# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_s
_database_code_depnum_ccdc_archive 'CCDC 2081879'
loop_
_audit_author_name
_audit_author_address
jiangyansong
;Jilin University
China
;
_audit_update_record             
;
2021-05-05 deposited with the CCDC.	2021-09-22 downloaded from the CCDC.
;
_audit_creation_date             2021-05-04
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C34 H19 Eu N2 O8'
_chemical_formula_sum            'C34 H19 Eu N2 O8'
_chemical_formula_weight         735.47
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, y+1/2, -z+1/2'
3 '-x, -y, -z'
4 'x, -y-1/2, z-1/2'

_cell_length_a                   11.590(2)
_cell_length_b                   16.888(3)
_cell_length_c                   14.725(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 109.92(3)
_cell_angle_gamma                90.00
_cell_volume                     2709.7(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    23474
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.43
_cell_measurement_theta_min      3.0
_exptl_absorpt_coefficient_mu    2.377
_exptl_absorpt_correction_T_max  0.490
_exptl_absorpt_correction_T_min  0.429
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_crystal_colour            'whiteish colourless'
_exptl_crystal_colour_lustre     .
_exptl_crystal_colour_modifier   whiteish
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.803
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1456
_exptl_crystal_preparation       ?
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.3
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0623
_diffrn_reflns_av_unetI/netI     0.0541
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            23474
_diffrn_reflns_theta_full        27.43
_diffrn_reflns_theta_max         27.43
_diffrn_reflns_theta_min         3.00
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         ?
_reflns_number_gt                4850
_reflns_number_total             6014
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_refine_diff_density_max         0.620
_refine_diff_density_min         -1.753
_refine_diff_density_rms         0.132
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         6014
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0504
_refine_ls_R_factor_gt           0.0351
_refine_ls_restrained_S_all      1.031
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0197P)²+4.8171P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0630
_refine_ls_wR_factor_ref         0.0689
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description    
;
1. Others
 Fixed Uiso: H6(0.027) H2(0.028) H18(0.03) H6A(0.066) H20(0.028) H11(0.037)
 H4(0.026) H14(0.032) H10(0.035) H28(0.051) H30(0.044) H16(0.035) H12(0.036)
 H29(0.058) H27(0.055) H26(0.057) H25(0.059) H23(0.049) H24(0.063)
 Fixed X: H6(0.5295) H2(0.398) H18(-0.363) H6A(-0.4116) H20(-0.0727)
 H11(0.2852) H4(0.3354) H14(0.1353) H10(0.4007) H28(1.1595) H30(0.8067) H16(-
 0.0451) H12(0.0919) H29(1.0121) H27(1.214) H26(1.1535) H25(0.9817) H23(0.6389)
 H24(0.7728)
 Fixed Y: H6(0.1776) H2(0.1406) H18(-0.1521) H6A(-0.2564) H20(-0.0214) H11(-
 0.046) H4(-0.0187) H14(-0.0193) H10(0.0177) H28(0.4015) H30(0.4317) H16(-
 0.1674) H12(-0.0913) H29(0.4366) H27(0.3463) H26(0.2948) H25(0.2496)
 H23(0.2683) H24(0.2278)
 Fixed Z: H6(0.7637) H2(0.9783) H18(0.7464) H6A(0.9179) H20(0.7475)
 H11(1.1407) H4(0.7651) H14(0.8087) H10(1.063) H28(1.0246) H30(0.8707)
 H16(0.9689) H12(1.0545) H29(0.8822) H27(1.1952) H26(1.3135) H25(1.3686)
 H23(1.1855) H24(1.3325)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.606785(16) 0.398908(11) 1.001856(13) 0.01282(6) Uani 1 1 d . . .
O1 O 0.5844(3) 0.29131(17) 0.8855(2) 0.0296(7) Uani 1 1 d . . .
O2 O 0.5059(3) 0.27167(17) 0.99986(19) 0.0257(7) Uani 1 1 d . . .
O8 O -0.2569(3) 0.01094(18) 0.6072(2) 0.0302(7) Uani 1 1 d . . .
O4 O 0.3867(2) -0.01016(17) 0.6149(2) 0.0272(7) Uani 1 1 d . . .
O7 O -0.4052(2) -0.07611(18) 0.5896(2) 0.0314(8) Uani 1 1 d . . .
O3 O 0.5214(3) 0.08752(16) 0.62606(19) 0.0250(7) Uani 1 1 d . . .
N1 N 0.8281(3) 0.3835(2) 0.9951(2) 0.0260(8) Uani 1 1 d . . .
N2 N 0.7558(3) 0.3147(2) 1.1331(2) 0.0271(8) Uani 1 1 d . . .
C7 C 0.4489(3) 0.0488(2) 0.6566(3) 0.0184(8) Uani 1 1 d . . .
