# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2053030'
loop_
_audit_author_name
_audit_author_address
'Wei-Bin Yu'
;Anhui University of Technology
China
;
_audit_update_record             
;
2020-12-29 deposited with the CCDC.	2021-03-10 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C132 H119 Cl6 N6 O12 Rh6'
_chemical_formula_weight         2811.48

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           5
_space_group_name_H-M_alt        'C 2'
_space_group_name_Hall           'C 2y'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'

_cell_length_a                   41.690(5)
_cell_length_b                   27.665(4)
_cell_length_c                   16.596(2)
_cell_angle_alpha                90
_cell_angle_beta                 90.706(6)
_cell_angle_gamma                90
_cell_volume                     19140(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9573
_cell_measurement_theta_min      3.29
_cell_measurement_theta_max      77.42

_exptl_crystal_description       block
_exptl_crystal_colour            green
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    0.976
_exptl_crystal_F_000             5684
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.130
_exptl_absorpt_coefficient_mu    5.180
_shelx_estimated_absorpt_T_min   0.424
_shelx_estimated_absorpt_T_max   0.552
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.424
_exptl_absorpt_correction_T_max  0.552
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            172995
_diffrn_reflns_av_unetI/netI     0.1017
_diffrn_reflns_av_R_equivalents  0.1386
_diffrn_reflns_limit_h_min       -51
_diffrn_reflns_limit_h_max       52
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         2.120
_diffrn_reflns_theta_max         77.252
_diffrn_reflns_theta_full        67.679
_diffrn_measured_fraction_theta_max 0.947
_diffrn_measured_fraction_theta_full 0.983
_diffrn_reflns_Laue_measured_fraction_max 0.947
_diffrn_reflns_Laue_measured_fraction_full 0.983
_diffrn_reflns_point_group_measured_fraction_max 0.948
_diffrn_reflns_point_group_measured_fraction_full 0.984
_reflns_number_total             37376
_reflns_number_gt                27713
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.960
_reflns_Friedel_fraction_max     0.949
_reflns_Friedel_fraction_full    0.985

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0100P)²+130.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.790(11)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         37376
_refine_ls_number_parameters     1487
_refine_ls_number_restraints     3737
_refine_ls_R_factor_all          0.1069
_refine_ls_R_factor_gt           0.0807
_refine_ls_wR_factor_ref         0.1976
_refine_ls_wR_factor_gt          0.1803
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_restrained_S_all      21.339
_refine_ls_shift/su_max          0.015
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1 Cl -0.19028(12) 0.11239(16) 0.1838(2) 0.0934(12) Uani 1 1 d . U . . .
O1 O 0.1808(2) 0.3359(3) 0.0326(5) 0.0586(18) Uani 1 1 d . U . . .
N1 N 0.1072(4) -0.2701(5) -0.1058(12) 0.112(4) Uani 1 1 d . U . . .
C1 C 0.1328(5) -0.2384(6) -0.1317(14) 0.109(3) Uani 1 1 d . U . . .
H1 H 0.152190 -0.251794 -0.150916 0.130 Uiso 1 1 calc R U . . .
Cl2 Cl -0.18621(12) -0.09873(13) 0.0338(3) 0.1001(14) Uani 1 1 d . U . . .
O2 O 0.1288(2) 0.3700(3) -0.0312(5) 0.0618(19) Uani 1 1 d . U . . .
N2 N 0.1594(4) -0.2338(5) 0.3294(11) 0.127(4) Uani 1 1 d D U . . .
C2 C 0.1293(5) -0.1913(6) -0.1289(14) 0.105(3) Uani 1 1 d . U . . .
H2 H 0.146102 -0.170408 -0.144851 0.126 Uiso 1 1 calc R U . . .
Cl3 Cl 0.06755(11) 0.3972(2) 0.0483(3) 0.120(2) Uani 1 1 d . U . . .
O3 O 0.1392(2) 0.3625(3) 0.2886(5) 0.063(2) Uani 1 1 d . U . . .
N3 N 0.1472(3) 0.2738(4) -0.0830(6) 0.059(2) Uani 1 1 d . U . . .
C3 C 0.1003(5) -0.1726(6) -0.1018(14) 0.102(3) Uani 1 1 d . U . . .
Cl4 Cl 0.19618(9) 0.32054(17) 0.2091(2) 0.0843(11) Uani 1 1 d . U . . .
O4 O 0.0835(2) 0.3854(3) 0.2238(5) 0.063(2) Uani 1 1 d . U . . .
N4 N 0.0885(3) 0.3023(4) 0.3366(7) 0.072(3) Uani 1 1 d . U . . .
C4 C 0.0742(5) -0.2036(6) -0.0834(14) 0.105(3) Uani 1 1 d . U . . .
H4 H 0.053968 -0.190619 -0.068568 0.126 Uiso 1 1 calc R U . . .
Cl5 Cl 0.21329(11) -0.29007(15) 0.0385(3) 0.0944(12) Uani 1 1 d . U . . .
O5 O -0.1848(2) 0.0832(3) 0.0103(5) 0.064(2) Uani 1 1 d . U . . .
N5 N -0.1366(3) 0.0498(4) -0.1048(7) 0.073(3) Uani 1 1 d . U . . .
C5 C 0.0788(5) -0.2525(6) -0.0877(14) 0.112(3) Uani 1 1 d . U . . .
H5 H 0.061512 -0.273855 -0.077581 0.134 Uiso 1 1 calc R U . . .
Cl6 Cl 0.0806(2) -0.3652(3) 0.1718(8) 0.217(5) Uani 1 1 d . U . . .
O6 O -0.1906(2) -0.0047(3) -0.0525(6) 0.070(2) Uani 1 1 d . U . . .
C6 C 0.0932(4) -0.1209(6) -0.1036(13) 0.100(3) Uani 1 1 d . U . . .
Rh7 Rh 0.16928(2) 0.34244(3) -0.09124(5) 0.0584(2) Uani 1 1 d . U . . .
O7 O -0.1945(3) 0.0183(5) 0.2677(7) 0.096(3) Uani 1 1 d . U . . .
N7 N -0.1423(4) -0.0370(5) 0.3205(9) 0.109(4) Uani 1 1 d D U . . .
C7 C 0.0872(4) -0.0810(6) -0.1010(14) 0.098(3) Uani 1 1 d . U . . .
Rh8 Rh 0.09542(3) 0.37882(4) 0.34803(6) 0.0665(3) Uani 1 1 d . U . . .
O8 O -0.1904(3) -0.0709(4) 0.2052(8) 0.104(3) Uani 1 1 d . U . . .
C8 C 0.0734(3) -0.0317(5) -0.1021(13) 0.093(2) Uani 1 1 d D U . . .
Rh9 Rh -0.18616(3) 0.06222(3) -0.11363(6) 0.0622(2) Uani 1 1 d . U . . .
O9 O 0.1560(3) -0.3327(4) -0.0544(9) 0.108(3) Uani 1 1 d . U . . .
C9 C 0.0401(3) -0.0279(5) -0.1020(12) 0.095(2) Uani 1 1 d D U . . .
H9 H 0.027234 -0.056090 -0.097075 0.113 Uiso 1 1 calc R U . . .
Rh10 Rh -0.19082(4) -0.04765(7) 0.33166(9) 0.1203(7) Uani 1 1 d . U . . .
O10 O 0.1004(4) -0.3527(4) 0.0021(11) 0.131(3) Uani 1 1 d . U . . .
C10 C 0.0257(4) 0.0174(4) -0.1090(13) 0.093(2) Uani 1 1 d D U . . .
Rh11 Rh 0.17708(6) -0.30425(5) 0.32874(10) 0.1310(8) Uani 1 1 d . U . . .
O11 O 0.1920(3) -0.2962(4) 0.2118(9) 0.107(3) Uani 1 1 d . U . . .
C11 C 0.0448(3) 0.0585(5) -0.1048(12) 0.093(2) Uani 1 1 d D U . . .
H11 H 0.035466 0.089623 -0.098549 0.112 Uiso 1 1 calc R U . . .
Rh12 Rh 0.11443(5) -0.34528(5) -0.12161(14) 0.1332(7) Uani 1 1 d . U . . .
O12 O 0.1356(4) -0.3283(5) 0.2597(10) 0.137(4) Uani 1 1 d . U . . .
C12 C 0.0779(3) 0.0530(5) -0.1099(12) 0.091(2) Uani 1 1 d D U . . .
C13 C 0.0933(4) 0.0087(4) -0.1030(12) 0.091(2) Uani 1 1 d D U . . .
H13 H 0.115999 0.006045 -0.099180 0.110 Uiso 1 1 calc R U . . .
C14 C 0.0947(4) 0.0977(5) -0.1060(12) 0.086(2) Uani 1 1 d . U . . .
C15 C 0.1105(4) 0.1361(5) -0.1027(11) 0.082(2) Uani 1 1 d . U . . .
C16 C 0.1222(4) 0.1824(5) -0.0942(10) 0.077(2) Uani 1 1 d . U . . .
C17 C 0.1522(4) 0.1905(5) -0.0599(10) 0.075(2) Uani 1 1 d . U . . .
H17 H 0.164548 0.163876 -0.041061 0.091 Uiso 1 1 calc R U . . .
C18 C 0.1644(4) 0.2363(5) -0.0529(9) 0.071(2) Uani 1 1 d . U . . .
H18 H 0.184534 0.241648 -0.027165 0.085 Uiso 1 1 calc R U . . .
C19 C 0.1178(4) 0.2677(5) -0.1150(10) 0.075(2) Uani 1 1 d . U . . .
H19 H 0.106349 0.294840 -0.135199 0.090 Uiso 1 1 calc R U . . .
C20 C 0.1043(4) 0.2232(5) -0.1189(10) 0.079(3) Uani 1 1 d . U . . .
H20 H 0.082924 0.219504 -0.138259 0.094 Uiso 1 1 calc R U . . .
C21 C -0.0088(4) 0.0241(6) -0.1043(13) 0.094(2) Uani 1 1 d . U . . .
C22 C -0.0374(4) 0.0261(6) -0.1065(13) 0.096(2) Uani 1 1 d . U . . .
C23 C -0.0714(4) 0.0327(6) -0.1071(13) 0.093(3) Uani 1 1 d . U . . .
C24 C -0.0915(4) -0.0057(6) -0.1143(12) 0.092(3) Uani 1 1 d . U . . .
H24 H -0.083454 -0.037682 -0.119828 0.110 Uiso 1 1 calc R U . . .
C25 C -0.1241(4) 0.0035(6) -0.1133(11) 0.087(3) Uani 1 1 d . U . . .
H25 H -0.138588 -0.022876 -0.118557 0.104 Uiso 1 1 calc R U . . .
C26 C -0.0839(4) 0.0799(6) -0.0993(12) 0.091(3) Uani 1 1 d . U . . .
H26 H -0.069951 0.107038 -0.096810 0.109 Uiso 1 1 calc R U . . .
C27 C -0.1160(4) 0.0855(6) -0.0952(11) 0.084(3) Uani 1 1 d . U . . .
H27 H -0.124224 0.116886 -0.084987 0.101 Uiso 1 1 calc R U . . .
C28 C 0.1782(5) -0.1947(5) 0.3117(14) 0.129(3) Uani 1 1 d D U . . .
H28 H 0.200130 -0.198138 0.298023 0.155 Uiso 1 1 calc R U . . .
C29 C 0.1635(5) -0.1504(6) 0.3149(14) 0.125(3) Uani 1 1 d D U . . .
H29 H 0.176637 -0.122403 0.311936 0.150 Uiso 1 1 calc R U . . .
C30 C 0.1264(5) -0.2279(7) 0.3332(15) 0.131(3) Uani 1 1 d D U . . .
H30 H 0.113389 -0.256002 0.333503 0.157 Uiso 1 1 calc R U . . .
C31 C 0.1115(5) -0.1837(6) 0.3365(15) 0.128(3) Uani 1 1 d D U . . .
H31 H 0.089380 -0.180572 0.348033 0.154 Uiso 1 1 calc R U . . .
C32 C 0.1307(5) -0.1440(6) 0.3220(15) 0.125(3) Uani 1 1 d D U . . .
C33 C 0.1148(6) -0.0972(8) 0.3208(16) 0.124(3) Uani 1 1 d . U . . .
C34 C 0.0986(6) -0.0617(8) 0.3243(16) 0.125(3) Uani 1 1 d . U . . .
C35 C 0.0744(4) -0.0231(6) 0.3140(13) 0.122(3) Uani 1 1 d D U . . .
C36 C 0.0847(5) 0.0245(5) 0.3208(11) 0.120(3) Uani 1 1 d D U . . .
H36 H 0.106706 0.033001 0.326274 0.144 Uiso 1 1 calc R U . . .
C37 C 0.0605(4) 0.0586(7) 0.3188(13) 0.122(3) Uani 1 1 d D U . . .
C38 C 0.0277(4) 0.0491(6) 0.3135(14) 0.121(3) Uani 1 1 d D U . . .
H38 H 0.012330 0.074429 0.313423 0.145 Uiso 1 1 calc R U . . .
C39 C 0.0187(5) 0.0011(6) 0.3083(15) 0.124(3) Uani 1 1 d D U . . .
C40 C 0.0423(4) -0.0340(7) 0.3075(14) 0.124(3) Uani 1 1 d D U . . .
H40 H 0.036167 -0.066953 0.302230 0.149 Uiso 1 1 calc R U . . .
C41 C 0.0692(5) 0.1125(7) 0.3177(15) 0.114(3) Uani 1 1 d . U . . .
C42 C 0.0740(5) 0.1534(7) 0.3286(13) 0.106(3) Uani 1 1 d . U . . .
C43 C 0.0785(5) 0.2056(7) 0.3341(13) 0.099(3) Uani 1 1 d . U . . .
C44 C 0.1083(4) 0.2241(6) 0.3578(12) 0.095(3) Uani 1 1 d . U . . .
