ?
C93 C91 H91 119.5 . . ?
C93 C91 C131 121.1(8) . . ?
C131 C91 H91 119.5 . . ?
C91 C93 H93 120.3 . . ?
C91 C93 C114 119.5(8) . . ?
C114 C93 H93 120.3 . . ?
C68 C98 H98 119.5 . . ?
C110 C98 C68 120.9(8) . . ?
C110 C98 H98 119.5 . . ?
C85 C110 H110 120.0 . . ?
C98 C110 C85 120.1(8) . . ?
C98 C110 H110 120.0 . . ?
C80 C112 H112 119.6 . . ?
C80 C112 C131 120.7(8) . . ?
C131 C112 H112 119.6 . . ?
C80 C114 C93 120.4(8) . . ?
C80 C114 H114 119.8 . . ?
C93 C114 H114 119.8 . . ?
C39 C116 C131 124.1(7) . . ?
C89 C116 C39 117.5(8) . . ?
C89 C116 C131 118.4(8) . . ?
N33 C119 C69 125.0(8) . . ?
N33 C119 H119 117.5 . . ?
C69 C119 H119 117.5 . . ?
C35 C129 C85 120.4(8) . . ?
C35 C129 H129 119.8 . . ?
C85 C129 H129 119.8 . . ?
C91 C131 C112 118.5(8) . . ?
C91 C131 C116 122.9(8) . . ?
C112 C131 C116 118.4(7) . . ?
O18 Eu1 Eu1 123.35(14) . 2 ?
O18 Eu1 O118 144.60(19) . . ?
O18 Eu1 O121 150.96(18) . 2 ?
O18 Eu1 O124 52.62(19) . . ?
O18 Eu1 N13 73.5(2) . . ?
O18 Eu1 N15 87.7(2) . . ?
O18 Eu1 C26 26.4(2) . . ?
O18 Eu1 C37 160.7(2) . 2 ?
O118 Eu1 Eu1 86.29(12) . 2 ?
O118 Eu1 O121 51.47(16) . 2 ?
O118 Eu1 O124 138.62(19) . . ?
O118 Eu1 N13 71.5(2) . . ?
O118 Eu1 N15 71.80(19) . . ?
O118 Eu1 C26 151.72(19) . . ?
O118 Eu1 C37 25.14(18) . 2 ?
O121 Eu1 Eu1 39.50(13) . 2 ?
O121 Eu1 Eu1 35.16(11) 2 2 ?
O121 Eu1 O18 87.4(2) . . ?
O121 Eu1 O118 125.43(18) . . ?
O121 Eu1 O121 74.7(2) . 2 ?
O121 Eu1 O122 76.66(18) . . ?
O121 Eu1 O124 77.73(18) . . ?
O121 Eu1 O126 74.54(18) . . ?
O121 Eu1 N13 145.36(19) . . ?
O121 Eu1 N13 109.03(19) 2 . ?
O121 Eu1 N15 146.53(19) . . ?
O121 Eu1 C26 80.8(2) . . ?
O121 Eu1 C26 155.36(19) 2 . ?
O121 Eu1 C37 26.38(18) 2 2 ?
O121 Eu1 C37 100.5(2) . 2 ?
O122 Eu1 Eu1 69.57(12) . 2 ?
O122 Eu1 O18 127.08(19) . . ?
O122 Eu1 O118 78.46(19) . . ?
O122 Eu1 O121 71.32(18) . 2 ?
O122 Eu1 O124 74.63(19) . . ?
O122 Eu1 N13 137.82(19) . . ?
O122 Eu1 N15 80.13(18) . . ?
O122 Eu1 C26 100.7(2) . . ?
O122 Eu1 C37 72.1(2) . 2 ?
O124 Eu1 Eu1 112.25(12) . 2 ?
O124 Eu1 O121 140.04(17) . 2 ?
O124 Eu1 N13 110.14(19) . . ?
O124 Eu1 N15 73.05(19) . . ?
O124 Eu1 C26 26.3(2) . . ?
O124 Eu1 C37 146.1(2) . 2 ?
O126 Eu1 Eu1 68.31(13) . 2 ?
O126 Eu1 O18 82.0(2) . . ?
O126 Eu1 O118 93.6(2) . . ?
O126 Eu1 O121 71.39(19) . 2 ?
O126 Eu1 O122 137.54(18) . . ?
O126 Eu1 O124 127.3(2) . . ?
O126 Eu1 N13 74.39(18) . . ?
O126 Eu1 N15 137.22(19) . . ?
O126 Eu1 C26 104.7(2) . . ?
O126 Eu1 C37 83.2(2) . 2 ?
N13 Eu1 Eu1 134.94(14) . 2 ?
N13 Eu1 C26 92.6(2) . . ?
N13 Eu1 C37 90.6(2) . 2 ?
N15 Eu1 Eu1 145.67(14) . 2 ?
N15 Eu1 O121 119.79(18) . 2 ?
N15 Eu1 N13 62.88(19) . . ?
N15 Eu1 C26 80.2(2) . . ?
N15 Eu1 C37 94.9(2) . 2 ?
C26 Eu1 Eu1 120.29(15) . 2 ?
C26 Eu1 C37 172.0(2) . 2 ?
C37 Eu1 Eu1 61.17(15) 2 2 ?
C26 O18 Eu1 94.5(5) . . ?
C37 O118 Eu1 97.9(5) 2 . ?
Eu1 O121 Eu1 105.3(2) . 2 ?
C37 O121 Eu1 160.5(5) . . ?
C37 O121 Eu1 90.2(4) . 2 ?
C50 O122 Eu1 136.5(5) 2 . ?
C26 O124 Eu1 92.5(5) . . ?
C50 O126 Eu1 139.1(5) . . ?
C25 N13 Eu1 118.6(5) . . ?
C87 N13 Eu1 123.5(5) . . ?
C87 N13 C25 117.3(6) . . ?
C11 N15 Eu1 121.0(5) . . ?
C11 N15 C51 117.3(6) . . ?
C51 N15 Eu1 121.5(5) . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C26 C1 H1A 109.5 . . ?
C26 C1 H1B 109.5 . . ?
C26 C1 H1C 109.5 . . ?
N15 C11 H11 118.1 . . ?
N15 C11 C65 123.8(7) . . ?
C65 C11 H11 118.1 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C50 C12 H12A 109.5 . . ?
C50 C12 H12B 109.5 . . ?
C50 C12 H12C 109.5 . . ?
C21 C17 C25 118.6(6) . . ?
C21 C17 C44 123.2(7) . . ?
C25 C17 C44 118.1(7) . . ?
C17 C21 C47 121.5(6) . . ?
C24 C21 C17 117.5(7) . . ?
C24 C21 C47 121.0(7) . . ?
C21 C24 H24 120.1 . . ?
C21 C24 C87 119.9(7) . . ?
C87 C24 H24 120.1 . . ?
N13 C25 C17 122.3(7) . . ?
N13 C25 C51 118.3(6) . . ?
C17 C25 C51 119.4(6) . . ?
O18 C26 Eu1 59.2(4) . . ?
O18 C26 C1 119.2(8) . . ?
O124 C26 Eu1 61.2(4) . . ?
O124 C26 O18 120.3(7) . . ?
O124 C26 C1 120.5(8) . . ?
C1 C26 Eu1 174.9(6) . . ?
C46 C29 C43 121.1(7) . . ?
C65 C29 C43 121.4(7) . . ?
C65 C29 C46 117.5(7) . . ?
O118 C37 Eu1 56.9(4) 2 2 ?
O118 C37 O121 120.2(7) 2 . ?
O118 C37 C81 121.1(7) 2 . ?
O121 C37 Eu1 63.4(4) . 2 ?
O121 C37 C81 118.7(7) . . ?
C81 C37 Eu1 174.2(6) . 2 ?
C70 C43 C29 120.4(7) . . ?
C70 C43 C97 119.2(7) . . ?
C97 C43 C29 120.4(7) . . ?
C17 C44 H44 119.0 . . ?
C78 C44 C17 122.0(7) . . ?
C78 C44 H44 119.0 . . ?
C29 C46 C78 122.8(7) . . ?
C51 C46 C29 118.9(7) . . ?
C51 C46 C78 118.2(7) . . ?
C52 C47 C21 119.1(7) . . ?
C56 C47 C21 121.5(7) . . ?
C56 C47 C52 119.4(7) . . ?
O122 C50 C12 116.7(6) 2 . ?
O126 C50 O122 125.4(7) . 2 ?
O126 C50 C12 117.9(7) . . ?
N15 C51 C25 117.2(6) . . ?
N15 C51 C46 122.6(7) . . ?
C46 C51 C25 120.2(7) . . ?
C47 C52 H52 119.8 . . ?
C47 C52 C74 120.5(8) . . ?
C74 C52 H52 119.8 . . ?
C47 C56 H56 120.2 . . ?
C47 C56 C95 119.5(8) . . ?
C95 C56 H56 120.2 . . ?
C11 C65 H65 120.1 . . ?
C29 C65 C11 119.9(7) . . ?
C29 C65 H65 120.1 . . ?
C43 C70 H70 119.9 . . ?
C84 C70 C43 120.2(8) . . ?
C84 C70 H70 119.9 . . ?
C52 C74 H74 120.4 . . ?
C76 C74 C52 119.1(8) . . ?
C76 C74 H74 120.4 . . ?
C74 C76 H76 119.7 . . ?
C95 C76 C74 120.7(8) . . ?
C95 C76 H76 119.7 . . ?
C44 C78 C46 121.7(7) . . ?
C44 C78 H78 119.2 . . ?
C46 C78 H78 119.2 . . ?
C37 C81 H81A 109.5 . . ?
C37 C81 H81B 109.5 . . ?
C37 C81 H81C 109.5 . . ?
H81A C81 H81B 109.5 . . ?
H81A C81 H81C 109.5 . . ?
H81B C81 H81C 109.5 . . ?
C70 C84 H84 120.2 . . ?
C96 C84 C70 119.5(8) . . ?
C96 C84 H84 120.2 . . ?
N13 C87 C24 123.9(7) . . ?
N13 C87 H87 118.0 . . ?
C24 C87 H87 118.0 . . ?
C56 C95 H95 119.6 . . ?
C76 C95 C56 120.8(8) . . ?
C76 C95 H95 119.6 . . ?
C84 C96 H96 119.9 . . ?
C113 C96 C84 120.2(7) . . ?
C113 C96 H96 119.9 . . ?
C43 C97 H97 120.1 . . ?
C113 C97 C43 119.7(8) . . ?
C113 C97 H97 120.1 . . ?
C96 C113 C97 121.1(8) . . ?
C96 C113 H113 119.5 . . ?
C97 C113 H113 119.5 . . ?
C7 C3 H3 121.8 . . ?
O23 C3 H3 121.8 . . ?
O23 C3 C7 116.3(10) . . ?
C3 C7 H7A 109.5 . . ?
C3 C7 H7B 109.5 . . ?
C3 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C3 O23 H23 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C8 C89 C116 C39 -0.3(12) . . . . ?
C8 C89 C116 C131 177.1(7) . . . . ?
C35 C68 C98 C110 -0.5(11) . . . . ?
C39 C40 N59 C8 0.9(12) . . . . ?
C39 C40 C88 N33 -179.2(7) . . . . ?
C39 C40 C88 C63 0.5(11) . . . . ?
C39 C48 C77 C63 0.6(12) . . . . ?
C39 C116 C131 C91 -57.1(12) . . . . ?
C39 C116 C131 C112 128.5(9) . . . . ?
C40 C39 C48 C77 2.7(11) . . . . ?
C40 C39 C116 C89 1.2(11) . . . . ?
C40 C39 C116 C131 -176.1(7) . . . . ?
C48 C39 C40 N59 -180.0(7) . . . . ?
C48 C39 C40 C88 -3.2(11) . . . . ?
C48 C39 C116 C89 179.6(7) . . . . ?
C48 C39 C116 C131 2.2(12) . . . . ?
N59 C8 C89 C116 -0.4(14) . . . . ?
N59 C40 C88 N33 -2.2(11) . . . . ?
N59 C40 C88 C63 177.5(7) . . . . ?
C63 C64 C68 C35 -61.3(10) . . . . ?
C63 C64 C68 C98 124.2(8) . . . . ?
C63 C64 C69 C119 0.7(11) . . . . ?
C64 C63 C77 C48 177.2(8) . . . . ?
C64 C63 C88 N33 1.9(11) . . . . ?
C64 C63 C88 C40 -177.8(7) . . . . ?
C64 C68 C98 C110 174.2(7) . . . . ?
C64 C69 C119 N33 0.8(13) . . . . ?
C68 C35 C129 C85 -2.0(12) . . . . ?
C68 C64 C69 C119 -179.7(7) . . . . ?
C68 C98 C110 C85 -1.0(12) . . . . ?
C69 C64 C68 C35 119.1(9) . . . . ?
C69 C64 C68 C98 -55.4(10) . . . . ?
C77 C63 C64 C68 -2.0(12) . . . . ?
C77 C63 C64 C69 177.6(7) . . . . ?
C77 C63 C88 N33 -177.7(7) . . . . ?
C77 C63 C88 C40 2.6(11) . . . . ?
C80 C112 C131 C91 1.8(13) . . . . ?
C80 C112 C131 C116 176.4(8) . . . . ?
C88 N33 C119 C69 -0.9(12) . . . . ?
C88 C40 N59 C8 -175.9(7) . . . . ?
C88 C63 C64 C68 178.5(7) . . . . ?
C88 C63 C64 C69 -1.9(11) . . . . ?
C88 C63 C77 C48 -3.3(11) . . . . ?
C89 C8 N59 C40 0.1(13) . . . . ?
C89 C116 C131 C91 125.6(9) . . . . ?
C89 C116 C131 C112 -48.9(11) . . . . ?
C91 C93 C114 C80 1.3(13) . . . . ?
C93 C91 C131 C112 -0.8(13) . . . . ?
C93 C91 C131 C116 -175.2(8) . . . . ?
C110 C85 C129 C35 0.4(12) . . . . ?
C112 C80 C114 C93 -0.3(14) . . . . ?
C114 C80 C112 C131 -1.2(13) . . . . ?
C116 C39 C40 N59 -1.6(11) . . . . ?
C116 C39 C40 C88 175.1(7) . . . . ?
C116 C39 C48 C77 -175.5(8) . . . . ?
C119 N33 C88 C40 179.2(7) . . . . ?
C119 N33 C88 C63 -0.5(11) . . . . ?
C129 C35 C68 C64 -172.6(7) . . . . ?
C129 C35 C68 C98 2.0(11) . . . . ?
C129 C85 C110 C98 1.0(12) . . . . ?
C131 C91 C93 C114 -0.7(13) . . . . ?
Eu1 Eu1 O18 C26 91.8(4) 2 . . . ?
Eu1 Eu1 O118 C37 2.5(5) 2 . . 2 ?
Eu1 Eu1 O121 C37 -141.8(16) 2 . . . ?
Eu1 Eu1 O122 C50 -10.9(7) 2 . . 2 ?
Eu1 Eu1 O124 C26 -113.7(4) 2 . . . ?
Eu1 Eu1 O126 C50 7.3(8) 2 . . . ?
Eu1 Eu1 N13 C25 -132.6(5) 2 . . . ?
Eu1 Eu1 N13 C87 38.8(7) 2 . . . ?
Eu1 Eu1 N15 C11 -51.6(7) 2 . . . ?
Eu1 Eu1 N15 C51 122.4(5) 2 . . . ?
Eu1 Eu1 C26 O18 -104.8(4) 2 . . . ?
Eu1 Eu1 C26 O124 78.9(4) 2 . . . ?
Eu1 Eu1 C26 C1 -32(7) 2 . . . ?
Eu1 O18 C26 O124 3.7(7) . . . . ?
Eu1 O18 C26 C1 -174.4(6) . . . . ?
Eu1 O121 C37 Eu1 143.4(15) . . . 2 ?
Eu1 O121 C37 O118 4.8(8) 2 . . 2 ?
Eu1 O121 C37 O118 148.2(12) . . . 2 ?
Eu1 O121 C37 C81 -30(2) . . . . ?
Eu1 O121 C37 C81 -173.9(7) 2 . . . ?
Eu1 O124 C26 O18 -3.6(7) . . . . ?
Eu1 O124 C26 C1 174.4(7) . . . . ?
Eu1 O126 C50 O122 -2.8(14) . . . 2 ?
Eu1 O126 C50 C12 175.1(6) . . . . ?
Eu1 N13 C25 C17 169.3(6) . . . . ?
Eu1 N13 C25 C51 -11.9(9) . . . . ?
Eu1 N13 C87 C24 -166.2(6) . . . . ?
Eu1 N15 C11 C65 173.3(6) . . . . ?
Eu1 N15 C51 C25 6.6(9) . . . . ?
Eu1 N15 C51 C46 -173.5(6) . . . . ?
O18 Eu1 O118 C37 -146.8(5) . . . 2 ?
O18 Eu1 O121 Eu1 156.9(2) . . . 2 ?
O18 Eu1 O121 C37 15.1(15) . . . . ?
O18 Eu1 O122 C50 106.1(8) . . . 2 ?
O18 Eu1 O124 C26 2.0(4) . . . . ?
O18 Eu1 O126 C50 -123.5(8) . . . . ?
O18 Eu1 N13 C25 106.4(6) . . . . ?
O18 Eu1 N13 C87 -82.1(6) . . . . ?
O18 Eu1 N15 C11 104.7(6) . . . . ?
O18 Eu1 N15 C51 -81.3(6) . . . . ?
O18 Eu1 C26 O124 -176.3(7) . . . . ?
O18 Eu1 C26 C1 72(7) . . . . ?
O118 Eu1 O18 C26 -125.8(5) . . . . ?
O118 Eu1 O121 Eu1 -8.9(3) . . . 2 ?
O118 Eu1 O121 C37 -150.7(15) . . . . ?
O118 Eu1 O122 C50 -101.2(8) . . . 2 ?
O118 Eu1 O124 C26 135.3(4) . . . . ?
O118 Eu1 O126 C50 91.8(8) . . . . ?
O118 Eu1 N13 C25 -68.1(6) . . . . ?
O118 Eu1 N13 C87 103.4(6) . . . . ?
O118 Eu1 N15 C11 -104.6(6) . . . . ?
O118 Eu1 N15 C51 69.4(6) . . . . ?
O118 Eu1 C26 O18 97.2(6) . . . . ?
O118 Eu1 C26 O124 -79.2(6) . . . . ?
O118 Eu1 C26 C1 170(7) . . . . ?
O121 Eu1 O18 C26 74.5(5) . . . . ?
O121 Eu1 O18 C26 125.6(5) 2 . . . ?
O121 Eu1 O118 C37 8.2(6) . . . 2 ?
O121 Eu1 O118 C37 -2.8(4) 2 . . 2 ?
O121 Eu1 O121 Eu1 -0.001(1) 2 . . 2 ?
O121 Eu1 O121 C37 -141.8(16) 2 . . . ?
O121 Eu1 O122 C50 29.8(7) . . . 2 ?
O121 Eu1 O122 C50 -48.2(7) 2 . . 2 ?
O121 Eu1 O124 C26 -94.2(4) . . . . ?
O121 Eu1 O124 C26 -141.2(4) 2 . . . ?
O121 Eu1 O126 C50 44.7(8) 2 . . . ?
O121 Eu1 O126 C50 -34.0(8) . . . . ?
O121 Eu1 N13 C25 -104.0(6) 2 . . . ?
O121 Eu1 N13 C25 165.6(5) . . . . ?
O121 Eu1 N13 C87 -22.9(8) . . . . ?
O121 Eu1 N13 C87 67.5(6) 2 . . . ?
O121 Eu1 N15 C11 22.9(8) . . . . ?
O121 Eu1 N15 C11 -85.3(6) 2 . . . ?
O121 Eu1 N15 C51 88.7(6) 2 . . . ?
O121 Eu1 N15 C51 -163.1(5) . . . . ?
O121 Eu1 C26 O18 -102.9(5) . . . . ?
O121 Eu1 C26 O18 -108.9(6) 2 . . . ?
O121 Eu1 C26 O124 74.8(7) 2 . . . ?
O121 Eu1 C26 O124 80.8(4) . . . . ?
O121 Eu1 C26 C1 -30(7) . . . . ?
O121 Eu1 C26 C1 -36(7) 2 . . . ?
O122 Eu1 O18 C26 3.4(5) . . . . ?
O122 Eu1 O118 C37 72.4(5) . . . 2 ?
O122 Eu1 O121 Eu1 -74.0(2) . . . 2 ?
O122 Eu1 O121 C37 144.2(15) . . . . ?
O122 Eu1 O124 C26 -173.5(5) . . . . ?
O122 Eu1 O126 C50 14.9(10) . . . . ?
O122 Eu1 N13 C25 -21.1(7) . . . . ?
O122 Eu1 N13 C87 150.4(6) . . . . ?
O122 Eu1 N15 C11 -23.6(6) . . . . ?
O122 Eu1 N15 C51 150.4(6) . . . . ?
O122 Eu1 C26 O18 -177.3(4) . . . . ?
O122 Eu1 C26 O124 6.4(4) . . . . ?
O122 Eu1 C26 C1 -105(7) . . . . ?
O124 Eu1 O18 C26 -2.0(4) . . . . ?
O124 Eu1 O118 C37 122.5(5) . . . 2 ?
O124 Eu1 O121 Eu1 -150.8(2) . . . 2 ?
O124 Eu1 O121 C37 67.3(15) . . . . ?
O124 Eu1 O122 C50 110.6(8) . . . 2 ?
O124 Eu1 O126 C50 -94.8(8) . . . . ?
O124 Eu1 N13 C25 68.0(6) . . . . ?
O124 Eu1 N13 C87 -120.5(6) . . . . ?
O124 Eu1 N15 C11 53.2(6) . . . . ?
O124 Eu1 N15 C51 -132.8(6) . . . . ?
O124 Eu1 C26 O18 176.3(7) . . . . ?
O124 Eu1 C26 C1 -111(7) . . . . ?
O126 Eu1 O18 C26 149.2(5) . . . . ?
O126 Eu1 O118 C37 -65.4(5) . . . 2 ?
O126 Eu1 O121 Eu1 74.5(2) . . . 2 ?
O126 Eu1 O121 C37 -67.3(15) . . . . ?
O126 Eu1 O122 C50 -18.5(9) . . . 2 ?
O126 Eu1 O124 C26 -34.7(5) . . . . ?
O126 Eu1 N13 C25 -167.4(6) . . . . ?
O126 Eu1 N13 C87 4.0(6) . . . . ?
O126 Eu1 N15 C11 -179.7(6) . . . . ?
O126 Eu1 N15 C51 -5.7(7) . . . . ?
O126 Eu1 C26 O18 -31.6(5) . . . . ?
O126 Eu1 C26 O124 152.1(4) . . . . ?
O126 Eu1 C26 C1 41(7) . . . . ?
N13 Eu1 O18 C26 -134.8(5) . . . . ?
N13 Eu1 O118 C37 -137.6(5) . . . 2 ?
