# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_mf1444
_database_code_depnum_ccdc_archive 'CCDC 2087925'
loop_
_audit_author_name
_audit_author_address
'Brian Patrick '
;The University of British Columbia 
Canada
;
_audit_update_record             
;
2021-06-03 deposited with the CCDC.	2021-11-02 downloaded from the CCDC.
;
_audit_creation_date             2021-04-14
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        Rh(COE)[P2N2]Cu
_chemical_formula_moiety         'C32 H56 Cu N2 P2 Rh Si4'
_chemical_formula_sum            'C32 H56 Cu N2 P2 Rh Si4'
_chemical_formula_weight         809.53
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu -1.9646 0.5888 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   15.9598(7)
_cell_length_b                   13.5924(6)
_cell_length_c                   18.3198(8)
_cell_angle_alpha                90
_cell_angle_beta                 102.314(3)
_cell_angle_gamma                90
_cell_volume                     3882.7(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9890
_cell_measurement_temperature    90
_cell_measurement_theta_max      59.15
_cell_measurement_theta_min      2.834
_shelx_estimated_absorpt_T_max   0.635
_shelx_estimated_absorpt_T_min   0.368
_exptl_absorpt_coefficient_mu    6.250
_exptl_absorpt_correction_T_max  0.607
_exptl_absorpt_correction_T_min  0.399
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1076 before and 0.0791 after correction.
The Ratio of minimum to maximum transmission is 0.6583.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.385
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             1688
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1088
_diffrn_reflns_av_unetI/netI     0.0591
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            43620
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        59.368
_diffrn_reflns_theta_max         59.368
_diffrn_reflns_theta_min         2.834
_diffrn_ambient_temperature      90.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4348
_reflns_number_total             5623
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_refine_diff_density_max         0.964
_refine_diff_density_min         -0.934
_refine_diff_density_rms         0.089
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         5623
_refine_ls_number_restraints     896
_refine_ls_R_factor_all          0.0651
_refine_ls_R_factor_gt           0.0450
_refine_ls_restrained_S_all      0.958
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0537P)²+6.7052P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1075
_refine_ls_wR_factor_ref         0.1171
_refine_special_details          ?
_olex2_refinement_description    
;
1. Restrained distances
 C27A-C26A
 1.54 with sigma of 0.02
 C25A-C26A
 1.54 with sigma of 0.02
 C30A-C31A
 1.54 with sigma of 0.02
 C29A-C30A
 1.54 with sigma of 0.02
2. Uiso/Uaniso restraints and constraints
All non-hydrogen atoms have similar U: within 2A with sigma of 0.04 and sigma
for terminal atoms of 0.08 within 2A
3. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4. Others
 Sof(C25A)=Sof(H25A)=Sof(C26A)=Sof(H26C)=Sof(H26D)=Sof(C27A)=Sof(H27C)=
 Sof(H27D)=Sof(C28A)=Sof(H28C)=Sof(H28D)=Sof(C29A)=Sof(H29C)=Sof(H29D)=
 Sof(C30A)=Sof(H30C)=Sof(H30D)=Sof(C31A)=Sof(H31C)=Sof(H31D)=Sof(C32A)=
 Sof(H32A)=1-FVAR(1)
 Sof(C25)=Sof(H25)=Sof(C26)=Sof(H26A)=Sof(H26B)=Sof(C27)=Sof(H27A)=Sof(H27B)=
 Sof(C28)=Sof(H28A)=Sof(H28B)=Sof(C29)=Sof(H29A)=Sof(H29B)=Sof(C30)=Sof(H30A)=
 Sof(H30B)=Sof(C31)=Sof(H31A)=Sof(H31B)=Sof(C32)=Sof(H32)=FVAR(1)
5.a Ternary CH refined with riding coordinates:
 C25(H25), C25A(H25A), C32(H32), C32A(H32A)
5.b Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C2(H2A,H2B), C3(H3A,H3B), C4(H4A,H4B), C26(H26A,H26B), C26A(H26C,
 H26D), C27(H27A,H27B), C27A(H27C,H27D), C28(H28A,H28B), C28A(H28C,H28D),
 C29(H29A,H29B), C29A(H29C,H29D), C30(H30A,H30B), C30A(H30C,H30D), C31(H31A,
 H31B), C31A(H31C,H31D)
5.c Aromatic/amide H refined with riding coordinates:
 C6(H6), C7(H7), C8(H8), C9(H9), C10(H10), C12(H12), C13(H13), C14(H14),
 C15(H15), C16(H16)
5.d Idealised Me refined as rotating group:
 C17(H17A,H17B,H17C), C18(H18A,H18B,H18C), C19(H19A,H19B,H19C), C20(H20A,H20B,
 H20C), C21(H21A,H21B,H21C), C22(H22A,H22B,H22C), C23(H23A,H23B,H23C), C24(H24A,
 H24B,H24C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.24739(2) 0.56917(3) 0.69346(2) 0.03011(14) Uani 1 1 d . . . . .
Cu1 Cu 0.35205(5) 0.71425(6) 0.71843(4) 0.0363(2) Uani 1 1 d . U . . .
P1 P 0.25310(9) 0.59643(11) 0.81787(8) 0.0373(4) Uani 1 1 d . U . . .
P2 P 0.30075(9) 0.56392(11) 0.58441(8) 0.0351(3) Uani 1 1 d . U . . .
Si1 Si 0.49364(10) 0.60925(13) 0.68228(10) 0.0434(4) Uani 1 1 d . U . . .
Si2 Si 0.45987(11) 0.63395(14) 0.84729(9) 0.0493(5) Uani 1 1 d . U . . .
Si3 Si 0.17417(10) 0.77613(11) 0.73729(9) 0.0371(4) Uani 1 1 d . U . . .
Si4 Si 0.22282(11) 0.76946(13) 0.58491(9) 0.0423(4) Uani 1 1 d . U . . .
N1 N 0.2348(3) 0.7337(3) 0.6769(2) 0.0323(10) Uani 1 1 d . U . . .
N2 N 0.4553(3) 0.6519(4) 0.7561(3) 0.0453(12) Uani 1 1 d . U . . .
C1 C 0.4152(3) 0.5351(5) 0.6082(3) 0.0437(15) Uani 1 1 d . U . . .
H1A H 0.436488 0.539033 0.561321 0.052 Uiso 1 1 calc R U . . .
H1B H 0.420374 0.465379 0.624257 0.052 Uiso 1 1 calc R U . . .
C2 C 0.3612(4) 0.5739(5) 0.8710(3) 0.0483(16) Uani 1 1 d . U . . .
H2A H 0.370420 0.501938 0.870170 0.058 Uiso 1 1 calc R U . . .
H2B H 0.361369 0.591548 0.923498 0.058 Uiso 1 1 calc R U . . .
C3 C 0.2263(4) 0.7250(5) 0.8317(3) 0.0448(15) Uani 1 1 d . U . . .
H3A H 0.278814 0.762670 0.853269 0.054 Uiso 1 1 calc R U . . .
H3B H 0.186455 0.729343 0.866211 0.054 Uiso 1 1 calc R U . . .
C4 C 0.2953(4) 0.6877(5) 0.5427(3) 0.0428(14) Uani 1 1 d . U . . .
H4A H 0.273084 0.682913 0.488035 0.051 Uiso 1 1 calc R U . . .
H4B H 0.353469 0.716601 0.551464 0.051 Uiso 1 1 calc R U . . .
C5 C 0.2570(4) 0.4867(5) 0.5031(3) 0.0382(13) Uani 1 1 d . U . . .
C6 C 0.2991(4) 0.4074(5) 0.4811(4) 0.0505(16) Uani 1 1 d . U . . .
H6 H 0.356296 0.393496 0.506338 0.061 Uiso 1 1 calc R U . . .
C7 C 0.2593(5) 0.3475(6) 0.4226(4) 0.0637(19) Uani 1 1 d . U . . .
H7 H 0.289536 0.293418 0.407884 0.076 Uiso 1 1 calc R U . . .
C8 C 0.1767(5) 0.3660(6) 0.3861(3) 0.0590(18) Uani 1 1 d . U . . .
H8 H 0.149129 0.323797 0.346932 0.071 Uiso 1 1 calc R U . . .
C9 C 0.1340(4) 0.4453(5) 0.4060(3) 0.0517(16) Uani 1 1 d . U . . .
H9 H 0.077015 0.458779 0.380016 0.062 Uiso 1 1 calc R U . . .
C10 C 0.1734(4) 0.5060(5) 0.4637(3) 0.0453(15) Uani 1 1 d . U . . .
H10 H 0.143380 0.561366 0.476756 0.054 Uiso 1 1 calc R U . . .
C11 C 0.1856(4) 0.5261(5) 0.8688(3) 0.0429(14) Uani 1 1 d . U . . .
C12 C 0.1014(4) 0.5537(6) 0.8651(4) 0.0578(18) Uani 1 1 d . U . . .
H12 H 0.078330 0.608660 0.835429 0.069 Uiso 1 1 calc R U . . .
C13 C 0.0502(5) 0.5016(6) 0.9045(4) 0.070(2) Uani 1 1 d . U . . .
H13 H -0.006953 0.522530 0.902758 0.084 Uiso 1 1 calc R U . . .
C14 C 0.0816(6) 0.4209(6) 0.9456(4) 0.072(2) Uani 1 1 d . U . . .
H14 H 0.046864 0.385797 0.972856 0.087 Uiso 1 1 calc R U . . .
C15 C 0.1628(6) 0.3917(6) 0.9470(4) 0.073(2) Uani 1 1 d . U . . .
H15 H 0.184335 0.334735 0.974889 0.088 Uiso 1 1 calc R U . . .
C16 C 0.2166(5) 0.4431(5) 0.9085(3) 0.0554(17) Uani 1 1 d . U . . .
H16 H 0.273306 0.420827 0.909843 0.067 Uiso 1 1 calc R U . . .
C17 C 0.5863(4) 0.5218(5) 0.7078(4) 0.0598(19) Uani 1 1 d . U . . .
H17A H 0.631928 0.552407 0.745231 0.090 Uiso 1 1 calc R U . . .
H17B H 0.608274 0.506053 0.663101 0.090 Uiso 1 1 calc R U . . .
H17C H 0.567200 0.461275 0.728305 0.090 Uiso 1 1 calc R U . . .
