# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1_151221_sq
_database_code_depnum_ccdc_archive 'CCDC 2121103'
loop_
_audit_author_name
_audit_author_address
'Yuan Qiong'
;Peking University
China
;
_audit_update_record             
;
2021-11-09 deposited with the CCDC.	2022-04-12 downloaded from the CCDC.
;
_audit_creation_date             2017-03-28
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.08.25 svn.r3337 for OlexSys, GUI svn.r5227)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C48 H74 Dy3 F3 Si6'
_chemical_formula_sum            'C48 H74 Dy3 F3 Si6'
_chemical_formula_weight         1364.11
_chemical_melting_point          ?
_chemical_oxdiff_formula         'c48 h78 f3 dy3 si6'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.1349(4)
_cell_length_b                   12.1825(3)
_cell_length_c                   22.6447(7)
_cell_angle_alpha                81.832(2)
_cell_angle_beta                 74.493(3)
_cell_angle_gamma                69.021(3)
_cell_volume                     3007.96(17)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    13882
_cell_measurement_temperature    180.01(10)
_cell_measurement_theta_max      29.7640
_cell_measurement_theta_min      3.6720
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    3.844
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.49908
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.506
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1342
_exptl_crystal_size_max          0.67
_exptl_crystal_size_mid          0.39
_exptl_crystal_size_min          0.27
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0574
_diffrn_reflns_av_unetI/netI     0.0589
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            48913
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.214
_diffrn_reflns_theta_max         27.454
_diffrn_reflns_theta_min         3.051
_diffrn_ambient_temperature      180.01(10)
_diffrn_detector_area_resol_mean 10.3914
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega   36.00   75.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191 -132.0000   -2.3184 39

#__ type_ start__ end____ width___ exp.time_
  2 omega   19.00   91.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191 -154.0000  118.2078 72

#__ type_ start__ end____ width___ exp.time_
  3 omega  -15.00   88.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191   57.0000   30.0000 103

#__ type_ start__ end____ width___ exp.time_
  4 omega  -16.00   88.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191   77.0000  150.0000 104

#__ type_ start__ end____ width___ exp.time_
  5 omega  -12.00   90.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191   38.0000  -60.0000 102

#__ type_ start__ end____ width___ exp.time_
  6 omega  -62.00   23.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191  -38.0000 -120.0000 85

#__ type_ start__ end____ width___ exp.time_
  7 omega  -36.00   28.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191  -77.0000    0.0000 64

#__ type_ start__ end____ width___ exp.time_
  8 omega   17.00   91.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191 -154.0000 -128.5064 74
;
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0481903000
_diffrn_orient_matrix_UB_12      0.0355508000
_diffrn_orient_matrix_UB_13      0.0220648000
_diffrn_orient_matrix_UB_21      0.0420046000
_diffrn_orient_matrix_UB_22      -0.0007678000
_diffrn_orient_matrix_UB_23      0.0167665000
_diffrn_orient_matrix_UB_31      0.0077239000
_diffrn_orient_matrix_UB_32      0.0513243000
_diffrn_orient_matrix_UB_33      -0.0170735000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10818
_reflns_number_total             13758
_reflns_odcompleteness_completeness 99.84
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     27.42
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         2.434
_refine_diff_density_min         -0.904
_refine_diff_density_rms         0.150
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     558
_refine_ls_number_reflns         13758
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0546
_refine_ls_R_factor_gt           0.0346
_refine_ls_restrained_S_all      1.055
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0281P)²+0.0444P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0678
_refine_ls_wR_factor_ref         0.0781
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C4(H4), C3AA(H3AA), C12(H12), C24(H24), C26(H26), C27(H27), C31(H31),
 C37(H37), C40(H40), C41(H41), C44(H44), C45(H45), C48(H48), C2AA(H2AA),
 C53(H53), C58(H58), C65(H65), C71(H71), C76(H76), C77(H77), C80(H80), C93(H93),
  C98(H98)
2.b Idealised Me refined as rotating group:
 C16(H16A,H16B,H16C), C50(H50A,H50B,H50C), C56(H56A,H56B,H56C), C60(H60A,H60B,
 H60C), C62(H62A,H62B,H62C), C67(H67A,H67B,H67C), C73(H73A,H73B,H73C), C86(H86A,
 H86B,H86C), C90(H90A,H90B,H90C), C91(H91A,H91B,H91C), C96(H96A,H96B,H96C),
 C100(H10A,H10B,H10C), C114(H11A,H11B,H11C), C118(H11D,H11E,H11F), C119(H11G,
 H11H,H11I), C0AA(H0AA,H0AB,H0AC), C1AA(H1AA,H1AB,H1AC)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.10561(2) 0.60434(2) 0.31189(2) 0.01969(6) Uani 1 1 d . . . . .
Dy3 Dy -0.00332(2) 0.89957(2) 0.18838(2) 0.01978(6) Uani 1 1 d . . . . .
Dy6 Dy 0.26456(2) 0.87517(2) 0.28510(2) 0.02211(6) Uani 1 1 d . . . . .
Si2 Si 0.38011(12) 0.34122(11) 0.36269(6) 0.0281(3) Uani 1 1 d . . . . .
Si4 Si -0.19826(13) 1.24410(11) 0.15265(6) 0.0315(3) Uani 1 1 d . . . . .
Si6 Si 0.42721(13) 1.05227(12) 0.14653(7) 0.0317(3) Uani 1 1 d . . . . .
Si8 Si 0.33877(13) 0.89801(12) 0.44764(6) 0.0307(3) Uani 1 1 d . . . . .
Si9 Si -0.05701(14) 0.69104(13) 0.08531(6) 0.0363(3) Uani 1 1 d . . . . .
Si11 Si -0.18304(13) 0.48777(13) 0.38427(7) 0.0355(3) Uani 1 1 d . . . . .
C18 C -0.1869(4) 1.1053(4) 0.2011(2) 0.0236(10) Uani 1 1 d . . . . .
C4 C 0.3150(4) 0.4649(4) 0.2490(2) 0.0268(10) Uani 1 1 d . . . . .
H4 H 0.3805 0.4948 0.2374 0.032 Uiso 1 1 calc R . . . .
C3AA C 0.1826(4) 0.3732(4) 0.3022(2) 0.0261(10) Uani 1 1 d . . . . .
H3AA H 0.1421 0.3298 0.3328 0.031 Uiso 1 1 calc R . . . .
C9 C 0.2857(4) 0.3993(4) 0.3050(2) 0.0219(9) Uani 1 1 d . . . . .
C12 C -0.1172(4) 0.6969(4) 0.3806(2) 0.0289(11) Uani 1 1 d . . . . .
H12 H -0.1783 0.7462 0.3605 0.035 Uiso 1 1 calc R . . . .
C14 C 0.4433(4) 0.9146(4) 0.1964(2) 0.0273(10) Uani 1 1 d . . . . .
C16 C -0.1086(6) 0.3289(5) 0.4010(4) 0.076(2) Uani 1 1 d . . . . .
H16A H -0.0409 0.2963 0.3663 0.113 Uiso 1 1 calc GR . . . .
H16B H -0.1676 0.2880 0.4075 0.113 Uiso 1 1 calc GR . . . .
H16C H -0.0780 0.3184 0.4380 0.113 Uiso 1 1 calc GR . . . .
C19 C -0.0875(4) 0.5732(4) 0.3913(2) 0.0256(10) Uani 1 1 d . . . . .
C24 C 0.2315(5) 0.4778(4) 0.2141(2) 0.0362(12) Uani 1 1 d . . . . .
H24 H 0.2308 0.5177 0.1749 0.043 Uiso 1 1 calc R . . . .
C26 C 0.1497(5) 0.4223(4) 0.2466(2) 0.0345(12) Uani 1 1 d . . . . .
H26 H 0.0832 0.4181 0.2335 0.041 Uiso 1 1 calc R . . . .
C27 C -0.2298(4) 0.9427(4) 0.2528(2) 0.0289(11) Uani 1 1 d . . . . .
H27 H -0.2573 0.8769 0.2628 0.035 Uiso 1 1 calc R . . . .
C31 C 0.1311(4) 0.9427(4) 0.3966(2) 0.0282(11) Uani 1 1 d . . . . .
H31 H 0.1037 0.8863 0.4241 0.034 Uiso 1 1 calc R . . . .
C34 C 0.1422(4) 0.7653(4) 0.0955(2) 0.0280(11) Uani 1 1 d . . . . .
C37 C -0.1487(4) 1.0816(4) 0.2572(2) 0.0265(10) Uani 1 1 d . . . . .
H37 H -0.1114 1.1261 0.2714 0.032 Uiso 1 1 calc R . . . .
C40 C 0.4352(4) 0.8076(4) 0.1833(2) 0.0339(12) Uani 1 1 d . . . . .
H40 H 0.4094 0.7970 0.1491 0.041 Uiso 1 1 calc R . . . .
C41 C 0.5020(4) 0.7700(4) 0.2707(3) 0.0363(12) Uani 1 1 d . . . . .
H41 H 0.5288 0.7308 0.3063 0.044 Uiso 1 1 calc R . . . .
C44 C -0.0182(4) 0.9200(4) 0.07326(19) 0.0256(10) Uani 1 1 d . . . . .
H44 H -0.0948 0.9655 0.0649 0.031 Uiso 1 1 calc R . . . .
C45 C 0.2435(4) 1.0546(4) 0.3456(2) 0.0287(11) Uani 1 1 d . . . . .
H45 H 0.3061 1.0883 0.3321 0.034 Uiso 1 1 calc R . . . .
C48 C -0.1747(4) 0.9822(4) 0.2885(2) 0.0275(10) Uani 1 1 d . . . . .
H48 H -0.1579 0.9480 0.3269 0.033 Uiso 1 1 calc R . . . .
C50 C 0.5159(5) 0.2131(4) 0.3331(3) 0.0433(14) Uani 1 1 d . . . . .
H50A H 0.4900 0.1483 0.3278 0.065 Uiso 1 1 calc GR . . . .
H50B H 0.5680 0.1874 0.3624 0.065 Uiso 1 1 calc GR . . . .
H50C H 0.5613 0.2360 0.2935 0.065 Uiso 1 1 calc GR . . . .
C2AA C 0.0682(4) 1.0183(4) 0.3553(2) 0.0313(11) Uani 1 1 d . . . . .
H2AA H -0.0079 1.0222 0.3495 0.038 Uiso 1 1 calc R . . . .
C53 C -0.2374(4) 1.0169(4) 0.1998(2) 0.0255(10) Uani 1 1 d . . . . .
H53 H -0.2710 1.0094 0.1679 0.031 Uiso 1 1 calc R . . . .
C56 C 0.4909(5) 0.9142(5) 0.4196(3) 0.0457(14) Uani 1 1 d . . . . .
H56A H 0.4817 0.9979 0.4123 0.069 Uiso 1 1 calc GR . . . .
H56B H 0.5328 0.8738 0.3813 0.069 Uiso 1 1 calc GR . . . .
H56C H 0.5386 0.8795 0.4505 0.069 Uiso 1 1 calc GR . . . .
C58 C 0.1739(4) 0.8682(4) 0.0863(2) 0.0314(11) Uani 1 1 d . . . . .
H58 H 0.2492 0.8724 0.0887 0.038 Uiso 1 1 calc R . . . .
C60 C -0.3284(5) 0.5420(5) 0.4418(3) 0.0474(15) Uani 1 1 d . . . . .
H60A H -0.3833 0.5021 0.4381 0.071 Uiso 1 1 calc GR . . . .
H60B H -0.3656 0.6271 0.4346 0.071 Uiso 1 1 calc GR . . . .
H60C H -0.3132 0.5256 0.4831 0.071 Uiso 1 1 calc GR . . . .
C62 C -0.3352(5) 1.3650(4) 0.1893(3) 0.0443(14) Uani 1 1 d . . . . .
H62A H -0.4078 1.3438 0.1939 0.066 Uiso 1 1 calc GR . . . .
H62B H -0.3420 1.4377 0.1635 0.066 Uiso 1 1 calc GR . . . .
H62C H -0.3279 1.3770 0.2298 0.066 Uiso 1 1 calc GR . . . .
C4AA C -0.2143(5) 1.2294(5) 0.0738(2) 0.0469(14) Uani 1 1 d . . . . .
C65 C 0.0069(4) 0.5378(4) 0.4229(2) 0.0290(11) Uani 1 1 d . . . . .
H65 H 0.0453 0.4594 0.4368 0.035 Uiso 1 1 calc R . . . .
C67 C 0.2606(6) 0.9735(5) 0.5204(3) 0.0526(16) Uani 1 1 d . . . . .
H67A H 0.3100 0.9400 0.5507 0.079 Uiso 1 1 calc GR . . . .
H67B H 0.1814 0.9627 0.5361 0.079 Uiso 1 1 calc GR . . . .
H67C H 0.2490 1.0577 0.5130 0.079 Uiso 1 1 calc GR . . . .
C69 C 0.2420(4) 0.9620(4) 0.3917(2) 0.0247(10) Uani 1 1 d . . . . .
C71 C 0.4706(4) 0.7205(4) 0.2281(3) 0.0383(13) Uani 1 1 d . . . . .
H71 H 0.4731 0.6413 0.2294 0.046 Uiso 1 1 calc R . . . .
C73 C 0.2924(5) 0.2906(5) 0.4359(2) 0.0398(13) Uani 1 1 d . . . . .
H73A H 0.2299 0.3589 0.4568 0.060 Uiso 1 1 calc GR . . . .
H73B H 0.3476 0.2475 0.4625 0.060 Uiso 1 1 calc GR . . . .
H73C H 0.2538 0.2387 0.4268 0.060 Uiso 1 1 calc GR . . . .
C76 C 0.0754(4) 0.9630(4) 0.0731(2) 0.0291(11) Uani 1 1 d . . . . .
H76 H 0.0721 1.0427 0.0654 0.035 Uiso 1 1 calc R . . . .
C77 C -0.0417(4) 0.7349(4) 0.4045(2) 0.0324(11) Uani 1 1 d . . . . .
H77 H -0.0425 0.8135 0.4032 0.039 Uiso 1 1 calc R . . . .
C80 C 0.4864(4) 0.8887(4) 0.2511(2) 0.0295(11) Uani 1 1 d . . . . .
H80 H 0.5021 0.9428 0.2712 0.035 Uiso 1 1 calc R . . . .
C82 C 0.0220(4) 0.7959(4) 0.0881(2) 0.0261(10) Uani 1 1 d . . . . .
C86 C 0.2794(6) 1.1093(6) 0.1246(3) 0.066(2) Uani 1 1 d . . . . .
H86A H 0.2724 1.0502 0.1020 0.099 Uiso 1 1 calc GR . . . .
H86B H 0.2743 1.1816 0.0986 0.099 Uiso 1 1 calc GR . . . .
H86C H 0.2134 1.1263 0.1617 0.099 Uiso 1 1 calc GR . . . .
C90 C 0.0621(6) 0.5444(5) 0.0685(3) 0.0609(18) Uani 1 1 d . . . . .
H90A H 0.1240 0.5522 0.0318 0.091 Uiso 1 1 calc GR . . . .
H90B H 0.0250 0.4894 0.0616 0.091 Uiso 1 1 calc GR . . . .
H90C H 0.0999 0.5146 0.1035 0.091 Uiso 1 1 calc GR . . . .
C91 C 0.4383(5) 1.1676(4) 0.1874(2) 0.0387(13) Uani 1 1 d . . . . .
H91A H 0.3677 1.1910 0.2220 0.058 Uiso 1 1 calc GR . . . .
H91B H 0.4406 1.2361 0.1592 0.058 Uiso 1 1 calc GR . . . .
H91C H 0.5126 1.1367 0.2027 0.058 Uiso 1 1 calc GR . . . .
C93 C 0.0344(5) 0.6358(4) 0.4304(2) 0.0339(12) Uani 1 1 d . . . . .
H93 H 0.0949 0.6353 0.4499 0.041 Uiso 1 1 calc R . . . .
C96 C -0.0648(5) 1.2876(5) 0.1502(3) 0.0527(16) Uani 1 1 d . . . . .
H96A H -0.0605 1.2938 0.1921 0.079 Uiso 1 1 calc GR . . . .
H96B H -0.0732 1.3638 0.1276 0.079 Uiso 1 1 calc GR . . . .
H96C H 0.0095 1.2280 0.1296 0.079 Uiso 1 1 calc GR . . . .
C98 C 0.1390(4) 1.0879(4) 0.3235(2) 0.0330(12) Uani 1 1 d . . . . .
H98 H 0.1188 1.1473 0.2923 0.040 Uiso 1 1 calc R . . . .
C100 C 0.5514(6) 1.0182(5) 0.0751(2) 0.0549(16) Uani 1 1 d . . . . .
H10A H 0.6303 0.9910 0.0859 0.082 Uiso 1 1 calc GR . . . .
H10B H 0.5441 1.0893 0.0479 0.082 Uiso 1 1 calc GR . . . .
H10C H 0.5450 0.9565 0.0541 0.082 Uiso 1 1 calc GR . . . .
C114 C -0.2153(7) 0.5123(8) 0.3074(3) 0.087(3) Uani 1 1 d . . . . .
H11A H -0.1402 0.4772 0.2768 0.130 Uiso 1 1 calc GR . . . .
H11B H -0.2478 0.5971 0.2977 0.130 Uiso 1 1 calc GR . . . .
H11C H -0.2750 0.4758 0.3069 0.130 Uiso 1 1 calc GR . . . .
C118 C 0.3541(5) 0.7396(4) 0.4625(3) 0.0468(14) Uani 1 1 d . . . . .
H11D H 0.4005 0.6973 0.4252 0.070 Uiso 1 1 calc GR . . . .
H11E H 0.2733 0.7319 0.4747 0.070 Uiso 1 1 calc GR . . . .
H11F H 0.3967 0.7063 0.4956 0.070 Uiso 1 1 calc GR . . . .
C119 C -0.1399(6) 0.7427(5) 0.0225(3) 0.0566(17) Uani 1 1 d . . . . .
H11G H -0.1960 0.8234 0.0293 0.085 Uiso 1 1 calc GR . . . .
H11H H -0.1857 0.6910 0.0223 0.085 Uiso 1 1 calc GR . . . .
H11I H -0.0815 0.7410 -0.0170 0.085 Uiso 1 1 calc GR . . . .
F1 F 0.1399(2) 0.9199(2) 0.22357(11) 0.0275(6) Uani 1 1 d . . . . .
F2 F 0.0283(2) 0.7297(2) 0.24179(11) 0.0261(6) Uani 1 1 d . . . . .
F3 F 0.2156(2) 0.7146(2) 0.31189(12) 0.0300(6) Uani 1 1 d . . . . .
C0AA C 0.4322(6) 0.4591(5) 0.3765(3) 0.0501(16) Uani 1 1 d . . . . .
H0AA H 0.4800 0.4828 0.3379 0.075 Uiso 1 1 calc GR . . . .
H0AB H 0.4826 0.4297 0.4065 0.075 Uiso 1 1 calc GR . . . .
H0AC H 0.3617 0.5271 0.3924 0.075 Uiso 1 1 calc GR . . . .
C1AA C -0.1705(7) 0.6819(7) 0.1586(3) 0.082(3) Uani 1 1 d . . . . .
H1AA H -0.1289 0.6526 0.1922 0.123 Uiso 1 1 calc GR . . . .
H1AB H -0.2115 0.6281 0.1547 0.123 Uiso 1 1 calc GR . . . .
H1AC H -0.2306 0.7603 0.1674 0.123 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 C4 2.652(5) . ?
Dy1 C3AA 2.652(4) . ?
Dy1 C9 2.657(4) . ?
Dy1 C12 2.659(5) . ?
Dy1 C19 2.657(4) . ?
Dy1 C24 2.663(5) . ?
Dy1 C26 2.656(5) . ?
Dy1 C65 2.630(4) . ?
Dy1 C77 2.651(5) . ?
Dy1 C93 2.629(5) . ?
Dy1 F2 2.194(2) . ?
Dy1 F3 2.207(2) . ?
Dy3 C18 2.682(4) . ?
Dy3 C27 2.645(5) . ?
Dy3 C34 2.672(5) . ?
Dy3 C37 2.678(5) . ?
Dy3 C44 2.631(4) . ?
Dy3 C48 2.665(5) . ?
Dy3 C53 2.642(4) . ?
Dy3 C58 2.668(5) . ?
Dy3 C76 2.635(4) . ?
Dy3 C82 2.647(4) . ?
Dy3 F1 2.195(2) . ?
Dy3 F2 2.205(2) . ?
Dy6 C14 2.668(4) . ?
Dy6 C31 2.669(5) . ?
Dy6 C40 2.654(5) . ?
Dy6 C41 2.650(5) . ?
Dy6 C45 2.642(4) . ?
Dy6 C2AA 2.651(5) . ?
Dy6 C69 2.680(4) . ?
Dy6 C71 2.658(5) . ?
Dy6 C80 2.653(4) . ?
Dy6 C98 2.626(5) . ?
Dy6 F1 2.202(2) . ?
Dy6 F3 2.202(2) . ?
Si2 C9 1.864(4) . ?
Si2 C50 1.862(5) . ?
Si2 C73 1.871(5) . ?
Si2 C0AA 1.856(5) . ?
Si4 C18 1.863(4) . ?
Si4 C62 1.865(5) . ?
Si4 C4AA 1.886(6) . ?
Si4 C96 1.861(5) . ?
Si6 C14 1.863(5) . ?
Si6 C86 1.852(5) . ?
Si6 C91 1.849(5) . ?
Si6 C100 1.871(6) . ?
Si8 C56 1.858(5) . ?
Si8 C67 1.853(6) . ?
Si8 C69 1.858(4) . ?
Si8 C118 1.861(5) . ?
Si9 C82 1.868(4) . ?
Si9 C90 1.864(6) . ?
Si9 C119 1.867(6) . ?
Si9 C1AA 1.871(6) . ?
Si11 C16 1.851(6) . ?
Si11 C19 1.861(4) . ?
Si11 C60 1.851(6) . ?
Si11 C114 1.845(6) . ?
C18 C37 1.425(6) . ?
C18 C53 1.424(6) . ?
C4 H4 0.9500 . ?
C4 C9 1.431(6) . ?
C4 C24 1.399(7) . ?
C3AA H3AA 0.9500 . ?
C3AA C9 1.416(6) . ?
C3AA C26 1.410(6) . ?
C12 H12 0.9500 . ?
C12 C19 1.418(6) . ?
C12 C77 1.410(6) . ?
C14 C40 1.418(6) . ?
C14 C80 1.423(6) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C19 C65 1.416(6) . ?
C24 H24 0.9500 . ?
C24 C26 1.390(7) . ?
C26 H26 0.9500 . ?
C27 H27 0.9500 . ?
C27 C48 1.401(6) . ?
C27 C53 1.398(6) . ?
C31 H31 0.9500 . ?
C31 C2AA 1.392(6) . ?
C31 C69 1.421(6) . ?
C34 C58 1.411(6) . ?
C34 C82 1.421(6) . ?
C37 H37 0.9500 . ?
C37 C48 1.406(6) . ?
C40 H40 0.9500 . ?
C40 C71 1.392(7) . ?
C41 H41 0.9500 . ?
C41 C71 1.403(7) . ?
C41 C80 1.411(6) . ?
C44 H44 0.9500 . ?
C44 C76 1.409(6) . ?
C44 C82 1.432(6) . ?
C45 H45 0.9500 . ?
C45 C69 1.425(6) . ?
C45 C98 1.392(6) . ?
C48 H48 0.9500 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C2AA H2AA 0.9500 . ?
C2AA C98 1.412(6) . ?
C53 H53 0.9500 . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C58 H58 0.9500 . ?
C58 C76 1.398(6) . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C65 H65 0.9500 . ?
C65 C93 1.394(6) . ?
C67 H67A 0.9800 . ?
C67 H67B 0.9800 . ?
C67 H67C 0.9800 . ?
C71 H71 0.9500 . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?
C76 H76 0.9500 . ?
C77 H77 0.9500 . ?
C77 C93 1.395(7) . ?
C80 H80 0.9500 . ?
C86 H86A 0.9800 . ?
C86 H86B 0.9800 . ?
C86 H86C 0.9800 . ?
C90 H90A 0.9800 . ?
C90 H90B 0.9800 . ?
C90 H90C 0.9800 . ?
C91 H91A 0.9800 . ?
C91 H91B 0.9800 . ?
C91 H91C 0.9800 . ?
C93 H93 0.9500 . ?
C96 H96A 0.9800 . ?
C96 H96B 0.9800 . ?
C96 H96C 0.9800 . ?
C98 H98 0.9500 . ?
C100 H10A 0.9800 . ?
C100 H10B 0.9800 . ?
C100 H10C 0.9800 . ?
C114 H11A 0.9800 . ?
C114 H11B 0.9800 . ?
C114 H11C 0.9800 . ?
C118 H11D 0.9800 . ?
C118 H11E 0.9800 . ?
C118 H11F 0.9800 . ?
C119 H11G 0.9800 . ?
C119 H11H 0.9800 . ?
C119 H11I 0.9800 . ?
C0AA H0AA 0.9800 . ?
C0AA H0AB 0.9800 . ?
C0AA H0AC 0.9800 . ?
C1AA H1AA 0.9800 . ?
C1AA H1AB 0.9800 . ?
C1AA H1AC 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C4 Dy1 C9 31.27(13) . . ?
C4 Dy1 C12 166.25(13) . . ?
C4 Dy1 C19 135.62(13) . . ?
C4 Dy1 C24 30.51(14) . . ?
C4 Dy1 C26 50.41(15) . . ?
C3AA Dy1 C4 50.67(14) . . ?
C3AA Dy1 C9 30.94(12) . . ?
C3AA Dy1 C12 115.62(14) . . ?
C3AA Dy1 C19 85.13(14) . . ?
C3AA Dy1 C24 50.53(14) . . ?
C3AA Dy1 C26 30.81(14) . . ?
C3AA Dy1 C77 130.17(15) . . ?
C9 Dy1 C12 137.68(13) . . ?
C9 Dy1 C19 107.63(13) . . ?
C9 Dy1 C24 51.29(14) . . ?
C12 Dy1 C24 143.14(16) . . ?
C19 Dy1 C12 30.95(13) . . ?
C19 Dy1 C24 124.89(15) . . ?
C26 Dy1 C9 51.28(14) . . ?
C26 Dy1 C12 118.06(15) . . ?
C26 Dy1 C19 94.80(15) . . ?
C26 Dy1 C24 30.31(15) . . ?
C65 Dy1 C4 120.45(14) . . ?
C65 Dy1 C3AA 79.54(15) . . ?
C65 Dy1 C9 89.21(14) . . ?
C65 Dy1 C12 50.52(14) . . ?
C65 Dy1 C19 31.07(13) . . ?
C65 Dy1 C24 129.88(15) . . ?
C65 Dy1 C26 102.85(15) . . ?
C65 Dy1 C77 50.75(15) . . ?
C77 Dy1 C4 155.91(15) . . ?
C77 Dy1 C9 133.44(14) . . ?
C77 Dy1 C12 30.81(14) . . ?
C77 Dy1 C19 51.50(14) . . ?
C77 Dy1 C24 173.56(15) . . ?
C77 Dy1 C26 146.20(15) . . ?
C93 Dy1 C4 128.79(15) . . ?
C93 Dy1 C3AA 105.32(15) . . ?
C93 Dy1 C9 102.81(15) . . ?
C93 Dy1 C12 50.59(15) . . ?
C93 Dy1 C19 51.40(14) . . ?
C93 Dy1 C24 153.59(15) . . ?
C93 Dy1 C26 132.59(15) . . ?
C93 Dy1 C65 30.73(14) . . ?
C93 Dy1 C77 30.63(15) . . ?
F2 Dy1 C4 103.97(11) . . ?
F2 Dy1 C3AA 122.51(12) . . ?
F2 Dy1 C9 132.56(11) . . ?
F2 Dy1 C12 82.39(12) . . ?
F2 Dy1 C19 103.60(12) . . ?
F2 Dy1 C24 81.58(12) . . ?
F2 Dy1 C26 91.79(12) . . ?
F2 Dy1 C65 132.27(12) . . ?
F2 Dy1 C77 93.99(13) . . ?
F2 Dy1 C93 124.60(13) . . ?
F2 Dy1 F3 87.52(9) . . ?
F3 Dy1 C4 82.74(12) . . ?
F3 Dy1 C3AA 127.38(12) . . ?
F3 Dy1 C9 96.52(11) . . ?
F3 Dy1 C12 109.97(12) . . ?
F3 Dy1 C19 132.48(12) . . ?
F3 Dy1 C24 102.25(14) . . ?
F3 Dy1 C26 131.43(13) . . ?
F3 Dy1 C65 113.07(12) . . ?
F3 Dy1 C77 82.13(12) . . ?
F3 Dy1 C93 84.05(12) . . ?
C27 Dy3 C18 51.30(13) . . ?
C27 Dy3 C34 136.18(15) . . ?
C27 Dy3 C37 50.41(14) . . ?
C27 Dy3 C48 30.60(14) . . ?
C27 Dy3 C58 155.38(15) . . ?
C27 Dy3 C82 107.97(15) . . ?
C34 Dy3 C18 136.28(13) . . ?
C34 Dy3 C37 164.15(13) . . ?
C37 Dy3 C18 30.83(13) . . ?
C44 Dy3 C18 85.66(14) . . ?
C44 Dy3 C27 104.57(14) . . ?
C44 Dy3 C34 51.04(14) . . ?
C44 Dy3 C37 116.17(14) . . ?
C44 Dy3 C48 129.76(14) . . ?
C44 Dy3 C53 79.29(14) . . ?
C44 Dy3 C58 50.86(14) . . ?
C44 Dy3 C76 31.04(13) . . ?
C44 Dy3 C82 31.48(13) . . ?
C48 Dy3 C18 51.20(13) . . ?
C48 Dy3 C34 163.24(14) . . ?
C48 Dy3 C37 30.51(13) . . ?
C48 Dy3 C58 166.04(14) . . ?
C53 Dy3 C18 31.00(13) . . ?
C53 Dy3 C27 30.66(13) . . ?
C53 Dy3 C34 125.51(14) . . ?
C53 Dy3 C37 50.32(14) . . ?
C53 Dy3 C48 50.52(14) . . ?
C53 Dy3 C58 128.04(14) . . ?
C53 Dy3 C82 94.82(14) . . ?
C58 Dy3 C18 119.07(14) . . ?
C58 Dy3 C34 30.65(13) . . ?
C58 Dy3 C37 135.79(14) . . ?
C76 Dy3 C18 89.78(14) . . ?
C76 Dy3 C27 128.61(15) . . ?
C76 Dy3 C34 50.85(14) . . ?
C76 Dy3 C37 113.31(14) . . ?
C76 Dy3 C48 140.88(14) . . ?
C76 Dy3 C53 98.55(15) . . ?
C76 Dy3 C58 30.58(14) . . ?
C76 Dy3 C82 51.72(13) . . ?
C82 Dy3 C18 112.40(14) . . ?
C82 Dy3 C34 30.98(14) . . ?
C82 Dy3 C37 142.68(14) . . ?
C82 Dy3 C48 138.55(14) . . ?
C82 Dy3 C58 51.26(14) . . ?
F1 Dy3 C18 106.84(11) . . ?
F1 Dy3 C27 123.41(13) . . ?
F1 Dy3 C34 97.18(12) . . ?
F1 Dy3 C37 84.09(12) . . ?
F1 Dy3 C44 127.32(12) . . ?
F1 Dy3 C48 93.06(12) . . ?
F1 Dy3 C53 134.28(12) . . ?
F1 Dy3 C58 80.04(12) . . ?
F1 Dy3 C76 96.72(12) . . ?
F1 Dy3 C82 127.76(12) . . ?
F1 Dy3 F2 86.25(9) . . ?
F2 Dy3 C18 133.13(11) . . ?
F2 Dy3 C27 83.58(11) . . ?
F2 Dy3 C34 83.38(11) . . ?
F2 Dy3 C37 112.47(11) . . ?
F2 Dy3 C44 122.14(11) . . ?
F2 Dy3 C48 84.09(11) . . ?
F2 Dy3 C53 111.72(11) . . ?
F2 Dy3 C58 107.35(12) . . ?
F2 Dy3 C76 134.20(13) . . ?
F2 Dy3 C82 90.98(11) . . ?
C14 Dy6 C31 141.34(14) . . ?
C14 Dy6 C69 112.63(13) . . ?
C31 Dy6 C69 30.81(13) . . ?
C40 Dy6 C14 30.91(14) . . ?
C40 Dy6 C31 168.11(14) . . ?
C40 Dy6 C69 137.67(14) . . ?
C40 Dy6 C71 30.39(15) . . ?
C41 Dy6 C14 51.55(15) . . ?
C41 Dy6 C31 118.40(16) . . ?
C41 Dy6 C40 50.50(16) . . ?
C41 Dy6 C2AA 143.71(15) . . ?
C41 Dy6 C69 92.58(15) . . ?
C41 Dy6 C71 30.65(15) . . ?
C41 Dy6 C80 30.86(14) . . ?
C45 Dy6 C14 91.65(14) . . ?
C45 Dy6 C31 50.29(14) . . ?
C45 Dy6 C40 122.31(15) . . ?
C45 Dy6 C41 97.26(15) . . ?
C45 Dy6 C2AA 50.85(15) . . ?
C45 Dy6 C69 31.05(13) . . ?
C45 Dy6 C71 126.34(15) . . ?
C45 Dy6 C80 77.32(15) . . ?
C2AA Dy6 C14 132.38(14) . . ?
C2AA Dy6 C31 30.33(14) . . ?
C2AA Dy6 C40 156.33(15) . . ?
C2AA Dy6 C69 51.31(14) . . ?
C2AA Dy6 C71 172.61(16) . . ?
C2AA Dy6 C80 128.00(15) . . ?
C71 Dy6 C14 51.23(14) . . ?
C71 Dy6 C31 142.31(16) . . ?
C71 Dy6 C69 122.21(15) . . ?
C80 Dy6 C14 31.02(13) . . ?
C80 Dy6 C31 118.27(14) . . ?
C80 Dy6 C40 50.33(15) . . ?
C80 Dy6 C69 87.47(14) . . ?
C80 Dy6 C71 50.56(15) . . ?
C98 Dy6 C14 101.64(15) . . ?
C98 Dy6 C31 50.39(15) . . ?
C98 Dy6 C40 129.68(15) . . ?
C98 Dy6 C41 126.07(15) . . ?
C98 Dy6 C45 30.63(14) . . ?
C98 Dy6 C2AA 31.03(14) . . ?
C98 Dy6 C69 51.33(14) . . ?
C98 Dy6 C71 150.40(15) . . ?
C98 Dy6 C80 100.43(15) . . ?
F1 Dy6 C14 92.97(11) . . ?
F1 Dy6 C31 107.46(12) . . ?
F1 Dy6 C40 83.87(13) . . ?
F1 Dy6 C41 134.11(14) . . ?
F1 Dy6 C45 113.82(12) . . ?
F1 Dy6 C2AA 80.58(12) . . ?
F1 Dy6 C69 131.29(12) . . ?
F1 Dy6 C71 106.26(14) . . ?
F1 Dy6 C80 123.88(12) . . ?
F1 Dy6 C98 84.28(12) . . ?
F1 Dy6 F3 85.96(9) . . ?
F3 Dy6 C14 130.28(12) . . ?
F3 Dy6 C31 84.64(12) . . ?
F3 Dy6 C40 100.08(13) . . ?
F3 Dy6 C41 96.38(12) . . ?
F3 Dy6 C45 133.83(12) . . ?
F3 Dy6 C2AA 96.52(12) . . ?
F3 Dy6 C69 104.56(11) . . ?
F3 Dy6 C71 81.42(12) . . ?
F3 Dy6 C80 127.06(12) . . ?
F3 Dy6 C98 127.55(13) . . ?
C9 Si2 C73 111.1(2) . . ?
C50 Si2 C9 110.3(2) . . ?
C50 Si2 C73 107.7(2) . . ?
C0AA Si2 C9 108.5(2) . . ?
C0AA Si2 C50 108.5(3) . . ?
C0AA Si2 C73 110.7(3) . . ?
C18 Si4 C62 109.4(2) . . ?
C18 Si4 C4AA 111.7(2) . . ?
C62 Si4 C4AA 107.6(3) . . ?
C96 Si4 C18 108.8(2) . . ?
C96 Si4 C62 106.5(3) . . ?
C96 Si4 C4AA 112.7(3) . . ?
C14 Si6 C100 108.0(2) . . ?
C86 Si6 C14 111.9(2) . . ?
C86 Si6 C100 108.6(3) . . ?
C91 Si6 C14 109.9(2) . . ?
C91 Si6 C86 108.1(3) . . ?
C91 Si6 C100 110.3(2) . . ?
C56 Si8 C69 112.3(2) . . ?
C56 Si8 C118 110.2(3) . . ?
C67 Si8 C56 109.3(3) . . ?
C67 Si8 C69 108.4(2) . . ?
C67 Si8 C118 108.4(3) . . ?
C69 Si8 C118 108.1(2) . . ?
C82 Si9 C1AA 112.2(2) . . ?
C90 Si9 C82 107.2(2) . . ?
C90 Si9 C119 110.0(3) . . ?
C90 Si9 C1AA 110.7(3) . . ?
C119 Si9 C82 108.9(2) . . ?
C119 Si9 C1AA 107.8(3) . . ?
C16 Si11 C19 110.5(3) . . ?
C60 Si11 C16 109.3(3) . . ?
C60 Si11 C19 106.8(2) . . ?
C114 Si11 C16 110.4(4) . . ?
C114 Si11 C19 111.3(3) . . ?
C114 Si11 C60 108.5(3) . . ?
Si4 C18 Dy3 128.0(2) . . ?
C37 C18 Dy3 74.4(2) . . ?
C37 C18 Si4 124.0(3) . . ?
C53 C18 Dy3 73.0(2) . . ?
C53 C18 Si4 129.4(3) . . ?
C53 C18 C37 105.2(4) . . ?
Dy1 C4 H4 116.7 . . ?
C9 C4 Dy1 74.6(3) . . ?
C9 C4 H4 125.5 . . ?
C24 C4 Dy1 75.2(3) . . ?
C24 C4 H4 125.5 . . ?
C24 C4 C9 108.9(4) . . ?
Dy1 C3AA H3AA 116.9 . . ?
C9 C3AA Dy1 74.8(2) . . ?
C9 C3AA H3AA 125.6 . . ?
C26 C3AA Dy1 74.8(3) . . ?
C26 C3AA H3AA 125.6 . . ?
C26 C3AA C9 108.9(4) . . ?
Si2 C9 Dy1 123.8(2) . . ?
C4 C9 Dy1 74.1(2) . . ?
C4 C9 Si2 125.9(3) . . ?
C3AA C9 Dy1 74.3(2) . . ?
C3AA C9 Si2 127.7(3) . . ?
C3AA C9 C4 105.7(4) . . ?
Dy1 C12 H12 117.7 . . ?
C19 C12 Dy1 74.4(3) . . ?
C19 C12 H12 125.4 . . ?
C77 C12 Dy1 74.3(3) . . ?
C77 C12 H12 125.4 . . ?
C77 C12 C19 109.2(4) . . ?
Si6 C14 Dy6 124.5(2) . . ?
C40 C14 Dy6 74.0(3) . . ?
C40 C14 Si6 127.8(4) . . ?
C40 C14 C80 105.2(4) . . ?
C80 C14 Dy6 73.9(2) . . ?
C80 C14 Si6 126.3(3) . . ?
Si11 C16 H16A 109.5 . . ?
Si11 C16 H16B 109.5 . . ?
Si11 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si11 C19 Dy1 129.4(2) . . ?
C12 C19 Dy1 74.6(3) . . ?
C12 C19 Si11 124.9(4) . . ?
C65 C19 Dy1 73.4(2) . . ?
C65 C19 Si11 127.5(3) . . ?
C65 C19 C12 105.6(4) . . ?
Dy1 C24 H24 117.3 . . ?
C4 C24 Dy1 74.3(3) . . ?
C4 C24 H24 125.9 . . ?
C26 C24 Dy1 74.6(3) . . ?
C26 C24 C4 108.3(4) . . ?
C26 C24 H24 125.9 . . ?
Dy1 C26 H26 116.6 . . ?
C3AA C26 Dy1 74.4(3) . . ?
C3AA C26 H26 125.9 . . ?
C24 C26 Dy1 75.1(3) . . ?
C24 C26 C3AA 108.2(4) . . ?
C24 C26 H26 125.9 . . ?
Dy3 C27 H27 116.1 . . ?
C48 C27 Dy3 75.5(3) . . ?
C48 C27 H27 126.0 . . ?
C53 C27 Dy3 74.5(3) . . ?
C53 C27 H27 126.0 . . ?
C53 C27 C48 108.0(4) . . ?
Dy6 C31 H31 117.7 . . ?
C2AA C31 Dy6 74.1(3) . . ?
C2AA C31 H31 124.9 . . ?
C2AA C31 C69 110.3(4) . . ?
C69 C31 Dy6 75.0(3) . . ?
C69 C31 H31 124.9 . . ?
C58 C34 Dy3 74.5(3) . . ?
C58 C34 C82 108.5(4) . . ?
C82 C34 Dy3 73.6(3) . . ?
Dy3 C37 H37 117.6 . . ?
C18 C37 Dy3 74.7(3) . . ?
C18 C37 H37 125.3 . . ?
C48 C37 Dy3 74.2(3) . . ?
C48 C37 C18 109.4(4) . . ?
C48 C37 H37 125.3 . . ?
Dy6 C40 H40 116.8 . . ?
C14 C40 Dy6 75.1(3) . . ?
C14 C40 H40 125.0 . . ?
C71 C40 Dy6 75.0(3) . . ?
C71 C40 C14 110.0(4) . . ?
C71 C40 H40 125.0 . . ?
Dy6 C41 H41 116.2 . . ?
C71 C41 Dy6 75.0(3) . . ?
C71 C41 H41 126.3 . . ?
C71 C41 C80 107.4(4) . . ?
C80 C41 Dy6 74.7(3) . . ?
C80 C41 H41 126.3 . . ?
Dy3 C44 H44 116.7 . . ?
C76 C44 Dy3 74.6(2) . . ?
C76 C44 H44 125.8 . . ?
C76 C44 C82 108.3(4) . . ?
C82 C44 Dy3 74.9(2) . . ?
C82 C44 H44 125.8 . . ?
Dy6 C45 H45 116.6 . . ?
C69 C45 Dy6 75.9(2) . . ?
C69 C45 H45 125.3 . . ?
C98 C45 Dy6 74.1(3) . . ?
C98 C45 H45 125.3 . . ?
C98 C45 C69 109.4(4) . . ?
Dy3 C48 H48 116.8 . . ?
C27 C48 Dy3 73.9(3) . . ?
C27 C48 C37 107.7(4) . . ?
C27 C48 H48 126.1 . . ?
C37 C48 Dy3 75.2(3) . . ?
C37 C48 H48 126.1 . . ?
Si2 C50 H50A 109.5 . . ?
Si2 C50 H50B 109.5 . . ?
Si2 C50 H50C 109.5 . . ?
H50A C50 H50B 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
Dy6 C2AA H2AA 116.7 . . ?
C31 C2AA Dy6 75.5(3) . . ?
C31 C2AA H2AA 126.5 . . ?
C31 C2AA C98 107.0(4) . . ?
C98 C2AA Dy6 73.5(3) . . ?
C98 C2AA H2AA 126.5 . . ?
Dy3 C53 H53 115.9 . . ?
C18 C53 Dy3 76.0(2) . . ?
C18 C53 H53 125.2 . . ?
C27 C53 Dy3 74.8(3) . . ?
C27 C53 C18 109.7(4) . . ?
C27 C53 H53 125.2 . . ?
Si8 C56 H56A 109.5 . . ?
Si8 C56 H56B 109.5 . . ?
Si8 C56 H56C 109.5 . . ?
H56A C56 H56B 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
Dy3 C58 H58 117.9 . . ?
C34 C58 Dy3 74.8(3) . . ?
C34 C58 H58 125.8 . . ?
C76 C58 Dy3 73.4(3) . . ?
C76 C58 C34 108.4(4) . . ?
C76 C58 H58 125.8 . . ?
Si11 C60 H60A 109.5 . . ?
Si11 C60 H60B 109.5 . . ?
Si11 C60 H60C 109.5 . . ?
H60A C60 H60B 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
Si4 C62 H62A 109.5 . . ?
Si4 C62 H62B 109.5 . . ?
Si4 C62 H62C 109.5 . . ?
H62A C62 H62B 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
Dy1 C65 H65 116.5 . . ?
C19 C65 Dy1 75.5(2) . . ?
C19 C65 H65 125.3 . . ?
C93 C65 Dy1 74.6(3) . . ?
C93 C65 C19 109.3(4) . . ?
C93 C65 H65 125.3 . . ?
Si8 C67 H67A 109.5 . . ?
Si8 C67 H67B 109.5 . . ?
Si8 C67 H67C 109.5 . . ?
H67A C67 H67B 109.5 . . ?
H67A C67 H67C 109.5 . . ?
H67B C67 H67C 109.5 . . ?
Si8 C69 Dy6 127.3(2) . . ?
C31 C69 Dy6 74.2(3) . . ?
C31 C69 Si8 123.5(3) . . ?
C31 C69 C45 104.9(4) . . ?
C45 C69 Dy6 73.0(2) . . ?
C45 C69 Si8 130.3(3) . . ?
Dy6 C71 H71 117.0 . . ?
C40 C71 Dy6 74.7(3) . . ?
C40 C71 C41 108.1(4) . . ?
C40 C71 H71 126.0 . . ?
C41 C71 Dy6 74.4(3) . . ?
C41 C71 H71 126.0 . . ?
Si2 C73 H73A 109.5 . . ?
Si2 C73 H73B 109.5 . . ?
Si2 C73 H73C 109.5 . . ?
H73A C73 H73B 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
Dy3 C76 H76 115.9 . . ?
C44 C76 Dy3 74.3(2) . . ?
C44 C76 H76 125.9 . . ?
C58 C76 Dy3 76.0(3) . . ?
C58 C76 C44 108.3(4) . . ?
C58 C76 H76 125.9 . . ?
Dy1 C77 H77 117.1 . . ?
C12 C77 Dy1 74.9(3) . . ?
C12 C77 H77 126.3 . . ?
C93 C77 Dy1 73.8(3) . . ?
C93 C77 C12 107.3(4) . . ?
C93 C77 H77 126.3 . . ?
Dy6 C80 H80 117.0 . . ?
C14 C80 Dy6 75.1(2) . . ?
C14 C80 H80 125.3 . . ?
C41 C80 Dy6 74.5(3) . . ?
C41 C80 C14 109.4(4) . . ?
C41 C80 H80 125.3 . . ?
Si9 C82 Dy3 123.9(2) . . ?
C34 C82 Dy3 75.5(3) . . ?
C34 C82 Si9 126.2(3) . . ?
C34 C82 C44 106.5(4) . . ?
C44 C82 Dy3 73.7(2) . . ?
C44 C82 Si9 126.6(3) . . ?
Si6 C86 H86A 109.5 . . ?
Si6 C86 H86B 109.5 . . ?
Si6 C86 H86C 109.5 . . ?
H86A C86 H86B 109.5 . . ?
H86A C86 H86C 109.5 . . ?
H86B C86 H86C 109.5 . . ?
Si9 C90 H90A 109.5 . . ?
Si9 C90 H90B 109.5 . . ?
Si9 C90 H90C 109.5 . . ?
H90A C90 H90B 109.5 . . ?
H90A C90 H90C 109.5 . . ?
H90B C90 H90C 109.5 . . ?
Si6 C91 H91A 109.5 . . ?
Si6 C91 H91B 109.5 . . ?
Si6 C91 H91C 109.5 . . ?
H91A C91 H91B 109.5 . . ?
H91A C91 H91C 109.5 . . ?
H91B C91 H91C 109.5 . . ?
Dy1 C93 H93 116.1 . . ?
C65 C93 Dy1 74.7(3) . . ?
C65 C93 C77 108.5(4) . . ?
C65 C93 H93 125.7 . . ?
C77 C93 Dy1 75.6(3) . . ?
C77 C93 H93 125.7 . . ?
Si4 C96 H96A 109.5 . . ?
Si4 C96 H96B 109.5 . . ?
Si4 C96 H96C 109.5 . . ?
H96A C96 H96B 109.5 . . ?
H96A C96 H96C 109.5 . . ?
H96B C96 H96C 109.5 . . ?
Dy6 C98 H98 115.5 . . ?
C45 C98 Dy6 75.3(3) . . ?
C45 C98 C2AA 108.3(4) . . ?
C45 C98 H98 125.8 . . ?
C2AA C98 Dy6 75.5(3) . . ?
C2AA C98 H98 125.8 . . ?
Si6 C100 H10A 109.5 . . ?
Si6 C100 H10B 109.5 . . ?
Si6 C100 H10C 109.5 . . ?
H10A C100 H10B 109.5 . . ?
H10A C100 H10C 109.5 . . ?
H10B C100 H10C 109.5 . . ?
Si11 C114 H11A 109.5 . . ?
Si11 C114 H11B 109.5 . . ?
Si11 C114 H11C 109.5 . . ?
H11A C114 H11B 109.5 . . ?
H11A C114 H11C 109.5 . . ?
H11B C114 H11C 109.5 . . ?
Si8 C118 H11D 109.5 . . ?
Si8 C118 H11E 109.5 . . ?
Si8 C118 H11F 109.5 . . ?
H11D C118 H11E 109.5 . . ?
H11D C118 H11F 109.5 . . ?
H11E C118 H11F 109.5 . . ?
Si9 C119 H11G 109.5 . . ?
Si9 C119 H11H 109.5 . . ?
Si9 C119 H11I 109.5 . . ?
H11G C119 H11H 109.5 . . ?
H11G C119 H11I 109.5 . . ?
H11H C119 H11I 109.5 . . ?
Dy3 F1 Dy6 154.30(12) . . ?
Dy1 F2 Dy3 152.06(12) . . ?
Dy6 F3 Dy1 152.46(12) . . ?
Si2 C0AA H0AA 109.5 . . ?
Si2 C0AA H0AB 109.5 . . ?
Si2 C0AA H0AC 109.5 . . ?
H0AA C0AA H0AB 109.5 . . ?
H0AA C0AA H0AC 109.5 . . ?
H0AB C0AA H0AC 109.5 . . ?
Si9 C1AA H1AA 109.5 . . ?
Si9 C1AA H1AB 109.5 . . ?
Si9 C1AA H1AC 109.5 . . ?
H1AA C1AA H1AB 109.5 . . ?
H1AA C1AA H1AC 109.5 . . ?
H1AB C1AA H1AC 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 C4 C9 Si2 -120.6(3) . . . . ?
Dy1 C4 C9 C3AA 68.2(3) . . . . ?
Dy1 C4 C24 C26 -67.4(3) . . . . ?
Dy1 C3AA C9 Si2 120.9(4) . . . . ?
Dy1 C3AA C9 C4 -68.1(3) . . . . ?
Dy1 C3AA C26 C24 68.2(3) . . . . ?
Dy1 C12 C19 Si11 -127.7(3) . . . . ?
Dy1 C12 C19 C65 67.4(3) . . . . ?
Dy1 C12 C77 C93 -67.3(3) . . . . ?
Dy1 C19 C65 C93 67.6(3) . . . . ?
Dy1 C24 C26 C3AA -67.7(3) . . . . ?
Dy1 C65 C93 C77 68.6(3) . . . . ?
Dy1 C77 C93 C65 -68.0(3) . . . . ?
Dy3 C18 C37 C48 -66.8(3) . . . . ?
Dy3 C18 C53 C27 67.9(3) . . . . ?
Dy3 C27 C48 C37 68.3(3) . . . . ?
Dy3 C27 C53 C18 -68.7(3) . . . . ?
Dy3 C34 C58 C76 -66.3(3) . . . . ?
Dy3 C34 C82 Si9 -121.6(3) . . . . ?
Dy3 C34 C82 C44 67.7(3) . . . . ?
Dy3 C37 C48 C27 -67.4(3) . . . . ?
Dy3 C44 C76 C58 69.1(3) . . . . ?
Dy3 C44 C82 Si9 120.4(4) . . . . ?
Dy3 C44 C82 C34 -68.9(3) . . . . ?
Dy3 C58 C76 C44 -68.0(3) . . . . ?
Dy6 C14 C40 C71 -67.5(4) . . . . ?
Dy6 C14 C80 C41 67.2(3) . . . . ?
Dy6 C31 C2AA C98 -67.3(3) . . . . ?
Dy6 C31 C69 Si8 -124.6(3) . . . . ?
Dy6 C31 C69 C45 67.0(3) . . . . ?
Dy6 C40 C71 C41 -67.5(4) . . . . ?
Dy6 C41 C71 C40 67.6(3) . . . . ?
Dy6 C41 C80 C14 -67.6(3) . . . . ?
Dy6 C45 C69 Si8 124.9(4) . . . . ?
Dy6 C45 C69 C31 -67.9(3) . . . . ?
Dy6 C45 C98 C2AA 68.9(3) . . . . ?
Dy6 C2AA C98 C45 -68.8(3) . . . . ?
Si4 C18 C37 Dy3 -125.7(3) . . . . ?
Si4 C18 C37 C48 167.6(3) . . . . ?
Si4 C18 C53 Dy3 125.6(4) . . . . ?
Si4 C18 C53 C27 -166.5(4) . . . . ?
Si6 C14 C40 Dy6 -121.5(4) . . . . ?
Si6 C14 C40 C71 171.0(4) . . . . ?
Si6 C14 C80 Dy6 121.3(4) . . . . ?
Si6 C14 C80 C41 -171.6(4) . . . . ?
Si11 C19 C65 Dy1 127.4(4) . . . . ?
Si11 C19 C65 C93 -165.1(4) . . . . ?
C18 C37 C48 Dy3 67.1(3) . . . . ?
C18 C37 C48 C27 -0.3(5) . . . . ?
C4 C24 C26 Dy1 67.3(3) . . . . ?
C4 C24 C26 C3AA -0.4(5) . . . . ?
C9 C4 C24 Dy1 67.6(3) . . . . ?
C9 C4 C24 C26 0.1(5) . . . . ?
C9 C3AA C26 Dy1 -67.6(3) . . . . ?
C9 C3AA C26 C24 0.6(5) . . . . ?
C12 C19 C65 Dy1 -68.3(3) . . . . ?
C12 C19 C65 C93 -0.7(5) . . . . ?
C12 C77 C93 Dy1 68.0(3) . . . . ?
C12 C77 C93 C65 -0.1(5) . . . . ?
C14 C40 C71 Dy6 67.6(3) . . . . ?
C14 C40 C71 C41 0.1(6) . . . . ?
C16 Si11 C19 Dy1 80.1(4) . . . . ?
C16 Si11 C19 C12 179.0(4) . . . . ?
C16 Si11 C19 C65 -19.5(5) . . . . ?
C19 C12 C77 Dy1 66.9(3) . . . . ?
C19 C12 C77 C93 -0.4(5) . . . . ?
C19 C65 C93 Dy1 -68.2(3) . . . . ?
C19 C65 C93 C77 0.5(5) . . . . ?
C24 C4 C9 Dy1 -68.0(3) . . . . ?
C24 C4 C9 Si2 171.5(3) . . . . ?
C24 C4 C9 C3AA 0.2(5) . . . . ?
C26 C3AA C9 Dy1 67.6(3) . . . . ?
C26 C3AA C9 Si2 -171.5(3) . . . . ?
C26 C3AA C9 C4 -0.5(5) . . . . ?
C31 C2AA C98 Dy6 68.7(3) . . . . ?
C31 C2AA C98 C45 -0.1(5) . . . . ?
C34 C58 C76 Dy3 67.3(3) . . . . ?
C34 C58 C76 C44 -0.7(5) . . . . ?
C37 C18 C53 Dy3 -68.0(3) . . . . ?
C37 C18 C53 C27 -0.1(5) . . . . ?
C40 C14 C80 Dy6 -68.0(3) . . . . ?
C40 C14 C80 C41 -0.8(5) . . . . ?
C48 C27 C53 Dy3 68.7(3) . . . . ?
C48 C27 C53 C18 0.0(5) . . . . ?
C50 Si2 C9 Dy1 -167.7(2) . . . . ?
C50 Si2 C9 C4 -73.1(4) . . . . ?
C50 Si2 C9 C3AA 96.2(4) . . . . ?
C2AA C31 C69 Dy6 -66.4(3) . . . . ?
C2AA C31 C69 Si8 169.0(3) . . . . ?
C2AA C31 C69 C45 0.7(5) . . . . ?
C53 C18 C37 Dy3 67.0(3) . . . . ?
C53 C18 C37 C48 0.2(5) . . . . ?
C53 C27 C48 Dy3 -68.1(3) . . . . ?
C53 C27 C48 C37 0.2(5) . . . . ?
C56 Si8 C69 Dy6 72.8(3) . . . . ?
C56 Si8 C69 C31 168.1(4) . . . . ?
C56 Si8 C69 C45 -26.8(5) . . . . ?
C58 C34 C82 Dy3 -66.9(3) . . . . ?
C58 C34 C82 Si9 171.5(3) . . . . ?
C58 C34 C82 C44 0.8(5) . . . . ?
C60 Si11 C19 Dy1 -161.2(3) . . . . ?
C60 Si11 C19 C12 -62.3(5) . . . . ?
C60 Si11 C19 C65 99.2(5) . . . . ?
C62 Si4 C18 Dy3 -171.7(3) . . . . ?
C62 Si4 C18 C37 -75.0(4) . . . . ?
C62 Si4 C18 C53 89.1(5) . . . . ?
C4AA Si4 C18 Dy3 69.4(3) . . . . ?
C4AA Si4 C18 C37 166.1(4) . . . . ?
C4AA Si4 C18 C53 -29.8(5) . . . . ?
C67 Si8 C69 Dy6 -166.3(3) . . . . ?
C67 Si8 C69 C31 -71.0(4) . . . . ?
C67 Si8 C69 C45 94.1(5) . . . . ?
C69 C31 C2AA Dy6 67.0(3) . . . . ?
C69 C31 C2AA C98 -0.4(5) . . . . ?
C69 C45 C98 Dy6 -68.4(3) . . . . ?
C69 C45 C98 C2AA 0.5(5) . . . . ?
C71 C41 C80 Dy6 68.4(3) . . . . ?
C71 C41 C80 C14 0.9(6) . . . . ?
C73 Si2 C9 Dy1 72.9(3) . . . . ?
C73 Si2 C9 C4 167.5(4) . . . . ?
C73 Si2 C9 C3AA -23.2(5) . . . . ?
C76 C44 C82 Dy3 67.7(3) . . . . ?
C76 C44 C82 Si9 -171.9(3) . . . . ?
C76 C44 C82 C34 -1.2(5) . . . . ?
C77 C12 C19 Dy1 -66.8(3) . . . . ?
C77 C12 C19 Si11 165.6(3) . . . . ?
C77 C12 C19 C65 0.7(5) . . . . ?
C80 C14 C40 Dy6 67.9(3) . . . . ?
C80 C14 C40 C71 0.4(5) . . . . ?
C80 C41 C71 Dy6 -68.2(3) . . . . ?
C80 C41 C71 C40 -0.6(6) . . . . ?
C82 C34 C58 Dy3 66.2(3) . . . . ?
C82 C34 C58 C76 -0.1(5) . . . . ?
C82 C44 C76 Dy3 -67.9(3) . . . . ?
C82 C44 C76 C58 1.2(5) . . . . ?
C86 Si6 C14 Dy6 -39.2(4) . . . . ?
C86 Si6 C14 C40 57.1(5) . . . . ?
C86 Si6 C14 C80 -134.2(5) . . . . ?
C90 Si9 C82 Dy3 -114.7(3) . . . . ?
C90 Si9 C82 C34 -18.0(5) . . . . ?
C90 Si9 C82 C44 150.9(4) . . . . ?
C91 Si6 C14 Dy6 80.9(3) . . . . ?
C91 Si6 C14 C40 177.2(4) . . . . ?
C91 Si6 C14 C80 -14.1(5) . . . . ?
C96 Si4 C18 Dy3 -55.7(3) . . . . ?
C96 Si4 C18 C37 41.0(5) . . . . ?
C96 Si4 C18 C53 -154.9(4) . . . . ?
C98 C45 C69 Dy6 67.1(3) . . . . ?
C98 C45 C69 Si8 -167.9(4) . . . . ?
C98 C45 C69 C31 -0.7(5) . . . . ?
C100 Si6 C14 Dy6 -158.7(3) . . . . ?
C100 Si6 C14 C40 -62.4(5) . . . . ?
C100 Si6 C14 C80 106.3(5) . . . . ?
C114 Si11 C19 Dy1 -42.9(4) . . . . ?
C114 Si11 C19 C12 56.0(5) . . . . ?
C114 Si11 C19 C65 -142.5(5) . . . . ?
C118 Si8 C69 Dy6 -49.0(3) . . . . ?
C118 Si8 C69 C31 46.3(5) . . . . ?
C118 Si8 C69 C45 -148.6(5) . . . . ?
C119 Si9 C82 Dy3 126.4(3) . . . . ?
C119 Si9 C82 C34 -137.0(4) . . . . ?
C119 Si9 C82 C44 31.9(5) . . . . ?
C0AA Si2 C9 Dy1 -49.0(3) . . . . ?
C0AA Si2 C9 C4 45.6(5) . . . . ?
C0AA Si2 C9 C3AA -145.0(4) . . . . ?
C1AA Si9 C82 Dy3 7.1(4) . . . . ?
C1AA Si9 C82 C34 103.8(5) . . . . ?
C1AA Si9 C82 C44 -87.3(5) . . . . ?

