# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_75dnn23_0m
_audit_block_doi                 10.5517/ccdc.csd.cc281c90
_database_code_depnum_ccdc_archive 'CCDC 2086681'
loop_
_audit_author_name
_audit_author_address
'qiulan liang'
;Harbin normal university
China
;
_audit_update_record             
;
2021-05-29 deposited with the CCDC.	2021-07-06 downloaded from the CCDC.
;
_audit_creation_date             2019-03-08
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2016/4
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C120 H80 Ag6 B2 N20 O80 W24'
_chemical_formula_sum            'C120 H80 Ag6 B2 N20 O80 W24'
_chemical_formula_weight         8163.05
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.3019(10)
_cell_length_b                   14.9420(11)
_cell_length_c                   21.4307(15)
_cell_angle_alpha                74.0570(10)
_cell_angle_beta                 86.3790(10)
_cell_angle_gamma                65.4190(10)
_cell_volume                     3997.6(5)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    9863
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.29
_cell_measurement_theta_min      2.34
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    17.996
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    3.391
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3648.0
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.26
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0331
_diffrn_reflns_av_unetI/netI     0.0490
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.971
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            38592
_diffrn_reflns_point_group_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.971
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.332
_diffrn_reflns_theta_min         2.335
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                16324
_reflns_number_total             19906
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.18C (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.18C (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_refine_diff_density_max         3.396
_refine_diff_density_min         -7.023
_refine_diff_density_rms         0.363
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1135
_refine_ls_number_reflns         19323
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0511
_refine_ls_R_factor_gt           0.0415
_refine_ls_restrained_S_all      1.024
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0596P)²+92.1261P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1188
_refine_ls_wR_factor_ref         0.1248
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(Ag2) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(Ag3) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
3.a Aromatic/amide H refined with riding coordinates:
 C5(H5), C12(H12), C13(H13), C16(H16), C17(H17), C18(H18), C19(H19), C21(H21),
 C24(H24), C25(H25), C26(H26), C28(H28), C29(H29), C31(H31), C32(H32), C33(H33),
  C34(H34), C35(H35), C36(H36), C37(H37), C38(H38), C39(H39), C41(H41),
 C43(H43), C44(H44), C45(H45), C46(H46), C48(H48), C49(H49), C50(H50), C51(H51),
  C52(H52), C53(H53), C54(H54), C55(H55), C56(H56), C57(H57), C58(H58),
 C59(H59), C60(H60)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.62340(3) 1.03559(3) 0.61458(2) 0.01586(9) Uani 1 1 d . . . . .
W2 W 0.46400(3) 1.04102(3) 0.73339(2) 0.01511(9) Uani 1 1 d . . . . .
W3 W 0.68675(3) 1.04914(3) 0.75714(2) 0.01683(9) Uani 1 1 d . . . . .
W4 W 0.92500(3) 0.81767(3) 0.76711(2) 0.01891(9) Uani 1 1 d . . . . .
W5 W 0.61135(3) 0.80239(3) 0.60062(2) 0.01656(9) Uani 1 1 d . . . . .
W6 W 0.52151(3) 0.82329(3) 0.87759(2) 0.01783(9) Uani 1 1 d . . . . .
W7 W 0.73734(3) 0.61440(3) 0.88629(2) 0.01786(9) Uani 1 1 d . . . . .
W8 W 0.66888(3) 0.59958(3) 0.72931(2) 0.01773(9) Uani 1 1 d . . . . .
W9 W 0.45271(3) 0.80734(3) 0.71989(2) 0.01749(9) Uani 1 1 d . . . . .
W10 W 0.86031(3) 0.80591(3) 0.62537(2) 0.01817(9) Uani 1 1 d . . . . .
W11 W 0.74764(3) 0.82675(3) 0.89735(2) 0.01793(9) Uani 1 1 d . . . . .
W12 W 0.91571(3) 0.60554(3) 0.75501(2) 0.01745(9) Uani 1 1 d . . . . .
O1 O 0.4881(6) 1.0986(5) 0.6447(4) 0.0187(15) Uani 1 1 d . . . . .
O2 O 0.4770(6) 0.9598(5) 0.8196(3) 0.0177(14) Uani 1 1 d . . . . .
Ag1 Ag 0.55794(11) 0.69998(9) 0.47437(7) 0.0516(3) Uani 1 1 d . . . . .
Ag2 Ag 0.83831(11) 0.80433(11) 1.06371(7) 0.0564(3) Uani 1 1 d . U . . .
Ag3 Ag 0.22836(11) 1.23925(10) 0.65443(7) 0.0537(3) Uani 1 1 d . U . . .
O3 O 0.5845(6) 0.9409(5) 0.5916(3) 0.0171(14) Uani 1 1 d . . . . .
O4 O 0.4332(5) 0.9467(5) 0.7067(3) 0.0162(14) Uani 1 1 d . . . . .
O5 O 0.6782(6) 0.5906(5) 0.8188(4) 0.0194(15) Uani 1 1 d . . . . .
O6 O 0.3391(6) 1.1379(5) 0.7283(4) 0.0201(15) Uani 1 1 d . . . . .
O7 O 0.5951(6) 0.8035(6) 0.5211(4) 0.0254(17) Uani 1 1 d . . . . .
O8 O 0.5398(6) 1.1051(5) 0.7605(3) 0.0185(15) Uani 1 1 d . . . . .
O9 O 0.6754(5) 0.7879(5) 0.8204(3) 0.0126(13) Uani 1 1 d . . . . .
O10 O 0.6959(6) 0.9603(5) 0.8423(3) 0.0187(15) Uani 1 1 d . . . . .
O11 O 0.6274(5) 0.7768(5) 0.7135(3) 0.0144(13) Uani 1 1 d . . . . .
O12 O 0.6318(5) 0.9379(5) 0.7234(3) 0.0129(13) Uani 1 1 d . . . . .
O13 O 0.8067(6) 0.5828(5) 0.7249(3) 0.0194(15) Uani 1 1 d . . . . .
O14 O 0.7961(5) 0.7815(5) 0.7308(3) 0.0154(14) Uani 1 1 d . . . . .