C18 C 0.5286(4) 0.7173(5) 0.6315(4) 0.0515(16) Uani 1 1 d . U . . .
H18A H 0.481552 0.764963 0.619488 0.077 Uiso 1 1 calc R U . . .
H18B H 0.543763 0.694490 0.585294 0.077 Uiso 1 1 calc R U . . .
H18C H 0.578524 0.748676 0.663442 0.077 Uiso 1 1 calc R U . . .
C19 C 0.5495(5) 0.5524(7) 0.8947(5) 0.092(3) Uani 1 1 d . U . . .
H19A H 0.545570 0.488902 0.868752 0.139 Uiso 1 1 calc R U . . .
H19B H 0.545379 0.541947 0.946704 0.139 Uiso 1 1 calc R U . . .
H19C H 0.604554 0.583491 0.893324 0.139 Uiso 1 1 calc R U . . .
C20 C 0.4750(5) 0.7524(6) 0.8992(4) 0.079(2) Uani 1 1 d . U . . .
H20A H 0.531513 0.779622 0.897796 0.119 Uiso 1 1 calc R U . . .
H20B H 0.471212 0.741083 0.951239 0.119 Uiso 1 1 calc R U . . .
H20C H 0.430330 0.798929 0.875981 0.119 Uiso 1 1 calc R U . . .
C21 C 0.0611(4) 0.7319(5) 0.7098(4) 0.0464(15) Uani 1 1 d . U . . .
H21A H 0.032807 0.763551 0.662967 0.070 Uiso 1 1 calc R U . . .
H21B H 0.030418 0.748658 0.749153 0.070 Uiso 1 1 calc R U . . .
H21C H 0.060686 0.660429 0.702989 0.070 Uiso 1 1 calc R U . . .
C22 C 0.1715(5) 0.9134(5) 0.7428(4) 0.0621(19) Uani 1 1 d . U . . .
H22A H 0.139071 0.933177 0.780174 0.093 Uiso 1 1 calc R U . . .
H22B H 0.143792 0.940212 0.693945 0.093 Uiso 1 1 calc R U . . .
H22C H 0.230199 0.938693 0.757127 0.093 Uiso 1 1 calc R U . . .
C23 C 0.1103(4) 0.7523(7) 0.5333(4) 0.080(3) Uani 1 1 d . U . . .
H23A H 0.088442 0.689508 0.547724 0.119 Uiso 1 1 calc R U . . .
H23B H 0.108271 0.752302 0.479467 0.119 Uiso 1 1 calc R U . . .
H23C H 0.074833 0.806205 0.545514 0.119 Uiso 1 1 calc R U . . .
C24 C 0.2543(7) 0.8989(6) 0.5744(5) 0.095(3) Uani 1 1 d . U . . .
H24A H 0.216615 0.942631 0.595258 0.143 Uiso 1 1 calc R U . . .
H24B H 0.249171 0.913801 0.521272 0.143 Uiso 1 1 calc R U . . .
H24C H 0.313821 0.908676 0.601024 0.143 Uiso 1 1 calc R U . . .
C25 C 0.1669(4) 0.4448(5) 0.6924(4) 0.0346(16) Uani 0.852(7) 1 d . U P A 1
H25 H 0.131323 0.447921 0.731107 0.042 Uiso 0.852(7) 1 calc R U P A 1
C25A C 0.178(2) 0.447(3) 0.636(2) 0.039(6) Uani 0.148(7) 1 d D U P A 2
H25A H 0.165202 0.451204 0.579971 0.047 Uiso 0.148(7) 1 calc R U P A 2
C26 C 0.1184(5) 0.4098(6) 0.6186(4) 0.054(2) Uani 0.852(7) 1 d . U P A 1
H26A H 0.158538 0.395374 0.585596 0.065 Uiso 0.852(7) 1 calc R U P A 1
H26B H 0.078144 0.461565 0.594659 0.065 Uiso 0.852(7) 1 calc R U P A 1
C26A C 0.102(2) 0.427(3) 0.671(2) 0.038(7) Uani 0.148(7) 1 d D U P A 2
H26C H 0.071462 0.489650 0.676625 0.045 Uiso 0.148(7) 1 calc R U P A 2
H26D H 0.120113 0.396285 0.720475 0.045 Uiso 0.148(7) 1 calc R U P A 2
C27 C 0.0669(6) 0.3138(8) 0.6298(5) 0.055(3) Uani 0.852(7) 1 d . U P A 1
H27A H 0.019051 0.332374 0.653663 0.066 Uiso 0.852(7) 1 calc R U P A 1
H27B H 0.041538 0.285929 0.580070 0.066 Uiso 0.852(7) 1 calc R U P A 1
C27A C 0.043(3) 0.357(3) 0.616(2) 0.035(7) Uani 0.148(7) 1 d D U P A 2
H27C H 0.032122 0.385265 0.564558 0.042 Uiso 0.148(7) 1 calc R U P A 2
H27D H -0.013140 0.350367 0.630289 0.042 Uiso 0.148(7) 1 calc R U P A 2
C28 C 0.1209(6) 0.2328(10) 0.6778(8) 0.052(3) Uani 0.852(7) 1 d . U P A 1
H28A H 0.138358 0.257515 0.729642 0.062 Uiso 0.852(7) 1 calc R U P A 1
H28B H 0.083591 0.174886 0.678857 0.062 Uiso 0.852(7) 1 calc R U P A 1
C28A C 0.085(3) 0.253(3) 0.615(2) 0.032(7) Uani 0.148(7) 1 d . U P A 2
H28C H 0.038693 0.203916 0.602800 0.038 Uiso 0.148(7) 1 calc R U P A 2
H28D H 0.117194 0.252197 0.574607 0.038 Uiso 0.148(7) 1 calc R U P A 2
C29 C 0.2007(6) 0.1988(6) 0.6527(5) 0.058(2) Uani 0.852(7) 1 d . U P A 1
H29A H 0.201644 0.126006 0.653452 0.069 Uiso 0.852(7) 1 calc R U P A 1
H29B H 0.195963 0.219724 0.600220 0.069 Uiso 0.852(7) 1 calc R U P A 1
C29A C 0.146(3) 0.221(6) 0.687(5) 0.039(8) Uani 0.148(7) 1 d D U P A 2
H29C H 0.136548 0.150044 0.693044 0.047 Uiso 0.148(7) 1 calc R U P A 2
H29D H 0.126794 0.254904 0.728794 0.047 Uiso 0.148(7) 1 calc R U P A 2
C30 C 0.2850(6) 0.2352(6) 0.6976(5) 0.053(2) Uani 0.852(7) 1 d . U P A 1
H30A H 0.331750 0.194724 0.685410 0.064 Uiso 0.852(7) 1 calc R U P A 1
H30B H 0.285817 0.225908 0.751396 0.064 Uiso 0.852(7) 1 calc R U P A 1
C30A C 0.243(3) 0.238(3) 0.698(3) 0.040(7) Uani 0.148(7) 1 d D U P A 2
H30C H 0.258479 0.226050 0.649245 0.048 Uiso 0.148(7) 1 calc R U P A 2
H30D H 0.271808 0.186702 0.732755 0.048 Uiso 0.148(7) 1 calc R U P A 2
C31 C 0.3027(5) 0.3443(5) 0.6837(4) 0.0462(19) Uani 0.852(7) 1 d . U P A 1
H31A H 0.364653 0.357484 0.701786 0.055 Uiso 0.852(7) 1 calc R U P A 1
H31B H 0.288423 0.356977 0.629231 0.055 Uiso 0.852(7) 1 calc R U P A 1
C31A C 0.282(3) 0.340(3) 0.728(3) 0.040(7) Uani 0.148(7) 1 d D U P A 2
H31C H 0.255626 0.361999 0.769312 0.048 Uiso 0.148(7) 1 calc R U P A 2
H31D H 0.344333 0.332883 0.747153 0.048 Uiso 0.148(7) 1 calc R U P A 2
C32 C 0.2525(4) 0.4140(5) 0.7215(4) 0.0305(15) Uani 0.852(7) 1 d . U P A 1
H32 H 0.263753 0.403035 0.776689 0.037 Uiso 0.852(7) 1 calc R U P A 1
C32A C 0.266(2) 0.409(3) 0.671(3) 0.035(6) Uani 0.148(7) 1 d . U P A 2
H32A H 0.303038 0.398857 0.633279 0.041 Uiso 0.148(7) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 Cu1 2.5617(9) . ?
Rh1 P1 2.2917(15) . ?
Rh1 P2 2.3338(15) . ?
Rh1 N1 2.260(4) . ?
Rh1 C25 2.121(6) . ?
Rh1 C25A 2.15(4) . ?
Rh1 C32 2.168(6) . ?
Rh1 C32A 2.25(4) . ?
Cu1 N1 1.883(4) . ?
Cu1 N2 1.851(5) . ?
P1 C2 1.816(6) . ?
P1 C3 1.829(6) . ?
P1 C11 1.837(6) . ?
P2 C1 1.828(6) . ?
P2 C4 1.842(6) . ?
P2 C5 1.835(6) . ?
Si1 N2 1.701(5) . ?
Si1 C1 1.924(6) . ?
Si1 C17 1.878(6) . ?
Si1 C18 1.885(7) . ?
Si2 N2 1.674(5) . ?
Si2 C2 1.905(6) . ?
Si2 C19 1.871(8) . ?
Si2 C20 1.859(8) . ?
Si3 N1 1.717(5) . ?
Si3 C3 1.884(6) . ?
Si3 C21 1.866(6) . ?
Si3 C22 1.869(6) . ?
Si4 N1 1.725(4) . ?
Si4 C4 1.885(6) . ?
Si4 C23 1.857(7) . ?
Si4 C24 1.851(8) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.375(8) . ?
C5 C10 1.400(8) . ?
C6 H6 0.9500 . ?
C6 C7 1.387(9) . ?
C7 H7 0.9500 . ?
C7 C8 1.369(10) . ?
C8 H8 0.9500 . ?
C8 C9 1.365(10) . ?
C9 H9 0.9500 . ?
C9 C10 1.382(8) . ?
C10 H10 0.9500 . ?
C11 C12 1.383(9) . ?
C11 C16 1.376(9) . ?