N13 Eu1 O121 Eu1 101.4(3) . . . 2 ?
N13 Eu1 O121 C37 -40.4(17) . . . . ?
N13 Eu1 O122 C50 -146.2(7) . . . 2 ?
N13 Eu1 O124 C26 50.6(5) . . . . ?
N13 Eu1 O126 C50 161.5(9) . . . . ?
N13 Eu1 N15 C11 177.3(7) . . . . ?
N13 Eu1 N15 C51 -8.7(5) . . . . ?
N13 Eu1 C26 O18 42.9(5) . . . . ?
N13 Eu1 C26 O124 -133.4(4) . . . . ?
N13 Eu1 C26 C1 115(7) . . . . ?
N13 C25 C51 N15 3.8(11) . . . . ?
N13 C25 C51 C46 -176.1(7) . . . . ?
N15 Eu1 O18 C26 -72.4(5) . . . . ?
N15 Eu1 O118 C37 155.7(5) . . . 2 ?
N15 Eu1 O121 Eu1 -121.3(3) . . . 2 ?
N15 Eu1 O121 C37 96.9(15) . . . . ?
N15 Eu1 O122 C50 -174.5(8) . . . 2 ?
N15 Eu1 O124 C26 102.4(4) . . . . ?
N15 Eu1 O126 C50 158.8(8) . . . . ?
N15 Eu1 N13 C25 10.5(5) . . . . ?
N15 Eu1 N13 C87 -178.1(7) . . . . ?
N15 Eu1 C26 O18 104.8(5) . . . . ?
N15 Eu1 C26 O124 -71.5(4) . . . . ?
N15 Eu1 C26 C1 177(100) . . . . ?
N15 C11 C65 C29 -1.1(13) . . . . ?
C11 N15 C51 C25 -179.2(7) . . . . ?
C11 N15 C51 C46 0.7(11) . . . . ?
C17 C21 C24 C87 -5.8(12) . . . . ?
C17 C21 C47 C52 46.7(11) . . . . ?
C17 C21 C47 C56 -136.9(8) . . . . ?
C17 C25 C51 N15 -177.4(7) . . . . ?
C17 C25 C51 C46 2.7(11) . . . . ?
C17 C44 C78 C46 2.4(13) . . . . ?
C21 C17 C25 N13 -4.1(12) . . . . ?
C21 C17 C25 C51 177.1(7) . . . . ?
C21 C17 C44 C78 -179.7(8) . . . . ?
C21 C24 C87 N13 -1.1(13) . . . . ?
C21 C47 C52 C74 177.6(7) . . . . ?
C21 C47 C56 C95 -178.0(7) . . . . ?
C24 C21 C47 C52 -132.6(8) . . . . ?
C24 C21 C47 C56 43.8(11) . . . . ?
C25 N13 C87 C24 5.4(12) . . . . ?
C25 C17 C21 C24 8.2(11) . . . . ?
C25 C17 C21 C47 -171.2(7) . . . . ?
C25 C17 C44 C78 4.0(12) . . . . ?
C26 Eu1 O118 C37 163.7(5) . . . 2 ?
C26 Eu1 O121 Eu1 -177.4(3) . . . 2 ?
C26 Eu1 O121 C37 40.8(15) . . . . ?
C26 Eu1 O122 C50 107.6(8) . . . 2 ?
C26 Eu1 O126 C50 -109.9(8) . . . . ?
C26 Eu1 N13 C25 88.0(6) . . . . ?
C26 Eu1 N13 C87 -100.5(6) . . . . ?
C26 Eu1 N15 C11 79.2(6) . . . . ?
C26 Eu1 N15 C51 -106.8(6) . . . . ?
C29 C43 C70 C84 -179.5(8) . . . . ?
C29 C43 C97 C113 -179.7(7) . . . . ?
C29 C46 C51 N15 1.6(12) . . . . ?
C29 C46 C51 C25 -178.5(7) . . . . ?
C29 C46 C78 C44 175.9(8) . . . . ?
C37 Eu1 O18 C26 -170.5(6) 2 . . . ?
C37 Eu1 O121 Eu1 -5.3(2) 2 . . 2 ?
C37 Eu1 O121 C37 -147.2(14) 2 . . . ?
C37 Eu1 O122 C50 -76.0(8) 2 . . 2 ?
C37 Eu1 O124 C26 175.2(4) 2 . . . ?
C37 Eu1 O126 C50 68.9(8) 2 . . . ?
C37 Eu1 N13 C25 -84.7(6) 2 . . . ?
C37 Eu1 N13 C87 86.8(6) 2 . . . ?
C37 Eu1 N15 C11 -94.5(6) 2 . . . ?
C37 Eu1 N15 C51 79.5(6) 2 . . . ?
C37 Eu1 C26 O18 156.8(14) 2 . . . ?
C37 Eu1 C26 O124 -19.5(18) 2 . . . ?
C37 Eu1 C26 C1 -131(7) 2 . . . ?
C43 C29 C46 C51 177.9(7) . . . . ?
C43 C29 C46 C78 -4.2(12) . . . . ?
C43 C29 C65 C11 -178.1(7) . . . . ?
C43 C70 C84 C96 -1.6(13) . . . . ?
C43 C97 C113 C96 -0.1(13) . . . . ?
C44 C17 C21 C24 -168.1(8) . . . . ?
C44 C17 C21 C47 12.5(12) . . . . ?
C44 C17 C25 N13 172.4(7) . . . . ?
C44 C17 C25 C51 -6.4(11) . . . . ?
C46 C29 C43 C70 128.3(8) . . . . ?
C46 C29 C43 C97 -53.2(11) . . . . ?
C46 C29 C65 C11 3.3(12) . . . . ?
C47 C21 C24 C87 173.5(7) . . . . ?
C47 C52 C74 C76 -0.1(12) . . . . ?
C47 C56 C95 C76 1.2(12) . . . . ?
C51 N15 C11 C65 -1.0(12) . . . . ?
C51 C46 C78 C44 -6.1(12) . . . . ?
C52 C47 C56 C95 -1.6(11) . . . . ?
C52 C74 C76 C95 -0.3(12) . . . . ?
C56 C47 C52 C74 1.1(11) . . . . ?
C65 C29 C43 C70 -50.2(11) . . . . ?
C65 C29 C43 C97 128.2(9) . . . . ?
C65 C29 C46 C51 -3.5(11) . . . . ?
C65 C29 C46 C78 174.4(8) . . . . ?
C70 C43 C97 C113 -1.2(12) . . . . ?
C70 C84 C96 C113 0.2(14) . . . . ?
C74 C76 C95 C56 -0.3(12) . . . . ?
C78 C46 C51 N15 -176.4(7) . . . . ?
C78 C46 C51 C25 3.5(11) . . . . ?
C84 C96 C113 C97 0.6(14) . . . . ?
C87 N13 C25 C17 -2.7(11) . . . . ?
C87 N13 C25 C51 176.1(7) . . . . ?
C97 C43 C70 C84 2.1(12) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a_CCDC2
_database_code_depnum_ccdc_archive 'CCDC 2089886'
loop_
_audit_author_name
_audit_author_address
'Alexander Goloveshkin'
;Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2021-06-14 deposited with the CCDC.	2021-08-09 downloaded from the CCDC.
;
_audit_creation_date             2021-06-14
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C78 H86 Eu2 N4 O12, 2(C2 H6 O)'
_chemical_formula_sum            'C82 H98 Eu2 N4 O14'
_chemical_formula_weight         1667.56
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.2202(5)
_cell_length_b                   14.2180(6)
_cell_length_c                   23.2725(10)
_cell_angle_alpha                100.3430(10)
_cell_angle_beta                 90.8000(10)
_cell_angle_gamma                100.0040(10)
_cell_volume                     3913.1(3)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9117
_cell_measurement_temperature    120
_cell_measurement_theta_max      30.38
_cell_measurement_theta_min      2.30
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.653
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6098
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0687 before and 0.0525 after correction.
The Ratio of minimum to maximum transmission is 0.8173.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.415
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1712
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.14
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0669
_diffrn_reflns_av_unetI/netI     0.0965
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            46343
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.282
_diffrn_reflns_theta_min         0.890
_diffrn_ambient_temperature      120
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                12711
_reflns_number_total             19411
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'XS n/a (Sheldrick, 2008)'
_refine_diff_density_max         2.318
_refine_diff_density_min         -1.306
_refine_diff_density_rms         0.137
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.974
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1196
_refine_ls_number_reflns         19411
_refine_ls_number_restraints     1124
_refine_ls_R_factor_all          0.0930
_refine_ls_R_factor_gt           0.0483
_refine_ls_restrained_S_all      0.987
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0524P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1000
_refine_ls_wR_factor_ref         0.1161
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2. Restrained distances
 C51A-C50B = C91A-C88A = C91A-C51A = C52B-C50B = C52B-C48B = C88A-C48B
 1.4 with sigma of 0.01
 C91B-C51B = C91B-C88B = C88B-C48A = C52A-C48A = C52A-C50A = C51B-C50A
 1.4 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
C48B \\sim C50B \\sim C51B \\sim C52B \\sim C88B \\sim C91B \\sim C48A \\sim
C50A \\sim C51A \\sim C52A \\sim C88A \\sim C91A \\sim C84: within 2A with
sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C7 \\sim C16 \\sim C18 \\sim C47 \\sim C58: within 2A with sigma of 0.01 and
sigma for terminal atoms of 0.02 within 2A
C1B \\sim C32B \\sim C66 \\sim C90B \\sim C2B \\sim C2A \\sim C1A \\sim C90A
\\sim C32A: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
within 2A
C5B \\sim C10B \\sim C27B \\sim C67 \\sim C4 \\sim C5A \\sim C5 \\sim C10A
\\sim C27A: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
within 2A
C3B \\sim C69B \\sim C87B \\sim C92B \\sim C3A \\sim C92A \\sim C69A \\sim C19:
within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C19 \\sim C3B \\sim C69B \\sim C87B \\sim C92B \\sim C3A \\sim C92A \\sim C69A
\\sim C87A: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
within 2A
C6B \\sim C40B \\sim C46 \\sim C49 \\sim C82B \\sim C6A \\sim C40A \\sim C82A
\\sim C60: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
within 2A
C18 \\sim C7 \\sim C47 \\sim C16: within 2A with sigma of 0.01 and sigma for
terminal atoms of 0.02 within 2A
C7 \\sim C18 \\sim C16 \\sim C47 \\sim C58: within 2A with sigma of 0.001 and
sigma for terminal atoms of 0.002 within 2A
O1 \\sim H1 \\sim C3 \\sim C1 \\sim C2 \\sim H3A \\sim H3B \\sim H1A \\sim H1B
\\sim C6 \\sim H2A \\sim H2B \\sim H2C \\sim H6A \\sim H6B \\sim H6C: within 2A
with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C22 \\sim C34B \\sim C37 \\sim H37 \\sim C78B \\sim C79B \\sim C81 \\sim C83B
\\sim C85B \\sim C86B \\sim C78A \\sim C83A \\sim C86A \\sim C85A \\sim C79A
\\sim C34A \\sim C30: within 2A with sigma of 0.01 and sigma for terminal atoms
of 0.02 within 2A
O52 \\sim C58: within 2A with sigma of 0.01 and sigma for terminal atoms of
0.02 within 2A
C58 \\sim O52: within 2A with sigma of 0.001 and sigma for terminal atoms of
0.002 within 2A
Uanis(C10B) = Uanis(C27B)
Uanis(C3) = Uanis(O1) = Uanis(C2)
Uanis(C8) = Uanis(O39) = Uanis(C54)
4. Others
 Sof(C1B)=Sof(H1BA)=Sof(H1BB)=Sof(H1BC)=Sof(C5B)=Sof(H5BA)=Sof(H5BB)=Sof(H5BC)=
 Sof(C32B)=Sof(C48B)=Sof(H48B)=Sof(C50B)=Sof(H50B)=Sof(C52B)=Sof(H52B)=
 Sof(C90B)=Sof(H90A)=Sof(H90B)=Sof(H90C)=Sof(C4)=Sof(H4A)=Sof(H4B)=Sof(H4C)=
 Sof(C51A)=Sof(H51A)=Sof(C88A)=Sof(C91A)=Sof(H91A)=Sof(C2A)=Sof(H2AA)=Sof(H2AB)=
 Sof(H2AC)=Sof(C10A)=Sof(C27A)=Sof(H27D)=Sof(H27E)=Sof(H27F)=Sof(C3A)=Sof(H3AA)=
 Sof(H3AB)=Sof(H3AC)=Sof(C92A)=Sof(H92D)=Sof(H92E)=Sof(H92F)=Sof(C69A)=
 Sof(C87A)=Sof(H87D)=Sof(H87E)=Sof(H87F)=Sof(C1)=Sof(H1A)=Sof(H1B)=Sof(C6)=
 Sof(H6A)=Sof(H6B)=Sof(H6C)=1-FVAR(1)
 Sof(C3B)=Sof(H3BA)=Sof(H3BB)=Sof(H3BC)=Sof(C10B)=Sof(C27B)=Sof(H27A)=
 Sof(H27B)=Sof(H27C)=Sof(C51B)=Sof(H51B)=Sof(C69B)=Sof(C87B)=Sof(H87A)=
 Sof(H87B)=Sof(H87C)=Sof(C88B)=Sof(C91B)=Sof(H91B)=Sof(C92B)=Sof(H92A)=
 Sof(H92B)=Sof(H92C)=Sof(C2B)=Sof(H2BA)=Sof(H2BB)=Sof(H2BC)=Sof(C48A)=Sof(H48A)=
 Sof(C50A)=Sof(H50A)=Sof(C52A)=Sof(H52A)=Sof(C1A)=Sof(H1AA)=Sof(H1AB)=Sof(H1AC)=
 Sof(C90A)=Sof(H90D)=Sof(H90E)=Sof(H90F)=Sof(C32A)=Sof(C5A)=Sof(H5AA)=Sof(H5AB)=
 Sof(H5AC)=Sof(C5)=Sof(H5A)=Sof(H5B)=Sof(H5C)=Sof(C2)=Sof(H2A)=Sof(H2B)=
 Sof(H2C)=Sof(C3)=Sof(H3A)=Sof(H3B)=FVAR(1)
 Sof(C6B)=Sof(H6BA)=Sof(H6BB)=Sof(H6BC)=Sof(C46)=Sof(H46A)=Sof(H46B)=Sof(H46C)=
 Sof(C82B)=Sof(H82A)=Sof(H82B)=Sof(H82C)=Sof(C40A)=1-FVAR(2)
 Sof(C40B)=Sof(C49)=Sof(H49A)=Sof(H49B)=Sof(H49C)=Sof(C6A)=Sof(H6AA)=Sof(H6AB)=
 Sof(H6AC)=Sof(C82A)=Sof(H82D)=Sof(H82E)=Sof(H82F)=FVAR(2)
 Sof(C34B)=Sof(C78B)=Sof(H78B)=Sof(C79B)=Sof(H79B)=Sof(C83B)=Sof(H83B)=
 Sof(C85B)=Sof(H85B)=Sof(C86B)=Sof(H86B)=1-FVAR(3)
 Sof(C78A)=Sof(H78A)=Sof(C83A)=Sof(H83A)=Sof(C86A)=Sof(H86A)=Sof(C85A)=
 Sof(H85A)=Sof(C79A)=Sof(H79A)=Sof(C34A)=FVAR(3)
5.a Riding coordinates:
 O1(H1)
5.b Secondary CH2 refined with riding coordinates:
 C8(H8A,H8B), C3(H3A,H3B), C1(H1A,H1B)
5.c Aromatic/amide H refined with riding coordinates:
 C9(H9), C11(H11), C20(H20), C21(H21), C22(H22), C25(H25), C26(H26), C31(H31),
 C37(H37), C38(H38), C41(H41), C44(H44), C48B(H48B), C50B(H50B), C51B(H51B),
 C52B(H52B), C56(H56), C59(H59), C68(H68), C71(H71), C73(H73), C74(H74),
 C75(H75), C76(H76), C77(H77), C78B(H78B), C79B(H79B), C80(H80), C83B(H83B),
 C85B(H85B), C86B(H86B), C91B(H91B), C48A(H48A), C50A(H50A), C51A(H51A),
 C52A(H52A), C91A(H91A), C78A(H78A), C83A(H83A), C86A(H86A), C85A(H85A),
 C79A(H79A)
5.d Idealised Me refined as rotating group:
 C1B(H1BA,H1BB,H1BC), C3B(H3BA,H3BB,H3BC), C5B(H5BA,H5BB,H5BC), C6B(H6BA,H6BB,
 H6BC), C7(H7A,H7B,H7C), C14(H14A,H14B,H14C), C16(H16A,H16B,H16C), C27B(H27A,
 H27B,H27C), C36(H36A,H36B,H36C), C43(H43A,H43B,H43C), C46(H46A,H46B,H46C),
 C47(H47A,H47B,H47C), C49(H49A,H49B,H49C), C82B(H82A,H82B,H82C), C87B(H87A,H87B,
 H87C), C90B(H90A,H90B,H90C), C92B(H92A,H92B,H92C), C2B(H2BA,H2BB,H2BC), C4(H4A,
 H4B,H4C), C54(H54A,H54B,H54C), C2A(H2AA,H2AB,H2AC), C1A(H1AA,H1AB,H1AC),
 C90A(H90D,H90E,H90F), C5A(H5AA,H5AB,H5AC), C5(H5A,H5B,H5C), C27A(H27D,H27E,
 H27F), C3A(H3AA,H3AB,H3AC), C92A(H92D,H92E,H92F), C87A(H87D,H87E,H87F),
 C6A(H6AA,H6AB,H6AC), C82A(H82D,H82E,H82F), C2(H2A,H2B,H2C), C6(H6A,H6B,H6C)
5.e Idealised tetrahedral OH refined as rotating group:
 O39(H39)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.14307(2) 0.37065(2) 0.22551(2) 0.01614(7) Uani 1 1 d . . . . .
Eu3 Eu 0.24333(2) 0.64563(2) 0.30178(2) 0.01927(7) Uani 1 1 d . . . . .
O46 O 0.3255(3) 0.4318(3) 0.19863(15) 0.0253(8) Uani 1 1 d . . . . .
O47 O 0.2692(3) 0.6804(2) 0.40988(15) 0.0265(8) Uani 1 1 d . . . . .
O48 O -0.0198(3) 0.2973(2) 0.15999(15) 0.0252(8) Uani 1 1 d . . . . .
O50 O 0.1315(3) 0.3392(3) 0.11468(16) 0.0297(9) Uani 1 1 d . . . . .
O52 O 0.4151(3) 0.7220(3) 0.35987(18) 0.0449(8) Uani 1 1 d . U . . .
O53 O 0.1195(3) 0.6836(2) 0.22921(17) 0.0318(9) Uani 1 1 d . . . . .
O54 O 0.2467(3) 0.3291(2) 0.30394(16) 0.0271(8) Uani 1 1 d . . . . .
O61 O 0.0196(3) 0.4213(2) 0.29969(14) 0.0197(7) Uani 1 1 d . . . . .
O62 O 0.0659(3) 0.5815(2) 0.33321(15) 0.0215(7) Uani 1 1 d . . . . .
O63 O 0.1206(2) 0.5266(2) 0.21186(14) 0.0181(7) Uani 1 1 d . . . . .
O64 O 0.2625(3) 0.4882(2) 0.31724(15) 0.0221(7) Uani 1 1 d . . . . .
O65 O 0.3670(3) 0.5920(3) 0.23124(17) 0.0277(8) Uani 1 1 d . . . . .
N49 N 0.1762(3) 0.8060(3) 0.34601(19) 0.0228(9) Uani 1 1 d . . . . .
N51 N 0.2091(3) 0.2092(3) 0.17909(18) 0.0241(9) Uani 1 1 d . . . . .
N55 N 0.3355(3) 0.8089(3) 0.26770(19) 0.0260(10) Uani 1 1 d . . . . .
N57 N 0.0367(4) 0.2054(3) 0.24892(19) 0.0274(10) Uani 1 1 d . . . . .
C1B C 0.4778(9) 0.4795(8) 0.3666(6) 0.039(3) Uani 0.501(4) 1 d . U P A 2
H1BA H 0.504374 0.452126 0.329794 0.058 Uiso 0.501(4) 1 calc R U P A 2
H1BB H 0.532618 0.483140 0.397194 0.058 Uiso 0.501(4) 1 calc R U P A 2
H1BC H 0.464063 0.543516 0.365139 0.058 Uiso 0.501(4) 1 calc R U P A 2
C3B C 0.0665(12) 0.1816(11) 0.0164(6) 0.048(4) Uani 0.499(4) 1 d . U P A 1
H3BA H 0.107489 0.143824 0.035892 0.072 Uiso 0.499(4) 1 calc R U P A 1
H3BB H 0.116320 0.236405 0.007221 0.072 Uiso 0.499(4) 1 calc R U P A 1
H3BC H 0.031087 0.142171 -0.019087 0.072 Uiso 0.499(4) 1 calc R U P A 1
C5B C 0.5725(8) 0.6141(8) 0.1827(5) 0.027(2) Uani 0.501(4) 1 d . U P A 2
H5BA H 0.564434 0.669027 0.211961 0.041 Uiso 0.501(4) 1 calc R U P A 2
H5BB H 0.536773 0.618548 0.146521 0.041 Uiso 0.501(4) 1 calc R U P A 2
H5BC H 0.650072 0.613395 0.177173 0.041 Uiso 0.501(4) 1 calc R U P A 2
C6B C -0.1420(9) 0.5773(8) 0.3789(5) 0.021(2) Uani 0.459(8) 1 d . U P B 2
H6BA H -0.173907 0.569080 0.339960 0.032 Uiso 0.459(8) 1 calc R U P B 2
H6BB H -0.096302 0.640477 0.389135 0.032 Uiso 0.459(8) 1 calc R U P B 2
H6BC H -0.200349 0.571059 0.405843 0.032 Uiso 0.459(8) 1 calc R U P B 2
C7 C 0.5501(6) 0.7877(6) 0.4633(3) 0.0602(12) Uani 1 1 d . U . . .
H7A H 0.585420 0.825933 0.499092 0.090 Uiso 1 1 calc R U . . .
H7B H 0.577602 0.816979 0.430973 0.090 Uiso 1 1 calc R U . . .
H7C H 0.566356 0.723184 0.458605 0.090 Uiso 1 1 calc R U . . .
C9 C 0.0508(7) 1.2266(5) 0.4676(3) 0.063(2) Uani 1 1 d . . . . .
H9 H 0.093518 1.286587 0.483668 0.076 Uiso 1 1 calc R U . . .
C10B C 0.5033(10) 0.5080(9) 0.1724(6) 0.0270(19) Uani 0.499(4) 1 d . U P A 1
C11 C -0.0624(7) 1.2141(5) 0.4670(3) 0.064(2) Uani 1 1 d . . . . .
H11 H -0.096647 1.266429 0.481509 0.077 Uiso 1 1 calc R U . . .