C6 C 0.4858(4) 0.1464(2) 0.7928(3) 0.0226(9) Uani 1 1 d . . .
H6 H 0.5295 0.1776 0.7637 0.027 Uiso 1 1 calc R . .
C2 C 0.4063(4) 0.1241(2) 0.9206(3) 0.0230(9) Uani 1 1 d . . .
H2 H 0.3980 0.1406 0.9783 0.028 Uiso 1 1 calc R . .
C18 C -0.2820(4) -0.1364(3) 0.7763(3) 0.0252(9) Uani 1 1 d . . .
H18 H -0.3630 -0.1521 0.7464 0.030 Uiso 1 1 calc R . .
C3 C 0.3523(3) 0.0525(2) 0.8797(3) 0.0209(9) Uani 1 1 d . . .
C15 C -0.0351(4) -0.0889(2) 0.8680(3) 0.0242(9) Uani 1 1 d . . .
O6 O -0.3866(3) -0.2282(2) 0.8833(2) 0.0440(9) Uani 1 1 d . . .
H6A H -0.4116 -0.2564 0.9179 0.066 Uiso 1 1 calc R . .
C19 C -0.2279(4) -0.0837(2) 0.7310(3) 0.0222(9) Uani 1 1 d . . .
C20 C -0.1066(3) -0.0588(3) 0.7774(3) 0.0232(9) Uani 1 1 d . . .
H20 H -0.0727 -0.0214 0.7475 0.028 Uiso 1 1 calc R . .
C8 C 0.5243(4) 0.2489(2) 0.9236(3) 0.0195(9) Uani 1 1 d . . .
C11 C 0.2542(4) -0.0396(3) 1.0740(3) 0.0312(11) Uani 1 1 d . . .
H11 H 0.2852 -0.0460 1.1407 0.037 Uiso 1 1 calc R . .
C33 C 0.9180(4) 0.3589(2) 1.0783(3) 0.0256(10) Uani 1 1 d . . .
C9 C 0.2797(3) 0.0065(2) 0.9271(3) 0.0225(9) Uani 1 1 d . . .
C5 C 0.4356(4) 0.0752(2) 0.7502(3) 0.0211(9) Uani 1 1 d . . .
C4 C 0.3692(3) 0.0289(2) 0.7937(3) 0.0219(9) Uani 1 1 d . . .
H4 H 0.3354 -0.0187 0.7651 0.026 Uiso 1 1 calc R . .
C14 C 0.1646(4) -0.0239(3) 0.8756(3) 0.0265(10) Uani 1 1 d . . .
H14 H 0.1353 -0.0193 0.8087 0.032 Uiso 1 1 calc R . .
O5 O -0.2093(3) -0.2429(2) 1.0041(2) 0.0457(9) Uani 1 1 d . . .
C10 C 0.3236(4) -0.0021(3) 1.0273(3) 0.0290(10) Uani 1 1 d . . .
H10 H 0.4007 0.0177 1.0630 0.035 Uiso 1 1 calc R . .
C28 C 1.0770(4) 0.3965(3) 1.0176(4) 0.0424(12) Uani 1 1 d . . .
H28 H 1.1595 0.4015 1.0246 0.051 Uiso 1 1 calc R . .
C30 C 0.8659(4) 0.4131(3) 0.9269(3) 0.0367(12) Uani 1 1 d . . .
H30 H 0.8067 0.4317 0.8707 0.044 Uiso 1 1 calc R . .
C22 C -0.3009(4) -0.0474(3) 0.6353(3) 0.0227(9) Uani 1 1 d . . .
C13 C 0.0918(4) -0.0610(3) 0.9208(3) 0.0246(9) Uani 1 1 d . . .
C21 C -0.2675(4) -0.2164(3) 0.9249(3) 0.0301(10) Uani 1 1 d . . .
C16 C -0.0910(4) -0.1443(3) 0.9104(3) 0.0288(10) Uani 1 1 d . . .
H16 H -0.0451 -0.1674 0.9689 0.035 Uiso 1 1 calc R . .
C32 C 0.8789(4) 0.3235(3) 1.1520(3) 0.0271(10) Uani 1 1 d . . .
C31 C 0.9684(4) 0.2988(3) 1.2395(3) 0.0366(12) Uani 1 1 d . . .
C12 C 0.1391(4) -0.0676(3) 1.0221(3) 0.0303(11) Uani 1 1 d . . .
H12 H 0.0919 -0.0913 1.0545 0.036 Uiso 1 1 calc R . .
C17 C -0.2139(4) -0.1658(3) 0.8671(3) 0.0257(10) Uani 1 1 d . . .
C29 C 0.9905(5) 0.4184(3) 0.9339(4) 0.0480(14) Uani 1 1 d . . .