C12 H12 0.9500 . ?
C12 C13 1.394(9) . ?
C13 H13 0.9500 . ?
C13 C14 1.364(12) . ?
C14 H14 0.9500 . ?
C14 C15 1.351(12) . ?
C15 H15 0.9500 . ?
C15 C16 1.407(9) . ?
C16 H16 0.9500 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25 1.0000 . ?
C25 C26 1.486(10) . ?
C25 C32 1.419(9) . ?
C25A H25A 1.0000 . ?
C25A C26A 1.52(2) . ?
C25A C32A 1.50(5) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C26 C27 1.578(11) . ?
C26A H26C 0.9900 . ?
C26A H26D 0.9900 . ?
C26A C27A 1.56(2) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C27 C28 1.551(15) . ?
C27A H27C 0.9900 . ?
C27A H27D 0.9900 . ?
C27A C28A 1.56(6) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C28 C29 1.515(15) . ?
C28A H28C 0.9900 . ?
C28A H28D 0.9900 . ?
C28A C29A 1.52(8) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C29 C30 1.503(12) . ?
C29A H29C 0.9900 . ?
C29A H29D 0.9900 . ?
C29A C30A 1.54(2) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C30 C31 1.541(11) . ?
C30A H30C 0.9900 . ?
C30A H30D 0.9900 . ?
C30A C31A 1.57(2) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C31 C32 1.502(11) . ?
C31A H31C 0.9900 . ?
C31A H31D 0.9900 . ?
C31A C32A 1.39(6) . ?
C32 H32 1.0000 . ?
C32A H32A 1.0000 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Rh1 Cu1 79.15(4) . . ?
P1 Rh1 P2 155.77(5) . . ?
P2 Rh1 Cu1 80.41(4) . . ?
N1 Rh1 Cu1 45.44(11) . . ?
N1 Rh1 P1 87.55(12) . . ?
N1 Rh1 P2 87.34(12) . . ?
C25 Rh1 Cu1 170.36(18) . . ?
C25 Rh1 P1 91.93(19) . . ?
C25 Rh1 P2 107.4(2) . . ?
C25 Rh1 N1 138.7(2) . . ?
C25 Rh1 C32 38.6(2) . . ?
C25A Rh1 Cu1 158.7(9) . . ?
C25A Rh1 P1 121.5(10) . . ?
C25A Rh1 P2 78.3(9) . . ?
C25A Rh1 N1 132.8(11) . . ?
C25A Rh1 C32A 40.0(14) . . ?
C32 Rh1 Cu1 135.75(17) . . ?
C32 Rh1 P1 86.01(19) . . ?
C32 Rh1 P2 99.83(19) . . ?
C32 Rh1 N1 172.8(2) . . ?
C32A Rh1 Cu1 132.0(10) . . ?
C32A Rh1 P1 111.3(12) . . ?
C32A Rh1 P2 73.9(12) . . ?
C32A Rh1 N1 160.8(13) . . ?
N1 Cu1 Rh1 58.78(14) . . ?
N2 Cu1 Rh1 102.08(16) . . ?
N2 Cu1 N1 160.8(2) . . ?
C2 P1 Rh1 109.7(2) . . ?
C2 P1 C3 108.1(3) . . ?
C2 P1 C11 103.5(3) . . ?
C3 P1 Rh1 109.3(2) . . ?
C3 P1 C11 104.3(3) . . ?
C11 P1 Rh1 121.17(18) . . ?
C1 P2 Rh1 109.3(2) . . ?
C1 P2 C4 104.6(3) . . ?
C1 P2 C5 105.0(3) . . ?
C4 P2 Rh1 109.50(19) . . ?
C5 P2 Rh1 124.59(19) . . ?
C5 P2 C4 102.1(3) . . ?
N2 Si1 C1 116.7(3) . . ?
N2 Si1 C17 114.6(3) . . ?
N2 Si1 C18 108.7(3) . . ?
C17 Si1 C1 101.7(3) . . ?
C17 Si1 C18 108.4(3) . . ?
C18 Si1 C1 106.1(3) . . ?
N2 Si2 C2 115.4(3) . . ?
N2 Si2 C19 114.5(4) . . ?
N2 Si2 C20 110.9(3) . . ?
C19 Si2 C2 103.2(3) . . ?
C20 Si2 C2 106.1(3) . . ?
C20 Si2 C19 105.8(4) . . ?
N1 Si3 C3 105.6(3) . . ?
N1 Si3 C21 111.3(3) . . ?
N1 Si3 C22 113.1(3) . . ?
C21 Si3 C3 109.9(3) . . ?
C21 Si3 C22 107.7(3) . . ?
C22 Si3 C3 109.2(3) . . ?
N1 Si4 C4 106.6(2) . . ?
N1 Si4 C23 110.8(3) . . ?
N1 Si4 C24 113.2(3) . . ?
C23 Si4 C4 109.2(3) . . ?
C24 Si4 C4 108.3(4) . . ?
C24 Si4 C23 108.7(4) . . ?
Cu1 N1 Rh1 75.78(15) . . ?
Si3 N1 Rh1 107.0(2) . . ?
Si3 N1 Cu1 115.7(2) . . ?
Si3 N1 Si4 125.1(3) . . ?
Si4 N1 Rh1 113.5(2) . . ?
Si4 N1 Cu1 109.1(2) . . ?
Si1 N2 Cu1 107.6(2) . . ?
Si2 N2 Cu1 106.5(3) . . ?
Si2 N2 Si1 142.9(3) . . ?
P2 C1 Si1 121.5(3) . . ?
P2 C1 H1A 107.0 . . ?
P2 C1 H1B 107.0 . . ?
Si1 C1 H1A 107.0 . . ?
Si1 C1 H1B 107.0 . . ?
H1A C1 H1B 106.7 . . ?
P1 C2 Si2 122.8(3) . . ?
P1 C2 H2A 106.6 . . ?
P1 C2 H2B 106.6 . . ?
Si2 C2 H2A 106.6 . . ?
Si2 C2 H2B 106.6 . . ?
H2A C2 H2B 106.6 . . ?
P1 C3 Si3 107.2(3) . . ?
P1 C3 H3A 110.3 . . ?
P1 C3 H3B 110.3 . . ?
Si3 C3 H3A 110.3 . . ?
Si3 C3 H3B 110.3 . . ?
H3A C3 H3B 108.5 . . ?
P2 C4 Si4 110.3(3) . . ?
P2 C4 H4A 109.6 . . ?
P2 C4 H4B 109.6 . . ?
Si4 C4 H4A 109.6 . . ?
Si4 C4 H4B 109.6 . . ?
H4A C4 H4B 108.1 . . ?
C6 C5 P2 124.1(5) . . ?
C6 C5 C10 117.9(6) . . ?
C10 C5 P2 117.9(4) . . ?
C5 C6 H6 119.5 . . ?
C5 C6 C7 120.9(6) . . ?
C7 C6 H6 119.5 . . ?
C6 C7 H7 119.8 . . ?
C8 C7 C6 120.3(7) . . ?
C8 C7 H7 119.8 . . ?
C7 C8 H8 120.1 . . ?
C9 C8 C7 119.9(6) . . ?
C9 C8 H8 120.1 . . ?
C8 C9 H9 119.9 . . ?
C8 C9 C10 120.3(6) . . ?
C10 C9 H9 119.9 . . ?
C5 C10 H10 119.6 . . ?
C9 C10 C5 120.7(6) . . ?
C9 C10 H10 119.6 . . ?
C12 C11 P1 120.2(5) . . ?
C16 C11 P1 120.8(5) . . ?
C16 C11 C12 119.0(6) . . ?
C11 C12 H12 119.8 . . ?
C11 C12 C13 120.5(7) . . ?
C13 C12 H12 119.8 . . ?
C12 C13 H13 119.7 . . ?
C14 C13 C12 120.5(8) . . ?
C14 C13 H13 119.7 . . ?
C13 C14 H14 120.5 . . ?
C15 C14 C13 119.0(7) . . ?
C15 C14 H14 120.5 . . ?
C14 C15 H15 119.0 . . ?
C14 C15 C16 122.0(8) . . ?
C16 C15 H15 119.0 . . ?
C11 C16 C15 118.9(8) . . ?
C11 C16 H16 120.5 . . ?
C15 C16 H16 120.5 . . ?
Si1 C17 H17A 109.5 . . ?
Si1 C17 H17B 109.5 . . ?
Si1 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si1 C18 H18A 109.5 . . ?
Si1 C18 H18B 109.5 . . ?
Si1 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si2 C19 H19A 109.5 . . ?
Si2 C19 H19B 109.5 . . ?
Si2 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si2 C20 H20A 109.5 . . ?
Si2 C20 H20B 109.5 . . ?
Si2 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si3 C21 H21A 109.5 . . ?
Si3 C21 H21B 109.5 . . ?
Si3 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si3 C22 H22A 109.5 . . ?
Si3 C22 H22B 109.5 . . ?
Si3 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si4 C23 H23A 109.5 . . ?
Si4 C23 H23B 109.5 . . ?
Si4 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si4 C24 H24A 109.5 . . ?
Si4 C24 H24B 109.5 . . ?
Si4 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Rh1 C25 H25 113.2 . . ?
C26 C25 Rh1 117.4(5) . . ?
C26 C25 H25 113.2 . . ?
C32 C25 Rh1 72.5(4) . . ?
C32 C25 H25 113.2 . . ?
C32 C25 C26 121.4(7) . . ?
Rh1 C25A H25A 115.4 . . ?
C26A C25A Rh1 107(3) . . ?
C26A C25A H25A 115.4 . . ?
C32A C25A Rh1 74(2) . . ?
C32A C25A H25A 115.4 . . ?
C32A C25A C26A 122(4) . . ?
C25 C26 H26A 109.8 . . ?
C25 C26 H26B 109.8 . . ?
C25 C26 C27 109.3(6) . . ?
H26A C26 H26B 108.3 . . ?
C27 C26 H26A 109.8 . . ?
C27 C26 H26B 109.8 . . ?
C25A C26A H26C 110.7 . . ?
C25A C26A H26D 110.7 . . ?
C25A C26A C27A 105(3) . . ?
H26C C26A H26D 108.8 . . ?
C27A C26A H26C 110.7 . . ?
C27A C26A H26D 110.7 . . ?
