# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 2064014'
loop_
_audit_author_name
_audit_author_address
'Ni Jun'
;Dalian University of Technology
China
;
_audit_update_record             
;
2021-02-20 deposited with the CCDC.	2021-07-21 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT220_a                   
;
PROBLEM: NonSolvent   Resd 1  C   Ueq(max)/Ueq(min) Range        6.4 Ratio
RESPONSE: This alert is due to the low quality of the crystal and the severely disorder  of the molecule
;
# Added during the CSD deposition process: Saturday 20 February 2021 06:43 AM
# end Validation Reply Form


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C46 H54 N2 Pt Si2'
_chemical_formula_weight         886.18

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'

_cell_length_a                   21.9102(16)
_cell_length_b                   15.4983(13)
_cell_length_c                   13.0730(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 103.155(4)
_cell_angle_gamma                90.00
_cell_volume                     4322.7(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    210(2)
_cell_measurement_reflns_used    4670
_cell_measurement_theta_min      3.05
_cell_measurement_theta_max      27.43

_exptl_crystal_description       needle
_exptl_crystal_colour            'dark brown'
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.362
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1800
_exptl_absorpt_coefficient_mu    3.333
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.733
_exptl_absorpt_correction_T_max  0.792
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
; 
############################################################################
PLAT220_ALERT_2_B NonSolvent  Resd 1 C  Ueq(max)/Ueq(min) Range   6.4 Ratio
############################################################################

Response
This alert is due to the low quality of the crystal and the severely disorder 
of the molecule.  
;

_diffrn_ambient_temperature      210(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Smart APEX II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            14648
_diffrn_reflns_av_R_equivalents  0.0391
_diffrn_reflns_av_sigmaI/netI    0.0663
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         2.43
_diffrn_reflns_theta_max         25.00
_reflns_number_total             7557
_reflns_number_gt                5425
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0633P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7557
_refine_ls_number_parameters     520
_refine_ls_number_restraints     326
_refine_ls_R_factor_all          0.0700
_refine_ls_R_factor_gt           0.0451
_refine_ls_wR_factor_ref         0.1175
_refine_ls_wR_factor_gt          0.1070
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_restrained_S_all      1.059
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Si2 Si 0.42336(18) 0.2205(3) 0.4483(4) 0.1435(15) Uani 1 1 d DU . .
Pt1 Pt 0.006244(12) 0.382275(18) 0.373094(14) 0.03937(12) Uani 1 1 d . . .
Si1 Si 0.27020(13) 0.8562(2) 0.4845(2) 0.0943(9) Uani 1 1 d DU . .
N2 N 0.0969(3) 0.3403(4) 0.3869(3) 0.0404(14) Uani 1 1 d . . .
C9 C 0.0291(4) 0.5772(6) 0.3823(4) 0.0432(18) Uani 1 1 d . . .
H9 H -0.0141 0.5826 0.3724 0.052 Uiso 1 1 calc R . .
C13 C 0.1173(3) 0.4907(5) 0.3972(4) 0.0416(18) Uani 1 1 d . . .
C27 C -0.0775(3) 0.4316(5) 0.3578(4) 0.0385(17) Uani 1 1 d . . .
N1 N 0.0535(3) 0.4974(4) 0.3832(3) 0.0419(15) Uani 1 1 d . . .
C15 C 0.2033(4) 0.3820(5) 0.4079(5) 0.0496(19) Uani 1 1 d . . .
H15 H 0.2333 0.4254 0.4162 0.060 Uiso 1 1 calc R . .
C28 C -0.1290(3) 0.4613(5) 0.3469(4) 0.0442(19) Uani 1 1 d . . .
C12 C 0.1552(4) 0.5635(6) 0.4083(4) 0.048(2) Uani 1 1 d . . .
H12 H 0.1982 0.5576 0.4158 0.057 Uiso 1 1 calc R . .
