# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2101335'
loop_
_audit_author_name
_audit_author_address
'Vassilios Nastopoulos'
;University of Patras
Greece
;
_audit_update_record             
;
2021-08-04 deposited with the CCDC.	2022-01-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C73 H58 Dy2 O13, C H4 O'
_chemical_formula_sum            'C74 H62 Dy2 O14'
_chemical_formula_weight         1500.23

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -9.8046 9.8477 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.2128(4)
_cell_length_b                   16.0056(7)
_cell_length_c                   18.6715(9)
_cell_angle_alpha                78.035(4)
_cell_angle_beta                 75.762(4)
_cell_angle_gamma                72.617(4)
_cell_volume                     3067.0(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    106.8(2)
_cell_measurement_reflns_used    9445
_cell_measurement_theta_min      4.211
_cell_measurement_theta_max      73.106

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.624
_exptl_crystal_F_000             1500
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.05
_exptl_absorpt_coefficient_mu    13.456
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7369
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      106.8(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   'SuperNova (Cu) X-ray Source'
_diffrn_measurement_device_type  
'Oxford Diffraction SuperNova with Atlas CCD detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 10.4223
_diffrn_reflns_number            20441
_diffrn_reflns_av_unetI/netI     0.0472
_diffrn_reflns_av_R_equivalents  0.0323
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.543
_diffrn_reflns_theta_max         67.495
_diffrn_reflns_theta_full        67.495
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             11046
_reflns_number_gt                9621
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_structure_solution    'SHELXT-2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    
;
PLATON (Spek, 2009); MERCURY (Macrae et al. 2020);
DIAMOND (Brandenburg, 2005)
;
_computing_publication_material  'WINGX (Farrugia, 2012)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0493P)²+4.0531P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         11046
_refine_ls_number_parameters     825
_refine_ls_number_restraints     44
_refine_ls_R_factor_all          0.0454
_refine_ls_R_factor_gt           0.0382
_refine_ls_wR_factor_ref         0.1022
_refine_ls_wR_factor_gt          0.0969
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.50843(2) 0.66277(2) 0.73718(2) 0.02264(7) Uani 1 1 d . . . . .
Dy2 Dy 0.83799(2) 0.65555(2) 0.70603(2) 0.02344(8) Uani 1 1 d . . . . .
O1 O 0.6931(3) 0.63798(19) 0.64251(15) 0.0231(6) Uani 1 1 d . . . . .
O2 O 0.4820(3) 0.7731(2) 0.62734(16) 0.0260(6) Uani 1 1 d . . . . .
O3 O 0.4601(3) 0.5770(2) 0.66916(17) 0.0303(7) Uani 1 1 d . . . . .
O4 O 0.4444(4) 0.5421(2) 0.8171(2) 0.0413(8) Uani 1 1 d . . . . .
O5 O 0.2960(3) 0.7233(2) 0.75599(17) 0.0297(7) Uani 1 1 d . . . . .
O6 O 0.4404(3) 0.7175(2) 0.85120(16) 0.0268(6) Uani 1 1 d . . . . .
O7 O 0.6911(3) 0.5801(2) 0.78649(16) 0.0279(6) Uani 1 1 d . . . . .
O8 O 0.9147(3) 0.4987(2) 0.70476(16) 0.0296(7) Uani 1 1 d . . . . .
O9 O 0.8161(3) 0.6955(2) 0.82431(17) 0.0338(7) Uani 1 1 d . . . . .
O10 O 0.6407(3) 0.75739(19) 0.73459(15) 0.0240(6) Uani 1 1 d . . . . .
O11 O 0.8850(3) 0.7875(2) 0.66349(17) 0.0312(7) Uani 1 1 d . . . . .
O12 O 0.9532(3) 0.6540(2) 0.58646(16) 0.0308(7) Uani 1 1 d . . . . .
C1 C 0.5423(5) 0.8756(3) 0.5266(3) 0.0403(11) Uani 1 1 d . . . . .
H1A H 0.5916 0.8750 0.4766 0.060 Uiso 1 1 calc R U . . .
H1B H 0.5776 0.9027 0.5547 0.060 Uiso 1 1 calc R U . . .
H1C H 0.4558 0.9086 0.5249 0.060 Uiso 1 1 calc R U . . .
C2 C 0.5450(4) 0.7819(3) 0.5633(2) 0.0255(9) Uani 1 1 d . . . . .
C3 C 0.6264(4) 0.7054(3) 0.5273(2) 0.0256(9) Uani 1 1 d . . . . .
C4 C 0.6402(4) 0.7010(3) 0.4491(2) 0.0285(9) Uani 1 1 d . . . . .
C5 C 0.5661(5) 0.7651(4) 0.4019(3) 0.0368(11) Uani 1 1 d . . . . .
H5 H 0.5038 0.8122 0.4216 0.044 Uiso 1 1 calc R U . . .
C6 C 0.5847(5) 0.7588(4) 0.3268(3) 0.0448(13) Uani 1 1 d . . . . .
H6 H 0.5366 0.8027 0.2964 0.054 Uiso 1 1 calc R U . . .
C7 C 0.6748(5) 0.6877(4) 0.2962(3) 0.0473(14) Uani 1 1 d . . . . .
H7 H 0.6886 0.6847 0.2455 0.057 Uiso 1 1 calc R U . . .
C8 C 0.7427(5) 0.6222(4) 0.3416(3) 0.0398(12) Uani 1 1 d . . . . .
H8 H 0.7998 0.5732 0.3219 0.048 Uiso 1 1 calc R U . . .
C9 C 0.7276(4) 0.6278(3) 0.4183(2) 0.0317(10) Uani 1 1 d . . . . .
C10 C 0.8006(5) 0.5592(3) 0.4640(3) 0.0336(10) Uani 1 1 d . . . . .
H10 H 0.8587 0.5112 0.4433 0.040 Uiso 1 1 calc R U . . .
C11 C 0.7860(4) 0.5634(3) 0.5376(2) 0.0290(9) Uani 1 1 d . . . . .
H11 H 0.8341 0.5177 0.5667 0.035 Uiso 1 1 calc R U . . .
C12 C 0.6985(4) 0.6363(3) 0.5713(2) 0.0240(8) Uani 1 1 d . . . . .
C13 C 0.4079(8) 0.4044(5) 0.8741(4) 0.0690(19) Uani 1 1 d . . . . .
H13A H 0.4096 0.3510 0.8577 0.103 Uiso 1 1 calc R U . . .
H13B H 0.3212 0.4360 0.8908 0.103 Uiso 1 1 calc R U . . .
H13C H 0.4529 0.3899 0.9145 0.103 Uiso 1 1 calc R U . . .
C14 C 0.4742(7) 0.4643(4) 0.8071(3) 0.0572(17) Uani 1 1 d . . . . .
C15 C 0.5393(5) 0.4348(3) 0.7362(4) 0.0473(14) Uani 1 1 d . . . . .
C16 C 0.6144(5) 0.3447(4) 0.7315(4) 0.0562(14) Uani 1 1 d . U . . .
C17 C 0.6473(6) 0.2875(4) 0.7970(5) 0.0738(19) Uani 1 1 d . U . . .
H17 H 0.6194 0.3064 0.8436 0.089 Uiso 1 1 calc R U . . .
C18 C 0.7226(7) 0.2024(5) 0.7887(6) 0.092(2) Uani 1 1 d . U . . .
H18 H 0.7477 0.1649 0.8306 0.111 Uiso 1 1 calc R U . . .
C19 C 0.7622(7) 0.1706(5) 0.7205(6) 0.0795(19) Uani 1 1 d D U . . .
H19 H 0.8080 0.1120 0.7180 0.095 Uiso 1 1 calc R U . . .
C20 C 0.7344(7) 0.2247(5) 0.6582(6) 0.079(2) Uani 1 1 d D U . . .
H20 H 0.7634 0.2052 0.6118 0.095 Uiso 1 1 calc R U . . .
C21 C 0.6589(7) 0.3129(4) 0.6651(5) 0.0706(18) Uani 1 1 d . U . . .
C22 C 0.6162(7) 0.3700(5) 0.6042(4) 0.0652(16) Uani 1 1 d . U . . .
H22 H 0.6382 0.3468 0.5596 0.078 Uiso 1 1 calc R U . . .
C23 C 0.5425(7) 0.4600(4) 0.6018(4) 0.0629(17) Uani 1 1 d . U . . .
H23 H 0.5161 0.4935 0.5588 0.076 Uiso 1 1 calc R U . . .
C24 C 0.5128(4) 0.4944(3) 0.6700(3) 0.0337(10) Uani 1 1 d . . . . .
C25 C 0.3551(5) 0.7912(4) 0.9550(3) 0.0393(11) Uani 1 1 d . . . . .
H25A H 0.2720 0.8233 0.9776 0.059 Uiso 1 1 calc R U . . .
H25B H 0.4159 0.8237 0.9520 0.059 Uiso 1 1 calc R U . . .
H25C H 0.3787 0.7344 0.9845 0.059 Uiso 1 1 calc R U . . .
C26 C 0.3528(4) 0.7787(3) 0.8772(2) 0.0280(9) Uani 1 1 d . . . . .
C27 C 0.2484(4) 0.8287(3) 0.8405(2) 0.0280(9) Uani 1 1 d . . . . .
C28 C 0.1629(4) 0.9110(3) 0.8623(3) 0.0339(10) Uani 1 1 d . . . . .
C29 C 0.1988(5) 0.9676(4) 0.8968(3) 0.0472(13) Uani 1 1 d . . . . .
H29 H 0.2803 0.9512 0.9071 0.057 Uiso 1 1 calc R U . . .
C30 C 0.1169(6) 1.0461(4) 0.9156(4) 0.0607(17) Uani 1 1 d . . . . .
H30 H 0.1426 1.0812 0.9396 0.073 Uiso 1 1 calc R U . . .
C31 C -0.0027(6) 1.0732(4) 0.8991(4) 0.0599(17) Uani 1 1 d . . . . .
H31 H -0.0586 1.1260 0.9128 0.072 Uiso 1 1 calc R U . . .
C32 C -0.0396(6) 1.0215(4) 0.8620(4) 0.0544(15) Uani 1 1 d . . . . .
H32 H -0.1201 1.0406 0.8499 0.065 Uiso 1 1 calc R U . . .
C33 C 0.0422(5) 0.9409(4) 0.8424(3) 0.0402(11) Uani 1 1 d . . . . .
C34 C 0.0076(4) 0.8895(3) 0.7995(3) 0.0373(11) Uani 1 1 d . . . . .
H34 H -0.0745 0.9067 0.7899 0.045 Uiso 1 1 calc R U . . .
C35 C 0.0908(4) 0.8177(3) 0.7728(2) 0.0325(10) Uani 1 1 d . . . . .
H35 H 0.0659 0.7872 0.7442 0.039 Uiso 1 1 calc R U . . .
C36 C 0.2192(4) 0.7871(3) 0.7880(2) 0.0276(9) Uani 1 1 d . . . . .
C37 C 0.9414(4) 0.3444(3) 0.7329(2) 0.0323(10) Uani 1 1 d . . . . .
H37A H 0.9268 0.3020 0.7765 0.048 Uiso 1 1 calc R U . . .
H37B H 1.0304 0.3304 0.7104 0.048 Uiso 1 1 calc R U . . .
H37C H 0.8926 0.3427 0.6979 0.048 Uiso 1 1 calc R U . . .
