# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2105384'
loop_
_audit_author_name
_audit_author_address
'Rui Zhang'
;YiLi Normal University
China
;
_audit_update_record             
;
2021-08-25 deposited with the CCDC.	2021-11-08 downloaded from the CCDC.
;
_audit_creation_date             2021-07-15
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        RbMoPO
_chemical_formula_moiety         'Mo2 O14 P3 Rb'
_chemical_formula_sum            'Mo2 O14 P3 Rb'
_chemical_formula_weight         594.26
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 1 21 1'
_space_group_name_Hall           'P 2yb'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   8.0271(3)
_cell_length_b                   6.3124(2)
_cell_length_c                   11.9022(4)
_cell_angle_alpha                90
_cell_angle_beta                 96.1210(10)
_cell_angle_gamma                90
_cell_volume                     599.65(4)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9170
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      27.51
_cell_measurement_theta_min      2.55
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    6.599
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5189
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0968 before and 0.0556 after correction.
The Ratio of minimum to maximum transmission is 0.6959.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    3.291
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             556
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0363
_diffrn_reflns_av_unetI/netI     0.0290
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            12256
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.551
_diffrn_reflns_theta_min         1.721
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean 5.6
_diffrn_detector_type            'Bruker SMART CCD 6000 area detector'
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.828
_reflns_Friedel_fraction_full    0.995
_reflns_Friedel_fraction_max     0.992
_reflns_number_gt                2701
_reflns_number_total             2781
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_refine_diff_density_max         0.631
_refine_diff_density_min         -0.610
_refine_diff_density_rms         0.106
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.422(10)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     182
_refine_ls_number_reflns         2781
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0207
_refine_ls_R_factor_gt           0.0195
_refine_ls_restrained_S_all      1.059
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0233P)²+0.1725P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0464
_refine_ls_wR_factor_ref         0.0471
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.578(10)
 0.422(10)
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Mo1 Mo 0.71957(5) 0.73608(5) 0.52050(3) 0.01229(10) Uani 1 1 d . . . . .
Mo2 Mo 0.72758(5) 0.96962(6) 0.03312(3) 0.01499(10) Uani 1 1 d . . . . .
Rb1 Rb 0.31667(9) 0.82139(13) 0.23794(5) 0.03866(17) Uani 1 1 d . . . . .
P1 P 0.84878(14) 0.2270(2) 0.49450(9) 0.0117(2) Uani 1 1 d . . . . .
P2 P 0.94315(16) 0.1966(2) 0.26585(10) 0.0137(3) Uani 1 1 d . . . . .
P3 P 0.86755(16) 0.4600(2) 0.07358(9) 0.0146(2) Uani 1 1 d . . . . .
O9 O 0.9046(6) 0.0199(6) 0.1851(3) 0.0237(10) Uani 1 1 d . . . . .
O12 O 0.7587(6) 0.2866(7) 0.0171(3) 0.0268(11) Uani 1 1 d . . . . .
O6 O 1.0312(4) 0.2412(7) 0.5330(3) 0.0171(7) Uani 1 1 d . . . . .
O4 O 0.7531(5) 0.4228(6) 0.5210(3) 0.0217(10) Uani 1 1 d . . . . .
O5 O 0.7635(5) 0.0446(6) 0.5482(3) 0.0181(8) Uani 1 1 d . . . . .
O13 O 0.7729(6) 0.6659(6) 0.0627(4) 0.0231(9) Uani 1 1 d . . . . .
O7 O 0.8212(4) 0.1887(7) 0.3612(3) 0.0217(8) Uani 1 1 d . . . . .
O3 O 0.5585(5) 0.7219(8) 0.5989(3) 0.0226(8) Uani 1 1 d . . . . .
O1 O 0.6269(5) 0.7571(8) 0.3878(3) 0.0273(9) Uani 1 1 d . . . . .
