# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ja252
_database_code_depnum_ccdc_archive 'CCDC 2118661'
loop_
_audit_author_name
_audit_author_address
'Nathan Schley'
;Vanderbilt University
United States of America
;
_audit_update_record             
;
2021-10-29 deposited with the CCDC.	2022-02-10 downloaded from the CCDC.
;
_audit_creation_date             2021-10-29
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C34 H35 Eu K1 N6 O11, 2(H2 O), H O'
_chemical_formula_sum            'C34 H40 Eu K N6 O14'
_chemical_formula_weight         947.88
_chemical_absolute_configuration ad
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C34 H42 Eu K N6 O14'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.3868 1.0657 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           5
_space_group_name_H-M_alt        'C 1 2 1'
_space_group_name_Hall           'C 2y'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'

_cell_length_a                   15.29779(11)
_cell_length_b                   21.15984(14)
_cell_length_c                   12.02910(9)
_cell_angle_alpha                90
_cell_angle_beta                 101.9753(7)
_cell_angle_gamma                90
_cell_volume                     3809.06(5)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    21860
_cell_measurement_temperature    100.01(10)
_cell_measurement_theta_max      71.6690
_cell_measurement_theta_min      3.6020
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    13.421
_exptl_absorpt_correction_T_max  0.526
_exptl_absorpt_correction_T_min  0.111
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.116a (Rigaku Oxford Diffraction, 2021)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.653
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             1920
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-1 -14 0 0.0563
-6 -7 6 0.0417
6 -7 -6 0.0568
7 6 -6 0.0585
-1 14 1 0.0595
0 8 6 0.0862
10 0 0 0.1046
6 -10 2 0.1051
5 -4 5 0.1226
-1 12 -4 0.0478
-6 -5 -4 0.1192
-9 0 -1 0.1187

_exptl_crystal_size_max          0.258
_exptl_crystal_size_mid          0.149
_exptl_crystal_size_min          0.105
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-1.1139 -13.6444 0.2559 -0.7993 0.1055 -0.5916
-5.7323 -6.5956 5.9810 -0.8207 0.5026 0.2718
6.0067 -6.6571 -5.8029 0.0416 -0.5380 -0.8419
6.5269 6.1132 -5.7113 0.7665 -0.5878 -0.2586
-0.6094 13.6518 0.7682 0.7288 0.0569 0.6824
-0.2334 7.8633 6.2985 -0.0471 -0.0594 0.9971
9.7327 0.4686 -0.0923 -0.0255 -0.9950 0.0964
5.9230 -10.0391 1.5620 -0.7389 -0.6315 -0.2350
4.9629 -3.7589 5.4701 -0.6825 -0.5844 0.4391
-1.2293 11.6452 -3.7364 0.9756 0.1813 0.1236
-5.8791 -5.2933 -4.4504 0.0856 0.6608 -0.7456
-9.4518 0.1047 -0.8018 0.1280 0.9787 -0.1605

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0307
_diffrn_reflns_av_unetI/netI     0.0252
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            28717
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         71.620
_diffrn_reflns_theta_min         3.618
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.01(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.3012
_diffrn_detector_type            EosS2
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -107.00  -7.00   1.00    1.00    --  -35.92 -19.00 -60.00  100
  2  ω   -107.00  -7.00   1.00    1.00    --  -35.92 -19.00  30.00  100
  3  ω   -105.00 -17.00   1.00    1.00    --  -35.92 -38.00 150.00   88
  4  ω    -55.00  33.00   1.00    1.00    --  -35.92  38.00 -30.00   88
  5  ω     61.00 108.00   1.00    1.00    --   35.92 178.00   0.00   47
  6  ω     61.00 108.00   1.00    1.00    --   35.92 178.00  60.00   47
  7  ω      4.00  31.00   1.00    1.00    --   35.92  86.00 -91.48   27
  8  ω     61.00 108.00   1.00    1.00    --   35.92 178.00 120.00   47
  9  ω     10.00  36.00   1.00    1.00    --   35.92  75.00  57.73   26
 10  ω      2.00  29.00   1.00    1.00    --   35.92  90.00 142.72   27
 11  ω      2.00  29.00   1.00    1.00    --   35.92  90.00-156.83   27
 12  ω     61.00 108.00   1.00    1.00    --   35.92 178.00-120.00   47
 13  ω     19.00 103.00   1.00    1.00    --   35.92  57.00   0.00   84
 14  ω     90.00 175.00   1.00    1.04    --  108.08  61.00-180.00   85
 15  ω     87.00 178.00   1.00    1.04    --  108.08  30.00  60.00   91
 16  ω    104.00 178.00   1.00    1.04    --  108.08 111.00 150.00   74
 17  ω     91.00 177.00   1.00    1.04    --  108.08  45.00  30.00   86
 18  ω     90.00 175.00   1.00    1.04    --  108.08  61.00 -30.00   85
 19  ω     41.00 126.00   1.00    1.04    --  108.08 -61.00-150.00   85
 20  ω     91.00 177.00   1.00    1.04    --  108.08  45.00   0.00   86
 21  ω    103.00 176.00   1.00    1.04    --  108.08  77.00-120.00   73
 22  ω     87.00 178.00   1.00    1.04    --  108.08  30.00   0.00   91
 23  ω     90.00 175.00   1.00    1.04    --  108.08  61.00 -60.00   85
 24  ω    103.00 176.00   1.00    1.04    --  108.08  77.00 -90.00   73
 25  ω     87.00 178.00   1.00    1.04    --  108.08  30.00 -30.00   91
 26  ω     39.00 106.00   1.00    1.04    --  108.08 -94.00-150.00   67
 27  ω     87.00 178.00   1.00    1.04    --  108.08  30.00  30.00   91
 28  ω     41.00 126.00   1.00    1.04    --  108.08 -61.00 150.00   85
