# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 2064017'
loop_
_audit_author_name
_audit_author_address
'Ni Jun'
;Dalian University of Technology
China
;
_audit_update_record             
;
2021-02-20 deposited with the CCDC.	2021-07-21 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT220_a                   
;
PROBLEM: NonSolvent   Resd 1  C   Ueq(max)/Ueq(min) Range        6.6 Ratio
RESPONSE: This alert is due to the low quality of the crystal and the severely disorder of the molecule
;
# Added during the CSD deposition process: Saturday 20 February 2021 06:52 AM
# end Validation Reply Form


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C42 H44 Br2 N2 Pt Si2'
_chemical_formula_weight         987.88

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   42.721(4)
_cell_length_b                   15.0203(16)
_cell_length_c                   13.1674(14)
_cell_angle_alpha                90.00
_cell_angle_beta                 95.929(5)
_cell_angle_gamma                90.00
_cell_volume                     8404.1(15)
_cell_formula_units_Z            8
_cell_measurement_temperature    210(2)
_cell_measurement_reflns_used    5908
_cell_measurement_theta_min      3.91
_cell_measurement_theta_max      25.81

_exptl_crystal_description       needle
_exptl_crystal_colour            'dark brown'
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.13
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.562
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3888
_exptl_absorpt_coefficient_mu    5.328
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.440
_exptl_absorpt_correction_T_max  0.501
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
; 
############################################################################
PLAT220_ALERT_2_B NonSolvent  Resd 1  C  Ueq(max)/Ueq(min) Range  6.6 Ratio
############################################################################

Response
This alert is due to the low quality of the crystal and the severely disorder 
of the molecule.  
;

_diffrn_ambient_temperature      210(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Smart APEX II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            18689
_diffrn_reflns_av_R_equivalents  0.0658
_diffrn_reflns_av_sigmaI/netI    0.0956
_diffrn_reflns_limit_h_min       -43
_diffrn_reflns_limit_h_max       50
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         1.92
_diffrn_reflns_theta_max         25.00
_reflns_number_total             7293
_reflns_number_gt                5758
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0000P)²+866.6093P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7293
_refine_ls_number_parameters     552
_refine_ls_number_restraints     531
_refine_ls_R_factor_all          0.1387
_refine_ls_R_factor_gt           0.1162
_refine_ls_wR_factor_ref         0.2729
_refine_ls_wR_factor_gt          0.2603
_refine_ls_goodness_of_fit_ref   1.108
_refine_ls_restrained_S_all      1.081
_refine_ls_shift/su_max          0.014
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.501028(10) 0.61659(3) 0.62916(3) 0.04489(11) Uani 1 1 d D . .
Si1 Si 0.7124(2) 0.7795(7) 0.7564(8) 0.1806(19) Uani 1 1 d U . .
Si2 Si 0.63401(12) 0.1260(4) 0.6488(3) 0.1288(15) Uani 1 1 d DU . .
N1 N 0.5486(2) 0.6592(7) 0.6600(6) 0.054(3) Uani 1 1 d . . .
N2 N 0.5246(2) 0.4962(7) 0.6409(6) 0.045(3) Uani 1 1 d . . .
C7 C 0.6704(3) 0.7440(12) 0.7284(12) 0.099(3) Uani 1 1 d U . .
C8 C 0.6440(4) 0.7219(12) 0.7129(12) 0.097(2) Uani 1 1 d U . .
C9 C 0.5555(3) 0.7445(9) 0.6705(9) 0.064(4) Uani 1 1 d . . .
H9 H 0.5401 0.7885 0.6645 0.077 Uiso 1 1 calc R . .
C10 C 0.5879(3) 0.7646(12) 0.6914(11) 0.092(3) Uani 1 1 d U . .
H10 H 0.5937 0.8238 0.7022 0.110 Uiso 1 1 calc R . .
C11 C 0.6111(3) 0.7017(12) 0.6966(11) 0.091(2) Uani 1 1 d U . .
C12 C 0.6020(3) 0.6060(9) 0.6836(8) 0.061(3) Uani 1 1 d . . .
H12 H 0.6164 0.5594 0.6865 0.073 Uiso 1 1 calc R . .
C13 C 0.5697(2) 0.5948(10) 0.6665(8) 0.060(2) Uani 1 1 d U . .
C14 C 0.5578(2) 0.5060(10) 0.6559(8) 0.054(2) Uani 1 1 d U . .
C15 C 0.5754(2) 0.4286(9) 0.6609(7) 0.0495(19) Uani 1 1 d U . .
H15 H 0.5972 0.4322 0.6710 0.059 Uiso 1 1 calc R . .
C16 C 0.5604(2) 0.3417(9) 0.6506(7) 0.054(2) Uani 1 1 d U B .
C17 C 0.5296(2) 0.3382(8) 0.6356(7) 0.043(3) Uani 1 1 d . . .
H17 H 0.5198 0.2830 0.6285 0.052 Uiso 1 1 calc R . .
C18 C 0.5112(2) 0.4144(7) 0.6300(6) 0.034(2) Uani 1 1 d . . .
H18 H 0.4894 0.4094 0.6186 0.041 Uiso 1 1 calc R . .
C19 C 0.5837(3) 0.2682(9) 0.6531(9) 0.067(4) Uani 1 1 d . . .
