# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_wlh23_a_sq
_database_code_depnum_ccdc_archive 'CCDC 2026120'
loop_
_audit_author_name
_audit_author_address
'Lin-Hui Wu'
;Jiangxi University of Science and Technology 
China
;
_audit_update_record             
;
2021-04-28 deposited with the CCDC.	2021-11-12 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2017/1
_shelx_SHELXL_version_number     2017/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C33 H21 N5 O5 Zn'
_chemical_formula_weight         632.92

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.5282(6)
_cell_length_b                   12.3363(6)
_cell_length_c                   13.9052(9)
_cell_angle_alpha                100.973(2)
_cell_angle_beta                 108.398(2)
_cell_angle_gamma                103.231(2)
_cell_volume                     1599.37(16)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3297
_cell_measurement_theta_min      2.91
_cell_measurement_theta_max      24.41

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.314
_exptl_crystal_F_000             648
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.20
_exptl_absorpt_coefficient_mu    0.814
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            16457
_diffrn_reflns_av_unetI/netI     0.1088
_diffrn_reflns_av_R_equivalents  0.0574
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         2.991
_diffrn_reflns_theta_max         27.511
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measured_fraction_theta_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_point_group_measured_fraction_full 0.993
_reflns_number_total             7251
_reflns_number_gt                4349
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0529P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         7251
_refine_ls_number_parameters     397
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1155
_refine_ls_R_factor_gt           0.0581
_refine_ls_wR_factor_ref         0.1314
_refine_ls_wR_factor_gt          0.1129
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_restrained_S_all      1.000
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.4741(4) 0.2772(3) -0.0128(3) 0.0360(9) Uani 1 1 d . . . . .
H1 H 0.424463 0.305282 -0.065347 0.043 Uiso 1 1 calc R U . . .
N1 N -0.1968(3) 0.2952(2) -0.0873(2) 0.0314(7) Uani 1 1 d . . . . .
O1 O 0.8507(3) 0.6220(3) 0.1794(2) 0.0675(10) Uani 1 1 d . . . . .
Zn1 Zn 0.75224(4) 0.42533(4) -0.00358(3) 0.03167(14) Uani 1 1 d . . . . .
O2 O 0.9286(3) 0.4817(2) 0.11904(19) 0.0477(7) Uani 1 1 d . . . . .
C2 C 0.6440(4) 0.2550(3) 0.1104(3) 0.0360(9) Uani 1 1 d . . . . .
N2 N -0.0789(3) 0.1726(2) -0.1164(2) 0.0339(7) Uani 1 1 d . . . . .
C4 C 0.7720(5) 0.1906(4) 0.2479(3) 0.0543(12) Uani 1 1 d . . . . .
H4 H 0.856169 0.194925 0.299466 0.065 Uiso 1 1 calc R U . . .
O4 O 1.5326(4) 0.4276(3) 0.8600(3) 0.0744(10) Uani 1 1 d . . . . .
N4 N 0.4126(3) 0.1891(3) 0.0185(2) 0.0368(7) Uani 1 1 d . . . . .
C3 C 0.7741(4) 0.2648(3) 0.1862(3) 0.0453(10) Uani 1 1 d . . . . .
H3 H 0.857193 0.318658 0.194176 0.054 Uiso 1 1 calc R U . . .
O3 O 1.4473(3) 0.7405(2) 0.5481(2) 0.0673(10) Uani 1 1 d . . . . .
N3 N 0.0875(4) -0.0583(3) -0.0913(3) 0.0487(9) Uani 1 1 d . . . . .
C6 C 0.5202(4) 0.0979(3) 0.1624(3) 0.0494(11) Uani 1 1 d . . . . .
H6 H 0.437794 0.043704 0.155306 0.059 Uiso 1 1 calc R U . . .
C5 C 0.6486(5) 0.1090(4) 0.2363(3) 0.0584(12) Uani 1 1 d . . . . .
H5 H 0.653107 0.060404 0.280063 0.070 Uiso 1 1 calc R U . . .
O5 O 1.7468(3) 0.5488(2) 0.9208(2) 0.0572(8) Uani 1 1 d . . . . .
N5 N 0.6113(3) 0.3192(2) 0.0385(2) 0.0350(7) Uani 1 1 d . . . . .
C7 C 0.5205(4) 0.1725(3) 0.0985(3) 0.0372(9) Uani 1 1 d . . . . .
C9 C 0.2208(4) 0.0057(3) -0.0491(3) 0.0471(10) Uani 1 1 d . . . . .
H9 H 0.288483 -0.032153 -0.034096 0.056 Uiso 1 1 calc R U . . .
C8 C 0.2669(4) 0.1259(3) -0.0255(3) 0.0353(9) Uani 1 1 d . . . . .