O15 O 0.7604(6) 0.9434(5) 0.6120(3) 0.0180(14) Uani 1 1 d . . . . .
O16 O 0.9883(6) 0.6728(6) 0.7806(4) 0.0214(15) Uani 1 1 d . . . . .
O17 O 0.7824(6) 0.6836(6) 0.9329(3) 0.0202(15) Uani 1 1 d . . . . .
O18 O 0.5211(6) 0.6635(6) 0.7333(4) 0.0204(15) Uani 1 1 d . . . . .
O19 O 0.4715(6) 0.7926(5) 0.8095(3) 0.0181(15) Uani 1 1 d . . . . .
O40 O 0.6492(6) 0.6585(5) 0.6372(3) 0.0177(14) Uani 1 1 d . . . . .
O20 O 0.6098(6) 0.8518(5) 0.9247(3) 0.0178(14) Uani 1 1 d . . . . .
O21 O 0.8549(6) 0.5949(5) 0.8360(3) 0.0180(14) Uani 1 1 d . . . . .
O22 O 0.7523(6) 0.7762(5) 0.6022(3) 0.0186(15) Uani 1 1 d . . . . .
O23 O 0.8223(6) 0.9548(5) 0.7497(3) 0.0186(15) Uani 1 1 d . . . . .
O24 O 0.4765(6) 0.8255(5) 0.6289(4) 0.0184(15) Uani 1 1 d . . . . .
O25 O 0.6063(7) 1.1252(6) 0.5416(4) 0.0250(17) Uani 1 1 d . . . . .
O26 O 0.9454(6) 0.8329(6) 0.6767(4) 0.0221(16) Uani 1 1 d . . . . .
O27 O 0.9362(6) 0.6631(6) 0.6664(4) 0.0197(15) Uani 1 1 d . . . . .
O28 O 0.6840(7) 0.4774(6) 0.7333(4) 0.0282(18) Uani 1 1 d . . . . .
O29 O 0.8664(6) 0.7958(6) 0.8495(4) 0.0211(15) Uani 1 1 d . . . . .
O30 O 0.4201(7) 0.8442(6) 0.9266(4) 0.0276(18) Uani 1 1 d . . . . .
O31 O 0.6711(6) 1.0990(5) 0.6648(3) 0.0191(15) Uani 1 1 d . . . . .
O32 O 0.7084(7) 1.1437(6) 0.7747(4) 0.0266(18) Uani 1 1 d . . . . .
O33 O 0.6008(6) 0.6810(6) 0.9140(4) 0.0216(16) Uani 1 1 d . . . . .
O34 O 0.7764(7) 0.4970(6) 0.9421(4) 0.0272(18) Uani 1 1 d . . . . .
O35 O 0.3275(6) 0.8235(6) 0.7173(4) 0.0278(18) Uani 1 1 d . . . . .
O36 O 0.9201(6) 0.8152(7) 0.5539(4) 0.0303(19) Uani 1 1 d . . . . .
O37 O 0.7931(7) 0.8492(6) 0.9628(4) 0.0253(17) Uani 1 1 d . . . . .
O38 O 1.0136(7) 0.4854(6) 0.7696(4) 0.0286(18) Uani 1 1 d . . . . .
O39 O 1.0289(7) 0.8325(7) 0.7899(5) 0.035(2) Uani 1 1 d . . . . .
B1 B 0.6837(8) 0.8199(7) 0.7469(5) 0.0096(19) Uani 1 1 d . . . . .
N1 N 0.2222(7) 1.1306(7) 0.6218(4) 0.0201(18) Uani 1 1 d . . . . .
N2 N 0.6933(7) 0.8206(7) 1.0774(4) 0.0219(19) Uani 1 1 d . . . . .
N3 N 0.8642(8) 0.6561(7) 1.0756(4) 0.0227(19) Uani 1 1 d . . . . .
N4 N 0.2259(8) 1.3566(7) 0.6801(5) 0.0223(19) Uani 1 1 d . . . . .
N5 N 0.8445(8) 0.8983(7) 1.1135(5) 0.026(2) Uani 1 1 d . . . . .
N6 N 0.0852(8) 1.2406(8) 0.6931(5) 0.028(2) Uani 1 1 d . . . . .
N7 N 0.9742(8) 0.8033(8) 1.0369(5) 0.028(2) Uani 1 1 d . . . . .
N8 N 0.6274(8) 0.5210(8) 0.5190(5) 0.029(2) Uani 1 1 d . . . . .
N9 N 0.1854(8) 1.3444(7) 0.5656(5) 0.026(2) Uani 1 1 d . . . . .
C1 C 0.6833(9) 0.7317(9) 1.0802(6) 0.024(2) Uani 1 1 d . . . . .
C2 C 0.7756(9) 0.6446(8) 1.0793(5) 0.023(2) Uani 1 1 d . . . . .
C3 C 0.6200(8) 0.4689(8) 0.4781(5) 0.020(2) Uani 1 1 d . . . . .
C4 C 0.1672(8) 1.4407(8) 0.5685(5) 0.021(2) Uani 1 1 d . . . . .
C5 C 0.6088(10) 0.9037(9) 1.0757(6) 0.031(3) Uani 1 1 d . . . . .
H5 H 0.614542 0.964979 1.070693 0.038 Uiso 1 1 calc R . . . .
C6 C 0.1739(9) 1.5402(9) 0.6409(6) 0.026(2) Uani 1 1 d . . . . .
C7 C 0.1892(8) 1.4443(8) 0.6327(6) 0.022(2) Uani 1 1 d . . . . .
N10 N 0.5541(8) 0.6253(7) 0.3931(5) 0.029(2) Uani 1 1 d . . . . .
C8 C 0.5814(9) 0.5232(8) 0.4122(6) 0.023(2) Uani 1 1 d . . . . .
C9 C 1.0038(10) 0.8605(9) 1.0633(6) 0.028(2) Uani 1 1 d . . . . .
C10 C 0.1268(9) 1.5290(9) 0.5170(6) 0.028(2) Uani 1 1 d . . . . .