O2 O 0.5689(6) 0.9866(10) 0.1145(4) 0.0400(11) Uani 1 1 d . . . . .
O11 O 1.0384(6) 0.4661(9) 0.0376(4) 0.0387(11) Uani 1 1 d . . . . .
O8 O 1.1188(5) 0.2073(7) 0.3160(3) 0.0212(8) Uani 1 1 d . . . . .
O14 O 0.6257(6) 0.9491(8) -0.0967(4) 0.0387(12) Uani 1 1 d . . . . .
O10 O 0.8874(5) 0.4138(6) 0.2061(3) 0.0205(8) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Mo1 Rb1 3.9219(8) 2_646 ?
Mo1 O6 2.164(4) 2_756 ?
Mo1 O4 1.996(4) . ?
Mo1 O5 2.001(4) 1_565 ?
Mo1 O3 1.676(4) . ?
Mo1 O1 1.678(4) . ?
Mo1 O8 2.228(3) 2_756 ?
Mo2 Rb1 3.9013(8) 2_655 ?
Mo2 O9 2.201(4) 1_565 ?
Mo2 O12 2.028(4) 1_565 ?
Mo2 O13 1.976(4) . ?
Mo2 O2 1.684(4) . ?
Mo2 O11 2.139(4) 2_755 ?
Mo2 O14 1.675(4) . ?
Rb1 P1 3.6279(13) 2_656 ?
Rb1 P2 3.8630(15) 1_465 ?
Rb1 O9 3.530(4) 1_465 ?
Rb1 O12 3.040(4) 2_655 ?
Rb1 O4 3.049(4) 2_656 ?
Rb1 O5 3.209(4) 2_656 ?
Rb1 O3 3.279(4) 2_656 ?
Rb1 O1 2.933(4) . ?
Rb1 O2 2.825(5) . ?
Rb1 O8 3.104(4) 1_465 ?
Rb1 O14 2.954(5) 2_645 ?
P1 O6 1.489(3) . ?
P1 O4 1.506(4) . ?
P1 O5 1.515(4) . ?
P1 O7 1.597(4) . ?
P2 O9 1.484(4) . ?
P2 O7 1.576(4) . ?
P2 O8 1.473(4) . ?
P2 O10 1.587(4) . ?
P3 O12 1.512(4) . ?
P3 O13 1.504(4) . ?
P3 O11 1.480(5) . ?
P3 O10 1.595(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Mo1 Rb1 111.66(10) 2_756 2_646 ?
O6 Mo1 O8 77.75(13) 2_756 2_756 ?
O4 Mo1 Rb1 49.98(12) . 2_646 ?
O4 Mo1 O6 83.53(17) . 2_756 ?
O4 Mo1 O5 160.56(15) . 1_565 ?
O4 Mo1 O8 81.43(17) . 2_756 ?
O5 Mo1 Rb1 123.69(11) 1_565 2_646 ?
O5 Mo1 O6 83.20(17) 1_565 2_756 ?
O5 Mo1 O8 81.92(17) 1_565 2_756 ?
O3 Mo1 Rb1 55.54(15) . 2_646 ?
O3 Mo1 O6 163.23(15) . 2_756 ?
O3 Mo1 O4 93.3(2) . . ?
O3 Mo1 O5 95.4(2) . 1_565 ?
O3 Mo1 O1 103.73(19) . . ?
O3 Mo1 O8 85.50(16) . 2_756 ?
O1 Mo1 Rb1 133.07(16) . 2_646 ?
O1 Mo1 O6 93.01(17) . 2_756 ?
O1 Mo1 O4 97.3(2) . . ?
O1 Mo1 O5 97.5(2) . 1_565 ?
O1 Mo1 O8 170.75(17) . 2_756 ?
O8 Mo1 Rb1 52.21(11) 2_756 2_646 ?
O9 Mo2 Rb1 126.25(11) 1_565 2_655 ?
O12 Mo2 Rb1 50.36(11) 1_565 2_655 ?