C38 C 0.9012(4) 0.4359(3) 0.7550(2) 0.0257(9) Uani 1 1 d . . . . .
C39 C 0.8373(4) 0.4501(3) 0.8316(2) 0.0247(8) Uani 1 1 d . . . . .
C40 C 0.8797(4) 0.3905(3) 0.8953(2) 0.0259(9) Uani 1 1 d . . . . .
C41 C 0.9998(4) 0.3276(3) 0.8906(3) 0.0310(9) Uani 1 1 d . . . . .
H41 H 1.0541 0.3222 0.8444 0.037 Uiso 1 1 calc R U . . .
C42 C 1.0371(5) 0.2750(3) 0.9526(3) 0.0389(11) Uani 1 1 d . . . . .
H42 H 1.1160 0.2336 0.9479 0.047 Uiso 1 1 calc R U . . .
C43 C 0.9592(5) 0.2819(4) 1.0232(3) 0.0432(12) Uani 1 1 d . . . . .
H43 H 0.9858 0.2448 1.0649 0.052 Uiso 1 1 calc R U . . .
C44 C 0.8437(4) 0.3434(4) 1.0309(2) 0.0359(11) Uani 1 1 d . . . . .
H44 H 0.7925 0.3490 1.0780 0.043 Uiso 1 1 calc R U . . .
C45 C 0.8018(4) 0.3987(3) 0.9670(2) 0.0313(10) Uani 1 1 d . . . . .
C46 C 0.6847(4) 0.4650(3) 0.9743(2) 0.0317(10) Uani 1 1 d . . . . .
H46 H 0.6314 0.4683 1.0210 0.038 Uiso 1 1 calc R U . . .
C47 C 0.6485(4) 0.5235(3) 0.9152(2) 0.0278(9) Uani 1 1 d . . . . .
H47 H 0.5717 0.5668 0.9221 0.033 Uiso 1 1 calc R U . . .
C48 C 0.7268(4) 0.5199(3) 0.8418(2) 0.0256(9) Uani 1 1 d . . . . .
C49 C 0.7185(5) 0.7276(4) 0.9447(3) 0.0421(12) Uani 1 1 d . . . . .
H49A H 0.6589 0.7762 0.9676 0.063 Uiso 1 1 calc R U . . .
H49B H 0.7977 0.7141 0.9611 0.063 Uiso 1 1 calc R U . . .
H49C H 0.6847 0.6767 0.9587 0.063 Uiso 1 1 calc R U . . .
C50 C 0.7407(4) 0.7522(3) 0.8608(2) 0.0316(10) Uani 1 1 d . . . . .
C51 C 0.6634(4) 0.8350(3) 0.8257(2) 0.0290(9) Uani 1 1 d . . . . .
C52 C 0.6261(5) 0.9170(4) 0.8561(3) 0.0353(11) Uani 1 1 d . . . . .
C53 C 0.6848(5) 0.9315(4) 0.9102(3) 0.0452(13) Uani 1 1 d . . . . .
H53 H 0.7514 0.8871 0.9268 0.054 Uiso 1 1 calc R U . . .
C54 C 0.6436(6) 1.0110(5) 0.9383(3) 0.0554(17) Uani 1 1 d . . . . .
H54 H 0.6825 1.0190 0.9741 0.067 Uiso 1 1 calc R U . . .
C55 C 0.5468(7) 1.0783(5) 0.9144(3) 0.0587(18) Uani 1 1 d . . . . .
H55 H 0.5190 1.1305 0.9352 0.070 Uiso 1 1 calc R U . . .
C56 C 0.4909(6) 1.0694(4) 0.8603(3) 0.0474(14) Uani 1 1 d . . . . .
H56 H 0.4264 1.1157 0.8436 0.057 Uiso 1 1 calc R U . . .
C57 C 0.5314(5) 0.9886(3) 0.8293(3) 0.0375(11) Uani 1 1 d . . . . .
C58 C 0.4782(5) 0.9798(3) 0.7708(3) 0.0379(11) Uani 1 1 d . . . . .
H58 H 0.4153 1.0268 0.7533 0.045 Uiso 1 1 calc R U . . .
C59 C 0.5173(4) 0.9041(3) 0.7395(3) 0.0315(9) Uani 1 1 d . . . . .
H59 H 0.4819 0.9009 0.7003 0.038 Uiso 1 1 calc R U . . .
C60 C 0.6120(4) 0.8293(3) 0.7656(2) 0.0276(9) Uani 1 1 d . . . . .
C61 C 1.0441(6) 0.6741(4) 0.4602(3) 0.0484(13) Uani 1 1 d . . . . .
H61A H 1.0615 0.7222 0.4226 0.073 Uiso 1 1 calc R U . . .
H61B H 1.0037 0.6405 0.4412 0.073 Uiso 1 1 calc R U . . .
H61C H 1.1226 0.6365 0.4730 0.073 Uiso 1 1 calc R U . . .
C62 C 0.9561(5) 0.7105(3) 0.5295(2) 0.0339(10) Uani 1 1 d . . . . .
C63 C 0.8950(4) 0.8028(4) 0.5313(3) 0.0355(11) Uani 1 1 d . . . . .
C64 C 0.8687(4) 0.8628(3) 0.4637(3) 0.0370(11) Uani 1 1 d . . . . .
C65 C 0.8610(5) 0.8349(4) 0.3989(3) 0.0426(12) Uani 1 1 d . . . . .
H65 H 0.8781 0.7747 0.3971 0.051 Uiso 1 1 calc R U . . .
C66 C 0.8278(5) 0.8961(4) 0.3369(3) 0.0527(15) Uani 1 1 d . . . . .
H66 H 0.8218 0.8764 0.2947 0.063 Uiso 1 1 calc R U . . .
C67 C 0.8042(6) 0.9853(5) 0.3381(3) 0.0554(16) Uani 1 1 d . . . . .
H67 H 0.7860 1.0253 0.2959 0.066 Uiso 1 1 calc R U . . .
C68 C 0.8073(6) 1.0150(4) 0.3995(4) 0.0593(17) Uani 1 1 d . . . . .
H68 H 0.7889 1.0756 0.3999 0.071 Uiso 1 1 calc R U . . .
C69 C 0.8387(6) 0.9542(4) 0.4651(3) 0.0476(13) Uani 1 1 d . . . . .
C70 C 0.8345(7) 0.9858(4) 0.5300(4) 0.0601(17) Uani 1 1 d . . . . .
H70 H 0.8184 1.0464 0.5296 0.072 Uiso 1 1 calc R U . . .
C71 C 0.8541(6) 0.9281(4) 0.5958(3) 0.0540(15) Uani 1 1 d . . . . .
H71 H 0.8518 0.9510 0.6382 0.065 Uiso 1 1 calc R U . . .
C72 C 0.8775(4) 0.8357(3) 0.5994(3) 0.0339(10) Uani 1 1 d . . . . .
C73 C 1.1065(5) 0.5738(4) 0.7903(3) 0.0406(11) Uani 1 1 d . . . . .
H73A H 1.0416 0.5821 0.8345 0.061 Uiso 1 1 calc R U . . .
H73B H 1.1724 0.6001 0.7915 0.061 Uiso 1 1 calc R U . . .
H73C H 1.1421 0.5117 0.7881 0.061 Uiso 1 1 calc R U . . .
O1M O 1.0515(3) 0.6152(2) 0.72530(18) 0.0344(7) Uani 1 1 d D . . . .
H1M H 1.114(4) 0.619(4) 0.689(2) 0.052 Uiso 1 1 d D U . . .
C74 C 0.2322(5) 0.7315(4) 0.5830(3) 0.0508(14) Uani 1 1 d . . . . .
H74A H 0.2983 0.7363 0.5397 0.076 Uiso 1 1 calc R U . . .
H74B H 0.2406 0.7617 0.6202 0.076 Uiso 1 1 calc R U . . .
H74C H 0.1505 0.7579 0.5693 0.076 Uiso 1 1 calc R U . . .
O2M O 0.2429(3) 0.6401(3) 0.6125(2) 0.0472(9) Uani 1 1 d D . . . .
H2M H 0.309(4) 0.621(5) 0.632(4) 0.071 Uiso 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O5 2.255(3) . ?
Dy1 O3 2.302(3) . ?
Dy1 O6 2.336(3) . ?
Dy1 O1 2.360(3) . ?
Dy1 O4 2.362(3) . ?
Dy1 O7 2.365(3) . ?
Dy1 O10 2.403(3) . ?
Dy1 O2 2.428(3) . ?
Dy1 Dy2 3.5669(3) . ?
Dy2 O11 2.266(3) . ?
Dy2 O12 2.289(3) . ?
Dy2 O10 2.337(3) . ?
Dy2 O1 2.342(3) . ?
Dy2 O9 2.360(3) . ?
Dy2 O7 2.376(3) . ?
Dy2 O1M 2.383(3) . ?
Dy2 O8 2.402(3) . ?
O1 C12 1.322(5) . ?
O2 C2 1.233(5) . ?
O3 C24 1.275(6) . ?
O4 C14 1.232(7) . ?
O5 C36 1.271(5) . ?
O6 C26 1.244(5) . ?
O7 C48 1.310(5) . ?
O8 C38 1.242(5) . ?
O9 C50 1.232(6) . ?
O10 C60 1.313(5) . ?
O11 C72 1.289(6) . ?
O12 C62 1.246(5) . ?
C1 C2 1.509(6) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2 C3 1.469(6) . ?
C3 C12 1.402(6) . ?
C3 C4 1.445(6) . ?
C4 C9 1.407(7) . ?
C4 C5 1.412(7) . ?
C5 C6 1.387(7) . ?
C5 H5 0.9300 . ?
C6 C7 1.394(9) . ?
C6 H6 0.9300 . ?
C7 C8 1.368(8) . ?
C7 H7 0.9300 . ?
C8 C9 1.418(6) . ?
C8 H8 0.9300 . ?
C9 C10 1.421(7) . ?
C10 C11 1.356(6) . ?
C10 H10 0.9300 . ?
C11 C12 1.428(6) . ?
C11 H11 0.9300 . ?
C13 C14 1.584(9) . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 C15 1.443(9) . ?
C15 C24 1.432(8) . ?
C15 C16 1.445(8) . ?
C16 C21 1.360(11) . ?
C16 C17 1.424(10) . ?
C17 C18 1.390(10) . ?
C17 H17 0.9300 . ?
C18 C19 1.390(13) . ?
C18 H18 0.9300 . ?
C19 C20 1.341(12) . ?
C19 H19 0.9300 . ?
C20 C21 1.427(10) . ?
C20 H20 0.9300 . ?
C21 C22 1.391(10) . ?
C22 C23 1.429(10) . ?
C22 H22 0.9300 . ?
C23 C24 1.416(8) . ?
C23 H23 0.9300 . ?
C25 C26 1.514(6) . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 C27 1.443(6) . ?
C27 C36 1.439(6) . ?
C27 C28 1.448(6) . ?
C28 C33 1.409(7) . ?
C28 C29 1.408(7) . ?
C29 C30 1.371(8) . ?
C29 H29 0.9300 . ?
C30 C31 1.371(9) . ?
C30 H30 0.9300 . ?
C31 C32 1.386(9) . ?
C31 H31 0.9300 . ?
C32 C33 1.401(8) . ?
C32 H32 0.9300 . ?
C33 C34 1.444(8) . ?
C34 C35 1.345(7) . ?