_shelx_SHELXL_version_number     2014/7

_olex2_submission_special_instructions 'No special instructions were received'
# SQUEEZE RESULTS (Version = 230916)
# Note: Data are Listed for all Voids in the P1 Unit Cell
# i.e. Centre of Gravity, Solvent Accessible Volume,
# Recovered number of Electrons in the Void and
# Details about the Squeezed Material
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.500 0.500 1.000 245 72 ' '
_platon_squeeze_void_probe_radius 1.20
_platon_squeeze_details          ?

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2121120'
loop_
_audit_author_name
_audit_author_address
'Yuan Qiong'
;Peking University
China
;
_audit_update_record             
;
2021-11-09 deposited with the CCDC.	2022-04-12 downloaded from the CCDC.
;
_audit_creation_date             2016-06-24
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_shelxl_version_number           2014-3
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C32 H54 Dy2 O2 Si4'
_chemical_formula_sum            'C32 H54 Dy2 O2 Si4'
_chemical_formula_weight         908.11
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C32 H54 Dy2 O2'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   13.1068(2)
_cell_length_b                   23.7324(3)
_cell_length_c                   25.4803(5)
_cell_angle_alpha                90
_cell_angle_beta                 102.1981(17)
_cell_angle_gamma                90
_cell_volume                     7746.9(2)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    39048
_cell_measurement_temperature    180.00(10)
_cell_measurement_theta_max      29.9550
_cell_measurement_theta_min      3.0480
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    3.976
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.42843
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.557
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_F_000             3600
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0576
_diffrn_reflns_av_unetI/netI     0.0374
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            124672
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.214
_diffrn_reflns_theta_max         27.454
_diffrn_reflns_theta_min         3.023
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      180.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.3914
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega    7.00   76.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       13.4628 -133.0000   71.5975 69

#__ type_ start__ end____ width___ exp.time_
  2 omega  -16.00   87.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       13.4628   57.0000  -30.0000 103

#__ type_ start__ end____ width___ exp.time_
  3 omega  -17.00   92.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       13.4628   77.0000   90.0000 109

#__ type_ start__ end____ width___ exp.time_
  4 omega  -13.00   89.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       13.4628   38.0000 -120.0000 102

#__ type_ start__ end____ width___ exp.time_
  5 omega  -62.00   32.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       13.4628  -38.0000 -180.0000 94

#__ type_ start__ end____ width___ exp.time_
  6 omega  -16.00   55.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       13.4628  -99.0000  -60.0000 71

#__ type_ start__ end____ width___ exp.time_
  7 omega   35.00  103.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       13.4628  178.0000 -150.0000 68

