# Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers.
# This journal is © the Partner Organisations 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_exp_6917
_audit_block_doi                 10.5517/ccdc.csd.cc2704v8
_database_code_depnum_ccdc_archive 'CCDC 2055729'
loop_
_audit_author_name
_audit_author_address
difluoromethoxyphenylmethylquinolinlbenzamide
;Capital Normal University
China
;
_audit_update_record             
;
2021-01-13 deposited with the CCDC.	2022-04-22 downloaded from the CCDC.
;
_audit_creation_date             2020-12-31
_audit_creation_method           
;
  Olex2 1.1
  (compiled 2011.02.15 svn.r1672, GUI svn.r3494)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'C24 H18 F2 N2 O2'
_chemical_formula_sum            'C24 H18 F2 N2 O2'
_chemical_formula_weight         404.40
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x+1/2, -y, z+1/2'
3 'x+1/2, -y+1/2, -z'
4 '-x, y+1/2, -z+1/2'
5 '-x, -y, -z'
6 'x-1/2, y, -z-1/2'
7 '-x-1/2, y-1/2, z'
8 'x, -y-1/2, z-1/2'

_cell_length_a                   15.1154(4)
_cell_length_b                   8.6495(3)
_cell_length_c                   28.5881(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3737.6(2)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    2628
_cell_measurement_temperature    109.90(10)
_cell_measurement_theta_max      27.7440
_cell_measurement_theta_min      3.9220
_exptl_absorpt_coefficient_mu    0.106
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.91417
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.437
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1680
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.33
_exptl_crystal_size_min          0.15
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0461
_diffrn_reflns_av_unetI/netI     0.0471
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            10777
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         3.05
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      109.90(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.0971
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.9955
_diffrn_measured_fraction_theta_max 0.8377
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -12.00   20.00   0.5000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      -10.8508  -99.0000   30.0000 64

#__ type_ start__ end____ width___ exp.time_
  2 omega   49.00   85.00   0.5000    5.0000
omega____ theta____ kappa____ phi______ frames
    -       16.0852   19.0000  -90.0000 72

#__ type_ start__ end____ width___ exp.time_
  3 omega  -44.00   44.00   0.5000    5.0000
omega____ theta____ kappa____ phi______ frames
    -       16.0852  -19.0000 -120.0000 176
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0062282000
_diffrn_orient_matrix_UB_12      -0.0703785000
_diffrn_orient_matrix_UB_13      0.0123225000
_diffrn_orient_matrix_UB_21      0.0067123000
_diffrn_orient_matrix_UB_22      0.0393035000
_diffrn_orient_matrix_UB_23      0.0214769000
_diffrn_orient_matrix_UB_31      -0.0460272000
_diffrn_orient_matrix_UB_32      0.0151437000
_diffrn_orient_matrix_UB_33      0.0014725000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Enhance (Mo) X-ray Source'
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         ?
_reflns_number_gt                2797
_reflns_number_total             3611
_reflns_odcompleteness_completeness 99.55
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     25.07
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_molecular_graphics    
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material  
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    
'A short history of SHELX (Sheldrick, 2007)/Bruker'
_refine_diff_density_max         0.197
_refine_diff_density_min         -0.221
_refine_diff_density_rms         0.045
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     272
_refine_ls_number_reflns         3611
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0611
_refine_ls_R_factor_gt           0.0431
_refine_ls_restrained_S_all      1.045
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0402P)²+0.5763P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0920
_refine_ls_wR_factor_ref         0.1028
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
F1 F 0.08518(6) 0.33309(12) 0.36641(4) 0.0378(3) Uani 1 1 d . . .
O2 O -0.07837(7) 0.83779(15) 0.49817(4) 0.0295(3) Uani 1 1 d . . .
F2 F 0.19203(6) 0.36883(14) 0.41661(4) 0.0425(3) Uani 1 1 d . . .
N2 N 0.29639(8) 0.66378(17) 0.27970(5) 0.0205(3) Uani 1 1 d . . .
N1 N 0.23216(8) 0.83115(17) 0.21093(5) 0.0210(3) Uani 1 1 d . . .
H1 H 0.2862 0.8035 0.2154 0.025 Uiso 1 1 calc R . .
O1 O 0.14609(7) 0.99236(15) 0.16736(4) 0.0286(3) Uani 1 1 d . . .
C5 C 0.20599(10) 0.6744(2) 0.27796(5) 0.0185(4) Uani 1 1 d . . .
C4 C 0.16951(10) 0.7614(2) 0.24021(5) 0.0198(4) Uani 1 1 d . . .
C11 C 0.07699(10) 0.5496(2) 0.41613(6) 0.0221(4) Uani 1 1 d . . .
C6 C 0.14882(10) 0.6026(2) 0.31099(6) 0.0199(4) Uani 1 1 d . . .
C14 C -0.03041(10) 0.7370(2) 0.47137(6) 0.0231(4) Uani 1 1 d . . .
