# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_kg40
_database_code_depnum_ccdc_archive 'CCDC 2078496'
loop_
_audit_author_name
_audit_author_address
'Ludmila A. Glinskaya'
;Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2021-04-19 deposited with the CCDC.	2021-06-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C47 H29 Eu F18 N4 O8 P2'
_chemical_formula_weight         1333.64

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.22493(15)
_cell_length_b                   22.3649(2)
_cell_length_c                   19.3523(2)
_cell_angle_alpha                90
_cell_angle_beta                 108.0842(13)
_cell_angle_gamma                90
_cell_volume                     5029.71(10)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    22228
_cell_measurement_theta_min      2.13
_cell_measurement_theta_max      28.08

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.761
_exptl_crystal_F_000             2632
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.13
_exptl_absorpt_coefficient_mu    1.435
_shelx_estimated_absorpt_T_min   0.743
_shelx_estimated_absorpt_T_max   0.835
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.84087
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?

_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            AtlasS2
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed X-ray tube'
_diffrn_measurement_device_type  'New Xcalibur, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 10.6
_diffrn_reflns_number            37209
_diffrn_reflns_av_unetI/netI     0.0201
_diffrn_reflns_av_R_equivalents  0.0180
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         1.975
_diffrn_reflns_theta_max         28.371
_diffrn_reflns_theta_full        25.500
_diffrn_measured_fraction_theta_max 0.899
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.899
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.899
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             11316
_reflns_number_gt                10084
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2015)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2015)'
_computing_structure_solution    'SHELXT-2018 (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL-2018 (Sheldrick, 2015)'
_computing_molecular_graphics    'ShelXle (Hübschle, 2011)'
_computing_publication_material  'CIFTAB (Sheldrick, 2015)'

_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0277P)²+2.5330P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         11316
_refine_ls_number_parameters     990
_refine_ls_number_restraints     2171
_refine_ls_R_factor_all          0.0282
_refine_ls_R_factor_gt           0.0230
_refine_ls_wR_factor_ref         0.0571
_refine_ls_wR_factor_gt          0.0551
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_restrained_S_all      1.173
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.31107(2) 0.28474(2) 0.49493(2) 0.02065(3) Uani 1 1 d . . . . .
O11 O 0.13799(12) 0.28768(6) 0.38429(8) 0.0304(3) Uani 1 1 d . . . . .
O12 O 0.15313(12) 0.32870(6) 0.52557(7) 0.0318(3) Uani 1 1 d . . . . .
C11 C -0.0076(2) 0.32929(13) 0.28672(14) 0.0546(7) Uani 1 1 d D U . . .
C12 C 0.05455(18) 0.32259(10) 0.36881(11) 0.0349(5) Uani 1 1 d . . . . .
C13 C 0.01346(19) 0.35767(11) 0.41527(12) 0.0391(5) Uani 1 1 d . . . . .
H13 H -0.052454 0.382027 0.395195 0.047 Uiso 1 1 calc R U . . .
C14 C 0.06634(19) 0.35783(9) 0.48976(12) 0.0333(5) Uani 1 1 d . . . . .
C15 C 0.0159(2) 0.39724(10) 0.53723(13) 0.0440(5) Uani 1 1 d D U . . .
F11 F -0.0304(8) 0.2792(3) 0.2500(6) 0.0525(14) Uani 0.58(2) 1 d D U P A 1
F12 F -0.1034(7) 0.3631(5) 0.2709(4) 0.0697(18) Uani 0.58(2) 1 d D U P A 1
F13 F 0.0654(7) 0.3614(3) 0.2601(4) 0.0516(13) Uani 0.58(2) 1 d D U P A 1
F11' F -0.0062(11) 0.2745(4) 0.2565(8) 0.054(2) Uani 0.42(2) 1 d D U P A 2
F12' F -0.1201(5) 0.3398(7) 0.2742(6) 0.074(2) Uani 0.42(2) 1 d D U P A 2
F13' F 0.0366(11) 0.3676(5) 0.2522(7) 0.067(2) Uani 0.42(2) 1 d D U P A 2
F14 F -0.0076(12) 0.3661(6) 0.5897(6) 0.0531(16) Uani 0.56(4) 1 d D U P B 1
F15 F -0.0819(8) 0.4233(6) 0.4978(6) 0.0543(16) Uani 0.56(4) 1 d D U P B 1
F16 F 0.0894(8) 0.4401(5) 0.5686(8) 0.0607(17) Uani 0.56(4) 1 d D U P B 1
F14' F -0.0306(14) 0.3612(6) 0.5759(9) 0.051(2) Uani 0.44(4) 1 d D U P B 2
F15' F -0.0654(11) 0.4359(6) 0.5026(8) 0.0543(19) Uani 0.44(4) 1 d D U P B 2
F16' F 0.0982(8) 0.4283(7) 0.5856(8) 0.0551(19) Uani 0.44(4) 1 d D U P B 2
O21 O 0.27793(12) 0.38058(6) 0.43315(7) 0.0286(3) Uani 1 1 d . . . . .
O22 O 0.39393(12) 0.36038(6) 0.58166(7) 0.0273(3) Uani 1 1 d . . . . .
C21 C 0.2622(3) 0.47864(11) 0.39076(13) 0.0565(7) Uani 1 1 d D U . . .
C22 C 0.3045(2) 0.43281(9) 0.45219(11) 0.0327(5) Uani 1 1 d . . . . .
C23 C 0.3619(2) 0.45418(9) 0.52148(12) 0.0411(6) Uani 1 1 d . . . . .
H23 H 0.376198 0.495851 0.528472 0.049 Uiso 1 1 calc R U . . .
C24 C 0.3987(2) 0.41595(9) 0.58051(11) 0.0328(5) Uani 1 1 d . . . . .
F21 F 0.2557(9) 0.4588(4) 0.3252(3) 0.0730(17) Uani 0.57(2) 1 d D U P C 1
F22 F 0.1584(5) 0.4982(5) 0.3878(5) 0.0821(17) Uani 0.57(2) 1 d D U P C 1
F23 F 0.3322(8) 0.5268(3) 0.4045(4) 0.0623(15) Uani 0.57(2) 1 d D U P C 1
F21' F 0.2948(12) 0.4580(5) 0.3352(5) 0.0672(19) Uani 0.43(2) 1 d D U P C 2
F22' F 0.1469(4) 0.4790(6) 0.3670(7) 0.088(2) Uani 0.43(2) 1 d D U P C 2
F23' F 0.2952(12) 0.5348(3) 0.4029(6) 0.079(2) Uani 0.43(2) 1 d D U P C 2
C25 C 0.4517(7) 0.4435(3) 0.6560(4) 0.0474(13) Uani 0.71(3) 1 d D U P D 1
F24 F 0.4859(11) 0.5000(2) 0.6564(4) 0.0658(17) Uani 0.71(3) 1 d D U P D 1
F25 F 0.5425(7) 0.4123(3) 0.6941(5) 0.0686(17) Uani 0.71(3) 1 d D U P D 1
F26 F 0.3762(10) 0.4423(4) 0.6932(4) 0.0728(14) Uani 0.71(3) 1 d D U P D 1
C25' C 0.4321(16) 0.4425(7) 0.6574(9) 0.055(2) Uani 0.29(3) 1 d D U P D 2
F24' F 0.447(2) 0.5012(6) 0.6560(9) 0.061(2) Uani 0.29(3) 1 d D U P D 2
F25' F 0.5259(16) 0.4191(8) 0.7038(10) 0.059(2) Uani 0.29(3) 1 d D U P D 2
F26' F 0.3460(16) 0.4334(7) 0.6853(9) 0.053(2) Uani 0.29(3) 1 d D U P D 2
O31 O 0.48116(12) 0.32766(6) 0.46485(7) 0.0287(3) Uani 1 1 d . . . . .
O32 O 0.36408(12) 0.22331(6) 0.40816(7) 0.0269(3) Uani 1 1 d . . . . .
C31 C 0.65656(19) 0.34600(9) 0.44467(11) 0.0366(5) Uani 1 1 d D U . . .
C32 C 0.55627(17) 0.30435(9) 0.44338(10) 0.0263(4) Uani 1 1 d . . . . .
C33 C 0.55749(18) 0.24635(9) 0.41629(10) 0.0282(4) Uani 1 1 d . . . . .
H33 H 0.625768 0.230967 0.409373 0.034 Uiso 1 1 calc R U . . .
C34 C 0.45951(19) 0.21159(8) 0.39964(10) 0.0271(4) Uani 1 1 d . . . . .
C35 C 0.46199(19) 0.15123(10) 0.36286(12) 0.0404(5) Uani 1 1 d D U . . .
F31 F 0.6181(5) 0.3957(3) 0.4068(5) 0.0636(13) Uani 0.639(17) 1 d D U P E 1
F32 F 0.7336(5) 0.3222(2) 0.4172(4) 0.0509(11) Uani 0.639(17) 1 d D U P E 1
F33 F 0.7128(6) 0.3633(4) 0.5116(2) 0.0532(12) Uani 0.639(17) 1 d D U P E 1
F31' F 0.6279(9) 0.3804(5) 0.3863(4) 0.0573(19) Uani 0.361(17) 1 d D U P E 2
F32' F 0.7514(7) 0.3163(4) 0.4452(8) 0.060(2) Uani 0.361(17) 1 d D U P E 2
F33' F 0.6844(10) 0.3814(4) 0.5022(4) 0.0485(17) Uani 0.361(17) 1 d D U P E 2
F34 F 0.4456(10) 0.1067(3) 0.4052(4) 0.0559(14) Uani 0.60(2) 1 d D U P F 1
F35 F 0.3758(6) 0.1459(4) 0.3005(3) 0.0558(14) Uani 0.60(2) 1 d D U P F 1
F36 F 0.5589(5) 0.1388(4) 0.3483(6) 0.0617(14) Uani 0.60(2) 1 d D U P F 1
F34' F 0.4128(10) 0.1083(5) 0.3903(8) 0.0586(19) Uani 0.40(2) 1 d D U P F 2
F35' F 0.4067(13) 0.1556(6) 0.2932(3) 0.064(2) Uani 0.40(2) 1 d D U P F 2
F36' F 0.5696(5) 0.1343(6) 0.3715(8) 0.0552(19) Uani 0.40(2) 1 d D U P F 2
O1 O 0.47992(12) 0.23287(6) 0.56088(7) 0.0255(3) Uani 1 1 d . . . . .
P1 P 0.52404(4) 0.21288(2) 0.63834(3) 0.02342(10) Uani 1 1 d . . . . .
N11 N 0.41932(16) 0.19217(8) 0.74077(9) 0.0324(4) Uani 1 1 d . . . . .
N12 N 0.31765(14) 0.25041(7) 0.63649(8) 0.0259(3) Uani 1 1 d . . . . .
C101 C 0.40688(18) 0.21872(8) 0.67706(10) 0.0257(4) Uani 1 1 d . . . . .
C102 C 0.3306(2) 0.19888(11) 0.76675(11) 0.0371(5) Uani 1 1 d . . . . .
H102 H 0.333282 0.179793 0.811095 0.045 Uiso 1 1 calc R U . . .
C103 C 0.2361(2) 0.23247(11) 0.73135(12) 0.0401(5) Uani 1 1 d . . . . .
H103 H 0.175297 0.238282 0.751551 0.048 Uiso 1 1 calc R U . . .
C104 C 0.23190(19) 0.25761(10) 0.66543(11) 0.0343(5) Uani 1 1 d . . . . .
H104 H 0.166563 0.280620 0.639842 0.041 Uiso 1 1 calc R U . . .
C105 C 0.63773(18) 0.25996(9) 0.69164(11) 0.0295(4) Uani 1 1 d . U . . .
C106 C 0.6864(2) 0.29987(11) 0.65566(13) 0.0435(6) Uani 1 1 d . U . . .
H106 H 0.658516 0.302338 0.604135 0.052 Uiso 1 1 calc R U . . .
C107 C 0.7763(2) 0.33655(12) 0.69436(15) 0.0541(7) Uani 1 1 d . U . . .
H107 H 0.810365 0.363812 0.669453 0.065 Uiso 1 1 calc R U . . .
C108 C 0.8155(2) 0.33315(13) 0.76899(15) 0.0524(7) Uani 1 1 d . U . . .
H108 H 0.875993 0.358664 0.795723 0.063 Uiso 1 1 calc R U . . .
C109 C 0.7680(3) 0.29329(15) 0.80482(15) 0.0655(9) Uani 1 1 d . U . . .
H109 H 0.796374 0.290732 0.856327 0.079 Uiso 1 1 calc R U . . .
C110 C 0.6789(2) 0.25666(15) 0.76645(13) 0.0570(8) Uani 1 1 d . U . . .
H110 H 0.645858 0.229118 0.791641 0.068 Uiso 1 1 calc R U . . .
C111 C 0.57436(18) 0.13723(9) 0.64485(12) 0.0312(4) Uani 1 1 d . U . . .
C112 C 0.5579(3) 0.10652(11) 0.58093(15) 0.0535(7) Uani 1 1 d . U . . .
H112 H 0.517462 0.124501 0.535738 0.064 Uiso 1 1 calc R U . . .
C113 C 0.6012(3) 0.04861(13) 0.5832(2) 0.0800(10) Uani 1 1 d . U . . .
H113 H 0.589515 0.026881 0.539314 0.096 Uiso 1 1 calc R U . . .
C114 C 0.6603(3) 0.02296(13) 0.6479(2) 0.0792(11) Uani 1 1 d . U . . .
H114 H 0.690546 -0.016265 0.648863 0.095 Uiso 1 1 calc R U . . .
C115 C 0.6759(3) 0.05299(14) 0.7105(2) 0.0709(9) Uani 1 1 d . U . . .
H115 H 0.716596 0.034585 0.755355 0.085 Uiso 1 1 calc R U . . .
C116 C 0.6335(2) 0.11016(12) 0.71031(15) 0.0542(7) Uani 1 1 d . U . . .
H116 H 0.644730 0.130917 0.754804 0.065 Uiso 1 1 calc R U . . .
O2 O 0.21372(12) 0.19242(6) 0.49409(7) 0.0289(3) Uani 1 1 d . . . . .
P2 P 0.14513(5) 0.13683(2) 0.49059(3) 0.02490(10) Uani 1 1 d . . . . .
C201 C 0.22390(19) 0.07957(9) 0.55346(10) 0.0298(4) Uani 1 1 d . U . . .
N21 N 0.2852(3) 0.09843(11) 0.61937(12) 0.0495(7) Uani 0.869(3) 1 d . U P G 1
N22 N 0.2182(3) 0.02226(12) 0.53177(14) 0.0671(10) Uani 0.869(3) 1 d . U P G 1
C202 C 0.3388(3) 0.05682(13) 0.66848(14) 0.0494(8) Uani 0.869(3) 1 d D U P G 1
H202 H 0.381516 0.068948 0.716301 0.059 Uiso 0.869(3) 1 calc R U P G 1
C203 C 0.3332(5) -0.0016(3) 0.6511(2) 0.0514(9) Uani 0.869(3) 1 d D U P G 1
H203 H 0.369927 -0.030813 0.686406 0.062 Uiso 0.869(3) 1 calc R U P G 1
C204 C 0.2738(4) -0.01795(15) 0.58203(18) 0.0788(13) Uani 0.869(3) 1 d D U P G
1
H204 H 0.271530 -0.058960 0.568844 0.095 Uiso 0.869(3) 1 calc R U P G 1
N31 N 0.2023(19) 0.0814(8) 0.6210(9) 0.055(3) Uani 0.131(3) 1 d . U P G 2
N32 N 0.289(2) 0.0491(8) 0.5369(9) 0.057(3) Uani 0.131(3) 1 d . U P G 2
C302 C 0.267(2) 0.0347(10) 0.6679(11) 0.057(3) Uani 0.131(3) 1 d D U P G 2
H302 H 0.252443 0.030056 0.713118 0.068 Uiso 0.131(3) 1 calc R U P G 2
C303 C 0.345(4) -0.0033(19) 0.6559(16) 0.057(3) Uani 0.131(3) 1 d D U P G 2
H303 H 0.388936 -0.031851 0.689681 0.069 Uiso 0.131(3) 1 calc R U P G 2
C304 C 0.352(2) 0.0057(10) 0.5880(11) 0.058(3) Uani 0.131(3) 1 d D U P G 2
H304 H 0.403758 -0.019037 0.572995 0.070 Uiso 0.131(3) 1 calc R U P G 2
C205 C 0.02056(19) 0.14936(9) 0.51947(11) 0.0326(4) Uani 1 1 d D U . . .
C206 C -0.0215(3) 0.20561(12) 0.5189(2) 0.0454(10) Uani 0.869(5) 1 d D U P H 1
H206 H 0.012866 0.237727 0.500997 0.055 Uiso 0.869(5) 1 calc R U P H 1
C207 C -0.1135(3) 0.21664(16) 0.5441(2) 0.0588(12) Uani 0.869(5) 1 d D U P H 1
H207 H -0.143899 0.255910 0.542038 0.071 Uiso 0.869(5) 1 calc R U P H 1
C208 C -0.1606(3) 0.17080(16) 0.5720(2) 0.0550(10) Uani 0.869(5) 1 d D U P H 1
H208 H -0.222508 0.178357 0.590683 0.066 Uiso 0.869(5) 1 calc R U P H 1
C209 C -0.1188(3) 0.11447(14) 0.5730(2) 0.0585(9) Uani 0.869(5) 1 d D U P H 1
H209 H -0.153677 0.082472 0.590707 0.070 Uiso 0.869(5) 1 calc R U P H 1
C210 C -0.0263(3) 0.10324(13) 0.5485(2) 0.0502(8) Uani 0.869(5) 1 d D U P H 1
H210 H 0.004979 0.064083 0.551626 0.060 Uiso 0.869(5) 1 calc R U P H 1
C306 C 0.0038(19) 0.2065(5) 0.5413(16) 0.040(3) Uani 0.131(5) 1 d D U P H 2
H306 H 0.051774 0.239542 0.539551 0.048 Uiso 0.131(5) 1 calc R U P H 2
C307 C -0.0905(19) 0.2104(11) 0.5659(16) 0.050(3) Uani 0.131(5) 1 d D U P H 2
H307 H -0.090314 0.241211 0.599650 0.060 Uiso 0.131(5) 1 calc R U P H 2
C308 C -0.1837(17) 0.1737(11) 0.5458(17) 0.059(3) Uani 0.131(5) 1 d D U P H 2
H308 H -0.252897 0.185521 0.554513 0.071 Uiso 0.131(5) 1 calc R U P H 2
C309 C -0.1787(14) 0.1204(9) 0.5134(14) 0.062(3) Uani 0.131(5) 1 d D U P H 2
H309 H -0.242079 0.094035 0.494998 0.074 Uiso 0.131(5) 1 calc R U P H 2
C310 C -0.0696(14) 0.1098(7) 0.5111(10) 0.054(3) Uani 0.131(5) 1 d D U P H 2
H310 H -0.053421 0.069457 0.502435 0.065 Uiso 0.131(5) 1 calc DR U P H 2
C211 C 0.10137(18) 0.10413(9) 0.40138(10) 0.0296(4) Uani 1 1 d . . . . .
C212 C 0.1399(2) 0.12981(10) 0.34809(11) 0.0368(5) Uani 1 1 d . . . . .
H212 H 0.186748 0.164610 0.358634 0.044 Uiso 1 1 calc R U . . .
C213 C 0.1099(2) 0.10451(12) 0.27906(12) 0.0452(6) Uani 1 1 d . . . . .
H213 H 0.136544 0.122097 0.242580 0.054 Uiso 1 1 calc R U . . .
C214 C 0.0422(2) 0.05457(11) 0.26329(12) 0.0464(6) Uani 1 1 d . . . . .
H214 H 0.023792 0.036962 0.216394 0.056 Uiso 1 1 calc R U . . .
C215 C 0.0008(3) 0.02973(11) 0.31538(13) 0.0541(7) Uani 1 1 d . . . . .
H215 H -0.048307 -0.004200 0.303805 0.065 Uiso 1 1 calc R U . . .
C216 C 0.0303(2) 0.05400(10) 0.38439(13) 0.0467(6) Uani 1 1 d . . . . .