C12 C 0.2131(4) 0.8931(4) 0.3297(2) 0.0270(12) Uani 1 1 d . . . . .
C13 C 0.3021(4) 0.8943(3) 0.2890(2) 0.0244(11) Uani 1 1 d . . . . .
C14 C -0.0480(5) 0.6809(4) 0.1507(2) 0.0332(13) Uani 1 1 d . . . . .
H14A H 0.014254 0.726841 0.142321 0.050 Uiso 1 1 calc R U . . .
H14B H -0.077385 0.706191 0.187160 0.050 Uiso 1 1 calc R U . . .
H14C H -0.104633 0.669731 0.119992 0.050 Uiso 1 1 calc R U . . .
C15 C 0.1467(4) 0.1204(4) 0.1806(2) 0.0240(11) Uani 1 1 d . . . . .
C16 C 0.3818(5) 0.7457(5) 0.5179(3) 0.0464(11) Uani 1 1 d . U . . .
H16A H 0.391980 0.679690 0.515522 0.070 Uiso 1 1 calc R U . . .
H16B H 0.303898 0.748395 0.519326 0.070 Uiso 1 1 calc R U . . .
H16C H 0.420130 0.785068 0.552653 0.070 Uiso 1 1 calc R U . . .
C17 C 0.0545(5) 0.1189(4) 0.2181(2) 0.0270(12) Uani 1 1 d . . . . .
C18 C 0.4278(5) 0.7833(5) 0.4651(3) 0.0501(8) Uani 1 1 d . U . . .
C19 C 0.0329(4) 0.2913(4) 0.1140(2) 0.0231(10) Uani 1 1 d . U . . .
C20 C 0.4784(5) 0.8964(4) 0.2193(2) 0.0434(17) Uani 1 1 d . . . . .
H20 H 0.538338 0.893885 0.195289 0.052 Uiso 1 1 calc R U . . .
C21 C 0.3029(5) 1.0668(4) 0.2935(3) 0.0377(16) Uani 1 1 d . . . . .
H21 H 0.330770 1.124621 0.281128 0.045 Uiso 1 1 calc R U . . .
C22 C -0.0465(6) 0.2034(4) 0.2838(3) 0.0528(19) Uani 1 1 d . U . . .
H22 H -0.062203 0.262163 0.303372 0.063 Uiso 1 1 calc R U . . .
C23 C 0.1725(4) 0.9786(4) 0.3517(3) 0.0328(14) Uani 1 1 d . . . . .
C24 C 0.1692(5) 0.0327(4) 0.1472(2) 0.0297(12) Uani 1 1 d . . . . .
C25 C 0.0047(6) -0.0568(4) 0.1826(2) 0.0379(15) Uani 1 1 d . . . . .
H25 H -0.044274 -0.115115 0.181415 0.045 Uiso 1 1 calc R U . . .
C26 C 0.2167(5) 1.0646(4) 0.3285(3) 0.0416(17) Uani 1 1 d . . . . .
H26 H 0.184508 1.119645 0.338103 0.050 Uiso 1 1 calc R U . . .
C27B C 0.5232(16) 0.4088(12) 0.1484(9) 0.0270(19) Uani 0.499(4) 1 d . U P A 1
H27A H 0.512432 0.369659 0.178160 0.041 Uiso 0.499(4) 1 calc R U P A 1
H27B H 0.598015 0.412440 0.135821 0.041 Uiso 0.499(4) 1 calc R U P A 1
H27C H 0.471976 0.380207 0.115791 0.041 Uiso 0.499(4) 1 calc R U P A 1
C28 C 0.4501(5) 0.9849(4) 0.2415(2) 0.0352(14) Uani 1 1 d . . . . .
C29 C 0.3538(5) 0.9843(4) 0.2745(2) 0.0302(13) Uani 1 1 d . . . . .
C30 C -0.0134(5) 0.0286(4) 0.2221(2) 0.0345(13) Uani 1 1 d . U . . .
C31 C 0.3271(5) 0.1290(6) 0.1141(3) 0.056(2) Uani 1 1 d . . . . .
H31 H 0.390369 0.134849 0.092372 0.067 Uiso 1 1 calc R U . . .
C32B C 0.3696(10) 0.4151(9) 0.3786(6) 0.025(2) Uani 0.501(4) 1 d . U P A 2
C33 C 0.0397(5) 1.0587(4) 0.4197(3) 0.0406(16) Uani 1 1 d . . . . .
C34B C -0.1808(14) -0.0571(11) 0.2775(7) 0.025(2) Uani 0.482(13) 1 d . U P C 2
C35 C 0.0909(4) 0.9744(4) 0.3939(3) 0.0348(14) Uani 1 1 d . . . . .
C36 C 0.0352(7) 0.5450(5) 0.0961(3) 0.063(2) Uani 1 1 d . . . . .
H36A H 0.057265 0.484034 0.098109 0.095 Uiso 1 1 calc R U . . .
H36B H 0.098353 0.590244 0.087904 0.095 Uiso 1 1 calc R U . . .
H36C H -0.021495 0.535513 0.065604 0.095 Uiso 1 1 calc R U . . .
C37 C -0.1135(6) 0.1167(4) 0.2931(3) 0.0599(18) Uani 1 1 d . U . . .
H37 H -0.169796 0.119275 0.319512 0.072 Uiso 1 1 calc R U . . .
C38 C 0.0917(5) -0.0542(4) 0.1469(2) 0.0349(14) Uani 1 1 d . . . . .
H38 H 0.100812 -0.110755 0.121726 0.042 Uiso 1 1 calc R U . . .
C40B C -0.1038(10) 0.4938(11) 0.3682(6) 0.023(2) Uani 0.541(8) 1 d . U P B 1
C41 C 0.5541(6) 1.1518(4) 0.2796(3) 0.0498(18) Uani 1 1 d . . . . .
H41 H 0.523264 1.147608 0.315526 0.060 Uiso 1 1 calc R U . . .
C42 C 0.5235(6) 1.0761(4) 0.2323(3) 0.0443(17) Uani 1 1 d . . . . .
C43 C -0.1079(5) 0.5126(4) 0.1693(3) 0.0502(19) Uani 1 1 d . . . . .
H43A H -0.168168 0.505195 0.140996 0.075 Uiso 1 1 calc R U . . .
H43B H -0.131901 0.535539 0.207574 0.075 Uiso 1 1 calc R U . . .
H43C H -0.085315 0.450980 0.168454 0.075 Uiso 1 1 calc R U . . .
C44 C 0.1025(6) 1.1490(4) 0.4441(3) 0.0510(19) Uani 1 1 d . . . . .
H44 H 0.179755 1.157622 0.444782 0.061 Uiso 1 1 calc R U . . .
C45 C 0.0824(4) 0.6003(3) 0.2014(2) 0.0188(10) Uani 1 1 d . . . . .
C46 C -0.0011(9) 0.5177(7) 0.4382(4) 0.019(2) Uani 0.459(8) 1 d . U P B 2
H46A H -0.049453 0.516476 0.470365 0.029 Uiso 0.459(8) 1 calc R U P B 2
H46B H 0.046155 0.580224 0.442860 0.029 Uiso 0.459(8) 1 calc R U P B 2
H46C H 0.043773 0.468383 0.437501 0.029 Uiso 0.459(8) 1 calc R U P B 2
C47 C 0.3978(6) 0.8875(5) 0.4676(3) 0.0602(12) Uani 1 1 d . U . . .
H47A H 0.425577 0.928224 0.504199 0.090 Uiso 1 1 calc R U . . .
H47B H 0.318443 0.882103 0.464239 0.090 Uiso 1 1 calc R U . . .
H47C H 0.430981 0.915473 0.436034 0.090 Uiso 1 1 calc R U . . .
C48B C 0.3205(9) -0.1168(8) 0.0956(5) 0.033(2) Uani 0.501(4) 1 d D U P A 1
H48B H 0.294652 -0.121829 0.132498 0.040 Uiso 0.501(4) 1 calc R U P A 1
C49 C -0.2017(8) 0.4891(7) 0.3226(5) 0.030(2) Uani 0.541(8) 1 d . U P B 1
H49A H -0.193981 0.549694 0.309025 0.045 Uiso 0.541(8) 1 calc R U P B 1
H49B H -0.271420 0.477423 0.340911 0.045 Uiso 0.541(8) 1 calc R U P B 1
H49C H -0.199327 0.437397 0.290146 0.045 Uiso 0.541(8) 1 calc R U P B 1
C50B C 0.4079(11) -0.1851(9) 0.0098(5) 0.037(2) Uani 0.501(4) 1 d D U P A 1
H50B H 0.440881 -0.233810 -0.011353 0.045 Uiso 0.501(4) 1 calc R U P A 1
C51B C 0.3951(12) -0.1508(8) 0.0141(6) 0.040(2) Uani 0.499(4) 1 d D U P A 2
H51B H 0.429485 -0.153700 -0.021384 0.048 Uiso 0.499(4) 1 calc R U P A 2
C52B C 0.3665(9) -0.1924(8) 0.0646(5) 0.036(2) Uani 0.501(4) 1 d D U P A 1
H52B H 0.369618 -0.247548 0.080424 0.043 Uiso 0.501(4) 1 calc R U P A 1
C56 C 0.2960(4) 0.2127(5) 0.1456(3) 0.0405(16) Uani 1 1 d . . . . .
H56 H 0.337708 0.272943 0.143076 0.049 Uiso 1 1 calc R U . . .
C58 C 0.3684(5) 0.7236(5) 0.4080(3) 0.0463(8) Uani 1 1 d . U . . .
C59 C 0.4186(5) 0.8099(4) 0.2323(2) 0.0361(14) Uani 1 1 d . . . . .
H59 H 0.438264 0.751253 0.215263 0.043 Uiso 1 1 calc R U . . .
C60 C 0.0066(4) 0.5000(3) 0.3324(2) 0.0173(9) Uani 1 1 d . U . . .
C66 C 0.2838(4) 0.4119(4) 0.3331(2) 0.0239(11) Uani 1 1 d . U . . .
C67 C 0.3912(4) 0.5121(4) 0.2074(3) 0.0285(12) Uani 1 1 d . U . . .
C68 C 0.1002(4) 0.8051(4) 0.3855(3) 0.0297(13) Uani 1 1 d . . . . .
H68 H 0.074801 0.746552 0.397594 0.036 Uiso 1 1 calc R U . . .
C69B C -0.022(4) 0.2172(19) 0.0562(18) 0.029(3) Uani 0.499(4) 1 d . U P A 1
C70 C -0.0105(4) 0.5854(4) 0.1549(2) 0.0247(11) Uani 1 1 d . . . . .
C71 C 0.0550(4) 0.8857(4) 0.4106(3) 0.0351(14) Uani 1 1 d . . . . .
H71 H 0.001322 0.880036 0.438357 0.042 Uiso 1 1 calc R U . . .
C73 C 0.5698(7) 1.0841(5) 0.1796(3) 0.063(2) Uani 1 1 d . . . . .
H73 H 0.549037 1.034044 0.147645 0.076 Uiso 1 1 calc R U . . .
C74 C 0.6472(7) 1.1655(6) 0.1728(3) 0.076(3) Uani 1 1 d . . . . .
H74 H 0.678222 1.169206 0.136825 0.091 Uiso 1 1 calc R U . . .
C75 C 0.6771(7) 1.2404(6) 0.2199(4) 0.081(3) Uani 1 1 d . . . . .
H75 H 0.728369 1.294989 0.215648 0.097 Uiso 1 1 calc R U . . .
C76 C 0.6312(7) 1.2346(5) 0.2736(4) 0.068(2) Uani 1 1 d . . . . .
H76 H 0.651281 1.285060 0.305316 0.082 Uiso 1 1 calc R U . . .
C77 C -0.1264(6) 1.1251(5) 0.4452(3) 0.062(2) Uani 1 1 d . . . . .
H77 H -0.203504 1.117270 0.445612 0.074 Uiso 1 1 calc R U . . .
C78B C -0.3495(12) -0.1362(9) 0.3161(6) 0.025(2) Uani 0.482(13) 1 d . U P C 2
H78B H -0.422711 -0.136702 0.326560 0.030 Uiso 0.482(13) 1 calc R U P C 2
C79B C -0.2925(12) -0.0589(11) 0.2927(7) 0.027(2) Uani 0.482(13) 1 d . U P C 2
H79B H -0.328274 -0.008341 0.287108 0.032 Uiso 0.482(13) 1 calc R U P C 2
C80 C -0.0766(5) 1.0469(4) 0.4226(3) 0.0500(18) Uani 1 1 d . . . . .
H80 H -0.120269 0.986202 0.409275 0.060 Uiso 1 1 calc R U . . .
C81 C -0.0959(6) 0.0286(4) 0.2635(3) 0.0442(14) Uani 1 1 d . U . . .
C82B C -0.1516(15) 0.3977(16) 0.3740(7) 0.026(4) Uani 0.459(8) 1 d . U P B 2
H82A H -0.109619 0.347389 0.376775 0.039 Uiso 0.459(8) 1 calc R U P B 2
H82B H -0.190475 0.384090 0.336467 0.039 Uiso 0.459(8) 1 calc R U P B 2
H82C H -0.204303 0.400078 0.404206 0.039 Uiso 0.459(8) 1 calc R U P B 2
C83B C -0.2961(13) -0.2133(11) 0.3237(6) 0.025(2) Uani 0.482(13) 1 d . U P C 2
H83B H -0.334201 -0.263893 0.339991 0.030 Uiso 0.482(13) 1 calc R U P C 2
C84 C 0.2664(5) 0.0383(5) 0.1144(3) 0.0442(16) Uani 1 1 d . U . . .
C85B C -0.1316(13) -0.1359(11) 0.2849(6) 0.025(2) Uani 0.482(13) 1 d . U P C 2
H85B H -0.058445 -0.136163 0.274438 0.030 Uiso 0.482(13) 1 calc R U P C 2
C86B C -0.1891(15) -0.2153(10) 0.3077(6) 0.027(2) Uani 0.482(13) 1 d . U P C 2
H86B H -0.155015 -0.267540 0.311659 0.032 Uiso 0.482(13) 1 calc R U P C 2
C87B C -0.0947(14) 0.1262(19) 0.0734(11) 0.033(4) Uani 0.499(4) 1 d . U P A 1
H87A H -0.147828 0.146548 0.100752 0.049 Uiso 0.499(4) 1 calc R U P A 1
H87B H -0.048112 0.090300 0.090888 0.049 Uiso 0.499(4) 1 calc R U P A 1
H87C H -0.133260 0.085755 0.039018 0.049 Uiso 0.499(4) 1 calc R U P A 1
C88B C 0.2995(11) -0.0659(9) 0.0915(5) 0.033(2) Uani 0.499(4) 1 d D U P A 2
C90B C 0.3923(12) 0.3146(10) 0.3845(6) 0.034(3) Uani 0.501(4) 1 d . U P A 2
H90A H 0.420647 0.285077 0.348733 0.050 Uiso 0.501(4) 1 calc R U P A 2
H90B H 0.324408 0.274648 0.392255 0.050 Uiso 0.501(4) 1 calc R U P A 2
H90C H 0.446030 0.321200 0.416066 0.050 Uiso 0.501(4) 1 calc R U P A 2
C91B C 0.3542(9) -0.0672(8) 0.0392(5) 0.036(2) Uani 0.499(4) 1 d D U P A 2
H91B H 0.363567 -0.013230 0.021153 0.043 Uiso 0.499(4) 1 calc R U P A 2
C92B C -0.0926(15) 0.2730(15) 0.0255(8) 0.052(4) Uani 0.499(4) 1 d . U P A 1
H92A H -0.137003 0.229134 -0.005842 0.079 Uiso 0.499(4) 1 calc R U P A 1
H92B H -0.045215 0.322709 0.009922 0.079 Uiso 0.499(4) 1 calc R U P A 1
H92C H -0.140400 0.302245 0.052903 0.079 Uiso 0.499(4) 1 calc R U P A 1
O39 O 0.3444(7) 0.2112(6) -0.0176(3) 0.1126(19) Uani 1 1 d . . . . .
H39 H 0.340082 0.263628 0.002869 0.169 Uiso 1 1 calc R U . . .
C2B C 0.2484(10) 0.4596(8) 0.4425(5) 0.025(2) Uani 0.499(4) 1 d . U P A 1
H2BA H 0.234556 0.521894 0.437019 0.038 Uiso 0.499(4) 1 calc R U P A 1
H2BB H 0.276593 0.464365 0.481827 0.038 Uiso 0.499(4) 1 calc R U P A 1
H2BC H 0.180415 0.413072 0.435557 0.038 Uiso 0.499(4) 1 calc R U P A 1
C4 C 0.5695(8) 0.5149(9) 0.2618(5) 0.031(2) Uani 0.501(4) 1 d . U P A 2
H4A H 0.648861 0.522896 0.259567 0.046 Uiso 0.501(4) 1 calc R U P A 2
H4B H 0.541437 0.453239 0.272347 0.046 Uiso 0.501(4) 1 calc R U P A 2
H4C H 0.550915 0.566055 0.290826 0.046 Uiso 0.501(4) 1 calc R U P A 2
C8 C 0.3266(10) 0.2168(9) -0.0800(4) 0.1126(19) Uani 1 1 d . . . . .
H8A H 0.278452 0.262376 -0.085440 0.135 Uiso 1 1 calc R U . . .
H8B H 0.395654 0.231302 -0.099278 0.135 Uiso 1 1 calc R U . . .
C54 C 0.2716(9) 0.1156(8) -0.0973(5) 0.1126(19) Uani 1 1 d . . . . .
H54A H 0.245880 0.103817 -0.137541 0.169 Uiso 1 1 calc R U . . .
H54B H 0.209453 0.102846 -0.073297 0.169 Uiso 1 1 calc R U . . .
H54C H 0.323316 0.073662 -0.092404 0.169 Uiso 1 1 calc R U . . .
C48A C 0.2866(10) -0.1468(7) 0.1183(6) 0.037(2) Uani 0.499(4) 1 d D U P A 2
H48A H 0.251934 -0.144496 0.153715 0.044 Uiso 0.499(4) 1 calc R U P A 2
C50A C 0.3835(10) -0.2295(9) 0.0429(5) 0.045(2) Uani 0.499(4) 1 d D U P A 2
H50A H 0.416444 -0.282407 0.027981 0.055 Uiso 0.499(4) 1 calc R U P A 2
C51A C 0.3978(9) -0.1009(7) -0.0124(5) 0.035(2) Uani 0.501(4) 1 d D U P A 1
H51A H 0.424118 -0.095402 -0.049165 0.042 Uiso 0.501(4) 1 calc R U P A 1
C52A C 0.3242(9) -0.2312(8) 0.0934(5) 0.040(2) Uani 0.499(4) 1 d D U P A 2
H52A H 0.310200 -0.286762 0.109858 0.048 Uiso 0.499(4) 1 calc R U P A 2
C88A C 0.3120(10) -0.0340(8) 0.0731(5) 0.032(2) Uani 0.501(4) 1 d D U P A 1
C91A C 0.3505(9) -0.0258(8) 0.0180(5) 0.030(2) Uani 0.501(4) 1 d D U P A 1
H91A H 0.344720 0.028538 0.001890 0.036 Uiso 0.501(4) 1 calc R U P A 1
C2A C 0.3186(12) 0.4611(9) 0.4345(6) 0.034(3) Uani 0.501(4) 1 d . U P A 2
H2AA H 0.373641 0.476963 0.466227 0.051 Uiso 0.501(4) 1 calc R U P A 2
H2AB H 0.256567 0.415853 0.443860 0.051 Uiso 0.501(4) 1 calc R U P A 2
H2AC H 0.293870 0.519116 0.428297 0.051 Uiso 0.501(4) 1 calc R U P A 2
C1A C 0.4445(8) 0.5046(8) 0.4083(5) 0.026(2) Uani 0.499(4) 1 d . U P A 1
H1AA H 0.502801 0.479531 0.386622 0.039 Uiso 0.499(4) 1 calc R U P A 1
H1AB H 0.466463 0.520658 0.449122 0.039 Uiso 0.499(4) 1 calc R U P A 1
H1AC H 0.431034 0.561880 0.394966 0.039 Uiso 0.499(4) 1 calc R U P A 1
C90A C 0.3595(11) 0.3289(10) 0.4080(6) 0.030(3) Uani 0.499(4) 1 d . U P A 1
H90D H 0.292880 0.280910 0.399317 0.044 Uiso 0.499(4) 1 calc R U P A 1
H90E H 0.384222 0.333780 0.447903 0.044 Uiso 0.499(4) 1 calc R U P A 1
H90F H 0.416348 0.310123 0.382576 0.044 Uiso 0.499(4) 1 calc R U P A 1
C32A C 0.3360(9) 0.4262(9) 0.3986(6) 0.020(2) Uani 0.499(4) 1 d . U P A 1
C5A C 0.5909(9) 0.5649(10) 0.2172(6) 0.041(3) Uani 0.499(4) 1 d . U P A 1
H5AA H 0.595559 0.529971 0.248564 0.061 Uiso 0.499(4) 1 calc R U P A 1
H5AB H 0.571659 0.627033 0.232298 0.061 Uiso 0.499(4) 1 calc R U P A 1
H5AC H 0.661367 0.574097 0.199401 0.061 Uiso 0.499(4) 1 calc R U P A 1
C5 C 0.5000(10) 0.5611(10) 0.1211(5) 0.043(3) Uani 0.499(4) 1 d . U P A 1
H5A H 0.573344 0.574322 0.106739 0.064 Uiso 0.499(4) 1 calc R U P A 1
H5B H 0.474248 0.621183 0.133786 0.064 Uiso 0.499(4) 1 calc R U P A 1
H5C H 0.450440 0.521192 0.090409 0.064 Uiso 0.499(4) 1 calc R U P A 1
C10A C 0.5177(9) 0.5189(9) 0.2028(6) 0.025(2) Uani 0.501(4) 1 d . U P A 2
C27A C 0.5380(16) 0.4332(12) 0.1596(9) 0.036(4) Uani 0.501(4) 1 d . U P A 2
H27D H 0.500516 0.431926 0.122874 0.055 Uiso 0.501(4) 1 calc R U P A 2
H27E H 0.510037 0.374648 0.173809 0.055 Uiso 0.501(4) 1 calc R U P A 2
H27F H 0.616394 0.437861 0.154392 0.055 Uiso 0.501(4) 1 calc R U P A 2
C3A C 0.0564(11) 0.2411(11) 0.0085(6) 0.043(3) Uani 0.501(4) 1 d . U P A 2
H3AA H 0.021442 0.200457 -0.026667 0.065 Uiso 0.501(4) 1 calc R U P A 2
H3AB H 0.124202 0.220256 0.017672 0.065 Uiso 0.501(4) 1 calc R U P A 2
H3AC H 0.072847 0.307283 0.002976 0.065 Uiso 0.501(4) 1 calc R U P A 2
C92A C -0.1256(12) 0.2780(13) 0.0465(7) 0.033(3) Uani 0.501(4) 1 d . U P A 2
H92D H -0.101575 0.340126 0.035683 0.049 Uiso 0.501(4) 1 calc R U P A 2
H92E H -0.168100 0.285943 0.080873 0.049 Uiso 0.501(4) 1 calc R U P A 2
H92F H -0.171005 0.235482 0.015050 0.049 Uiso 0.501(4) 1 calc R U P A 2
C69A C -0.023(4) 0.2334(18) 0.0592(18) 0.029(3) Uani 0.501(4) 1 d . U P A 2
C87A C -0.0573(15) 0.134(2) 0.0684(12) 0.043(4) Uani 0.501(4) 1 d . U P A 2
H87D H -0.100790 0.096643 0.034751 0.064 Uiso 0.501(4) 1 calc R U P A 2
H87E H -0.101325 0.134712 0.102261 0.064 Uiso 0.501(4) 1 calc R U P A 2
H87F H 0.007091 0.106443 0.074222 0.064 Uiso 0.501(4) 1 calc R U P A 2
C6A C -0.1024(9) 0.5835(7) 0.4143(5) 0.033(3) Uani 0.541(8) 1 d . U P B 1
H6AA H -0.090845 0.639894 0.396278 0.050 Uiso 0.541(8) 1 calc R U P B 1
H6AB H -0.043328 0.588699 0.442910 0.050 Uiso 0.541(8) 1 calc R U P B 1
H6AC H -0.172252 0.578884 0.432895 0.050 Uiso 0.541(8) 1 calc R U P B 1
C40A C -0.0702(12) 0.4986(13) 0.3815(7) 0.019(2) Uani 0.459(8) 1 d . U P B 2
C82A C -0.1256(14) 0.4027(14) 0.3937(7) 0.029(3) Uani 0.541(8) 1 d . U P B 1
H82D H -0.187348 0.404722 0.418619 0.044 Uiso 0.541(8) 1 calc R U P B 1
H82E H -0.060747 0.398065 0.415995 0.044 Uiso 0.541(8) 1 calc R U P B 1
H82F H -0.142608 0.347261 0.362619 0.044 Uiso 0.541(8) 1 calc R U P B 1
O1 O 0.2985(4) 0.3824(4) 0.0414(2) 0.0704(10) Uani 1 1 d . U . . .