C34 H34 0.9300 . ?
C35 C36 1.455(6) . ?
C35 H35 0.9300 . ?
C37 C38 1.511(6) . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C38 C39 1.464(6) . ?
C39 C48 1.402(6) . ?
C39 C40 1.446(6) . ?
C40 C45 1.415(6) . ?
C40 C41 1.415(6) . ?
C41 C42 1.359(7) . ?
C41 H41 0.9300 . ?
C42 C43 1.396(7) . ?
C42 H42 0.9300 . ?
C43 C44 1.369(8) . ?
C43 H43 0.9300 . ?
C44 C45 1.419(6) . ?
C44 H44 0.9300 . ?
C45 C46 1.416(7) . ?
C46 C47 1.351(6) . ?
C46 H46 0.9300 . ?
C47 C48 1.435(6) . ?
C47 H47 0.9300 . ?
C49 C50 1.510(6) . ?
C49 H49A 0.9600 . ?
C49 H49B 0.9600 . ?
C49 H49C 0.9600 . ?
C50 C51 1.473(7) . ?
C51 C60 1.412(6) . ?
C51 C52 1.443(7) . ?
C52 C57 1.410(8) . ?
C52 C53 1.421(7) . ?
C53 C54 1.384(8) . ?
C53 H53 0.9300 . ?
C54 C55 1.371(10) . ?
C54 H54 0.9300 . ?
C55 C56 1.362(9) . ?
C55 H55 0.9300 . ?
C56 C57 1.430(7) . ?
C56 H56 0.9300 . ?
C57 C58 1.415(7) . ?
C58 C59 1.360(7) . ?
C58 H58 0.9300 . ?
C59 C60 1.432(7) . ?
C59 H59 0.9300 . ?
C61 C62 1.527(7) . ?
C61 H61A 0.9600 . ?
C61 H61B 0.9600 . ?
C61 H61C 0.9600 . ?
C62 C63 1.435(7) . ?
C63 C72 1.423(7) . ?
C63 C64 1.453(7) . ?
C64 C69 1.403(8) . ?
C64 C65 1.405(8) . ?
C65 C66 1.400(7) . ?
C65 H65 0.9300 . ?
C66 C67 1.376(9) . ?
C66 H66 0.9300 . ?
C67 C68 1.342(9) . ?
C67 H67 0.9300 . ?
C68 C69 1.444(8) . ?
C68 H68 0.9300 . ?
C69 C70 1.393(9) . ?
C70 C71 1.397(9) . ?
C70 H70 0.9300 . ?
C71 C72 1.414(7) . ?
C71 H71 0.9300 . ?
C73 O1M 1.443(6) . ?
C73 H73A 0.9600 . ?
C73 H73B 0.9600 . ?
C73 H73C 0.9600 . ?
O1M H1M 0.851(10) . ?
C74 O2M 1.432(7) . ?
C74 H74A 0.9600 . ?
C74 H74B 0.9600 . ?
C74 H74C 0.9600 . ?
O2M H2M 0.852(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Dy1 O3 82.52(11) . . ?
O5 Dy1 O6 70.62(10) . . ?
O3 Dy1 O6 141.43(11) . . ?
O5 Dy1 O1 142.54(10) . . ?
O3 Dy1 O1 78.54(10) . . ?
O6 Dy1 O1 138.66(10) . . ?
O5 Dy1 O4 81.89(12) . . ?
O3 Dy1 O4 69.98(12) . . ?
O6 Dy1 O4 79.03(12) . . ?
O1 Dy1 O4 120.29(12) . . ?
O5 Dy1 O7 149.07(10) . . ?
O3 Dy1 O7 108.92(11) . . ?
O6 Dy1 O7 84.18(10) . . ?
O1 Dy1 O7 68.30(10) . . ?
O4 Dy1 O7 75.79(11) . . ?
O5 Dy1 O10 117.15(11) . . ?
O3 Dy1 O10 144.78(10) . . ?
O6 Dy1 O10 73.65(10) . . ?
O1 Dy1 O10 68.30(10) . . ?
O4 Dy1 O10 137.76(11) . . ?
O7 Dy1 O10 69.99(10) . . ?
O5 Dy1 O2 76.84(10) . . ?
O3 Dy1 O2 83.22(10) . . ?
O6 Dy1 O2 115.44(10) . . ?
O1 Dy1 O2 69.10(10) . . ?
O4 Dy1 O2 147.66(11) . . ?
O7 Dy1 O2 131.87(10) . . ?
O10 Dy1 O2 74.32(10) . . ?
O5 Dy1 Dy2 157.48(8) . . ?
O3 Dy1 Dy2 115.11(8) . . ?
O6 Dy1 Dy2 98.82(7) . . ?
O1 Dy1 Dy2 40.47(7) . . ?
O4 Dy1 Dy2 116.42(9) . . ?
O7 Dy1 Dy2 41.33(7) . . ?
O10 Dy1 Dy2 40.49(7) . . ?
O2 Dy1 Dy2 90.87(7) . . ?
O11 Dy2 O12 70.91(11) . . ?
O11 Dy2 O10 77.11(11) . . ?
O12 Dy2 O10 121.79(11) . . ?
O11 Dy2 O1 110.84(11) . . ?
O12 Dy2 O1 78.04(10) . . ?
O10 Dy2 O1 69.70(10) . . ?
O11 Dy2 O9 83.46(11) . . ?
O12 Dy2 O9 146.14(11) . . ?
O10 Dy2 O9 70.91(11) . . ?
O1 Dy2 O9 133.23(10) . . ?
O11 Dy2 O7 146.07(11) . . ?
O12 Dy2 O7 136.91(11) . . ?
O10 Dy2 O7 70.93(10) . . ?
O1 Dy2 O7 68.40(10) . . ?
O9 Dy2 O7 75.70(11) . . ?
O11 Dy2 O1M 80.78(12) . . ?
O12 Dy2 O1M 77.99(11) . . ?
O10 Dy2 O1M 142.09(11) . . ?
O1 Dy2 O1M 147.88(11) . . ?
O9 Dy2 O1M 76.33(11) . . ?
O7 Dy2 O1M 118.73(11) . . ?
O11 Dy2 O8 144.88(11) . . ?
O12 Dy2 O8 80.20(11) . . ?
O10 Dy2 O8 136.79(10) . . ?
O1 Dy2 O8 81.21(10) . . ?
O9 Dy2 O8 112.88(11) . . ?
O7 Dy2 O8 68.91(10) . . ?
O1M Dy2 O8 73.89(12) . . ?
O11 Dy2 Dy1 115.24(8) . . ?
O12 Dy2 Dy1 118.10(8) . . ?
O10 Dy2 Dy1 41.88(7) . . ?
O1 Dy2 Dy1 40.84(7) . . ?
O9 Dy2 Dy1 92.45(8) . . ?
O7 Dy2 Dy1 41.10(7) . . ?
O1M Dy2 Dy1 159.64(8) . . ?
O8 Dy2 Dy1 95.64(7) . . ?
C12 O1 Dy2 132.5(2) . . ?
C12 O1 Dy1 127.1(2) . . ?
Dy2 O1 Dy1 98.69(10) . . ?
C2 O2 Dy1 134.1(3) . . ?
C24 O3 Dy1 123.1(3) . . ?
C14 O4 Dy1 128.4(4) . . ?
C36 O5 Dy1 135.5(3) . . ?
C26 O6 Dy1 135.5(3) . . ?
C48 O7 Dy1 142.0(3) . . ?
C48 O7 Dy2 120.0(3) . . ?
Dy1 O7 Dy2 97.57(10) . . ?
C38 O8 Dy2 130.6(3) . . ?
C50 O9 Dy2 135.4(3) . . ?
C60 O10 Dy2 129.3(3) . . ?
C60 O10 Dy1 129.0(2) . . ?
Dy2 O10 Dy1 97.63(10) . . ?
C72 O11 Dy2 128.3(3) . . ?
C62 O12 Dy2 133.8(3) . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
O2 C2 C3 121.8(4) . . ?
O2 C2 C1 116.3(4) . . ?
C3 C2 C1 121.7(4) . . ?
C12 C3 C4 119.6(4) . . ?
C12 C3 C2 117.2(4) . . ?
C4 C3 C2 123.1(4) . . ?
C9 C4 C5 117.7(4) . . ?
C9 C4 C3 119.0(4) . . ?
C5 C4 C3 123.2(4) . . ?
C6 C5 C4 121.0(5) . . ?
C6 C5 H5 119.5 . . ?
C4 C5 H5 119.5 . . ?
C5 C6 C7 120.8(5) . . ?
C5 C6 H6 119.6 . . ?
C7 C6 H6 119.6 . . ?
C8 C7 C6 119.2(5) . . ?
C8 C7 H7 120.4 . . ?
C6 C7 H7 120.4 . . ?
C7 C8 C9 121.2(5) . . ?
C7 C8 H8 119.4 . . ?
C9 C8 H8 119.4 . . ?
C4 C9 C8 120.0(5) . . ?
C4 C9 C10 120.2(4) . . ?
C8 C9 C10 119.9(5) . . ?
C11 C10 C9 120.4(4) . . ?
C11 C10 H10 119.8 . . ?
C9 C10 H10 119.8 . . ?
C10 C11 C12 121.4(4) . . ?
C10 C11 H11 119.3 . . ?
C12 C11 H11 119.3 . . ?
O1 C12 C3 122.3(4) . . ?
O1 C12 C11 118.3(4) . . ?
C3 C12 C11 119.3(4) . . ?
C14 C13 H13A 109.5 . . ?
C14 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C14 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
O4 C14 C15 123.4(5) . . ?
O4 C14 C13 112.4(6) . . ?
C15 C14 C13 123.0(5) . . ?
C24 C15 C14 117.5(5) . . ?
C24 C15 C16 120.3(6) . . ?
C14 C15 C16 121.6(6) . . ?
C21 C16 C17 118.2(6) . . ?
C21 C16 C15 121.7(6) . . ?
C17 C16 C15 120.0(7) . . ?
C18 C17 C16 117.4(9) . . ?
C18 C17 H17 121.3 . . ?
C16 C17 H17 121.3 . . ?
C19 C18 C17 123.0(8) . . ?
C19 C18 H18 118.5 . . ?
C17 C18 H18 118.5 . . ?
C20 C19 C18 119.9(7) . . ?
C20 C19 H19 120.0 . . ?
C18 C19 H19 120.0 . . ?
C19 C20 C21 118.1(9) . . ?
C19 C20 H20 121.0 . . ?
C21 C20 H20 121.0 . . ?
C16 C21 C22 115.2(6) . . ?
C16 C21 C20 123.3(8) . . ?
C22 C21 C20 121.2(8) . . ?
C21 C22 C23 127.9(7) . . ?
C21 C22 H22 116.1 . . ?
C23 C22 H22 116.1 . . ?
C24 C23 C22 114.9(7) . . ?
C24 C23 H23 122.6 . . ?
C22 C23 H23 122.6 . . ?
O3 C24 C23 117.7(5) . . ?
O3 C24 C15 123.5(5) . . ?
C23 C24 C15 118.8(5) . . ?
C26 C25 H25A 109.5 . . ?
C26 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C26 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
O6 C26 C27 123.5(4) . . ?
O6 C26 C25 114.8(4) . . ?
C27 C26 C25 121.4(4) . . ?
C36 C27 C26 117.1(4) . . ?
C36 C27 C28 119.5(4) . . ?