#__ type_ start__ end____ width___ exp.time_
  8 omega  -92.00  -66.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -      -14.5566  154.0000  100.0750 26
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0529817000
_diffrn_orient_matrix_UB_12      0.0078859000
_diffrn_orient_matrix_UB_13      0.0023910000
_diffrn_orient_matrix_UB_21      0.0105056000
_diffrn_orient_matrix_UB_22      -0.0075480000
_diffrn_orient_matrix_UB_23      0.0275580000
_diffrn_orient_matrix_UB_31      0.0121713000
_diffrn_orient_matrix_UB_32      -0.0278185000
_diffrn_orient_matrix_UB_33      -0.0067970000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                13726
_reflns_number_total             17739
_reflns_odcompleteness_completeness 99.84
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     27.42
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    
;
Superflip (Palatinus & Chapuis, 2007;Palatinus & van der Lee, 2008;
Palatinus et al., 2012)
;
_refine_diff_density_max         1.480
_refine_diff_density_min         -0.881
_refine_diff_density_rms         0.135
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.128
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     757
_refine_ls_number_reflns         17739
_refine_ls_number_restraints     4
_refine_ls_R_factor_all          0.0556
_refine_ls_R_factor_gt           0.0340
_refine_ls_restrained_S_all      1.129
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0191P)²+17.5696P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0667
_refine_ls_wR_factor_ref         0.0770
_refine_special_details          
;
 ?
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All O(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 O52-H52
 0.99 with sigma of 0.02
 O64-H64
 0.99 with sigma of 0.02
 O74-H74
 0.99 with sigma of 0.02
 O86-H86
 0.99 with sigma of 0.02
3.a Aromatic/amide H refined with riding coordinates:
 C34(H34), C51(H51), C63(H63), C66(H66), C72(H72), C99(H99), C101(H101),
 C106(H106), C108(H108), C120(H120), C131(H131), C163(H163), C165(H165),
 C171(H171), C175(H175), C181(H181), C191(H191), C194(H194), C226(H226),
 C231(H231), C234(H234), C237(H237), C240(H240), C267(H267), C275(H275),
 C285(H285), C287(H287), C304(H304), C4(H4), C1AA(H1AA), C7(H7), C2AA(H2AA)
3.b Idealised Me refined as rotating group:
 C78(H78A,H78B,H78C), C103(H10A,H10B,H10C), C130(H13A,H13B,H13C), C249(H24A,
 H24B,H24C), C278(H27A,H27B,H27C), C295(H29A,H29B,H29C), C311(H31A,H31B,H31C),
 C322(H32A,H32B,H32C), C10(H10D,H10E,H10F), C11(H11A,H11B,H11C), C12(H12A,H12B,
 H12C), C13(H13D,H13E,H13F), C14(H14A,H14B,H14C), C16(H16A,H16B,H16C), C18(H18A,
 H18B,H18C), C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C3AA(H3AA,H3AB,H3AC),
 C4AA(H4AA,H4AB,H4AC), C5(H5A,H5B,H5C), C6(H6A,H6B,H6C), C8(H8A,H8B,H8C),
 C2(H2A,H2B,H2C), C3(H3A,H3B,H3C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.63328(2) 0.34244(2) 0.44379(2) 0.02326(5) Uani 1 1 d . . . . .
Dy6 Dy 0.73660(2) 0.76492(2) 0.32290(2) 0.02481(5) Uani 1 1 d . . . . .
Dy10 Dy 0.63349(2) 0.19209(2) 0.43951(2) 0.02569(5) Uani 1 1 d . . . . .
Dy16 Dy 0.99925(2) 0.76039(2) 0.30235(2) 0.02713(6) Uani 1 1 d . . . . .
Si6 Si 0.34202(10) 0.38489(6) 0.44978(6) 0.0349(3) Uani 1 1 d . . . . .
Si12 Si 0.66779(12) 0.60774(5) 0.34784(6) 0.0365(3) Uani 1 1 d . . . . .
Si18 Si 0.89340(12) 0.10034(7) 0.44371(6) 0.0450(4) Uani 1 1 d . . . . .
Si23 Si 0.65255(13) 0.92645(6) 0.30540(7) 0.0495(4) Uani 1 1 d . . . . .
Si26 Si 0.37263(13) 0.09763(7) 0.42318(7) 0.0479(4) Uani 1 1 d . . . . .
Si31 Si 1.13097(14) 0.61074(6) 0.29803(7) 0.0491(4) Uani 1 1 d . . . . .
O52 O 0.8468(2) 0.71381(13) 0.28501(13) 0.0312(7) Uani 1 1 d D . . . .
H52 H 0.820(4) 0.6870(16) 0.2570(14) 0.037 Uiso 1 1 d DR . . . .
O64 O 0.8901(2) 0.81150(13) 0.34064(13) 0.0307(7) Uani 1 1 d D . . . .
H64 H 0.911(4) 0.8397(15) 0.3675(15) 0.037 Uiso 1 1 d DR . . . .
O74 O 0.5389(2) 0.26745(12) 0.40637(12) 0.0261(7) Uani 1 1 d D . . . .
H74 H 0.503(3) 0.2711(18) 0.3698(9) 0.031 Uiso 1 1 d DR . . . .
O86 O 0.7267(2) 0.26569(12) 0.47761(12) 0.0272(7) Uani 1 1 d D . . . .
H86 H 0.768(3) 0.2672(19) 0.5133(10) 0.033 Uiso 1 1 d DR . . . .
C34 C 1.0762(4) 0.7306(2) 0.4046(2) 0.0372(12) Uani 1 1 d . . . . .
H34 H 1.0414 0.7445 0.4312 0.045 Uiso 1 1 calc R . . . .
C51 C 0.6809(4) 0.1084(2) 0.3789(2) 0.0376(12) Uani 1 1 d . . . . .
H51 H 0.6610 0.0714 0.3869 0.045 Uiso 1 1 calc R . . . .
C63 C 1.0547(4) 0.6798(2) 0.37663(19) 0.0344(11) Uani 1 1 d . . . . .
H63 H 1.0026 0.6534 0.3810 0.041 Uiso 1 1 calc R . . . .
C66 C 0.5556(4) 0.8153(2) 0.2843(2) 0.0401(12) Uani 1 1 d . . . . .
H66 H 0.5102 0.8202 0.3085 0.048 Uiso 1 1 calc R . . . .
C68 C 0.6312(4) 0.85421(19) 0.2760(2) 0.0352(11) Uani 1 1 d . . . . .
C72 C 0.6650(5) 0.7662(2) 0.4126(2) 0.0445(14) Uani 1 1 d . . . . .
H72 H 0.6318 0.7999 0.4202 0.053 Uiso 1 1 calc R . . . .
C78 C 0.5575(4) 0.5728(2) 0.3712(2) 0.0482(14) Uani 1 1 d . . . . .
H78A H 0.5780 0.5654 0.4098 0.072 Uiso 1 1 calc GR . . . .
H78B H 0.5403 0.5372 0.3519 0.072 Uiso 1 1 calc GR . . . .
H78C H 0.4963 0.5976 0.3641 0.072 Uiso 1 1 calc GR . . . .
C98 C 0.7768(4) 0.1342(2) 0.40156(19) 0.0334(11) Uani 1 1 d . . . . .
C99 C 0.6437(4) 0.1339(2) 0.5308(2) 0.0397(12) Uani 1 1 d . . . . .
H99 H 0.7112 0.1251 0.5512 0.048 Uiso 1 1 calc R . . . .
C101 C 1.1878(4) 0.7223(2) 0.3485(2) 0.0415(13) Uani 1 1 d . . . . .
H101 H 1.2431 0.7299 0.3307 0.050 Uiso 1 1 calc R . . . .
C103 C 0.2654(4) 0.4234(3) 0.4919(2) 0.0570(17) Uani 1 1 d . . . . .
H10A H 0.1925 0.4263 0.4726 0.086 Uiso 1 1 calc GR . . . .
H10B H 0.2945 0.4612 0.4997 0.086 Uiso 1 1 calc GR . . . .
H10C H 0.2688 0.4029 0.5257 0.086 Uiso 1 1 calc GR . . . .
C106 C 0.6783(4) 0.8304(2) 0.2364(2) 0.0405(12) Uani 1 1 d . . . . .
H106 H 0.7324 0.8474 0.2222 0.049 Uiso 1 1 calc R . . . .
C108 C 0.6306(4) 0.3591(2) 0.54691(19) 0.0358(11) Uani 1 1 d . . . . .
H108 H 0.6800 0.3386 0.5725 0.043 Uiso 1 1 calc R . . . .
C120 C 0.6459(4) 0.4129(2) 0.5269(2) 0.0371(12) Uani 1 1 d . . . . .
H120 H 0.7070 0.4353 0.5365 0.045 Uiso 1 1 calc R . . . .
C130 C 0.2907(4) 0.3117(2) 0.4383(3) 0.0543(16) Uani 1 1 d . . . . .
H13A H 0.2898 0.2939 0.4729 0.082 Uiso 1 1 calc GR . . . .
H13B H 0.3358 0.2899 0.4196 0.082 Uiso 1 1 calc GR . . . .
H13C H 0.2197 0.3128 0.4163 0.082 Uiso 1 1 calc GR . . . .
C131 C 1.1575(4) 0.7575(2) 0.3869(2) 0.0435(14) Uani 1 1 d . . . . .
H131 H 1.1870 0.7930 0.3987 0.052 Uiso 1 1 calc R . . . .
C163 C 0.5542(4) 0.42713(19) 0.49031(18) 0.0315(11) Uani 1 1 d . . . . .
H163 H 0.5431 0.4615 0.4708 0.038 Uiso 1 1 calc R . . . .
C165 C 0.5856(4) 0.1828(2) 0.5359(2) 0.0384(12) Uani 1 1 d . . . . .
H165 H 0.6069 0.2130 0.5602 0.046 Uiso 1 1 calc R . . . .
C171 C 0.7705(5) 0.7537(2) 0.4291(2) 0.0403(13) Uani 1 1 d . . . . .
H171 H 0.8221 0.7772 0.4500 0.048 Uiso 1 1 calc R . . . .
C175 C 0.5306(4) 0.34095(19) 0.52276(18) 0.0313(10) Uani 1 1 d . . . . .
H175 H 0.5004 0.3060 0.5294 0.038 Uiso 1 1 calc R . . . .
C181 C 0.7870(4) 0.7005(2) 0.40941(18) 0.0342(11) Uani 1 1 d . . . . .
H181 H 0.8523 0.6817 0.4149 0.041 Uiso 1 1 calc R . . . .
C185 C 0.6909(4) 0.67879(18) 0.37975(18) 0.0300(10) Uani 1 1 d . . . . .
C191 C 0.6163(4) 0.7204(2) 0.3830(2) 0.0394(12) Uani 1 1 d . . . . .
H191 H 0.5439 0.7178 0.3674 0.047 Uiso 1 1 calc R . . . .
C194 C 0.4911(4) 0.1788(2) 0.4985(2) 0.0361(11) Uani 1 1 d . . . . .
H194 H 0.4368 0.2060 0.4934 0.043 Uiso 1 1 calc R . . . .
C197 C 0.4809(3) 0.38316(19) 0.48665(18) 0.0293(10) Uani 1 1 d . . . . .
C226 C 0.7734(4) 0.18861(19) 0.3773(2) 0.0329(11) Uani 1 1 d . . . . .
H226 H 0.8278 0.2158 0.3843 0.040 Uiso 1 1 calc R . . . .
C229 C 1.1236(4) 0.6739(2) 0.34035(19) 0.0345(11) Uani 1 1 d . . . . .
C231 C 0.5572(4) 0.7682(2) 0.2514(2) 0.0490(15) Uani 1 1 d . . . . .
H231 H 0.5145 0.7356 0.2497 0.059 Uiso 1 1 calc R . . . .
C234 C 1.1127(4) 0.7886(2) 0.2315(2) 0.0397(12) Uani 1 1 d . . . . .
H234 H 1.1823 0.7750 0.2378 0.048 Uiso 1 1 calc R . . . .
C237 C 0.9383(5) 0.7950(3) 0.2010(2) 0.0482(14) Uani 1 1 d . . . . .
H237 H 0.8685 0.7868 0.1835 0.058 Uiso 1 1 calc R . . . .
C240 C 1.0265(5) 0.7607(2) 0.2014(2) 0.0485(14) Uani 1 1 d . . . . .
H240 H 1.0269 0.7251 0.1843 0.058 Uiso 1 1 calc R . . . .
C245 C 0.4886(4) 0.1277(2) 0.46948(19) 0.0348(11) Uani 1 1 d . . . . .
C249 C 0.5525(6) 0.9754(2) 0.2694(3) 0.069(2) Uani 1 1 d . . . . .
H24A H 0.5597 0.9790 0.2320 0.104 Uiso 1 1 calc GR . . . .
H24B H 0.5616 1.0124 0.2868 0.104 Uiso 1 1 calc GR . . . .
H24C H 0.4829 0.9608 0.2702 0.104 Uiso 1 1 calc GR . . . .
C267 C 0.5842(4) 0.1009(2) 0.4906(2) 0.0371(12) Uani 1 1 d . . . . .
H267 H 0.6050 0.0654 0.4792 0.045 Uiso 1 1 calc R . . . .
C275 C 0.6191(4) 0.1457(2) 0.3427(2) 0.0408(12) Uani 1 1 d . . . . .
H275 H 0.5506 0.1386 0.3227 0.049 Uiso 1 1 calc R . . . .
C278 C 0.3321(4) 0.4219(3) 0.3847(2) 0.0526(15) Uani 1 1 d . . . . .
H27A H 0.2585 0.4253 0.3667 0.079 Uiso 1 1 calc GR . . . .
H27B H 0.3697 0.4004 0.3619 0.079 Uiso 1 1 calc GR . . . .
H27C H 0.3630 0.4596 0.3911 0.079 Uiso 1 1 calc GR . . . .
C285 C 0.6333(5) 0.7781(2) 0.2214(2) 0.0484(15) Uani 1 1 d . . . . .
H285 H 0.6511 0.7535 0.1954 0.058 Uiso 1 1 calc R . . . .
C287 C 0.9719(4) 0.8431(2) 0.2310(2) 0.0399(12) Uani 1 1 d . . . . .
H287 H 0.9282 0.8732 0.2371 0.048 Uiso 1 1 calc R . . . .
C291 C 1.0819(4) 0.8402(2) 0.25110(19) 0.0353(11) Uani 1 1 d . . . . .
C295 C 0.6274(6) 0.6131(3) 0.2734(2) 0.069(2) Uani 1 1 d . . . . .
H29A H 0.6093 0.5756 0.2582 0.103 Uiso 1 1 calc GR . . . .
H29B H 0.6850 0.6286 0.2589 0.103 Uiso 1 1 calc GR . . . .
H29C H 0.5665 0.6379 0.2639 0.103 Uiso 1 1 calc GR . . . .
C304 C 0.6771(4) 0.1956(2) 0.34153(19) 0.0356(11) Uani 1 1 d . . . . .
H304 H 0.6549 0.2280 0.3203 0.043 Uiso 1 1 calc R . . . .
C311 C 1.1526(7) 0.5476(2) 0.3407(3) 0.077(2) Uani 1 1 d . . . . .
H31A H 1.2234 0.5485 0.3629 0.115 Uiso 1 1 calc GR . . . .
H31B H 1.1441 0.5139 0.3180 0.115 Uiso 1 1 calc GR . . . .
H31C H 1.1017 0.5468 0.3639 0.115 Uiso 1 1 calc GR . . . .
C322 C 0.7922(5) 0.5676(2) 0.3642(2) 0.0485(14) Uani 1 1 d . . . . .
H32A H 0.8151 0.5644 0.4033 0.073 Uiso 1 1 calc GR . . . .
H32B H 0.8457 0.5873 0.3496 0.073 Uiso 1 1 calc GR . . . .
H32C H 0.7815 0.5298 0.3485 0.073 Uiso 1 1 calc GR . . . .
Si1 Si 0.92316(10) 0.38926(6) 0.43696(6) 0.0342(3) Uani 1 1 d . . . . .
Si2 Si 1.16766(12) 0.89630(6) 0.28793(6) 0.0401(3) Uani 1 1 d . . . . .
C4 C 0.6337(4) 0.3641(2) 0.34057(19) 0.0369(12) Uani 1 1 d . . . . .
H4 H 0.5849 0.3445 0.3140 0.044 Uiso 1 1 calc R . . . .
C1AA C 0.7353(4) 0.34642(19) 0.36360(18) 0.0297(10) Uani 1 1 d . . . . .
H1AA H 0.7671 0.3126 0.3550 0.036 Uiso 1 1 calc R . . . .
C0AA C 0.7833(3) 0.38739(18) 0.40199(18) 0.0277(10) Uani 1 1 d . . . . .
C7 C 0.6168(4) 0.4158(2) 0.3637(2) 0.0376(12) Uani 1 1 d . . . . .
H7 H 0.5544 0.4373 0.3557 0.045 Uiso 1 1 calc R . . . .
C2AA C 0.7085(4) 0.43032(18) 0.40099(19) 0.0308(10) Uani 1 1 d . . . . .
H2AA H 0.7184 0.4637 0.4221 0.037 Uiso 1 1 calc R . . . .
C10 C 0.9761(4) 0.3161(2) 0.4462(2) 0.0504(15) Uani 1 1 d . . . . .
H10D H 0.9304 0.2929 0.4632 0.076 Uiso 1 1 calc GR . . . .
H10E H 1.0463 0.3170 0.4691 0.076 Uiso 1 1 calc GR . . . .
H10F H 0.9795 0.3001 0.4112 0.076 Uiso 1 1 calc GR . . . .
C11 C 1.1786(5) 0.9558(2) 0.2416(2) 0.0614(18) Uani 1 1 d . . . . .
H11A H 1.2105 0.9423 0.2125 0.092 Uiso 1 1 calc GR . . . .
H11B H 1.2220 0.9856 0.2615 0.092 Uiso 1 1 calc GR . . . .
H11C H 1.1088 0.9708 0.2265 0.092 Uiso 1 1 calc GR . . . .
C12 C 1.1122(5) 0.9230(3) 0.3446(2) 0.0578(16) Uani 1 1 d . . . . .
H12A H 1.0427 0.9388 0.3306 0.087 Uiso 1 1 calc GR . . . .
H12B H 1.1579 0.9523 0.3639 0.087 Uiso 1 1 calc GR . . . .
H12C H 1.1068 0.8919 0.3692 0.087 Uiso 1 1 calc GR . . . .
C13 C 1.3012(4) 0.8678(3) 0.3131(2) 0.0550(15) Uani 1 1 d . . . . .
H13D H 1.2978 0.8355 0.3366 0.082 Uiso 1 1 calc GR . . . .
H13E H 1.3455 0.8972 0.3333 0.082 Uiso 1 1 calc GR . . . .
H13F H 1.3308 0.8559 0.2826 0.082 Uiso 1 1 calc GR . . . .
C14 C 0.9942(4) 0.4306(3) 0.3938(2) 0.0597(18) Uani 1 1 d . . . . .
H14A H 0.9880 0.4116 0.3591 0.090 Uiso 1 1 calc GR . . . .
H14B H 1.0681 0.4335 0.4115 0.090 Uiso 1 1 calc GR . . . .
H14C H 0.9640 0.4684 0.3881 0.090 Uiso 1 1 calc GR . . . .
C16 C 0.9778(6) 0.0753(5) 0.4007(3) 0.118(4) Uani 1 1 d . . . . .
H16A H 0.9371 0.0524 0.3717 0.176 Uiso 1 1 calc GR . . . .
H16B H 1.0340 0.0523 0.4218 0.176 Uiso 1 1 calc GR . . . .
H16C H 1.0079 0.1075 0.3853 0.176 Uiso 1 1 calc GR . . . .
C18 C 0.3115(6) 0.1503(3) 0.3724(3) 0.069(2) Uani 1 1 d . . . . .
H18A H 0.2923 0.1838 0.3907 0.104 Uiso 1 1 calc GR . . . .
H18B H 0.2489 0.1341 0.3496 0.104 Uiso 1 1 calc GR . . . .
H18C H 0.3612 0.1609 0.3503 0.104 Uiso 1 1 calc GR . . . .
C19 C 0.9582(7) 0.1467(3) 0.4974(3) 0.106(3) Uani 1 1 d . . . . .
H19A H 0.9841 0.1802 0.4818 0.159 Uiso 1 1 calc GR . . . .
H19B H 1.0170 0.1268 0.5199 0.159 Uiso 1 1 calc GR . . . .
H19C H 0.9086 0.1581 0.5192 0.159 Uiso 1 1 calc GR . . . .
C20 C 0.8506(6) 0.0361(3) 0.4767(4) 0.104(3) Uani 1 1 d . . . . .
H20A H 0.8197 0.0478 0.5068 0.156 Uiso 1 1 calc GR . . . .
H20B H 0.9111 0.0119 0.4899 0.156 Uiso 1 1 calc GR . . . .
H20C H 0.7987 0.0153 0.4505 0.156 Uiso 1 1 calc GR . . . .
C3AA C 0.9358(4) 0.4234(2) 0.5035(2) 0.0502(14) Uani 1 1 d . . . . .
H3AA H 0.8994 0.4598 0.4991 0.075 Uiso 1 1 calc GR . . . .
H3AB H 1.0098 0.4295 0.5195 0.075 Uiso 1 1 calc GR . . . .
H3AC H 0.9048 0.3991 0.5271 0.075 Uiso 1 1 calc GR . . . .
C4AA C 1.2362(7) 0.6206(3) 0.2614(4) 0.099(3) Uani 1 1 d . . . . .
H4AA H 1.2256 0.6562 0.2415 0.149 Uiso 1 1 calc GR . . . .
H4AB H 1.2355 0.5894 0.2362 0.149 Uiso 1 1 calc GR . . . .
H4AC H 1.3035 0.6215 0.2869 0.149 Uiso 1 1 calc GR . . . .
C5 C 0.2806(6) 0.0753(4) 0.4645(3) 0.113(4) Uani 1 1 d . . . . .
H5A H 0.3182 0.0539 0.4955 0.170 Uiso 1 1 calc GR . . . .
H5B H 0.2264 0.0514 0.4430 0.170 Uiso 1 1 calc GR . . . .
H5C H 0.2483 0.1085 0.4770 0.170 Uiso 1 1 calc GR . . . .
C6 C 1.0032(6) 0.6002(3) 0.2497(3) 0.081(2) Uani 1 1 d . . . . .
H6A H 0.9468 0.5987 0.2695 0.121 Uiso 1 1 calc GR . . . .
H6B H 1.0051 0.5647 0.2302 0.121 Uiso 1 1 calc GR . . . .
H6C H 0.9910 0.6315 0.2241 0.121 Uiso 1 1 calc GR . . . .
C8 C 0.4097(6) 0.0344(3) 0.3885(3) 0.091(3) Uani 1 1 d . . . . .
H8A H 0.4558 0.0456 0.3647 0.137 Uiso 1 1 calc GR . . . .
H8B H 0.3467 0.0167 0.3674 0.137 Uiso 1 1 calc GR . . . .
H8C H 0.4461 0.0075 0.4153 0.137 Uiso 1 1 calc GR . . . .
C2 C 0.6458(8) 0.9238(3) 0.3767(3) 0.100(3) Uani 1 1 d . . . . .
H2A H 0.5802 0.9059 0.3803 0.149 Uiso 1 1 calc GR . . . .
H2B H 0.6487 0.9622 0.3911 0.149 Uiso 1 1 calc GR . . . .
H2C H 0.7048 0.9019 0.3967 0.149 Uiso 1 1 calc GR . . . .
C3 C 0.7832(6) 0.9527(3) 0.2981(4) 0.107(3) Uani 1 1 d . . . . .
H3A H 0.8379 0.9283 0.3185 0.160 Uiso 1 1 calc GR . . . .
H3B H 0.7933 0.9913 0.3120 0.160 Uiso 1 1 calc GR . . . .
H3C H 0.7870 0.9523 0.2601 0.160 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O74 2.260(3) . ?
Dy1 O86 2.262(3) . ?
Dy1 C108 2.665(5) . ?
Dy1 C120 2.676(5) . ?
Dy1 C163 2.653(4) . ?
Dy1 C175 2.647(5) . ?
Dy1 C197 2.653(4) . ?
Dy1 C4 2.681(5) . ?
Dy1 C1AA 2.670(4) . ?
Dy1 C0AA 2.651(4) . ?
Dy1 C7 2.655(5) . ?
Dy1 C2AA 2.639(4) . ?
Dy6 O52 2.253(3) . ?
Dy6 O64 2.256(3) . ?
Dy6 C66 2.653(5) . ?
Dy6 C68 2.670(4) . ?
Dy6 C72 2.649(5) . ?
Dy6 C106 2.673(5) . ?
Dy6 C171 2.661(5) . ?
Dy6 C181 2.649(5) . ?
Dy6 C185 2.646(4) . ?
Dy6 C191 2.640(5) . ?
Dy6 C231 2.654(5) . ?
Dy6 C285 2.672(5) . ?
Dy10 O74 2.237(3) . ?
Dy10 O86 2.233(3) . ?
Dy10 C51 2.668(5) . ?
Dy10 C98 2.668(5) . ?
Dy10 C99 2.685(5) . ?
Dy10 C165 2.669(5) . ?
Dy10 C194 2.652(5) . ?
Dy10 C226 2.666(5) . ?
Dy10 C245 2.671(5) . ?
Dy10 C267 2.675(5) . ?
Dy10 C275 2.670(5) . ?
Dy10 C304 2.677(5) . ?
Dy16 O52 2.244(3) . ?
Dy16 O64 2.249(3) . ?
Dy16 C34 2.683(5) . ?
Dy16 C63 2.681(4) . ?
Dy16 C101 2.661(5) . ?
Dy16 C131 2.658(5) . ?
Dy16 C229 2.672(5) . ?
Dy16 C234 2.657(5) . ?
Dy16 C237 2.666(5) . ?
Dy16 C240 2.671(5) . ?
Dy16 C287 2.648(5) . ?
Dy16 C291 2.658(5) . ?
Si6 C103 1.858(5) . ?
Si6 C130 1.863(6) . ?
Si6 C197 1.864(5) . ?
Si6 C278 1.857(6) . ?
Si12 C78 1.870(6) . ?
Si12 C185 1.869(5) . ?
Si12 C295 1.863(6) . ?
Si12 C322 1.858(6) . ?
Si18 C98 1.855(5) . ?
Si18 C16 1.815(8) . ?
Si18 C19 1.820(7) . ?
Si18 C20 1.882(8) . ?
Si23 C68 1.868(5) . ?
Si23 C249 1.845(6) . ?
Si23 C2 1.839(8) . ?
Si23 C3 1.868(8) . ?
Si26 C245 1.859(5) . ?
Si26 C18 1.854(6) . ?
Si26 C5 1.838(7) . ?
Si26 C8 1.857(7) . ?
Si31 C229 1.861(5) . ?
Si31 C311 1.837(6) . ?
Si31 C4AA 1.836(7) . ?
Si31 C6 1.874(8) . ?
C34 C63 1.401(7) . ?
C34 C131 1.396(8) . ?
C51 C98 1.407(7) . ?
C51 C275 1.406(7) . ?
C63 C229 1.429(7) . ?
C66 C68 1.403(7) . ?
C66 C231 1.400(7) . ?
C68 C106 1.408(7) . ?
C72 C171 1.389(8) . ?
C72 C191 1.398(7) . ?
C98 C226 1.428(7) . ?
C99 C165 1.409(7) . ?
C99 C267 1.390(7) . ?
C101 C131 1.407(8) . ?
C101 C229 1.413(7) . ?
C106 C285 1.393(7) . ?
C108 C120 1.404(7) . ?
C108 C175 1.394(7) . ?
C120 C163 1.398(7) . ?
C163 C197 1.408(7) . ?
C165 C194 1.397(7) . ?
C171 C181 1.391(7) . ?
C175 C197 1.422(6) . ?
C181 C185 1.422(7) . ?
C185 C191 1.404(7) . ?
C194 C245 1.417(7) . ?
C226 C304 1.401(7) . ?
C231 C285 1.398(9) . ?
C234 C240 1.392(8) . ?
C234 C291 1.412(7) . ?
C237 C240 1.413(8) . ?
C237 C287 1.391(8) . ?
C245 C267 1.407(7) . ?
C275 C304 1.410(7) . ?
C287 C291 1.426(7) . ?
C291 Si2 1.863(5) . ?
Si1 C0AA 1.861(5) . ?
Si1 C10 1.865(6) . ?
Si1 C14 1.864(5) . ?
Si1 C3AA 1.856(6) . ?
Si2 C11 1.866(6) . ?
Si2 C12 1.859(6) . ?
Si2 C13 1.860(6) . ?
C4 C1AA 1.402(7) . ?
C4 C7 1.399(7) . ?
C1AA C0AA 1.428(6) . ?
C0AA C2AA 1.411(6) . ?
C7 C2AA 1.408(7) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O74 Dy1 O86 74.36(11) . . ?
O74 Dy1 C108 114.39(14) . . ?
O74 Dy1 C120 139.70(14) . . ?
O74 Dy1 C163 123.69(13) . . ?
O74 Dy1 C175 89.40(13) . . ?
O74 Dy1 C197 93.91(13) . . ?
O74 Dy1 C4 81.45(13) . . ?
O74 Dy1 C1AA 91.30(12) . . ?
O74 Dy1 C0AA 122.25(12) . . ?
O74 Dy1 C7 104.10(13) . . ?
O74 Dy1 C2AA 131.82(13) . . ?
O86 Dy1 C108 82.11(13) . . ?
O86 Dy1 C120 105.29(13) . . ?
O86 Dy1 C163 132.16(13) . . ?
O86 Dy1 C175 91.21(13) . . ?
O86 Dy1 C197 122.06(13) . . ?
O86 Dy1 C4 114.52(14) . . ?
O86 Dy1 C1AA 90.09(13) . . ?
O86 Dy1 C0AA 95.12(12) . . ?
O86 Dy1 C7 140.36(14) . . ?
O86 Dy1 C2AA 125.06(13) . . ?
C108 Dy1 C120 30.48(15) . . ?
C108 Dy1 C4 160.40(15) . . ?
C108 Dy1 C1AA 149.60(15) . . ?
C120 Dy1 C4 130.11(16) . . ?
C163 Dy1 C108 50.15(14) . . ?
C163 Dy1 C120 30.42(14) . . ?
C163 Dy1 C197 30.79(14) . . ?
C163 Dy1 C4 112.03(15) . . ?
C163 Dy1 C1AA 128.41(14) . . ?
C163 Dy1 C7 82.58(16) . . ?
C175 Dy1 C108 30.42(15) . . ?
C175 Dy1 C120 50.42(15) . . ?
C175 Dy1 C163 50.29(15) . . ?
C175 Dy1 C197 31.12(13) . . ?
C175 Dy1 C4 148.76(15) . . ?
C175 Dy1 C1AA 178.65(14) . . ?
C175 Dy1 C0AA 148.27(14) . . ?
C175 Dy1 C7 128.39(15) . . ?
C197 Dy1 C108 51.11(14) . . ?
C197 Dy1 C120 51.14(15) . . ?
C197 Dy1 C4 119.45(15) . . ?
C197 Dy1 C1AA 147.63(14) . . ?
C197 Dy1 C7 97.56(15) . . ?
C1AA Dy1 C120 128.81(15) . . ?
C1AA Dy1 C4 30.37(15) . . ?
C0AA Dy1 C108 120.13(15) . . ?
C0AA Dy1 C120 98.03(15) . . ?
C0AA Dy1 C163 105.53(14) . . ?
C0AA Dy1 C197 134.91(14) . . ?
C0AA Dy1 C4 51.19(14) . . ?
C0AA Dy1 C1AA 31.13(13) . . ?
C0AA Dy1 C7 51.26(15) . . ?
C7 Dy1 C108 130.12(16) . . ?
C7 Dy1 C120 100.38(16) . . ?
C7 Dy1 C4 30.39(15) . . ?
C7 Dy1 C1AA 50.30(15) . . ?
C2AA Dy1 C108 111.96(15) . . ?
C2AA Dy1 C120 82.39(15) . . ?
C2AA Dy1 C163 78.53(15) . . ?
C2AA Dy1 C175 128.25(14) . . ?
C2AA Dy1 C197 105.17(14) . . ?
C2AA Dy1 C4 50.57(14) . . ?
C2AA Dy1 C1AA 50.54(14) . . ?
C2AA Dy1 C0AA 30.93(14) . . ?
C2AA Dy1 C7 30.84(14) . . ?
O52 Dy6 O64 74.01(11) . . ?
O52 Dy6 C66 133.44(15) . . ?
O52 Dy6 C68 123.60(14) . . ?
O52 Dy6 C72 138.74(15) . . ?
O52 Dy6 C106 93.29(14) . . ?
O52 Dy6 C171 113.40(15) . . ?
O52 Dy6 C181 88.64(14) . . ?
O52 Dy6 C185 93.36(13) . . ?
O52 Dy6 C191 123.26(13) . . ?
O52 Dy6 C231 106.07(16) . . ?
O52 Dy6 C285 83.59(15) . . ?
O64 Dy6 C66 122.91(13) . . ?
O64 Dy6 C68 93.21(13) . . ?
O64 Dy6 C72 106.57(15) . . ?
O64 Dy6 C106 88.14(15) . . ?
O64 Dy6 C171 84.00(14) . . ?
O64 Dy6 C181 93.50(14) . . ?
O64 Dy6 C185 124.36(13) . . ?
O64 Dy6 C191 134.17(15) . . ?
O64 Dy6 C231 138.28(15) . . ?
O64 Dy6 C285 112.62(17) . . ?
C66 Dy6 C68 30.56(15) . . ?
C66 Dy6 C106 49.84(17) . . ?
C66 Dy6 C171 111.48(18) . . ?
C66 Dy6 C231 30.59(16) . . ?
C66 Dy6 C285 50.03(18) . . ?
C68 Dy6 C106 30.55(16) . . ?
C68 Dy6 C285 50.60(16) . . ?
C72 Dy6 C66 82.11(18) . . ?
C72 Dy6 C68 97.65(17) . . ?
C72 Dy6 C106 127.84(17) . . ?
C72 Dy6 C171 30.33(17) . . ?
C72 Dy6 C231 99.7(2) . . ?
C72 Dy6 C285 129.4(2) . . ?
C171 Dy6 C68 119.61(16) . . ?
C171 Dy6 C106 148.63(16) . . ?
C171 Dy6 C285 159.60(19) . . ?
C181 Dy6 C66 127.92(17) . . ?
C181 Dy6 C68 147.65(16) . . ?
C181 Dy6 C72 50.17(16) . . ?
C181 Dy6 C106 177.76(17) . . ?
C181 Dy6 C171 30.36(15) . . ?
C181 Dy6 C231 128.10(17) . . ?
C181 Dy6 C285 149.25(16) . . ?
C185 Dy6 C66 105.23(16) . . ?
C185 Dy6 C68 134.61(16) . . ?
C185 Dy6 C72 51.21(15) . . ?
C185 Dy6 C106 147.38(16) . . ?
C185 Dy6 C171 51.26(14) . . ?
C185 Dy6 C181 31.15(14) . . ?
C185 Dy6 C231 97.36(17) . . ?
C185 Dy6 C285 119.56(17) . . ?
C191 Dy6 C66 78.36(17) . . ?
C191 Dy6 C68 105.13(16) . . ?
C191 Dy6 C72 30.66(16) . . ?
C191 Dy6 C106 127.54(17) . . ?
C191 Dy6 C171 50.35(17) . . ?
C191 Dy6 C181 50.27(16) . . ?
C191 Dy6 C185 30.81(14) . . ?
C191 Dy6 C231 81.87(19) . . ?
C191 Dy6 C285 111.43(19) . . ?
C231 Dy6 C68 50.94(15) . . ?
C231 Dy6 C106 50.19(18) . . ?
C231 Dy6 C171 129.4(2) . . ?
C231 Dy6 C285 30.44(18) . . ?
C285 Dy6 C106 30.21(16) . . ?
O74 Dy10 C51 123.70(14) . . ?
O74 Dy10 C98 130.63(13) . . ?
O74 Dy10 C99 131.33(14) . . ?
O74 Dy10 C165 101.18(14) . . ?
O74 Dy10 C194 84.79(13) . . ?
O74 Dy10 C226 101.30(13) . . ?
O74 Dy10 C245 101.22(13) . . ?
O74 Dy10 C267 131.23(13) . . ?
O74 Dy10 C275 93.17(14) . . ?
O74 Dy10 C304 80.43(13) . . ?
O86 Dy10 O74 75.37(11) . . ?
O86 Dy10 C51 131.36(14) . . ?
O86 Dy10 C98 101.41(13) . . ?
O86 Dy10 C99 95.91(14) . . ?
O86 Dy10 C165 82.98(14) . . ?
O86 Dy10 C194 103.46(14) . . ?
O86 Dy10 C226 84.31(13) . . ?
O86 Dy10 C245 132.83(13) . . ?
O86 Dy10 C267 125.98(14) . . ?
O86 Dy10 C275 130.48(14) . . ?
O86 Dy10 C304 100.15(14) . . ?
C51 Dy10 C99 98.25(16) . . ?
C51 Dy10 C165 126.85(16) . . ?
C51 Dy10 C245 90.36(15) . . ?
C51 Dy10 C267 77.84(16) . . ?
C51 Dy10 C275 30.54(15) . . ?
C51 Dy10 C304 50.35(15) . . ?
C98 Dy10 C51 30.58(15) . . ?
C98 Dy10 C99 98.01(15) . . ?
C98 Dy10 C165 127.70(15) . . ?
C98 Dy10 C245 113.99(15) . . ?
C98 Dy10 C267 91.20(15) . . ?
C98 Dy10 C275 51.02(15) . . ?
C98 Dy10 C304 51.15(15) . . ?
C165 Dy10 C99 30.52(15) . . ?
C165 Dy10 C245 50.97(15) . . ?
C165 Dy10 C267 50.00(16) . . ?
C165 Dy10 C275 146.23(16) . . ?
C165 Dy10 C304 176.78(15) . . ?
C194 Dy10 C51 121.16(16) . . ?
C194 Dy10 C98 141.08(15) . . ?
C194 Dy10 C99 50.15(16) . . ?
C194 Dy10 C165 30.44(15) . . ?
C194 Dy10 C226 171.23(15) . . ?
C194 Dy10 C245 30.86(15) . . ?
C194 Dy10 C267 49.90(15) . . ?
C194 Dy10 C275 123.63(16) . . ?
C194 Dy10 C304 147.88(16) . . ?
C226 Dy10 C51 50.16(15) . . ?
C226 Dy10 C98 31.06(14) . . ?
C226 Dy10 C99 125.79(15) . . ?
C226 Dy10 C165 150.39(16) . . ?
C226 Dy10 C245 140.52(15) . . ?
C226 Dy10 C267 122.13(15) . . ?
C226 Dy10 C275 50.31(16) . . ?
C226 Dy10 C304 30.41(15) . . ?
C245 Dy10 C99 50.67(15) . . ?
C245 Dy10 C267 30.52(15) . . ?
C245 Dy10 C304 126.08(15) . . ?
C267 Dy10 C99 30.07(15) . . ?
C267 Dy10 C304 126.89(16) . . ?
C275 Dy10 C99 124.71(16) . . ?
C275 Dy10 C245 96.47(16) . . ?
C275 Dy10 C267 98.01(16) . . ?
C275 Dy10 C304 30.57(15) . . ?
C304 Dy10 C99 147.43(15) . . ?
O52 Dy16 O64 74.31(11) . . ?
O52 Dy16 C34 101.42(14) . . ?
O52 Dy16 C63 83.38(14) . . ?
O52 Dy16 C101 128.67(14) . . ?
O52 Dy16 C131 131.06(15) . . ?
O52 Dy16 C229 98.18(13) . . ?
O52 Dy16 C234 126.39(15) . . ?
O52 Dy16 C237 83.63(15) . . ?
O52 Dy16 C240 96.11(15) . . ?
O52 Dy16 C287 104.13(14) . . ?
O52 Dy16 C291 133.84(13) . . ?
O64 Dy16 C34 82.16(14) . . ?
O64 Dy16 C63 100.43(13) . . ?
O64 Dy16 C101 127.45(15) . . ?
O64 Dy16 C131 96.97(15) . . ?
O64 Dy16 C229 130.70(14) . . ?
O64 Dy16 C234 131.10(14) . . ?
O64 Dy16 C237 99.54(16) . . ?
O64 Dy16 C240 130.02(16) . . ?
O64 Dy16 C287 83.81(14) . . ?
O64 Dy16 C291 101.05(13) . . ?
C63 Dy16 C34 30.28(14) . . ?
C101 Dy16 C34 50.05(16) . . ?
C101 Dy16 C63 50.04(16) . . ?
C101 Dy16 C229 30.73(15) . . ?
C101 Dy16 C237 126.38(18) . . ?
C101 Dy16 C240 97.22(18) . . ?
C131 Dy16 C34 30.30(16) . . ?
C131 Dy16 C63 50.25(16) . . ?
C131 Dy16 C101 30.68(17) . . ?
C131 Dy16 C229 51.28(16) . . ?
C131 Dy16 C237 144.70(18) . . ?
C131 Dy16 C240 122.74(19) . . ?
C229 Dy16 C34 50.99(15) . . ?
C229 Dy16 C63 30.96(14) . . ?
C234 Dy16 C34 125.28(17) . . ?
C234 Dy16 C63 123.57(16) . . ?
C234 Dy16 C101 77.61(16) . . ?
C234 Dy16 C131 96.03(18) . . ?
C234 Dy16 C229 93.12(16) . . ?
C234 Dy16 C237 50.20(17) . . ?
C234 Dy16 C240 30.28(16) . . ?
C234 Dy16 C291 30.82(15) . . ?
C237 Dy16 C34 174.95(17) . . ?
C237 Dy16 C63 152.20(17) . . ?
C237 Dy16 C229 128.52(18) . . ?
C237 Dy16 C240 30.71(18) . . ?
C240 Dy16 C34 146.82(18) . . ?
C240 Dy16 C63 127.60(17) . . ?
C240 Dy16 C229 98.95(17) . . ?
C287 Dy16 C34 146.19(16) . . ?
C287 Dy16 C63 172.21(16) . . ?
C287 Dy16 C101 122.25(16) . . ?
C287 Dy16 C131 123.05(16) . . ?
C287 Dy16 C229 143.30(16) . . ?
C287 Dy16 C234 50.18(16) . . ?
C287 Dy16 C237 30.34(17) . . ?
C287 Dy16 C240 50.40(18) . . ?
C287 Dy16 C291 31.19(15) . . ?
C291 Dy16 C34 123.79(16) . . ?
C291 Dy16 C63 141.03(15) . . ?
C291 Dy16 C101 91.27(16) . . ?
C291 Dy16 C131 95.02(16) . . ?
C291 Dy16 C229 116.41(15) . . ?
C291 Dy16 C237 51.27(16) . . ?
C291 Dy16 C240 51.21(16) . . ?
C103 Si6 C130 109.2(3) . . ?
C103 Si6 C197 108.0(2) . . ?
C130 Si6 C197 109.9(2) . . ?
C278 Si6 C103 109.8(3) . . ?
C278 Si6 C130 110.2(3) . . ?
C278 Si6 C197 109.7(2) . . ?
C185 Si12 C78 109.0(2) . . ?
C295 Si12 C78 106.4(3) . . ?
C295 Si12 C185 111.5(2) . . ?
C322 Si12 C78 113.7(3) . . ?
C322 Si12 C185 108.1(2) . . ?
C322 Si12 C295 108.1(3) . . ?
C98 Si18 C20 108.8(3) . . ?
C16 Si18 C98 109.0(3) . . ?
C16 Si18 C19 113.9(5) . . ?
C16 Si18 C20 106.4(5) . . ?
C19 Si18 C98 111.7(3) . . ?
C19 Si18 C20 106.9(4) . . ?
C249 Si23 C68 110.3(3) . . ?
C249 Si23 C3 108.1(4) . . ?
C2 Si23 C68 109.3(3) . . ?
C2 Si23 C249 109.6(4) . . ?
C2 Si23 C3 110.2(4) . . ?
C3 Si23 C68 109.2(3) . . ?
C18 Si26 C245 111.0(3) . . ?
C18 Si26 C8 109.4(4) . . ?
C5 Si26 C245 107.1(3) . . ?
C5 Si26 C18 110.8(4) . . ?
C5 Si26 C8 107.9(4) . . ?
C8 Si26 C245 110.6(3) . . ?
C229 Si31 C6 109.9(3) . . ?
C311 Si31 C229 109.5(3) . . ?
C311 Si31 C6 106.5(4) . . ?
C4AA Si31 C229 109.2(3) . . ?
C4AA Si31 C311 111.5(4) . . ?
C4AA Si31 C6 110.2(4) . . ?
Dy16 O52 Dy6 105.97(12) . . ?
Dy16 O64 Dy6 105.72(12) . . ?
Dy10 O74 Dy1 105.08(12) . . ?
Dy10 O86 Dy1 105.18(12) . . ?
C63 C34 Dy16 74.8(3) . . ?
C131 C34 Dy16 73.9(3) . . ?
C131 C34 C63 108.3(5) . . ?
C98 C51 Dy10 74.7(3) . . ?
C275 C51 Dy10 74.8(3) . . ?
C275 C51 C98 109.6(4) . . ?
C34 C63 Dy16 74.9(3) . . ?
C34 C63 C229 109.1(5) . . ?
C229 C63 Dy16 74.2(3) . . ?
C68 C66 Dy6 75.4(3) . . ?
C231 C66 Dy6 74.7(3) . . ?
C231 C66 C68 109.6(5) . . ?
Si23 C68 Dy6 122.0(2) . . ?
C66 C68 Dy6 74.1(3) . . ?
C66 C68 Si23 126.5(4) . . ?
C66 C68 C106 106.0(4) . . ?
C106 C68 Dy6 74.8(3) . . ?
C106 C68 Si23 127.1(4) . . ?
C171 C72 Dy6 75.3(3) . . ?
C171 C72 C191 108.0(5) . . ?
C191 C72 Dy6 74.3(3) . . ?
Si18 C98 Dy10 124.8(2) . . ?
C51 C98 Dy10 74.7(3) . . ?
C51 C98 Si18 127.1(4) . . ?
C51 C98 C226 105.8(4) . . ?
C226 C98 Dy10 74.4(3) . . ?
C226 C98 Si18 126.1(4) . . ?
C165 C99 Dy10 74.1(3) . . ?
C267 C99 Dy10 74.6(3) . . ?
C267 C99 C165 107.6(5) . . ?
C131 C101 Dy16 74.6(3) . . ?
C131 C101 C229 109.8(5) . . ?
C229 C101 Dy16 75.1(3) . . ?
C68 C106 Dy6 74.6(3) . . ?
C285 C106 Dy6 74.9(3) . . ?
C285 C106 C68 109.2(5) . . ?
C120 C108 Dy1 75.2(3) . . ?
C175 C108 Dy1 74.1(3) . . ?
C175 C108 C120 108.3(4) . . ?
C108 C120 Dy1 74.3(3) . . ?
C163 C120 Dy1 73.9(3) . . ?
C163 C120 C108 107.1(4) . . ?
C34 C131 Dy16 75.8(3) . . ?
C34 C131 C101 107.5(5) . . ?
C101 C131 Dy16 74.8(3) . . ?
C120 C163 Dy1 75.7(3) . . ?
C120 C163 C197 110.1(4) . . ?
C197 C163 Dy1 74.6(2) . . ?
C99 C165 Dy10 75.4(3) . . ?
C194 C165 Dy10 74.1(3) . . ?
C194 C165 C99 107.4(5) . . ?
C72 C171 Dy6 74.4(3) . . ?
C72 C171 C181 107.8(5) . . ?
C181 C171 Dy6 74.3(3) . . ?
C108 C175 Dy1 75.5(3) . . ?
C108 C175 C197 109.1(4) . . ?
C197 C175 Dy1 74.7(3) . . ?
C171 C181 Dy6 75.3(3) . . ?
C171 C181 C185 109.4(5) . . ?
C185 C181 Dy6 74.3(3) . . ?
Si12 C185 Dy6 119.6(2) . . ?
C181 C185 Dy6 74.5(3) . . ?
C181 C185 Si12 127.0(4) . . ?
C191 C185 Dy6 74.3(3) . . ?
C191 C185 Si12 127.5(4) . . ?
C191 C185 C181 105.3(4) . . ?
C72 C191 Dy6 75.0(3) . . ?
C72 C191 C185 109.5(5) . . ?
C185 C191 Dy6 74.9(3) . . ?
C165 C194 Dy10 75.4(3) . . ?
C165 C194 C245 109.5(4) . . ?
C245 C194 Dy10 75.3(3) . . ?
Si6 C197 Dy1 122.7(2) . . ?
C163 C197 Dy1 74.6(3) . . ?
C163 C197 Si6 126.7(3) . . ?
C163 C197 C175 105.4(4) . . ?
C175 C197 Dy1 74.2(3) . . ?
C175 C197 Si6 127.4(4) . . ?
C98 C226 Dy10 74.5(3) . . ?
C304 C226 Dy10 75.2(3) . . ?
C304 C226 C98 109.3(4) . . ?
Si31 C229 Dy16 120.8(2) . . ?
C63 C229 Dy16 74.9(3) . . ?
C63 C229 Si31 124.8(4) . . ?
C101 C229 Dy16 74.2(3) . . ?
C101 C229 Si31 129.6(4) . . ?
C101 C229 C63 105.3(4) . . ?
C66 C231 Dy6 74.7(3) . . ?
C285 C231 Dy6 75.5(3) . . ?
C285 C231 C66 107.2(5) . . ?
C240 C234 Dy16 75.4(3) . . ?
C240 C234 C291 110.4(5) . . ?
C291 C234 Dy16 74.6(3) . . ?
C240 C237 Dy16 74.8(3) . . ?
C287 C237 Dy16 74.1(3) . . ?
C287 C237 C240 107.8(5) . . ?
C234 C240 Dy16 74.3(3) . . ?
C234 C240 C237 107.2(5) . . ?
C237 C240 Dy16 74.5(3) . . ?
Si26 C245 Dy10 125.0(2) . . ?
C194 C245 Dy10 73.8(3) . . ?
C194 C245 Si26 125.8(4) . . ?
C267 C245 Dy10 74.9(3) . . ?
C267 C245 Si26 127.7(4) . . ?
C267 C245 C194 105.5(4) . . ?
C99 C267 Dy10 75.4(3) . . ?
C99 C267 C245 110.0(4) . . ?
C245 C267 Dy10 74.6(3) . . ?
C51 C275 Dy10 74.6(3) . . ?
C51 C275 C304 107.7(4) . . ?
C304 C275 Dy10 75.0(3) . . ?
C106 C285 Dy6 74.9(3) . . ?
C106 C285 C231 108.1(5) . . ?
C231 C285 Dy6 74.1(3) . . ?
C237 C287 Dy16 75.5(3) . . ?
C237 C287 C291 109.7(5) . . ?
C291 C287 Dy16 74.8(3) . . ?
C234 C291 Dy16 74.6(3) . . ?
C234 C291 C287 104.9(5) . . ?
C234 C291 Si2 127.7(4) . . ?
C287 C291 Dy16 74.0(3) . . ?
C287 C291 Si2 127.1(4) . . ?
Si2 C291 Dy16 121.8(2) . . ?
C226 C304 Dy10 74.4(3) . . ?
C226 C304 C275 107.6(4) . . ?
C275 C304 Dy10 74.4(3) . . ?
C0AA Si1 C10 109.9(2) . . ?
C0AA Si1 C14 107.1(2) . . ?
C14 Si1 C10 110.2(3) . . ?
C3AA Si1 C0AA 109.7(2) . . ?
C3AA Si1 C10 109.4(3) . . ?
C3AA Si1 C14 110.5(3) . . ?
C291 Si2 C11 109.9(2) . . ?
C12 Si2 C291 110.0(3) . . ?
C12 Si2 C11 109.2(3) . . ?
C12 Si2 C13 110.5(3) . . ?
C13 Si2 C291 109.7(3) . . ?
C13 Si2 C11 107.5(3) . . ?
C1AA C4 Dy1 74.4(3) . . ?
C7 C4 Dy1 73.8(3) . . ?
C7 C4 C1AA 107.8(4) . . ?
C4 C1AA Dy1 75.3(3) . . ?
C4 C1AA C0AA 109.0(4) . . ?
C0AA C1AA Dy1 73.7(3) . . ?
Si1 C0AA Dy1 123.8(2) . . ?
C1AA C0AA Dy1 75.2(3) . . ?
C1AA C0AA Si1 126.2(4) . . ?
C2AA C0AA Dy1 74.1(3) . . ?
C2AA C0AA Si1 127.0(3) . . ?
C2AA C0AA C1AA 106.0(4) . . ?
C4 C7 Dy1 75.8(3) . . ?
C4 C7 C2AA 108.2(4) . . ?
C2AA C7 Dy1 74.0(3) . . ?
C0AA C2AA Dy1 75.0(2) . . ?
C7 C2AA Dy1 75.2(3) . . ?
C7 C2AA C0AA 109.0(4) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_6592_sq
_database_code_depnum_ccdc_archive 'CCDC 2121121'
loop_
_audit_author_name
_audit_author_address
'Yuan Qiong'
;Peking University
China
;
_audit_update_record             
;
2021-11-09 deposited with the CCDC.	2022-04-12 downloaded from the CCDC.
;
_audit_creation_date             2017-03-29
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.08.25 svn.r3337 for OlexSys, GUI svn.r5227)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C64 H110 Dy7 F15 O4 Si6'
_chemical_formula_sum            'C64 H110 Dy7 F15 O4 Si6'
_chemical_formula_weight         2534.55
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C48 H78 Si6 Dy3 I3'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.4849(3)
_cell_length_b                   16.1855(4)
_cell_length_c                   20.3478(4)
_cell_angle_alpha                76.1439(19)
_cell_angle_beta                 75.9937(18)
_cell_angle_gamma                78.922(2)
_cell_volume                     4448.10(18)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    22664
_cell_measurement_temperature    180.01(10)
_cell_measurement_theta_max      30.0000
_cell_measurement_theta_min      3.1660
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.952
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.65372
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.892
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2414
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0453
_diffrn_reflns_av_unetI/netI     0.0515
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            68719
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.485
_diffrn_reflns_theta_min         3.033
_diffrn_ambient_temperature      180.01(10)
_diffrn_detector_area_resol_mean 10.3914
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega    6.00   75.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191 -131.0000   66.9754 69