C18 C 0.1146(4) 0.2586(6) 0.3804(5) 0.057(2) Uani 1 1 d . . .
H18 H 0.0838 0.2161 0.3684 0.068 Uiso 1 1 calc R . .
C38 C -0.0477(4) 0.1917(6) 0.3729(5) 0.054(2) Uani 1 1 d . . .
C14 C 0.1417(3) 0.4030(5) 0.3977(4) 0.0424(19) Uani 1 1 d . . .
C39 C -0.0678(4) 0.1035(5) 0.3683(5) 0.051(2) Uani 1 1 d . . .
C37 C -0.0308(3) 0.2663(7) 0.3723(4) 0.053(2) Uani 1 1 d . . .
C29 C -0.1925(3) 0.4909(6) 0.3337(4) 0.049(2) Uani 1 1 d . . .
C11 C 0.1291(4) 0.6447(6) 0.4081(4) 0.0476(19) Uani 1 1 d . A .
C10 C 0.0648(4) 0.6509(6) 0.3952(4) 0.0457(18) Uani 1 1 d . . .
H10 H 0.0459 0.7046 0.3953 0.055 Uiso 1 1 calc R . .
C8 C 0.1706(4) 0.7197(7) 0.4263(5) 0.061(2) Uani 1 1 d . . .
C44 C -0.0766(4) 0.0601(6) 0.4552(5) 0.077(3) Uani 1 1 d . . .
H44 H -0.0706 0.0888 0.5192 0.092 Uiso 1 1 calc R . .
C16 C 0.2214(4) 0.2959(7) 0.4059(6) 0.066(2) Uani 1 1 d . . .
C7 C 0.2083(4) 0.7770(7) 0.4436(6) 0.072(3) Uani 1 1 d . A .
C17 C 0.1755(4) 0.2342(6) 0.3905(6) 0.065(2) Uani 1 1 d . . .
H17 H 0.1857 0.1762 0.3869 0.079 Uiso 1 1 calc R . .
C19 C 0.2876(4) 0.2735(6) 0.4163(7) 0.078(3) Uani 1 1 d . . .
C40 C -0.0758(6) 0.0567(6) 0.2782(6) 0.102(4) Uani 1 1 d . . .
H40 H -0.0675 0.0825 0.2185 0.122 Uiso 1 1 calc R . .
C41 C -0.0957(6) -0.0279(7) 0.2730(6) 0.112(4) Uani 1 1 d . . .
H41 H -0.1017 -0.0566 0.2091 0.134 Uiso 1 1 calc R . .
C20 C 0.3416(5) 0.2544(8) 0.4282(8) 0.098(3) Uani 1 1 d . . .
C24 C 0.4273(7) 0.1227(9) 0.3660(13) 0.183(5) Uani 1 1 d DU . .
H24A H 0.3986 0.0799 0.3822 0.219 Uiso 1 1 calc R . .
H24B H 0.4123 0.1386 0.2929 0.219 Uiso 1 1 calc R . .
C21 C 0.4206(8) 0.1479(11) 0.6395(13) 0.177(5) Uani 1 1 d DU . .
H21A H 0.3837 0.1752 0.6519 0.266 Uiso 1 1 calc R . .
H21B H 0.4461 0.1279 0.7049 0.266 Uiso 1 1 calc R . .
H21C H 0.4087 0.0998 0.5929 0.266 Uiso 1 1 calc R . .
C22 C 0.4575(7) 0.2122(11) 0.5900(8) 0.179(5) Uani 1 1 d DU . .
H22A H 0.5008 0.1936 0.6014 0.215 Uiso 1 1 calc R . .
H22B H 0.4568 0.2682 0.6226 0.215 Uiso 1 1 calc R . .
C23 C 0.4913(7) 0.0802(14) 0.3782(13) 0.203(6) Uani 1 1 d DU . .
H23A H 0.5141 0.0844 0.4500 0.305 Uiso 1 1 calc R . .
