# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_linzg_1104_twin1_hklf4
_database_code_depnum_ccdc_archive 'CCDC 2114829'
loop_
_audit_author_name
_audit_author_address
'Xin- Xin Yu'
;Lanzhoujiaotong university
China
;
_audit_update_record             
;
2021-10-10 deposited with the CCDC.	2022-01-20 downloaded from the CCDC.
;
_audit_creation_date             2019-11-07
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C10 H6 Cu N O5'
_chemical_formula_sum            'C10 H6 Cu N O5'
_chemical_formula_weight         283.71
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C10 H6 Cu N O5'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu -1.9646 0.5888 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   14.0500(9)
_cell_length_b                   5.0906(3)
_cell_length_c                   26.2723(16)
_cell_angle_alpha                90
_cell_angle_beta                 104.268(6)
_cell_angle_gamma                90
_cell_volume                     1821.1(2)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    1934
_cell_measurement_temperature    173.20(10)
_cell_measurement_theta_max      69.7710
_cell_measurement_theta_min      7.2090
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    3.543
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.74827
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.38.43f (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    2.070
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1136
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0586
_diffrn_reflns_av_unetI/netI     0.0154
_diffrn_reflns_Laue_measured_fraction_full 0.977
_diffrn_reflns_Laue_measured_fraction_max 0.977
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            1773
_diffrn_reflns_point_group_measured_fraction_full 0.977
_diffrn_reflns_point_group_measured_fraction_max 0.977
_diffrn_reflns_theta_full        66.548
_diffrn_reflns_theta_max         66.548
_diffrn_reflns_theta_min         3.472
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      173.20(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.0733
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -85.00 -55.00   1.00    2.00    --   -8.50 178.00  60.00   30
  2  ω    -27.00   0.00   1.00    2.00    --   -8.50 111.00  60.00   27
  3  ω    -56.00  -2.00   1.00    2.00    --   -8.50 -50.00 -90.00   54
  4  ω    -54.00 -28.00   1.00    2.00    --   -8.50 111.00  60.00   26
  5  ω     22.00 112.00   1.00    2.00    --   54.00  77.00-120.00   90
  6  ω     20.00  45.00   1.00    2.00    --   54.00  81.00 139.27   25
  7  ω     90.00 116.00   1.00    2.00    --   54.00 152.00 -45.00   26
  8  ω    101.00 157.00   1.00    3.00    --  108.00 111.00-120.00   56
  9  ω     41.00  92.00   1.00    3.00    --  108.00 -38.00-120.00   51
 10  ω     41.00 115.00   1.00    3.00    --  108.00-111.00 -30.00   74
 11  ω     36.00  92.00   1.00    3.00    --  108.00 -25.00 -30.00   56
 12  ω     98.00 123.00   1.00    3.00    --  108.00 121.00 154.00   25
 13  ω     52.00  94.00   1.00    3.00    --  108.00 -25.00 -90.00   42
 14  ω     81.00 128.00   1.00    3.00    --  108.00 -91.00  30.00   47
 15  ω     48.00  73.00   1.00    3.00    --  108.00 -38.00  30.00   25
 16  ω    121.00 178.00   1.00    3.00    --  108.00  38.00  60.00   57
 17  ω     44.00 130.00   1.00    3.00    --  108.00 -63.00 120.00   86
 18  ω    -10.00  21.00   1.00    2.00    --   -8.50 -77.00 -60.00   31
 19  ω     41.00  68.00   1.00    2.00    --   54.00 -99.00  60.00   27