C26 C27 H27A 108.6 . . ?
C26 C27 H27B 108.6 . . ?
H27A C27 H27B 107.6 . . ?
C28 C27 C26 114.7(7) . . ?
C28 C27 H27A 108.6 . . ?
C28 C27 H27B 108.6 . . ?
C26A C27A H27C 109.5 . . ?
C26A C27A H27D 109.5 . . ?
C26A C27A C28A 111(3) . . ?
H27C C27A H27D 108.1 . . ?
C28A C27A H27C 109.5 . . ?
C28A C27A H27D 109.5 . . ?
C27 C28 H28A 108.2 . . ?
C27 C28 H28B 108.2 . . ?
H28A C28 H28B 107.3 . . ?
C29 C28 C27 116.5(10) . . ?
C29 C28 H28A 108.2 . . ?
C29 C28 H28B 108.2 . . ?
C27A C28A H28C 108.1 . . ?
C27A C28A H28D 108.1 . . ?
H28C C28A H28D 107.3 . . ?
C29A C28A C27A 117(5) . . ?
C29A C28A H28C 108.1 . . ?
C29A C28A H28D 108.1 . . ?
C28 C29 H29A 108.2 . . ?
C28 C29 H29B 108.2 . . ?
H29A C29 H29B 107.3 . . ?
C30 C29 C28 116.5(9) . . ?
C30 C29 H29A 108.2 . . ?
C30 C29 H29B 108.2 . . ?
C28A C29A H29C 107.2 . . ?
C28A C29A H29D 107.2 . . ?
C28A C29A C30A 121(6) . . ?
H29C C29A H29D 106.8 . . ?
C30A C29A H29C 107.2 . . ?
C30A C29A H29D 107.2 . . ?
C29 C30 H30A 108.9 . . ?
C29 C30 H30B 108.9 . . ?
C29 C30 C31 113.5(7) . . ?
H30A C30 H30B 107.7 . . ?
C31 C30 H30A 108.9 . . ?
C31 C30 H30B 108.9 . . ?
C29A C30A H30C 107.5 . . ?
C29A C30A H30D 107.5 . . ?
C29A C30A C31A 119(5) . . ?
H30C C30A H30D 107.0 . . ?
C31A C30A H30C 107.5 . . ?
C31A C30A H30D 107.5 . . ?
C30 C31 H31A 108.9 . . ?
C30 C31 H31B 108.9 . . ?
H31A C31 H31B 107.7 . . ?
C32 C31 C30 113.4(7) . . ?
C32 C31 H31A 108.9 . . ?
C32 C31 H31B 108.9 . . ?
C30A C31A H31C 109.6 . . ?
C30A C31A H31D 109.6 . . ?
H31C C31A H31D 108.2 . . ?
C32A C31A C30A 110(4) . . ?
C32A C31A H31C 109.6 . . ?
C32A C31A H31D 109.6 . . ?
Rh1 C32 H32 112.0 . . ?
C25 C32 Rh1 68.9(4) . . ?
C25 C32 C31 125.3(6) . . ?
C25 C32 H32 112.0 . . ?
C31 C32 Rh1 120.1(5) . . ?
C31 C32 H32 112.0 . . ?
Rh1 C32A H32A 112.7 . . ?
C25A C32A Rh1 66(2) . . ?
C25A C32A H32A 112.7 . . ?
C31A C32A Rh1 122(4) . . ?
C31A C32A C25A 123(4) . . ?
C31A C32A H32A 112.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 Cu1 N1 Si3 102.3(3) . . . . ?
Rh1 Cu1 N1 Si4 -110.3(2) . . . . ?
Rh1 Cu1 N2 Si1 81.6(2) . . . . ?
Rh1 Cu1 N2 Si2 -83.5(3) . . . . ?
Rh1 P1 C2 Si2 52.5(5) . . . . ?
Rh1 P1 C3 Si3 15.9(3) . . . . ?
Rh1 P1 C11 C12 -82.5(5) . . . . ?
Rh1 P1 C11 C16 94.8(5) . . . . ?
Rh1 P2 C1 Si1 -52.3(4) . . . . ?
Rh1 P2 C4 Si4 -15.2(3) . . . . ?
Rh1 P2 C5 C6 -111.2(5) . . . . ?
Rh1 P2 C5 C10 64.6(5) . . . . ?
Rh1 C25 C26 C27 176.9(6) . . . . ?
Rh1 C25 C32 C31 -112.7(7) . . . . ?
Rh1 C25A C26A C27A 166(3) . . . . ?
Rh1 C25A C32A C31A 114(5) . . . . ?
P1 C11 C12 C13 -179.0(5) . . . . ?
P1 C11 C16 C15 179.6(5) . . . . ?
P2 C5 C6 C7 174.7(5) . . . . ?
P2 C5 C10 C9 -174.3(5) . . . . ?
N1 Cu1 N2 Si1 78.2(7) . . . . ?
N1 Cu1 N2 Si2 -86.8(7) . . . . ?
N1 Si3 C3 P1 -43.3(3) . . . . ?
N1 Si4 C4 P2 33.7(4) . . . . ?
N2 Cu1 N1 Rh1 3.8(7) . . . . ?
N2 Cu1 N1 Si3 106.1(6) . . . . ?
N2 Cu1 N1 Si4 -106.5(6) . . . . ?
C1 P2 C4 Si4 -132.3(3) . . . . ?
C1 P2 C5 C6 15.8(6) . . . . ?
C1 P2 C5 C10 -168.4(5) . . . . ?
C1 Si1 N2 Cu1 -49.5(4) . . . . ?
C1 Si1 N2 Si2 106.3(5) . . . . ?
C2 P1 C3 Si3 135.3(3) . . . . ?
C2 P1 C11 C12 154.1(5) . . . . ?
C2 P1 C11 C16 -28.6(6) . . . . ?
C2 Si2 N2 Cu1 50.2(4) . . . . ?
C2 Si2 N2 Si1 -105.8(5) . . . . ?
C3 P1 C2 Si2 -66.6(5) . . . . ?
C3 P1 C11 C12 41.1(5) . . . . ?
C3 P1 C11 C16 -141.5(5) . . . . ?
C3 Si3 N1 Rh1 51.3(3) . . . . ?
C3 Si3 N1 Cu1 -30.8(3) . . . . ?
C3 Si3 N1 Si4 -172.3(3) . . . . ?
C4 P2 C1 Si1 64.8(4) . . . . ?
C4 P2 C5 C6 124.6(6) . . . . ?
C4 P2 C5 C10 -59.5(5) . . . . ?
C4 Si4 N1 Rh1 -38.6(3) . . . . ?
C4 Si4 N1 Cu1 43.8(3) . . . . ?
C4 Si4 N1 Si3 -172.6(3) . . . . ?
C5 P2 C1 Si1 171.9(4) . . . . ?
C5 P2 C4 Si4 118.5(3) . . . . ?
C5 C6 C7 C8 -0.6(11) . . . . ?
C6 C5 C10 C9 1.8(9) . . . . ?
C6 C7 C8 C9 1.7(11) . . . . ?
C7 C8 C9 C10 -1.1(10) . . . . ?
C8 C9 C10 C5 -0.7(9) . . . . ?
C10 C5 C6 C7 -1.1(10) . . . . ?
C11 P1 C2 Si2 -176.9(4) . . . . ?
C11 P1 C3 Si3 -115.1(3) . . . . ?
C11 C12 C13 C14 -1.9(10) . . . . ?
C12 C11 C16 C15 -3.0(9) . . . . ?
C12 C13 C14 C15 -0.6(10) . . . . ?
C13 C14 C15 C16 1.2(11) . . . . ?
C14 C15 C16 C11 0.6(10) . . . . ?
C16 C11 C12 C13 3.7(9) . . . . ?
C17 Si1 N2 Cu1 -168.2(3) . . . . ?
C17 Si1 N2 Si2 -12.4(6) . . . . ?
C18 Si1 N2 Cu1 70.3(3) . . . . ?
C18 Si1 N2 Si2 -133.8(5) . . . . ?
C19 Si2 N2 Cu1 169.8(3) . . . . ?
C19 Si2 N2 Si1 13.8(7) . . . . ?
C20 Si2 N2 Cu1 -70.5(4) . . . . ?
C20 Si2 N2 Si1 133.5(6) . . . . ?
C21 Si3 N1 Rh1 -67.9(3) . . . . ?
C21 Si3 N1 Cu1 -150.0(3) . . . . ?
C21 Si3 N1 Si4 68.4(4) . . . . ?
C21 Si3 C3 P1 76.8(4) . . . . ?
C22 Si3 N1 Rh1 170.7(3) . . . . ?
C22 Si3 N1 Cu1 88.6(4) . . . . ?
C22 Si3 N1 Si4 -52.9(4) . . . . ?
C22 Si3 C3 P1 -165.2(3) . . . . ?
C23 Si4 N1 Rh1 80.0(4) . . . . ?
C23 Si4 N1 Cu1 162.4(3) . . . . ?
C23 Si4 N1 Si3 -53.9(4) . . . . ?
C23 Si4 C4 P2 -86.0(4) . . . . ?
C24 Si4 N1 Rh1 -157.5(4) . . . . ?
C24 Si4 N1 Cu1 -75.2(4) . . . . ?
C24 Si4 N1 Si3 68.5(5) . . . . ?
C24 Si4 C4 P2 155.8(4) . . . . ?
C25 C26 C27 C28 -50.4(13) . . . . ?
C25A C26A C27A C28A 69(4) . . . . ?
C26 C25 C32 Rh1 111.9(6) . . . . ?
C26 C25 C32 C31 -0.8(11) . . . . ?
C26 C27 C28 C29 -54.8(15) . . . . ?
C26A C25A C32A Rh1 -101(4) . . . . ?
C26A C25A C32A C31A 13(7) . . . . ?
C26A C27A C28A C29A 29(5) . . . . ?
C27 C28 C29 C30 104.7(11) . . . . ?
C27A C28A C29A C30A -95(7) . . . . ?
C28 C29 C30 C31 -74.0(10) . . . . ?
C28A C29A C30A C31A 85(9) . . . . ?
C29 C30 C31 C32 76.2(9) . . . . ?
C29A C30A C31A C32A -78(7) . . . . ?