C10 C -0.0081(4) -0.0022(3) -0.1135(3) 0.0436(10) Uani 1 1 d . . . . .
H10 H -0.103163 -0.045016 -0.143159 0.052 Uiso 1 1 calc R U . . .
C11 C 0.0297(4) 0.1182(3) -0.0939(3) 0.0354(9) Uani 1 1 d . . . . .
C12 C 0.1679(4) 0.1838(3) -0.0499(3) 0.0334(8) Uani 1 1 d . . . . .
H12 H 0.194688 0.264083 -0.036777 0.040 Uiso 1 1 calc R U . . .
C13 C -0.2086(4) 0.1306(3) -0.2004(3) 0.0341(9) Uani 1 1 d . . . . .
C16 C -0.4721(4) 0.0994(4) -0.3406(3) 0.0532(11) Uani 1 1 d . . . . .
H16 H -0.561881 0.087078 -0.389179 0.064 Uiso 1 1 calc R U . . .
C15 C -0.3992(5) 0.0234(3) -0.3596(3) 0.0532(12) Uani 1 1 d . . . . .
H15 H -0.441795 -0.039434 -0.420169 0.064 Uiso 1 1 calc R U . . .
C14 C -0.2649(4) 0.0376(3) -0.2913(3) 0.0425(10) Uani 1 1 d . . . . .
H14 H -0.214766 -0.012313 -0.305406 0.051 Uiso 1 1 calc R U . . .
C17 C -0.4153(4) 0.1932(3) -0.2516(3) 0.0416(10) Uani 1 1 d . . . . .
H17 H -0.464829 0.244292 -0.239258 0.050 Uiso 1 1 calc R U . . .
C18 C -0.2812(4) 0.2083(3) -0.1810(3) 0.0313(8) Uani 1 1 d . . . . .
C19 C 0.9400(4) 0.5703(4) 0.1898(3) 0.0451(10) Uani 1 1 d . . . . .
C20 C 1.0717(4) 0.6122(3) 0.2871(3) 0.0372(9) Uani 1 1 d . . . . .
C21 C 1.0998(5) 0.7116(4) 0.3648(3) 0.0595(13) Uani 1 1 d . . . . .
H21 H 1.034350 0.751871 0.357719 0.071 Uiso 1 1 calc R U . . .
C22 C 1.2240(5) 0.7534(4) 0.4538(3) 0.0628(14) Uani 1 1 d . . . . .
H22 H 1.242463 0.821474 0.505319 0.075 Uiso 1 1 calc R U . . .
C23 C 1.3178(4) 0.6929(3) 0.4641(3) 0.0482(11) Uani 1 1 d . . . . .
C24 C 1.2931(5) 0.5937(4) 0.3876(3) 0.0587(13) Uani 1 1 d . . . . .
H24 H 1.358830 0.553661 0.394803 0.070 Uiso 1 1 calc R U . . .
C25 C 1.1680(4) 0.5538(3) 0.2990(3) 0.0498(11) Uani 1 1 d . . . . .
H25 H 1.150154 0.486177 0.247134 0.060 Uiso 1 1 calc R U . . .
C26 C 1.4824(5) 0.6824(3) 0.6235(3) 0.0464(11) Uani 1 1 d . . . . .
C27 C 1.3856(4) 0.6023(4) 0.6415(3) 0.0497(11) Uani 1 1 d . . . . .
H27 H 1.290075 0.583263 0.601499 0.060 Uiso 1 1 calc R U . . .
C28 C 1.4310(4) 0.5499(4) 0.7195(3) 0.0514(11) Uani 1 1 d . . . . .
H28 H 1.365473 0.494359 0.730840 0.062 Uiso 1 1 calc R U . . .
C29 C 1.5720(4) 0.5786(3) 0.7809(3) 0.0380(9) Uani 1 1 d . . . . .
C30 C 1.6676(4) 0.6630(3) 0.7642(3) 0.0453(10) Uani 1 1 d . . . . .
H30 H 1.762530 0.685216 0.806937 0.054 Uiso 1 1 calc R U . . .
C31 C 1.6246(4) 0.7149(3) 0.6854(3) 0.0481(11) Uani 1 1 d . . . . .
H31 H 1.689831 0.770705 0.673906 0.058 Uiso 1 1 calc R U . . .
C32 C 1.6178(5) 0.5143(4) 0.8598(3) 0.0478(11) Uani 1 1 d . . . . .
C33 C -0.0793(4) 0.2701(3) -0.0520(3) 0.0351(9) Uani 1 1 d . . . . .
H33 H -0.004245 0.314342 0.010375 0.042 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N5 1.315(4) . ?
C1 N4 1.352(4) . ?
