# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_mo_19nov8btta_0m_pl
_database_code_depnum_ccdc_archive 'CCDC 2065473'
loop_
_audit_author_name
_audit_author_address
'Tongdao Wang'
;Dalian University of Technology
China
;
_audit_update_record             
;
2021-08-13 deposited with the CCDC.	2021-08-16 downloaded from the CCDC.
;
_audit_creation_date             2021-02-28
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C65 H56 Ag O Os P3'
_chemical_formula_sum            'C65 H56 Ag O Os P3'
_chemical_formula_weight         1244.07
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.1963(4)
_cell_length_b                   29.4703(10)
_cell_length_c                   13.9338(4)
_cell_angle_alpha                90
_cell_angle_beta                 97.0280(10)
_cell_angle_gamma                90
_cell_volume                     5378.1(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9519
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.444
_cell_measurement_theta_min      2.437
_shelx_estimated_absorpt_T_max   0.599
_shelx_estimated_absorpt_T_min   0.366
_exptl_absorpt_coefficient_mu    2.856
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6182
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0652 before and 0.0455 after correction.
The Ratio of minimum to maximum transmission is 0.8291.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.536
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2488
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0350
_diffrn_reflns_av_unetI/netI     0.0182
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       38
_diffrn_reflns_limit_k_min       -38
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            125506
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.522
_diffrn_reflns_theta_min         2.372
_diffrn_ambient_temperature      120.15
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker APEX2 microsource'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_type              'Incoatec I\ms'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                11039
_reflns_number_total             12348
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (?, 2016)'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'SAINT V8.40A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         1.814
_refine_diff_density_min         -0.797
_refine_diff_density_rms         0.119
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     689
_refine_ls_number_reflns         12348
_refine_ls_number_restraints     49
_refine_ls_R_factor_all          0.0449
_refine_ls_R_factor_gt           0.0379
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0426P)²+23.7083P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0947
_refine_ls_wR_factor_ref         0.1004
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 P2-C21A \\sim P2-C211
 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(C24A) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C21A) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
4. Rigid body (RIGU) restrains
 C211, C212, C213, C214, C215, C216
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
5. Others
 Sof(C26A)=Sof(H26A)=Sof(C21A)=Sof(C22A)=Sof(H22A)=Sof(C23A)=Sof(H23A)=
 Sof(C24A)=Sof(H24A)=Sof(C25A)=Sof(H25A)=1-FVAR(1)
 Sof(C211)=Sof(C212)=Sof(H212)=Sof(C213)=Sof(H213)=Sof(C214)=Sof(H214)=
 Sof(C215)=Sof(H215)=Sof(C216)=Sof(H216)=FVAR(1)
6.a Aromatic/amide H refined with riding coordinates:
 C26A(H26A), C22A(H22A), C23A(H23A), C24A(H24A), C25A(H25A), C102(H102),
 C103(H103), C104(H104), C105(H105), C106(H106), C112(H112), C113(H113),
 C114(H114), C115(H115), C116(H116), C122(H122), C123(H123), C124(H124),
 C125(H125), C126(H126), C202(H202), C203(H203), C204(H204), C205(H205),
 C206(H206), C212(H212), C213(H213), C214(H214), C215(H215), C216(H216),
 C222(H222), C223(H223), C224(H224), C225(H225), C226(H226), C302(H302),
 C303(H303), C304(H304), C305(H305), C306(H306), C312(H312), C313(H313),
 C314(H314), C315(H315), C316(H316), C322(H322), C323(H323), C324(H324),
 C325(H325), C326(H326)
6.b Fitted hexagon refined as free rotating group:
 C26A(C21A,C22A,C23A,C24A,C25A)
6.c X=CH2 refined with riding coordinates:
 C4(H4A,H4B), C9(H9A,H9B)
6.d Idealised Me refined as rotating group:
 C5(H5A,H5B,H5C), C10(H10A,H10B,H10C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.16018(2) 0.17305(2) 0.35247(2) 0.02397(6) Uani 1 1 d . . . . .
H H 0.161(4) 0.154(2) 0.240(4) 0.046(15) Uiso 1 1 d . . . . .
O1 O -0.0607(3) 0.19450(16) 0.2841(4) 0.0644(13) Uani 1 1 d . . . . .
C1 C 0.3184(3) 0.16030(17) 0.3791(3) 0.0332(9) Uani 1 1 d . . . . .
P1 P 0.21270(8) 0.24372(4) 0.29696(7) 0.0268(2) Uani 1 1 d . . . . .
Ag1 Ag 0.28499(3) 0.12662(2) 0.23065(3) 0.04304(10) Uani 1 1 d . . . . .
C2 C 0.4096(4) 0.1540(2) 0.3855(4) 0.0441(12) Uani 1 1 d . . . . .
P2 P 0.10991(9) 0.10183(4) 0.40606(10) 0.0346(3) Uani 1 1 d D . . . .
C3 C 0.5194(4) 0.1502(3) 0.3998(5) 0.0661(19) Uani 1 1 d . . . . .
P3 P 0.36491(10) 0.07848(4) 0.12807(9) 0.0358(3) Uani 1 1 d . . . . .
C4 C 0.5650(6) 0.1106(4) 0.4298(10) 0.135(5) Uani 1 1 d . . . . .
H4A H 0.524629 0.085004 0.441524 0.163 Uiso 1 1 calc R . . . .
H4B H 0.637385 0.108499 0.439004 0.163 Uiso 1 1 calc R . . . .
C5 C 0.5764(5) 0.1911(4) 0.3820(7) 0.097(3) Uani 1 1 d . . . . .
H5A H 0.566351 0.198162 0.312744 0.146 Uiso 1 1 calc GR . . . .
H5B H 0.649148 0.186127 0.402876 0.146 Uiso 1 1 calc GR . . . .
H5C H 0.551886 0.216470 0.418338 0.146 Uiso 1 1 calc GR . . . .
C6 C 0.1632(3) 0.19436(14) 0.4944(3) 0.0259(8) Uani 1 1 d . . . . .
C7 C 0.1660(3) 0.20236(15) 0.5790(3) 0.0302(9) Uani 1 1 d . . . . .
C8 C 0.1694(4) 0.21204(18) 0.6809(3) 0.0373(10) Uani 1 1 d . . . . .
C9 C 0.1079(6) 0.1907(3) 0.7356(4) 0.0669(19) Uani 1 1 d . . . . .
H9A H 0.060750 0.168692 0.707516 0.080 Uiso 1 1 calc R . . . .
H9B H 0.111400 0.197607 0.802484 0.080 Uiso 1 1 calc R . . . .
C10 C 0.2443(4) 0.2468(2) 0.7216(4) 0.0493(13) Uani 1 1 d . . . . .
H10A H 0.313228 0.237417 0.710692 0.074 Uiso 1 1 calc GR . . . .
H10B H 0.241014 0.249875 0.791146 0.074 Uiso 1 1 calc GR . . . .
H10C H 0.228038 0.275988 0.689682 0.074 Uiso 1 1 calc GR . . . .
C11 C 0.0220(4) 0.18682(16) 0.3138(4) 0.0370(10) Uani 1 1 d . . . . .
C26A C -0.0044(9) 0.0786(3) 0.2201(8) 0.069(7) Uani 0.331(8) 1 d . . P A 2
H26A H -0.044422 0.104349 0.232084 0.083 Uiso 0.331(8) 1 calc R . P A 2
C21A C 0.0769(10) 0.0656(4) 0.2874(7) 0.041(4) Uani 0.331(8) 1 d DG U P A 2
C22A C 0.1354(8) 0.0280(5) 0.2698(9) 0.071(7) Uani 0.331(8) 1 d G . P A 2
H22A H 0.190954 0.019148 0.315811 0.085 Uiso 0.331(8) 1 calc R . P A 2
C23A C 0.1125(10) 0.0034(4) 0.1848(10) 0.076(7) Uani 0.331(8) 1 d G . P A 2
H23A H 0.152521 -0.022344 0.172806 0.091 Uiso 0.331(8) 1 calc R . P A 2
C24A C 0.0312(11) 0.0164(4) 0.1175(8) 0.084(7) Uani 0.331(8) 1 d G U P A 2
H24A H 0.015617 -0.000490 0.059439 0.101 Uiso 0.331(8) 1 calc R . P A 2
C25A C -0.0273(9) 0.0540(4) 0.1351(7) 0.039(4) Uani 0.331(8) 1 d G . P A 2
H25A H -0.082855 0.062857 0.089077 0.047 Uiso 0.331(8) 1 calc R . P A 2
C101 C 0.1071(3) 0.28384(15) 0.2677(3) 0.0303(9) Uani 1 1 d . . . . .
C102 C 0.0726(4) 0.29944(19) 0.1754(4) 0.0463(12) Uani 1 1 d . . . . .
H102 H 0.108165 0.291347 0.122685 0.056 Uiso 1 1 calc R . . . .
C103 C -0.0137(5) 0.3268(2) 0.1596(5) 0.0551(15) Uani 1 1 d . . . . .
H103 H -0.037912 0.336292 0.095732 0.066 Uiso 1 1 calc R . . . .
C104 C -0.0638(4) 0.34016(18) 0.2347(5) 0.0506(14) Uani 1 1 d . . . . .
H104 H -0.122425 0.359018 0.223384 0.061 Uiso 1 1 calc R . . . .
C105 C -0.0292(5) 0.32626(17) 0.3266(5) 0.0491(14) Uani 1 1 d . . . . .
H105 H -0.063144 0.336106 0.379228 0.059 Uiso 1 1 calc R . . . .
C106 C 0.0556(4) 0.29771(17) 0.3437(4) 0.0388(11) Uani 1 1 d . . . . .
H106 H 0.078119 0.287751 0.407597 0.047 Uiso 1 1 calc R . . . .
C111 C 0.2709(3) 0.24032(16) 0.1840(3) 0.0322(9) Uani 1 1 d . . . . .
C112 C 0.2151(4) 0.2208(2) 0.1036(3) 0.0447(12) Uani 1 1 d . . . . .
H112 H 0.149679 0.208202 0.108608 0.054 Uiso 1 1 calc R . . . .
C113 C 0.2549(5) 0.2197(2) 0.0155(4) 0.0546(15) Uani 1 1 d . . . . .
H113 H 0.215503 0.207110 -0.039699 0.066 Uiso 1 1 calc R . . . .
C114 C 0.3502(5) 0.2366(2) 0.0076(4) 0.0531(14) Uani 1 1 d . . . . .
H114 H 0.375613 0.236954 -0.053311 0.064 Uiso 1 1 calc R . . . .
C115 C 0.4081(4) 0.2530(2) 0.0875(4) 0.0514(14) Uani 1 1 d . . . . .
H115 H 0.475749 0.263034 0.082968 0.062 Uiso 1 1 calc R . . . .
C116 C 0.3693(4) 0.25516(19) 0.1763(4) 0.0416(11) Uani 1 1 d . . . . .
H116 H 0.410392 0.266841 0.231494 0.050 Uiso 1 1 calc R . . . .
C121 C 0.3015(3) 0.27937(17) 0.3757(3) 0.0335(9) Uani 1 1 d . . . . .
C122 C 0.3200(5) 0.32386(18) 0.3472(4) 0.0477(13) Uani 1 1 d . . . . .
H122 H 0.287439 0.335138 0.287418 0.057 Uiso 1 1 calc R . . . .