C26 C27 C28 122.9(4) . . ?
C33 C28 C29 117.5(5) . . ?
C33 C28 C27 119.3(5) . . ?
C29 C28 C27 122.9(5) . . ?
C30 C29 C28 121.9(6) . . ?
C30 C29 H29 119.1 . . ?
C28 C29 H29 119.1 . . ?
C29 C30 C31 120.4(6) . . ?
C29 C30 H30 119.8 . . ?
C31 C30 H30 119.8 . . ?
C30 C31 C32 119.5(6) . . ?
C30 C31 H31 120.2 . . ?
C32 C31 H31 120.2 . . ?
C31 C32 C33 121.1(6) . . ?
C31 C32 H32 119.4 . . ?
C33 C32 H32 119.4 . . ?
C32 C33 C28 119.4(5) . . ?
C32 C33 C34 121.4(5) . . ?
C28 C33 C34 119.2(5) . . ?
C35 C34 C33 121.9(5) . . ?
C35 C34 H34 119.0 . . ?
C33 C34 H34 119.0 . . ?
C34 C35 C36 120.9(5) . . ?
C34 C35 H35 119.5 . . ?
C36 C35 H35 119.5 . . ?
O5 C36 C27 124.8(4) . . ?
O5 C36 C35 117.5(4) . . ?
C27 C36 C35 117.7(4) . . ?
C38 C37 H37A 109.5 . . ?
C38 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C38 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
O8 C38 C39 121.7(4) . . ?
O8 C38 C37 117.5(4) . . ?
C39 C38 C37 120.5(4) . . ?
C48 C39 C40 120.2(4) . . ?
C48 C39 C38 118.0(4) . . ?
C40 C39 C38 121.7(4) . . ?
C45 C40 C41 117.7(4) . . ?
C45 C40 C39 118.9(4) . . ?
C41 C40 C39 123.3(4) . . ?
C42 C41 C40 121.1(4) . . ?
C42 C41 H41 119.4 . . ?
C40 C41 H41 119.4 . . ?
C41 C42 C43 121.2(5) . . ?
C41 C42 H42 119.4 . . ?
C43 C42 H42 119.4 . . ?
C44 C43 C42 119.9(4) . . ?
C44 C43 H43 120.1 . . ?
C42 C43 H43 120.1 . . ?
C43 C44 C45 120.1(4) . . ?
C43 C44 H44 119.9 . . ?
C45 C44 H44 119.9 . . ?
C40 C45 C44 120.0(4) . . ?
C40 C45 C46 119.2(4) . . ?
C44 C45 C46 120.8(4) . . ?
C47 C46 C45 121.7(4) . . ?
C47 C46 H46 119.1 . . ?
C45 C46 H46 119.1 . . ?
C46 C47 C48 121.0(4) . . ?
C46 C47 H47 119.5 . . ?
C48 C47 H47 119.5 . . ?
O7 C48 C39 122.3(4) . . ?
O7 C48 C47 119.2(4) . . ?
C39 C48 C47 118.5(4) . . ?
C50 C49 H49A 109.5 . . ?
C50 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C50 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
O9 C50 C51 122.4(4) . . ?
O9 C50 C49 116.3(5) . . ?
C51 C50 C49 120.8(4) . . ?
C60 C51 C52 119.8(4) . . ?
C60 C51 C50 117.1(4) . . ?
C52 C51 C50 122.7(4) . . ?
C57 C52 C53 117.2(5) . . ?
C57 C52 C51 119.6(4) . . ?
C53 C52 C51 123.1(5) . . ?
C54 C53 C52 120.6(6) . . ?
C54 C53 H53 119.7 . . ?
C52 C53 H53 119.7 . . ?
C55 C54 C53 121.3(6) . . ?
C55 C54 H54 119.3 . . ?
C53 C54 H54 119.3 . . ?
C54 C55 C56 120.5(6) . . ?
C54 C55 H55 119.8 . . ?
C56 C55 H55 119.8 . . ?
C55 C56 C57 120.0(6) . . ?
C55 C56 H56 120.0 . . ?
C57 C56 H56 120.0 . . ?
C52 C57 C58 119.2(4) . . ?
C52 C57 C56 120.2(5) . . ?
C58 C57 C56 120.5(5) . . ?
C59 C58 C57 121.4(5) . . ?
C59 C58 H58 119.3 . . ?
C57 C58 H58 119.3 . . ?
C58 C59 C60 121.3(5) . . ?
C58 C59 H59 119.3 . . ?
C60 C59 H59 119.3 . . ?
O10 C60 C51 123.7(4) . . ?
O10 C60 C59 117.7(4) . . ?
C51 C60 C59 118.5(4) . . ?
C62 C61 H61A 109.5 . . ?
C62 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C62 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
O12 C62 C63 122.8(4) . . ?
O12 C62 C61 113.5(5) . . ?
C63 C62 C61 123.2(4) . . ?
C72 C63 C62 117.3(4) . . ?
C72 C63 C64 120.8(5) . . ?
C62 C63 C64 121.3(5) . . ?
C69 C64 C65 117.7(5) . . ?
C69 C64 C63 118.5(5) . . ?
C65 C64 C63 123.6(5) . . ?
C66 C65 C64 121.2(6) . . ?
C66 C65 H65 119.4 . . ?
C64 C65 H65 119.4 . . ?
C67 C66 C65 120.2(6) . . ?
C67 C66 H66 119.9 . . ?
C65 C66 H66 119.9 . . ?
C68 C67 C66 120.6(6) . . ?
C68 C67 H67 119.7 . . ?
C66 C67 H67 119.7 . . ?
C67 C68 C69 120.8(6) . . ?
C67 C68 H68 119.6 . . ?
C69 C68 H68 119.6 . . ?
C70 C69 C64 120.2(5) . . ?
C70 C69 C68 120.3(6) . . ?
C64 C69 C68 119.4(6) . . ?
C69 C70 C71 121.1(5) . . ?
C69 C70 H70 119.4 . . ?
C71 C70 H70 119.4 . . ?
C70 C71 C72 121.4(6) . . ?
C70 C71 H71 119.3 . . ?
C72 C71 H71 119.3 . . ?
O11 C72 C71 117.6(5) . . ?
O11 C72 C63 125.1(4) . . ?
C71 C72 C63 117.3(5) . . ?
O1M C73 H73A 109.5 . . ?
O1M C73 H73B 109.5 . . ?
H73A C73 H73B 109.5 . . ?
O1M C73 H73C 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
C73 O1M Dy2 132.1(3) . . ?
C73 O1M H1M 106(4) . . ?
Dy2 O1M H1M 122(4) . . ?
O2M C74 H74A 109.5 . . ?
O2M C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
O2M C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C74 O2M H2M 107(5) . . ?

_refine_diff_density_max         1.892
_refine_diff_density_min         -0.670
_refine_diff_density_rms         0.094


# start Validation Reply Form
_vrf_PLAT154_1                   
;
RESPONSE: Provided data is correct. Unrounded su's show slight differences.
;
_vrf_PLAT094_1                   
;
RESPONSE: The maximum residual density is located close to a highly 
disordered naphthalene ring of a ligand. 
;
# end Validation Reply Form





_exptl_crystal_preparation       'Magnetic properties'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 2101336'
loop_
_audit_author_name
_audit_author_address
'Vassilios Nastopoulos'
;University of Patras
Greece
;
_audit_update_record             
;
2021-08-04 deposited with the CCDC.	2022-01-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C73 H58 Dy0.14 O13 Y1.86, C H4 O'
_chemical_formula_sum            'C74 H62 Dy0.14 O14 Y1.86'
_chemical_formula_weight         1363.18

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Y Y -0.2670 2.0244 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -9.8046 9.8477 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.1868(4)
_cell_length_b                   16.0404(6)
_cell_length_c                   18.6620(6)
_cell_angle_alpha                78.186(3)
_cell_angle_beta                 75.862(3)
_cell_angle_gamma                72.605(3)
_cell_volume                     3067.2(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    107.7(6)
_cell_measurement_reflns_used    8989
_cell_measurement_theta_min      4.406
_cell_measurement_theta_max      73.288

_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.476
_exptl_crystal_F_000             1399
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.03
_exptl_absorpt_coefficient_mu    3.813
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8694
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      107.7(6)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_source                   'SuperNova (Cu) X-ray Source'
_diffrn_measurement_device_type  
'Oxford Diffraction SuperNova with Atlas CCD detector'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 10.4223
_diffrn_reflns_number            20366
_diffrn_reflns_av_unetI/netI     0.0575
_diffrn_reflns_av_R_equivalents  0.0391
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         3.543
_diffrn_reflns_theta_max         67.498
_diffrn_reflns_theta_full        67.498
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             11053
_reflns_number_gt                9158
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_structure_solution    'SHELXT-2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    
;
PLATON (Spek, 2009); MERCURY (Macrae et al. 2020);
DIAMOND (Brandenburg, 2005)
;
_computing_publication_material  'WINGX (Farrugia, 2012)'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0593P)²+2.8237P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         11053
_refine_ls_number_parameters     827
_refine_ls_number_restraints     50
_refine_ls_R_factor_all          0.0560
_refine_ls_R_factor_gt           0.0444
_refine_ls_wR_factor_ref         0.1225
_refine_ls_wR_factor_gt          0.1129
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_restrained_S_all      1.022
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Y1 Y 0.50870(9) 0.66226(9) 0.73810(6) 0.02217(9) Uani 0.922(4) 1 d . . P . .
Dy1 Dy 0.5046(8) 0.6685(8) 0.7304(5) 0.02217(9) Uani 0.078(4) 1 d . . P . .
Y2 Y 0.83680(6) 0.65653(6) 0.70672(5) 0.02217(9) Uani 0.940(4) 1 d . . P . .
Dy2 Dy 0.8367(7) 0.6417(7) 0.7013(6) 0.02217(9) Uani 0.060(4) 1 d . . P . .
O1 O 0.6930(2) 0.63801(17) 0.64349(13) 0.0250(5) Uani 1 1 d . . . . .
O2 O 0.4819(2) 0.77267(17) 0.62879(14) 0.0273(5) Uani 1 1 d . . . . .
O3 O 0.4594(3) 0.57869(17) 0.66960(15) 0.0305(6) Uani 1 1 d . . . . .
O4 O 0.4426(3) 0.54382(19) 0.81705(16) 0.0380(7) Uani 1 1 d . . . . .
O5 O 0.2962(2) 0.72360(18) 0.75530(15) 0.0308(6) Uani 1 1 d . . . . .
O6 O 0.4407(2) 0.71672(17) 0.85093(14) 0.0288(6) Uani 1 1 d . . . . .
O7 O 0.6894(2) 0.58051(17) 0.78628(14) 0.0284(6) Uani 1 1 d . . . . .
O8 O 0.9144(2) 0.49934(17) 0.70466(14) 0.0300(6) Uani 1 1 d . . . . .
O9 O 0.8161(2) 0.69397(19) 0.82416(14) 0.0335(6) Uani 1 1 d . . . . .
O10 O 0.6402(2) 0.75665(17) 0.73496(14) 0.0269(5) Uani 1 1 d . . . . .
O11 O 0.8834(3) 0.78703(18) 0.66412(15) 0.0331(6) Uani 1 1 d . . . . .
O12 O 0.9522(2) 0.65330(18) 0.58756(14) 0.0309(6) Uani 1 1 d . . . . .
