# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_m4912_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2087418'
loop_
_audit_author_name
_audit_author_address
'HT CHEN'
;JNHH
China
;
_audit_update_record             
;
2021-06-01 deposited with the CCDC.	2021-08-04 downloaded from the CCDC.
;
_audit_creation_date             2020-11-08
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '0.25(C280 H128 Eu16 N12 O136), O'
_chemical_formula_sum            'C70 H32 Eu4 N3 O35'
_chemical_formula_weight         2082.82
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_H-M_alt        'P n m a'
_space_group_name_Hall           '-P 2ac 2n'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'

_cell_length_a                   32.6303(18)
_cell_length_b                   18.587(3)
_cell_length_c                   16.648(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     10097(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    5020
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.405
_cell_measurement_theta_min      2.509
_shelx_estimated_absorpt_T_max   0.884
_shelx_estimated_absorpt_T_min   0.704
_exptl_absorpt_coefficient_mu    2.520
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.4370
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1598 before and 0.1044 after correction. The Ratio of minimum to maximum transmission is 0.5860. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.370
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             4020
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1597
_diffrn_reflns_av_unetI/netI     0.1254
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            52323
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.100
_diffrn_reflns_theta_max         25.100
_diffrn_reflns_theta_min         2.237
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker D8 VENTURE PHOTON II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  'Helios multilayer optic'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_source            'Incoatc Ius 3.0 '
_diffrn_source_type              Microfocus
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5385
_reflns_number_total             9248
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.158
_refine_diff_density_min         -0.971
_refine_diff_density_rms         0.146
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.989
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     529
_refine_ls_number_reflns         9248
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.1094
_refine_ls_R_factor_gt           0.0584
_refine_ls_restrained_S_all      0.994
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0545P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1209
_refine_ls_wR_factor_ref         0.1450
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(O4) \\sim Ueq: with sigma of 0.003 and sigma for terminal atoms of 0.006
Uanis(O1W) \\sim Ueq, Uanis(O2W) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
3. Others
 Fixed Sof: H1A(0.5) H1B(0.5) H2A(0.5) H2B(0.5) H3A(0.5) H3B(0.5)
4.a Rotating group:
 N1(H1A,H1B), N2(H2A,H2B), N3(H3A,H3B)
4.b Secondary CH2 refined with riding coordinates:
 C24(H24A,H24B)
4.c Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C6(H6), C11(H11), C15(H15), C17(H17), C19(H19), C28(H28),
 C30(H30), C32(H32), C37(H37)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.67589(2) 0.38379(3) 0.40422(3) 0.03254(15) Uani 1 1 d . . . . .
Eu2 Eu 1.02535(2) 0.57196(3) 0.62245(3) 0.04124(17) Uani 1 1 d . . . . .
O1 O 0.4852(2) -0.0860(4) 0.7514(4) 0.057(2) Uani 1 1 d . . . . .
O2 O 0.5356(2) -0.0050(5) 0.7572(5) 0.080(3) Uani 1 1 d . . . . .
O3 O 0.3727(2) -0.0456(4) 0.5355(4) 0.064(2) Uani 1 1 d . . . . .
O4 O 0.3816(3) 0.0430(6) 0.4510(6) 0.129(4) Uani 1 1 d . U . . .
O5 O 0.6212(2) 0.3091(4) 0.4204(4) 0.060(2) Uani 1 1 d . . . . .
O6 O 0.5674(2) 0.0320(4) -0.0743(5) 0.068(2) Uani 1 1 d . . . . .
O7 O 0.59872(19) -0.0632(4) -0.1264(4) 0.058(2) Uani 1 1 d . . . . .
O8 O 0.74889(19) -0.0942(4) -0.1029(4) 0.055(2) Uani 1 1 d . . . . .
O9 O 0.7839(2) -0.0275(4) -0.0183(4) 0.058(2) Uani 1 1 d . . . . .