C123 C 0.3864(5) 0.3516(2) 0.4069(5) 0.0578(15) Uani 1 1 d . . . . .
H123 H 0.399355 0.381691 0.387074 0.069 Uiso 1 1 calc R . . . .
C124 C 0.4332(5) 0.3357(2) 0.4941(4) 0.0524(14) Uani 1 1 d . . . . .
H124 H 0.478023 0.354832 0.534557 0.063 Uiso 1 1 calc R . . . .
C125 C 0.4149(4) 0.2921(2) 0.5225(4) 0.0472(13) Uani 1 1 d . . . . .
H125 H 0.447408 0.281244 0.582766 0.057 Uiso 1 1 calc R . . . .
C126 C 0.3493(3) 0.26363(18) 0.4641(3) 0.0358(10) Uani 1 1 d . . . . .
H126 H 0.337196 0.233570 0.484486 0.043 Uiso 1 1 calc R . . . .
C201 C 0.0195(5) 0.1023(2) 0.4993(5) 0.0603(16) Uani 1 1 d . . . . .
C202 C -0.0547(5) 0.1325(2) 0.4982(5) 0.0599(16) Uani 1 1 d . . . . .
H202 H -0.057772 0.156355 0.452222 0.072 Uiso 1 1 calc R . . . .
C203 C -0.1281(5) 0.1308(3) 0.5612(5) 0.0671(18) Uani 1 1 d . . . . .
H203 H -0.184017 0.151289 0.551883 0.081 Uiso 1 1 calc R . . . .
C204 C -0.1230(8) 0.1021(3) 0.6330(7) 0.088(3) Uani 1 1 d . . . . .
H204 H -0.173429 0.102107 0.676148 0.106 Uiso 1 1 calc R . . . .
C205 C -0.0425(8) 0.0716(3) 0.6450(6) 0.090(3) Uani 1 1 d . . . . .
H205 H -0.036203 0.050748 0.697351 0.108 Uiso 1 1 calc R . . . .
C206 C 0.0300(7) 0.0719(3) 0.5784(5) 0.075(2) Uani 1 1 d . . . . .
H206 H 0.086270 0.051569 0.586776 0.090 Uiso 1 1 calc R . . . .
C211 C 0.0419(6) 0.0649(2) 0.3171(6) 0.0348(15) Uani 0.669(8) 1 d D U P A 1
C212 C 0.0880(10) 0.0494(4) 0.2463(8) 0.070(3) Uani 0.669(8) 1 d . U P A 1
H212 H 0.159328 0.054161 0.247327 0.084 Uiso 0.669(8) 1 calc R . P A 1
C213 C 0.0355(12) 0.0262(5) 0.1700(9) 0.089(4) Uani 0.669(8) 1 d . U P A 1
H213 H 0.070452 0.019675 0.115872 0.107 Uiso 0.669(8) 1 calc R . P A 1
C214 C -0.0563(9) 0.0131(3) 0.1670(7) 0.071(3) Uani 0.669(8) 1 d . U P A 1
H214 H -0.086518 -0.006504 0.117485 0.086 Uiso 0.669(8) 1 calc R . P A 1
C215 C -0.1124(10) 0.0293(5) 0.2422(10) 0.108(5) Uani 0.669(8) 1 d . U P A 1
H215 H -0.183690 0.023521 0.237729 0.130 Uiso 0.669(8) 1 calc R . P A 1
C216 C -0.0640(8) 0.0535(4) 0.3227(8) 0.072(3) Uani 0.669(8) 1 d . U P A 1
H216 H -0.098339 0.061751 0.376188 0.086 Uiso 0.669(8) 1 calc R . P A 1
C221 C 0.2052(5) 0.06479(17) 0.4713(4) 0.0490(14) Uani 1 1 d . . . . .
C222 C 0.1939(7) 0.0179(3) 0.4707(7) 0.101(3) Uani 1 1 d . . . . .
H222 H 0.136774 0.004486 0.433055 0.121 Uiso 1 1 calc R . . . .
C223 C 0.2654(9) -0.0098(3) 0.5247(8) 0.127(5) Uani 1 1 d . . . . .
H223 H 0.257241 -0.041832 0.522651 0.152 Uiso 1 1 calc R . . . .
C224 C 0.3472(7) 0.0091(3) 0.5805(6) 0.085(3) Uani 1 1 d . . . . .
H224 H 0.394667 -0.009685 0.618940 0.102 Uiso 1 1 calc R . . . .
C225 C 0.3607(5) 0.0565(2) 0.5807(4) 0.0514(14) Uani 1 1 d . . . . .
H225 H 0.420621 0.069816 0.613805 0.062 Uiso 1 1 calc R . . . .
C226 C 0.2854(4) 0.08339(17) 0.5320(4) 0.0374(10) Uani 1 1 d . . . . .
H226 H 0.288788 0.115375 0.540329 0.045 Uiso 1 1 calc R . . . .
C301 C 0.3648(4) 0.01899(17) 0.1643(4) 0.0405(11) Uani 1 1 d . . . . .
C302 C 0.3759(6) 0.0095(3) 0.2646(5) 0.073(2) Uani 1 1 d . . . . .
H302 H 0.381510 0.033695 0.310085 0.087 Uiso 1 1 calc R . . . .
C303 C 0.3785(7) -0.0360(4) 0.2969(7) 0.098(3) Uani 1 1 d . . . . .
H303 H 0.389434 -0.042967 0.363925 0.118 Uiso 1 1 calc R . . . .
C304 C 0.3644(7) -0.0711(3) 0.2264(7) 0.082(3) Uani 1 1 d . . . . .
H304 H 0.359540 -0.101753 0.246511 0.098 Uiso 1 1 calc R . . . .
C305 C 0.3585(8) -0.0622(3) 0.1403(8) 0.101(3) Uani 1 1 d . . . . .
H305 H 0.356479 -0.086693 0.095878 0.121 Uiso 1 1 calc R . . . .
C306 C 0.3545(6) -0.0173(2) 0.1026(6) 0.075(2) Uani 1 1 d . . . . .
H306 H 0.344762 -0.012505 0.034688 0.090 Uiso 1 1 calc R . . . .
C311 C 0.4976(4) 0.09354(19) 0.1252(4) 0.0462(12) Uani 1 1 d . . . . .
C312 C 0.5771(7) 0.0627(4) 0.1458(9) 0.114(4) Uani 1 1 d . . . . .
H312 H 0.566484 0.032064 0.163227 0.137 Uiso 1 1 calc R . . . .
C313 C 0.6751(9) 0.0808(7) 0.1387(16) 0.227(11) Uani 1 1 d . . . . .
H313 H 0.729052 0.059279 0.142088 0.273 Uiso 1 1 calc R . . . .
C314 C 0.7006(9) 0.1214(5) 0.1285(10) 0.115(4) Uani 1 1 d . . . . .
H314 H 0.769420 0.131353 0.140558 0.138 Uiso 1 1 calc R . . . .
C315 C 0.6216(12) 0.1501(5) 0.0989(8) 0.154(7) Uani 1 1 d . . . . .
H315 H 0.635948 0.179128 0.074229 0.185 Uiso 1 1 calc R . . . .
C316 C 0.5170(8) 0.1372(3) 0.1041(8) 0.111(4) Uani 1 1 d . . . . .
H316 H 0.463336 0.158774 0.093014 0.133 Uiso 1 1 calc R . . . .
C321 C 0.3120(4) 0.07796(17) 0.0020(3) 0.0395(11) Uani 1 1 d . . . . .
C322 C 0.3665(6) 0.0620(2) -0.0686(4) 0.0602(17) Uani 1 1 d . . . . .
H322 H 0.433825 0.050796 -0.051563 0.072 Uiso 1 1 calc R . . . .
C323 C 0.3244(7) 0.0620(2) -0.1642(4) 0.075(2) Uani 1 1 d . . . . .
H323 H 0.362230 0.050238 -0.212367 0.090 Uiso 1 1 calc R . . . .
C324 C 0.2286(6) 0.0789(3) -0.1901(5) 0.075(2) Uani 1 1 d . . . . .
H324 H 0.200416 0.079298 -0.256137 0.090 Uiso 1 1 calc R . . . .
C325 C 0.1742(7) 0.0948(4) -0.1219(6) 0.093(3) Uani 1 1 d . . . . .
H325 H 0.107607 0.106563 -0.139992 0.112 Uiso 1 1 calc R . . . .
C326 C 0.2149(6) 0.0942(3) -0.0248(5) 0.075(2) Uani 1 1 d . . . . .
H326 H 0.175538 0.105124 0.023059 0.090 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Os1 H 1.66(6) . ?
Os1 C1 2.110(4) . ?
Os1 P1 2.3552(11) . ?
Os1 Ag1 2.8547(4) . ?
Os1 P2 2.3504(12) . ?
Os1 C6 2.070(4) . ?
Os1 C11 1.881(5) . ?
O1 C11 1.142(6) . ?
C1 Ag1 2.288(5) . ?
C1 C2 1.210(7) . ?
P1 C101 1.835(5) . ?
P1 C111 1.836(4) . ?
P1 C121 1.835(5) . ?
Ag1 H 1.85(6) . ?
Ag1 C2 2.672(5) . ?
Ag1 P3 2.3531(12) . ?
C2 C3 1.442(7) . ?
P2 C21A 1.971(8) . ?
P2 C201 1.869(7) . ?
P2 C211 1.804(6) . ?
P2 C221 1.822(5) . ?
C3 C4 1.355(12) . ?
C3 C5 1.457(12) . ?
P3 C301 1.825(5) . ?
P3 C311 1.811(6) . ?
P3 C321 1.809(5) . ?
C4 H4A 0.9500 . ?
C4 H4B 0.9500 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 C7 1.198(6) . ?
C7 C8 1.444(6) . ?
C8 C9 1.336(8) . ?
C8 C10 1.487(7) . ?
C9 H9A 0.9500 . ?
C9 H9B 0.9500 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C26A H26A 0.9500 . ?
C26A C21A 1.3900 . ?
C26A C25A 1.3900 . ?
C21A C22A 1.3900 . ?
C22A H22A 0.9500 . ?
C22A C23A 1.3900 . ?
C23A H23A 0.9500 . ?
C23A C24A 1.3900 . ?
C24A H24A 0.9500 . ?
C24A C25A 1.3900 . ?
C25A H25A 0.9500 . ?
C101 C102 1.388(7) . ?
C101 C106 1.388(6) . ?
C102 H102 0.9500 . ?
C102 C103 1.390(8) . ?
C103 H103 0.9500 . ?
C103 C104 1.363(9) . ?
C104 H104 0.9500 . ?
C104 C105 1.368(9) . ?
C105 H105 0.9500 . ?
C105 C106 1.397(7) . ?
C106 H106 0.9500 . ?
C111 C112 1.388(7) . ?
C111 C116 1.387(7) . ?
C112 H112 0.9500 . ?
C112 C113 1.393(7) . ?
C113 H113 0.9500 . ?
C113 C114 1.369(9) . ?
C114 H114 0.9500 . ?
C114 C115 1.360(8) . ?
C115 H115 0.9500 . ?
C115 C116 1.397(7) . ?
C116 H116 0.9500 . ?
C121 C122 1.400(7) . ?
C121 C126 1.392(6) . ?
C122 H122 0.9500 . ?
C122 C123 1.396(8) . ?
C123 H123 0.9500 . ?