C7 C 0.19075(10) 0.5230(2) 0.34883(6) 0.0219(4) Uani 1 1 d . . .
C20 C 0.36271(11) 1.1524(2) 0.09130(6) 0.0267(4) Uani 1 1 d . . .
H20 H 0.3566 1.2352 0.0708 0.032 Uiso 1 1 calc R . .
C16 C 0.11266(11) 0.6748(2) 0.44020(6) 0.0249(4) Uani 1 1 d . . .
H16 H 0.1728 0.6961 0.4377 0.030 Uiso 1 1 calc R . .
C19 C 0.29123(11) 1.1048(2) 0.11810(6) 0.0231(4) Uani 1 1 d . . .
H19 H 0.2374 1.1562 0.1155 0.028 Uiso 1 1 calc R . .
C8 C 0.28104(10) 0.5143(2) 0.35010(6) 0.0240(4) Uani 1 1 d . . .
H8 H 0.3093 0.4625 0.3744 0.029 Uiso 1 1 calc R . .
C24 C -0.17221(10) 0.8354(2) 0.49228(7) 0.0317(5) Uani 1 1 d . . .
H24A H -0.1864 0.8503 0.4599 0.048 Uiso 1 1 calc R . .
H24B H -0.1983 0.9167 0.5105 0.048 Uiso 1 1 calc R . .
H24C H -0.1950 0.7375 0.5025 0.048 Uiso 1 1 calc R . .
C23 C 0.38016(10) 0.9041(2) 0.15172(6) 0.0231(4) Uani 1 1 d . . .
H23 H 0.3861 0.8198 0.1717 0.028 Uiso 1 1 calc R . .
C9 C 0.33087(11) 0.5845(2) 0.31436(6) 0.0240(4) Uani 1 1 d . . .
H9 H 0.3921 0.5741 0.3153 0.029 Uiso 1 1 calc R . .
C13 C -0.06622(10) 0.6119(2) 0.44789(6) 0.0241(4) Uani 1 1 d . . .
H13 H -0.1263 0.5902 0.4505 0.029 Uiso 1 1 calc R . .
C12 C -0.01254(10) 0.5193(2) 0.42046(6) 0.0237(4) Uani 1 1 d . . .
H12 H -0.0370 0.4355 0.4047 0.028 Uiso 1 1 calc R . .
C15 C 0.05999(10) 0.7676(2) 0.46773(6) 0.0254(4) Uani 1 1 d . . .
H15 H 0.0846 0.8505 0.4839 0.030 Uiso 1 1 calc R . .
C21 C 0.44316(11) 1.0769(2) 0.09496(6) 0.0279(4) Uani 1 1 d . . .
H21 H 0.4913 1.1095 0.0773 0.033 Uiso 1 1 calc R . .
C22 C 0.45152(11) 0.9525(2) 0.12507(6) 0.0255(4) Uani 1 1 d . . .
H22 H 0.5054 0.9012 0.1274 0.031 Uiso 1 1 calc R . .
C3 C 0.07959(10) 0.7672(2) 0.23391(6) 0.0229(4) Uani 1 1 d . . .
H3 H 0.0557 0.8208 0.2087 0.027 Uiso 1 1 calc R . .
C18 C 0.29934(10) 0.9814(2) 0.14872(5) 0.0202(4) Uani 1 1 d . . .
C1 C 0.05628(10) 0.6133(2) 0.30380(6) 0.0233(4) Uani 1 1 d . . .
H1A H 0.0175 0.5671 0.3249 0.028 Uiso 1 1 calc R . .
C2 C 0.02395(10) 0.6912(2) 0.26596(6) 0.0254(4) Uani 1 1 d . . .
H2 H -0.0369 0.6942 0.2612 0.031 Uiso 1 1 calc R . .
C17 C 0.21884(10) 0.9369(2) 0.17634(6) 0.0208(4) Uani 1 1 d . . .
C10 C 0.13510(11) 0.4473(2) 0.38681(6) 0.0268(4) Uani 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F1 C10 1.373(2) . ?
O2 C14 1.369(2) . ?
O2 C24 1.4285(19) . ?
F2 C10 1.3879(19) . ?
N2 C5 1.3705(19) . ?
N2 C9 1.313(2) . ?
N1 H1 0.8600 . ?
N1 C4 1.400(2) . ?
N1 C17 1.362(2) . ?
O1 C17 1.2269(19) . ?
C5 C4 1.426(2) . ?
C5 C6 1.423(2) . ?
C4 C3 1.372(2) . ?
C11 C16 1.392(2) . ?
C11 C12 1.384(2) . ?
C11 C10 1.502(2) . ?
C6 C7 1.430(2) . ?
C6 C1 1.417(2) . ?
C14 C13 1.383(2) . ?
C14 C15 1.396(2) . ?
C7 C8 1.367(2) . ?
C7 C10 1.522(2) . ?
C20 H20 0.9300 . ?
C20 C19 1.387(2) . ?
