# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_f
_database_code_depnum_ccdc_archive 'CCDC 2044516'
loop_
_audit_author_name
_audit_author_address
'Junfang Guo'
;Wuhan Institute of Technology
China
;
_audit_update_record             
;
2021-09-30 deposited with the CCDC.	2021-10-01 downloaded from the CCDC.
;
_audit_creation_date             2021-09-23
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C33 H22 Eu N O10'
_chemical_formula_sum            'C33 H22 Eu N O10'
_chemical_formula_weight         744.47
_chemical_absolute_configuration ad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           43
_space_group_name_H-M_alt        'F d d 2'
_space_group_name_Hall           'F 2 -2d'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'x+1/4, -y+1/4, z+1/4'
'-x+1/4, y+1/4, z+1/4'
'x, y+1/2, z+1/2'
'-x, -y+1/2, z+1/2'
'x+1/4, -y+3/4, z+3/4'
'-x+1/4, y+3/4, z+3/4'
'x+1/2, y, z+1/2'
'-x+1/2, -y, z+1/2'
'x+3/4, -y+1/4, z+3/4'
'-x+3/4, y+1/4, z+3/4'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z'
'x+3/4, -y+3/4, z+1/4'
'-x+3/4, y+3/4, z+1/4'

_cell_length_a                   8.5329(4)
_cell_length_b                   34.8978(14)
_cell_length_c                   52.933(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     15762.2(12)
_cell_formula_units_Z            16
_cell_measurement_reflns_used    8594
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.12
_cell_measurement_theta_min      2.49
_shelx_estimated_absorpt_T_max   0.952
_shelx_estimated_absorpt_T_min   0.923
_exptl_absorpt_coefficient_mu    1.638
_exptl_absorpt_correction_T_max  0.997
_exptl_absorpt_correction_T_min  0.984
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.255
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             5920
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0554
_diffrn_reflns_av_unetI/netI     0.0726
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       46
_diffrn_reflns_limit_k_min       -37
_diffrn_reflns_limit_l_max       67
_diffrn_reflns_limit_l_min       -69
_diffrn_reflns_number            23979
_diffrn_reflns_point_group_measured_fraction_full 0.982
_diffrn_reflns_point_group_measured_fraction_max 0.937
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.257
_diffrn_reflns_theta_min         1.398
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.870
_reflns_Friedel_fraction_full    0.965
_reflns_Friedel_fraction_max     0.881
_reflns_number_gt                6585
_reflns_number_total             9158
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         0.918
_refine_diff_density_min         -0.667
_refine_diff_density_rms         0.085
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.256(18)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.915
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     410
_refine_ls_number_reflns         9158
_refine_ls_number_restraints     28
_refine_ls_R_factor_all          0.0553
_refine_ls_R_factor_gt           0.0390
_refine_ls_restrained_S_all      0.948
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0385P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0807
_refine_ls_wR_factor_ref         0.0855
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.744(18)
 0.256(18)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3. Restrained distances
 N1-C33
 1.5 with sigma of 0.02
 N1-C32
 1.5 with sigma of 0.02
 N1-C31
 1.4 with sigma of 0.02
4. Uiso/Uaniso restraints and constraints
O10: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
O10 \\sim C31 \\sim N1 \\sim C32 \\sim C33: within 2A with sigma of 0.01 and
sigma for terminal atoms of 0.02
C33 \\sim N1 \\sim C32 \\sim C31 \\sim O10: within 2A with sigma of 0.002 and
sigma for terminal atoms of 0.004
5.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C6(H6), C11(H11), C12(H12), C14(H14), C15(H15), C17(H17),
 C18(H18), C20(H20), C21(H21), C23(H23), C24(H24), C26(H26), C27(H27), C31(H31)
5.b Idealised Me refined as rotating group:
 C33(H33A,H33B,H33C), C32(H32A,H32B,H32C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1356(8) 0.46116(19) -0.14722(13) 0.0258(15) Uani 1 1 d . . . . .
C2 C 0.1226(8) 0.45259(18) -0.17249(14) 0.0287(16) Uani 1 1 d . . . . .
H2 H 0.062748 0.431559 -0.177343 0.034 Uiso 1 1 calc R . . . .
C3 C 0.1961(9) 0.4744(2) -0.19101(15) 0.0359(18) Uani 1 1 d . . . . .