O10 O 0.7003(2) 0.3097(4) 0.3047(4) 0.0541(19) Uani 1 1 d . . . . .
O11 O 0.9587(2) 0.4048(4) 0.5104(4) 0.067(2) Uani 1 1 d . . . . .
O12 O 0.9776(2) 0.4877(4) 0.5995(5) 0.070(2) Uani 1 1 d . . . . .
O13 O 0.86864(19) 0.5917(4) 0.7856(4) 0.0496(18) Uani 1 1 d . . . . .
O14 O 0.8149(2) 0.5222(4) 0.8085(4) 0.069(2) Uani 1 1 d . . . . .
O15 O 0.7016(2) 0.3098(4) 0.5040(4) 0.058(2) Uani 1 1 d . . . . .
O16 O 1.0407(3) 0.6896(4) 0.6466(5) 0.092(3) Uani 1 1 d . . . . .
O1W O 0.9643(3) 0.6327(6) 0.5670(6) 0.111(3) Uani 1 1 d . U . . .
N1 N 0.4495(4) 0.250000 0.5961(9) 0.088(5) Uani 1 2 d S T P . .
H1A H 0.432277 0.210454 0.649664 0.106 Uiso 0.5 1 d GR . . . .
H1B H 0.429554 0.295722 0.638823 0.106 Uiso 0.5 1 d GR . . . .
N2 N 0.8778(4) 0.250000 0.6674(9) 0.080(5) Uani 1 2 d S T P . .
H2A H 0.879101 0.275841 0.715735 0.096 Uiso 0.5 1 d GR . . . .
H2B H 0.889111 0.205010 0.684166 0.096 Uiso 0.5 1 d GR . . . .
N3 N 0.6759(4) 0.250000 -0.0730(8) 0.070(4) Uani 1 2 d S T P . .
H3A H 0.677562 0.206691 -0.091015 0.083 Uiso 0.5 1 d GR . . . .
H3B H 0.651747 0.266695 -0.082694 0.083 Uiso 0.5 1 d GR . . . .
O2W O 0.9594(5) 0.750000 0.4843(10) 0.173(7) Uani 1 2 d S TU P . .
C1 C 0.4854(3) 0.0089(6) 0.6520(6) 0.048(3) Uani 1 1 d . . . . .
C2 C 0.4482(3) -0.0122(6) 0.6141(6) 0.049(3) Uani 1 1 d . . . . .
H2 H 0.434905 -0.053776 0.630994 0.059 Uiso 1 1 calc R . . . .
C3 C 0.4319(3) 0.0280(6) 0.5531(7) 0.054(3) Uani 1 1 d . . . . .
C4 C 0.4514(3) 0.0917(6) 0.5270(7) 0.062(3) Uani 1 1 d . . . . .
H4 H 0.440147 0.118457 0.485238 0.075 Uiso 1 1 calc R . . . .
C5 C 0.4877(3) 0.1146(6) 0.5640(7) 0.055(3) Uani 1 1 d . . . . .
C6 C 0.5048(3) 0.0710(6) 0.6261(6) 0.054(3) Uani 1 1 d . . . . .
H6 H 0.529483 0.084550 0.649647 0.065 Uiso 1 1 calc R . . . .
C7 C 0.5030(3) -0.0307(6) 0.7225(7) 0.056(3) Uani 1 1 d . . . . .
C8 C 0.3921(4) 0.0056(8) 0.5100(8) 0.080(4) Uani 1 1 d . . . . .
C9 C 0.5081(3) 0.1837(5) 0.5408(6) 0.045(3) Uani 1 1 d . . . . .
C10 C 0.4886(4) 0.250000 0.5585(9) 0.056(4) Uani 1 2 d S T P . .
C11 C 0.5463(3) 0.1854(5) 0.5051(6) 0.050(3) Uani 1 1 d . . . . .
H11 H 0.559512 0.142221 0.493763 0.060 Uiso 1 1 calc R . . . .
