# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 2064016'
loop_
_audit_author_name
_audit_author_address
'Ni Jun'
;Dalian University of Technology
China
;
_audit_update_record             
;
2021-02-20 deposited with the CCDC.	2021-07-21 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT220_a                   
;
PROBLEM: NonSolvent   Resd 1  C   Ueq(max)/Ueq(min) Range        6.3 Ratio
RESPONSE: This alert is due to the low quality of the crystal and the severely disorder of the molecule
;
# Added during the CSD deposition process: Saturday 20 February 2021 06:47 AM
# end Validation Reply Form


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C42 H44 Cl2 N2 Pt Si2'
_chemical_formula_weight         898.96

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   42.451(4)
_cell_length_b                   14.8742(14)
_cell_length_c                   13.1745(12)
_cell_angle_alpha                90.00
_cell_angle_beta                 95.890(3)
_cell_angle_gamma                90.00
_cell_volume                     8274.8(13)
_cell_formula_units_Z            8
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9926
_cell_measurement_theta_min      2.43
_cell_measurement_theta_max      21.19

_exptl_crystal_description       needle
_exptl_crystal_colour            'dark brown'
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.443
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3600
_exptl_absorpt_coefficient_mu    3.609
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.628
_exptl_absorpt_correction_T_max  0.698
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
; 
############################################################################
PLAT220_ALERT_2_B NonSolvent  Resd 1 C  Ueq(max)/Ueq(min) Range   6.3 Ratio
############################################################################

Response
This alert is due to the low quality of the crystal and the severely disorder 
of the molecule.  
;

_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Smart APEX II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            71115
_diffrn_reflns_av_R_equivalents  0.1616
_diffrn_reflns_av_sigmaI/netI    0.0854
_diffrn_reflns_limit_h_min       -48
_diffrn_reflns_limit_h_max       50
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         2.43
_diffrn_reflns_theta_max         25.00
_reflns_number_total             7279
_reflns_number_gt                4854
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0633P)²+21.4594P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7279
_refine_ls_number_parameters     555
_refine_ls_number_restraints     408
_refine_ls_R_factor_all          0.0966
_refine_ls_R_factor_gt           0.0549
_refine_ls_wR_factor_ref         0.1453
_refine_ls_wR_factor_gt          0.1266
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_restrained_S_all      1.086
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.000509(8) 0.88044(2) 0.12884(2) 0.04083(14) Uani 1 1 d . . .
Si1 Si 0.21407(11) 0.7308(5) 0.2528(5) 0.152(2) Uani 1 1 d DU . .
N2 N 0.04692(18) 0.8377(5) 0.1568(5) 0.0449(18) Uani 1 1 d . . .
C14 C 0.0560(2) 0.9962(6) 0.1557(6) 0.039(2) Uani 1 1 d . . .
C12 C 0.1013(2) 0.8836(7) 0.1818(7) 0.056(3) Uani 1 1 d . . .
H12 H 0.1166 0.9305 0.1849 0.067 Uiso 1 1 calc R . .
C9 C 0.0569(2) 0.7542(7) 0.1700(7) 0.056(3) Uani 1 1 d . . .
H9 H 0.0415 0.7077 0.1677 0.067 Uiso 1 1 calc R . .
N1 N 0.02422(17) 1.0019(5) 0.1405(5) 0.0416(19) Uani 1 1 d . . .
C36 C -0.0682(2) 0.9614(6) 0.0894(7) 0.049(2) Uani 1 1 d . . .
C15 C 0.0748(2) 1.0719(7) 0.1621(6) 0.048(2) Uani 1 1 d . . .
H15 H 0.0972 1.0660 0.1731 0.058 Uiso 1 1 calc R . .
C28 C -0.0265(2) 0.6826(7) 0.1068(7) 0.048(2) Uani 1 1 d . A .
C27 C -0.0175(2) 0.7611(7) 0.1148(6) 0.047(2) Uani 1 1 d . . .