H29 H 1.0121 0.4366 0.8822 0.058 Uiso 1 1 calc R . .
C34 C 1.0442(4) 0.3661(3) 1.0944(4) 0.0341(11) Uani 1 1 d . . .
C27 C 1.1306(4) 0.3409(3) 1.1847(4) 0.0458(14) Uani 1 1 d . . .
H27 H 1.2140 0.3463 1.1952 0.055 Uiso 1 1 calc R . .
C26 C 1.0951(4) 0.3094(3) 1.2550(4) 0.0473(14) Uani 1 1 d . . .
H26 H 1.1535 0.2948 1.3135 0.057 Uiso 1 1 calc R . .
C25 C 0.9262(5) 0.2643(3) 1.3088(4) 0.0489(15) Uani 1 1 d . . .
H25 H 0.9817 0.2496 1.3686 0.059 Uiso 1 1 calc R . .
C23 C 0.7222(4) 0.2778(3) 1.1994(3) 0.0406(12) Uani 1 1 d . . .
H23 H 0.6389 0.2683 1.1855 0.049 Uiso 1 1 calc R . .
C24 C 0.8022(5) 0.2523(3) 1.2882(4) 0.0522(15) Uani 1 1 d . . .
H24 H 0.7728 0.2278 1.3325 0.063 Uiso 1 1 calc R . .
C1 C 0.4717(3) 0.1713(2) 0.8779(3) 0.0185(8) Uani 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 Eu1 4.2067(7) 3_667 ?
Eu1 O1 2.450(3) . ?
Eu1 O2 2.442(3) . ?
Eu1 O8 2.356(3) 4_666 ?
Eu1 O4 2.325(3) 2_656 ?
Eu1 O7 2.303(3) 2_556 ?
Eu1 O3 2.369(3) 4_566 ?
Eu1 N1 2.614(4) . ?
Eu1 N2 2.543(3) . ?
Eu1 C8 2.812(4) . ?
Eu1 C22 3.140(4) 4_666 ?
O1 C8 1.257(5) . ?
O2 C8 1.271(5) . ?
O8 Eu1 2.356(3) 4_465 ?
O8 C22 1.243(5) . ?
O4 Eu1 2.325(3) 2_646 ?
O4 C7 1.260(5) . ?
O7 Eu1 2.303(3) 2_546 ?
O7 C22 1.263(5) . ?
O3 Eu1 2.369(3) 4_565 ?
O3 C7 1.262(5) . ?
N1 C33 1.375(5) . ?
N1 C30 1.323(6) . ?
N2 C32 1.366(5) . ?
N2 C23 1.322(6) . ?
C7 C5 1.506(5) . ?
C6 H6 0.9300 . ?
C6 C5 1.389(5) . ?
C6 C1 1.384(5) . ?
C2 H2 0.9300 . ?
C2 C3 1.399(5) . ?
C2 C1 1.390(5) . ?
C18 H18 0.9300 . ?
C18 C19 1.384(6) . ?
C18 C17 1.391(6) . ?
C3 C9 1.484(6) . ?
C3 C4 1.402(5) . ?
C15 C20 1.404(5) . ?
C15 C13 1.487(5) . ?
C15 C16 1.401(6) . ?
O6 H6A 0.8200 . ?
O6 C21 1.321(5) . ?
C19 C20 1.402(5) . ?
C19 C22 1.505(5) . ?
C20 H20 0.9300 . ?
C8 C1 1.504(5) . ?
C11 H11 0.9300 . ?
C11 C10 1.379(6) . ?
C11 C12 1.375(6) . ?
C33 C32 1.441(6) . ?
C33 C34 1.405(6) . ?
C9 C14 1.390(5) . ?
C9 C10 1.394(5) . ?
C5 C4 1.397(6) . ?
C4 H4 0.9300 . ?
C14 H14 0.9300 . ?
C14 C13 1.389(6) . ?
O5 C21 1.217(5) . ?
C10 H10 0.9300 . ?
C28 H28 0.9300 . ?
C28 C29 1.349(7) . ?
C28 C34 1.408(7) . ?
C30 H30 0.9300 . ?
C30 C29 1.415(7) . ?
C22 Eu1 3.140(4) 4_465 ?
C13 C12 1.408(6) . ?
C21 C17 1.483(6) . ?
C16 H16 0.9300 . ?
C16 C17 1.396(6) . ?
C32 C31 1.414(6) . ?
C31 C26 1.419(7) . ?
C31 C25 1.399(7) . ?
C12 H12 0.9300 . ?
C29 H29 0.9300 . ?
C34 C27 1.430(7) . ?
C27 H27 0.9300 . ?
C27 C26 1.346(7) . ?
C26 H26 0.9300 . ?
