data_2
_audit_creation_date               2021-07-22
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number       '2018/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C20 H19 Cl N2 O Pt, C H Cl3'
_chemical_formula_sum              'C21 H20 Cl4 N2 O Pt'
_chemical_formula_weight           653.28
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Pt' 'Pt' -1.7033 8.3905
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     11.0564(7)
_cell_length_b                     14.0350(9)
_cell_length_c                     16.4321(10)
_cell_angle_alpha                  113.018(2)
_cell_angle_beta                   99.705(2)
_cell_angle_gamma                  100.551(2)
_cell_volume                       2224.4(2)
_cell_formula_units_Z              4
_cell_measurement_reflns_used      9822
_cell_measurement_temperature      150.0
_cell_measurement_theta_max        30.53
_cell_measurement_theta_min        2.58
_shelx_estimated_absorpt_T_max     0.686
_shelx_estimated_absorpt_T_min     0.199
_exptl_absorpt_coefficient_mu      6.804
_exptl_absorpt_correction_T_max    0.7461
_exptl_absorpt_correction_T_min    0.4108
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1362 before and 0.0598 after correction.
The Ratio of minimum to maximum transmission is 0.5506.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              orange
_exptl_crystal_colour_primary      orange
_exptl_crystal_density_diffrn      1.951
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         block
_exptl_crystal_F_000               1256
_exptl_crystal_size_max            0.35
_exptl_crystal_size_mid            0.14
_exptl_crystal_size_min            0.06
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_radiation_monochromator    'TRIUMPH curved--crystal'
_diffrn_reflns_av_R_equivalents    0.0468
_diffrn_reflns_av_unetI/netI       0.0377
_diffrn_reflns_Laue_measured_fraction_full  0.998
_diffrn_reflns_Laue_measured_fraction_max  0.995
_diffrn_reflns_limit_h_max         15
_diffrn_reflns_limit_h_min         -15
_diffrn_reflns_limit_k_max         20
_diffrn_reflns_limit_k_min         -20
_diffrn_reflns_limit_l_max         23
_diffrn_reflns_limit_l_min         -23
_diffrn_reflns_number              61734
_diffrn_reflns_point_group_measured_fraction_full  0.998
_diffrn_reflns_point_group_measured_fraction_max  0.995
_diffrn_reflns_reduction_process   narrow--frame
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           30.591
_diffrn_reflns_theta_min           2.550
_diffrn_ambient_temperature        150.0
_diffrn_ambient_temp_esd                2.0
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.998
_diffrn_measured_fraction_theta_max  0.995
_diffrn_measurement_device_type    'Bruker D8 QUEST ECO CMOS'
_diffrn_measurement_method         'φ and ω scans'
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     'fine--focus tube'
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  10931
_reflns_number_total               13610
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         ?
_computing_data_collection         ?
_computing_data_reduction          ?
_computing_molecular_graphics      'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement    'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution      'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max           1.784
_refine_diff_density_min           -1.569
_refine_diff_density_rms           0.157
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.043
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       531
_refine_ls_number_reflns           13610
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0509
_refine_ls_R_factor_gt             0.0335
_refine_ls_restrained_S_all        1.043
_refine_ls_shift/su_max            0.002
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+9.7058P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0590
_refine_ls_wR_factor_ref           0.0652
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C42(H42), C41(H41)
2.b Aromatic/amide H refined with riding coordinates:
 C6(H6), C36(H36), C33(H33), C16(H16), C13(H13), C11(H11), C26(H26), C25(H25),
 C5(H5), C31(H31), C3(H3), C23(H23), C4(H4), C24(H24)
2.c Idealised Me refined as rotating group:
 C20(H20A,H20B,H20C), C14(H14A,H14B,H14C), C40(H40A,H40B,H40C), C39(H39A,H39B,
 H39C), C19(H19A,H19B,H19C), C34(H34A,H34B,H34C), C18(H18A,H18B,H18C), C38(H38A,
 H38B,H38C)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Pt2 Pt 0.26481(2) 0.77801(2) 0.61269(2) 0.02180(4) Uani 1 1 d . . . . .
 Pt1 Pt 0.53605(2) 0.71627(2) 0.83676(2) 0.02045(4) Uani 1 1 d . . . . .
 Cl1 Cl 0.75660(9) 0.76647(8) 0.85872(7) 0.0278(2) Uani 1 1 d . . . . .
 Cl2 Cl 0.40931(10) 0.76655(9) 0.52337(8) 0.0331(2) Uani 1 1 d . . . . .
 Cl8 Cl 0.36269(15) 0.98033(13) 0.41218(10) 0.0570(4) Uani 1 1 d . . . . .