C20 C 0.6016(3) 0.2130(12) 0.6549(11) 0.093(5) Uani 1 1 d . B .
C27 C 0.4836(2) 0.7375(4) 0.6148(7) 0.047(3) Uani 1 1 d D A .
C28 C 0.4736(2) 0.8125(4) 0.6049(8) 0.063(4) Uani 1 1 d D . .
C29 C 0.4647(6) 0.9044(8) 0.6009(19) 0.0642(14) Uani 0.524(4) 1 d PDU A 1
C30 C 0.4754(7) 0.9524(15) 0.6890(18) 0.0655(16) Uani 0.524(4) 1 d PU A 1
H30A H 0.4858 0.9258 0.7466 0.079 Uiso 0.524(4) 1 calc PR A 1
C31 C 0.4694(7) 1.0398(15) 0.6832(18) 0.0663(14) Uani 0.524(4) 1 d PU A 1
H31A H 0.4752 1.0697 0.7441 0.080 Uiso 0.524(4) 1 calc PR A 1
C32 C 0.4552(7) 1.1002(9) 0.5994(18) 0.0665(14) Uani 0.524(4) 1 d PDU A 1
C33 C 0.4490(7) 1.0327(15) 0.5094(18) 0.0656(14) Uani 0.524(4) 1 d PU A 1
H33A H 0.4406 1.0566 0.4473 0.079 Uiso 0.524(4) 1 calc PR A 1
C34 C 0.4547(7) 0.9381(15) 0.5105(18) 0.0653(16) Uani 0.524(4) 1 d PU A 1
H34A H 0.4515 0.9032 0.4519 0.078 Uiso 0.524(4) 1 calc PR A 1
Br1 Br 0.44977(6) 1.22282(15) 0.59768(19) 0.0539(7) Uani 0.524(4) 1 d PDU A 1
C29' C 0.4647(7) 0.9043(8) 0.602(2) 0.0642(14) Uani 0.476(4) 1 d PDU A 2
C30' C 0.4480(7) 0.9588(17) 0.677(2) 0.0656(14) Uani 0.476(4) 1 d PU A 2
H30B H 0.4408 0.9273 0.7302 0.079 Uiso 0.476(4) 1 calc PR A 2
C31' C 0.4423(8) 1.0482(17) 0.676(2) 0.0664(15) Uani 0.476(4) 1 d PU A 2
H31B H 0.4308 1.0796 0.7200 0.080 Uiso 0.476(4) 1 calc PR A 2
C32' C 0.4569(7) 1.0830(11) 0.595(2) 0.0669(14) Uani 0.476(4) 1 d PDU A 2
C33' C 0.4662(8) 1.0558(18) 0.520(2) 0.0666(15) Uani 0.476(4) 1 d PU A 2
H33B H 0.4715 1.0918 0.4672 0.080 Uiso 0.476(4) 1 calc PR A 2
C34' C 0.4684(7) 0.9676(17) 0.521(2) 0.0650(14) Uani 0.476(4) 1 d PU A 2
H34B H 0.4730 0.9425 0.4593 0.078 Uiso 0.476(4) 1 calc PR A 2
Br1' Br 0.44393(11) 1.2009(2) 0.5923(3) 0.0878(12) Uani 0.476(4) 1 d PDU A 2
C35 C 0.45848(10) 0.5683(5) 0.6032(7) 0.0360(4) Uani 1 1 d DU . .
C36 C 0.43247(12) 0.5353(6) 0.5912(7) 0.0363(3) Uani 1 1 d DU . .
C37 C 0.40034(12) 0.5098(5) 0.5752(4) 0.0366(4) Uani 1 1 d GDU . .
C38 C 0.39362(18) 0.4196(5) 0.5809(7) 0.063(4) Uani 1 1 d G . .
H38 H 0.4099 0.3787 0.5941 0.075 Uiso 1 1 calc R . .
C39 C 0.3626(2) 0.3904(6) 0.5670(9) 0.095(6) Uani 1 1 d G . .
H39 H 0.3581 0.3299 0.5709 0.114 Uiso 1 1 calc R . .
C40 C 0.33829(14) 0.4515(8) 0.5473(9) 0.113(8) Uani 1 1 d GD . .
C41 C 0.34501(13) 0.5418(8) 0.5415(8) 0.096(3) Uani 1 1 d GU . .
H41 H 0.3287 0.5826 0.5283 0.116 Uiso 1 1 calc R . .
C42 C 0.37603(16) 0.5709(5) 0.5554(7) 0.088(3) Uani 1 1 d GU . .
H42 H 0.3805 0.6314 0.5516 0.105 Uiso 1 1 calc R . .
Br2 Br 0.29562(5) 0.4149(3) 0.5329(3) 0.2067(17) Uani 1 1 d D . .