 29  ω     90.00 175.00   1.00    1.04    --  108.08  61.00   0.00   85
 30  ω     38.00 109.00   1.00    1.04    --  108.08-111.00 120.00   71
 31  ω     41.00 135.00   1.00    1.04    --  108.08 -77.00 120.00   94
 32  ω     91.00 177.00   1.00    1.04    --  108.08  45.00 -60.00   86
 33  ω     91.00 177.00   1.00    1.04    --  108.08  45.00 -30.00   86
 34  ω     37.00 146.00   1.00    1.04    --  108.08 -15.00-150.00  109
 35  ω    -55.00  33.00   1.00    1.00    --  -35.92  38.00  90.00   88
 36  ω   -107.00  -7.00   1.00    1.00    --  -35.92 -19.00-150.00  100
 37  ω    -55.00  33.00   1.00    1.00    --  -35.92  38.00-180.00   88
 38  ω      3.00  30.00   1.00    1.00    --   35.92  88.00  95.28   27
 39  ω      6.00  75.00   1.00    1.00    --   35.92 -99.00-150.00   69
 40  ω      6.00  75.00   1.00    1.00    --   35.92 -99.00   0.00   69
 41  ω      2.00  29.00   1.00    1.00    --   35.92  90.00 172.31   27
 42  ω     58.00 109.00   1.00    1.00    --   35.92-178.00 150.00   51
 43  ω      3.00  30.00   1.00    1.00    --   35.92  89.00 -22.58   27
 44  ω      4.00  31.00   1.00    1.00    --   35.92  87.00 -57.11   27
 45  ω     70.00 123.00   1.00    1.04    --  108.08  15.00 150.00   53
 46  ω     87.00 178.00   1.00    1.04    --  108.08  30.00-120.00   91
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, EosS2'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0061531000
_diffrn_orient_matrix_UB_12      0.0575873000
_diffrn_orient_matrix_UB_13      -0.0796062000
_diffrn_orient_matrix_UB_21      -0.1023821000
_diffrn_orient_matrix_UB_22      0.0003709000
_diffrn_orient_matrix_UB_23      -0.0136826000
_diffrn_orient_matrix_UB_31      0.0087346000
_diffrn_orient_matrix_UB_32      0.0445804000
_diffrn_orient_matrix_UB_33      0.1029793000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage         0.927
_reflns_Friedel_fraction_full    0.997
_reflns_Friedel_fraction_max     0.978
_reflns_number_gt                7182
_reflns_number_total             7354
_reflns_odcompleteness_completeness 100.00
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.116a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.116a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.116a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.821
_refine_diff_density_min         -1.308
_refine_diff_density_rms         0.122
_refine_ls_abs_structure_details 
;
 Flack x determined using 3333 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.004(3)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     523
_refine_ls_number_reflns         7354
_refine_ls_number_restraints     57
_refine_ls_R_factor_all          0.0402
_refine_ls_R_factor_gt           0.0395
_refine_ls_restrained_S_all      1.074
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0570P)²+26.9330P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1060
_refine_ls_wR_factor_ref         0.1065
_refine_special_details          
'Extensive disorder in the potassium ion site was modeled over several positions in the asymmetric unit per Eu, resulting in 4-6 symmetry-related sites per Eu site. The potassium thermal parameters were constrained to be approximately isotropic. Water molecules were modeled as rigid fragments that were refined in position and orientation.'
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All O(H) groups, All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
K1A \\sim K1B \\sim K1C: within 2A with sigma of 0.005 and sigma for terminal
atoms of 0.01
K2A \\sim K2B: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(K1B) \\sim Ueq, Uanis(K1C) \\sim Ueq, Uanis(K1A) \\sim Ueq: with sigma of
0.01 and sigma for terminal atoms of 0.02
Uanis(K2B) \\sim Ueq, Uanis(K2A) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
3. Others
 2*[Sof(K2B)]+2*[Sof(K2A)]=1 with esd of 0.001
 1*[Sof(K1B)]+1*[Sof(K1C)]+1*[Sof(K1A)]=0.5 with esd of 0.001
4.a Everything fixed:
 O14, H14A, H14B, O11, H11C, H11D, O13, H13A, H13B
4.b Riding coordinates:
 O9(H9), O12(H12A,H12B)
4.c Free rotating group:
 O10(H10)
4.d Ternary CH refined with riding coordinates:
 C8(H8), C25(H25)
4.e Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C9(H9A,H9B), C10(H10A,H10B), C11(H11A,H11B), C24(H24A,H24B),
 C26(H26A,H26B), C27(H27A,H27B), C28(H28A,H28B)
4.f Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C13(H13), C14(H14), C15(H15), C20(H20), C21(H21),
 C22(H22), C30(H30), C31(H31), C32(H32)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.500000 0.25697(2) -0.500000 0.01110(19) Uani 1 2 d S T P A .
Eu2 Eu 1.000000 0.24297(2) 0.000000 0.01111(19) Uani 1 2 d S T P B .
K1A K 0.552(2) 0.4469(14) -0.338(3) 0.031(3) Uani 0.101(12) 1 d . U . A -3
K1B K 0.5397(19) 0.4313(16) -0.372(4) 0.030(3) Uani 0.132(18) 1 d . U . A -2
K1C K 0.5342(8) 0.4444(6) -0.4124(16) 0.028(2) Uani 0.269(16) 1 d . U . A -1
K2A K 0.9565(17) 0.0556(12) -0.140(3) 0.046(5) Uani 0.172(16) 1 d . U . B -2
K2B K 0.9708(6) 0.0614(4) -0.0949(13) 0.028(2) Uani 0.328(16) 1 d . U . B -1
O1 O 0.5587(4) 0.3092(3) -0.3203(5) 0.0190(12) Uani 1 1 d . . . . .
O2 O 0.6159(5) 0.3001(3) -0.1332(5) 0.0274(15) Uani 1 1 d . . . . .
O3 O 0.5955(4) 0.3439(3) -0.5217(5) 0.0177(12) Uani 1 1 d . . . . .
O4 O 0.6763(5) 0.4043(3) -0.6137(6) 0.0290(15) Uani 1 1 d . . . . .