H1 H 0.248273 0.369262 0.063237 0.106 Uiso 1 1 d R U . A .
C2 C 0.2683(14) 0.5095(13) -0.0024(8) 0.0704(10) Uani 0.499(4) 1 d . U P A 2
H2A H 0.284379 0.472139 -0.038906 0.106 Uiso 0.499(4) 1 calc R U P A 2
H2B H 0.286830 0.577495 -0.003759 0.106 Uiso 0.499(4) 1 calc R U P A 2
H2C H 0.190626 0.493016 0.004359 0.106 Uiso 0.499(4) 1 calc R U P A 2
C3 C 0.3349(15) 0.4878(12) 0.0456(8) 0.0704(10) Uani 0.499(4) 1 d . U P A 2
H3A H 0.413975 0.503589 0.039802 0.084 Uiso 0.499(4) 1 calc R U P A 2
H3B H 0.318729 0.523244 0.083224 0.084 Uiso 0.499(4) 1 calc R U P A 2
C1 C 0.2470(16) 0.4623(14) 0.0191(8) 0.0800(18) Uani 0.501(4) 1 d . U P A 1
H1A H 0.170743 0.436425 0.004906 0.096 Uiso 0.501(4) 1 calc R U P A 1
H1B H 0.246365 0.516475 0.050999 0.096 Uiso 0.501(4) 1 calc R U P A 1
C6 C 0.3127(15) 0.4965(14) -0.0288(8) 0.082(3) Uani 0.501(4) 1 d . U P A 1
H6A H 0.308458 0.443915 -0.061442 0.124 Uiso 0.501(4) 1 calc R U P A 1
H6B H 0.388890 0.518996 -0.015189 0.124 Uiso 0.501(4) 1 calc R U P A 1
H6C H 0.283138 0.548754 -0.040611 0.124 Uiso 0.501(4) 1 calc R U P A 1
C78A C -0.3075(12) -0.1589(10) 0.3141(6) 0.028(2) Uani 0.518(13) 1 d . U P C 1
H78A H -0.381800 -0.164178 0.323435 0.033 Uiso 0.518(13) 1 calc R U P C 1
C83A C -0.2520(14) -0.2322(10) 0.3181(6) 0.026(2) Uani 0.518(13) 1 d . U P C 1
H83A H -0.287769 -0.287245 0.331043 0.032 Uiso 0.518(13) 1 calc R U P C 1
C86A C -0.1404(12) -0.2255(9) 0.3026(5) 0.027(2) Uani 0.518(13) 1 d . U P C 1
H86A H -0.103456 -0.276865 0.304508 0.032 Uiso 0.518(13) 1 calc R U P C 1
C85A C -0.0863(12) -0.1447(10) 0.2851(6) 0.025(2) Uani 0.518(13) 1 d . U P C 1
H85A H -0.011984 -0.140578 0.276004 0.030 Uiso 0.518(13) 1 calc R U P C 1
C79A C -0.2517(13) -0.0734(9) 0.2955(6) 0.025(2) Uani 0.518(13) 1 d . U P C 1
H79A H -0.288850 -0.022194 0.293375 0.030 Uiso 0.518(13) 1 calc R U P C 1
C34A C -0.1404(12) -0.0675(11) 0.2804(6) 0.027(2) Uani 0.518(13) 1 d . U P C 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Eu3 3.9648(4) . ?
Eu1 O46 2.383(3) . ?
Eu1 O48 2.449(3) . ?
Eu1 O50 2.535(4) . ?
Eu1 O54 2.422(3) . ?
Eu1 O61 2.404(3) . ?
Eu1 O63 2.357(3) . ?
Eu1 O64 2.695(3) . ?
Eu1 N51 2.620(4) . ?
Eu1 N57 2.631(4) . ?
Eu1 C19 2.853(5) . ?
Eu1 C66 2.927(5) . ?
Eu3 O47 2.480(4) . ?
Eu3 O52 2.453(4) . ?
Eu3 O53 2.444(3) . ?
Eu3 O62 2.381(3) . ?
Eu3 O63 2.693(3) . ?
Eu3 O64 2.380(3) . ?
Eu3 O65 2.362(4) . ?
Eu3 N49 2.601(4) . ?
Eu3 N55 2.657(4) . ?
Eu3 C45 2.937(5) . ?
Eu3 C58 2.828(6) . ?
O46 C67 1.258(6) . ?
O47 C58 1.266(7) . ?
O48 C19 1.254(6) . ?
O50 C19 1.275(6) . ?
O52 C58 1.263(8) . ?
O53 C45 1.247(6) . ?
O54 C66 1.253(6) . ?
O61 C60 1.271(5) . ?
O62 C60 1.252(5) . ?
O63 C45 1.279(5) . ?
O64 C66 1.272(6) . ?
O65 C67 1.257(6) . ?
N49 C12 1.364(6) . ?
N49 C68 1.316(7) . ?
N51 C15 1.363(7) . ?
N51 C56 1.324(6) . ?
N55 C13 1.360(7) . ?
N55 C59 1.317(7) . ?
N57 C17 1.363(6) . ?
N57 C22 1.309(7) . ?
C1B H1BA 0.9600 . ?
C1B H1BB 0.9600 . ?
C1B H1BC 0.9600 . ?
C1B C32B 1.532(16) . ?
C3B H3BA 0.9600 . ?
C3B H3BB 0.9600 . ?
C3B H3BC 0.9600 . ?
C3B C69B 1.52(4) . ?
C5B H5BA 0.9600 . ?
C5B H5BB 0.9600 . ?
C5B H5BC 0.9600 . ?
C5B C10A 1.555(14) . ?
C6B H6BA 0.9600 . ?
C6B H6BB 0.9600 . ?
C6B H6BC 0.9600 . ?
C6B C40A 1.54(2) . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C7 C18 1.486(9) . ?
C9 H9 0.9300 . ?
C9 C11 1.364(11) . ?
C9 C44 1.397(9) . ?
C10B C27B 1.483(19) . ?
C10B C67 1.608(12) . ?
C10B C5A 1.500(18) . ?
C10B C5 1.527(17) . ?
C11 H11 0.9300 . ?
C11 C77 1.373(10) . ?
C12 C13 1.453(8) . ?
C12 C23 1.406(7) . ?
C13 C29 1.425(6) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C14 C70 1.526(7) . ?
C15 C17 1.434(7) . ?
C15 C24 1.419(7) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C16 C18 1.505(9) . ?
C17 C30 1.421(7) . ?
C18 C47 1.578(10) . ?
C18 C58 1.538(8) . ?
C19 C69B 1.61(3) . ?
C19 C69A 1.47(4) . ?
C20 H20 0.9300 . ?
C20 C28 1.375(9) . ?
C20 C59 1.401(7) . ?
C21 H21 0.9300 . ?
C21 C26 1.340(9) . ?
C21 C29 1.426(8) . ?
C22 H22 0.9300 . ?
C22 C37 1.410(8) . ?
C23 C26 1.447(7) . ?
C23 C35 1.410(8) . ?
C24 C38 1.420(8) . ?
C24 C84 1.418(8) . ?
C25 H25 0.9300 . ?
C25 C30 1.438(7) . ?
C25 C38 1.358(8) . ?
C26 H26 0.9300 . ?
C27B H27A 0.9600 . ?
C27B H27B 0.9600 . ?
C27B H27C 0.9600 . ?
C28 C29 1.414(8) . ?
C28 C42 1.493(7) . ?
C30 C81 1.404(8) . ?
C31 H31 0.9300 . ?
C31 C56 1.397(8) . ?
C31 C84 1.373(9) . ?
C32B C66 1.470(13) . ?
C32B C90B 1.530(18) . ?
C32B C2A 1.538(17) . ?
C33 C35 1.483(8) . ?
C33 C44 1.394(7) . ?
C33 C80 1.406(8) . ?
C34B C79B 1.412(18) . ?
C34B C81 1.542(17) . ?
C34B C85B 1.395(17) . ?
C35 C71 1.387(7) . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C36 C70 1.537(8) . ?
C37 H37 0.9300 . ?
C37 C81 1.370(8) . ?
C38 H38 0.9300 . ?
C40B C49 1.573(15) . ?
C40B C60 1.593(14) . ?
C40B C6A 1.509(18) . ?
C40B C82A 1.50(3) . ?
C41 H41 0.9300 . ?
C41 C42 1.390(8) . ?
C41 C76 1.403(8) . ?
C42 C73 1.374(9) . ?
C43 H43A 0.9600 . ?
C43 H43B 0.9600 . ?
C43 H43C 0.9600 . ?
C43 C70 1.520(8) . ?
C44 H44 0.9300 . ?
C45 C70 1.518(7) . ?
C46 H46A 0.9600 . ?
C46 H46B 0.9600 . ?
C46 H46C 0.9600 . ?
C46 C40A 1.514(17) . ?
C47 H47A 0.9600 . ?
C47 H47B 0.9600 . ?
C47 H47C 0.9600 . ?
C48B H48B 0.9300 . ?
C48B C52B 1.390(9) . ?
C48B C88A 1.391(9) . ?
C49 H49A 0.9600 . ?
C49 H49B 0.9600 . ?
C49 H49C 0.9600 . ?
C50B H50B 0.9300 . ?
C50B C52B 1.395(9) . ?
C50B C51A 1.408(9) . ?
C51B H51B 0.9300 . ?
C51B C91B 1.403(9) . ?
C51B C50A 1.391(9) . ?
C52B H52B 0.9300 . ?
C56 H56 0.9300 . ?
C59 H59 0.9300 . ?
C60 C40A 1.488(16) . ?
C66 C32A 1.611(14) . ?
C67 C10A 1.539(12) . ?
C68 H68 0.9300 . ?
C68 C71 1.396(7) . ?
C69B C87B 1.56(4) . ?
C69B C92B 1.52(4) . ?
C71 H71 0.9300 . ?
C73 H73 0.9300 . ?
C73 C74 1.396(9) . ?
C74 H74 0.9300 . ?
C74 C75 1.380(11) . ?
C75 H75 0.9300 . ?
C75 C76 1.387(11) . ?
C76 H76 0.9300 . ?
C77 H77 0.9300 . ?
C77 C80 1.385(8) . ?
C78B H78B 0.9300 . ?
C78B C79B 1.396(18) . ?
C78B C83B 1.405(17) . ?
C79B H79B 0.9300 . ?
C80 H80 0.9300 . ?
C81 C34A 1.503(16) . ?
C82B H82A 0.9600 . ?
C82B H82B 0.9600 . ?
C82B H82C 0.9600 . ?
C82B C40A 1.58(3) . ?
C83B H83B 0.9300 . ?
C83B C86B 1.369(18) . ?
C84 C88B 1.603(14) . ?
C84 C88A 1.466(12) . ?
C85B H85B 0.9300 . ?
C85B C86B 1.414(19) . ?
C86B H86B 0.9300 . ?
C87B H87A 0.9600 . ?
C87B H87B 0.9600 . ?
C87B H87C 0.9600 . ?
C88B C91B 1.395(9) . ?
C88B C48A 1.392(9) . ?
C90B H90A 0.9600 . ?
C90B H90B 0.9600 . ?
C90B H90C 0.9600 . ?
C91B H91B 0.9300 . ?
C92B H92A 0.9600 . ?
C92B H92B 0.9600 . ?
C92B H92C 0.9600 . ?
O39 H39 0.8200 . ?
O39 C8 1.482(12) . ?
C2B H2BA 0.9600 . ?
C2B H2BB 0.9600 . ?
C2B H2BC 0.9600 . ?
C2B C32A 1.564(15) . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C4 C10A 1.519(16) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 C54 1.460(14) . ?
C54 H54A 0.9600 . ?
C54 H54B 0.9600 . ?
C54 H54C 0.9600 . ?
C48A H48A 0.9300 . ?
C48A C52A 1.391(9) . ?
C50A H50A 0.9300 . ?
C50A C52A 1.390(9) . ?
C51A H51A 0.9300 . ?
C51A C91A 1.390(8) . ?
C52A H52A 0.9300 . ?
C88A C91A 1.389(9) . ?
C91A H91A 0.9300 . ?
C2A H2AA 0.9600 . ?
C2A H2AB 0.9600 . ?
C2A H2AC 0.9600 . ?
C1A H1AA 0.9600 . ?
C1A H1AB 0.9600 . ?
C1A H1AC 0.9600 . ?
C1A C32A 1.562(15) . ?
C90A H90D 0.9600 . ?
C90A H90E 0.9600 . ?
C90A H90F 0.9600 . ?
C90A C32A 1.512(17) . ?
C5A H5AA 0.9600 . ?
C5A H5AB 0.9600 . ?
C5A H5AC 0.9600 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C10A C27A 1.49(2) . ?
C27A H27D 0.9600 . ?
C27A H27E 0.9600 . ?
C27A H27F 0.9600 . ?
C3A H3AA 0.9600 . ?
C3A H3AB 0.9600 . ?
C3A H3AC 0.9600 . ?
C3A C69A 1.54(5) . ?
C92A H92D 0.9600 . ?
C92A H92E 0.9600 . ?
C92A H92F 0.9600 . ?
C92A C69A 1.55(4) . ?
C69A C87A 1.45(4) . ?
C87A H87D 0.9600 . ?
C87A H87E 0.9600 . ?
C87A H87F 0.9600 . ?
C6A H6AA 0.9600 . ?
C6A H6AB 0.9600 . ?
C6A H6AC 0.9600 . ?
C82A H82D 0.9600 . ?
C82A H82E 0.9600 . ?
C82A H82F 0.9600 . ?
O1 H1 0.8204 . ?
O1 C3 1.472(17) . ?
O1 C1 1.553(16) . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C2 C3 1.48(2) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C1 C6 1.49(2) . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C78A H78A 0.9300 . ?
C78A C83A 1.355(17) . ?
C78A C79A 1.428(18) . ?
C83A H83A 0.9300 . ?
C83A C86A 1.406(16) . ?
C86A H86A 0.9300 . ?
C86A C85A 1.355(16) . ?
C85A H85A 0.9300 . ?
C85A C34A 1.395(17) . ?
C79A H79A 0.9300 . ?
C79A C34A 1.401(17) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O46 Eu1 Eu3 68.66(9) . . ?
O46 Eu1 O48 127.27(11) . . ?
O46 Eu1 O50 75.29(11) . . ?
O46 Eu1 O54 81.95(12) . . ?
O46 Eu1 O61 136.05(12) . . ?
O46 Eu1 O64 68.97(11) . . ?
O46 Eu1 N51 78.95(12) . . ?
O46 Eu1 N57 136.55(13) . . ?
O46 Eu1 C19 101.64(13) . . ?
O46 Eu1 C66 74.16(12) . . ?
O48 Eu1 Eu3 129.45(8) . . ?
O48 Eu1 O50 52.00(11) . . ?
O48 Eu1 O64 157.84(11) . . ?
O48 Eu1 N51 81.54(12) . . ?
O48 Eu1 N57 66.17(13) . . ?
O48 Eu1 C19 25.94(12) . . ?
O48 Eu1 C66 157.07(12) . . ?
O50 Eu1 Eu3 115.37(8) . . ?
O50 Eu1 O64 140.91(10) . . ?
O50 Eu1 N51 67.13(12) . . ?
O50 Eu1 N57 102.29(13) . . ?
O50 Eu1 C19 26.54(12) . . ?
O50 Eu1 C66 147.73(12) . . ?
O54 Eu1 Eu3 86.47(8) . . ?
O54 Eu1 O48 137.97(12) . . ?
O54 Eu1 O50 138.77(12) . . ?
O54 Eu1 O64 50.60(11) . . ?
O54 Eu1 N51 75.13(12) . . ?
O54 Eu1 N57 71.99(13) . . ?
O54 Eu1 C19 142.60(13) . . ?
O54 Eu1 C66 24.88(12) . . ?
O61 Eu1 Eu3 68.66(7) . . ?
O61 Eu1 O48 88.72(11) . . ?
O61 Eu1 O50 134.07(11) . . ?
O61 Eu1 O54 85.50(11) . . ?
O61 Eu1 O64 70.55(10) . . ?
O61 Eu1 N51 137.31(12) . . ?
O61 Eu1 N57 76.68(11) . . ?
O61 Eu1 C19 113.40(13) . . ?
O61 Eu1 C66 76.92(13) . . ?
O63 Eu1 Eu3 41.38(8) . . ?
O63 Eu1 O46 79.71(11) . . ?
O63 Eu1 O48 90.30(11) . . ?
O63 Eu1 O50 81.41(12) . . ?
O63 Eu1 O54 127.83(12) . . ?
O63 Eu1 O61 75.36(11) . . ?
O63 Eu1 O64 77.24(10) . . ?
O63 Eu1 N51 145.51(12) . . ?
O63 Eu1 N57 143.59(12) . . ?
O63 Eu1 C19 89.06(12) . . ?
O63 Eu1 C66 102.95(13) . . ?
O64 Eu1 Eu3 35.87(7) . . ?
O64 Eu1 C19 164.44(12) . . ?
O64 Eu1 C66 25.72(12) . . ?
N51 Eu1 Eu3 144.67(9) . . ?
N51 Eu1 O64 118.92(11) . . ?
N51 Eu1 N57 61.31(13) . . ?
N51 Eu1 C19 69.25(13) . . ?
N51 Eu1 C66 96.87(14) . . ?
N57 Eu1 Eu3 140.40(9) . . ?
N57 Eu1 O64 114.33(12) . . ?
N57 Eu1 C19 81.10(14) . . ?
N57 Eu1 C66 92.87(14) . . ?
C19 Eu1 Eu3 129.87(10) . . ?
C19 Eu1 C66 166.11(14) . . ?
C66 Eu1 Eu3 61.59(10) . . ?
O47 Eu3 Eu1 117.19(8) . . ?
O47 Eu3 O63 143.12(10) . . ?
O47 Eu3 N49 69.04(12) . . ?
O47 Eu3 N55 105.21(12) . . ?
O47 Eu3 C45 145.92(12) . . ?
O47 Eu3 C58 26.56(15) . . ?
O52 Eu3 Eu1 129.52(11) . . ?
O52 Eu3 O47 52.87(13) . . ?
O52 Eu3 O63 155.43(13) . . ?
O52 Eu3 N49 83.72(14) . . ?
O52 Eu3 N55 68.91(13) . . ?
O52 Eu3 C45 157.63(13) . . ?
O52 Eu3 C58 26.46(16) . . ?
O53 Eu3 Eu1 85.57(8) . . ?
O53 Eu3 O47 136.45(12) . . ?
O53 Eu3 O52 138.79(12) . . ?
O53 Eu3 O63 50.39(10) . . ?
O53 Eu3 N49 71.62(13) . . ?
O53 Eu3 N55 70.36(12) . . ?
O53 Eu3 C45 24.68(12) . . ?
O53 Eu3 C58 143.50(17) . . ?
O62 Eu3 Eu1 68.63(8) . . ?
O62 Eu3 O47 76.68(11) . . ?
O62 Eu3 O52 129.51(13) . . ?
O62 Eu3 O53 78.75(12) . . ?
O62 Eu3 O63 69.72(10) . . ?
O62 Eu3 N49 79.86(11) . . ?
O62 Eu3 N55 136.08(12) . . ?
O62 Eu3 C45 71.30(12) . . ?
O62 Eu3 C58 103.22(16) . . ?
O63 Eu3 Eu1 35.34(6) . . ?
O63 Eu3 C45 25.79(11) . . ?
O63 Eu3 C58 164.53(14) . . ?
O64 Eu3 Eu1 41.57(8) . . ?
O64 Eu3 O47 80.80(11) . . ?
O64 Eu3 O52 92.16(13) . . ?
O64 Eu3 O53 126.77(11) . . ?
O64 Eu3 O62 76.20(11) . . ?
O64 Eu3 O63 76.90(10) . . ?
O64 Eu3 N49 145.02(12) . . ?
O64 Eu3 N55 147.68(13) . . ?
O64 Eu3 C45 102.21(12) . . ?
O64 Eu3 C58 88.12(16) . . ?
O65 Eu3 Eu1 67.91(8) . . ?
O65 Eu3 O47 128.84(12) . . ?
O65 Eu3 O52 83.63(14) . . ?
O65 Eu3 O53 93.36(13) . . ?
O65 Eu3 O62 136.28(12) . . ?
O65 Eu3 O63 72.34(11) . . ?
O65 Eu3 O64 74.78(11) . . ?
O65 Eu3 N49 138.53(12) . . ?
O65 Eu3 N55 77.19(13) . . ?
O65 Eu3 C45 83.74(13) . . ?
O65 Eu3 C58 107.74(17) . . ?
N49 Eu3 Eu1 144.19(8) . . ?
N49 Eu3 O63 117.77(11) . . ?
N49 Eu3 N55 61.41(13) . . ?
N49 Eu3 C45 93.71(13) . . ?
N49 Eu3 C58 72.91(18) . . ?
N55 Eu3 Eu1 136.09(10) . . ?