H216 H 0.002180 0.036500 0.420290 0.056 Uiso 1 1 calc DR U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O11 2.5006(14) . yes
Eu1 O12 2.3994(14) . yes
Eu1 O21 2.4263(13) . yes
Eu1 O22 2.3768(13) . yes
Eu1 O31 2.5170(14) . yes
Eu1 O32 2.4091(13) . yes
Eu1 O1 2.3664(13) . yes
Eu1 P1 3.5465(5) . ?
Eu1 N12 2.8219(16) . yes
Eu1 O2 2.3807(14) . yes
O11 C12 1.245(3) . ?
O12 C14 1.255(3) . ?
C11 C12 1.541(3) . ?
C11 F11 1.309(5) . ?
C11 F12 1.346(4) . ?
C11 F13 1.365(5) . ?
C11 F11' 1.360(6) . ?
C11 F12' 1.341(5) . ?
C11 F13' 1.303(6) . ?
C12 C13 1.399(3) . ?
C13 H13 0.9500 . ?
C13 C14 1.385(3) . ?
C14 C15 1.534(3) . ?
C15 F14 1.334(5) . ?
C15 F15 1.336(5) . ?
C15 F16 1.325(5) . ?
C15 F14' 1.340(6) . ?
C15 F15' 1.331(6) . ?
C15 F16' 1.338(5) . ?
O21 C22 1.238(2) . ?
O22 C24 1.245(2) . ?
C21 C22 1.533(3) . ?
C21 F21 1.323(5) . ?
C21 F22 1.327(5) . ?
C21 F23 1.349(4) . ?
C21 F21' 1.340(5) . ?
C21 F22' 1.340(5) . ?
C21 F23' 1.317(5) . ?
C22 C23 1.391(3) . ?
C23 H23 0.9500 . ?
C23 C24 1.386(3) . ?
C24 C25 1.531(7) . ?
C24 C25' 1.534(16) . ?
C25 F24 1.329(4) . ?
C25 F25 1.325(4) . ?
C25 F26 1.335(5) . ?
C25' F24' 1.327(7) . ?
C25' F25' 1.325(7) . ?
C25' F26' 1.340(7) . ?
O31 C32 1.235(2) . ?
O32 C34 1.255(3) . ?
C31 C32 1.534(3) . ?
C31 F31 1.333(4) . ?
C31 F32 1.329(4) . ?
C31 F33 1.322(4) . ?
C31 F31' 1.321(5) . ?
C31 F32' 1.334(5) . ?
C31 F33' 1.322(5) . ?
C32 C33 1.401(3) . ?
C33 H33 0.9500 . ?
C33 C34 1.380(3) . ?
C34 C35 1.531(3) . ?
C35 F34 1.343(4) . ?
C35 F35 1.339(4) . ?
C35 F36 1.329(4) . ?
C35 F34' 1.329(6) . ?
C35 F35' 1.311(5) . ?
C35 F36' 1.329(5) . ?
O1 P1 1.4953(13) . ?
P1 C101 1.816(2) . ?
P1 C105 1.793(2) . ?
P1 C111 1.791(2) . ?
N11 C101 1.334(2) . ?
N11 C102 1.338(3) . ?
N12 C101 1.333(3) . ?
N12 C104 1.343(3) . ?
C102 H102 0.9500 . ?
C102 C103 1.370(4) . ?
C103 H103 0.9500 . ?
C103 C104 1.380(3) . ?
C104 H104 0.9500 . ?
C105 C106 1.376(3) . ?
C105 C110 1.379(3) . ?
C106 H106 0.9500 . ?
C106 C107 1.389(3) . ?
C107 H107 0.9500 . ?
C107 C108 1.375(4) . ?
C108 H108 0.9500 . ?
C108 C109 1.365(4) . ?
C109 H109 0.9500 . ?
C109 C110 1.381(4) . ?
C110 H110 0.9500 . ?
C111 C112 1.374(3) . ?
C111 C116 1.388(3) . ?
C112 H112 0.9500 . ?
C112 C113 1.395(4) . ?
C113 H113 0.9500 . ?
C113 C114 1.363(5) . ?
C114 H114 0.9500 . ?
C114 C115 1.345(5) . ?
C115 H115 0.9500 . ?
C115 C116 1.379(4) . ?
C116 H116 0.9500 . ?
O2 P2 1.4894(15) . ?
P2 C201 1.822(2) . ?
P2 C205 1.799(2) . ?
P2 C211 1.7967(19) . ?
C201 N21 1.331(3) . ?
C201 N22 1.344(3) . ?
C201 N31 1.413(18) . ?
C201 N32 1.16(2) . ?
N21 C202 1.346(3) . ?
N22 C204 1.344(4) . ?
C202 H202 0.9500 . ?
C202 C203 1.346(6) . ?
C203 H203 0.9500 . ?
C203 C204 1.359(5) . ?
C204 H204 0.9500 . ?
N31 C302 1.45(3) . ?
N32 C304 1.43(2) . ?
C302 H302 0.9500 . ?
C302 C303 1.355(8) . ?
C303 H303 0.9500 . ?
C303 C304 1.357(8) . ?
C304 H304 0.9500 . ?
C205 C206 1.358(3) . ?
C205 C210 1.382(3) . ?
C205 C306 1.382(8) . ?
C205 C310 1.382(7) . ?
C206 H206 0.9500 . ?
C206 C207 1.380(4) . ?
C207 H207 0.9500 . ?
C207 C208 1.367(4) . ?
C208 H208 0.9500 . ?
C208 C209 1.357(4) . ?
C209 H209 0.9500 . ?
C209 C210 1.377(4) . ?
C210 H210 0.9500 . ?
C306 H306 0.9500 . ?
C306 C307 1.379(9) . ?
C307 H307 0.9500 . ?
C307 C308 1.358(8) . ?
C308 H308 0.9500 . ?
C308 C309 1.358(8) . ?
C309 H309 0.9500 . ?
C309 C310 1.370(9) . ?
C310 H310 0.9500 . ?
C211 C212 1.385(3) . ?
C211 C216 1.394(3) . ?
C212 H212 0.9500 . ?
C212 C213 1.391(3) . ?
C213 H213 0.9500 . ?
C213 C214 1.367(4) . ?
C214 H214 0.9500 . ?
C214 C215 1.378(4) . ?
C215 H215 0.9500 . ?
C215 C216 1.382(3) . ?
C216 H216 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 Eu1 O31 109.40(5) . . yes
O11 Eu1 P1 154.48(3) . . ?
O11 Eu1 N12 126.86(5) . . yes
O12 Eu1 O11 70.66(5) . . yes
O12 Eu1 O21 74.68(5) . . yes
O12 Eu1 O31 133.38(5) . . yes
O12 Eu1 O32 144.81(5) . . yes
O12 Eu1 P1 116.35(3) . . ?
O12 Eu1 N12 69.77(5) . . yes
O21 Eu1 O11 65.63(5) . . yes
O21 Eu1 O31 64.70(5) . . yes
O21 Eu1 P1 139.09(3) . . ?
O21 Eu1 N12 131.98(5) . . yes
O22 Eu1 O11 130.37(5) . . yes
O22 Eu1 O12 74.52(5) . . yes
O22 Eu1 O21 71.86(4) . . yes
O22 Eu1 O31 71.96(5) . . yes
O22 Eu1 O32 138.62(5) . . yes
O22 Eu1 P1 73.83(3) . . ?
O22 Eu1 N12 68.33(4) . . yes
O22 Eu1 O2 136.44(4) . . yes
O31 Eu1 P1 83.99(3) . . ?
O31 Eu1 N12 123.48(5) . . yes
O32 Eu1 O11 75.96(5) . . yes
O32 Eu1 O21 101.55(4) . . yes
O32 Eu1 O31 68.65(4) . . yes
O32 Eu1 P1 89.77(3) . . ?
O32 Eu1 N12 126.06(5) . . yes
O1 Eu1 O11 147.06(4) . . yes
O1 Eu1 O12 134.57(4) . . yes
O1 Eu1 O21 133.09(5) . . yes
O1 Eu1 O22 81.89(5) . . yes
O1 Eu1 O31 70.54(5) . . yes
O1 Eu1 O32 73.62(4) . . yes
O1 Eu1 P1 18.24(3) . . ?
O1 Eu1 N12 65.53(5) . . yes
O1 Eu1 O2 85.93(5) . . yes
N12 Eu1 P1 47.49(4) . . ?
O2 Eu1 O11 74.25(5) . . yes
O2 Eu1 O12 85.31(5) . . yes
O2 Eu1 O21 139.12(5) . . yes
O2 Eu1 O31 140.92(5) . . yes
O2 Eu1 O32 75.08(5) . . yes
O2 Eu1 P1 81.74(3) . . ?
O2 Eu1 N12 68.55(4) . . yes
C12 O11 Eu1 129.40(13) . . ?
C14 O12 Eu1 133.13(13) . . ?
F11 C11 C12 115.5(5) . . ?
F11 C11 F12 109.4(4) . . ?
F11 C11 F13 107.4(4) . . ?
F12 C11 C12 113.9(4) . . ?
F12 C11 F13 104.1(4) . . ?
F13 C11 C12 105.6(4) . . ?
F11' C11 C12 106.7(7) . . ?
F12' C11 C12 110.7(5) . . ?
F12' C11 F11' 103.3(5) . . ?
F13' C11 C12 116.3(6) . . ?
F13' C11 F11' 108.0(6) . . ?
F13' C11 F12' 110.9(5) . . ?
O11 C12 C11 114.46(19) . . ?
O11 C12 C13 128.9(2) . . ?
C13 C12 C11 116.6(2) . . ?
C12 C13 H13 119.1 . . ?
C14 C13 C12 121.7(2) . . ?
C14 C13 H13 119.1 . . ?
O12 C14 C13 128.0(2) . . ?
O12 C14 C15 113.31(19) . . ?
C13 C14 C15 118.71(19) . . ?
F14 C15 C14 112.2(7) . . ?
F14 C15 F15 107.3(5) . . ?
F15 C15 C14 111.3(6) . . ?
F16 C15 C14 110.4(5) . . ?
F16 C15 F14 107.7(5) . . ?
F16 C15 F15 107.8(4) . . ?
F14' C15 C14 107.9(8) . . ?
F15' C15 C14 116.6(7) . . ?
F15' C15 F14' 107.0(6) . . ?
F15' C15 F16' 107.2(5) . . ?
F16' C15 C14 111.3(6) . . ?
F16' C15 F14' 106.2(5) . . ?
C22 O21 Eu1 134.34(13) . . ?
C24 O22 Eu1 135.25(13) . . ?
F21 C21 C22 115.2(5) . . ?
F21 C21 F22 107.3(4) . . ?
F21 C21 F23 107.6(4) . . ?
F22 C21 C22 110.0(3) . . ?
F22 C21 F23 106.6(4) . . ?
F23 C21 C22 109.9(4) . . ?
F21' C21 C22 106.2(5) . . ?
F21' C21 F22' 105.7(4) . . ?
F22' C21 C22 109.7(4) . . ?
F23' C21 C22 119.2(5) . . ?
F23' C21 F21' 108.7(5) . . ?
F23' C21 F22' 106.6(4) . . ?
O21 C22 C21 113.96(18) . . ?
O21 C22 C23 128.22(19) . . ?
C23 C22 C21 117.76(19) . . ?
C22 C23 H23 119.3 . . ?
C24 C23 C22 121.35(19) . . ?
C24 C23 H23 119.3 . . ?
O22 C24 C23 128.75(19) . . ?
O22 C24 C25 113.2(3) . . ?
O22 C24 C25' 111.7(6) . . ?
C23 C24 C25 118.1(3) . . ?
C23 C24 C25' 118.7(6) . . ?
F24 C25 C24 115.3(5) . . ?
F24 C25 F26 106.6(4) . . ?
F25 C25 C24 110.6(5) . . ?
F25 C25 F24 106.8(4) . . ?
F25 C25 F26 106.8(4) . . ?
F26 C25 C24 110.4(5) . . ?
F24' C25' C24 111.1(11) . . ?
F24' C25' F26' 106.8(7) . . ?
F25' C25' C24 114.7(13) . . ?
F25' C25' F24' 108.0(8) . . ?
F25' C25' F26' 106.8(7) . . ?
F26' C25' C24 109.0(11) . . ?
C32 O31 Eu1 132.13(13) . . ?
C34 O32 Eu1 132.27(12) . . ?
F31 C31 C32 110.7(3) . . ?
F32 C31 C32 114.3(3) . . ?
F32 C31 F31 106.7(3) . . ?
F33 C31 C32 111.3(3) . . ?
F33 C31 F31 106.4(3) . . ?
F33 C31 F32 107.0(3) . . ?
F31' C31 C32 110.0(5) . . ?
F31' C31 F32' 107.2(5) . . ?
F31' C31 F33' 107.5(4) . . ?
F32' C31 C32 112.7(5) . . ?
F33' C31 C32 111.9(5) . . ?
F33' C31 F32' 107.3(4) . . ?
O31 C32 C31 114.35(17) . . ?
O31 C32 C33 127.76(19) . . ?
C33 C32 C31 117.85(18) . . ?
C32 C33 H33 120.0 . . ?
C34 C33 C32 120.00(19) . . ?
C34 C33 H33 120.0 . . ?
O32 C34 C33 128.78(18) . . ?
O32 C34 C35 113.48(18) . . ?
C33 C34 C35 117.68(18) . . ?
F34 C35 C34 110.0(4) . . ?
F35 C35 C34 112.0(4) . . ?
F35 C35 F34 105.1(3) . . ?
F36 C35 C34 115.5(4) . . ?
F36 C35 F34 106.6(4) . . ?
F36 C35 F35 107.1(4) . . ?
F34' C35 C34 112.0(7) . . ?
F34' C35 F36' 107.3(5) . . ?
F35' C35 C34 109.5(6) . . ?
F35' C35 F34' 108.2(5) . . ?
F35' C35 F36' 108.9(5) . . ?
F36' C35 C34 110.8(6) . . ?
P1 O1 Eu1 132.07(8) . . ?
O1 P1 Eu1 29.69(5) . . ?
O1 P1 C101 107.87(9) . . ?
O1 P1 C105 112.03(9) . . ?
O1 P1 C111 111.23(9) . . ?
C101 P1 Eu1 78.98(6) . . ?
C105 P1 Eu1 115.70(7) . . ?
C105 P1 C101 106.88(9) . . ?
C111 P1 Eu1 129.48(7) . . ?
C111 P1 C101 109.67(9) . . ?
C111 P1 C105 109.04(10) . . ?
C101 N11 C102 115.11(19) . . ?
C101 N12 Eu1 119.21(12) . . ?
C101 N12 C104 114.84(17) . . ?
C104 N12 Eu1 125.56(14) . . ?
N11 C101 P1 118.11(16) . . ?
N12 C101 P1 113.66(14) . . ?
N12 C101 N11 128.23(19) . . ?
N11 C102 H102 119.0 . . ?
N11 C102 C103 122.0(2) . . ?
C103 C102 H102 119.0 . . ?
C102 C103 H103 121.0 . . ?
C102 C103 C104 118.0(2) . . ?
C104 C103 H103 121.0 . . ?
N12 C104 C103 121.8(2) . . ?
N12 C104 H104 119.1 . . ?
C103 C104 H104 119.1 . . ?
C106 C105 P1 118.02(16) . . ?
C106 C105 C110 119.5(2) . . ?
C110 C105 P1 122.52(17) . . ?
C105 C106 H106 119.9 . . ?
C105 C106 C107 120.3(2) . . ?
C107 C106 H106 119.9 . . ?
C106 C107 H107 120.2 . . ?
C108 C107 C106 119.6(2) . . ?
C108 C107 H107 120.2 . . ?
C107 C108 H108 119.8 . . ?
C109 C108 C107 120.3(2) . . ?
C109 C108 H108 119.8 . . ?
C108 C109 H109 119.9 . . ?
C108 C109 C110 120.2(3) . . ?
C110 C109 H109 119.9 . . ?
C105 C110 C109 120.2(2) . . ?
C105 C110 H110 119.9 . . ?
C109 C110 H110 119.9 . . ?
C112 C111 P1 117.24(17) . . ?
C112 C111 C116 119.5(2) . . ?
C116 C111 P1 123.13(19) . . ?
C111 C112 H112 120.4 . . ?
C111 C112 C113 119.2(3) . . ?
C113 C112 H112 120.4 . . ?
C112 C113 H113 119.8 . . ?
C114 C113 C112 120.5(3) . . ?
C114 C113 H113 119.8 . . ?
C113 C114 H114 119.9 . . ?
C115 C114 C113 120.2(3) . . ?
C115 C114 H114 119.9 . . ?
C114 C115 H115 119.6 . . ?
C114 C115 C116 120.8(3) . . ?
C116 C115 H115 119.6 . . ?
C111 C116 H116 120.1 . . ?
C115 C116 C111 119.7(3) . . ?
C115 C116 H116 120.1 . . ?
P2 O2 Eu1 175.94(9) . . ?
O2 P2 C201 112.51(9) . . ?
O2 P2 C205 112.00(9) . . ?
O2 P2 C211 112.27(9) . . ?
C205 P2 C201 102.99(10) . . ?
C211 P2 C201 107.07(9) . . ?
C211 P2 C205 109.49(10) . . ?
N21 C201 P2 116.15(17) . . ?
N21 C201 N22 124.1(2) . . ?
N22 C201 P2 119.75(16) . . ?
N31 C201 P2 112.7(7) . . ?
N32 C201 P2 119.5(8) . . ?
N32 C201 N31 127.6(11) . . ?
C201 N21 C202 117.6(2) . . ?
C201 N22 C204 116.5(2) . . ?
N21 C202 H202 119.4 . . ?
C203 C202 N21 121.3(3) . . ?
C203 C202 H202 119.4 . . ?
C202 C203 H203 120.8 . . ?
C202 C203 C204 118.4(4) . . ?
C204 C203 H203 120.8 . . ?
N22 C204 C203 121.9(3) . . ?
N22 C204 H204 119.1 . . ?
C203 C204 H204 119.1 . . ?
C201 N31 C302 109.7(16) . . ?
C201 N32 C304 118.5(18) . . ?
N31 C302 H302 115.8 . . ?
C303 C302 N31 128(2) . . ?
C303 C302 H302 115.8 . . ?
C302 C303 H303 125.3 . . ?
C302 C303 C304 109(3) . . ?
C304 C303 H303 125.3 . . ?
N32 C304 H304 117.0 . . ?
C303 C304 N32 126(2) . . ?
C303 C304 H304 117.0 . . ?
C206 C205 P2 119.8(2) . . ?
C206 C205 C210 119.4(3) . . ?
C210 C205 P2 120.54(18) . . ?
C306 C205 P2 117.3(9) . . ?
C306 C205 C310 116.0(8) . . ?
C310 C205 P2 125.8(5) . . ?
C205 C206 H206 119.6 . . ?
C205 C206 C207 120.7(3) . . ?
C207 C206 H206 119.6 . . ?
C206 C207 H207 120.2 . . ?
C208 C207 C206 119.7(3) . . ?
C208 C207 H207 120.2 . . ?
C207 C208 H208 120.0 . . ?
C209 C208 C207 119.9(3) . . ?
C209 C208 H208 120.0 . . ?
C208 C209 H209 119.7 . . ?
C208 C209 C210 120.7(3) . . ?
C210 C209 H209 119.7 . . ?
C205 C210 H210 120.3 . . ?
C209 C210 C205 119.5(3) . . ?
C209 C210 H210 120.3 . . ?
C205 C306 H306 123.8 . . ?
C307 C306 C205 112.5(15) . . ?
C307 C306 H306 123.8 . . ?
C306 C307 H307 117.3 . . ?
C308 C307 C306 125.5(16) . . ?
C308 C307 H307 117.3 . . ?
C307 C308 H308 119.7 . . ?
C309 C308 C307 120.6(11) . . ?
C309 C308 H308 119.7 . . ?
C308 C309 H309 124.8 . . ?
C308 C309 C310 110.5(14) . . ?
C310 C309 H309 124.8 . . ?
C205 C310 H310 115.3 . . ?
C309 C310 C205 129.4(14) . . ?
C309 C310 H310 115.3 . . ?
C212 C211 P2 118.56(15) . . ?