 20  ω     11.00  37.00   1.00    2.00    --   54.00 -99.00  60.00   26
 21  ω    105.00 140.00   1.00    3.00    --  108.00 -77.00 150.00   35
 22  ω     57.00 101.00   1.00    3.00    --  108.00 -50.00  30.00   44
 23  ω     58.00  84.00   1.00    3.00    --  108.00 -25.00 -60.00   26
 24  ω     73.00  99.00   1.00    3.00    --  108.00 -77.00 150.00   26
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0159122000
_diffrn_orient_matrix_UB_12      0.2779810000
_diffrn_orient_matrix_UB_13      0.0237145000
_diffrn_orient_matrix_UB_21      -0.0352590000
_diffrn_orient_matrix_UB_22      0.1193745000
_diffrn_orient_matrix_UB_23      -0.0553679000
_diffrn_orient_matrix_UB_31      -0.1063204000
_diffrn_orient_matrix_UB_32      0.0023700000
_diffrn_orient_matrix_UB_33      0.0060747000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1715
_reflns_number_total             1773
_reflns_special_details          
;
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         0.526
_refine_diff_density_min         -0.793
_refine_diff_density_rms         0.124
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     156
_refine_ls_number_reflns         1773
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0456
_refine_ls_R_factor_gt           0.0447
_refine_ls_restrained_S_all      1.055
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0848P)²+13.3174P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1248
_refine_ls_wR_factor_ref         0.1257
_refine_special_details          
;
 Refined as a 2-component twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.812(2)
 0.188(2)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
3.a Rotating group:
 O5(H5A,H5B)
3.b Aromatic/amide H refined with riding coordinates:
 C9(H9), C10(H10), C3(H3), C5(H5)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.77895(4) 0.10920(12) 0.30008(2) 0.0071(2) Uani 1 1 d . . . A 1
O5 O 0.9054(2) 0.3800(6) 0.32563(12) 0.0119(7) Uani 1 1 d . . . . .
H5A H 0.9299 0.4223 0.2992 0.018 Uiso 1 1 d GR . . A .
H5B H 0.9011 0.2660 0.3480 0.018 Uiso 1 1 d GR . . . .
O3 O 0.6922(2) 0.4318(6) 0.25968(11) 0.0088(6) Uani 1 1 d . . . . .
O4 O 0.6025(2) 0.7650(7) 0.27964(12) 0.0135(7) Uani 1 1 d . . . . .
C2 C 0.7209(3) 0.0708(9) 0.39344(17) 0.0088(9) Uani 1 1 d . . . . .
O2 O 0.8105(2) -0.3076(7) 0.43199(12) 0.0126(7) Uani 1 1 d . . . . .
N1 N 0.7087(3) 0.2117(7) 0.34975(14) 0.0069(7) Uani 1 1 d . . . . .
C6 C 0.6443(3) 0.4110(9) 0.33989(16) 0.0071(9) Uani 1 1 d . . . . .
O1 O 0.8241(2) -0.1735(6) 0.35254(12) 0.0123(7) Uani 1 1 d . . . . .
C7 C 0.6423(3) 0.5535(9) 0.28934(17) 0.0080(9) Uani 1 1 d . . . . .
C9 C 0.5592(3) 0.2796(9) 0.50840(17) 0.0098(9) Uani 1 1 d . . . . .
H9 H 0.5989 0.1311 0.5143 0.012 Uiso 1 1 calc R . . . .
C10 C 0.4908(3) 0.6466(9) 0.45471(17) 0.0111(9) Uani 1 1 d . . . . .
H10 H 0.4842 0.7462 0.4244 0.013 Uiso 1 1 calc R . . . .
C3 C 0.6713(3) 0.1343(9) 0.43166(17) 0.0090(9) Uani 1 1 d . . . . .
H3 H 0.6825 0.0386 0.4627 0.011 Uiso 1 1 calc R . . . .
C4 C 0.6045(3) 0.3432(8) 0.42289(16) 0.0079(8) Uani 1 1 d . . . . .
C8 C 0.5511(3) 0.4241(9) 0.46231(16) 0.0081(9) Uani 1 1 d . . . . .
C5 C 0.5908(3) 0.4817(9) 0.37492(16) 0.0089(9) Uani 1 1 d . . . . .
H5 H 0.5459 0.6193 0.3672 0.011 Uiso 1 1 calc R . . . .
C1 C 0.7913(3) -0.1568(8) 0.39510(17) 0.0079(9) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 O5 2.218(3) . ?
Cu1 H5B 2.0248 . ?
Cu1 O3 2.161(3) . ?
Cu1 O3 1.939(3) 4_645 ?
Cu1 N1 1.893(4) . ?