C21 C 0.6303(6) 0.179(3) 0.462(2) 0.142(3) Uani 0.458(10) 1 d PDU B 1
H21A H 0.6388 0.1961 0.4001 0.213 Uiso 0.458(10) 1 calc PR B 1
H21B H 0.6166 0.2244 0.4819 0.213 Uiso 0.458(10) 1 calc PR B 1
H21C H 0.6187 0.1242 0.4501 0.213 Uiso 0.458(10) 1 calc PR B 1
C22 C 0.6570(4) 0.1645(18) 0.5459(11) 0.144(2) Uani 0.458(10) 1 d PDU B 1
H22A H 0.6682 0.2193 0.5639 0.173 Uiso 0.458(10) 1 calc PR B 1
H22B H 0.6718 0.1195 0.5276 0.173 Uiso 0.458(10) 1 calc PR B 1
C23 C 0.6370(6) -0.0604(17) 0.594(4) 0.150(3) Uani 0.458(10) 1 d PDU B 1
H23A H 0.6247 -0.1133 0.5792 0.225 Uiso 0.458(10) 1 calc PR B 1
H23B H 0.6512 -0.0694 0.6541 0.225 Uiso 0.458(10) 1 calc PR B 1
H23C H 0.6487 -0.0473 0.5372 0.225 Uiso 0.458(10) 1 calc PR B 1
C24 C 0.6155(5) 0.0158(8) 0.6101(19) 0.152(3) Uani 0.458(10) 1 d PDU B 1
H24A H 0.6022 -0.0017 0.6622 0.182 Uiso 0.458(10) 1 calc PR B 1
H24B H 0.6019 0.0248 0.5474 0.182 Uiso 0.458(10) 1 calc PR B 1
C25 C 0.6489(8) 0.157(2) 0.8613(9) 0.157(3) Uani 0.458(10) 1 d PDU B 1
H25A H 0.6642 0.1479 0.9189 0.235 Uiso 0.458(10) 1 calc PR B 1
H25B H 0.6288 0.1357 0.8766 0.235 Uiso 0.458(10) 1 calc PR B 1
H25C H 0.6474 0.2200 0.8465 0.235 Uiso 0.458(10) 1 calc PR B 1
C26 C 0.6587(5) 0.1094(18) 0.7715(9) 0.150(3) Uani 0.458(10) 1 d PDU B 1
H26A H 0.6591 0.0463 0.7869 0.180 Uiso 0.458(10) 1 calc PR B 1
H26B H 0.6800 0.1273 0.7623 0.180 Uiso 0.458(10) 1 calc PR B 1
C21' C 0.6265(9) 0.134(2) 0.4200(17) 0.144(3) Uani 0.542(10) 1 d PDU B 2
H21D H 0.6293 0.0967 0.3624 0.216 Uiso 0.542(10) 1 calc PR B 2
H21E H 0.6390 0.1868 0.4171 0.216 Uiso 0.542(10) 1 calc PR B 2
H21F H 0.6047 0.1503 0.4186 0.216 Uiso 0.542(10) 1 calc PR B 2
C22' C 0.6365(7) 0.0841(14) 0.5173(8) 0.147(2) Uani 0.542(10) 1 d PDU B 2
H22C H 0.6584 0.0685 0.5139 0.176 Uiso 0.542(10) 1 calc PR B 2
H22D H 0.6249 0.0286 0.5125 0.176 Uiso 0.542(10) 1 calc PR B 2
C23' C 0.6255(8) 0.0604(18) 0.8465(9) 0.145(3) Uani 0.542(10) 1 d PDU B 2
H23D H 0.6213 0.0088 0.8861 0.218 Uiso 0.542(10) 1 calc PR B 2
H23E H 0.6095 0.1043 0.8529 0.218 Uiso 0.542(10) 1 calc PR B 2
H23F H 0.6456 0.0846 0.8709 0.218 Uiso 0.542(10) 1 calc PR B 2
C24' C 0.6254(7) 0.0347(10) 0.7378(10) 0.149(3) Uani 0.542(10) 1 d PDU B 2
H24C H 0.6050 0.0099 0.7146 0.178 Uiso 0.542(10) 1 calc PR B 2
H24D H 0.6409 -0.0120 0.7332 0.178 Uiso 0.542(10) 1 calc PR B 2
C25' C 0.6786(9) 0.2901(13) 0.676(3) 0.167(3) Uani 0.542(10) 1 d PDU B 2
H25D H 0.6985 0.3006 0.7149 0.250 Uiso 0.542(10) 1 calc PR B 2
H25E H 0.6635 0.3328 0.6956 0.250 Uiso 0.542(10) 1 calc PR B 2
H25F H 0.6807 0.2959 0.6048 0.250 Uiso 0.542(10) 1 calc PR B 2
C26' C 0.6675(4) 0.1980(11) 0.6978(18) 0.167(3) Uani 0.542(10) 1 d PDU B 2
H26C H 0.6660 0.1990 0.7708 0.200 Uiso 0.542(10) 1 calc PR B 2
H26D H 0.6857 0.1614 0.6890 0.200 Uiso 0.542(10) 1 calc PR B 2
C2 C 0.7117(7) 0.8643(15) 0.8486(17) 0.202(3) Uani 1 1 d DU . .
H2A H 0.6950 0.9053 0.8239 0.242 Uiso 1 1 calc R . .
H2B H 0.7053 0.8370 0.9099 0.242 Uiso 1 1 calc R . .
C6 C 0.7302(7) 0.6790(12) 0.8428(15) 0.216(3) Uani 1 1 d DU . .
H6A H 0.7492 0.6986 0.8834 0.259 Uiso 1 1 calc R . .