C25 H25 0.9300 . ?
C25 C24 1.380(7) . ?
C23 H23 0.9300 . ?
C23 C24 1.389(6) . ?
C24 H24 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 Eu1 132.17(7) . 3_667 ?
O1 Eu1 N1 76.76(10) . . ?
O1 Eu1 N2 89.96(11) . . ?
O1 Eu1 C8 26.50(10) . . ?
O1 Eu1 C22 164.21(10) . 4_666 ?
O2 Eu1 Eu1 115.90(7) . 3_667 ?
O2 Eu1 O1 53.32(9) . . ?
O2 Eu1 N1 112.59(10) . . ?
O2 Eu1 N2 73.46(11) . . ?
O2 Eu1 C8 26.84(10) . . ?
O2 Eu1 C22 140.34(10) . 4_666 ?
O8 Eu1 Eu1 75.15(7) 4_666 3_667 ?
O8 Eu1 O1 145.82(10) 4_666 . ?
O8 Eu1 O2 141.96(10) 4_666 . ?
O8 Eu1 O3 78.00(10) 4_666 4_566 ?
O8 Eu1 N1 69.07(11) 4_666 . ?
O8 Eu1 N2 74.43(11) 4_666 . ?
O8 Eu1 C8 155.50(11) 4_666 . ?
O8 Eu1 C22 20.43(10) 4_666 4_666 ?
O4 Eu1 Eu1 67.76(7) 2_656 3_667 ?
O4 Eu1 O1 89.74(10) 2_656 . ?
O4 Eu1 O2 135.10(10) 2_656 . ?
O4 Eu1 O8 82.90(11) 2_656 4_666 ?
O4 Eu1 O3 129.36(10) 2_656 4_566 ?
O4 Eu1 N1 76.00(10) 2_656 . ?
O4 Eu1 N2 138.29(11) 2_656 . ?
O4 Eu1 C8 112.60(11) 2_656 . ?
O4 Eu1 C22 81.10(11) 2_656 4_666 ?
O7 Eu1 Eu1 50.84(8) 2_556 3_667 ?
O7 Eu1 O1 83.25(11) 2_556 . ?
O7 Eu1 O2 76.58(10) 2_556 . ?
O7 Eu1 O8 125.84(11) 2_556 4_666 ?
O7 Eu1 O4 74.27(10) 2_556 2_656 ?
O7 Eu1 O3 79.98(10) 2_556 4_566 ?
O7 Eu1 N1 144.01(11) 2_556 . ?
O7 Eu1 N2 146.89(11) 2_556 . ?
O7 Eu1 C8 77.88(11) 2_556 . ?
O7 Eu1 C22 106.31(11) 2_556 4_666 ?
O3 Eu1 Eu1 62.14(7) 4_566 3_667 ?
O3 Eu1 O1 129.73(10) 4_566 . ?
O3 Eu1 O2 76.70(9) 4_566 . ?
O3 Eu1 N1 135.46(10) 4_566 . ?
O3 Eu1 N2 79.71(10) 4_566 . ?
O3 Eu1 C8 103.31(11) 4_566 . ?
O3 Eu1 C22 65.32(10) 4_566 4_666 ?
N1 Eu1 Eu1 131.38(7) . 3_667 ?
N1 Eu1 C8 95.50(11) . . ?
N1 Eu1 C22 88.51(11) . 4_666 ?
N2 Eu1 Eu1 135.07(8) . 3_667 ?
N2 Eu1 N1 63.40(11) . . ?
N2 Eu1 C8 81.70(11) . . ?
N2 Eu1 C22 88.43(11) . 4_666 ?
C8 Eu1 Eu1 127.55(8) . 3_667 ?
C8 Eu1 C22 166.27(11) . 4_666 ?
C22 Eu1 Eu1 55.49(8) 4_666 3_667 ?
C8 O1 Eu1 93.0(2) . . ?
C8 O2 Eu1 93.0(2) . . ?
C22 O8 Eu1 118.2(3) . 4_465 ?
C7 O4 Eu1 136.5(3) . 2_646 ?
C22 O7 Eu1 167.9(3) . 2_546 ?
C7 O3 Eu1 146.0(3) . 4_565 ?
C33 N1 Eu1 116.8(3) . . ?
C30 N1 Eu1 125.0(3) . . ?
C30 N1 C33 116.4(4) . . ?
C32 N2 Eu1 119.1(3) . . ?
C23 N2 Eu1 122.0(3) . . ?
C23 N2 C32 116.8(4) . . ?
O4 C7 O3 125.1(4) . . ?
O4 C7 C5 117.4(3) . . ?
O3 C7 C5 117.5(3) . . ?
C5 C6 H6 119.6 . . ?
C1 C6 H6 119.6 . . ?