O5 O 0.9014(4) 0.1574(3) 0.0183(5) 0.0179(12) Uani 1 1 d . . . . .
O6 O 0.8255(5) 0.0989(3) 0.1200(6) 0.0323(16) Uani 1 1 d . . . . .
O7 O 0.9443(4) 0.1875(3) -0.1824(5) 0.0179(12) Uani 1 1 d . . . . .
O8 O 0.8884(5) 0.1918(3) -0.3701(5) 0.0267(14) Uani 1 1 d . . . . .
O9 O 0.8259(6) 0.0006(4) -0.0326(7) 0.046(2) Uani 1 1 d . . . . .
H9 H 0.797441 -0.034032 -0.025097 0.069 Uiso 1 1 d R . . B .
O12 O 0.6750(6) 0.5018(4) -0.4652(7) 0.054(2) Uani 1 1 d . . . . .
H12A H 0.675839 0.466643 -0.501958 0.081 Uiso 1 1 d R . . A .
H12B H 0.668369 0.530923 -0.516798 0.081 Uiso 1 1 d R . . . .
O14 O 0.952420 0.077100 -0.407140 0.087 Uani 1 1 d . . . . .
H14A H 0.932380 0.108300 -0.451510 0.130 Uiso 1 1 d . . . . .
H14B H 1.004980 0.069310 -0.420510 0.130 Uiso 1 1 d . . . . .
N1 N 0.5999(4) 0.2472(3) -0.6596(5) 0.0152(13) Uani 1 1 d . . . . .
N2 N 0.5635(4) 0.1322(3) -0.5760(5) 0.0135(13) Uani 1 1 d . . . . .
N3 N 0.6289(5) 0.2002(3) -0.3648(6) 0.0155(13) Uani 1 1 d . . . . .
N4 N 0.9017(4) 0.2568(3) 0.1522(6) 0.0160(13) Uani 1 1 d . . . . .
N5 N 0.9210(4) 0.3689(3) 0.0494(5) 0.0138(13) Uani 1 1 d . . . . .
N6 N 0.8644(4) 0.2936(3) -0.1462(6) 0.0145(13) Uani 1 1 d . . . . .
C1 C 0.6349(6) 0.3545(4) -0.6019(7) 0.0187(17) Uani 1 1 d . . . . .
C2 C 0.6314(6) 0.3027(4) -0.6895(7) 0.0181(17) Uani 1 1 d . . . . .
C3 C 0.6548(6) 0.3128(4) -0.7923(7) 0.0230(18) Uani 1 1 d . . . . .
H3 H 0.676608 0.352845 -0.810001 0.028 Uiso 1 1 calc R . . . .
C4 C 0.6461(7) 0.2634(5) -0.8700(8) 0.030(2) Uani 1 1 d . . . . .
H4 H 0.660346 0.269455 -0.942447 0.036 Uiso 1 1 calc R . . . .
C5 C 0.6167(6) 0.2059(4) -0.8402(7) 0.0238(18) Uani 1 1 d . . . . .
H5 H 0.611400 0.171068 -0.891106 0.029 Uiso 1 1 calc R . . . .
C6 C 0.5945(5) 0.1993(4) -0.7334(7) 0.0164(16) Uani 1 1 d . . . . .
C7 C 0.5615(6) 0.1367(4) -0.6994(6) 0.0179(16) Uani 1 1 d . . . . .
H7A H 0.499506 0.130006 -0.741805 0.021 Uiso 1 1 calc R . . . .
H7B H 0.598998 0.102548 -0.721086 0.021 Uiso 1 1 calc R . . . .
C8 C 0.5158(5) 0.0729(3) -0.5562(6) 0.0149(14) Uani 1 1 d . . . . .
H8 H 0.460988 0.070387 -0.618012 0.018 Uiso 1 1 calc R . . . .
C9 C 0.5700(6) 0.0118(4) -0.5637(7) 0.0188(17) Uani 1 1 d . . . . .
H9A H 0.590734 0.011520 -0.636325 0.023 Uiso 1 1 calc R . . . .
H9B H 0.623313 0.011363 -0.500955 0.023 Uiso 1 1 calc R . . . .
C10 C 0.5148(6) -0.0472(3) -0.5565(7) 0.0214(16) Uani 1 1 d . . . . .
H10A H 0.551004 -0.085367 -0.562556 0.026 Uiso 1 1 calc R . . . .
H10B H 0.461924 -0.047748 -0.619889 0.026 Uiso 1 1 calc R . . . .
C11 C 0.6581(5) 0.1329(4) -0.5148(7) 0.0166(16) Uani 1 1 d . . . . .
H11A H 0.690967 0.165035 -0.549796 0.020 Uiso 1 1 calc R . . . .
H11B H 0.685194 0.091214 -0.523649 0.020 Uiso 1 1 calc R . . . .
C12 C 0.6689(5) 0.1472(4) -0.3909(7) 0.0169(16) Uani 1 1 d . . . . .
C13 C 0.7210(6) 0.1099(4) -0.3072(7) 0.0226(18) Uani 1 1 d . . . . .
H13 H 0.748434 0.072534 -0.327467 0.027 Uiso 1 1 calc R . . . .
C14 C 0.7326(6) 0.1275(5) -0.1940(8) 0.0253(19) Uani 1 1 d . . . . .
H14 H 0.766320 0.101706 -0.135944 0.030 Uiso 1 1 calc R . . . .
C15 C 0.6947(6) 0.1828(5) -0.1670(7) 0.0229(19) Uani 1 1 d . . . . .
H15 H 0.703533 0.196735 -0.090443 0.028 Uiso 1 1 calc R . . . .
C16 C 0.6432(5) 0.2179(4) -0.2543(7) 0.0172(16) Uani 1 1 d . . . . .
C17 C 0.6028(6) 0.2806(4) -0.2323(7) 0.0193(17) Uani 1 1 d . . . . .
C18 C 0.8651(5) 0.1482(4) 0.1032(7) 0.0168(16) Uani 1 1 d . . . . .