H6B H 0.7151 0.6608 0.8890 0.259 Uiso 1 1 calc R . .
C4 C 0.7308(7) 0.7852(16) 0.6582(17) 0.189(2) Uani 1 1 d DU . .
H4A H 0.7311 0.7274 0.6255 0.227 Uiso 1 1 calc R . .
H4B H 0.7523 0.8040 0.6770 0.227 Uiso 1 1 calc R . .
C1 C 0.7399(7) 0.918(2) 0.880(2) 0.202(3) Uani 1 1 d U . .
H1A H 0.7584 0.8830 0.8744 0.304 Uiso 1 1 calc R . .
H1B H 0.7394 0.9377 0.9488 0.304 Uiso 1 1 calc R . .
H1C H 0.7402 0.9692 0.8356 0.304 Uiso 1 1 calc R . .
C3 C 0.7122(7) 0.859(2) 0.579(2) 0.197(3) Uani 1 1 d U . .
H3A H 0.7256 0.8756 0.5277 0.296 Uiso 1 1 calc R . .
H3B H 0.7071 0.9107 0.6164 0.296 Uiso 1 1 calc R . .
H3C H 0.6933 0.8328 0.5463 0.296 Uiso 1 1 calc R . .
C5 C 0.7376(7) 0.6026(15) 0.779(2) 0.223(3) Uani 1 1 d DU . .
H5A H 0.7402 0.6230 0.7111 0.335 Uiso 1 1 calc R . .
H5B H 0.7207 0.5602 0.7759 0.335 Uiso 1 1 calc R . .
H5C H 0.7567 0.5748 0.8079 0.335 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C35 1.954(4) . ?
Pt1 C27 1.964(6) . ?
Pt1 N2 2.067(10) . ?
Pt1 N1 2.130(10) . ?
Pt1 Pt1 3.1925(8) 2_656 ?
Si1 C4 1.58(3) . ?
Si1 C2 1.76(2) . ?
Si1 C7 1.872(17) . ?
Si1 C6 1.99(2) . ?
Si2 C22 1.847(14) . ?
Si2 C26 1.853(13) . ?
Si2 C26' 1.854(14) . ?
Si2 C22' 1.856(13) . ?
Si2 C24' 1.865(14) . ?
Si2 C24 1.881(13) . ?
Si2 C20 1.912(17) . ?
N1 C9 1.318(17) . ?
N1 C13 1.318(16) . ?
N2 C18 1.357(14) . ?
N2 C14 1.418(13) . ?
C7 C8 1.17(2) . ?
C8 C11 1.43(2) . ?
C9 C10 1.42(2) . ?
C9 H9 0.9300 . ?
C10 C11 1.37(2) . ?
C10 H10 0.9300 . ?
C11 C12 1.49(2) . ?
C12 C13 1.388(15) . ?
C12 H12 0.9300 . ?
C13 C14 1.429(19) . ?
C14 C15 1.383(18) . ?
C15 C16 1.452(18) . ?
C15 H15 0.9300 . ?
C16 C17 1.314(14) . ?
C16 C19 1.484(18) . ?
C17 C18 1.385(15) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C20 1.13(2) . ?
C27 C28 1.208(7) . ?
C28 C29 1.431(12) . ?
C28 C29' 1.431(13) . ?
C29 C34 1.32(3) . ?
C29 C30 1.40(3) . ?
C30 C31 1.34(3) . ?
C30 H30A 0.9300 . ?
C31 C32 1.51(3) . ?
C31 H31A 0.9300 . ?
C32 C33 1.56(3) . ?
C32 Br1 1.856(14) . ?
C33 C34 1.44(3) . ?
C33 H33A 0.9300 . ?
C34 H34A 0.9300 . ?
C29' C34' 1.46(4) . ?
C29' C30' 1.51(4) . ?
C30' C31' 1.37(4) . ?
C30' H30B 0.9300 . ?
C31' C32' 1.39(4) . ?
C31' H31B 0.9300 . ?
C32' C33' 1.17(4) . ?
C32' Br1' 1.855(17) . ?
C33' C34' 1.33(4) . ?
C33' H33B 0.9300 . ?
C34' H34B 0.9300 . ?
C35 C36 1.213(6) . ?
C36 C37 1.420(7) . ?
C37 C38 1.3900 . ?
C37 C42 1.3900 . ?
C38 C39 1.3900 . ?
C38 H38 0.9300 . ?
C39 C40 1.3900 . ?
C39 H39 0.9300 . ?
C40 C41 1.3900 . ?
C40 Br2 1.895(6) . ?
C41 C42 1.3900 . ?
C41 H41 0.9300 . ?
C42 H42 0.9300 . ?
C21 C22 1.52(2) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 C24 1.50(2) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C25 C26 1.48(2) . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C21' C22' 1.51(2) . ?
C21' H21D 0.9600 . ?
C21' H21E 0.9600 . ?
C21' H21F 0.9600 . ?
C22' H22C 0.9700 . ?
C22' H22D 0.9700 . ?
C23' C24' 1.482(17) . ?
C23' H23D 0.9600 . ?
C23' H23E 0.9600 . ?
C23' H23F 0.9600 . ?
C24' H24C 0.9700 . ?
C24' H24D 0.9700 . ?