C42 C -0.1075(2) 1.0835(7) 0.0794(8) 0.061(3) Uani 1 1 d . . .
H42 H -0.0908 1.1260 0.0919 0.074 Uiso 1 1 calc R . .
C18 C 0.0109(2) 1.0844(6) 0.1298(6) 0.044(2) Uani 1 1 d . . .
H18 H -0.0115 1.0891 0.1178 0.053 Uiso 1 1 calc R . .
C37 C -0.1000(2) 0.9934(6) 0.0743(7) 0.044(2) Uani 1 1 d . . .
C13 C 0.0690(2) 0.9050(7) 0.1655(6) 0.047(2) Uani 1 1 d . . .
C11 C 0.1111(2) 0.7964(8) 0.1935(8) 0.065(3) Uani 1 1 d . . .
C8 C 0.1445(3) 0.7760(8) 0.2122(9) 0.080(4) Uani 1 1 d . . .
C38 C -0.1251(2) 0.9335(8) 0.0535(9) 0.075(3) Uani 1 1 d . . .
H38 H -0.1206 0.8712 0.0479 0.091 Uiso 1 1 calc R . .
C10 C 0.0886(3) 0.7305(8) 0.1872(8) 0.071(3) Uani 1 1 d . . .
H10 H 0.0946 0.6692 0.1945 0.085 Uiso 1 1 calc R . .
C7 C 0.1719(3) 0.7592(10) 0.2262(11) 0.098(4) Uani 1 1 d . . .
Cl2 Cl -0.20142(10) 1.0906(4) 0.0313(5) 0.178(2) Uani 1 1 d . . .
C17 C 0.0287(2) 1.1611(6) 0.1356(6) 0.042(2) Uani 1 1 d . . .
H17 H 0.0184 1.2177 0.1278 0.051 Uiso 1 1 calc R . .
C16 C 0.0610(2) 1.1583(7) 0.1524(7) 0.049(2) Uani 1 1 d . . .
C19 C 0.0821(3) 1.2352(7) 0.1544(8) 0.061(3) Uani 1 1 d . . .
C20 C 0.1019(3) 1.2897(9) 0.1573(10) 0.082(4) Uani 1 1 d . B .
C39 C -0.1562(3) 0.9614(11) 0.0406(11) 0.105(5) Uani 1 1 d . . .
H39 H -0.1731 0.9196 0.0280 0.126 Uiso 1 1 calc R . .
C40 C -0.1618(3) 1.0523(12) 0.0468(11) 0.096(4) Uani 1 1 d . . .
C35 C -0.0417(2) 0.9281(6) 0.1035(6) 0.042(2) Uani 1 1 d . . .
C29 C -0.0348(3) 0.5902(7) 0.1035(8) 0.061(2) Uani 1 1 d U . .
C30 C -0.0483(6) 0.5526(14) 0.0212(17) 0.061(3) Uani 0.512(10) 1 d PU A 1
H30A H -0.0547 0.5889 -0.0367 0.073 Uiso 0.512(10) 1 calc PR A 1
C31 C -0.0535(5) 0.4618(13) 0.0163(16) 0.061(3) Uani 0.512(10) 1 d PU A 1
H31A H -0.0616 0.4341 -0.0459 0.073 Uiso 0.512(10) 1 calc PR A 1
C32 C -0.0466(15) 0.4113(16) 0.104(5) 0.060(3) Uani 0.512(10) 1 d PDU A 1
C33 C -0.0327(6) 0.4494(13) 0.1939(17) 0.061(3) Uani 0.512(10) 1 d PU A 1
H33A H -0.0272 0.4136 0.2528 0.074 Uiso 0.512(10) 1 calc PR A 1
C34 C -0.0270(5) 0.5428(14) 0.1950(17) 0.063(3) Uani 0.512(10) 1 d PU A 1
H34A H -0.0184 0.5727 0.2552 0.076 Uiso 0.512(10) 1 calc PR A 1
Cl1 Cl -0.0543(6) 0.2973(15) 0.094(2) 0.117(8) Uani 0.512(10) 1 d PD A 1