C19 C 0.8726(5) 0.2015(4) 0.1870(7) 0.0164(16) Uani 1 1 d . . . . .
C20 C 0.8548(6) 0.1942(5) 0.2945(8) 0.0255(19) Uani 1 1 d . . . . .
H20 H 0.834137 0.154936 0.317416 0.031 Uiso 1 1 calc R . . . .
C21 C 0.8676(7) 0.2449(5) 0.3674(8) 0.030(2) Uani 1 1 d . . . . .
H21 H 0.859695 0.240428 0.443285 0.036 Uiso 1 1 calc R . . . .
C22 C 0.8922(6) 0.3026(4) 0.3292(7) 0.0234(18) Uani 1 1 d . . . . .
H22 H 0.897262 0.338740 0.376888 0.028 Uiso 1 1 calc R . . . .
C23 C 0.9096(6) 0.3072(4) 0.2204(7) 0.0168(16) Uani 1 1 d . . . . .
C24 C 0.9355(5) 0.3690(4) 0.1743(6) 0.0160(16) Uani 1 1 d . . . . .
H24A H 0.899946 0.403425 0.198697 0.019 Uiso 1 1 calc R . . . .
H24B H 0.999335 0.377500 0.206606 0.019 Uiso 1 1 calc R . . . .
C25 C 0.9509(5) 0.4290(3) 0.0034(6) 0.0149(14) Uani 1 1 d . . . . .
H25 H 0.916393 0.432580 -0.076650 0.018 Uiso 1 1 calc R . . . .
C26 C 0.9298(6) 0.4892(4) 0.0652(7) 0.0188(17) Uani 1 1 d . . . . .
H26A H 0.865687 0.489348 0.068539 0.023 Uiso 1 1 calc R . . . .
H26B H 0.965077 0.488953 0.144091 0.023 Uiso 1 1 calc R . . . .
C27 C 0.9513(5) 0.5489(3) 0.0051(7) 0.0209(16) Uani 1 1 d . . . . .
H27A H 0.912413 0.551253 -0.071563 0.025 Uiso 1 1 calc R . . . .
H27B H 0.939368 0.586574 0.048558 0.025 Uiso 1 1 calc R . . . .
C28 C 0.8254(5) 0.3615(4) -0.0024(7) 0.0162(15) Uani 1 1 d . . . . .
H28A H 0.793053 0.401421 0.004248 0.019 Uiso 1 1 calc R . . . .
H28B H 0.798793 0.327706 0.036859 0.019 Uiso 1 1 calc R . . . .
C29 C 0.8178(5) 0.3447(4) -0.1257(7) 0.0149(15) Uani 1 1 d . . . . .
C30 C 0.7684(5) 0.3816(4) -0.2132(7) 0.0200(17) Uani 1 1 d . . . . .
H30 H 0.737003 0.417875 -0.196358 0.024 Uiso 1 1 calc R . . . .
C31 C 0.7661(6) 0.3643(5) -0.3243(8) 0.0260(19) Uani 1 1 d . . . . .
H31 H 0.735844 0.389695 -0.385379 0.031 Uiso 1 1 calc R . . . .
C32 C 0.8091(6) 0.3089(5) -0.3449(7) 0.0214(17) Uani 1 1 d . . . . .
H32 H 0.805756 0.294678 -0.420602 0.026 Uiso 1 1 calc R . . . .
C33 C 0.8565(6) 0.2751(4) -0.2548(7) 0.0179(17) Uani 1 1 d . . . . .
C34 C 0.9008(6) 0.2131(4) -0.2710(7) 0.0172(16) Uani 1 1 d . . . . .
O11 O 0.780220 0.459790 -0.758130 0.050 Uani 1 1 d . . . . .
H11C H 0.755710 0.447620 -0.703230 0.075 Uiso 1 1 d . . . . .
H11D H 0.738840 0.481030 -0.802720 0.075 Uiso 1 1 d . . . . .
O13 O 0.719100 0.039410 -0.743640 0.062 Uani 1 1 d . . . . .
H13A H 0.772410 0.024250 -0.721290 0.093 Uiso 1 1 d . . . . .
H13B H 0.727300 0.076890 -0.768840 0.093 Uiso 1 1 d . . . . .
O10 O 0.9394(8) -0.0886(5) 0.0670(15) 0.122(6) Uani 1 1 d . . . . .
H10 H 0.930316 -0.126339 0.090223 0.183 Uiso 1 1 d G . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 K1B 3.99(4) . ?
Eu1 K1C 4.109(11) . ?
Eu1 O1 2.428(6) 2_654 ?
Eu1 O1 2.428(6) . ?
Eu1 O3 2.396(6) . ?
Eu1 O3 2.396(6) 2_654 ?
Eu1 N1 2.699(6) . ?
Eu1 N1 2.699(6) 2_654 ?
Eu1 N2 3.019(7) . ?
Eu1 N2 3.019(7) 2_654 ?
Eu1 N3 2.578(7) . ?
Eu1 N3 2.578(7) 2_654 ?
Eu2 K2A 4.31(3) . ?
Eu2 K2B 4.007(10) . ?
Eu2 O5 2.395(6) . ?
Eu2 O5 2.395(6) 2_755 ?
Eu2 O7 2.478(5) . ?
Eu2 O7 2.478(5) 2_755 ?
Eu2 N4 2.615(7) 2_755 ?
Eu2 N4 2.615(7) . ?
Eu2 N5 3.034(7) . ?
Eu2 N5 3.034(7) 2_755 ?
Eu2 N6 2.651(7) 2_755 ?
Eu2 N6 2.651(7) . ?
K1A O1 2.92(3) . ?
K1A O3 3.27(4) . ?
K1A O12 2.91(3) . ?
K1A H12A 3.0368 . ?
K1B O1 2.66(4) . ?
K1B O3 2.83(4) . ?
K1B O12 2.95(4) . ?
K1B H12A 2.9463 . ?
K1C O1 3.063(17) . ?
K1C O3 2.764(12) . ?