C25' C26' 1.50(2) . ?
C25' H25D 0.9600 . ?
C25' H25E 0.9600 . ?
C25' H25F 0.9600 . ?
C26' H26C 0.9700 . ?
C26' H26D 0.9700 . ?
C2 C1 1.47(4) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C6 C5 1.48(2) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C4 C3 1.67(4) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C35 Pt1 C27 89.4(4) . . ?
C35 Pt1 N2 97.2(3) . . ?
C27 Pt1 N2 172.9(4) . . ?
C35 Pt1 N1 175.7(4) . . ?
C27 Pt1 N1 94.8(4) . . ?
N2 Pt1 N1 78.5(4) . . ?
C35 Pt1 Pt1 93.1(3) . 2_656 ?
C27 Pt1 Pt1 92.7(3) . 2_656 ?
N2 Pt1 Pt1 89.4(2) . 2_656 ?
N1 Pt1 Pt1 86.2(2) . 2_656 ?
C4 Si1 C2 124.6(13) . . ?
C4 Si1 C7 113.6(12) . . ?
C2 Si1 C7 104.9(12) . . ?
C4 Si1 C6 108.4(12) . . ?
C2 Si1 C6 100.8(10) . . ?
C7 Si1 C6 101.4(11) . . ?
C22 Si2 C26 112.6(8) . . ?
C22 Si2 C26' 67.9(10) . . ?
C26 Si2 C26' 55.0(10) . . ?
C22 Si2 C22' 48.3(11) . . ?
C26 Si2 C22' 133.3(11) . . ?
C26' Si2 C22' 113.9(11) . . ?
C22 Si2 C24' 147.7(12) . . ?
C26 Si2 C24' 58.9(10) . . ?
C26' Si2 C24' 113.9(9) . . ?
C22' Si2 C24' 111.8(8) . . ?
C22 Si2 C24 108.5(10) . . ?
C26 Si2 C24 107.6(10) . . ?
C26' Si2 C24 153.4(9) . . ?
C22' Si2 C24 60.8(11) . . ?
C24' Si2 C24 54.5(9) . . ?
C22 Si2 C20 105.1(9) . . ?
C26 Si2 C20 113.9(9) . . ?
C26' Si2 C20 97.0(8) . . ?
C22' Si2 C20 112.5(9) . . ?
C24' Si2 C20 106.6(10) . . ?
C24 Si2 C20 109.1(8) . . ?
C9 N1 C13 124.3(11) . . ?
C9 N1 Pt1 120.7(9) . . ?
C13 N1 Pt1 115.0(8) . . ?
C18 N2 C14 120.8(10) . . ?
C18 N2 Pt1 126.0(7) . . ?
C14 N2 Pt1 113.1(8) . . ?
C8 C7 Si1 178.7(16) . . ?
C7 C8 C11 175(2) . . ?
N1 C9 C10 115.6(13) . . ?
N1 C9 H9 122.2 . . ?
C10 C9 H9 122.2 . . ?
C11 C10 C9 123.4(16) . . ?
C11 C10 H10 118.3 . . ?
C9 C10 H10 118.3 . . ?
C10 C11 C8 123.8(16) . . ?
C10 C11 C12 118.9(13) . . ?
C8 C11 C12 117.3(15) . . ?
C13 C12 C11 112.1(12) . . ?
C13 C12 H12 123.9 . . ?
C11 C12 H12 123.9 . . ?
N1 C13 C12 125.6(13) . . ?
N1 C13 C14 116.5(10) . . ?
C12 C13 C14 117.9(12) . . ?
C15 C14 N2 116.8(11) . . ?
C15 C14 C13 126.4(10) . . ?
N2 C14 C13 116.7(11) . . ?
C14 C15 C16 121.3(9) . . ?
C14 C15 H15 119.4 . . ?
C16 C15 H15 119.4 . . ?
C17 C16 C15 118.3(12) . . ?
C17 C16 C19 129.3(13) . . ?
C15 C16 C19 112.3(10) . . ?
C16 C17 C18 122.0(11) . . ?
C16 C17 H17 119.0 . . ?
C18 C17 H17 119.0 . . ?
N2 C18 C17 120.9(9) . . ?
N2 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C20 C19 C16 179.3(16) . . ?
C19 C20 Si2 174.4(15) . . ?
C28 C27 Pt1 178.4(9) . . ?
C27 C28 C29 173.4(14) . . ?
C27 C28 C29' 173.1(15) . . ?
C29 C28 C29' 1(2) . . ?
C34 C29 C30 126.5(17) . . ?
C34 C29 C28 117.5(19) . . ?
C30 C29 C28 113.8(18) . . ?
C31 C30 C29 114(2) . . ?
C31 C30 H30A 122.8 . . ?
C29 C30 H30A 122.8 . . ?
C30 C31 C32 134(2) . . ?
C30 C31 H31A 113.1 . . ?
C32 C31 H31A 113.1 . . ?
C31 C32 C33 100.9(15) . . ?
C31 C32 Br1 130.3(17) . . ?
C33 C32 Br1 128.5(16) . . ?
C34 C33 C32 128(2) . . ?
C34 C33 H33A 116.0 . . ?
C32 C33 H33A 116.0 . . ?
C29 C34 C33 115(2) . . ?