C212 C211 C216 119.30(19) . . ?
C216 C211 P2 122.14(17) . . ?
C211 C212 H212 120.1 . . ?
C211 C212 C213 119.8(2) . . ?
C213 C212 H212 120.1 . . ?
C212 C213 H213 119.7 . . ?
C214 C213 C212 120.5(2) . . ?
C214 C213 H213 119.7 . . ?
C213 C214 H214 120.0 . . ?
C213 C214 C215 120.0(2) . . ?
C215 C214 H214 120.0 . . ?
C214 C215 H215 119.9 . . ?
C214 C215 C216 120.2(2) . . ?
C216 C215 H215 119.9 . . ?
C211 C216 H216 120.0 . . ?
C215 C216 C211 120.1(2) . . ?
C215 C216 H216 120.0 . . ?

_refine_diff_density_max         0.601
_refine_diff_density_min         -0.299
_refine_diff_density_rms         0.059


_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent: MeOH'
_exptl_crystal_preparation       Luminescent
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_eu280_s2_100k
_database_code_depnum_ccdc_archive 'CCDC 2078495'
loop_
_audit_author_name
_audit_author_address
'Ludmila A. Glinskaya'
;Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2021-05-19 deposited with the CCDC.	2021-06-25 downloaded from the CCDC.
;
_audit_creation_date             2021-02-18
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6257)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C49 H31 Eu F18 N2 O8 P2'
_chemical_formula_sum            'C49 H31 Eu F18 N2 O8 P2'
_chemical_formula_weight         1331.66
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.7089(5)
_cell_length_b                   17.7622(7)
_cell_length_c                   23.0802(10)
_cell_angle_alpha                81.090(2)
_cell_angle_beta                 88.144(2)
_cell_angle_gamma                88.268(2)
_cell_volume                     5142.8(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9749
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      31.30
_cell_measurement_theta_min      2.70
_shelx_estimated_absorpt_T_max   0.933
_shelx_estimated_absorpt_T_min   0.796
_exptl_absorpt_coefficient_mu    1.402
_exptl_absorpt_correction_T_max  0.7463
_exptl_absorpt_correction_T_min  0.6421
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.0569 before and 0.0466 after correction.
The Ratio of minimum to maximum transmission is 0.8604.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.720
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2632
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0383
_diffrn_reflns_av_unetI/netI     0.0535
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.943
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            94520
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.943
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         31.577
_diffrn_reflns_theta_min         1.604
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 CCD
_diffrn_detector_area_resol_mean 8.33
_diffrn_detector_type            'Bruker APEXII CCD area detector'
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.943
_diffrn_measurement_device       'κ-geometry diffractometer'
_diffrn_measurement_device_type  'Bruker APEX diffractometer'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'sealed tube'
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_special_details          ?
_diffrn_standards_number         .
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                24970
_reflns_number_total             32502
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.153
_refine_diff_density_min         -1.349
_refine_diff_density_rms         0.110
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.010
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1459
_refine_ls_number_reflns         32502
_refine_ls_number_restraints     139
_refine_ls_R_factor_all          0.0601
_refine_ls_R_factor_gt           0.0378
_refine_ls_restrained_S_all      1.018
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0279P)²+4.9972P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0745
_refine_ls_wR_factor_ref         0.0824
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Restrained distances
 F21-C21 \\sim F22-C21 \\sim F23-C21 \\sim F1B-C4B \\sim F2B-C4B \\sim F3B-C4B
\\sim F1C-C4C \\sim F2C-C4C
 \\sim F3C-C4C \\sim F1D-C4D \\sim F2D-C4D \\sim F3D-C4D
 with sigma of 0.02
 F21-F22 \\sim F22-F23 \\sim F23-F21 \\sim F1B-F2B \\sim F2B-F3B \\sim F3B-F1B
\\sim F1C-F2C \\sim F2C-F3C
 \\sim F3C-F1C \\sim F1D-F2D \\sim F2D-F3D \\sim F3D-F1D
 with sigma of 0.02
 C4C-C22 \\sim C4D-C22 \\sim C4B-C22 \\sim C22-C21
 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
Uiso(C4C) = Uiso(C4D) = Uiso(C4B) = Uiso(C21)
Uiso(F23) = Uiso(F1C) = Uiso(F3C) = Uiso(F3D) = Uiso(F3B) = Uiso(F21) =
Uiso(F1B) = Uiso(F1D) = Uiso(F22) = Uiso(F2B) = Uiso(F2C) = Uiso(F2D)
4. Others
 1*[Sof(F1D)+Sof(F2D)+Sof(F3D)+Sof(C4D)]+1*[Sof(F1C)+Sof(F2C)+Sof(F3C)+
 Sof(C4C)]+1*[Sof(F1B)+Sof(F2B)+Sof(F3B)+Sof(C4B)]+1*[Sof(F21)+Sof(F22)+
 Sof(F23)+Sof(C21)]=1 with esd of 0.001
 Sof(F21)=Sof(F22)=Sof(F23)=Sof(C21)=FVAR(1)
 Sof(F1B)=Sof(F2B)=Sof(F3B)=Sof(C4B)=FVAR(2)
 Sof(F1C)=Sof(F2C)=Sof(F3C)=Sof(C4C)=FVAR(3)
 Sof(F1D)=Sof(F2D)=Sof(F3D)=Sof(C4D)=FVAR(4)
5.a Aromatic/amide H refined with riding coordinates:
 C13(H13), C23(H23), C33(H33), C102(H102), C103(H103), C104(H104), C105(H105),
 C107(H107), C108(H108), C109(H109), C110(H110), C111(H111), C113(H113),
 C114(H114), C115(H115), C116(H116), C117(H117), C202(H202), C203(H203),
 C204(H204), C205(H205), C207(H207), C208(H208), C209(H209), C210(H210),
 C211(H211), C213(H213), C214(H214), C215(H215), C216(H216), C217(H217),
 C43(H43), C53(H53), C63(H63), C302(H302), C303(H303), C304(H304), C305(H305),
 C307(H307), C308(H308), C309(H309), C310(H310), C311(H311), C313(H313),
 C314(H314), C315(H315), C316(H316), C317(H317), C402(H402), C403(H403),
 C404(H404), C405(H405), C407(H407), C408(H408), C409(H409), C410(H410),
 C411(H411), C413(H413), C414(H414), C415(H415), C416(H416), C417(H417)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.27094(2) 0.27862(2) 0.01744(2) 0.01257(3) Uani 1 1 d . . . . .
P1 P 0.25714(5) 0.24421(4) -0.13679(3) 0.01548(12) Uani 1 1 d . . . . .
P2 P 0.23482(5) 0.18587(3) 0.17151(3) 0.01430(12) Uani 1 1 d . . . . .
F11 F 0.34919(14) 0.44597(10) 0.16738(7) 0.0341(4) Uani 1 1 d . . . . .
F12 F 0.19637(14) 0.48477(11) 0.13625(8) 0.0381(4) Uani 1 1 d . . . . .
F13 F 0.32974(15) 0.55612(9) 0.11494(8) 0.0389(4) Uani 1 1 d . . . . .
F15 F 0.38493(19) 0.58358(10) -0.09071(9) 0.0525(6) Uani 1 1 d . . . . .
F16 F 0.44895(16) 0.48443(11) -0.12177(10) 0.0533(6) Uani 1 1 d . . . . .
F17 F 0.28644(17) 0.51647(12) -0.13355(8) 0.0494(5) Uani 1 1 d . . . . .
F25 F 0.49540(12) -0.01544(9) 0.06382(7) 0.0281(4) Uani 1 1 d . . . . .
F26 F 0.36509(14) 0.00920(9) 0.12002(7) 0.0313(4) Uani 1 1 d . . . . .
F27 F 0.33769(13) -0.00582(8) 0.03121(7) 0.0269(4) Uani 1 1 d . . . . .
F31 F -0.09364(17) 0.11180(11) 0.03858(10) 0.0547(6) Uani 1 1 d . . . . .
F32 F -0.09500(18) 0.15724(12) -0.05176(10) 0.0578(6) Uani 1 1 d . . . . .
F33 F 0.03082(14) 0.08275(11) -0.01699(11) 0.0576(7) Uani 1 1 d . . . . .
F35 F -0.08638(19) 0.44726(13) 0.01060(11) 0.0666(7) Uani 1 1 d . . . . .
F36 F -0.01090(15) 0.43183(12) 0.09249(10) 0.0513(6) Uani 1 1 d . . . . .
F37 F -0.14610(16) 0.36850(13) 0.08066(13) 0.0740(9) Uani 1 1 d . . . . .
O1 O 0.29843(13) 0.25025(9) -0.07758(8) 0.0169(3) Uani 1 1 d . . . . .
O2 O 0.21387(13) 0.23297(9) 0.11301(8) 0.0177(4) Uani 1 1 d . . . . .
O11 O 0.30739(13) 0.37506(9) 0.07647(8) 0.0184(4) Uani 1 1 d . . . . .
O12 O 0.31313(13) 0.39536(9) -0.04573(8) 0.0183(4) Uani 1 1 d . . . . .
O21 O 0.45879(13) 0.27039(10) 0.01632(8) 0.0199(4) Uani 1 1 d . . . . .
O22 O 0.32753(13) 0.14563(9) 0.04005(8) 0.0183(4) Uani 1 1 d . . . . .
O31 O 0.12481(13) 0.20506(9) -0.00295(8) 0.0175(3) Uani 1 1 d . . . . .
O32 O 0.10919(13) 0.35192(9) 0.02567(8) 0.0181(4) Uani 1 1 d . . . . .
N1 N 0.3072(2) 0.30411(15) -0.24940(11) 0.0350(6) Uani 1 1 d . . . . .
N2 N 0.1963(2) 0.19966(16) 0.28633(12) 0.0369(6) Uani 1 1 d . . . . .
C11 C 0.2995(2) 0.48386(16) 0.12154(13) 0.0263(6) Uani 1 1 d . . . . .
C12 C 0.31761(19) 0.44574(14) 0.06646(11) 0.0183(5) Uani 1 1 d . . . . .
C13 C 0.3377(2) 0.49179(14) 0.01313(12) 0.0230(6) Uani 1 1 d . . . . .
H13 H 0.3524 0.5441 0.0121 0.028 Uiso 1 1 calc R U . . .
C14 C 0.33625(19) 0.46125(14) -0.03870(12) 0.0188(5) Uani 1 1 d . . . . .
C15 C 0.3644(2) 0.51267(15) -0.09649(13) 0.0276(6) Uani 1 1 d . . . . .
C22 C 0.52719(19) 0.21766(15) 0.02022(13) 0.0245(6) Uani 1 1 d D . . . .
C23 C 0.5137(2) 0.13986(15) 0.03554(13) 0.0253(6) Uani 1 1 d . . . . .
H23 H 0.5738 0.1065 0.0395 0.030 Uiso 1 1 calc R U . . .
C24 C 0.41427(19) 0.10998(14) 0.04520(11) 0.0177(5) Uani 1 1 d . . . . .
C25 C 0.4037(2) 0.02363(14) 0.06482(12) 0.0205(5) Uani 1 1 d . . . . .
C31 C -0.0330(2) 0.13959(16) -0.00652(14) 0.0267(6) Uani 1 1 d . . . . .
C32 C 0.02753(19) 0.20844(14) 0.00582(11) 0.0176(5) Uani 1 1 d . . . . .
C33 C -0.03155(19) 0.26709(15) 0.02567(12) 0.0224(5) Uani 1 1 d . . . . .
H33 H -0.1050 0.2612 0.0334 0.027 Uiso 1 1 calc R U . . .
C34 C 0.01505(19) 0.33401(14) 0.03434(12) 0.0195(5) Uani 1 1 d . . . . .
C35 C -0.0571(2) 0.39564(17) 0.05571(15) 0.0318(7) Uani 1 1 d . . . . .
C101 C 0.3401(2) 0.29715(14) -0.19286(12) 0.0204(5) Uani 1 1 d . . . . .
C102 C 0.4312(2) 0.32804(16) -0.17740(13) 0.0282(6) Uani 1 1 d . . . . .
H102 H 0.4509 0.3222 -0.1376 0.034 Uiso 1 1 calc R U . . .
C103 C 0.4935(3) 0.36805(19) -0.22167(15) 0.0377(8) Uani 1 1 d . . . . .
H103 H 0.5569 0.3901 -0.2124 0.045 Uiso 1 1 calc R U . . .
C104 C 0.4629(3) 0.37554(18) -0.27902(15) 0.0391(8) Uani 1 1 d . . . . .
H104 H 0.5049 0.4023 -0.3098 0.047 Uiso 1 1 calc R U . . .
C105 C 0.3699(3) 0.3434(2) -0.29091(14) 0.0408(8) Uani 1 1 d . . . . .
H105 H 0.3490 0.3493 -0.3305 0.049 Uiso 1 1 calc R U . . .
C106 C 0.12422(19) 0.28204(14) -0.14531(11) 0.0184(5) Uani 1 1 d . . . . .
C107 C 0.0959(2) 0.34541(14) -0.11915(11) 0.0199(5) Uani 1 1 d . . . . .
H107 H 0.1471 0.3696 -0.0998 0.024 Uiso 1 1 calc R U . . .
C108 C -0.0072(2) 0.37318(16) -0.12135(12) 0.0251(6) Uani 1 1 d . . . . .
H108 H -0.0267 0.4164 -0.1034 0.030 Uiso 1 1 calc R U . . .
C109 C -0.0818(2) 0.33816(16) -0.14960(13) 0.0276(6) Uani 1 1 d . . . . .
H109 H -0.1527 0.3566 -0.1502 0.033 Uiso 1 1 calc R U . . .
C110 C -0.0535(2) 0.27634(17) -0.17701(14) 0.0322(7) Uani 1 1 d . . . . .
H110 H -0.1044 0.2534 -0.1975 0.039 Uiso 1 1 calc R U . . .
C111 C 0.0496(2) 0.24770(16) -0.17461(13) 0.0269(6) Uani 1 1 d . . . . .
H111 H 0.0690 0.2048 -0.1929 0.032 Uiso 1 1 calc R U . . .
C112 C 0.25625(19) 0.14640(14) -0.14835(11) 0.0179(5) Uani 1 1 d . . . . .
C113 C 0.2560(2) 0.09111(14) -0.09840(12) 0.0207(5) Uani 1 1 d . . . . .
H113 H 0.2587 0.1056 -0.0605 0.025 Uiso 1 1 calc R U . . .
C114 C 0.2519(2) 0.01477(15) -0.10446(14) 0.0269(6) Uani 1 1 d . . . . .
H114 H 0.2520 -0.0234 -0.0707 0.032 Uiso 1 1 calc R U . . .
C115 C 0.2474(2) -0.00546(16) -0.15951(15) 0.0310(7) Uani 1 1 d . . . . .
H115 H 0.2443 -0.0577 -0.1637 0.037 Uiso 1 1 calc R U . . .
C116 C 0.2476(2) 0.04962(18) -0.20871(14) 0.0342(7) Uani 1 1 d . . . . .
H116 H 0.2444 0.0350 -0.2465 0.041 Uiso 1 1 calc R U . . .
C117 C 0.2524(2) 0.12602(16) -0.20358(12) 0.0244(6) Uani 1 1 d . . . . .
H117 H 0.2530 0.1639 -0.2375 0.029 Uiso 1 1 calc R U . . .
C201 C 0.18049(19) 0.23372(15) 0.22932(11) 0.0192(5) Uani 1 1 d . . . . .
C202 C 0.1294(2) 0.30346(16) 0.21589(13) 0.0267(6) Uani 1 1 d . . . . .
H202 H 0.1204 0.3259 0.1762 0.032 Uiso 1 1 calc R U . . .
C203 C 0.0911(2) 0.34060(18) 0.26166(16) 0.0361(7) Uani 1 1 d . . . . .
H203 H 0.0557 0.3887 0.2534 0.043 Uiso 1 1 calc R U . . .
C204 C 0.1049(2) 0.3072(2) 0.31855(15) 0.0400(8) Uani 1 1 d . . . . .
H204 H 0.0783 0.3318 0.3499 0.048 Uiso 1 1 calc R U . . .
C205 C 0.1572(3) 0.2380(2) 0.33028(14) 0.0392(8) Uani 1 1 d . . . . .
H205 H 0.1668 0.2158 0.3700 0.047 Uiso 1 1 calc R U . . .
C206 C 0.37320(19) 0.17219(14) 0.18523(11) 0.0171(5) Uani 1 1 d . . . . .
C207 C 0.4381(2) 0.23360(15) 0.16689(12) 0.0211(5) Uani 1 1 d . . . . .
H207 H 0.4093 0.2800 0.1468 0.025 Uiso 1 1 calc R U . . .
C208 C 0.5449(2) 0.22683(17) 0.17802(13) 0.0270(6) Uani 1 1 d . . . . .
H208 H 0.5895 0.2684 0.1650 0.032 Uiso 1 1 calc R U . . .
C209 C 0.5861(2) 0.16003(17) 0.20786(13) 0.0288(6) Uani 1 1 d . . . . .
H209 H 0.6592 0.1559 0.2158 0.035 Uiso 1 1 calc R U . . .
C210 C 0.5222(2) 0.09875(17) 0.22647(13) 0.0300(6) Uani 1 1 d . . . . .
H210 H 0.5514 0.0526 0.2468 0.036 Uiso 1 1 calc R U . . .
C211 C 0.4152(2) 0.10474(15) 0.21545(12) 0.0235(5) Uani 1 1 d . . . . .
H211 H 0.3709 0.0630 0.2285 0.028 Uiso 1 1 calc R U . . .
C212 C 0.17548(19) 0.09377(13) 0.17717(11) 0.0171(5) Uani 1 1 d . . . . .
C213 C 0.1354(2) 0.07233(15) 0.12702(12) 0.0218(5) Uani 1 1 d . . . . .
H213 H 0.1394 0.1054 0.0905 0.026 Uiso 1 1 calc R U . . .
C214 C 0.0895(2) 0.00170(17) 0.13125(15) 0.0337(7) Uani 1 1 d . . . . .
H214 H 0.0606 -0.0140 0.0977 0.040 Uiso 1 1 calc R U . . .
C215 C 0.0862(3) -0.04540(17) 0.18453(17) 0.0417(8) Uani 1 1 d . . . . .
H215 H 0.0557 -0.0941 0.1879 0.050 Uiso 1 1 calc R U . . .
C216 C 0.1274(3) -0.02152(19) 0.23297(16) 0.0457(9) Uani 1 1 d . . . . .
H216 H 0.1249 -0.0545 0.2695 0.055 Uiso 1 1 calc R U . . .
C217 C 0.1715(2) 0.04789(15) 0.22988(12) 0.0242(6) Uani 1 1 d . . . . .
H217 H 0.1988 0.0638 0.2637 0.029 Uiso 1 1 calc R U . . .
F21 F 0.7132(5) 0.1893(3) 0.0360(4) 0.0341(5) Uiso 0.336(4) 1 d D . P A 1
F22 F 0.6576(6) 0.3038(4) 0.0359(3) 0.0341(5) Uiso 0.336(4) 1 d D . P A 1
F23 F 0.6618(5) 0.2511(4) -0.0444(3) 0.0341(5) Uiso 0.336(4) 1 d D . P A 1
C21 C 0.6407(7) 0.2412(5) 0.0151(4) 0.0226(8) Uiso 0.336(4) 1 d D . P A 1
F1B F 0.7059(7) 0.2073(6) 0.0534(4) 0.0341(5) Uiso 0.211(4) 1 d D . P A 2
F2B F 0.6552(9) 0.3145(4) 0.0011(5) 0.0341(5) Uiso 0.211(4) 1 d D . P A 2
F3B F 0.6814(8) 0.2138(6) -0.0405(4) 0.0341(5) Uiso 0.211(4) 1 d D . P A 2
C4B C 0.6433(9) 0.2396(7) 0.0089(6) 0.0226(8) Uiso 0.211(4) 1 d D . P A 2
F1C F 0.7112(7) 0.1951(4) 0.0046(5) 0.0341(5) Uiso 0.226(4) 1 d D . P A 3
F2C F 0.6633(11) 0.3072(6) 0.0201(5) 0.0341(5) Uiso 0.226(4) 1 d D . P A 3
F3C F 0.6372(7) 0.2797(5) -0.0637(3) 0.0341(5) Uiso 0.226(4) 1 d D . P A 3
C4C C 0.6367(8) 0.2504(6) -0.0082(5) 0.0226(8) Uiso 0.226(4) 1 d D . P A 3
F1D F 0.6855(6) 0.2644(5) 0.0489(3) 0.0341(5) Uiso 0.227(3) 1 d D . P A 4
F2D F 0.6414(6) 0.3117(4) -0.0376(4) 0.0341(5) Uiso 0.227(3) 1 d D . P A 4
F3D F 0.7024(7) 0.1964(5) -0.0213(4) 0.0341(5) Uiso 0.227(3) 1 d D . P A 4
C4D C 0.6391(9) 0.2485(7) -0.0005(5) 0.0226(8) Uiso 0.227(3) 1 d D . P A 4
Eu2 Eu 0.74457(2) 0.22962(2) 0.48880(2) 0.01280(3) Uani 1 1 d . . . . .