C30' C -0.0294(6) 0.5314(14) 0.0149(17) 0.059(3) Uani 0.488(10) 1 d PU A 2
H30B H -0.0233 0.5585 -0.0454 0.071 Uiso 0.488(10) 1 calc PR A 2
C31' C -0.0332(6) 0.4369(14) 0.0175(17) 0.061(3) Uani 0.488(10) 1 d PU A 2
H31B H -0.0272 0.4011 -0.0370 0.074 Uiso 0.488(10) 1 calc PR A 2
C32' C -0.0452(15) 0.3977(14) 0.098(5) 0.060(3) Uani 0.488(10) 1 d PDU A 2
C33' C -0.0545(6) 0.4447(14) 0.1756(17) 0.059(3) Uani 0.488(10) 1 d PU A 2
H33B H -0.0645 0.4162 0.2284 0.071 Uiso 0.488(10) 1 calc PR A 2
C34' C -0.0489(6) 0.5419(14) 0.1762(17) 0.062(3) Uani 0.488(10) 1 d PU A 2
H34B H -0.0555 0.5749 0.2319 0.074 Uiso 0.488(10) 1 calc PR A 2
Cl1' Cl -0.0502(4) 0.2822(14) 0.0997(16) 0.060(3) Uani 0.488(10) 1 d PD A 2
Si2 Si 0.13533(12) 1.3677(4) 0.1528(5) 0.1347(18) Uani 1 1 d DU . .
C41 C -0.1382(3) 1.1135(9) 0.0668(11) 0.089(4) Uani 1 1 d . . .
H41 H -0.1428 1.1757 0.0720 0.107 Uiso 1 1 calc R . .
C21 C 0.1234(11) 1.372(3) -0.069(3) 0.169(7) Uani 0.544(9) 1 d PDU B 1
H21A H 0.1232 1.4122 -0.1275 0.254 Uiso 0.544(9) 1 calc PR B 1
H21B H 0.1024 1.3452 -0.0664 0.254 Uiso 0.544(9) 1 calc PR B 1
H21C H 0.1390 1.3242 -0.0744 0.254 Uiso 0.544(9) 1 calc PR B 1
C22 C 0.1324(9) 1.426(2) 0.0309(17) 0.169(6) Uani 0.544(9) 1 d PDU B 1
H22A H 0.1166 1.4748 0.0337 0.202 Uiso 0.544(9) 1 calc PR B 1
H22B H 0.1531 1.4554 0.0247 0.202 Uiso 0.544(9) 1 calc PR B 1
C23 C 0.1799(9) 1.196(2) 0.169(3) 0.193(8) Uani 0.544(9) 1 d PDU B 1
H23A H 0.2017 1.1882 0.1527 0.289 Uiso 0.544(9) 1 calc PR B 1
H23B H 0.1659 1.1551 0.1266 0.289 Uiso 0.544(9) 1 calc PR B 1
H23C H 0.1787 1.1818 0.2412 0.289 Uiso 0.544(9) 1 calc PR B 1
C24 C 0.1699(7) 1.288(2) 0.149(3) 0.189(7) Uani 0.544(9) 1 d PDU B 1
H24A H 0.1748 1.2958 0.0776 0.227 Uiso 0.544(9) 1 calc PR B 1
H24B H 0.1869 1.3216 0.1902 0.227 Uiso 0.544(9) 1 calc PR B 1
C25 C 0.1381(10) 1.399(2) 0.3640(10) 0.178(8) Uani 0.544(9) 1 d PDU B 1
H25A H 0.1415 1.4456 0.4168 0.267 Uiso 0.544(9) 1 calc PR B 1
H25B H 0.1539 1.3514 0.3778 0.267 Uiso 0.544(9) 1 calc PR B 1
H25C H 0.1168 1.3738 0.3643 0.267 Uiso 0.544(9) 1 calc PR B 1
C26 C 0.1415(9) 1.4389(19) 0.2644(17) 0.176(6) Uani 0.544(9) 1 d PDU B 1