C1 C 0.5418(4) 0.8756(3) 0.5273(3) 0.0400(10) Uani 1 1 d . . . . .
H1A H 0.5959 0.8743 0.4787 0.060 Uiso 1 1 calc R U . . .
H1B H 0.5720 0.9044 0.5569 0.060 Uiso 1 1 calc R U . . .
H1C H 0.4559 0.9074 0.5225 0.060 Uiso 1 1 calc R U . . .
C2 C 0.5444(3) 0.7825(3) 0.5647(2) 0.0282(8) Uani 1 1 d . . . . .
C3 C 0.6262(3) 0.7060(2) 0.5279(2) 0.0266(7) Uani 1 1 d . . . . .
C4 C 0.6395(4) 0.7016(3) 0.4499(2) 0.0307(8) Uani 1 1 d . . . . .
C5 C 0.5656(4) 0.7662(3) 0.4021(2) 0.0357(9) Uani 1 1 d . . . . .
H5 H 0.5034 0.8133 0.4218 0.043 Uiso 1 1 calc R U . . .
C6 C 0.5840(4) 0.7605(3) 0.3273(2) 0.0454(11) Uani 1 1 d . . . . .
H6 H 0.5366 0.8049 0.2969 0.054 Uiso 1 1 calc R U . . .
C7 C 0.6736(4) 0.6886(4) 0.2966(2) 0.0461(11) Uani 1 1 d . . . . .
H7 H 0.6862 0.6854 0.2460 0.055 Uiso 1 1 calc R U . . .
C8 C 0.7428(4) 0.6227(3) 0.3417(2) 0.0425(10) Uani 1 1 d . . . . .
H8 H 0.8004 0.5740 0.3217 0.051 Uiso 1 1 calc R U . . .
C9 C 0.7272(4) 0.6283(3) 0.4182(2) 0.0322(8) Uani 1 1 d . . . . .
C10 C 0.7987(4) 0.5600(3) 0.4646(2) 0.0356(9) Uani 1 1 d . . . . .
H10 H 0.8560 0.5114 0.4443 0.043 Uiso 1 1 calc R U . . .
C11 C 0.7851(4) 0.5642(3) 0.5375(2) 0.0309(8) Uani 1 1 d . . . . .
H11 H 0.8338 0.5187 0.5664 0.037 Uiso 1 1 calc R U . . .
C12 C 0.6979(3) 0.6368(2) 0.5716(2) 0.0260(7) Uani 1 1 d . . . . .
C13 C 0.4070(6) 0.4064(4) 0.8735(3) 0.0632(15) Uani 1 1 d . . . . .
H13A H 0.4124 0.3520 0.8575 0.095 Uiso 1 1 calc R U . . .
H13B H 0.3189 0.4367 0.8889 0.095 Uiso 1 1 calc R U . . .
H13C H 0.4499 0.3942 0.9147 0.095 Uiso 1 1 calc R U . . .
C14 C 0.4717(5) 0.4657(3) 0.8077(3) 0.0470(12) Uani 1 1 d . . . . .
C15 C 0.5385(4) 0.4360(3) 0.7356(3) 0.0431(11) Uani 1 1 d . . . . .
C16 C 0.6128(4) 0.3459(3) 0.7305(3) 0.0511(13) Uani 1 1 d . U . . .
C17 C 0.6475(5) 0.2883(4) 0.7955(4) 0.074(2) Uani 1 1 d . U . . .
H17 H 0.6206 0.3075 0.8420 0.089 Uiso 1 1 calc R U . . .
C18 C 0.7219(6) 0.2032(4) 0.7881(4) 0.088(2) Uani 1 1 d . U . . .
H18 H 0.7462 0.1658 0.8302 0.106 Uiso 1 1 calc R U . . .
C19 C 0.7619(5) 0.1716(4) 0.7190(4) 0.078(2) Uani 1 1 d . U . . .
H19 H 0.8077 0.1132 0.7158 0.094 Uiso 1 1 calc R U . . .
C20 C 0.7326(6) 0.2275(3) 0.6571(4) 0.0694(17) Uani 1 1 d . U . . .
H20 H 0.7622 0.2084 0.6106 0.083 Uiso 1 1 calc R U . . .
C21 C 0.6573(5) 0.3145(3) 0.6630(4) 0.0585(14) Uani 1 1 d . U . . .
C22 C 0.6159(6) 0.3729(4) 0.6019(3) 0.0639(14) Uani 1 1 d . U . . .
H22 H 0.6386 0.3511 0.5565 0.077 Uiso 1 1 calc R U . . .
C23 C 0.5433(6) 0.4612(3) 0.6019(3) 0.0627(15) Uani 1 1 d . U . . .
H23 H 0.5169 0.4955 0.5591 0.075 Uiso 1 1 calc R U . . .
C24 C 0.5124(4) 0.4954(3) 0.6704(2) 0.0325(8) Uani 1 1 d . . . . .
C25 C 0.3549(4) 0.7904(3) 0.9552(2) 0.0393(10) Uani 1 1 d . . . . .
H25A H 0.2713 0.8213 0.9783 0.059 Uiso 1 1 calc R U . . .
H25B H 0.4145 0.8239 0.9524 0.059 Uiso 1 1 calc R U . . .
H25C H 0.3805 0.7337 0.9842 0.059 Uiso 1 1 calc R U . . .
C26 C 0.3525(4) 0.7783(3) 0.8767(2) 0.0298(8) Uani 1 1 d . . . . .
C27 C 0.2483(4) 0.8282(3) 0.8400(2) 0.0292(8) Uani 1 1 d . . . . .
C28 C 0.1622(4) 0.9106(3) 0.8623(2) 0.0336(8) Uani 1 1 d . . . . .
C29 C 0.1991(5) 0.9668(3) 0.8972(3) 0.0492(11) Uani 1 1 d . . . . .
H29 H 0.2807 0.9504 0.9078 0.059 Uiso 1 1 calc R U . . .
C30 C 0.1162(5) 1.0455(4) 0.9157(3) 0.0617(15) Uani 1 1 d . . . . .
H30 H 0.1420 1.0805 0.9399 0.074 Uiso 1 1 calc R U . . .
C31 C -0.0038(5) 1.0731(3) 0.8993(3) 0.0582(14) Uani 1 1 d . . . . .
H31 H -0.0599 1.1254 0.9135 0.070 Uiso 1 1 calc R U . . .
C32 C -0.0406(5) 1.0221(3) 0.8612(3) 0.0513(12) Uani 1 1 d . . . . .
H32 H -0.1206 1.0418 0.8481 0.062 Uiso 1 1 calc R U . . .
C33 C 0.0418(4) 0.9409(3) 0.8421(3) 0.0409(10) Uani 1 1 d . . . . .
C34 C 0.0069(4) 0.8895(3) 0.7995(2) 0.0362(9) Uani 1 1 d . . . . .
H34 H -0.0758 0.9062 0.7905 0.043 Uiso 1 1 calc R U . . .
C35 C 0.0908(4) 0.8178(3) 0.7722(2) 0.0327(8) Uani 1 1 d . . . . .
H35 H 0.0660 0.7875 0.7432 0.039 Uiso 1 1 calc R U . . .
C36 C 0.2188(4) 0.7876(2) 0.7875(2) 0.0286(8) Uani 1 1 d . . . . .
C37 C 0.9405(4) 0.3459(3) 0.7317(2) 0.0324(8) Uani 1 1 d . . . . .
H37A H 0.9256 0.3034 0.7750 0.049 Uiso 1 1 calc R U . . .
H37B H 1.0297 0.3319 0.7093 0.049 Uiso 1 1 calc R U . . .
H37C H 0.8917 0.3446 0.6964 0.049 Uiso 1 1 calc R U . . .
C38 C 0.9003(3) 0.4371(3) 0.7545(2) 0.0271(8) Uani 1 1 d . . . . .
C39 C 0.8369(3) 0.4502(2) 0.8311(2) 0.0268(7) Uani 1 1 d . . . . .
C40 C 0.8795(4) 0.3902(3) 0.8945(2) 0.0287(8) Uani 1 1 d . . . . .
C41 C 0.9998(4) 0.3275(3) 0.8895(2) 0.0328(8) Uani 1 1 d . . . . .
H41 H 1.0543 0.3224 0.8433 0.039 Uiso 1 1 calc R U . . .
C42 C 1.0370(4) 0.2744(3) 0.9514(2) 0.0391(10) Uani 1 1 d . . . . .
H42 H 1.1159 0.2328 0.9466 0.047 Uiso 1 1 calc R U . . .
C43 C 0.9588(4) 0.2810(3) 1.0222(2) 0.0423(10) Uani 1 1 d . . . . .
H43 H 0.9850 0.2434 1.0638 0.051 Uiso 1 1 calc R U . . .
C44 C 0.8445(4) 0.3424(3) 1.0299(2) 0.0374(9) Uani 1 1 d . . . . .
H44 H 0.7935 0.3478 1.0771 0.045 Uiso 1 1 calc R U . . .
C45 C 0.8019(4) 0.3987(3) 0.9665(2) 0.0313(8) Uani 1 1 d . . . . .
C46 C 0.6841(4) 0.4650(3) 0.9742(2) 0.0309(8) Uani 1 1 d . . . . .
H46 H 0.6307 0.4683 1.0209 0.037 Uiso 1 1 calc R U . . .
C47 C 0.6482(3) 0.5234(3) 0.9151(2) 0.0283(8) Uani 1 1 d . . . . .
H47 H 0.5715 0.5669 0.9222 0.034 Uiso 1 1 calc R U . . .
C48 C 0.7260(4) 0.5197(2) 0.8416(2) 0.0274(8) Uani 1 1 d . . . . .
C49 C 0.7198(4) 0.7267(3) 0.9445(2) 0.0431(10) Uani 1 1 d . . . . .
H49A H 0.6589 0.7748 0.9675 0.065 Uiso 1 1 calc R U . . .
H49B H 0.7991 0.7146 0.9607 0.065 Uiso 1 1 calc R U . . .
H49C H 0.6878 0.6752 0.9587 0.065 Uiso 1 1 calc R U . . .
C50 C 0.7411(4) 0.7512(3) 0.8603(2) 0.0329(9) Uani 1 1 d . . . . .
C51 C 0.6642(4) 0.8335(3) 0.8259(2) 0.0311(8) Uani 1 1 d . . . . .
C52 C 0.6271(4) 0.9154(3) 0.8564(2) 0.0362(9) Uani 1 1 d . . . . .
C53 C 0.6862(5) 0.9300(4) 0.9106(2) 0.0451(11) Uani 1 1 d . . . . .
H53 H 0.7529 0.8857 0.9273 0.054 Uiso 1 1 calc R U . . .
C54 C 0.6455(5) 1.0094(4) 0.9384(3) 0.0570(15) Uani 1 1 d . . . . .
H54 H 0.6849 1.0173 0.9740 0.068 Uiso 1 1 calc R U . . .
C55 C 0.5478(5) 1.0771(4) 0.9147(3) 0.0560(13) Uani 1 1 d . . . . .
H55 H 0.5192 1.1291 0.9358 0.067 Uiso 1 1 calc R U . . .
C56 C 0.4934(5) 1.0674(3) 0.8602(3) 0.0501(12) Uani 1 1 d . . . . .
H56 H 0.4299 1.1139 0.8428 0.060 Uiso 1 1 calc R U . . .