C4 C 0.2813(8) 0.50620(17) -0.18415(13) 0.0249(15) Uani 1 1 d . . . . .
H4 H 0.331342 0.520923 -0.196375 0.030 Uiso 1 1 calc R . . . .
C5 C 0.2919(7) 0.51606(19) -0.15897(14) 0.0263(16) Uani 1 1 d . . . . .
C6 C 0.2180(8) 0.49328(18) -0.14082(14) 0.0289(16) Uani 1 1 d . . . . .
H6 H 0.225033 0.500192 -0.123896 0.035 Uiso 1 1 calc R . . . .
C7 C 0.0491(9) 0.4389(2) -0.12871(15) 0.0360(18) Uani 1 1 d . . . . .
C8 C 0.1712(10) 0.4659(2) -0.21916(16) 0.0409(19) Uani 1 1 d . . . . .
C9 C 0.3837(8) 0.54960(18) -0.14936(14) 0.0257(15) Uani 1 1 d . . . . .
C10 C 0.0797(8) 0.44347(18) -0.10093(14) 0.0263(15) Uani 1 1 d . . . . .
C11 C -0.0443(9) 0.4450(2) -0.08448(16) 0.039(2) Uani 1 1 d . . . . .
H11 H -0.146135 0.442507 -0.090515 0.047 Uiso 1 1 calc R . . . .
C12 C -0.0176(8) 0.4503(2) -0.05835(16) 0.0362(18) Uani 1 1 d . . . . .
H12 H -0.101508 0.450965 -0.047152 0.043 Uiso 1 1 calc R . . . .
C13 C 0.1350(8) 0.45441(18) -0.04949(14) 0.0269(15) Uani 1 1 d . . . . .
C14 C 0.2604(8) 0.4504(2) -0.06661(14) 0.0343(17) Uani 1 1 d . . . . .
H14 H 0.363113 0.450917 -0.060746 0.041 Uiso 1 1 calc R . . . .
C15 C 0.2317(8) 0.4459(2) -0.09146(14) 0.0336(17) Uani 1 1 d . . . . .
H15 H 0.315708 0.444351 -0.102607 0.040 Uiso 1 1 calc R . . . .
C16 C 0.1279(9) 0.4260(2) -0.22669(14) 0.0372(19) Uani 1 1 d . . . . .
C17 C 0.1925(9) 0.3946(2) -0.21439(16) 0.0401(19) Uani 1 1 d . . . . .
H17 H 0.264399 0.398165 -0.201390 0.048 Uiso 1 1 calc R . . . .
C18 C 0.1485(8) 0.3575(2) -0.22172(15) 0.0374(18) Uani 1 1 d . . . . .
H18 H 0.193868 0.336426 -0.213894 0.045 Uiso 1 1 calc R . . . .
C19 C 0.0394(8) 0.3522(2) -0.24029(13) 0.0303(17) Uani 1 1 d . . . . .
C20 C -0.0226(10) 0.3836(2) -0.25301(16) 0.051(2) Uani 1 1 d . . . . .
H20 H -0.094264 0.379921 -0.266016 0.061 Uiso 1 1 calc R . . . .
C21 C 0.0226(10) 0.4210(2) -0.24627(16) 0.052(2) Uani 1 1 d . . . . .
H21 H -0.017770 0.442010 -0.254862 0.062 Uiso 1 1 calc R . . . .
C22 C 0.3984(8) 0.58554(18) -0.16568(15) 0.0300(17) Uani 1 1 d . . . . .
C23 C 0.2879(8) 0.5962(2) -0.18316(15) 0.0349(18) Uani 1 1 d . . . . .
H23 H 0.206315 0.579516 -0.186988 0.042 Uiso 1 1 calc R . . . .
C24 C 0.2957(8) 0.63118(19) -0.19513(15) 0.0311(17) Uani 1 1 d . . . . .
H24 H 0.217118 0.638645 -0.206260 0.037 Uiso 1 1 calc R . . . .
C25 C 0.4186(8) 0.6545(2) -0.19055(14) 0.0339(17) Uani 1 1 d . . . . .
C26 C 0.5334(7) 0.6437(2) -0.17362(14) 0.0318(17) Uani 1 1 d . . . . .
H26 H 0.620241 0.659408 -0.171148 0.038 Uiso 1 1 calc R . . . .
C27 C 0.5204(8) 0.6107(2) -0.16063(17) 0.0407(19) Uani 1 1 d . . . . .