H44 H 0.125634 0.203671 0.373366 0.114 Uiso 1 1 calc R U . . .
C45 C 0.1110(4) 0.2708(6) 0.3573(11) 0.088(3) Uani 1 1 d . U . . .
H45 H 0.131228 0.283756 0.373422 0.106 Uiso 1 1 calc R U . . .
C46 C 0.0538(5) 0.2377(6) 0.3063(12) 0.096(3) Uani 1 1 d . U . . .
H46 H 0.033852 0.226363 0.285445 0.115 Uiso 1 1 calc R U . . .
C47 C 0.0606(4) 0.2842(6) 0.3116(11) 0.090(3) Uani 1 1 d . U . . .
H47 H 0.044308 0.306494 0.296236 0.108 Uiso 1 1 calc R U . . .
C48 C -0.0133(6) -0.0107(8) 0.3122(16) 0.124(3) Uani 1 1 d . U . . .
C49 C -0.0397(6) -0.0209(8) 0.3067(16) 0.128(3) Uani 1 1 d . U . . .
C50 C -0.0774(5) -0.0233(6) 0.3146(15) 0.127(3) Uani 1 1 d D U . . .
C51 C -0.0963(4) 0.0142(8) 0.3418(15) 0.128(3) Uani 1 1 d D U . . .
H51 H -0.086946 0.043195 0.361556 0.153 Uiso 1 1 calc R U . . .
C52 C -0.1293(5) 0.0084(6) 0.3396(13) 0.119(3) Uani 1 1 d D U . . .
H52 H -0.143050 0.034971 0.350848 0.143 Uiso 1 1 calc R U . . .
C53 C -0.0892(4) -0.0691(7) 0.2970(14) 0.124(3) Uani 1 1 d D U . . .
H53 H -0.075543 -0.094747 0.280544 0.149 Uiso 1 1 calc R U . . .
C54 C -0.1220(4) -0.0752(7) 0.3049(15) 0.126(3) Uani 1 1 d D U . . .
H54 H -0.130831 -0.106713 0.299505 0.151 Uiso 1 1 calc R U . . .
C55 C -0.1906(3) -0.0337(5) 0.1570(7) 0.074(2) Uani 1 1 d D U . . .
C56 C -0.1917(4) 0.0142(4) 0.1913(8) 0.075(2) Uani 1 1 d D U . . .
C57 C -0.1889(3) 0.0551(5) 0.1430(7) 0.071(2) Uani 1 1 d D U . . .
C58 C -0.1876(3) 0.0484(4) 0.0593(7) 0.066(2) Uani 1 1 d D U . . .
C59 C -0.1896(3) -0.0002(4) 0.0268(8) 0.067(2) Uani 1 1 d D U . . .
C60 C -0.1887(3) -0.0423(5) 0.0745(7) 0.074(2) Uani 1 1 d D U . . .
C61 C 0.1228(4) -0.3433(5) 0.0578(12) 0.109(3) Uani 1 1 d D U . . .
C62 C 0.1522(4) -0.3280(5) 0.0244(12) 0.102(3) Uani 1 1 d D U . . .
C63 C 0.1776(4) -0.3104(5) 0.0702(10) 0.102(3) Uani 1 1 d D U . . .
C64 C 0.1694(4) -0.3107(6) 0.1510(11) 0.104(3) Uani 1 1 d D U . . .
C65 C 0.1403(4) -0.3282(6) 0.1811(13) 0.107(3) Uani 1 1 d D U . . .
C66 C 0.1136(4) -0.3448(6) 0.1379(11) 0.110(3) Uani 1 1 d D U . . .
C67 C 0.1064(3) 0.3758(4) 0.1761(6) 0.058(2) Uani 1 1 d D U . . .
C68 C 0.1367(3) 0.3615(4) 0.2118(7) 0.063(2) Uani 1 1 d D U . . .
C69 C 0.1625(3) 0.3458(5) 0.1646(6) 0.058(2) Uani 1 1 d D U . . .
C70 C 0.1586(3) 0.3489(4) 0.0813(6) 0.056(2) Uani 1 1 d D U . . .
C71 C 0.1293(2) 0.3663(4) 0.0446(6) 0.056(2) Uani 1 1 d D U . . .
C72 C 0.1027(3) 0.3785(5) 0.0927(6) 0.064(2) Uani 1 1 d D U . . .
C83 C 0.2107(4) 0.3316(5) -0.1635(9) 0.076(2) Uani 1 1 d . U . . .
C84 C 0.2131(4) 0.3756(5) -0.1272(9) 0.076(2) Uani 1 1 d . U . . .
C85 C 0.1856(4) 0.4058(5) -0.1485(9) 0.074(2) Uani 1 1 d . U . . .
C86 C 0.1658(4) 0.3786(5) -0.2037(9) 0.077(2) Uani 1 1 d . U . . .
C87 C 0.1803(4) 0.3354(5) -0.2159(9) 0.078(2) Uani 1 1 d . U . . .
C88 C 0.2322(4) 0.2927(6) -0.1634(11) 0.089(3) Uani 1 1 d . U . . .
H88A H 0.252018 0.295027 -0.134587 0.107 Uiso 1 1 calc R U . . .
H88B H 0.227058 0.263929 -0.192035 0.107 Uiso 1 1 calc R U . . .
C89 C 0.2395(4) 0.3890(6) -0.0692(11) 0.090(3) Uani 1 1 d . U . . .
H89A H 0.256931 0.404645 -0.098474 0.135 Uiso 1 1 calc R U . . .
H89B H 0.247672 0.359749 -0.042578 0.135 Uiso 1 1 calc R U . . .
H89C H 0.231210 0.411274 -0.028543 0.135 Uiso 1 1 calc R U . . .
C90 C 0.1801(4) 0.4556(5) -0.1141(11) 0.085(3) Uani 1 1 d . U . . .
H90A H 0.187148 0.480038 -0.152903 0.128 Uiso 1 1 calc R U . . .
H90B H 0.192488 0.459186 -0.063797 0.128 Uiso 1 1 calc R U . . .
H90C H 0.157273 0.460052 -0.103257 0.128 Uiso 1 1 calc R U . . .
C91 C 0.1346(4) 0.3997(6) -0.2428(11) 0.091(4) Uani 1 1 d . U . . .
H91A H 0.139293 0.411566 -0.296991 0.137 Uiso 1 1 calc R U . . .
H91B H 0.126723 0.426395 -0.209685 0.137 Uiso 1 1 calc R U . . .
H91C H 0.118242 0.374329 -0.246169 0.137 Uiso 1 1 calc R U . . .
C92 C 0.1682(5) 0.2961(6) -0.2728(9) 0.088(3) Uani 1 1 d . U . . .
H92A H 0.169300 0.307616 -0.328502 0.132 Uiso 1 1 calc R U . . .
H92B H 0.145953 0.288036 -0.259986 0.132 Uiso 1 1 calc R U . . .
H92C H 0.181632 0.267181 -0.266510 0.132 Uiso 1 1 calc R U . . .
C93 C 0.0706(4) 0.3862(7) 0.4632(9) 0.088(3) Uani 1 1 d . U . . .
C94 C 0.0602(4) 0.4235(7) 0.4044(9) 0.088(3) Uani 1 1 d . U . . .
C95 C 0.0889(5) 0.4508(7) 0.3838(10) 0.089(3) Uani 1 1 d . U . . .
C96 C 0.1137(5) 0.4330(7) 0.4251(10) 0.090(3) Uani 1 1 d . U . . .
C97 C 0.1020(4) 0.3926(7) 0.4698(9) 0.088(3) Uani 1 1 d . U . . .
C98 C 0.0507(5) 0.3481(7) 0.4949(11) 0.103(4) Uani 1 1 d . U . . .
H98A H 0.042620 0.357597 0.547754 0.155 Uiso 1 1 calc R U . . .
H98B H 0.063381 0.318397 0.500343 0.155 Uiso 1 1 calc R U . . .
H98C H 0.032553 0.342285 0.457957 0.155 Uiso 1 1 calc R U . . .
C99 C 0.0253(4) 0.4324(8) 0.3627(12) 0.105(4) Uani 1 1 d . U . . .
H99A H 0.027900 0.449832 0.311757 0.157 Uiso 1 1 calc R U . . .
H99B H 0.011915 0.451539 0.398888 0.157 Uiso 1 1 calc R U . . .
H99C H 0.014932 0.401186 0.352123 0.157 Uiso 1 1 calc R U . . .
C100 C 0.0861(5) 0.4933(7) 0.3296(12) 0.105(4) Uani 1 1 d . U . . .
H10A H 0.087471 0.523004 0.361487 0.158 Uiso 1 1 calc R U . . .
H10B H 0.065379 0.492175 0.300984 0.158 Uiso 1 1 calc R U . . .
H10L H 0.103483 0.492631 0.290447 0.158 Uiso 1 1 calc R U . . .
C101 C 0.1460(5) 0.4491(7) 0.4278(12) 0.107(4) Uani 1 1 d . U . . .
H10C H 0.160063 0.421969 0.442323 0.160 Uiso 1 1 calc R U . . .
H10D H 0.148273 0.474725 0.468176 0.160 Uiso 1 1 calc R U . . .
H10E H 0.151944 0.461587 0.374834 0.160 Uiso 1 1 calc R U . . .
C102 C 0.1223(5) 0.3632(8) 0.5348(11) 0.109(4) Uani 1 1 d . U . . .
H10M H 0.144299 0.375726 0.536868 0.164 Uiso 1 1 calc R U . . .
H10N H 0.122698 0.328935 0.519743 0.164 Uiso 1 1 calc R U . . .
H10O H 0.112493 0.366741 0.587764 0.164 Uiso 1 1 calc R U . . .
C103 C -0.2272(4) 0.0535(6) -0.1891(8) 0.077(2) Uani 1 1 d . U . . .
C104 C -0.1981(4) 0.0550(6) -0.2357(8) 0.076(2) Uani 1 1 d . U . . .
C105 C -0.1844(4) 0.1012(6) -0.2231(9) 0.076(2) Uani 1 1 d . U . . .
C106 C -0.2022(4) 0.1265(5) -0.1696(9) 0.074(2) Uani 1 1 d . U . . .
C107 C -0.2292(4) 0.0958(6) -0.1474(9) 0.076(2) Uani 1 1 d . U . . .
C108 C -0.2488(4) 0.0115(6) -0.1917(10) 0.089(4) Uani 1 1 d . U . . .
H10I H -0.271019 0.022623 -0.197487 0.134 Uiso 1 1 calc R U . . .
H10J H -0.246394 -0.007059 -0.141731 0.134 Uiso 1 1 calc R U . . .
H10K H -0.243342 -0.008997 -0.237706 0.134 Uiso 1 1 calc R U . . .
C109 C -0.1867(5) 0.0199(7) -0.2912(10) 0.096(4) Uani 1 1 d . U . . .
H10F H -0.189576 0.031929 -0.346315 0.144 Uiso 1 1 calc R U . . .
H10G H -0.198729 -0.010224 -0.284692 0.144 Uiso 1 1 calc R U . . .
H10H H -0.163842 0.013849 -0.280620 0.144 Uiso 1 1 calc R U . . .
C110 C -0.1554(4) 0.1171(6) -0.2667(10) 0.088(3) Uani 1 1 d . U . . .
H11M H -0.158245 0.110847 -0.324468 0.131 Uiso 1 1 calc R U . . .
H11N H -0.136659 0.099209 -0.246455 0.131 Uiso 1 1 calc R U . . .
H11O H -0.152018 0.151806 -0.258003 0.131 Uiso 1 1 calc R U . . .
C111 C -0.1961(4) 0.1788(6) -0.1362(11) 0.088(4) Uani 1 1 d . U . . .
H11J H -0.180137 0.195089 -0.169285 0.131 Uiso 1 1 calc R U . . .
H11K H -0.188272 0.176787 -0.080373 0.131 Uiso 1 1 calc R U . . .
H11L H -0.216258 0.197081 -0.137918 0.131 Uiso 1 1 calc R U . . .
C112 C -0.2556(4) 0.1123(6) -0.0867(10) 0.084(3) Uani 1 1 d . U . . .
H11G H -0.268186 0.138726 -0.110506 0.126 Uiso 1 1 calc R U . . .
H11H H -0.245389 0.123409 -0.036537 0.126 Uiso 1 1 calc R U . . .
H11I H -0.269838 0.084997 -0.075067 0.126 Uiso 1 1 calc R U . . .
C113 C 0.1319(6) -0.3991(6) -0.2075(13) 0.152(4) Uani 1 1 d D U . . .
C114 C 0.1228(5) -0.3555(7) -0.2585(13) 0.153(4) Uani 1 1 d D U . . .
C115 C 0.0904(5) -0.3497(7) -0.2441(13) 0.150(3) Uani 1 1 d D U . . .
C116 C 0.0789(6) -0.3868(7) -0.1840(15) 0.155(4) Uani 1 1 d D U . . .
C117 C 0.1042(5) -0.4175(7) -0.1643(16) 0.153(4) Uani 1 1 d D U . . .
C118 C 0.1669(5) -0.4167(8) -0.2033(17) 0.158(5) Uani 1 1 d D U . . .
H11D H 0.170586 -0.439938 -0.246776 0.236 Uiso 1 1 calc R U . . .
H11E H 0.170892 -0.432379 -0.151167 0.236 Uiso 1 1 calc R U . . .
H11F H 0.181352 -0.389107 -0.209195 0.236 Uiso 1 1 calc R U . . .
C119 C 0.1484(6) -0.3253(8) -0.2960(17) 0.172(6) Uani 1 1 d D U . . .
H11A H 0.168776 -0.342965 -0.294531 0.258 Uiso 1 1 calc R U . . .
H11B H 0.142454 -0.318133 -0.352037 0.258 Uiso 1 1 calc R U . . .
H11C H 0.150753 -0.294983 -0.265904 0.258 Uiso 1 1 calc R U . . .
C120 C 0.0670(6) -0.3123(7) -0.2819(16) 0.157(5) Uani 1 1 d D U . . .