#__ type_ start__ end____ width___ exp.time_
  2 omega  -10.00   87.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191   38.0000 -120.0000 97

#__ type_ start__ end____ width___ exp.time_
  3 omega   -2.00   90.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191   38.0000   60.0000 92

#__ type_ start__ end____ width___ exp.time_
  4 omega  -10.00   87.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191   38.0000  150.0000 97

#__ type_ start__ end____ width___ exp.time_
  5 omega   -8.00   71.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191   57.0000  -60.0000 79

#__ type_ start__ end____ width___ exp.time_
  6 omega  -58.00   41.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191  -57.0000  120.0000 99

#__ type_ start__ end____ width___ exp.time_
  7 omega   18.00   91.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191 -154.0000  -29.1146 73
;
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0403303000
_diffrn_orient_matrix_UB_12      -0.0224178000
_diffrn_orient_matrix_UB_13      0.0126418000
_diffrn_orient_matrix_UB_21      -0.0275520000
_diffrn_orient_matrix_UB_22      0.0363817000
_diffrn_orient_matrix_UB_23      0.0125083000
_diffrn_orient_matrix_UB_31      -0.0146351000
_diffrn_orient_matrix_UB_32      0.0159161000
_diffrn_orient_matrix_UB_33      -0.0320899000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                15048
_reflns_number_total             20322
_reflns_odcompleteness_completeness 99.62
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     27.42
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         2.042
_refine_diff_density_min         -1.050
_refine_diff_density_rms         0.169
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     883
_refine_ls_number_reflns         20322
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0598
_refine_ls_R_factor_gt           0.0327
_refine_ls_restrained_S_all      1.078
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0179P)²+4.4488P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0578
_refine_ls_wR_factor_ref         0.0683
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C73) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.01
Uanis(C2) \\sim Ueq: with sigma of 0.02 and sigma for terminal atoms of 0.01
3.a Secondary CH2 refined with riding coordinates:
 C91(H91A,H91B), C76(H76A,H76B), C77(H77A,H77B), C93(H93A,H93B), C78(H78A,
 H78B), C94(H94A,H94B), C86(H86A,H86B), C79(H79A,H79B), C89(H89A,H89B),
 C84(H84A,H84B), C88(H88A,H88B), C92(H92A,H92B), C82(H82A,H82B), C83(H83A,H83B),
  C87(H87A,H87B), C80(H80A,H80B)
3.b Aromatic/amide H refined with riding coordinates:
 C37(H37), C68(H68), C10(H10), C18(H18), C39(H39), C28(H28), C20(H20),
 C46(H46), C12(H12), C11(H11), C21(H21), C9(H9), C70(H70), C30(H30), C45(H45),
 C27(H27), C71(H71), C29(H29), C48(H48), C38(H38), C19(H19), C47(H47), C36(H36),
  C69(H69)
3.c Idealised Me refined as rotating group:
 C23(H23A,H23B,H23C), C14(H14A,H14B,H14C), C15(H15A,H15B,H15C), C16(H16A,H16B,
 H16C), C32(H32A,H32B,H32C), C41(H41A,H41B,H41C), C24(H24A,H24B,H24C), C25(H25A,
 H25B,H25C), C42(H42A,H42B,H42C), C43(H43A,H43B,H43C), C33(H33A,H33B,H33C),
 C74(H74A,H74B,H74C), C34(H34A,H34B,H34C), C50(H50A,H50B,H50C), C51(H51A,H51B,
 H51C), C52(H52A,H52B,H52C), C73(H73A,H73B,H73C), C2(H2A,H2B,H2C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.74127(2) 0.92502(2) 0.76969(2) 0.01959(6) Uani 1 1 d . . . . .
Dy2 Dy 0.81417(2) 0.80288(2) 0.60885(2) 0.02099(6) Uani 1 1 d . . . . .
Dy3 Dy 0.48182(2) 1.00497(2) 0.76094(2) 0.02151(6) Uani 1 1 d . . . . .
Dy4 Dy 0.54589(2) 0.78132(2) 0.72427(2) 0.02148(6) Uani 1 1 d . . . . .
Dy5 Dy 0.93540(2) 0.71032(2) 0.76595(2) 0.02316(6) Uani 1 1 d . . . . .
Dy6 Dy 0.68119(2) 0.69456(2) 0.88597(2) 0.02436(6) Uani 1 1 d . . . . .
Dy7 Dy 0.76505(2) 0.58302(2) 0.72628(2) 0.02516(6) Uani 1 1 d . . . . .
Si13 Si 0.19603(11) 0.99478(12) 0.83890(8) 0.0358(4) Uani 1 1 d . . . . .
Si22 Si 0.85573(12) 0.69997(11) 0.44124(8) 0.0322(4) Uani 1 1 d . . . . .
Si31 Si 0.52514(15) 1.25528(11) 0.68677(9) 0.0474(5) Uani 1 1 d . . . . .
Si40 Si 0.79671(13) 0.65528(11) 1.05021(8) 0.0394(4) Uani 1 1 d . . . . .
Si49 Si 0.82390(14) 0.36174(11) 0.85106(9) 0.0425(4) Uani 1 1 d . . . . .
F58 F 0.62135(19) 1.02945(18) 0.77979(14) 0.0244(6) Uani 1 1 d . . . . .
F63 F 0.8129(2) 0.66442(18) 0.62426(14) 0.0295(7) Uani 1 1 d . . . . .
F57 F 0.43255(19) 0.88888(18) 0.74225(14) 0.0243(6) Uani 1 1 d . . . . .
Si72 Si 1.17412(15) 0.62167(19) 0.64719(13) 0.0787(8) Uani 1 1 d . . . . .
F56 F 0.7868(2) 0.91039(18) 0.66222(13) 0.0251(6) Uani 1 1 d . . . . .
F55 F 0.60659(18) 0.89084(17) 0.74728(13) 0.0213(6) Uani 1 1 d . . . . .
F53 F 0.6230(2) 0.65405(19) 0.71128(15) 0.0299(7) Uani 1 1 d . . . . .
F62 F 0.7675(2) 0.73297(19) 0.74468(15) 0.0322(7) Uani 1 1 d . . . . .
F54 F 0.65677(19) 0.81648(18) 0.63178(13) 0.0259(7) Uani 1 1 d . . . . .
O75 O 0.8321(3) 1.0395(2) 0.71469(18) 0.0343(9) Uani 1 1 d . . . . .
O81 O 0.4191(3) 0.6947(3) 0.77372(19) 0.0369(10) Uani 1 1 d . . . . .
O85 O 0.4695(3) 0.7909(3) 0.63147(18) 0.0397(10) Uani 1 1 d . . . . .
F61 F 0.9413(2) 0.76407(19) 0.65559(14) 0.0279(7) Uani 1 1 d . . . . .
F60 F 0.5617(2) 0.73586(18) 0.83156(14) 0.0278(7) Uani 1 1 d . . . . .
F64 F 0.7056(2) 0.58388(19) 0.83629(15) 0.0329(7) Uani 1 1 d . . . . .
F66 F 0.8389(2) 0.67801(19) 0.86765(14) 0.0314(7) Uani 1 1 d . . . . .
O90 O 0.7770(2) 0.9773(2) 0.86035(17) 0.0298(9) Uani 1 1 d . . . . .
C37 C 0.5624(5) 0.6121(6) 0.9905(3) 0.061(2) Uani 1 1 d . . . . .
H37 H 0.5248 0.5771 0.9797 0.073 Uiso 1 1 calc R . . . .
C68 C 1.0955(4) 0.6113(4) 0.7951(4) 0.0469(17) Uani 1 1 d . . . . .
H68 H 1.0944 0.5511 0.8054 0.056 Uiso 1 1 calc R . . . .
C91 C 0.7070(4) 0.9964(5) 0.9202(3) 0.0454(17) Uani 1 1 d . . . . .
H91A H 0.6864 0.9431 0.9512 0.054 Uiso 1 1 calc R . . . .
H91B H 0.6498 1.0347 0.9065 0.054 Uiso 1 1 calc R . . . .
C44 C 0.7904(4) 0.4125(3) 0.7665(3) 0.0310(13) Uani 1 1 d . . . . .
C10 C 0.4341(4) 1.0547(4) 0.8833(3) 0.0327(13) Uani 1 1 d . . . . .
H10 H 0.4712 1.0934 0.8898 0.039 Uiso 1 1 calc R . . . .
C17 C 0.8612(4) 0.7957(3) 0.4741(2) 0.0264(12) Uani 1 1 d . . . . .
C18 C 0.7910(4) 0.8708(4) 0.4783(3) 0.0329(13) Uani 1 1 d . . . . .
H18 H 0.7284 0.8780 0.4690 0.039 Uiso 1 1 calc R . . . .
C39 C 0.6088(4) 0.7254(4) 1.0135(3) 0.0426(16) Uani 1 1 d . . . . .
H39 H 0.6080 0.7813 1.0209 0.051 Uiso 1 1 calc R . . . .
C76 C 0.9302(4) 1.0278(4) 0.6749(3) 0.0415(15) Uani 1 1 d . . . . .
H76A H 0.9306 1.0271 0.6263 0.050 Uiso 1 1 calc R . . . .
H76B H 0.9667 0.9734 0.6953 0.050 Uiso 1 1 calc R . . . .
C28 C 0.4206(5) 1.0620(4) 0.6419(3) 0.0453(17) Uani 1 1 d . . . . .
H28 H 0.3707 1.0354 0.6363 0.054 Uiso 1 1 calc R . . . .
C77 C 0.9718(4) 1.1037(4) 0.6790(3) 0.0417(16) Uani 1 1 d . . . . .
H77A H 1.0260 1.1167 0.6397 0.050 Uiso 1 1 calc R . . . .
H77B H 0.9939 1.0945 0.7230 0.050 Uiso 1 1 calc R . . . .
C93 C 0.8604(5) 1.0006(5) 0.9386(3) 0.0478(17) Uani 1 1 d . . . . .
H93A H 0.9037 1.0431 0.9340 0.057 Uiso 1 1 calc R . . . .
H93B H 0.8746 0.9506 0.9754 0.057 Uiso 1 1 calc R . . . .
C20 C 0.9236(5) 0.8977(4) 0.5058(3) 0.0425(16) Uani 1 1 d . . . . .
H20 H 0.9671 0.9256 0.5181 0.051 Uiso 1 1 calc R . . . .
C46 C 0.7021(6) 0.4668(4) 0.6820(4) 0.0511(19) Uani 1 1 d . . . . .
H46 H 0.6493 0.4872 0.6595 0.061 Uiso 1 1 calc R . . . .
C12 C 0.3813(4) 0.9325(4) 0.8823(2) 0.0286(12) Uani 1 1 d . . . . .
H12 H 0.3768 0.8732 0.8886 0.034 Uiso 1 1 calc R . . . .
C23 C 0.9548(5) 0.6152(4) 0.4656(3) 0.0510(18) Uani 1 1 d . . . . .
H23A H 1.0162 0.6378 0.4481 0.077 Uiso 1 1 calc GR . . . .
H23B H 0.9565 0.5655 0.4455 0.077 Uiso 1 1 calc GR . . . .
H23C H 0.9441 0.5975 0.5161 0.077 Uiso 1 1 calc GR . . . .
C78 C 0.8865(5) 1.1740(4) 0.6756(3) 0.0486(17) Uani 1 1 d . . . . .
H78A H 0.8768 1.1952 0.6276 0.058 Uiso 1 1 calc R . . . .
H78B H 0.8944 1.2228 0.6942 0.058 Uiso 1 1 calc R . . . .
C11 C 0.4534(4) 0.9650(4) 0.8987(3) 0.0342(14) Uani 1 1 d . . . . .
H11 H 0.5064 0.9319 0.9172 0.041 Uiso 1 1 calc R . . . .
C67 C 1.1246(4) 0.6613(4) 0.7279(3) 0.0334(13) Uani 1 1 d . . . . .
C8 C 0.3155(4) 1.0018(4) 0.8545(3) 0.0287(13) Uani 1 1 d . . . . .
C21 C 0.9422(4) 0.8153(4) 0.4918(2) 0.0322(13) Uani 1 1 d . . . . .
H21 H 1.0008 0.7775 0.4938 0.039 Uiso 1 1 calc R . . . .
C9 C 0.3501(4) 1.0772(4) 0.8563(3) 0.0328(13) Uani 1 1 d . . . . .
H9 H 0.3209 1.1343 0.8415 0.039 Uiso 1 1 calc R . . . .
C70 C 1.0798(4) 0.7459(5) 0.8089(4) 0.0514(19) Uani 1 1 d . . . . .
H70 H 1.0659 0.7948 0.8296 0.062 Uiso 1 1 calc R . . . .
C14 C 0.1979(4) 0.9727(5) 0.7527(3) 0.0492(18) Uani 1 1 d . . . . .
H14A H 0.2192 1.0211 0.7163 0.074 Uiso 1 1 calc GR . . . .
H14B H 0.1332 0.9654 0.7505 0.074 Uiso 1 1 calc GR . . . .
H14C H 0.2423 0.9201 0.7459 0.074 Uiso 1 1 calc GR . . . .
C26 C 0.4992(4) 1.1546(4) 0.6702(3) 0.0306(13) Uani 1 1 d . . . . .
C15 C 0.1446(4) 0.9053(4) 0.9056(3) 0.0487(17) Uani 1 1 d . . . . .
H15A H 0.1866 0.8510 0.9008 0.073 Uiso 1 1 calc GR . . . .
H15B H 0.0806 0.9019 0.8994 0.073 Uiso 1 1 calc GR . . . .
H15C H 0.1396 0.9161 0.9518 0.073 Uiso 1 1 calc GR . . . .
C30 C 0.5674(4) 1.0910(4) 0.6396(3) 0.0324(13) Uani 1 1 d . . . . .
H30 H 0.6353 1.0875 0.6318 0.039 Uiso 1 1 calc R . . . .
C45 C 0.6961(4) 0.4358(4) 0.7529(3) 0.0425(16) Uani 1 1 d . . . . .
H45 H 0.6382 0.4310 0.7867 0.051 Uiso 1 1 calc R . . . .
C27 C 0.4083(4) 1.1338(4) 0.6703(3) 0.0376(15) Uani 1 1 d . . . . .
H27 H 0.3480 1.1646 0.6873 0.045 Uiso 1 1 calc R . . . .
C35 C 0.6856(4) 0.6559(4) 1.0201(3) 0.0339(14) Uani 1 1 d . . . . .
C71 C 1.1145(4) 0.7460(4) 0.7383(3) 0.0391(15) Uani 1 1 d . . . . .
H71 H 1.1289 0.7950 0.7032 0.047 Uiso 1 1 calc R . . . .
C29 C 0.5193(5) 1.0352(4) 0.6230(3) 0.0399(15) Uani 1 1 d . . . . .
H29 H 0.5483 0.9872 0.6023 0.048 Uiso 1 1 calc R . . . .
C48 C 0.8518(4) 0.4298(3) 0.7006(3) 0.0367(14) Uani 1 1 d . . . . .
H48 H 0.9200 0.4201 0.6925 0.044 Uiso 1 1 calc R . . . .
C94 C 0.8723(4) 0.9735(4) 0.8720(3) 0.0443(16) Uani 1 1 d . . . . .
H94A H 0.9092 1.0125 0.8339 0.053 Uiso 1 1 calc R . . . .
H94B H 0.9072 0.9143 0.8743 0.053 Uiso 1 1 calc R . . . .
C38 C 0.5355(5) 0.6980(6) 0.9945(3) 0.059(2) Uani 1 1 d . . . . .
H38 H 0.4771 0.7323 0.9857 0.071 Uiso 1 1 calc R . . . .
F95 F 0.88018(19) 0.84456(18) 0.77733(14) 0.0259(7) Uani 1 1 d . . . . .
F59 F 0.6900(2) 0.83204(18) 0.86297(13) 0.0253(6) Uani 1 1 d . . . . .
F65 F 0.9048(2) 0.59180(19) 0.74632(15) 0.0328(7) Uani 1 1 d . . . . .
C19 C 0.8293(5) 0.9322(4) 0.4984(3) 0.0462(17) Uani 1 1 d . . . . .
H19 H 0.7971 0.9872 0.5056 0.055 Uiso 1 1 calc R . . . .
C86 C 0.3734(4) 0.8285(4) 0.6241(3) 0.0434(16) Uani 1 1 d . . . . .
H86A H 0.3529 0.8803 0.6446 0.052 Uiso 1 1 calc R . . . .
H86B H 0.3277 0.7869 0.6470 0.052 Uiso 1 1 calc R . . . .
C79 C 0.8042(5) 1.1284(4) 0.7209(3) 0.0452(16) Uani 1 1 d . . . . .
H79A H 0.7952 1.1340 0.7695 0.054 Uiso 1 1 calc R . . . .
H79B H 0.7437 1.1527 0.7046 0.054 Uiso 1 1 calc R . . . .
C16 C 0.1174(4) 1.0987(4) 0.8482(4) 0.0536(19) Uani 1 1 d . . . . .
H16A H 0.1125 1.1092 0.8944 0.080 Uiso 1 1 calc GR . . . .
H16B H 0.0533 1.0961 0.8416 0.080 Uiso 1 1 calc GR . . . .
H16C H 0.1452 1.1455 0.8133 0.080 Uiso 1 1 calc GR . . . .
C47 C 0.7986(6) 0.4627(4) 0.6501(3) 0.0516(18) Uani 1 1 d . . . . .
H47 H 0.8236 0.4795 0.6020 0.062 Uiso 1 1 calc R . . . .
C32 C 0.5456(5) 1.2455(4) 0.7750(3) 0.0559(19) Uani 1 1 d . . . . .
H32A H 0.4848 1.2400 0.8086 0.084 Uiso 1 1 calc GR . . . .
H32B H 0.5703 1.2968 0.7772 0.084 Uiso 1 1 calc GR . . . .
H32C H 0.5924 1.1945 0.7858 0.084 Uiso 1 1 calc GR . . . .
C36 C 0.6546(5) 0.5856(4) 1.0053(3) 0.0473(17) Uani 1 1 d . . . . .
H36 H 0.6903 0.5299 1.0053 0.057 Uiso 1 1 calc R . . . .
C41 C 0.8829(5) 0.5595(4) 1.0299(3) 0.0545(19) Uani 1 1 d . . . . .
H41A H 0.8531 0.5075 1.0516 0.082 Uiso 1 1 calc GR . . . .
H41B H 0.9408 0.5566 1.0477 0.082 Uiso 1 1 calc GR . . . .
H41C H 0.9003 0.5640 0.9797 0.082 Uiso 1 1 calc GR . . . .
C24 C 0.8707(5) 0.7297(4) 0.3448(3) 0.0483(17) Uani 1 1 d . . . . .
H24A H 0.8248 0.7808 0.3323 0.072 Uiso 1 1 calc GR . . . .
H24B H 0.8586 0.6818 0.3278 0.072 Uiso 1 1 calc GR . . . .
H24C H 0.9363 0.7419 0.3240 0.072 Uiso 1 1 calc GR . . . .
C69 C 1.0692(5) 0.6635(5) 0.8428(3) 0.055(2) Uani 1 1 d . . . . .
H69 H 1.0474 0.6453 0.8912 0.066 Uiso 1 1 calc R . . . .
C25 C 0.7380(5) 0.6602(4) 0.4765(3) 0.0508(18) Uani 1 1 d . . . . .
H25A H 0.7259 0.6476 0.5271 0.076 Uiso 1 1 calc GR . . . .
H25B H 0.7389 0.6077 0.4601 0.076 Uiso 1 1 calc GR . . . .
H25C H 0.6869 0.7042 0.4608 0.076 Uiso 1 1 calc GR . . . .
C89 C 0.5189(5) 0.7623(6) 0.5680(3) 0.074(3) Uani 1 1 d . . . . .
H89A H 0.5428 0.7000 0.5780 0.088 Uiso 1 1 calc R . . . .
H89B H 0.5743 0.7936 0.5452 0.088 Uiso 1 1 calc R . . . .
C84 C 0.3188(5) 0.6354(5) 0.8764(3) 0.063(2) Uani 1 1 d . . . . .
H84A H 0.2494 0.6370 0.8972 0.075 Uiso 1 1 calc R . . . .
H84B H 0.3552 0.6242 0.9138 0.075 Uiso 1 1 calc R . . . .
C88 C 0.4491(5) 0.7801(5) 0.5231(3) 0.062(2) Uani 1 1 d . . . . .
H88A H 0.4182 0.7288 0.5281 0.074 Uiso 1 1 calc R . . . .
H88B H 0.4802 0.7983 0.4740 0.074 Uiso 1 1 calc R . . . .
C92 C 0.7577(5) 1.0399(6) 0.9546(4) 0.074(3) Uani 1 1 d . . . . .
H92A H 0.7322 1.0296 1.0051 0.089 Uiso 1 1 calc R . . . .
H92B H 0.7505 1.1027 0.9359 0.089 Uiso 1 1 calc R . . . .
C42 C 0.8497(5) 0.7561(5) 1.0083(4) 0.059(2) Uani 1 1 d . . . . .
H42A H 0.8684 0.7596 0.9582 0.089 Uiso 1 1 calc GR . . . .
H42B H 0.9064 0.7559 1.0266 0.089 Uiso 1 1 calc GR . . . .
H42C H 0.8020 0.8058 1.0180 0.089 Uiso 1 1 calc GR . . . .
C43 C 0.7676(6) 0.6500(5) 1.1455(3) 0.063(2) Uani 1 1 d . . . . .
H43A H 0.7175 0.6977 1.1564 0.095 Uiso 1 1 calc GR . . . .
H43B H 0.8254 0.6543 1.1607 0.095 Uiso 1 1 calc GR . . . .
H43C H 0.7447 0.5953 1.1694 0.095 Uiso 1 1 calc GR . . . .
C82 C 0.4368(6) 0.6011(5) 0.7836(4) 0.081(3) Uani 1 1 d . . . . .
H82A H 0.4455 0.5831 0.7390 0.097 Uiso 1 1 calc R . . . .
H82B H 0.4954 0.5779 0.8027 0.097 Uiso 1 1 calc R . . . .
C83 C 0.3527(6) 0.5695(5) 0.8320(4) 0.070(2) Uani 1 1 d . . . . .
H83A H 0.3704 0.5120 0.8600 0.084 Uiso 1 1 calc R . . . .
H83B H 0.3028 0.5663 0.8074 0.084 Uiso 1 1 calc R . . . .
C33 C 0.6314(6) 1.2892(5) 0.6210(4) 0.076(3) Uani 1 1 d . . . . .
H33A H 0.6815 1.2395 0.6169 0.114 Uiso 1 1 calc GR . . . .
H33B H 0.6560 1.3332 0.6351 0.114 Uiso 1 1 calc GR . . . .
H33C H 0.6128 1.3130 0.5763 0.114 Uiso 1 1 calc GR . . . .
C74 C 1.3040(5) 0.5780(6) 0.6411(5) 0.085(3) Uani 1 1 d . . . . .
H74A H 1.3385 0.6218 0.6463 0.127 Uiso 1 1 calc GR . . . .
H74B H 1.3307 0.5623 0.5959 0.127 Uiso 1 1 calc GR . . . .
H74C H 1.3112 0.5270 0.6778 0.127 Uiso 1 1 calc GR . . . .
C87 C 0.3776(6) 0.8513(6) 0.5482(4) 0.081(3) Uani 1 1 d . . . . .
H87A H 0.3999 0.9078 0.5276 0.098 Uiso 1 1 calc R . . . .
H87B H 0.3142 0.8524 0.5375 0.098 Uiso 1 1 calc R . . . .
C34 C 0.4213(7) 1.3396(5) 0.6744(4) 0.087(3) Uani 1 1 d . . . . .
H34A H 0.4176 1.3545 0.6255 0.130 Uiso 1 1 calc GR . . . .
H34B H 0.4293 1.3907 0.6891 0.130 Uiso 1 1 calc GR . . . .
H34C H 0.3621 1.3182 0.7022 0.130 Uiso 1 1 calc GR . . . .
C50 C 0.9049(7) 0.4205(6) 0.8736(5) 0.104(4) Uani 1 1 d . . . . .
H50A H 0.9618 0.4269 0.8362 0.156 Uiso 1 1 calc GR . . . .
H50B H 0.9248 0.3885 0.9165 0.156 Uiso 1 1 calc GR . . . .
H50C H 0.8713 0.4775 0.8801 0.156 Uiso 1 1 calc GR . . . .
C51 C 0.8830(8) 0.2511(5) 0.8492(4) 0.106(4) Uani 1 1 d . . . . .
H51A H 0.8396 0.2185 0.8389 0.158 Uiso 1 1 calc GR . . . .
H51B H 0.8988 0.2238 0.8944 0.158 Uiso 1 1 calc GR . . . .
H51C H 0.9420 0.2518 0.8135 0.158 Uiso 1 1 calc GR . . . .
C52 C 0.7121(7) 0.3570(7) 0.9192(4) 0.109(4) Uani 1 1 d . . . . .
H52A H 0.6800 0.4155 0.9221 0.163 Uiso 1 1 calc GR . . . .
H52B H 0.7283 0.3277 0.9639 0.163 Uiso 1 1 calc GR . . . .
H52C H 0.6690 0.3254 0.9076 0.163 Uiso 1 1 calc GR . . . .
C80 C 0.3385(5) 0.7166(5) 0.8263(4) 0.070(2) Uani 1 1 d . . . . .
H80A H 0.2817 0.7433 0.8058 0.084 Uiso 1 1 calc R . . . .
H80B H 0.3535 0.7579 0.8498 0.084 Uiso 1 1 calc R . . . .
C73 C 1.1663(7) 0.7143(8) 0.5728(5) 0.131(4) Uani 1 1 d . U . . .
H73A H 1.1690 0.7674 0.5870 0.197 Uiso 1 1 calc GR . . . .
H73B H 1.1055 0.7191 0.5581 0.197 Uiso 1 1 calc GR . . . .
H73C H 1.2201 0.7051 0.5343 0.197 Uiso 1 1 calc GR . . . .
C2 C 1.1082(9) 0.5430(9) 0.6392(7) 0.180(5) Uani 1 1 d . U . . .
H2A H 1.1149 0.4921 0.6761 0.271 Uiso 1 1 calc GR . . . .
H2B H 1.1333 0.5267 0.5941 0.271 Uiso 1 1 calc GR . . . .
H2C H 1.0401 0.5671 0.6429 0.271 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 Dy3 3.7649(3) . ?
Dy1 F58 2.187(3) . ?
Dy1 F56 2.183(3) . ?
Dy1 F55 2.299(2) . ?
Dy1 O75 2.376(4) . ?
Dy1 O90 2.401(3) . ?
Dy1 F95 2.195(3) . ?
Dy1 F59 2.191(3) . ?
Dy2 Dy5 3.8675(3) . ?
Dy2 Dy7 3.8672(4) . ?
Dy2 F63 2.190(3) . ?
Dy2 F56 2.190(3) . ?
Dy2 F62 2.696(3) . ?
Dy2 F54 2.192(3) . ?
Dy2 F61 2.193(3) . ?
Dy2 C17 2.686(5) . ?
Dy2 C18 2.697(5) . ?
Dy2 C20 2.656(6) . ?
Dy2 C21 2.632(5) . ?
Dy2 C19 2.678(6) . ?
Dy3 F58 2.268(3) . ?
Dy3 F57 2.275(3) . ?
Dy3 F55 2.340(3) . ?
Dy3 C28 2.675(5) . ?
Dy3 C12 2.668(5) . ?
Dy3 C11 2.669(5) . ?
Dy3 C8 2.685(5) . ?
Dy3 C9 2.685(5) . ?
Dy3 C26 2.685(5) . ?
Dy3 C30 2.666(5) . ?
Dy3 C27 2.672(5) . ?
Dy3 C29 2.669(5) . ?
Dy4 F57 2.185(3) . ?
Dy4 F55 2.309(3) . ?
Dy4 F53 2.189(3) . ?
Dy4 F54 2.195(3) . ?
Dy4 O81 2.402(4) . ?
Dy4 O85 2.371(3) . ?
Dy4 F60 2.184(3) . ?
Dy5 Dy7 3.8338(3) . ?
Dy5 F62 2.516(3) . ?
Dy5 F61 2.192(3) . ?
Dy5 F66 2.207(3) . ?
Dy5 C68 2.661(6) . ?
Dy5 C67 2.678(5) . ?
Dy5 C70 2.656(5) . ?
Dy5 C71 2.664(5) . ?
Dy5 F95 2.213(3) . ?
Dy5 F65 2.195(3) . ?
Dy5 C69 2.667(6) . ?
Dy6 Dy7 3.9177(4) . ?
Dy6 F62 2.814(3) . ?
Dy6 F60 2.190(3) . ?
Dy6 F64 2.192(3) . ?
Dy6 F66 2.198(3) . ?
Dy6 C37 2.649(6) . ?
Dy6 C39 2.680(6) . ?
Dy6 C35 2.664(5) . ?
Dy6 C38 2.663(7) . ?
Dy6 F59 2.183(3) . ?
Dy6 C36 2.629(6) . ?
Dy7 F63 2.207(3) . ?
Dy7 F53 2.208(3) . ?
Dy7 F62 2.551(3) . ?
Dy7 F64 2.198(3) . ?
Dy7 C44 2.665(5) . ?
Dy7 C46 2.655(6) . ?
Dy7 C45 2.647(6) . ?
Dy7 C48 2.666(5) . ?
Dy7 F65 2.195(3) . ?
Dy7 C47 2.674(6) . ?
Si13 C8 1.863(5) . ?
Si13 C14 1.865(5) . ?
Si13 C15 1.865(7) . ?
Si13 C16 1.864(6) . ?
Si22 C17 1.850(5) . ?
Si22 C23 1.858(6) . ?
Si22 C24 1.873(6) . ?
Si22 C25 1.857(6) . ?
Si31 C26 1.863(6) . ?
Si31 C32 1.854(6) . ?
Si31 C33 1.854(8) . ?
Si31 C34 1.848(8) . ?
Si40 C35 1.853(6) . ?
Si40 C41 1.856(6) . ?
Si40 C42 1.865(7) . ?
Si40 C43 1.866(6) . ?
Si49 C44 1.856(6) . ?
Si49 C50 1.842(8) . ?
Si49 C51 1.836(8) . ?
Si49 C52 1.861(9) . ?
Si72 C67 1.839(6) . ?
Si72 C74 1.864(7) . ?
Si72 C73 1.866(10) . ?
Si72 C2 1.790(11) . ?
O75 C76 1.458(6) . ?
O75 C79 1.445(7) . ?
O81 C82 1.461(8) . ?
O81 C80 1.432(8) . ?
O85 C86 1.436(6) . ?
O85 C89 1.452(7) . ?
O90 C91 1.439(6) . ?
O90 C94 1.443(6) . ?
C37 H37 0.9500 . ?
C37 C38 1.387(10) . ?
C37 C36 1.403(9) . ?
C68 H68 0.9500 . ?
C68 C67 1.422(8) . ?
C68 C69 1.376(9) . ?
C91 H91A 0.9900 . ?
C91 H91B 0.9900 . ?
C91 C92 1.486(8) . ?
C44 C45 1.420(8) . ?
C44 C48 1.416(8) . ?
C10 H10 0.9500 . ?
C10 C11 1.397(8) . ?
C10 C9 1.404(7) . ?
C17 C18 1.433(7) . ?
C17 C21 1.417(7) . ?
C18 H18 0.9500 . ?
C18 C19 1.407(8) . ?
C39 H39 0.9500 . ?
C39 C35 1.427(8) . ?
C39 C38 1.391(9) . ?
C76 H76A 0.9900 . ?
C76 H76B 0.9900 . ?
C76 C77 1.497(8) . ?
C28 H28 0.9500 . ?
C28 C27 1.381(8) . ?
C28 C29 1.398(9) . ?
C77 H77A 0.9900 . ?
C77 H77B 0.9900 . ?
C77 C78 1.513(9) . ?
C93 H93A 0.9900 . ?
C93 H93B 0.9900 . ?
C93 C94 1.484(7) . ?
C93 C92 1.491(9) . ?
C20 H20 0.9500 . ?
C20 C21 1.393(8) . ?
C20 C19 1.402(9) . ?
C46 H46 0.9500 . ?
C46 C45 1.397(9) . ?
C46 C47 1.387(9) . ?
C12 H12 0.9500 . ?
C12 C11 1.394(7) . ?
C12 C8 1.425(7) . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C78 H78A 0.9900 . ?
C78 H78B 0.9900 . ?
C78 C79 1.514(8) . ?
C11 H11 0.9500 . ?
C67 C71 1.410(8) . ?
C8 C9 1.417(7) . ?
C21 H21 0.9500 . ?
C9 H9 0.9500 . ?
C70 H70 0.9500 . ?
C70 C71 1.402(9) . ?
C70 C69 1.366(9) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C26 C30 1.429(8) . ?
C26 C27 1.421(8) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C30 H30 0.9500 . ?
C30 C29 1.384(8) . ?
C45 H45 0.9500 . ?
C27 H27 0.9500 . ?
C35 C36 1.420(8) . ?
C71 H71 0.9500 . ?
C29 H29 0.9500 . ?
C48 H48 0.9500 . ?
C48 C47 1.377(8) . ?
C94 H94A 0.9900 . ?
C94 H94B 0.9900 . ?
C38 H38 0.9500 . ?
C19 H19 0.9500 . ?
C86 H86A 0.9900 . ?
C86 H86B 0.9900 . ?
C86 C87 1.488(8) . ?
C79 H79A 0.9900 . ?
C79 H79B 0.9900 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C47 H47 0.9500 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C36 H36 0.9500 . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C69 H69 0.9500 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C89 H89A 0.9900 . ?
C89 H89B 0.9900 . ?
C89 C88 1.465(8) . ?
C84 H84A 0.9900 . ?
C84 H84B 0.9900 . ?
C84 C83 1.496(10) . ?
C84 C80 1.486(10) . ?
C88 H88A 0.9900 . ?
C88 H88B 0.9900 . ?
C88 C87 1.492(10) . ?
C92 H92A 0.9900 . ?
C92 H92B 0.9900 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C82 H82A 0.9900 . ?
C82 H82B 0.9900 . ?
C82 C83 1.460(10) . ?
C83 H83A 0.9900 . ?
C83 H83B 0.9900 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C87 H87A 0.9900 . ?
C87 H87B 0.9900 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C80 H80A 0.9900 . ?
C80 H80B 0.9900 . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F58 Dy1 Dy3 32.99(7) . . ?
F58 Dy1 F55 69.10(9) . . ?
F58 Dy1 O75 83.36(12) . . ?
F58 Dy1 O90 80.87(11) . . ?
F58 Dy1 F95 161.19(10) . . ?
F58 Dy1 F59 98.92(10) . . ?
F56 Dy1 Dy3 95.35(7) . . ?
F56 Dy1 F58 110.17(10) . . ?
F56 Dy1 F55 76.90(10) . . ?
F56 Dy1 O75 75.84(11) . . ?
F56 Dy1 O90 145.86(11) . . ?
F56 Dy1 F95 81.95(10) . . ?
F56 Dy1 F59 129.86(10) . . ?
F55 Dy1 Dy3 36.12(7) . . ?
F55 Dy1 O75 131.01(11) . . ?
F55 Dy1 O90 135.79(11) . . ?
O75 Dy1 Dy3 108.38(9) . . ?
O75 Dy1 O90 73.50(12) . . ?
O90 Dy1 Dy3 108.23(8) . . ?
F95 Dy1 Dy3 164.41(7) . . ?
F95 Dy1 F55 129.00(10) . . ?
F95 Dy1 O75 85.95(12) . . ?
F95 Dy1 O90 81.27(11) . . ?
F59 Dy1 Dy3 87.45(7) . . ?
F59 Dy1 F55 76.70(9) . . ?
F59 Dy1 O75 149.48(11) . . ?
F59 Dy1 O90 76.82(11) . . ?
F59 Dy1 F95 82.68(10) . . ?
Dy7 Dy2 Dy5 59.427(6) . . ?
F63 Dy2 Dy5 77.28(7) . . ?
F63 Dy2 Dy7 28.54(7) . . ?
F63 Dy2 F62 69.40(9) . . ?
F63 Dy2 F54 86.80(11) . . ?
F63 Dy2 F61 84.53(10) . . ?
F63 Dy2 C17 83.94(13) . . ?
F63 Dy2 C18 106.27(14) . . ?
F63 Dy2 C20 126.31(16) . . ?
F63 Dy2 C21 95.82(15) . . ?
F63 Dy2 C19 134.51(14) . . ?
F56 Dy2 Dy5 76.59(7) . . ?
F56 Dy2 Dy7 115.37(7) . . ?
F56 Dy2 F63 143.88(10) . . ?
F56 Dy2 F62 74.53(9) . . ?
F56 Dy2 F54 82.54(10) . . ?
F56 Dy2 F61 84.05(10) . . ?
F56 Dy2 C17 132.09(13) . . ?
F56 Dy2 C18 106.61(14) . . ?
F56 Dy2 C20 86.84(15) . . ?
F56 Dy2 C21 116.74(15) . . ?
F56 Dy2 C19 81.08(15) . . ?
F62 Dy2 Dy5 40.33(6) . . ?
F62 Dy2 Dy7 41.08(6) . . ?
F62 Dy2 C18 158.67(14) . . ?
F54 Dy2 Dy5 115.69(7) . . ?
F54 Dy2 Dy7 77.66(7) . . ?
F54 Dy2 F62 75.62(9) . . ?
F54 Dy2 F61 143.77(10) . . ?
F54 Dy2 C17 103.22(13) . . ?
F54 Dy2 C18 83.36(14) . . ?
F54 Dy2 C20 126.50(17) . . ?
F54 Dy2 C21 132.30(13) . . ?
F54 Dy2 C19 96.02(17) . . ?
F61 Dy2 Dy5 28.12(7) . . ?
F61 Dy2 Dy7 78.05(8) . . ?
F61 Dy2 F62 68.39(9) . . ?
F61 Dy2 C17 110.71(13) . . ?
F61 Dy2 C18 132.81(15) . . ?
F61 Dy2 C20 85.98(16) . . ?
F61 Dy2 C21 83.63(14) . . ?
F61 Dy2 C19 114.89(17) . . ?
C17 Dy2 Dy5 135.22(11) . . ?
C17 Dy2 Dy7 112.28(11) . . ?
C17 Dy2 F62 153.33(13) . . ?
C17 Dy2 C18 30.87(15) . . ?
C18 Dy2 Dy5 160.92(13) . . ?
C18 Dy2 Dy7 130.60(12) . . ?
C20 Dy2 Dy5 112.29(13) . . ?
C20 Dy2 Dy7 150.65(15) . . ?
C20 Dy2 F62 149.40(14) . . ?
C20 Dy2 C17 51.17(16) . . ?
C20 Dy2 C18 50.18(18) . . ?
C20 Dy2 C19 30.48(19) . . ?
C21 Dy2 Dy5 111.28(12) . . ?
C21 Dy2 Dy7 121.99(13) . . ?
C21 Dy2 F62 149.04(14) . . ?
C21 Dy2 C17 30.87(15) . . ?
C21 Dy2 C18 50.12(17) . . ?
C21 Dy2 C20 30.55(18) . . ?
C21 Dy2 C19 50.3(2) . . ?
C19 Dy2 Dy5 137.79(14) . . ?
C19 Dy2 Dy7 160.93(13) . . ?
C19 Dy2 F62 154.99(15) . . ?
C19 Dy2 C17 51.13(17) . . ?
C19 Dy2 C18 30.35(17) . . ?
F58 Dy3 F57 133.91(10) . . ?
F58 Dy3 F55 67.05(9) . . ?
F58 Dy3 C28 124.96(15) . . ?
F58 Dy3 C12 107.58(13) . . ?
F58 Dy3 C11 78.14(13) . . ?
F58 Dy3 C8 124.83(12) . . ?
F58 Dy3 C9 102.10(13) . . ?
F58 Dy3 C26 81.61(13) . . ?
F58 Dy3 C30 75.19(14) . . ?
F58 Dy3 C27 112.20(15) . . ?
F58 Dy3 C29 100.45(16) . . ?
F57 Dy3 F55 67.20(9) . . ?
F57 Dy3 C28 75.53(15) . . ?
F57 Dy3 C12 73.79(13) . . ?
F57 Dy3 C11 99.18(15) . . ?
F57 Dy3 C8 80.49(13) . . ?
F57 Dy3 C9 110.96(14) . . ?
F57 Dy3 C26 125.49(13) . . ?
F57 Dy3 C30 108.29(14) . . ?
F57 Dy3 C27 102.35(15) . . ?
F57 Dy3 C29 79.08(15) . . ?
F55 Dy3 C28 108.52(17) . . ?
F55 Dy3 C12 98.07(13) . . ?
F55 Dy3 C11 93.22(14) . . ?
F55 Dy3 C8 127.15(14) . . ?
F55 Dy3 C9 143.09(14) . . ?
F55 Dy3 C26 117.72(14) . . ?
F55 Dy3 C30 87.85(14) . . ?
F55 Dy3 C27 132.43(15) . . ?
F55 Dy3 C29 82.83(15) . . ?
C28 Dy3 C8 101.94(18) . . ?
C28 Dy3 C9 106.3(2) . . ?
C28 Dy3 C26 50.68(17) . . ?
C12 Dy3 C28 126.82(18) . . ?
C12 Dy3 C11 30.29(15) . . ?
C12 Dy3 C8 30.89(16) . . ?
C12 Dy3 C9 49.84(17) . . ?
C12 Dy3 C26 143.39(17) . . ?
C12 Dy3 C27 124.40(18) . . ?
C11 Dy3 C28 152.78(19) . . ?
C11 Dy3 C8 50.97(15) . . ?
C11 Dy3 C9 49.96(18) . . ?
C11 Dy3 C26 132.10(18) . . ?