H27 H 0.593621 0.604648 -0.148235 0.049 Uiso 1 1 calc R . . . .
C28 C 0.1654(8) 0.4619(2) -0.02305(15) 0.0302(17) Uani 1 1 d . . . . .
C29 C -0.0270(7) 0.3121(2) -0.24557(15) 0.0301(16) Uani 1 1 d . . . . .
C30 C 0.4312(9) 0.6926(2) -0.20403(15) 0.0305(17) Uani 1 1 d . . . . .
O1 O -0.0575(7) 0.41635(18) -0.13496(10) 0.0529(16) Uani 1 1 d . . . . .
O2 O 0.1847(9) 0.49154(16) -0.23449(16) 0.0692(19) Uani 1 1 d . . . . .
O3 O 0.4391(7) 0.55006(14) -0.12859(11) 0.0426(14) Uani 1 1 d . . . . .
O4 O 0.3075(7) 0.47121(18) -0.01737(12) 0.0408(16) Uani 1 1 d . . . . .
O5 O 0.0590(8) 0.46185(19) -0.00716(13) 0.0399(17) Uani 1 1 d . . . . .
O6 O 0.0175(6) 0.28377(11) -0.2324(2) 0.0296(10) Uani 1 1 d . . . . .
O7 O -0.1294(6) 0.30834(15) -0.26226(11) 0.0418(14) Uani 1 1 d . . . . .
O8 O 0.3057(8) 0.70730(18) -0.21231(13) 0.0381(16) Uani 1 1 d . . . . .
O9 O 0.5650(8) 0.70770(17) -0.20519(13) 0.0420(17) Uani 1 1 d . . . . .
O10 O 0.1067(7) 0.53129(19) 0.06782(12) 0.0608(15) Uani 1 1 d . U . . .
Eu1 Eu 0.000000 0.500000 0.02994(2) 0.02589(18) Uani 1 2 d S T P . .
Eu2 Eu 0.500000 0.500000 0.00491(2) 0.02721(19) Uani 1 2 d S T P . .
C31 C 0.2328(13) 0.5337(4) 0.0767(2) 0.0784(17) Uani 1 1 d D U . . .
H31 H 0.315073 0.522947 0.067584 0.094 Uiso 1 1 calc R . . . .
N1 N 0.2691(12) 0.5508(3) 0.09898(19) 0.0925(18) Uani 1 1 d D U . . .
C33 C 0.4312(16) 0.5535(4) 0.1063(3) 0.111(3) Uani 1 1 d D U . . .
H33A H 0.490891 0.534397 0.097508 0.167 Uiso 1 1 calc GR . . . .
H33B H 0.440217 0.549397 0.124203 0.167 Uiso 1 1 calc GR . . . .
H33C H 0.470617 0.578481 0.102170 0.167 Uiso 1 1 calc GR . . . .
C32 C 0.1554(17) 0.5628(4) 0.1194(3) 0.122(3) Uani 1 1 d D U . . .
H32A H 0.082372 0.581058 0.112597 0.183 Uiso 1 1 calc GR . . . .
H32B H 0.211945 0.574279 0.133112 0.183 Uiso 1 1 calc GR . . . .
H32C H 0.099469 0.540752 0.125379 0.183 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.375(9) . ?
C1 C6 1.365(9) . ?
C1 C7 1.452(10) . ?
C2 H2 0.9300 . ?
C2 C3 1.391(10) . ?
C3 C4 1.375(10) . ?
C3 C8 1.535(11) . ?
C4 H4 0.9300 . ?
C4 C5 1.380(10) . ?
C5 C6 1.397(10) . ?
C5 C9 1.497(9) . ?
C6 H6 0.9300 . ?
C7 C10 1.502(10) . ?
C7 O1 1.247(9) . ?
C8 C16 1.494(10) . ?
C8 O2 1.214(11) . ?
C9 C22 1.528(9) . ?
C9 O3 1.197(8) . ?
C10 C11 1.371(10) . ?
C10 C15 1.393(9) . ?
C11 H11 0.9300 . ?
C11 C12 1.414(11) . ?
C12 H12 0.9300 . ?
C12 C13 1.391(9) . ?
C13 C14 1.409(10) . ?
C13 C28 1.448(10) . ?
C14 H14 0.9300 . ?
C14 C15 1.347(10) . ?
C15 H15 0.9300 . ?