C123 C124 1.377(9) . ?
C124 H124 0.9500 . ?
C124 C125 1.375(8) . ?
C125 H125 0.9500 . ?
C125 C126 1.395(7) . ?
C126 H126 0.9500 . ?
C201 C202 1.321(9) . ?
C201 C206 1.413(9) . ?
C202 H202 0.9500 . ?
C202 C203 1.385(9) . ?
C203 H203 0.9500 . ?
C203 C204 1.306(11) . ?
C204 H204 0.9500 . ?
C204 C205 1.385(13) . ?
C205 H205 0.9500 . ?
C205 C206 1.413(12) . ?
C206 H206 0.9500 . ?
C211 C212 1.304(14) . ?
C211 C216 1.449(13) . ?
C212 H212 0.9500 . ?
C212 C213 1.376(13) . ?
C213 H213 0.9500 . ?
C213 C214 1.268(17) . ?
C214 H214 0.9500 . ?
C214 C215 1.435(18) . ?
C215 H215 0.9500 . ?
C215 C216 1.415(14) . ?
C216 H216 0.9500 . ?
C221 C222 1.391(9) . ?
C221 C226 1.384(7) . ?
C222 H222 0.9500 . ?
C222 C223 1.395(11) . ?
C223 H223 0.9500 . ?
C223 C224 1.370(11) . ?
C224 H224 0.9500 . ?
C224 C225 1.409(10) . ?
C225 H225 0.9500 . ?
C225 C226 1.382(7) . ?
C226 H226 0.9500 . ?
C301 C302 1.415(9) . ?
C301 C306 1.368(9) . ?
C302 H302 0.9500 . ?
C302 C303 1.415(12) . ?
C303 H303 0.9500 . ?
C303 C304 1.423(14) . ?
C304 H304 0.9500 . ?
C304 C305 1.221(12) . ?
C305 H305 0.9500 . ?
C305 C306 1.422(11) . ?
C306 H306 0.9500 . ?
C311 C312 1.392(11) . ?
C311 C316 1.352(10) . ?
C312 H312 0.9500 . ?
C312 C313 1.413(15) . ?
C313 H313 0.9500 . ?
C313 C314 1.26(2) . ?
C314 H314 0.9500 . ?
C314 C315 1.366(18) . ?
C315 H315 0.9500 . ?
C315 C316 1.442(16) . ?
C316 H316 0.9500 . ?
C321 C322 1.372(8) . ?
C321 C326 1.375(8) . ?
C322 H322 0.9500 . ?
C322 C323 1.379(8) . ?
C323 H323 0.9500 . ?
C323 C324 1.364(11) . ?
C324 H324 0.9500 . ?
C324 C325 1.343(12) . ?
C325 H325 0.9500 . ?
C325 C326 1.393(10) . ?
C326 H326 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Os1 H 89.3(19) . . ?
C1 Os1 P1 83.71(14) . . ?
C1 Os1 Ag1 52.30(12) . . ?
C1 Os1 P2 95.57(14) . . ?
P1 Os1 H 87(2) . . ?
P1 Os1 Ag1 90.81(3) . . ?
Ag1 Os1 H 37.8(19) . . ?
P2 Os1 H 92(2) . . ?
P2 Os1 P1 178.91(4) . . ?
P2 Os1 Ag1 88.09(3) . . ?
C6 Os1 H 177(2) . . ?
C6 Os1 C1 89.03(16) . . ?
C6 Os1 P1 94.20(11) . . ?
C6 Os1 Ag1 140.18(11) . . ?
C6 Os1 P2 86.60(12) . . ?
C11 Os1 H 85.4(19) . . ?
C11 Os1 C1 173.0(2) . . ?
C11 Os1 P1 91.65(15) . . ?
C11 Os1 Ag1 122.84(16) . . ?
C11 Os1 P2 88.99(15) . . ?
C11 Os1 C6 96.50(19) . . ?
Os1 C1 Ag1 80.84(15) . . ?
C2 C1 Os1 173.9(4) . . ?
C2 C1 Ag1 94.5(4) . . ?
C101 P1 Os1 113.38(14) . . ?
C101 P1 C111 103.3(2) . . ?
C111 P1 Os1 113.82(16) . . ?
C121 P1 Os1 120.14(16) . . ?
C121 P1 C101 100.2(2) . . ?
C121 P1 C111 103.9(2) . . ?
Os1 Ag1 H 33.4(17) . . ?
C1 Ag1 Os1 46.85(11) . . ?
C1 Ag1 H 79.6(17) . . ?
C1 Ag1 C2 26.84(15) . . ?
C1 Ag1 P3 139.42(12) . . ?
C2 Ag1 Os1 73.65(11) . . ?
C2 Ag1 H 105.9(17) . . ?
P3 Ag1 Os1 169.80(4) . . ?
P3 Ag1 H 140.8(17) . . ?
P3 Ag1 C2 113.25(11) . . ?
C1 C2 Ag1 58.6(3) . . ?
C1 C2 C3 174.2(6) . . ?
C3 C2 Ag1 126.7(4) . . ?
C21A P2 Os1 105.0(4) . . ?
C201 P2 Os1 116.33(19) . . ?
C201 P2 C21A 119.5(5) . . ?
C211 P2 Os1 117.2(2) . . ?
C211 P2 C201 100.1(4) . . ?
C211 P2 C221 103.7(3) . . ?
C221 P2 Os1 119.3(2) . . ?
C221 P2 C21A 99.4(4) . . ?
C221 P2 C201 96.8(3) . . ?
C2 C3 C5 116.3(7) . . ?
C4 C3 C2 120.6(8) . . ?
C4 C3 C5 123.0(7) . . ?
C301 P3 Ag1 113.30(16) . . ?
C311 P3 Ag1 111.83(17) . . ?
C311 P3 C301 106.0(3) . . ?
C321 P3 Ag1 116.50(17) . . ?
C321 P3 C301 104.3(2) . . ?
C321 P3 C311 103.9(3) . . ?
C3 C4 H4A 120.0 . . ?
C3 C4 H4B 120.0 . . ?
H4A C4 H4B 120.0 . . ?
C3 C5 H5A 109.5 . . ?
C3 C5 H5B 109.5 . . ?
C3 C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C7 C6 Os1 173.7(4) . . ?
C6 C7 C8 179.9(6) . . ?
C7 C8 C10 116.8(5) . . ?
C9 C8 C7 121.3(5) . . ?
C9 C8 C10 121.9(5) . . ?
C8 C9 H9A 120.0 . . ?
C8 C9 H9B 120.0 . . ?
H9A C9 H9B 120.0 . . ?
C8 C10 H10A 109.5 . . ?
C8 C10 H10B 109.5 . . ?
C8 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O1 C11 Os1 175.4(5) . . ?
C21A C26A H26A 120.0 . . ?
C21A C26A C25A 120.0 . . ?
C25A C26A H26A 120.0 . . ?
C26A C21A P2 119.4(6) . . ?
C22A C21A P2 120.6(6) . . ?
C22A C21A C26A 120.0 . . ?
C21A C22A H22A 120.0 . . ?
C21A C22A C23A 120.0 . . ?
C23A C22A H22A 120.0 . . ?
C22A C23A H23A 120.0 . . ?
C24A C23A C22A 120.0 . . ?
C24A C23A H23A 120.0 . . ?
C23A C24A H24A 120.0 . . ?
C23A C24A C25A 120.0 . . ?
C25A C24A H24A 120.0 . . ?
C26A C25A H25A 120.0 . . ?
C24A C25A C26A 120.0 . . ?
C24A C25A H25A 120.0 . . ?
C102 C101 P1 125.0(4) . . ?
C102 C101 C106 118.2(4) . . ?
C106 C101 P1 116.7(3) . . ?
C101 C102 H102 119.7 . . ?
C101 C102 C103 120.6(5) . . ?
C103 C102 H102 119.7 . . ?
C102 C103 H103 119.7 . . ?
C104 C103 C102 120.7(5) . . ?
C104 C103 H103 119.7 . . ?
C103 C104 H104 120.2 . . ?
C103 C104 C105 119.6(5) . . ?
C105 C104 H104 120.2 . . ?
C104 C105 H105 119.7 . . ?
C104 C105 C106 120.6(5) . . ?
C106 C105 H105 119.7 . . ?
C101 C106 C105 120.3(5) . . ?
C101 C106 H106 119.9 . . ?
C105 C106 H106 119.9 . . ?
C112 C111 P1 118.6(4) . . ?
C116 C111 P1 122.9(4) . . ?
C116 C111 C112 118.5(4) . . ?
C111 C112 H112 120.0 . . ?
C111 C112 C113 120.0(5) . . ?
C113 C112 H112 120.0 . . ?
C112 C113 H113 119.6 . . ?
C114 C113 C112 120.8(5) . . ?
C114 C113 H113 119.6 . . ?
C113 C114 H114 120.2 . . ?
C115 C114 C113 119.5(5) . . ?
C115 C114 H114 120.2 . . ?
C114 C115 H115 119.6 . . ?
C114 C115 C116 120.7(5) . . ?
C116 C115 H115 119.6 . . ?
C111 C116 C115 120.2(5) . . ?
C111 C116 H116 119.9 . . ?
C115 C116 H116 119.9 . . ?
C122 C121 P1 119.2(4) . . ?
C126 C121 P1 121.7(4) . . ?
C126 C121 C122 119.1(4) . . ?
C121 C122 H122 120.0 . . ?
C123 C122 C121 119.9(5) . . ?
C123 C122 H122 120.0 . . ?
C122 C123 H123 119.8 . . ?
C124 C123 C122 120.5(5) . . ?
C124 C123 H123 119.8 . . ?
C123 C124 H124 120.1 . . ?
C125 C124 C123 119.8(5) . . ?
C125 C124 H124 120.1 . . ?
C124 C125 H125 119.6 . . ?
C124 C125 C126 120.8(5) . . ?
C126 C125 H125 119.6 . . ?
C121 C126 C125 119.8(5) . . ?
C121 C126 H126 120.1 . . ?
C125 C126 H126 120.1 . . ?
C202 C201 P2 122.2(5) . . ?
C202 C201 C206 115.9(7) . . ?
C206 C201 P2 121.8(6) . . ?
C201 C202 H202 118.5 . . ?
C201 C202 C203 122.9(7) . . ?
C203 C202 H202 118.5 . . ?
C202 C203 H203 118.9 . . ?
C204 C203 C202 122.2(9) . . ?
C204 C203 H203 118.9 . . ?
C203 C204 H204 120.7 . . ?
C203 C204 C205 118.7(9) . . ?
C205 C204 H204 120.7 . . ?
C204 C205 H205 120.4 . . ?
C204 C205 C206 119.2(8) . . ?
C206 C205 H205 120.4 . . ?
C201 C206 H206 119.8 . . ?
C205 C206 C201 120.4(8) . . ?
C205 C206 H206 119.8 . . ?
C212 C211 P2 119.5(7) . . ?
C212 C211 C216 120.1(8) . . ?
C216 C211 P2 120.3(7) . . ?
C211 C212 H212 119.3 . . ?
C211 C212 C213 121.4(12) . . ?
C213 C212 H212 119.3 . . ?
C212 C213 H213 117.8 . . ?
C214 C213 C212 124.4(13) . . ?
C214 C213 H213 117.8 . . ?
C213 C214 H214 121.6 . . ?