C1 C6 C5 120.8(4) . . ?
C3 C2 H2 118.9 . . ?
C1 C2 H2 118.9 . . ?
C1 C2 C3 122.2(4) . . ?
C19 C18 H18 120.3 . . ?
C19 C18 C17 119.4(4) . . ?
C17 C18 H18 120.3 . . ?
C2 C3 C9 119.4(4) . . ?
C2 C3 C4 117.1(4) . . ?
C4 C3 C9 123.4(4) . . ?
C20 C15 C13 122.7(4) . . ?
C16 C15 C20 116.9(4) . . ?
C16 C15 C13 120.3(4) . . ?
C21 O6 H6A 109.5 . . ?
C18 C19 C20 120.1(4) . . ?
C18 C19 C22 120.7(4) . . ?
C20 C19 C22 119.0(4) . . ?
C15 C20 H20 119.2 . . ?
C19 C20 C15 121.6(4) . . ?
C19 C20 H20 119.2 . . ?
O1 C8 Eu1 60.4(2) . . ?
O1 C8 O2 120.5(4) . . ?
O1 C8 C1 119.9(4) . . ?
O2 C8 Eu1 60.1(2) . . ?
O2 C8 C1 119.6(4) . . ?
C1 C8 Eu1 176.0(3) . . ?
C10 C11 H11 119.9 . . ?
C12 C11 H11 119.9 . . ?
C12 C11 C10 120.1(4) . . ?
N1 C33 C32 117.3(4) . . ?
N1 C33 C34 123.6(4) . . ?
C34 C33 C32 119.0(4) . . ?
C14 C9 C3 122.0(4) . . ?
C14 C9 C10 118.4(4) . . ?
C10 C9 C3 119.5(3) . . ?
C6 C5 C7 120.7(4) . . ?
C6 C5 C4 119.3(4) . . ?
C4 C5 C7 119.9(4) . . ?
C3 C4 H4 119.3 . . ?
C5 C4 C3 121.5(4) . . ?
C5 C4 H4 119.3 . . ?
C9 C14 H14 118.9 . . ?
C13 C14 C9 122.2(4) . . ?
C13 C14 H14 118.9 . . ?
C11 C10 C9 120.7(4) . . ?
C11 C10 H10 119.6 . . ?
C9 C10 H10 119.6 . . ?
C29 C28 H28 119.5 . . ?
C29 C28 C34 120.9(5) . . ?
C34 C28 H28 119.5 . . ?
N1 C30 H30 117.9 . . ?
N1 C30 C29 124.2(5) . . ?
C29 C30 H30 117.9 . . ?
O8 C22 Eu1 41.41(19) . 4_465 ?
O8 C22 O7 123.6(4) . . ?
O8 C22 C19 118.1(3) . . ?
O7 C22 Eu1 85.0(2) . 4_465 ?
O7 C22 C19 118.3(4) . . ?
C19 C22 Eu1 151.0(3) . 4_465 ?
C14 C13 C15 123.1(4) . . ?
C14 C13 C12 117.5(4) . . ?
C12 C13 C15 119.2(4) . . ?
O6 C21 C17 113.4(4) . . ?
O5 C21 O6 122.7(4) . . ?
O5 C21 C17 123.9(4) . . ?
C15 C16 H16 119.2 . . ?
C17 C16 C15 121.6(4) . . ?
C17 C16 H16 119.2 . . ?
N2 C32 C33 117.8(4) . . ?
N2 C32 C31 123.0(4) . . ?
C31 C32 C33 119.2(4) . . ?
C32 C31 C26 120.4(5) . . ?
C25 C31 C32 117.2(4) . . ?
C25 C31 C26 122.4(4) . . ?
C11 C12 C13 121.0(4) . . ?
C11 C12 H12 119.5 . . ?
C13 C12 H12 119.5 . . ?
C18 C17 C21 123.1(4) . . ?
C18 C17 C16 120.2(4) . . ?
C16 C17 C21 116.7(4) . . ?
C28 C29 C30 118.2(5) . . ?
C28 C29 H29 120.9 . . ?
C30 C29 H29 120.9 . . ?
C33 C34 C28 116.5(4) . . ?
C33 C34 C27 119.4(5) . . ?
C28 C34 C27 124.1(4) . . ?
C34 C27 H27 118.9 . . ?
C26 C27 C34 122.1(5) . . ?
C26 C27 H27 118.9 . . ?
C31 C26 H26 120.1 . . ?
C27 C26 C31 119.8(5) . . ?
C27 C26 H26 120.1 . . ?
C31 C25 H25 120.1 . . ?
C24 C25 C31 119.8(4) . . ?
C24 C25 H25 120.1 . . ?
N2 C23 H23 117.6 . . ?
N2 C23 C24 124.8(5) . . ?