C11 Dy3 C27 134.16(19) . . ?
C8 Dy3 C9 30.59(16) . . ?
C8 Dy3 C26 115.04(17) . . ?
C9 Dy3 C26 93.85(18) . . ?
C30 Dy3 C28 49.86(18) . . ?
C30 Dy3 C12 174.05(17) . . ?
C30 Dy3 C11 150.52(17) . . ?
C30 Dy3 C8 143.29(17) . . ?
C30 Dy3 C9 124.77(18) . . ?
C30 Dy3 C26 30.97(16) . . ?
C30 Dy3 C27 49.94(18) . . ?
C30 Dy3 C29 30.07(16) . . ?
C27 Dy3 C28 29.93(18) . . ?
C27 Dy3 C8 93.60(18) . . ?
C27 Dy3 C9 84.47(18) . . ?
C27 Dy3 C26 30.76(16) . . ?
C29 Dy3 C28 30.34(18) . . ?
C29 Dy3 C12 149.95(18) . . ?
C29 Dy3 C11 176.04(19) . . ?
C29 Dy3 C8 131.68(18) . . ?
C29 Dy3 C9 133.97(18) . . ?
C29 Dy3 C26 50.83(17) . . ?
C29 Dy3 C27 49.80(19) . . ?
F57 Dy4 Dy3 33.10(7) . . ?
F57 Dy4 F55 69.21(9) . . ?
F57 Dy4 F53 163.15(10) . . ?
F57 Dy4 F54 112.31(10) . . ?
F57 Dy4 O81 84.47(12) . . ?
F57 Dy4 O85 80.49(11) . . ?
F55 Dy4 Dy3 36.15(6) . . ?
F55 Dy4 O81 139.46(12) . . ?
F55 Dy4 O85 126.36(12) . . ?
F53 Dy4 Dy3 162.89(7) . . ?
F53 Dy4 F55 126.89(10) . . ?
F53 Dy4 F54 79.38(11) . . ?
F53 Dy4 O81 79.28(13) . . ?
F53 Dy4 O85 91.13(12) . . ?
F54 Dy4 Dy3 94.41(8) . . ?
F54 Dy4 F55 75.96(10) . . ?
F54 Dy4 O81 144.22(12) . . ?
F54 Dy4 O85 76.29(11) . . ?
O81 Dy4 Dy3 113.31(10) . . ?
O85 Dy4 Dy3 102.96(10) . . ?
O85 Dy4 O81 75.76(13) . . ?
F60 Dy4 Dy3 87.52(8) . . ?
F60 Dy4 F57 96.63(10) . . ?
F60 Dy4 F55 76.13(10) . . ?
F60 Dy4 F53 84.11(11) . . ?
F60 Dy4 F54 128.55(10) . . ?
F60 Dy4 O81 77.01(11) . . ?
F60 Dy4 O85 152.76(12) . . ?
Dy7 Dy5 Dy2 60.283(6) . . ?
F62 Dy5 Dy2 43.91(7) . . ?
F62 Dy5 Dy7 41.17(7) . . ?
F62 Dy5 C68 152.68(16) . . ?
F62 Dy5 C67 150.72(13) . . ?
F62 Dy5 C70 155.73(16) . . ?
F62 Dy5 C71 153.42(15) . . ?
F62 Dy5 C69 155.11(17) . . ?
F61 Dy5 Dy2 28.12(7) . . ?
F61 Dy5 Dy7 78.84(7) . . ?
F61 Dy5 F62 71.96(10) . . ?
F61 Dy5 F66 144.69(10) . . ?
F61 Dy5 C68 114.59(17) . . ?
F61 Dy5 C67 85.24(14) . . ?
F61 Dy5 C70 111.87(19) . . ?
F61 Dy5 C71 84.28(15) . . ?
F61 Dy5 F95 83.81(10) . . ?
F61 Dy5 F65 86.84(11) . . ?
F61 Dy5 C69 132.92(18) . . ?
F66 Dy5 Dy2 116.62(7) . . ?
F66 Dy5 Dy7 77.89(7) . . ?
F66 Dy5 F62 73.01(10) . . ?
F66 Dy5 C68 98.70(17) . . ?
F66 Dy5 C67 129.28(14) . . ?
F66 Dy5 C70 98.37(18) . . ?
F66 Dy5 C71 128.54(15) . . ?
F66 Dy5 F95 83.81(11) . . ?
F66 Dy5 C69 82.16(17) . . ?
C68 Dy5 Dy2 138.99(15) . . ?
C68 Dy5 Dy7 112.17(15) . . ?
C68 Dy5 C67 30.89(18) . . ?
C68 Dy5 C71 49.82(19) . . ?
C68 Dy5 C69 29.92(19) . . ?
C67 Dy5 Dy2 112.32(12) . . ?
C67 Dy5 Dy7 117.57(12) . . ?
C70 Dy5 Dy2 135.37(18) . . ?
C70 Dy5 Dy7 160.91(17) . . ?
C70 Dy5 C68 49.4(2) . . ?
C70 Dy5 C67 50.76(18) . . ?
C70 Dy5 C71 30.57(19) . . ?
C70 Dy5 C69 29.7(2) . . ?
C71 Dy5 Dy2 111.36(14) . . ?
C71 Dy5 Dy7 145.75(13) . . ?
C71 Dy5 C67 30.61(17) . . ?
C71 Dy5 C69 49.8(2) . . ?
F95 Dy5 Dy2 77.20(7) . . ?
F95 Dy5 Dy7 117.52(7) . . ?
F95 Dy5 F62 76.36(9) . . ?
F95 Dy5 C68 129.55(17) . . ?
F95 Dy5 C67 120.08(14) . . ?
F95 Dy5 C70 80.21(17) . . ?
F95 Dy5 C71 89.65(15) . . ?
F95 Dy5 C69 103.04(19) . . ?
F65 Dy5 Dy2 79.55(7) . . ?
F65 Dy5 Dy7 29.15(7) . . ?
F65 Dy5 F62 70.32(10) . . ?
F65 Dy5 F66 85.63(11) . . ?
F65 Dy5 C68 83.29(17) . . ?
F65 Dy5 C67 90.78(14) . . ?
F65 Dy5 C70 132.70(17) . . ?
F65 Dy5 C71 121.17(15) . . ?
F65 Dy5 F95 146.67(10) . . ?
F65 Dy5 C69 106.7(2) . . ?
C69 Dy5 Dy2 160.92(16) . . ?
C69 Dy5 Dy7 131.90(19) . . ?
C69 Dy5 C67 50.67(19) . . ?
Dy5 Dy6 Dy7 58.643(6) . . ?
F62 Dy6 Dy5 39.90(5) . . ?
F62 Dy6 Dy7 40.52(6) . . ?
F60 Dy6 Dy5 114.35(7) . . ?
F60 Dy6 Dy7 76.25(8) . . ?
F60 Dy6 F62 74.62(9) . . ?
F60 Dy6 F64 82.92(11) . . ?
F60 Dy6 F66 141.79(10) . . ?
F60 Dy6 C37 87.86(16) . . ?
F60 Dy6 C39 105.30(15) . . ?
F60 Dy6 C35 131.83(15) . . ?
F60 Dy6 C38 80.79(17) . . ?
F60 Dy6 C36 118.20(16) . . ?
F64 Dy6 Dy5 76.92(8) . . ?
F64 Dy6 Dy7 26.86(8) . . ?
F64 Dy6 F62 67.33(10) . . ?
F64 Dy6 F66 84.11(11) . . ?
F64 Dy6 C37 88.6(2) . . ?
F64 Dy6 C39 136.30(17) . . ?
F64 Dy6 C35 115.16(15) . . ?
F64 Dy6 C38 116.5(2) . . ?
F64 Dy6 C36 87.32(17) . . ?
F66 Dy6 Dy5 27.45(7) . . ?
F66 Dy6 Dy7 76.03(7) . . ?
F66 Dy6 F62 67.21(9) . . ?
F66 Dy6 C37 127.55(18) . . ?
F66 Dy6 C39 108.86(15) . . ?
F66 Dy6 C35 86.07(14) . . ?
F66 Dy6 C38 136.72(17) . . ?
F66 Dy6 C36 96.85(17) . . ?
C37 Dy6 Dy5 151.15(19) . . ?
C37 Dy6 Dy7 113.93(19) . . ?
C37 Dy6 F62 151.43(17) . . ?
C37 Dy6 C39 50.0(2) . . ?
C37 Dy6 C35 51.13(19) . . ?
C37 Dy6 C38 30.3(2) . . ?
C39 Dy6 Dy5 131.67(14) . . ?
C39 Dy6 Dy7 163.13(15) . . ?
C39 Dy6 F62 156.35(16) . . ?
C35 Dy6 Dy5 113.20(13) . . ?
C35 Dy6 Dy7 138.14(13) . . ?
C35 Dy6 F62 153.04(14) . . ?
C35 Dy6 C39 30.98(17) . . ?
C38 Dy6 Dy5 161.82(17) . . ?
C38 Dy6 Dy7 138.26(19) . . ?
C38 Dy6 F62 154.52(16) . . ?
C38 Dy6 C39 30.2(2) . . ?
C38 Dy6 C35 51.04(19) . . ?
F59 Dy6 Dy5 76.89(7) . . ?
F59 Dy6 Dy7 115.14(7) . . ?
F59 Dy6 F62 74.85(9) . . ?
F59 Dy6 F60 83.29(10) . . ?
F59 Dy6 F64 141.95(10) . . ?
F59 Dy6 F66 85.22(11) . . ?
F59 Dy6 C37 126.1(2) . . ?
F59 Dy6 C39 81.63(16) . . ?
F59 Dy6 C35 100.37(15) . . ?
F59 Dy6 C38 95.9(2) . . ?
F59 Dy6 C36 130.23(16) . . ?
C36 Dy6 Dy5 122.30(16) . . ?
C36 Dy6 Dy7 113.53(15) . . ?
C36 Dy6 F62 150.68(17) . . ?
C36 Dy6 C37 30.8(2) . . ?
C36 Dy6 C39 50.5(2) . . ?
C36 Dy6 C35 31.11(17) . . ?
C36 Dy6 C38 50.6(2) . . ?
Dy5 Dy7 Dy2 60.290(6) . . ?
F63 Dy7 Dy2 28.30(7) . . ?
F63 Dy7 Dy5 77.91(7) . . ?
F63 Dy7 F53 82.10(11) . . ?
F63 Dy7 F62 72.07(10) . . ?
F63 Dy7 C44 129.92(14) . . ?
F63 Dy7 C46 97.47(17) . . ?
F63 Dy7 C45 127.78(16) . . ?
F63 Dy7 C48 99.56(15) . . ?
F63 Dy7 C47 81.95(17) . . ?
F53 Dy7 Dy2 74.20(8) . . ?
F53 Dy7 Dy5 116.20(7) . . ?
F53 Dy7 F62 75.73(9) . . ?
F53 Dy7 C44 120.81(14) . . ?
F53 Dy7 C46 80.80(17) . . ?
F53 Dy7 C45 90.02(15) . . ?
F53 Dy7 C48 130.38(15) . . ?
F53 Dy7 C47 104.09(17) . . ?
F62 Dy7 Dy2 43.99(6) . . ?
F62 Dy7 Dy5 40.49(6) . . ?
F62 Dy7 C44 151.27(13) . . ?
F62 Dy7 C46 155.34(16) . . ?
F62 Dy7 C45 154.30(16) . . ?
F62 Dy7 C48 152.26(15) . . ?
F62 Dy7 C47 153.85(17) . . ?
F64 Dy7 Dy2 115.92(8) . . ?
F64 Dy7 Dy5 78.69(8) . . ?
F64 Dy7 F63 144.21(11) . . ?
F64 Dy7 F53 84.41(11) . . ?
F64 Dy7 F62 72.52(10) . . ?
F64 Dy7 C44 85.23(14) . . ?
F64 Dy7 C46 112.87(19) . . ?
F64 Dy7 C45 85.06(16) . . ?
F64 Dy7 C48 114.31(15) . . ?
F64 Dy7 C47 133.62(17) . . ?
C44 Dy7 Dy2 156.35(12) . . ?
C44 Dy7 Dy5 118.37(11) . . ?
C44 Dy7 C48 30.81(16) . . ?
C44 Dy7 C47 50.89(18) . . ?
C46 Dy7 Dy2 121.65(15) . . ?
C46 Dy7 Dy5 161.08(17) . . ?
C46 Dy7 C44 51.16(18) . . ?
C46 Dy7 C48 49.7(2) . . ?
C46 Dy7 C47 30.2(2) . . ?
C45 Dy7 Dy2 151.54(14) . . ?
C45 Dy7 Dy5 147.17(13) . . ?
C45 Dy7 C44 31.02(17) . . ?
C45 Dy7 C46 30.56(19) . . ?
C45 Dy7 C48 49.93(19) . . ?
C45 Dy7 C47 50.1(2) . . ?
C48 Dy7 Dy2 125.64(13) . . ?
C48 Dy7 Dy5 112.51(13) . . ?
C48 Dy7 C47 29.89(17) . . ?
F65 Dy7 Dy2 79.55(8) . . ?
F65 Dy7 Dy5 29.15(7) . . ?
F65 Dy7 F63 85.47(11) . . ?
F65 Dy7 F53 145.30(10) . . ?
F65 Dy7 F62 69.63(10) . . ?
F65 Dy7 F64 87.11(11) . . ?
F65 Dy7 C44 91.80(14) . . ?
F65 Dy7 C46 133.08(18) . . ?
F65 Dy7 C45 122.70(15) . . ?
F65 Dy7 C48 83.57(15) . . ?
F65 Dy7 C47 106.05(18) . . ?
C47 Dy7 Dy2 110.21(15) . . ?
C47 Dy7 Dy5 131.31(17) . . ?
C8 Si13 C14 115.1(3) . . ?
C8 Si13 C15 108.2(3) . . ?
C8 Si13 C16 107.8(3) . . ?
C15 Si13 C14 107.1(3) . . ?
C16 Si13 C14 108.7(3) . . ?
C16 Si13 C15 109.9(3) . . ?
C17 Si22 C23 108.1(3) . . ?
C17 Si22 C24 109.0(3) . . ?
C17 Si22 C25 111.7(3) . . ?
C23 Si22 C24 110.2(3) . . ?
C25 Si22 C23 110.4(3) . . ?
C25 Si22 C24 107.3(3) . . ?
C32 Si31 C26 114.2(3) . . ?
C33 Si31 C26 108.0(3) . . ?
C33 Si31 C32 110.2(3) . . ?
C34 Si31 C26 108.1(3) . . ?
C34 Si31 C32 108.1(3) . . ?
C34 Si31 C33 108.0(4) . . ?
C35 Si40 C41 108.5(3) . . ?
C35 Si40 C42 110.7(3) . . ?
C35 Si40 C43 109.6(3) . . ?
C41 Si40 C42 110.9(4) . . ?
C41 Si40 C43 109.8(3) . . ?
C42 Si40 C43 107.4(3) . . ?
C44 Si49 C52 108.5(3) . . ?
C50 Si49 C44 112.8(3) . . ?
C50 Si49 C52 109.2(5) . . ?
C51 Si49 C44 109.6(3) . . ?
C51 Si49 C50 108.7(5) . . ?
C51 Si49 C52 107.9(5) . . ?
Dy1 F58 Dy3 115.36(12) . . ?
Dy2 F63 Dy7 123.16(13) . . ?
Dy4 F57 Dy3 115.24(11) . . ?
C67 Si72 C74 110.6(3) . . ?
C67 Si72 C73 108.5(4) . . ?
C74 Si72 C73 106.8(4) . . ?
C2 Si72 C67 111.8(5) . . ?
C2 Si72 C74 110.9(5) . . ?
C2 Si72 C73 108.2(6) . . ?
Dy1 F56 Dy2 135.34(13) . . ?
Dy1 F55 Dy3 108.49(10) . . ?
Dy1 F55 Dy4 143.03(12) . . ?
Dy4 F55 Dy3 108.25(10) . . ?
Dy4 F53 Dy7 134.63(13) . . ?
Dy2 F62 Dy6 165.69(12) . . ?
Dy5 F62 Dy2 95.76(10) . . ?
Dy5 F62 Dy6 94.26(8) . . ?
Dy5 F62 Dy7 98.35(10) . . ?
Dy7 F62 Dy2 94.93(9) . . ?
Dy7 F62 Dy6 93.70(9) . . ?
Dy2 F54 Dy4 135.14(12) . . ?
C76 O75 Dy1 123.8(3) . . ?
C79 O75 Dy1 126.4(3) . . ?
C79 O75 C76 109.5(4) . . ?
C82 O81 Dy4 122.0(4) . . ?
C80 O81 Dy4 123.1(4) . . ?
C80 O81 C82 107.4(5) . . ?
C86 O85 Dy4 129.0(3) . . ?
C86 O85 C89 107.8(4) . . ?
C89 O85 Dy4 123.0(3) . . ?
Dy5 F61 Dy2 123.77(13) . . ?
Dy4 F60 Dy6 136.40(14) . . ?
Dy6 F64 Dy7 126.36(14) . . ?
Dy6 F66 Dy5 125.23(12) . . ?
C91 O90 Dy1 124.0(3) . . ?
C91 O90 C94 109.4(4) . . ?
C94 O90 Dy1 124.9(3) . . ?
Dy6 C37 H37 117.0 . . ?
C38 C37 Dy6 75.4(4) . . ?
C38 C37 H37 125.8 . . ?
C38 C37 C36 108.4(6) . . ?
C36 C37 Dy6 73.8(4) . . ?
C36 C37 H37 125.8 . . ?
Dy5 C68 H68 116.2 . . ?
C67 C68 Dy5 75.2(3) . . ?
C67 C68 H68 125.1 . . ?
C69 C68 Dy5 75.3(3) . . ?
C69 C68 H68 125.1 . . ?
C69 C68 C67 109.7(6) . . ?
O90 C91 H91A 110.9 . . ?
O90 C91 H91B 110.9 . . ?
O90 C91 C92 104.4(5) . . ?
H91A C91 H91B 108.9 . . ?
C92 C91 H91A 110.9 . . ?
C92 C91 H91B 110.9 . . ?
Si49 C44 Dy7 120.2(2) . . ?
C45 C44 Dy7 73.8(3) . . ?
C45 C44 Si49 127.1(5) . . ?
C48 C44 Dy7 74.7(3) . . ?
C48 C44 Si49 128.3(4) . . ?
C48 C44 C45 104.5(5) . . ?
Dy3 C10 H10 117.1 . . ?
C11 C10 Dy3 74.1(3) . . ?
C11 C10 H10 126.2 . . ?
C11 C10 C9 107.6(5) . . ?
C9 C10 Dy3 74.7(3) . . ?
C9 C10 H10 126.2 . . ?
Si22 C17 Dy2 123.4(2) . . ?
C18 C17 Dy2 75.0(3) . . ?
C18 C17 Si22 128.2(4) . . ?
C21 C17 Dy2 72.5(3) . . ?
C21 C17 Si22 126.5(4) . . ?
C21 C17 C18 104.8(5) . . ?
Dy2 C18 H18 118.2 . . ?
C17 C18 Dy2 74.2(3) . . ?
C17 C18 H18 125.4 . . ?
C19 C18 Dy2 74.1(3) . . ?
C19 C18 C17 109.2(5) . . ?
C19 C18 H18 125.4 . . ?
Dy6 C39 H39 118.3 . . ?
C35 C39 Dy6 73.9(3) . . ?
C35 C39 H39 125.5 . . ?
C38 C39 Dy6 74.2(4) . . ?
C38 C39 H39 125.5 . . ?
C38 C39 C35 109.1(6) . . ?
O75 C76 H76A 110.9 . . ?
O75 C76 H76B 110.9 . . ?
O75 C76 C77 104.2(5) . . ?
H76A C76 H76B 108.9 . . ?
C77 C76 H76A 110.9 . . ?
C77 C76 H76B 110.9 . . ?
Dy3 C28 H28 116.6 . . ?
C27 C28 Dy3 74.9(3) . . ?
C27 C28 H28 126.0 . . ?
C27 C28 C29 108.0(5) . . ?
C29 C28 Dy3 74.6(3) . . ?
C29 C28 H28 126.0 . . ?
C76 C77 H77A 111.5 . . ?
C76 C77 H77B 111.5 . . ?
C76 C77 C78 101.6(5) . . ?
H77A C77 H77B 109.3 . . ?
C78 C77 H77A 111.5 . . ?
C78 C77 H77B 111.5 . . ?
H93A C93 H93B 108.8 . . ?
C94 C93 H93A 110.8 . . ?
C94 C93 H93B 110.8 . . ?
C94 C93 C92 104.9(5) . . ?
C92 C93 H93A 110.8 . . ?
C92 C93 H93B 110.8 . . ?
Dy2 C20 H20 116.6 . . ?
C21 C20 Dy2 73.8(3) . . ?
C21 C20 H20 126.1 . . ?
C21 C20 C19 107.8(5) . . ?
C19 C20 Dy2 75.6(3) . . ?
C19 C20 H20 126.1 . . ?
Dy7 C46 H46 116.1 . . ?
C45 C46 Dy7 74.4(3) . . ?
C45 C46 H46 126.0 . . ?
C47 C46 Dy7 75.7(4) . . ?
C47 C46 H46 126.0 . . ?
C47 C46 C45 108.0(6) . . ?
Dy3 C12 H12 116.6 . . ?
C11 C12 Dy3 74.9(3) . . ?
C11 C12 H12 125.2 . . ?
C11 C12 C8 109.6(5) . . ?
C8 C12 Dy3 75.2(3) . . ?
C8 C12 H12 125.2 . . ?
Si22 C23 H23A 109.5 . . ?
Si22 C23 H23B 109.5 . . ?
Si22 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C77 C78 H78A 111.3 . . ?
C77 C78 H78B 111.3 . . ?
C77 C78 C79 102.4(5) . . ?
H78A C78 H78B 109.2 . . ?
C79 C78 H78A 111.3 . . ?
C79 C78 H78B 111.3 . . ?
Dy3 C11 H11 115.7 . . ?
C10 C11 Dy3 75.7(3) . . ?
C10 C11 H11 126.0 . . ?
C12 C11 Dy3 74.8(3) . . ?
C12 C11 C10 108.1(5) . . ?
C12 C11 H11 126.0 . . ?
Si72 C67 Dy5 120.6(2) . . ?
C68 C67 Dy5 73.9(3) . . ?
C68 C67 Si72 127.0(5) . . ?
C71 C67 Dy5 74.1(3) . . ?
C71 C67 Si72 128.1(5) . . ?
C71 C67 C68 104.7(5) . . ?
Si13 C8 Dy3 126.6(2) . . ?
C12 C8 Dy3 73.9(3) . . ?
C12 C8 Si13 126.8(4) . . ?
C9 C8 Dy3 74.7(3) . . ?
C9 C8 Si13 126.8(4) . . ?
C9 C8 C12 105.0(4) . . ?
Dy2 C21 H21 114.8 . . ?
C17 C21 Dy2 76.7(3) . . ?
C17 C21 H21 124.8 . . ?
C20 C21 Dy2 75.7(3) . . ?
C20 C21 C17 110.4(5) . . ?
C20 C21 H21 124.8 . . ?
Dy3 C9 H9 116.9 . . ?
C10 C9 Dy3 75.0(3) . . ?
C10 C9 C8 109.6(5) . . ?
C10 C9 H9 125.2 . . ?
C8 C9 Dy3 74.7(3) . . ?
C8 C9 H9 125.2 . . ?
Dy5 C70 H70 115.7 . . ?
C71 C70 Dy5 75.0(3) . . ?
C71 C70 H70 125.8 . . ?
C69 C70 Dy5 75.6(4) . . ?
C69 C70 H70 125.8 . . ?
C69 C70 C71 108.4(6) . . ?
Si13 C14 H14A 109.5 . . ?
Si13 C14 H14B 109.5 . . ?
Si13 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si31 C26 Dy3 126.9(2) . . ?
C30 C26 Dy3 73.8(3) . . ?
C30 C26 Si31 126.5(4) . . ?
C27 C26 Dy3 74.1(3) . . ?
C27 C26 Si31 127.6(5) . . ?
C27 C26 C30 104.5(5) . . ?
Si13 C15 H15A 109.5 . . ?
Si13 C15 H15B 109.5 . . ?
Si13 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Dy3 C30 H30 116.4 . . ?
C26 C30 Dy3 75.2(3) . . ?
C26 C30 H30 125.2 . . ?
C29 C30 Dy3 75.1(3) . . ?
C29 C30 C26 109.5(5) . . ?
C29 C30 H30 125.2 . . ?
Dy7 C45 H45 116.3 . . ?
C44 C45 Dy7 75.2(3) . . ?
C44 C45 H45 125.4 . . ?
C46 C45 Dy7 75.0(3) . . ?
C46 C45 C44 109.2(6) . . ?
C46 C45 H45 125.4 . . ?
Dy3 C27 H27 116.5 . . ?
C28 C27 Dy3 75.2(3) . . ?
C28 C27 C26 109.9(6) . . ?
C28 C27 H27 125.0 . . ?
C26 C27 Dy3 75.1(3) . . ?
C26 C27 H27 125.0 . . ?
Si40 C35 Dy6 121.2(3) . . ?
C39 C35 Dy6 75.1(3) . . ?
C39 C35 Si40 126.8(5) . . ?
C36 C35 Dy6 73.1(3) . . ?
C36 C35 Si40 127.4(5) . . ?
C36 C35 C39 105.5(5) . . ?
Dy5 C71 H71 116.7 . . ?
C67 C71 Dy5 75.3(3) . . ?
C67 C71 H71 125.6 . . ?
C70 C71 Dy5 74.4(3) . . ?
C70 C71 C67 108.8(6) . . ?
C70 C71 H71 125.6 . . ?
Dy3 C29 H29 116.2 . . ?
C28 C29 Dy3 75.1(3) . . ?
C28 C29 H29 126.0 . . ?
C30 C29 Dy3 74.9(3) . . ?
C30 C29 C28 108.0(5) . . ?
C30 C29 H29 126.0 . . ?
Dy7 C48 H48 117.1 . . ?
C44 C48 Dy7 74.5(3) . . ?
C44 C48 H48 124.8 . . ?
C47 C48 Dy7 75.4(3) . . ?
C47 C48 C44 110.4(6) . . ?
C47 C48 H48 124.8 . . ?
O90 C94 C93 106.9(5) . . ?
O90 C94 H94A 110.3 . . ?
O90 C94 H94B 110.3 . . ?
C93 C94 H94A 110.3 . . ?
C93 C94 H94B 110.3 . . ?
H94A C94 H94B 108.6 . . ?
Dy6 C38 H38 116.3 . . ?
C37 C38 Dy6 74.3(4) . . ?
C37 C38 C39 108.3(6) . . ?
C37 C38 H38 125.8 . . ?
C39 C38 Dy6 75.6(4) . . ?
C39 C38 H38 125.8 . . ?
Dy1 F95 Dy5 132.34(12) . . ?
Dy6 F59 Dy1 134.68(13) . . ?
Dy5 F65 Dy7 121.70(13) . . ?
Dy2 C19 H19 116.5 . . ?
C18 C19 Dy2 75.6(3) . . ?
C18 C19 H19 126.1 . . ?
C20 C19 Dy2 73.9(3) . . ?
C20 C19 C18 107.8(6) . . ?
C20 C19 H19 126.1 . . ?
O85 C86 H86A 110.7 . . ?
O85 C86 H86B 110.7 . . ?
O85 C86 C87 105.2(5) . . ?
H86A C86 H86B 108.8 . . ?
C87 C86 H86A 110.7 . . ?
C87 C86 H86B 110.7 . . ?
O75 C79 C78 105.0(5) . . ?
O75 C79 H79A 110.7 . . ?
O75 C79 H79B 110.7 . . ?
C78 C79 H79A 110.7 . . ?
C78 C79 H79B 110.7 . . ?
H79A C79 H79B 108.8 . . ?
Si13 C16 H16A 109.5 . . ?
Si13 C16 H16B 109.5 . . ?
Si13 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Dy7 C47 H47 117.1 . . ?
C46 C47 Dy7 74.2(4) . . ?
C46 C47 H47 126.1 . . ?
C48 C47 Dy7 74.7(3) . . ?
C48 C47 C46 107.9(6) . . ?
C48 C47 H47 126.1 . . ?
Si31 C32 H32A 109.5 . . ?
Si31 C32 H32B 109.5 . . ?
Si31 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
Dy6 C36 H36 115.2 . . ?
C37 C36 Dy6 75.4(3) . . ?
C37 C36 C35 108.7(6) . . ?
C37 C36 H36 125.7 . . ?
C35 C36 Dy6 75.8(3) . . ?
C35 C36 H36 125.7 . . ?
Si40 C41 H41A 109.5 . . ?
Si40 C41 H41B 109.5 . . ?
Si40 C41 H41C 109.5 . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
Si22 C24 H24A 109.5 . . ?
Si22 C24 H24B 109.5 . . ?
Si22 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Dy5 C69 H69 116.8 . . ?
C68 C69 Dy5 74.8(3) . . ?
C68 C69 H69 125.8 . . ?
C70 C69 Dy5 74.7(3) . . ?
C70 C69 C68 108.4(6) . . ?
C70 C69 H69 125.8 . . ?
Si22 C25 H25A 109.5 . . ?
Si22 C25 H25B 109.5 . . ?
Si22 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
O85 C89 H89A 110.3 . . ?
O85 C89 H89B 110.3 . . ?
O85 C89 C88 107.0(5) . . ?
H89A C89 H89B 108.6 . . ?
C88 C89 H89A 110.3 . . ?
C88 C89 H89B 110.3 . . ?
H84A C84 H84B 109.2 . . ?
C83 C84 H84A 111.3 . . ?
C83 C84 H84B 111.3 . . ?
C80 C84 H84A 111.3 . . ?
C80 C84 H84B 111.3 . . ?
C80 C84 C83 102.5(6) . . ?
C89 C88 H88A 111.0 . . ?
C89 C88 H88B 111.0 . . ?
C89 C88 C87 103.7(6) . . ?
H88A C88 H88B 109.0 . . ?
C87 C88 H88A 111.0 . . ?
C87 C88 H88B 111.0 . . ?
C91 C92 C93 104.7(6) . . ?
C91 C92 H92A 110.8 . . ?
C91 C92 H92B 110.8 . . ?
C93 C92 H92A 110.8 . . ?
C93 C92 H92B 110.8 . . ?
H92A C92 H92B 108.9 . . ?
Si40 C42 H42A 109.5 . . ?
Si40 C42 H42B 109.5 . . ?
Si40 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
Si40 C43 H43A 109.5 . . ?
Si40 C43 H43B 109.5 . . ?
Si40 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
O81 C82 H82A 110.4 . . ?
O81 C82 H82B 110.4 . . ?
H82A C82 H82B 108.6 . . ?
C83 C82 O81 106.6(7) . . ?
C83 C82 H82A 110.4 . . ?
C83 C82 H82B 110.4 . . ?
C84 C83 H83A 111.1 . . ?
C84 C83 H83B 111.1 . . ?
C82 C83 C84 103.3(7) . . ?
C82 C83 H83A 111.1 . . ?
C82 C83 H83B 111.1 . . ?
H83A C83 H83B 109.1 . . ?
Si31 C33 H33A 109.5 . . ?
Si31 C33 H33B 109.5 . . ?
Si31 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
Si72 C74 H74A 109.5 . . ?
Si72 C74 H74B 109.5 . . ?
Si72 C74 H74C 109.5 . . ?
H74A C74 H74B 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C86 C87 C88 102.3(6) . . ?
C86 C87 H87A 111.3 . . ?
C86 C87 H87B 111.3 . . ?
C88 C87 H87A 111.3 . . ?
C88 C87 H87B 111.3 . . ?
H87A C87 H87B 109.2 . . ?
Si31 C34 H34A 109.5 . . ?
Si31 C34 H34B 109.5 . . ?
Si31 C34 H34C 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
Si49 C50 H50A 109.5 . . ?
Si49 C50 H50B 109.5 . . ?
Si49 C50 H50C 109.5 . . ?
H50A C50 H50B 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
Si49 C51 H51A 109.5 . . ?
Si49 C51 H51B 109.5 . . ?
Si49 C51 H51C 109.5 . . ?
H51A C51 H51B 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
Si49 C52 H52A 109.5 . . ?
Si49 C52 H52B 109.5 . . ?
Si49 C52 H52C 109.5 . . ?
H52A C52 H52B 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
O81 C80 C84 107.0(6) . . ?
O81 C80 H80A 110.3 . . ?
O81 C80 H80B 110.3 . . ?
C84 C80 H80A 110.3 . . ?
C84 C80 H80B 110.3 . . ?
H80A C80 H80B 108.6 . . ?
Si72 C73 H73A 109.5 . . ?
Si72 C73 H73B 109.5 . . ?
Si72 C73 H73C 109.5 . . ?
H73A C73 H73B 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?
Si72 C2 H2A 109.5 . . ?
Si72 C2 H2B 109.5 . . ?
Si72 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O75 C76 C77 -154.5(3) . . . . ?
Dy1 O75 C79 C78 -179.7(3) . . . . ?
Dy1 O90 C91 C92 -170.7(5) . . . . ?
Dy1 O90 C94 C93 -171.8(4) . . . . ?
Dy2 C17 C18 C19 66.4(4) . . . . ?
Dy2 C17 C21 C20 -68.9(4) . . . . ?
Dy2 C18 C19 C20 67.5(4) . . . . ?
Dy2 C20 C21 C17 69.6(4) . . . . ?
Dy2 C20 C19 C18 -68.6(4) . . . . ?
Dy3 C10 C11 C12 -68.4(4) . . . . ?
Dy3 C10 C9 C8 67.3(4) . . . . ?
Dy3 C28 C27 C26 67.8(4) . . . . ?
Dy3 C28 C29 C30 -68.2(4) . . . . ?
Dy3 C12 C11 C10 69.0(4) . . . . ?
Dy3 C12 C8 Si13 124.0(4) . . . . ?
Dy3 C12 C8 C9 -68.8(4) . . . . ?
Dy3 C8 C9 C10 -67.5(4) . . . . ?
Dy3 C26 C30 C29 67.9(4) . . . . ?
Dy3 C26 C27 C28 -67.8(4) . . . . ?
Dy3 C30 C29 C28 68.4(4) . . . . ?
Dy4 O81 C82 C83 163.5(5) . . . . ?
Dy4 O81 C80 C84 -139.7(4) . . . . ?
Dy4 O85 C86 C87 155.6(5) . . . . ?
Dy4 O85 C89 C88 -178.9(5) . . . . ?
Dy5 C68 C67 Si72 -116.4(4) . . . . ?
Dy5 C68 C67 C71 68.3(4) . . . . ?
Dy5 C68 C69 C70 -67.7(4) . . . . ?
Dy5 C67 C71 C70 67.5(4) . . . . ?
Dy5 C70 C71 C67 -68.0(4) . . . . ?
Dy5 C70 C69 C68 67.8(4) . . . . ?
Dy6 C37 C38 C39 -68.6(5) . . . . ?
Dy6 C37 C36 C35 69.2(4) . . . . ?
Dy6 C39 C35 Si40 118.1(4) . . . . ?
Dy6 C39 C35 C36 -67.3(4) . . . . ?
Dy6 C39 C38 C37 67.8(5) . . . . ?
Dy6 C35 C36 C37 -68.9(4) . . . . ?
Dy7 C44 C45 C46 68.0(4) . . . . ?
Dy7 C44 C48 C47 -67.5(4) . . . . ?
Dy7 C46 C45 C44 -68.1(4) . . . . ?
Dy7 C46 C47 C48 67.7(4) . . . . ?
Dy7 C48 C47 C46 -67.3(4) . . . . ?
Si13 C8 C9 Dy3 -124.5(4) . . . . ?
Si13 C8 C9 C10 167.9(4) . . . . ?
Si22 C17 C18 Dy2 120.9(4) . . . . ?
Si22 C17 C18 C19 -172.7(4) . . . . ?
Si22 C17 C21 Dy2 -118.9(4) . . . . ?
Si22 C17 C21 C20 172.1(4) . . . . ?
Si31 C26 C30 Dy3 124.2(4) . . . . ?
Si31 C26 C30 C29 -167.9(4) . . . . ?
Si31 C26 C27 Dy3 -124.6(4) . . . . ?
Si31 C26 C27 C28 167.6(4) . . . . ?
Si40 C35 C36 Dy6 -116.7(4) . . . . ?
Si40 C35 C36 C37 174.4(4) . . . . ?
Si49 C44 C45 Dy7 115.9(4) . . . . ?
Si49 C44 C45 C46 -176.1(4) . . . . ?
Si49 C44 C48 Dy7 -116.6(4) . . . . ?
Si49 C44 C48 C47 175.9(4) . . . . ?
Si72 C67 C71 Dy5 116.7(4) . . . . ?
Si72 C67 C71 C70 -175.8(4) . . . . ?
O75 C76 C77 C78 -37.2(6) . . . . ?
O81 C82 C83 C84 -30.8(8) . . . . ?
O85 C86 C87 C88 35.1(8) . . . . ?
O85 C89 C88 C87 24.3(9) . . . . ?
O90 C91 C92 C93 -31.4(8) . . . . ?
C68 C67 C71 Dy5 -68.1(4) . . . . ?
C68 C67 C71 C70 -0.6(6) . . . . ?
C91 O90 C94 C93 -6.2(7) . . . . ?
C44 C48 C47 Dy7 67.0(4) . . . . ?
C44 C48 C47 C46 -0.4(7) . . . . ?
C17 C18 C19 Dy2 -66.4(4) . . . . ?
C17 C18 C19 C20 1.0(6) . . . . ?
C18 C17 C21 Dy2 68.6(4) . . . . ?
C18 C17 C21 C20 -0.3(6) . . . . ?
C39 C35 C36 Dy6 68.7(4) . . . . ?
C39 C35 C36 C37 -0.2(6) . . . . ?
C76 O75 C79 C78 6.3(6) . . . . ?
C76 C77 C78 C79 40.7(6) . . . . ?
C77 C78 C79 O75 -29.3(6) . . . . ?
C12 C8 C9 Dy3 68.2(3) . . . . ?
C12 C8 C9 C10 0.7(6) . . . . ?
C23 Si22 C17 Dy2 -71.3(4) . . . . ?
C23 Si22 C17 C18 -168.3(5) . . . . ?
C23 Si22 C17 C21 20.9(5) . . . . ?
C11 C10 C9 Dy3 -67.3(4) . . . . ?
C11 C10 C9 C8 0.0(6) . . . . ?
C11 C12 C8 Dy3 67.7(4) . . . . ?
C11 C12 C8 Si13 -168.4(4) . . . . ?
C11 C12 C8 C9 -1.1(6) . . . . ?
C67 C68 C69 Dy5 68.0(4) . . . . ?
C67 C68 C69 C70 0.3(7) . . . . ?
C8 C12 C11 Dy3 -67.9(4) . . . . ?
C8 C12 C11 C10 1.2(6) . . . . ?
C21 C17 C18 Dy2 -66.8(3) . . . . ?
C21 C17 C18 C19 -0.4(6) . . . . ?
C21 C20 C19 Dy2 67.4(4) . . . . ?
C21 C20 C19 C18 -1.2(6) . . . . ?
C9 C10 C11 Dy3 67.7(4) . . . . ?
C9 C10 C11 C12 -0.7(6) . . . . ?
C14 Si13 C8 Dy3 8.9(5) . . . . ?
C14 Si13 C8 C12 -88.1(5) . . . . ?
C14 Si13 C8 C9 107.3(5) . . . . ?
C26 C30 C29 Dy3 -68.0(4) . . . . ?
C26 C30 C29 C28 0.4(6) . . . . ?
C15 Si13 C8 Dy3 128.7(3) . . . . ?
C15 Si13 C8 C12 31.6(5) . . . . ?
C15 Si13 C8 C9 -133.0(5) . . . . ?
C30 C26 C27 Dy3 68.1(3) . . . . ?
C30 C26 C27 C28 0.3(6) . . . . ?
C45 C44 C48 Dy7 68.3(4) . . . . ?
C45 C44 C48 C47 0.8(6) . . . . ?
C45 C46 C47 Dy7 -68.0(4) . . . . ?
C45 C46 C47 C48 -0.2(7) . . . . ?
C27 C28 C29 Dy3 68.0(4) . . . . ?
C27 C28 C29 C30 -0.2(6) . . . . ?
C27 C26 C30 Dy3 -68.3(3) . . . . ?
C27 C26 C30 C29 -0.4(6) . . . . ?
C35 C39 C38 Dy6 -66.2(4) . . . . ?
C35 C39 C38 C37 1.5(7) . . . . ?
C71 C70 C69 Dy5 -68.5(4) . . . . ?
C71 C70 C69 C68 -0.7(7) . . . . ?
C29 C28 C27 Dy3 -67.8(4) . . . . ?
C29 C28 C27 C26 -0.1(6) . . . . ?
C48 C44 C45 Dy7 -68.9(4) . . . . ?
C48 C44 C45 C46 -0.9(6) . . . . ?
C94 O90 C91 C92 23.5(7) . . . . ?
C94 C93 C92 C91 27.6(8) . . . . ?
C38 C37 C36 Dy6 -68.1(5) . . . . ?
C38 C37 C36 C35 1.1(7) . . . . ?
C38 C39 C35 Dy6 66.5(4) . . . . ?
C38 C39 C35 Si40 -175.4(4) . . . . ?
C38 C39 C35 C36 -0.8(6) . . . . ?
C19 C20 C21 Dy2 -68.6(4) . . . . ?
C19 C20 C21 C17 1.0(6) . . . . ?
C86 O85 C89 C88 -2.4(8) . . . . ?
C79 O75 C76 C77 19.6(6) . . . . ?
C16 Si13 C8 Dy3 -112.5(4) . . . . ?
C16 Si13 C8 C12 150.4(5) . . . . ?
C16 Si13 C8 C9 -14.2(6) . . . . ?
C47 C46 C45 Dy7 68.8(4) . . . . ?
C47 C46 C45 C44 0.8(7) . . . . ?
C32 Si31 C26 Dy3 2.9(5) . . . . ?
C32 Si31 C26 C30 -94.1(5) . . . . ?
C32 Si31 C26 C27 101.2(5) . . . . ?
C36 C37 C38 Dy6 67.0(5) . . . . ?
C36 C37 C38 C39 -1.6(8) . . . . ?
C41 Si40 C35 Dy6 -72.7(4) . . . . ?
C41 Si40 C35 C39 -167.2(5) . . . . ?
C41 Si40 C35 C36 19.3(6) . . . . ?
C24 Si22 C17 Dy2 168.9(3) . . . . ?
C24 Si22 C17 C18 71.9(5) . . . . ?
C24 Si22 C17 C21 -98.9(5) . . . . ?
C69 C68 C67 Dy5 -68.1(4) . . . . ?
C69 C68 C67 Si72 175.5(4) . . . . ?
C69 C68 C67 C71 0.2(6) . . . . ?
C69 C70 C71 Dy5 68.9(4) . . . . ?
C69 C70 C71 C67 0.8(6) . . . . ?
C25 Si22 C17 Dy2 50.5(4) . . . . ?
C25 Si22 C17 C18 -46.6(6) . . . . ?
C25 Si22 C17 C21 142.7(5) . . . . ?
C89 O85 C86 C87 -20.7(8) . . . . ?
C89 C88 C87 C86 -36.1(9) . . . . ?
C92 C93 C94 O90 -13.6(7) . . . . ?
C42 Si40 C35 Dy6 49.2(4) . . . . ?
C42 Si40 C35 C39 -45.3(6) . . . . ?
C42 Si40 C35 C36 141.2(5) . . . . ?
C43 Si40 C35 Dy6 167.5(3) . . . . ?
C43 Si40 C35 C39 72.9(6) . . . . ?
C43 Si40 C35 C36 -100.6(5) . . . . ?
C82 O81 C80 C84 10.5(8) . . . . ?
C83 C84 C80 O81 -29.0(8) . . . . ?
C33 Si31 C26 Dy3 125.9(4) . . . . ?
C33 Si31 C26 C30 28.9(6) . . . . ?
C33 Si31 C26 C27 -135.7(5) . . . . ?
C74 Si72 C67 Dy5 -171.8(4) . . . . ?
C74 Si72 C67 C68 -79.5(6) . . . . ?
C74 Si72 C67 C71 94.7(6) . . . . ?
C34 Si31 C26 Dy3 -117.4(4) . . . . ?
C34 Si31 C26 C30 145.6(5) . . . . ?
C34 Si31 C26 C27 -19.1(6) . . . . ?
C50 Si49 C44 Dy7 -35.6(5) . . . . ?
C50 Si49 C44 C45 -127.6(6) . . . . ?
C50 Si49 C44 C48 58.3(6) . . . . ?
C51 Si49 C44 Dy7 -156.9(4) . . . . ?
C51 Si49 C44 C45 111.1(6) . . . . ?
C51 Si49 C44 C48 -63.0(7) . . . . ?
C52 Si49 C44 Dy7 85.5(5) . . . . ?
C52 Si49 C44 C45 -6.5(6) . . . . ?
C52 Si49 C44 C48 179.5(6) . . . . ?
C80 O81 C82 C83 12.9(8) . . . . ?
C80 C84 C83 C82 36.2(8) . . . . ?
C73 Si72 C67 Dy5 71.4(5) . . . . ?
C73 Si72 C67 C68 163.8(6) . . . . ?
C73 Si72 C67 C71 -22.0(6) . . . . ?
C2 Si72 C67 Dy5 -47.8(7) . . . . ?
C2 Si72 C67 C68 44.6(8) . . . . ?
C2 Si72 C67 C71 -141.2(7) . . . . ?