H12G H 0.075827 -0.300141 -0.332388 0.236 Uiso 1 1 calc R U . . .
H12H H 0.064025 -0.285402 -0.244345 0.236 Uiso 1 1 calc R U . . .
H12I H 0.046229 -0.327838 -0.292815 0.236 Uiso 1 1 calc R U . . .
C121 C 0.0426(5) -0.3888(9) -0.1653(18) 0.171(6) Uani 1 1 d D U . . .
H12D H 0.032093 -0.359585 -0.186043 0.257 Uiso 1 1 calc R U . . .
H12E H 0.039650 -0.390849 -0.106928 0.257 Uiso 1 1 calc R U . . .
H12F H 0.033050 -0.417329 -0.191246 0.257 Uiso 1 1 calc R U . . .
C122 C 0.1073(7) -0.4589(7) -0.1008(14) 0.162(5) Uani 1 1 d D U . . .
H12A H 0.089664 -0.481952 -0.108466 0.243 Uiso 1 1 calc R U . . .
H12B H 0.106434 -0.445250 -0.046456 0.243 Uiso 1 1 calc R U . . .
H12C H 0.127825 -0.475657 -0.107780 0.243 Uiso 1 1 calc R U . . .
C123 C 0.2186(6) -0.3053(7) 0.4026(14) 0.147(3) Uani 1 1 d D U . . .
C124 C 0.2164(5) -0.3508(6) 0.3650(14) 0.143(3) Uani 1 1 d D U . . .
C125 C 0.1891(5) -0.3716(7) 0.3972(15) 0.147(3) Uani 1 1 d D U . . .
C126 C 0.1731(6) -0.3384(6) 0.4469(15) 0.149(3) Uani 1 1 d D U . . .
C127 C 0.1928(5) -0.2983(7) 0.4532(15) 0.148(3) Uani 1 1 d D U . . .
C128 C 0.2508(6) -0.2733(8) 0.3998(16) 0.158(5) Uani 1 1 d D U . . .
H12J H 0.268941 -0.292495 0.420198 0.237 Uiso 1 1 calc R U . . .
H12K H 0.248245 -0.244481 0.433341 0.237 Uiso 1 1 calc R U . . .
H12L H 0.254906 -0.263565 0.344067 0.237 Uiso 1 1 calc R U . . .
C129 C 0.2410(6) -0.3726(7) 0.3050(14) 0.145(5) Uani 1 1 d D U . . .
H12M H 0.234136 -0.365451 0.249591 0.218 Uiso 1 1 calc R U . . .
H12N H 0.242187 -0.407686 0.312553 0.218 Uiso 1 1 calc R U . . .
H12O H 0.262199 -0.358335 0.315181 0.218 Uiso 1 1 calc R U . . .
C130 C 0.1733(6) -0.4220(6) 0.3707(15) 0.149(5) Uani 1 1 d D U . . .
H13A H 0.169075 -0.421760 0.312527 0.223 Uiso 1 1 calc R U . . .
H13B H 0.153172 -0.426698 0.399413 0.223 Uiso 1 1 calc R U . . .
H13C H 0.188134 -0.448448 0.384021 0.223 Uiso 1 1 calc R U . . .
C131 C 0.1371(5) -0.3446(9) 0.4754(17) 0.166(5) Uani 1 1 d D U . . .
H13D H 0.129586 -0.377303 0.462544 0.250 Uiso 1 1 calc R U . . .
H13E H 0.135982 -0.339348 0.533716 0.250 Uiso 1 1 calc DR U . . .
H13F H 0.123410 -0.320904 0.447560 0.250 Uiso 1 1 calc R U . . .
C132 C 0.1876(7) -0.2538(7) 0.5106(14) 0.154(5) Uani 1 1 d D U . . .
H13G H 0.165728 -0.241549 0.503646 0.231 Uiso 1 1 calc R U . . .
H13H H 0.202971 -0.228256 0.497292 0.231 Uiso 1 1 calc R U . . .
H13I H 0.191014 -0.263872 0.566718 0.231 Uiso 1 1 calc R U . . .
C133 C -0.2220(5) -0.0378(8) 0.4189(12) 0.144(3) Uani 1 1 d D U . . .
C134 C -0.1935(5) -0.0567(7) 0.4527(13) 0.136(3) Uani 1 1 d D U . . .
C135 C -0.1898(5) -0.1051(7) 0.4284(12) 0.141(3) Uani 1 1 d D U . . .
C136 C -0.2129(4) -0.1160(8) 0.3715(13) 0.146(4) Uani 1 1 d D U . . .
C137 C -0.2345(5) -0.0770(6) 0.3757(13) 0.142(4) Uani 1 1 d D U . . .
C138 C -0.2402(6) 0.0096(7) 0.4425(15) 0.160(5) Uani 1 1 d D U . . .
H13M H -0.250429 0.023464 0.394381 0.241 Uiso 1 1 calc R U . . .
H13N H -0.224885 0.032874 0.465425 0.241 Uiso 1 1 calc R U . . .
H13O H -0.256544 0.001980 0.482396 0.241 Uiso 1 1 calc R U . . .
C139 C -0.1678(6) -0.0327(8) 0.5119(13) 0.146(5) Uani 1 1 d D U . . .
H13J H -0.165271 0.001542 0.498239 0.218 Uiso 1 1 calc R U . . .
H13K H -0.147172 -0.049266 0.506437 0.218 Uiso 1 1 calc R U . . .
H13L H -0.175126 -0.035589 0.567608 0.218 Uiso 1 1 calc R U . . .
C140 C -0.1589(5) -0.1366(8) 0.4552(15) 0.153(5) Uani 1 1 d D U . . .
H14A H -0.144115 -0.116287 0.486795 0.229 Uiso 1 1 calc R U . . .
H14B H -0.147976 -0.148427 0.407089 0.229 Uiso 1 1 calc R U . . .
H14C H -0.165755 -0.164055 0.487936 0.229 Uiso 1 1 calc R U . . .
C141 C -0.2208(7) -0.1651(8) 0.3243(15) 0.166(6) Uani 1 1 d D U . . .
H14D H -0.201447 -0.185189 0.322452 0.249 Uiso 1 1 calc R U . . .
H14E H -0.227966 -0.157537 0.269318 0.249 Uiso 1 1 calc R U . . .
H14F H -0.237755 -0.182625 0.352350 0.249 Uiso 1 1 calc R U . . .
C142 C -0.2671(5) -0.0778(9) 0.3214(15) 0.157(5) Uani 1 1 d D U . . .
H14G H -0.271473 -0.045277 0.300800 0.235 Uiso 1 1 calc R U . . .
H14H H -0.285029 -0.088600 0.354451 0.235 Uiso 1 1 calc R U . . .
H14I H -0.264411 -0.100128 0.276052 0.235 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1 C57 1.725(14) . ?
O1 C70 1.285(13) . ?
O1 Rh7 2.113(8) . ?
N1 C5 1.32(2) . ?
N1 C1 1.45(3) . ?
N1 Rh12 2.119(14) . ?
C1 C2 1.31(2) . ?
C1 H1 0.9500 . ?
Cl2 C60 1.704(14) . ?
O2 C71 1.262(13) . ?
O2 Rh7 2.112(8) . ?
N2 C28 1.369(12) . ?
N2 C30 1.386(13) . ?
N2 Rh11 2.083(16) . ?
C2 C3 1.39(3) . ?
C2 H2 0.9500 . ?
Cl3 C72 1.714(13) . ?
O3 C68 1.277(14) . ?
O3 Rh8 2.134(8) . ?
N3 C19 1.339(18) . ?
N3 C18 1.354(17) . ?
N3 Rh7 2.115(11) . ?
C3 C4 1.42(3) . ?
C3 C6 1.46(2) . ?
Cl4 C69 1.727(12) . ?
O4 C67 1.275(13) . ?
O4 Rh8 2.122(8) . ?
N4 C45 1.32(2) . ?
N4 C47 1.33(2) . ?
N4 Rh8 2.145(12) . ?
C4 C5 1.37(2) . ?
C4 H4 0.9500 . ?
Cl5 C63 1.680(17) . ?
O5 C58 1.266(14) . ?
O5 Rh9 2.137(9) . ?
N5 C27 1.314(19) . ?
N5 C25 1.391(19) . ?
N5 Rh9 2.099(13) . ?
C5 H5 0.9500 . ?
Cl6 C66 1.594(18) . ?
O6 C59 1.321(16) . ?
O6 Rh9 2.122(8) . ?
C6 C7 1.13(2) . ?
Rh7 C85 2.109(13) . ?
Rh7 C86 2.120(14) . ?
Rh7 C87 2.133(14) . ?
Rh7 C84 2.134(14) . ?
Rh7 C83 2.135(13) . ?
O7 C56 1.281(17) . ?
O7 Rh10 2.116(12) . ?
N7 C54 1.380(13) . ?
N7 C52 1.403(13) . ?
N7 Rh10 2.055(17) . ?
C7 C8 1.48(2) . ?
Rh8 C97 2.072(15) . ?
Rh8 C95 2.096(17) . ?
Rh8 C96 2.106(15) . ?
Rh8 C94 2.143(15) . ?
Rh8 C93 2.194(14) . ?
O8 C55 1.302(16) . ?
O8 Rh10 2.195(14) . ?
C8 C9 1.391(12) . ?
C8 C13 1.392(12) . ?
Rh9 C107 2.090(16) . ?
Rh9 C104 2.090(14) . ?
Rh9 C106 2.110(15) . ?
Rh9 C105 2.114(14) . ?
Rh9 C103 2.121(16) . ?
O9 C62 1.32(2) . ?
O9 Rh12 2.078(14) . ?
C9 C10 1.394(12) . ?
C9 H9 0.9500 . ?
Rh10 C133 1.98(2) . ?
Rh10 C134 2.03(2) . ?
Rh10 C137 2.13(2) . ?
Rh10 C136 2.21(2) . ?
Rh10 C135 2.26(2) . ?
O10 C61 1.33(2) . ?
O10 Rh12 2.152(18) . ?
C10 C11 1.389(12) . ?
C10 C21 1.45(2) . ?
Rh11 O11 2.058(13) . ?
Rh11 C123 2.11(3) . ?
Rh11 C124 2.16(3) . ?
Rh11 O12 2.166(19) . ?
Rh11 C127 2.17(3) . ?
Rh11 C126 2.19(3) . ?
Rh11 C125 2.24(3) . ?
O11 C64 1.43(2) . ?
C11 C12 1.395(12) . ?
C11 H11 0.9500 . ?
Rh12 C116 2.13(2) . ?
Rh12 C117 2.160(19) . ?
Rh12 C113 2.193(18) . ?
Rh12 C115 2.26(2) . ?
Rh12 C114 2.32(2) . ?
O12 C65 1.32(2) . ?
C12 C13 1.387(12) . ?
C12 C14 1.42(2) . ?
C13 H13 0.9500 . ?
C14 C15 1.25(2) . ?
C15 C16 1.38(2) . ?
C16 C17 1.39(2) . ?
C16 C20 1.41(2) . ?
C17 C18 1.368(19) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C20 1.35(2) . ?
C19 H19 0.9500 . ?
C20 H20 0.9500 . ?
C21 C22 1.20(2) . ?
C22 C23 1.43(2) . ?
C23 C24 1.36(2) . ?
C23 C26 1.41(2) . ?
C24 C25 1.38(2) . ?
C24 H24 0.9500 . ?
C25 H25 0.9500 . ?
C26 C27 1.35(2) . ?
C26 H26 0.9500 . ?
C27 H27 0.9500 . ?
C28 C29 1.372(13) . ?
C28 H28 0.9500 . ?
C29 C32 1.384(13) . ?
C29 H29 0.9500 . ?
C30 C31 1.372(13) . ?
C30 H30 0.9500 . ?
C31 C32 1.381(13) . ?
C31 H31 0.9500 . ?
C32 C33 1.46(3) . ?
C33 C34 1.19(3) . ?
C34 C35 1.48(3) . ?
C35 C40 1.373(13) . ?
C35 C36 1.389(13) . ?
C36 C37 1.382(13) . ?
C36 H36 0.9500 . ?
C37 C38 1.391(13) . ?
C37 C41 1.54(3) . ?
C38 C39 1.383(13) . ?
C38 H38 0.9500 . ?
C39 C48 1.37(3) . ?
C39 C40 1.385(13) . ?
C40 H40 0.9500 . ?
C41 C42 1.16(3) . ?
C42 C43 1.46(3) . ?
C43 C44 1.40(3) . ?
C43 C46 1.43(3) . ?
C44 C45 1.30(2) . ?
C44 H44 0.9500 . ?
C45 H45 0.9500 . ?
C46 C47 1.32(2) . ?
C46 H46 0.9500 . ?
C47 H47 0.9500 . ?
C48 C49 1.14(3) . ?
C49 C50 1.58(3) . ?
C50 C51 1.383(13) . ?
C50 C53 1.390(13) . ?
C51 C52 1.385(13) . ?
C51 H51 0.9500 . ?
C52 H52 0.9500 . ?
C53 C54 1.388(13) . ?
C53 H53 0.9500 . ?
C54 H54 0.9500 . ?
C55 C60 1.393(12) . ?
C55 C56 1.444(12) . ?
C56 C57 1.392(11) . ?
C57 C58 1.402(11) . ?
C58 C59 1.452(11) . ?
C59 C60 1.408(11) . ?
C61 C66 1.388(13) . ?
C61 C62 1.417(13) . ?
C62 C63 1.385(13) . ?
C63 C64 1.388(13) . ?
C64 C65 1.406(12) . ?
C65 C66 1.396(13) . ?
C67 C72 1.393(11) . ?
C67 C68 1.442(11) . ?
C68 C69 1.407(11) . ?
C69 C70 1.394(11) . ?
C70 C71 1.442(11) . ?
C71 C72 1.413(11) . ?
C83 C84 1.36(2) . ?
C83 C88 1.40(2) . ?