C12 C 0.5657(4) 0.250000 0.4857(9) 0.047(4) Uani 1 2 d S T P . .
C13 C 0.6064(4) 0.250000 0.4409(8) 0.047(4) Uani 1 2 d S T P . .
C14 C 0.6406(3) 0.0244(5) -0.0623(6) 0.044(3) Uani 1 1 d . . . . .
C15 C 0.6766(3) -0.0167(5) -0.0740(6) 0.044(3) Uani 1 1 d . . . . .
H15 H 0.675251 -0.059511 -0.102893 0.053 Uiso 1 1 calc R . . . .
C16 C 0.7143(3) 0.0063(6) -0.0427(6) 0.046(3) Uani 1 1 d . . . . .
C17 C 0.7168(3) 0.0711(6) -0.0015(6) 0.043(3) Uani 1 1 d . . . . .
H17 H 0.741878 0.085388 0.019671 0.052 Uiso 1 1 calc R . . . .
C18 C 0.6829(3) 0.1151(5) 0.0091(6) 0.042(2) Uani 1 1 d . . . . .
C19 C 0.6444(3) 0.0912(6) -0.0214(6) 0.050(3) Uani 1 1 d . . . . .
H19 H 0.621299 0.119859 -0.014434 0.060 Uiso 1 1 calc R . . . .
C20 C 0.6005(3) -0.0036(6) -0.0912(6) 0.051(3) Uani 1 1 d . . . . .
C21 C 0.7508(3) -0.0422(6) -0.0559(6) 0.042(3) Uani 1 1 d . . . . .
C22 C 0.6860(3) 0.1845(5) 0.0519(6) 0.038(2) Uani 1 1 d . . . . .
C23 C 0.6823(4) 0.250000 0.0120(8) 0.041(4) Uani 1 2 d S T P . .
C24 C 0.6930(3) 0.1855(6) 0.1354(6) 0.047(3) Uani 1 1 d . . . . .
H24A H 0.671298 0.157362 0.159986 0.056 Uiso 1 1 calc R . . . .
H24B H 0.718340 0.159563 0.144780 0.056 Uiso 1 1 calc R . . . .
C25 C 0.6956(4) 0.250000 0.1786(8) 0.041(4) Uani 1 2 d S T P . .
C26 C 0.6989(4) 0.250000 0.2686(9) 0.040(4) Uani 1 2 d S T P . .
C27 C 0.9095(3) 0.4442(6) 0.6064(6) 0.049(3) Uani 1 1 d . . . . .
C28 C 0.8975(3) 0.4924(5) 0.6645(5) 0.046(3) Uani 1 1 d . . . . .
H28 H 0.915741 0.528132 0.680282 0.055 Uiso 1 1 calc R . . . .
C29 C 0.8582(3) 0.4898(6) 0.7013(6) 0.045(3) Uani 1 1 d . . . . .
C30 C 0.8324(3) 0.4325(5) 0.6782(6) 0.043(3) Uani 1 1 d . . . . .
H30 H 0.806858 0.428069 0.702346 0.051 Uiso 1 1 calc R . . . .
C31 C 0.8440(3) 0.3827(6) 0.6209(6) 0.043(3) Uani 1 1 d . . . . .
C32 C 0.8817(3) 0.3906(6) 0.5853(6) 0.049(3) Uani 1 1 d . . . . .
H32 H 0.889070 0.358466 0.544950 0.059 Uiso 1 1 calc R . . . .
C33 C 0.9517(3) 0.4465(7) 0.5696(6) 0.054(3) Uani 1 1 d . . . . .
C34 C 0.8471(3) 0.5377(6) 0.7691(6) 0.045(3) Uani 1 1 d . . . . .
C35 C 0.8198(3) 0.3172(5) 0.6065(5) 0.041(2) Uani 1 1 d . . . . .
C36 C 0.8389(4) 0.250000 0.6272(9) 0.048(4) Uani 1 2 d S T P . .