C16 C17 1.388(10) . ?
C16 C21 1.383(10) . ?
C17 H17 0.9300 . ?
C17 C18 1.402(11) . ?
C18 H18 0.9300 . ?
C18 C19 1.367(10) . ?
C19 C20 1.391(11) . ?
C19 C29 1.535(10) . ?
C20 H20 0.9300 . ?
C20 C21 1.404(11) . ?
C21 H21 0.9300 . ?
C22 C23 1.373(9) . ?
C22 C27 1.387(10) . ?
C23 H23 0.9300 . ?
C23 C24 1.377(10) . ?
C24 H24 0.9300 . ?
C24 C25 1.349(9) . ?
C25 C26 1.380(10) . ?
C25 C30 1.511(10) . ?
C26 H26 0.9300 . ?
C26 C27 1.348(10) . ?
C27 H27 0.9300 . ?
C28 O4 1.290(9) . ?
C28 O5 1.238(9) . ?
C29 O6 1.269(10) . ?
C29 O7 1.249(8) . ?
C29 Eu2 2.884(7) 7_454 ?
C30 O8 1.266(9) . ?
C30 O9 1.260(9) . ?
O4 Eu2 2.258(6) . ?
O5 Eu1 2.425(7) . ?
O6 Eu1 2.398(6) 7_554 ?
O6 Eu2 2.655(5) 7_454 ?
O7 Eu2 2.456(5) 7_454 ?
O8 Eu2 2.336(6) 11_464 ?
O9 Eu1 2.300(6) 11_564 ?
O10 Eu1 2.458(6) . ?
O10 C31 1.177(10) . ?
Eu1 Eu2 4.4674(2) . ?
Eu1 Eu2 4.4673(2) 1_455 ?
C31 H31 0.9300 . ?
C31 N1 1.359(13) . ?
N1 C33 1.440(13) . ?
N1 C32 1.511(14) . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C7 119.9(6) . . ?
C6 C1 C2 117.5(6) . . ?
C6 C1 C7 122.3(7) . . ?
C1 C2 H2 119.0 . . ?
C1 C2 C3 122.0(6) . . ?
C3 C2 H2 119.0 . . ?
C2 C3 C8 121.0(7) . . ?
C4 C3 C2 119.6(7) . . ?
C4 C3 C8 119.1(7) . . ?
C3 C4 H4 120.3 . . ?
C3 C4 C5 119.4(7) . . ?
C5 C4 H4 120.3 . . ?
C4 C5 C6 119.5(6) . . ?
C4 C5 C9 123.9(6) . . ?
C6 C5 C9 116.6(7) . . ?
C1 C6 C5 121.9(7) . . ?
C1 C6 H6 119.0 . . ?
C5 C6 H6 119.0 . . ?
C1 C7 C10 121.0(6) . . ?
O1 C7 C1 122.0(7) . . ?
O1 C7 C10 117.0(7) . . ?
C16 C8 C3 118.3(7) . . ?
O2 C8 C3 119.5(7) . . ?
O2 C8 C16 122.2(8) . . ?
C5 C9 C22 119.5(6) . . ?
O3 C9 C5 121.9(6) . . ?
O3 C9 C22 118.4(6) . . ?
C11 C10 C7 119.5(7) . . ?
C11 C10 C15 119.2(7) . . ?
C15 C10 C7 121.4(7) . . ?
C10 C11 H11 119.9 . . ?
C10 C11 C12 120.1(7) . . ?
C12 C11 H11 119.9 . . ?
C11 C12 H12 120.2 . . ?
C13 C12 C11 119.6(7) . . ?
C13 C12 H12 120.2 . . ?
C12 C13 C14 118.9(7) . . ?
C12 C13 C28 120.9(7) . . ?
C14 C13 C28 120.2(6) . . ?
C13 C14 H14 120.0 . . ?
C15 C14 C13 120.1(7) . . ?
C15 C14 H14 120.0 . . ?
C10 C15 H15 119.1 . . ?
C14 C15 C10 121.8(7) . . ?
C14 C15 H15 119.1 . . ?
C17 C16 C8 120.7(7) . . ?
C21 C16 C8 118.6(7) . . ?
C21 C16 C17 120.6(7) . . ?
C16 C17 H17 120.3 . . ?
C16 C17 C18 119.4(7) . . ?
C18 C17 H17 120.3 . . ?