C30 C31 C32 Rh1 -168.2(5) . . . . ?
C30 C31 C32 C25 -83.9(9) . . . . ?
C30A C31A C32A Rh1 148(3) . . . . ?
C30A C31A C32A C25A 67(6) . . . . ?
C32 C25 C26 C27 91.5(9) . . . . ?
C32A C25A C26A C27A -112(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mf1451
_database_code_depnum_ccdc_archive 'CCDC 2087926'
loop_
_audit_author_name
_audit_author_address
'Brian Patrick'
;The University of British Columbia 
Canada
;
_audit_update_record             
;
2021-06-03 deposited with the CCDC.	2021-11-02 downloaded from the CCDC.
;
_audit_creation_date             2021-04-14
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ([P2N2H]Rh(H)(μ-H)2Cu)2
_chemical_formula_moiety         'C48 H92 Cu2 N4 P4 Rh2 Si8, 2(C7 H8)'
_chemical_formula_sum            'C62 H108 Cu2 N4 P4 Rh2 Si8'
_chemical_formula_weight         1591.02
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   33.949(3)
_cell_length_b                   13.5303(10)
_cell_length_c                   21.6795(17)
_cell_angle_alpha                90
_cell_angle_beta                 128.4150(10)
_cell_angle_gamma                90
_cell_volume                     7802.5(10)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9814
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      30.523
_cell_measurement_theta_min      2.514
_shelx_estimated_absorpt_T_max   0.910
_shelx_estimated_absorpt_T_min   0.832
_exptl_absorpt_coefficient_mu    1.195
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6787
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0512 before and 0.0467 after correction.
The Ratio of minimum to maximum transmission is 0.9097.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.354
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       irregular
_exptl_crystal_F_000             3312
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0413
_diffrn_reflns_av_unetI/netI     0.0382
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       48
_diffrn_reflns_limit_h_min       -41
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            57083
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.568
_diffrn_reflns_theta_min         1.531
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           30.0
_diffrn_source_power             1.35
_diffrn_source_voltage           45.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9335
_reflns_number_total             11955
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.781
_refine_diff_density_min         -0.473
_refine_diff_density_rms         0.092
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     445
_refine_ls_number_reflns         11955
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0485
_refine_ls_R_factor_gt           0.0306
_refine_ls_restrained_S_all      1.014
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0305P)²+7.1092P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0653
_refine_ls_wR_factor_ref         0.0723
_refine_special_details          ?
_olex2_refinement_description    
;
1. Others
 Fixed Uiso: H11A(0.03) H11B(0.03) H9A(0.029) H9B(0.029) H10A(0.031)
 H10B(0.031) H12A(0.032) H12B(0.032) H18(0.039) H17(0.051) H16(0.058)
 H15(0.056) H14(0.04) H24(0.037) H23(0.054) H22(0.066) H21(0.068) H20(0.05)
 H4A(0.061) H4B(0.061) H4C(0.061) H3A(0.055) H3B(0.055) H3C(0.055) H2A(0.054)
 H2B(0.054) H2C(0.054) H1A(0.057) H1B(0.057) H1C(0.057) H8A(0.055) H8B(0.055)
 H8C(0.055) H7A(0.062) H7B(0.062) H7C(0.062) H6A(0.072) H6B(0.072) H6C(0.072)
 H5A(0.06) H5B(0.06) H5C(0.06) H30A(0.091) H30B(0.091) H30C(0.091) H25(0.061)
 H26(0.084) H27(0.084) H28(0.079) H29(0.052) H32A(0.108) H32B(0.108)
 H32C(0.108) H34(0.043) H35(0.055) H36(0.053) H37(0.062) H38(0.049)
 Fixed X: H11A(0.6982) H11B(0.698962) H9A(0.684631) H9B(0.666988)
 H10A(0.56544) H10B(0.620387) H12A(0.692374) H12B(0.671345) H18(0.675867)
 H17(0.651202) H16(0.567938) H15(0.509432) H14(0.533936) H24(0.516535)
 H23(0.466435) H22(0.477933) H21(0.537641) H20(0.587222) H4A(0.707387)
 H4B(0.718848) H4C(0.742469) H3A(0.57399) H3B(0.6109) H3C(0.59841)
 H2A(0.750027) H2B(0.754293) H2C(0.743156) H1A(0.655225) H1B(0.658262)
 H1C(0.608806) H8A(0.70811) H8B(0.707195) H8C(0.702765) H7A(0.575106)
 H7B(0.626265) H7C(0.624169) H6A(0.688868) H6B(0.66734) H6C(0.639921)
 H5A(0.586853) H5B(0.552584) H5C(0.548178) H30A(0.733792) H30B(0.692705)
 H30C(0.74183) H25(0.74286) H26(0.705056) H27(0.630964) H28(0.594956)
 H29(0.632874) H32A(0.632572) H32B(0.689223) H32C(0.652558) H34(0.618678)
 H35(0.637558) H36(0.703723) H37(0.754073) H38(0.732126)
 Fixed Y: H11A(0.587743) H11B(0.69022) H9A(0.860734) H9B(0.970668)
 H10A(0.908386) H10B(0.949755) H12A(0.591124) H12B(0.484899) H18(0.423705)
 H17(0.284462) H16(0.262473) H15(0.381743) H14(0.522987) H24(0.879409)
 H23(1.004653) H22(1.165472) H21(1.200732) H20(1.07603) H4A(0.742583)
 H4B(0.634635) H4C(0.724903) H3A(0.65179) H3B(0.573577) H3C(0.670469)
 H2A(0.849764) H2B(0.964814) H2C(0.917831) H1A(1.052193) H1B(1.092629)
 H1C(1.042157) H8A(0.732834) H8B(0.84586) H8C(0.767282) H7A(0.805688)
 H7B(0.862076) H7C(0.747301) H6A(0.572872) H6B(0.46504) H6C(0.549681)
 H5A(0.399245) H5B(0.469004) H5C(0.469423) H30A(0.878995) H30B(0.799178)
 H30C(0.769233) H25(0.94208) H26(0.973811) H27(0.894089) H28(0.782839)
 H29(0.751281) H32A(0.969231) H32B(0.96353) H32C(0.876652) H34(0.77817)
 H35(0.70526) H36(0.763217) H37(0.888264) H38(0.959209)
 Fixed Z: H11A(0.770351) H11B(0.804164) H9A(0.848538) H9B(0.834861)
 H10A(0.841856) H10B(0.88897) H12A(0.902457) H12B(0.867811) H18(0.767049)
 H17(0.691055) H16(0.583001) H15(0.551972) H14(0.628213) H24(0.607993)
 H23(0.520217) H22(0.564498) H21(0.696467) H20(0.784569) H4A(0.628574)
 H4B(0.661915) H4C(0.719756) H3A(0.573205) H3B(0.580917) H3C(0.532195)
 H2A(0.809696) H2B(0.820612) H2C(0.745104) H1A(0.650213) H1B(0.72083)
 H1C(0.649159) H8A(1.02827) H8B(1.011512) H8C(0.954341) H7A(0.970758)
 H7B(1.027636) H7C(1.035148) H6A(1.030526) H6B(1.011017) H6C(1.020487)
 H5A(0.859838) H5B(0.786928) H5C(0.854748) H30A(0.400627) H30B(0.346293)
 H30C(0.4294) H25(0.515987) H26(0.572942) H27(0.527403) H28(0.424015)
 H29(0.367183) H32A(0.493923) H32B(0.568664) H32C(0.549274) H34(0.427945)
 H35(0.349176) H36(0.357044) H37(0.446319) H38(0.51716)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.56716(2) 0.70884(2) 0.74086(2) 0.01562(4) Uani 1 1 d . . . . .
H1 H 0.5478(9) 0.7223(17) 0.6595(14) 0.030(6) Uiso 1 1 d . . . . .
H2 H 0.5178(10) 0.772(2) 0.7109(16) 0.053(8) Uiso 1 1 d . . . . .
H3 H 0.5292(9) 0.6134(19) 0.7056(14) 0.040(7) Uiso 1 1 d . . . . .
Cu1 Cu 0.52547(2) 0.68043(2) 0.82438(2) 0.02194(6) Uani 1 1 d . . . . .
P1 P 0.59792(2) 0.86651(4) 0.77671(3) 0.01936(10) Uani 1 1 d . . . . .
P2 P 0.62834(2) 0.60193(4) 0.76607(3) 0.01974(10) Uani 1 1 d . . . . .
Si1 Si 0.65754(2) 0.70617(4) 0.66766(4) 0.02368(12) Uani 1 1 d . . . . .
Si2 Si 0.66854(2) 0.91958(4) 0.73178(3) 0.02242(11) Uani 1 1 d . . . . .
Si3 Si 0.62386(2) 0.78296(5) 0.92790(3) 0.02386(12) Uani 1 1 d . . . . .
Si4 Si 0.61968(2) 0.56166(5) 0.89443(4) 0.02722(13) Uani 1 1 d . . . . .
N1 N 0.59524(6) 0.67921(13) 0.87034(9) 0.0218(3) Uani 1 1 d . . . . .
N2 N 0.63878(7) 0.82626(13) 0.66324(10) 0.0216(3) Uani 1 1 d . . . . .
H4 H 0.6098(10) 0.830(2) 0.6373(16) 0.040(8) Uiso 1 1 d . . . . .
C1 C 0.67763(7) 0.64437(16) 0.76109(13) 0.0251(4) Uani 1 1 d . . . . .
H11A H 0.698200 0.587743 0.770351 0.030 Uiso 1 1 calc R U . . .
H11B H 0.698962 0.690220 0.804164 0.030 Uiso 1 1 calc R U . . .
C2 C 0.65971(8) 0.90710(16) 0.80913(12) 0.0244(4) Uani 1 1 d . . . . .
H9A H 0.684631 0.860734 0.848538 0.029 Uiso 1 1 calc R U . . .
H9B H 0.666988 0.970668 0.834861 0.029 Uiso 1 1 calc R U . . .
C3 C 0.59912(8) 0.89288(16) 0.86047(12) 0.0255(4) Uani 1 1 d . . . . .
H10A H 0.565440 0.908386 0.841856 0.031 Uiso 1 1 calc R U . . .
H10B H 0.620387 0.949755 0.888970 0.031 Uiso 1 1 calc R U . . .