K1C O12 2.661(16) . ?
K1C H12A 2.6537 . ?
K2A O5 3.11(3) . ?
K2A O7 2.84(3) . ?
K2A O9 2.84(3) . ?
K2A O14 3.23(3) . ?
K2B O5 2.777(12) . ?
K2B O7 2.866(12) . ?
K2B O9 2.796(12) . ?
O1 C17 1.282(11) . ?
O2 C17 1.238(11) . ?
O3 C1 1.260(11) . ?
O4 C1 1.253(11) . ?
O5 C18 1.275(10) . ?
O6 C18 1.243(11) . ?
O7 C34 1.257(10) . ?
O8 C34 1.251(10) . ?
O9 H9 0.8674 . ?
O12 H12A 0.8674 . ?
O12 H12B 0.8657 . ?
O14 H14A 0.8642 . ?
O14 H14B 0.8679 . ?
N1 C2 1.346(11) . ?
N1 C6 1.338(11) . ?
N2 C7 1.481(9) . ?
N2 C8 1.495(9) . ?
N2 C11 1.482(9) . ?
N3 C12 1.347(11) . ?
N3 C16 1.353(11) . ?
N4 C19 1.351(11) . ?
N4 C23 1.335(11) . ?
N5 C24 1.473(9) . ?
N5 C25 1.497(9) . ?
N5 C28 1.475(10) . ?
N6 C29 1.345(11) . ?
N6 C33 1.345(11) . ?
C1 C2 1.514(12) . ?
C2 C3 1.374(12) . ?
C3 H3 0.9500 . ?
C3 C4 1.389(13) . ?
C4 H4 0.9500 . ?
C4 C5 1.372(13) . ?
C5 H5 0.9500 . ?
C5 C6 1.403(12) . ?
C6 C7 1.504(11) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C8 1.527(14) 2_654 ?
C8 H8 1.0000 . ?
C8 C9 1.549(11) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C9 C10 1.519(11) . ?
C10 C10 1.520(15) 2_654 ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C11 C12 1.496(11) . ?
C12 C13 1.392(12) . ?
C13 H13 0.9500 . ?
C13 C14 1.387(13) . ?
C14 H14 0.9500 . ?
C14 C15 1.374(14) . ?
C15 H15 0.9500 . ?
C15 C16 1.389(12) . ?
C16 C17 1.512(13) . ?
C18 C19 1.500(11) . ?
C19 C20 1.384(12) . ?
C20 H20 0.9500 . ?
C20 C21 1.374(14) . ?
C21 H21 0.9500 . ?
C21 C22 1.383(14) . ?
C22 H22 0.9500 . ?
C22 C23 1.392(12) . ?
C23 C24 1.505(11) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 C25 1.520(14) 2_755 ?
C25 H25 1.0000 . ?
C25 C26 1.543(10) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C26 C27 1.525(11) . ?
C27 C27 1.519(16) 2_755 ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C28 C29 1.506(11) . ?
C29 C30 1.399(11) . ?
C30 H30 0.9500 . ?
C30 C31 1.378(12) . ?
C31 H31 0.9500 . ?
C31 C32 1.391(14) . ?
C32 H32 0.9500 . ?
C32 C33 1.375(12) . ?
C33 C34 1.508(12) . ?
O11 H11C 0.8636 . ?
O11 H11D 0.8657 . ?
O13 H13A 0.8656 . ?
O13 H13B 0.8674 . ?
O10 H10 0.8670 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 K1B 40.4(6) . . ?
O1 Eu1 K1B 85.5(6) 2_654 . ?
O1 Eu1 K1C 78.1(3) 2_654 . ?
O1 Eu1 K1C 47.8(3) . . ?
O1 Eu1 O1 125.9(3) . 2_654 ?
O1 Eu1 N1 120.6(2) . . ?
O1 Eu1 N1 120.6(2) 2_654 2_654 ?
O1 Eu1 N1 64.0(2) . 2_654 ?
O1 Eu1 N1 64.0(2) 2_654 . ?
O1 Eu1 N2 125.78(18) 2_654 2_654 ?
O1 Eu1 N2 102.18(19) . 2_654 ?
O1 Eu1 N2 102.18(19) 2_654 . ?
O1 Eu1 N2 125.78(18) . . ?
O1 Eu1 N3 63.7(2) 2_654 2_654 ?
O1 Eu1 N3 150.1(2) . 2_654 ?
O1 Eu1 N3 150.1(2) 2_654 . ?
O1 Eu1 N3 63.7(2) . . ?
O3 Eu1 K1B 45.3(4) 2_654 . ?
O3 Eu1 K1B 44.4(5) . . ?
O3 Eu1 K1C 40.4(2) . . ?
O3 Eu1 K1C 43.9(2) 2_654 . ?
O3 Eu1 O1 68.1(2) . . ?
O3 Eu1 O1 71.0(2) . 2_654 ?
O3 Eu1 O1 71.0(2) 2_654 . ?
O3 Eu1 O1 68.1(2) 2_654 2_654 ?
O3 Eu1 O3 79.7(3) 2_654 . ?
O3 Eu1 N1 125.8(2) 2_654 . ?
O3 Eu1 N1 62.2(2) 2_654 2_654 ?
O3 Eu1 N1 62.2(2) . . ?
O3 Eu1 N1 125.8(2) . 2_654 ?
O3 Eu1 N2 113.35(19) . . ?
O3 Eu1 N2 161.04(18) 2_654 . ?
O3 Eu1 N2 113.35(19) 2_654 2_654 ?
O3 Eu1 N2 161.04(18) . 2_654 ?
O3 Eu1 N3 133.8(2) 2_654 . ?
O3 Eu1 N3 91.3(2) . . ?
O3 Eu1 N3 91.3(2) 2_654 2_654 ?
O3 Eu1 N3 133.8(2) . 2_654 ?
N1 Eu1 K1B 82.0(5) 2_654 . ?
N1 Eu1 K1B 106.3(5) . . ?
N1 Eu1 K1C 101.3(3) . . ?