C213 C214 C215 116.9(10) . . ?
C215 C214 H214 121.6 . . ?
C214 C215 H215 119.3 . . ?
C216 C215 C214 121.5(11) . . ?
C216 C215 H215 119.3 . . ?
C211 C216 H216 122.6 . . ?
C215 C216 C211 114.8(11) . . ?
C215 C216 H216 122.6 . . ?
C222 C221 P2 121.7(5) . . ?
C226 C221 P2 119.8(4) . . ?
C226 C221 C222 118.1(5) . . ?
C221 C222 H222 119.6 . . ?
C221 C222 C223 120.9(7) . . ?
C223 C222 H222 119.6 . . ?
C222 C223 H223 119.9 . . ?
C224 C223 C222 120.2(7) . . ?
C224 C223 H223 119.9 . . ?
C223 C224 H224 120.2 . . ?
C223 C224 C225 119.6(7) . . ?
C225 C224 H224 120.2 . . ?
C224 C225 H225 120.5 . . ?
C226 C225 C224 119.0(6) . . ?
C226 C225 H225 120.5 . . ?
C221 C226 H226 119.2 . . ?
C225 C226 C221 121.5(5) . . ?
C225 C226 H226 119.2 . . ?
C302 C301 P3 117.3(5) . . ?
C306 C301 P3 125.5(5) . . ?
C306 C301 C302 117.2(6) . . ?
C301 C302 H302 120.1 . . ?
C303 C302 C301 119.8(8) . . ?
C303 C302 H302 120.1 . . ?
C302 C303 H303 120.8 . . ?
C302 C303 C304 118.3(8) . . ?
C304 C303 H303 120.8 . . ?
C303 C304 H304 119.7 . . ?
C305 C304 C303 120.5(8) . . ?
C305 C304 H304 119.7 . . ?
C304 C305 H305 118.0 . . ?
C304 C305 C306 124.0(9) . . ?
C306 C305 H305 118.0 . . ?
C301 C306 C305 119.9(8) . . ?
C301 C306 H306 120.0 . . ?
C305 C306 H306 120.0 . . ?
C312 C311 P3 122.9(6) . . ?
C316 C311 P3 116.6(6) . . ?
C316 C311 C312 120.5(8) . . ?
C311 C312 H312 122.8 . . ?
C311 C312 C313 114.4(12) . . ?
C313 C312 H312 122.8 . . ?
C312 C313 H313 115.6 . . ?
C314 C313 C312 128.9(14) . . ?
C314 C313 H313 115.6 . . ?
C313 C314 H314 122.6 . . ?
C313 C314 C315 114.8(11) . . ?
C315 C314 H314 122.6 . . ?
C314 C315 H315 119.3 . . ?
C314 C315 C316 121.4(11) . . ?
C316 C315 H315 119.3 . . ?
C311 C316 C315 118.0(11) . . ?
C311 C316 H316 121.0 . . ?
C315 C316 H316 121.0 . . ?
C322 C321 P3 121.7(4) . . ?
C322 C321 C326 118.5(5) . . ?
C326 C321 P3 119.8(4) . . ?
C321 C322 H322 119.8 . . ?
C321 C322 C323 120.5(7) . . ?
C323 C322 H322 119.8 . . ?
C322 C323 H323 119.8 . . ?
C324 C323 C322 120.4(7) . . ?
C324 C323 H323 119.8 . . ?
C323 C324 H324 120.1 . . ?
C325 C324 C323 119.9(6) . . ?
C325 C324 H324 120.1 . . ?
C324 C325 H325 119.8 . . ?
C324 C325 C326 120.4(8) . . ?
C326 C325 H325 119.8 . . ?
C321 C326 C325 120.2(7) . . ?
C321 C326 H326 119.9 . . ?
C325 C326 H326 119.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Os1 P1 C101 C102 -112.9(4) . . . . ?
Os1 P1 C101 C106 64.0(4) . . . . ?
Os1 P1 C111 C112 56.6(4) . . . . ?
Os1 P1 C111 C116 -121.5(4) . . . . ?
Os1 P1 C121 C122 -170.6(4) . . . . ?
Os1 P1 C121 C126 7.9(5) . . . . ?
Os1 P2 C201 C202 37.3(7) . . . . ?
Os1 P2 C201 C206 -139.0(5) . . . . ?
Os1 P2 C211 C212 64.9(9) . . . . ?
Os1 P2 C211 C216 -113.4(7) . . . . ?
Os1 P2 C221 C222 -153.3(7) . . . . ?
Os1 P2 C221 C226 34.0(6) . . . . ?
P1 C101 C102 C103 174.4(5) . . . . ?
P1 C101 C106 C105 -176.5(4) . . . . ?
P1 C111 C112 C113 176.8(5) . . . . ?
P1 C111 C116 C115 -178.0(4) . . . . ?
P1 C121 C122 C123 179.2(5) . . . . ?
P1 C121 C126 C125 -178.9(4) . . . . ?
Ag1 C2 C3 C4 -80.9(10) . . . . ?
Ag1 C2 C3 C5 100.1(8) . . . . ?
Ag1 P3 C301 C302 -35.7(5) . . . . ?
Ag1 P3 C301 C306 144.1(5) . . . . ?
Ag1 P3 C311 C312 125.2(7) . . . . ?
Ag1 P3 C311 C316 -53.2(7) . . . . ?
Ag1 P3 C321 C322 161.4(5) . . . . ?
Ag1 P3 C321 C326 -18.0(6) . . . . ?
P2 C21A C22A C23A -178.6(10) . . . . ?
P2 C201 C202 C203 173.9(5) . . . . ?
P2 C201 C206 C205 -176.9(6) . . . . ?
P2 C211 C212 C213 -171.1(11) . . . . ?
P2 C211 C216 C215 172.2(10) . . . . ?
P2 C221 C222 C223 -177.1(9) . . . . ?
P2 C221 C226 C225 -178.2(5) . . . . ?
P3 C301 C302 C303 -178.6(6) . . . . ?
P3 C301 C306 C305 178.3(6) . . . . ?
P3 C311 C312 C313 179.3(10) . . . . ?
P3 C311 C316 C315 -178.5(8) . . . . ?
P3 C321 C322 C323 -179.9(6) . . . . ?
P3 C321 C326 C325 178.7(7) . . . . ?
C26A C21A C22A C23A 0.0 . . . . ?
C21A P2 C201 C202 -90.4(7) . . . . ?
C21A P2 C201 C206 93.3(7) . . . . ?
C21A P2 C221 C222 -40.2(9) . . . . ?
C21A P2 C221 C226 147.2(6) . . . . ?
C21A C26A C25A C24A 0.0 . . . . ?
C21A C22A C23A C24A 0.0 . . . . ?
C22A C23A C24A C25A 0.0 . . . . ?
C23A C24A C25A C26A 0.0 . . . . ?
C25A C26A C21A P2 178.7(10) . . . . ?
C25A C26A C21A C22A 0.0 . . . . ?
C101 P1 C111 C112 -66.8(4) . . . . ?
C101 P1 C111 C116 115.1(4) . . . . ?
C101 P1 C121 C122 -45.9(5) . . . . ?
C101 P1 C121 C126 132.7(4) . . . . ?
C101 C102 C103 C104 2.4(9) . . . . ?
C102 C101 C106 C105 0.6(8) . . . . ?
C102 C103 C104 C105 -0.4(10) . . . . ?
C103 C104 C105 C106 -1.4(9) . . . . ?
C104 C105 C106 C101 1.3(8) . . . . ?
C106 C101 C102 C103 -2.4(8) . . . . ?
C111 P1 C101 C102 10.8(5) . . . . ?
C111 P1 C101 C106 -172.3(4) . . . . ?
C111 P1 C121 C122 60.7(5) . . . . ?
C111 P1 C121 C126 -120.7(4) . . . . ?
C111 C112 C113 C114 1.8(10) . . . . ?
C112 C111 C116 C115 4.0(8) . . . . ?
C112 C113 C114 C115 2.7(10) . . . . ?
C113 C114 C115 C116 -3.8(10) . . . . ?
C114 C115 C116 C111 0.4(9) . . . . ?
C116 C111 C112 C113 -5.1(8) . . . . ?
C121 P1 C101 C102 117.8(5) . . . . ?
C121 P1 C101 C106 -65.3(4) . . . . ?
C121 P1 C111 C112 -171.0(4) . . . . ?
C121 P1 C111 C116 11.0(5) . . . . ?
C121 C122 C123 C124 -0.6(10) . . . . ?
C122 C121 C126 C125 -0.3(7) . . . . ?
C122 C123 C124 C125 0.4(10) . . . . ?
C123 C124 C125 C126 -0.1(9) . . . . ?
C124 C125 C126 C121 0.0(8) . . . . ?
C126 C121 C122 C123 0.6(8) . . . . ?
C201 P2 C211 C212 -168.4(8) . . . . ?
C201 P2 C211 C216 13.4(8) . . . . ?
C201 P2 C221 C222 81.3(8) . . . . ?
C201 P2 C221 C226 -91.3(5) . . . . ?
C201 C202 C203 C204 7.5(12) . . . . ?
C202 C201 C206 C205 6.6(10) . . . . ?
C202 C203 C204 C205 -1.5(13) . . . . ?
C203 C204 C205 C206 -1.3(13) . . . . ?
C204 C205 C206 C201 -1.3(12) . . . . ?
C206 C201 C202 C203 -9.6(11) . . . . ?
C211 P2 C201 C202 -90.0(6) . . . . ?
C211 P2 C201 C206 93.7(6) . . . . ?
C211 P2 C221 C222 -20.9(8) . . . . ?
C211 P2 C221 C226 166.5(6) . . . . ?
C211 C212 C213 C214 -9(2) . . . . ?
C212 C211 C216 C215 -6.1(17) . . . . ?
C212 C213 C214 C215 9(2) . . . . ?
C213 C214 C215 C216 -8(2) . . . . ?
C214 C215 C216 C211 7(2) . . . . ?
C216 C211 C212 C213 7.1(18) . . . . ?
C221 P2 C201 C202 164.8(6) . . . . ?
C221 P2 C201 C206 -11.5(6) . . . . ?
C221 P2 C211 C212 -68.8(9) . . . . ?
C221 P2 C211 C216 112.9(7) . . . . ?
C221 C222 C223 C224 1(2) . . . . ?
C222 C221 C226 C225 8.9(10) . . . . ?
C222 C223 C224 C225 -2.1(18) . . . . ?
C223 C224 C225 C226 6.4(13) . . . . ?
C224 C225 C226 C221 -10.0(10) . . . . ?
C226 C221 C222 C223 -4.3(15) . . . . ?
C301 P3 C311 C312 1.3(7) . . . . ?
C301 P3 C311 C316 -177.1(6) . . . . ?
C301 P3 C321 C322 -72.9(6) . . . . ?
C301 P3 C321 C326 107.7(6) . . . . ?
C301 C302 C303 C304 -3.3(12) . . . . ?
C302 C301 C306 C305 -1.9(11) . . . . ?
C302 C303 C304 C305 5.8(14) . . . . ?
C303 C304 C305 C306 -6.6(16) . . . . ?
C304 C305 C306 C301 4.8(15) . . . . ?
C306 C301 C302 C303 1.6(10) . . . . ?
C311 P3 C301 C302 87.3(5) . . . . ?
C311 P3 C301 C306 -92.9(6) . . . . ?