C4 C 0.66195(8) 0.55320(16) 0.86590(12) 0.0263(4) Uani 1 1 d . . . . .
H12A H 0.692374 0.591124 0.902457 0.032 Uiso 1 1 calc R U . . .
H12B H 0.671345 0.484899 0.867811 0.032 Uiso 1 1 calc R U . . .
C5 C 0.60757(8) 0.48918(15) 0.70631(13) 0.0247(4) Uani 1 1 d . . . . .
C6 C 0.64222(9) 0.41577(16) 0.72377(15) 0.0322(5) Uani 1 1 d . . . . .
H18 H 0.675867 0.423705 0.767049 0.039 Uiso 1 1 calc R U . . .
C7 C 0.62752(11) 0.33229(18) 0.67829(18) 0.0423(6) Uani 1 1 d . . . . .
H17 H 0.651202 0.284462 0.691055 0.051 Uiso 1 1 calc R U . . .
C8 C 0.57786(11) 0.31901(19) 0.61380(19) 0.0481(7) Uani 1 1 d . . . . .
H16 H 0.567938 0.262473 0.583001 0.058 Uiso 1 1 calc R U . . .
C9 C 0.54300(10) 0.3904(2) 0.59536(18) 0.0466(7) Uani 1 1 d . . . . .
H15 H 0.509432 0.381743 0.551972 0.056 Uiso 1 1 calc R U . . .
C10 C 0.55773(8) 0.47528(18) 0.64129(14) 0.0333(5) Uani 1 1 d . . . . .
H14 H 0.533936 0.522987 0.628213 0.040 Uiso 1 1 calc R U . . .
C11 C 0.55736(8) 0.96383(15) 0.70578(13) 0.0264(4) Uani 1 1 d . . . . .
C12 C 0.52093(8) 0.94385(17) 0.62618(13) 0.0312(5) Uani 1 1 d . . . . .
H24 H 0.516535 0.879409 0.607993 0.037 Uiso 1 1 calc R U . . .
C13 C 0.49094(10) 1.0190(2) 0.57332(16) 0.0450(6) Uani 1 1 d . . . . .
H23 H 0.466435 1.004653 0.520217 0.054 Uiso 1 1 calc R U . . .
C14 C 0.49764(12) 1.1150(2) 0.5999(2) 0.0552(8) Uani 1 1 d . . . . .
H22 H 0.477933 1.165472 0.564498 0.066 Uiso 1 1 calc R U . . .
C15 C 0.53342(13) 1.1361(2) 0.6787(2) 0.0568(8) Uani 1 1 d . . . . .
H21 H 0.537641 1.200732 0.696467 0.068 Uiso 1 1 calc R U . . .
C16 C 0.56314(11) 1.06125(18) 0.73144(16) 0.0420(6) Uani 1 1 d . . . . .
H20 H 0.587222 1.076030 0.784569 0.050 Uiso 1 1 calc R U . . .
C17 C 0.71334(10) 0.70151(18) 0.66973(18) 0.0410(6) Uani 1 1 d . . . . .
H4A H 0.707387 0.742583 0.628574 0.061 Uiso 1 1 calc R U . . .
H4B H 0.718848 0.634635 0.661915 0.061 Uiso 1 1 calc R U . . .
H4C H 0.742469 0.724903 0.719756 0.061 Uiso 1 1 calc R U . . .
C18 C 0.60371(9) 0.64285(18) 0.57762(14) 0.0364(5) Uani 1 1 d . . . . .
H3A H 0.573990 0.651790 0.573205 0.055 Uiso 1 1 calc R U . . .
H3B H 0.610900 0.573577 0.580917 0.055 Uiso 1 1 calc R U . . .
H3C H 0.598410 0.670469 0.532195 0.055 Uiso 1 1 calc R U . . .
C19 C 0.73735(8) 0.91209(19) 0.78301(14) 0.0363(5) Uani 1 1 d . . . . .
H2A H 0.750027 0.849764 0.809696 0.054 Uiso 1 1 calc R U . . .
H2B H 0.754293 0.964814 0.820612 0.054 Uiso 1 1 calc R U . . .
H2C H 0.743156 0.917831 0.745104 0.054 Uiso 1 1 calc R U . . .
C20 C 0.64485(10) 1.04134(17) 0.68198(15) 0.0377(6) Uani 1 1 d . . . . .
H1A H 0.655225 1.052193 0.650213 0.057 Uiso 1 1 calc R U . . .
H1B H 0.658262 1.092629 0.720830 0.057 Uiso 1 1 calc R U . . .
H1C H 0.608806 1.042157 0.649159 0.057 Uiso 1 1 calc R U . . .
C21 C 0.69405(8) 0.7821(2) 0.98782(13) 0.0365(5) Uani 1 1 d . . . . .
H8A H 0.708110 0.732834 1.028270 0.055 Uiso 1 1 calc R U . . .
H8B H 0.707195 0.845860 1.011512 0.055 Uiso 1 1 calc R U . . .
H8C H 0.702765 0.767282 0.954341 0.055 Uiso 1 1 calc R U . . .
C22 C 0.61076(10) 0.8018(2) 0.99900(14) 0.0415(6) Uani 1 1 d . . . . .
H7A H 0.575106 0.805688 0.970758 0.062 Uiso 1 1 calc R U . . .
H7B H 0.626265 0.862076 1.027636 0.062 Uiso 1 1 calc R U . . .
H7C H 0.624169 0.747301 1.035148 0.062 Uiso 1 1 calc R U . . .
C23 C 0.65871(10) 0.5339(2) 1.00226(15) 0.0481(7) Uani 1 1 d . . . . .
H6A H 0.688868 0.572872 1.030526 0.072 Uiso 1 1 calc R U . . .
H6B H 0.667340 0.465040 1.011017 0.072 Uiso 1 1 calc R U . . .
H6C H 0.639921 0.549681 1.020487 0.072 Uiso 1 1 calc R U . . .
C24 C 0.57091(9) 0.46284(18) 0.84271(17) 0.0403(6) Uani 1 1 d . . . . .
H5A H 0.586853 0.399245 0.859838 0.060 Uiso 1 1 calc R U . . .
H5B H 0.552584 0.469004 0.786928 0.060 Uiso 1 1 calc R U . . .
H5C H 0.548178 0.469423 0.854748 0.060 Uiso 1 1 calc R U . . .
C30 C 0.71739(18) 0.8206(4) 0.3997(3) 0.060(2) Uani 0.586(5) 1 d G . P A 1
H30A H 0.733792 0.878995 0.400627 0.091 Uiso 0.586(5) 1 calc R U P A 1
H30B H 0.692705 0.799178 0.346293 0.091 Uiso 0.586(5) 1 calc R U P A 1
H30C H 0.741830 0.769233 0.429400 0.091 Uiso 0.586(5) 1 calc R U P A 1
C25 C 0.71315(14) 0.9098(3) 0.4973(2) 0.051(3) Uani 0.586(5) 1 d G . P A 1
H25 H 0.742860 0.942080 0.515987 0.061 Uiso 0.586(5) 1 calc R U P A 1
C26 C 0.6905(2) 0.9290(3) 0.5316(2) 0.070(2) Uani 0.586(5) 1 d G . P A 1
H26 H 0.705056 0.973811 0.572942 0.084 Uiso 0.586(5) 1 calc R U P A 1
C27 C 0.64618(19) 0.8814(3) 0.5044(3) 0.070(2) Uani 0.586(5) 1 d G . P A 1
H27 H 0.630964 0.894089 0.527403 0.084 Uiso 0.586(5) 1 calc R U P A 1
C28 C 0.62472(15) 0.8149(3) 0.4426(3) 0.0658(19) Uani 0.586(5) 1 d G . P A 1
H28 H 0.594956 0.782839 0.424015 0.079 Uiso 0.586(5) 1 calc R U P A 1
C29 C 0.64757(13) 0.7960(3) 0.4086(2) 0.0436(18) Uani 0.586(5) 1 d G . P A 1
H29 H 0.632874 0.751281 0.367183 0.052 Uiso 0.586(5) 1 calc R U P A 1
C31 C 0.69216(11) 0.8430(2) 0.43541(18) 0.0361(11) Uani 0.586(5) 1 d G . P A 1
C32 C 0.6608(5) 0.9259(7) 0.5271(8) 0.072(4) Uani 0.414(5) 1 d . . P A 2
H32A H 0.632572 0.969231 0.493923 0.108 Uiso 0.414(5) 1 calc R U P A 2
H32B H 0.689223 0.963530 0.568664 0.108 Uiso 0.414(5) 1 calc R U P A 2
H32C H 0.652558 0.876652 0.549274 0.108 Uiso 0.414(5) 1 calc R U P A 2
C33 C 0.6732(3) 0.8771(5) 0.4797(4) 0.0399(17) Uani 0.414(5) 1 d . . P A 2
C34 C 0.6456(3) 0.8018(7) 0.4310(5) 0.0361(18) Uani 0.414(5) 1 d . . P A 2
H34 H 0.618678 0.778170 0.427945 0.043 Uiso 0.414(5) 1 calc R U P A 2
C35 C 0.6572(3) 0.7569(5) 0.3832(5) 0.0460(17) Uani 0.414(5) 1 d . . P A 2
H35 H 0.637558 0.705260 0.349176 0.055 Uiso 0.414(5) 1 calc R U P A 2
C36 C 0.6965(3) 0.7905(6) 0.3883(5) 0.044(2) Uani 0.414(5) 1 d . . P A 2
H36 H 0.703723 0.763217 0.357044 0.053 Uiso 0.414(5) 1 calc R U P A 2
C37 C 0.7260(3) 0.8659(6) 0.4404(5) 0.051(2) Uani 0.414(5) 1 d . . P A 2
H37 H 0.754073 0.888264 0.446319 0.062 Uiso 0.414(5) 1 calc R U P A 2
C38 C 0.7127(3) 0.9073(7) 0.4834(7) 0.041(3) Uani 0.414(5) 1 d . . P A 2
H38 H 0.732126 0.959209 0.517160 0.049 Uiso 0.414(5) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 H1 1.46(2) . ?
Rh1 H2 1.61(3) . ?
Rh1 H3 1.64(3) . ?
Rh1 P1 2.2885(5) . ?