H23B H 0.5143 0.1089 0.3337 0.305 Uiso 1 1 calc R . .
H23C H 0.4859 0.0206 0.3584 0.305 Uiso 1 1 calc R . .
C42 C -0.1067(4) -0.0703(6) 0.3558(5) 0.066(2) Uani 1 1 d . . .
C30 C -0.2084(4) 0.5774(7) 0.3235(6) 0.079(3) Uani 1 1 d DU . .
H30 H -0.1778 0.6192 0.3241 0.095 Uiso 1 1 calc R . .
C45 C -0.1293(5) -0.1640(7) 0.3503(7) 0.086(3) Uani 1 1 d . . .
H45A H -0.1482 -0.1763 0.4089 0.103 Uiso 1 1 calc R . .
H45B H -0.1605 -0.1736 0.2856 0.103 Uiso 1 1 calc R . .
C46 C -0.0735(5) -0.2220(8) 0.3545(8) 0.107(4) Uani 1 1 d . . .
H46A H -0.0484 -0.1994 0.3092 0.160 Uiso 1 1 calc R . .
H46B H -0.0877 -0.2789 0.3316 0.160 Uiso 1 1 calc R . .
H46C H -0.0488 -0.2246 0.4252 0.160 Uiso 1 1 calc R . .
C31 C -0.2715(5) 0.6010(8) 0.3122(8) 0.098(3) Uani 1 1 d DU . .
H31 H -0.2811 0.6595 0.3070 0.117 Uiso 1 1 calc R . .
C32 C -0.3187(6) 0.5453(11) 0.3085(10) 0.122(3) Uani 1 1 d DU . .
C33 C -0.3019(4) 0.4598(10) 0.3192(8) 0.110(4) Uani 1 1 d . . .
H33 H -0.3334 0.4193 0.3178 0.133 Uiso 1 1 calc R . .
C34 C -0.2409(4) 0.4303(7) 0.3320(6) 0.078(3) Uani 1 1 d . . .
H34 H -0.2320 0.3716 0.3394 0.093 Uiso 1 1 calc R . .
C43 C -0.0943(5) -0.0249(6) 0.4493(5) 0.082(3) Uani 1 1 d . . .
H43 H -0.0981 -0.0531 0.5104 0.098 Uiso 1 1 calc R . .
C25 C 0.4616(11) 0.3810(13) 0.4104(18) 0.242(7) Uani 1 1 d DU . .
H25A H 0.4191 0.4014 0.3953 0.363 Uiso 1 1 calc R . .
H25B H 0.4867 0.4189 0.3790 0.363 Uiso 1 1 calc R . .
H25C H 0.4778 0.3796 0.4851 0.363 Uiso 1 1 calc R . .
C26 C 0.4633(10) 0.2914(12) 0.3663(15) 0.239(6) Uani 1 1 d DU . .
H26A H 0.5062 0.2729 0.3718 0.287 Uiso 1 1 calc R . .
H26B H 0.4412 0.2896 0.2931 0.287 Uiso 1 1 calc R . .