C17 C18 H18 119.8 . . ?
C19 C18 C17 120.5(7) . . ?
C19 C18 H18 119.7 . . ?
C18 C19 C20 120.0(7) . . ?
C18 C19 C29 120.4(7) . . ?
C20 C19 C29 119.4(6) . . ?
C19 C20 H20 119.9 . . ?
C19 C20 C21 120.3(7) . . ?
C21 C20 H20 119.9 . . ?
C16 C21 C20 119.1(8) . . ?
C16 C21 H21 120.4 . . ?
C20 C21 H21 120.4 . . ?
C23 C22 C9 123.2(6) . . ?
C23 C22 C27 118.3(6) . . ?
C27 C22 C9 118.1(6) . . ?
C22 C23 H23 119.4 . . ?
C22 C23 C24 121.2(6) . . ?
C24 C23 H23 119.4 . . ?
C23 C24 H24 120.3 . . ?
C25 C24 C23 119.3(7) . . ?
C25 C24 H24 120.3 . . ?
C24 C25 C26 120.3(7) . . ?
C24 C25 C30 120.0(7) . . ?
C26 C25 C30 119.7(7) . . ?
C25 C26 H26 119.8 . . ?
C27 C26 C25 120.4(7) . . ?
C27 C26 H26 119.8 . . ?
C22 C27 H27 119.8 . . ?
C26 C27 C22 120.3(7) . . ?
C26 C27 H27 119.8 . . ?
O4 C28 C13 116.1(7) . . ?
O5 C28 C13 121.6(7) . . ?
O5 C28 O4 122.1(8) . . ?
C19 C29 Eu2 157.9(4) . 7_454 ?
O6 C29 C19 120.0(7) . . ?
O6 C29 Eu2 66.8(4) . 7_454 ?
O7 C29 C19 118.9(6) . . ?
O7 C29 O6 121.1(7) . . ?
O7 C29 Eu2 57.7(4) . 7_454 ?
O8 C30 C25 117.4(7) . . ?
O9 C30 C25 117.1(7) . . ?
O9 C30 O8 125.4(7) . . ?
C28 O4 Eu2 156.5(5) . . ?
C28 O5 Eu1 134.5(5) . . ?
C29 O6 Eu1 141.3(5) . 7_554 ?
C29 O6 Eu2 87.1(4) . 7_454 ?
Eu1 O6 Eu2 124.19(16) 7_554 7_454 ?
C29 O7 Eu2 96.8(4) . 7_454 ?
C30 O8 Eu2 133.5(6) . 11_464 ?
C30 O9 Eu1 155.2(6) . 11_564 ?
C31 O10 Eu1 134.0(8) . . ?
O5 Eu1 O5 71.9(3) 2_565 . ?
O5 Eu1 O10 145.9(2) . . ?
O5 Eu1 O10 119.6(2) 2_565 . ?
O5 Eu1 O10 145.9(2) 2_565 2_565 ?
O5 Eu1 O10 119.6(2) . 2_565 ?
O5 Eu1 Eu2 64.01(16) . . ?
O5 Eu1 Eu2 87.60(17) 2_565 . ?
O5 Eu1 Eu2 87.60(17) . 1_455 ?
O5 Eu1 Eu2 64.01(16) 2_565 1_455 ?
O6 Eu1 O5 71.4(3) 15_455 . ?
O6 Eu1 O5 71.4(3) 4 2_565 ?
O6 Eu1 O5 83.0(3) 15_455 2_565 ?
O6 Eu1 O5 83.0(3) 4 . ?
O6 Eu1 O6 148.4(5) 15_455 4 ?
O6 Eu1 O10 72.4(3) 15_455 2_565 ?
O6 Eu1 O10 72.4(3) 4 . ?
O6 Eu1 O10 138.3(3) 4 2_565 ?
O6 Eu1 O10 138.3(3) 15_455 . ?
O6 Eu1 Eu2 29.45(10) 15_455 1_455 ?
O6 Eu1 Eu2 29.45(10) 4 . ?
O6 Eu1 Eu2 135.2(2) 15_455 . ?
O6 Eu1 Eu2 135.2(2) 4 1_455 ?
O9 Eu1 O5 77.4(2) 16_545 . ?
O9 Eu1 O5 140.5(2) 3_465 . ?
O9 Eu1 O5 140.5(2) 16_545 2_565 ?