C83 C87 1.53(2) . ?
C84 C85 1.46(2) . ?
C84 C89 1.50(2) . ?
C85 C86 1.44(2) . ?
C85 C90 1.51(2) . ?
C86 C87 1.35(2) . ?
C86 C91 1.56(2) . ?
C87 C92 1.52(2) . ?
C88 H88A 0.9500 . ?
C88 H88B 0.9500 . ?
C89 H89A 0.9800 . ?
C89 H89B 0.9800 . ?
C89 H89C 0.9800 . ?
C90 H90A 0.9800 . ?
C90 H90B 0.9800 . ?
C90 H90C 0.9800 . ?
C91 H91A 0.9800 . ?
C91 H91B 0.9800 . ?
C91 H91C 0.9800 . ?
C92 H92A 0.9800 . ?
C92 H92B 0.9800 . ?
C92 H92C 0.9800 . ?
C93 C97 1.33(2) . ?
C93 C98 1.45(2) . ?
C93 C94 1.48(3) . ?
C94 C95 1.46(2) . ?
C94 C99 1.62(3) . ?
C95 C96 1.33(3) . ?
C95 C100 1.48(3) . ?
C96 C101 1.42(2) . ?
C96 C97 1.43(3) . ?
C97 C102 1.59(3) . ?
C98 H98A 0.9800 . ?
C98 H98B 0.9800 . ?
C98 H98C 0.9800 . ?
C99 H99A 0.9800 . ?
C99 H99B 0.9800 . ?
C99 H99C 0.9800 . ?
C100 H10A 0.9800 . ?
C100 H10B 0.9800 . ?
C100 H10L 0.9800 . ?
C101 H10C 0.9800 . ?
C101 H10D 0.9800 . ?
C101 H10E 0.9800 . ?
C102 H10M 0.9800 . ?
C102 H10N 0.9800 . ?
C102 H10O 0.9800 . ?
C103 C107 1.36(2) . ?
C103 C104 1.45(2) . ?
C103 C108 1.47(2) . ?
C104 C105 1.41(2) . ?
C104 C109 1.42(2) . ?
C105 C106 1.35(2) . ?
C105 C110 1.49(2) . ?
C106 C107 1.46(2) . ?
C106 C111 1.57(2) . ?
C107 C112 1.57(2) . ?
C108 H10I 0.9800 . ?
C108 H10J 0.9800 . ?
C108 H10K 0.9800 . ?
C109 H10F 0.9800 . ?
C109 H10G 0.9800 . ?
C109 H10H 0.9800 . ?
C110 H11M 0.9800 . ?
C110 H11N 0.9800 . ?
C110 H11O 0.9800 . ?
C111 H11J 0.9800 . ?
C111 H11K 0.9800 . ?
C111 H11L 0.9800 . ?
C112 H11G 0.9800 . ?
C112 H11H 0.9800 . ?
C112 H11I 0.9800 . ?
C113 C117 1.46(3) . ?
C113 C114 1.52(3) . ?
C113 C118 1.54(2) . ?
C114 C115 1.38(3) . ?
C114 C119 1.50(2) . ?
C115 C116 1.51(3) . ?
C115 C120 1.55(2) . ?
C116 C117 1.39(2) . ?
C116 C121 1.55(2) . ?
C117 C122 1.56(2) . ?
C118 H11D 0.9800 . ?
C118 H11E 0.9800 . ?
C118 H11F 0.9800 . ?
C119 H11A 0.9800 . ?
C119 H11B 0.9800 . ?
C119 H11C 0.9800 . ?
C120 H12G 0.9800 . ?
C120 H12H 0.9800 . ?
C120 H12I 0.9800 . ?
C121 H12D 0.9800 . ?
C121 H12E 0.9800 . ?
C121 H12F 0.9800 . ?
C122 H12A 0.9800 . ?
C122 H12B 0.9800 . ?
C122 H12C 0.9800 . ?
C123 C127 1.385(12) . ?
C123 C124 1.407(12) . ?
C123 C128 1.611(19) . ?
C124 C125 1.388(12) . ?
C124 C129 1.561(18) . ?
C125 C126 1.409(12) . ?
C125 C130 1.600(18) . ?
C126 C127 1.384(12) . ?
C126 C131 1.589(19) . ?
C127 C132 1.574(18) . ?
C128 H12J 0.9800 . ?
C128 H12K 0.9800 . ?
C128 H12L 0.9800 . ?
C129 H12M 0.9800 . ?
C129 H12N 0.9800 . ?
C129 H12O 0.9800 . ?
C130 H13A 0.9800 . ?
C130 H13B 0.9800 . ?
C130 H13C 0.9800 . ?
C131 H13D 0.9800 . ?
C131 H13E 0.9800 . ?
C131 H13F 0.9800 . ?
C132 H13G 0.9800 . ?
C132 H13H 0.9800 . ?
C132 H13I 0.9800 . ?
C133 C137 1.399(12) . ?
C133 C134 1.404(12) . ?
C133 C138 1.567(19) . ?
C134 C135 1.408(13) . ?
C134 C139 1.591(19) . ?
C135 C136 1.374(12) . ?
C135 C140 1.614(19) . ?
C136 C137 1.407(13) . ?
C136 C141 1.599(19) . ?
C137 C142 1.620(19) . ?
C138 H13M 0.9800 . ?
C138 H13N 0.9800 . ?
C138 H13O 0.9800 . ?
C139 H13J 0.9800 . ?
C139 H13K 0.9800 . ?
C139 H13L 0.9800 . ?
C140 H14A 0.9800 . ?
C140 H14B 0.9800 . ?
C140 H14C 0.9800 . ?
C141 H14D 0.9800 . ?
C141 H14E 0.9800 . ?
C141 H14F 0.9800 . ?
C142 H14G 0.9800 . ?
C142 H14H 0.9800 . ?
C142 H14I 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C70 O1 Rh7 115.5(7) . . ?
C5 N1 C1 120.6(16) . . ?
C5 N1 Rh12 121.4(13) . . ?
C1 N1 Rh12 116.8(12) . . ?
C2 C1 N1 120.5(18) . . ?
C2 C1 H1 119.7 . . ?
N1 C1 H1 119.7 . . ?
C71 O2 Rh7 116.0(7) . . ?
C28 N2 C30 119.0(18) . . ?
C28 N2 Rh11 122.3(13) . . ?
C30 N2 Rh11 117.6(11) . . ?
C1 C2 C3 118.5(19) . . ?
C1 C2 H2 120.8 . . ?
C3 C2 H2 120.8 . . ?
C68 O3 Rh8 113.9(7) . . ?
C19 N3 C18 121.7(12) . . ?
C19 N3 Rh7 119.0(9) . . ?
C18 N3 Rh7 118.9(10) . . ?
C2 C3 C4 121.1(15) . . ?
C2 C3 C6 122.1(18) . . ?
C4 C3 C6 116.1(16) . . ?
C67 O4 Rh8 114.7(7) . . ?
C45 N4 C47 116.7(14) . . ?
C45 N4 Rh8 122.1(11) . . ?
C47 N4 Rh8 121.1(11) . . ?
C5 C4 C3 118.3(18) . . ?
C5 C4 H4 120.9 . . ?
C3 C4 H4 120.9 . . ?
C58 O5 Rh9 114.2(7) . . ?
C27 N5 C25 117.4(14) . . ?
C27 N5 Rh9 121.7(10) . . ?
C25 N5 Rh9 120.8(10) . . ?
N1 C5 C4 120(2) . . ?
N1 C5 H5 119.8 . . ?
C4 C5 H5 119.8 . . ?
C59 O6 Rh9 113.0(7) . . ?
C7 C6 C3 176(3) . . ?
C85 Rh7 O1 116.0(5) . . ?
C85 Rh7 O2 100.1(5) . . ?
O1 Rh7 O2 75.2(3) . . ?
C85 Rh7 N3 156.6(5) . . ?
O1 Rh7 N3 87.4(4) . . ?
O2 Rh7 N3 86.7(4) . . ?
C85 Rh7 C86 39.7(6) . . ?
O1 Rh7 C86 155.3(5) . . ?
O2 Rh7 C86 101.5(5) . . ?
N3 Rh7 C86 117.1(5) . . ?
C85 Rh7 C87 64.2(6) . . ?
O1 Rh7 C87 152.5(5) . . ?
O2 Rh7 C87 132.3(5) . . ?
N3 Rh7 C87 94.6(5) . . ?
C86 Rh7 C87 37.1(6) . . ?
C85 Rh7 C84 40.2(6) . . ?
O1 Rh7 C84 97.1(5) . . ?
O2 Rh7 C84 131.9(5) . . ?
N3 Rh7 C84 141.1(5) . . ?
C86 Rh7 C84 66.4(6) . . ?
C87 Rh7 C84 64.8(6) . . ?
C85 Rh7 C83 66.2(5) . . ?
O1 Rh7 C83 111.1(5) . . ?
O2 Rh7 C83 166.3(4) . . ?
N3 Rh7 C83 105.4(5) . . ?
C86 Rh7 C83 67.6(6) . . ?
C87 Rh7 C83 42.1(6) . . ?
C84 Rh7 C83 37.2(6) . . ?
C56 O7 Rh10 114.4(10) . . ?
C54 N7 C52 119.6(18) . . ?
C54 N7 Rh10 120.9(11) . . ?
C52 N7 Rh10 119.0(14) . . ?
C6 C7 C8 170(2) . . ?
C97 Rh8 C95 64.2(7) . . ?
C97 Rh8 C96 40.0(7) . . ?
C95 Rh8 C96 36.8(7) . . ?
C97 Rh8 O4 163.5(6) . . ?
C95 Rh8 O4 99.5(6) . . ?
C96 Rh8 O4 127.4(6) . . ?
C97 Rh8 O3 112.7(6) . . ?
C95 Rh8 O3 116.5(5) . . ?
C96 Rh8 O3 97.3(5) . . ?
O4 Rh8 O3 76.1(3) . . ?
C97 Rh8 C94 63.3(7) . . ?
C95 Rh8 C94 40.2(7) . . ?
C96 Rh8 C94 64.4(7) . . ?
O4 Rh8 C94 102.8(5) . . ?
O3 Rh8 C94 156.7(5) . . ?
C97 Rh8 N4 106.5(6) . . ?
C95 Rh8 N4 160.9(6) . . ?
C96 Rh8 N4 143.4(7) . . ?
O4 Rh8 N4 88.2(4) . . ?
O3 Rh8 N4 82.2(4) . . ?
C94 Rh8 N4 121.1(6) . . ?
C97 Rh8 C93 36.1(6) . . ?
C95 Rh8 C93 66.5(7) . . ?
C96 Rh8 C93 64.9(6) . . ?
O4 Rh8 C93 137.0(6) . . ?
O3 Rh8 C93 146.9(6) . . ?
C94 Rh8 C93 39.9(7) . . ?
N4 Rh8 C93 96.0(6) . . ?
C55 O8 Rh10 110.9(10) . . ?
C9 C8 C13 122.4(14) . . ?
C9 C8 C7 117.1(12) . . ?
C13 C8 C7 120.5(13) . . ?
C107 Rh9 C104 65.7(6) . . ?
C107 Rh9 N5 158.8(5) . . ?
C104 Rh9 N5 106.0(6) . . ?
C107 Rh9 C106 40.7(6) . . ?
C104 Rh9 C106 65.3(6) . . ?
N5 Rh9 C106 118.3(5) . . ?
C107 Rh9 C105 65.2(6) . . ?
C104 Rh9 C105 39.3(6) . . ?
N5 Rh9 C105 95.7(6) . . ?
C106 Rh9 C105 37.4(6) . . ?
C107 Rh9 O6 115.9(5) . . ?
C104 Rh9 O6 111.1(5) . . ?
N5 Rh9 O6 85.1(4) . . ?
C106 Rh9 O6 156.5(5) . . ?
C105 Rh9 O6 149.4(5) . . ?
C107 Rh9 C103 37.8(6) . . ?
C104 Rh9 C103 40.2(6) . . ?
N5 Rh9 C103 144.0(5) . . ?
C106 Rh9 C103 65.6(6) . . ?
C105 Rh9 C103 65.6(6) . . ?
O6 Rh9 C103 96.3(5) . . ?
C107 Rh9 O5 98.6(5) . . ?
C104 Rh9 O5 164.2(5) . . ?
N5 Rh9 O5 87.8(4) . . ?
C106 Rh9 O5 101.5(5) . . ?
C105 Rh9 O5 133.4(5) . . ?
O6 Rh9 O5 77.2(3) . . ?
C103 Rh9 O5 127.6(5) . . ?
C62 O9 Rh12 116.0(11) . . ?
C8 C9 C10 119.7(14) . . ?
C8 C9 H9 120.2 . . ?
C10 C9 H9 120.2 . . ?
C133 Rh10 C134 41.0(4) . . ?
C133 Rh10 N7 134.7(7) . . ?
C134 Rh10 N7 100.0(7) . . ?
C133 Rh10 O7 101.8(7) . . ?
C134 Rh10 O7 126.7(6) . . ?
N7 Rh10 O7 84.0(5) . . ?
C133 Rh10 C137 39.6(4) . . ?
C134 Rh10 C137 63.6(8) . . ?
N7 Rh10 C137 158.7(7) . . ?
O7 Rh10 C137 116.4(6) . . ?
C133 Rh10 O8 139.0(6) . . ?
C134 Rh10 O8 155.8(6) . . ?
N7 Rh10 O8 86.3(6) . . ?
O7 Rh10 O8 77.0(4) . . ?
C137 Rh10 O8 103.5(6) . . ?
C133 Rh10 C136 67.5(8) . . ?
C134 Rh10 C136 64.5(8) . . ?
N7 Rh10 C136 124.4(6) . . ?
O7 Rh10 C136 149.4(5) . . ?
C137 Rh10 C136 37.8(4) . . ?
O8 Rh10 C136 92.5(6) . . ?
C133 Rh10 C135 65.3(8) . . ?