C6 C 0.2704(13) 0.9327(14) 0.3753(15) 0.142(5) Uani 0.522(7) 1 d PDU A 1
H6A H 0.2284 0.9520 0.3421 0.170 Uiso 0.522(7) 1 calc PR A 1
H6B H 0.2970 0.9823 0.3984 0.170 Uiso 0.522(7) 1 calc PR A 1
C5 C 0.2966(15) 0.8764(17) 0.306(2) 0.151(6) Uani 0.522(7) 1 d PDU A 1
H5A H 0.2997 0.9077 0.2444 0.227 Uiso 0.522(7) 1 calc PR A 1
H5B H 0.2697 0.8274 0.2869 0.227 Uiso 0.522(7) 1 calc PR A 1
H5C H 0.3375 0.8573 0.3426 0.227 Uiso 0.522(7) 1 calc PR A 1
C4 C 0.3417(9) 0.7891(15) 0.5348(18) 0.147(7) Uani 0.522(7) 1 d PDU A 1
H4A H 0.3780 0.8267 0.5442 0.176 Uiso 0.522(7) 1 calc PR A 1
H4B H 0.3398 0.7676 0.6036 0.176 Uiso 0.522(7) 1 calc PR A 1
C3 C 0.3530(13) 0.7112(16) 0.467(2) 0.156(7) Uani 0.522(7) 1 d PDU A 1
H3A H 0.3908 0.6821 0.5012 0.234 Uiso 0.522(7) 1 calc PR A 1
H3B H 0.3567 0.7312 0.3993 0.234 Uiso 0.522(7) 1 calc PRD A 1
H3C H 0.3183 0.6719 0.4589 0.234 Uiso 0.522(7) 1 calc PR A 1
C2 C 0.2541(11) 0.9233(13) 0.5927(13) 0.124(4) Uani 0.522(7) 1 d PDU A 1
H2A H 0.2916 0.9564 0.6216 0.149 Uiso 0.522(7) 1 calc PR A 1
H2B H 0.2216 0.9643 0.5621 0.149 Uiso 0.522(7) 1 calc PR A 1
C1 C 0.2346(16) 0.881(2) 0.681(2) 0.125(6) Uani 0.522(7) 1 d PDU A 1
H1A H 0.2279 0.9235 0.7308 0.188 Uiso 0.522(7) 1 calc PR A 1
H1B H 0.2668 0.8415 0.7155 0.188 Uiso 0.522(7) 1 calc PR A 1
H1C H 0.1964 0.8493 0.6555 0.188 Uiso 0.522(7) 1 calc PR A 1
C6' C 0.2370(12) 0.9679(9) 0.460(2) 0.141(5) Uani 0.478(7) 1 d PDU A 2
H6'A H 0.2266 0.9788 0.3854 0.169 Uiso 0.478(7) 1 calc PR A 2
H6'B H 0.1985 0.9710 0.4850 0.169 Uiso 0.478(7) 1 calc PR A 2
C5' C 0.2819(13) 1.0389(17) 0.515(2) 0.151(7) Uani 0.478(7) 1 d PDU A 2
H5'A H 0.2623 1.0943 0.4994 0.226 Uiso 0.478(7) 1 calc PR A 2
H5'B H 0.3198 1.0371 0.4902 0.226 Uiso 0.478(7) 1 calc PR A 2
H5'C H 0.2915 1.0296 0.5896 0.226 Uiso 0.478(7) 1 calc PR A 2
C4' C 0.3278(12) 0.8286(15) 0.405(2) 0.149(6) Uani 0.478(7) 1 d PDU A 2
H4'A H 0.3653 0.8025 0.4481 0.179 Uiso 0.478(7) 1 calc PR A 2
H4'B H 0.3099 0.7906 0.3475 0.179 Uiso 0.478(7) 1 calc PR A 2
C3' C 0.3408(13) 0.9193(18) 0.367(2) 0.159(6) Uani 0.478(7) 1 d PDU A 2
H3'A H 0.3723 0.9155 0.3268 0.239 Uiso 0.478(7) 1 calc PR A 2
H3'B H 0.3554 0.9563 0.4265 0.239 Uiso 0.478(7) 1 calc PR A 2
H3'C H 0.3030 0.9425 0.3241 0.239 Uiso 0.478(7) 1 calc PR A 2
C2' C 0.3015(10) 0.8394(17) 0.6274(8) 0.110(4) Uani 0.478(7) 1 d PDU A 2
H2'A H 0.3155 0.7801 0.6394 0.132 Uiso 0.478(7) 1 calc PR A 2
H2'B H 0.3375 0.8766 0.6513 0.132 Uiso 0.478(7) 1 calc PR A 2
C1' C 0.2540(15) 0.858(2) 0.690(3) 0.117(6) Uani 0.478(7) 1 d PDU A 2
H1'A H 0.2724 0.8486 0.7636 0.176 Uiso 0.478(7) 1 calc PR A 2
H1'B H 0.2188 0.8198 0.6687 0.176 Uiso 0.478(7) 1 calc PR A 2
H1'C H 0.2403 0.9165 0.6796 0.176 Uiso 0.478(7) 1 calc PR A 2
C35 C -0.3865(6) 0.5686(11) 0.3161(11) 0.164(4) Uani 1 1 d DU . .