 Cl4 Cl 0.67940(15) 0.53515(13) 1.00852(10) 0.0549(3) Uani 1 1 d . . . . .
 Cl7 Cl 0.2106(2) 0.75955(14) 0.29907(12) 0.0711(5) Uani 1 1 d . . . . .
 Cl6 Cl 0.09604(17) 0.91896(15) 0.40202(16) 0.0788(5) Uani 1 1 d . . . . .
 Cl3 Cl 0.8700(2) 0.5160(3) 0.9115(2) 0.1311(12) Uani 1 1 d . . . . .
 N1 N 0.4965(3) 0.8528(3) 0.8418(2) 0.0213(6) Uani 1 1 d . . . . .
 O2 O 0.2873(3) 0.9228(2) 0.6150(2) 0.0328(7) Uani 1 1 d . . . . .
 N2 N 0.3575(3) 0.6825(3) 0.8456(2) 0.0223(6) Uani 1 1 d . . . . .
 O1 O 0.5621(3) 0.5742(2) 0.8216(2) 0.0282(6) Uani 1 1 d . . . . .
 N3 N 0.2329(3) 0.6305(3) 0.6111(2) 0.0204(6) Uani 1 1 d . . . . .
 Cl5 Cl 0.9051(3) 0.7058(3) 1.0786(2) 0.1663(18) Uani 1 1 d . . . . .
 N4 N 0.1249(3) 0.7880(3) 0.6757(2) 0.0218(6) Uani 1 1 d . . . . .
 C9 C 0.3942(4) 0.8683(3) 0.8807(2) 0.0208(7) Uani 1 1 d . . . . .
 C10 C 0.3218(4) 0.7787(3) 0.8870(3) 0.0215(7) Uani 1 1 d . . . . .
 C1 C 0.5534(4) 0.9250(3) 0.8178(3) 0.0226(7) Uani 1 1 d . . . . .
 C29 C 0.1117(3) 0.6009(3) 0.6237(2) 0.0190(7) Uani 1 1 d . . . . .
 C30 C 0.0525(3) 0.6839(3) 0.6586(2) 0.0195(7) Uani 1 1 d . . . . .
 C21 C 0.3004(4) 0.5603(3) 0.5924(2) 0.0208(7) Uani 1 1 d . . . . .
 C6 C 0.4202(4) 1.1561(3) 0.9280(3) 0.0299(9) Uani 1 1 d . . . . .
 H6 H 0.357421 1.172653 0.960225 0.036 Uiso 1 1 calc R U . . .
 C15 C 0.2888(4) 0.5827(3) 0.8224(3) 0.0252(8) Uani 1 1 d . . . . .
 C8 C 0.3648(4) 0.9672(3) 0.9120(3) 0.0224(7) Uani 1 1 d . . . . .
 C35 C 0.0999(4) 0.8804(3) 0.7201(3) 0.0256(8) Uani 1 1 d . . . . .
 C2 C 0.5282(4) 1.0285(3) 0.8464(3) 0.0239(8) Uani 1 1 d . . . . .
 C7 C 0.4370(4) 1.0523(3) 0.8964(3) 0.0245(8) Uani 1 1 d . . . . .
 C28 C 0.0517(3) 0.4945(3) 0.6032(3) 0.0210(7) Uani 1 1 d . . . . .
 C36 C 0.1589(4) 0.9764(4) 0.7171(3) 0.0307(9) Uani 1 1 d . . . . .
 H36 H 0.140156 1.039182 0.756395 0.037 Uiso 1 1 calc R U . . .
 C33 C -0.0722(3) 0.4703(3) 0.6139(3) 0.0222(7) Uani 1 1 d . . . . .
 H33 H -0.114717 0.398160 0.599471 0.027 Uiso 1 1 calc R U . . .
 C16 C 0.3398(4) 0.4939(3) 0.7920(3) 0.0290(9) Uani 1 1 d . . . . .
 H16 H 0.279450 0.425330 0.766444 0.035 Uiso 1 1 calc R U . . .
 C20 C 0.6430(4) 0.8981(3) 0.7586(3) 0.0273(8) Uani 1 1 d . . . . .
 H20A H 0.729127 0.945398 0.792890 0.041 Uiso 1 1 calc R U . . .
 H20B H 0.614721 0.908292 0.703553 0.041 Uiso 1 1 calc R U . . .
 H20C H 0.643720 0.822935 0.740818 0.041 Uiso 1 1 calc R U . . .
 C27 C 0.1189(4) 0.4139(3) 0.5703(3) 0.0224(7) Uani 1 1 d . . . . .
 C22 C 0.2453(4) 0.4486(3) 0.5684(3) 0.0222(7) Uani 1 1 d . . . . .