C11 C 0.9332(9) 0.9113(9) 1.1055(5) 0.024(2) Uani 1 1 d . . . . .
C12 C 0.2020(10) 1.5399(10) 0.7030(7) 0.033(3) Uani 1 1 d . . . . .
H12 H 0.193121 1.601024 0.710936 0.040 Uiso 1 1 calc R . . . .
C13 C 0.8642(12) 0.4662(9) 1.0817(6) 0.034(3) Uani 1 1 d . . . . .
H13 H 0.864928 0.402721 1.084240 0.041 Uiso 1 1 calc R . . . .
C14 C 0.6513(10) 0.3616(9) 0.4978(6) 0.029(3) Uani 1 1 d . . . . .
C15 C 0.7678(10) 0.5509(9) 1.0824(6) 0.027(2) Uani 1 1 d . . . . .
C16 C 0.9513(11) 0.5731(9) 1.0742(6) 0.031(3) Uani 1 1 d . . . . .
H16 H 1.013365 0.579818 1.071059 0.037 Uiso 1 1 calc R . . . .
C17 C 0.2420(11) 1.4508(11) 0.7516(7) 0.035(3) Uani 1 1 d . . . . .
H17 H 0.262190 1.449605 0.792309 0.042 Uiso 1 1 calc R . . . .
C18 C 0.6051(11) 0.3623(10) 0.3926(7) 0.035(3) Uani 1 1 d . . . . .
H18 H 0.599249 0.326947 0.364563 0.042 Uiso 1 1 calc R . . . .
C19 C 0.2928(10) 1.0750(9) 0.5871(5) 0.027(2) Uani 1 1 d . . . . .
H19 H 0.353713 1.083396 0.579423 0.033 Uiso 1 1 calc R . . . .
C20 C 0.0601(10) 1.1766(9) 0.6718(6) 0.030(3) Uani 1 1 d . . . . .
C21 C 0.2516(10) 1.3597(10) 0.7374(6) 0.032(3) Uani 1 1 d . . . . .
H21 H 0.277423 1.298782 0.770429 0.038 Uiso 1 1 calc R . . . .
C22 C 0.5720(9) 0.4709(9) 0.3688(6) 0.026(2) Uani 1 1 d . . . . .
C23 C 0.1343(10) 1.1164(9) 0.6343(6) 0.029(3) Uani 1 1 d . . . . .
C24 C 0.1328(10) 1.6308(9) 0.5863(7) 0.035(3) Uani 1 1 d . . . . .
H24 H 0.121887 1.693969 0.591763 0.041 Uiso 1 1 calc R . . . .
C25 C 0.9534(10) 0.4765(9) 1.0773(6) 0.030(3) Uani 1 1 d . . . . .
H25 H 1.015340 0.421305 1.076363 0.036 Uiso 1 1 calc R . . . .
C26 C 0.6618(11) 0.4687(13) 0.5794(6) 0.040(3) Uani 1 1 d . . . . .
H26 H 0.663533 0.504897 0.608031 0.048 Uiso 1 1 calc R . . . .
C27 C 0.5860(10) 0.7271(10) 1.0841(7) 0.031(3) Uani 1 1 d . . . . .
C28 C 0.1653(11) 1.3381(9) 0.5057(6) 0.032(3) Uani 1 1 d . . . . .
H28 H 0.176607 1.274205 0.501301 0.039 Uiso 1 1 calc R . . . .
C29 C 0.7785(11) 0.9427(11) 1.1541(6) 0.035(3) Uani 1 1 d . . . . .
H29 H 0.719402 0.930715 1.161722 0.042 Uiso 1 1 calc R . . . .
C30 C 0.9557(11) 0.9743(10) 1.1353(7) 0.034(3) Uani 1 1 d . . . . .
C31 C 0.2771(12) 1.0052(10) 0.5623(6) 0.040(3) Uani 1 1 d . . . . .
H31 H 0.326588 0.968923 0.537678 0.047 Uiso 1 1 calc R . . . .
C32 C 0.8827(12) 1.0221(11) 1.1767(8) 0.043(3) Uani 1 1 d . . . . .
H32 H 0.894561 1.063725 1.197568 0.051 Uiso 1 1 calc R . . . .
C33 C 0.7937(12) 1.0064(11) 1.1859(7) 0.040(3) Uani 1 1 d . . . . .
H33 H 0.744645 1.037649 1.212757 0.048 Uiso 1 1 calc R . . . .
C34 C 0.1085(11) 1.5182(10) 0.4570(7) 0.037(3) Uani 1 1 d . . . . .
H34 H 0.082797 1.575226 0.421236 0.045 Uiso 1 1 calc R . . . .
C35 C 0.6432(12) 0.3104(9) 0.4524(7) 0.038(3) Uani 1 1 d . . . . .
H35 H 0.665128 0.239746 0.465235 0.046 Uiso 1 1 calc R . . . .
C36 C 0.1290(11) 1.4216(11) 0.4510(7) 0.037(3) Uani 1 1 d . . . . .
H36 H 0.118543 1.412879 0.411062 0.045 Uiso 1 1 calc R . . . .
C37 C 0.1105(10) 1.6253(10) 0.5287(7) 0.037(3) Uani 1 1 d . . . . .
H37 H 0.083694 1.684942 0.494774 0.045 Uiso 1 1 calc R . . . .
C38 C 0.6713(12) 0.5477(10) 1.0859(8) 0.039(3) Uani 1 1 d . . . . .
H38 H 0.666973 0.486578 1.088046 0.047 Uiso 1 1 calc R . . . .
C39 C 0.5006(11) 0.8172(12) 1.0845(8) 0.044(4) Uani 1 1 d . . . . .
H39 H 0.435084 0.818053 1.087103 0.053 Uiso 1 1 calc R . . . .
C40 C 1.0956(12) 0.8732(12) 1.0503(8) 0.043(3) Uani 1 1 d . . . . .
C41 C 0.5305(10) 0.5273(11) 0.3054(6) 0.035(3) Uani 1 1 d . . . . .
H41 H 0.523041 0.494803 0.275983 0.042 Uiso 1 1 calc R . . . .