P3 P 0.76024(5) 0.27124(4) 0.64048(3) 0.01617(12) Uani 1 1 d . . . . .
P4 P 0.77396(5) 0.30482(4) 0.32947(3) 0.01536(12) Uani 1 1 d . . . . .
F41 F 0.5989(2) 0.03287(11) 0.64840(10) 0.0677(8) Uani 1 1 d . . . . .
F42 F 0.7539(2) -0.01201(15) 0.63797(10) 0.0747(8) Uani 1 1 d . . . . .
F43 F 0.6236(2) -0.06780(10) 0.61036(9) 0.0595(7) Uani 1 1 d . . . . .
F45 F 0.63364(19) 0.05667(10) 0.34912(8) 0.0515(6) Uani 1 1 d . . . . .
F46 F 0.6282(2) -0.04971(11) 0.40656(9) 0.0711(8) Uani 1 1 d . . . . .
F47 F 0.7760(2) -0.00096(14) 0.37718(10) 0.0643(7) Uani 1 1 d . . . . .
F51 F 0.37405(13) 0.18562(10) 0.45676(10) 0.0469(5) Uani 1 1 d . . . . .
F52 F 0.30538(13) 0.29798(10) 0.44677(10) 0.0432(5) Uani 1 1 d . . . . .
F53 F 0.34281(15) 0.24034(13) 0.53202(10) 0.0524(6) Uani 1 1 d . . . . .
F55 F 0.51043(13) 0.51770(9) 0.42957(9) 0.0360(4) Uani 1 1 d . . . . .
F56 F 0.65782(15) 0.51304(9) 0.47233(8) 0.0351(4) Uani 1 1 d . . . . .
F57 F 0.65355(15) 0.49596(9) 0.38283(8) 0.0370(4) Uani 1 1 d . . . . .
F61 F 0.99204(14) 0.41293(11) 0.54765(9) 0.0444(5) Uani 1 1 d . . . . .
F62 F 1.05008(17) 0.42136(10) 0.45899(9) 0.0478(5) Uani 1 1 d . . . . .
F63 F 1.14113(13) 0.36211(10) 0.52901(9) 0.0432(5) Uani 1 1 d . . . . .
F65 F 1.04695(14) 0.07680(10) 0.42587(8) 0.0364(4) Uani 1 1 d . . . . .
F66 F 1.17588(13) 0.12422(10) 0.46459(11) 0.0489(6) Uani 1 1 d . . . . .
F67 F 1.07153(13) 0.04814(9) 0.51899(8) 0.0338(4) Uani 1 1 d . . . . .
O3 O 0.71708(13) 0.26357(9) 0.58212(8) 0.0179(4) Uani 1 1 d . . . . .
O4 O 0.79438(14) 0.27291(10) 0.39226(8) 0.0193(4) Uani 1 1 d . . . . .
O41 O 0.70565(14) 0.11583(9) 0.55630(8) 0.0191(4) Uani 1 1 d . . . . .
O42 O 0.70698(14) 0.12705(9) 0.43390(8) 0.0188(4) Uani 1 1 d . . . . .
O51 O 0.55875(13) 0.23352(9) 0.48427(8) 0.0186(4) Uani 1 1 d . . . . .
O52 O 0.68293(13) 0.36195(9) 0.46594(8) 0.0194(4) Uani 1 1 d . . . . .
O61 O 0.88891(13) 0.30903(10) 0.50356(8) 0.0185(4) Uani 1 1 d . . . . .
O62 O 0.90648(13) 0.15689(9) 0.48647(8) 0.0190(4) Uani 1 1 d . . . . .
N3 N 0.7186(2) 0.21158(18) 0.75368(12) 0.0462(8) Uani 1 1 d . . . . .
N4 N 0.8307(2) 0.42879(15) 0.25163(12) 0.0392(7) Uani 1 1 d . . . . .
C41 C 0.6609(3) -0.00028(16) 0.61234(13) 0.0324(7) Uani 1 1 d . . . . .
C42 C 0.6756(2) 0.05033(14) 0.55270(11) 0.0189(5) Uani 1 1 d . . . . .
C43 C 0.6591(2) 0.01841(14) 0.50285(12) 0.0223(5) Uani 1 1 d . . . . .
H43 H 0.6328 -0.0317 0.5065 0.027 Uiso 1 1 calc R U . . .
C44 C 0.6808(2) 0.05905(14) 0.44757(12) 0.0207(5) Uani 1 1 d . . . . .
C45 C 0.6784(3) 0.01601(16) 0.39479(14) 0.0354(8) Uani 1 1 d . . . . .
C51 C 0.3765(2) 0.25169(16) 0.47661(15) 0.0301(7) Uani 1 1 d . . . . .
C52 C 0.48788(19) 0.28321(14) 0.47147(12) 0.0191(5) Uani 1 1 d . . . . .
C53 C 0.49832(19) 0.36156(15) 0.45542(12) 0.0211(5) Uani 1 1 d . . . . .
H53 H 0.4377 0.3929 0.4454 0.025 Uiso 1 1 calc R U . . .
C54 C 0.59652(19) 0.39435(14) 0.45395(11) 0.0176(5) Uani 1 1 d . . . . .
C55 C 0.6037(2) 0.48093(14) 0.43464(12) 0.0202(5) Uani 1 1 d . . . . .
C61 C 1.0438(2) 0.37499(15) 0.51034(12) 0.0230(5) Uani 1 1 d . . . . .
C62 C 0.98674(19) 0.30262(14) 0.50232(11) 0.0171(5) Uani 1 1 d . . . . .
C63 C 1.04881(19) 0.23920(14) 0.49270(12) 0.0205(5) Uani 1 1 d . . . . .
H63 H 1.1234 0.2422 0.4915 0.025 Uiso 1 1 calc R U . . .
C64 C 1.00232(19) 0.17159(14) 0.48481(12) 0.0191(5) Uani 1 1 d . . . . .
C65 C 1.0753(2) 0.10423(15) 0.47345(14) 0.0280(6) Uani 1 1 d . . . . .
C301 C 0.6797(2) 0.21962(15) 0.69827(12) 0.0224(5) Uani 1 1 d . . . . .
C302 C 0.5845(2) 0.19257(17) 0.68542(14) 0.0324(7) Uani 1 1 d . . . . .
H302 H 0.5609 0.1996 0.6463 0.039 Uiso 1 1 calc R U . . .
C303 C 0.5233(3) 0.1545(2) 0.73151(18) 0.0480(9) Uani 1 1 d . . . . .
H303 H 0.4569 0.1351 0.7243 0.058 Uiso 1 1 calc R U . . .
C304 C 0.5606(3) 0.1456(2) 0.78743(18) 0.0553(11) Uani 1 1 d . . . . .
H304 H 0.5203 0.1199 0.8195 0.066 Uiso 1 1 calc R U . . .
C305 C 0.6574(3) 0.1744(3) 0.79650(17) 0.0587(12) Uani 1 1 d . . . . .
H305 H 0.6820 0.1675 0.8354 0.070 Uiso 1 1 calc R U . . .
C306 C 0.75868(19) 0.36961(14) 0.65073(11) 0.0185(5) Uani 1 1 d . . . . .
C307 C 0.7486(2) 0.42438(14) 0.60084(12) 0.0210(5) Uani 1 1 d . . . . .
H307 H 0.7423 0.4096 0.5633 0.025 Uiso 1 1 calc R U . . .
C308 C 0.7478(2) 0.50088(16) 0.60697(14) 0.0287(6) Uani 1 1 d . . . . .
H308 H 0.7409 0.5389 0.5734 0.034 Uiso 1 1 calc R U . . .
C309 C 0.7570(2) 0.52195(17) 0.66116(16) 0.0349(7) Uani 1 1 d . . . . .
H309 H 0.7561 0.5745 0.6649 0.042 Uiso 1 1 calc R U . . .
C310 C 0.7675(2) 0.4676(2) 0.71032(15) 0.0394(8) Uani 1 1 d . . . . .
H310 H 0.7742 0.4829 0.7477 0.047 Uiso 1 1 calc R U . . .
C311 C 0.7684(2) 0.39060(18) 0.70562(12) 0.0283(6) Uani 1 1 d . . . . .
H311 H 0.7755 0.3530 0.7394 0.034 Uiso 1 1 calc R U . . .
C312 C 0.8933(2) 0.23353(15) 0.64859(11) 0.0202(5) Uani 1 1 d . . . . .
C313 C 0.9144(2) 0.16115(15) 0.63424(11) 0.0218(5) Uani 1 1 d . . . . .
H313 H 0.8592 0.1326 0.6223 0.026 Uiso 1 1 calc R U . . .
C314 C 1.0164(2) 0.13080(17) 0.63746(13) 0.0292(6) Uani 1 1 d . . . . .
H314 H 1.0311 0.0814 0.6277 0.035 Uiso 1 1 calc R U . . .
C315 C 1.0965(2) 0.17244(19) 0.65482(14) 0.0352(7) Uani 1 1 d . . . . .
H315 H 1.1663 0.1516 0.6570 0.042 Uiso 1 1 calc R U . . .
C316 C 1.0759(2) 0.2440(2) 0.66903(16) 0.0428(8) Uani 1 1 d . . . . .
H316 H 1.1315 0.2723 0.6808 0.051 Uiso 1 1 calc R U . . .
C317 C 0.9739(2) 0.27500(18) 0.66617(14) 0.0326(7) Uani 1 1 d . . . . .
H317 H 0.9597 0.3243 0.6762 0.039 Uiso 1 1 calc R U . . .
C401 C 0.8332(2) 0.39603(14) 0.30917(12) 0.0207(5) Uani 1 1 d . . . . .
C402 C 0.8790(2) 0.43078(15) 0.35162(12) 0.0239(6) Uani 1 1 d . . . . .
H402 H 0.8789 0.4070 0.3914 0.029 Uiso 1 1 calc R U . . .
C403 C 0.9253(3) 0.50108(17) 0.33475(15) 0.0355(7) Uani 1 1 d . . . . .
H403 H 0.9582 0.5256 0.3629 0.043 Uiso 1 1 calc R U . . .
C404 C 0.9229(3) 0.53476(18) 0.27702(15) 0.0401(8) Uani 1 1 d . . . . .
H404 H 0.9534 0.5831 0.2652 0.048 Uiso 1 1 calc R U . . .
C405 C 0.8760(3) 0.49824(19) 0.23630(15) 0.0432(9) Uani 1 1 d . . . . .
H405 H 0.8752 0.5220 0.1965 0.052 Uiso 1 1 calc R U . . .
C406 C 0.63604(19) 0.31578(14) 0.31476(11) 0.0170(5) Uani 1 1 d . . . . .
C407 C 0.5739(2) 0.25187(15) 0.33059(11) 0.0206(5) Uani 1 1 d . . . . .
H407 H 0.6049 0.2050 0.3485 0.025 Uiso 1 1 calc R U . . .
C408 C 0.4671(2) 0.25699(15) 0.32016(12) 0.0235(6) Uani 1 1 d . . . . .
H408 H 0.4248 0.2135 0.3309 0.028 Uiso 1 1 calc R U . . .
C409 C 0.4219(2) 0.32496(16) 0.29428(13) 0.0263(6) Uani 1 1 d . . . . .
H409 H 0.3488 0.3279 0.2866 0.032 Uiso 1 1 calc R U . . .
C410 C 0.4821(2) 0.38853(17) 0.27958(13) 0.0294(6) Uani 1 1 d . . . . .
H410 H 0.4500 0.4355 0.2627 0.035 Uiso 1 1 calc R U . . .
C411 C 0.5898(2) 0.38450(15) 0.28925(12) 0.0237(6) Uani 1 1 d . . . . .
H411 H 0.6314 0.4283 0.2785 0.028 Uiso 1 1 calc R U . . .
C412 C 0.8304(2) 0.24018(16) 0.28304(12) 0.0233(6) Uani 1 1 d . . . . .
C413 C 0.8769(3) 0.17281(19) 0.30897(16) 0.0382(8) Uani 1 1 d . . . . .
H413 H 0.8800 0.1611 0.3505 0.046 Uiso 1 1 calc R U . . .
C414 C 0.9190(3) 0.1223(2) 0.2738(2) 0.0528(10) Uani 1 1 d . . . . .
H414 H 0.9502 0.0752 0.2911 0.063 Uiso 1 1 calc R U . . .
C415 C 0.9157(3) 0.1404(2) 0.21445(19) 0.0501(11) Uani 1 1 d . . . . .
H415 H 0.9453 0.1064 0.1900 0.060 Uiso 1 1 calc R U . . .
C416 C 0.8690(3) 0.2084(2) 0.19013(17) 0.0491(10) Uani 1 1 d . . . . .
H416 H 0.8669 0.2209 0.1486 0.059 Uiso 1 1 calc R U . . .
C417 C 0.8255(2) 0.25825(18) 0.22415(13) 0.0303(7) Uani 1 1 d . . . . .
H417 H 0.7924 0.3046 0.2068 0.036 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.3384(17) . ?
Eu1 O2 2.3296(17) . ?
Eu1 O11 2.4119(16) . ?
Eu1 O12 2.4069(17) . ?
Eu1 O21 2.3871(17) . ?
Eu1 O22 2.4309(17) . ?
Eu1 O31 2.4024(16) . ?
Eu1 O32 2.4180(17) . ?
P1 O1 1.4999(18) . ?
P1 C101 1.807(3) . ?
P1 C106 1.804(3) . ?
P1 C112 1.798(2) . ?
P2 O2 1.5011(18) . ?
P2 C201 1.799(3) . ?
P2 C206 1.800(3) . ?
P2 C212 1.807(2) . ?
F11 C11 1.330(3) . ?
F12 C11 1.343(3) . ?
F13 C11 1.335(3) . ?
F15 C15 1.322(3) . ?
F16 C15 1.329(3) . ?
F17 C15 1.323(3) . ?
F25 C25 1.340(3) . ?
F26 C25 1.340(3) . ?
F27 C25 1.332(3) . ?
F31 C31 1.316(3) . ?
F32 C31 1.321(3) . ?
F33 C31 1.322(3) . ?
F35 C35 1.331(4) . ?
F36 C35 1.305(3) . ?
F37 C35 1.322(3) . ?
O11 C12 1.251(3) . ?
O12 C14 1.251(3) . ?
O21 C22 1.253(3) . ?
O22 C24 1.254(3) . ?
O31 C32 1.247(3) . ?
O32 C34 1.249(3) . ?
N1 C101 1.369(4) . ?
N1 C105 1.348(4) . ?
N2 C201 1.379(4) . ?
N2 C205 1.379(4) . ?
C11 C12 1.538(4) . ?
C12 C13 1.389(4) . ?
C13 H13 0.9500 . ?
C13 C14 1.389(4) . ?
C14 C15 1.534(4) . ?
C22 C23 1.387(4) . ?
C22 C21 1.509(9) . ?
C22 C4B 1.542(12) . ?
C22 C4C 1.606(11) . ?
C22 C4D 1.573(11) . ?
C23 H23 0.9500 . ?
C23 C24 1.384(4) . ?
C24 C25 1.539(3) . ?
C31 C32 1.532(3) . ?
C32 C33 1.392(4) . ?
C33 H33 0.9500 . ?
C33 C34 1.388(4) . ?
C34 C35 1.536(4) . ?
C101 C102 1.376(4) . ?
C102 H102 0.9500 . ?
C102 C103 1.391(4) . ?
C103 H103 0.9500 . ?
C103 C104 1.377(5) . ?
C104 H104 0.9500 . ?
C104 C105 1.381(5) . ?
C105 H105 0.9500 . ?
C106 C107 1.391(4) . ?
C106 C111 1.390(4) . ?
C107 H107 0.9500 . ?
C107 C108 1.386(4) . ?
C108 H108 0.9500 . ?
C108 C109 1.383(4) . ?
C109 H109 0.9500 . ?
C109 C110 1.383(4) . ?
C110 H110 0.9500 . ?
C110 C111 1.390(4) . ?
C111 H111 0.9500 . ?
C112 C113 1.394(4) . ?
C112 C117 1.381(4) . ?
C113 H113 0.9500 . ?
C113 C114 1.387(3) . ?
C114 H114 0.9500 . ?
C114 C115 1.376(4) . ?
C115 H115 0.9500 . ?
C115 C116 1.379(5) . ?
C116 H116 0.9500 . ?
C116 C117 1.383(4) . ?
C117 H117 0.9500 . ?
C201 C202 1.378(4) . ?
C202 H202 0.9500 . ?
C202 C203 1.397(4) . ?
C203 H203 0.9500 . ?
C203 C204 1.369(5) . ?
C204 H204 0.9500 . ?
C204 C205 1.372(5) . ?
C205 H205 0.9500 . ?
C206 C207 1.392(3) . ?
C206 C211 1.390(4) . ?
C207 H207 0.9500 . ?
C207 C208 1.388(4) . ?
C208 H208 0.9500 . ?
C208 C209 1.375(4) . ?
C209 H209 0.9500 . ?
C209 C210 1.384(4) . ?
C210 H210 0.9500 . ?
C210 C211 1.390(4) . ?
C211 H211 0.9500 . ?
C212 C213 1.389(4) . ?
C212 C217 1.356(3) . ?
C213 H213 0.9500 . ?
C213 C214 1.388(4) . ?
C214 H214 0.9500 . ?
C214 C215 1.376(5) . ?
C215 H215 0.9500 . ?
C215 C216 1.379(5) . ?
C216 H216 0.9500 . ?
C216 C217 1.361(4) . ?
C217 H217 0.9500 . ?
F21 C21 1.331(9) . ?
F22 C21 1.303(9) . ?
F23 C21 1.377(9) . ?
F1B C4B 1.364(12) . ?
F2B C4B 1.327(12) . ?
F3B C4B 1.363(12) . ?
F1C C4C 1.349(11) . ?
F2C C4C 1.340(11) . ?
F3C C4C 1.306(11) . ?
F1D C4D 1.373(11) . ?
F2D C4D 1.303(11) . ?
F3D C4D 1.341(11) . ?
Eu2 O3 2.3378(17) . ?
Eu2 O4 2.3161(17) . ?
Eu2 O41 2.4068(17) . ?
Eu2 O42 2.4413(16) . ?
Eu2 O51 2.3658(17) . ?
Eu2 O52 2.4389(17) . ?
Eu2 O61 2.4116(16) . ?
Eu2 O62 2.3999(17) . ?
P3 O3 1.4977(18) . ?
P3 C301 1.805(3) . ?
P3 C306 1.799(3) . ?
P3 C312 1.804(3) . ?
P4 O4 1.4998(18) . ?
P4 C401 1.796(3) . ?
P4 C406 1.795(3) . ?
P4 C412 1.806(3) . ?
F41 C41 1.319(4) . ?
F42 C41 1.336(4) . ?
F43 C41 1.311(3) . ?
F45 C45 1.317(3) . ?
F46 C45 1.334(4) . ?
F47 C45 1.334(4) . ?
F51 C51 1.326(3) . ?
F52 C51 1.337(3) . ?
F53 C51 1.323(4) . ?
F55 C55 1.336(3) . ?
F56 C55 1.331(3) . ?
F57 C55 1.328(3) . ?
F61 C61 1.321(3) . ?
F62 C61 1.336(3) . ?
F63 C61 1.325(3) . ?
F65 C65 1.332(4) . ?