N1 Eu1 K1C 87.3(3) 2_654 . ?
N1 Eu1 N1 171.2(3) 2_654 . ?
N1 Eu1 N2 56.8(2) . . ?
N1 Eu1 N2 114.4(2) 2_654 . ?
N1 Eu1 N2 114.4(2) . 2_654 ?
N1 Eu1 N2 56.8(2) 2_654 2_654 ?
N2 Eu1 K1B 153.0(4) . . ?
N2 Eu1 K1B 136.4(6) 2_654 . ?
N2 Eu1 K1C 142.9(3) 2_654 . ?
N2 Eu1 K1C 152.8(2) . . ?
N2 Eu1 N2 58.1(2) 2_654 . ?
N3 Eu1 K1B 98.7(5) . . ?
N3 Eu1 K1B 135.1(5) 2_654 . ?
N3 Eu1 K1C 130.7(3) 2_654 . ?
N3 Eu1 K1C 104.3(3) . . ?
N3 Eu1 N1 89.3(2) 2_654 . ?
N3 Eu1 N1 86.6(2) . . ?
N3 Eu1 N1 86.6(2) 2_654 2_654 ?
N3 Eu1 N1 89.3(2) . 2_654 ?
N3 Eu1 N2 62.09(19) 2_654 2_654 ?
N3 Eu1 N2 69.74(19) 2_654 . ?
N3 Eu1 N2 69.74(19) . 2_654 ?
N3 Eu1 N2 62.09(19) . . ?
N3 Eu1 N3 124.5(3) 2_654 . ?
O5 Eu2 K2A 46.9(4) 2_755 . ?
O5 Eu2 K2A 44.9(4) . . ?
O5 Eu2 K2B 44.28(19) 2_755 . ?
O5 Eu2 K2B 42.81(19) . . ?
O5 Eu2 O5 81.8(3) . 2_755 ?
O5 Eu2 O7 70.60(19) 2_755 . ?
O5 Eu2 O7 67.4(2) 2_755 2_755 ?
O5 Eu2 O7 70.60(19) . 2_755 ?
O5 Eu2 O7 67.4(2) . . ?
O5 Eu2 N4 127.8(2) 2_755 . ?
O5 Eu2 N4 63.6(2) . . ?
O5 Eu2 N4 63.6(2) 2_755 2_755 ?
O5 Eu2 N4 127.8(2) . 2_755 ?
O5 Eu2 N5 164.88(18) . 2_755 ?
O5 Eu2 N5 164.88(18) 2_755 . ?
O5 Eu2 N5 111.20(19) 2_755 2_755 ?
O5 Eu2 N5 111.20(19) . . ?
O5 Eu2 N6 131.7(2) . 2_755 ?
O5 Eu2 N6 86.9(2) . . ?
O5 Eu2 N6 86.9(2) 2_755 2_755 ?
O5 Eu2 N6 131.7(2) 2_755 . ?
O7 Eu2 K2A 84.7(4) 2_755 . ?
O7 Eu2 K2A 38.8(4) . . ?
O7 Eu2 K2B 78.2(2) 2_755 . ?
O7 Eu2 K2B 45.2(3) . . ?
O7 Eu2 O7 123.4(3) . 2_755 ?
O7 Eu2 N4 64.9(2) 2_755 . ?
O7 Eu2 N4 122.0(2) . . ?
O7 Eu2 N4 64.9(2) . 2_755 ?
O7 Eu2 N4 122.0(2) 2_755 2_755 ?
O7 Eu2 N5 120.76(18) . . ?
O7 Eu2 N5 108.70(18) . 2_755 ?
O7 Eu2 N5 108.70(18) 2_755 . ?
O7 Eu2 N5 120.76(18) 2_755 2_755 ?
O7 Eu2 N6 61.7(2) 2_755 2_755 ?
O7 Eu2 N6 148.9(2) . 2_755 ?
O7 Eu2 N6 61.7(2) . . ?
O7 Eu2 N6 148.9(2) 2_755 . ?
N4 Eu2 K2A 108.2(4) . . ?
N4 Eu2 K2A 83.9(4) 2_755 . ?
N4 Eu2 K2B 87.4(2) 2_755 . ?
N4 Eu2 K2B 105.1(2) . . ?
N4 Eu2 N4 167.1(3) . 2_755 ?
N4 Eu2 N5 56.9(2) . . ?
N4 Eu2 N5 110.4(2) . 2_755 ?
N4 Eu2 N5 110.4(2) 2_755 . ?
N4 Eu2 N5 56.9(2) 2_755 2_755 ?
N4 Eu2 N6 88.6(2) . 2_755 ?
N4 Eu2 N6 88.6(2) 2_755 . ?
N4 Eu2 N6 86.2(2) . . ?
N4 Eu2 N6 86.2(2) 2_755 2_755 ?
N5 Eu2 K2A 140.1(4) 2_755 . ?
N5 Eu2 K2A 148.2(4) . . ?
N5 Eu2 K2B 144.2(2) 2_755 . ?
N5 Eu2 K2B 150.73(18) . . ?
N5 Eu2 N5 57.2(3) . 2_755 ?
N6 Eu2 K2A 131.9(4) 2_755 . ?
N6 Eu2 K2A 94.4(4) . . ?
N6 Eu2 K2B 127.0(2) 2_755 . ?
N6 Eu2 K2B 100.0(2) . . ?
N6 Eu2 N5 78.69(19) 2_755 . ?
N6 Eu2 N5 78.69(19) . 2_755 ?
N6 Eu2 N5 59.09(19) . . ?
N6 Eu2 N5 59.09(19) 2_755 2_755 ?
N6 Eu2 N6 132.3(3) . 2_755 ?
Eu1 K1A H12A 85.3 . . ?
O1 K1A Eu1 30.1(5) . . ?
O1 K1A O3 51.3(6) . . ?
O1 K1A H12A 99.6 . . ?
O3 K1A Eu1 31.5(3) . . ?
O3 K1A H12A 53.8 . . ?