C29 C34 H34A 122.4 . . ?
C33 C34 H34A 122.4 . . ?
C28 C29' C34' 127(2) . . ?
C28 C29' C30' 130(2) . . ?
C34' C29' C30' 102.7(17) . . ?
C31' C30' C29' 129(2) . . ?
C31' C30' H30B 115.7 . . ?
C29' C30' H30B 115.7 . . ?
C30' C31' C32' 106(2) . . ?
C30' C31' H31B 126.8 . . ?
C32' C31' H31B 126.8 . . ?
C33' C32' C31' 137(2) . . ?
C33' C32' Br1' 116(2) . . ?
C31' C32' Br1' 102.5(19) . . ?
C32' C33' C34' 112(3) . . ?
C32' C33' H33B 124.0 . . ?
C34' C33' H33B 124.0 . . ?
C33' C34' C29' 130(3) . . ?
C33' C34' H34B 115.1 . . ?
C29' C34' H34B 115.1 . . ?
C36 C35 Pt1 176.6(8) . . ?
C35 C36 C37 171.4(9) . . ?
C38 C37 C42 120.0 . . ?
C38 C37 C36 117.2(5) . . ?
C42 C37 C36 122.8(5) . . ?
C37 C38 C39 120.0 . . ?
C37 C38 H38 120.0 . . ?
C39 C38 H38 120.0 . . ?
C40 C39 C38 120.0 . . ?
C40 C39 H39 120.0 . . ?
C38 C39 H39 120.0 . . ?
C39 C40 C41 120.0 . . ?
C39 C40 Br2 121.3(6) . . ?
C41 C40 Br2 118.6(6) . . ?
C40 C41 C42 120.0 . . ?
C40 C41 H41 120.0 . . ?
C42 C41 H41 120.0 . . ?
C41 C42 C37 120.0 . . ?
C41 C42 H42 120.0 . . ?
C37 C42 H42 120.0 . . ?
C22 C21 H21A 109.5 . . ?
C22 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C22 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C21 C22 Si2 99.3(15) . . ?
C21 C22 H22A 111.9 . . ?
Si2 C22 H22A 111.9 . . ?
C21 C22 H22B 111.9 . . ?
Si2 C22 H22B 111.9 . . ?
H22A C22 H22B 109.6 . . ?
C24 C23 H23A 109.5 . . ?
C24 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C24 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C23 C24 Si2 117.8(16) . . ?
C23 C24 H24A 107.9 . . ?
Si2 C24 H24A 107.9 . . ?
C23 C24 H24B 107.9 . . ?
Si2 C24 H24B 107.9 . . ?
H24A C24 H24B 107.2 . . ?
C26 C25 H25A 109.5 . . ?
C26 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C26 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C25 C26 Si2 116.7(15) . . ?
C25 C26 H26A 108.1 . . ?
Si2 C26 H26A 108.1 . . ?
C25 C26 H26B 108.1 . . ?
Si2 C26 H26B 108.1 . . ?
H26A C26 H26B 107.3 . . ?
C22' C21' H21D 109.5 . . ?
C22' C21' H21E 109.5 . . ?
H21D C21' H21E 109.5 . . ?
C22' C21' H21F 109.5 . . ?
H21D C21' H21F 109.5 . . ?
H21E C21' H21F 109.5 . . ?
C21' C22' Si2 125.8(18) . . ?
C21' C22' H22C 105.9 . . ?
Si2 C22' H22C 105.9 . . ?
C21' C22' H22D 105.9 . . ?
Si2 C22' H22D 105.9 . . ?
H22C C22' H22D 106.2 . . ?
C24' C23' H23D 109.5 . . ?
C24' C23' H23E 109.5 . . ?
H23D C23' H23E 109.5 . . ?
C24' C23' H23F 109.5 . . ?
H23D C23' H23F 109.5 . . ?
H23E C23' H23F 109.5 . . ?
C23' C24' Si2 115.8(13) . . ?
C23' C24' H24C 108.3 . . ?
Si2 C24' H24C 108.3 . . ?
C23' C24' H24D 108.3 . . ?
Si2 C24' H24D 108.3 . . ?
H24C C24' H24D 107.4 . . ?
C26' C25' H25D 109.5 . . ?
C26' C25' H25E 109.5 . . ?
H25D C25' H25E 109.5 . . ?
C26' C25' H25F 109.5 . . ?
H25D C25' H25F 109.5 . . ?
H25E C25' H25F 109.5 . . ?
C25' C26' Si2 136(2) . . ?
C25' C26' H26C 103.1 . . ?
Si2 C26' H26C 103.1 . . ?
C25' C26' H26D 103.1 . . ?
Si2 C26' H26D 103.1 . . ?
H26C C26' H26D 105.1 . . ?
C1 C2 Si1 121(2) . . ?
C1 C2 H2A 107.1 . . ?
Si1 C2 H2A 107.1 . . ?
C1 C2 H2B 107.1 . . ?
Si1 C2 H2B 107.1 . . ?
H2A C2 H2B 106.8 . . ?
C5 C6 Si1 110.8(16) . . ?
C5 C6 H6A 109.5 . . ?
Si1 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
Si1 C6 H6B 109.5 . . ?
H6A C6 H6B 108.1 . . ?