C42 C 0.1131(12) 1.0460(11) 0.6115(8) 0.042(3) Uani 1 1 d . . . . .
C43 C 0.5151(11) 0.6770(11) 0.3323(7) 0.041(3) Uani 1 1 d . . . . .
H43 H 0.496457 0.747223 0.319434 0.049 Uiso 1 1 calc R . . . .
C44 C 0.5009(12) 0.6320(12) 0.2872(7) 0.044(4) Uani 1 1 d . . . . .
H44 H 0.472046 0.671364 0.245721 0.053 Uiso 1 1 calc R . . . .
C45 C 0.6887(12) 0.3105(11) 0.5630(7) 0.040(3) Uani 1 1 d . . . . .
H45 H 0.708722 0.240175 0.578323 0.048 Uiso 1 1 calc R . . . .
C46 C 0.0195(11) 1.2946(11) 0.7296(7) 0.042(3) Uani 1 1 d . . . . .
H46 H 0.035473 1.339497 0.744722 0.050 Uiso 1 1 calc R . . . .
C47 C -0.0313(11) 1.1611(12) 0.6868(8) 0.043(3) Uani 1 1 d . . . . .
C48 C 0.5836(11) 0.6320(12) 1.0863(8) 0.045(4) Uani 1 1 d . . . . .
H48 H 0.520542 0.627314 1.088131 0.053 Uiso 1 1 calc R . . . .
C49 C 0.6955(12) 0.3638(13) 0.6033(7) 0.046(4) Uani 1 1 d . . . . .
H49 H 0.722164 0.330574 0.645940 0.055 Uiso 1 1 calc R . . . .
C50 C 1.0364(12) 0.7592(12) 0.9942(8) 0.045(4) Uani 1 1 d . . . . .
H50 H 1.017774 0.720472 0.974298 0.054 Uiso 1 1 calc R . . . .
C51 C 0.5127(13) 0.9036(13) 1.0811(9) 0.051(4) Uani 1 1 d . . . . .
H51 H 0.455694 0.963201 1.082321 0.061 Uiso 1 1 calc R . . . .
C52 C 1.1159(12) 0.9384(12) 1.0830(9) 0.048(4) Uani 1 1 d . . . . .
H52 H 1.176539 0.947381 1.075326 0.058 Uiso 1 1 calc R . . . .
C53 C -0.0745(12) 1.2855(14) 0.7459(8) 0.054(4) Uani 1 1 d . . . . .
H53 H -0.120539 1.325453 0.770298 0.065 Uiso 1 1 calc R . . . .
C54 C 0.1877(13) 0.9897(11) 0.5743(8) 0.049(4) Uani 1 1 d . . . . .
H54 H 0.176995 0.942864 0.557947 0.058 Uiso 1 1 calc R . . . .
C55 C 1.1580(12) 0.8243(12) 1.0071(9) 0.051(4) Uani 1 1 d . . . . .
H55 H 1.220358 0.829161 0.997846 0.061 Uiso 1 1 calc R . . . .
C56 C 1.1288(13) 0.7700(13) 0.9786(9) 0.053(4) Uani 1 1 d . . . . .
H56 H 1.169860 0.739333 0.948384 0.064 Uiso 1 1 calc R . . . .
C57 C 1.0514(13) 0.9849(13) 1.1229(8) 0.047(4) Uani 1 1 d . . . . .
H57 H 1.068046 1.024542 1.143078 0.057 Uiso 1 1 calc R . . . .
C58 C -0.0959(12) 1.2190(13) 0.7258(8) 0.051(4) Uani 1 1 d . . . . .
H58 H -0.156019 1.210866 0.738321 0.061 Uiso 1 1 calc R . . . .
C59 C 0.0206(15) 1.0360(14) 0.6249(10) 0.061(5) Uani 1 1 d . . . . .
H59 H 0.005384 0.991707 0.608641 0.073 Uiso 1 1 calc R . . . .
C60 C -0.0479(15) 1.0921(15) 0.6624(11) 0.071(6) Uani 1 1 d . . . . .
H60 H -0.108322 1.083048 0.671739 0.085 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 O1 1.926(7) . ?
W1 O3 1.904(7) . ?
W1 O12 2.367(6) . ?
W1 O15 1.877(7) . ?
W1 O25 1.710(8) . ?
W1 O31 1.927(7) . ?
W2 O1 1.932(7) . ?
W2 O2 1.884(7) . ?
W2 O4 1.871(7) . ?
W2 O6 1.757(7) . ?
W2 O8 1.919(7) . ?
W2 O12 2.285(7) . ?
W3 O8 1.916(8) . ?
W3 O10 1.914(7) . ?
W3 O12 2.392(7) . ?
W3 O23 1.893(7) . ?
W3 O31 1.905(7) . ?
W3 O32 1.704(7) . ?
W4 O14 2.354(7) . ?
W4 O16 1.910(7) . ?
W4 O23 1.908(7) . ?
W4 O26 1.906(8) . ?
W4 O29 1.910(8) . ?
W4 O39 1.709(9) . ?
W5 O3 1.897(7) . ?
W5 O7 1.728(8) . ?
W5 O11 2.353(7) . ?
W5 O40 1.921(7) . ?
W5 O22 1.887(8) . ?
W5 O24 1.902(8) . ?
W6 O2 1.933(7) . ?
W6 O9 2.381(7) . ?
W6 O19 1.904(7) . ?
W6 O20 1.907(8) . ?
W6 O30 1.708(8) . ?
W6 O33 1.901(7) . ?
W7 O5 1.903(7) . ?
W7 O9 2.395(6) . ?
W7 O17 1.919(7) . ?
W7 O21 1.900(7) . ?
W7 O33 1.928(8) . ?
W7 O34 1.713(7) . ?
W8 O5 1.895(7) . ?
W8 O11 2.389(6) . ?
W8 O13 1.880(8) . ?
W8 O18 1.931(8) . ?
W8 O40 1.912(7) . ?
W8 O28 1.725(8) . ?
W9 O4 1.922(7) . ?
W9 O11 2.348(7) . ?
W9 O18 1.898(7) . ?
W9 O19 1.894(7) . ?