C134 Rh10 C135 37.9(4) . . ?
N7 Rh10 C135 98.9(7) . . ?
O7 Rh10 C135 164.5(6) . . ?
C137 Rh10 C135 59.8(8) . . ?
O8 Rh10 C135 118.2(6) . . ?
C136 Rh10 C135 35.8(4) . . ?
C61 O10 Rh12 116.5(11) . . ?
C11 C10 C9 119.2(14) . . ?
C11 C10 C21 117.2(12) . . ?
C9 C10 C21 122.4(13) . . ?
O11 Rh11 N2 90.8(6) . . ?
O11 Rh11 C123 107.1(7) . . ?
N2 Rh11 C123 107.3(7) . . ?
O11 Rh11 C124 95.2(7) . . ?
N2 Rh11 C124 145.3(7) . . ?
C123 Rh11 C124 38.4(5) . . ?
O11 Rh11 O12 77.5(6) . . ?
N2 Rh11 O12 90.6(7) . . ?
C123 Rh11 O12 161.3(7) . . ?
C124 Rh11 O12 124.1(6) . . ?
O11 Rh11 C127 143.1(6) . . ?
N2 Rh11 C127 91.5(8) . . ?
C123 Rh11 C127 37.8(5) . . ?
C124 Rh11 C127 63.9(8) . . ?
O12 Rh11 C127 139.3(6) . . ?
O11 Rh11 C126 157.1(6) . . ?
N2 Rh11 C126 111.6(6) . . ?
C123 Rh11 C126 62.8(8) . . ?
C124 Rh11 C126 63.8(7) . . ?
O12 Rh11 C126 105.8(7) . . ?
C127 Rh11 C126 37.1(4) . . ?
O11 Rh11 C125 120.1(5) . . ?
N2 Rh11 C125 148.6(7) . . ?
C123 Rh11 C125 61.1(8) . . ?
C124 Rh11 C125 36.7(4) . . ?
O12 Rh11 C125 100.7(7) . . ?
C127 Rh11 C125 61.0(8) . . ?
C126 Rh11 C125 37.1(4) . . ?
C64 O11 Rh11 115.6(9) . . ?
C10 C11 C12 118.2(14) . . ?
C10 C11 H11 120.9 . . ?
C12 C11 H11 120.9 . . ?
O9 Rh12 N1 83.6(6) . . ?
O9 Rh12 C116 157.0(6) . . ?
N1 Rh12 C116 119.3(7) . . ?
O9 Rh12 O10 74.9(6) . . ?
N1 Rh12 O10 86.2(6) . . ?
C116 Rh12 O10 102.5(8) . . ?
O9 Rh12 C117 119.5(6) . . ?
N1 Rh12 C117 157.0(7) . . ?
C116 Rh12 C117 37.7(7) . . ?
O10 Rh12 C117 99.8(8) . . ?
O9 Rh12 C113 100.5(7) . . ?
N1 Rh12 C113 142.8(8) . . ?
C116 Rh12 C113 63.4(9) . . ?
O10 Rh12 C113 130.8(7) . . ?
C117 Rh12 C113 39.2(7) . . ?
O9 Rh12 C115 148.2(7) . . ?
N1 Rh12 C115 95.9(7) . . ?
C116 Rh12 C115 40.2(8) . . ?
O10 Rh12 C115 136.9(7) . . ?
C117 Rh12 C115 64.6(8) . . ?
C113 Rh12 C115 61.7(8) . . ?
O9 Rh12 C114 114.3(7) . . ?
N1 Rh12 C114 105.3(7) . . ?
C116 Rh12 C114 64.6(9) . . ?
O10 Rh12 C114 165.6(6) . . ?
C117 Rh12 C114 66.3(9) . . ?
C113 Rh12 C114 39.2(7) . . ?
C115 Rh12 C114 35.2(6) . . ?
C65 O12 Rh11 113.3(11) . . ?
C13 C12 C11 123.4(14) . . ?
C13 C12 C14 122.6(13) . . ?
C11 C12 C14 112.8(12) . . ?
C12 C13 C8 115.7(14) . . ?
C12 C13 H13 122.1 . . ?
C8 C13 H13 122.1 . . ?
C15 C14 C12 177.6(17) . . ?
C14 C15 C16 168.5(17) . . ?
C15 C16 C17 120.6(14) . . ?
C15 C16 C20 122.0(15) . . ?
C17 C16 C20 117.4(13) . . ?
C18 C17 C16 121.1(14) . . ?
C18 C17 H17 119.4 . . ?
C16 C17 H17 119.4 . . ?
N3 C18 C17 119.0(15) . . ?
N3 C18 H18 120.5 . . ?
C17 C18 H18 120.5 . . ?
N3 C19 C20 120.8(14) . . ?
N3 C19 H19 119.6 . . ?
C20 C19 H19 119.6 . . ?
C19 C20 C16 119.7(15) . . ?
C19 C20 H20 120.2 . . ?
C16 C20 H20 120.2 . . ?
C22 C21 C10 173(2) . . ?
C21 C22 C23 175.0(19) . . ?
C24 C23 C26 120.5(16) . . ?
C24 C23 C22 120.7(15) . . ?
C26 C23 C22 118.9(16) . . ?
C23 C24 C25 117.3(15) . . ?
C23 C24 H24 121.3 . . ?
C25 C24 H24 121.3 . . ?
C24 C25 N5 122.6(15) . . ?
C24 C25 H25 118.7 . . ?
N5 C25 H25 118.7 . . ?
C27 C26 C23 118.4(15) . . ?
C27 C26 H26 120.8 . . ?
C23 C26 H26 120.8 . . ?
N5 C27 C26 123.6(15) . . ?
N5 C27 H27 118.2 . . ?
C26 C27 H27 118.2 . . ?
N2 C28 C29 116.2(18) . . ?
N2 C28 H28 121.9 . . ?
C29 C28 H28 121.9 . . ?
C28 C29 C32 123.9(18) . . ?
C28 C29 H29 118.0 . . ?
C32 C29 H29 118.0 . . ?
C31 C30 N2 123.9(19) . . ?
C31 C30 H30 118.1 . . ?
N2 C30 H30 118.1 . . ?
C30 C31 C32 115.9(19) . . ?
C30 C31 H31 122.0 . . ?
C32 C31 H31 122.0 . . ?
C31 C32 C29 119.2(19) . . ?
C31 C32 C33 116.4(17) . . ?
C29 C32 C33 124.3(16) . . ?
C34 C33 C32 172(2) . . ?
C33 C34 C35 167(3) . . ?
C40 C35 C36 121.1(19) . . ?
C40 C35 C34 120.8(16) . . ?
C36 C35 C34 117.7(17) . . ?
C37 C36 C35 114.7(19) . . ?
C37 C36 H36 122.6 . . ?
C35 C36 H36 122.6 . . ?
C36 C37 C38 126.1(19) . . ?
C36 C37 C41 119.3(16) . . ?
C38 C37 C41 114.5(16) . . ?
C39 C38 C37 116.8(19) . . ?
C39 C38 H38 121.6 . . ?
C37 C38 H38 121.6 . . ?
C48 C39 C38 119.4(18) . . ?
C48 C39 C40 121.6(17) . . ?
C38 C39 C40 118.8(19) . . ?
C35 C40 C39 122.4(19) . . ?
C35 C40 H40 118.8 . . ?
C39 C40 H40 118.8 . . ?
C42 C41 C37 170(2) . . ?
C41 C42 C43 174(3) . . ?
C44 C43 C46 119.8(17) . . ?
C44 C43 C42 119.6(19) . . ?
C46 C43 C42 120.3(18) . . ?
C45 C44 C43 116.1(19) . . ?
C45 C44 H44 121.9 . . ?
C43 C44 H44 121.9 . . ?
C44 C45 N4 126.5(18) . . ?
C44 C45 H45 116.7 . . ?
N4 C45 H45 116.7 . . ?
C47 C46 C43 115.5(18) . . ?
C47 C46 H46 122.3 . . ?
C43 C46 H46 122.3 . . ?
C46 C47 N4 125.1(19) . . ?
C46 C47 H47 117.4 . . ?
N4 C47 H47 117.4 . . ?
C49 C48 C39 173(3) . . ?
C48 C49 C50 165(3) . . ?
C51 C50 C53 123(2) . . ?
C51 C50 C49 124.7(17) . . ?
C53 C50 C49 111.7(18) . . ?
C50 C51 C52 119(2) . . ?
C50 C51 H51 120.7 . . ?
C52 C51 H51 120.7 . . ?
C51 C52 N7 119.2(19) . . ?
C51 C52 H52 120.4 . . ?
N7 C52 H52 120.4 . . ?
C54 C53 C50 116(2) . . ?
C54 C53 H53 122.0 . . ?
C50 C53 H53 122.0 . . ?
N7 C54 C53 122.2(19) . . ?
N7 C54 H54 118.9 . . ?
C53 C54 H54 118.9 . . ?
O8 C55 C60 118.0(12) . . ?
O8 C55 C56 118.9(11) . . ?
C60 C55 C56 123.0(12) . . ?
O7 C56 C57 120.5(12) . . ?
O7 C56 C55 118.4(11) . . ?
C57 C56 C55 121.1(12) . . ?
C56 C57 C58 117.9(12) . . ?
C56 C57 Cl1 121.1(10) . . ?
C58 C57 Cl1 120.8(8) . . ?
O5 C58 C57 122.8(10) . . ?
O5 C58 C59 118.1(10) . . ?
C57 C58 C59 119.2(11) . . ?
O6 C59 C60 118.8(11) . . ?
O6 C59 C58 117.3(9) . . ?
C60 C59 C58 123.8(12) . . ?
C55 C60 C59 114.3(12) . . ?
C55 C60 Cl2 123.3(9) . . ?
C59 C60 Cl2 122.4(10) . . ?
O10 C61 C66 117.3(16) . . ?
O10 C61 C62 112.9(17) . . ?
C66 C61 C62 129.4(19) . . ?
O9 C62 C63 118.5(15) . . ?
O9 C62 C61 118.1(16) . . ?
C63 C62 C61 123.4(18) . . ?
C62 C63 C64 109.4(17) . . ?
C62 C63 Cl5 128.3(13) . . ?
C64 C63 Cl5 122.2(13) . . ?
C63 C64 C65 124.7(19) . . ?
C63 C64 O11 120.9(14) . . ?
C65 C64 O11 114.2(15) . . ?
O12 C65 C66 112.4(15) . . ?
O12 C65 C64 119.3(17) . . ?
C66 C65 C64 128.2(19) . . ?
C61 C66 C65 104.7(17) . . ?
C61 C66 Cl6 126.8(15) . . ?
C65 C66 Cl6 128.4(15) . . ?
O4 C67 C72 122.1(10) . . ?
O4 C67 C68 117.3(9) . . ?
C72 C67 C68 120.5(10) . . ?
O3 C68 C69 120.5(10) . . ?
O3 C68 C67 117.7(9) . . ?
C69 C68 C67 121.7(11) . . ?
C70 C69 C68 117.1(10) . . ?
C70 C69 Cl4 122.1(8) . . ?
C68 C69 Cl4 120.7(8) . . ?
O1 C70 C69 122.2(10) . . ?
O1 C70 C71 116.1(9) . . ?
C69 C70 C71 121.7(10) . . ?
O2 C71 C72 122.7(10) . . ?
O2 C71 C70 116.8(9) . . ?
C72 C71 C70 120.5(10) . . ?
C67 C72 C71 118.1(11) . . ?
C67 C72 Cl3 121.8(8) . . ?
C71 C72 Cl3 120.1(8) . . ?
C84 C83 C88 130.0(18) . . ?
C84 C83 C87 104.2(13) . . ?
C88 C83 C87 125.4(15) . . ?
C84 C83 Rh7 71.4(8) . . ?
C88 C83 Rh7 129.0(10) . . ?
C87 C83 Rh7 68.9(7) . . ?
C83 C84 C85 110.6(15) . . ?
C83 C84 C89 123.6(15) . . ?
C85 C84 C89 125.7(14) . . ?
C83 C84 Rh7 71.4(9) . . ?
C85 C84 Rh7 69.0(8) . . ?
C89 C84 Rh7 123.4(10) . . ?
C86 C85 C84 107.3(13) . . ?
C86 C85 C90 129.2(15) . . ?
C84 C85 C90 123.5(15) . . ?
C86 C85 Rh7 70.6(8) . . ?
C84 C85 Rh7 70.8(8) . . ?
C90 C85 Rh7 122.5(10) . . ?
C87 C86 C85 107.8(15) . . ?
C87 C86 C91 129.6(16) . . ?
C85 C86 C91 122.5(14) . . ?
C87 C86 Rh7 71.9(9) . . ?
C85 C86 Rh7 69.7(8) . . ?
C91 C86 Rh7 126.1(10) . . ?
C86 C87 C92 125.5(17) . . ?
C86 C87 C83 110.0(14) . . ?
C92 C87 C83 124.6(14) . . ?
C86 C87 Rh7 70.9(9) . . ?
C92 C87 Rh7 126.4(10) . . ?
C83 C87 Rh7 69.0(8) . . ?
C83 C88 H88A 120.0 . . ?
C83 C88 H88B 120.0 . . ?
H88A C88 H88B 120.0 . . ?
C84 C89 H89A 109.5 . . ?
C84 C89 H89B 109.5 . . ?
H89A C89 H89B 109.5 . . ?
C84 C89 H89C 109.5 . . ?
H89A C89 H89C 109.5 . . ?
H89B C89 H89C 109.5 . . ?
C85 C90 H90A 109.5 . . ?
C85 C90 H90B 109.5 . . ?
H90A C90 H90B 109.5 . . ?
C85 C90 H90C 109.5 . . ?
H90A C90 H90C 109.5 . . ?
H90B C90 H90C 109.5 . . ?
C86 C91 H91A 109.5 . . ?
C86 C91 H91B 109.5 . . ?
H91A C91 H91B 109.5 . . ?