 C14 C 0.1520(4) 0.5573(4) 0.8254(3) 0.0302(9) Uani 1 1 d . . . . .
 H14A H 0.148644 0.567929 0.887449 0.045 Uiso 1 1 calc R U . . .
 H14B H 0.108311 0.482287 0.781984 0.045 Uiso 1 1 calc R U . . .
 H14C H 0.109726 0.605096 0.808551 0.045 Uiso 1 1 calc R U . . .
 C13 C 0.2687(4) 0.9791(3) 0.9585(3) 0.0267(8) Uani 1 1 d . . . . .
 H13 H 0.248578 1.046011 0.981372 0.032 Uiso 1 1 calc R U . . .
 C40 C 0.4386(4) 0.5971(4) 0.5994(3) 0.0271(8) Uani 1 1 d . . . . .
 H40A H 0.452198 0.568985 0.537879 0.041 Uiso 1 1 calc R U . . .
 H40B H 0.487915 0.570428 0.636949 0.041 Uiso 1 1 calc R U . . .
 H40C H 0.466484 0.675916 0.627807 0.041 Uiso 1 1 calc R U . . .
 C32 C -0.1325(4) 0.5499(3) 0.6451(3) 0.0247(8) Uani 1 1 d . . . . .
 C11 C 0.2296(4) 0.7943(3) 0.9351(3) 0.0264(8) Uani 1 1 d . . . . .
 H11 H 0.183455 0.736322 0.943690 0.032 Uiso 1 1 calc R U . . .
 C37 C 0.2393(4) 0.9928(3) 0.6660(3) 0.0320(9) Uani 1 1 d . . . . .
 C26 C 0.0645(4) 0.3035(3) 0.5420(3) 0.0285(8) Uani 1 1 d . . . . .
 H26 H -0.020563 0.279071 0.543856 0.034 Uiso 1 1 calc R U . . .
 C17 C 0.4639(4) 0.4919(3) 0.7939(3) 0.0287(9) Uani 1 1 d . . . . .
 C25 C 0.1334(5) 0.2307(4) 0.5119(3) 0.0353(10) Uani 1 1 d . . . . .
 H25 H 0.094838 0.156264 0.492022 0.042 Uiso 1 1 calc R U . . .
 C12 C 0.2038(4) 0.8951(4) 0.9714(3) 0.0282(8) Uani 1 1 d . . . . .
 C5 C 0.4941(5) 1.2340(4) 0.9126(3) 0.0370(11) Uani 1 1 d . . . . .
 H5 H 0.483212 1.304523 0.935684 0.044 Uiso 1 1 calc R U . . .
 C39 C -0.2650(4) 0.5240(4) 0.6558(3) 0.0347(10) Uani 1 1 d . . . . .
 H39A H -0.305955 0.446666 0.619603 0.052 Uiso 1 1 calc R U . . .
 H39B H -0.314646 0.564562 0.634140 0.052 Uiso 1 1 calc R U . . .
 H39C H -0.260825 0.543691 0.720567 0.052 Uiso 1 1 calc R U . . .
 C31 C -0.0702(3) 0.6562(3) 0.6664(3) 0.0232(8) Uani 1 1 d . . . . .
 H31 H -0.113095 0.710432 0.686560 0.028 Uiso 1 1 calc R U . . .
 C19 C 0.1026(4) 0.9080(4) 1.0228(3) 0.0374(10) Uani 1 1 d . . . . .
 H19A H 0.104722 0.984241 1.052043 0.056 Uiso 1 1 calc R U . . .
 H19B H 0.118826 0.882088 1.069888 0.056 Uiso 1 1 calc R U . . .
 H19C H 0.018565 0.866225 0.979985 0.056 Uiso 1 1 calc R U . . .
 C34 C 0.0059(4) 0.8914(4) 0.7782(3) 0.0333(10) Uani 1 1 d . . . . .
 H34A H -0.079717 0.876527 0.739830 0.050 Uiso 1 1 calc R U . . .
 H34B H 0.031015 0.964841 0.827390 0.050 Uiso 1 1 calc R U . . .
 H34C H 0.005616 0.840075 0.804939 0.050 Uiso 1 1 calc R U . . .
 C3 C 0.6006(4) 1.1100(3) 0.8300(3) 0.0307(9) Uani 1 1 d . . . . .
 H3 H 0.660826 1.094334 0.795139 0.037 Uiso 1 1 calc R U . . .
 C23 C 0.3146(4) 0.3718(4) 0.5388(3) 0.0298(9) Uani 1 1 d . . . . .
 H23 H 0.400910 0.394949 0.538914 0.036 Uiso 1 1 calc R U . . .