O12 Mo2 O9 81.93(15) 1_565 1_565 ?
O12 Mo2 O11 81.4(2) 1_565 2_755 ?
O13 Mo2 Rb1 134.30(12) . 2_655 ?
O13 Mo2 O9 84.43(16) . 1_565 ?
O13 Mo2 O12 162.15(17) . 1_565 ?
O13 Mo2 O11 84.7(2) . 2_755 ?
O2 Mo2 Rb1 115.56(18) . 2_655 ?
O2 Mo2 O9 88.9(2) . 1_565 ?
O2 Mo2 O12 95.7(3) . 1_565 ?
O2 Mo2 O13 95.5(2) . . ?
O2 Mo2 O11 167.7(2) . 2_755 ?
O11 Mo2 Rb1 71.74(14) 2_755 2_655 ?
O11 Mo2 O9 78.92(18) 2_755 1_565 ?
O14 Mo2 Rb1 44.65(17) . 2_655 ?
O14 Mo2 O9 168.1(2) . 1_565 ?
O14 Mo2 O12 92.45(19) . 1_565 ?
O14 Mo2 O13 98.7(2) . . ?
O14 Mo2 O2 102.1(3) . . ?
O14 Mo2 O11 89.9(2) . 2_755 ?
P1 Rb1 Mo2 128.52(3) 2_656 2_645 ?
P1 Rb1 P2 70.43(3) 2_656 1_465 ?
P2 Rb1 Mo2 114.65(2) 1_465 2_645 ?
O9 Rb1 Mo2 93.07(6) 1_465 2_645 ?
O9 Rb1 P1 77.94(7) 1_465 2_656 ?
O9 Rb1 P2 22.58(7) 1_465 1_465 ?
O12 Rb1 Mo2 30.92(8) 2_655 2_645 ?
O12 Rb1 P1 144.33(10) 2_655 2_656 ?
O12 Rb1 P2 93.24(9) 2_655 1_465 ?
O12 Rb1 O9 76.38(11) 2_655 1_465 ?
O12 Rb1 O4 156.64(11) 2_655 2_656 ?
O12 Rb1 O5 135.86(13) 2_655 2_656 ?
O12 Rb1 O3 131.52(11) 2_655 2_656 ?
O12 Rb1 O8 107.58(11) 2_655 1_465 ?
O4 Rb1 Mo2 152.61(8) 2_656 2_645 ?
O4 Rb1 P1 24.13(8) 2_656 2_656 ?
O4 Rb1 P2 64.43(8) 2_656 1_465 ?
O4 Rb1 O9 80.26(10) 2_656 1_465 ?
O4 Rb1 O5 45.19(10) 2_656 2_656 ?
O4 Rb1 O3 49.91(10) 2_656 2_656 ?
O4 Rb1 O8 53.30(10) 2_656 1_465 ?
O5 Rb1 Mo2 109.75(7) 2_656 2_645 ?
O5 Rb1 P1 24.64(7) 2_656 2_656 ?
O5 Rb1 P2 92.43(8) 2_656 1_465 ?
O5 Rb1 O9 94.09(10) 2_656 1_465 ?
O5 Rb1 O3 91.40(10) 2_656 2_656 ?
O3 Rb1 Mo2 157.47(7) 2_656 2_645 ?
O3 Rb1 P1 73.98(7) 2_656 2_656 ?
O3 Rb1 P2 70.57(7) 2_656 1_465 ?
O3 Rb1 O9 93.06(9) 2_656 1_465 ?
O1 Rb1 Mo2 114.88(9) . 2_645 ?
O1 Rb1 P1 79.05(8) . 2_656 ?
O1 Rb1 P2 130.47(9) . 1_465 ?
O1 Rb1 O9 151.19(11) . 1_465 ?
O1 Rb1 O12 131.54(13) . 2_655 ?
O1 Rb1 O4 71.69(11) . 2_656 ?