C37 C 0.7804(3) 0.3148(6) 0.5730(6) 0.047(3) Uani 1 1 d . . . . .
H37 H 0.767661 0.358089 0.560397 0.057 Uiso 1 1 calc R . . . .
C38 C 0.7588(4) 0.250000 0.5571(8) 0.040(3) Uani 1 2 d S T P . .
C39 C 0.7175(4) 0.250000 0.5209(9) 0.047(4) Uani 1 2 d S T P . .
C40 C 1.0431(6) 0.750000 0.6093(12) 0.084(6) Uani 1 2 d S T P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.289(7) 3_656 ?
Eu1 O5 2.276(7) . ?
Eu1 O8 2.491(6) 8_766 ?
Eu1 O9 2.470(7) 8_766 ?
Eu1 O10 2.295(7) . ?
Eu1 O13 2.493(6) 2_664 ?
Eu1 O14 2.384(7) 2_664 ?
Eu1 O15 2.313(7) . ?
Eu1 C21 2.838(10) 8_766 ?
Eu1 C34 2.784(10) 2_664 ?
Eu2 O1 2.490(6) 4_556 ?
Eu2 O2 2.382(7) 4_556 ?
Eu2 O6 2.501(7) 4 ?
Eu2 O7 2.401(6) 4 ?
Eu2 O11 2.312(7) 5_766 ?
Eu2 O12 2.243(8) . ?
Eu2 O16 2.279(9) . ?
Eu2 O1W 2.468(9) . ?
Eu2 C7 2.791(11) 4_556 ?
Eu2 C20 2.811(11) 4 ?
O1 C7 1.276(12) . ?
O2 C7 1.304(12) . ?
O3 C8 1.220(13) . ?
O4 C8 1.252(13) . ?
O5 C13 1.248(9) . ?
O6 C20 1.297(11) . ?
O7 C20 1.255(11) . ?
O8 C21 1.245(11) . ?
O9 C21 1.278(10) . ?
O10 C26 1.264(9) . ?
O11 C33 1.275(12) . ?
O12 C33 1.243(12) . ?
O13 C34 1.258(11) . ?
O14 C34 1.271(11) . ?
O15 C39 1.259(9) . ?
O16 C40 1.286(12) . ?
N1 H1A 1.2851 . ?
N1 H1B 1.2854 . ?
N1 C10 1.419(17) . ?
N2 H2A 0.94(12) 7_565 ?
N2 H2A 0.9384 . ?
N2 H2B 0.9554 . ?
N2 C36 1.435(16) . ?
N3 H3A 0.86(3) 7_565 ?
N3 H3A 0.8611 . ?
N3 H3B 0.8614 . ?
N3 H3B 0.86(10) 7_565 ?
N3 C23 1.430(17) . ?
C1 C2 1.421(13) . ?
C1 C6 1.387(13) . ?
C1 C7 1.498(13) . ?
C2 H2 0.9300 . ?
C2 C3 1.369(13) . ?
C3 C4 1.414(13) . ?
C3 C8 1.540(14) . ?
C4 H4 0.9300 . ?
C4 C5 1.401(13) . ?
C5 C6 1.428(14) . ?
C5 C9 1.496(14) . ?
C6 H6 0.9300 . ?
C9 C10 1.418(11) . ?
C9 C11 1.382(12) . ?
C11 H11 0.9300 . ?
C11 C12 1.395(11) . ?
C12 C13 1.522(18) . ?
C14 C15 1.415(12) . ?
C14 C19 1.421(13) . ?
C14 C20 1.489(13) . ?
C15 H15 0.9300 . ?
C15 C16 1.405(12) . ?
C16 C17 1.387(13) . ?
C16 C21 1.509(13) . ?
C17 H17 0.9300 . ?
C17 C18 1.388(12) . ?
C18 C19 1.425(12) . ?
C18 C22 1.478(12) . ?
C19 H19 0.9300 . ?
C22 C23 1.392(11) . ?
C22 C24 1.409(12) . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C24 C25 1.401(11) . ?