W9 O24 1.922(7) . ?
W9 O35 1.707(8) . ?
W10 O14 2.376(7) . ?
W10 O15 1.906(7) . ?
W10 O22 1.903(8) . ?
W10 O26 1.917(8) . ?
W10 O27 1.916(7) . ?
W10 O36 1.706(8) . ?
W11 O9 2.316(6) . ?
W11 O10 1.874(7) . ?
W11 O17 1.916(7) . ?
W11 O20 1.931(8) . ?
W11 O29 1.881(8) . ?
W11 O37 1.749(8) . ?
W12 O13 1.911(8) . ?
W12 O14 2.393(7) . ?
W12 O16 1.905(8) . ?
W12 O21 1.889(7) . ?
W12 O27 1.916(7) . ?
W12 O38 1.713(8) . ?
Ag1 O7 2.298(8) . ?
Ag1 N8 2.357(11) . ?
Ag1 N10 2.326(11) . ?
Ag2 O37 2.136(8) . ?
Ag2 N2 1.997(10) . ?
Ag2 N3 2.032(9) . ?
Ag2 N5 2.014(9) . ?
Ag2 N7 1.987(10) . ?
Ag3 O6 2.077(8) . ?
Ag3 N1 1.970(9) . ?
Ag3 N4 1.963(9) . ?
Ag3 N6 2.154(10) . ?
Ag3 N9 2.043(10) . ?
O9 B1 1.528(11) . ?
O11 B1 1.528(12) . ?
O12 B1 1.544(11) . ?
O14 B1 1.517(12) . ?
N1 C19 1.346(15) . ?
N1 C23 1.360(16) . ?
N2 C1 1.380(14) . ?
N2 C5 1.317(15) . ?
N3 C2 1.342(15) . ?
N3 C16 1.349(16) . ?
N4 C7 1.338(14) . ?
N4 C21 1.322(15) . ?
N5 C11 1.355(16) . ?
N5 C29 1.334(16) . ?
N6 C20 1.342(16) . ?
N6 C46 1.329(16) . ?
N7 C9 1.352(15) . ?
N7 C50 1.344(17) . ?
N8 C3 1.356(14) . ?
N8 C26 1.317(17) . ?
N9 C4 1.370(14) . ?
N9 C28 1.369(15) . ?
C1 C2 1.420(16) . ?
C1 C27 1.417(17) . ?
C2 C15 1.434(15) . ?
C3 C8 1.434(16) . ?
C3 C14 1.415(16) . ?
C4 C7 1.452(15) . ?
C4 C10 1.392(16) . ?
C5 C51 1.37(2) . ?
C6 C7 1.415(15) . ?
C6 C12 1.413(18) . ?
C6 C24 1.450(19) . ?
N10 C8 1.353(14) . ?
N10 C43 1.337(18) . ?
C8 C22 1.412(15) . ?
C9 C11 1.426(17) . ?
C9 C40 1.403(19) . ?
C10 C34 1.393(19) . ?
C10 C37 1.448(18) . ?
C11 C30 1.415(15) . ?
C12 C17 1.36(2) . ?
C13 C15 1.436(18) . ?
C13 C25 1.34(2) . ?
C14 C35 1.429(18) . ?
C14 C45 1.410(19) . ?
C15 C38 1.396(19) . ?
C16 C25 1.414(17) . ?
C17 C21 1.426(17) . ?
C18 C22 1.434(17) . ?
C18 C35 1.32(2) . ?
C19 C31 1.389(17) . ?
C20 C23 1.440(17) . ?
C20 C47 1.422(18) . ?
C22 C41 1.402(18) . ?
C23 C42 1.415(16) . ?
C24 C37 1.33(2) . ?
C26 C49 1.38(2) . ?
C27 C39 1.394(18) . ?
C27 C48 1.424(19) . ?
C28 C36 1.390(18) . ?
C29 C33 1.403(17) . ?
C30 C32 1.41(2) . ?
C30 C57 1.44(2) . ?
C31 C54 1.39(2) . ?
C32 C33 1.38(2) . ?
C34 C36 1.39(2) . ?
C38 C48 1.36(2) . ?
C39 C51 1.35(2) . ?
C40 C52 1.47(2) . ?
C40 C55 1.38(2) . ?
C41 C44 1.38(2) . ?
C42 C54 1.41(2) . ?
C42 C59 1.40(2) . ?
C43 C44 1.39(2) . ?
C45 C49 1.36(2) . ?
C46 C53 1.42(2) . ?
C47 C58 1.39(2) . ?
C47 C60 1.38(3) . ?
C50 C56 1.41(2) . ?
C52 C57 1.33(2) . ?
C53 C58 1.33(3) . ?
C55 C56 1.34(2) . ?
C59 C60 1.38(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 W1 O12 74.9(3) . . ?
O1 W1 O31 88.3(3) . . ?
O3 W1 O1 89.9(3) . . ?
O3 W1 O12 85.9(3) . . ?
O3 W1 O31 161.4(3) . . ?
O15 W1 O1 161.1(3) . . ?
O15 W1 O3 86.8(3) . . ?
O15 W1 O12 86.3(3) . . ?
O15 W1 O31 89.0(3) . . ?
O25 W1 O1 97.6(4) . . ?
O25 W1 O3 101.8(3) . . ?
O25 W1 O12 169.4(3) . . ?
O25 W1 O15 101.3(4) . . ?
O25 W1 O31 96.9(3) . . ?
O31 W1 O12 75.7(3) . . ?
O1 W2 O12 76.8(3) . . ?
O2 W2 O1 164.7(3) . . ?
O2 W2 O8 88.9(3) . . ?
O2 W2 O12 87.9(3) . . ?
O4 W2 O1 89.9(3) . . ?
O4 W2 O2 88.4(3) . . ?
O4 W2 O8 161.4(3) . . ?
O4 W2 O12 85.2(3) . . ?
O6 W2 O1 92.8(3) . . ?
O6 W2 O2 102.5(3) . . ?
O6 W2 O4 99.2(3) . . ?
O6 W2 O8 99.3(3) . . ?
O6 W2 O12 168.8(3) . . ?