N55 Eu3 O63 109.38(11) . . ?
N55 Eu3 C45 90.30(12) . . ?
N55 Eu3 C58 85.37(15) . . ?
C45 Eu3 Eu1 60.89(9) . . ?
C58 Eu3 Eu1 129.64(13) . . ?
C58 Eu3 C45 166.41(18) . . ?
C67 O46 Eu1 136.9(3) . . ?
C58 O47 Eu3 92.3(3) . . ?
C19 O48 Eu1 95.3(3) . . ?
C19 O50 Eu1 90.8(3) . . ?
C58 O52 Eu3 93.6(3) . . ?
C45 O53 Eu3 100.4(3) . . ?
C66 O54 Eu1 100.7(3) . . ?
C60 O61 Eu1 137.4(3) . . ?
C60 O62 Eu3 138.1(3) . . ?
Eu1 O63 Eu3 103.28(11) . . ?
C45 O63 Eu1 165.2(3) . . ?
C45 O63 Eu3 87.8(3) . . ?
Eu3 O64 Eu1 102.56(11) . . ?
C66 O64 Eu1 87.4(3) . . ?
C66 O64 Eu3 170.1(3) . . ?
C67 O65 Eu3 136.9(3) . . ?
C12 N49 Eu3 123.9(3) . . ?
C68 N49 Eu3 119.7(3) . . ?
C68 N49 C12 116.4(4) . . ?
C15 N51 Eu1 121.7(3) . . ?
C56 N51 Eu1 119.6(4) . . ?
C56 N51 C15 117.9(5) . . ?
C13 N55 Eu3 120.8(3) . . ?
C59 N55 Eu3 120.8(4) . . ?
C59 N55 C13 118.4(4) . . ?
C17 N57 Eu1 120.7(3) . . ?
C22 N57 Eu1 121.1(3) . . ?
C22 N57 C17 117.4(4) . . ?
H1BA C1B H1BB 109.5 . . ?
H1BA C1B H1BC 109.5 . . ?
H1BB C1B H1BC 109.5 . . ?
C32B C1B H1BA 109.5 . . ?
C32B C1B H1BB 109.5 . . ?
C32B C1B H1BC 109.5 . . ?
H3BA C3B H3BB 109.5 . . ?
H3BA C3B H3BC 109.5 . . ?
H3BB C3B H3BC 109.5 . . ?
C69B C3B H3BA 109.5 . . ?
C69B C3B H3BB 109.5 . . ?
C69B C3B H3BC 109.5 . . ?
H5BA C5B H5BB 109.5 . . ?
H5BA C5B H5BC 109.5 . . ?
H5BB C5B H5BC 109.5 . . ?
C10A C5B H5BA 109.5 . . ?
C10A C5B H5BB 109.5 . . ?
C10A C5B H5BC 109.5 . . ?
H6BA C6B H6BB 109.5 . . ?
H6BA C6B H6BC 109.5 . . ?
H6BB C6B H6BC 109.5 . . ?
C40A C6B H6BA 109.5 . . ?
C40A C6B H6BB 109.5 . . ?
C40A C6B H6BC 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C18 C7 H7A 109.5 . . ?
C18 C7 H7B 109.5 . . ?
C18 C7 H7C 109.5 . . ?
C11 C9 H9 120.1 . . ?
C11 C9 C44 119.8(6) . . ?
C44 C9 H9 120.1 . . ?
C27B C10B C67 115.0(10) . . ?
C27B C10B C5A 113.4(12) . . ?
C27B C10B C5 107.2(13) . . ?
C5A C10B C67 102.2(9) . . ?
C5A C10B C5 109.4(10) . . ?
C5 C10B C67 109.4(9) . . ?
C9 C11 H11 119.6 . . ?
C9 C11 C77 120.7(6) . . ?
C77 C11 H11 119.6 . . ?
N49 C12 C13 115.7(5) . . ?
N49 C12 C23 123.6(5) . . ?
C23 C12 C13 120.6(5) . . ?
N55 C13 C12 118.0(4) . . ?
N55 C13 C29 122.5(5) . . ?
C29 C13 C12 119.4(5) . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C70 C14 H14A 109.5 . . ?
C70 C14 H14B 109.5 . . ?
C70 C14 H14C 109.5 . . ?
N51 C15 C17 116.6(4) . . ?
N51 C15 C24 123.1(5) . . ?
C24 C15 C17 120.3(5) . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C16 H16A 109.5 . . ?
C18 C16 H16B 109.5 . . ?
C18 C16 H16C 109.5 . . ?
N57 C17 C15 117.7(5) . . ?
N57 C17 C30 122.8(5) . . ?
C30 C17 C15 119.5(5) . . ?
C7 C18 C16 111.7(5) . . ?
C7 C18 C47 110.7(6) . . ?
C7 C18 C58 111.0(6) . . ?
C16 C18 C47 107.5(6) . . ?
C16 C18 C58 111.8(5) . . ?
C58 C18 C47 103.8(5) . . ?
O48 C19 Eu1 58.7(3) . . ?
O48 C19 O50 119.7(5) . . ?
O48 C19 C69B 119.3(17) . . ?
O48 C19 C69A 119.3(18) . . ?
O50 C19 Eu1 62.7(3) . . ?
O50 C19 C69B 120.8(17) . . ?
O50 C19 C69A 120.9(18) . . ?
C69B C19 Eu1 163.0(13) . . ?
C69A C19 Eu1 169.7(14) . . ?
C28 C20 H20 119.4 . . ?
C28 C20 C59 121.3(6) . . ?
C59 C20 H20 119.4 . . ?
C26 C21 H21 118.6 . . ?
C26 C21 C29 122.8(5) . . ?
C29 C21 H21 118.6 . . ?
N57 C22 H22 118.3 . . ?
N57 C22 C37 123.4(5) . . ?
C37 C22 H22 118.3 . . ?
C12 C23 C26 117.2(6) . . ?
C12 C23 C35 118.1(5) . . ?
C35 C23 C26 124.7(5) . . ?
C15 C24 C38 118.3(5) . . ?
C84 C24 C15 117.6(5) . . ?
C84 C24 C38 124.1(5) . . ?
C30 C25 H25 119.3 . . ?
C38 C25 H25 119.3 . . ?
C38 C25 C30 121.4(5) . . ?
C21 C26 C23 121.7(6) . . ?
C21 C26 H26 119.2 . . ?
C23 C26 H26 119.2 . . ?
C10B C27B H27A 109.5 . . ?
C10B C27B H27B 109.5 . . ?
C10B C27B H27C 109.5 . . ?
H27A C27B H27B 109.5 . . ?
H27A C27B H27C 109.5 . . ?
H27B C27B H27C 109.5 . . ?
C20 C28 C29 117.2(5) . . ?
C20 C28 C42 119.6(6) . . ?
C29 C28 C42 123.2(6) . . ?
C13 C29 C21 117.3(5) . . ?
C28 C29 C13 117.8(5) . . ?
C28 C29 C21 124.9(5) . . ?
C17 C30 C25 118.0(5) . . ?
C81 C30 C17 118.0(5) . . ?
C81 C30 C25 124.0(5) . . ?
C56 C31 H31 119.2 . . ?
C84 C31 H31 119.2 . . ?
C84 C31 C56 121.6(6) . . ?
C1B C32B C2A 111.1(10) . . ?
C66 C32B C1B 109.9(9) . . ?
C66 C32B C90B 113.4(10) . . ?
C66 C32B C2A 102.7(9) . . ?
C90B C32B C1B 109.7(10) . . ?
C90B C32B C2A 109.9(10) . . ?
C44 C33 C35 122.7(5) . . ?
C44 C33 C80 117.9(5) . . ?
C80 C33 C35 119.3(5) . . ?
C79B C34B C81 128.6(11) . . ?
C85B C34B C79B 117.9(13) . . ?
C85B C34B C81 112.5(12) . . ?
C23 C35 C33 123.5(5) . . ?
C71 C35 C23 117.7(5) . . ?
C71 C35 C33 118.7(6) . . ?
H36A C36 H36B 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C70 C36 H36A 109.5 . . ?
C70 C36 H36B 109.5 . . ?
C70 C36 H36C 109.5 . . ?
C22 C37 H37 119.9 . . ?
C81 C37 C22 120.3(6) . . ?
C81 C37 H37 119.9 . . ?
C24 C38 H38 119.2 . . ?
C25 C38 C24 121.5(5) . . ?
C25 C38 H38 119.2 . . ?
C49 C40B C60 106.0(9) . . ?
C6A C40B C49 107.2(11) . . ?
C6A C40B C60 112.1(9) . . ?
C82A C40B C49 108.0(11) . . ?
C82A C40B C60 111.5(13) . . ?
C82A C40B C6A 111.8(13) . . ?
C42 C41 H41 119.7 . . ?
C42 C41 C76 120.7(6) . . ?
C76 C41 H41 119.7 . . ?
C41 C42 C28 119.4(5) . . ?
C73 C42 C28 121.7(6) . . ?
C73 C42 C41 118.7(5) . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C70 C43 H43A 109.5 . . ?
C70 C43 H43B 109.5 . . ?
C70 C43 H43C 109.5 . . ?
C9 C44 H44 119.6 . . ?
C33 C44 C9 120.8(6) . . ?
C33 C44 H44 119.6 . . ?
O53 C45 Eu3 54.9(2) . . ?
O53 C45 O63 121.0(4) . . ?
O53 C45 C70 119.9(4) . . ?
O63 C45 Eu3 66.4(2) . . ?
O63 C45 C70 119.0(4) . . ?
C70 C45 Eu3 172.1(3) . . ?
H46A C46 H46B 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C40A C46 H46A 109.5 . . ?
C40A C46 H46B 109.5 . . ?
C40A C46 H46C 109.5 . . ?
C18 C47 H47A 109.5 . . ?
C18 C47 H47B 109.5 . . ?
C18 C47 H47C 109.5 . . ?
H47A C47 H47B 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C52B C48B H48B 119.0 . . ?
C52B C48B C88A 122.1(11) . . ?
C88A C48B H48B 119.0 . . ?
C40B C49 H49A 109.5 . . ?
C40B C49 H49B 109.5 . . ?
C40B C49 H49C 109.5 . . ?
H49A C49 H49B 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C52B C50B H50B 121.3 . . ?
C52B C50B C51A 117.4(11) . . ?
C51A C50B H50B 121.3 . . ?
C91B C51B H51B 120.3 . . ?
C50A C51B H51B 120.3 . . ?
C50A C51B C91B 119.3(12) . . ?
C48B C52B C50B 119.6(11) . . ?
C48B C52B H52B 120.2 . . ?
C50B C52B H52B 120.2 . . ?
N51 C56 C31 122.3(6) . . ?
N51 C56 H56 118.9 . . ?
C31 C56 H56 118.9 . . ?
O47 C58 Eu3 61.2(3) . . ?
O47 C58 C18 118.4(6) . . ?
O52 C58 Eu3 59.9(3) . . ?
O52 C58 O47 120.6(5) . . ?
O52 C58 C18 120.9(5) . . ?
C18 C58 Eu3 169.3(5) . . ?
N55 C59 C20 122.3(6) . . ?
N55 C59 H59 118.8 . . ?
C20 C59 H59 118.8 . . ?
O61 C60 C40B 115.5(6) . . ?
O61 C60 C40A 120.7(8) . . ?
O62 C60 O61 125.2(4) . . ?
O62 C60 C40B 118.8(7) . . ?
O62 C60 C40A 113.3(7) . . ?
O54 C66 Eu1 54.4(2) . . ?
O54 C66 O64 121.3(5) . . ?
O54 C66 C32B 115.2(6) . . ?
O54 C66 C32A 121.4(6) . . ?
O64 C66 Eu1 66.9(3) . . ?
O64 C66 C32B 122.5(7) . . ?
O64 C66 C32A 115.9(6) . . ?
C32B C66 Eu1 165.7(6) . . ?
C32A C66 Eu1 167.3(5) . . ?
O46 C67 C10B 112.6(6) . . ?
O46 C67 C10A 122.0(6) . . ?
O65 C67 O46 125.2(5) . . ?
O65 C67 C10B 120.9(6) . . ?
O65 C67 C10A 111.5(6) . . ?
N49 C68 H68 117.7 . . ?
N49 C68 C71 124.7(5) . . ?
C71 C68 H68 117.7 . . ?
C3B C69B C19 112(3) . . ?
C3B C69B C87B 107.4(19) . . ?
C87B C69B C19 110(3) . . ?
C92B C69B C3B 111(3) . . ?
C92B C69B C19 106.0(17) . . ?
C92B C69B C87B 111(3) . . ?
C14 C70 C36 109.0(5) . . ?
C43 C70 C14 110.0(4) . . ?
C43 C70 C36 109.8(5) . . ?
C45 C70 C14 111.3(4) . . ?
C45 C70 C36 107.5(4) . . ?
C45 C70 C43 109.2(4) . . ?
C35 C71 C68 119.4(6) . . ?
C35 C71 H71 120.3 . . ?
C68 C71 H71 120.3 . . ?
C42 C73 H73 119.2 . . ?
C42 C73 C74 121.6(7) . . ?
C74 C73 H73 119.2 . . ?
C73 C74 H74 120.3 . . ?
C75 C74 C73 119.4(7) . . ?
C75 C74 H74 120.3 . . ?
C74 C75 H75 119.9 . . ?
C74 C75 C76 120.3(6) . . ?
C76 C75 H75 119.9 . . ?
C41 C76 H76 120.3 . . ?
C75 C76 C41 119.4(7) . . ?
C75 C76 H76 120.3 . . ?
C11 C77 H77 119.9 . . ?
C11 C77 C80 120.3(7) . . ?
C80 C77 H77 119.9 . . ?
C79B C78B H78B 120.0 . . ?
C79B C78B C83B 119.9(12) . . ?
C83B C78B H78B 120.0 . . ?
C34B C79B H79B 119.9 . . ?
C78B C79B C34B 120.2(12) . . ?
C78B C79B H79B 119.9 . . ?
C33 C80 H80 119.8 . . ?
C77 C80 C33 120.4(6) . . ?
C77 C80 H80 119.8 . . ?
C30 C81 C34B 129.5(7) . . ?
C30 C81 C34A 116.4(7) . . ?
C37 C81 C30 117.8(5) . . ?
C37 C81 C34B 112.5(8) . . ?
C37 C81 C34A 124.5(7) . . ?
H82A C82B H82B 109.5 . . ?
H82A C82B H82C 109.5 . . ?
H82B C82B H82C 109.5 . . ?
C40A C82B H82A 109.5 . . ?
C40A C82B H82B 109.5 . . ?
C40A C82B H82C 109.5 . . ?
C78B C83B H83B 119.4 . . ?
C86B C83B C78B 121.3(12) . . ?
C86B C83B H83B 119.4 . . ?
C24 C84 C88B 113.0(6) . . ?
C24 C84 C88A 132.8(7) . . ?
C31 C84 C24 117.4(5) . . ?
C31 C84 C88B 128.8(6) . . ?
C31 C84 C88A 109.4(7) . . ?
C34B C85B H85B 118.9 . . ?
C34B C85B C86B 122.3(13) . . ?
C86B C85B H85B 118.9 . . ?
C83B C86B C85B 118.3(12) . . ?
C83B C86B H86B 120.9 . . ?
C85B C86B H86B 120.9 . . ?
C69B C87B H87A 109.5 . . ?
C69B C87B H87B 109.5 . . ?
C69B C87B H87C 109.5 . . ?
H87A C87B H87B 109.5 . . ?
H87A C87B H87C 109.5 . . ?
H87B C87B H87C 109.5 . . ?
C91B C88B C84 111.2(9) . . ?
C48A C88B C84 128.8(9) . . ?
C48A C88B C91B 119.9(11) . . ?
C32B C90B H90A 109.5 . . ?
C32B C90B H90B 109.5 . . ?
C32B C90B H90C 109.5 . . ?
H90A C90B H90B 109.5 . . ?
H90A C90B H90C 109.5 . . ?
H90B C90B H90C 109.5 . . ?
C51B C91B H91B 120.3 . . ?
C88B C91B C51B 119.3(11) . . ?
C88B C91B H91B 120.3 . . ?
C69B C92B H92A 109.5 . . ?
C69B C92B H92B 109.5 . . ?
C69B C92B H92C 109.5 . . ?
H92A C92B H92B 109.5 . . ?
H92A C92B H92C 109.5 . . ?
H92B C92B H92C 109.5 . . ?
C8 O39 H39 109.5 . . ?
H2BA C2B H2BB 109.5 . . ?
H2BA C2B H2BC 109.5 . . ?
H2BB C2B H2BC 109.5 . . ?
C32A C2B H2BA 109.5 . . ?
C32A C2B H2BB 109.5 . . ?
C32A C2B H2BC 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C10A C4 H4A 109.5 . . ?
C10A C4 H4B 109.5 . . ?
C10A C4 H4C 109.5 . . ?
O39 C8 H8A 112.7 . . ?
O39 C8 H8B 112.7 . . ?
H8A C8 H8B 110.2 . . ?
C54 C8 O39 95.0(9) . . ?
C54 C8 H8A 112.7 . . ?
C54 C8 H8B 112.7 . . ?
C8 C54 H54A 109.5 . . ?
C8 C54 H54B 109.5 . . ?
C8 C54 H54C 109.5 . . ?
H54A C54 H54B 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C88B C48A H48A 119.2 . . ?
C52A C48A C88B 121.6(12) . . ?
C52A C48A H48A 119.2 . . ?
C51B C50A H50A 119.0 . . ?
C52A C50A C51B 121.9(12) . . ?
C52A C50A H50A 119.0 . . ?
C50B C51A H51A 118.4 . . ?
C91A C51A C50B 123.2(11) . . ?
C91A C51A H51A 118.4 . . ?
C48A C52A H52A 121.2 . . ?
C50A C52A C48A 117.6(12) . . ?
C50A C52A H52A 121.2 . . ?
C48B C88A C84 112.7(9) . . ?
C91A C88A C48B 119.4(10) . . ?
C91A C88A C84 127.8(9) . . ?
C51A C91A H91A 120.9 . . ?
C88A C91A C51A 118.2(11) . . ?
C88A C91A H91A 120.9 . . ?
C32B C2A H2AA 109.5 . . ?
C32B C2A H2AB 109.5 . . ?
C32B C2A H2AC 109.5 . . ?
H2AA C2A H2AB 109.5 . . ?
H2AA C2A H2AC 109.5 . . ?
H2AB C2A H2AC 109.5 . . ?
H1AA C1A H1AB 109.5 . . ?
H1AA C1A H1AC 109.5 . . ?
H1AB C1A H1AC 109.5 . . ?
C32A C1A H1AA 109.5 . . ?
C32A C1A H1AB 109.5 . . ?
C32A C1A H1AC 109.5 . . ?
H90D C90A H90E 109.5 . . ?
H90D C90A H90F 109.5 . . ?
H90E C90A H90F 109.5 . . ?
C32A C90A H90D 109.5 . . ?
C32A C90A H90E 109.5 . . ?
C32A C90A H90F 109.5 . . ?
C2B C32A C66 108.6(8) . . ?
C1A C32A C66 110.9(9) . . ?
C1A C32A C2B 109.2(10) . . ?
C90A C32A C66 107.7(10) . . ?
C90A C32A C2B 109.5(10) . . ?
C90A C32A C1A 110.9(9) . . ?
C10B C5A H5AA 109.5 . . ?
C10B C5A H5AB 109.5 . . ?
C10B C5A H5AC 109.5 . . ?
H5AA C5A H5AB 109.5 . . ?
H5AA C5A H5AC 109.5 . . ?
H5AB C5A H5AC 109.5 . . ?
C10B C5 H5A 109.5 . . ?
C10B C5 H5B 109.5 . . ?
C10B C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C67 C10A C5B 111.8(8) . . ?
C4 C10A C5B 109.4(10) . . ?
C4 C10A C67 109.4(8) . . ?
C27A C10A C5B 109.5(12) . . ?
C27A C10A C67 108.1(10) . . ?
C27A C10A C4 108.6(12) . . ?
C10A C27A H27D 109.5 . . ?
C10A C27A H27E 109.5 . . ?
C10A C27A H27F 109.5 . . ?
H27D C27A H27E 109.5 . . ?
H27D C27A H27F 109.5 . . ?
H27E C27A H27F 109.5 . . ?
H3AA C3A H3AB 109.5 . . ?
H3AA C3A H3AC 109.5 . . ?
H3AB C3A H3AC 109.5 . . ?
C69A C3A H3AA 109.5 . . ?
C69A C3A H3AB 109.5 . . ?
C69A C3A H3AC 109.5 . . ?
H92D C92A H92E 109.5 . . ?
H92D C92A H92F 109.5 . . ?
H92E C92A H92F 109.5 . . ?
C69A C92A H92D 109.5 . . ?
C69A C92A H92E 109.5 . . ?
C69A C92A H92F 109.5 . . ?
C19 C69A C3A 110(3) . . ?
C19 C69A C92A 107(2) . . ?
C3A C69A C92A 108(3) . . ?
C87A C69A C19 108(3) . . ?
C87A C69A C3A 113(2) . . ?
C87A C69A C92A 110(3) . . ?
C69A C87A H87D 109.5 . . ?
C69A C87A H87E 109.5 . . ?
C69A C87A H87F 109.5 . . ?
H87D C87A H87E 109.5 . . ?
H87D C87A H87F 109.5 . . ?
H87E C87A H87F 109.5 . . ?
C40B C6A H6AA 109.5 . . ?
C40B C6A H6AB 109.5 . . ?
C40B C6A H6AC 109.5 . . ?
H6AA C6A H6AB 109.5 . . ?
H6AA C6A H6AC 109.5 . . ?
H6AB C6A H6AC 109.5 . . ?
C6B C40A C82B 107.4(13) . . ?
C46 C40A C6B 112.3(12) . . ?
C46 C40A C82B 110.4(13) . . ?
C60 C40A C6B 107.6(11) . . ?
C60 C40A C46 108.4(10) . . ?
C60 C40A C82B 110.8(13) . . ?
C40B C82A H82D 109.5 . . ?
C40B C82A H82E 109.5 . . ?
C40B C82A H82F 109.5 . . ?
H82D C82A H82E 109.5 . . ?
H82D C82A H82F 109.5 . . ?
H82E C82A H82F 109.5 . . ?
C3 O1 H1 112.6 . . ?
C1 O1 H1 94.9 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C3 C2 H2A 109.5 . . ?
C3 C2 H2B 109.5 . . ?
C3 C2 H2C 109.5 . . ?
O1 C3 C2 102.8(15) . . ?
O1 C3 H3A 111.2 . . ?
O1 C3 H3B 111.2 . . ?
C2 C3 H3A 111.2 . . ?
C2 C3 H3B 111.2 . . ?
H3A C3 H3B 109.1 . . ?
O1 C1 H1A 109.7 . . ?
O1 C1 H1B 109.7 . . ?
H1A C1 H1B 108.2 . . ?
C6 C1 O1 110.0(11) . . ?