O9 Eu1 O5 77.4(2) 3_465 2_565 ?
O9 Eu1 O6 80.8(2) 3_465 15_455 ?
O9 Eu1 O6 110.22(19) 3_465 4 ?
O9 Eu1 O6 80.8(2) 16_545 4 ?
O9 Eu1 O6 110.22(19) 16_545 15_455 ?
O9 Eu1 O9 140.0(3) 16_545 3_465 ?
O9 Eu1 O10 71.9(2) 16_545 2_565 ?
O9 Eu1 O10 75.6(2) 3_465 2_565 ?
O9 Eu1 O10 75.6(2) 16_545 . ?
O9 Eu1 O10 71.9(2) 3_465 . ?
O9 Eu1 Eu2 139.20(17) 3_465 . ?
O9 Eu1 Eu2 56.35(16) 3_465 1_455 ?
O9 Eu1 Eu2 139.20(17) 16_545 1_455 ?
O9 Eu1 Eu2 56.35(16) 16_545 . ?
O10 Eu1 O10 70.7(3) 2_565 . ?
O10 Eu1 Eu2 83.59(15) 2_565 1_455 ?
O10 Eu1 Eu2 126.55(15) . 1_455 ?
O10 Eu1 Eu2 126.55(15) 2_565 . ?
O10 Eu1 Eu2 83.59(15) . . ?
Eu2 Eu1 Eu2 145.504(13) 1_455 . ?
C29 Eu2 C29 179.0(3) 4 15 ?
C29 Eu2 Eu1 51.14(14) 15 1_655 ?
C29 Eu2 Eu1 129.24(14) 15 . ?
C29 Eu2 Eu1 51.14(14) 4 . ?
C29 Eu2 Eu1 129.24(14) 4 1_655 ?
O4 Eu2 C29 81.4(2) . 4 ?
O4 Eu2 C29 81.4(2) 2_665 15 ?
O4 Eu2 C29 98.1(2) 2_665 4 ?
O4 Eu2 C29 98.1(2) . 15 ?
O4 Eu2 O4 117.0(3) . 2_665 ?
O4 Eu2 O6 124.1(2) 2_665 4 ?
O4 Eu2 O6 72.8(2) 2_665 15 ?
O4 Eu2 O6 72.8(2) . 4 ?
O4 Eu2 O6 124.1(2) . 15 ?
O4 Eu2 O7 82.6(2) . 4 ?
O4 Eu2 O7 82.6(2) 2_665 15 ?
O4 Eu2 O7 75.07(19) 2_665 4 ?
O4 Eu2 O7 75.08(19) . 15 ?
O4 Eu2 O8 87.5(2) . 16_545 ?
O4 Eu2 O8 145.1(2) . 3_565 ?
O4 Eu2 O8 87.5(2) 2_665 3_565 ?
O4 Eu2 O8 145.1(2) 2_665 16_545 ?
O4 Eu2 Eu1 148.16(15) . 1_655 ?
O4 Eu2 Eu1 148.16(15) 2_665 . ?
O4 Eu2 Eu1 57.34(16) . . ?
O4 Eu2 Eu1 57.34(16) 2_665 1_655 ?
O6 Eu2 C29 26.1(2) 15 15 ?
O6 Eu2 C29 26.1(2) 4 4 ?
O6 Eu2 C29 154.52(19) 4 15 ?
O6 Eu2 C29 154.52(19) 15 4 ?
O6 Eu2 O6 150.6(5) 15 4 ?
O6 Eu2 Eu1 26.35(10) 4 . ?
O6 Eu2 Eu1 26.35(10) 15 1_655 ?
O6 Eu2 Eu1 138.23(18) 15 . ?
O6 Eu2 Eu1 138.23(18) 4 1_655 ?
O7 Eu2 C29 25.48(18) 4 4 ?
O7 Eu2 C29 25.48(18) 15 15 ?
O7 Eu2 C29 153.7(2) 4 15 ?
O7 Eu2 C29 153.7(2) 15 4 ?
O7 Eu2 O6 145.27(16) 4 15 ?
O7 Eu2 O6 50.6(2) 4 4 ?
O7 Eu2 O6 50.6(2) 15 15 ?
O7 Eu2 O6 145.27(16) 15 4 ?
O7 Eu2 O7 136.6(3) 15 4 ?
O7 Eu2 Eu1 73.12(12) 15 1_655 ?