O8 W2 O1 87.9(3) . . ?
O8 W2 O12 76.3(3) . . ?
O8 W3 O12 73.8(3) . . ?
O10 W3 O8 88.4(3) . . ?
O10 W3 O12 84.2(3) . . ?
O23 W3 O8 159.3(3) . . ?
O23 W3 O10 85.9(3) . . ?
O23 W3 O12 85.9(3) . . ?
O23 W3 O31 89.1(3) . . ?
O31 W3 O8 89.4(3) . . ?
O31 W3 O10 159.4(3) . . ?
O31 W3 O12 75.5(3) . . ?
O32 W3 O8 98.9(4) . . ?
O32 W3 O10 101.1(3) . . ?
O32 W3 O12 170.9(3) . . ?
O32 W3 O23 101.8(4) . . ?
O32 W3 O31 99.5(3) . . ?
O16 W4 O14 76.2(3) . . ?
O23 W4 O14 85.1(3) . . ?
O23 W4 O16 160.9(3) . . ?
O23 W4 O29 85.7(3) . . ?
O26 W4 O14 76.4(3) . . ?
O26 W4 O16 88.4(3) . . ?
O26 W4 O23 91.1(3) . . ?
O26 W4 O29 160.8(3) . . ?
O29 W4 O14 84.5(3) . . ?
O29 W4 O16 88.5(3) . . ?
O39 W4 O14 173.2(3) . . ?
O39 W4 O16 98.2(4) . . ?
O39 W4 O23 100.7(4) . . ?
O39 W4 O26 99.8(4) . . ?
O39 W4 O29 99.3(4) . . ?
O3 W5 O11 86.8(3) . . ?
O3 W5 O40 162.0(3) . . ?
O3 W5 O24 90.7(3) . . ?
O7 W5 O3 101.9(3) . . ?
O7 W5 O11 170.5(3) . . ?
O7 W5 O40 96.0(3) . . ?
O7 W5 O22 99.1(4) . . ?
O7 W5 O24 100.2(4) . . ?
O40 W5 O11 75.4(3) . . ?
O22 W5 O3 86.4(3) . . ?
O22 W5 O11 85.1(3) . . ?
O22 W5 O40 89.0(3) . . ?
O22 W5 O24 160.6(3) . . ?
O24 W5 O11 75.6(3) . . ?
O24 W5 O40 87.9(3) . . ?
O2 W6 O9 84.8(3) . . ?
O19 W6 O2 85.3(3) . . ?
O19 W6 O9 84.8(3) . . ?
O19 W6 O20 159.4(3) . . ?
O20 W6 O2 89.2(3) . . ?
O20 W6 O9 74.9(3) . . ?
O30 W6 O2 98.8(3) . . ?
O30 W6 O9 173.3(3) . . ?
O30 W6 O19 101.1(4) . . ?
O30 W6 O20 99.4(4) . . ?
O30 W6 O33 100.7(4) . . ?
O33 W6 O2 160.5(3) . . ?
O33 W6 O9 76.1(3) . . ?
O33 W6 O19 89.1(3) . . ?
O33 W6 O20 89.4(3) . . ?
O5 W7 O9 85.6(3) . . ?
O5 W7 O17 160.2(3) . . ?
O5 W7 O33 88.9(3) . . ?
O17 W7 O9 74.7(3) . . ?
O17 W7 O33 87.9(3) . . ?
O21 W7 O5 86.5(3) . . ?
O21 W7 O9 84.3(3) . . ?
O21 W7 O17 89.6(3) . . ?
O21 W7 O33 159.3(3) . . ?
O33 W7 O9 75.2(3) . . ?
O34 W7 O5 100.2(3) . . ?
O34 W7 O9 172.3(3) . . ?
O34 W7 O17 99.5(4) . . ?
O34 W7 O21 101.0(4) . . ?
O34 W7 O33 99.6(4) . . ?
O5 W8 O11 84.6(3) . . ?
O5 W8 O18 87.3(3) . . ?
O5 W8 O40 159.3(3) . . ?
O13 W8 O5 88.4(3) . . ?
O13 W8 O11 85.5(3) . . ?
O13 W8 O18 160.2(3) . . ?
O13 W8 O40 89.5(3) . . ?
O18 W8 O11 74.8(3) . . ?
O40 W8 O11 74.7(3) . . ?
O40 W8 O18 87.7(3) . . ?
O28 W8 O5 100.8(4) . . ?
O28 W8 O11 171.9(3) . . ?
O28 W8 O13 100.6(4) . . ?
O28 W8 O18 99.2(4) . . ?
O28 W8 O40 99.8(4) . . ?
O4 W9 O11 83.3(3) . . ?
O4 W9 O24 87.2(3) . . ?
O18 W9 O4 159.7(3) . . ?
O18 W9 O11 76.4(3) . . ?
O18 W9 O24 89.2(3) . . ?
O19 W9 O4 86.0(3) . . ?
O19 W9 O11 86.2(3) . . ?
O19 W9 O18 91.1(3) . . ?
O19 W9 O24 161.0(3) . . ?
O24 W9 O11 75.4(3) . . ?
O35 W9 O4 100.1(4) . . ?
O35 W9 O11 173.4(3) . . ?
O35 W9 O18 100.2(4) . . ?
O35 W9 O19 99.6(4) . . ?
O35 W9 O24 99.1(4) . . ?
O15 W10 O14 84.1(3) . . ?
O15 W10 O26 89.3(3) . . ?
O15 W10 O27 159.8(3) . . ?
O22 W10 O14 84.3(3) . . ?
O22 W10 O15 86.7(3) . . ?
O22 W10 O26 159.8(3) . . ?
O22 W10 O27 88.9(3) . . ?
O26 W10 O14 75.6(3) . . ?
O27 W10 O14 75.9(3) . . ?
O27 W10 O26 88.1(3) . . ?
O36 W10 O14 173.5(3) . . ?
O36 W10 O15 100.7(4) . . ?
O36 W10 O22 100.3(4) . . ?
O36 W10 O26 99.8(4) . . ?
O36 W10 O27 99.5(4) . . ?