 C42 C 0.2362(5) 0.8772(4) 0.4005(4) 0.0453(12) Uani 1 1 d . . . . .
 H42 H 0.257546 0.859848 0.453868 0.054 Uiso 1 1 calc R U . . .
 C18 C 0.4974(5) 0.3865(3) 0.7608(4) 0.0385(11) Uani 1 1 d . . . . .
 H18A H 0.510811 0.367554 0.699547 0.058 Uiso 1 1 calc R U . . .
 H18B H 0.427601 0.330131 0.758017 0.058 Uiso 1 1 calc R U . . .
 H18C H 0.575717 0.393100 0.803209 0.058 Uiso 1 1 calc R U . . .
 C4 C 0.5841(5) 1.2116(4) 0.8642(3) 0.0390(11) Uani 1 1 d . . . . .
 H4 H 0.634639 1.266648 0.854486 0.047 Uiso 1 1 calc R U . . .
 C38 C 0.2801(6) 1.1014(4) 0.6662(4) 0.0464(13) Uani 1 1 d . . . . .
 H38A H 0.373492 1.127444 0.685575 0.070 Uiso 1 1 calc R U . . .
 H38B H 0.244550 1.152245 0.708834 0.070 Uiso 1 1 calc R U . . .
 H38C H 0.248959 1.094989 0.604315 0.070 Uiso 1 1 calc R U . . .
 C41 C 0.7966(6) 0.6046(6) 0.9781(5) 0.0607(17) Uani 1 1 d . . . . .
 H41 H 0.755934 0.638633 0.941625 0.073 Uiso 1 1 calc R U . . .
 C24 C 0.2585(5) 0.2642(4) 0.5099(3) 0.0355(10) Uani 1 1 d . . . . .
 H24 H 0.305103 0.213058 0.488757 0.043 Uiso 1 1 calc R U . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Pt2 Cl2 2.3308(10) . ?
 Pt2 O2 1.986(3) . ?
 Pt2 N3 2.025(3) . ?
 Pt2 N4 1.998(3) . ?
 Pt1 Cl1 2.3341(10) . ?
 Pt1 N1 2.016(3) . ?
 Pt1 N2 1.987(3) . ?
 Pt1 O1 1.992(3) . ?
 Cl8 C42 1.744(6) . ?
 Cl4 C41 1.737(6) . ?
 Cl7 C42 1.761(6) . ?
 Cl6 C42 1.756(6) . ?
 Cl3 C41 1.734(8) . ?
 N1 C9 1.400(5) . ?
 N1 C1 1.319(5) . ?
 O2 C37 1.283(5) . ?
 N2 C10 1.418(5) . ?
 N2 C15 1.333(5) . ?
 O1 C17 1.297(5) . ?
 N3 C29 1.403(4) . ?
 N3 C21 1.315(5) . ?
 Cl5 C41 1.748(7) . ?
 N4 C30 1.425(5) . ?
 N4 C35 1.322(5) . ?
 C9 C10 1.412(5) . ?
 C9 C8 1.399(5) . ?
 C10 C11 1.390(5) . ?
 C1 C2 1.438(5) . ?
 C1 C20 1.498(6) . ?
 C29 C30 1.413(5) . ?
 C29 C28 1.398(5) . ?
 C30 C31 1.383(5) . ?
 C21 C22 1.440(6) . ?
 C21 C40 1.490(5) . ?
 C6 H6 0.9500 . ?
 C6 C7 1.403(6) . ?
 C6 C5 1.373(6) . ?
 C15 C16 1.410(6) . ?
 C15 C14 1.503(6) . ?
 C8 C7 1.445(6) . ?
 C8 C13 1.408(6) . ?
 C35 C36 1.409(6) . ?
 C35 C34 1.514(6) . ?
 C2 C7 1.411(6) . ?
 C2 C3 1.414(6) . ?
 C28 C33 1.407(5) . ?
 C28 C27 1.446(5) . ?
 C36 H36 0.9500 . ?
 C36 C37 1.369(6) . ?
 C33 H33 0.9500 . ?
 C33 C32 1.377(6) . ?
 C16 H16 0.9500 . ?
 C16 C17 1.373(6) . ?
 C20 H20A 0.9800 . ?
 C20 H20B 0.9800 . ?
 C20 H20C 0.9800 . ?
 C27 C22 1.403(5) . ?
 C27 C26 1.407(6) . ?
 C22 C23 1.415(6) . ?
 C14 H14A 0.9800 . ?
 C14 H14B 0.9800 . ?
 C14 H14C 0.9800 . ?
 C13 H13 0.9500 . ?
 C13 C12 1.373(6) . ?
 C40 H40A 0.9800 . ?
 C40 H40B 0.9800 . ?
 C40 H40C 0.9800 . ?