C86 C91 H91C 109.5 . . ?
H91A C91 H91C 109.5 . . ?
H91B C91 H91C 109.5 . . ?
C87 C92 H92A 109.5 . . ?
C87 C92 H92B 109.5 . . ?
H92A C92 H92B 109.5 . . ?
C87 C92 H92C 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?
C97 C93 C98 130(2) . . ?
C97 C93 C94 104.0(16) . . ?
C98 C93 C94 125.8(17) . . ?
C97 C93 Rh8 66.9(9) . . ?
C98 C93 Rh8 121.8(11) . . ?
C94 C93 Rh8 68.2(8) . . ?
C95 C94 C93 106.3(16) . . ?
C95 C94 C99 123.8(18) . . ?
C93 C94 C99 129.7(16) . . ?
C95 C94 Rh8 68.1(9) . . ?
C93 C94 Rh8 71.9(9) . . ?
C99 C94 Rh8 121.1(10) . . ?
C96 C95 C94 108.8(18) . . ?
C96 C95 C100 131.6(19) . . ?
C94 C95 C100 119.4(18) . . ?
C96 C95 Rh8 72.0(11) . . ?
C94 C95 Rh8 71.6(9) . . ?
C100 C95 Rh8 126.1(11) . . ?
C95 C96 C101 129(2) . . ?
C95 C96 C97 107.0(17) . . ?
C101 C96 C97 124(2) . . ?
C95 C96 Rh8 71.2(10) . . ?
C101 C96 Rh8 125.3(12) . . ?
C97 C96 Rh8 68.7(9) . . ?
C93 C97 C96 113.7(19) . . ?
C93 C97 C102 120.4(18) . . ?
C96 C97 C102 124.9(17) . . ?
C93 C97 Rh8 77.0(10) . . ?
C96 C97 Rh8 71.3(9) . . ?
C102 C97 Rh8 129.2(12) . . ?
C93 C98 H98A 109.5 . . ?
C93 C98 H98B 109.5 . . ?
H98A C98 H98B 109.5 . . ?
C93 C98 H98C 109.5 . . ?
H98A C98 H98C 109.5 . . ?
H98B C98 H98C 109.5 . . ?
C94 C99 H99A 109.5 . . ?
C94 C99 H99B 109.5 . . ?
H99A C99 H99B 109.5 . . ?
C94 C99 H99C 109.5 . . ?
H99A C99 H99C 109.5 . . ?
H99B C99 H99C 109.5 . . ?
C95 C100 H10A 109.5 . . ?
C95 C100 H10B 109.5 . . ?
H10A C100 H10B 109.5 . . ?
C95 C100 H10L 109.5 . . ?
H10A C100 H10L 109.5 . . ?
H10B C100 H10L 109.5 . . ?
C96 C101 H10C 109.5 . . ?
C96 C101 H10D 109.5 . . ?
H10C C101 H10D 109.5 . . ?
C96 C101 H10E 109.5 . . ?
H10C C101 H10E 109.5 . . ?
H10D C101 H10E 109.5 . . ?
C97 C102 H10M 109.5 . . ?
C97 C102 H10N 109.5 . . ?
H10M C102 H10N 109.5 . . ?
C97 C102 H10O 109.5 . . ?
H10M C102 H10O 109.5 . . ?
H10N C102 H10O 109.5 . . ?
C107 C103 C104 107.7(14) . . ?
C107 C103 C108 130.8(15) . . ?
C104 C103 C108 121.6(15) . . ?
C107 C103 Rh9 69.9(9) . . ?
C104 C103 Rh9 68.7(9) . . ?
C108 C103 Rh9 126.6(11) . . ?
C105 C104 C109 125.1(16) . . ?
C105 C104 C103 106.6(14) . . ?
C109 C104 C103 127.9(16) . . ?
C105 C104 Rh9 71.3(8) . . ?
C109 C104 Rh9 127.8(12) . . ?
C103 C104 Rh9 71.1(8) . . ?
C106 C105 C104 110.0(14) . . ?
C106 C105 C110 128.4(15) . . ?
C104 C105 C110 121.6(15) . . ?
C106 C105 Rh9 71.1(9) . . ?
C104 C105 Rh9 69.4(8) . . ?
C110 C105 Rh9 127.3(12) . . ?
C105 C106 C107 107.1(14) . . ?
C105 C106 C111 128.4(15) . . ?
C107 C106 C111 124.5(14) . . ?
C105 C106 Rh9 71.5(9) . . ?
C107 C106 Rh9 68.9(8) . . ?
C111 C106 Rh9 124.9(10) . . ?
C103 C107 C106 108.5(14) . . ?
C103 C107 C112 128.5(15) . . ?
C106 C107 C112 122.9(14) . . ?
C103 C107 Rh9 72.4(10) . . ?
C106 C107 Rh9 70.4(9) . . ?
C112 C107 Rh9 124.4(11) . . ?
C103 C108 H10I 109.5 . . ?
C103 C108 H10J 109.5 . . ?
H10I C108 H10J 109.5 . . ?
C103 C108 H10K 109.5 . . ?
H10I C108 H10K 109.5 . . ?
H10J C108 H10K 109.5 . . ?
C104 C109 H10F 109.5 . . ?
C104 C109 H10G 109.5 . . ?
H10F C109 H10G 109.5 . . ?
C104 C109 H10H 109.5 . . ?
H10F C109 H10H 109.5 . . ?
H10G C109 H10H 109.5 . . ?
C105 C110 H11M 109.5 . . ?
C105 C110 H11N 109.5 . . ?
H11M C110 H11N 109.5 . . ?
C105 C110 H11O 109.5 . . ?
H11M C110 H11O 109.5 . . ?
H11N C110 H11O 109.5 . . ?
C106 C111 H11J 109.5 . . ?
C106 C111 H11K 109.5 . . ?
H11J C111 H11K 109.5 . . ?
C106 C111 H11L 109.5 . . ?
H11J C111 H11L 109.5 . . ?
H11K C111 H11L 109.5 . . ?
C107 C112 H11G 109.5 . . ?
C107 C112 H11H 109.5 . . ?
H11G C112 H11H 109.5 . . ?
C107 C112 H11I 109.5 . . ?
H11G C112 H11I 109.5 . . ?
H11H C112 H11I 109.5 . . ?
C117 C113 C114 110.8(19) . . ?
C117 C113 C118 128.6(19) . . ?
C114 C113 C118 120.6(18) . . ?
C117 C113 Rh12 69.2(11) . . ?
C114 C113 Rh12 74.9(10) . . ?
C118 C113 Rh12 120.6(13) . . ?
C115 C114 C119 135.2(19) . . ?
C115 C114 C113 104(2) . . ?
C119 C114 C113 119.9(18) . . ?
C115 C114 Rh12 70.0(11) . . ?
C119 C114 Rh12 117.1(13) . . ?
C113 C114 Rh12 65.9(10) . . ?
C114 C115 C116 111(2) . . ?
C114 C115 C120 128(2) . . ?
C116 C115 C120 121.1(18) . . ?
C114 C115 Rh12 74.9(11) . . ?
C116 C115 Rh12 65.4(12) . . ?
C120 C115 Rh12 126.8(12) . . ?
C117 C116 C115 109(2) . . ?
C117 C116 C121 132(2) . . ?
C115 C116 C121 118.2(17) . . ?
C117 C116 Rh12 72.3(12) . . ?
C115 C116 Rh12 74.4(11) . . ?
C121 C116 Rh12 126.6(17) . . ?
C116 C117 C113 106(2) . . ?
C116 C117 C122 132(2) . . ?
C113 C117 C122 121.8(18) . . ?
C116 C117 Rh12 70.0(12) . . ?
C113 C117 Rh12 71.6(11) . . ?
C122 C117 Rh12 116.3(15) . . ?
C113 C118 H11D 109.5 . . ?
C113 C118 H11E 109.5 . . ?
H11D C118 H11E 109.5 . . ?
C113 C118 H11F 109.5 . . ?
H11D C118 H11F 109.5 . . ?
H11E C118 H11F 109.5 . . ?
C114 C119 H11A 109.5 . . ?
C114 C119 H11B 109.5 . . ?
H11A C119 H11B 109.5 . . ?
C114 C119 H11C 109.5 . . ?
H11A C119 H11C 109.5 . . ?
H11B C119 H11C 109.5 . . ?
C115 C120 H12G 109.5 . . ?
C115 C120 H12H 109.5 . . ?
H12G C120 H12H 109.5 . . ?
C115 C120 H12I 109.5 . . ?
H12G C120 H12I 109.5 . . ?
H12H C120 H12I 109.5 . . ?
C116 C121 H12D 109.5 . . ?
C116 C121 H12E 109.5 . . ?
H12D C121 H12E 109.5 . . ?
C116 C121 H12F 109.5 . . ?
H12D C121 H12F 109.5 . . ?
H12E C121 H12F 109.5 . . ?
C117 C122 H12A 109.5 . . ?
C117 C122 H12B 109.5 . . ?
H12A C122 H12B 109.5 . . ?
C117 C122 H12C 109.5 . . ?
H12A C122 H12C 109.5 . . ?
H12B C122 H12C 109.5 . . ?
C127 C123 C124 110.3(16) . . ?
C127 C123 C128 126.5(14) . . ?
C124 C123 C128 121.9(14) . . ?
C127 C123 Rh11 73.4(17) . . ?
C124 C123 Rh11 72.9(16) . . ?
C128 C123 Rh11 130.9(19) . . ?
C125 C124 C123 104.5(15) . . ?
C125 C124 C129 129.3(14) . . ?
C123 C124 C129 126.1(14) . . ?
C125 C124 Rh11 74.5(16) . . ?
C123 C124 Rh11 68.6(16) . . ?
C129 C124 Rh11 123.7(19) . . ?
C124 C125 C126 110.5(16) . . ?
C124 C125 C130 126.3(14) . . ?
C126 C125 C130 122.2(14) . . ?
C124 C125 Rh11 68.7(15) . . ?
C126 C125 Rh11 69.5(15) . . ?
C130 C125 Rh11 119.9(19) . . ?
C127 C126 C125 106.3(16) . . ?
C127 C126 C131 128.8(15) . . ?
C125 C126 C131 124.1(14) . . ?
C127 C126 Rh11 70.7(15) . . ?
C125 C126 Rh11 73.4(15) . . ?
C131 C126 Rh11 113.4(19) . . ?
C123 C127 C126 107.9(16) . . ?
C123 C127 C132 126.1(14) . . ?
C126 C127 C132 126.0(14) . . ?
C123 C127 Rh11 68.8(16) . . ?
C126 C127 Rh11 72.2(15) . . ?
C132 C127 Rh11 126(2) . . ?
C123 C128 H12J 109.5 . . ?
C123 C128 H12K 109.5 . . ?
H12J C128 H12K 109.5 . . ?
C123 C128 H12L 109.5 . . ?
H12J C128 H12L 109.5 . . ?
H12K C128 H12L 109.5 . . ?
C124 C129 H12M 109.5 . . ?
C124 C129 H12N 109.5 . . ?
H12M C129 H12N 109.5 . . ?
C124 C129 H12O 109.5 . . ?
H12M C129 H12O 109.5 . . ?
H12N C129 H12O 109.5 . . ?
C125 C130 H13A 109.5 . . ?
C125 C130 H13B 109.5 . . ?
H13A C130 H13B 109.5 . . ?
C125 C130 H13C 109.5 . . ?
H13A C130 H13C 109.5 . . ?
H13B C130 H13C 109.5 . . ?
C126 C131 H13D 109.5 . . ?
C126 C131 H13E 109.5 . . ?
H13D C131 H13E 109.5 . . ?
C126 C131 H13F 109.5 . . ?
H13D C131 H13F 109.5 . . ?
H13E C131 H13F 109.5 . . ?
C127 C132 H13G 109.5 . . ?
C127 C132 H13H 109.5 . . ?
H13G C132 H13H 109.5 . . ?
C127 C132 H13I 109.5 . . ?
H13G C132 H13I 109.5 . . ?
H13H C132 H13I 109.5 . . ?
C137 C133 C134 103.1(19) . . ?
C137 C133 C138 126.7(16) . . ?
C134 C133 C138 128.3(17) . . ?
C137 C133 Rh10 76.2(13) . . ?
C134 C133 Rh10 71.5(13) . . ?
C138 C133 Rh10 128.5(15) . . ?
C133 C134 C135 109.5(19) . . ?
C133 C134 C139 130.6(16) . . ?
C135 C134 C139 119.9(15) . . ?
C133 C134 Rh10 67.5(13) . . ?
C135 C134 Rh10 80.0(13) . . ?
C139 C134 Rh10 121.0(14) . . ?
C136 C135 C134 109(2) . . ?
C136 C135 C140 128.4(17) . . ?
C134 C135 C140 121.6(15) . . ?
C136 C135 Rh10 70.1(12) . . ?
C134 C135 Rh10 62.2(12) . . ?
C140 C135 Rh10 125.7(15) . . ?
C135 C136 C137 104(2) . . ?
C135 C136 C141 131.4(17) . . ?
C137 C136 C141 123.2(16) . . ?
C135 C136 Rh10 74.1(13) . . ?
C137 C136 Rh10 68.2(12) . . ?
C141 C136 Rh10 131.7(15) . . ?
C133 C137 C136 113(2) . . ?
C133 C137 C142 127.0(16) . . ?
C136 C137 C142 119.6(16) . . ?
C133 C137 Rh10 64.2(12) . . ?
C136 C137 Rh10 74.1(13) . . ?
C142 C137 Rh10 121.9(14) . . ?
C133 C138 H13M 109.5 . . ?
C133 C138 H13N 109.5 . . ?
H13M C138 H13N 109.5 . . ?
C133 C138 H13O 109.5 . . ?
H13M C138 H13O 109.5 . . ?
H13N C138 H13O 109.5 . . ?
C134 C139 H13J 109.5 . . ?
C134 C139 H13K 109.5 . . ?
H13J C139 H13K 109.5 . . ?