O10 W11 O9 85.9(3) . . ?
O10 W11 O17 162.6(3) . . ?
O10 W11 O20 88.7(3) . . ?
O10 W11 O29 88.5(3) . . ?
O17 W11 O9 76.8(3) . . ?
O17 W11 O20 87.6(3) . . ?
O20 W11 O9 76.1(3) . . ?
O29 W11 O9 86.6(3) . . ?
O29 W11 O17 90.0(3) . . ?
O29 W11 O20 162.7(3) . . ?
O37 W11 O9 172.5(3) . . ?
O37 W11 O10 98.5(3) . . ?
O37 W11 O17 98.8(3) . . ?
O37 W11 O20 97.9(3) . . ?
O37 W11 O29 99.5(4) . . ?
O13 W12 O14 85.6(3) . . ?
O13 W12 O27 88.8(3) . . ?
O16 W12 O13 160.8(3) . . ?
O16 W12 O14 75.3(3) . . ?
O16 W12 O27 88.2(3) . . ?
O21 W12 O13 86.1(3) . . ?
O21 W12 O14 84.3(3) . . ?
O21 W12 O16 90.1(3) . . ?
O21 W12 O27 159.4(3) . . ?
O27 W12 O14 75.4(3) . . ?
O38 W12 O13 100.7(4) . . ?
O38 W12 O14 172.5(3) . . ?
O38 W12 O16 98.5(4) . . ?
O38 W12 O21 100.0(4) . . ?
O38 W12 O27 100.5(4) . . ?
W1 O1 W2 117.8(4) . . ?
W2 O2 W6 146.9(4) . . ?
O7 Ag1 N8 121.6(3) . . ?
O7 Ag1 N10 156.2(3) . . ?
N10 Ag1 N8 71.5(4) . . ?
N2 Ag2 O37 84.5(3) . . ?
N2 Ag2 N3 82.5(4) . . ?
N2 Ag2 N5 99.8(4) . . ?
N3 Ag2 O37 93.6(3) . . ?
N5 Ag2 O37 125.0(4) . . ?
N5 Ag2 N3 141.4(4) . . ?
N7 Ag2 O37 87.5(4) . . ?
N7 Ag2 N2 171.3(4) . . ?
N7 Ag2 N3 101.7(4) . . ?
N7 Ag2 N5 81.8(4) . . ?
O6 Ag3 N6 104.4(4) . . ?
N1 Ag3 O6 94.1(3) . . ?
N1 Ag3 N6 81.1(4) . . ?
N1 Ag3 N9 93.2(4) . . ?
N4 Ag3 O6 91.1(4) . . ?
N4 Ag3 N1 174.8(4) . . ?
N4 Ag3 N6 98.2(4) . . ?
N4 Ag3 N9 82.0(4) . . ?
N9 Ag3 O6 151.3(4) . . ?
N9 Ag3 N6 104.1(4) . . ?
W5 O3 W1 147.9(4) . . ?
W2 O4 W9 148.5(4) . . ?
W8 O5 W7 148.1(4) . . ?
W2 O6 Ag3 136.1(4) . . ?
W5 O7 Ag1 133.7(4) . . ?
W3 O8 W2 119.6(3) . . ?
W6 O9 W7 88.2(2) . . ?
W11 O9 W6 89.7(2) . . ?
W11 O9 W7 89.2(2) . . ?
B1 O9 W6 127.0(5) . . ?
B1 O9 W7 124.6(5) . . ?
B1 O9 W11 126.2(5) . . ?
W11 O10 W3 148.2(4) . . ?
W5 O11 W8 89.2(2) . . ?
W9 O11 W5 89.3(2) . . ?
W9 O11 W8 88.8(2) . . ?
B1 O11 W5 125.6(5) . . ?
B1 O11 W8 125.7(5) . . ?
B1 O11 W9 126.4(5) . . ?
W1 O12 W3 88.5(2) . . ?
W2 O12 W1 90.5(2) . . ?
W2 O12 W3 90.2(2) . . ?
B1 O12 W1 124.7(5) . . ?
B1 O12 W2 126.8(5) . . ?
B1 O12 W3 124.8(5) . . ?
W8 O13 W12 148.4(4) . . ?
W4 O14 W10 88.5(2) . . ?
W4 O14 W12 88.3(2) . . ?
W10 O14 W12 88.3(2) . . ?
B1 O14 W4 127.4(5) . . ?
B1 O14 W10 126.5(5) . . ?
B1 O14 W12 125.3(5) . . ?
W1 O15 W10 149.2(4) . . ?
W12 O16 W4 120.2(4) . . ?
W11 O17 W7 119.3(4) . . ?
W9 O18 W8 119.9(4) . . ?
W9 O19 W6 150.6(4) . . ?
W8 O40 W5 120.6(3) . . ?
W6 O20 W11 119.2(4) . . ?
W12 O21 W7 151.1(4) . . ?
W5 O22 W10 149.6(4) . . ?
W3 O23 W4 150.4(4) . . ?
W5 O24 W9 119.6(4) . . ?
W4 O26 W10 119.4(4) . . ?
W10 O27 W12 120.3(4) . . ?
W11 O29 W4 147.8(4) . . ?
W3 O31 W1 120.2(4) . . ?
W6 O33 W7 120.4(4) . . ?
W11 O37 Ag2 149.7(5) . . ?
O9 B1 O12 108.0(7) . . ?
O11 B1 O9 109.8(7) . . ?
O11 B1 O12 109.0(7) . . ?
O14 B1 O9 110.0(7) . . ?
O14 B1 O11 110.1(7) . . ?
O14 B1 O12 109.9(7) . . ?
C19 N1 Ag3 126.7(8) . . ?
C19 N1 C23 119.0(10) . . ?
C23 N1 Ag3 114.3(8) . . ?
C1 N2 Ag2 111.5(7) . . ?
C5 N2 Ag2 129.8(9) . . ?
C5 N2 C1 118.1(11) . . ?
C2 N3 Ag2 111.4(7) . . ?
C2 N3 C16 117.0(10) . . ?
C16 N3 Ag2 131.4(9) . . ?