O7 Eu2 Eu1 73.12(12) 4 . ?
O7 Eu2 Eu1 120.66(12) 15 . ?
O7 Eu2 Eu1 120.66(12) 4 1_655 ?
O8 Eu2 C29 70.2(2) 16_545 15 ?
O8 Eu2 C29 110.6(2) 3_565 15 ?
O8 Eu2 C29 110.6(2) 16_545 4 ?
O8 Eu2 C29 70.2(2) 3_565 4 ?
O8 Eu2 O6 72.8(3) 16_545 15 ?
O8 Eu2 O6 85.4(2) 3_565 15 ?
O8 Eu2 O6 85.4(2) 16_545 4 ?
O8 Eu2 O6 72.8(3) 3_565 4 ?
O8 Eu2 O7 135.9(2) 16_545 4 ?
O8 Eu2 O7 80.3(2) 3_565 4 ?
O8 Eu2 O7 135.9(2) 3_565 15 ?
O8 Eu2 O7 80.3(2) 16_545 15 ?
O8 Eu2 O8 84.1(3) 3_565 16_545 ?
O8 Eu2 Eu1 65.51(17) 3_565 1_655 ?
O8 Eu2 Eu1 88.52(18) 16_545 1_655 ?
O8 Eu2 Eu1 88.52(18) 3_565 . ?
O8 Eu2 Eu1 65.51(17) 16_545 . ?
Eu1 Eu2 Eu1 145.503(13) 1_655 . ?
O10 C31 H31 117.1 . . ?
O10 C31 N1 125.8(12) . . ?
N1 C31 H31 117.1 . . ?
C31 N1 C33 118.8(11) . . ?
C31 N1 C32 126.6(11) . . ?
C33 N1 C32 114.0(11) . . ?
N1 C33 H33A 109.5 . . ?
N1 C33 H33B 109.5 . . ?
N1 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
N1 C32 H32A 109.5 . . ?
N1 C32 H32B 109.5 . . ?
N1 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 C4 -1.8(11) . . . . ?
C1 C2 C3 C8 -176.0(7) . . . . ?
C1 C7 C10 C11 137.1(7) . . . . ?
C1 C7 C10 C15 -43.5(10) . . . . ?
C2 C1 C6 C5 -2.4(10) . . . . ?
C2 C1 C7 C10 170.5(7) . . . . ?
C2 C1 C7 O1 -12.5(11) . . . . ?
C2 C3 C4 C5 -0.3(10) . . . . ?
C2 C3 C8 C16 -26.0(11) . . . . ?
C2 C3 C8 O2 152.9(8) . . . . ?
C3 C4 C5 C6 1.0(10) . . . . ?
C3 C4 C5 C9 178.9(6) . . . . ?
C3 C8 C16 C17 -37.6(11) . . . . ?
C3 C8 C16 C21 142.8(8) . . . . ?
C4 C3 C8 C16 159.8(7) . . . . ?
C4 C3 C8 O2 -21.3(11) . . . . ?
C4 C5 C6 C1 0.4(10) . . . . ?
C4 C5 C9 C22 32.3(10) . . . . ?
C4 C5 C9 O3 -152.0(7) . . . . ?
C5 C9 C22 C23 27.5(11) . . . . ?
C5 C9 C22 C27 -159.7(7) . . . . ?
C6 C1 C2 C3 3.1(10) . . . . ?
C6 C1 C7 C10 -16.6(11) . . . . ?
C6 C1 C7 O1 160.4(7) . . . . ?
C6 C5 C9 C22 -149.7(6) . . . . ?
C6 C5 C9 O3 26.0(10) . . . . ?
C7 C1 C2 C3 176.4(7) . . . . ?
C7 C1 C6 C5 -175.5(7) . . . . ?
C7 C10 C11 C12 -178.4(7) . . . . ?
C7 C10 C15 C14 179.3(7) . . . . ?
C8 C3 C4 C5 174.0(6) . . . . ?
C8 C16 C17 C18 179.4(7) . . . . ?
C8 C16 C21 C20 -178.1(8) . . . . ?
C9 C5 C6 C1 -177.7(6) . . . . ?
C9 C22 C23 C24 171.6(7) . . . . ?
C9 C22 C27 C26 -176.5(7) . . . . ?
C10 C11 C12 C13 0.8(12) . . . . ?
C11 C10 C15 C14 -1.3(11) . . . . ?