Si1 C4 C3 107.8(19) . . ?
Si1 C4 H4A 110.1 . . ?
C3 C4 H4A 110.1 . . ?
Si1 C4 H4B 110.1 . . ?
C3 C4 H4B 110.1 . . ?
H4A C4 H4B 108.5 . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C4 C3 H3A 109.5 . . ?
C4 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C4 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C6 C5 H5A 109.5 . . ?
C6 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C6 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C35 Pt1 N1 C9 -168(4) . . . . ?
C27 Pt1 N1 C9 5.2(9) . . . . ?
N2 Pt1 N1 C9 -177.3(9) . . . . ?
Pt1 Pt1 N1 C9 -87.2(8) 2_656 . . . ?
C35 Pt1 N1 C13 13(5) . . . . ?
C27 Pt1 N1 C13 -174.3(7) . . . . ?
N2 Pt1 N1 C13 3.2(7) . . . . ?
Pt1 Pt1 N1 C13 93.3(7) 2_656 . . . ?
C35 Pt1 N2 C18 1.0(8) . . . . ?
C27 Pt1 N2 C18 -159(3) . . . . ?
N1 Pt1 N2 C18 -179.7(8) . . . . ?
Pt1 Pt1 N2 C18 94.0(7) 2_656 . . . ?
C35 Pt1 N2 C14 177.3(6) . . . . ?
C27 Pt1 N2 C14 17(3) . . . . ?
N1 Pt1 N2 C14 -3.5(6) . . . . ?
Pt1 Pt1 N2 C14 -89.7(6) 2_656 . . . ?
C4 Si1 C7 C8 -180(100) . . . . ?
C2 Si1 C7 C8 -41(78) . . . . ?
C6 Si1 C7 C8 64(78) . . . . ?
Si1 C7 C8 C11 65(88) . . . . ?
C13 N1 C9 C10 -0.9(17) . . . . ?
Pt1 N1 C9 C10 179.6(8) . . . . ?
N1 C9 C10 C11 3(2) . . . . ?
C9 C10 C11 C8 176.9(14) . . . . ?
C9 C10 C11 C12 -2(2) . . . . ?
C7 C8 C11 C10 16(23) . . . . ?
C7 C8 C11 C12 -165(22) . . . . ?
C10 C11 C12 C13 0.4(17) . . . . ?
C8 C11 C12 C13 -178.9(12) . . . . ?
C9 N1 C13 C12 -1.1(17) . . . . ?
Pt1 N1 C13 C12 178.4(8) . . . . ?
C9 N1 C13 C14 178.3(10) . . . . ?
Pt1 N1 C13 C14 -2.2(12) . . . . ?
C11 C12 C13 N1 1.3(16) . . . . ?
C11 C12 C13 C14 -178.1(10) . . . . ?
C18 N2 C14 C15 -1.3(13) . . . . ?
Pt1 N2 C14 C15 -177.8(7) . . . . ?
C18 N2 C14 C13 180.0(8) . . . . ?
Pt1 N2 C14 C13 3.5(11) . . . . ?
N1 C13 C14 C15 -179.4(10) . . . . ?
C12 C13 C14 C15 0.1(16) . . . . ?
N1 C13 C14 N2 -0.9(14) . . . . ?
C12 C13 C14 N2 178.6(9) . . . . ?
N2 C14 C15 C16 0.3(14) . . . . ?
C13 C14 C15 C16 178.9(10) . . . . ?
C14 C15 C16 C17 0.5(14) . . . . ?
C14 C15 C16 C19 177.1(9) . . . . ?
C15 C16 C17 C18 -0.4(14) . . . . ?
C19 C16 C17 C18 -176.3(10) . . . . ?
C14 N2 C18 C17 1.5(13) . . . . ?
Pt1 N2 C18 C17 177.5(7) . . . . ?
C16 C17 C18 N2 -0.6(14) . . . . ?
C17 C16 C19 C20 165(100) . . . . ?
C15 C16 C19 C20 -11(100) . . . . ?
C16 C19 C20 Si2 -35(100) . . . . ?
C22 Si2 C20 C19 -8(16) . . . . ?
C26 Si2 C20 C19 115(16) . . . . ?
C26' Si2 C20 C19 61(16) . . . . ?
C22' Si2 C20 C19 -59(16) . . . . ?
C24' Si2 C20 C19 178(100) . . . . ?
C24 Si2 C20 C19 -124(16) . . . . ?
C35 Pt1 C27 C28 -144(37) . . . . ?
N2 Pt1 C27 C28 16(39) . . . . ?
N1 Pt1 C27 C28 36(37) . . . . ?
Pt1 Pt1 C27 C28 122(37) 2_656 . . . ?
Pt1 C27 C28 C29 -63(43) . . . . ?
Pt1 C27 C28 C29' -69(42) . . . . ?
C27 C28 C29 C34 136(12) . . . . ?
C29' C28 C29 C34 -158(100) . . . . ?
C27 C28 C29 C30 -28(14) . . . . ?
C29' C28 C29 C30 37(100) . . . . ?
C34 C29 C30 C31 12(4) . . . . ?
C28 C29 C30 C31 175(2) . . . . ?
C29 C30 C31 C32 -5(5) . . . . ?
C30 C31 C32 C33 -1(4) . . . . ?