C7 N4 Ag3 113.6(7) . . ?
C21 N4 Ag3 128.6(8) . . ?
C21 N4 C7 117.8(10) . . ?
C11 N5 Ag2 112.1(8) . . ?
C29 N5 Ag2 129.8(9) . . ?
C29 N5 C11 118.0(10) . . ?
C20 N6 Ag3 109.5(8) . . ?
C46 N6 Ag3 132.4(10) . . ?
C46 N6 C20 117.9(12) . . ?
C9 N7 Ag2 113.9(8) . . ?
C50 N7 Ag2 129.3(9) . . ?
C50 N7 C9 116.7(11) . . ?
C3 N8 Ag1 114.3(8) . . ?
C26 N8 Ag1 127.8(9) . . ?
C26 N8 C3 117.6(12) . . ?
C4 N9 Ag3 112.4(7) . . ?
C28 N9 Ag3 132.5(8) . . ?
C28 N9 C4 115.0(10) . . ?
N2 C1 C2 116.6(10) . . ?
N2 C1 C27 121.8(11) . . ?
C27 C1 C2 121.6(11) . . ?
N3 C2 C1 117.5(10) . . ?
N3 C2 C15 124.6(11) . . ?
C1 C2 C15 117.9(11) . . ?
N8 C3 C8 119.3(10) . . ?
N8 C3 C14 122.3(11) . . ?
C14 C3 C8 118.3(10) . . ?
N9 C4 C7 113.4(10) . . ?
N9 C4 C10 125.0(10) . . ?
C10 C4 C7 121.6(10) . . ?
N2 C5 C51 122.9(13) . . ?
C7 C6 C24 119.3(11) . . ?
C12 C6 C7 116.4(11) . . ?
C12 C6 C24 124.3(11) . . ?
N4 C7 C4 118.2(10) . . ?
N4 C7 C6 123.9(11) . . ?
C6 C7 C4 117.9(10) . . ?
C8 N10 Ag1 116.0(8) . . ?
C43 N10 Ag1 124.8(9) . . ?
C43 N10 C8 118.5(12) . . ?
N10 C8 C3 118.2(10) . . ?
N10 C8 C22 121.3(11) . . ?
C22 C8 C3 120.5(10) . . ?
N7 C9 C11 115.4(11) . . ?
N7 C9 C40 124.1(12) . . ?
C40 C9 C11 120.5(11) . . ?
C4 C10 C34 117.7(11) . . ?
C4 C10 C37 118.0(12) . . ?
C34 C10 C37 124.3(12) . . ?
N5 C11 C9 116.9(10) . . ?
N5 C11 C30 122.9(12) . . ?
C30 C11 C9 120.2(11) . . ?
C17 C12 C6 120.7(11) . . ?
C25 C13 C15 121.4(11) . . ?
C3 C14 C35 119.9(12) . . ?
C45 C14 C3 116.9(12) . . ?
C45 C14 C35 123.1(12) . . ?
C2 C15 C13 114.7(11) . . ?
C38 C15 C2 119.8(11) . . ?
C38 C15 C13 125.5(11) . . ?
N3 C16 C25 123.6(13) . . ?
C12 C17 C21 117.4(12) . . ?
C35 C18 C22 122.9(11) . . ?
N1 C19 C31 121.9(13) . . ?
N6 C20 C23 116.8(11) . . ?
N6 C20 C47 124.2(12) . . ?
C47 C20 C23 119.0(13) . . ?
N4 C21 C17 123.9(12) . . ?
C8 C22 C18 117.7(11) . . ?
C41 C22 C8 118.8(11) . . ?
C41 C22 C18 123.5(11) . . ?
N1 C23 C20 118.0(11) . . ?
N1 C23 C42 122.6(12) . . ?
C42 C23 C20 119.4(12) . . ?
C37 C24 C6 121.2(11) . . ?
C13 C25 C16 118.7(12) . . ?
N8 C26 C49 124.6(13) . . ?
C1 C27 C48 117.6(12) . . ?
C39 C27 C1 116.7(12) . . ?
C39 C27 C48 125.7(13) . . ?
N9 C28 C36 123.9(12) . . ?
N5 C29 C33 123.3(13) . . ?
C11 C30 C57 118.9(13) . . ?
C32 C30 C11 117.4(13) . . ?
C32 C30 C57 123.7(12) . . ?
C54 C31 C19 120.1(13) . . ?
C33 C32 C30 119.3(12) . . ?
C32 C33 C29 118.9(13) . . ?
C36 C34 C10 119.5(12) . . ?
C18 C35 C14 120.6(11) . . ?
C28 C36 C34 118.9(12) . . ?
C24 C37 C10 121.9(13) . . ?
C48 C38 C15 121.6(12) . . ?
C51 C39 C27 120.1(14) . . ?
C9 C40 C52 117.2(13) . . ?
C55 C40 C9 116.8(13) . . ?
C55 C40 C52 126.0(14) . . ?
C44 C41 C22 119.0(12) . . ?
C54 C42 C23 117.3(14) . . ?
C59 C42 C23 120.0(15) . . ?
C59 C42 C54 122.7(14) . . ?
N10 C43 C44 123.8(14) . . ?
C41 C44 C43 118.6(13) . . ?
C49 C45 C14 120.0(13) . . ?
N6 C46 C53 121.7(15) . . ?
C58 C47 C20 114.9(15) . . ?
C60 C47 C20 118.7(15) . . ?
C60 C47 C58 126.4(16) . . ?
C38 C48 C27 121.5(13) . . ?
C45 C49 C26 118.4(13) . . ?
N7 C50 C56 121.8(13) . . ?
C39 C51 C5 120.3(14) . . ?
C57 C52 C40 122.8(14) . . ?
C58 C53 C46 119.1(15) . . ?
C31 C54 C42 119.1(13) . . ?
C56 C55 C40 120.3(14) . . ?
C55 C56 C50 120.2(14) . . ?
C52 C57 C30 120.3(13) . . ?
C53 C58 C47 122.2(15) . . ?
C60 C59 C42 119.7(16) . . ?
C59 C60 C47 123.2(16) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