 C32 C39 1.500(5) . ?
 C32 C31 1.399(6) . ?
 C11 H11 0.9500 . ?
 C11 C12 1.409(6) . ?
 C37 C38 1.507(6) . ?
 C26 H26 0.9500 . ?
 C26 C25 1.373(6) . ?
 C17 C18 1.504(6) . ?
 C25 H25 0.9500 . ?
 C25 C24 1.386(7) . ?
 C12 C19 1.507(6) . ?
 C5 H5 0.9500 . ?
 C5 C4 1.381(7) . ?
 C39 H39A 0.9800 . ?
 C39 H39B 0.9800 . ?
 C39 H39C 0.9800 . ?
 C31 H31 0.9500 . ?
 C19 H19A 0.9800 . ?
 C19 H19B 0.9800 . ?
 C19 H19C 0.9800 . ?
 C34 H34A 0.9800 . ?
 C34 H34B 0.9800 . ?
 C34 H34C 0.9800 . ?
 C3 H3 0.9500 . ?
 C3 C4 1.374(6) . ?
 C23 H23 0.9500 . ?
 C23 C24 1.374(6) . ?
 C42 H42 1.0000 . ?
 C18 H18A 0.9800 . ?
 C18 H18B 0.9800 . ?
 C18 H18C 0.9800 . ?
 C4 H4 0.9500 . ?
 C38 H38A 0.9800 . ?
 C38 H38B 0.9800 . ?
 C38 H38C 0.9800 . ?
 C41 H41 1.0000 . ?
 C24 H24 0.9500 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 O2 Pt2 Cl2 81.97(9) . . ?
 O2 Pt2 N3 177.09(13) . . ?
 O2 Pt2 N4 95.03(13) . . ?
 N3 Pt2 Cl2 100.60(9) . . ?
 N4 Pt2 Cl2 172.48(9) . . ?
 N4 Pt2 N3 82.26(13) . . ?
 N1 Pt1 Cl1 99.63(9) . . ?
 N2 Pt1 Cl1 168.24(10) . . ?
 N2 Pt1 N1 81.87(13) . . ?
 N2 Pt1 O1 95.47(13) . . ?
 O1 Pt1 Cl1 83.88(9) . . ?
 O1 Pt1 N1 174.83(12) . . ?
 C9 N1 Pt1 109.8(2) . . ?
 C1 N1 Pt1 130.2(3) . . ?
 C1 N1 C9 119.9(3) . . ?
 C37 O2 Pt2 121.7(3) . . ?
 C10 N2 Pt1 110.3(2) . . ?
 C15 N2 Pt1 122.8(3) . . ?
 C15 N2 C10 126.6(3) . . ?
 C17 O1 Pt1 119.6(3) . . ?
 C29 N3 Pt2 109.8(2) . . ?
 C21 N3 Pt2 130.5(3) . . ?
 C21 N3 C29 119.4(3) . . ?
 C30 N4 Pt2 111.0(2) . . ?
 C35 N4 Pt2 122.3(3) . . ?
 C35 N4 C30 126.4(3) . . ?
 N1 C9 C10 116.4(3) . . ?
 C8 C9 N1 122.1(3) . . ?
 C8 C9 C10 121.5(4) . . ?
 C9 C10 N2 114.4(3) . . ?
 C11 C10 N2 127.4(4) . . ?
 C11 C10 C9 118.1(4) . . ?
 N1 C1 C2 120.6(4) . . ?
 N1 C1 C20 119.7(3) . . ?
 C2 C1 C20 119.7(3) . . ?
 N3 C29 C30 117.0(3) . . ?
 C28 C29 N3 121.9(3) . . ?
 C28 C29 C30 121.2(3) . . ?
 C29 C30 N4 114.8(3) . . ?
 C31 C30 N4 126.8(3) . . ?
 C31 C30 C29 118.2(3) . . ?
 N3 C21 C22 121.6(3) . . ?
 N3 C21 C40 119.8(4) . . ?
 C22 C21 C40 118.6(3) . . ?
 C7 C6 H6 119.9 . . ?
 C5 C6 H6 119.9 . . ?
 C5 C6 C7 120.3(4) . . ?
 N2 C15 C16 121.8(4) . . ?
 N2 C15 C14 122.5(4) . . ?
 C16 C15 C14 115.7(4) . . ?
 C9 C8 C7 118.1(4) . . ?
 C9 C8 C13 118.3(4) . . ?
 C13 C8 C7 123.6(4) . . ?
 N4 C35 C36 122.6(4) . . ?
 N4 C35 C34 122.7(4) . . ?
 C36 C35 C34 114.7(4) . . ?
 C7 C2 C1 120.4(4) . . ?