C134 C139 H13L 109.5 . . ?
H13J C139 H13L 109.5 . . ?
H13K C139 H13L 109.5 . . ?
C135 C140 H14A 109.5 . . ?
C135 C140 H14B 109.5 . . ?
H14A C140 H14B 109.5 . . ?
C135 C140 H14C 109.5 . . ?
H14A C140 H14C 109.5 . . ?
H14B C140 H14C 109.5 . . ?
C136 C141 H14D 109.5 . . ?
C136 C141 H14E 109.5 . . ?
H14D C141 H14E 109.5 . . ?
C136 C141 H14F 109.5 . . ?
H14D C141 H14F 109.5 . . ?
H14E C141 H14F 109.5 . . ?
C137 C142 H14G 109.5 . . ?
C137 C142 H14H 109.5 . . ?
H14G C142 H14H 109.5 . . ?
C137 C142 H14I 109.5 . . ?
H14G C142 H14I 109.5 . . ?
H14H C142 H14I 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 8(3) . . . . ?
Rh12 N1 C1 C2 175.6(18) . . . . ?
N1 C1 C2 C3 -1(3) . . . . ?
C1 C2 C3 C4 -5(4) . . . . ?
C1 C2 C3 C6 -174(2) . . . . ?
C2 C3 C4 C5 4(4) . . . . ?
C6 C3 C4 C5 175(2) . . . . ?
C1 N1 C5 C4 -8(4) . . . . ?
Rh12 N1 C5 C4 -175.3(17) . . . . ?
C3 C4 C5 N1 2(4) . . . . ?
C6 C7 C8 C9 17(15) . . . . ?
C6 C7 C8 C13 -163(13) . . . . ?
C13 C8 C9 C10 5(3) . . . . ?
C7 C8 C9 C10 -175(2) . . . . ?
C8 C9 C10 C11 -9(3) . . . . ?
C8 C9 C10 C21 -176(2) . . . . ?
C9 C10 C11 C12 13(3) . . . . ?
C21 C10 C11 C12 -179.5(19) . . . . ?
C10 C11 C12 C13 -13(3) . . . . ?
C10 C11 C12 C14 179.1(19) . . . . ?
C11 C12 C13 C8 9(3) . . . . ?
C14 C12 C13 C8 175.4(19) . . . . ?
C9 C8 C13 C12 -5(3) . . . . ?
C7 C8 C13 C12 175(2) . . . . ?
C14 C15 C16 C17 139(10) . . . . ?
C14 C15 C16 C20 -41(11) . . . . ?
C15 C16 C17 C18 178.5(16) . . . . ?
C20 C16 C17 C18 -2(2) . . . . ?
C19 N3 C18 C17 4(2) . . . . ?
Rh7 N3 C18 C17 -169.0(11) . . . . ?
C16 C17 C18 N3 -3(2) . . . . ?
C18 N3 C19 C20 -1(2) . . . . ?
Rh7 N3 C19 C20 172.6(12) . . . . ?
N3 C19 C20 C16 -4(2) . . . . ?
C15 C16 C20 C19 -175.0(17) . . . . ?
C17 C16 C20 C19 6(2) . . . . ?
C26 C23 C24 C25 0(3) . . . . ?
C22 C23 C24 C25 179.1(19) . . . . ?
C23 C24 C25 N5 0(3) . . . . ?
C27 N5 C25 C24 -2(3) . . . . ?
Rh9 N5 C25 C24 174.7(15) . . . . ?
C24 C23 C26 C27 3(3) . . . . ?
C22 C23 C26 C27 -176.2(19) . . . . ?
C25 N5 C27 C26 5(3) . . . . ?
Rh9 N5 C27 C26 -171.5(15) . . . . ?
C23 C26 C27 N5 -6(3) . . . . ?
C30 N2 C28 C29 13(3) . . . . ?
Rh11 N2 C28 C29 -179.7(17) . . . . ?
N2 C28 C29 C32 -10(4) . . . . ?
C28 N2 C30 C31 -14(4) . . . . ?
Rh11 N2 C30 C31 178(2) . . . . ?
N2 C30 C31 C32 11(4) . . . . ?
C30 C31 C32 C29 -7(4) . . . . ?
C30 C31 C32 C33 177(2) . . . . ?
C28 C29 C32 C31 8(4) . . . . ?
C28 C29 C32 C33 -176(2) . . . . ?
C33 C34 C35 C40 46(12) . . . . ?
C33 C34 C35 C36 -142(10) . . . . ?
C40 C35 C36 C37 -1(2) . . . . ?
C34 C35 C36 C37 -174(2) . . . . ?
C35 C36 C37 C38 2(2) . . . . ?
C35 C36 C37 C41 -174(2) . . . . ?
C36 C37 C38 C39 -1(3) . . . . ?
C41 C37 C38 C39 175(2) . . . . ?
C37 C38 C39 C48 173(2) . . . . ?
C37 C38 C39 C40 -1(4) . . . . ?
C36 C35 C40 C39 -1(3) . . . . ?
C34 C35 C40 C39 171(2) . . . . ?
C48 C39 C40 C35 -171(2) . . . . ?
C38 C39 C40 C35 2(4) . . . . ?
C36 C37 C41 C42 -110(14) . . . . ?
C38 C37 C41 C42 73(15) . . . . ?
C46 C43 C44 C45 4(3) . . . . ?
C42 C43 C44 C45 176.6(18) . . . . ?
C43 C44 C45 N4 0(3) . . . . ?
C47 N4 C45 C44 -2(3) . . . . ?
Rh8 N4 C45 C44 174.9(15) . . . . ?
C44 C43 C46 C47 -5(3) . . . . ?
C42 C43 C46 C47 -178.0(18) . . . . ?
C43 C46 C47 N4 3(3) . . . . ?
C45 N4 C47 C46 0(3) . . . . ?
Rh8 N4 C47 C46 -176.7(14) . . . . ?
C48 C49 C50 C51 18(12) . . . . ?
C48 C49 C50 C53 -157(10) . . . . ?
C53 C50 C51 C52 -10(4) . . . . ?
C49 C50 C51 C52 175(2) . . . . ?
C50 C51 C52 N7 9(3) . . . . ?
C54 N7 C52 C51 1(3) . . . . ?
Rh10 N7 C52 C51 172.1(17) . . . . ?
C51 C50 C53 C54 3(4) . . . . ?
C49 C50 C53 C54 178(2) . . . . ?
C52 N7 C54 C53 -9(3) . . . . ?
Rh10 N7 C54 C53 179.9(18) . . . . ?
C50 C53 C54 N7 7(4) . . . . ?
Rh10 O8 C55 C60 176.8(10) . . . . ?
Rh10 O8 C55 C56 -1.5(17) . . . . ?
Rh10 O7 C56 C57 -170.5(11) . . . . ?
Rh10 O7 C56 C55 7.5(17) . . . . ?
O8 C55 C56 O7 -4(2) . . . . ?
C60 C55 C56 O7 177.8(14) . . . . ?
O8 C55 C56 C57 173.9(14) . . . . ?
C60 C55 C56 C57 -4(2) . . . . ?
O7 C56 C57 C58 -176.9(14) . . . . ?
C55 C56 C57 C58 5(2) . . . . ?
O7 C56 C57 Cl1 -2(2) . . . . ?
C55 C56 C57 Cl1 -179.9(11) . . . . ?
Rh9 O5 C58 C57 -176.6(11) . . . . ?
Rh9 O5 C58 C59 3.1(16) . . . . ?
C56 C57 C58 O5 -179.4(13) . . . . ?
Cl1 C57 C58 O5 6(2) . . . . ?
C56 C57 C58 C59 1(2) . . . . ?
Cl1 C57 C58 C59 -174.1(10) . . . . ?
Rh9 O6 C59 C60 -172.9(10) . . . . ?
Rh9 O6 C59 C58 3.3(15) . . . . ?
O5 C58 C59 O6 -4.5(19) . . . . ?
C57 C58 C59 O6 175.3(13) . . . . ?
O5 C58 C59 C60 171.6(13) . . . . ?
C57 C58 C59 C60 -9(2) . . . . ?
O8 C55 C60 C59 178.8(13) . . . . ?
C56 C55 C60 C59 -3(2) . . . . ?
O8 C55 C60 Cl2 0(2) . . . . ?
C56 C55 C60 Cl2 178.2(11) . . . . ?
O6 C59 C60 C55 -174.6(12) . . . . ?
C58 C59 C60 C55 9(2) . . . . ?
O6 C59 C60 Cl2 4.2(19) . . . . ?
C58 C59 C60 Cl2 -171.8(11) . . . . ?
Rh12 O10 C61 C66 176.0(11) . . . . ?
Rh12 O10 C61 C62 2.3(16) . . . . ?
Rh12 O9 C62 C63 -167.6(9) . . . . ?
Rh12 O9 C62 C61 15.0(16) . . . . ?
O10 C61 C62 O9 -11.3(18) . . . . ?
C66 C61 C62 O9 176.0(17) . . . . ?
O10 C61 C62 C63 171.5(14) . . . . ?
C66 C61 C62 C63 -1(2) . . . . ?
O9 C62 C63 C64 -176.9(14) . . . . ?
C61 C62 C63 C64 0.3(16) . . . . ?
O9 C62 C63 Cl5 4.3(19) . . . . ?
C61 C62 C63 Cl5 -178.6(13) . . . . ?
C62 C63 C64 C65 2(2) . . . . ?
Cl5 C63 C64 C65 -178.6(14) . . . . ?
C62 C63 C64 O11 177.4(14) . . . . ?
Cl5 C63 C64 O11 -4(2) . . . . ?
Rh11 O11 C64 C63 -175.1(12) . . . . ?
Rh11 O11 C64 C65 0.3(18) . . . . ?
Rh11 O12 C65 C66 178.6(11) . . . . ?
Rh11 O12 C65 C64 -4(2) . . . . ?
C63 C64 C65 O12 177.5(16) . . . . ?
O11 C64 C65 O12 2(2) . . . . ?
C63 C64 C65 C66 -5(3) . . . . ?
O11 C64 C65 C66 179.7(16) . . . . ?
O10 C61 C66 C65 -173.1(14) . . . . ?
C62 C61 C66 C65 -1(2) . . . . ?
O10 C61 C66 Cl6 11(2) . . . . ?
C62 C61 C66 Cl6 -176.4(14) . . . . ?
O12 C65 C66 C61 -178.8(15) . . . . ?
C64 C65 C66 C61 4(2) . . . . ?
O12 C65 C66 Cl6 -3(2) . . . . ?
C64 C65 C66 Cl6 179.3(15) . . . . ?
Rh8 O4 C67 C72 -179.8(10) . . . . ?
Rh8 O4 C67 C68 0.6(14) . . . . ?
Rh8 O3 C68 C69 -172.5(9) . . . . ?
Rh8 O3 C68 C67 5.8(14) . . . . ?
O4 C67 C68 O3 -4.4(18) . . . . ?
C72 C67 C68 O3 176.0(12) . . . . ?
O4 C67 C68 C69 173.8(12) . . . . ?
C72 C67 C68 C69 -5.7(19) . . . . ?
O3 C68 C69 C70 -175.8(11) . . . . ?
C67 C68 C69 C70 6.0(19) . . . . ?
O3 C68 C69 Cl4 7.9(18) . . . . ?
C67 C68 C69 Cl4 -170.3(10) . . . . ?
Rh7 O1 C70 C69 178.8(9) . . . . ?
Rh7 O1 C70 C71 -0.5(13) . . . . ?
C68 C69 C70 O1 179.2(11) . . . . ?
Cl4 C69 C70 O1 -4.5(18) . . . . ?
C68 C69 C70 C71 -1.5(18) . . . . ?
Cl4 C69 C70 C71 174.8(10) . . . . ?
Rh7 O2 C71 C72 -173.4(10) . . . . ?
Rh7 O2 C71 C70 6.7(14) . . . . ?
O1 C70 C71 O2 -4.2(16) . . . . ?
C69 C70 C71 O2 176.5(11) . . . . ?
O1 C70 C71 C72 175.9(11) . . . . ?
C69 C70 C71 C72 -3.4(19) . . . . ?
O4 C67 C72 C71 -178.9(12) . . . . ?
C68 C67 C72 C71 0.7(19) . . . . ?
O4 C67 C72 Cl3 2.7(19) . . . . ?
C68 C67 C72 Cl3 -177.8(10) . . . . ?
O2 C71 C72 C67 -176.2(12) . . . . ?
C70 C71 C72 C67 3.7(19) . . . . ?
O2 C71 C72 Cl3 2.3(18) . . . . ?
C70 C71 C72 Cl3 -177.8(10) . . . . ?
C88 C83 C84 C85 176.3(14) . . . . ?
C87 C83 C84 C85 3.5(14) . . . . ?
Rh7 C83 C84 C85 -58.0(10) . . . . ?
C88 C83 C84 C89 -7(2) . . . . ?
C87 C83 C84 C89 179.8(13) . . . . ?
Rh7 C83 C84 C89 118.3(14) . . . . ?
C88 C83 C84 Rh7 -125.7(16) . . . . ?
C87 C83 C84 Rh7 61.5(8) . . . . ?
C83 C84 C85 C86 -2.1(15) . . . . ?
C89 C84 C85 C86 -178.3(13) . . . . ?
Rh7 C84 C85 C86 -61.5(9) . . . . ?
C83 C84 C85 C90 176.3(13) . . . . ?
C89 C84 C85 C90 0(2) . . . . ?
Rh7 C84 C85 C90 116.9(13) . . . . ?
C83 C84 C85 Rh7 59.4(10) . . . . ?
C89 C84 C85 Rh7 -116.7(14) . . . . ?
C84 C85 C86 C87 -0.6(15) . . . . ?
C90 C85 C86 C87 -178.9(14) . . . . ?
Rh7 C85 C86 C87 -62.3(10) . . . . ?
C84 C85 C86 C91 -177.6(12) . . . . ?
C90 C85 C86 C91 4(2) . . . . ?