Cu1 O1 1.985(3) . ?
O5 H5A 0.8751 . ?
O5 H5B 0.8386 . ?
O3 Cu1 1.939(3) 4_655 ?
O3 C7 1.324(5) . ?
O4 C7 1.211(6) . ?
C2 N1 1.328(6) . ?
C2 C3 1.394(6) . ?
C2 C1 1.517(6) . ?
O2 C1 1.213(6) . ?
N1 C6 1.341(6) . ?
C6 C7 1.507(6) . ?
C6 C5 1.372(6) . ?
O1 C1 1.313(5) . ?
C9 H9 0.9300 . ?
C9 C10 1.381(6) 5_666 ?
C9 C8 1.397(6) . ?
C10 C9 1.381(6) 5_666 ?
C10 H10 0.9300 . ?
C10 C8 1.399(6) . ?
C3 H3 0.9300 . ?
C3 C4 1.399(6) . ?
C4 C8 1.479(6) . ?
C4 C5 1.415(6) . ?
C5 H5 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Cu1 H5B 22.2 . . ?
O3 Cu1 O5 102.89(13) 4_645 . ?
O3 Cu1 O5 89.37(12) . . ?
O3 Cu1 H5B 111.9 4_645 . ?
O3 Cu1 H5B 107.1 . . ?
O3 Cu1 O3 99.29(8) 4_645 . ?
O3 Cu1 O1 97.45(13) 4_645 . ?
N1 Cu1 O5 97.75(14) . . ?
N1 Cu1 H5B 88.2 . . ?
N1 Cu1 O3 78.59(13) . . ?
N1 Cu1 O3 159.25(15) . 4_645 ?
N1 Cu1 O1 81.55(14) . . ?
O1 Cu1 O5 98.35(13) . . ?
O1 Cu1 H5B 77.1 . . ?
O1 Cu1 O3 159.50(12) . . ?
Cu1 O5 H5A 110.8 . . ?
Cu1 O5 H5B 65.8 . . ?
H5A O5 H5B 146.8 . . ?
Cu1 O3 Cu1 123.13(15) 4_655 . ?
C7 O3 Cu1 120.4(3) . 4_655 ?
C7 O3 Cu1 112.5(3) . . ?
N1 C2 C3 121.1(4) . . ?
N1 C2 C1 112.4(4) . . ?
C3 C2 C1 126.5(4) . . ?
C2 N1 Cu1 117.9(3) . . ?
C2 N1 C6 120.8(4) . . ?
C6 N1 Cu1 121.1(3) . . ?
N1 C6 C7 113.5(4) . . ?
N1 C6 C5 121.6(4) . . ?
C5 C6 C7 124.8(4) . . ?
C1 O1 Cu1 115.2(3) . . ?
O3 C7 C6 113.3(4) . . ?
O4 C7 O3 125.2(4) . . ?
O4 C7 C6 121.4(4) . . ?
C10 C9 H9 119.4 5_666 . ?
C10 C9 C8 121.2(4) 5_666 . ?
C8 C9 H9 119.4 . . ?
C9 C10 H10 119.5 5_666 . ?
C9 C10 C8 121.0(4) 5_666 . ?
C8 C10 H10 119.5 . . ?
C2 C3 H3 120.3 . . ?
C2 C3 C4 119.4(4) . . ?
C4 C3 H3 120.3 . . ?
C3 C4 C8 122.1(4) . . ?
C3 C4 C5 117.7(4) . . ?
C5 C4 C8 120.2(4) . . ?
C9 C8 C10 117.8(4) . . ?
C9 C8 C4 120.9(4) . . ?
C10 C8 C4 121.3(4) . . ?
C6 C5 C4 119.3(4) . . ?
C6 C5 H5 120.4 . . ?
C4 C5 H5 120.4 . . ?
O2 C1 C2 121.4(4) . . ?
O2 C1 O1 125.7(4) . . ?
O1 C1 C2 112.8(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cu1 O3 C7 O4 166.3(4) . . . . ?
Cu1 O3 C7 O4 8.1(6) 4_655 . . . ?
Cu1 O3 C7 C6 -9.9(4) . . . . ?