_shelx_SHELXL_version_number     2014/7

_olex2_submission_special_instructions 'No special instructions were received'
# SQUEEZE RESULTS (Version = 230916)
# Note: Data are Listed for all Voids in the P1 Unit Cell
# i.e. Centre of Gravity, Solvent Accessible Volume,
# Recovered number of Electrons in the Void and
# Details about the Squeezed Material
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.126 0.921 0.614 19 0 ' '
2 0.102 0.725 0.975 14 0 ' '
3 0.178 0.879 0.458 17 0 ' '
4 0.500 0.500 0.500 113 9 ' '
5 0.403 0.810 0.083 7 0 ' '
6 0.597 0.190 0.917 8 0 ' '
7 0.822 0.121 0.542 17 0 ' '
8 0.874 0.079 0.386 18 0 ' '
9 0.898 0.275 0.025 14 0 ' '
_platon_squeeze_void_probe_radius 1.20
_platon_squeeze_details          ?
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1_sq
_database_code_depnum_ccdc_archive 'CCDC 2121109'
loop_
_audit_author_name
_audit_author_address
'Yuan Qiong'
;Peking University
China
;
_audit_update_record             
;
2021-11-09 deposited with the CCDC.	2022-04-12 downloaded from the CCDC.
;
_audit_creation_date             2017-03-29
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.08.25 svn.r3337 for OlexSys, GUI svn.r5227)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C56 H94 Dy4 F6 O2 Si6'
_chemical_formula_sum            'C56 H94 Dy4 F6 O2 Si6'
_chemical_formula_weight         1731.85
_chemical_melting_point          ?
_chemical_oxdiff_formula         'c72 h120 f6 si8 dy4 o2'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.8238(3)
_cell_length_b                   25.4525(6)
_cell_length_c                   22.0905(5)
_cell_angle_alpha                90
_cell_angle_beta                 90.064(2)
_cell_angle_gamma                90
_cell_volume                     7772.5(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    20609
_cell_measurement_temperature    180.00(10)
_cell_measurement_theta_max      28.2410
_cell_measurement_theta_min      3.1190
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    3.939
_exptl_absorpt_correction_T_max  0.765
_exptl_absorpt_correction_T_min  0.638
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
'CrysAlisPro, Agilent Technologies, Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET) (compiled Aug 13 2014,18:06:01) Numerical absorption correction based on gaussian integration over a multifaceted crystal model Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.480
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3392
_exptl_crystal_size_max          0.1668
_exptl_crystal_size_mid          0.0999
_exptl_crystal_size_min          0.0928
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0729
_diffrn_reflns_av_unetI/netI     0.0642
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            81731
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.484
_diffrn_reflns_theta_min         3.475
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      180.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.3914
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega   15.00   40.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191  -38.0000 -180.0000 25

#__ type_ start__ end____ width___ exp.time_
  2 omega   55.00   81.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191   57.0000  -30.0000 26

#__ type_ start__ end____ width___ exp.time_
  3 omega   24.00   50.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -       13.6191   57.0000  -30.0000 26

#__ type_ start__ end____ width___ exp.time_
  4 omega   27.00   57.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -14.7128   38.0000   60.0000 30

#__ type_ start__ end____ width___ exp.time_
  5 omega   -8.00   17.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -14.7128  -99.0000 -180.0000 25

#__ type_ start__ end____ width___ exp.time_
  6 omega  -88.00   15.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -14.7128  -57.0000   60.0000 103

#__ type_ start__ end____ width___ exp.time_
  7 omega  -20.00   61.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -14.7128   38.0000 -150.0000 81