C30 C31 C32 Br1 -176(3) . . . . ?
C31 C32 C33 C34 2(4) . . . . ?
Br1 C32 C33 C34 177(2) . . . . ?
C30 C29 C34 C33 -12(4) . . . . ?
C28 C29 C34 C33 -174(2) . . . . ?
C32 C33 C34 C29 4(4) . . . . ?
C27 C28 C29' C34' 108(14) . . . . ?
C29 C28 C29' C34' -12(100) . . . . ?
C27 C28 C29' C30' -76(15) . . . . ?
C29 C28 C29' C30' 164(100) . . . . ?
C28 C29' C30' C31' 174(3) . . . . ?
C34' C29' C30' C31' -9(4) . . . . ?
C29' C30' C31' C32' -4(4) . . . . ?
C30' C31' C32' C33' 20(6) . . . . ?
C30' C31' C32' Br1' 174(2) . . . . ?
C31' C32' C33' C34' -14(6) . . . . ?
Br1' C32' C33' C34' -166(2) . . . . ?
C32' C33' C34' C29' -8(5) . . . . ?
C28 C29' C34' C33' -166(3) . . . . ?
C30' C29' C34' C33' 17(4) . . . . ?
C27 Pt1 C35 C36 -137(13) . . . . ?
N2 Pt1 C35 C36 46(13) . . . . ?
N1 Pt1 C35 C36 36(16) . . . . ?
Pt1 Pt1 C35 C36 -44(13) 2_656 . . . ?
Pt1 C35 C36 C37 138(10) . . . . ?
C35 C36 C37 C38 -179(100) . . . . ?
C35 C36 C37 C42 1(6) . . . . ?
C42 C37 C38 C39 0.0 . . . . ?
C36 C37 C38 C39 179.4(6) . . . . ?
C37 C38 C39 C40 0.0 . . . . ?
C38 C39 C40 C41 0.0 . . . . ?
C38 C39 C40 Br2 -177.6(7) . . . . ?
C39 C40 C41 C42 0.0 . . . . ?
Br2 C40 C41 C42 177.7(7) . . . . ?
C40 C41 C42 C37 0.0 . . . . ?
C38 C37 C42 C41 0.0 . . . . ?
C36 C37 C42 C41 -179.3(6) . . . . ?
C26 Si2 C22 C21 -175(2) . . . . ?
C26' Si2 C22 C21 -143(3) . . . . ?
C22' Si2 C22 C21 56(2) . . . . ?
C24' Si2 C22 C21 117(2) . . . . ?
C24 Si2 C22 C21 66(2) . . . . ?
C20 Si2 C22 C21 -51(2) . . . . ?
C22 Si2 C24 C23 62(3) . . . . ?
C26 Si2 C24 C23 -60(3) . . . . ?
C26' Si2 C24 C23 -15(4) . . . . ?
C22' Si2 C24 C23 70(3) . . . . ?
C24' Si2 C24 C23 -87(3) . . . . ?
C20 Si2 C24 C23 176(2) . . . . ?
C22 Si2 C26 C25 125(2) . . . . ?
C26' Si2 C26 C25 87(2) . . . . ?
C22' Si2 C26 C25 179(2) . . . . ?
C24' Si2 C26 C25 -90(2) . . . . ?
C24 Si2 C26 C25 -115(2) . . . . ?
C20 Si2 C26 C25 6(2) . . . . ?
C22 Si2 C22' C21' -64(3) . . . . ?
C26 Si2 C22' C21' -147(3) . . . . ?
C26' Si2 C22' C21' -83(3) . . . . ?
C24' Si2 C22' C21' 146(3) . . . . ?
C24 Si2 C22' C21' 126(3) . . . . ?
C20 Si2 C22' C21' 26(3) . . . . ?
C22 Si2 C24' C23' 130(2) . . . . ?
C26 Si2 C24' C23' 47(2) . . . . ?
C26' Si2 C24' C23' 44(3) . . . . ?
C22' Si2 C24' C23' 175(2) . . . . ?
C24 Si2 C24' C23' -163(3) . . . . ?
C20 Si2 C24' C23' -61(2) . . . . ?
C22 Si2 C26' C25' 56(3) . . . . ?
C26 Si2 C26' C25' -162(3) . . . . ?
C22' Si2 C26' C25' 71(3) . . . . ?
C24' Si2 C26' C25' -159(3) . . . . ?
C24 Si2 C26' C25' 143(3) . . . . ?
C20 Si2 C26' C25' -47(3) . . . . ?
C4 Si1 C2 C1 -38(3) . . . . ?
C7 Si1 C2 C1 -171(2) . . . . ?
C6 Si1 C2 C1 84(2) . . . . ?
C4 Si1 C6 C5 -39(2) . . . . ?
C2 Si1 C6 C5 -171(2) . . . . ?
C7 Si1 C6 C5 81(2) . . . . ?
C2 Si1 C4 C3 -70(2) . . . . ?
C7 Si1 C4 C3 60(2) . . . . ?
C6 Si1 C4 C3 171.6(16) . . . . ?

_diffrn_measured_fraction_theta_max 0.986
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.986
_refine_diff_density_max         3.074
_refine_diff_density_min         -5.334
_refine_diff_density_rms         0.215