C6 C1 H1A 109.7 . . ?
C6 C1 H1B 109.7 . . ?
C1 C6 H6A 109.5 . . ?
C1 C6 H6B 109.5 . . ?
C1 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C83A C78A H78A 120.1 . . ?
C83A C78A C79A 119.8(12) . . ?
C79A C78A H78A 120.1 . . ?
C78A C83A H83A 119.9 . . ?
C78A C83A C86A 120.3(12) . . ?
C86A C83A H83A 119.9 . . ?
C83A C86A H86A 119.8 . . ?
C85A C86A C83A 120.5(12) . . ?
C85A C86A H86A 119.8 . . ?
C86A C85A H85A 119.5 . . ?
C86A C85A C34A 121.0(12) . . ?
C34A C85A H85A 119.5 . . ?
C78A C79A H79A 120.4 . . ?
C34A C79A C78A 119.3(11) . . ?
C34A C79A H79A 120.4 . . ?
C85A C34A C81 129.6(11) . . ?
C85A C34A C79A 119.0(12) . . ?
C79A C34A C81 111.3(11) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O46 C67 O65 -8.6(9) . . . . ?
Eu1 O46 C67 C10B -175.9(6) . . . . ?
Eu1 O46 C67 C10A 156.8(6) . . . . ?
Eu1 O48 C19 O50 -15.3(5) . . . . ?
Eu1 O48 C19 C69B 160.4(16) . . . . ?
Eu1 O48 C19 C69A 168.3(16) . . . . ?
Eu1 O50 C19 O48 14.7(5) . . . . ?
Eu1 O50 C19 C69B -160.9(16) . . . . ?
Eu1 O50 C19 C69A -169.0(16) . . . . ?
Eu1 O54 C66 O64 -0.3(5) . . . . ?
Eu1 O54 C66 C32B -168.6(6) . . . . ?
Eu1 O54 C66 C32A 165.6(6) . . . . ?
Eu1 O61 C60 O62 -0.3(8) . . . . ?
Eu1 O61 C60 C40B 171.1(6) . . . . ?
Eu1 O61 C60 C40A -169.2(7) . . . . ?
Eu1 O63 C45 Eu3 139.3(12) . . . . ?
Eu1 O63 C45 O53 145.0(10) . . . . ?
Eu1 O63 C45 C70 -34.2(15) . . . . ?
Eu1 O64 C66 O54 0.3(5) . . . . ?
Eu1 O64 C66 C32B 167.7(7) . . . . ?
Eu1 O64 C66 C32A -166.4(6) . . . . ?
Eu1 N51 C15 C17 -11.5(6) . . . . ?
Eu1 N51 C15 C24 168.2(4) . . . . ?
Eu1 N51 C56 C31 -172.2(5) . . . . ?
Eu1 N57 C17 C15 11.4(6) . . . . ?
Eu1 N57 C17 C30 -169.2(4) . . . . ?
Eu1 N57 C22 C37 173.3(6) . . . . ?
Eu1 C19 C69B C3B -73(7) . . . . ?
Eu1 C19 C69B C87B 46(8) . . . . ?
Eu1 C19 C69B C92B 165(3) . . . . ?
Eu1 C19 C69A C3A -107(10) . . . . ?
Eu1 C19 C69A C92A 136(8) . . . . ?
Eu1 C19 C69A C87A 17(13) . . . . ?
Eu1 C66 C32A C2B -36(3) . . . . ?
Eu1 C66 C32A C1A -155.9(19) . . . . ?
Eu1 C66 C32A C90A 82(3) . . . . ?
Eu3 O47 C58 O52 -8.4(6) . . . . ?
Eu3 O47 C58 C18 167.9(5) . . . . ?
Eu3 O52 C58 O47 8.5(7) . . . . ?
Eu3 O52 C58 C18 -167.7(6) . . . . ?
Eu3 O53 C45 O63 -6.4(5) . . . . ?
Eu3 O53 C45 C70 172.9(4) . . . . ?
Eu3 O62 C60 O61 -17.4(8) . . . . ?
Eu3 O62 C60 C40B 171.4(6) . . . . ?
Eu3 O62 C60 C40A 152.1(7) . . . . ?
Eu3 O63 C45 O53 5.7(4) . . . . ?
Eu3 O63 C45 C70 -173.6(4) . . . . ?
Eu3 O65 C67 O46 29.5(9) . . . . ?
Eu3 O65 C67 C10B -164.3(6) . . . . ?
Eu3 O65 C67 C10A -137.3(6) . . . . ?
Eu3 N49 C12 C13 -5.5(6) . . . . ?
Eu3 N49 C12 C23 176.7(4) . . . . ?
Eu3 N49 C68 C71 -177.5(4) . . . . ?
Eu3 N55 C13 C12 -1.4(6) . . . . ?
Eu3 N55 C13 C29 176.3(3) . . . . ?
Eu3 N55 C59 C20 -171.7(4) . . . . ?
O46 C67 C10A C5B 149.7(8) . . . . ?
O46 C67 C10A C4 -89.0(10) . . . . ?
O46 C67 C10A C27A 29.1(14) . . . . ?
O48 C19 C69B C3B -151.9(17) . . . . ?
O48 C19 C69B C87B -33(3) . . . . ?
O48 C19 C69B C92B 87(3) . . . . ?
O48 C19 C69A C3A 177.2(13) . . . . ?
O48 C19 C69A C92A 60(3) . . . . ?
O48 C19 C69A C87A -59(3) . . . . ?
O50 C19 C69B C3B 24(3) . . . . ?
O50 C19 C69B C87B 143(2) . . . . ?
O50 C19 C69B C92B -97(3) . . . . ?
O50 C19 C69A C3A 1(3) . . . . ?
O50 C19 C69A C92A -117(2) . . . . ?
O50 C19 C69A C87A 125(2) . . . . ?
O53 C45 C70 C14 -1.8(7) . . . . ?
O53 C45 C70 C36 117.5(5) . . . . ?
O53 C45 C70 C43 -123.4(5) . . . . ?
O54 C66 C32A C2B -102.8(9) . . . . ?
O54 C66 C32A C1A 137.2(7) . . . . ?
O54 C66 C32A C90A 15.7(11) . . . . ?
O61 C60 C40A C6B -133.6(9) . . . . ?
O61 C60 C40A C46 104.8(10) . . . . ?
O61 C60 C40A C82B -16.4(16) . . . . ?
O62 C60 C40A C6B 56.4(11) . . . . ?
O62 C60 C40A C46 -65.3(12) . . . . ?
O62 C60 C40A C82B 173.5(11) . . . . ?
O63 C45 C70 C14 177.5(4) . . . . ?
O63 C45 C70 C36 -63.2(6) . . . . ?
O63 C45 C70 C43 55.9(6) . . . . ?
O64 C66 C32A C2B 63.8(9) . . . . ?
O64 C66 C32A C1A -56.1(10) . . . . ?
O64 C66 C32A C90A -177.7(7) . . . . ?
O65 C67 C10A C5B -43.1(11) . . . . ?
O65 C67 C10A C4 78.3(9) . . . . ?
O65 C67 C10A C27A -163.6(11) . . . . ?
N49 C12 C13 N55 4.3(7) . . . . ?
N49 C12 C13 C29 -173.4(4) . . . . ?
N49 C12 C23 C26 -177.6(5) . . . . ?
N49 C12 C23 C35 1.5(8) . . . . ?
N49 C68 C71 C35 -0.1(9) . . . . ?
N51 C15 C17 N57 0.0(7) . . . . ?
N51 C15 C17 C30 -179.4(5) . . . . ?
N51 C15 C24 C38 -172.9(5) . . . . ?
N51 C15 C24 C84 5.0(7) . . . . ?
N55 C13 C29 C21 172.4(5) . . . . ?
N55 C13 C29 C28 -6.5(7) . . . . ?
N57 C17 C30 C25 172.8(5) . . . . ?
N57 C17 C30 C81 -5.7(9) . . . . ?
N57 C22 C37 C81 -2.4(13) . . . . ?
C1B C32B C66 Eu1 79(2) . . . . ?
C1B C32B C66 O54 119.5(9) . . . . ?
C1B C32B C66 O64 -48.7(12) . . . . ?
C7 C18 C58 Eu3 -123(2) . . . . ?
C7 C18 C58 O47 152.2(6) . . . . ?
C7 C18 C58 O52 -31.6(9) . . . . ?
C9 C11 C77 C80 -1.0(12) . . . . ?
C11 C9 C44 C33 0.3(11) . . . . ?
C11 C77 C80 C33 -2.4(12) . . . . ?
C12 N49 C68 C71 0.9(8) . . . . ?
C12 C13 C29 C21 -10.0(7) . . . . ?
C12 C13 C29 C28 171.1(5) . . . . ?
C12 C23 C26 C21 -8.6(8) . . . . ?
C12 C23 C35 C33 -178.8(5) . . . . ?
C12 C23 C35 C71 -0.6(8) . . . . ?
C13 N55 C59 C20 4.7(8) . . . . ?
C13 C12 C23 C26 4.8(7) . . . . ?
C13 C12 C23 C35 -176.1(5) . . . . ?
C15 N51 C56 C31 -2.3(8) . . . . ?
C15 C17 C30 C25 -7.8(8) . . . . ?
C15 C17 C30 C81 173.7(6) . . . . ?
C15 C24 C38 C25 -7.4(8) . . . . ?
C15 C24 C84 C31 -4.7(8) . . . . ?
C15 C24 C84 C88B 165.9(6) . . . . ?
C15 C24 C84 C88A -175.7(8) . . . . ?
C16 C18 C58 Eu3 112(2) . . . . ?
C16 C18 C58 O47 26.8(9) . . . . ?
C16 C18 C58 O52 -157.0(6) . . . . ?
C17 N57 C22 C37 3.6(11) . . . . ?
C17 C15 C24 C38 6.7(7) . . . . ?
C17 C15 C24 C84 -175.3(5) . . . . ?
C17 C30 C81 C34B 179.9(9) . . . . ?
C17 C30 C81 C37 6.7(10) . . . . ?
C17 C30 C81 C34A -161.0(8) . . . . ?
C20 C28 C29 C13 8.3(7) . . . . ?
C20 C28 C29 C21 -170.5(5) . . . . ?
C20 C28 C42 C41 -131.8(7) . . . . ?
C20 C28 C42 C73 42.3(9) . . . . ?
C22 N57 C17 C15 -178.9(6) . . . . ?
C22 N57 C17 C30 0.5(9) . . . . ?
C22 C37 C81 C30 -3.0(12) . . . . ?
C22 C37 C81 C34B -177.3(9) . . . . ?
C22 C37 C81 C34A 163.6(10) . . . . ?
C23 C12 C13 N55 -177.8(5) . . . . ?
C23 C12 C13 C29 4.4(7) . . . . ?
C23 C35 C71 C68 0.0(8) . . . . ?
C24 C15 C17 N57 -179.7(5) . . . . ?
C24 C15 C17 C30 0.9(8) . . . . ?
C24 C84 C88B C91B 150.4(8) . . . . ?
C24 C84 C88B C48A -34.0(15) . . . . ?
C24 C84 C88A C48B -52.2(14) . . . . ?
C24 C84 C88A C91A 131.3(11) . . . . ?
C25 C30 C81 C34B 1.5(13) . . . . ?
C25 C30 C81 C37 -171.7(7) . . . . ?
C25 C30 C81 C34A 20.6(11) . . . . ?
C26 C21 C29 C13 6.5(8) . . . . ?
C26 C21 C29 C28 -174.7(5) . . . . ?
C26 C23 C35 C33 0.2(9) . . . . ?
C26 C23 C35 C71 178.4(5) . . . . ?
C27B C10B C67 O46 -14.3(14) . . . . ?
C27B C10B C67 O65 177.9(11) . . . . ?
C28 C20 C59 N55 -2.5(9) . . . . ?
C28 C42 C73 C74 -173.4(8) . . . . ?
C29 C21 C26 C23 3.0(9) . . . . ?
C29 C28 C42 C41 45.2(9) . . . . ?
C29 C28 C42 C73 -140.7(7) . . . . ?
C30 C25 C38 C24 0.3(9) . . . . ?
C30 C81 C34A C85A 33.5(17) . . . . ?
C30 C81 C34A C79A -149.4(9) . . . . ?
C31 C84 C88B C91B -40.3(14) . . . . ?
C31 C84 C88B C48A 135.3(11) . . . . ?
C31 C84 C88A C48B 136.3(9) . . . . ?
C31 C84 C88A C91A -40.2(14) . . . . ?
C33 C35 C71 C68 178.3(5) . . . . ?
C34B C85B C86B C83B -1(2) . . . . ?
C35 C23 C26 C21 172.3(5) . . . . ?
C35 C33 C44 C9 179.6(7) . . . . ?
C35 C33 C80 C77 -178.4(7) . . . . ?
C37 C81 C34A C85A -133.2(13) . . . . ?
C37 C81 C34A C79A 43.9(15) . . . . ?
C38 C24 C84 C31 173.1(6) . . . . ?
C38 C24 C84 C88B -16.3(9) . . . . ?
C38 C24 C84 C88A 2.2(11) . . . . ?
C38 C25 C30 C17 7.4(9) . . . . ?
C38 C25 C30 C81 -174.2(6) . . . . ?
C41 C42 C73 C74 0.8(12) . . . . ?
C42 C28 C29 C13 -168.8(5) . . . . ?
C42 C28 C29 C21 12.4(8) . . . . ?
C42 C41 C76 C75 -0.1(13) . . . . ?
C42 C73 C74 C75 -0.8(14) . . . . ?
C44 C9 C11 C77 2.1(12) . . . . ?
C44 C33 C35 C23 -51.3(9) . . . . ?
C44 C33 C35 C71 130.5(7) . . . . ?
C44 C33 C80 C77 4.7(11) . . . . ?
C47 C18 C58 Eu3 -4(3) . . . . ?
C47 C18 C58 O47 -88.9(7) . . . . ?
C47 C18 C58 O52 87.4(8) . . . . ?
C48B C88A C91A C51A -0.8(17) . . . . ?
C49 C40B C60 O61 -74.4(10) . . . . ?
C49 C40B C60 O62 97.6(9) . . . . ?
C50B C51A C91A C88A 0.4(17) . . . . ?
C51B C50A C52A C48A -7.0(19) . . . . ?
C52B C48B C88A C84 -176.9(10) . . . . ?
C52B C48B C88A C91A -0.1(18) . . . . ?
C52B C50B C51A C91A 0.9(19) . . . . ?
C56 N51 C15 C17 178.8(5) . . . . ?
C56 N51 C15 C24 -1.5(7) . . . . ?
C56 C31 C84 C24 1.3(10) . . . . ?
C56 C31 C84 C88B -167.6(8) . . . . ?
C56 C31 C84 C88A 174.3(7) . . . . ?
C59 N55 C13 C12 -177.8(5) . . . . ?
C59 N55 C13 C29 -0.1(7) . . . . ?
C59 C20 C28 C29 -4.2(8) . . . . ?
C59 C20 C28 C42 173.0(5) . . . . ?
C68 N49 C12 C13 176.1(4) . . . . ?
C68 N49 C12 C23 -1.7(7) . . . . ?
C73 C74 C75 C76 0.3(15) . . . . ?
C74 C75 C76 C41 0.1(14) . . . . ?
C76 C41 C42 C28 174.0(7) . . . . ?
C76 C41 C42 C73 -0.3(12) . . . . ?
C78B C83B C86B C85B 2.1(19) . . . . ?
C79B C34B C81 C30 -142.9(13) . . . . ?
C79B C34B C81 C37 30.7(17) . . . . ?
C79B C34B C85B C86B -1(2) . . . . ?
C79B C78B C83B C86B -1.2(19) . . . . ?
C80 C33 C35 C23 132.0(7) . . . . ?
C80 C33 C35 C71 -46.2(9) . . . . ?
C80 C33 C44 C9 -3.6(11) . . . . ?
C81 C34B C79B C78B -166.1(13) . . . . ?
C81 C34B C85B C86B 168.9(12) . . . . ?
C83B C78B C79B C34B -0.9(19) . . . . ?
C84 C24 C38 C25 174.7(6) . . . . ?
C84 C31 C56 N51 2.4(10) . . . . ?
C84 C88B C91B C51B 176.5(11) . . . . ?
C84 C88B C48A C52A -177.2(10) . . . . ?
C84 C88A C91A C51A 175.5(10) . . . . ?
C85B C34B C79B C78B 2.0(19) . . . . ?
C85B C34B C81 C30 48.5(16) . . . . ?
C85B C34B C81 C37 -138.0(11) . . . . ?
C88B C48A C52A C50A 5.1(17) . . . . ?
C90B C32B C66 Eu1 -44(3) . . . . ?
C90B C32B C66 O54 -3.7(12) . . . . ?
C90B C32B C66 O64 -171.8(8) . . . . ?
C91B C51B C50A C52A 6(2) . . . . ?
C91B C88B C48A C52A -1.9(18) . . . . ?
C48A C88B C91B C51B 0.4(18) . . . . ?
C50A C51B C91B C88B -2(2) . . . . ?
C51A C50B C52B C48B -1.8(19) . . . . ?
C88A C48B C52B C50B 1.4(18) . . . . ?
C2A C32B C66 Eu1 -162.6(18) . . . . ?
C2A C32B C66 O54 -122.2(8) . . . . ?
C2A C32B C66 O64 69.6(10) . . . . ?
C5A C10B C67 O46 -137.6(8) . . . . ?
C5A C10B C67 O65 54.5(11) . . . . ?
C5 C10B C67 O46 106.5(9) . . . . ?
C5 C10B C67 O65 -61.4(12) . . . . ?
C6A C40B C60 O61 169.0(9) . . . . ?
C6A C40B C60 O62 -19.0(13) . . . . ?
C82A C40B C60 O61 42.8(12) . . . . ?
C82A C40B C60 O62 -145.2(9) . . . . ?
C78A C83A C86A C85A 1.7(18) . . . . ?
C78A C79A C34A C81 -178.6(11) . . . . ?
C78A C79A C34A C85A -1.2(18) . . . . ?
C83A C78A C79A C34A 1.3(18) . . . . ?
C83A C86A C85A C34A -1.7(18) . . . . ?
C86A C85A C34A C81 178.3(12) . . . . ?
C86A C85A C34A C79A 1.4(18) . . . . ?
C79A C78A C83A C86A -1.5(18) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a_CCDC3
_database_code_depnum_ccdc_archive 'CCDC 2089888'
loop_
_audit_author_name
_audit_author_address
'Alexander Goloveshkin'
;Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2021-06-14 deposited with the CCDC.	2021-08-09 downloaded from the CCDC.
;
_audit_creation_date             2021-06-14
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C45 H18 Eu F15 N2 O7, 2(C4 H8 O)'
_chemical_formula_sum            'C53 H34 Eu F15 N2 O9'
_chemical_formula_weight         1279.78
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, y+1/2, -z+1/2'
3 '-x, -y, -z'
4 'x, -y-1/2, z-1/2'

_cell_length_a                   10.8114(6)
_cell_length_b                   15.8899(8)
_cell_length_c                   28.6502(15)
_cell_angle_alpha                90.00
_cell_angle_beta                 92.3140(10)
_cell_angle_gamma                90.00
_cell_volume                     4917.9(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    7652
_cell_measurement_temperature    120
_cell_measurement_theta_max      27.62
_cell_measurement_theta_min      2.28
_exptl_absorpt_coefficient_mu    1.394
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6409
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0751 before and 0.0642 after correction.
The Ratio of minimum to maximum transmission is 0.8590.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.728
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2544
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.19
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0999
_diffrn_reflns_av_unetI/netI     0.0789
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_number            57591
_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         1.91
_diffrn_ambient_temperature      120
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_number_gt                7349
_reflns_number_total             12218
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'XS  (Sheldrick, 2008)'
_refine_diff_density_max         1.094
_refine_diff_density_min         -0.669
_refine_diff_density_rms         0.112
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.992
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     722
_refine_ls_number_reflns         12218
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0925
_refine_ls_R_factor_gt           0.0390
_refine_ls_restrained_S_all      0.992
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0287P)²+0.3577P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0684
_refine_ls_wR_factor_ref         0.0825
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description    
;
1.a Rotating group:
 O5(H5A,H5B)
1.b Secondary CH2 refined with riding coordinates:
 C56(H56A,H56B), C62(H62A,H62B), C75(H75A,H75B), C76(H76A,H76B), C78(H78A,
 H78B), C1(H1A,H1B), C2(H2A,H2B), C3(H3A,H3B)
1.c Aromatic/amide H refined with riding coordinates:
 C26(H26), C30(H30), C31(H31), C33(H33), C44(H44), C49(H49), C51(H51),
 C54(H54), C55(H55), C57(H57), C59(H59), C60(H60), C64(H64), C71(H71), C72(H72),
  C73(H73)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.831070(15) -0.001519(15) 0.042301(6) 0.01166(5) Uani 1 1 d . . .
F80 F 1.17189(19) -0.00622(16) 0.16374(7) 0.0227(5) Uani 1 1 d . . .
O81 O 1.0174(2) -0.06371(16) 0.07829(8) 0.0152(6) Uani 1 1 d . . .
F4 F 1.2988(2) -0.08694(15) 0.23278(7) 0.0282(6) Uani 1 1 d . . .
O5 O 0.6281(2) -0.03386(16) 0.01109(9) 0.0170(6) Uani 1 1 d . . .
H5A H 0.6005 -0.0773 0.0248 0.025 Uiso 1 1 d R . .
H5B H 0.6323 -0.0489 -0.0174 0.025 Uiso 1 1 d R . .
F6 F 1.0007(2) -0.26201(16) 0.05554(8) 0.0285(6) Uani 1 1 d . . .
O7 O 0.8509(2) -0.13794(17) 0.00574(9) 0.0191(6) Uani 1 1 d . . .
N8 N 0.7038(3) 0.13491(19) 0.05046(10) 0.0135(7) Uani 1 1 d . . .
F9 F 0.7356(3) -0.31519(16) 0.07000(9) 0.0381(7) Uani 1 1 d . . .
F10 F 1.3799(2) -0.31045(15) 0.13061(9) 0.0331(6) Uani 1 1 d . . .
N11 N 0.8417(3) 0.07318(19) 0.12190(10) 0.0139(7) Uani 1 1 d . . .
F12 F 1.4017(2) -0.24005(16) 0.21746(8) 0.0329(6) Uani 1 1 d . . .
O14 O 0.7433(2) -0.09461(16) 0.09671(8) 0.0170(6) Uani 1 1 d . . .
F15 F 0.6300(3) -0.13823(16) 0.19402(8) 0.0358(6) Uani 1 1 d . . .
F16 F 1.2514(2) -0.23228(14) 0.06137(7) 0.0232(5) Uani 1 1 d . . .
C17 C 1.2213(3) -0.0823(2) 0.15451(13) 0.0174(8) Uani 1 1 d . . .
O18 O 0.5623(3) -0.15219(19) 0.07181(10) 0.0291(7) Uani 1 1 d . . .