C311 P3 C321 C322 38.0(6) . . . . ?
C311 P3 C321 C326 -141.5(6) . . . . ?
C311 C312 C313 C314 10(3) . . . . ?
C312 C311 C316 C315 3.1(14) . . . . ?
C312 C313 C314 C315 -16(3) . . . . ?
C313 C314 C315 C316 16(2) . . . . ?
C314 C315 C316 C311 -9.9(19) . . . . ?
C316 C311 C312 C313 -2.3(16) . . . . ?
C321 P3 C301 C302 -163.4(5) . . . . ?
C321 P3 C301 C306 16.5(6) . . . . ?
C321 P3 C311 C312 -108.3(7) . . . . ?
C321 P3 C311 C316 73.3(7) . . . . ?
C321 C322 C323 C324 1.4(12) . . . . ?
C322 C321 C326 C325 -0.8(12) . . . . ?
C322 C323 C324 C325 -1.1(13) . . . . ?
C323 C324 C325 C326 -0.1(15) . . . . ?
C324 C325 C326 C321 1.0(15) . . . . ?
C326 C321 C322 C323 -0.4(10) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mo_20aug09btt1_0m_pl
_database_code_depnum_ccdc_archive 'CCDC 2065472'
loop_
_audit_author_name
_audit_author_address
'Tongdao Wang'
;Dalian University of Technology
China
;
_audit_update_record             
;
2021-08-13 deposited with the CCDC.	2021-08-16 downloaded from the CCDC.
;
_audit_creation_date             2021-02-28
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C68 H60 Ag O Os P3 Si'
_chemical_formula_sum            'C68 H60 Ag O Os P3 Si'
_chemical_formula_weight         1312.23
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'

_cell_length_a                   21.1275(9)
_cell_length_b                   19.3012(9)
_cell_length_c                   28.9253(14)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     11795.3(9)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    6757
_cell_measurement_temperature    200.15
_cell_measurement_theta_max      22.910
_cell_measurement_theta_min      2.388
_shelx_estimated_absorpt_T_max   0.779
_shelx_estimated_absorpt_T_min   0.420
_exptl_absorpt_coefficient_mu    2.628
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6523
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_crystal_colour            'clear light yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.478
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             5264
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1538
_diffrn_reflns_av_unetI/netI     0.1005
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            69295
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         2.198
_diffrn_ambient_temperature      200.15
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_type              'Incoatec I\ms'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6487
_reflns_number_total             10377
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (?, 2016)'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'SAINT V8.40A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS-1997 (Sheldrick, 2008)'
_refine_diff_density_max         0.543
_refine_diff_density_min         -0.552
_refine_diff_density_rms         0.133
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.965
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     683
_refine_ls_number_reflns         10377
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1003
_refine_ls_R_factor_gt           0.0466
_refine_ls_restrained_S_all      0.965
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0299P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0847
_refine_ls_wR_factor_ref         0.0959
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C12(H12), C13(H13), C14(H14), C15(H15), C16(H16), C102(H102), C103(H103),
 C104(H104), C105(H105), C106(H106), C112(H112), C113(H113), C114(H114),
 C115(H115), C116(H116), C122(H122), C123(H123), C124(H124), C125(H125),
 C126(H126), C202(H202), C203(H203), C204(H204), C205(H205), C206(H206),
 C212(H212), C213(H213), C214(H214), C215(H215), C216(H216), C222(H222),
 C223(H223), C224(H224), C225(H225), C226(H226), C302(H302), C303(H303),
 C304(H304), C305(H305), C306(H306), C312(H312), C313(H313), C314(H314),
 C315(H315), C316(H316), C322(H322), C323(H323), C324(H324), C325(H325),
 C326(H326)
2.b Idealised Me refined as rotating group:
 C3(H3A,H3B,H3C), C4(H4A,H4B,H4C), C5(H5A,H5B,H5C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.48361(2) 0.16655(2) 0.33135(2) 0.02250(8) Uani 1 1 d . . . . .
H H 0.517(3) 0.249(3) 0.321(2) 0.07(2) Uiso 1 1 d . . . . .
Ag1 Ag 0.59111(2) 0.24816(3) 0.36359(2) 0.03494(15) Uani 1 1 d . . . . .
P1 P 0.41888(8) 0.21004(9) 0.39068(6) 0.0266(4) Uani 1 1 d . . . . .
P2 P 0.54995(8) 0.11861(8) 0.27389(6) 0.0255(4) Uani 1 1 d . . . . .
P3 P 0.65699(8) 0.34433(9) 0.37606(7) 0.0329(5) Uani 1 1 d . . . . .
Si1 Si 0.66959(10) 0.10952(12) 0.43860(9) 0.0522(6) Uani 1 1 d . . . . .
O1 O 0.3924(2) 0.2278(2) 0.26100(18) 0.0469(14) Uani 1 1 d . . . . .
C1 C 0.5555(3) 0.1419(3) 0.3790(2) 0.0279(16) Uani 1 1 d . . . . .
C2 C 0.6001(3) 0.1349(3) 0.4048(3) 0.0333(18) Uani 1 1 d . . . . .
C3 C 0.6974(4) 0.1787(4) 0.4763(3) 0.072(3) Uani 1 1 d . . . . .
H3A H 0.662488 0.194590 0.495937 0.108 Uiso 1 1 calc GR . . . .
H3B H 0.712901 0.217351 0.457538 0.108 Uiso 1 1 calc GR . . . .
H3C H 0.731839 0.161246 0.495854 0.108 Uiso 1 1 calc GR . . . .
C4 C 0.6514(4) 0.0311(4) 0.4733(3) 0.075(3) Uani 1 1 d . . . . .
H4A H 0.634445 -0.005087 0.453026 0.112 Uiso 1 1 calc GR . . . .
H4B H 0.619966 0.042655 0.497006 0.112 Uiso 1 1 calc GR . . . .
H4C H 0.690144 0.014381 0.488199 0.112 Uiso 1 1 calc GR . . . .
C5 C 0.7350(4) 0.0879(5) 0.3959(3) 0.097(4) Uani 1 1 d . . . . .
H5A H 0.741283 0.127009 0.374765 0.145 Uiso 1 1 calc GR . . . .
H5B H 0.723172 0.046655 0.378088 0.145 Uiso 1 1 calc GR . . . .
H5C H 0.774425 0.078807 0.412719 0.145 Uiso 1 1 calc GR . . . .
C6 C 0.4458(3) 0.0683(3) 0.3427(2) 0.0276(16) Uani 1 1 d . . . . .
C7 C 0.4274(3) 0.0121(3) 0.3525(2) 0.0330(18) Uani 1 1 d . . . . .
C8 C 0.4262(3) 0.2022(3) 0.2882(2) 0.0283(17) Uani 1 1 d . . . . .
C11 C 0.4062(3) -0.0574(4) 0.3624(2) 0.0378(18) Uani 1 1 d . . . . .
C12 C 0.4384(4) -0.1145(4) 0.3452(3) 0.050(2) Uani 1 1 d . . . . .
H12 H 0.474797 -0.107560 0.326528 0.060 Uiso 1 1 calc R . . . .
C13 C 0.4188(6) -0.1808(5) 0.3545(3) 0.089(4) Uani 1 1 d . . . . .
H13 H 0.442163 -0.218968 0.342831 0.107 Uiso 1 1 calc R . . . .
C14 C 0.3658(6) -0.1922(5) 0.3805(4) 0.093(5) Uani 1 1 d . . . . .
H14 H 0.351805 -0.238094 0.386447 0.112 Uiso 1 1 calc R . . . .
C15 C 0.3332(4) -0.1371(6) 0.3978(4) 0.080(3) Uani 1 1 d . . . . .
H15 H 0.296123 -0.144572 0.415691 0.096 Uiso 1 1 calc R . . . .
C16 C 0.3545(4) -0.0689(4) 0.3893(3) 0.059(3) Uani 1 1 d . . . . .
H16 H 0.332492 -0.030820 0.402529 0.071 Uiso 1 1 calc R . . . .
C101 C 0.3383(3) 0.1742(3) 0.3965(2) 0.0281(16) Uani 1 1 d . . . . .
C102 C 0.3096(3) 0.1395(3) 0.3603(3) 0.0357(18) Uani 1 1 d . . . . .
H102 H 0.331617 0.133166 0.331976 0.043 Uiso 1 1 calc R . . . .
C103 C 0.2485(3) 0.1138(4) 0.3653(3) 0.048(2) Uani 1 1 d . . . . .
H103 H 0.228059 0.091401 0.340133 0.057 Uiso 1 1 calc R . . . .
C104 C 0.2185(3) 0.1210(4) 0.4062(3) 0.048(2) Uani 1 1 d . . . . .
H104 H 0.177940 0.100637 0.410104 0.058 Uiso 1 1 calc R . . . .
C105 C 0.2452(3) 0.1569(4) 0.4424(3) 0.051(2) Uani 1 1 d . . . . .
H105 H 0.222492 0.163668 0.470429 0.061 Uiso 1 1 calc R . . . .
C106 C 0.3055(3) 0.1830(3) 0.4371(2) 0.040(2) Uani 1 1 d . . . . .
H106 H 0.324750 0.207399 0.461875 0.048 Uiso 1 1 calc R . . . .
C111 C 0.4499(3) 0.1948(4) 0.4485(2) 0.0293(16) Uani 1 1 d . . . . .
C112 C 0.4574(3) 0.1249(4) 0.4613(3) 0.043(2) Uani 1 1 d . . . . .
H112 H 0.443874 0.089528 0.440669 0.051 Uiso 1 1 calc R . . . .
C113 C 0.4838(3) 0.1067(4) 0.5027(3) 0.0458(19) Uani 1 1 d . . . . .
H113 H 0.486717 0.059207 0.511096 0.055 Uiso 1 1 calc R . . . .
C114 C 0.5060(3) 0.1566(5) 0.5319(3) 0.052(2) Uani 1 1 d . . . . .
H114 H 0.526073 0.143654 0.560054 0.063 Uiso 1 1 calc R . . . .
C115 C 0.4996(3) 0.2250(4) 0.5210(3) 0.049(2) Uani 1 1 d . . . . .
H115 H 0.514858 0.259595 0.541509 0.058 Uiso 1 1 calc R . . . .
C116 C 0.4702(3) 0.2445(4) 0.4791(2) 0.0403(19) Uani 1 1 d . . . . .
H116 H 0.464381 0.292164 0.472154 0.048 Uiso 1 1 calc R . . . .
C121 C 0.4032(3) 0.3029(3) 0.3874(2) 0.0329(17) Uani 1 1 d . . . . .
C122 C 0.3441(3) 0.3306(4) 0.3793(3) 0.049(2) Uani 1 1 d . . . . .
H122 H 0.308711 0.300529 0.376849 0.058 Uiso 1 1 calc R . . . .
C123 C 0.3352(4) 0.4024(4) 0.3746(3) 0.065(3) Uani 1 1 d . . . . .
H123 H 0.293979 0.420193 0.369169 0.078 Uiso 1 1 calc R . . . .
C124 C 0.3851(4) 0.4468(4) 0.3778(3) 0.057(2) Uani 1 1 d . . . . .
H124 H 0.378799 0.495380 0.375046 0.069 Uiso 1 1 calc R . . . .
C125 C 0.4442(4) 0.4207(4) 0.3851(3) 0.052(2) Uani 1 1 d . . . . .