O1 Rb1 O5 70.81(12) . 2_656 ?
O1 Rb1 O3 63.92(12) . 2_656 ?
O1 Rb1 O8 110.78(11) . 1_465 ?
O1 Rb1 O14 93.53(13) . 2_645 ?
O2 Rb1 Mo2 77.70(11) . 2_645 ?
O2 Rb1 P1 150.11(11) . 2_656 ?
O2 Rb1 P2 115.10(12) . 1_465 ?
O2 Rb1 O9 119.07(13) . 1_465 ?
O2 Rb1 O12 65.44(14) . 2_655 ?
O2 Rb1 O4 128.73(14) . 2_656 ?
O2 Rb1 O5 146.02(13) . 2_656 ?
O2 Rb1 O3 80.37(14) . 2_656 ?
O2 Rb1 O1 76.02(13) . . ?
O2 Rb1 O8 106.50(14) . 1_465 ?
O2 Rb1 O14 80.40(16) . 2_645 ?
O8 Rb1 Mo2 133.63(7) 1_465 2_645 ?
O8 Rb1 P1 67.61(8) 1_465 2_656 ?
O8 Rb1 P2 21.01(7) 1_465 1_465 ?
O8 Rb1 O9 43.56(9) 1_465 1_465 ?
O8 Rb1 O5 92.14(10) 1_465 2_656 ?
O8 Rb1 O3 49.57(10) 1_465 2_656 ?
O14 Rb1 Mo2 23.47(8) 2_645 2_645 ?
O14 Rb1 P1 117.58(11) 2_645 2_656 ?
O14 Rb1 P2 134.97(9) 2_645 1_465 ?
O14 Rb1 O9 112.43(11) 2_645 1_465 ?
O14 Rb1 O12 53.19(12) 2_645 2_655 ?
O14 Rb1 O4 139.28(12) 2_645 2_656 ?
O14 Rb1 O5 94.31(12) 2_645 2_656 ?
O14 Rb1 O3 153.34(12) 2_645 2_656 ?
O14 Rb1 O8 155.62(11) 2_645 1_465 ?
O6 P1 Rb1 99.18(14) . 2_646 ?
O6 P1 O4 113.1(2) . . ?
O6 P1 O5 112.9(2) . . ?
O6 P1 O7 110.0(2) . . ?
O4 P1 Rb1 55.86(16) . 2_646 ?
O4 P1 O5 105.8(2) . . ?
O4 P1 O7 108.2(2) . . ?
O5 P1 Rb1 62.00(15) . 2_646 ?
O5 P1 O7 106.4(2) . . ?
O7 P1 Rb1 150.70(14) . 2_646 ?
O9 P2 Rb1 66.00(17) . 1_645 ?
O9 P2 O7 109.9(2) . . ?
O9 P2 O10 109.26(19) . . ?
O7 P2 Rb1 126.13(16) . 1_645 ?
O7 P2 O10 100.5(2) . . ?
O8 P2 Rb1 49.07(17) . 1_645 ?
O8 P2 O9 114.9(3) . . ?
O8 P2 O7 110.5(2) . . ?
O8 P2 O10 110.7(2) . . ?
O10 P2 Rb1 132.50(16) . 1_645 ?
O12 P3 Rb1 43.97(16) . 2_645 ?
O12 P3 O10 107.4(2) . . ?
O13 P3 Rb1 88.60(16) . 2_645 ?
O13 P3 O12 108.9(2) . . ?
O13 P3 O10 103.8(2) . . ?
O11 P3 Rb1 90.01(19) . 2_645 ?
O11 P3 O12 113.6(3) . . ?
O11 P3 O13 115.3(3) . . ?
O11 P3 O10 107.0(2) . . ?
O10 P3 Rb1 151.36(15) . 2_645 ?
Mo2 O9 Rb1 127.31(16) 1_545 1_645 ?
P2 O9 Mo2 135.5(2) . 1_545 ?