H35A H -0.4103 0.5178 0.3260 0.197 Uiso 1 1 calc R . .
H35B H -0.3868 0.6095 0.3722 0.197 Uiso 1 1 calc R . .
C36 C -0.4107(10) 0.6086(12) 0.2095(13) 0.229(7) Uani 1 1 d DU . .
H36A H -0.3779 0.6094 0.1718 0.343 Uiso 1 1 calc R . .
H36B H -0.4243 0.6665 0.2177 0.343 Uiso 1 1 calc R . .
H36C H -0.4453 0.5753 0.1710 0.343 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si2 C20 1.827(10) . ?
Si2 C22 1.837(9) . ?
Si2 C24 1.873(9) . ?
Si2 C26 1.883(10) . ?
Pt1 C27 1.955(8) . ?
Pt1 C37 1.972(10) . ?
Pt1 N1 2.052(6) . ?
Pt1 N2 2.059(5) . ?
Pt1 Pt1 3.1674(4) 2 ?
Si1 C7 1.817(11) . ?
Si1 C4' 1.853(10) . ?
Si1 C2 1.853(10) . ?
Si1 C2' 1.856(10) . ?
Si1 C6 1.856(10) . ?
Si1 C4 1.870(10) . ?
Si1 C6' 1.876(10) . ?
N2 C18 1.332(10) . ?
N2 C14 1.366(9) . ?
C9 N1 1.346(9) . ?
C9 C10 1.372(11) . ?
C9 H9 0.9300 . ?
C13 N1 1.371(8) . ?
C13 C12 1.389(10) . ?
C13 C14 1.459(10) . ?
C27 C28 1.198(9) . ?
C15 C14 1.365(10) . ?
C15 C16 1.394(11) . ?
C15 H15 0.9300 . ?
C28 C29 1.436(10) . ?
C12 C11 1.382(11) . ?
C12 H12 0.9300 . ?
C18 C17 1.365(10) . ?
C18 H18 0.9300 . ?
C38 C37 1.214(11) . ?
C38 C39 1.434(11) . ?
C39 C40 1.360(10) . ?
C39 C44 1.371(10) . ?
C29 C30 1.384(12) . ?
C29 C34 1.413(12) . ?
C11 C10 1.385(10) . ?
C11 C8 1.461(12) . ?
C10 H10 0.9300 . ?
C8 C7 1.199(11) . ?
C44 C43 1.370(11) . ?
C44 H44 0.9300 . ?
C16 C17 1.370(12) . ?
C16 C19 1.466(12) . ?
C17 H17 0.9300 . ?
C19 C20 1.196(12) . ?
C40 C41 1.379(12) . ?
C40 H40 0.9300 . ?
C41 C42 1.333(11) . ?
C41 H41 0.9300 . ?
C24 C23 1.523(9) . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C21 C22 1.518(9) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C42 C43 1.383(10) . ?
C42 C45 1.531(13) . ?
C30 C31 1.405(8) . ?
C30 H30 0.9300 . ?
C45 C46 1.509(13) . ?
C45 H45A 0.9700 . ?
C45 H45B 0.9700 . ?
C46 H46A 0.9600 . ?
C46 H46B 0.9600 . ?
C46 H46C 0.9600 . ?
C31 C32 1.340(16) . ?
C31 H31 0.9300 . ?
C32 C33 1.374(16) . ?
C32 C35 1.553(9) . ?
C33 C34 1.387(13) . ?
C33 H33 0.9300 . ?