F66 C65 1.338(3) . ?
F67 C65 1.332(3) . ?
O41 C42 1.251(3) . ?
O42 C44 1.252(3) . ?
O51 C52 1.251(3) . ?
O52 C54 1.243(3) . ?
O61 C62 1.245(3) . ?
O62 C64 1.252(3) . ?
N3 C301 1.371(4) . ?
N3 C305 1.341(5) . ?
N4 C401 1.366(4) . ?
N4 C405 1.369(4) . ?
C41 C42 1.532(4) . ?
C42 C43 1.383(4) . ?
C43 H43 0.9500 . ?
C43 C44 1.389(4) . ?
C44 C45 1.537(4) . ?
C51 C52 1.532(4) . ?
C52 C53 1.393(4) . ?
C53 H53 0.9500 . ?
C53 C54 1.390(3) . ?
C54 C55 1.538(3) . ?
C61 C62 1.533(3) . ?
C62 C63 1.398(4) . ?
C63 H63 0.9500 . ?
C63 C64 1.394(3) . ?
C64 C65 1.541(4) . ?
C301 C302 1.373(4) . ?
C302 H302 0.9500 . ?
C302 C303 1.396(4) . ?
C303 H303 0.9500 . ?
C303 C304 1.374(6) . ?
C304 H304 0.9500 . ?
C304 C305 1.381(6) . ?
C305 H305 0.9500 . ?
C306 C307 1.394(4) . ?
C306 C311 1.385(4) . ?
C307 H307 0.9500 . ?
C307 C308 1.387(4) . ?
C308 H308 0.9500 . ?
C308 C309 1.369(4) . ?
C309 H309 0.9500 . ?
C309 C310 1.379(5) . ?
C310 H310 0.9500 . ?
C310 C311 1.388(4) . ?
C311 H311 0.9500 . ?
C312 C313 1.393(4) . ?
C312 C317 1.387(4) . ?
C313 H313 0.9500 . ?
C313 C314 1.389(4) . ?
C314 H314 0.9500 . ?
C314 C315 1.381(4) . ?
C315 H315 0.9500 . ?
C315 C316 1.377(5) . ?
C316 H316 0.9500 . ?
C316 C317 1.392(4) . ?
C317 H317 0.9500 . ?
C401 C402 1.388(4) . ?
C402 H402 0.9500 . ?
C402 C403 1.391(4) . ?
C403 H403 0.9500 . ?
C403 C404 1.374(4) . ?
C404 H404 0.9500 . ?
C404 C405 1.381(4) . ?
C405 H405 0.9500 . ?
C406 C407 1.397(3) . ?
C406 C411 1.393(4) . ?
C407 H407 0.9500 . ?
C407 C408 1.384(4) . ?
C408 H408 0.9500 . ?
C408 C409 1.379(4) . ?
C409 H409 0.9500 . ?
C409 C410 1.375(4) . ?
C410 H410 0.9500 . ?
C410 C411 1.391(4) . ?
C411 H411 0.9500 . ?
C412 C413 1.377(4) . ?
C412 C417 1.351(4) . ?
C413 H413 0.9500 . ?
C413 C414 1.385(4) . ?
C414 H414 0.9500 . ?
C414 C415 1.359(6) . ?
C415 H415 0.9500 . ?
C415 C416 1.376(6) . ?
C416 H416 0.9500 . ?
C416 C417 1.366(4) . ?
C417 H417 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O11 141.02(6) . . ?
O1 Eu1 O12 72.32(6) . . ?
O1 Eu1 O21 81.67(6) . . ?
O1 Eu1 O22 80.10(6) . . ?
O1 Eu1 O31 72.78(6) . . ?
O1 Eu1 O32 111.31(6) . . ?
O2 Eu1 O1 145.70(6) . . ?
O2 Eu1 O11 72.96(6) . . ?
O2 Eu1 O12 141.38(6) . . ?
O2 Eu1 O21 106.73(6) . . ?
O2 Eu1 O22 72.05(6) . . ?
O2 Eu1 O31 80.40(6) . . ?
O2 Eu1 O32 78.26(6) . . ?
O11 Eu1 O22 124.47(6) . . ?
O11 Eu1 O32 73.20(6) . . ?
O12 Eu1 O11 70.65(6) . . ?
O12 Eu1 O22 141.68(6) . . ?
O12 Eu1 O32 79.31(6) . . ?
O21 Eu1 O11 79.91(6) . . ?
O21 Eu1 O12 79.23(6) . . ?
O21 Eu1 O22 70.75(6) . . ?
O21 Eu1 O31 139.12(6) . . ?
O21 Eu1 O32 149.89(6) . . ?
O31 Eu1 O11 138.56(6) . . ?
O31 Eu1 O12 120.48(6) . . ?
O31 Eu1 O22 73.76(6) . . ?
O31 Eu1 O32 70.68(6) . . ?
O32 Eu1 O22 136.65(6) . . ?
O1 P1 C101 109.26(11) . . ?
O1 P1 C106 112.08(11) . . ?
O1 P1 C112 110.88(11) . . ?
C106 P1 C101 108.23(12) . . ?
C112 P1 C101 108.95(12) . . ?
C112 P1 C106 107.35(11) . . ?
O2 P2 C201 109.85(11) . . ?
O2 P2 C206 112.65(11) . . ?
O2 P2 C212 110.71(11) . . ?
C201 P2 C206 105.92(11) . . ?
C201 P2 C212 108.61(12) . . ?
C206 P2 C212 108.92(11) . . ?
P1 O1 Eu1 150.07(10) . . ?
P2 O2 Eu1 149.30(11) . . ?
C12 O11 Eu1 134.81(16) . . ?
C14 O12 Eu1 135.89(17) . . ?
C22 O21 Eu1 135.85(16) . . ?
C24 O22 Eu1 135.78(16) . . ?
C32 O31 Eu1 135.27(16) . . ?
C34 O32 Eu1 133.16(15) . . ?
C105 N1 C101 116.3(3) . . ?
C205 N2 C201 117.1(3) . . ?
F11 C11 F12 107.0(2) . . ?
F11 C11 F13 107.3(2) . . ?
F11 C11 C12 111.8(2) . . ?
F12 C11 C12 109.8(2) . . ?
F13 C11 F12 106.4(2) . . ?
F13 C11 C12 114.1(2) . . ?
O11 C12 C11 113.0(2) . . ?
O11 C12 C13 128.5(2) . . ?
C13 C12 C11 118.5(2) . . ?
C12 C13 H13 120.0 . . ?
C14 C13 C12 119.9(2) . . ?
C14 C13 H13 120.0 . . ?
O12 C14 C13 128.5(2) . . ?
O12 C14 C15 113.0(2) . . ?
C13 C14 C15 118.5(2) . . ?
F15 C15 F16 107.1(2) . . ?
F15 C15 F17 106.7(2) . . ?
F15 C15 C14 114.3(2) . . ?
F16 C15 C14 110.0(2) . . ?
F17 C15 F16 107.7(3) . . ?
F17 C15 C14 110.8(2) . . ?
O21 C22 C23 128.6(2) . . ?
O21 C22 C21 116.6(4) . . ?
O21 C22 C4B 117.9(5) . . ?
O21 C22 C4C 109.5(5) . . ?
O21 C22 C4D 111.5(5) . . ?
C23 C22 C21 114.3(4) . . ?
C23 C22 C4B 113.5(5) . . ?
C23 C22 C4C 120.9(5) . . ?
C23 C22 C4D 119.7(5) . . ?
C22 C23 H23 119.4 . . ?
C24 C23 C22 121.1(2) . . ?
C24 C23 H23 119.4 . . ?
O22 C24 C23 127.3(2) . . ?
O22 C24 C25 113.6(2) . . ?
C23 C24 C25 119.1(2) . . ?
F25 C25 F26 106.5(2) . . ?
F25 C25 C24 113.4(2) . . ?
F26 C25 C24 110.6(2) . . ?
F27 C25 F25 107.6(2) . . ?
F27 C25 F26 107.0(2) . . ?
F27 C25 C24 111.3(2) . . ?
F31 C31 F32 106.7(2) . . ?
F31 C31 F33 105.9(3) . . ?
F31 C31 C32 111.7(2) . . ?
F32 C31 F33 108.1(3) . . ?
F32 C31 C32 112.0(2) . . ?
F33 C31 C32 112.1(2) . . ?
O31 C32 C31 115.7(2) . . ?
O31 C32 C33 127.5(2) . . ?
C33 C32 C31 116.8(2) . . ?
C32 C33 H33 119.5 . . ?
C34 C33 C32 121.1(2) . . ?
C34 C33 H33 119.5 . . ?
O32 C34 C33 128.2(2) . . ?
O32 C34 C35 114.7(2) . . ?
C33 C34 C35 117.1(2) . . ?
F35 C35 C34 110.4(3) . . ?
F36 C35 F35 107.3(3) . . ?
F36 C35 F37 108.3(3) . . ?
F36 C35 C34 112.4(2) . . ?
F37 C35 F35 105.0(3) . . ?
F37 C35 C34 113.0(2) . . ?
N1 C101 P1 116.8(2) . . ?
N1 C101 C102 123.6(3) . . ?
C102 C101 P1 119.7(2) . . ?
C101 C102 H102 120.9 . . ?
C101 C102 C103 118.2(3) . . ?
C103 C102 H102 120.9 . . ?
C102 C103 H103 120.2 . . ?
C104 C103 C102 119.6(3) . . ?
C104 C103 H103 120.2 . . ?
C103 C104 H104 120.6 . . ?
C103 C104 C105 118.8(3) . . ?
C105 C104 H104 120.6 . . ?
N1 C105 C104 123.6(3) . . ?
N1 C105 H105 118.2 . . ?
C104 C105 H105 118.2 . . ?
C107 C106 P1 118.03(19) . . ?
C111 C106 P1 122.0(2) . . ?
C111 C106 C107 119.9(2) . . ?
C106 C107 H107 120.1 . . ?
C108 C107 C106 119.8(2) . . ?
C108 C107 H107 120.1 . . ?
C107 C108 H108 119.9 . . ?
C109 C108 C107 120.2(3) . . ?
C109 C108 H108 119.9 . . ?
C108 C109 H109 119.9 . . ?
C110 C109 C108 120.2(3) . . ?
C110 C109 H109 119.9 . . ?
C109 C110 H110 120.0 . . ?
C109 C110 C111 120.0(3) . . ?
C111 C110 H110 120.0 . . ?
C106 C111 C110 119.8(3) . . ?
C106 C111 H111 120.1 . . ?
C110 C111 H111 120.1 . . ?
C113 C112 P1 116.77(19) . . ?
C117 C112 P1 122.4(2) . . ?
C117 C112 C113 120.8(2) . . ?
C112 C113 H113 120.3 . . ?
C114 C113 C112 119.4(3) . . ?
C114 C113 H113 120.3 . . ?
C113 C114 H114 120.1 . . ?
C115 C114 C113 119.8(3) . . ?
C115 C114 H114 120.1 . . ?
C114 C115 H115 119.8 . . ?
C114 C115 C116 120.5(3) . . ?
C116 C115 H115 119.8 . . ?
C115 C116 H116 119.7 . . ?
C115 C116 C117 120.6(3) . . ?
C117 C116 H116 119.7 . . ?
C112 C117 C116 119.0(3) . . ?
C112 C117 H117 120.5 . . ?
C116 C117 H117 120.5 . . ?
N2 C201 P2 117.6(2) . . ?
C202 C201 P2 120.0(2) . . ?
C202 C201 N2 122.4(2) . . ?
C201 C202 H202 120.6 . . ?
C201 C202 C203 118.8(3) . . ?
C203 C202 H202 120.6 . . ?
C202 C203 H203 120.2 . . ?
C204 C203 C202 119.6(3) . . ?
C204 C203 H203 120.2 . . ?
C203 C204 H204 120.0 . . ?
C203 C204 C205 120.0(3) . . ?
C205 C204 H204 120.0 . . ?
N2 C205 H205 118.9 . . ?
C204 C205 N2 122.2(3) . . ?
C204 C205 H205 118.9 . . ?
C207 C206 P2 117.49(19) . . ?
C211 C206 P2 122.5(2) . . ?
C211 C206 C207 120.0(2) . . ?
C206 C207 H207 120.1 . . ?
C208 C207 C206 119.8(3) . . ?
C208 C207 H207 120.1 . . ?
C207 C208 H208 120.0 . . ?
C209 C208 C207 120.0(3) . . ?
C209 C208 H208 120.0 . . ?
C208 C209 H209 119.7 . . ?
C208 C209 C210 120.5(3) . . ?
C210 C209 H209 119.7 . . ?
C209 C210 H210 120.0 . . ?
C209 C210 C211 120.0(3) . . ?
C211 C210 H210 120.0 . . ?
C206 C211 H211 120.2 . . ?
C210 C211 C206 119.6(3) . . ?
C210 C211 H211 120.2 . . ?
C213 C212 P2 118.59(19) . . ?
C217 C212 P2 119.2(2) . . ?
C217 C212 C213 122.2(2) . . ?
C212 C213 H213 120.6 . . ?
C214 C213 C212 118.7(3) . . ?
C214 C213 H213 120.6 . . ?
C213 C214 H214 120.3 . . ?
C215 C214 C213 119.3(3) . . ?
C215 C214 H214 120.3 . . ?
C214 C215 H215 120.2 . . ?
C214 C215 C216 119.7(3) . . ?
C216 C215 H215 120.2 . . ?
C215 C216 H216 119.1 . . ?
C217 C216 C215 121.9(3) . . ?
C217 C216 H216 119.1 . . ?
C212 C217 C216 118.2(3) . . ?
C212 C217 H217 120.9 . . ?
C216 C217 H217 120.9 . . ?
F21 C21 C22 117.5(7) . . ?
F21 C21 F23 102.9(7) . . ?
F22 C21 C22 114.0(7) . . ?
F22 C21 F21 108.1(7) . . ?
F22 C21 F23 110.3(7) . . ?
F23 C21 C22 103.3(6) . . ?
F1B C4B C22 112.2(9) . . ?
F2B C4B C22 112.2(10) . . ?
F2B C4B F1B 108.4(9) . . ?
F2B C4B F3B 107.5(10) . . ?
F3B C4B C22 109.7(9) . . ?
F3B C4B F1B 106.5(10) . . ?
F1C C4C C22 107.4(8) . . ?
F2C C4C C22 107.7(9) . . ?
F2C C4C F1C 105.6(9) . . ?
F3C C4C C22 116.9(8) . . ?
F3C C4C F1C 113.1(10) . . ?
F3C C4C F2C 105.5(9) . . ?
F1D C4D C22 105.8(8) . . ?
F2D C4D C22 116.7(9) . . ?
F2D C4D F1D 105.5(9) . . ?
F2D C4D F3D 108.7(9) . . ?
F3D C4D C22 113.3(9) . . ?
F3D C4D F1D 106.1(9) . . ?
O3 Eu2 O41 71.98(6) . . ?
O3 Eu2 O42 140.36(6) . . ?
O3 Eu2 O51 85.35(6) . . ?
O3 Eu2 O52 77.83(6) . . ?
O3 Eu2 O61 73.64(6) . . ?
O3 Eu2 O62 109.30(6) . . ?
O4 Eu2 O3 145.00(6) . . ?
O4 Eu2 O41 142.77(6) . . ?
O4 Eu2 O42 73.98(6) . . ?
O4 Eu2 O51 101.90(6) . . ?
O4 Eu2 O52 72.64(6) . . ?
O4 Eu2 O61 79.85(6) . . ?
O4 Eu2 O62 82.33(6) . . ?
O41 Eu2 O42 70.57(6) . . ?
O41 Eu2 O52 139.62(6) . . ?
O41 Eu2 O61 121.58(6) . . ?
O51 Eu2 O41 80.49(6) . . ?
O51 Eu2 O42 76.20(6) . . ?
O51 Eu2 O52 70.80(6) . . ?
O51 Eu2 O61 140.75(6) . . ?
O51 Eu2 O62 148.28(6) . . ?
O52 Eu2 O42 126.03(6) . . ?
O61 Eu2 O42 139.14(6) . . ?
O61 Eu2 O52 72.55(6) . . ?
O62 Eu2 O41 77.88(6) . . ?
O62 Eu2 O42 74.87(6) . . ?
O62 Eu2 O52 138.61(6) . . ?
O62 Eu2 O61 70.94(6) . . ?
O3 P3 C301 109.59(12) . . ?
O3 P3 C306 110.59(11) . . ?
O3 P3 C312 112.30(11) . . ?
C306 P3 C301 107.96(12) . . ?
C306 P3 C312 108.52(12) . . ?
C312 P3 C301 107.73(12) . . ?
O4 P4 C401 111.01(11) . . ?
O4 P4 C406 112.66(11) . . ?
O4 P4 C412 108.87(12) . . ?
C401 P4 C412 108.53(13) . . ?
C406 P4 C401 108.19(12) . . ?
C406 P4 C412 107.44(12) . . ?
P3 O3 Eu2 148.78(11) . . ?
P4 O4 Eu2 154.15(11) . . ?
C42 O41 Eu2 136.36(17) . . ?
C44 O42 Eu2 134.74(17) . . ?
C52 O51 Eu2 136.92(16) . . ?
C54 O52 Eu2 135.03(16) . . ?
C62 O61 Eu2 135.92(15) . . ?
C64 O62 Eu2 135.46(15) . . ?
C305 N3 C301 115.7(3) . . ?
C401 N4 C405 117.7(3) . . ?
F41 C41 F42 106.2(3) . . ?
F41 C41 C42 111.8(2) . . ?
F42 C41 C42 109.2(3) . . ?
F43 C41 F41 107.6(3) . . ?
F43 C41 F42 106.5(3) . . ?
F43 C41 C42 115.1(2) . . ?
O41 C42 C41 113.6(2) . . ?
O41 C42 C43 128.5(2) . . ?
C43 C42 C41 117.8(2) . . ?
C42 C43 H43 119.8 . . ?
C42 C43 C44 120.4(2) . . ?
C44 C43 H43 119.8 . . ?
O42 C44 C43 128.9(2) . . ?
O42 C44 C45 113.3(2) . . ?
C43 C44 C45 117.7(2) . . ?
F45 C45 F46 107.3(3) . . ?
F45 C45 F47 106.3(3) . . ?
F45 C45 C44 112.5(2) . . ?
F46 C45 F47 106.6(3) . . ?
F46 C45 C44 113.3(3) . . ?
F47 C45 C44 110.4(2) . . ?
F51 C51 F52 106.7(3) . . ?
F51 C51 C52 111.3(2) . . ?
F52 C51 C52 113.6(2) . . ?
F53 C51 F51 107.7(2) . . ?
F53 C51 F52 106.7(2) . . ?
F53 C51 C52 110.6(2) . . ?
O51 C52 C51 113.8(2) . . ?
O51 C52 C53 128.3(2) . . ?
C53 C52 C51 117.9(2) . . ?
C52 C53 H53 119.7 . . ?
C54 C53 C52 120.7(2) . . ?
C54 C53 H53 119.7 . . ?
O52 C54 C53 127.9(2) . . ?
O52 C54 C55 113.7(2) . . ?
C53 C54 C55 118.4(2) . . ?
F55 C55 C54 114.1(2) . . ?
F56 C55 F55 106.7(2) . . ?
F56 C55 C54 111.4(2) . . ?
F57 C55 F55 106.9(2) . . ?
F57 C55 F56 106.9(2) . . ?
F57 C55 C54 110.5(2) . . ?
F61 C61 F62 107.1(2) . . ?
F61 C61 F63 107.5(2) . . ?
F61 C61 C62 111.6(2) . . ?
F62 C61 C62 109.3(2) . . ?
F63 C61 F62 107.1(2) . . ?
F63 C61 C62 113.9(2) . . ?
O61 C62 C61 114.6(2) . . ?
O61 C62 C63 127.9(2) . . ?
C63 C62 C61 117.5(2) . . ?
C62 C63 H63 119.7 . . ?
C64 C63 C62 120.6(2) . . ?
C64 C63 H63 119.7 . . ?
O62 C64 C63 128.3(2) . . ?
O62 C64 C65 113.7(2) . . ?
C63 C64 C65 117.9(2) . . ?
F65 C65 F66 106.9(3) . . ?