C25 C26 1.501(18) . ?
C27 C28 1.375(12) . ?
C27 C32 1.393(13) . ?
C27 C33 1.506(13) . ?
C28 H28 0.9300 . ?
C28 C29 1.420(12) . ?
C29 C30 1.412(12) . ?
C29 C34 1.483(13) . ?
C30 H30 0.9300 . ?
C30 C31 1.381(12) . ?
C31 C32 1.375(12) . ?
C31 C35 1.470(13) . ?
C32 H32 0.9300 . ?
C35 C36 1.438(11) . ?
C35 C37 1.403(12) . ?
C37 H37 0.9300 . ?
C37 C38 1.420(11) . ?
C38 C39 1.477(17) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O8 127.5(3) 3_656 8_766 ?
O3 Eu1 O9 75.9(2) 3_656 8_766 ?
O3 Eu1 O10 154.1(2) 3_656 . ?
O3 Eu1 O13 80.8(2) 3_656 2_664 ?
O3 Eu1 O14 87.7(3) 3_656 2_664 ?
O3 Eu1 O15 106.0(3) 3_656 . ?
O3 Eu1 C21 101.7(3) 3_656 8_766 ?
O3 Eu1 C34 82.4(3) 3_656 2_664 ?
O5 Eu1 O3 75.8(3) . 3_656 ?
O5 Eu1 O8 151.4(2) . 8_766 ?
O5 Eu1 O9 139.6(3) . 8_766 ?
O5 Eu1 O10 89.5(3) . . ?
O5 Eu1 O13 75.4(2) . 2_664 ?
O5 Eu1 O14 128.7(2) . 2_664 ?
O5 Eu1 O15 80.6(2) . . ?
O5 Eu1 C21 158.2(3) . 8_766 ?
O5 Eu1 C34 101.8(3) . 2_664 ?
O8 Eu1 O13 120.4(2) 8_766 2_664 ?
O8 Eu1 C21 26.0(2) 8_766 8_766 ?
O8 Eu1 C34 98.1(3) 8_766 2_664 ?
O9 Eu1 O8 52.6(2) 8_766 8_766 ?
O9 Eu1 O13 127.0(2) 8_766 2_664 ?
O9 Eu1 C21 26.7(2) 8_766 8_766 ?
O9 Eu1 C34 102.4(3) 8_766 2_664 ?
O10 Eu1 O8 73.9(2) . 8_766 ?
O10 Eu1 O9 126.4(2) . 8_766 ?
O10 Eu1 O13 74.9(2) . 2_664 ?
O10 Eu1 O14 85.0(3) . 2_664 ?
O10 Eu1 O15 92.1(2) . . ?
O10 Eu1 C21 99.6(3) . 8_766 ?
O10 Eu1 C34 79.9(3) . 2_664 ?
O13 Eu1 C21 126.0(2) 2_664 8_766 ?
O13 Eu1 C34 26.9(2) 2_664 2_664 ?
O14 Eu1 O8 74.0(2) 2_664 8_766 ?
O14 Eu1 O9 78.1(2) 2_664 8_766 ?
O14 Eu1 O13 53.9(2) 2_664 2_664 ?
O14 Eu1 C21 72.2(3) 2_664 8_766 ?
O14 Eu1 C34 27.1(2) 2_664 2_664 ?
O15 Eu1 O8 77.0(2) . 8_766 ?
O15 Eu1 O9 80.2(2) . 8_766 ?
O15 Eu1 O13 152.6(2) . 2_664 ?
O15 Eu1 O14 150.5(2) . 2_664 ?
O15 Eu1 C21 79.3(3) . 8_766 ?
O15 Eu1 C34 171.6(3) . 2_664 ?
C34 Eu1 C21 99.3(3) 2_664 8_766 ?
O1 Eu2 O6 129.8(2) 4_556 4 ?
O1 Eu2 C7 27.2(3) 4_556 4_556 ?