P2 O9 Rb1 91.42(19) . 1_645 ?
Mo2 O12 Rb1 98.72(14) 1_545 2_645 ?
P3 O12 Mo2 138.0(2) . 1_545 ?
P3 O12 Rb1 115.8(2) . 2_645 ?
P1 O6 Mo1 144.9(2) . 2_746 ?
Mo1 O4 Rb1 99.94(15) . 2_646 ?
P1 O4 Mo1 152.1(3) . . ?
P1 O4 Rb1 100.01(19) . 2_646 ?
Mo1 O5 Rb1 127.88(16) 1_545 2_646 ?
P1 O5 Mo1 138.6(2) . 1_545 ?
P1 O5 Rb1 93.36(18) . 2_646 ?
P3 O13 Mo2 159.3(3) . . ?
P2 O7 P1 132.8(2) . . ?
Mo1 O3 Rb1 99.54(17) . 2_646 ?
Mo1 O1 Rb1 147.8(2) . . ?
Mo2 O2 Rb1 154.7(3) . . ?
P3 O11 Mo2 173.6(3) . 2_745 ?
Mo1 O8 Rb1 93.25(13) 2_746 1_645 ?
P2 O8 Mo1 143.2(2) . 2_746 ?
P2 O8 Rb1 109.9(2) . 1_645 ?
Mo2 O14 Rb1 111.9(2) . 2_655 ?
P2 O10 P3 126.5(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rb1 Mo1 O1 Rb1 65.1(5) 2_646 . . . ?
Rb1 Mo2 O2 Rb1 129.1(5) 2_655 . . . ?
Rb1 P1 O6 Mo1 -176.3(4) 2_646 . . 2_746 ?
Rb1 P1 O4 Mo1 135.1(6) 2_646 . . . ?
Rb1 P1 O5 Mo1 -175.3(5) 2_646 . . 1_545 ?
Rb1 P1 O7 P2 165.49(15) 2_646 . . . ?
Rb1 P2 O9 Mo2 -152.8(4) 1_645 . . 1_545 ?
Rb1 P2 O7 P1 65.2(4) 1_645 . . . ?
Rb1 P2 O8 Mo1 -125.9(6) 1_645 . . 2_746 ?
Rb1 P2 O10 P3 50.4(4) 1_645 . . . ?
Rb1 P3 O12 Mo2 142.1(6) 2_645 . . 1_545 ?
Rb1 P3 O13 Mo2 -94.4(8) 2_645 . . . ?
Rb1 P3 O10 P2 52.9(6) 2_645 . . . ?
O9 Mo2 O2 Rb1 -100.7(6) 1_565 . . . ?
O9 Mo2 O14 Rb1 -43.5(11) 1_565 . . 2_655 ?
O9 P2 O7 P1 139.4(4) . . . . ?
O9 P2 O8 Mo1 -130.3(4) . . . 2_746 ?
O9 P2 O8 Rb1 -4.5(3) . . . 1_645 ?
O9 P2 O10 P3 -24.3(4) . . . . ?
O12 Mo2 O2 Rb1 177.5(6) 1_565 . . . ?
O12 Mo2 O14 Rb1 17.8(2) 1_565 . . 2_655 ?
O12 P3 O13 Mo2 -134.1(7) . . . . ?
O12 P3 O10 P2 51.1(4) . . . . ?
O6 Mo1 O3 Rb1 -43.5(8) 2_756 . . 2_646 ?
O6 Mo1 O1 Rb1 -171.2(4) 2_756 . . . ?
O6 P1 O4 Mo1 49.7(6) . . . . ?
O6 P1 O4 Rb1 -85.4(2) . . . 2_646 ?
O6 P1 O5 Mo1 -87.0(4) . . . 1_545 ?
O6 P1 O5 Rb1 88.4(2) . . . 2_646 ?
O6 P1 O7 P2 -10.2(5) . . . . ?