O12 K1A Eu1 101.9(9) . . ?
O12 K1A O1 114.8(10) . . ?
O12 K1A O3 70.4(7) . . ?
O12 K1A H12A 16.6 . . ?
Eu1 K1B H12A 95.6 . . ?
O1 K1B Eu1 36.3(5) . . ?
O1 K1B O3 58.8(7) . . ?
O1 K1B O12 121.9(10) . . ?
O1 K1B H12A 108.4 . . ?
O3 K1B Eu1 36.3(4) . . ?
O3 K1B O12 76.3(9) . . ?
O3 K1B H12A 59.3 . . ?
O12 K1B Eu1 112.5(10) . . ?
O12 K1B H12A 16.9 . . ?
Eu1 K1C H12A 98.0 . . ?
O1 K1C Eu1 35.98(16) . . ?
O1 K1C H12A 105.3 . . ?
O3 K1C Eu1 34.23(19) . . ?
O3 K1C O1 54.9(3) . . ?
O3 K1C H12A 63.8 . . ?
O12 K1C Eu1 116.5(4) . . ?
O12 K1C O1 117.9(5) . . ?
O12 K1C O3 82.4(4) . . ?
O12 K1C H12A 18.8 . . ?
O5 K2A Eu2 32.9(3) . . ?
O5 K2A O14 124.1(8) . . ?
O7 K2A Eu2 33.2(4) . . ?
O7 K2A O5 53.9(5) . . ?
O7 K2A O9 117.2(9) . . ?
O7 K2A O14 72.3(6) . . ?
O9 K2A Eu2 105.3(8) . . ?
O9 K2A O5 72.5(7) . . ?
O9 K2A O14 129.7(11) . . ?
O14 K2A Eu2 103.2(6) . . ?
O5 K2B Eu2 35.88(17) . . ?
O5 K2B O7 57.3(3) . . ?
O5 K2B O9 78.5(3) . . ?
O7 K2B Eu2 37.89(17) . . ?
O9 K2B Eu2 114.4(3) . . ?
O9 K2B O7 117.8(4) . . ?
Eu1 O1 K1A 112.8(8) . . ?
Eu1 O1 K1B 103.3(9) . . ?
Eu1 O1 K1C 96.2(3) . . ?
C17 O1 Eu1 123.7(6) . . ?
C17 O1 K1A 122.3(10) . . ?
C17 O1 K1B 131.7(10) . . ?
C17 O1 K1C 138.0(6) . . ?
Eu1 O3 K1A 102.9(5) . . ?
Eu1 O3 K1B 99.3(7) . . ?
Eu1 O3 K1C 105.3(3) . . ?
C1 O3 Eu1 128.3(6) . . ?
C1 O3 K1A 126.6(7) . . ?
C1 O3 K1B 128.7(9) . . ?
C1 O3 K1C 119.4(6) . . ?
Eu2 O5 K2A 102.2(5) . . ?
Eu2 O5 K2B 101.3(3) . . ?
C18 O5 Eu2 125.2(5) . . ?
C18 O5 K2A 127.2(7) . . ?
C18 O5 K2B 123.7(6) . . ?
Eu2 O7 K2A 108.1(7) . . ?
Eu2 O7 K2B 96.9(3) . . ?
C34 O7 Eu2 124.8(5) . . ?
C34 O7 K2A 125.5(8) . . ?
C34 O7 K2B 136.3(6) . . ?
K2A O9 H9 143.9 . . ?
K2B O9 H9 149.3 . . ?
K1A O12 H12A 90.3 . . ?
K1A O12 H12B 132.1 . . ?
K1B O12 H12A 81.1 . . ?
K1B O12 H12B 130.1 . . ?
K1C O12 H12A 80.1 . . ?
K1C O12 H12B 121.1 . . ?
H12A O12 H12B 104.8 . . ?
K2A O14 H14A 130.8 . . ?
K2A O14 H14B 109.2 . . ?
H14A O14 H14B 104.7 . . ?
C2 N1 Eu1 114.2(6) . . ?
C6 N1 Eu1 124.3(5) . . ?
C6 N1 C2 117.4(7) . . ?
C7 N2 Eu1 107.9(5) . . ?
C7 N2 C8 107.7(6) . . ?
C7 N2 C11 108.2(6) . . ?
C8 N2 Eu1 119.1(4) . . ?
C11 N2 Eu1 100.5(4) . . ?
C11 N2 C8 112.8(6) . . ?
C12 N3 Eu1 124.5(5) . . ?
C12 N3 C16 118.0(7) . . ?
C16 N3 Eu1 116.0(5) . . ?
C19 N4 Eu2 113.2(5) . . ?
C23 N4 Eu2 121.9(5) . . ?
C23 N4 C19 119.7(7) . . ?
C24 N5 Eu2 102.7(4) . . ?
C24 N5 C25 112.5(6) . . ?
C24 N5 C28 110.9(6) . . ?
C25 N5 Eu2 120.6(4) . . ?
C28 N5 Eu2 103.0(4) . . ?
C28 N5 C25 106.6(6) . . ?
C29 N6 Eu2 125.1(5) . . ?
C29 N6 C33 117.9(7) . . ?
C33 N6 Eu2 115.2(5) . . ?
O3 C1 C2 116.8(8) . . ?
O4 C1 O3 124.8(8) . . ?
O4 C1 C2 118.5(8) . . ?
N1 C2 C1 114.2(8) . . ?
N1 C2 C3 123.5(8) . . ?
C3 C2 C1 122.3(8) . . ?
C2 C3 H3 120.6 . . ?
C2 C3 C4 118.7(8) . . ?
C4 C3 H3 120.6 . . ?
C3 C4 H4 120.5 . . ?
C5 C4 C3 118.9(8) . . ?
C5 C4 H4 120.5 . . ?
C4 C5 H5 120.6 . . ?
C4 C5 C6 118.8(8) . . ?
C6 C5 H5 120.6 . . ?
N1 C6 C5 122.6(8) . . ?