O1 Eu2 C20 131.5(3) 4_556 4 ?
O2 Eu2 O1 54.5(2) 4_556 4_556 ?
O2 Eu2 O6 77.8(3) 4_556 4 ?
O2 Eu2 O7 78.5(2) 4_556 4 ?
O2 Eu2 O1W 131.9(3) 4_556 . ?
O2 Eu2 C7 27.8(3) 4_556 4_556 ?
O2 Eu2 C20 78.2(3) 4_556 4 ?
O6 Eu2 C7 103.1(3) 4 4_556 ?
O6 Eu2 C20 27.5(2) 4 4 ?
O7 Eu2 O1 120.6(2) 4 4_556 ?
O7 Eu2 O6 53.8(2) 4 4 ?
O7 Eu2 O1W 147.8(3) 4 . ?
O7 Eu2 C7 102.5(3) 4 4_556 ?
O7 Eu2 C20 26.4(2) 4 4 ?
O11 Eu2 O1 154.9(3) 5_766 4_556 ?
O11 Eu2 O2 150.4(3) 5_766 4_556 ?
O11 Eu2 O6 73.4(3) 5_766 4 ?
O11 Eu2 O7 79.3(3) 5_766 4 ?
O11 Eu2 O1W 74.8(3) 5_766 . ?
O11 Eu2 C7 174.2(3) 5_766 4_556 ?
O11 Eu2 C20 73.2(3) 5_766 4 ?
O12 Eu2 O1 81.5(3) . 4_556 ?
O12 Eu2 O2 82.9(3) . 4_556 ?
O12 Eu2 O6 77.7(3) . 4 ?
O12 Eu2 O7 130.6(3) . 4 ?
O12 Eu2 O11 97.1(3) . 5_766 ?
O12 Eu2 O16 148.6(3) . . ?
O12 Eu2 O1W 72.2(3) . . ?
O12 Eu2 C7 77.5(3) . 4_556 ?
O12 Eu2 C20 105.0(3) . 4 ?
O16 Eu2 O1 82.3(3) . 4_556 ?
O16 Eu2 O2 108.8(3) . 4_556 ?
O16 Eu2 O6 132.6(3) . 4 ?
O16 Eu2 O7 80.8(3) . 4 ?
O16 Eu2 O11 86.6(3) . 5_766 ?
O16 Eu2 O1W 78.8(3) . . ?
O16 Eu2 C7 99.1(3) . 4_556 ?
O16 Eu2 C20 105.9(3) . 4 ?
O1W Eu2 O1 81.0(3) . 4_556 ?
O1W Eu2 O6 132.5(3) . 4 ?
O1W Eu2 C7 105.1(3) . 4_556 ?
O1W Eu2 C20 147.3(3) . 4 ?
C7 Eu2 C20 106.0(3) 4_556 4 ?
C7 O1 Eu2 89.7(6) . 4_456 ?
C7 O2 Eu2 93.8(6) . 4_456 ?
C8 O3 Eu1 163.6(9) . 3_646 ?
C13 O5 Eu1 150.9(8) . . ?
C20 O6 Eu2 89.7(6) . 4_455 ?
C20 O7 Eu2 95.3(6) . 4_455 ?
C21 O8 Eu1 92.8(6) . 8_755 ?
C21 O9 Eu1 92.9(6) . 8_755 ?
C26 O10 Eu1 149.2(8) . . ?
C33 O11 Eu2 131.8(7) . 5_766 ?
C33 O12 Eu2 166.0(8) . . ?
C34 O13 Eu1 89.6(6) . 2_665 ?
C34 O14 Eu1 94.3(6) . 2_665 ?
C39 O15 Eu1 146.6(9) . . ?
C40 O16 Eu2 140.0(11) . . ?
H1A N1 H1B 76.9 . . ?
C10 N1 H1A 134.3 . . ?
C10 N1 H1B 134.3 . . ?
H2A N2 H2A 61.6 . 7_565 ?