C19 C 1.3407(4) -0.1996(3) 0.18239(14) 0.0230(10) Uani 1 1 d . . .
C20 C 1.2069(3) -0.1162(2) 0.11019(13) 0.0163(8) Uani 1 1 d . . .
C22 C 0.9754(3) -0.2434(2) -0.02642(14) 0.0168(8) Uani 1 1 d . . .
F23 F 0.7835(3) -0.44149(17) 0.13116(11) 0.0538(8) Uani 1 1 d . . .
C25 C 0.6593(3) 0.2634(2) 0.09326(13) 0.0150(8) Uani 1 1 d . . .
C26 C 0.7538(4) 0.2799(2) 0.17105(14) 0.0209(9) Uani 1 1 d . . .
H26 H 0.7656 0.3121 0.1980 0.025 Uiso 1 1 calc R . .
F27 F 0.9481(2) -0.23527(16) -0.10801(8) 0.0325(6) Uani 1 1 d . . .
F28 F 1.0930(2) -0.41708(17) 0.04541(11) 0.0491(8) Uani 1 1 d . . .
F29 F 1.0343(3) -0.39403(18) -0.11780(10) 0.0513(8) Uani 1 1 d . . .
C30 C 0.9294(4) 0.1782(3) 0.29037(13) 0.0213(9) Uani 1 1 d . . .
H30 H 0.8957 0.1248 0.2933 0.026 Uiso 1 1 calc R . .
C31 C 0.9723(4) 0.2215(3) 0.32974(13) 0.0242(10) Uani 1 1 d . . .
H31 H 0.9660 0.1973 0.3591 0.029 Uiso 1 1 calc R . .
C32 C 1.2632(3) -0.1936(3) 0.10322(13) 0.0180(8) Uani 1 1 d . . .
C33 C 0.5632(3) 0.2388(2) 0.01773(13) 0.0166(8) Uani 1 1 d . . .
H33 H 0.5095 0.2539 -0.0070 0.020 Uiso 1 1 calc R . .
C34 C 0.7944(3) 0.1523(2) 0.12721(12) 0.0137(8) Uani 1 1 d . . .
C35 C 0.7181(3) 0.1850(2) 0.08868(12) 0.0141(8) Uani 1 1 d . . .
C36 C 0.5104(4) 0.3720(2) 0.05651(13) 0.0177(8) Uani 1 1 d . . .
C37 C 0.5794(3) 0.2915(2) 0.05558(13) 0.0159(8) Uani 1 1 d . . .
C38 C 1.3293(4) -0.2346(3) 0.13848(14) 0.0210(9) Uani 1 1 d . . .
F39 F 1.1138(3) -0.48373(16) -0.04139(12) 0.0570(9) Uani 1 1 d . . .
C40 C 0.8165(3) 0.2006(2) 0.16791(12) 0.0147(8) Uani 1 1 d . . .
C41 C 1.1301(3) -0.0726(2) 0.07131(12) 0.0135(8) Uani 1 1 d . . .
F42 F 0.6753(3) -0.26526(19) 0.25495(9) 0.0494(8) Uani 1 1 d . . .
C43 C 0.6824(4) -0.2233(2) 0.13068(14) 0.0190(9) Uani 1 1 d . . .
C44 C 0.9376(4) 0.0849(3) 0.19837(12) 0.0192(9) Uani 1 1 d . . .
H44 H 0.9862 0.0596 0.2219 0.023 Uiso 1 1 calc R . .
C45 C 1.0561(4) -0.3723(3) 0.00745(17) 0.0316(11) Uani 1 1 d . . .
C46 C 0.9851(4) -0.2796(3) -0.06982(14) 0.0215(9) Uani 1 1 d . . .
C47 C 0.6595(4) -0.1505(3) 0.09651(13) 0.0192(9) Uani 1 1 d . . .
F48 F 0.7540(3) -0.41735(18) 0.22368(11) 0.0553(9) Uani 1 1 d . . .
C49 C 0.6783(4) 0.3090(3) 0.13604(14) 0.0202(9) Uani 1 1 d . . .
H49 H 0.6375 0.3599 0.1398 0.024 Uiso 1 1 calc R . .
C50 C 0.8954(4) 0.1664(2) 0.20404(13) 0.0173(8) Uani 1 1 d . . .
C51 C 1.0247(4) 0.3006(3) 0.32566(14) 0.0254(10) Uani 1 1 d . . .
H51 H 1.0535 0.3294 0.3522 0.030 Uiso 1 1 calc R . .
C52 C 0.9416(4) -0.1522(2) -0.01837(13) 0.0160(8) Uani 1 1 d . . .
C53 C 1.2872(4) -0.1220(3) 0.19037(13) 0.0202(9) Uani 1 1 d . . .
C54 C 0.9898(4) 0.2942(3) 0.24251(14) 0.0223(9) Uani 1 1 d . . .
H54 H 0.9956 0.3189 0.2133 0.027 Uiso 1 1 calc R . .
C55 C 0.6274(3) 0.1624(2) 0.01632(13) 0.0167(8) Uani 1 1 d . . .
H55 H 0.6158 0.1289 -0.0101 0.020 Uiso 1 1 calc R . .
C57 C 1.0339(4) 0.3368(3) 0.28178(14) 0.0255(10) Uani 1 1 d . . .
H57 H 1.0698 0.3896 0.2788 0.031 Uiso 1 1 calc R . .
C58 C 0.9367(4) 0.2147(3) 0.24617(13) 0.0184(8) Uani 1 1 d . . .
C59 C 0.3162(4) 0.4469(3) 0.04672(15) 0.0285(10) Uani 1 1 d . . .
H59 H 0.2311 0.4462 0.0405 0.034 Uiso 1 1 calc R . .
C60 C 0.9074(4) 0.0406(3) 0.15737(13) 0.0184(8) Uani 1 1 d . . .
H60 H 0.9349 -0.0147 0.1549 0.022 Uiso 1 1 calc R . .
C61 C 0.6678(4) -0.2136(3) 0.17783(14) 0.0240(9) Uani 1 1 d . . .
C63 C 1.0284(4) -0.3598(3) -0.07530(17) 0.0337(11) Uani 1 1 d . . .
C64 C 0.3827(4) 0.3726(3) 0.04693(14) 0.0218(9) Uani 1 1 d . . .
H64 H 0.3417 0.3222 0.0406 0.026 Uiso 1 1 calc R . .
C66 C 0.7200(4) -0.3018(3) 0.11564(16) 0.0271(10) Uani 1 1 d . . .
C67 C 1.0083(4) -0.2929(3) 0.01239(14) 0.0215(9) Uani 1 1 d . . .
C68 C 1.0660(4) -0.4061(3) -0.03607(19) 0.0358(12) Uani 1 1 d . . .
C69 C 0.7434(4) -0.3670(3) 0.14672(18) 0.0340(11) Uani 1 1 d . . .
C70 C 0.6905(4) -0.2781(3) 0.20952(15) 0.0318(11) Uani 1 1 d . . .
C71 C 0.5022(4) 0.5230(2) 0.06503(14) 0.0259(10) Uani 1 1 d . . .
H71 H 0.5427 0.5737 0.0711 0.031 Uiso 1 1 calc R . .
C72 C 0.3762(4) 0.5224(3) 0.05580(15) 0.0287(11) Uani 1 1 d . . .
H72 H 0.3317 0.5724 0.0557 0.034 Uiso 1 1 calc R . .
C73 C 0.5687(4) 0.4489(3) 0.06541(14) 0.0225(9) Uani 1 1 d . . .
H73 H 0.6538 0.4503 0.0717 0.027 Uiso 1 1 calc R . .
C74 C 0.7295(4) -0.3542(3) 0.19328(17) 0.0341(12) Uani 1 1 d . . .
O24 O 0.4235(3) 0.0857(2) 0.08012(10) 0.0327(8) Uani 1 1 d . . .
C56 C 0.3206(4) 0.1344(3) 0.09456(14) 0.0256(10) Uani 1 1 d . . .
H56A H 0.2485 0.0990 0.0982 0.031 Uiso 1 1 calc R . .
H56B H 0.2999 0.1781 0.0720 0.031 Uiso 1 1 calc R . .
C62 C 0.4763(4) 0.0470(3) 0.12119(15) 0.0296(10) Uani 1 1 d . . .
H62A H 0.5642 0.0377 0.1180 0.035 Uiso 1 1 calc R . .
H62B H 0.4369 -0.0067 0.1266 0.035 Uiso 1 1 calc R . .
C75 C 0.3635(5) 0.1720(3) 0.14066(15) 0.0368(12) Uani 1 1 d . . .
H75A H 0.2944 0.1801 0.1608 0.044 Uiso 1 1 calc R . .
H75B H 0.4039 0.2257 0.1362 0.044 Uiso 1 1 calc R . .
O65 O 0.2246(3) 0.4919(2) 0.22196(11) 0.0433(8) Uani 1 1 d . . .
C76 C 0.3875(5) 0.4276(4) 0.18290(19) 0.0521(15) Uani 1 1 d . . .
H76A H 0.4167 0.4213 0.1515 0.062 Uiso 1 1 calc R . .
H76B H 0.4113 0.3785 0.2013 0.062 Uiso 1 1 calc R . .
C78 C 0.3369(5) 0.5303(3) 0.23911(18) 0.0420(13) Uani 1 1 d . . .
H78A H 0.3593 0.5094 0.2701 0.050 Uiso 1 1 calc R . .
H78B H 0.3269 0.5909 0.2408 0.050 Uiso 1 1 calc R . .
C1 C 0.4357(4) 0.5081(4) 0.2056(2) 0.0532(15) Uani 1 1 d . . .
H1A H 0.5148 0.4988 0.2220 0.064 Uiso 1 1 calc R . .
H1B H 0.4451 0.5522 0.1826 0.064 Uiso 1 1 calc R . .
C2 C 0.4548(4) 0.1071(3) 0.16149(15) 0.0363(12) Uani 1 1 d . . .
H2A H 0.5316 0.1338 0.1721 0.044 Uiso 1 1 calc R . .
H2B H 0.4198 0.0777 0.1875 0.044 Uiso 1 1 calc R . .
C3 C 0.2499(5) 0.4419(5) 0.1825(2) 0.0671(19) Uani 1 1 d . . .
H3A H 0.2225 0.4705 0.1540 0.081 Uiso 1 1 calc R . .
H3B H 0.2067 0.3885 0.1840 0.081 Uiso 1 1 calc R . .
O1 O 1.0110(3) -0.09892(17) -0.03563(10) 0.0247(7) Uani 1 1 d . . .
O2 O 1.1874(2) -0.05042(17) 0.03638(9) 0.0193(6) Uani 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Eu1 4.4648(4) 3_755 ?
Eu1 O81 2.435(2) . ?
Eu1 O5 2.392(2) . ?
Eu1 H5A 2.7952 . ?
Eu1 H5B 2.7954 . ?
Eu1 O7 2.421(3) . ?
Eu1 N8 2.583(3) . ?
Eu1 N11 2.569(3) . ?
Eu1 O14 2.374(2) . ?
Eu1 C52 3.217(4) . ?
Eu1 O1 2.351(3) 3_755 ?
Eu1 O2 2.401(2) 3_755 ?
F80 C17 1.353(4) . ?
O81 C41 1.251(4) . ?
F4 C53 1.338(4) . ?
O5 H5A 0.8540 . ?
O5 H5B 0.8540 . ?
F6 C67 1.335(5) . ?
O7 C52 1.243(4) . ?
N8 C35 1.358(4) . ?
N8 C55 1.328(4) . ?
F9 C66 1.342(5) . ?
F10 C38 1.346(4) . ?
N11 C34 1.368(5) . ?
N11 C60 1.322(5) . ?
F12 C19 1.343(4) . ?
O14 C47 1.268(4) . ?
F15 C61 1.354(5) . ?
F16 C32 1.349(4) . ?
C17 C20 1.382(5) . ?
C17 C53 1.379(5) . ?
O18 C47 1.243(5) . ?
C19 C38 1.377(6) . ?
C19 C53 1.385(6) . ?
C20 C32 1.390(5) . ?
C20 C41 1.529(5) . ?
C22 C46 1.378(5) . ?
C22 C52 1.515(5) . ?
C22 C67 1.396(5) . ?
F23 C69 1.342(5) . ?
C25 C35 1.407(5) . ?
C25 C37 1.426(5) . ?
C25 C49 1.431(5) . ?
C26 H26 0.9300 . ?
C26 C40 1.436(5) . ?
C26 C49 1.349(5) . ?
F27 C46 1.348(5) . ?
F28 C45 1.347(5) . ?
F29 C63 1.337(5) . ?
C30 H30 0.9300 . ?
C30 C31 1.384(5) . ?
C30 C58 1.398(5) . ?
C31 H31 0.9300 . ?
C31 C51 1.386(6) . ?
C32 C38 1.378(5) . ?
C33 H33 0.9300 . ?
C33 C37 1.376(5) . ?
C33 C55 1.398(5) . ?
C34 C35 1.448(5) . ?
C34 C40 1.408(5) . ?
C36 C37 1.482(5) . ?
C36 C64 1.397(5) . ?
C36 C73 1.394(5) . ?
F39 C68 1.348(5) . ?
C40 C50 1.422(5) . ?
C41 O2 1.249(4) . ?
F42 C70 1.334(5) . ?
C43 C47 1.530(5) . ?
C43 C61 1.375(5) . ?
C43 C66 1.385(6) . ?
C44 H44 0.9300 . ?
C44 C50 1.385(5) . ?
C44 C60 1.397(5) . ?
C45 C67 1.373(6) . ?
C45 C68 1.366(7) . ?
C46 C63 1.369(6) . ?
F48 C74 1.348(5) . ?
C49 H49 0.9300 . ?
C50 C58 1.484(5) . ?
C51 H51 0.9300 . ?
C51 C57 1.390(6) . ?
C52 O1 1.246(4) . ?
C54 H54 0.9300 . ?
C54 C57 1.381(5) . ?
C54 C58 1.392(6) . ?
C55 H55 0.9300 . ?
C57 H57 0.9300 . ?
C59 H59 0.9300 . ?
C59 C64 1.382(6) . ?
C59 C72 1.383(6) . ?
C60 H60 0.9300 . ?
C61 C70 1.384(6) . ?
C63 C68 1.391(7) . ?
C64 H64 0.9300 . ?
C66 C69 1.384(6) . ?
C69 C74 1.364(7) . ?
C70 C74 1.368(7) . ?
C71 H71 0.9300 . ?
C71 C72 1.377(6) . ?
C71 C73 1.379(6) . ?
C72 H72 0.9300 . ?
C73 H73 0.9300 . ?
O24 C56 1.430(5) . ?
O24 C62 1.427(5) . ?
C56 H56A 0.9700 . ?
C56 H56B 0.9700 . ?
C56 C75 1.506(6) . ?
C62 H62A 0.9700 . ?
C62 H62B 0.9700 . ?
C62 C2 1.523(6) . ?
C75 H75A 0.9700 . ?
C75 H75B 0.9700 . ?
C75 C2 1.533(6) . ?
O65 C78 1.428(6) . ?
O65 C3 1.419(6) . ?
C76 H76A 0.9700 . ?
C76 H76B 0.9700 . ?
C76 C1 1.517(8) . ?
C76 C3 1.505(8) . ?
C78 H78A 0.9700 . ?
C78 H78B 0.9700 . ?
C78 C1 1.507(7) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
O1 Eu1 2.351(3) 3_755 ?
O2 Eu1 2.401(2) 3_755 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Eu1 Eu1 H5A 130.6 3_755 . ?
Eu1 Eu1 H5B 107.2 3_755 . ?
O81 Eu1 Eu1 63.48(6) . 3_755 ?
O81 Eu1 H5A 128.1 . . ?
O81 Eu1 H5B 138.8 . . ?
O81 Eu1 N8 137.46(9) . . ?
O81 Eu1 N11 78.75(9) . . ?
O81 Eu1 C52 66.91(9) . . ?
O5 Eu1 Eu1 123.90(6) . 3_755 ?
O5 Eu1 O81 143.31(9) . . ?
O5 Eu1 H5A 16.7 . . ?
O5 Eu1 H5B 16.7 . . ?
O5 Eu1 O7 75.03(9) . . ?
O5 Eu1 N8 74.34(9) . . ?
O5 Eu1 N11 116.02(9) . . ?
O5 Eu1 C52 89.61(9) . . ?
O5 Eu1 O2 71.49(9) . 3_755 ?
H5A Eu1 H5B 27.9 . . ?
O7 Eu1 Eu1 71.71(6) . 3_755 ?
O7 Eu1 O81 74.55(8) . . ?
O7 Eu1 H5A 68.3 . . ?
O7 Eu1 H5B 64.7 . . ?
O7 Eu1 N8 147.92(9) . . ?
O7 Eu1 N11 142.76(9) . . ?
O7 Eu1 C52 19.69(9) . . ?
N8 Eu1 Eu1 119.37(7) . 3_755 ?
N8 Eu1 H5A 84.4 . . ?
N8 Eu1 H5B 83.2 . . ?
N8 Eu1 C52 152.16(9) . . ?
N11 Eu1 Eu1 117.94(7) . 3_755 ?
N11 Eu1 H5A 111.5 . . ?
N11 Eu1 H5B 132.3 . . ?
N11 Eu1 N8 62.42(9) . . ?
N11 Eu1 C52 145.00(9) . . ?
O14 Eu1 Eu1 136.10(6) . 3_755 ?
O14 Eu1 O81 79.33(8) . . ?
O14 Eu1 O5 74.13(9) . . ?
O14 Eu1 H5A 58.1 . . ?
O14 Eu1 H5B 85.2 . . ?
O14 Eu1 O7 76.76(9) . . ?
O14 Eu1 N8 103.58(9) . . ?
O14 Eu1 N11 73.13(9) . . ?
O14 Eu1 C52 93.34(9) . . ?
O14 Eu1 O2 144.10(9) . 3_755 ?
C52 Eu1 Eu1 52.03(7) . 3_755 ?
C52 Eu1 H5A 86.0 . . ?
C52 Eu1 H5B 76.2 . . ?
O1 Eu1 Eu1 48.36(7) 3_755 3_755 ?
O1 Eu1 O81 73.67(9) 3_755 . ?
O1 Eu1 O5 140.71(9) 3_755 . ?
O1 Eu1 H5A 157.4 3_755 . ?
O1 Eu1 H5B 132.5 3_755 . ?
O1 Eu1 O7 119.70(10) 3_755 . ?
O1 Eu1 N8 80.16(10) 3_755 . ?
O1 Eu1 N11 75.64(10) 3_755 . ?
O1 Eu1 O14 141.93(9) 3_755 . ?
O1 Eu1 C52 100.04(10) 3_755 . ?
O1 Eu1 O2 73.95(9) 3_755 3_755 ?
O2 Eu1 Eu1 61.68(6) 3_755 3_755 ?
O2 Eu1 O81 124.97(8) 3_755 . ?
O2 Eu1 H5A 86.6 3_755 . ?
O2 Eu1 H5B 59.0 3_755 . ?
O2 Eu1 O7 84.67(9) 3_755 . ?
O2 Eu1 N8 76.82(9) 3_755 . ?
O2 Eu1 N11 132.33(9) 3_755 . ?
O2 Eu1 C52 76.54(9) 3_755 . ?
C41 O81 Eu1 140.6(2) . . ?
Eu1 O5 H5A 109.5 . . ?
Eu1 O5 H5B 109.5 . . ?
H5A O5 H5B 104.4 . . ?
C52 O7 Eu1 119.3(2) . . ?
C35 N8 Eu1 121.4(2) . . ?
C55 N8 Eu1 121.8(2) . . ?
C55 N8 C35 116.6(3) . . ?
C34 N11 Eu1 121.3(2) . . ?
C60 N11 Eu1 120.3(2) . . ?
C60 N11 C34 117.8(3) . . ?
C47 O14 Eu1 137.5(2) . . ?
F80 C17 C20 119.8(3) . . ?
F80 C17 C53 117.3(3) . . ?
C53 C17 C20 122.8(4) . . ?
F12 C19 C38 120.9(4) . . ?
F12 C19 C53 119.9(4) . . ?
C38 C19 C53 119.2(4) . . ?
C17 C20 C32 116.3(3) . . ?
C17 C20 C41 122.1(3) . . ?
C32 C20 C41 121.6(3) . . ?
C46 C22 C52 124.4(4) . . ?
C46 C22 C67 117.2(4) . . ?
C67 C22 C52 118.2(3) . . ?
C35 C25 C37 117.9(3) . . ?
C35 C25 C49 118.5(3) . . ?
C37 C25 C49 123.5(3) . . ?
C40 C26 H26 119.1 . . ?
C49 C26 H26 119.1 . . ?
C49 C26 C40 121.8(4) . . ?
C31 C30 H30 119.9 . . ?
C31 C30 C58 120.2(4) . . ?
C58 C30 H30 119.9 . . ?
C30 C31 H31 119.8 . . ?
C30 C31 C51 120.4(4) . . ?
C51 C31 H31 119.8 . . ?
F16 C32 C20 120.3(3) . . ?
F16 C32 C38 117.6(4) . . ?
C38 C32 C20 122.0(4) . . ?
C37 C33 H33 119.9 . . ?
C37 C33 C55 120.2(3) . . ?
C55 C33 H33 119.9 . . ?
N11 C34 C35 116.7(3) . . ?
N11 C34 C40 122.7(3) . . ?
C40 C34 C35 120.5(3) . . ?
N8 C35 C25 123.9(3) . . ?
N8 C35 C34 116.5(3) . . ?
C25 C35 C34 119.5(3) . . ?
C64 C36 C37 119.8(4) . . ?
C73 C36 C37 122.4(4) . . ?
C73 C36 C64 117.8(4) . . ?
C25 C37 C36 123.1(3) . . ?
C33 C37 C25 117.4(3) . . ?
C33 C37 C36 119.5(3) . . ?
F10 C38 C19 119.5(3) . . ?
F10 C38 C32 120.2(4) . . ?
C19 C38 C32 120.2(4) . . ?
C34 C40 C26 117.7(3) . . ?
C34 C40 C50 118.2(3) . . ?
C50 C40 C26 124.0(3) . . ?
O81 C41 C20 116.0(3) . . ?
O2 C41 O81 127.9(3) . . ?
O2 C41 C20 116.0(3) . . ?
C61 C43 C47 121.5(4) . . ?
C61 C43 C66 116.9(4) . . ?
C66 C43 C47 121.6(4) . . ?
C50 C44 H44 119.9 . . ?
C50 C44 C60 120.3(4) . . ?
C60 C44 H44 119.9 . . ?
F28 C45 C67 120.2(4) . . ?
F28 C45 C68 119.8(4) . . ?
C68 C45 C67 120.0(4) . . ?
F27 C46 C22 118.9(4) . . ?
F27 C46 C63 119.0(4) . . ?
C63 C46 C22 122.1(4) . . ?
O14 C47 C43 115.5(3) . . ?
O18 C47 O14 127.2(4) . . ?
O18 C47 C43 117.3(3) . . ?