C34 H34 0.9300 . ?
C43 H43 0.9300 . ?
C25 C26 1.507(10) . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C6 C5 1.461(18) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C4 C3 1.550(18) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C2 C1 1.480(19) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C6' C5' 1.539(18) . ?
C6' H6'A 0.9700 . ?
C6' H6'B 0.9700 . ?
C5' H5'A 0.9600 . ?
C5' H5'B 0.9600 . ?
C5' H5'C 0.9600 . ?
C4' C3' 1.541(19) . ?
C4' H4'A 0.9700 . ?
C4' H4'B 0.9700 . ?
C3' H3'A 0.9600 . ?
C3' H3'B 0.9600 . ?
C3' H3'C 0.9600 . ?
C2' C1' 1.494(19) . ?
C2' H2'A 0.9700 . ?
C2' H2'B 0.9700 . ?
C1' H1'A 0.9600 . ?
C1' H1'B 0.9600 . ?
C1' H1'C 0.9600 . ?
C35 C36 1.507(10) . ?
C35 H35A 0.9700 . ?
C35 H35B 0.9700 . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C20 Si2 C22 109.0(7) . . ?
C20 Si2 C24 108.8(6) . . ?
C22 Si2 C24 117.4(8) . . ?
C20 Si2 C26 108.5(8) . . ?
C22 Si2 C26 118.6(9) . . ?
C24 Si2 C26 93.3(9) . . ?
C27 Pt1 C37 88.9(3) . . ?
C27 Pt1 N1 96.6(3) . . ?
C37 Pt1 N1 173.9(2) . . ?
C27 Pt1 N2 175.3(3) . . ?
C37 Pt1 N2 95.8(3) . . ?
N1 Pt1 N2 78.8(2) . . ?
C27 Pt1 Pt1 91.93(14) . 2 ?
C37 Pt1 Pt1 93.10(17) . 2 ?
N1 Pt1 Pt1 89.47(11) . 2 ?
N2 Pt1 Pt1 86.98(12) . 2 ?
C7 Si1 C4' 103.7(9) . . ?
C7 Si1 C2 110.1(8) . . ?
C4' Si1 C2 145.8(12) . . ?
C7 Si1 C2' 106.3(8) . . ?
C4' Si1 C2' 112.7(11) . . ?
C2 Si1 C2' 53.2(9) . . ?
C7 Si1 C6 109.7(9) . . ?
C4' Si1 C6 66.3(10) . . ?
C2 Si1 C6 105.3(10) . . ?
C2' Si1 C6 143.0(12) . . ?
C7 Si1 C4 103.7(9) . . ?
C4' Si1 C4 56.3(11) . . ?
C2 Si1 C4 109.5(10) . . ?
C2' Si1 C4 58.7(10) . . ?
C6 Si1 C4 118.5(11) . . ?
C7 Si1 C6' 109.8(9) . . ?
C4' Si1 C6' 114.0(11) . . ?
C2 Si1 C6' 58.5(10) . . ?
C2' Si1 C6' 109.8(10) . . ?
C6 Si1 C6' 49.5(10) . . ?
C4 Si1 C6' 146.5(11) . . ?
C18 N2 C14 118.1(6) . . ?
C18 N2 Pt1 125.6(6) . . ?
C14 N2 Pt1 116.1(5) . . ?
N1 C9 C10 123.4(7) . . ?
N1 C9 H9 118.3 . . ?
C10 C9 H9 118.3 . . ?
N1 C13 C12 121.3(7) . . ?
N1 C13 C14 115.6(7) . . ?
C12 C13 C14 123.1(7) . . ?
C28 C27 Pt1 179.1(5) . . ?
C9 N1 C13 117.5(7) . . ?
C9 N1 Pt1 127.2(5) . . ?
C13 N1 Pt1 115.3(5) . . ?
C14 C15 C16 120.5(8) . . ?
C14 C15 H15 119.8 . . ?