C11 C12 C13 C14 -4.6(11) . . . . ?
C11 C12 C13 C28 176.6(7) . . . . ?
C12 C13 C14 C15 5.5(10) . . . . ?
C12 C13 C28 O4 -169.6(7) . . . . ?
C12 C13 C28 O5 5.9(11) . . . . ?
C13 C14 C15 C10 -2.6(11) . . . . ?
C13 C28 O4 Eu2 150.9(11) . . . . ?
C13 C28 O5 Eu1 -141.8(6) . . . . ?
C14 C13 C28 O4 11.7(9) . . . . ?
C14 C13 C28 O5 -172.8(7) . . . . ?
C15 C10 C11 C12 2.2(11) . . . . ?
C16 C17 C18 C19 -2.0(11) . . . . ?
C17 C16 C21 C20 2.2(13) . . . . ?
C17 C18 C19 C20 3.5(11) . . . . ?
C17 C18 C19 C29 -170.7(7) . . . . ?
C18 C19 C20 C21 -2.1(12) . . . . ?
C18 C19 C29 O6 1.1(10) . . . . ?
C18 C19 C29 O7 178.3(7) . . . . ?
C18 C19 C29 Eu2 103.6(13) . . . 7_454 ?
C19 C20 C21 C16 -0.7(13) . . . . ?
C19 C29 O6 Eu1 -56.7(14) . . . 7_554 ?
C19 C29 O6 Eu2 156.5(6) . . . 7_454 ?
C19 C29 O7 Eu2 -154.6(5) . . . 7_454 ?
C20 C19 C29 O6 -173.1(8) . . . . ?
C20 C19 C29 O7 4.0(10) . . . . ?
C20 C19 C29 Eu2 -70.7(16) . . . 7_454 ?
C21 C16 C17 C18 -0.9(12) . . . . ?
C22 C23 C24 C25 3.5(12) . . . . ?
C23 C22 C27 C26 -3.3(12) . . . . ?
C23 C24 C25 C26 -1.4(11) . . . . ?
C23 C24 C25 C30 178.4(7) . . . . ?
C24 C25 C26 C27 -3.0(12) . . . . ?
C24 C25 C30 O8 23.6(11) . . . . ?
C24 C25 C30 O9 -159.2(8) . . . . ?
C25 C26 C27 C22 5.4(12) . . . . ?
C25 C30 O8 Eu2 -154.2(5) . . . 11_464 ?
C25 C30 O9 Eu1 165.0(10) . . . 11_564 ?
C26 C25 C30 O8 -156.6(8) . . . . ?
C26 C25 C30 O9 20.6(11) . . . . ?
C27 C22 C23 C24 -1.1(12) . . . . ?
C28 C13 C14 C15 -175.7(7) . . . . ?
C29 C19 C20 C21 172.1(7) . . . . ?
C30 C25 C26 C27 177.1(7) . . . . ?
O1 C7 C10 C11 -40.1(10) . . . . ?
O1 C7 C10 C15 139.3(8) . . . . ?
O2 C8 C16 C17 143.6(9) . . . . ?
O2 C8 C16 C21 -36.1(12) . . . . ?
O3 C9 C22 C23 -148.3(8) . . . . ?
O3 C9 C22 C27 24.4(11) . . . . ?
O4 C28 O5 Eu1 33.4(12) . . . . ?
O5 C28 O4 Eu2 -24.5(18) . . . . ?
O6 C29 O7 Eu2 22.5(8) . . . 7_454 ?
O7 C29 O6 Eu1 126.2(8) . . . 7_554 ?
O7 C29 O6 Eu2 -20.6(7) . . . 7_454 ?
O8 C30 O9 Eu1 -18(2) . . . 11_564 ?
O9 C30 O8 Eu2 28.8(13) . . . 11_464 ?
O10 C31 N1 C33 -176.0(12) . . . . ?
O10 C31 N1 C32 14(2) . . . . ?
Eu1 O10 C31 N1 -176.1(8) . . . . ?
Eu2 C29 O6 Eu1 146.8(11) 7_454 . . 7_554 ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.932 -0.768 0.191 1412.8 0.0 ?
2 -0.258 -0.707 0.691 1412.8 0.0 ?
3 -0.516 -0.420 0.941 1412.8 0.0 ?
4 -0.651 -0.760 0.441 1412.8 0.0 ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.744(18)
2 0.256(18)