C24 C23 H23 117.6 . . ?
C25 C24 C23 118.2(5) . . ?
C25 C24 H24 120.9 . . ?
C23 C24 H24 120.9 . . ?
C6 C1 C2 119.1(4) . . ?
C6 C1 C8 121.0(4) . . ?
C2 C1 C8 119.9(4) . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O6 H6A O2 0.82 1.90 2.652(4) 151.0 3_557

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 Eu1 O1 C8 -91.5(2) 3_667 . . . ?
Eu1 Eu1 O2 C8 122.7(2) 3_667 . . . ?
Eu1 Eu1 N1 C33 109.4(3) 3_667 . . . ?
Eu1 Eu1 N1 C30 -55.2(4) 3_667 . . . ?
Eu1 Eu1 N2 C32 -103.1(3) 3_667 . . . ?
Eu1 Eu1 N2 C23 59.6(4) 3_667 . . . ?
Eu1 Eu1 C8 O1 110.9(2) 3_667 . . . ?
Eu1 Eu1 C8 O2 -72.6(2) 3_667 . . . ?
Eu1 Eu1 C8 C1 15(4) 3_667 . . . ?
Eu1 O1 C8 O2 -3.5(4) . . . . ?
Eu1 O1 C8 C1 175.4(3) . . . . ?
Eu1 O2 C8 O1 3.5(4) . . . . ?
Eu1 O2 C8 C1 -175.4(3) . . . . ?
Eu1 O8 C22 O7 24.3(6) 4_465 . . . ?
Eu1 O8 C22 C19 -153.3(3) 4_465 . . . ?
Eu1 O4 C7 O3 19.2(6) 2_646 . . . ?
Eu1 O4 C7 C5 -160.9(3) 2_646 . . . ?
Eu1 O7 C22 Eu1 -20.2(14) 2_546 . . 4_465 ?
Eu1 O7 C22 O8 -36.0(17) 2_546 . . . ?
Eu1 O7 C22 C19 141.6(12) 2_546 . . . ?
Eu1 O3 C7 O4 0.6(7) 4_565 . . . ?
Eu1 O3 C7 C5 -179.3(3) 4_565 . . . ?
Eu1 N1 C33 C32 16.6(5) . . . . ?
Eu1 N1 C33 C34 -163.9(3) . . . . ?
Eu1 N1 C30 C29 166.5(4) . . . . ?
Eu1 N2 C32 C33 -20.2(5) . . . . ?
Eu1 N2 C32 C31 160.3(3) . . . . ?
Eu1 N2 C23 C24 -158.8(4) . . . . ?
Eu1 C8 C1 C6 92(4) . . . . ?
Eu1 C8 C1 C2 -87(4) . . . . ?
O1 Eu1 O2 C8 -1.9(2) . . . . ?
O1 Eu1 N1 C33 -115.3(3) . . . . ?
O1 Eu1 N1 C30 80.2(4) . . . . ?
O1 Eu1 N2 C32 95.1(3) . . . . ?
O1 Eu1 N2 C23 -102.2(4) . . . . ?
O1 Eu1 C8 O2 176.5(4) . . . . ?
O1 Eu1 C8 C1 -96(4) . . . . ?
O1 C8 C1 C6 -1.6(6) . . . . ?
O1 C8 C1 C2 179.4(4) . . . . ?
O2 Eu1 O1 C8 2.0(2) . . . . ?
O2 Eu1 N1 C33 -74.9(3) . . . . ?
O2 Eu1 N1 C30 120.5(4) . . . . ?
O2 Eu1 N2 C32 146.5(3) . . . . ?
O2 Eu1 N2 C23 -50.7(4) . . . . ?
O2 Eu1 C8 O1 -176.5(4) . . . . ?
O2 Eu1 C8 C1 88(4) . . . . ?
O2 C8 C1 C6 177.3(4) . . . . ?
O2 C8 C1 C2 -1.7(6) . . . . ?
O8 Eu1 O1 C8 132.6(2) 4_666 . . . ?
O8 Eu1 O2 C8 -138.2(2) 4_666 . . . ?
O8 Eu1 N1 C33 64.0(3) 4_666 . . . ?
O8 Eu1 N1 C30 -100.5(4) 4_666 . . . ?
O8 Eu1 N2 C32 -54.1(3) 4_666 . . . ?
O8 Eu1 N2 C23 108.6(4) 4_666 . . . ?
O8 Eu1 C8 O1 -94.0(3) 4_666 . . . ?
O8 Eu1 C8 O2 82.5(4) 4_666 . . . ?
O8 Eu1 C8 C1 170(4) 4_666 . . . ?
O4 Eu1 O1 C8 -150.5(2) 2_656 . . . ?
O4 Eu1 O2 C8 39.0(3) 2_656 . . . ?