H125 H 0.479381 0.451219 0.386870 0.062 Uiso 1 1 calc R . . . .
C126 C 0.4534(3) 0.3502(3) 0.3898(2) 0.0386(19) Uani 1 1 d . . . . .
H126 H 0.495069 0.333253 0.394721 0.046 Uiso 1 1 calc R . . . .
C201 C 0.5715(3) 0.0267(3) 0.2795(3) 0.0310(17) Uani 1 1 d . . . . .
C202 C 0.5884(3) -0.0009(4) 0.3218(2) 0.0393(19) Uani 1 1 d . . . . .
H202 H 0.588481 0.028360 0.348201 0.047 Uiso 1 1 calc R . . . .
C203 C 0.6051(3) -0.0697(3) 0.3271(3) 0.046(2) Uani 1 1 d . . . . .
H203 H 0.615664 -0.087650 0.356658 0.055 Uiso 1 1 calc R . . . .
C204 C 0.6061(3) -0.1122(4) 0.2883(3) 0.049(2) Uani 1 1 d . . . . .
H204 H 0.618443 -0.159279 0.291381 0.059 Uiso 1 1 calc R . . . .
C205 C 0.5897(4) -0.0872(4) 0.2458(3) 0.057(2) Uani 1 1 d . . . . .
H205 H 0.589206 -0.116798 0.219582 0.069 Uiso 1 1 calc R . . . .
C206 C 0.5734(3) -0.0166(4) 0.2415(3) 0.047(2) Uani 1 1 d . . . . .
H206 H 0.563410 0.001474 0.211873 0.057 Uiso 1 1 calc R . . . .
C211 C 0.5178(3) 0.1203(3) 0.2150(2) 0.0270(15) Uani 1 1 d . . . . .
C212 C 0.4556(3) 0.0998(3) 0.2079(3) 0.0377(18) Uani 1 1 d . . . . .
H212 H 0.429932 0.088643 0.233807 0.045 Uiso 1 1 calc R . . . .
C213 C 0.4304(4) 0.0953(4) 0.1641(3) 0.051(2) Uani 1 1 d . . . . .
H213 H 0.388127 0.079897 0.159724 0.062 Uiso 1 1 calc R . . . .
C214 C 0.4673(4) 0.1135(4) 0.1264(3) 0.058(2) Uani 1 1 d . . . . .
H214 H 0.449855 0.112349 0.096117 0.070 Uiso 1 1 calc R . . . .
C215 C 0.5293(4) 0.1331(4) 0.1329(3) 0.051(2) Uani 1 1 d . . . . .
H215 H 0.554798 0.145120 0.107065 0.061 Uiso 1 1 calc R . . . .
C216 C 0.5540(3) 0.1355(3) 0.1763(2) 0.0373(18) Uani 1 1 d . . . . .
H216 H 0.597227 0.147810 0.180138 0.045 Uiso 1 1 calc R . . . .
C221 C 0.6264(3) 0.1619(3) 0.2661(2) 0.0281(16) Uani 1 1 d . . . . .
C222 C 0.6252(3) 0.2327(3) 0.2529(2) 0.0322(17) Uani 1 1 d . . . . .
H222 H 0.586066 0.256757 0.251925 0.039 Uiso 1 1 calc R . . . .
C223 C 0.6804(3) 0.2668(4) 0.2414(2) 0.0385(19) Uani 1 1 d . . . . .
H223 H 0.678899 0.313958 0.232007 0.046 Uiso 1 1 calc R . . . .
C224 C 0.7376(3) 0.2326(4) 0.2436(3) 0.043(2) Uani 1 1 d . . . . .
H224 H 0.775521 0.255905 0.235168 0.052 Uiso 1 1 calc R . . . .
C225 C 0.7397(3) 0.1645(4) 0.2580(2) 0.043(2) Uani 1 1 d . . . . .
H225 H 0.779210 0.141506 0.261011 0.052 Uiso 1 1 calc R . . . .
C226 C 0.6840(3) 0.1297(3) 0.2679(2) 0.0334(18) Uani 1 1 d . . . . .
H226 H 0.685890 0.082163 0.276296 0.040 Uiso 1 1 calc R . . . .
C301 C 0.6307(3) 0.3985(4) 0.4234(3) 0.0372(19) Uani 1 1 d . . . . .
C302 C 0.6010(3) 0.3679(4) 0.4607(3) 0.050(2) Uani 1 1 d . . . . .
H302 H 0.594454 0.319181 0.460871 0.060 Uiso 1 1 calc R . . . .
C303 C 0.5807(4) 0.4075(6) 0.4980(3) 0.074(3) Uani 1 1 d . . . . .
H303 H 0.559651 0.385349 0.522969 0.089 Uiso 1 1 calc R . . . .
C304 C 0.5903(4) 0.4773(6) 0.4996(3) 0.076(3) Uani 1 1 d . . . . .
H304 H 0.576726 0.504128 0.525301 0.091 Uiso 1 1 calc R . . . .
C305 C 0.6198(4) 0.5066(5) 0.4632(3) 0.073(3) Uani 1 1 d . . . . .
H305 H 0.627002 0.555135 0.463560 0.088 Uiso 1 1 calc R . . . .
C306 C 0.6398(4) 0.4690(4) 0.4253(3) 0.057(2) Uani 1 1 d . . . . .
H306 H 0.660181 0.491991 0.400385 0.069 Uiso 1 1 calc R . . . .
C311 C 0.7384(3) 0.3217(3) 0.3897(2) 0.0327(17) Uani 1 1 d . . . . .
C312 C 0.7663(3) 0.2712(4) 0.3630(3) 0.046(2) Uani 1 1 d . . . . .
H312 H 0.742326 0.250428 0.338935 0.055 Uiso 1 1 calc R . . . .
C313 C 0.8278(3) 0.2498(4) 0.3700(3) 0.059(2) Uani 1 1 d . . . . .
H313 H 0.845987 0.214847 0.351089 0.071 Uiso 1 1 calc R . . . .
C314 C 0.8622(4) 0.2800(4) 0.4047(3) 0.054(2) Uani 1 1 d . . . . .
H314 H 0.904902 0.266451 0.409461 0.064 Uiso 1 1 calc R . . . .
C315 C 0.8357(3) 0.3293(4) 0.4326(3) 0.049(2) Uani 1 1 d . . . . .
H315 H 0.859421 0.348274 0.457481 0.059 Uiso 1 1 calc R . . . .
C316 C 0.7736(3) 0.3519(4) 0.4246(2) 0.039(2) Uani 1 1 d . . . . .
H316 H 0.755798 0.387718 0.442954 0.047 Uiso 1 1 calc R . . . .
C321 C 0.6633(3) 0.4000(3) 0.3258(2) 0.0325(17) Uani 1 1 d . . . . .
C322 C 0.6094(3) 0.4126(3) 0.3007(3) 0.0400(19) Uani 1 1 d . . . . .
H322 H 0.569961 0.394836 0.311045 0.048 Uiso 1 1 calc R . . . .
C323 C 0.6122(4) 0.4512(4) 0.2604(3) 0.049(2) Uani 1 1 d . . . . .
H323 H 0.574315 0.461783 0.244215 0.058 Uiso 1 1 calc R . . . .
C324 C 0.6696(4) 0.4747(4) 0.2434(3) 0.050(2) Uani 1 1 d . . . . .
H324 H 0.671641 0.499405 0.215002 0.060 Uiso 1 1 calc R . . . .
C325 C 0.7239(4) 0.4612(4) 0.2685(3) 0.051(2) Uani 1 1 d . . . . .
H325 H 0.763723 0.477236 0.257645 0.061 Uiso 1 1 calc R . . . .
C326 C 0.7203(3) 0.4243(4) 0.3097(3) 0.044(2) Uani 1 1 d . . . . .
H326 H 0.757791 0.415880 0.326966 0.053 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Os1 H 1.76(6) . ?
Os1 Ag1 2.9170(5) . ?
Os1 P1 2.3494(17) . ?
Os1 P2 2.3628(17) . ?
Os1 C1 2.105(7) . ?
Os1 C6 2.084(7) . ?
Os1 C8 1.872(7) . ?
Ag1 H 1.99(6) . ?
Ag1 P3 2.3481(18) . ?
Ag1 C1 2.230(6) . ?
Ag1 C2 2.497(7) . ?
P1 C101 1.846(6) . ?
P1 C111 1.819(7) . ?
P1 C121 1.826(6) . ?
P2 C201 1.839(6) . ?
P2 C211 1.834(6) . ?
P2 C221 1.833(6) . ?
P3 C301 1.810(7) . ?
P3 C311 1.817(7) . ?
P3 C321 1.813(7) . ?
Si1 C2 1.831(7) . ?
Si1 C3 1.822(8) . ?
Si1 C4 1.856(8) . ?
Si1 C5 1.901(8) . ?
O1 C8 1.171(7) . ?
C1 C2 1.210(8) . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 C7 1.187(8) . ?
C7 C11 1.442(9) . ?
C11 C12 1.387(10) . ?
C11 C16 1.361(9) . ?
C12 H12 0.9500 . ?
C12 C13 1.371(10) . ?
C13 H13 0.9500 . ?
C13 C14 1.366(14) . ?
C14 H14 0.9500 . ?
C14 C15 1.362(13) . ?
C15 H15 0.9500 . ?
C15 C16 1.412(11) . ?
C16 H16 0.9500 . ?
C101 C102 1.384(9) . ?
C101 C106 1.372(8) . ?
C102 H102 0.9500 . ?
C102 C103 1.389(8) . ?
C103 H103 0.9500 . ?
C103 C104 1.349(10) . ?
C104 H104 0.9500 . ?
C104 C105 1.377(10) . ?
C105 H105 0.9500 . ?
C105 C106 1.380(9) . ?
C106 H106 0.9500 . ?
C111 C112 1.410(9) . ?
C111 C116 1.375(9) . ?
C112 H112 0.9500 . ?
C112 C113 1.366(9) . ?
C113 H113 0.9500 . ?
C113 C114 1.366(10) . ?
C114 H114 0.9500 . ?
C114 C115 1.366(10) . ?
C115 H115 0.9500 . ?
C115 C116 1.410(9) . ?
C116 H116 0.9500 . ?
C121 C122 1.376(9) . ?
C121 C126 1.401(9) . ?
C122 H122 0.9500 . ?
C122 C123 1.406(9) . ?
C123 H123 0.9500 . ?
C123 C124 1.361(10) . ?
C124 H124 0.9500 . ?
C124 C125 1.363(9) . ?
C125 H125 0.9500 . ?
C125 C126 1.381(9) . ?
C126 H126 0.9500 . ?
C201 C202 1.383(9) . ?
C201 C206 1.380(9) . ?
C202 H202 0.9500 . ?
C202 C203 1.382(9) . ?
C203 H203 0.9500 . ?
C203 C204 1.389(9) . ?
C204 H204 0.9500 . ?
C204 C205 1.365(10) . ?
C205 H205 0.9500 . ?
C205 C206 1.410(9) . ?
C206 H206 0.9500 . ?
C211 C212 1.387(8) . ?
C211 C216 1.388(9) . ?
C212 H212 0.9500 . ?
C212 C213 1.379(9) . ?
C213 H213 0.9500 . ?
C213 C214 1.385(10) . ?
C214 H214 0.9500 . ?