#__ type_ start__ end____ width___ exp.time_
  8 omega  -90.00   16.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
    -      -14.7128  -77.0000  -60.0000 106
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0236807000
_diffrn_orient_matrix_UB_12      0.0049461000
_diffrn_orient_matrix_UB_13      0.0278881000
_diffrn_orient_matrix_UB_21      0.0163073000
_diffrn_orient_matrix_UB_22      0.0264167000
_diffrn_orient_matrix_UB_23      -0.0007966000
_diffrn_orient_matrix_UB_31      -0.0424897000
_diffrn_orient_matrix_UB_32      0.0073768000
_diffrn_orient_matrix_UB_33      -0.0158958000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                14409
_reflns_number_total             17778
_reflns_odcompleteness_completeness 99.79
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
'CrysAlisPro, Agilent Technologies, Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET) (compiled Aug 13 2014,18:06:01)'
_computing_data_collection       
'CrysAlisPro, Agilent Technologies, Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET) (compiled Aug 13 2014,18:06:01)'
_computing_data_reduction        
'CrysAlisPro, Agilent Technologies, Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET) (compiled Aug 13 2014,18:06:01)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         2.198
_refine_diff_density_min         -1.704
_refine_diff_density_rms         0.210
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     686
_refine_ls_number_reflns         17778
_refine_ls_number_restraints     18
_refine_ls_R_factor_all          0.0781
_refine_ls_R_factor_gt           0.0545
_refine_ls_restrained_S_all      1.056
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0665P)²+71.4972P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1333
_refine_ls_wR_factor_ref         0.1535
_refine_special_details          
;
 Refined as a 2-component twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.7682(9) 0.2318(9)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3. Uiso/Uaniso restraints and constraints
Uanis(C81) \\sim Ueq, Uanis(C82) \\sim Ueq, Uanis(C83) \\sim Ueq: with sigma of
0.005 and sigma for terminal atoms of 0.005
4.a Secondary CH2 refined with riding coordinates:
 C52(H52A,H52B), C50(H50A,H50B), C51(H51A,H51B), C80(H80A,H80B), C83(H83A,
 H83B), C81(H81A,H81B), C82(H82A,H82B), C91(H91A,H91B)
4.b Aromatic/amide H refined with riding coordinates:
 C6(H6), C11(H11), C12(H12), C26(H26), C5(H5), C13(H13), C4(H4), C9(H9),
 C3(H3), C10(H10), C7(H7), C14(H14), C1(H1), C22(H22), C28(H28), C34(H34),
 C35(H35), C36(H36), C37(H37), C41(H41), C43(H43), C30(H30), C47(H47), C27(H27)
4.c Idealised Me refined as rotating group:
 C45(H45A,H45B,H45C), C32(H32A,H32B,H32C), C23(H23A,H23B,H23C), C31(H31A,H31B,
 H31C), C33(H33A,H33B,H33C), C25(H25A,H25B,H25C), C38(H38A,H38B,H38C), C42(H42A,
 H42B,H42C), C24(H24A,H24B,H24C), C46(H46A,H46B,H46C), C48(H48A,H48B,H48C),
 C39(H39A,H39B,H39C), C49(H49A,H49B,H49C), C88(H88A,H88B,H88C), C84(H84A,H84B,
 H84C), C87(H87A,H87B,H87C), C86(H86A,H86B,H86C), C85(H85A,H85B,H85C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.22537(3) 0.27001(2) 0.27207(2) 0.02427(10) Uani 1 1 d . . . . .
Dy3 Dy 0.22417(4) 0.20143(2) 0.10126(2) 0.02584(11) Uani 1 1 d . . . . .
Dy4 Dy 0.22807(3) 0.18606(2) 0.43557(2) 0.02531(11) Uani 1 1 d . . . . .
Dy2 Dy 0.32460(3) 0.13652(2) 0.26317(2) 0.02496(11) Uani 1 1 d . . . . .
Si1 Si 0.2413(2) 0.31833(12) 0.53219(15) 0.0349(7) Uani 1 1 d . . . . .
Si6 Si 0.5002(2) 0.32891(12) 0.27323(14) 0.0306(6) Uani 1 1 d . . . . .
Si2 Si 0.4492(2) 0.02051(13) 0.36047(17) 0.0400(8) Uani 1 1 d . . . . .
Si5 Si 0.2457(2) 0.33413(13) 0.00763(16) 0.0388(7) Uani 1 1 d . . . . .
Si4 Si 0.1442(2) 0.08546(13) -0.01601(16) 0.0383(7) Uani 1 1 d . . . . .
Si3 Si 0.1619(2) 0.07393(13) 0.56343(16) 0.0395(7) Uani 1 1 d . . . . .
F3 F 0.2032(4) 0.2595(2) 0.1733(3) 0.0325(14) Uani 1 1 d . . . . .
F5 F 0.1997(4) 0.2476(2) 0.3682(3) 0.0310(13) Uani 1 1 d . . . . .
F2 F 0.3578(4) 0.2218(2) 0.2701(3) 0.0341(14) Uani 1 1 d . . . . .
F1 F 0.1874(4) 0.1835(2) 0.2658(3) 0.0312(13) Uani 1 1 d . . . . .
F4 F 0.2901(4) 0.1473(2) 0.1652(3) 0.0328(13) Uani 1 1 d . . . . .
F6 F 0.2907(4) 0.1379(2) 0.3628(3) 0.0328(14) Uani 1 1 d . . . . .
O1 O 0.2142(5) 0.0649(3) 0.2495(4) 0.0395(19) Uani 1 1 d . . . . .
O10 O 0.0526(5) 0.2826(3) 0.2707(4) 0.0375(18) Uani 1 1 d . . . . .
C6 C 0.0342(8) 0.2100(4) 0.0796(5) 0.034(2) Uani 1 1 d . . . . .
H6 H 0.0048 0.2436 0.0830 0.040 Uiso 1 1 calc R . . . .
C11 C 0.0405(8) 0.1897(5) 0.4587(6) 0.041(3) Uani 1 1 d . . . . .
H11 H 0.0097 0.2225 0.4519 0.049 Uiso 1 1 calc R . . . .
C12 C 0.3758(8) 0.1753(5) 0.5133(5) 0.036(3) Uani 1 1 d . . . . .
H12 H 0.3910 0.1406 0.5262 0.043 Uiso 1 1 calc R . . . .
C26 C 0.2188(9) 0.3699(4) 0.3113(6) 0.039(3) Uani 1 1 d . . . . .
H26 H 0.1664 0.3777 0.3376 0.047 Uiso 1 1 calc R . . . .
C5 C 0.0749(7) 0.1885(5) 0.0264(5) 0.034(3) Uani 1 1 d . . . . .
H5 H 0.0793 0.2056 -0.0117 0.041 Uiso 1 1 calc R . . . .
C13 C 0.3105(7) 0.2101(4) 0.5420(5) 0.033(2) Uani 1 1 d . . . . .
H13 H 0.2746 0.2026 0.5776 0.039 Uiso 1 1 calc R . . . .
C4 C 0.5170(7) 0.1412(5) 0.2434(6) 0.038(3) Uani 1 1 d . . . . .
H4 H 0.5421 0.1750 0.2338 0.045 Uiso 1 1 calc R . . . .
C9 C 0.0824(7) 0.1733(5) 0.5126(5) 0.032(2) Uani 1 1 d . . . . .
H9 H 0.0855 0.1933 0.5489 0.039 Uiso 1 1 calc R . . . .
C2 C 0.4658(8) 0.0692(4) 0.2977(5) 0.033(2) Uani 1 1 d . . . . .
C3 C 0.5065(8) 0.1198(5) 0.3011(6) 0.038(3) Uani 1 1 d . . . . .
H3 H 0.5244 0.1370 0.3376 0.045 Uiso 1 1 calc R . . . .
C10 C 0.1006(8) 0.1074(5) 0.4429(5) 0.038(3) Uani 1 1 d . . . . .
H10 H 0.1178 0.0754 0.4237 0.045 Uiso 1 1 calc R . . . .
C7 C 0.0450(8) 0.1727(5) 0.1269(6) 0.041(3) Uani 1 1 d . . . . .
H7 H 0.0272 0.1771 0.1681 0.049 Uiso 1 1 calc R . . . .
C14 C 0.3716(8) 0.2516(5) 0.4597(5) 0.035(2) Uani 1 1 d . . . . .
H14 H 0.3844 0.2772 0.4295 0.041 Uiso 1 1 calc R . . . .
C1 C 0.4518(8) 0.0595(5) 0.2347(6) 0.044(3) Uani 1 1 d . . . . .
H1 H 0.4253 0.0285 0.2176 0.053 Uiso 1 1 calc R . . . .
C8 C 0.3072(7) 0.2717(4) 0.0290(5) 0.031(2) Uani 1 1 d . . . . .
C21 C 0.1080(8) 0.1368(5) 0.0397(5) 0.034(2) Uani 1 1 d . . . . .
C22 C 0.0870(8) 0.1280(5) 0.1006(6) 0.038(3) Uani 1 1 d . . . . .
H22 H 0.0995 0.0961 0.1215 0.045 Uiso 1 1 calc R . . . .
C28 C 0.3086(8) 0.3580(4) 0.2274(6) 0.035(2) Uani 1 1 d . . . . .
H28 H 0.3283 0.3566 0.1862 0.042 Uiso 1 1 calc R . . . .
C34 C 0.3722(7) 0.2650(5) 0.0783(5) 0.033(2) Uani 1 1 d . . . . .
H34 H 0.3861 0.2908 0.1082 0.040 Uiso 1 1 calc R . . . .
C35 C 0.4119(7) 0.2151(5) 0.0759(6) 0.036(3) Uani 1 1 d . . . . .
H35 H 0.4580 0.2015 0.1038 0.043 Uiso 1 1 calc R . . . .
C36 C 0.3737(8) 0.1875(5) 0.0260(6) 0.037(3) Uani 1 1 d . . . . .
H36 H 0.3881 0.1525 0.0141 0.044 Uiso 1 1 calc R . . . .
C44 C 0.1208(8) 0.1207(4) 0.5043(5) 0.033(2) Uani 1 1 d . . . . .
C45 C 0.2192(10) 0.1083(5) 0.6297(6) 0.045(3) Uani 1 1 d . . . . .
H45A H 0.2869 0.1163 0.6203 0.067 Uiso 1 1 calc GR . . . .
H45B H 0.2162 0.0856 0.6654 0.067 Uiso 1 1 calc GR . . . .
H45C H 0.1843 0.1411 0.6378 0.067 Uiso 1 1 calc GR . . . .
C29 C 0.3684(7) 0.3438(4) 0.2764(5) 0.031(2) Uani 1 1 d . . . . .
C37 C 0.3073(8) 0.2239(5) -0.0034(6) 0.039(3) Uani 1 1 d . . . . .
H37 H 0.2701 0.2167 -0.0386 0.047 Uiso 1 1 calc R . . . .
C41 C 0.4144(8) 0.2013(5) 0.4621(6) 0.042(3) Uani 1 1 d . . . . .
H41 H 0.4605 0.1875 0.4345 0.050 Uiso 1 1 calc R . . . .
C52 C 0.2215(9) 0.0202(4) 0.2068(5) 0.040(3) Uani 1 1 d . . . . .
H52A H 0.2701 -0.0056 0.2207 0.048 Uiso 1 1 calc R . . . .
H52B H 0.2393 0.0325 0.1657 0.048 Uiso 1 1 calc R . . . .
C50 C 0.1202(8) 0.0666(5) 0.2767(6) 0.045(3) Uani 1 1 d . . . . .
H50A H 0.0786 0.0930 0.2565 0.054 Uiso 1 1 calc R . . . .
H50B H 0.1246 0.0751 0.3203 0.054 Uiso 1 1 calc R . . . .
C32 C 0.5330(8) 0.2940(5) 0.2010(5) 0.038(3) Uani 1 1 d . . . . .
H32A H 0.4913 0.2632 0.1959 0.057 Uiso 1 1 calc GR . . . .
H32B H 0.6008 0.2828 0.2028 0.057 Uiso 1 1 calc GR . . . .
H32C H 0.5241 0.3179 0.1666 0.057 Uiso 1 1 calc GR . . . .
C43 C 0.0518(8) 0.1488(5) 0.4157(5) 0.037(3) Uani 1 1 d . . . . .
H43 H 0.0296 0.1496 0.3750 0.044 Uiso 1 1 calc R . . . .
C30 C 0.3100(8) 0.3525(4) 0.3287(5) 0.033(2) Uani 1 1 d . . . . .
H30 H 0.3303 0.3471 0.3693 0.039 Uiso 1 1 calc R . . . .
C23 C 0.2213(10) 0.1116(5) -0.0783(6) 0.050(3) Uani 1 1 d . . . . .
H23A H 0.1903 0.1426 -0.0961 0.075 Uiso 1 1 calc GR . . . .
H23B H 0.2292 0.0846 -0.1095 0.075 Uiso 1 1 calc GR . . . .
H23C H 0.2848 0.1214 -0.0621 0.075 Uiso 1 1 calc GR . . . .
C31 C 0.5379(9) 0.2870(6) 0.3381(6) 0.046(3) Uani 1 1 d . . . . .
H31A H 0.5342 0.3074 0.3757 0.069 Uiso 1 1 calc GR . . . .
H31B H 0.6045 0.2750 0.3319 0.069 Uiso 1 1 calc GR . . . .
H31C H 0.4948 0.2565 0.3410 0.069 Uiso 1 1 calc GR . . . .
C40 C 0.3071(8) 0.2585(4) 0.5087(5) 0.034(2) Uani 1 1 d . . . . .
C47 C 0.4836(9) 0.1037(5) 0.2025(6) 0.045(3) Uani 1 1 d . . . . .
H47 H 0.4826 0.1074 0.1597 0.054 Uiso 1 1 calc R . . . .
C27 C 0.2180(9) 0.3740(4) 0.2460(6) 0.041(3) Uani 1 1 d . . . . .
H27 H 0.1660 0.3854 0.2212 0.050 Uiso 1 1 calc R . . . .
C33 C 0.5718(8) 0.3930(5) 0.2752(6) 0.042(3) Uani 1 1 d . . . . .
H33A H 0.5614 0.4122 0.2373 0.063 Uiso 1 1 calc GR . . . .
H33B H 0.6408 0.3851 0.2798 0.063 Uiso 1 1 calc GR . . . .
H33C H 0.5499 0.4144 0.3093 0.063 Uiso 1 1 calc GR . . . .
C25 C 0.0315(10) 0.0574(6) -0.0504(7) 0.055(4) Uani 1 1 d . . . . .
H25A H -0.0114 0.0448 -0.0182 0.082 Uiso 1 1 calc GR . . . .
H25B H 0.0486 0.0281 -0.0771 0.082 Uiso 1 1 calc GR . . . .
H25C H -0.0017 0.0847 -0.0739 0.082 Uiso 1 1 calc GR . . . .
C38 C 0.1407(10) 0.3495(5) 0.0563(7) 0.051(3) Uani 1 1 d . . . . .
H38A H 0.0930 0.3211 0.0534 0.077 Uiso 1 1 calc GR . . . .
H38B H 0.1111 0.3826 0.0430 0.077 Uiso 1 1 calc GR . . . .
H38C H 0.1622 0.3531 0.0984 0.077 Uiso 1 1 calc GR . . . .
C51 C 0.0812(10) 0.0106(5) 0.2668(7) 0.054(3) Uani 1 1 d . . . . .
H51A H 0.1045 -0.0136 0.2987 0.065 Uiso 1 1 calc R . . . .
H51B H 0.0096 0.0102 0.2661 0.065 Uiso 1 1 calc R . . . .
C42 C 0.3251(9) 0.3758(5) 0.5280(7) 0.048(3) Uani 1 1 d . . . . .
H42A H 0.3806 0.3698 0.5548 0.072 Uiso 1 1 calc GR . . . .
H42B H 0.2908 0.4076 0.5406 0.072 Uiso 1 1 calc GR . . . .
H42C H 0.3479 0.3800 0.4863 0.072 Uiso 1 1 calc GR . . . .
C24 C 0.2111(11) 0.0317(5) 0.0253(7) 0.054(3) Uani 1 1 d . . . . .
H24A H 0.2558 0.0474 0.0547 0.081 Uiso 1 1 calc GR . . . .
H24B H 0.2477 0.0106 -0.0038 0.081 Uiso 1 1 calc GR . . . .
H24C H 0.1647 0.0093 0.0466 0.081 Uiso 1 1 calc GR . . . .
C46 C 0.2511(13) 0.0283(5) 0.5300(6) 0.063(4) Uani 1 1 d . . . . .
H46A H 0.2174 -0.0024 0.5136 0.095 Uiso 1 1 calc GR . . . .
H46B H 0.2969 0.0170 0.5613 0.095 Uiso 1 1 calc GR . . . .
H46C H 0.2863 0.0462 0.4975 0.095 Uiso 1 1 calc GR . . . .
C48 C 0.3196(10) -0.0008(5) 0.3689(6) 0.048(3) Uani 1 1 d . . . . .
H48A H 0.2802 0.0291 0.3817 0.073 Uiso 1 1 calc GR . . . .
H48B H 0.3155 -0.0288 0.3993 0.073 Uiso 1 1 calc GR . . . .
H48C H 0.2957 -0.0140 0.3300 0.073 Uiso 1 1 calc GR . . . .
C39 C 0.2055(14) 0.3271(7) -0.0715(7) 0.081(6) Uani 1 1 d . . . . .
H39A H 0.2395 0.2976 -0.0904 0.122 Uiso 1 1 calc GR . . . .
H39B H 0.2199 0.3595 -0.0938 0.122 Uiso 1 1 calc GR . . . .
H39C H 0.1357 0.3206 -0.0725 0.122 Uiso 1 1 calc GR . . . .
C49 C 0.4907(11) 0.0526(5) 0.4315(6) 0.053(3) Uani 1 1 d . . . . .
H49A H 0.5615 0.0514 0.4336 0.079 Uiso 1 1 calc GR . . . .
H49B H 0.4635 0.0340 0.4664 0.079 Uiso 1 1 calc GR . . . .
H49C H 0.4691 0.0892 0.4320 0.079 Uiso 1 1 calc GR . . . .
C88 C 0.1355(10) 0.3334(6) 0.4827(7) 0.056(4) Uani 1 1 d . . . . .
H88A H 0.1563 0.3341 0.4403 0.084 Uiso 1 1 calc GR . . . .
H88B H 0.1087 0.3677 0.4938 0.084 Uiso 1 1 calc GR . . . .
H88C H 0.0860 0.3063 0.4880 0.084 Uiso 1 1 calc GR . . . .
C84 C 0.5228(10) -0.0388(6) 0.3455(8) 0.063(4) Uani 1 1 d . . . . .
H84A H 0.5018 -0.0549 0.3074 0.094 Uiso 1 1 calc GR . . . .
H84B H 0.5144 -0.0639 0.3787 0.094 Uiso 1 1 calc GR . . . .
H84C H 0.5911 -0.0289 0.3425 0.094 Uiso 1 1 calc GR . . . .
C80 C -0.0037(9) 0.3035(6) 0.2205(7) 0.055(4) Uani 1 1 d . . . . .
H80A H 0.0088 0.2831 0.1832 0.066 Uiso 1 1 calc R . . . .
H80B H 0.0133 0.3407 0.2130 0.066 Uiso 1 1 calc R . . . .
C87 C 0.1986(13) 0.3097(6) 0.6129(7) 0.064(4) Uani 1 1 d . . . . .
H87A H 0.1602 0.2775 0.6161 0.096 Uiso 1 1 calc GR . . . .
H87B H 0.1587 0.3399 0.6246 0.096 Uiso 1 1 calc GR . . . .
H87C H 0.2547 0.3073 0.6399 0.096 Uiso 1 1 calc GR . . . .
C86 C 0.3308(12) 0.3872(6) 0.0140(10) 0.077(6) Uani 1 1 d . . . . .
H86A H 0.3493 0.3917 0.0565 0.116 Uiso 1 1 calc GR . . . .
H86B H 0.3011 0.4196 -0.0010 0.116 Uiso 1 1 calc GR . . . .
H86C H 0.3884 0.3791 -0.0101 0.116 Uiso 1 1 calc GR . . . .
C85 C 0.0565(12) 0.0352(7) 0.5890(9) 0.078(5) Uani 1 1 d . . . . .
H85A H 0.0030 0.0590 0.5989 0.117 Uiso 1 1 calc GR . . . .
H85B H 0.0741 0.0148 0.6250 0.117 Uiso 1 1 calc GR . . . .
H85C H 0.0363 0.0113 0.5566 0.117 Uiso 1 1 calc GR . . . .
C83 C -0.0092(17) 0.2784(10) 0.3236(12) 0.109(8) Uani 1 1 d . U . . .
H83A H 0.0140 0.3020 0.3563 0.131 Uiso 1 1 calc R . . . .
H83B H -0.0101 0.2419 0.3390 0.131 Uiso 1 1 calc R . . . .
C81 C -0.107(3) 0.2987(16) 0.2385(19) 0.187(15) Uani 1 1 d . U . . .
H81A H -0.1440 0.3301 0.2254 0.224 Uiso 1 1 calc R . . . .
H81B H -0.1367 0.2672 0.2200 0.224 Uiso 1 1 calc R . . . .
C82 C -0.108(2) 0.2946(12) 0.3028(14) 0.132(10) Uani 1 1 d . U . . .
H82A H -0.1559 0.2682 0.3157 0.159 Uiso 1 1 calc R . . . .
H82B H -0.1251 0.3288 0.3210 0.159 Uiso 1 1 calc R . . . .
C91 C 0.1219(10) -0.0031(5) 0.2071(7) 0.050(3) Uani 1 1 d . . . . .
H91A H 0.0820 0.0120 0.1741 0.060 Uiso 1 1 calc R . . . .
H91B H 0.1249 -0.0417 0.2019 0.060 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 Dy2 3.6695(6) . ?
Dy1 F3 2.218(6) . ?
Dy1 F5 2.227(6) . ?
Dy1 F2 2.204(6) . ?
Dy1 F1 2.268(5) . ?
Dy1 O10 2.409(7) . ?
Dy1 C26 2.688(11) . ?
Dy1 C28 2.704(11) . ?
Dy1 C29 2.728(10) . ?
Dy1 C30 2.708(10) . ?
Dy1 C27 2.711(12) . ?
Dy3 F3 2.192(6) . ?
Dy3 F4 2.171(6) . ?
Dy3 C6 2.677(11) . ?
Dy3 C5 2.663(11) . ?
Dy3 C7 2.645(11) . ?
Dy3 C8 2.658(11) . ?
Dy3 C21 2.671(11) . ?
Dy3 C22 2.662(11) . ?
Dy3 C34 2.658(10) . ?
Dy3 C35 2.678(10) . ?
Dy3 C36 2.677(10) . ?
Dy3 C37 2.645(12) . ?
Dy4 F5 2.197(6) . ?
Dy4 F6 2.200(6) . ?
Dy4 C11 2.645(11) . ?
Dy4 C12 2.681(11) . ?
Dy4 C13 2.682(11) . ?
Dy4 C9 2.658(10) . ?
Dy4 C10 2.672(11) . ?
Dy4 C14 2.646(11) . ?
Dy4 C44 2.698(10) . ?
Dy4 C41 2.669(11) . ?
Dy4 C43 2.651(11) . ?
Dy4 C40 2.683(11) . ?
Dy2 F2 2.224(6) . ?
Dy2 F1 2.243(6) . ?
Dy2 F4 2.233(6) . ?
Dy2 F6 2.251(6) . ?
Dy2 O1 2.397(7) . ?
Dy2 C4 2.699(10) . ?
Dy2 C2 2.707(10) . ?
Dy2 C3 2.684(10) . ?
Dy2 C1 2.707(11) . ?
Dy2 C47 2.708(12) . ?
Si1 C40 1.849(12) . ?
Si1 C42 1.868(13) . ?
Si1 C88 1.864(14) . ?
Si1 C87 1.892(14) . ?
Si6 C29 1.862(10) . ?
Si6 C32 1.883(12) . ?
Si6 C31 1.860(12) . ?
Si6 C33 1.908(11) . ?
Si2 C2 1.873(12) . ?
Si2 C48 1.881(14) . ?
Si2 C49 1.859(14) . ?
Si2 C84 1.850(14) . ?
Si5 C8 1.863(11) . ?
Si5 C38 1.851(14) . ?
Si5 C39 1.843(16) . ?
Si5 C86 1.796(15) . ?
Si4 C21 1.862(12) . ?
Si4 C23 1.865(13) . ?
Si4 C25 1.874(13) . ?
Si4 C24 1.886(14) . ?
Si3 C44 1.855(12) . ?
Si3 C45 1.879(12) . ?
Si3 C46 1.847(15) . ?
Si3 C85 1.849(15) . ?
O1 C52 1.480(13) . ?
O1 C50 1.433(14) . ?
O10 C80 1.456(15) . ?
O10 C83 1.45(2) . ?
C6 H6 0.9500 . ?
C6 C5 1.412(16) . ?
C6 C7 1.419(17) . ?
C11 H11 0.9500 . ?
C11 C9 1.388(16) . ?
C11 C43 1.418(18) . ?
C12 H12 0.9500 . ?
C12 C13 1.415(16) . ?
C12 C41 1.416(17) . ?
C26 H26 0.9500 . ?
C26 C30 1.391(16) . ?
C26 C27 1.445(19) . ?
C5 H5 0.9500 . ?
C5 C21 1.424(16) . ?
C13 H13 0.9500 . ?
C13 C40 1.435(15) . ?
C4 H4 0.9500 . ?
C4 C3 1.393(17) . ?
C4 C47 1.394(19) . ?
C9 H9 0.9500 . ?
C9 C44 1.453(16) . ?
C2 C3 1.409(16) . ?
C2 C1 1.426(17) . ?
C3 H3 0.9500 . ?
C10 H10 0.9500 . ?
C10 C44 1.425(16) . ?
C10 C43 1.388(17) . ?
C7 H7 0.9500 . ?
C7 C22 1.403(17) . ?
C14 H14 0.9500 . ?
C14 C41 1.411(18) . ?
C14 C40 1.414(16) . ?
C1 H1 0.9500 . ?
C1 C47 1.402(18) . ?
C8 C34 1.421(15) . ?
C8 C37 1.410(16) . ?
C21 C22 1.396(17) . ?
C22 H22 0.9500 . ?
C28 H28 0.9500 . ?
C28 C29 1.410(15) . ?
C28 C27 1.380(16) . ?
C34 H34 0.9500 . ?
C34 C35 1.386(16) . ?
C35 H35 0.9500 . ?
C35 C36 1.410(17) . ?
C36 H36 0.9500 . ?
C36 C37 1.457(16) . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C29 C30 1.427(15) . ?
C37 H37 0.9500 . ?
C41 H41 0.9500 . ?
C52 H52A 0.9900 . ?
C52 H52B 0.9900 . ?
C52 C91 1.499(17) . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C50 C51 1.540(17) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C43 H43 0.9500 . ?
C30 H30 0.9500 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C47 H47 0.9500 . ?
C27 H27 0.9500 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C51 C91 1.48(2) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C88 H88A 0.9800 . ?
C88 H88B 0.9800 . ?
C88 H88C 0.9800 . ?
C84 H84A 0.9800 . ?
C84 H84B 0.9800 . ?
C84 H84C 0.9800 . ?
C80 H80A 0.9900 . ?
C80 H80B 0.9900 . ?
C80 C81 1.49(4) . ?
C87 H87A 0.9800 . ?
C87 H87B 0.9800 . ?
C87 H87C 0.9800 . ?
C86 H86A 0.9800 . ?
C86 H86B 0.9800 . ?
C86 H86C 0.9800 . ?
C85 H85A 0.9800 . ?
C85 H85B 0.9800 . ?
C85 H85C 0.9800 . ?
C83 H83A 0.9900 . ?
C83 H83B 0.9900 . ?
C83 C82 1.49(3) . ?
C81 H81A 0.9900 . ?
C81 H81B 0.9900 . ?
C81 C82 1.42(4) . ?
C82 H82A 0.9900 . ?
C82 H82B 0.9900 . ?
C91 H91A 0.9900 . ?
C91 H91B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F3 Dy1 Dy2 83.52(15) . . ?
F3 Dy1 F5 152.2(2) . . ?
F3 Dy1 F1 78.0(2) . . ?
F3 Dy1 O10 82.4(3) . . ?
F3 Dy1 C26 115.2(3) . . ?
F3 Dy1 C28 78.4(3) . . ?
F3 Dy1 C29 102.5(3) . . ?
F3 Dy1 C30 127.3(3) . . ?
F3 Dy1 C27 84.5(3) . . ?
F5 Dy1 Dy2 82.78(15) . . ?
F5 Dy1 F1 76.9(2) . . ?
F5 Dy1 O10 83.5(2) . . ?
F5 Dy1 C26 85.9(3) . . ?
F5 Dy1 C28 128.9(3) . . ?
F5 Dy1 C29 105.0(3) . . ?
F5 Dy1 C30 80.0(3) . . ?
F5 Dy1 C27 116.5(3) . . ?
F2 Dy1 Dy2 34.22(15) . . ?
F2 Dy1 F3 91.6(2) . . ?
F2 Dy1 F5 90.5(2) . . ?
F2 Dy1 F1 69.6(2) . . ?
F2 Dy1 O10 153.7(2) . . ?
F2 Dy1 C26 124.1(3) . . ?
F2 Dy1 C28 95.7(3) . . ?
F2 Dy1 C29 77.4(3) . . ?
F2 Dy1 C30 94.7(3) . . ?
F2 Dy1 C27 124.8(3) . . ?
F1 Dy1 Dy2 35.34(14) . . ?
F1 Dy1 O10 84.2(2) . . ?
F1 Dy1 C26 158.5(3) . . ?
F1 Dy1 C28 151.6(3) . . ?
F1 Dy1 C29 146.9(3) . . ?
F1 Dy1 C30 151.7(3) . . ?
F1 Dy1 C27 157.9(3) . . ?
O10 Dy1 Dy2 119.5(2) . . ?
O10 Dy1 C26 81.1(3) . . ?
O10 Dy1 C28 107.9(3) . . ?
O10 Dy1 C29 128.9(3) . . ?
O10 Dy1 C30 109.3(3) . . ?
O10 Dy1 C27 80.3(3) . . ?
C26 Dy1 Dy2 155.0(3) . . ?
C26 Dy1 C28 49.4(4) . . ?
C26 Dy1 C29 50.4(3) . . ?
C26 Dy1 C30 29.9(3) . . ?
C26 Dy1 C27 31.0(4) . . ?
C28 Dy1 Dy2 126.0(2) . . ?
C28 Dy1 C29 30.1(3) . . ?
C28 Dy1 C30 49.0(4) . . ?
C28 Dy1 C27 29.5(3) . . ?
C29 Dy1 Dy2 111.6(2) . . ?
C30 Dy1 Dy2 125.5(2) . . ?
C30 Dy1 C29 30.4(3) . . ?
C30 Dy1 C27 50.0(3) . . ?
C27 Dy1 Dy2 155.1(3) . . ?
C27 Dy1 C29 50.4(3) . . ?
F3 Dy3 C6 86.8(3) . . ?
F3 Dy3 C5 115.5(3) . . ?
F3 Dy3 C7 84.6(3) . . ?
F3 Dy3 C8 92.3(3) . . ?
F3 Dy3 C21 134.9(3) . . ?
F3 Dy3 C22 112.5(3) . . ?
F3 Dy3 C34 80.2(3) . . ?
F3 Dy3 C35 101.1(3) . . ?
F3 Dy3 C36 130.0(3) . . ?
F3 Dy3 C37 123.1(3) . . ?
F4 Dy3 F3 90.6(2) . . ?
F4 Dy3 C6 125.4(3) . . ?
F4 Dy3 C5 130.5(3) . . ?
F4 Dy3 C7 94.5(3) . . ?
F4 Dy3 C8 129.5(3) . . ?
F4 Dy3 C21 101.1(3) . . ?
F4 Dy3 C22 81.8(3) . . ?
F4 Dy3 C34 100.8(3) . . ?
F4 Dy3 C35 79.2(3) . . ?
F4 Dy3 C36 89.8(3) . . ?
F4 Dy3 C37 121.5(3) . . ?
C6 Dy3 C35 154.5(3) . . ?
C5 Dy3 C6 30.7(3) . . ?
C5 Dy3 C21 31.0(3) . . ?
C5 Dy3 C35 129.6(4) . . ?
C5 Dy3 C36 101.3(4) . . ?
C7 Dy3 C6 30.9(4) . . ?
C7 Dy3 C5 51.2(4) . . ?
C7 Dy3 C8 136.0(4) . . ?
C7 Dy3 C21 51.4(4) . . ?
C7 Dy3 C22 30.6(4) . . ?
C7 Dy3 C34 158.5(4) . . ?
C7 Dy3 C35 171.4(4) . . ?
C7 Dy3 C36 145.1(4) . . ?
C7 Dy3 C37 130.9(4) . . ?
C8 Dy3 C6 105.2(3) . . ?
C8 Dy3 C5 92.6(4) . . ?
C8 Dy3 C21 111.6(3) . . ?
C8 Dy3 C22 141.0(4) . . ?
C8 Dy3 C35 50.8(3) . . ?
C8 Dy3 C36 51.8(3) . . ?
C21 Dy3 C6 50.9(4) . . ?
C21 Dy3 C35 123.8(4) . . ?
C21 Dy3 C36 93.8(4) . . ?
C22 Dy3 C6 50.0(4) . . ?
C22 Dy3 C5 50.1(4) . . ?
C22 Dy3 C21 30.4(4) . . ?
C22 Dy3 C35 141.3(4) . . ?
C22 Dy3 C36 117.0(4) . . ?