Rh7 C85 C86 C91 120.7(13) . . . . ?
C84 C85 C86 Rh7 61.7(9) . . . . ?
C90 C85 C86 Rh7 -116.6(15) . . . . ?
C85 C86 C87 C92 -177.5(13) . . . . ?
C91 C86 C87 C92 -1(2) . . . . ?
Rh7 C86 C87 C92 121.7(14) . . . . ?
C85 C86 C87 C83 2.7(15) . . . . ?
C91 C86 C87 C83 179.5(13) . . . . ?
Rh7 C86 C87 C83 -58.1(9) . . . . ?
C85 C86 C87 Rh7 60.8(9) . . . . ?
C91 C86 C87 Rh7 -122.4(15) . . . . ?
C84 C83 C87 C86 -4.0(15) . . . . ?
C88 C83 C87 C86 -177.2(13) . . . . ?
Rh7 C83 C87 C86 59.2(10) . . . . ?
C84 C83 C87 C92 176.2(13) . . . . ?
C88 C83 C87 C92 3(2) . . . . ?
Rh7 C83 C87 C92 -120.6(13) . . . . ?
C84 C83 C87 Rh7 -63.2(9) . . . . ?
C88 C83 C87 Rh7 123.6(14) . . . . ?
C97 C93 C94 C95 -2.1(15) . . . . ?
C98 C93 C94 C95 -174.1(14) . . . . ?
Rh8 C93 C94 C95 -59.8(9) . . . . ?
C97 C93 C94 C99 173.4(14) . . . . ?
C98 C93 C94 C99 1(2) . . . . ?
Rh8 C93 C94 C99 115.8(15) . . . . ?
C97 C93 C94 Rh8 57.6(10) . . . . ?
C98 C93 C94 Rh8 -114.3(15) . . . . ?
C93 C94 C95 C96 -0.6(16) . . . . ?
C99 C94 C95 C96 -176.4(13) . . . . ?
Rh8 C94 C95 C96 -62.8(11) . . . . ?
C93 C94 C95 C100 -176.0(13) . . . . ?
C99 C94 C95 C100 8(2) . . . . ?
Rh8 C94 C95 C100 121.7(14) . . . . ?
C93 C94 C95 Rh8 62.2(10) . . . . ?
C99 C94 C95 Rh8 -113.6(13) . . . . ?
C94 C95 C96 C101 -176.7(15) . . . . ?
C100 C95 C96 C101 -2(3) . . . . ?
Rh8 C95 C96 C101 120.7(17) . . . . ?
C94 C95 C96 C97 2.9(16) . . . . ?
C100 C95 C96 C97 177.6(16) . . . . ?
Rh8 C95 C96 C97 -59.7(10) . . . . ?
C94 C95 C96 Rh8 62.6(10) . . . . ?
C100 C95 C96 Rh8 -122.7(18) . . . . ?
C98 C93 C97 C96 175.6(15) . . . . ?
C94 C93 C97 C96 4.1(17) . . . . ?
Rh8 C93 C97 C96 62.5(11) . . . . ?
C98 C93 C97 C102 -15(2) . . . . ?
C94 C93 C97 C102 173.4(13) . . . . ?
Rh8 C93 C97 C102 -128.1(15) . . . . ?
C98 C93 C97 Rh8 113.0(17) . . . . ?
C94 C93 C97 Rh8 -58.5(10) . . . . ?
C95 C96 C97 C93 -4.6(18) . . . . ?
C101 C96 C97 C93 175.0(14) . . . . ?
Rh8 C96 C97 C93 -65.9(12) . . . . ?
C95 C96 C97 C102 -173.5(14) . . . . ?
C101 C96 C97 C102 6(2) . . . . ?
Rh8 C96 C97 C102 125.3(15) . . . . ?
C95 C96 C97 Rh8 61.3(11) . . . . ?
C101 C96 C97 Rh8 -119.1(15) . . . . ?
C107 C103 C104 C105 -3.6(17) . . . . ?
C108 C103 C104 C105 176.3(14) . . . . ?
Rh9 C103 C104 C105 -62.9(10) . . . . ?
C107 C103 C104 C109 -177.0(16) . . . . ?
C108 C103 C104 C109 3(3) . . . . ?
Rh9 C103 C104 C109 123.7(17) . . . . ?
C107 C103 C104 Rh9 59.3(11) . . . . ?
C108 C103 C104 Rh9 -120.8(15) . . . . ?
C109 C104 C105 C106 176.6(16) . . . . ?
C103 C104 C105 C106 3.0(18) . . . . ?
Rh9 C104 C105 C106 -59.7(11) . . . . ?
C109 C104 C105 C110 -2(3) . . . . ?
C103 C104 C105 C110 -175.3(14) . . . . ?
Rh9 C104 C105 C110 121.9(15) . . . . ?
C109 C104 C105 Rh9 -123.6(17) . . . . ?
C103 C104 C105 Rh9 62.7(10) . . . . ?
C104 C105 C106 C107 -1.3(18) . . . . ?
C110 C105 C106 C107 176.9(15) . . . . ?
Rh9 C105 C106 C107 -60.0(10) . . . . ?
C104 C105 C106 C111 179.0(14) . . . . ?
C110 C105 C106 C111 -3(3) . . . . ?
Rh9 C105 C106 C111 120.3(16) . . . . ?
C104 C105 C106 Rh9 58.7(11) . . . . ?
C110 C105 C106 Rh9 -123.1(17) . . . . ?
C104 C103 C107 C106 2.9(17) . . . . ?
C108 C103 C107 C106 -177.0(16) . . . . ?
Rh9 C103 C107 C106 61.4(11) . . . . ?
C104 C103 C107 C112 -178.8(15) . . . . ?
C108 C103 C107 C112 1(3) . . . . ?
Rh9 C103 C107 C112 -120.3(16) . . . . ?
C104 C103 C107 Rh9 -58.5(11) . . . . ?
C108 C103 C107 Rh9 121.5(18) . . . . ?
C105 C106 C107 C103 -1.1(18) . . . . ?
C111 C106 C107 C103 178.7(14) . . . . ?
Rh9 C106 C107 C103 -62.7(11) . . . . ?
C105 C106 C107 C112 -179.5(14) . . . . ?
C111 C106 C107 C112 0(2) . . . . ?
Rh9 C106 C107 C112 118.9(15) . . . . ?
C105 C106 C107 Rh9 61.6(11) . . . . ?
C111 C106 C107 Rh9 -118.6(14) . . . . ?
C117 C113 C114 C115 -0.1(13) . . . . ?
C118 C113 C114 C115 -177.3(15) . . . . ?
Rh12 C113 C114 C115 -60.4(8) . . . . ?
C117 C113 C114 C119 168.8(19) . . . . ?
C118 C113 C114 C119 -8(2) . . . . ?
Rh12 C113 C114 C119 108.5(15) . . . . ?
C117 C113 C114 Rh12 60.3(12) . . . . ?
C118 C113 C114 Rh12 -116.9(15) . . . . ?
C119 C114 C115 C116 -164(2) . . . . ?
C113 C114 C115 C116 1.9(13) . . . . ?
Rh12 C114 C115 C116 -55.7(12) . . . . ?
C119 C114 C115 C120 16(3) . . . . ?
C113 C114 C115 C120 -177.2(17) . . . . ?
Rh12 C114 C115 C120 125.2(16) . . . . ?
C119 C114 C115 Rh12 -109(2) . . . . ?
C113 C114 C115 Rh12 57.6(7) . . . . ?
C114 C115 C116 C117 -3(2) . . . . ?
C120 C115 C116 C117 176.0(17) . . . . ?
Rh12 C115 C116 C117 -64.5(15) . . . . ?
C114 C115 C116 C121 -175.1(16) . . . . ?
C120 C115 C116 C121 4(3) . . . . ?
Rh12 C115 C116 C121 124(2) . . . . ?
C114 C115 C116 Rh12 61.3(10) . . . . ?
C120 C115 C116 Rh12 -119.5(15) . . . . ?
C115 C116 C117 C113 3(2) . . . . ?
C121 C116 C117 C113 173(2) . . . . ?
Rh12 C116 C117 C113 -63.0(14) . . . . ?
C115 C116 C117 C122 173.9(19) . . . . ?
C121 C116 C117 C122 -16(4) . . . . ?
Rh12 C116 C117 C122 108(2) . . . . ?
C115 C116 C117 Rh12 65.9(14) . . . . ?
C121 C116 C117 Rh12 -124(3) . . . . ?
C114 C113 C117 C116 -2(2) . . . . ?
C118 C113 C117 C116 175.1(18) . . . . ?
Rh12 C113 C117 C116 62.0(14) . . . . ?
C114 C113 C117 C122 -173.9(15) . . . . ?
C118 C113 C117 C122 3(3) . . . . ?
Rh12 C113 C117 C122 -110.1(19) . . . . ?
C114 C113 C117 Rh12 -63.8(10) . . . . ?
C118 C113 C117 Rh12 113.1(18) . . . . ?
C127 C123 C124 C125 -2(4) . . . . ?
C128 C123 C124 C125 165(3) . . . . ?
Rh11 C123 C124 C125 -67(2) . . . . ?
C127 C123 C124 C129 -179(3) . . . . ?
C128 C123 C124 C129 -11(5) . . . . ?
Rh11 C123 C124 C129 117(3) . . . . ?
C127 C123 C124 Rh11 64(2) . . . . ?
C128 C123 C124 Rh11 -128(3) . . . . ?
C123 C124 C125 C126 6(4) . . . . ?
C129 C124 C125 C126 -178(3) . . . . ?
Rh11 C124 C125 C126 -57(2) . . . . ?
C123 C124 C125 C130 175(3) . . . . ?
C129 C124 C125 C130 -9(5) . . . . ?
Rh11 C124 C125 C130 112(3) . . . . ?
C123 C124 C125 Rh11 62(2) . . . . ?
C129 C124 C125 Rh11 -121(3) . . . . ?
C124 C125 C126 C127 -7(4) . . . . ?
C130 C125 C126 C127 -177(3) . . . . ?
Rh11 C125 C126 C127 -63(2) . . . . ?
C124 C125 C126 C131 164(3) . . . . ?
C130 C125 C126 C131 -6(5) . . . . ?
Rh11 C125 C126 C131 107(3) . . . . ?
C124 C125 C126 Rh11 56(2) . . . . ?
C130 C125 C126 Rh11 -113(3) . . . . ?
C124 C123 C127 C126 -2(4) . . . . ?
C128 C123 C127 C126 -169(3) . . . . ?
Rh11 C123 C127 C126 62(2) . . . . ?
C124 C123 C127 C132 175(3) . . . . ?
C128 C123 C127 C132 9(5) . . . . ?
Rh11 C123 C127 C132 -120(3) . . . . ?
C124 C123 C127 Rh11 -64(2) . . . . ?
C128 C123 C127 Rh11 129(3) . . . . ?
C125 C126 C127 C123 5(4) . . . . ?
C131 C126 C127 C123 -165(3) . . . . ?
Rh11 C126 C127 C123 -60(2) . . . . ?
C125 C126 C127 C132 -172(3) . . . . ?
C131 C126 C127 C132 18(5) . . . . ?
Rh11 C126 C127 C132 123(3) . . . . ?
C125 C126 C127 Rh11 65(2) . . . . ?
C131 C126 C127 Rh11 -105(3) . . . . ?
C137 C133 C134 C135 1(2) . . . . ?
C138 C133 C134 C135 165(2) . . . . ?
Rh10 C133 C134 C135 -69.7(16) . . . . ?
C137 C133 C134 C139 -177(2) . . . . ?
C138 C133 C134 C139 -13(4) . . . . ?
Rh10 C133 C134 C139 112(2) . . . . ?
C137 C133 C134 Rh10 70.4(15) . . . . ?
C138 C133 C134 Rh10 -125(2) . . . . ?
C133 C134 C135 C136 8(3) . . . . ?
C139 C134 C135 C136 -173.9(19) . . . . ?
Rh10 C134 C135 C136 -53.8(17) . . . . ?
C133 C134 C135 C140 178.3(19) . . . . ?
C139 C134 C135 C140 -3(3) . . . . ?
Rh10 C134 C135 C140 116.7(19) . . . . ?
C133 C134 C135 Rh10 61.6(15) . . . . ?
C139 C134 C135 Rh10 -120.1(19) . . . . ?
C134 C135 C136 C137 -13(3) . . . . ?
C140 C135 C136 C137 178(2) . . . . ?
Rh10 C135 C136 C137 -62.0(15) . . . . ?
C134 C135 C136 C141 -179(2) . . . . ?
C140 C135 C136 C141 12(4) . . . . ?
Rh10 C135 C136 C141 132(3) . . . . ?
C134 C135 C136 Rh10 49.4(16) . . . . ?
C140 C135 C136 Rh10 -120(2) . . . . ?
C134 C133 C137 C136 -9(3) . . . . ?
C138 C133 C137 C136 -174(2) . . . . ?
Rh10 C133 C137 C136 57.9(17) . . . . ?
C134 C133 C137 C142 -179(2) . . . . ?
C138 C133 C137 C142 16(4) . . . . ?
Rh10 C133 C137 C142 -112(2) . . . . ?
C134 C133 C137 Rh10 -66.9(14) . . . . ?
C138 C133 C137 Rh10 128(2) . . . . ?
C135 C136 C137 C133 14(3) . . . . ?
C141 C136 C137 C133 -178.9(19) . . . . ?
Rh10 C136 C137 C133 -52.4(16) . . . . ?
C135 C136 C137 C142 -175.8(18) . . . . ?
C141 C136 C137 C142 -8(3) . . . . ?
Rh10 C136 C137 C142 118.0(19) . . . . ?
C135 C136 C137 Rh10 66.2(15) . . . . ?
C141 C136 C137 Rh10 -126(2) . . . . ?

_refine_diff_density_max         1.390
_refine_diff_density_min         -1.018
_refine_diff_density_rms         0.109