F65 C65 C64 110.8(2) . . ?
F66 C65 C64 112.4(2) . . ?
F67 C65 F65 108.4(2) . . ?
F67 C65 F66 107.5(2) . . ?
F67 C65 C64 110.6(2) . . ?
N3 C301 P3 116.1(2) . . ?
N3 C301 C302 124.1(3) . . ?
C302 C301 P3 119.8(2) . . ?
C301 C302 H302 120.9 . . ?
C301 C302 C303 118.1(3) . . ?
C303 C302 H302 120.9 . . ?
C302 C303 H303 120.5 . . ?
C304 C303 C302 118.9(4) . . ?
C304 C303 H303 120.5 . . ?
C303 C304 H304 120.4 . . ?
C303 C304 C305 119.2(3) . . ?
C305 C304 H304 120.4 . . ?
N3 C305 C304 124.0(4) . . ?
N3 C305 H305 118.0 . . ?
C304 C305 H305 118.0 . . ?
C307 C306 P3 117.21(19) . . ?
C311 C306 P3 121.8(2) . . ?
C311 C306 C307 121.0(2) . . ?
C306 C307 H307 120.6 . . ?
C308 C307 C306 118.9(3) . . ?
C308 C307 H307 120.6 . . ?
C307 C308 H308 119.8 . . ?
C309 C308 C307 120.4(3) . . ?
C309 C308 H308 119.8 . . ?
C308 C309 H309 119.7 . . ?
C308 C309 C310 120.5(3) . . ?
C310 C309 H309 119.7 . . ?
C309 C310 H310 119.8 . . ?
C309 C310 C311 120.4(3) . . ?
C311 C310 H310 119.8 . . ?
C306 C311 C310 118.8(3) . . ?
C306 C311 H311 120.6 . . ?
C310 C311 H311 120.6 . . ?
C313 C312 P3 117.5(2) . . ?
C317 C312 P3 122.4(2) . . ?
C317 C312 C313 120.0(2) . . ?
C312 C313 H313 120.1 . . ?
C314 C313 C312 119.8(3) . . ?
C314 C313 H313 120.1 . . ?
C313 C314 H314 120.0 . . ?
C315 C314 C313 120.0(3) . . ?
C315 C314 H314 120.0 . . ?
C314 C315 H315 119.8 . . ?
C316 C315 C314 120.4(3) . . ?
C316 C315 H315 119.8 . . ?
C315 C316 H316 119.9 . . ?
C315 C316 C317 120.3(3) . . ?
C317 C316 H316 119.9 . . ?
C312 C317 C316 119.6(3) . . ?
C312 C317 H317 120.2 . . ?
C316 C317 H317 120.2 . . ?
N4 C401 P4 117.8(2) . . ?
N4 C401 C402 122.4(2) . . ?
C402 C401 P4 119.8(2) . . ?
C401 C402 H402 120.6 . . ?
C401 C402 C403 118.7(3) . . ?
C403 C402 H402 120.6 . . ?
C402 C403 H403 120.3 . . ?
C404 C403 C402 119.4(3) . . ?
C404 C403 H403 120.3 . . ?
C403 C404 H404 120.1 . . ?
C403 C404 C405 119.9(3) . . ?
C405 C404 H404 120.1 . . ?
N4 C405 C404 121.9(3) . . ?
N4 C405 H405 119.1 . . ?
C404 C405 H405 119.1 . . ?
C407 C406 P4 117.37(19) . . ?
C411 C406 P4 122.92(19) . . ?
C411 C406 C407 119.7(2) . . ?
C406 C407 H407 120.1 . . ?
C408 C407 C406 119.9(2) . . ?
C408 C407 H407 120.1 . . ?
C407 C408 H408 119.9 . . ?
C409 C408 C407 120.2(2) . . ?
C409 C408 H408 119.9 . . ?
C408 C409 H409 119.8 . . ?
C410 C409 C408 120.3(3) . . ?
C410 C409 H409 119.8 . . ?
C409 C410 H410 119.8 . . ?
C409 C410 C411 120.4(3) . . ?
C411 C410 H410 119.8 . . ?
C406 C411 H411 120.3 . . ?
C410 C411 C406 119.5(2) . . ?
C410 C411 H411 120.3 . . ?
C413 C412 P4 118.7(2) . . ?
C417 C412 P4 119.8(2) . . ?
C417 C412 C413 121.5(3) . . ?
C412 C413 H413 120.4 . . ?
C412 C413 C414 119.2(4) . . ?
C414 C413 H413 120.4 . . ?
C413 C414 H414 120.1 . . ?
C415 C414 C413 119.8(4) . . ?
C415 C414 H414 120.1 . . ?
C414 C415 H415 120.3 . . ?
C414 C415 C416 119.4(3) . . ?
C416 C415 H415 120.3 . . ?
C415 C416 H416 119.2 . . ?
C417 C416 C415 121.7(4) . . ?
C417 C416 H416 119.2 . . ?
C412 C417 C416 118.5(3) . . ?
C412 C417 H417 120.8 . . ?
C416 C417 H417 120.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O11 C12 C11 158.33(17) . . . . ?
Eu1 O11 C12 C13 -18.5(4) . . . . ?
Eu1 O12 C14 C13 -5.5(4) . . . . ?
Eu1 O12 C14 C15 175.51(17) . . . . ?
Eu1 O21 C22 C23 -10.3(5) . . . . ?
Eu1 O21 C22 C21 178.1(4) . . . . ?
Eu1 O21 C22 C4B 172.0(5) . . . . ?
Eu1 O21 C22 C4C 158.1(5) . . . . ?
Eu1 O21 C22 C4D 164.5(5) . . . . ?
Eu1 O22 C24 C23 -3.8(4) . . . . ?
Eu1 O22 C24 C25 175.94(16) . . . . ?
Eu1 O31 C32 C31 -170.28(17) . . . . ?
Eu1 O31 C32 C33 9.4(4) . . . . ?
Eu1 O32 C34 C33 -20.5(4) . . . . ?
Eu1 O32 C34 C35 161.32(18) . . . . ?
P1 C101 C102 C103 179.6(2) . . . . ?
P1 C106 C107 C108 -175.8(2) . . . . ?
P1 C106 C111 C110 176.2(2) . . . . ?
P1 C112 C113 C114 177.9(2) . . . . ?
P1 C112 C117 C116 -177.4(2) . . . . ?
P2 C201 C202 C203 -177.8(2) . . . . ?
P2 C206 C207 C208 178.0(2) . . . . ?
P2 C206 C211 C210 -177.7(2) . . . . ?
P2 C212 C213 C214 -179.8(2) . . . . ?
P2 C212 C217 C216 -179.4(2) . . . . ?
F11 C11 C12 O11 45.5(3) . . . . ?
F11 C11 C12 C13 -137.3(2) . . . . ?
F12 C11 C12 O11 -73.1(3) . . . . ?
F12 C11 C12 C13 104.1(3) . . . . ?
F13 C11 C12 O11 167.5(2) . . . . ?
F13 C11 C12 C13 -15.3(3) . . . . ?
F31 C31 C32 O31 127.4(3) . . . . ?
F31 C31 C32 C33 -52.3(3) . . . . ?
F32 C31 C32 O31 -113.0(3) . . . . ?
F32 C31 C32 C33 67.4(3) . . . . ?
F33 C31 C32 O31 8.7(4) . . . . ?
F33 C31 C32 C33 -171.0(3) . . . . ?
O1 P1 C101 N1 -173.5(2) . . . . ?
O1 P1 C101 C102 6.5(3) . . . . ?
O1 P1 C106 C107 35.7(2) . . . . ?
O1 P1 C106 C111 -141.3(2) . . . . ?
O1 P1 C112 C113 21.8(2) . . . . ?
O1 P1 C112 C117 -160.4(2) . . . . ?
O2 P2 C201 N2 -177.46(19) . . . . ?
O2 P2 C201 C202 -0.3(2) . . . . ?
O2 P2 C206 C207 38.8(2) . . . . ?
O2 P2 C206 C211 -144.3(2) . . . . ?
O2 P2 C212 C213 10.4(2) . . . . ?
O2 P2 C212 C217 -169.7(2) . . . . ?
O11 C12 C13 C14 7.8(4) . . . . ?
O12 C14 C15 F15 177.3(2) . . . . ?
O12 C14 C15 F16 -62.1(3) . . . . ?
O12 C14 C15 F17 56.8(3) . . . . ?
O21 C22 C23 C24 4.5(5) . . . . ?
O21 C22 C21 F21 160.4(6) . . . . ?
O21 C22 C21 F22 32.4(9) . . . . ?
O21 C22 C21 F23 -87.3(6) . . . . ?
O21 C22 C4B F1B 127.7(8) . . . . ?
O21 C22 C4B F2B 5.3(11) . . . . ?
O21 C22 C4B F3B -114.1(9) . . . . ?
O21 C22 C4C F1C 171.0(7) . . . . ?
O21 C22 C4C F2C 57.7(9) . . . . ?
O21 C22 C4C F3C -60.7(10) . . . . ?
O21 C22 C4D F1D 91.6(8) . . . . ?
O21 C22 C4D F2D -25.3(11) . . . . ?
O21 C22 C4D F3D -152.7(8) . . . . ?
O22 C24 C25 F25 172.8(2) . . . . ?
O22 C24 C25 F26 -67.6(3) . . . . ?
O22 C24 C25 F27 51.2(3) . . . . ?
O31 C32 C33 C34 4.7(4) . . . . ?
O32 C34 C35 F35 81.5(3) . . . . ?
O32 C34 C35 F36 -38.2(4) . . . . ?
O32 C34 C35 F37 -161.2(3) . . . . ?
N1 C101 C102 C103 -0.4(4) . . . . ?
N2 C201 C202 C203 -0.8(4) . . . . ?
C11 C12 C13 C14 -168.8(2) . . . . ?
C12 C13 C14 O12 4.1(4) . . . . ?
C12 C13 C14 C15 -176.9(2) . . . . ?
C13 C14 C15 F15 -1.8(4) . . . . ?
C13 C14 C15 F16 118.7(3) . . . . ?
C13 C14 C15 F17 -122.4(3) . . . . ?
C22 C23 C24 O22 2.4(5) . . . . ?
C22 C23 C24 C25 -177.3(3) . . . . ?
C23 C22 C21 F21 -12.4(9) . . . . ?
C23 C22 C21 F22 -140.3(6) . . . . ?
C23 C22 C21 F23 99.9(6) . . . . ?
C23 C22 C4B F1B -50.3(11) . . . . ?
C23 C22 C4B F2B -172.7(8) . . . . ?
C23 C22 C4B F3B 67.9(10) . . . . ?
C23 C22 C4C F1C -19.5(10) . . . . ?
C23 C22 C4C F2C -132.9(7) . . . . ?
C23 C22 C4C F3C 108.7(8) . . . . ?
C23 C22 C4D F1D -93.1(8) . . . . ?
C23 C22 C4D F2D 150.0(8) . . . . ?
C23 C22 C4D F3D 22.7(11) . . . . ?
C23 C24 C25 F25 -7.5(3) . . . . ?
C23 C24 C25 F26 112.1(3) . . . . ?
C23 C24 C25 F27 -129.0(3) . . . . ?
C31 C32 C33 C34 -175.7(3) . . . . ?
C32 C33 C34 O32 1.2(5) . . . . ?
C32 C33 C34 C35 179.4(3) . . . . ?
C33 C34 C35 F35 -96.9(3) . . . . ?
C33 C34 C35 F36 143.4(3) . . . . ?
C33 C34 C35 F37 20.4(4) . . . . ?
C101 P1 O1 Eu1 127.5(2) . . . . ?
C101 P1 C106 C107 -84.8(2) . . . . ?
C101 P1 C106 C111 98.2(2) . . . . ?
C101 P1 C112 C113 142.1(2) . . . . ?
C101 P1 C112 C117 -40.1(3) . . . . ?
C101 N1 C105 C104 0.2(5) . . . . ?
C101 C102 C103 C104 0.0(5) . . . . ?
C102 C103 C104 C105 0.6(5) . . . . ?
C103 C104 C105 N1 -0.7(5) . . . . ?
C105 N1 C101 P1 -179.7(2) . . . . ?
C105 N1 C101 C102 0.4(4) . . . . ?
C106 P1 O1 Eu1 7.5(2) . . . . ?
C106 P1 C101 N1 -51.2(2) . . . . ?
C106 P1 C101 C102 128.8(2) . . . . ?
C106 P1 C112 C113 -100.9(2) . . . . ?
C106 P1 C112 C117 76.9(2) . . . . ?
C106 C107 C108 C109 -0.2(4) . . . . ?
C107 C106 C111 C110 -0.8(4) . . . . ?
C107 C108 C109 C110 -1.5(4) . . . . ?
C108 C109 C110 C111 2.0(5) . . . . ?
C109 C110 C111 C106 -0.9(5) . . . . ?
C111 C106 C107 C108 1.3(4) . . . . ?
C112 P1 O1 Eu1 -112.4(2) . . . . ?
C112 P1 C101 N1 65.3(2) . . . . ?
C112 P1 C101 C102 -114.8(2) . . . . ?
C112 P1 C106 C107 157.7(2) . . . . ?
C112 P1 C106 C111 -19.3(3) . . . . ?
C112 C113 C114 C115 -0.4(4) . . . . ?
C113 C112 C117 C116 0.4(4) . . . . ?
C113 C114 C115 C116 0.3(4) . . . . ?
C114 C115 C116 C117 0.1(5) . . . . ?
C115 C116 C117 C112 -0.4(4) . . . . ?
C117 C112 C113 C114 0.0(4) . . . . ?
C201 P2 O2 Eu1 141.36(19) . . . . ?
C201 P2 C206 C207 -81.3(2) . . . . ?
C201 P2 C206 C211 95.6(2) . . . . ?
C201 P2 C212 C213 131.1(2) . . . . ?
C201 P2 C212 C217 -49.0(2) . . . . ?
C201 N2 C205 C204 -0.2(4) . . . . ?
C201 C202 C203 C204 0.0(4) . . . . ?
C202 C203 C204 C205 0.7(5) . . . . ?
C203 C204 C205 N2 -0.6(5) . . . . ?
C205 N2 C201 P2 178.0(2) . . . . ?
C205 N2 C201 C202 0.9(4) . . . . ?
C206 P2 O2 Eu1 23.5(2) . . . . ?
C206 P2 C201 N2 -55.5(2) . . . . ?
C206 P2 C201 C202 121.6(2) . . . . ?
C206 P2 C212 C213 -114.0(2) . . . . ?
C206 P2 C212 C217 65.9(2) . . . . ?
C206 C207 C208 C209 -1.0(4) . . . . ?
C207 C206 C211 C210 -0.9(4) . . . . ?
C207 C208 C209 C210 0.7(4) . . . . ?
C208 C209 C210 C211 -0.6(4) . . . . ?
C209 C210 C211 C206 0.6(4) . . . . ?
C211 C206 C207 C208 1.1(4) . . . . ?
C212 P2 O2 Eu1 -98.7(2) . . . . ?
C212 P2 C201 N2 61.3(2) . . . . ?
C212 P2 C201 C202 -121.5(2) . . . . ?
C212 P2 C206 C207 162.06(19) . . . . ?
C212 P2 C206 C211 -21.1(3) . . . . ?
C212 C213 C214 C215 -0.9(4) . . . . ?
C213 C212 C217 C216 0.5(4) . . . . ?
C213 C214 C215 C216 0.7(5) . . . . ?
C214 C215 C216 C217 0.1(6) . . . . ?
C215 C216 C217 C212 -0.7(5) . . . . ?
C217 C212 C213 C214 0.3(4) . . . . ?
C21 C22 C23 C24 176.3(4) . . . . ?
C4B C22 C23 C24 -177.7(6) . . . . ?
C4C C22 C23 C24 -162.7(5) . . . . ?
C4D C22 C23 C24 -169.9(5) . . . . ?
Eu2 O41 C42 C41 -178.66(18) . . . . ?
Eu2 O41 C42 C43 4.4(4) . . . . ?
Eu2 O42 C44 C43 3.1(4) . . . . ?
Eu2 O42 C44 C45 -173.76(18) . . . . ?
Eu2 O51 C52 C51 -179.93(18) . . . . ?
Eu2 O51 C52 C53 -2.1(4) . . . . ?
Eu2 O52 C54 C53 7.1(4) . . . . ?
Eu2 O52 C54 C55 -172.05(16) . . . . ?
Eu2 O61 C62 C61 175.19(16) . . . . ?
Eu2 O61 C62 C63 -2.5(4) . . . . ?
Eu2 O62 C64 C63 10.8(4) . . . . ?
Eu2 O62 C64 C65 -170.24(18) . . . . ?
P3 C301 C302 C303 -178.5(2) . . . . ?
P3 C306 C307 C308 -179.6(2) . . . . ?
P3 C306 C311 C310 179.4(2) . . . . ?
P3 C312 C313 C314 177.4(2) . . . . ?
P3 C312 C317 C316 -177.1(3) . . . . ?
P4 C401 C402 C403 179.4(2) . . . . ?
P4 C406 C407 C408 -179.9(2) . . . . ?
P4 C406 C411 C410 -179.6(2) . . . . ?
P4 C412 C413 C414 179.0(3) . . . . ?
P4 C412 C417 C416 179.9(2) . . . . ?
F41 C41 C42 O41 53.1(4) . . . . ?
F41 C41 C42 C43 -129.6(3) . . . . ?
F42 C41 C42 O41 -64.1(3) . . . . ?
F42 C41 C42 C43 113.2(3) . . . . ?
F43 C41 C42 O41 176.2(3) . . . . ?
F43 C41 C42 C43 -6.4(4) . . . . ?
F51 C51 C52 O51 -40.2(4) . . . . ?
F51 C51 C52 C53 141.7(3) . . . . ?
F52 C51 C52 O51 -160.6(2) . . . . ?
F52 C51 C52 C53 21.3(4) . . . . ?
F53 C51 C52 O51 79.4(3) . . . . ?
F53 C51 C52 C53 -98.7(3) . . . . ?
F61 C61 C62 O61 35.9(3) . . . . ?
F61 C61 C62 C63 -146.1(2) . . . . ?
F62 C61 C62 O61 -82.4(3) . . . . ?
F62 C61 C62 C63 95.6(3) . . . . ?
F63 C61 C62 O61 157.9(2) . . . . ?
F63 C61 C62 C63 -24.2(3) . . . . ?
O3 P3 C301 N3 170.3(2) . . . . ?
O3 P3 C301 C302 -11.1(3) . . . . ?
O3 P3 C306 C307 -17.6(2) . . . . ?
O3 P3 C306 C311 163.1(2) . . . . ?
O3 P3 C312 C313 -48.7(2) . . . . ?
O3 P3 C312 C317 128.8(2) . . . . ?
O4 P4 C401 N4 173.4(2) . . . . ?
O4 P4 C401 C402 -6.8(3) . . . . ?
O4 P4 C406 C407 -53.5(2) . . . . ?
O4 P4 C406 C411 125.9(2) . . . . ?
O4 P4 C412 C413 3.2(3) . . . . ?
O4 P4 C412 C417 -177.5(2) . . . . ?
O41 C42 C43 C44 2.9(4) . . . . ?
O42 C44 C45 F45 -43.6(4) . . . . ?
O42 C44 C45 F46 -165.5(3) . . . . ?
O42 C44 C45 F47 75.0(3) . . . . ?
O51 C52 C53 C54 -2.3(4) . . . . ?
O52 C54 C55 F55 -171.2(2) . . . . ?
O52 C54 C55 F56 -50.3(3) . . . . ?
O52 C54 C55 F57 68.4(3) . . . . ?
O61 C62 C63 C64 -2.1(4) . . . . ?
O62 C64 C65 F65 52.6(3) . . . . ?
O62 C64 C65 F66 172.2(2) . . . . ?
O62 C64 C65 F67 -67.7(3) . . . . ?
N3 C301 C302 C303 0.0(5) . . . . ?
N4 C401 C402 C403 -0.8(4) . . . . ?
C41 C42 C43 C44 -173.9(3) . . . . ?
C42 C43 C44 O42 -6.6(4) . . . . ?
C42 C43 C44 C45 170.1(3) . . . . ?