H26A H 0.1630 1.4646 0.2665 0.211 Uiso 0.544(9) 1 calc PR B 1
H26B H 0.1264 1.4897 0.2547 0.211 Uiso 0.544(9) 1 calc PR B 1
C21' C 0.1305(12) 1.325(3) -0.066(3) 0.160(8) Uani 0.456(9) 1 d PDU B 2
H21D H 0.1434 1.3107 -0.1217 0.240 Uiso 0.456(9) 1 calc PR B 2
H21E H 0.1190 1.3810 -0.0816 0.240 Uiso 0.456(9) 1 calc PR B 2
H21F H 0.1154 1.2760 -0.0591 0.240 Uiso 0.456(9) 1 calc PR B 2
C22' C 0.1517(9) 1.335(3) 0.032(2) 0.161(6) Uani 0.456(9) 1 d PDU B 2
H22C H 0.1679 1.3803 0.0192 0.193 Uiso 0.456(9) 1 calc PR B 2
H22D H 0.1628 1.2772 0.0446 0.193 Uiso 0.456(9) 1 calc PR B 2
C24' C 0.1639(9) 1.347(3) 0.267(2) 0.181(6) Uani 0.456(9) 1 d PDU B 2
H24C H 0.1808 1.3933 0.2714 0.217 Uiso 0.456(9) 1 calc PR B 2
H24D H 0.1529 1.3513 0.3297 0.217 Uiso 0.456(9) 1 calc PR B 2
C23' C 0.1790(9) 1.252(3) 0.261(3) 0.200(7) Uani 0.456(9) 1 d PDU B 2
H23D H 0.1940 1.2420 0.3217 0.300 Uiso 0.456(9) 1 calc PR B 2
H23E H 0.1903 1.2485 0.1998 0.300 Uiso 0.456(9) 1 calc PR B 2
H23F H 0.1623 1.2064 0.2576 0.300 Uiso 0.456(9) 1 calc PR B 2
C25' C 0.1360(11) 1.574(3) 0.100(3) 0.183(9) Uani 0.456(9) 1 d PU B 2
H25D H 0.1241 1.6270 0.1182 0.275 Uiso 0.456(9) 1 calc PR B 2
H25E H 0.1348 1.5685 0.0258 0.275 Uiso 0.456(9) 1 calc PR B 2
H25F H 0.1582 1.5804 0.1281 0.275 Uiso 0.456(9) 1 calc PR B 2
C26' C 0.1216(10) 1.4875(16) 0.146(3) 0.178(8) Uani 0.456(9) 1 d PDU B 2
H26C H 0.0998 1.4844 0.1120 0.213 Uiso 0.456(9) 1 calc PR B 2
H26D H 0.1194 1.5038 0.2180 0.213 Uiso 0.456(9) 1 calc PR B 2
C2 C 0.2318(5) 0.6981(16) 0.1406(14) 0.218(7) Uani 1 1 d DU . .
H2A H 0.2392 0.7537 0.1092 0.262 Uiso 1 1 calc R . .
H2B H 0.2509 0.6623 0.1633 0.262 Uiso 1 1 calc R . .
C4 C 0.2170(6) 0.6421(14) 0.3545(17) 0.230(7) Uani 1 1 d DU . .
H4A H 0.2065 0.6644 0.4135 0.276 Uiso 1 1 calc R . .
H4B H 0.2053 0.5881 0.3278 0.276 Uiso 1 1 calc R . .
C6 C 0.2352(6) 0.8275(14) 0.3140(18) 0.247(7) Uani 1 1 d DU . .
H6A H 0.2321 0.8245 0.3873 0.296 Uiso 1 1 calc R . .
H6B H 0.2580 0.8169 0.3092 0.296 Uiso 1 1 calc R . .
C1 C 0.2137(5) 0.6475(16) 0.0605(18) 0.211(7) Uani 1 1 d DU . .
H1A H 0.2052 0.5931 0.0896 0.317 Uiso 1 1 calc R . .
