40
Computed structure unbridged silyl cation [5]+
Si     -1.663900   -1.846800   -0.474100
Si      0.160400   -0.360800   -0.301600
Si      2.380100   -0.853300   -0.959900
Si     -0.496600    1.719300   -0.900300
Si      0.314300    0.459100    1.956800
C       0.638000    3.182900   -0.854300
C      -2.260200    2.210900   -1.185800
C      -1.029500    1.714100    2.376100
C       0.211200   -1.059500    3.048400
C       3.362200    0.737000   -1.109100
C       3.071400   -1.976500    0.370100
C      -3.074900   -1.177300    0.571100
C      -2.148400   -2.049700   -2.272500
H      -1.158200   -3.118500    0.095700
H       2.276800   -1.546300   -2.264700
H       1.642400    1.117900    2.046200
H       0.136500    4.055000   -0.426700
H       0.915500    3.444500   -1.883200
H       1.558100    2.978200   -0.306000
H      -2.320900    3.065200   -1.865300
H      -2.870200    1.393800   -1.571400
H      -2.687900    2.531800   -0.227300
H      -1.002100    1.926300    3.448600
H      -0.893900    2.675500    1.869400
H      -2.027300    1.332300    2.144900
H       0.331000   -0.770800    4.096100
H       0.993300   -1.780300    2.802700
H      -0.754600   -1.558700    2.944800
H       4.394100    0.500000   -1.381800
H       2.964300    1.400900   -1.879200
H       3.391000    1.273300   -0.157500
H       4.071300   -2.317800    0.090400
H       2.448600   -2.860600    0.522300
H       3.157600   -1.443700    1.320800
H      -3.932000   -1.853500    0.512000
H      -2.795900   -1.094300    1.623800
H      -3.409700   -0.195500    0.227300
H      -2.956700   -2.779300   -2.365000
H      -1.309200   -2.402300   -2.875100
H      -2.501400   -1.107900   -2.699600
40
Intramolecularly Si-H-Si bridged silyl cation [5]+
Si     -0.306200    0.088400   -0.155600
Si      1.565200   -0.814300   -1.202100
Si     -2.024900   -1.513400    0.040400
Si     -0.730500    2.357800   -0.644400
Si      1.359000   -0.358600    1.409000
C      -3.020800   -1.119000    1.577900
C      -3.058300   -1.473400   -1.520900
C       2.490400    0.974500    2.054300
C       1.195200   -1.880500    2.471800
C       2.765800    0.320200   -2.064600
C       1.570300   -2.599500   -1.732300
C      -2.380300    2.772200    0.142000
C       0.655400    3.443000    0.002600
H      -1.331000   -2.820000    0.184300
H      -0.810800    2.435300   -2.122400
H      -3.836300   -1.837200    1.694400
H      -2.405300   -1.163300    2.478900
H      -3.461500   -0.121400    1.514800
H      -3.871100   -2.200700   -1.453200
H      -2.464700   -1.715000   -2.404600
H      -3.505700   -0.488000   -1.671100
H       3.405300    0.544000    2.465700
H       2.753000    1.693600    1.276900
H       1.980700    1.520000    2.853500
H       0.581200   -1.636300    3.343600
H       0.701200   -2.692300    1.934700
H       2.167500   -2.226100    2.827500
H       3.739200   -0.155100   -2.197500
H       2.368800    0.572700   -3.051700
H       2.900000    1.252900   -1.513800
H       1.067800   -2.682100   -2.700300
H       2.587500   -2.979500   -1.842100
H       1.028000   -3.226700   -1.022700
H      -2.651300    3.808500   -0.074900
H      -3.179000    2.134000   -0.242400
H      -2.340900    2.657000    1.227700
H       0.433900    4.489500   -0.223000
H       1.615800    3.207100   -0.460300
H       0.757400    3.352200    1.086200
H       2.388300   -0.987700    0.244100