C214 C215 1.377(10) . ?
C215 H215 0.9500 . ?
C215 C216 1.359(9) . ?
C216 H216 0.9500 . ?
C221 C222 1.418(8) . ?
C221 C226 1.367(8) . ?
C222 H222 0.9500 . ?
C222 C223 1.379(8) . ?
C223 H223 0.9500 . ?
C223 C224 1.379(8) . ?
C224 H224 0.9500 . ?
C224 C225 1.380(9) . ?
C225 H225 0.9500 . ?
C225 C226 1.384(8) . ?
C226 H226 0.9500 . ?
C301 C302 1.380(9) . ?
C301 C306 1.375(9) . ?
C302 H302 0.9500 . ?
C302 C303 1.390(10) . ?
C303 H303 0.9500 . ?
C303 C304 1.363(11) . ?
C304 H304 0.9500 . ?
C304 C305 1.349(12) . ?
C305 H305 0.9500 . ?
C305 C306 1.380(10) . ?
C306 H306 0.9500 . ?
C311 C312 1.376(9) . ?
C311 C316 1.381(9) . ?
C312 H312 0.9500 . ?
C312 C313 1.379(9) . ?
C313 H313 0.9500 . ?
C313 C314 1.368(10) . ?
C314 H314 0.9500 . ?
C314 C315 1.368(10) . ?
C315 H315 0.9500 . ?
C315 C316 1.403(9) . ?
C316 H316 0.9500 . ?
C321 C322 1.372(8) . ?
C321 C326 1.374(8) . ?
C322 H322 0.9500 . ?
C322 C323 1.385(10) . ?
C323 H323 0.9500 . ?
C323 C324 1.384(9) . ?
C324 H324 0.9500 . ?
C324 C325 1.383(9) . ?
C325 H325 0.9500 . ?
C325 C326 1.389(9) . ?
C326 H326 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag1 Os1 H 42.0(19) . . ?
P1 Os1 H 92(2) . . ?
P1 Os1 Ag1 91.53(4) . . ?
P1 Os1 P2 177.42(6) . . ?
P2 Os1 H 90(2) . . ?
P2 Os1 Ag1 88.54(4) . . ?
C1 Os1 H 91.5(19) . . ?
C1 Os1 Ag1 49.57(16) . . ?
C1 Os1 P1 91.27(18) . . ?
C1 Os1 P2 86.81(17) . . ?
C6 Os1 H 179(2) . . ?
C6 Os1 Ag1 137.70(17) . . ?
C6 Os1 P1 89.27(17) . . ?
C6 Os1 P2 88.94(17) . . ?
C6 Os1 C1 88.1(2) . . ?
C8 Os1 H 79.3(19) . . ?
C8 Os1 Ag1 121.28(19) . . ?
C8 Os1 P1 88.8(2) . . ?
C8 Os1 P2 93.4(2) . . ?
C8 Os1 C1 170.8(2) . . ?
C8 Os1 C6 101.0(2) . . ?
Os1 Ag1 H 36.3(19) . . ?
P3 Ag1 Os1 159.65(5) . . ?
P3 Ag1 H 123.7(19) . . ?
P3 Ag1 C2 125.00(16) . . ?
C1 Ag1 Os1 45.92(17) . . ?
C1 Ag1 H 82.2(19) . . ?
C1 Ag1 P3 153.71(18) . . ?
C1 Ag1 C2 29.0(2) . . ?
C2 Ag1 Os1 74.88(15) . . ?
C2 Ag1 H 111.2(19) . . ?
C101 P1 Os1 118.0(2) . . ?
C111 P1 Os1 113.8(2) . . ?
C111 P1 C101 100.8(3) . . ?
C111 P1 C121 105.7(3) . . ?
C121 P1 Os1 114.8(2) . . ?
C121 P1 C101 101.8(3) . . ?
C201 P2 Os1 117.6(2) . . ?
C211 P2 Os1 115.3(2) . . ?
C211 P2 C201 101.0(3) . . ?
C221 P2 Os1 115.5(2) . . ?
C221 P2 C201 103.4(3) . . ?
C221 P2 C211 101.8(3) . . ?
C301 P3 Ag1 113.0(2) . . ?
C301 P3 C311 105.3(3) . . ?
C301 P3 C321 106.7(3) . . ?
C311 P3 Ag1 113.9(2) . . ?
C321 P3 Ag1 112.9(2) . . ?
C321 P3 C311 104.3(3) . . ?
C2 Si1 C4 109.9(4) . . ?
C2 Si1 C5 107.2(4) . . ?
C3 Si1 C2 112.5(3) . . ?
C3 Si1 C4 109.9(4) . . ?
C3 Si1 C5 108.4(4) . . ?
C4 Si1 C5 108.8(4) . . ?
Os1 C1 Ag1 84.5(2) . . ?
C2 C1 Os1 172.3(6) . . ?
C2 C1 Ag1 87.8(5) . . ?
Si1 C2 Ag1 123.4(3) . . ?
C1 C2 Ag1 63.2(4) . . ?
C1 C2 Si1 169.7(6) . . ?
Si1 C3 H3A 109.5 . . ?
Si1 C3 H3B 109.5 . . ?
Si1 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si1 C4 H4A 109.5 . . ?
Si1 C4 H4B 109.5 . . ?
Si1 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
Si1 C5 H5A 109.5 . . ?
Si1 C5 H5B 109.5 . . ?
Si1 C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C7 C6 Os1 174.3(6) . . ?
C6 C7 C11 177.4(8) . . ?
O1 C8 Os1 176.1(6) . . ?
C12 C11 C7 121.0(7) . . ?
C16 C11 C7 121.0(7) . . ?
C16 C11 C12 117.9(7) . . ?
C11 C12 H12 119.2 . . ?
C13 C12 C11 121.5(9) . . ?
C13 C12 H12 119.2 . . ?
C12 C13 H13 119.8 . . ?
C14 C13 C12 120.4(10) . . ?
C14 C13 H13 119.8 . . ?
C13 C14 H14 120.3 . . ?
C15 C14 C13 119.4(9) . . ?
C15 C14 H14 120.3 . . ?
C14 C15 H15 119.9 . . ?
C14 C15 C16 120.2(10) . . ?
C16 C15 H15 119.9 . . ?
C11 C16 C15 120.5(9) . . ?
C11 C16 H16 119.7 . . ?
C15 C16 H16 119.7 . . ?
C102 C101 P1 121.1(5) . . ?
C106 C101 P1 119.8(5) . . ?
C106 C101 C102 119.0(6) . . ?
C101 C102 H102 120.0 . . ?
C101 C102 C103 120.1(7) . . ?
C103 C102 H102 120.0 . . ?
C102 C103 H103 120.3 . . ?
C104 C103 C102 119.4(7) . . ?
C104 C103 H103 120.3 . . ?
C103 C104 H104 119.1 . . ?
C103 C104 C105 121.8(7) . . ?
C105 C104 H104 119.1 . . ?
C104 C105 H105 120.8 . . ?
C104 C105 C106 118.4(7) . . ?
C106 C105 H105 120.8 . . ?
C101 C106 C105 121.2(7) . . ?
C101 C106 H106 119.4 . . ?
C105 C106 H106 119.4 . . ?
C112 C111 P1 115.9(5) . . ?
C116 C111 P1 126.4(6) . . ?
C116 C111 C112 117.6(7) . . ?
C111 C112 H112 119.2 . . ?
C113 C112 C111 121.5(7) . . ?
C113 C112 H112 119.2 . . ?
C112 C113 H113 119.9 . . ?
C114 C113 C112 120.1(8) . . ?
C114 C113 H113 119.9 . . ?
C113 C114 H114 119.9 . . ?
C115 C114 C113 120.2(8) . . ?
C115 C114 H114 119.9 . . ?
C114 C115 H115 120.0 . . ?
C114 C115 C116 120.1(7) . . ?
C116 C115 H115 120.0 . . ?
C111 C116 C115 120.4(7) . . ?
C111 C116 H116 119.8 . . ?
C115 C116 H116 119.8 . . ?
C122 C121 P1 123.7(6) . . ?
C122 C121 C126 116.2(6) . . ?
C126 C121 P1 119.9(5) . . ?
C121 C122 H122 119.3 . . ?
C121 C122 C123 121.3(7) . . ?
C123 C122 H122 119.3 . . ?
C122 C123 H123 119.6 . . ?
C124 C123 C122 120.7(8) . . ?
C124 C123 H123 119.6 . . ?
C123 C124 H124 120.4 . . ?
C123 C124 C125 119.1(8) . . ?
C125 C124 H124 120.4 . . ?
C124 C125 H125 119.7 . . ?
C124 C125 C126 120.6(8) . . ?
C126 C125 H125 119.7 . . ?
C121 C126 H126 119.0 . . ?
C125 C126 C121 122.0(7) . . ?
C125 C126 H126 119.0 . . ?
C202 C201 P2 120.9(5) . . ?
C206 C201 P2 121.5(6) . . ?
C206 C201 C202 117.6(6) . . ?
C201 C202 H202 118.9 . . ?
C203 C202 C201 122.3(7) . . ?
C203 C202 H202 118.9 . . ?
C202 C203 H203 120.6 . . ?
C202 C203 C204 118.8(7) . . ?
C204 C203 H203 120.6 . . ?
C203 C204 H204 119.5 . . ?
C205 C204 C203 120.9(7) . . ?
C205 C204 H204 119.5 . . ?
C204 C205 H205 120.6 . . ?
C204 C205 C206 118.8(7) . . ?
C206 C205 H205 120.6 . . ?
C201 C206 C205 121.5(7) . . ?
C201 C206 H206 119.3 . . ?
C205 C206 H206 119.3 . . ?
C212 C211 P2 118.9(5) . . ?
C212 C211 C216 117.6(6) . . ?
C216 C211 P2 123.3(5) . . ?
C211 C212 H212 119.3 . . ?
C213 C212 C211 121.3(7) . . ?
C213 C212 H212 119.3 . . ?
C212 C213 H213 120.3 . . ?
C212 C213 C214 119.4(7) . . ?
C214 C213 H213 120.3 . . ?
C213 C214 H214 120.1 . . ?
C215 C214 C213 119.8(8) . . ?
C215 C214 H214 120.1 . . ?
C214 C215 H215 120.0 . . ?
C216 C215 C214 120.1(8) . . ?
C216 C215 H215 120.0 . . ?
C211 C216 H216 119.1 . . ?
C215 C216 C211 121.7(7) . . ?
C215 C216 H216 119.1 . . ?
C222 C221 P2 117.2(5) . . ?
C226 C221 P2 124.9(5) . . ?
C226 C221 C222 117.6(6) . . ?
C221 C222 H222 119.6 . . ?
C223 C222 C221 120.7(6) . . ?
C223 C222 H222 119.6 . . ?
C222 C223 H223 120.0 . . ?
C222 C223 C224 120.0(7) . . ?
C224 C223 H223 120.0 . . ?
C223 C224 H224 120.1 . . ?
C223 C224 C225 119.8(6) . . ?
C225 C224 H224 120.1 . . ?
C224 C225 H225 120.1 . . ?
C224 C225 C226 119.9(6) . . ?
C226 C225 H225 120.1 . . ?
C221 C226 C225 121.8(6) . . ?
C221 C226 H226 119.1 . . ?
C225 C226 H226 119.1 . . ?
C302 C301 P3 118.9(6) . . ?