H1B H 0.2275 0.6307 0.0083 0.317 Uiso 1 1 calc R . .
H1C H 0.1962 0.6846 0.0296 0.317 Uiso 1 1 calc R . .
C5 C 0.2293(6) 0.9139(16) 0.284(2) 0.246(8) Uani 1 1 d DU . .
H5A H 0.2335 0.9212 0.2130 0.369 Uiso 1 1 calc R . .
H5B H 0.2431 0.9544 0.3276 0.369 Uiso 1 1 calc R . .
H5C H 0.2071 0.9285 0.2911 0.369 Uiso 1 1 calc R . .
C3 C 0.2490(6) 0.6170(15) 0.389(2) 0.245(8) Uani 1 1 d DU . .
H3A H 0.2610 0.6084 0.3298 0.368 Uiso 1 1 calc R . .
H3B H 0.2490 0.5609 0.4279 0.368 Uiso 1 1 calc R . .
H3C H 0.2590 0.6647 0.4325 0.368 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C35 1.923(10) . ?
Pt1 C27 1.933(10) . ?
Pt1 N1 2.066(7) . ?
Pt1 N2 2.067(8) . ?
Pt1 Pt1 3.1973(7) 2 ?
Si1 C2 1.793(15) . ?
Si1 C6 1.836(16) . ?
Si1 C7 1.839(13) . ?
Si1 C4 1.876(15) . ?
N2 C9 1.317(12) . ?
N2 C13 1.369(12) . ?
C14 N1 1.348(10) . ?
C14 C15 1.378(12) . ?
C14 C13 1.466(12) . ?
C12 C11 1.367(13) . ?
C12 C13 1.400(12) . ?
C12 H12 0.9500 . ?
C9 C10 1.387(13) . ?
C9 H9 0.9500 . ?
N1 C18 1.353(11) . ?
C36 C35 1.228(12) . ?
C36 C37 1.424(13) . ?
C15 C16 1.413(13) . ?
C15 H15 0.9500 . ?
C28 C27 1.230(12) . ?
C28 C29 1.419(14) . ?
C42 C41 1.371(15) . ?
C42 C37 1.381(13) . ?
C42 H42 0.9500 . ?
C18 C17 1.367(13) . ?
C18 H18 0.9500 . ?
C37 C38 1.394(13) . ?
C11 C10 1.364(15) . ?
C11 C8 1.448(14) . ?
C8 C7 1.183(15) . ?
C38 C39 1.379(15) . ?
C38 H38 0.9500 . ?
C10 H10 0.9500 . ?
Cl2 C40 1.768(12) . ?
C17 C16 1.367(12) . ?
C17 H17 0.9500 . ?
C16 C19 1.451(14) . ?
C19 C20 1.167(14) . ?
C20 Si2 1.838(13) . ?
C39 C40 1.376(18) . ?
C39 H39 0.9500 . ?
C40 C41 1.361(18) . ?
C29 C30 1.30(2) . ?
C29 C34' 1.38(2) . ?
C29 C34 1.41(2) . ?
C29 C30' 1.49(2) . ?
C30 C31 1.37(3) . ?
C30 H30A 0.9500 . ?
C31 C32 1.38(6) . ?
C31 H31A 0.9500 . ?
C32 C33 1.39(6) . ?
C32 Cl1 1.729(10) . ?
C33 C34 1.41(3) . ?
C33 H33A 0.9500 . ?
C34 H34A 0.9500 . ?
C30' C31' 1.42(3) . ?
C30' H30B 0.9500 . ?
C31' C32' 1.35(6) . ?
C31' H31B 0.9500 . ?
C32' C33' 1.34(6) . ?
C32' Cl1' 1.732(10) . ?
C33' C34' 1.47(3) . ?
C33' H33B 0.9500 . ?
C34' H34B 0.9500 . ?
Si2 C26 1.809(18) . ?
Si2 C22 1.819(18) . ?
Si2 C24' 1.863(19) . ?
Si2 C22' 1.868(18) . ?
Si2 C26' 1.875(19) . ?