H2A N2 H2B 100.4 . . ?
H2B N2 H2A 44.3 . 7_565 ?
C36 N2 H2A 116.0 . . ?
C36 N2 H2A 116(4) . 7_565 ?
C36 N2 H2B 118.5 . . ?
H3A N3 H3A 138.4 . 7_565 ?
H3A N3 H3B 69.9 . 7_565 ?
H3A N3 H3B 109.2 7_565 7_565 ?
H3A N3 H3B 109.2 . . ?
H3B N3 H3A 69.9 . 7_565 ?
H3B N3 H3B 42.2 . 7_565 ?
C23 N3 H3A 109.6 . . ?
C23 N3 H3A 109.6(8) . 7_565 ?
C23 N3 H3B 108.7 . . ?
C23 N3 H3B 109(2) . 7_565 ?
C2 C1 C7 122.6(10) . . ?
C6 C1 C2 118.8(9) . . ?
C6 C1 C7 118.5(10) . . ?
C1 C2 H2 119.6 . . ?
C3 C2 C1 120.8(10) . . ?
C3 C2 H2 119.6 . . ?
C2 C3 C4 120.6(9) . . ?
C2 C3 C8 121.9(10) . . ?
C4 C3 C8 117.5(10) . . ?
C3 C4 H4 120.0 . . ?
C5 C4 C3 120.0(10) . . ?
C5 C4 H4 120.0 . . ?
C4 C5 C6 118.4(10) . . ?
C4 C5 C9 121.5(9) . . ?
C6 C5 C9 120.0(9) . . ?
C1 C6 C5 121.3(10) . . ?
C1 C6 H6 119.3 . . ?
C5 C6 H6 119.3 . . ?
O1 C7 Eu2 63.1(5) . 4_456 ?
O1 C7 O2 120.0(10) . . ?
O1 C7 C1 121.1(10) . . ?
O2 C7 Eu2 58.4(5) . 4_456 ?
O2 C7 C1 118.8(10) . . ?
C1 C7 Eu2 163.6(8) . 4_456 ?
O3 C8 O4 124.3(12) . . ?
O3 C8 C3 119.1(10) . . ?
O4 C8 C3 116.6(12) . . ?
C10 C9 C5 119.5(9) . . ?
C11 C9 C5 122.1(9) . . ?
C11 C9 C10 118.4(10) . . ?
C9 C10 N1 119.7(7) 7_565 . ?
C9 C10 N1 119.7(7) . . ?
C9 C10 C9 120.6(13) . 7_565 ?
C9 C11 H11 119.0 . . ?
C9 C11 C12 121.9(10) . . ?
C12 C11 H11 119.0 . . ?
C11 C12 C11 118.8(12) . 7_565 ?
C11 C12 C13 120.6(6) . . ?
C11 C12 C13 120.6(6) 7_565 . ?
O5 C13 O5 123.3(14) . 7_565 ?
O5 C13 C12 118.2(7) . . ?
O5 C13 C12 118.2(7) 7_565 . ?
C15 C14 C19 117.8(9) . . ?
C15 C14 C20 119.7(9) . . ?
C19 C14 C20 122.4(9) . . ?
C14 C15 H15 119.6 . . ?
C16 C15 C14 120.7(9) . . ?
C16 C15 H15 119.6 . . ?
C15 C16 C21 117.0(9) . . ?
C17 C16 C15 119.9(9) . . ?
C17 C16 C21 123.1(9) . . ?
C16 C17 H17 119.1 . . ?
C16 C17 C18 121.9(9) . . ?
C18 C17 H17 119.1 . . ?
C17 C18 C19 118.3(9) . . ?
C17 C18 C22 121.4(9) . . ?
C19 C18 C22 120.3(9) . . ?
C14 C19 C18 121.3(9) . . ?
C14 C19 H19 119.4 . . ?
C18 C19 H19 119.4 . . ?
O6 C20 Eu2 62.9(5) . 4_455 ?