 C7 C2 C3 119.2(4) . . ?
 C3 C2 C1 120.2(4) . . ?
 C6 C7 C8 123.3(4) . . ?
 C6 C7 C2 119.0(4) . . ?
 C2 C7 C8 117.7(4) . . ?
 C29 C28 C33 118.6(3) . . ?
 C29 C28 C27 118.4(3) . . ?
 C33 C28 C27 123.0(4) . . ?
 C35 C36 H36 115.2 . . ?
 C37 C36 C35 129.6(4) . . ?
 C37 C36 H36 115.2 . . ?
 C28 C33 H33 119.6 . . ?
 C32 C33 C28 120.8(4) . . ?
 C32 C33 H33 119.6 . . ?
 C15 C16 H16 115.2 . . ?
 C17 C16 C15 129.5(4) . . ?
 C17 C16 H16 115.2 . . ?
 C1 C20 H20A 109.5 . . ?
 C1 C20 H20B 109.5 . . ?
 C1 C20 H20C 109.5 . . ?
 H20A C20 H20B 109.5 . . ?
 H20A C20 H20C 109.5 . . ?
 H20B C20 H20C 109.5 . . ?
 C22 C27 C28 117.9(4) . . ?
 C22 C27 C26 118.9(4) . . ?
 C26 C27 C28 123.2(4) . . ?
 C27 C22 C21 119.7(3) . . ?
 C27 C22 C23 119.1(4) . . ?
 C23 C22 C21 121.1(4) . . ?
 C15 C14 H14A 109.5 . . ?
 C15 C14 H14B 109.5 . . ?
 C15 C14 H14C 109.5 . . ?
 H14A C14 H14B 109.5 . . ?
 H14A C14 H14C 109.5 . . ?
 H14B C14 H14C 109.5 . . ?
 C8 C13 H13 119.6 . . ?
 C12 C13 C8 120.8(4) . . ?
 C12 C13 H13 119.6 . . ?
 C21 C40 H40A 109.5 . . ?
 C21 C40 H40B 109.5 . . ?
 C21 C40 H40C 109.5 . . ?
 H40A C40 H40B 109.5 . . ?
 H40A C40 H40C 109.5 . . ?
 H40B C40 H40C 109.5 . . ?
 C33 C32 C39 120.8(4) . . ?
 C33 C32 C31 119.7(3) . . ?
 C31 C32 C39 119.4(4) . . ?
 C10 C11 H11 119.7 . . ?
 C10 C11 C12 120.7(4) . . ?
 C12 C11 H11 119.7 . . ?
 O2 C37 C36 126.3(4) . . ?
 O2 C37 C38 113.2(4) . . ?
 C36 C37 C38 120.4(4) . . ?
 C27 C26 H26 119.7 . . ?
 C25 C26 C27 120.5(4) . . ?
 C25 C26 H26 119.7 . . ?
 O1 C17 C16 126.8(4) . . ?
 O1 C17 C18 112.9(4) . . ?
 C16 C17 C18 120.3(4) . . ?
 C26 C25 H25 119.5 . . ?
 C26 C25 C24 121.0(4) . . ?
 C24 C25 H25 119.5 . . ?
 C13 C12 C11 120.2(4) . . ?
 C13 C12 C19 121.0(4) . . ?
 C11 C12 C19 118.8(4) . . ?
 C6 C5 H5 119.5 . . ?
 C6 C5 C4 121.1(4) . . ?
 C4 C5 H5 119.5 . . ?
 C32 C39 H39A 109.5 . . ?
 C32 C39 H39B 109.5 . . ?
 C32 C39 H39C 109.5 . . ?
 H39A C39 H39B 109.5 . . ?
 H39A C39 H39C 109.5 . . ?
 H39B C39 H39C 109.5 . . ?
 C30 C31 C32 121.4(4) . . ?
 C30 C31 H31 119.3 . . ?
 C32 C31 H31 119.3 . . ?
 C12 C19 H19A 109.5 . . ?
 C12 C19 H19B 109.5 . . ?
 C12 C19 H19C 109.5 . . ?
 H19A C19 H19B 109.5 . . ?
 H19A C19 H19C 109.5 . . ?
 H19B C19 H19C 109.5 . . ?
 C35 C34 H34A 109.5 . . ?
 C35 C34 H34B 109.5 . . ?
 C35 C34 H34C 109.5 . . ?
 H34A C34 H34B 109.5 . . ?
 H34A C34 H34C 109.5 . . ?
 H34B C34 H34C 109.5 . . ?
 C2 C3 H3 119.9 . . ?
 C4 C3 C2 120.2(4) . . ?
 C4 C3 H3 119.9 . . ?