Cu1 O3 C7 C6 -168.1(3) 4_655 . . . ?
Cu1 N1 C6 C7 -5.5(5) . . . . ?
Cu1 N1 C6 C5 178.0(3) . . . . ?
Cu1 O1 C1 C2 3.0(5) . . . . ?
Cu1 O1 C1 O2 -179.4(4) . . . . ?
O5 Cu1 N1 C2 -95.8(3) . . . . ?
O5 Cu1 N1 C6 88.0(3) . . . . ?
O3 Cu1 N1 C2 176.5(3) . . . . ?
O3 Cu1 N1 C2 90.3(5) 4_645 . . . ?
O3 Cu1 N1 C6 0.2(3) . . . . ?
O3 Cu1 N1 C6 -85.9(5) 4_645 . . . ?
C2 N1 C6 C7 178.3(4) . . . . ?
C2 N1 C6 C5 1.8(7) . . . . ?
C2 C3 C4 C8 -178.7(4) . . . . ?
C2 C3 C4 C5 -0.1(7) . . . . ?
N1 C2 C3 C4 2.6(7) . . . . ?
N1 C2 C1 O2 -179.4(4) . . . . ?
N1 C2 C1 O1 -1.7(5) . . . . ?
N1 C6 C7 O3 10.3(5) . . . . ?
N1 C6 C7 O4 -166.1(4) . . . . ?
N1 C6 C5 C4 0.7(7) . . . . ?
O1 Cu1 N1 C2 1.6(3) . . . . ?
O1 Cu1 N1 C6 -174.6(4) . . . . ?
C7 C6 C5 C4 -175.4(4) . . . . ?
C9 C10 C8 C9 -0.1(8) 5_666 . . . ?
C9 C10 C8 C4 179.7(4) 5_666 . . . ?
C10 C9 C8 C10 0.1(8) 5_666 . . . ?
C10 C9 C8 C4 -179.7(4) 5_666 . . . ?
C3 C2 N1 Cu1 -179.8(3) . . . . ?
C3 C2 N1 C6 -3.5(7) . . . . ?
C3 C2 C1 O2 -0.1(7) . . . . ?
C3 C2 C1 O1 177.6(4) . . . . ?
C3 C4 C8 C9 -5.5(7) . . . . ?
C3 C4 C8 C10 174.7(4) . . . . ?
C3 C4 C5 C6 -1.5(6) . . . . ?
C8 C4 C5 C6 177.1(4) . . . . ?
C5 C6 C7 O3 -173.3(4) . . . . ?
C5 C6 C7 O4 10.3(7) . . . . ?
C5 C4 C8 C9 176.0(4) . . . . ?
C5 C4 C8 C10 -3.8(6) . . . . ?
C1 C2 N1 Cu1 -0.5(5) . . . . ?
C1 C2 N1 C6 175.8(4) . . . . ?
C1 C2 C3 C4 -176.6(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.635
_oxdiff_exptl_absorpt_empirical_full_min 0.553
_oxdiff_twin_integration_method  simultaneous
_oxdiff_twin_items               2
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
_oxdiff_twin_reflns_isolated
_oxdiff_twin_reflns_overlapped
_twin_individual_twin_lattice_type
_twin_individual_twin_matrix_11
_twin_individual_twin_matrix_12
_twin_individual_twin_matrix_13
_twin_individual_twin_matrix_21
_twin_individual_twin_matrix_22
_twin_individual_twin_matrix_23
_twin_individual_twin_matrix_31
_twin_individual_twin_matrix_32
_twin_individual_twin_matrix_33
1 0.812(2) 1014 2461 ref 1.0000 0.0000 0.0000 0.0000 1.0000 0.0000 0.0000
0.0000 1.0000
2 0.188(2) 0 2461 nmt -0.9976 -0.0078 -0.0006 0.0003 -0.9994 -0.0000 0.9193
-0.0030 1.0007

_twin_special_details            
;
Component 2 rotated by 179.9122° 
 around [-0.00 -0.00 1.00] (reciprocal) or [0.42 -0.00 0.91] (direct)
;