O4 Mo1 O3 Rb1 34.88(16) . . . 2_646 ?
O4 Mo1 O1 Rb1 105.0(5) . . . . ?
O4 P1 O6 Mo1 -119.6(4) . . . 2_746 ?
O4 P1 O5 Mo1 148.8(4) . . . 1_545 ?
O4 P1 O5 Rb1 -35.85(19) . . . 2_646 ?
O4 P1 O7 P2 113.9(4) . . . . ?
O5 Mo1 O3 Rb1 -127.69(15) 1_565 . . 2_646 ?
O5 Mo1 O1 Rb1 -87.7(5) 1_565 . . . ?
O5 P1 O6 Mo1 120.4(4) . . . 2_746 ?
O5 P1 O4 Mo1 173.8(6) . . . . ?
O5 P1 O4 Rb1 38.7(2) . . . 2_646 ?
O5 P1 O7 P2 -132.9(4) . . . . ?
O13 Mo2 O2 Rb1 -16.4(6) . . . . ?
O13 Mo2 O14 Rb1 -148.2(2) . . . 2_655 ?
O13 P3 O12 Mo2 -151.0(4) . . . 1_545 ?
O13 P3 O12 Rb1 66.9(3) . . . 2_645 ?
O13 P3 O10 P2 166.4(3) . . . . ?
O7 P1 O6 Mo1 1.6(5) . . . 2_746 ?
O7 P1 O4 Mo1 -72.5(6) . . . . ?
O7 P1 O4 Rb1 152.38(17) . . . 2_646 ?
O7 P1 O5 Mo1 33.9(5) . . . 1_545 ?
O7 P1 O5 Rb1 -150.80(16) . . . 2_646 ?
O7 P2 O9 Mo2 85.5(4) . . . 1_545 ?
O7 P2 O9 Rb1 -121.69(18) . . . 1_645 ?
O7 P2 O8 Mo1 -5.3(6) . . . 2_746 ?
O7 P2 O8 Rb1 120.6(2) . . . 1_645 ?
O7 P2 O10 P3 -139.9(3) . . . . ?
O3 Mo1 O1 Rb1 9.8(5) . . . . ?
O1 Mo1 O3 Rb1 133.23(19) . . . 2_646 ?
O2 Mo2 O14 Rb1 114.2(3) . . . 2_655 ?
O11 Mo2 O2 Rb1 -106.6(13) 2_755 . . . ?
O11 Mo2 O14 Rb1 -63.6(2) 2_755 . . 2_655 ?
O11 P3 O12 Mo2 79.0(5) . . . 1_545 ?
O11 P3 O12 Rb1 -63.1(3) . . . 2_645 ?
O11 P3 O13 Mo2 -5.1(9) . . . . ?
O11 P3 O10 P2 -71.2(4) . . . . ?
O8 Mo1 O3 Rb1 -46.25(15) 2_756 . . 2_646 ?
O8 P2 O9 Mo2 -149.1(3) . . . 1_545 ?
O8 P2 O9 Rb1 3.7(3) . . . 1_645 ?
O8 P2 O7 P1 11.6(5) . . . . ?
O8 P2 O10 P3 103.3(3) . . . . ?
O14 Mo2 O2 Rb1 83.8(6) . . . . ?
O10 P2 O9 Mo2 -23.9(4) . . . 1_545 ?
O10 P2 O9 Rb1 128.89(18) . . . 1_645 ?
O10 P2 O7 P1 -105.5(4) . . . . ?
O10 P2 O8 Mo1 105.3(5) . . . 2_746 ?
O10 P2 O8 Rb1 -128.9(2) . . . 1_645 ?
O10 P3 O12 Mo2 -39.1(5) . . . 1_545 ?
O10 P3 O12 Rb1 178.7(2) . . . 2_645 ?
O10 P3 O13 Mo2 111.7(8) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.578(10)
2 0.422(10)