C306 C301 P3 124.0(6) . . ?
C306 C301 C302 117.1(7) . . ?
C301 C302 H302 119.6 . . ?
C301 C302 C303 120.7(8) . . ?
C303 C302 H302 119.6 . . ?
C302 C303 H303 119.2 . . ?
C304 C303 C302 121.6(9) . . ?
C304 C303 H303 119.2 . . ?
C303 C304 H304 121.4 . . ?
C305 C304 C303 117.1(9) . . ?
C305 C304 H304 121.4 . . ?
C304 C305 H305 118.6 . . ?
C304 C305 C306 122.8(9) . . ?
C306 C305 H305 118.6 . . ?
C301 C306 C305 120.6(8) . . ?
C301 C306 H306 119.7 . . ?
C305 C306 H306 119.7 . . ?
C312 C311 P3 116.9(5) . . ?
C312 C311 C316 118.5(6) . . ?
C316 C311 P3 124.5(6) . . ?
C311 C312 H312 118.9 . . ?
C311 C312 C313 122.3(7) . . ?
C313 C312 H312 118.9 . . ?
C312 C313 H313 120.7 . . ?
C314 C313 C312 118.7(8) . . ?
C314 C313 H313 120.7 . . ?
C313 C314 H314 119.6 . . ?
C315 C314 C313 120.8(7) . . ?
C315 C314 H314 119.6 . . ?
C314 C315 H315 120.0 . . ?
C314 C315 C316 120.0(7) . . ?
C316 C315 H315 120.0 . . ?
C311 C316 C315 119.6(7) . . ?
C311 C316 H316 120.2 . . ?
C315 C316 H316 120.2 . . ?
C322 C321 P3 117.9(5) . . ?
C322 C321 C326 119.2(7) . . ?
C326 C321 P3 122.6(5) . . ?
C321 C322 H322 119.8 . . ?
C321 C322 C323 120.3(7) . . ?
C323 C322 H322 119.8 . . ?
C322 C323 H323 119.6 . . ?
C324 C323 C322 120.9(7) . . ?
C324 C323 H323 119.6 . . ?
C323 C324 H324 120.7 . . ?
C325 C324 C323 118.5(8) . . ?
C325 C324 H324 120.7 . . ?
C324 C325 H325 119.9 . . ?
C324 C325 C326 120.1(7) . . ?
C326 C325 H325 119.9 . . ?
C321 C326 C325 120.9(7) . . ?
C321 C326 H326 119.6 . . ?
C325 C326 H326 119.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Os1 P1 C101 C102 -19.2(6) . . . . ?
Os1 P1 C101 C106 162.0(5) . . . . ?
Os1 P1 C111 C112 -61.5(5) . . . . ?
Os1 P1 C111 C116 114.0(6) . . . . ?
Os1 P1 C121 C122 114.1(6) . . . . ?
Os1 P1 C121 C126 -60.9(6) . . . . ?
Os1 P2 C201 C202 -42.9(6) . . . . ?
Os1 P2 C201 C206 139.1(5) . . . . ?
Os1 P2 C211 C212 -45.8(5) . . . . ?
Os1 P2 C211 C216 139.9(5) . . . . ?
Os1 P2 C221 C222 -60.5(5) . . . . ?
Os1 P2 C221 C226 125.7(5) . . . . ?
Ag1 P3 C301 C302 32.9(6) . . . . ?
Ag1 P3 C301 C306 -148.8(6) . . . . ?
Ag1 P3 C311 C312 45.1(6) . . . . ?
Ag1 P3 C311 C316 -135.3(5) . . . . ?
Ag1 P3 C321 C322 41.0(6) . . . . ?
Ag1 P3 C321 C326 -133.0(5) . . . . ?
Ag1 C1 C2 Si1 -132(4) . . . . ?
P1 C101 C102 C103 -179.1(5) . . . . ?
P1 C101 C106 C105 179.8(5) . . . . ?
P1 C111 C112 C113 176.0(6) . . . . ?
P1 C111 C116 C115 -173.1(5) . . . . ?
P1 C121 C122 C123 -176.4(6) . . . . ?
P1 C121 C126 C125 176.6(6) . . . . ?
P2 C201 C202 C203 -179.7(5) . . . . ?
P2 C201 C206 C205 -179.8(6) . . . . ?
P2 C211 C212 C213 -175.3(5) . . . . ?
P2 C211 C216 C215 176.9(5) . . . . ?
P2 C221 C222 C223 -172.9(5) . . . . ?
P2 C221 C226 C225 174.6(5) . . . . ?
P3 C301 C302 C303 179.3(6) . . . . ?
P3 C301 C306 C305 -178.4(6) . . . . ?
P3 C311 C312 C313 179.8(6) . . . . ?
P3 C311 C316 C315 178.7(5) . . . . ?
P3 C321 C322 C323 -176.0(5) . . . . ?
P3 C321 C326 C325 173.7(6) . . . . ?
C3 Si1 C2 Ag1 45.5(5) . . . . ?
C3 Si1 C2 C1 173(4) . . . . ?
C4 Si1 C2 Ag1 168.3(4) . . . . ?
C4 Si1 C2 C1 -65(4) . . . . ?
C5 Si1 C2 Ag1 -73.5(5) . . . . ?
C5 Si1 C2 C1 54(4) . . . . ?
C7 C11 C12 C13 179.9(7) . . . . ?
C7 C11 C16 C15 178.3(7) . . . . ?
C11 C12 C13 C14 1.3(13) . . . . ?
C12 C11 C16 C15 -2.3(11) . . . . ?
C12 C13 C14 C15 -1.2(15) . . . . ?
C13 C14 C15 C16 -0.6(15) . . . . ?
C14 C15 C16 C11 2.4(14) . . . . ?
C16 C11 C12 C13 0.4(11) . . . . ?
C101 P1 C111 C112 65.9(5) . . . . ?
C101 P1 C111 C116 -118.6(6) . . . . ?
C101 P1 C121 C122 -14.6(7) . . . . ?
C101 P1 C121 C126 170.4(6) . . . . ?
C101 C102 C103 C104 -2.3(11) . . . . ?
C102 C101 C106 C105 1.0(11) . . . . ?
C102 C103 C104 C105 4.2(12) . . . . ?
C103 C104 C105 C106 -3.4(12) . . . . ?
C104 C105 C106 C101 0.8(11) . . . . ?
C106 C101 C102 C103 -0.2(10) . . . . ?
C111 P1 C101 C102 -143.8(6) . . . . ?
C111 P1 C101 C106 37.4(6) . . . . ?
C111 P1 C121 C122 -119.6(6) . . . . ?
C111 P1 C121 C126 65.4(6) . . . . ?
C111 C112 C113 C114 -2.7(11) . . . . ?
C112 C111 C116 C115 2.4(10) . . . . ?
C112 C113 C114 C115 2.8(11) . . . . ?
C113 C114 C115 C116 -0.4(11) . . . . ?
C114 C115 C116 C111 -2.3(10) . . . . ?
C116 C111 C112 C113 0.1(10) . . . . ?
C121 P1 C101 C102 107.5(6) . . . . ?
C121 P1 C101 C106 -71.4(6) . . . . ?
C121 P1 C111 C112 171.6(5) . . . . ?
C121 P1 C111 C116 -12.9(7) . . . . ?
C121 C122 C123 C124 0.3(13) . . . . ?
C122 C121 C126 C125 1.2(11) . . . . ?
C122 C123 C124 C125 0.9(13) . . . . ?
C123 C124 C125 C126 -0.9(12) . . . . ?
C124 C125 C126 C121 -0.1(12) . . . . ?
C126 C121 C122 C123 -1.2(11) . . . . ?
C201 P2 C211 C212 82.0(5) . . . . ?
C201 P2 C211 C216 -92.4(6) . . . . ?
C201 P2 C221 C222 169.6(5) . . . . ?
C201 P2 C221 C226 -4.2(7) . . . . ?
C201 C202 C203 C204 1.3(11) . . . . ?
C202 C201 C206 C205 2.2(11) . . . . ?
C202 C203 C204 C205 -1.4(12) . . . . ?
C203 C204 C205 C206 1.9(12) . . . . ?
C204 C205 C206 C201 -2.4(12) . . . . ?
C206 C201 C202 C203 -1.6(10) . . . . ?
C211 P2 C201 C202 -169.2(6) . . . . ?
C211 P2 C201 C206 12.9(6) . . . . ?
C211 P2 C221 C222 65.1(5) . . . . ?
C211 P2 C221 C226 -108.7(6) . . . . ?
C211 C212 C213 C214 -1.8(11) . . . . ?
C212 C211 C216 C215 2.5(10) . . . . ?
C212 C213 C214 C215 2.5(12) . . . . ?
C213 C214 C215 C216 -0.7(12) . . . . ?
C214 C215 C216 C211 -1.9(11) . . . . ?
C216 C211 C212 C213 -0.6(9) . . . . ?
C221 P2 C201 C202 85.8(6) . . . . ?
C221 P2 C201 C206 -92.2(6) . . . . ?
C221 P2 C211 C212 -171.6(5) . . . . ?
C221 P2 C211 C216 14.0(6) . . . . ?
C221 C222 C223 C224 -1.3(11) . . . . ?
C222 C221 C226 C225 0.8(10) . . . . ?
C222 C223 C224 C225 -1.1(11) . . . . ?
C223 C224 C225 C226 3.2(11) . . . . ?
C224 C225 C226 C221 -3.1(11) . . . . ?
C226 C221 C222 C223 1.4(10) . . . . ?
C301 P3 C311 C312 169.5(6) . . . . ?
C301 P3 C311 C316 -10.9(7) . . . . ?
C301 P3 C321 C322 -83.7(6) . . . . ?
C301 P3 C321 C326 102.3(6) . . . . ?
C301 C302 C303 C304 -1.3(13) . . . . ?
C302 C301 C306 C305 -0.2(12) . . . . ?
C302 C303 C304 C305 0.7(14) . . . . ?
C303 C304 C305 C306 0.1(15) . . . . ?
C304 C305 C306 C301 -0.4(14) . . . . ?
C306 C301 C302 C303 1.0(11) . . . . ?
C311 P3 C301 C302 -91.9(6) . . . . ?
C311 P3 C301 C306 86.3(7) . . . . ?
C311 P3 C321 C322 165.1(5) . . . . ?
C311 P3 C321 C326 -8.9(7) . . . . ?
C311 C312 C313 C314 0.0(13) . . . . ?
C312 C311 C316 C315 -1.7(10) . . . . ?
C312 C313 C314 C315 1.4(13) . . . . ?
C313 C314 C315 C316 -2.9(13) . . . . ?
C314 C315 C316 C311 3.0(11) . . . . ?
C316 C311 C312 C313 0.2(11) . . . . ?
C321 P3 C301 C302 157.6(6) . . . . ?
C321 P3 C301 C306 -24.2(7) . . . . ?
C321 P3 C311 C312 -78.3(6) . . . . ?
C321 P3 C311 C316 101.3(6) . . . . ?
C321 C322 C323 C324 3.4(11) . . . . ?
C322 C321 C326 C325 -0.2(11) . . . . ?
C322 C323 C324 C325 -2.7(11) . . . . ?
C323 C324 C325 C326 0.7(12) . . . . ?
C324 C325 C326 C321 0.8(12) . . . . ?
C326 C321 C322 C323 -1.8(11) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