C57 C 0.5320(4) 0.9876(3) 0.8297(2) 0.0390(10) Uani 1 1 d . . . . .
C58 C 0.4784(4) 0.9787(3) 0.7711(2) 0.0391(9) Uani 1 1 d . . . . .
H58 H 0.4154 1.0256 0.7536 0.047 Uiso 1 1 calc R U . . .
C59 C 0.5170(4) 0.9033(3) 0.7402(2) 0.0329(8) Uani 1 1 d . . . . .
H59 H 0.4811 0.9001 0.7012 0.039 Uiso 1 1 calc R U . . .
C60 C 0.6122(4) 0.8279(3) 0.7660(2) 0.0288(8) Uani 1 1 d . . . . .
C61 C 1.0423(5) 0.6734(3) 0.4618(2) 0.0444(10) Uani 1 1 d . . . . .
H61A H 1.0591 0.7213 0.4240 0.067 Uiso 1 1 calc R U . . .
H61B H 1.0018 0.6395 0.4432 0.067 Uiso 1 1 calc R U . . .
H61C H 1.1213 0.6363 0.4745 0.067 Uiso 1 1 calc R U . . .
C62 C 0.9551(4) 0.7099(3) 0.5305(2) 0.0321(8) Uani 1 1 d . . . . .
C63 C 0.8947(4) 0.8019(3) 0.5321(2) 0.0324(8) Uani 1 1 d . . . . .
C64 C 0.8684(4) 0.8629(3) 0.4647(2) 0.0354(9) Uani 1 1 d . . . . .
C65 C 0.8589(4) 0.8357(3) 0.3999(2) 0.0421(10) Uani 1 1 d . . . . .
H65 H 0.8742 0.7758 0.3984 0.051 Uiso 1 1 calc R U . . .
C66 C 0.8276(5) 0.8955(4) 0.3382(3) 0.0507(12) Uani 1 1 d . . . . .
H66 H 0.8217 0.8756 0.2960 0.061 Uiso 1 1 calc R U . . .
C67 C 0.8050(5) 0.9852(4) 0.3392(3) 0.0533(13) Uani 1 1 d . . . . .
H67 H 0.7862 1.0254 0.2972 0.064 Uiso 1 1 calc R U . . .
C68 C 0.8104(5) 1.0142(3) 0.4014(3) 0.0584(14) Uani 1 1 d . . . . .
H68 H 0.7940 1.0744 0.4021 0.070 Uiso 1 1 calc R U . . .
C69 C 0.8405(4) 0.9538(3) 0.4651(3) 0.0461(11) Uani 1 1 d . . . . .
C70 C 0.8374(5) 0.9849(3) 0.5317(3) 0.0559(13) Uani 1 1 d . . . . .
H70 H 0.8238 1.0450 0.5314 0.067 Uiso 1 1 calc R U . . .
C71 C 0.8540(5) 0.9279(3) 0.5964(3) 0.0501(12) Uani 1 1 d . . . . .
H71 H 0.8509 0.9508 0.6389 0.060 Uiso 1 1 calc R U . . .
C72 C 0.8758(4) 0.8352(3) 0.6006(2) 0.0336(9) Uani 1 1 d . . . . .
C73 C 1.1052(4) 0.5740(3) 0.7899(3) 0.0438(11) Uani 1 1 d . . . . .
H73A H 1.0486 0.5955 0.8338 0.066 Uiso 1 1 calc R U . . .
H73B H 1.1856 0.5870 0.7843 0.066 Uiso 1 1 calc R U . . .
H73C H 1.1183 0.5113 0.7948 0.066 Uiso 1 1 calc R U . . .
O1M O 1.0498(3) 0.6162(2) 0.72546(16) 0.0370(7) Uani 1 1 d . . . . .
H1M H 1.107(5) 0.615(4) 0.688(3) 0.055 Uiso 1 1 d . U . . .
C74 C 0.2315(4) 0.7322(3) 0.5836(3) 0.0474(11) Uani 1 1 d . . . . .
H74A H 0.3018 0.7371 0.5430 0.071 Uiso 1 1 calc R U . . .
H74B H 0.2329 0.7632 0.6222 0.071 Uiso 1 1 calc R U . . .
H74C H 0.1527 0.7575 0.5660 0.071 Uiso 1 1 calc R U . . .
O2M O 0.2418(3) 0.6420(2) 0.61255(19) 0.0464(8) Uani 1 1 d D . . . .
H2M H 0.310(3) 0.620(4) 0.630(3) 0.070 Uiso 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Y1 O5 2.254(3) . ?
Y1 O3 2.286(3) . ?
Y1 O6 2.313(3) . ?
Y1 O7 2.331(3) . ?
Y1 O1 2.354(3) . ?
Y1 O4 2.343(3) . ?
Y1 O10 2.390(3) . ?
Y1 O2 2.427(3) . ?
Y1 Dy2 3.490(7) . ?
Y1 Y2 3.5487(11) . ?
Dy1 O5 2.199(9) . ?
Dy1 O6 2.401(11) . ?
Dy1 O10 2.388(12) . ?
Dy1 O2 2.266(8) . ?
Dy1 O3 2.237(14) . ?
Dy1 O7 2.461(7) . ?
Dy1 O1 2.313(9) . ?
Dy1 O4 2.460(10) . ?
Dy1 Dy2 3.526(10) . ?
Dy1 Y2 3.585(9) . ?
Y2 O11 2.248(3) . ?
Y2 O12 2.284(3) . ?
Y2 O1 2.330(2) . ?
Y2 O10 2.315(3) . ?
Y2 O9 2.329(3) . ?
Y2 O1M 2.369(3) . ?
Y2 O7 2.383(3) . ?
Y2 O8 2.414(3) . ?
Dy2 O1 2.163(10) . ?
Dy2 O12 2.202(9) . ?
Dy2 O7 2.291(9) . ?
Dy2 O8 2.180(10) . ?
Dy2 O10 2.450(9) . ?
Dy2 O11 2.466(10) . ?
Dy2 O9 2.536(10) . ?
Dy2 O1M 2.434(9) . ?
O1 C12 1.333(4) . ?
O2 C2 1.235(5) . ?
O3 C24 1.289(5) . ?
O4 C14 1.235(6) . ?
O5 C36 1.278(5) . ?
O6 C26 1.249(5) . ?
O7 C48 1.319(4) . ?
O8 C38 1.237(5) . ?
O9 C50 1.232(5) . ?
O10 C60 1.307(5) . ?
O11 C72 1.282(5) . ?
O12 C62 1.250(5) . ?
C1 C2 1.509(5) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2 C3 1.477(5) . ?
C3 C12 1.399(5) . ?
C3 C4 1.440(5) . ?
C4 C9 1.416(6) . ?
C4 C5 1.423(6) . ?
C5 C6 1.379(6) . ?
C5 H5 0.9300 . ?
C6 C7 1.401(7) . ?
C6 H6 0.9300 . ?
C7 C8 1.374(7) . ?
C7 H7 0.9300 . ?
C8 C9 1.414(5) . ?
C8 H8 0.9300 . ?
C9 C10 1.421(6) . ?
C10 C11 1.346(5) . ?
C10 H10 0.9300 . ?
C11 C12 1.425(5) . ?
C11 H11 0.9300 . ?
C13 C14 1.561(7) . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 C15 1.467(7) . ?
C15 C24 1.416(6) . ?
C15 C16 1.445(6) . ?
C16 C21 1.376(8) . ?
C16 C17 1.425(8) . ?
C17 C18 1.385(8) . ?
C17 H17 0.9300 . ?
C18 C19 1.404(10) . ?
C18 H18 0.9300 . ?
C19 C20 1.353(9) . ?
C19 H19 0.9300 . ?
C20 C21 1.409(7) . ?
C20 H20 0.9300 . ?
C21 C22 1.398(8) . ?
C22 C23 1.406(8) . ?
C22 H22 0.9300 . ?
C23 C24 1.419(7) . ?
C23 H23 0.9300 . ?
C25 C26 1.524(5) . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 C27 1.441(5) . ?
C27 C36 1.429(5) . ?
C27 C28 1.454(5) . ?
C28 C33 1.406(6) . ?
C28 C29 1.415(6) . ?
C29 C30 1.376(7) . ?
C29 H29 0.9300 . ?
C30 C31 1.372(7) . ?
C30 H30 0.9300 . ?
C31 C32 1.387(8) . ?
C31 H31 0.9300 . ?
C32 C33 1.410(6) . ?
C32 H32 0.9300 . ?
C33 C34 1.440(6) . ?
C34 C35 1.351(6) . ?
C34 H34 0.9300 . ?
C35 C36 1.447(5) . ?
C35 H35 0.9300 . ?
C37 C38 1.512(5) . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C38 C39 1.459(5) . ?
C39 C48 1.401(5) . ?
C39 C40 1.447(5) . ?
C40 C45 1.419(5) . ?
C40 C41 1.414(5) . ?
C41 C42 1.362(6) . ?
C41 H41 0.9300 . ?
C42 C43 1.400(6) . ?
C42 H42 0.9300 . ?
C43 C44 1.358(6) . ?
C43 H43 0.9300 . ?
C44 C45 1.421(5) . ?
C44 H44 0.9300 . ?
C45 C46 1.421(6) . ?
C46 C47 1.351(5) . ?
C46 H46 0.9300 . ?
C47 C48 1.437(5) . ?
C47 H47 0.9300 . ?
C49 C50 1.518(5) . ?
C49 H49A 0.9600 . ?
C49 H49B 0.9600 . ?
C49 H49C 0.9600 . ?
C50 C51 1.463(6) . ?
C51 C60 1.410(5) . ?
C51 C52 1.443(6) . ?
C52 C57 1.416(6) . ?
C52 C53 1.425(6) . ?
C53 C54 1.381(7) . ?
C53 H53 0.9300 . ?
C54 C55 1.378(8) . ?
C54 H54 0.9300 . ?
C55 C56 1.361(7) . ?
C55 H55 0.9300 . ?
C56 C57 1.413(6) . ?
C56 H56 0.9300 . ?
C57 C58 1.419(6) . ?
C58 C59 1.354(6) . ?
C58 H58 0.9300 . ?
C59 C60 1.438(5) . ?
C59 H59 0.9300 . ?
C61 C62 1.516(6) . ?
C61 H61A 0.9600 . ?
C61 H61B 0.9600 . ?
C61 H61C 0.9600 . ?
C62 C63 1.431(6) . ?
C63 C72 1.430(6) . ?
C63 C64 1.458(5) . ?
C64 C69 1.398(7) . ?
C64 C65 1.405(6) . ?
C65 C66 1.383(6) . ?
C65 H65 0.9300 . ?
C66 C67 1.389(8) . ?
C66 H66 0.9300 . ?
C67 C68 1.357(8) . ?
C67 H67 0.9300 . ?
C68 C69 1.413(7) . ?
C68 H68 0.9300 . ?
C69 C70 1.419(7) . ?
C70 C71 1.372(7) . ?
C70 H70 0.9300 . ?
C71 C72 1.423(6) . ?
C71 H71 0.9300 . ?
C73 O1M 1.439(5) . ?
C73 H73A 0.9600 . ?
C73 H73B 0.9600 . ?
C73 H73C 0.9600 . ?
O1M H1M 0.83(6) . ?
C74 O2M 1.418(6) . ?
C74 H74A 0.9600 . ?
C74 H74B 0.9600 . ?
C74 H74C 0.9600 . ?