C16 C15 H15 119.8 . . ?
C27 C28 C29 176.0(9) . . ?
C11 C12 C13 120.2(7) . . ?
C11 C12 H12 119.9 . . ?
C13 C12 H12 119.9 . . ?
N2 C18 C17 123.3(8) . . ?
N2 C18 H18 118.3 . . ?
C17 C18 H18 118.3 . . ?
C37 C38 C39 177.2(7) . . ?
C15 C14 N2 120.7(7) . . ?
C15 C14 C13 125.2(7) . . ?
N2 C14 C13 114.1(6) . . ?
C40 C39 C44 116.2(8) . . ?
C40 C39 C38 121.5(7) . . ?
C44 C39 C38 122.2(6) . . ?
C38 C37 Pt1 173.6(7) . . ?
C30 C29 C34 118.1(8) . . ?
C30 C29 C28 122.4(8) . . ?
C34 C29 C28 119.5(8) . . ?
C12 C11 C10 118.2(7) . . ?
C12 C11 C8 118.8(7) . . ?
C10 C11 C8 122.9(8) . . ?
C9 C10 C11 119.5(8) . . ?
C9 C10 H10 120.2 . . ?
C11 C10 H10 120.2 . . ?
C7 C8 C11 175.1(10) . . ?
C43 C44 C39 121.1(7) . . ?
C43 C44 H44 119.5 . . ?
C39 C44 H44 119.5 . . ?
C17 C16 C15 117.9(8) . . ?
C17 C16 C19 121.7(9) . . ?
C15 C16 C19 120.3(9) . . ?
C8 C7 Si1 172.8(8) . . ?
C18 C17 C16 119.3(9) . . ?
C18 C17 H17 120.3 . . ?
C16 C17 H17 120.3 . . ?
C20 C19 C16 177.8(10) . . ?
C39 C40 C41 121.7(8) . . ?
C39 C40 H40 119.1 . . ?
C41 C40 H40 119.1 . . ?
C42 C41 C40 122.8(8) . . ?
C42 C41 H41 118.6 . . ?
C40 C41 H41 118.6 . . ?
C19 C20 Si2 177.5(11) . . ?
C23 C24 Si2 116.9(11) . . ?
C23 C24 H24A 108.1 . . ?
Si2 C24 H24A 108.1 . . ?
C23 C24 H24B 108.1 . . ?
Si2 C24 H24B 108.1 . . ?
H24A C24 H24B 107.3 . . ?
C22 C21 H21A 109.5 . . ?
C22 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C22 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C21 C22 Si2 110.0(10) . . ?
C21 C22 H22A 109.7 . . ?
Si2 C22 H22A 109.7 . . ?
C21 C22 H22B 109.7 . . ?
Si2 C22 H22B 109.7 . . ?
H22A C22 H22B 108.2 . . ?
C24 C23 H23A 109.5 . . ?
C24 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C24 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C41 C42 C43 115.6(9) . . ?
C41 C42 C45 123.1(7) . . ?
C43 C42 C45 121.3(7) . . ?
C29 C30 C31 118.8(10) . . ?
C29 C30 H30 120.6 . . ?
C31 C30 H30 120.6 . . ?
C46 C45 C42 108.2(9) . . ?
C46 C45 H45A 110.1 . . ?
C42 C45 H45A 110.1 . . ?
C46 C45 H45B 110.1 . . ?
C42 C45 H45B 110.1 . . ?
H45A C45 H45B 108.4 . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C32 C31 C30 124.8(12) . . ?
C32 C31 H31 117.6 . . ?
C30 C31 H31 117.6 . . ?
C31 C32 C33 115.5(11) . . ?
C31 C32 C35 126.2(14) . . ?
C33 C32 C35 117.1(13) . . ?
C32 C33 C34 124.0(12) . . ?
C32 C33 H33 118.0 . . ?
C34 C33 H33 118.0 . . ?