N1 C6 C7 117.7(7) . . ?
C5 C6 C7 119.7(8) . . ?
N2 C7 C6 113.0(7) . . ?
N2 C7 H7A 109.0 . . ?
N2 C7 H7B 109.0 . . ?
C6 C7 H7A 109.0 . . ?
C6 C7 H7B 109.0 . . ?
H7A C7 H7B 107.8 . . ?
N2 C8 C8 113.3(4) . 2_654 ?
N2 C8 H8 106.7 . . ?
N2 C8 C9 114.0(6) . . ?
C8 C8 H8 106.7 2_654 . ?
C8 C8 C9 108.8(5) 2_654 . ?
C9 C8 H8 106.7 . . ?
C8 C9 H9A 109.2 . . ?
C8 C9 H9B 109.2 . . ?
H9A C9 H9B 107.9 . . ?
C10 C9 C8 111.9(7) . . ?
C10 C9 H9A 109.2 . . ?
C10 C9 H9B 109.2 . . ?
C9 C10 C10 108.8(6) . 2_654 ?
C9 C10 H10A 109.9 . . ?
C9 C10 H10B 109.9 . . ?
C10 C10 H10A 109.9 2_654 . ?
C10 C10 H10B 109.9 2_654 . ?
H10A C10 H10B 108.3 . . ?
N2 C11 H11A 109.0 . . ?
N2 C11 H11B 109.0 . . ?
N2 C11 C12 113.1(6) . . ?
H11A C11 H11B 107.8 . . ?
C12 C11 H11A 109.0 . . ?
C12 C11 H11B 109.0 . . ?
N3 C12 C11 116.0(7) . . ?
N3 C12 C13 121.6(8) . . ?
C13 C12 C11 122.3(8) . . ?
C12 C13 H13 120.2 . . ?
C14 C13 C12 119.7(8) . . ?
C14 C13 H13 120.2 . . ?
C13 C14 H14 120.4 . . ?
C15 C14 C13 119.1(8) . . ?
C15 C14 H14 120.4 . . ?
C14 C15 H15 120.8 . . ?
C14 C15 C16 118.5(8) . . ?
C16 C15 H15 120.8 . . ?
N3 C16 C15 123.1(8) . . ?
N3 C16 C17 115.2(7) . . ?
C15 C16 C17 121.7(8) . . ?
O1 C17 C16 115.7(7) . . ?
O2 C17 O1 126.2(9) . . ?
O2 C17 C16 118.1(8) . . ?
O5 C18 C19 115.9(7) . . ?
O6 C18 O5 124.5(8) . . ?
O6 C18 C19 119.5(8) . . ?
N4 C19 C18 115.3(7) . . ?
N4 C19 C20 121.8(8) . . ?
C20 C19 C18 122.8(8) . . ?
C19 C20 H20 120.7 . . ?
C21 C20 C19 118.7(9) . . ?
C21 C20 H20 120.7 . . ?
C20 C21 H21 120.4 . . ?
C20 C21 C22 119.3(8) . . ?
C22 C21 H21 120.4 . . ?
C21 C22 H22 120.2 . . ?
C21 C22 C23 119.5(8) . . ?
C23 C22 H22 120.2 . . ?
N4 C23 C22 120.8(8) . . ?
N4 C23 C24 117.7(7) . . ?
C22 C23 C24 121.6(8) . . ?
N5 C24 C23 112.3(6) . . ?
N5 C24 H24A 109.1 . . ?
N5 C24 H24B 109.1 . . ?
C23 C24 H24A 109.1 . . ?
C23 C24 H24B 109.1 . . ?
H24A C24 H24B 107.9 . . ?
N5 C25 C25 113.6(4) . 2_755 ?
N5 C25 H25 106.2 . . ?
N5 C25 C26 114.4(6) . . ?
C25 C25 H25 106.2 2_755 . ?
C25 C25 C26 109.5(5) 2_755 . ?
C26 C25 H25 106.2 . . ?
C25 C26 H26A 109.3 . . ?
C25 C26 H26B 109.3 . . ?
H26A C26 H26B 108.0 . . ?
C27 C26 C25 111.6(6) . . ?
C27 C26 H26A 109.3 . . ?
C27 C26 H26B 109.3 . . ?
C26 C27 H27A 109.6 . . ?
C26 C27 H27B 109.6 . . ?
C27 C27 C26 110.5(5) 2_755 . ?
C27 C27 H27A 109.6 2_755 . ?
C27 C27 H27B 109.6 2_755 . ?
H27A C27 H27B 108.1 . . ?
N5 C28 H28A 110.1 . . ?
N5 C28 H28B 110.1 . . ?
N5 C28 C29 107.9(6) . . ?
H28A C28 H28B 108.4 . . ?
C29 C28 H28A 110.1 . . ?
C29 C28 H28B 110.1 . . ?
N6 C29 C28 115.7(7) . . ?
N6 C29 C30 122.3(7) . . ?
C30 C29 C28 121.9(8) . . ?
C29 C30 H30 120.6 . . ?
C31 C30 C29 118.8(8) . . ?
C31 C30 H30 120.6 . . ?
C30 C31 H31 120.7 . . ?
C30 C31 C32 118.6(8) . . ?
C32 C31 H31 120.7 . . ?
C31 C32 H32 120.3 . . ?
C33 C32 C31 119.3(8) . . ?
C33 C32 H32 120.3 . . ?
N6 C33 C32 122.7(8) . . ?
N6 C33 C34 115.3(7) . . ?
C32 C33 C34 121.9(8) . . ?
O7 C34 C33 116.0(7) . . ?
O8 C34 O7 127.0(8) . . ?
O8 C34 C33 117.0(8) . . ?
H11C O11 H11D 104.5 . . ?
H13A O13 H13B 104.6 . . ?

_olex2_date_sample_data_collection 2021-10-19
_olex2_exptl_crystal_mounting_method 'mounted in a polyimide loop'
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.110
_oxdiff_exptl_absorpt_empirical_full_min 0.929