Si2 C24 1.890(18) . ?
C41 H41 0.9500 . ?
C21 C22 1.55(3) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 C24 1.45(3) . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 C26 1.46(2) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C21' C22' 1.50(3) . ?
C21' H21D 0.9800 . ?
C21' H21E 0.9800 . ?
C21' H21F 0.9800 . ?
C22' H22C 0.9900 . ?
C22' H22D 0.9900 . ?
C24' C23' 1.55(3) . ?
C24' H24C 0.9900 . ?
C24' H24D 0.9900 . ?
C23' H23D 0.9800 . ?
C23' H23E 0.9800 . ?
C23' H23F 0.9800 . ?
C25' C26' 1.57(5) . ?
C25' H25D 0.9800 . ?
C25' H25E 0.9800 . ?
C25' H25F 0.9800 . ?
C26' H26C 0.9900 . ?
C26' H26D 0.9900 . ?
C2 C1 1.45(2) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C4 C3 1.44(2) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C6 C5 1.36(2) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C35 Pt1 C27 88.3(4) . . ?
C35 Pt1 N1 97.4(3) . . ?
C27 Pt1 N1 173.9(3) . . ?
C35 Pt1 N2 176.3(3) . . ?
C27 Pt1 N2 95.4(3) . . ?
N1 Pt1 N2 78.9(3) . . ?
C35 Pt1 Pt1 93.8(3) . 2 ?
C27 Pt1 Pt1 92.9(2) . 2 ?
N1 Pt1 Pt1 88.96(18) . 2 ?
N2 Pt1 Pt1 86.13(19) . 2 ?
C2 Si1 C6 110.3(11) . . ?
C2 Si1 C7 112.9(9) . . ?
C6 Si1 C7 109.0(10) . . ?
C2 Si1 C4 113.3(11) . . ?
C6 Si1 C4 104.1(11) . . ?
C7 Si1 C4 106.7(10) . . ?
C9 N2 C13 118.0(8) . . ?
C9 N2 Pt1 126.9(7) . . ?
C13 N2 Pt1 115.0(6) . . ?
N1 C14 C15 121.6(8) . . ?
N1 C14 C13 115.7(8) . . ?
C15 C14 C13 122.7(8) . . ?
C11 C12 C13 121.0(10) . . ?
C11 C12 H12 119.5 . . ?
C13 C12 H12 119.5 . . ?
N2 C9 C10 123.7(10) . . ?
N2 C9 H9 118.2 . . ?
C10 C9 H9 118.2 . . ?
C14 N1 C18 118.3(8) . . ?
C14 N1 Pt1 115.5(6) . . ?
C18 N1 Pt1 126.1(6) . . ?
C35 C36 C37 175.6(10) . . ?
C14 C15 C16 120.3(8) . . ?
C14 C15 H15 119.8 . . ?
C16 C15 H15 119.8 . . ?
C27 C28 C29 175.3(10) . . ?
C28 C27 Pt1 174.9(8) . . ?
C41 C42 C37 122.0(11) . . ?
C41 C42 H42 119.0 . . ?
C37 C42 H42 119.0 . . ?
N1 C18 C17 121.8(8) . . ?
N1 C18 H18 119.1 . . ?
C17 C18 H18 119.1 . . ?
C42 C37 C38 117.0(9) . . ?
C42 C37 C36 122.4(9) . . ?
C38 C37 C36 120.6(9) . . ?
N2 C13 C12 119.9(9) . . ?
N2 C13 C14 114.9(8) . . ?
C12 C13 C14 125.2(9) . . ?
C10 C11 C12 118.1(10) . . ?
C10 C11 C8 121.9(11) . . ?
C12 C11 C8 120.0(11) . . ?
C7 C8 C11 179.2(14) . . ?
C39 C38 C37 122.4(12) . . ?
C39 C38 H38 118.8 . . ?
C37 C38 H38 118.8 . . ?
C11 C10 C9 119.3(11) . . ?
C11 C10 H10 120.4 . . ?