C1 H1 0.9300 . ?
N1 C33 1.310(4) . ?
N1 C18 1.392(4) . ?
N1 Zn1 2.074(3) 1_455 ?
O1 C19 1.240(5) . ?
Zn1 O2 1.949(2) . ?
Zn1 O5 2.010(3) 1_454 ?
Zn1 N5 2.052(3) . ?
Zn1 C32 2.574(4) 1_454 ?
O2 C19 1.278(5) . ?
C2 C7 1.396(5) . ?
C2 N5 1.398(4) . ?
C2 C3 1.402(5) . ?
N2 C33 1.357(4) . ?
N2 C13 1.392(4) . ?
N2 C11 1.436(4) . ?
C4 C3 1.369(5) . ?
C4 C5 1.391(6) . ?
C4 H4 0.9300 . ?
O4 C32 1.230(5) . ?
N4 C7 1.402(4) . ?
N4 C8 1.419(4) . ?
C3 H3 0.9300 . ?
O3 C26 1.382(4) . ?
O3 C23 1.391(4) . ?
N3 C9 1.316(5) . ?
N3 C10 1.339(4) . ?
C6 C5 1.373(5) . ?
C6 C7 1.396(5) . ?
C6 H6 0.9300 . ?
C5 H5 0.9300 . ?
O5 C32 1.272(5) . ?
C9 C8 1.388(5) . ?
C9 H9 0.9300 . ?
C8 C12 1.386(5) . ?
C10 C11 1.394(5) . ?
C10 H10 0.9300 . ?
C11 C12 1.363(5) . ?
C12 H12 0.9300 . ?
C13 C14 1.388(5) . ?
C13 C18 1.394(5) . ?
C16 C17 1.379(5) . ?
C16 C15 1.379(6) . ?
C16 H16 0.9300 . ?
C15 C14 1.381(5) . ?
C15 H15 0.9300 . ?
C14 H14 0.9300 . ?
C17 C18 1.387(5) . ?
C17 H17 0.9300 . ?
C19 C20 1.498(5) . ?
C20 C25 1.359(5) . ?
C20 C21 1.373(5) . ?
C21 C22 1.391(5) . ?
C21 H21 0.9300 . ?
C22 C23 1.357(6) . ?
C22 H22 0.9300 . ?
C23 C24 1.370(5) . ?
C24 C25 1.394(5) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
C26 C27 1.369(5) . ?
C26 C31 1.387(5) . ?
C27 C28 1.379(5) . ?
C27 H27 0.9300 . ?
C28 C29 1.379(5) . ?
C28 H28 0.9300 . ?
C29 C30 1.382(5) . ?
C29 C32 1.495(5) . ?
C30 C31 1.380(5) . ?
C30 H30 0.9300 . ?
C31 H31 0.9300 . ?
C33 H33 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N5 C1 N4 113.2(3) . . ?
N5 C1 H1 123.4 . . ?
N4 C1 H1 123.4 . . ?
C33 N1 C18 105.8(3) . . ?
C33 N1 Zn1 124.4(2) . 1_455 ?
C18 N1 Zn1 129.2(2) . 1_455 ?
O2 Zn1 O5 107.63(11) . 1_454 ?
O2 Zn1 N5 105.55(11) . . ?
O5 Zn1 N5 135.42(12) 1_454 . ?
O2 Zn1 N1 96.24(11) . 1_655 ?
O5 Zn1 N1 107.99(11) 1_454 1_655 ?
N5 Zn1 N1 96.99(11) . 1_655 ?
O2 Zn1 C32 135.47(13) . 1_454 ?
O5 Zn1 C32 29.01(13) 1_454 1_454 ?
N5 Zn1 C32 109.04(14) . 1_454 ?
N1 Zn1 C32 106.33(12) 1_655 1_454 ?
C19 O2 Zn1 114.9(3) . . ?
C7 C2 N5 109.0(3) . . ?
C7 C2 C3 121.1(3) . . ?
N5 C2 C3 129.9(4) . . ?
C33 N2 C13 106.9(3) . . ?
C33 N2 C11 125.4(3) . . ?
C13 N2 C11 127.4(3) . . ?
C3 C4 C5 122.4(4) . . ?
C3 C4 H4 118.8 . . ?
C5 C4 H4 118.8 . . ?
C1 N4 C7 106.6(3) . . ?
C1 N4 C8 125.0(3) . . ?
C7 N4 C8 128.3(3) . . ?
C4 C3 C2 116.3(4) . . ?
C4 C3 H3 121.8 . . ?
C2 C3 H3 121.8 . . ?
C26 O3 C23 119.2(3) . . ?
C9 N3 C10 116.9(3) . . ?
C5 C6 C7 116.2(4) . . ?