Rh1 P2 2.3010(5) . ?
Rh1 N1 2.3715(16) . ?
Cu1 Cu1 2.5417(5) 2_656 ?
Cu1 N1 1.9157(16) . ?
P1 C2 1.834(2) . ?
P1 C3 1.826(2) . ?
P1 C11 1.834(2) . ?
P2 C1 1.8347(19) . ?
P2 C4 1.831(2) . ?
P2 C5 1.835(2) . ?
Si1 N2 1.7261(19) . ?
Si1 C1 1.884(2) . ?
Si1 C17 1.868(2) . ?
Si1 C18 1.858(2) . ?
Si2 N2 1.7196(18) . ?
Si2 C2 1.885(2) . ?
Si2 C19 1.865(2) . ?
Si2 C20 1.857(2) . ?
Si3 N1 1.7220(19) . ?
Si3 C3 1.879(2) . ?
Si3 C21 1.876(2) . ?
Si3 C22 1.868(2) . ?
Si4 N1 1.7183(18) . ?
Si4 C4 1.886(2) . ?
Si4 C23 1.874(2) . ?
Si4 C24 1.865(3) . ?
N2 H4 0.77(3) . ?
C1 H11A 0.9700 . ?
C1 H11B 0.9700 . ?
C2 H9A 0.9700 . ?
C2 H9B 0.9700 . ?
C3 H10A 0.9700 . ?
C3 H10B 0.9700 . ?
C4 H12A 0.9700 . ?
C4 H12B 0.9700 . ?
C5 C6 1.400(3) . ?
C5 C10 1.386(3) . ?
C6 H18 0.9300 . ?
C7 C6 1.373(3) . ?
C7 H17 0.9300 . ?
C8 C7 1.378(4) . ?
C8 H16 0.9300 . ?
C9 C8 1.380(4) . ?
C9 H15 0.9300 . ?
C10 C9 1.394(3) . ?
C10 H14 0.9300 . ?
C11 C12 1.389(3) . ?
C11 C16 1.396(3) . ?
C12 H24 0.9300 . ?
C13 C12 1.391(3) . ?
C13 H23 0.9300 . ?
C14 C13 1.381(4) . ?
C14 H22 0.9300 . ?
C15 C14 1.377(4) . ?
C15 H21 0.9300 . ?
C16 C15 1.385(4) . ?
C16 H20 0.9300 . ?
C17 H4A 0.9600 . ?
C17 H4B 0.9600 . ?
C17 H4C 0.9600 . ?
C18 H3A 0.9600 . ?
C18 H3B 0.9600 . ?
C18 H3C 0.9600 . ?
C19 H2A 0.9600 . ?
C19 H2B 0.9600 . ?
C19 H2C 0.9600 . ?
C20 H1A 0.9600 . ?
C20 H1B 0.9600 . ?
C20 H1C 0.9600 . ?
C21 H8A 0.9600 . ?
C21 H8B 0.9600 . ?
C21 H8C 0.9600 . ?
C22 H7A 0.9600 . ?
C22 H7B 0.9600 . ?
C22 H7C 0.9600 . ?
C23 H6A 0.9600 . ?
C23 H6B 0.9600 . ?
C23 H6C 0.9600 . ?
C24 H5A 0.9600 . ?
C24 H5B 0.9600 . ?
C24 H5C 0.9600 . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C30 C31 1.4992 . ?
C25 H25 0.9300 . ?
C25 C26 1.3862 . ?
C25 C31 1.3921 . ?
C26 H26 0.9300 . ?
C26 C27 1.3866 . ?
C27 H27 0.9300 . ?
C27 C28 1.3864 . ?
C28 H28 0.9300 . ?
C28 C29 1.3867 . ?
C29 H29 0.9300 . ?
C29 C31 1.3926 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C32 C33 1.487(11) . ?
C33 C34 1.341(11) . ?
C33 C38 1.355(12) . ?
C34 H34 0.9300 . ?
C34 C35 1.452(10) . ?
C35 H35 0.9300 . ?
C35 C36 1.348(10) . ?
C36 H36 0.9300 . ?
C36 C37 1.383(12) . ?
C37 H37 0.9300 . ?
C37 C38 1.381(16) . ?
C38 H38 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
H1 Rh1 H2 82.7(13) . . ?
H1 Rh1 H3 84.4(12) . . ?
H2 Rh1 H3 84.7(13) . . ?
P1 Rh1 H1 93.5(9) . . ?
P1 Rh1 H2 77.6(10) . . ?
P1 Rh1 H3 162.4(9) . . ?
P1 Rh1 P2 110.567(19) . . ?
P1 Rh1 N1 89.58(4) . . ?
P2 Rh1 H1 91.6(9) . . ?
P2 Rh1 H2 170.3(10) . . ?
P2 Rh1 H3 87.0(9) . . ?
P2 Rh1 N1 88.45(4) . . ?
N1 Rh1 H1 176.7(9) . . ?
N1 Rh1 H2 96.9(10) . . ?
N1 Rh1 H3 92.3(9) . . ?
Cu1 Cu1 Rh1 70.375(10) 2_656 2_656 ?
N1 Cu1 Rh1 171.59(5) . 2_656 ?
N1 Cu1 Cu1 107.85(5) . 2_656 ?
C2 P1 Rh1 125.53(7) . . ?
C3 P1 Rh1 104.09(7) . . ?
C3 P1 C2 104.30(9) . . ?
C3 P1 C11 103.57(10) . . ?
C11 P1 Rh1 115.99(7) . . ?
C11 P1 C2 100.98(10) . . ?
C1 P2 Rh1 120.72(7) . . ?
C1 P2 C5 100.54(9) . . ?
C4 P2 Rh1 108.35(7) . . ?
C4 P2 C1 105.13(9) . . ?
C4 P2 C5 102.65(10) . . ?
C5 P2 Rh1 117.44(7) . . ?
N2 Si1 C1 110.61(9) . . ?
N2 Si1 C17 111.52(10) . . ?
N2 Si1 C18 106.72(10) . . ?
C17 Si1 C1 105.96(11) . . ?
C18 Si1 C1 112.81(10) . . ?
C18 Si1 C17 109.30(12) . . ?
N2 Si2 C2 111.71(9) . . ?
N2 Si2 C19 108.72(10) . . ?
N2 Si2 C20 109.84(10) . . ?
C19 Si2 C2 107.34(10) . . ?
C20 Si2 C2 110.23(10) . . ?
C20 Si2 C19 108.93(12) . . ?
N1 Si3 C3 107.66(9) . . ?
N1 Si3 C21 113.52(10) . . ?
N1 Si3 C22 113.12(10) . . ?
C21 Si3 C3 107.75(11) . . ?
C22 Si3 C3 108.27(11) . . ?
C22 Si3 C21 106.30(11) . . ?
N1 Si4 C4 106.18(9) . . ?
N1 Si4 C23 113.46(12) . . ?
N1 Si4 C24 113.58(10) . . ?
C23 Si4 C4 107.74(11) . . ?
C24 Si4 C4 109.36(11) . . ?
C24 Si4 C23 106.37(13) . . ?
Cu1 N1 Rh1 85.71(6) . . ?
Si3 N1 Rh1 110.54(8) . . ?
Si3 N1 Cu1 109.18(9) . . ?
Si4 N1 Rh1 106.22(8) . . ?
Si4 N1 Cu1 111.94(9) . . ?
Si4 N1 Si3 125.86(10) . . ?
Si1 N2 H4 111(2) . . ?
Si2 N2 Si1 130.15(11) . . ?
Si2 N2 H4 112(2) . . ?
P2 C1 Si1 117.90(11) . . ?
P2 C1 H11A 107.8 . . ?
P2 C1 H11B 107.8 . . ?
Si1 C1 H11A 107.8 . . ?
Si1 C1 H11B 107.8 . . ?
H11A C1 H11B 107.2 . . ?
P1 C2 Si2 117.52(11) . . ?
P1 C2 H9A 107.9 . . ?
P1 C2 H9B 107.9 . . ?
Si2 C2 H9A 107.9 . . ?
Si2 C2 H9B 107.9 . . ?
H9A C2 H9B 107.2 . . ?
P1 C3 Si3 110.01(11) . . ?
P1 C3 H10A 109.7 . . ?
P1 C3 H10B 109.7 . . ?
Si3 C3 H10A 109.7 . . ?
Si3 C3 H10B 109.7 . . ?
H10A C3 H10B 108.2 . . ?
P2 C4 Si4 108.87(10) . . ?
P2 C4 H12A 109.9 . . ?
P2 C4 H12B 109.9 . . ?
Si4 C4 H12A 109.9 . . ?
Si4 C4 H12B 109.9 . . ?
H12A C4 H12B 108.3 . . ?
C6 C5 P2 120.62(17) . . ?
C10 C5 P2 121.43(16) . . ?
C10 C5 C6 117.9(2) . . ?
C5 C6 H18 119.3 . . ?
C7 C6 C5 121.3(2) . . ?
C7 C6 H18 119.3 . . ?
C6 C7 H17 119.8 . . ?
C6 C7 C8 120.3(2) . . ?
C8 C7 H17 119.8 . . ?
C7 C8 H16 120.3 . . ?
C7 C8 C9 119.4(2) . . ?
C9 C8 H16 120.3 . . ?
C8 C9 H15 119.8 . . ?
C8 C9 C10 120.5(2) . . ?
C10 C9 H15 119.8 . . ?
C5 C10 C9 120.5(2) . . ?
C5 C10 H14 119.7 . . ?
C9 C10 H14 119.7 . . ?
C12 C11 P1 121.81(16) . . ?
C12 C11 C16 118.4(2) . . ?
C16 C11 P1 119.82(18) . . ?
C11 C12 H24 119.6 . . ?
C11 C12 C13 120.8(2) . . ?
C13 C12 H24 119.6 . . ?
C12 C13 H23 120.1 . . ?
C14 C13 C12 119.8(3) . . ?
C14 C13 H23 120.1 . . ?
C13 C14 H22 119.9 . . ?
C15 C14 C13 120.2(3) . . ?
C15 C14 H22 119.9 . . ?
C14 C15 H21 120.0 . . ?
C14 C15 C16 120.1(3) . . ?
C16 C15 H21 120.0 . . ?
C11 C16 H20 119.6 . . ?