C9 C10 H10 120.4 . . ?
C8 C7 Si1 177.8(14) . . ?
C16 C17 C18 121.6(9) . . ?
C16 C17 H17 119.2 . . ?
C18 C17 H17 119.2 . . ?
C17 C16 C15 116.3(9) . . ?
C17 C16 C19 125.8(10) . . ?
C15 C16 C19 117.8(9) . . ?
C20 C19 C16 172.0(13) . . ?
C19 C20 Si2 173.9(11) . . ?
C40 C39 C38 117.2(12) . . ?
C40 C39 H39 121.4 . . ?
C38 C39 H39 121.4 . . ?
C41 C40 C39 122.8(12) . . ?
C41 C40 Cl2 118.7(12) . . ?
C39 C40 Cl2 118.5(12) . . ?
C36 C35 Pt1 177.6(8) . . ?
C30 C29 C34' 99.8(16) . . ?
C30 C29 C34 123.0(16) . . ?
C34' C29 C34 39.1(11) . . ?
C30 C29 C28 121.9(13) . . ?
C34' C29 C28 127.3(13) . . ?
C34 C29 C28 115.0(12) . . ?
C30 C29 C30' 35.6(11) . . ?
C34' C29 C30' 110.5(15) . . ?
C34 C29 C30' 109.7(15) . . ?
C28 C29 C30' 122.2(12) . . ?
C29 C30 C31 121(2) . . ?
C29 C30 H30A 119.4 . . ?
C31 C30 H30A 119.4 . . ?
C30 C31 C32 119(2) . . ?
C30 C31 H31A 120.7 . . ?
C32 C31 H31A 120.7 . . ?
C31 C32 C33 122(2) . . ?
C31 C32 Cl1 117(3) . . ?
C33 C32 Cl1 122(4) . . ?
C32 C33 C34 118(2) . . ?
C32 C33 H33A 121.1 . . ?
C34 C33 H33A 121.1 . . ?
C29 C34 C33 117.4(19) . . ?
C29 C34 H34A 121.3 . . ?
C33 C34 H34A 121.3 . . ?
C31' C30' C29 122.3(19) . . ?
C31' C30' H30B 118.8 . . ?
C29 C30' H30B 118.8 . . ?
C32' C31' C30' 120(2) . . ?
C32' C31' H31B 120.0 . . ?
C30' C31' H31B 120.0 . . ?
C33' C32' C31' 123(2) . . ?
C33' C32' Cl1' 117(3) . . ?
C31' C32' Cl1' 120(3) . . ?
C32' C33' C34' 117(2) . . ?
C32' C33' H33B 121.4 . . ?
C34' C33' H33B 121.4 . . ?
C29 C34' C33' 126.3(19) . . ?
C29 C34' H34B 116.9 . . ?
C33' C34' H34B 116.9 . . ?
C26 Si2 C22 115.4(13) . . ?
C26 Si2 C20 113.0(12) . . ?
C22 Si2 C20 110.3(12) . . ?
C26 Si2 C24' 53.9(13) . . ?
C22 Si2 C24' 140.7(18) . . ?
C20 Si2 C24' 108.1(16) . . ?
C26 Si2 C22' 144.2(17) . . ?
C22 Si2 C22' 50.8(14) . . ?
C20 Si2 C22' 102.6(14) . . ?
C24' Si2 C22' 112.4(15) . . ?
C26 Si2 C26' 59.9(14) . . ?
C22 Si2 C26' 60.8(14) . . ?
C20 Si2 C26' 111.4(14) . . ?
C24' Si2 C26' 111.6(15) . . ?
C22' Si2 C26' 110.4(15) . . ?
C26 Si2 C24 109.9(15) . . ?
C22 Si2 C24 105.0(14) . . ?
C20 Si2 C24 102.2(13) . . ?
C24' Si2 C24 58.3(14) . . ?
C22' Si2 C24 57.1(13) . . ?
C26' Si2 C24 146.3(18) . . ?
C40 C41 C42 118.6(12) . . ?