C25 C49 H49 119.2 . . ?
C26 C49 C25 121.7(4) . . ?
C26 C49 H49 119.2 . . ?
C40 C50 C58 123.2(3) . . ?
C44 C50 C40 117.5(3) . . ?
C44 C50 C58 119.3(3) . . ?
C31 C51 H51 120.1 . . ?
C31 C51 C57 119.7(4) . . ?
C57 C51 H51 120.1 . . ?
O7 C52 Eu1 41.04(18) . . ?
O7 C52 C22 117.3(3) . . ?
O7 C52 O1 126.7(4) . . ?
C22 C52 Eu1 153.1(3) . . ?
O1 C52 Eu1 87.2(2) . . ?
O1 C52 C22 115.9(3) . . ?
F4 C53 C17 120.9(4) . . ?
F4 C53 C19 119.7(3) . . ?
C17 C53 C19 119.4(4) . . ?
C57 C54 H54 119.6 . . ?
C57 C54 C58 120.9(4) . . ?
C58 C54 H54 119.6 . . ?
N8 C55 C33 124.0(3) . . ?
N8 C55 H55 118.0 . . ?
C33 C55 H55 118.0 . . ?
C51 C57 H57 120.0 . . ?
C54 C57 C51 119.9(4) . . ?
C54 C57 H57 120.0 . . ?
C30 C58 C50 119.8(4) . . ?
C54 C58 C30 118.9(4) . . ?
C54 C58 C50 121.3(4) . . ?
C64 C59 H59 120.0 . . ?
C64 C59 C72 120.0(4) . . ?
C72 C59 H59 120.0 . . ?
N11 C60 C44 123.3(4) . . ?
N11 C60 H60 118.4 . . ?
C44 C60 H60 118.4 . . ?
F15 C61 C43 118.9(4) . . ?
F15 C61 C70 118.5(4) . . ?
C43 C61 C70 122.5(4) . . ?
F29 C63 C46 120.8(5) . . ?
F29 C63 C68 119.8(4) . . ?
C46 C63 C68 119.4(4) . . ?
C36 C64 H64 119.5 . . ?
C59 C64 C36 121.1(4) . . ?
C59 C64 H64 119.5 . . ?
F9 C66 C43 119.7(4) . . ?
F9 C66 C69 118.7(4) . . ?
C69 C66 C43 121.5(4) . . ?
F6 C67 C22 120.5(4) . . ?
F6 C67 C45 118.1(4) . . ?
C45 C67 C22 121.4(4) . . ?
F39 C68 C45 120.5(5) . . ?
F39 C68 C63 119.6(5) . . ?
C45 C68 C63 119.9(4) . . ?
F23 C69 C66 120.0(5) . . ?
F23 C69 C74 120.5(4) . . ?
C74 C69 C66 119.5(4) . . ?
F42 C70 C61 120.1(4) . . ?
F42 C70 C74 121.2(4) . . ?
C74 C70 C61 118.7(4) . . ?
C72 C71 H71 119.8 . . ?
C72 C71 C73 120.5(4) . . ?
C73 C71 H71 119.8 . . ?
C59 C72 H72 120.2 . . ?
C71 C72 C59 119.7(4) . . ?
C71 C72 H72 120.2 . . ?
C36 C73 H73 119.5 . . ?
C71 C73 C36 121.0(4) . . ?
C71 C73 H73 119.5 . . ?
F48 C74 C69 119.6(5) . . ?
F48 C74 C70 119.6(4) . . ?
C69 C74 C70 120.9(4) . . ?
C62 O24 C56 106.5(3) . . ?
O24 C56 H56A 110.8 . . ?
O24 C56 H56B 110.8 . . ?
O24 C56 C75 104.6(3) . . ?
H56A C56 H56B 108.9 . . ?
C75 C56 H56A 110.8 . . ?
C75 C56 H56B 110.8 . . ?
O24 C62 H62A 110.4 . . ?
O24 C62 H62B 110.4 . . ?
O24 C62 C2 106.7(4) . . ?
H62A C62 H62B 108.6 . . ?
C2 C62 H62A 110.4 . . ?
C2 C62 H62B 110.4 . . ?
C56 C75 H75A 110.9 . . ?
C56 C75 H75B 110.9 . . ?
C56 C75 C2 104.2(4) . . ?
H75A C75 H75B 108.9 . . ?
C2 C75 H75A 110.9 . . ?
C2 C75 H75B 110.9 . . ?
C3 O65 C78 109.0(4) . . ?
H76A C76 H76B 109.3 . . ?
C1 C76 H76A 111.5 . . ?
C1 C76 H76B 111.5 . . ?
C3 C76 H76A 111.5 . . ?
C3 C76 H76B 111.5 . . ?
C3 C76 C1 101.5(4) . . ?
O65 C78 H78A 110.3 . . ?
O65 C78 H78B 110.3 . . ?
O65 C78 C1 107.2(4) . . ?
H78A C78 H78B 108.5 . . ?
C1 C78 H78A 110.3 . . ?
C1 C78 H78B 110.3 . . ?
C76 C1 H1A 111.1 . . ?
C76 C1 H1B 111.1 . . ?
C78 C1 C76 103.3(4) . . ?
C78 C1 H1A 111.1 . . ?
C78 C1 H1B 111.1 . . ?
H1A C1 H1B 109.1 . . ?
C62 C2 C75 104.0(3) . . ?
C62 C2 H2A 111.0 . . ?
C62 C2 H2B 111.0 . . ?
C75 C2 H2A 111.0 . . ?
C75 C2 H2B 111.0 . . ?
H2A C2 H2B 109.0 . . ?
O65 C3 C76 107.4(5) . . ?
O65 C3 H3A 110.2 . . ?
O65 C3 H3B 110.2 . . ?
C76 C3 H3A 110.2 . . ?
C76 C3 H3B 110.2 . . ?
H3A C3 H3B 108.5 . . ?
C52 O1 Eu1 160.7(3) . 3_755 ?
C41 O2 Eu1 145.5(2) . 3_755 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 Eu1 O81 C41 6.7(3) 3_755 . . . ?
Eu1 Eu1 O7 C52 2.4(2) 3_755 . . . ?
Eu1 Eu1 N8 C35 -98.2(3) 3_755 . . . ?
Eu1 Eu1 N8 C55 77.2(3) 3_755 . . . ?
Eu1 Eu1 N11 C34 99.5(3) 3_755 . . . ?
Eu1 Eu1 N11 C60 -71.6(3) 3_755 . . . ?
Eu1 Eu1 O14 C47 -99.0(4) 3_755 . . . ?
Eu1 Eu1 C52 O7 -177.1(3) 3_755 . . . ?
Eu1 Eu1 C52 C22 138.8(6) 3_755 . . . ?
Eu1 Eu1 C52 O1 -11.70(17) 3_755 . . . ?
Eu1 O81 C41 C20 176.5(2) . . . . ?
Eu1 O81 C41 O2 -3.8(6) . . . . ?
Eu1 O7 C52 C22 159.2(2) . . . . ?
Eu1 O7 C52 O1 -18.4(5) . . . . ?
Eu1 N8 C35 C25 174.4(3) . . . . ?
Eu1 N8 C35 C34 -8.6(4) . . . . ?
Eu1 N8 C55 C33 -175.3(3) . . . . ?
Eu1 N11 C34 C35 11.5(4) . . . . ?
Eu1 N11 C34 C40 -169.1(3) . . . . ?
Eu1 N11 C60 C44 166.9(3) . . . . ?
Eu1 O14 C47 O18 -32.2(7) . . . . ?
Eu1 O14 C47 C43 147.8(3) . . . . ?
Eu1 C52 O1 Eu1 67.0(8) . . . 3_755 ?
F80 C17 C20 C32 178.3(3) . . . . ?
F80 C17 C20 C41 -3.6(5) . . . . ?
F80 C17 C53 F4 1.5(5) . . . . ?
F80 C17 C53 C19 -179.2(3) . . . . ?
O81 Eu1 O7 C52 -64.2(3) . . . . ?
O81 Eu1 N8 C35 -16.5(3) . . . . ?
O81 Eu1 N8 C55 158.9(3) . . . . ?
O81 Eu1 N11 C34 151.1(3) . . . . ?
O81 Eu1 N11 C60 -20.0(3) . . . . ?
O81 Eu1 O14 C47 -130.7(4) . . . . ?
O81 Eu1 C52 O7 109.4(3) . . . . ?
O81 Eu1 C52 C22 65.2(5) . . . . ?
O81 Eu1 C52 O1 -85.3(2) . . . . ?
O81 C41 O2 Eu1 -10.3(7) . . . 3_755 ?
O5 Eu1 O81 C41 118.6(4) . . . . ?
O5 Eu1 O7 C52 136.6(3) . . . . ?
O5 Eu1 N8 C35 141.3(3) . . . . ?
O5 Eu1 N8 C55 -43.2(3) . . . . ?
O5 Eu1 N11 C34 -64.5(3) . . . . ?
O5 Eu1 N11 C60 124.4(3) . . . . ?
O5 Eu1 O14 C47 23.7(4) . . . . ?
O5 Eu1 C52 O7 -41.6(3) . . . . ?
O5 Eu1 C52 C22 -85.8(5) . . . . ?
O5 Eu1 C52 O1 123.8(2) . . . . ?
O7 Eu1 O81 C41 83.6(4) . . . . ?
O7 Eu1 N8 C35 159.1(2) . . . . ?
O7 Eu1 N8 C55 -25.5(4) . . . . ?
O7 Eu1 N11 C34 -164.1(2) . . . . ?
O7 Eu1 N11 C60 24.8(4) . . . . ?
O7 Eu1 O14 C47 -54.2(4) . . . . ?
O7 Eu1 C52 C22 -44.2(5) . . . . ?
O7 Eu1 C52 O1 165.4(4) . . . . ?
O7 C52 O1 Eu1 78.9(9) . . . 3_755 ?
N8 Eu1 O81 C41 -98.8(4) . . . . ?
N8 Eu1 O7 C52 118.9(3) . . . . ?
N8 Eu1 N11 C34 -11.0(3) . . . . ?
N8 Eu1 N11 C60 178.0(3) . . . . ?
N8 Eu1 O14 C47 92.8(4) . . . . ?
N8 Eu1 C52 O7 -95.4(3) . . . . ?
N8 Eu1 C52 C22 -139.6(5) . . . . ?
N8 Eu1 C52 O1 70.0(3) . . . . ?
F9 C66 C69 F23 1.4(6) . . . . ?
F9 C66 C69 C74 179.2(4) . . . . ?
N11 Eu1 O81 C41 -122.6(4) . . . . ?
N11 Eu1 O7 C52 -109.9(3) . . . . ?
N11 Eu1 N8 C35 10.0(3) . . . . ?
N11 Eu1 N8 C55 -174.6(3) . . . . ?
N11 Eu1 O14 C47 147.9(4) . . . . ?
N11 Eu1 C52 O7 97.4(3) . . . . ?
N11 Eu1 C52 C22 53.3(6) . . . . ?
N11 Eu1 C52 O1 -97.2(2) . . . . ?
N11 C34 C35 N8 -1.8(5) . . . . ?
N11 C34 C35 C25 175.4(3) . . . . ?
N11 C34 C40 C26 -175.0(3) . . . . ?
N11 C34 C40 C50 2.6(6) . . . . ?
F12 C19 C38 F10 0.0(6) . . . . ?
F12 C19 C38 C32 178.0(4) . . . . ?
F12 C19 C53 F4 1.5(6) . . . . ?
F12 C19 C53 C17 -177.8(3) . . . . ?
O14 Eu1 O81 C41 162.7(4) . . . . ?
O14 Eu1 O7 C52 -146.6(3) . . . . ?
O14 Eu1 N8 C35 72.4(3) . . . . ?
O14 Eu1 N8 C55 -112.1(3) . . . . ?
O14 Eu1 N11 C34 -126.8(3) . . . . ?
O14 Eu1 N11 C60 62.1(3) . . . . ?
O14 Eu1 C52 O7 32.5(3) . . . . ?
O14 Eu1 C52 C22 -11.7(5) . . . . ?
O14 Eu1 C52 O1 -162.2(2) . . . . ?
F15 C61 C70 F42 -0.1(6) . . . . ?
F15 C61 C70 C74 -179.6(4) . . . . ?
F16 C32 C38 F10 0.3(6) . . . . ?
F16 C32 C38 C19 -177.7(4) . . . . ?
C17 C20 C32 F16 178.3(3) . . . . ?
C17 C20 C32 C38 0.3(6) . . . . ?
C17 C20 C41 O81 -62.7(5) . . . . ?
C17 C20 C41 O2 117.6(4) . . . . ?
C20 C17 C53 F4 179.9(3) . . . . ?
C20 C17 C53 C19 -0.8(6) . . . . ?
C20 C32 C38 F10 178.4(4) . . . . ?
C20 C32 C38 C19 0.4(6) . . . . ?
C20 C41 O2 Eu1 169.4(3) . . . 3_755 ?
C22 C46 C63 F29 178.5(4) . . . . ?
C22 C46 C63 C68 -1.2(7) . . . . ?
C22 C52 O1 Eu1 -98.7(8) . . . 3_755 ?
F23 C69 C74 F48 -1.3(7) . . . . ?
F23 C69 C74 C70 179.0(4) . . . . ?
C26 C40 C50 C44 172.4(4) . . . . ?
C26 C40 C50 C58 -9.5(6) . . . . ?
F27 C46 C63 F29 0.1(6) . . . . ?
F27 C46 C63 C68 -179.6(4) . . . . ?
F28 C45 C67 F6 0.4(6) . . . . ?
F28 C45 C67 C22 176.7(4) . . . . ?
F28 C45 C68 F39 -0.8(7) . . . . ?
F28 C45 C68 C63 -179.8(4) . . . . ?
F29 C63 C68 F39 3.3(7) . . . . ?
F29 C63 C68 C45 -177.8(4) . . . . ?
C30 C31 C51 C57 0.1(6) . . . . ?
C31 C30 C58 C50 177.4(4) . . . . ?
C31 C30 C58 C54 1.3(6) . . . . ?
C31 C51 C57 C54 0.7(6) . . . . ?
C32 C20 C41 O81 115.3(4) . . . . ?
C32 C20 C41 O2 -64.4(5) . . . . ?
C34 N11 C60 C44 -4.5(6) . . . . ?
C34 C40 C50 C44 -5.1(5) . . . . ?
C34 C40 C50 C58 173.1(4) . . . . ?
C35 N8 C55 C33 0.4(6) . . . . ?
C35 C25 C37 C33 1.4(5) . . . . ?
C35 C25 C37 C36 178.8(4) . . . . ?
C35 C25 C49 C26 2.2(6) . . . . ?
C35 C34 C40 C26 4.4(5) . . . . ?
C35 C34 C40 C50 -178.0(3) . . . . ?
C37 C25 C35 N8 0.4(6) . . . . ?
C37 C25 C35 C34 -176.6(3) . . . . ?
C37 C25 C49 C26 179.4(4) . . . . ?
C37 C33 C55 N8 1.5(6) . . . . ?
C37 C36 C64 C59 -178.8(4) . . . . ?
C37 C36 C73 C71 178.6(4) . . . . ?
C38 C19 C53 F4 -179.3(4) . . . . ?
C38 C19 C53 C17 1.4(6) . . . . ?
C40 C26 C49 C25 -1.8(6) . . . . ?
C40 C34 C35 N8 178.7(3) . . . . ?
C40 C34 C35 C25 -4.1(5) . . . . ?
C40 C50 C58 C30 132.6(4) . . . . ?
C40 C50 C58 C54 -51.4(6) . . . . ?
C41 C20 C32 F16 0.2(6) . . . . ?
C41 C20 C32 C38 -177.8(4) . . . . ?
F42 C70 C74 F48 -0.5(7) . . . . ?
F42 C70 C74 C69 179.2(4) . . . . ?
C43 C61 C70 F42 179.8(4) . . . . ?
C43 C61 C70 C74 0.3(7) . . . . ?
C43 C66 C69 F23 -177.9(4) . . . . ?
C43 C66 C69 C74 -0.1(7) . . . . ?
C44 C50 C58 C30 -49.2(5) . . . . ?
C44 C50 C58 C54 126.8(4) . . . . ?
C46 C22 C52 Eu1 154.9(4) . . . . ?
C46 C22 C52 O7 123.9(4) . . . . ?
C46 C22 C52 O1 -58.3(5) . . . . ?
C46 C22 C67 F6 -179.7(4) . . . . ?
C46 C22 C67 C45 4.2(6) . . . . ?
C46 C63 C68 F39 -177.0(4) . . . . ?
C46 C63 C68 C45 1.9(7) . . . . ?
C47 C43 C61 F15 1.3(6) . . . . ?
C47 C43 C61 C70 -178.5(4) . . . . ?
C47 C43 C66 F9 -0.8(6) . . . . ?
C47 C43 C66 C69 178.5(4) . . . . ?
C49 C25 C35 N8 177.7(4) . . . . ?
C49 C25 C35 C34 0.7(6) . . . . ?
C49 C25 C37 C33 -175.7(4) . . . . ?
C49 C25 C37 C36 1.7(6) . . . . ?
C49 C26 C40 C34 -1.5(6) . . . . ?
C49 C26 C40 C50 -179.0(4) . . . . ?
C50 C44 C60 N11 1.9(6) . . . . ?
C52 Eu1 O81 C41 64.4(4) . . . . ?
C52 Eu1 N8 C35 -161.8(3) . . . . ?
C52 Eu1 N8 C55 13.7(4) . . . . ?
C52 Eu1 N11 C34 162.3(2) . . . . ?
C52 Eu1 N11 C60 -8.8(4) . . . . ?
C52 Eu1 O14 C47 -64.9(4) . . . . ?
C52 C22 C46 F27 -8.5(6) . . . . ?
C52 C22 C46 C63 173.0(4) . . . . ?
C52 C22 C67 F6 5.1(6) . . . . ?
C52 C22 C67 C45 -171.0(4) . . . . ?
C53 C17 C20 C32 -0.1(6) . . . . ?
C53 C17 C20 C41 178.0(4) . . . . ?
C53 C19 C38 F10 -179.3(4) . . . . ?
C53 C19 C38 C32 -1.2(6) . . . . ?
C55 N8 C35 C25 -1.3(6) . . . . ?
C55 N8 C35 C34 175.7(3) . . . . ?
C55 C33 C37 C25 -2.3(6) . . . . ?
C55 C33 C37 C36 -179.8(4) . . . . ?
C57 C54 C58 C30 -0.5(6) . . . . ?
C57 C54 C58 C50 -176.5(4) . . . . ?
C58 C30 C31 C51 -1.1(6) . . . . ?
C58 C54 C57 C51 -0.5(6) . . . . ?
C60 N11 C34 C35 -177.2(3) . . . . ?
C60 N11 C34 C40 2.2(5) . . . . ?
C60 C44 C50 C40 3.0(6) . . . . ?
C60 C44 C50 C58 -175.2(4) . . . . ?
C61 C43 C47 O14 75.2(5) . . . . ?
C61 C43 C47 O18 -104.9(5) . . . . ?
C61 C43 C66 F9 179.9(4) . . . . ?
C61 C43 C66 C69 -0.8(6) . . . . ?
C61 C70 C74 F48 179.0(4) . . . . ?
C61 C70 C74 C69 -1.3(7) . . . . ?
C64 C36 C37 C25 -127.6(4) . . . . ?
C64 C36 C37 C33 49.8(5) . . . . ?
C64 C36 C73 C71 0.4(6) . . . . ?
C64 C59 C72 C71 0.0(7) . . . . ?
C66 C43 C47 O14 -104.1(4) . . . . ?
C66 C43 C47 O18 75.8(5) . . . . ?
C66 C43 C61 F15 -179.4(4) . . . . ?
C66 C43 C61 C70 0.8(6) . . . . ?
C66 C69 C74 F48 -179.0(4) . . . . ?
C66 C69 C74 C70 1.2(7) . . . . ?
C67 C22 C46 F27 176.6(3) . . . . ?
C67 C22 C46 C63 -1.8(6) . . . . ?
C67 C22 C52 Eu1 -30.3(7) . . . . ?
C67 C22 C52 O7 -61.3(5) . . . . ?
C67 C22 C52 O1 116.5(4) . . . . ?
C67 C45 C68 F39 179.3(4) . . . . ?
C67 C45 C68 C63 0.4(7) . . . . ?
C68 C45 C67 F6 -179.8(4) . . . . ?
C68 C45 C67 C22 -3.5(7) . . . . ?
C72 C59 C64 C36 0.4(7) . . . . ?
C72 C71 C73 C36 0.0(6) . . . . ?
C73 C36 C37 C25 54.3(6) . . . . ?
C73 C36 C37 C33 -128.4(4) . . . . ?
C73 C36 C64 C59 -0.6(6) . . . . ?
C73 C71 C72 C59 -0.2(7) . . . . ?
O24 C56 C75 C2 -30.3(5) . . . . ?
O24 C62 C2 C75 11.3(5) . . . . ?
C56 O24 C62 C2 -31.3(4) . . . . ?
C56 C75 C2 C62 11.4(5) . . . . ?
C62 O24 C56 C75 38.8(4) . . . . ?
O65 C78 C1 C76 -24.2(5) . . . . ?
C78 O65 C3 C76 16.9(6) . . . . ?
C1 C76 C3 O65 -31.1(6) . . . . ?
C3 O65 C78 C1 4.9(6) . . . . ?
C3 C76 C1 C78 32.7(6) . . . . ?
O1 Eu1 O81 C41 -44.4(4) 3_755 . . . ?
O1 Eu1 O7 C52 -3.8(3) 3_755 . . . ?
O1 Eu1 N8 C35 -68.9(3) 3_755 . . . ?
O1 Eu1 N8 C55 106.6(3) 3_755 . . . ?
O1 Eu1 N11 C34 75.3(3) 3_755 . . . ?
O1 Eu1 N11 C60 -95.8(3) 3_755 . . . ?
O1 Eu1 O14 C47 -175.9(4) 3_755 . . . ?
O1 Eu1 C52 O7 176.7(3) 3_755 . . . ?
O1 Eu1 C52 C22 132.5(5) 3_755 . . . ?
O1 Eu1 C52 O1 -18.0(3) 3_755 . . . ?
O2 Eu1 O81 C41 11.7(4) 3_755 . . . ?
O2 Eu1 O7 C52 64.3(3) 3_755 . . . ?
O2 Eu1 N8 C35 -144.5(3) 3_755 . . . ?
O2 Eu1 N8 C55 30.9(3) 3_755 . . . ?
O2 Eu1 N11 C34 23.6(3) 3_755 . . . ?
O2 Eu1 N11 C60 -147.5(3) 3_755 . . . ?
O2 Eu1 O14 C47 6.6(5) 3_755 . . . ?
O2 Eu1 C52 O7 -112.7(3) 3_755 . . . ?
O2 Eu1 C52 C22 -156.8(6) 3_755 . . . ?
O2 Eu1 C52 O1 52.7(2) 3_755 . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_preparation       Luminescent