O4 Eu1 N1 C33 151.7(3) 2_656 . . . ?
O4 Eu1 N1 C30 -12.8(3) 2_656 . . . ?
O4 Eu1 N2 C32 5.5(4) 2_656 . . . ?
O4 Eu1 N2 C23 168.2(3) 2_656 . . . ?
O4 Eu1 C8 O1 32.2(3) 2_656 . . . ?
O4 Eu1 C8 O2 -151.2(2) 2_656 . . . ?
O4 Eu1 C8 C1 -64(4) 2_656 . . . ?
O4 C7 C5 C6 -170.0(4) . . . . ?
O4 C7 C5 C4 8.3(5) . . . . ?
O7 Eu1 O1 C8 -76.3(2) 2_556 . . . ?
O7 Eu1 O2 C8 89.6(2) 2_556 . . . ?
O7 Eu1 N1 C33 -173.3(3) 2_556 . . . ?
O7 Eu1 N1 C30 22.2(4) 2_556 . . . ?
O7 Eu1 N2 C32 172.6(3) 2_556 . . . ?
O7 Eu1 N2 C23 -24.7(5) 2_556 . . . ?
O7 Eu1 C8 O1 99.3(2) 2_556 . . . ?
O7 Eu1 C8 O2 -84.2(2) 2_556 . . . ?
O7 Eu1 C8 C1 3(4) 2_556 . . . ?
O3 Eu1 O1 C8 -5.3(3) 4_566 . . . ?
O3 Eu1 O2 C8 172.3(2) 4_566 . . . ?
O3 Eu1 N1 C33 18.9(3) 4_566 . . . ?
O3 Eu1 N1 C30 -145.6(3) 4_566 . . . ?
O3 Eu1 N2 C32 -134.4(3) 4_566 . . . ?
O3 Eu1 N2 C23 28.3(4) 4_566 . . . ?
O3 Eu1 C8 O1 175.8(2) 4_566 . . . ?
O3 Eu1 C8 O2 -7.7(2) 4_566 . . . ?
O3 Eu1 C8 C1 80(4) 4_566 . . . ?
O3 C7 C5 C6 9.9(5) . . . . ?
O3 C7 C5 C4 -171.8(4) . . . . ?
N1 Eu1 O1 C8 133.8(2) . . . . ?
N1 Eu1 O2 C8 -53.7(2) . . . . ?
N1 Eu1 N2 C32 19.9(3) . . . . ?
N1 Eu1 N2 C23 -177.4(4) . . . . ?
N1 Eu1 C8 O1 -44.9(2) . . . . ?
N1 Eu1 C8 O2 131.7(2) . . . . ?
N1 Eu1 C8 C1 -141(4) . . . . ?
N1 C33 C32 N2 1.8(6) . . . . ?
N1 C33 C32 C31 -178.8(4) . . . . ?
N1 C33 C34 C28 -3.4(7) . . . . ?
N1 C33 C34 C27 178.2(4) . . . . ?
N1 C30 C29 C28 -4.3(8) . . . . ?
N2 Eu1 O1 C8 71.2(2) . . . . ?
N2 Eu1 O2 C8 -104.7(2) . . . . ?
N2 Eu1 N1 C33 -18.5(3) . . . . ?
N2 Eu1 N1 C30 177.0(4) . . . . ?
N2 Eu1 C8 O1 -106.9(2) . . . . ?
N2 Eu1 C8 O2 69.6(2) . . . . ?
N2 Eu1 C8 C1 157(4) . . . . ?
N2 C32 C31 C26 180.0(4) . . . . ?
N2 C32 C31 C25 -0.3(7) . . . . ?
N2 C23 C24 C25 -1.6(9) . . . . ?
C7 C5 C4 C3 -178.4(4) . . . . ?
C6 C5 C4 C3 -0.1(6) . . . . ?
C2 C3 C9 C14 132.5(4) . . . . ?
C2 C3 C9 C10 -42.9(6) . . . . ?
C2 C3 C4 C5 -0.8(6) . . . . ?
C18 C19 C20 C15 3.1(6) . . . . ?
C18 C19 C22 Eu1 127.7(5) . . . 4_465 ?
C18 C19 C22 O8 165.5(4) . . . . ?
C18 C19 C22 O7 -12.2(6) . . . . ?
C3 C2 C1 C6 -1.0(6) . . . . ?
C3 C2 C1 C8 178.1(4) . . . . ?
C3 C9 C14 C13 -174.3(4) . . . . ?
C3 C9 C10 C11 175.3(4) . . . . ?
C15 C13 C12 C11 -177.3(4) . . . . ?
C15 C16 C17 C18 4.7(7) . . . . ?
C15 C16 C17 C21 -171.9(4) . . . . ?