C43 C44 C45 F45 139.2(3) . . . . ?
C43 C44 C45 F46 17.2(4) . . . . ?
C43 C44 C45 F47 -102.2(3) . . . . ?
C51 C52 C53 C54 175.5(3) . . . . ?
C52 C53 C54 O52 -0.4(4) . . . . ?
C52 C53 C54 C55 178.7(2) . . . . ?
C53 C54 C55 F55 9.6(3) . . . . ?
C53 C54 C55 F56 130.5(3) . . . . ?
C53 C54 C55 F57 -110.9(3) . . . . ?
C61 C62 C63 C64 -179.7(2) . . . . ?
C62 C63 C64 O62 -2.0(4) . . . . ?
C62 C63 C64 C65 179.1(2) . . . . ?
C63 C64 C65 F65 -128.4(3) . . . . ?
C63 C64 C65 F66 -8.8(4) . . . . ?
C63 C64 C65 F67 111.4(3) . . . . ?
C301 P3 O3 Eu2 -125.31(19) . . . . ?
C301 P3 C306 C307 -137.5(2) . . . . ?
C301 P3 C306 C311 43.2(3) . . . . ?
C301 P3 C312 C313 72.1(2) . . . . ?
C301 P3 C312 C317 -110.4(3) . . . . ?
C301 N3 C305 C304 -0.4(6) . . . . ?
C301 C302 C303 C304 -0.1(5) . . . . ?
C302 C303 C304 C305 0.0(5) . . . . ?
C303 C304 C305 N3 0.3(6) . . . . ?
C305 N3 C301 P3 178.8(3) . . . . ?
C305 N3 C301 C302 0.2(5) . . . . ?
C306 P3 O3 Eu2 115.8(2) . . . . ?
C306 P3 C301 N3 -69.2(2) . . . . ?
C306 P3 C301 C302 109.4(2) . . . . ?
C306 P3 C312 C313 -171.3(2) . . . . ?
C306 P3 C312 C317 6.3(3) . . . . ?
C306 C307 C308 C309 0.1(4) . . . . ?
C307 C306 C311 C310 0.2(4) . . . . ?
C307 C308 C309 C310 0.2(4) . . . . ?
C308 C309 C310 C311 -0.3(5) . . . . ?
C309 C310 C311 C306 0.1(4) . . . . ?
C311 C306 C307 C308 -0.3(4) . . . . ?
C312 P3 O3 Eu2 -5.6(2) . . . . ?
C312 P3 C301 N3 47.8(2) . . . . ?
C312 P3 C301 C302 -133.6(2) . . . . ?
C312 P3 C306 C307 105.9(2) . . . . ?
C312 P3 C306 C311 -73.3(2) . . . . ?
C312 C313 C314 C315 0.0(4) . . . . ?
C313 C312 C317 C316 0.4(5) . . . . ?
C313 C314 C315 C316 0.0(5) . . . . ?
C314 C315 C316 C317 0.2(5) . . . . ?
C315 C316 C317 C312 -0.4(5) . . . . ?
C317 C312 C313 C314 -0.2(4) . . . . ?
C401 P4 O4 Eu2 117.9(2) . . . . ?
C401 P4 C406 C407 -176.6(2) . . . . ?
C401 P4 C406 C411 2.8(3) . . . . ?
C401 P4 C412 C413 124.1(2) . . . . ?
C401 P4 C412 C417 -56.6(2) . . . . ?
C401 N4 C405 C404 0.0(5) . . . . ?
C401 C402 C403 C404 1.1(5) . . . . ?
C402 C403 C404 C405 -0.9(5) . . . . ?
C403 C404 C405 N4 0.3(6) . . . . ?
C405 N4 C401 P4 -179.9(3) . . . . ?
C405 N4 C401 C402 0.3(5) . . . . ?
C406 P4 O4 Eu2 -3.6(3) . . . . ?
C406 P4 C401 N4 -62.5(3) . . . . ?
C406 P4 C401 C402 117.3(2) . . . . ?
C406 P4 C412 C413 -119.1(2) . . . . ?
C406 P4 C412 C417 60.2(2) . . . . ?
C406 C407 C408 C409 -0.1(4) . . . . ?
C407 C406 C411 C410 -0.3(4) . . . . ?
C407 C408 C409 C410 -1.2(4) . . . . ?
C408 C409 C410 C411 1.7(4) . . . . ?
C409 C410 C411 C406 -0.9(4) . . . . ?
C411 C406 C407 C408 0.8(4) . . . . ?
C412 P4 O4 Eu2 -122.7(2) . . . . ?
C412 P4 C401 N4 53.8(3) . . . . ?
C412 P4 C401 C402 -126.4(2) . . . . ?
C412 P4 C406 C407 66.5(2) . . . . ?
C412 P4 C406 C411 -114.2(2) . . . . ?
C412 C413 C414 C415 1.1(5) . . . . ?
C413 C412 C417 C416 -0.8(4) . . . . ?
C413 C414 C415 C416 -0.9(5) . . . . ?
C414 C415 C416 C417 -0.2(5) . . . . ?
C415 C416 C417 C412 1.0(5) . . . . ?
C417 C412 C413 C414 -0.3(5) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'

# start Validation Reply Form
_vrf_PLAT230_eu280_s2_100k       
;
PROBLEM: Hirshfeld Test Diff for    C216     --C217     .        8.5 s.u.  
RESPONSE: Moderate ADP components inconsistency may be related to the presence
 of unresolved minor conformations of OP(Ph)2Py in the crystal structure.
;
# end Validation Reply Form
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_eu296
_database_code_depnum_ccdc_archive 'CCDC 2078497'
loop_
_audit_author_name
_audit_author_address
'Ludmila A. Glinskaya'
;Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences
Russia
;
_audit_update_record             
;
2021-04-19 deposited with the CCDC.	2021-06-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C47 H29 Eu F18 N4 O8 P2'
_chemical_formula_weight         1333.64

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.6533(5)
_cell_length_b                   13.3458(5)
_cell_length_c                   30.1222(15)
_cell_angle_alpha                90
_cell_angle_beta                 90.640(4)
_cell_angle_gamma                90
_cell_volume                     5086.4(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    11372
_cell_measurement_theta_min      2.31
_cell_measurement_theta_max      28.31

_exptl_crystal_description       plate
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.742
_exptl_crystal_F_000             2632
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.07
_exptl_absorpt_coefficient_mu    1.419
_shelx_estimated_absorpt_T_min   0.745
_shelx_estimated_absorpt_T_max   0.907
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.94862
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?

_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            AtlasS2
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed X-ray tube'
_diffrn_measurement_device_type  'New Xcalibur, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 10.6
_diffrn_reflns_number            22730
_diffrn_reflns_av_unetI/netI     0.0376
_diffrn_reflns_av_R_equivalents  0.0238
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_l_min       -40
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         2.039
_diffrn_reflns_theta_max         28.559
_diffrn_reflns_theta_full        25.500
_diffrn_measured_fraction_theta_max 0.848
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.848
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.848
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             10992
_reflns_number_gt                9383
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2015)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2015)'
_computing_structure_solution    'SHELXT-2018 (Sheldrick, 2015)'
_computing_structure_refinement  'SHELXL-2018 (Sheldrick, 2015)'
_computing_molecular_graphics    'ShelXle (Hübschle, 2011)'
_computing_publication_material  'CIFTAB (Sheldrick, 2015)'

_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0278P)²+6.4461P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         10992
_refine_ls_number_parameters     892
_refine_ls_number_restraints     567
_refine_ls_R_factor_all          0.0481
_refine_ls_R_factor_gt           0.0377
_refine_ls_wR_factor_ref         0.0802
_refine_ls_wR_factor_gt          0.0774
_refine_ls_goodness_of_fit_ref   1.109
_refine_ls_restrained_S_all      1.139
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.73116(2) 0.66351(2) 0.39298(2) 0.01981(5) Uani 1 1 d . . . . .
O1 O 0.70581(17) 0.56178(17) 0.33111(7) 0.0255(5) Uani 1 1 d . . . . .
P1 P 0.75143(6) 0.48777(6) 0.29942(3) 0.02297(17) Uani 1 1 d . . . . .
N11 N 0.7089(3) 0.2953(3) 0.27662(11) 0.0455(8) Uani 1 1 d . . . . .
N12 N 0.5189(3) 0.2876(3) 0.32343(13) 0.0532(10) Uani 1 1 d . . . . .
C101 C 0.6730(3) 0.3751(3) 0.29996(11) 0.0285(7) Uani 1 1 d . . . . .
C102 C 0.5798(3) 0.3712(3) 0.32323(13) 0.0371(9) Uani 1 1 d . . . . .
H102 H 0.557825 0.428329 0.339486 0.045 Uiso 1 1 calc R U . . .
C103 C 0.5539(4) 0.2097(3) 0.29975(15) 0.0502(11) Uani 1 1 d . . . . .
H103 H 0.512620 0.150304 0.298675 0.060 Uiso 1 1 calc R U . . .
C104 C 0.6474(4) 0.2126(3) 0.27691(15) 0.0523(11) Uani 1 1 d . . . . .
H104 H 0.669267 0.154927 0.260951 0.063 Uiso 1 1 calc R U . . .
C105 C 0.8849(3) 0.4539(3) 0.31330(11) 0.0274(7) Uani 1 1 d . . . . .
C106 C 0.9096(3) 0.4344(3) 0.35766(12) 0.0311(8) Uani 1 1 d . . . . .
H106 H 0.855572 0.436512 0.379267 0.037 Uiso 1 1 calc R U . . .
C107 C 1.0120(3) 0.4119(3) 0.37046(13) 0.0377(9) Uani 1 1 d . . . . .
H107 H 1.028466 0.399619 0.400817 0.045 Uiso 1 1 calc R U . . .
C108 C 1.0906(3) 0.4075(3) 0.33895(14) 0.0470(11) Uani 1 1 d . . . . .
H108 H 1.160960 0.391466 0.347638 0.056 Uiso 1 1 calc R U . . .
C109 C 1.0669(3) 0.4261(4) 0.29514(15) 0.0557(13) Uani 1 1 d . . . . .
H109 H 1.121233 0.423183 0.273668 0.067 Uiso 1 1 calc R U . . .
C110 C 0.9646(3) 0.4491(3) 0.28196(12) 0.0406(9) Uani 1 1 d . . . . .
H110 H 0.948863 0.461657 0.251556 0.049 Uiso 1 1 calc R U . . .
C111 C 0.7497(2) 0.5367(3) 0.24386(11) 0.0262(7) Uani 1 1 d . . . . .
C112 C 0.7520(3) 0.6400(3) 0.23888(12) 0.0360(9) Uani 1 1 d . . . . .
H112 H 0.753861 0.682258 0.264267 0.043 Uiso 1 1 calc R U . . .
C113 C 0.7516(3) 0.6808(3) 0.19716(12) 0.0407(9) Uani 1 1 d . . . . .
H113 H 0.753785 0.751441 0.193512 0.049 Uiso 1 1 calc R U . . .
C114 C 0.7480(3) 0.6201(3) 0.16106(13) 0.0430(10) Uani 1 1 d . . . . .
H114 H 0.747519 0.648418 0.132123 0.052 Uiso 1 1 calc R U . . .
C115 C 0.7449(3) 0.5173(3) 0.16623(12) 0.0417(9) Uani 1 1 d . . . . .
H115 H 0.742406 0.475245 0.140805 0.050 Uiso 1 1 calc R U . . .
C116 C 0.7456(3) 0.4760(3) 0.20754(11) 0.0292(7) Uani 1 1 d . . . . .
H116 H 0.743198 0.405301 0.211012 0.035 Uiso 1 1 calc R U . . .
O2 O 0.78326(18) 0.82054(17) 0.41807(7) 0.0279(5) Uani 1 1 d . . . . .
P2 P 0.76760(6) 0.92843(6) 0.42897(3) 0.02227(17) Uani 1 1 d . . . . .
N21 N 0.8387(3) 1.1042(2) 0.39620(11) 0.0388(8) Uani 1 1 d . . . . .
N22 N 0.9242(3) 1.0187(3) 0.31992(11) 0.0507(9) Uani 1 1 d . . . . .
C201 C 0.8335(2) 1.0057(3) 0.38836(11) 0.0263(7) Uani 1 1 d . . . . .
C202 C 0.8741(3) 0.9635(3) 0.35043(11) 0.0356(8) Uani 1 1 d . . . . .
H202 H 0.866384 0.893438 0.345748 0.043 Uiso 1 1 calc R U . . .
C203 C 0.9302(3) 1.1165(4) 0.32786(15) 0.0507(11) Uani 1 1 d . . . . .
H203 H 0.964760 1.158520 0.307104 0.061 Uiso 1 1 calc R U . . .
C204 C 0.8877(3) 1.1585(3) 0.36537(15) 0.0487(10) Uani 1 1 d . . . . .
H204 H 0.893503 1.228876 0.369522 0.058 Uiso 1 1 calc R U . . .
C205 C 0.8230(3) 0.9540(3) 0.48289(11) 0.0284(8) Uani 1 1 d . . . . .
C206 C 0.8274(3) 1.0494(3) 0.50030(12) 0.0408(9) Uani 1 1 d . . . . .
H206 H 0.802661 1.105305 0.483628 0.049 Uiso 1 1 calc R U . . .
C207 C 0.8689(4) 1.0620(4) 0.54281(14) 0.0546(13) Uani 1 1 d . . . . .
H207 H 0.873173 1.127192 0.555323 0.065 Uiso 1 1 calc R U . . .
C208 C 0.9037(3) 0.9814(4) 0.56678(14) 0.0543(13) Uani 1 1 d . . . . .
H208 H 0.931685 0.991196 0.595861 0.065 Uiso 1 1 calc R U . . .
C209 C 0.8989(3) 0.8882(4) 0.54964(14) 0.0530(12) Uani 1 1 d . . . . .
H209 H 0.923241 0.832595 0.566608 0.064 Uiso 1 1 calc R U . . .
C210 C 0.8587(3) 0.8738(3) 0.50767(12) 0.0400(9) Uani 1 1 d . . . . .
H210 H 0.855425 0.808090 0.495585 0.048 Uiso 1 1 calc R U . . .
C211 C 0.6307(2) 0.9638(2) 0.43000(10) 0.0230(7) Uani 1 1 d . . . . .
C212 C 0.5924(3) 1.0508(3) 0.41085(12) 0.0335(8) Uani 1 1 d . . . . .
H212 H 0.639004 1.094619 0.395751 0.040 Uiso 1 1 calc R U . . .
C213 C 0.4863(3) 1.0738(3) 0.41371(13) 0.0382(9) Uani 1 1 d . . . . .
H213 H 0.460049 1.133600 0.400479 0.046 Uiso 1 1 calc R U . . .
C214 C 0.4181(3) 1.0108(3) 0.43561(12) 0.0353(8) Uani 1 1 d . . . . .
H214 H 0.345338 1.027575 0.437769 0.042 Uiso 1 1 calc R U . . .
C215 C 0.4555(3) 0.9233(3) 0.45436(12) 0.0345(8) Uani 1 1 d . . . . .
H215 H 0.408319 0.879303 0.469074 0.041 Uiso 1 1 calc R U . . .
C216 C 0.5613(3) 0.8995(3) 0.45176(11) 0.0294(8) Uani 1 1 d . . . . .
H216 H 0.587040 0.839381 0.464812 0.035 Uiso 1 1 calc R U . . .
O11 O 0.69691(18) 0.49743(17) 0.41871(7) 0.0282(5) Uani 1 1 d . . . . .
O12 O 0.68483(18) 0.66868(18) 0.47085(7) 0.0297(5) Uani 1 1 d . . . . .
C11 C 0.6696(3) 0.3426(3) 0.45141(11) 0.0514(10) Uani 1 1 d D U . . .
C12 C 0.6744(3) 0.4572(2) 0.45451(12) 0.0293(7) Uani 1 1 d D U . . .
C13 C 0.6584(3) 0.5019(3) 0.49529(12) 0.0346(8) Uani 1 1 d . . . . .
H13 H 0.639926 0.462034 0.520159 0.042 Uiso 1 1 calc R U . . .
C14 C 0.6691(3) 0.6045(3) 0.50000(11) 0.0329(8) Uani 1 1 d D U . . .
C15 C 0.6571(8) 0.6430(7) 0.5475(2) 0.0550(19) Uani 0.5 1 d D U P A 1
F11 F 0.7712(6) 0.3119(10) 0.4493(3) 0.061(2) Uani 0.5 1 d D U P B 1
F12 F 0.6267(6) 0.3059(7) 0.4141(2) 0.0521(18) Uani 0.5 1 d D U P B 1
F13 F 0.6217(9) 0.3022(13) 0.4862(4) 0.065(3) Uani 0.5 1 d D U P B 1
C15' C 0.6771(8) 0.6519(7) 0.5467(2) 0.0567(18) Uani 0.5 1 d D U P A 2
F11' F 0.7589(6) 0.3010(11) 0.4373(3) 0.068(2) Uani 0.5 1 d D U P B 2
F12' F 0.5881(6) 0.3224(8) 0.4241(3) 0.070(2) Uani 0.5 1 d D U P B 2
F13' F 0.6522(8) 0.2951(13) 0.4897(3) 0.055(2) Uani 0.5 1 d D U P B 2
F14 F 0.6479(8) 0.7429(7) 0.5523(4) 0.0591(19) Uani 0.5 1 d D U P A 1
F15 F 0.7513(8) 0.6369(7) 0.5679(3) 0.0712(19) Uani 0.5 1 d D U P A 1
F16 F 0.5883(6) 0.5890(7) 0.5712(3) 0.0602(18) Uani 0.5 1 d D U P A 1
F14' F 0.6109(7) 0.7315(7) 0.5452(4) 0.065(2) Uani 0.5 1 d D U P A 2
F15' F 0.7789(7) 0.6675(6) 0.5588(3) 0.0680(19) Uani 0.5 1 d D U P A 2
F16' F 0.6403(6) 0.5916(7) 0.5789(3) 0.0670(19) Uani 0.5 1 d D U P A 2
O21 O 0.89137(17) 0.62603(18) 0.43328(7) 0.0274(5) Uani 1 1 d . . . . .
O22 O 0.87971(17) 0.69072(17) 0.34504(7) 0.0260(5) Uani 1 1 d . . . . .
C21 C 1.0580(3) 0.6314(4) 0.46848(14) 0.0441(10) Uani 1 1 d . U . . .
C22 C 0.9865(3) 0.6472(3) 0.42769(12) 0.0283(7) Uani 1 1 d . . . . .
C23 C 1.0349(3) 0.6803(3) 0.38938(12) 0.0350(9) Uani 1 1 d . . . . .
H23 H 1.108875 0.692461 0.389701 0.042 Uiso 1 1 calc R U . . .
C24 C 0.9775(3) 0.6961(3) 0.35065(11) 0.0272(7) Uani 1 1 d . . . . .
C25 C 1.0400(3) 0.7276(3) 0.30947(13) 0.0401(9) Uani 1 1 d . U . . .
F21 F 1.0971(12) 0.5454(14) 0.4729(8) 0.056(3) Uani 0.5 1 d . U P C 1
F22 F 1.0179(18) 0.6657(17) 0.5038(9) 0.050(3) Uani 0.5 1 d . U P C 1
F23 F 1.1553(10) 0.6670(8) 0.4637(5) 0.051(2) Uani 0.5 1 d . U P C 1
F21' F 1.0739(11) 0.5278(12) 0.4717(8) 0.050(2) Uani 0.5 1 d . U P C 2
F22' F 1.0028(18) 0.6476(16) 0.5069(9) 0.048(3) Uani 0.5 1 d . U P C 2
F23' F 1.1386(10) 0.6981(8) 0.4693(5) 0.058(2) Uani 0.5 1 d . U P C 2
F24 F 1.0653(7) 0.8210(11) 0.3118(4) 0.053(2) Uani 0.5 1 d . U P D 1
F25 F 1.1332(7) 0.6771(10) 0.3053(4) 0.049(2) Uani 0.5 1 d . U P D 1
F26 F 0.9863(9) 0.7090(6) 0.2720(3) 0.0532(19) Uani 0.5 1 d . U P D 1
F24' F 1.0971(7) 0.8124(12) 0.3190(5) 0.054(2) Uani 0.5 1 d . U P D 2
F25' F 1.1061(8) 0.6607(10) 0.2975(4) 0.059(2) Uani 0.5 1 d . U P D 2
F26' F 0.9779(8) 0.7531(6) 0.2762(3) 0.057(2) Uani 0.5 1 d . U P D 2
O31 O 0.67791(17) 0.78570(17) 0.33724(7) 0.0265(5) Uani 1 1 d . . . . .