 C22 C23 H23 119.6 . . ?
 C24 C23 C22 120.8(4) . . ?
 C24 C23 H23 119.6 . . ?
 Cl8 C42 Cl7 111.8(3) . . ?
 Cl8 C42 Cl6 110.4(3) . . ?
 Cl8 C42 H42 108.3 . . ?
 Cl7 C42 H42 108.3 . . ?
 Cl6 C42 Cl7 109.7(3) . . ?
 Cl6 C42 H42 108.3 . . ?
 C17 C18 H18A 109.5 . . ?
 C17 C18 H18B 109.5 . . ?
 C17 C18 H18C 109.5 . . ?
 H18A C18 H18B 109.5 . . ?
 H18A C18 H18C 109.5 . . ?
 H18B C18 H18C 109.5 . . ?
 C5 C4 H4 119.9 . . ?
 C3 C4 C5 120.2(4) . . ?
 C3 C4 H4 119.9 . . ?
 C37 C38 H38A 109.5 . . ?
 C37 C38 H38B 109.5 . . ?
 C37 C38 H38C 109.5 . . ?
 H38A C38 H38B 109.5 . . ?
 H38A C38 H38C 109.5 . . ?
 H38B C38 H38C 109.5 . . ?
 Cl4 C41 Cl5 108.2(4) . . ?
 Cl4 C41 H41 109.0 . . ?
 Cl3 C41 Cl4 109.7(4) . . ?
 Cl3 C41 Cl5 111.9(4) . . ?
 Cl3 C41 H41 109.0 . . ?
 Cl5 C41 H41 109.0 . . ?
 C25 C24 H24 120.2 . . ?
 C23 C24 C25 119.6(4) . . ?
 C23 C24 H24 120.2 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Pt2 O2 C37 C36 -6.6(6) . . . . ?
 Pt2 O2 C37 C38 173.2(3) . . . . ?
 Pt2 N3 C29 C30 -16.5(4) . . . . ?
 Pt2 N3 C29 C28 163.8(3) . . . . ?
 Pt2 N3 C21 C22 -161.2(3) . . . . ?
 Pt2 N3 C21 C40 21.1(5) . . . . ?
 Pt2 N4 C30 C29 15.9(4) . . . . ?
 Pt2 N4 C30 C31 -159.1(3) . . . . ?
 Pt2 N4 C35 C36 8.0(5) . . . . ?
 Pt2 N4 C35 C34 -171.9(3) . . . . ?
 Pt1 N1 C9 C10 -14.8(4) . . . . ?
 Pt1 N1 C9 C8 165.0(3) . . . . ?
 Pt1 N1 C1 C2 -165.6(3) . . . . ?
 Pt1 N1 C1 C20 15.6(5) . . . . ?
 Pt1 N2 C10 C9 22.6(4) . . . . ?
 Pt1 N2 C10 C11 -154.3(3) . . . . ?
 Pt1 N2 C15 C16 1.7(5) . . . . ?
 Pt1 N2 C15 C14 -177.3(3) . . . . ?
 Pt1 O1 C17 C16 -15.7(6) . . . . ?
 Pt1 O1 C17 C18 163.8(3) . . . . ?
 N1 C9 C10 N2 -5.0(5) . . . . ?
 N1 C9 C10 C11 172.3(3) . . . . ?
 N1 C9 C8 C7 5.1(5) . . . . ?
 N1 C9 C8 C13 -173.6(3) . . . . ?
 N1 C1 C2 C7 -3.5(6) . . . . ?
 N1 C1 C2 C3 172.4(4) . . . . ?
 N2 C10 C11 C12 -179.1(4) . . . . ?
 N2 C15 C16 C17 11.3(7) . . . . ?
 N3 C29 C30 N4 0.6(5) . . . . ?
 N3 C29 C30 C31 176.1(3) . . . . ?
 N3 C29 C28 C33 -177.3(3) . . . . ?
 N3 C29 C28 C27 1.5(5) . . . . ?
 N3 C21 C22 C27 -4.0(6) . . . . ?
 N3 C21 C22 C23 173.1(4) . . . . ?
 N4 C30 C31 C32 178.2(4) . . . . ?
 N4 C35 C36 C37 6.0(7) . . . . ?
 C9 N1 C1 C2 11.8(5) . . . . ?
 C9 N1 C1 C20 -167.0(3) . . . . ?
 C9 C10 C11 C12 4.0(6) . . . . ?
 C9 C8 C7 C6 -177.1(4) . . . . ?
 C9 C8 C7 C2 3.1(5) . . . . ?
 C9 C8 C13 C12 -1.2(6) . . . . ?
 C10 N2 C15 C16 -172.0(4) . . . . ?