C40 C41 H41 120.7 . . ?
C42 C41 H41 120.7 . . ?
C22 C21 H21A 109.5 . . ?
C22 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C22 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C21 C22 Si2 119(2) . . ?
C21 C22 H22A 107.6 . . ?
Si2 C22 H22A 107.6 . . ?
C21 C22 H22B 107.6 . . ?
Si2 C22 H22B 107.6 . . ?
H22A C22 H22B 107.0 . . ?
C24 C23 H23A 109.5 . . ?
C24 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C24 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C23 C24 Si2 143(3) . . ?
C23 C24 H24A 101.2 . . ?
Si2 C24 H24A 101.2 . . ?
C23 C24 H24B 101.2 . . ?
Si2 C24 H24B 101.2 . . ?
H24A C24 H24B 104.5 . . ?
C26 C25 H25A 109.5 . . ?
C26 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C26 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C25 C26 Si2 118.3(17) . . ?
C25 C26 H26A 107.7 . . ?
Si2 C26 H26A 107.7 . . ?
C25 C26 H26B 107.7 . . ?
Si2 C26 H26B 107.7 . . ?
H26A C26 H26B 107.1 . . ?
C22' C21' H21D 109.5 . . ?
C22' C21' H21E 109.5 . . ?
H21D C21' H21E 109.5 . . ?
C22' C21' H21F 109.5 . . ?
H21D C21' H21F 109.5 . . ?
H21E C21' H21F 109.5 . . ?
C21' C22' Si2 121(3) . . ?
C21' C22' H22C 107.0 . . ?
Si2 C22' H22C 107.0 . . ?
C21' C22' H22D 107.0 . . ?
Si2 C22' H22D 107.0 . . ?
H22C C22' H22D 106.8 . . ?
C23' C24' Si2 110.2(16) . . ?
C23' C24' H24C 109.6 . . ?
Si2 C24' H24C 109.6 . . ?
C23' C24' H24D 109.6 . . ?
Si2 C24' H24D 109.6 . . ?
H24C C24' H24D 108.1 . . ?
C24' C23' H23D 109.5 . . ?
C24' C23' H23E 109.5 . . ?
H23D C23' H23E 109.5 . . ?
C24' C23' H23F 109.5 . . ?
H23D C23' H23F 109.5 . . ?
H23E C23' H23F 109.5 . . ?
C26' C25' H25D 109.5 . . ?
C26' C25' H25E 109.5 . . ?
H25D C25' H25E 109.5 . . ?
C26' C25' H25F 109.5 . . ?
H25D C25' H25F 109.5 . . ?
H25E C25' H25F 109.5 . . ?
C25' C26' Si2 132(3) . . ?
C25' C26' H26C 104.3 . . ?
Si2 C26' H26C 104.3 . . ?
C25' C26' H26D 104.3 . . ?
Si2 C26' H26D 104.3 . . ?
H26C C26' H26D 105.6 . . ?
C1 C2 Si1 120.3(18) . . ?
C1 C2 H2A 107.2 . . ?
Si1 C2 H2A 107.2 . . ?
C1 C2 H2B 107.2 . . ?
Si1 C2 H2B 107.2 . . ?
H2A C2 H2B 106.9 . . ?
C3 C4 Si1 113.4(18) . . ?
C3 C4 H4A 108.9 . . ?
Si1 C4 H4A 108.9 . . ?
C3 C4 H4B 108.9 . . ?
Si1 C4 H4B 108.9 . . ?
H4A C4 H4B 107.7 . . ?
C5 C6 Si1 123(2) . . ?
C5 C6 H6A 106.5 . . ?
Si1 C6 H6A 106.5 . . ?
C5 C6 H6B 106.5 . . ?
Si1 C6 H6B 106.5 . . ?
H6A C6 H6B 106.5 . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C6 C5 H5A 109.5 . . ?
C6 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C6 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C4 C3 H3A 109.5 . . ?
C4 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C4 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         0.843
_refine_diff_density_min         -1.094
_refine_diff_density_rms         0.138