O32 O 0.54339(17) 0.67419(19) 0.39032(7) 0.0297(5) Uani 1 1 d . . . . .
C31 C 0.6047(3) 0.9026(3) 0.28881(12) 0.0352(8) Uani 1 1 d . U . . .
C32 C 0.5923(3) 0.8195(2) 0.32288(10) 0.0252(7) Uani 1 1 d . . . . .
C33 C 0.4915(3) 0.7916(3) 0.33525(12) 0.0370(9) Uani 1 1 d . . . . .
H33 H 0.431960 0.822119 0.321291 0.044 Uiso 1 1 calc R U . . .
C34 C 0.4763(3) 0.7200(3) 0.36758(12) 0.0356(9) Uani 1 1 d . U . . .
C35 C 0.3628(3) 0.6919(5) 0.37775(18) 0.0630(12) Uani 1 1 d . U . . .
F31 F 0.6755(8) 0.8806(11) 0.2580(5) 0.046(2) Uani 0.5 1 d . U P E 1
F32 F 0.6393(8) 0.9836(11) 0.3098(4) 0.045(2) Uani 0.5 1 d . U P E 1
F33 F 0.5139(15) 0.9246(8) 0.2685(5) 0.045(2) Uani 0.5 1 d . U P E 1
F31' F 0.6465(8) 0.8664(11) 0.2516(4) 0.046(2) Uani 0.5 1 d . U P E 2
F32' F 0.6699(7) 0.9761(11) 0.3021(4) 0.044(2) Uani 0.5 1 d . U P E 2
F33' F 0.5143(14) 0.9504(8) 0.2765(5) 0.042(2) Uani 0.5 1 d . U P E 2
F34 F 0.2896(8) 0.7420(8) 0.3563(3) 0.083(2) Uani 0.5 1 d . U P F 1
F35 F 0.3414(7) 0.6028(8) 0.3663(3) 0.086(2) Uani 0.5 1 d . U P F 1
F36 F 0.3492(6) 0.6967(6) 0.4228(3) 0.0668(19) Uani 0.5 1 d . U P F 1
F34' F 0.2950(7) 0.7715(7) 0.3741(3) 0.064(2) Uani 0.5 1 d . U P F 2
F35' F 0.3280(8) 0.6239(9) 0.3462(3) 0.093(2) Uani 0.5 1 d . U P F 2
F36' F 0.3437(7) 0.6435(7) 0.4125(3) 0.084(2) Uani 0.5 1 d . U P F 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.325(2) . yes
Eu1 O2 2.321(2) . yes
Eu1 O11 2.389(2) . yes
Eu1 O12 2.425(2) . yes
Eu1 O21 2.404(2) . yes
Eu1 O22 2.410(2) . yes
Eu1 O31 2.430(2) . yes
Eu1 O32 2.381(2) . yes
O1 P1 1.494(2) . ?
P1 C101 1.802(4) . ?
P1 C105 1.793(3) . ?
P1 C111 1.797(3) . ?
N11 C101 1.357(5) . ?
N11 C104 1.351(5) . ?
N12 C102 1.355(5) . ?
N12 C103 1.339(6) . ?
C101 C102 1.379(5) . ?
C102 H102 0.9500 . ?
C103 H103 0.9500 . ?
C103 C104 1.376(6) . ?
C104 H104 0.9500 . ?
C105 C106 1.393(5) . ?
C105 C110 1.390(5) . ?
C106 H106 0.9500 . ?
C106 C107 1.380(5) . ?
C107 H107 0.9500 . ?
C107 C108 1.383(5) . ?
C108 H108 0.9500 . ?
C108 C109 1.373(6) . ?
C109 H109 0.9500 . ?
C109 C110 1.384(5) . ?
C110 H110 0.9500 . ?
C111 C112 1.387(5) . ?
C111 C116 1.362(5) . ?
C112 H112 0.9500 . ?
C112 C113 1.369(5) . ?
C113 H113 0.9500 . ?
C113 C114 1.356(5) . ?
C114 H114 0.9500 . ?
C114 C115 1.381(6) . ?
C115 H115 0.9500 . ?
C115 C116 1.361(5) . ?
C116 H116 0.9500 . ?
O2 P2 1.490(2) . ?
P2 C201 1.810(3) . ?
P2 C205 1.795(3) . ?
P2 C211 1.796(3) . ?
N21 C201 1.337(4) . ?
N21 C204 1.336(5) . ?
N22 C202 1.343(5) . ?
N22 C203 1.329(6) . ?
C201 C202 1.378(5) . ?
C202 H202 0.9500 . ?
C203 H203 0.9500 . ?
C203 C204 1.376(6) . ?
C204 H204 0.9500 . ?
C205 C206 1.378(5) . ?
C205 C210 1.379(5) . ?
C206 H206 0.9500 . ?
C206 C207 1.389(6) . ?
C207 H207 0.9500 . ?
C207 C208 1.365(7) . ?
C208 H208 0.9500 . ?
C208 C209 1.349(7) . ?
C209 H209 0.9500 . ?
C209 C210 1.371(5) . ?
C210 H210 0.9500 . ?
C211 C212 1.381(5) . ?
C211 C216 1.396(5) . ?
C212 H212 0.9500 . ?
C212 C213 1.382(5) . ?
C213 H213 0.9500 . ?
C213 C214 1.379(5) . ?
C214 H214 0.9500 . ?
C214 C215 1.378(5) . ?
C215 H215 0.9500 . ?
C215 C216 1.379(5) . ?
C216 H216 0.9500 . ?
O11 C12 1.241(4) . ?
O12 C14 1.244(4) . ?
C11 C12 1.533(5) . ?
C11 F11 1.352(6) . ?
C11 F12 1.336(6) . ?
C11 F13 1.332(6) . ?
C11 F11' 1.332(6) . ?
C11 F12' 1.339(6) . ?
C11 F13' 1.335(6) . ?
C12 C13 1.383(5) . ?
C13 H13 0.9500 . ?
C13 C14 1.383(5) . ?
C14 C15 1.529(7) . ?
C14 C15' 1.545(7) . ?
C15 F14 1.346(7) . ?
C15 F15 1.338(7) . ?
C15 F16 1.341(6) . ?
C15' F14' 1.354(7) . ?
C15' F15' 1.351(6) . ?
C15' F16' 1.346(6) . ?
O21 C22 1.250(4) . ?
O22 C24 1.248(4) . ?
C21 C22 1.532(5) . ?
C21 F21 1.26(2) . ?
C21 F22 1.27(3) . ?
C21 F23 1.330(14) . ?
C21 F21' 1.400(18) . ?
C21 F22' 1.38(3) . ?
C21 F23' 1.354(14) . ?
C22 C23 1.385(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.384(5) . ?
C24 C25 1.538(5) . ?
C25 F24 1.288(15) . ?
C25 F25 1.366(13) . ?
C25 F26 1.335(11) . ?
C25 F24' 1.370(15) . ?
C25 F25' 1.278(14) . ?
C25 F26' 1.312(11) . ?
O31 C32 1.247(4) . ?
O32 C34 1.245(4) . ?
C31 C32 1.520(5) . ?
C31 F31 1.330(14) . ?
C31 F32 1.324(14) . ?
C31 F33 1.329(18) . ?
C31 F31' 1.336(15) . ?
C31 F32' 1.340(14) . ?
C31 F33' 1.357(17) . ?
C32 C33 1.384(5) . ?
C33 H33 0.9500 . ?
C33 C34 1.380(5) . ?
C34 C35 1.519(5) . ?
C35 F34 1.307(11) . ?
C35 F35 1.266(12) . ?
C35 F36 1.372(9) . ?
C35 F34' 1.369(10) . ?
C35 F35' 1.382(12) . ?
C35 F36' 1.257(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O11 72.20(8) . . ?
O1 Eu1 O12 139.39(8) . . ?
O1 Eu1 O21 113.03(8) . . ?
O1 Eu1 O22 73.10(8) . . ?
O1 Eu1 O31 78.66(8) . . ?
O1 Eu1 O32 83.07(8) . . ?
O2 Eu1 O1 145.53(8) . . ?
O2 Eu1 O11 141.62(8) . . ?
O2 Eu1 O12 74.35(8) . . ?
O2 Eu1 O21 77.80(8) . . ?
O2 Eu1 O22 80.71(8) . . ?
O2 Eu1 O31 72.22(8) . . ?
O2 Eu1 O32 103.69(8) . . ?
O11 Eu1 O12 70.49(8) . . ?
O11 Eu1 O21 78.36(8) . . ?
O11 Eu1 O22 118.65(8) . . ?
O11 Eu1 O31 142.81(8) . . ?
O12 Eu1 O31 125.51(8) . . ?
O21 Eu1 O12 74.28(8) . . ?
O21 Eu1 O22 71.04(7) . . ?
O21 Eu1 O31 135.58(7) . . ?
O22 Eu1 O12 140.69(8) . . ?
O22 Eu1 O31 72.37(7) . . ?
O32 Eu1 O11 83.22(8) . . ?
O32 Eu1 O12 77.22(8) . . ?
O32 Eu1 O21 149.90(8) . . ?
O32 Eu1 O22 139.06(7) . . ?
O32 Eu1 O31 70.59(8) . . ?
P1 O1 Eu1 147.92(13) . . ?
O1 P1 C101 109.22(15) . . ?
O1 P1 C105 112.78(14) . . ?
O1 P1 C111 110.74(15) . . ?
C105 P1 C101 107.76(16) . . ?
C105 P1 C111 108.08(15) . . ?
C111 P1 C101 108.11(16) . . ?
C104 N11 C101 116.2(4) . . ?
C103 N12 C102 116.4(4) . . ?
N11 C101 P1 117.6(3) . . ?
N11 C101 C102 121.8(3) . . ?
C102 C101 P1 120.7(3) . . ?
N12 C102 C101 121.5(4) . . ?
N12 C102 H102 119.2 . . ?
C101 C102 H102 119.2 . . ?
N12 C103 H103 118.8 . . ?
N12 C103 C104 122.4(4) . . ?
C104 C103 H103 118.8 . . ?
N11 C104 C103 121.6(4) . . ?
N11 C104 H104 119.2 . . ?
C103 C104 H104 119.2 . . ?
C106 C105 P1 118.1(3) . . ?
C110 C105 P1 122.8(3) . . ?
C110 C105 C106 119.1(3) . . ?
C105 C106 H106 119.7 . . ?
C107 C106 C105 120.6(3) . . ?
C107 C106 H106 119.7 . . ?
C106 C107 H107 120.1 . . ?
C106 C107 C108 119.8(4) . . ?
C108 C107 H107 120.1 . . ?
C107 C108 H108 120.0 . . ?
C109 C108 C107 120.1(4) . . ?
C109 C108 H108 120.0 . . ?
C108 C109 H109 119.7 . . ?
C108 C109 C110 120.6(4) . . ?
C110 C109 H109 119.7 . . ?
C105 C110 H110 120.1 . . ?
C109 C110 C105 119.9(4) . . ?
C109 C110 H110 120.1 . . ?
C112 C111 P1 117.5(3) . . ?
C116 C111 P1 122.2(3) . . ?
C116 C111 C112 120.3(3) . . ?
C111 C112 H112 120.2 . . ?
C113 C112 C111 119.6(3) . . ?
C113 C112 H112 120.2 . . ?
C112 C113 H113 120.0 . . ?
C114 C113 C112 119.9(4) . . ?
C114 C113 H113 120.0 . . ?
C113 C114 H114 119.9 . . ?
C113 C114 C115 120.2(4) . . ?
C115 C114 H114 119.9 . . ?
C114 C115 H115 119.8 . . ?
C116 C115 C114 120.4(4) . . ?
C116 C115 H115 119.8 . . ?
C111 C116 H116 120.2 . . ?
C115 C116 C111 119.6(3) . . ?
C115 C116 H116 120.2 . . ?
P2 O2 Eu1 154.96(15) . . ?
O2 P2 C201 109.75(15) . . ?
O2 P2 C205 109.37(16) . . ?
O2 P2 C211 112.85(15) . . ?
C205 P2 C201 108.95(16) . . ?
C205 P2 C211 107.53(15) . . ?
C211 P2 C201 108.29(15) . . ?
C204 N21 C201 115.6(3) . . ?
C203 N22 C202 116.3(4) . . ?
N21 C201 P2 117.5(3) . . ?
N21 C201 C202 122.0(3) . . ?
C202 C201 P2 120.4(3) . . ?
N22 C202 C201 121.7(4) . . ?
N22 C202 H202 119.1 . . ?
C201 C202 H202 119.1 . . ?
N22 C203 H203 119.1 . . ?
N22 C203 C204 121.7(4) . . ?
C204 C203 H203 119.1 . . ?
N21 C204 C203 122.6(4) . . ?
N21 C204 H204 118.7 . . ?
C203 C204 H204 118.7 . . ?
C206 C205 P2 122.3(3) . . ?
C206 C205 C210 120.0(3) . . ?
C210 C205 P2 117.7(3) . . ?
C205 C206 H206 120.8 . . ?
C205 C206 C207 118.4(4) . . ?
C207 C206 H206 120.8 . . ?
C206 C207 H207 119.7 . . ?
C208 C207 C206 120.6(4) . . ?
C208 C207 H207 119.7 . . ?
C207 C208 H208 119.6 . . ?
C209 C208 C207 120.7(4) . . ?
C209 C208 H208 119.6 . . ?
C208 C209 H209 120.1 . . ?
C208 C209 C210 119.8(5) . . ?
C210 C209 H209 120.1 . . ?
C205 C210 H210 119.8 . . ?
C209 C210 C205 120.4(4) . . ?
C209 C210 H210 119.8 . . ?
C212 C211 P2 123.2(3) . . ?
C212 C211 C216 119.6(3) . . ?
C216 C211 P2 117.3(3) . . ?
C211 C212 H212 120.1 . . ?
C211 C212 C213 119.8(3) . . ?
C213 C212 H212 120.1 . . ?
C212 C213 H213 119.7 . . ?
C214 C213 C212 120.5(4) . . ?
C214 C213 H213 119.7 . . ?
C213 C214 H214 120.0 . . ?
C215 C214 C213 119.9(3) . . ?
C215 C214 H214 120.0 . . ?
C214 C215 H215 120.0 . . ?
C214 C215 C216 120.0(3) . . ?
C216 C215 H215 120.0 . . ?
C211 C216 H216 119.9 . . ?
C215 C216 C211 120.1(3) . . ?
C215 C216 H216 119.9 . . ?
C12 O11 Eu1 136.7(2) . . ?
C14 O12 Eu1 134.9(2) . . ?
F11 C11 C12 105.5(7) . . ?
F12 C11 C12 115.6(5) . . ?
F12 C11 F11 103.2(6) . . ?
F13 C11 C12 112.0(9) . . ?
F13 C11 F11 110.8(8) . . ?
F13 C11 F12 109.3(8) . . ?
F11' C11 C12 113.7(7) . . ?
F11' C11 F12' 111.7(7) . . ?
F11' C11 F13' 103.0(9) . . ?
F12' C11 C12 105.6(5) . . ?
F13' C11 C12 115.3(9) . . ?
F13' C11 F12' 107.5(8) . . ?
O11 C12 C11 112.8(3) . . ?
O11 C12 C13 128.5(3) . . ?
C13 C12 C11 118.6(3) . . ?
C12 C13 H13 119.9 . . ?
C12 C13 C14 120.2(3) . . ?
C14 C13 H13 119.9 . . ?
O12 C14 C13 128.7(3) . . ?
O12 C14 C15 116.6(5) . . ?
O12 C14 C15' 110.6(5) . . ?
C13 C14 C15 114.7(4) . . ?
C13 C14 C15' 120.2(5) . . ?
F14 C15 C14 116.3(8) . . ?
F15 C15 C14 108.2(7) . . ?
F15 C15 F14 95.0(8) . . ?
F15 C15 F16 107.6(7) . . ?
F16 C15 C14 113.0(7) . . ?
F16 C15 F14 114.6(10) . . ?
F14' C15' C14 104.8(7) . . ?
F15' C15' C14 111.1(7) . . ?
F15' C15' F14' 118.4(9) . . ?
F16' C15' C14 113.1(7) . . ?
F16' C15' F14' 106.0(9) . . ?
F16' C15' F15' 103.6(7) . . ?
C22 O21 Eu1 133.9(2) . . ?
C24 O22 Eu1 134.9(2) . . ?
F21 C21 C22 116.1(10) . . ?
F21 C21 F22 113.7(15) . . ?
F21 C21 F23 88.5(8) . . ?
F22 C21 C22 112.6(12) . . ?
F22 C21 F23 110.0(11) . . ?
F23 C21 C22 113.8(7) . . ?
F21' C21 C22 105.9(8) . . ?
F22' C21 C22 110.7(11) . . ?
F22' C21 F21' 99.9(13) . . ?
F23' C21 C22 111.2(7) . . ?
F23' C21 F21' 122.7(8) . . ?
F23' C21 F22' 105.7(11) . . ?
O21 C22 C21 115.0(3) . . ?
O21 C22 C23 128.3(3) . . ?
C23 C22 C21 116.7(3) . . ?
C22 C23 H23 119.4 . . ?
C24 C23 C22 121.2(3) . . ?
C24 C23 H23 119.4 . . ?
O22 C24 C23 128.0(3) . . ?
O22 C24 C25 115.1(3) . . ?
C23 C24 C25 116.8(3) . . ?
F24 C25 C24 110.5(7) . . ?
F24 C25 F25 105.5(7) . . ?
F24 C25 F26 110.5(7) . . ?
F25 C25 C24 113.1(6) . . ?
F26 C25 C24 111.7(5) . . ?
F26 C25 F25 105.2(7) . . ?
F24' C25 C24 109.4(7) . . ?
F25' C25 C24 112.4(7) . . ?
F25' C25 F24' 106.9(7) . . ?
F25' C25 F26' 110.7(7) . . ?
F26' C25 C24 112.2(5) . . ?
F26' C25 F24' 104.8(7) . . ?
C32 O31 Eu1 135.7(2) . . ?
C34 O32 Eu1 136.2(2) . . ?
F31 C31 C32 112.7(7) . . ?
F32 C31 C32 108.0(6) . . ?
F32 C31 F31 107.0(7) . . ?
F32 C31 F33 108.6(7) . . ?
F33 C31 C32 112.1(7) . . ?
F33 C31 F31 108.2(8) . . ?
F31' C31 C32 110.3(7) . . ?
F31' C31 F32' 105.6(7) . . ?
F31' C31 F33' 106.4(8) . . ?
F32' C31 C32 113.5(6) . . ?
F32' C31 F33' 104.6(8) . . ?
F33' C31 C32 115.7(7) . . ?
O31 C32 C31 113.7(3) . . ?
O31 C32 C33 127.5(3) . . ?
C33 C32 C31 118.7(3) . . ?
C32 C33 H33 119.6 . . ?
C34 C33 C32 120.8(3) . . ?
C34 C33 H33 119.6 . . ?
O32 C34 C33 129.0(3) . . ?
O32 C34 C35 114.1(3) . . ?
C33 C34 C35 116.9(3) . . ?
F34 C35 C34 116.1(6) . . ?
F34 C35 F36 111.7(7) . . ?
F35 C35 C34 112.1(6) . . ?
F35 C35 F34 101.4(7) . . ?
F35 C35 F36 106.6(6) . . ?
F36 C35 C34 108.5(5) . . ?
F34' C35 C34 112.7(6) . . ?
F34' C35 F35' 105.1(6) . . ?
F35' C35 C34 108.5(6) . . ?
F36' C35 C34 119.1(5) . . ?
F36' C35 F34' 109.8(7) . . ?
F36' C35 F35' 100.0(7) . . ?

_refine_diff_density_max         0.968
_refine_diff_density_min         -0.700
_refine_diff_density_rms         0.082


_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent: MeOH'