81
Intermolecularly Si-H-Si bridged silyl cation [5]+
Si      1.433700    0.009900   -1.159300
C       1.651200   -1.180300   -2.584800
C       0.509200    1.550800   -1.671100
Si      3.184300    0.223300    0.360700
Si      2.505100    1.905500    1.846700
C       0.880900    1.300500    2.595300
C       2.304100    3.568000    0.993500
Si      3.405000   -1.840600    1.462700
C       5.149700   -2.004500    2.132600
C       2.976900   -3.252700    0.290100
Si      4.988500    0.710100   -1.071600
C       4.426200    1.979400   -2.344600
C       5.544900   -0.875800   -1.916000
H       2.344800   -0.726700   -3.301300
H       2.076200   -2.134200   -2.268900
H       0.713600   -1.364600   -3.113500
H       1.227800    2.299700   -2.018900
H      -0.048100    1.986100   -0.836400
H      -0.188400    1.351100   -2.486900
H       3.526300    2.008800    2.917800
H       1.063400    0.426100    3.225500
H       0.409800    2.070600    3.212200
H       0.168300    1.013900    1.813300
H       3.259800    3.918800    0.597300
H       1.946800    4.317400    1.704800
H       1.590100    3.524500    0.168100
H       2.429300   -1.838700    2.586500
H       5.388300   -1.183800    2.812500
H       5.264400   -2.941500    2.682800
H       5.885700   -1.996500    1.325500
H       1.946400   -3.178000   -0.070100
H       3.083800   -4.217100    0.793200
H       3.640400   -3.254700   -0.579000
H       6.082900    1.267000   -0.239600
H       4.015400    2.872600   -1.867800
H       5.263800    2.292500   -2.972900
H       3.660900    1.564800   -3.008200
H       5.889300   -1.616500   -1.190900
H       6.371100   -0.675000   -2.602600
H       4.732500   -1.322800   -2.495000
Si     -1.120400   -1.449800    0.059400
C      -1.147700   -2.818800   -1.213900
C      -0.653800   -2.086000    1.753500
Si     -2.855700    0.083700   -0.116100
Si     -3.185000    0.937100   -2.285800
C      -5.027000    1.248200   -2.478700
C      -2.575000   -0.265800   -3.599700
Si     -4.677800   -1.396500    0.224100
C      -6.156900   -0.390400    0.793200
C      -4.296600   -2.747600    1.480800
Si     -2.981500    1.784800    1.501800
C      -1.839000    3.231500    1.120000
C      -2.758600    1.088500    3.233500
H      -1.986200   -3.483100   -0.978100
H      -1.305400   -2.444700   -2.226000
H      -0.235500   -3.419600   -1.190700
H      -1.504700   -2.628200    2.175300
H      -0.399400   -1.275800    2.437600
H       0.192000   -2.775300    1.696100
H      -2.451400    2.224100   -2.407200
H      -5.395900    1.940000   -1.717800
H      -5.235000    1.687400   -3.457700
H      -5.595100    0.317500   -2.402300
H      -1.495500   -0.428200   -3.545500
H      -2.801400    0.120200   -4.596900
H      -3.074200   -1.232800   -3.496700
H      -4.949200   -2.030800   -1.095300
H      -6.391300    0.420600    0.101600
H      -7.037800   -1.032000    0.876100
H      -5.968200    0.050400    1.775500
H      -3.524100   -3.439700    1.136400
H      -5.198700   -3.337400    1.664200
H      -3.979900   -2.323300    2.437100
H      -4.381500    2.260700    1.342600
H      -2.006100    3.593000    0.102100
H      -2.054200    4.057900    1.802900
H      -0.782600    2.980800    1.228100
H      -3.507900    0.318700    3.435100
H      -2.881800    1.875200    3.982300
H      -1.770400    0.645700    3.372000
H       0.299800   -0.719600   -0.259400