C33 C34 C29 118.8(11) . . ?
C33 C34 H34 120.6 . . ?
C29 C34 H34 120.6 . . ?
C44 C43 C42 122.3(7) . . ?
C44 C43 H43 118.8 . . ?
C42 C43 H43 118.8 . . ?
C26 C25 H25A 109.5 . . ?
C26 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C26 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C25 C26 Si2 105.3(13) . . ?
C25 C26 H26A 110.7 . . ?
Si2 C26 H26A 110.7 . . ?
C25 C26 H26B 110.7 . . ?
Si2 C26 H26B 110.7 . . ?
H26A C26 H26B 108.8 . . ?
C5 C6 Si1 99.4(15) . . ?
C5 C6 H6A 111.9 . . ?
Si1 C6 H6A 111.9 . . ?
C5 C6 H6B 111.9 . . ?
Si1 C6 H6B 111.9 . . ?
H6A C6 H6B 109.6 . . ?
C6 C5 H5A 109.5 . . ?
C6 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C6 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C3 C4 Si1 117.5(16) . . ?
C3 C4 H4A 107.9 . . ?
Si1 C4 H4A 107.9 . . ?
C3 C4 H4B 107.9 . . ?
Si1 C4 H4B 107.9 . . ?
H4A C4 H4B 107.2 . . ?
C4 C3 H3A 109.5 . . ?
C4 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C4 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C1 C2 Si1 119.1(18) . . ?
C1 C2 H2A 107.5 . . ?
Si1 C2 H2A 107.5 . . ?
C1 C2 H2B 107.5 . . ?
Si1 C2 H2B 107.5 . . ?
H2A C2 H2B 107.0 . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C5' C6' Si1 113.5(16) . . ?
C5' C6' H6'A 108.9 . . ?
Si1 C6' H6'A 108.9 . . ?
C5' C6' H6'B 108.9 . . ?
Si1 C6' H6'B 108.9 . . ?
H6'A C6' H6'B 107.7 . . ?
C6' C5' H5'A 109.5 . . ?
C6' C5' H5'B 109.5 . . ?
H5'A C5' H5'B 109.5 . . ?
C6' C5' H5'C 109.5 . . ?
H5'A C5' H5'C 109.5 . . ?
H5'B C5' H5'C 109.5 . . ?
C3' C4' Si1 99.9(10) . . ?
C3' C4' H4'A 111.8 . . ?
Si1 C4' H4'A 111.8 . . ?
C3' C4' H4'B 111.8 . . ?
Si1 C4' H4'B 111.8 . . ?
H4'A C4' H4'B 109.5 . . ?
C4' C3' H3'A 109.5 . . ?
C4' C3' H3'B 109.5 . . ?
H3'A C3' H3'B 109.5 . . ?
C4' C3' H3'C 109.5 . . ?
H3'A C3' H3'C 109.5 . . ?
H3'B C3' H3'C 109.5 . . ?
C1' C2' Si1 112.6(18) . . ?
C1' C2' H2'A 109.1 . . ?
Si1 C2' H2'A 109.1 . . ?
C1' C2' H2'B 109.1 . . ?
Si1 C2' H2'B 109.1 . . ?
H2'A C2' H2'B 107.8 . . ?
C2' C1' H1'A 109.5 . . ?
C2' C1' H1'B 109.5 . . ?
H1'A C1' H1'B 109.5 . . ?
C2' C1' H1'C 109.5 . . ?
H1'A C1' H1'C 109.5 . . ?
H1'B C1' H1'C 109.5 . . ?
C36 C35 C32 100.1(13) . . ?
C36 C35 H35A 111.7 . . ?
C32 C35 H35A 111.7 . . ?
C36 C35 H35B 111.7 . . ?
C32 C35 H35B 111.7 . . ?
H35A C35 H35B 109.5 . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.992
_refine_diff_density_max         1.128
_refine_diff_density_min         -0.836
_refine_diff_density_rms         0.121