C5 C6 H6 121.9 . . ?
C7 C6 H6 121.9 . . ?
C6 C5 C4 122.1(4) . . ?
C6 C5 H5 118.9 . . ?
C4 C5 H5 118.9 . . ?
C32 O5 Zn1 100.9(3) . 1_656 ?
C1 N5 C2 105.7(3) . . ?
C1 N5 Zn1 126.6(2) . . ?
C2 N5 Zn1 126.0(2) . . ?
C6 C7 C2 121.8(4) . . ?
C6 C7 N4 132.6(4) . . ?
C2 C7 N4 105.5(3) . . ?
N3 C9 C8 124.3(3) . . ?
N3 C9 H9 117.9 . . ?
C8 C9 H9 117.9 . . ?
C12 C8 C9 118.8(3) . . ?
C12 C8 N4 119.9(3) . . ?
C9 C8 N4 121.2(3) . . ?
N3 C10 C11 122.3(4) . . ?
N3 C10 H10 118.8 . . ?
C11 C10 H10 118.8 . . ?
C12 C11 C10 120.4(3) . . ?
C12 C11 N2 120.4(3) . . ?
C10 C11 N2 119.1(3) . . ?
C11 C12 C8 117.2(3) . . ?
C11 C12 H12 121.4 . . ?
C8 C12 H12 121.4 . . ?
C14 C13 N2 132.6(3) . . ?
C14 C13 C18 121.9(3) . . ?
N2 C13 C18 105.4(3) . . ?
C17 C16 C15 121.7(4) . . ?
C17 C16 H16 119.2 . . ?
C15 C16 H16 119.2 . . ?
C16 C15 C14 122.0(4) . . ?
C16 C15 H15 119.0 . . ?
C14 C15 H15 119.0 . . ?
C15 C14 C13 116.4(4) . . ?
C15 C14 H14 121.8 . . ?
C13 C14 H14 121.8 . . ?
C16 C17 C18 117.3(4) . . ?
C16 C17 H17 121.3 . . ?
C18 C17 H17 121.3 . . ?
C17 C18 N1 130.2(3) . . ?
C17 C18 C13 120.6(3) . . ?
N1 C18 C13 109.2(3) . . ?
O1 C19 O2 123.2(4) . . ?
O1 C19 C20 120.7(4) . . ?
O2 C19 C20 116.1(4) . . ?
C25 C20 C21 118.6(4) . . ?
C25 C20 C19 120.4(4) . . ?
C21 C20 C19 121.0(4) . . ?
C20 C21 C22 121.5(4) . . ?
C20 C21 H21 119.2 . . ?
C22 C21 H21 119.2 . . ?
C23 C22 C21 118.7(4) . . ?
C23 C22 H22 120.6 . . ?
C21 C22 H22 120.6 . . ?
C22 C23 C24 121.1(4) . . ?
C22 C23 O3 118.4(4) . . ?
C24 C23 O3 120.1(4) . . ?
C23 C24 C25 119.0(4) . . ?
C23 C24 H24 120.5 . . ?
C25 C24 H24 120.5 . . ?
C20 C25 C24 121.0(4) . . ?
C20 C25 H25 119.5 . . ?
C24 C25 H25 119.5 . . ?
C27 C26 O3 123.7(4) . . ?
C27 C26 C31 120.9(3) . . ?
O3 C26 C31 115.4(4) . . ?
C26 C27 C28 119.4(4) . . ?
C26 C27 H27 120.3 . . ?
C28 C27 H27 120.3 . . ?
C29 C28 C27 121.1(4) . . ?
C29 C28 H28 119.4 . . ?
C27 C28 H28 119.4 . . ?
C28 C29 C30 118.6(3) . . ?
C28 C29 C32 119.4(4) . . ?
C30 C29 C32 121.9(4) . . ?
C31 C30 C29 121.1(4) . . ?
C31 C30 H30 119.4 . . ?
C29 C30 H30 119.4 . . ?
C30 C31 C26 118.8(4) . . ?
C30 C31 H31 120.6 . . ?
C26 C31 H31 120.6 . . ?
O4 C32 O5 122.5(4) . . ?
O4 C32 C29 119.6(4) . . ?
O5 C32 C29 117.8(4) . . ?
O4 C32 Zn1 72.4(2) . 1_656 ?
O5 C32 Zn1 50.06(19) . 1_656 ?
C29 C32 Zn1 167.1(3) . 1_656 ?
N1 C33 N2 112.7(3) . . ?
N1 C33 H33 123.6 . . ?
N2 C33 H33 123.6 . . ?

_refine_diff_density_max         0.449
_refine_diff_density_min         -0.459
_refine_diff_density_rms         0.068