O6 C21 C17 C18 -2.4(6) . . . . ?
O6 C21 C17 C16 174.0(4) . . . . ?
C19 C18 C17 C21 174.1(4) . . . . ?
C19 C18 C17 C16 -2.2(7) . . . . ?
C20 C15 C13 C14 -21.5(7) . . . . ?
C20 C15 C13 C12 154.5(4) . . . . ?
C20 C15 C16 C17 -3.1(7) . . . . ?
C20 C19 C22 Eu1 -47.4(8) . . . 4_465 ?
C20 C19 C22 O8 -9.6(6) . . . . ?
C20 C19 C22 O7 172.7(4) . . . . ?
C8 Eu1 N1 C33 -96.4(3) . . . . ?
C8 Eu1 N1 C30 99.1(4) . . . . ?
C8 Eu1 N2 C32 120.3(3) . . . . ?
C8 Eu1 N2 C23 -76.9(4) . . . . ?
C33 N1 C30 C29 2.0(7) . . . . ?
C33 C32 C31 C26 0.5(7) . . . . ?
C33 C32 C31 C25 -179.7(4) . . . . ?
C33 C34 C27 C26 0.8(8) . . . . ?
C9 C3 C4 C5 178.3(4) . . . . ?
C9 C14 C13 C15 175.5(4) . . . . ?
C9 C14 C13 C12 -0.5(7) . . . . ?
C5 C6 C1 C2 0.0(6) . . . . ?
C5 C6 C1 C8 -179.1(3) . . . . ?
C4 C3 C9 C14 -46.5(6) . . . . ?
C4 C3 C9 C10 138.1(4) . . . . ?
C14 C9 C10 C11 -0.3(7) . . . . ?
C14 C13 C12 C11 -1.2(7) . . . . ?
O5 C21 C17 C18 179.6(5) . . . . ?
O5 C21 C17 C16 -4.0(7) . . . . ?
C10 C11 C12 C13 2.1(7) . . . . ?
C10 C9 C14 C13 1.2(7) . . . . ?
C28 C34 C27 C26 -177.5(5) . . . . ?
C30 N1 C33 C32 -177.5(4) . . . . ?
C30 N1 C33 C34 2.0(6) . . . . ?
C22 Eu1 O1 C8 155.3(3) 4_666 . . . ?
C22 Eu1 O2 C8 -170.9(2) 4_666 . . . ?
C22 Eu1 N1 C33 70.5(3) 4_666 . . . ?
C22 Eu1 N1 C30 -94.1(4) 4_666 . . . ?
C22 Eu1 N2 C32 -69.2(3) 4_666 . . . ?
C22 Eu1 N2 C23 93.5(4) 4_666 . . . ?
C22 Eu1 C8 O1 -151.4(4) 4_666 . . . ?
C22 Eu1 C8 O2 25.2(6) 4_666 . . . ?
C22 Eu1 C8 C1 113(4) 4_666 . . . ?
C22 C19 C20 C15 178.2(4) . . . . ?
C13 C15 C20 C19 -177.2(4) . . . . ?
C13 C15 C16 C17 173.5(4) . . . . ?
C16 C15 C20 C19 -0.7(6) . . . . ?
C16 C15 C13 C14 162.1(4) . . . . ?
C16 C15 C13 C12 -21.9(6) . . . . ?
C32 N2 C23 C24 4.3(7) . . . . ?
C32 C33 C34 C28 176.0(4) . . . . ?
C32 C33 C34 C27 -2.4(7) . . . . ?
C32 C31 C26 C27 -2.2(8) . . . . ?
C32 C31 C25 C24 3.1(8) . . . . ?
C31 C25 C24 C23 -2.3(9) . . . . ?
C12 C11 C10 C9 -1.3(7) . . . . ?
C17 C18 C19 C20 -1.5(6) . . . . ?
C17 C18 C19 C22 -176.6(4) . . . . ?
C29 C28 C34 C33 1.0(7) . . . . ?
C29 C28 C34 C27 179.3(5) . . . . ?
C34 C33 C32 N2 -177.7(4) . . . . ?
C34 C33 C32 C31 1.7(6) . . . . ?
C34 C28 C29 C30 2.5(8) . . . . ?
C34 C27 C26 C31 1.5(8) . . . . ?
C26 C31 C25 C24 -177.2(5) . . . . ?
C25 C31 C26 C27 178.1(5) . . . . ?
C23 N2 C32 C33 176.2(4) . . . . ?
C23 N2 C32 C31 -3.3(7) . . . . ?
C1 C6 C5 C7 178.8(4) . . . . ?
C1 C6 C5 C4 0.6(6) . . . . ?
C1 C2 C3 C9 -177.7(4) . . . . ?
C1 C2 C3 C4 1.4(6) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