 C10 N2 C15 C14 9.1(6) . . . . ?
 C10 C9 C8 C7 -175.1(3) . . . . ?
 C10 C9 C8 C13 6.2(5) . . . . ?
 C10 C11 C12 C13 0.8(6) . . . . ?
 C10 C11 C12 C19 179.8(4) . . . . ?
 C1 N1 C9 C10 167.3(3) . . . . ?
 C1 N1 C9 C8 -12.9(5) . . . . ?
 C1 C2 C7 C6 176.2(4) . . . . ?
 C1 C2 C7 C8 -4.0(5) . . . . ?
 C1 C2 C3 C4 -174.4(4) . . . . ?
 C29 N3 C21 C22 11.2(5) . . . . ?
 C29 N3 C21 C40 -166.5(3) . . . . ?
 C29 C30 C31 C32 3.4(6) . . . . ?
 C29 C28 C33 C32 -0.9(5) . . . . ?
 C29 C28 C27 C22 5.6(5) . . . . ?
 C29 C28 C27 C26 -175.8(4) . . . . ?
 C30 N4 C35 C36 -165.9(4) . . . . ?
 C30 N4 C35 C34 14.2(6) . . . . ?
 C30 C29 C28 C33 3.0(5) . . . . ?
 C30 C29 C28 C27 -178.2(3) . . . . ?
 C21 N3 C29 C30 169.6(3) . . . . ?
 C21 N3 C29 C28 -10.1(5) . . . . ?
 C21 C22 C23 C24 -175.4(4) . . . . ?
 C6 C5 C4 C3 0.3(8) . . . . ?
 C15 N2 C10 C9 -163.0(4) . . . . ?
 C15 N2 C10 C11 20.0(6) . . . . ?
 C15 C16 C17 O1 -3.1(7) . . . . ?
 C15 C16 C17 C18 177.5(4) . . . . ?
 C8 C9 C10 N2 175.2(3) . . . . ?
 C8 C9 C10 C11 -7.6(5) . . . . ?
 C8 C13 C12 C11 -2.2(6) . . . . ?
 C8 C13 C12 C19 178.8(4) . . . . ?
 C35 N4 C30 C29 -169.6(4) . . . . ?
 C35 N4 C30 C31 15.4(6) . . . . ?
 C35 C36 C37 O2 -6.9(8) . . . . ?
 C35 C36 C37 C38 173.3(5) . . . . ?
 C2 C3 C4 C5 -1.8(7) . . . . ?
 C7 C6 C5 C4 1.5(7) . . . . ?
 C7 C8 C13 C12 -179.8(4) . . . . ?
 C7 C2 C3 C4 1.5(6) . . . . ?
 C28 C29 C30 N4 -179.6(3) . . . . ?
 C28 C29 C30 C31 -4.2(5) . . . . ?
 C28 C33 C32 C39 179.5(4) . . . . ?
 C28 C33 C32 C31 0.1(6) . . . . ?
 C28 C27 C22 C21 -4.5(5) . . . . ?
 C28 C27 C22 C23 178.3(4) . . . . ?
 C28 C27 C26 C25 -179.6(4) . . . . ?
 C33 C28 C27 C22 -175.7(4) . . . . ?
 C33 C28 C27 C26 3.0(6) . . . . ?
 C33 C32 C31 C30 -1.4(6) . . . . ?
 C20 C1 C2 C7 175.3(4) . . . . ?
 C20 C1 C2 C3 -8.8(6) . . . . ?
 C27 C28 C33 C32 -179.7(4) . . . . ?
 C27 C22 C23 C24 1.6(6) . . . . ?
 C27 C26 C25 C24 1.1(7) . . . . ?
 C22 C27 C26 C25 -1.0(6) . . . . ?
 C22 C23 C24 C25 -1.5(7) . . . . ?
 C14 C15 C16 C17 -169.7(4) . . . . ?
 C13 C8 C7 C6 1.5(6) . . . . ?
 C13 C8 C7 C2 -178.3(4) . . . . ?
 C40 C21 C22 C27 173.7(3) . . . . ?
 C40 C21 C22 C23 -9.2(5) . . . . ?
 C26 C27 C22 C21 176.8(4) . . . . ?
 C26 C27 C22 C23 -0.4(6) . . . . ?
 C26 C25 C24 C23 0.2(7) . . . . ?
 C5 C6 C7 C8 178.5(4) . . . . ?
 C5 C6 C7 C2 -1.8(6) . . . . ?
 C39 C32 C31 C30 179.2(4) . . . . ?
 C34 C35 C36 C37 -174.1(4) . . . . ?
 C3 C2 C7 C6 0.3(6) . . . . ?
 C3 C2 C7 C8 -179.9(4) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