C15 C16 C11 120.8(3) . . ?
C15 C16 H20 119.6 . . ?
Si1 C17 H4A 109.5 . . ?
Si1 C17 H4B 109.5 . . ?
Si1 C17 H4C 109.5 . . ?
H4A C17 H4B 109.5 . . ?
H4A C17 H4C 109.5 . . ?
H4B C17 H4C 109.5 . . ?
Si1 C18 H3A 109.5 . . ?
Si1 C18 H3B 109.5 . . ?
Si1 C18 H3C 109.5 . . ?
H3A C18 H3B 109.5 . . ?
H3A C18 H3C 109.5 . . ?
H3B C18 H3C 109.5 . . ?
Si2 C19 H2A 109.5 . . ?
Si2 C19 H2B 109.5 . . ?
Si2 C19 H2C 109.5 . . ?
H2A C19 H2B 109.5 . . ?
H2A C19 H2C 109.5 . . ?
H2B C19 H2C 109.5 . . ?
Si2 C20 H1A 109.5 . . ?
Si2 C20 H1B 109.5 . . ?
Si2 C20 H1C 109.5 . . ?
H1A C20 H1B 109.5 . . ?
H1A C20 H1C 109.5 . . ?
H1B C20 H1C 109.5 . . ?
Si3 C21 H8A 109.5 . . ?
Si3 C21 H8B 109.5 . . ?
Si3 C21 H8C 109.5 . . ?
H8A C21 H8B 109.5 . . ?
H8A C21 H8C 109.5 . . ?
H8B C21 H8C 109.5 . . ?
Si3 C22 H7A 109.5 . . ?
Si3 C22 H7B 109.5 . . ?
Si3 C22 H7C 109.5 . . ?
H7A C22 H7B 109.5 . . ?
H7A C22 H7C 109.5 . . ?
H7B C22 H7C 109.5 . . ?
Si4 C23 H6A 109.5 . . ?
Si4 C23 H6B 109.5 . . ?
Si4 C23 H6C 109.5 . . ?
H6A C23 H6B 109.5 . . ?
H6A C23 H6C 109.5 . . ?
H6B C23 H6C 109.5 . . ?
Si4 C24 H5A 109.5 . . ?
Si4 C24 H5B 109.5 . . ?
Si4 C24 H5C 109.5 . . ?
H5A C24 H5B 109.5 . . ?
H5A C24 H5C 109.5 . . ?
H5B C24 H5C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C31 C30 H30A 109.5 . . ?
C31 C30 H30B 109.5 . . ?
C31 C30 H30C 109.5 . . ?
C26 C25 H25 119.5 . . ?
C26 C25 C31 121.1 . . ?
C31 C25 H25 119.5 . . ?
C25 C26 H26 119.9 . . ?
C25 C26 C27 120.1 . . ?
C27 C26 H26 119.9 . . ?
C26 C27 H27 120.3 . . ?
C28 C27 C26 119.5 . . ?
C28 C27 H27 120.3 . . ?
C27 C28 H28 120.0 . . ?
C27 C28 C29 120.1 . . ?
C29 C28 H28 120.0 . . ?
C28 C29 H29 119.5 . . ?
C28 C29 C31 121.1 . . ?
C31 C29 H29 119.5 . . ?
C25 C31 C30 121.0 . . ?
C25 C31 C29 118.1 . . ?
C29 C31 C30 120.9 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C33 C32 H32A 109.5 . . ?
C33 C32 H32B 109.5 . . ?
C33 C32 H32C 109.5 . . ?
C34 C33 C32 121.4(8) . . ?
C34 C33 C38 117.3(8) . . ?
C38 C33 C32 121.3(9) . . ?
C33 C34 H34 119.6 . . ?
C33 C34 C35 120.8(7) . . ?
C35 C34 H34 119.6 . . ?
C34 C35 H35 120.2 . . ?
C36 C35 C34 119.6(8) . . ?
C36 C35 H35 120.2 . . ?
C35 C36 H36 120.2 . . ?
C35 C36 C37 119.6(7) . . ?
C37 C36 H36 120.2 . . ?
C36 C37 H37 120.8 . . ?
C38 C37 C36 118.3(7) . . ?
C38 C37 H37 120.8 . . ?
C33 C38 C37 124.3(9) . . ?
C33 C38 H38 117.8 . . ?
C37 C38 H38 117.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 P1 C2 Si2 74.25(14) . . . . ?
Rh1 P1 C3 Si3 42.86(11) . . . . ?
Rh1 P1 C11 C12 -23.5(2) . . . . ?
Rh1 P1 C11 C16 157.20(16) . . . . ?
Rh1 P2 C1 Si1 -54.25(14) . . . . ?
Rh1 P2 C4 Si4 24.01(12) . . . . ?
Rh1 P2 C5 C6 -173.12(15) . . . . ?
Rh1 P2 C5 C10 9.0(2) . . . . ?
P1 C11 C12 C13 -179.33(18) . . . . ?
P1 C11 C16 C15 179.0(2) . . . . ?
P2 C5 C6 C7 -178.10(18) . . . . ?
P2 C5 C10 C9 178.14(19) . . . . ?
N1 Si3 C3 P1 -44.59(12) . . . . ?
N1 Si4 C4 P2 -47.72(13) . . . . ?
N2 Si1 C1 P2 77.05(14) . . . . ?
N2 Si2 C2 P1 -39.04(16) . . . . ?
C1 P2 C4 Si4 154.35(11) . . . . ?
C1 P2 C5 C6 53.86(19) . . . . ?
C1 P2 C5 C10 -123.98(18) . . . . ?
C1 Si1 N2 Si2 50.42(15) . . . . ?
C2 P1 C3 Si3 -90.16(12) . . . . ?
C2 P1 C11 C12 115.37(18) . . . . ?
C2 P1 C11 C16 -63.9(2) . . . . ?
C2 Si2 N2 Si1 -80.67(15) . . . . ?
C3 P1 C2 Si2 -166.37(12) . . . . ?
C3 P1 C11 C12 -136.83(18) . . . . ?
C3 P1 C11 C16 43.9(2) . . . . ?
C3 Si3 N1 Rh1 23.56(10) . . . . ?
C3 Si3 N1 Cu1 -69.06(10) . . . . ?
C3 Si3 N1 Si4 153.26(11) . . . . ?
C4 P2 C1 Si1 -176.94(12) . . . . ?
C4 P2 C5 C6 -54.43(19) . . . . ?
C4 P2 C5 C10 127.73(18) . . . . ?
C4 Si4 N1 Rh1 47.11(10) . . . . ?
C4 Si4 N1 Cu1 139.01(9) . . . . ?
C4 Si4 N1 Si3 -84.26(13) . . . . ?
C5 P2 C1 Si1 76.73(13) . . . . ?
C5 P2 C4 Si4 -100.88(11) . . . . ?
C5 C10 C9 C8 -0.2(4) . . . . ?
C6 C5 C10 C9 0.2(3) . . . . ?
C8 C7 C6 C5 0.1(4) . . . . ?
C9 C8 C7 C6 0.0(4) . . . . ?
C10 C5 C6 C7 -0.2(3) . . . . ?
C10 C9 C8 C7 0.1(4) . . . . ?
C11 P1 C2 Si2 -59.14(14) . . . . ?
C11 P1 C3 Si3 164.55(10) . . . . ?
C11 C16 C15 C14 0.0(4) . . . . ?
C12 C11 C16 C15 -0.3(4) . . . . ?
C14 C13 C12 C11 0.6(4) . . . . ?
C15 C14 C13 C12 -0.9(4) . . . . ?
C16 C11 C12 C13 0.0(3) . . . . ?
C16 C15 C14 C13 0.6(5) . . . . ?
C17 Si1 N2 Si2 -67.23(17) . . . . ?
C17 Si1 C1 P2 -161.94(13) . . . . ?
C18 Si1 N2 Si2 173.47(13) . . . . ?
C18 Si1 C1 P2 -42.39(16) . . . . ?
C19 Si2 N2 Si1 37.59(16) . . . . ?
C19 Si2 C2 P1 -158.13(13) . . . . ?
C20 Si2 N2 Si1 156.69(13) . . . . ?
C20 Si2 C2 P1 83.37(15) . . . . ?
C21 Si3 N1 Rh1 -95.62(11) . . . . ?
C21 Si3 N1 Cu1 171.77(10) . . . . ?
C21 Si3 N1 Si4 34.08(15) . . . . ?
C21 Si3 C3 P1 78.20(13) . . . . ?
C22 Si3 N1 Rh1 143.14(10) . . . . ?
C22 Si3 N1 Cu1 50.52(13) . . . . ?
C22 Si3 N1 Si4 -87.16(14) . . . . ?
C22 Si3 C3 P1 -167.21(11) . . . . ?
C23 Si4 N1 Rh1 165.26(10) . . . . ?
C23 Si4 N1 Cu1 -102.85(12) . . . . ?
C23 Si4 N1 Si3 33.88(15) . . . . ?
C23 Si4 C4 P2 -169.59(13) . . . . ?
C24 Si4 N1 Rh1 -73.10(12) . . . . ?
C24 Si4 N1 Cu1 18.80(14) . . . . ?
C24 Si4 N1 Si3 155.53(13) . . . . ?
C24 Si4 C4 P2 75.19(14) . . . . ?
C25 C26 C27 C28 -0.1 . . . . ?
C26 C25 C31 C30 -178.5 . . . . ?
C26 C25 C31 C29 0.2 . . . . ?
C26 C27 C28 C29 0.1 . . . . ?
C27 C28 C29 C31 0.0 . . . . ?
C28 C29 C31 C30 178.5 . . . . ?
C28 C29 C31 C25 -0.2 . . . . ?
C31 C25 C26 C27 0.0 . . . . ?
C32 C33 C34 C35 178.0(8) . . . . ?
C32 C33 C38 C37 -179.3(8) . . . . ?
C33 C34 C35 C36 0.7(12) . . . . ?
C34 C33 C38 C37 0.3(13) . . . . ?
C34 C35 C36 C37 1.4(12) . . . . ?
C35 C36 C37 C38 -2.6(12) . . . . ?
C36 C37 C38 C33 1.9(14) . . . . ?
C38 C33 C34 C35 -1.5(11) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_chemical_properties_physical    
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