O2M H2M 0.855(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Y1 O3 81.90(10) . . ?
O5 Y1 O6 70.99(10) . . ?
O3 Y1 O6 141.47(11) . . ?
O5 Y1 O7 149.97(10) . . ?
O3 Y1 O7 109.25(11) . . ?
O6 Y1 O7 84.63(9) . . ?
O5 Y1 O1 141.66(10) . . ?
O3 Y1 O1 78.64(10) . . ?
O6 Y1 O1 138.75(10) . . ?
O7 Y1 O1 68.30(9) . . ?
O5 Y1 O4 81.81(11) . . ?
O3 Y1 O4 70.29(11) . . ?
O6 Y1 O4 78.99(11) . . ?
O7 Y1 O4 76.40(10) . . ?
O1 Y1 O4 121.01(11) . . ?
O5 Y1 O10 116.84(11) . . ?
O3 Y1 O10 144.31(10) . . ?
O6 Y1 O10 73.93(10) . . ?
O7 Y1 O10 70.48(9) . . ?
O1 Y1 O10 68.06(9) . . ?
O4 Y1 O10 138.61(10) . . ?
O5 Y1 O2 76.03(9) . . ?
O3 Y1 O2 82.83(9) . . ?
O6 Y1 O2 115.07(11) . . ?
O7 Y1 O2 131.85(10) . . ?
O1 Y1 O2 69.02(9) . . ?
O4 Y1 O2 147.25(10) . . ?
O10 Y1 O2 73.78(9) . . ?
O5 Y1 Dy2 160.76(17) . . ?
O3 Y1 Dy2 111.29(18) . . ?
O6 Y1 Dy2 102.47(19) . . ?
O7 Y1 Dy2 40.53(19) . . ?
O1 Y1 Dy2 37.46(17) . . ?
O4 Y1 Dy2 115.32(19) . . ?
O10 Y1 Dy2 44.55(17) . . ?
O2 Y1 Dy2 91.35(18) . . ?
O5 Y1 Y2 156.85(10) . . ?
O3 Y1 Y2 115.50(8) . . ?
O6 Y1 Y2 98.92(7) . . ?
O7 Y1 Y2 41.71(7) . . ?
O1 Y1 Y2 40.48(6) . . ?
O4 Y1 Y2 117.50(8) . . ?
O10 Y1 Y2 40.26(6) . . ?
O2 Y1 Y2 90.51(7) . . ?
Dy2 Y1 Y2 4.43(15) . . ?
O5 Dy1 O6 70.2(3) . . ?
O5 Dy1 O10 119.1(6) . . ?
O6 Dy1 O10 72.4(4) . . ?
O5 Dy1 O2 80.5(3) . . ?
O6 Dy1 O2 117.9(5) . . ?
O10 Dy1 O2 76.8(3) . . ?
O5 Dy1 O3 84.2(4) . . ?
O6 Dy1 O3 138.7(4) . . ?
O10 Dy1 O3 148.5(4) . . ?
O2 Dy1 O3 87.7(3) . . ?
O5 Dy1 O7 143.6(4) . . ?
O6 Dy1 O7 80.0(3) . . ?
O10 Dy1 O7 68.3(3) . . ?
O2 Dy1 O7 133.5(4) . . ?
O3 Dy1 O7 106.4(5) . . ?
O5 Dy1 O1 149.4(4) . . ?
O6 Dy1 O1 135.8(5) . . ?
O10 Dy1 O1 68.8(3) . . ?
O2 Dy1 O1 72.5(2) . . ?
O3 Dy1 O1 80.5(4) . . ?
O7 Dy1 O1 66.8(2) . . ?
O5 Dy1 O4 80.3(3) . . ?
O6 Dy1 O4 75.0(2) . . ?
O10 Dy1 O4 131.9(3) . . ?
O2 Dy1 O4 151.0(5) . . ?
O3 Dy1 O4 68.9(4) . . ?
O7 Dy1 O4 71.9(2) . . ?
O1 Dy1 O4 117.8(5) . . ?
O5 Dy1 Dy2 163.1(6) . . ?
O6 Dy1 Dy2 99.6(3) . . ?
O10 Dy1 Dy2 43.9(2) . . ?
O2 Dy1 Dy2 93.2(4) . . ?
O3 Dy1 Dy2 111.4(4) . . ?
O7 Dy1 Dy2 40.3(2) . . ?
O1 Dy1 Dy2 36.5(3) . . ?
O4 Dy1 Dy2 110.8(4) . . ?
O5 Dy1 Y2 158.7(6) . . ?
O6 Dy1 Y2 96.2(3) . . ?
O10 Dy1 Y2 39.61(14) . . ?
O2 Dy1 Y2 92.3(3) . . ?
O3 Dy1 Y2 115.7(4) . . ?
O7 Dy1 Y2 41.43(15) . . ?
O1 Dy1 Y2 39.62(15) . . ?
O4 Dy1 Y2 112.9(3) . . ?
O11 Y2 O12 71.22(10) . . ?
O11 Y2 O1 110.93(10) . . ?
O12 Y2 O1 77.82(9) . . ?
O11 Y2 O10 77.47(10) . . ?
O12 Y2 O10 122.16(10) . . ?
O1 Y2 O10 69.73(9) . . ?
O11 Y2 O9 84.43(11) . . ?
O12 Y2 O9 146.71(10) . . ?
O1 Y2 O9 133.49(9) . . ?
O10 Y2 O9 71.63(9) . . ?
O11 Y2 O1M 80.97(10) . . ?
O12 Y2 O1M 77.71(10) . . ?
O1 Y2 O1M 147.29(11) . . ?
O10 Y2 O1M 142.68(11) . . ?
O9 Y2 O1M 76.29(10) . . ?
O11 Y2 O7 146.58(10) . . ?
O12 Y2 O7 135.90(10) . . ?
O1 Y2 O7 67.84(9) . . ?
O10 Y2 O7 70.87(9) . . ?
O9 Y2 O7 75.82(10) . . ?
O1M Y2 O7 118.95(10) . . ?
O11 Y2 O8 144.61(10) . . ?
O12 Y2 O8 79.40(10) . . ?
O1 Y2 O8 80.68(9) . . ?
O10 Y2 O8 136.52(9) . . ?
O9 Y2 O8 112.35(10) . . ?
O1M Y2 O8 73.76(10) . . ?
O7 Y2 O8 68.73(9) . . ?
O11 Y2 Y1 115.59(8) . . ?
O12 Y2 Y1 118.13(7) . . ?
O1 Y2 Y1 41.00(6) . . ?
O10 Y2 Y1 41.85(7) . . ?
O9 Y2 Y1 92.52(7) . . ?
O1M Y2 Y1 159.39(8) . . ?
O7 Y2 Y1 40.61(6) . . ?
O8 Y2 Y1 95.31(7) . . ?
O11 Y2 Dy1 113.75(18) . . ?
O12 Y2 Dy1 116.02(17) . . ?
O1 Y2 Dy1 39.29(19) . . ?
O10 Y2 Dy1 41.1(2) . . ?
O9 Y2 Dy1 94.20(19) . . ?
O1M Y2 Dy1 161.97(14) . . ?
O7 Y2 Dy1 43.12(14) . . ?
O8 Y2 Dy1 96.5(2) . . ?
O1 Dy2 O12 83.2(4) . . ?
O1 Dy2 O7 72.3(2) . . ?
O12 Dy2 O7 148.7(5) . . ?
O1 Dy2 O8 90.0(4) . . ?
O12 Dy2 O8 86.5(3) . . ?
O7 Dy2 O8 74.5(3) . . ?
O1 Dy2 O10 70.0(3) . . ?
O12 Dy2 O10 119.8(5) . . ?
O7 Dy2 O10 70.1(2) . . ?
O8 Dy2 O10 143.1(4) . . ?
O1 Dy2 O11 108.9(4) . . ?
O12 Dy2 O11 68.6(3) . . ?
O7 Dy2 O11 137.6(4) . . ?
O8 Dy2 O11 145.8(3) . . ?
O10 Dy2 O11 71.0(3) . . ?
O1 Dy2 O9 131.1(3) . . ?
O12 Dy2 O9 137.7(4) . . ?
O7 Dy2 O9 73.5(3) . . ?
O8 Dy2 O9 113.1(5) . . ?
O10 Dy2 O9 66.0(2) . . ?
O11 Dy2 O9 75.9(3) . . ?
O1 Dy2 O1M 157.4(4) . . ?
O12 Dy2 O1M 77.9(2) . . ?
O7 Dy2 O1M 120.0(5) . . ?
O8 Dy2 O1M 76.7(3) . . ?
O10 Dy2 O1M 130.7(4) . . ?
O11 Dy2 O1M 75.5(3) . . ?
O9 Dy2 O1M 71.4(3) . . ?
O1 Dy2 Y1 41.45(14) . . ?
O12 Dy2 Y1 123.2(4) . . ?
O7 Dy2 Y1 41.39(14) . . ?
O8 Dy2 Y1 101.7(3) . . ?
O10 Dy2 Y1 43.19(13) . . ?
O11 Dy2 Y1 111.4(3) . . ?
O9 Dy2 Y1 90.4(2) . . ?
O1M Dy2 Y1 158.8(4) . . ?
O1 Dy2 Dy1 39.5(2) . . ?
O12 Dy2 Dy1 120.9(3) . . ?
O7 Dy2 Dy1 43.98(18) . . ?
O8 Dy2 Dy1 102.9(4) . . ?
O10 Dy2 Dy1 42.5(3) . . ?
O11 Dy2 Dy1 109.8(5) . . ?
O9 Dy2 Dy1 92.0(3) . . ?
O1M Dy2 Dy1 161.2(3) . . ?
C12 O1 Dy2 131.2(3) . . ?
C12 O1 Y2 132.6(2) . . ?
C12 O1 Y1 126.9(2) . . ?
Dy2 O1 Y1 101.1(2) . . ?
Y2 O1 Y1 98.52(9) . . ?
C12 O1 Dy1 123.7(3) . . ?
Dy2 O1 Dy1 103.9(4) . . ?
Y2 O1 Dy1 101.1(3) . . ?
C2 O2 Dy1 134.8(4) . . ?
C2 O2 Y1 134.6(2) . . ?
C24 O3 Y1 122.6(2) . . ?
C24 O3 Dy1 126.0(3) . . ?
C14 O4 Y1 128.8(3) . . ?
C14 O4 Dy1 128.1(4) . . ?
C36 O5 Dy1 136.2(4) . . ?
C36 O5 Y1 135.4(2) . . ?
C26 O6 Dy1 132.2(3) . . ?
C26 O6 Y1 135.4(2) . . ?
C48 O7 Dy2 119.7(3) . . ?
C48 O7 Y1 142.2(2) . . ?
Dy2 O7 Y1 98.1(3) . . ?
C48 O7 Y2 119.7(2) . . ?
Y1 O7 Y2 97.68(9) . . ?
C48 O7 Dy1 144.5(3) . . ?
Dy2 O7 Dy1 95.7(3) . . ?
Y2 O7 Dy1 95.5(2) . . ?
C38 O8 Dy2 131.8(3) . . ?
C38 O8 Y2 130.3(2) . . ?
C50 O9 Y2 134.6(2) . . ?
C50 O9 Dy2 136.7(3) . . ?
C60 O10 Dy1 129.1(3) . . ?
C60 O10 Y2 128.7(2) . . ?
Dy1 O10 Y2 99.3(3) . . ?