C34 Dy3 C6 132.2(3) . . ?
C34 Dy3 C5 123.6(4) . . ?
C34 Dy3 C8 31.0(3) . . ?
C34 Dy3 C21 137.8(4) . . ?
C34 Dy3 C22 167.1(4) . . ?
C34 Dy3 C35 30.1(3) . . ?
C34 Dy3 C36 50.8(4) . . ?
C36 Dy3 C6 131.1(4) . . ?
C36 Dy3 C35 30.5(4) . . ?
C37 Dy3 C6 104.6(4) . . ?
C37 Dy3 C5 79.7(4) . . ?
C37 Dy3 C8 30.8(3) . . ?
C37 Dy3 C21 87.1(4) . . ?
C37 Dy3 C22 117.2(4) . . ?
C37 Dy3 C34 50.7(4) . . ?
C37 Dy3 C35 50.8(4) . . ?
C37 Dy3 C36 31.8(4) . . ?
F5 Dy4 F6 88.4(2) . . ?
F5 Dy4 C11 86.1(3) . . ?
F5 Dy4 C12 130.0(3) . . ?
F5 Dy4 C13 120.5(3) . . ?
F5 Dy4 C9 112.7(3) . . ?
F5 Dy4 C10 117.3(3) . . ?
F5 Dy4 C14 79.7(3) . . ?
F5 Dy4 C44 136.4(3) . . ?
F5 Dy4 C41 102.5(3) . . ?
F5 Dy4 C43 88.8(3) . . ?
F5 Dy4 C40 89.5(3) . . ?
F6 Dy4 C11 123.2(3) . . ?
F6 Dy4 C12 96.4(3) . . ?
F6 Dy4 C13 126.9(3) . . ?
F6 Dy4 C9 134.4(3) . . ?
F6 Dy4 C10 83.5(3) . . ?
F6 Dy4 C14 101.7(3) . . ?
F6 Dy4 C44 106.5(3) . . ?
F6 Dy4 C41 82.0(3) . . ?
F6 Dy4 C43 92.4(3) . . ?
F6 Dy4 C40 131.5(3) . . ?
C11 Dy4 C12 128.7(4) . . ?
C11 Dy4 C13 103.8(4) . . ?
C11 Dy4 C9 30.3(4) . . ?
C11 Dy4 C10 50.8(4) . . ?
C11 Dy4 C14 132.4(4) . . ?
C11 Dy4 C44 51.2(4) . . ?
C11 Dy4 C41 153.9(4) . . ?
C11 Dy4 C43 31.1(4) . . ?
C11 Dy4 C40 105.0(4) . . ?
C12 Dy4 C13 30.6(3) . . ?
C12 Dy4 C44 89.7(4) . . ?
C12 Dy4 C40 51.3(3) . . ?
C13 Dy4 C44 83.1(3) . . ?
C13 Dy4 C40 31.0(3) . . ?
C9 Dy4 C12 98.9(3) . . ?
C9 Dy4 C13 77.7(3) . . ?
C9 Dy4 C10 50.9(4) . . ?
C9 Dy4 C44 31.5(3) . . ?
C9 Dy4 C41 127.5(4) . . ?
C9 Dy4 C40 90.4(4) . . ?
C10 Dy4 C12 112.7(4) . . ?
C10 Dy4 C13 113.4(4) . . ?
C10 Dy4 C44 30.8(4) . . ?
C10 Dy4 C40 138.3(4) . . ?
C14 Dy4 C12 50.6(4) . . ?
C14 Dy4 C13 50.3(3) . . ?
C14 Dy4 C9 121.1(4) . . ?
C14 Dy4 C10 162.6(3) . . ?
C14 Dy4 C44 133.4(3) . . ?
C14 Dy4 C41 30.8(4) . . ?
C14 Dy4 C43 161.4(4) . . ?
C14 Dy4 C40 30.8(3) . . ?
C41 Dy4 C12 30.7(4) . . ?
C41 Dy4 C13 50.6(4) . . ?
C41 Dy4 C10 137.0(4) . . ?
C41 Dy4 C44 119.8(4) . . ?
C41 Dy4 C40 51.4(4) . . ?
C43 Dy4 C12 140.2(4) . . ?
C43 Dy4 C13 128.0(4) . . ?
C43 Dy4 C9 50.6(4) . . ?
C43 Dy4 C10 30.2(4) . . ?
C43 Dy4 C44 50.7(3) . . ?
C43 Dy4 C41 167.2(4) . . ?
C43 Dy4 C40 136.0(4) . . ?
C40 Dy4 C44 108.0(4) . . ?
F2 Dy2 Dy1 33.86(15) . . ?
F2 Dy2 F1 69.7(2) . . ?
F2 Dy2 F4 89.5(2) . . ?
F2 Dy2 F6 87.7(2) . . ?
F2 Dy2 O1 152.0(2) . . ?
F2 Dy2 C4 76.4(3) . . ?
F2 Dy2 C2 116.7(3) . . ?
F2 Dy2 C3 86.5(3) . . ?
F2 Dy2 C1 126.1(3) . . ?
F2 Dy2 C47 99.7(3) . . ?
F1 Dy2 Dy1 35.79(14) . . ?
F1 Dy2 F6 77.9(2) . . ?
F1 Dy2 O1 82.6(2) . . ?
F1 Dy2 C4 144.5(3) . . ?
F1 Dy2 C2 160.0(3) . . ?
F1 Dy2 C3 150.3(3) . . ?
F1 Dy2 C1 160.3(3) . . ?
F1 Dy2 C47 149.8(3) . . ?
F4 Dy2 Dy1 81.85(16) . . ?
F4 Dy2 F1 77.3(2) . . ?
F4 Dy2 F6 154.4(2) . . ?
F4 Dy2 O1 80.6(3) . . ?
F4 Dy2 C4 92.7(3) . . ?
F4 Dy2 C2 120.3(3) . . ?
F4 Dy2 C3 121.4(3) . . ?
F4 Dy2 C1 90.1(3) . . ?
F4 Dy2 C47 74.4(3) . . ?
F6 Dy2 Dy1 81.68(15) . . ?
F6 Dy2 O1 90.1(3) . . ?
F6 Dy2 C4 111.3(3) . . ?
F6 Dy2 C2 83.4(3) . . ?
F6 Dy2 C3 83.9(3) . . ?
F6 Dy2 C1 111.9(3) . . ?
F6 Dy2 C47 131.2(3) . . ?
O1 Dy2 Dy1 118.26(18) . . ?
O1 Dy2 C4 129.8(3) . . ?
O1 Dy2 C2 90.7(3) . . ?
O1 Dy2 C3 121.0(3) . . ?
O1 Dy2 C1 80.4(3) . . ?
O1 Dy2 C47 102.7(4) . . ?
C4 Dy2 Dy1 109.6(2) . . ?
C4 Dy2 C2 50.4(3) . . ?
C4 Dy2 C1 49.8(4) . . ?
C4 Dy2 C47 29.9(4) . . ?
C2 Dy2 Dy1 147.2(2) . . ?
C2 Dy2 C47 50.1(4) . . ?
C3 Dy2 Dy1 118.7(3) . . ?
C3 Dy2 C4 30.0(4) . . ?
C3 Dy2 C2 30.3(3) . . ?
C3 Dy2 C1 49.4(4) . . ?
C3 Dy2 C47 49.1(4) . . ?
C1 Dy2 Dy1 157.8(3) . . ?
C1 Dy2 C2 30.5(4) . . ?
C1 Dy2 C47 30.0(4) . . ?
C47 Dy2 Dy1 128.0(3) . . ?
C40 Si1 C42 109.0(5) . . ?
C40 Si1 C88 113.0(6) . . ?
C40 Si1 C87 108.9(6) . . ?
C42 Si1 C87 109.4(7) . . ?
C88 Si1 C42 107.2(7) . . ?
C88 Si1 C87 109.3(7) . . ?
C29 Si6 C32 111.4(5) . . ?
C29 Si6 C33 109.4(5) . . ?
C32 Si6 C33 107.3(6) . . ?
C31 Si6 C29 111.1(5) . . ?
C31 Si6 C32 108.4(6) . . ?
C31 Si6 C33 109.1(6) . . ?
C2 Si2 C48 112.4(6) . . ?
C49 Si2 C2 107.2(6) . . ?
C49 Si2 C48 109.7(7) . . ?
C84 Si2 C2 109.8(6) . . ?
C84 Si2 C48 107.8(7) . . ?
C84 Si2 C49 109.8(7) . . ?
C38 Si5 C8 113.0(6) . . ?
C39 Si5 C8 107.1(6) . . ?
C39 Si5 C38 109.6(8) . . ?
C86 Si5 C8 108.9(6) . . ?
C86 Si5 C38 108.0(7) . . ?
C86 Si5 C39 110.1(9) . . ?
C21 Si4 C23 113.0(6) . . ?
C21 Si4 C25 108.1(6) . . ?
C21 Si4 C24 108.7(6) . . ?
C23 Si4 C25 108.2(7) . . ?
C23 Si4 C24 109.6(6) . . ?
C25 Si4 C24 109.1(7) . . ?
C44 Si3 C45 112.2(6) . . ?
C46 Si3 C44 109.0(6) . . ?
C46 Si3 C45 108.9(7) . . ?
C46 Si3 C85 108.3(8) . . ?
C85 Si3 C44 108.4(7) . . ?
C85 Si3 C45 110.0(8) . . ?
Dy3 F3 Dy1 141.0(3) . . ?
Dy4 F5 Dy1 143.1(3) . . ?
Dy1 F2 Dy2 111.9(2) . . ?
Dy2 F1 Dy1 108.9(2) . . ?
Dy3 F4 Dy2 142.9(3) . . ?
Dy4 F6 Dy2 143.6(3) . . ?
C52 O1 Dy2 128.4(7) . . ?
C50 O1 Dy2 120.0(6) . . ?
C50 O1 C52 110.7(8) . . ?
C80 O10 Dy1 126.0(7) . . ?
C83 O10 Dy1 124.4(11) . . ?
C83 O10 C80 108.9(12) . . ?
Dy3 C6 H6 118.6 . . ?
C5 C6 Dy3 74.1(6) . . ?
C5 C6 H6 125.9 . . ?
C5 C6 C7 108.2(10) . . ?
C7 C6 Dy3 73.3(6) . . ?
C7 C6 H6 125.9 . . ?
Dy4 C11 H11 116.1 . . ?
C9 C11 Dy4 75.3(6) . . ?
C9 C11 H11 126.0 . . ?
C9 C11 C43 108.0(11) . . ?
C43 C11 Dy4 74.7(6) . . ?
C43 C11 H11 126.0 . . ?
Dy4 C12 H12 117.0 . . ?
C13 C12 Dy4 74.7(6) . . ?
C13 C12 H12 126.1 . . ?
C13 C12 C41 107.8(11) . . ?
C41 C12 Dy4 74.2(6) . . ?
C41 C12 H12 126.1 . . ?
Dy1 C26 H26 114.9 . . ?
C30 C26 Dy1 75.9(6) . . ?
C30 C26 H26 126.1 . . ?
C30 C26 C27 107.7(11) . . ?
C27 C26 Dy1 75.3(7) . . ?
C27 C26 H26 126.1 . . ?
Dy3 C5 H5 116.2 . . ?
C6 C5 Dy3 75.2(6) . . ?
C6 C5 H5 125.8 . . ?
C6 C5 C21 108.4(10) . . ?
C21 C5 Dy3 74.8(6) . . ?
C21 C5 H5 125.8 . . ?
Dy4 C13 H13 117.3 . . ?
C12 C13 Dy4 74.7(6) . . ?
C12 C13 H13 125.4 . . ?
C12 C13 C40 109.2(10) . . ?
C40 C13 Dy4 74.5(6) . . ?
C40 C13 H13 125.4 . . ?
Dy2 C4 H4 115.9 . . ?
C3 C4 Dy2 74.4(6) . . ?
C3 C4 H4 126.6 . . ?
C3 C4 C47 106.9(11) . . ?
C47 C4 Dy2 75.4(7) . . ?
C47 C4 H4 126.6 . . ?
Dy4 C9 H9 116.3 . . ?
C11 C9 Dy4 74.3(6) . . ?
C11 C9 H9 125.6 . . ?
C11 C9 C44 108.7(11) . . ?
C44 C9 Dy4 75.8(6) . . ?
C44 C9 H9 125.6 . . ?
Si2 C2 Dy2 122.6(5) . . ?
C3 C2 Dy2 73.9(6) . . ?
C3 C2 Si2 128.0(9) . . ?
C3 C2 C1 105.2(11) . . ?
C1 C2 Dy2 74.7(6) . . ?
C1 C2 Si2 126.3(9) . . ?
Dy2 C3 H3 115.8 . . ?
C4 C3 Dy2 75.6(6) . . ?
C4 C3 C2 110.6(11) . . ?
C4 C3 H3 124.7 . . ?
C2 C3 Dy2 75.8(6) . . ?
C2 C3 H3 124.7 . . ?
Dy4 C10 H10 116.8 . . ?
C44 C10 Dy4 75.6(6) . . ?
C44 C10 H10 125.5 . . ?
C43 C10 Dy4 74.0(6) . . ?
C43 C10 H10 125.5 . . ?
C43 C10 C44 109.1(11) . . ?
Dy3 C7 H7 114.5 . . ?
C6 C7 Dy3 75.8(6) . . ?
C6 C7 H7 126.9 . . ?
C22 C7 Dy3 75.4(7) . . ?
C22 C7 C6 106.3(11) . . ?
C22 C7 H7 126.9 . . ?
Dy4 C14 H14 115.5 . . ?
C41 C14 Dy4 75.5(7) . . ?
C41 C14 H14 124.8 . . ?
C41 C14 C40 110.4(10) . . ?
C40 C14 Dy4 76.0(6) . . ?
C40 C14 H14 124.8 . . ?
Dy2 C1 H1 116.5 . . ?
C2 C1 Dy2 74.7(6) . . ?
C2 C1 H1 125.8 . . ?
C47 C1 Dy2 75.0(7) . . ?
C47 C1 C2 108.4(12) . . ?
C47 C1 H1 125.8 . . ?
Si5 C8 Dy3 121.9(5) . . ?
C34 C8 Dy3 74.5(6) . . ?
C34 C8 Si5 125.7(8) . . ?
C37 C8 Dy3 74.1(6) . . ?
C37 C8 Si5 127.4(9) . . ?
C37 C8 C34 106.6(10) . . ?
Si4 C21 Dy3 127.4(5) . . ?
C5 C21 Dy3 74.2(6) . . ?
C5 C21 Si4 126.8(9) . . ?
C22 C21 Dy3 74.5(6) . . ?
C22 C21 Si4 125.6(9) . . ?
C22 C21 C5 106.1(11) . . ?
Dy3 C22 H22 117.9 . . ?
C7 C22 Dy3 74.0(7) . . ?
C7 C22 H22 124.6 . . ?
C21 C22 Dy3 75.2(6) . . ?
C21 C22 C7 110.9(11) . . ?
C21 C22 H22 124.6 . . ?
Dy1 C28 H28 116.3 . . ?
C29 C28 Dy1 75.9(6) . . ?
C29 C28 H28 123.9 . . ?
C27 C28 Dy1 75.5(7) . . ?
C27 C28 H28 123.9 . . ?
C27 C28 C29 112.2(11) . . ?
Dy3 C34 H34 116.3 . . ?
C8 C34 Dy3 74.5(6) . . ?
C8 C34 H34 125.3 . . ?
C35 C34 Dy3 75.8(6) . . ?
C35 C34 C8 109.3(10) . . ?
C35 C34 H34 125.3 . . ?
Dy3 C35 H35 117.8 . . ?
C34 C35 Dy3 74.1(6) . . ?
C34 C35 H35 125.1 . . ?
C34 C35 C36 109.7(10) . . ?
C36 C35 Dy3 74.7(6) . . ?
C36 C35 H35 125.1 . . ?
Dy3 C36 H36 117.4 . . ?
C35 C36 Dy3 74.8(6) . . ?
C35 C36 H36 127.3 . . ?
C35 C36 C37 105.5(10) . . ?
C37 C36 Dy3 72.9(6) . . ?
C37 C36 H36 127.3 . . ?
Si3 C44 Dy4 128.6(5) . . ?
C9 C44 Dy4 72.7(6) . . ?
C9 C44 Si3 127.9(9) . . ?
C10 C44 Dy4 73.6(6) . . ?
C10 C44 Si3 125.3(9) . . ?
C10 C44 C9 105.5(10) . . ?
Si3 C45 H45A 109.5 . . ?
Si3 C45 H45B 109.5 . . ?
Si3 C45 H45C 109.5 . . ?
H45A C45 H45B 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
Si6 C29 Dy1 124.6(5) . . ?
C28 C29 Dy1 74.0(6) . . ?
C28 C29 Si6 126.6(9) . . ?
C28 C29 C30 104.5(9) . . ?
C30 C29 Dy1 74.0(6) . . ?
C30 C29 Si6 128.1(8) . . ?
Dy3 C37 H37 116.0 . . ?
C8 C37 Dy3 75.1(7) . . ?
C8 C37 C36 108.9(11) . . ?
C8 C37 H37 125.6 . . ?
C36 C37 Dy3 75.3(6) . . ?
C36 C37 H37 125.6 . . ?
Dy4 C41 H41 116.9 . . ?
C12 C41 Dy4 75.1(6) . . ?
C12 C41 H41 126.4 . . ?
C14 C41 Dy4 73.7(6) . . ?
C14 C41 C12 107.2(11) . . ?
C14 C41 H41 126.4 . . ?
O1 C52 H52A 111.0 . . ?
O1 C52 H52B 111.0 . . ?
O1 C52 C91 103.8(10) . . ?
H52A C52 H52B 109.0 . . ?
C91 C52 H52A 111.0 . . ?
C91 C52 H52B 111.0 . . ?
O1 C50 H50A 111.1 . . ?
O1 C50 H50B 111.1 . . ?
O1 C50 C51 103.3(10) . . ?
H50A C50 H50B 109.1 . . ?
C51 C50 H50A 111.1 . . ?
C51 C50 H50B 111.1 . . ?
Si6 C32 H32A 109.5 . . ?
Si6 C32 H32B 109.5 . . ?
Si6 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
Dy4 C43 H43 116.4 . . ?
C11 C43 Dy4 74.3(6) . . ?
C11 C43 H43 125.6 . . ?
C10 C43 Dy4 75.7(6) . . ?
C10 C43 C11 108.7(11) . . ?
C10 C43 H43 125.6 . . ?
Dy1 C30 H30 116.9 . . ?
C26 C30 Dy1 74.3(6) . . ?
C26 C30 C29 109.9(10) . . ?
C26 C30 H30 125.1 . . ?
C29 C30 Dy1 75.6(6) . . ?
C29 C30 H30 125.1 . . ?
Si4 C23 H23A 109.5 . . ?
Si4 C23 H23B 109.5 . . ?
Si4 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si6 C31 H31A 109.5 . . ?
Si6 C31 H31B 109.5 . . ?
Si6 C31 H31C 109.5 . . ?
H31A C31 H31B 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
Si1 C40 Dy4 122.3(5) . . ?
C13 C40 Dy4 74.5(6) . . ?
C13 C40 Si1 125.4(9) . . ?
C14 C40 Dy4 73.2(6) . . ?
C14 C40 Si1 128.8(9) . . ?
C14 C40 C13 105.4(10) . . ?
Dy2 C47 H47 116.8 . . ?
C4 C47 Dy2 74.7(7) . . ?
C4 C47 C1 108.9(12) . . ?
C4 C47 H47 125.6 . . ?
C1 C47 Dy2 74.9(7) . . ?
C1 C47 H47 125.6 . . ?
Dy1 C27 H27 116.7 . . ?
C26 C27 Dy1 73.6(6) . . ?
C26 C27 H27 127.1 . . ?
C28 C27 Dy1 75.0(6) . . ?
C28 C27 C26 105.7(10) . . ?
C28 C27 H27 127.1 . . ?
Si6 C33 H33A 109.5 . . ?
Si6 C33 H33B 109.5 . . ?
Si6 C33 H33C 109.5 . . ?
H33A C33 H33B 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
Si4 C25 H25A 109.5 . . ?
Si4 C25 H25B 109.5 . . ?
Si4 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
Si5 C38 H38A 109.5 . . ?
Si5 C38 H38B 109.5 . . ?
Si5 C38 H38C 109.5 . . ?
H38A C38 H38B 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C50 C51 H51A 111.3 . . ?
C50 C51 H51B 111.3 . . ?
H51A C51 H51B 109.2 . . ?
C91 C51 C50 102.2(11) . . ?
C91 C51 H51A 111.3 . . ?
C91 C51 H51B 111.3 . . ?
Si1 C42 H42A 109.5 . . ?
Si1 C42 H42B 109.5 . . ?
Si1 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
Si4 C24 H24A 109.5 . . ?
Si4 C24 H24B 109.5 . . ?
Si4 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Si3 C46 H46A 109.5 . . ?
Si3 C46 H46B 109.5 . . ?
Si3 C46 H46C 109.5 . . ?
H46A C46 H46B 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
Si2 C48 H48A 109.5 . . ?
Si2 C48 H48B 109.5 . . ?
Si2 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
Si5 C39 H39A 109.5 . . ?
Si5 C39 H39B 109.5 . . ?
Si5 C39 H39C 109.5 . . ?
H39A C39 H39B 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
Si2 C49 H49A 109.5 . . ?
Si2 C49 H49B 109.5 . . ?
Si2 C49 H49C 109.5 . . ?
H49A C49 H49B 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
Si1 C88 H88A 109.5 . . ?
Si1 C88 H88B 109.5 . . ?
Si1 C88 H88C 109.5 . . ?
H88A C88 H88B 109.5 . . ?
H88A C88 H88C 109.5 . . ?
H88B C88 H88C 109.5 . . ?
Si2 C84 H84A 109.5 . . ?
Si2 C84 H84B 109.5 . . ?
Si2 C84 H84C 109.5 . . ?
H84A C84 H84B 109.5 . . ?
H84A C84 H84C 109.5 . . ?
H84B C84 H84C 109.5 . . ?
O10 C80 H80A 110.5 . . ?
O10 C80 H80B 110.5 . . ?
O10 C80 C81 106.3(19) . . ?
H80A C80 H80B 108.7 . . ?
C81 C80 H80A 110.5 . . ?
C81 C80 H80B 110.5 . . ?
Si1 C87 H87A 109.5 . . ?
Si1 C87 H87B 109.5 . . ?
Si1 C87 H87C 109.5 . . ?
H87A C87 H87B 109.5 . . ?
H87A C87 H87C 109.5 . . ?
H87B C87 H87C 109.5 . . ?
Si5 C86 H86A 109.5 . . ?
Si5 C86 H86B 109.5 . . ?
Si5 C86 H86C 109.5 . . ?
H86A C86 H86B 109.5 . . ?
H86A C86 H86C 109.5 . . ?
H86B C86 H86C 109.5 . . ?
Si3 C85 H85A 109.5 . . ?
Si3 C85 H85B 109.5 . . ?
Si3 C85 H85C 109.5 . . ?
H85A C85 H85B 109.5 . . ?
H85A C85 H85C 109.5 . . ?
H85B C85 H85C 109.5 . . ?
O10 C83 H83A 110.6 . . ?
O10 C83 H83B 110.6 . . ?
O10 C83 C82 106(2) . . ?
H83A C83 H83B 108.7 . . ?
C82 C83 H83A 110.6 . . ?
C82 C83 H83B 110.6 . . ?
C80 C81 H81A 110.5 . . ?
C80 C81 H81B 110.5 . . ?
H81A C81 H81B 108.7 . . ?
C82 C81 C80 106(3) . . ?
C82 C81 H81A 110.5 . . ?
C82 C81 H81B 110.5 . . ?
C83 C82 H82A 109.9 . . ?
C83 C82 H82B 109.9 . . ?
C81 C82 C83 109(3) . . ?
C81 C82 H82A 109.9 . . ?
C81 C82 H82B 109.9 . . ?
H82A C82 H82B 108.3 . . ?
C52 C91 H91A 110.7 . . ?
C52 C91 H91B 110.7 . . ?
C51 C91 C52 105.1(11) . . ?
C51 C91 H91A 110.7 . . ?
C51 C91 H91B 110.7 . . ?
H91A C91 H91B 108.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O10 C80 C81 174.5(18) . . . . ?
Dy1 O10 C83 C82 174.3(15) . . . . ?
Dy1 C26 C30 C29 67.9(8) . . . . ?
Dy1 C26 C27 C28 -68.7(8) . . . . ?
Dy1 C28 C29 Si6 121.5(9) . . . . ?
Dy1 C28 C29 C30 -68.3(7) . . . . ?
Dy1 C28 C27 C26 67.7(8) . . . . ?
Dy1 C29 C30 C26 -67.0(8) . . . . ?
Dy3 C6 C5 C21 68.1(7) . . . . ?
Dy3 C6 C7 C22 -69.8(8) . . . . ?
Dy3 C5 C21 Si4 -125.2(8) . . . . ?
Dy3 C5 C21 C22 68.2(8) . . . . ?
Dy3 C7 C22 C21 -66.8(8) . . . . ?
Dy3 C8 C34 C35 68.4(8) . . . . ?
Dy3 C8 C37 C36 -68.4(8) . . . . ?
Dy3 C21 C22 C7 66.0(9) . . . . ?
Dy3 C34 C35 C36 66.8(8) . . . . ?
Dy3 C35 C36 C37 66.9(7) . . . . ?
Dy3 C36 C37 C8 68.2(8) . . . . ?
Dy4 C11 C9 C44 -68.6(8) . . . . ?
Dy4 C11 C43 C10 68.5(8) . . . . ?
Dy4 C12 C13 C40 -67.1(7) . . . . ?
Dy4 C12 C41 C14 67.3(8) . . . . ?
Dy4 C13 C40 Si1 118.9(8) . . . . ?
Dy4 C13 C40 C14 -67.2(7) . . . . ?
Dy4 C9 C44 Si3 125.8(9) . . . . ?
Dy4 C9 C44 C10 -66.8(7) . . . . ?
Dy4 C10 C44 Si3 -126.0(8) . . . . ?
Dy4 C10 C44 C9 66.2(7) . . . . ?
Dy4 C10 C43 C11 -67.5(8) . . . . ?
Dy4 C14 C41 C12 -68.2(8) . . . . ?
Dy4 C14 C40 Si1 -118.3(9) . . . . ?
Dy4 C14 C40 C13 68.1(7) . . . . ?
Dy2 O1 C52 C91 -165.5(8) . . . . ?
Dy2 O1 C50 C51 -170.3(8) . . . . ?
Dy2 C4 C3 C2 68.4(8) . . . . ?
Dy2 C4 C47 C1 -67.8(8) . . . . ?
Dy2 C2 C3 C4 -68.3(8) . . . . ?
Dy2 C2 C1 C47 68.1(8) . . . . ?
Dy2 C1 C47 C4 67.6(8) . . . . ?
Si6 C29 C30 Dy1 -121.7(8) . . . . ?
Si6 C29 C30 C26 171.3(8) . . . . ?
Si2 C2 C3 Dy2 -119.1(9) . . . . ?
Si2 C2 C3 C4 172.6(8) . . . . ?
Si2 C2 C1 Dy2 119.5(9) . . . . ?
Si2 C2 C1 C47 -172.4(8) . . . . ?
Si5 C8 C34 Dy3 118.5(8) . . . . ?
Si5 C8 C34 C35 -173.1(8) . . . . ?
Si5 C8 C37 Dy3 -118.3(8) . . . . ?
Si5 C8 C37 C36 173.3(8) . . . . ?
Si4 C21 C22 Dy3 125.1(8) . . . . ?
Si4 C21 C22 C7 -168.8(8) . . . . ?
O1 C52 C91 C51 -26.5(13) . . . . ?
O1 C50 C51 C91 -35.3(14) . . . . ?
O10 C80 C81 C82 21(3) . . . . ?
O10 C83 C82 C81 10(4) . . . . ?
C6 C5 C21 Dy3 -68.4(8) . . . . ?
C6 C5 C21 Si4 166.5(8) . . . . ?
C6 C5 C21 C22 -0.1(12) . . . . ?
C6 C7 C22 Dy3 70.1(8) . . . . ?
C6 C7 C22 C21 3.3(13) . . . . ?
C11 C9 C44 Dy4 67.7(8) . . . . ?
C11 C9 C44 Si3 -166.5(8) . . . . ?
C11 C9 C44 C10 0.8(12) . . . . ?
C12 C13 C40 Dy4 67.2(8) . . . . ?
C12 C13 C40 Si1 -173.9(8) . . . . ?
C12 C13 C40 C14 0.1(12) . . . . ?
C5 C6 C7 Dy3 66.5(8) . . . . ?
C5 C6 C7 C22 -3.3(13) . . . . ?
C5 C21 C22 Dy3 -68.0(7) . . . . ?
C5 C21 C22 C7 -2.0(13) . . . . ?
C13 C12 C41 Dy4 -67.8(8) . . . . ?
C13 C12 C41 C14 -0.5(13) . . . . ?
C9 C11 C43 Dy4 -68.6(8) . . . . ?
C9 C11 C43 C10 -0.1(13) . . . . ?
C2 C1 C47 Dy2 -67.9(8) . . . . ?
C2 C1 C47 C4 -0.3(13) . . . . ?
C3 C4 C47 Dy2 68.3(7) . . . . ?
C3 C4 C47 C1 0.6(13) . . . . ?
C3 C2 C1 Dy2 -68.2(7) . . . . ?
C3 C2 C1 C47 -0.1(13) . . . . ?
C7 C6 C5 Dy3 -65.9(8) . . . . ?
C7 C6 C5 C21 2.2(13) . . . . ?
C1 C2 C3 Dy2 68.7(7) . . . . ?
C1 C2 C3 C4 0.4(12) . . . . ?
C8 C34 C35 Dy3 -67.6(8) . . . . ?
C8 C34 C35 C36 -0.8(13) . . . . ?
C28 C29 C30 Dy1 68.3(7) . . . . ?
C28 C29 C30 C26 1.3(12) . . . . ?
C34 C8 C37 Dy3 68.0(7) . . . . ?
C34 C8 C37 C36 -0.4(12) . . . . ?
C34 C35 C36 Dy3 -66.5(8) . . . . ?
C34 C35 C36 C37 0.5(13) . . . . ?
C35 C36 C37 Dy3 -68.3(8) . . . . ?
C35 C36 C37 C8 0.0(12) . . . . ?
C44 C10 C43 Dy4 68.2(8) . . . . ?
C44 C10 C43 C11 0.6(13) . . . . ?
C45 Si3 C44 Dy4 64.1(8) . . . . ?
C45 Si3 C44 C9 -33.9(12) . . . . ?
C45 Si3 C44 C10 161.1(10) . . . . ?
C29 C28 C27 Dy1 -67.9(8) . . . . ?
C29 C28 C27 C26 -0.1(13) . . . . ?
C37 C8 C34 Dy3 -67.7(7) . . . . ?
C37 C8 C34 C35 0.7(12) . . . . ?
C41 C12 C13 Dy4 67.4(8) . . . . ?
C41 C12 C13 C40 0.3(12) . . . . ?
C41 C14 C40 Dy4 -68.4(8) . . . . ?
C41 C14 C40 Si1 173.3(9) . . . . ?
C41 C14 C40 C13 -0.4(12) . . . . ?
C52 O1 C50 C51 19.6(14) . . . . ?
C50 O1 C52 C91 3.5(13) . . . . ?
C50 C51 C91 C52 38.1(14) . . . . ?
C32 Si6 C29 Dy1 59.7(8) . . . . ?
C32 Si6 C29 C28 -35.8(11) . . . . ?
C32 Si6 C29 C30 156.3(9) . . . . ?
C43 C11 C9 Dy4 68.2(8) . . . . ?
C43 C11 C9 C44 -0.5(13) . . . . ?
C43 C10 C44 Dy4 -67.1(8) . . . . ?
C43 C10 C44 Si3 166.9(8) . . . . ?
C43 C10 C44 C9 -0.9(12) . . . . ?
C30 C26 C27 Dy1 69.6(7) . . . . ?
C30 C26 C27 C28 0.9(13) . . . . ?
C23 Si4 C21 Dy3 -54.5(9) . . . . ?
C23 Si4 C21 C5 43.8(11) . . . . ?
C23 Si4 C21 C22 -152.1(10) . . . . ?
C31 Si6 C29 Dy1 -61.3(8) . . . . ?
C31 Si6 C29 C28 -156.7(10) . . . . ?
C31 Si6 C29 C30 35.4(12) . . . . ?
C40 C14 C41 Dy4 68.8(8) . . . . ?
C40 C14 C41 C12 0.5(13) . . . . ?
C47 C4 C3 Dy2 -69.1(8) . . . . ?
C47 C4 C3 C2 -0.6(13) . . . . ?
C27 C26 C30 Dy1 -69.3(8) . . . . ?
C27 C26 C30 C29 -1.4(12) . . . . ?
C27 C28 C29 Dy1 67.6(8) . . . . ?
C27 C28 C29 Si6 -170.9(8) . . . . ?
C27 C28 C29 C30 -0.7(12) . . . . ?
C33 Si6 C29 Dy1 178.1(6) . . . . ?
C33 Si6 C29 C28 82.7(11) . . . . ?
C33 Si6 C29 C30 -85.2(11) . . . . ?
C25 Si4 C21 Dy3 -174.2(7) . . . . ?
C25 Si4 C21 C5 -75.9(11) . . . . ?
C25 Si4 C21 C22 88.2(11) . . . . ?
C38 Si5 C8 Dy3 15.2(8) . . . . ?
C38 Si5 C8 C34 -78.2(11) . . . . ?
C38 Si5 C8 C37 109.2(11) . . . . ?
C42 Si1 C40 Dy4 -137.1(6) . . . . ?
C42 Si1 C40 C13 129.4(10) . . . . ?
C42 Si1 C40 C14 -43.1(12) . . . . ?
C24 Si4 C21 Dy3 67.4(8) . . . . ?
C24 Si4 C21 C5 165.7(10) . . . . ?
C24 Si4 C21 C22 -30.1(12) . . . . ?
C46 Si3 C44 Dy4 -56.5(9) . . . . ?
C46 Si3 C44 C9 -154.5(10) . . . . ?
C46 Si3 C44 C10 40.5(12) . . . . ?
C48 Si2 C2 Dy2 29.0(8) . . . . ?
C48 Si2 C2 C3 123.8(10) . . . . ?
C48 Si2 C2 C1 -65.6(11) . . . . ?
C39 Si5 C8 Dy3 -105.7(8) . . . . ?
C39 Si5 C8 C34 160.9(11) . . . . ?
C39 Si5 C8 C37 -11.7(13) . . . . ?
C49 Si2 C2 Dy2 -91.6(7) . . . . ?
C49 Si2 C2 C3 3.1(12) . . . . ?
C49 Si2 C2 C1 173.8(10) . . . . ?
C88 Si1 C40 Dy4 -18.0(9) . . . . ?
C88 Si1 C40 C13 -111.5(10) . . . . ?
C88 Si1 C40 C14 76.0(12) . . . . ?
C84 Si2 C2 Dy2 149.1(7) . . . . ?
C84 Si2 C2 C3 -116.2(11) . . . . ?
C84 Si2 C2 C1 54.4(12) . . . . ?
C80 O10 C83 C82 3(2) . . . . ?
C80 C81 C82 C83 -19(4) . . . . ?
C87 Si1 C40 Dy4 103.6(8) . . . . ?
C87 Si1 C40 C13 10.1(12) . . . . ?
C87 Si1 C40 C14 -162.4(11) . . . . ?
C86 Si5 C8 Dy3 135.3(8) . . . . ?
C86 Si5 C8 C34 41.9(12) . . . . ?
C86 Si5 C8 C37 -130.7(11) . . . . ?
C85 Si3 C44 Dy4 -174.2(8) . . . . ?
C85 Si3 C44 C9 87.8(12) . . . . ?
C85 Si3 C44 C10 -77.2(12) . . . . ?
C83 O10 C80 C81 -15(2) . . . . ?

_shelx_SHELXL_version_number     2014/7

loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
16 -2 -18 0.0271 15.9990 -2.0143 -17.9935 -0.8906 0.2220 -0.4086
0 36 -2 0.0373 -0.0046 35.9941 -2.0016 0.1223 0.9524 0.2975
-11 14 -22 0.0885 -11.0019 14.0040 -22.0037 -0.2838 0.2081 0.9205
7 -1 29 0.0627 7.0007 -1.0021 29.0014 0.6381 0.0646 -0.7658
-1 4 31 0.0520 -0.9995 4.0036 30.9982 0.9080 0.0648 -0.4207
-14 -7 21 0.0469 -13.9979 -6.9855 20.9945 0.8824 -0.4295 0.2095
4 -35 -1 0.0454 4.0042 -34.9977 -0.9969 -0.2957 -0.8584 -0.4125
-12 -20 -16 0.0780 -11.9975 -19.9892 -16.0027 -0.2610 -0.7109 0.6167
17 -3 16 0.0581 17.0001 -3.0111 16.0055 0.0289 0.1849 -0.9990

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.7682(9)
2 0.2318(9)