O6 C20 C14 119.0(10) . . ?
O7 C20 Eu2 58.3(5) . 4_455 ?
O7 C20 O6 120.8(10) . . ?
O7 C20 C14 120.0(9) . . ?
C14 C20 Eu2 170.1(8) . 4_455 ?
O8 C21 Eu1 61.2(5) . 8_755 ?
O8 C21 O9 121.0(9) . . ?
O8 C21 C16 121.1(9) . . ?
O9 C21 Eu1 60.4(5) . 8_755 ?
O9 C21 C16 117.9(9) . . ?
C16 C21 Eu1 171.2(7) . 8_755 ?
C23 C22 C18 121.8(8) . . ?
C23 C22 C24 118.3(9) . . ?
C24 C22 C18 119.9(9) . . ?
C22 C23 N3 119.0(6) . . ?
C22 C23 N3 119.0(6) 7_565 . ?
C22 C23 C22 122.0(12) 7_565 . ?
C22 C24 H24A 106.9 . . ?
C22 C24 H24B 106.9 . . ?
H24A C24 H24B 106.7 . . ?
C25 C24 C22 121.8(10) . . ?
C25 C24 H24A 106.9 . . ?
C25 C24 H24B 106.9 . . ?
C24 C25 C24 117.7(12) . 7_565 ?
C24 C25 C26 121.1(6) 7_565 . ?
C24 C25 C26 121.1(6) . . ?
O10 C26 O10 122.9(13) . 7_565 ?
O10 C26 C25 118.5(7) 7_565 . ?
O10 C26 C25 118.5(7) . . ?
C28 C27 C32 117.2(9) . . ?
C28 C27 C33 121.9(10) . . ?
C32 C27 C33 120.8(10) . . ?
C27 C28 H28 118.7 . . ?
C27 C28 C29 122.6(9) . . ?
C29 C28 H28 118.7 . . ?
C28 C29 C34 122.0(9) . . ?
C30 C29 C28 116.5(9) . . ?
C30 C29 C34 120.9(9) . . ?
C29 C30 H30 119.0 . . ?
C31 C30 C29 122.1(9) . . ?
C31 C30 H30 119.0 . . ?
C30 C31 C35 121.4(9) . . ?
C32 C31 C30 118.1(9) . . ?
C32 C31 C35 119.9(9) . . ?
C27 C32 H32 118.3 . . ?
C31 C32 C27 123.4(10) . . ?
C31 C32 H32 118.3 . . ?
O11 C33 C27 117.5(10) . . ?
O12 C33 O11 124.1(10) . . ?
O12 C33 C27 118.4(10) . . ?
O13 C34 Eu1 63.5(5) . 2_665 ?
O13 C34 O14 122.0(9) . . ?
O13 C34 C29 120.5(9) . . ?
O14 C34 Eu1 58.6(5) . 2_665 ?
O14 C34 C29 117.5(10) . . ?
C29 C34 Eu1 174.8(8) . 2_665 ?
C36 C35 C31 116.5(9) . . ?
C37 C35 C31 125.7(9) . . ?
C37 C35 C36 117.7(10) . . ?
N2 C36 C35 119.7(6) . . ?
N2 C36 C35 119.7(6) . 7_565 ?
C35 C36 C35 120.6(12) 7_565 . ?
C35 C37 H37 118.1 . . ?
C35 C37 C38 123.8(10) . . ?
C38 C37 H37 118.1 . . ?
C37 C38 C37 116.0(12) 7_565 . ?
C37 C38 C39 121.9(6) 7_565 . ?
C37 C38 C39 122.0(6) . . ?
O15 C39 O15 124.1(14) 7_565 . ?
O15 C39 C38 117.9(7) . . ?
O15 C39 C38 117.9(7) 7_565 . ?
O16 C40 O16 121.7(19) . 7_575 ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.608 -0.152 -0.381 4238.4 1037.1 ?

_olex2_submission_special_instructions 'No special instructions were received'