C60 O10 Dy2 134.5(3) . . ?
Dy1 O10 Dy2 93.6(3) . . ?
C60 O10 Y1 129.2(2) . . ?
Y2 O10 Y1 97.88(10) . . ?
Dy2 O10 Y1 92.3(2) . . ?
C72 O11 Y2 129.0(3) . . ?
C72 O11 Dy2 125.3(4) . . ?
C62 O12 Dy2 137.6(4) . . ?
C62 O12 Y2 133.2(3) . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
O2 C2 C3 121.3(3) . . ?
O2 C2 C1 117.5(4) . . ?
C3 C2 C1 121.0(3) . . ?
C12 C3 C4 119.5(3) . . ?
C12 C3 C2 117.0(3) . . ?
C4 C3 C2 123.5(3) . . ?
C9 C4 C5 116.9(4) . . ?
C9 C4 C3 119.6(4) . . ?
C5 C4 C3 123.5(4) . . ?
C6 C5 C4 121.5(4) . . ?
C6 C5 H5 119.2 . . ?
C4 C5 H5 119.2 . . ?
C5 C6 C7 120.6(4) . . ?
C5 C6 H6 119.7 . . ?
C7 C6 H6 119.7 . . ?
C8 C7 C6 119.7(4) . . ?
C8 C7 H7 120.2 . . ?
C6 C7 H7 120.2 . . ?
C7 C8 C9 120.5(4) . . ?
C7 C8 H8 119.7 . . ?
C9 C8 H8 119.7 . . ?
C8 C9 C4 120.7(4) . . ?
C8 C9 C10 120.4(4) . . ?
C4 C9 C10 118.9(3) . . ?
C11 C10 C9 121.1(4) . . ?
C11 C10 H10 119.4 . . ?
C9 C10 H10 119.4 . . ?
C10 C11 C12 121.6(4) . . ?
C10 C11 H11 119.2 . . ?
C12 C11 H11 119.2 . . ?
O1 C12 C3 122.5(3) . . ?
O1 C12 C11 118.2(3) . . ?
C3 C12 C11 119.2(3) . . ?
C14 C13 H13A 109.5 . . ?
C14 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C14 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
O4 C14 C15 122.5(4) . . ?
O4 C14 C13 113.4(5) . . ?
C15 C14 C13 123.0(4) . . ?
C24 C15 C16 120.6(5) . . ?
C24 C15 C14 117.2(4) . . ?
C16 C15 C14 121.6(4) . . ?
C21 C16 C17 118.1(5) . . ?
C21 C16 C15 121.4(5) . . ?
C17 C16 C15 120.5(6) . . ?
C18 C17 C16 118.8(7) . . ?
C18 C17 H17 120.6 . . ?
C16 C17 H17 120.6 . . ?
C17 C18 C19 122.0(6) . . ?
C17 C18 H18 119.0 . . ?
C19 C18 H18 119.0 . . ?
C20 C19 C18 118.9(5) . . ?
C20 C19 H19 120.5 . . ?
C18 C19 H19 120.5 . . ?
C19 C20 C21 120.1(7) . . ?
C19 C20 H20 119.9 . . ?
C21 C20 H20 119.9 . . ?
C16 C21 C22 115.4(5) . . ?
C16 C21 C20 121.9(6) . . ?
C22 C21 C20 122.6(6) . . ?
C21 C22 C23 126.7(6) . . ?
C21 C22 H22 116.7 . . ?
C23 C22 H22 116.7 . . ?
C22 C23 C24 116.6(6) . . ?
C22 C23 H23 121.7 . . ?
C24 C23 H23 121.7 . . ?
O3 C24 C15 124.0(4) . . ?
O3 C24 C23 117.6(4) . . ?
C15 C24 C23 118.4(4) . . ?
C26 C25 H25A 109.5 . . ?
C26 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C26 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
O6 C26 C27 123.8(3) . . ?
O6 C26 C25 114.4(3) . . ?
C27 C26 C25 121.5(3) . . ?
C36 C27 C26 117.4(3) . . ?
C36 C27 C28 119.3(3) . . ?
C26 C27 C28 122.7(4) . . ?
C33 C28 C29 117.7(4) . . ?
C33 C28 C27 119.3(4) . . ?
C29 C28 C27 122.7(4) . . ?
C30 C29 C28 121.1(5) . . ?
C30 C29 H29 119.5 . . ?
C28 C29 H29 119.5 . . ?
C31 C30 C29 121.1(5) . . ?
C31 C30 H30 119.5 . . ?
C29 C30 H30 119.5 . . ?
C30 C31 C32 119.4(5) . . ?
C30 C31 H31 120.3 . . ?
C32 C31 H31 120.3 . . ?
C31 C32 C33 120.7(5) . . ?
C31 C32 H32 119.6 . . ?
C33 C32 H32 119.6 . . ?
C28 C33 C32 119.8(5) . . ?
C28 C33 C34 119.0(4) . . ?
C32 C33 C34 121.1(4) . . ?
C35 C34 C33 122.0(4) . . ?
C35 C34 H34 119.0 . . ?
C33 C34 H34 119.0 . . ?
C34 C35 C36 120.6(4) . . ?
C34 C35 H35 119.7 . . ?
C36 C35 H35 119.7 . . ?
O5 C36 C27 124.4(3) . . ?
O5 C36 C35 117.4(3) . . ?
C27 C36 C35 118.2(4) . . ?
C38 C37 H37A 109.5 . . ?
C38 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C38 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
O8 C38 C39 122.2(3) . . ?
O8 C38 C37 117.3(3) . . ?
C39 C38 C37 120.3(3) . . ?
C48 C39 C40 120.2(3) . . ?
C48 C39 C38 117.6(3) . . ?
C40 C39 C38 121.9(3) . . ?
C45 C40 C41 117.8(3) . . ?
C45 C40 C39 118.8(3) . . ?
C41 C40 C39 123.2(4) . . ?
C42 C41 C40 120.9(4) . . ?
C42 C41 H41 119.5 . . ?
C40 C41 H41 119.5 . . ?
C41 C42 C43 121.3(4) . . ?
C41 C42 H42 119.3 . . ?
C43 C42 H42 119.3 . . ?
C44 C43 C42 119.7(4) . . ?
C44 C43 H43 120.2 . . ?
C42 C43 H43 120.2 . . ?
C43 C44 C45 120.7(4) . . ?
C43 C44 H44 119.7 . . ?
C45 C44 H44 119.7 . . ?
C40 C45 C44 119.6(4) . . ?
C40 C45 C46 119.3(3) . . ?
C44 C45 C46 121.1(4) . . ?
C47 C46 C45 121.4(4) . . ?
C47 C46 H46 119.3 . . ?
C45 C46 H46 119.3 . . ?
C46 C47 C48 121.4(4) . . ?
C46 C47 H47 119.3 . . ?
C48 C47 H47 119.3 . . ?
O7 C48 C39 122.5(3) . . ?
O7 C48 C47 119.0(3) . . ?
C39 C48 C47 118.5(3) . . ?
C50 C49 H49A 109.5 . . ?
C50 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C50 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
O9 C50 C51 123.2(4) . . ?
O9 C50 C49 115.8(4) . . ?
C51 C50 C49 120.6(4) . . ?
C60 C51 C52 119.7(4) . . ?
C60 C51 C50 116.7(4) . . ?
C52 C51 C50 123.0(4) . . ?
C57 C52 C53 116.7(4) . . ?
C57 C52 C51 119.9(4) . . ?
C53 C52 C51 123.3(4) . . ?
C54 C53 C52 120.6(5) . . ?
C54 C53 H53 119.7 . . ?
C52 C53 H53 119.7 . . ?
C55 C54 C53 121.7(5) . . ?
C55 C54 H54 119.2 . . ?
C53 C54 H54 119.2 . . ?
C56 C55 C54 119.4(5) . . ?
C56 C55 H55 120.3 . . ?
C54 C55 H55 120.3 . . ?
C55 C56 C57 121.0(5) . . ?
C55 C56 H56 119.5 . . ?
C57 C56 H56 119.5 . . ?
C52 C57 C56 120.3(4) . . ?
C52 C57 C58 118.8(4) . . ?
C56 C57 C58 120.9(5) . . ?
C59 C58 C57 121.3(4) . . ?
C59 C58 H58 119.3 . . ?
C57 C58 H58 119.3 . . ?
C58 C59 C60 121.9(4) . . ?
C58 C59 H59 119.1 . . ?
C60 C59 H59 119.1 . . ?
O10 C60 C51 123.9(4) . . ?
O10 C60 C59 117.8(3) . . ?
C51 C60 C59 118.2(4) . . ?
C62 C61 H61A 109.5 . . ?
C62 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C62 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
O12 C62 C63 123.2(4) . . ?
O12 C62 C61 113.3(4) . . ?
C63 C62 C61 123.1(4) . . ?
C62 C63 C72 117.4(3) . . ?
C62 C63 C64 122.2(4) . . ?
C72 C63 C64 119.9(4) . . ?
C69 C64 C65 116.9(4) . . ?
C69 C64 C63 119.7(4) . . ?
C65 C64 C63 123.2(4) . . ?
C66 C65 C64 121.9(5) . . ?
C66 C65 H65 119.0 . . ?
C64 C65 H65 119.0 . . ?
C65 C66 C67 119.9(5) . . ?
C65 C66 H66 120.0 . . ?
C67 C66 H66 120.0 . . ?
C68 C67 C66 119.9(5) . . ?
C68 C67 H67 120.0 . . ?
C66 C67 H67 120.0 . . ?
C67 C68 C69 120.6(5) . . ?
C67 C68 H68 119.7 . . ?
C69 C68 H68 119.7 . . ?
C64 C69 C68 120.7(5) . . ?
C64 C69 C70 119.0(4) . . ?
C68 C69 C70 120.2(5) . . ?
C71 C70 C69 121.3(4) . . ?
C71 C70 H70 119.3 . . ?
C69 C70 H70 119.3 . . ?
C70 C71 C72 122.3(5) . . ?
C70 C71 H71 118.8 . . ?
C72 C71 H71 118.8 . . ?
O11 C72 C71 118.4(4) . . ?
O11 C72 C63 124.6(4) . . ?
C71 C72 C63 116.9(4) . . ?
O1M C73 H73A 109.5 . . ?
O1M C73 H73B 109.5 . . ?
H73A C73 H73B 109.5 . . ?
O1M C73 H73C 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
C73 O1M Y2 132.0(3) . . ?
C73 O1M Dy2 132.0(4) . . ?
C73 O1M H1M 110(4) . . ?
Y2 O1M H1M 117(4) . . ?
Dy2 O1M H1M 114(4) . . ?
O2M C74 H74A 109.5 . . ?
O2M C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
O2M C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C74 O2M H2M 110(4) . . ?

_refine_diff_density_max         1.673
_refine_diff_density_min         -0.703
_refine_diff_density_rms         0.085


# start Validation Reply Form
_vrf_PLAT154_2                   
;
RESPONSE: Provided data is correct. Unrounded su's show slight differences.
;
_vrf_PLAT068_2                   
;
RESPONSE: Due to the rounding of the site occupancies of the disordered 
metal sites with only two decimals.
;
_vrf_PLAT077_2                   
;
RESPONSE: Due to substitutional disorder of the Dy/Y metal sites.
;
# end Validation Reply Form




_exptl_crystal_preparation       'Magnetic properties'