C20 C21 1.384(2) . ?
C16 H16 0.9300 . ?
C16 C15 1.378(2) . ?
C19 H19 0.9300 . ?
C19 C18 1.386(2) . ?
C8 H8 0.9300 . ?
C8 C9 1.407(2) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C23 H23 0.9300 . ?
C23 C22 1.386(2) . ?
C23 C18 1.395(2) . ?
C9 H9 0.9300 . ?
C13 H13 0.9300 . ?
C13 C12 1.384(2) . ?
C12 H12 0.9300 . ?
C15 H15 0.9300 . ?
C21 H21 0.9300 . ?
C21 C22 1.383(3) . ?
C22 H22 0.9300 . ?
C3 H3 0.9300 . ?
C3 C2 1.407(2) . ?
C18 C17 1.501(2) . ?
C1 H1A 0.9300 . ?
C1 C2 1.365(2) . ?
C2 H2 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C14 O2 C24 116.79(13) . . ?
C9 N2 C5 117.28(14) . . ?
C4 N1 H1 115.7 . . ?
C17 N1 H1 115.7 . . ?
C17 N1 C4 128.56(13) . . ?
N2 C5 C4 116.64(14) . . ?
N2 C5 C6 123.50(15) . . ?
C6 C5 C4 119.85(14) . . ?
N1 C4 C5 114.71(13) . . ?
C3 C4 N1 125.15(15) . . ?
C3 C4 C5 120.09(15) . . ?
C16 C11 C10 120.52(14) . . ?
C12 C11 C16 118.81(16) . . ?
C12 C11 C10 120.66(16) . . ?
C5 C6 C7 116.29(14) . . ?
C1 C6 C5 118.35(15) . . ?
C1 C6 C7 125.35(15) . . ?
O2 C14 C13 124.23(14) . . ?
O2 C14 C15 116.06(16) . . ?
C13 C14 C15 119.70(16) . . ?
C6 C7 C10 120.12(13) . . ?
C8 C7 C6 119.27(15) . . ?
C8 C7 C10 120.60(15) . . ?
C19 C20 H20 119.9 . . ?
C21 C20 H20 119.9 . . ?
C21 C20 C19 120.19(17) . . ?
C11 C16 H16 119.6 . . ?
C15 C16 C11 120.79(15) . . ?
C15 C16 H16 119.6 . . ?
C20 C19 H19 119.7 . . ?
C18 C19 C20 120.55(16) . . ?
C18 C19 H19 119.7 . . ?
C7 C8 H8 120.3 . . ?
C7 C8 C9 119.43(16) . . ?
C9 C8 H8 120.3 . . ?
O2 C24 H24A 109.5 . . ?
O2 C24 H24B 109.5 . . ?
O2 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C22 C23 H23 119.9 . . ?
C22 C23 C18 120.19(17) . . ?
C18 C23 H23 119.9 . . ?
N2 C9 C8 124.12(15) . . ?
N2 C9 H9 117.9 . . ?
C8 C9 H9 117.9 . . ?
C14 C13 H13 120.1 . . ?
C14 C13 C12 119.88(15) . . ?
C12 C13 H13 120.1 . . ?
C11 C12 C13 120.96(17) . . ?
C11 C12 H12 119.5 . . ?
C13 C12 H12 119.5 . . ?
C14 C15 H15 120.1 . . ?
C16 C15 C14 119.85(17) . . ?
C16 C15 H15 120.1 . . ?
C20 C21 H21 120.2 . . ?
C22 C21 C20 119.61(16) . . ?
C22 C21 H21 120.2 . . ?
C23 C22 H22 119.8 . . ?
C21 C22 C23 120.41(16) . . ?
C21 C22 H22 119.8 . . ?
C4 C3 H3 120.3 . . ?
C4 C3 C2 119.33(16) . . ?
C2 C3 H3 120.3 . . ?
C19 C18 C23 119.04(15) . . ?
C19 C18 C17 117.26(15) . . ?
C23 C18 C17 123.69(16) . . ?
C6 C1 H1A 120.0 . . ?
C2 C1 C6 120.04(16) . . ?
C2 C1 H1A 120.0 . . ?
C3 C2 H2 118.9 . . ?
C1 C2 C3 122.20(15) . . ?
C1 C2 H2 118.9 . . ?
N1 C17 C18 115.74(14) . . ?
O1 C17 N1 123.16(15) . . ?
O1 C17 C18 121.09(15) . . ?
F1 C10 F2 104.47(14) . . ?
F1 C10 C11 109.85(13) . . ?
F1 C10 C7 108.08(14) . . ?
F2 C10 C11 107.93(14) . . ?
F2 C10 C7 107.80(13) . . ?
C11 C10 C7 117.88(15) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 C14 C13 C12 178.00(15) . . . . ?
O2 C14 C15 C16 -177.88(15) . . . . ?
N2 C5 C4 N1 -2.9(2) . . . . ?
N2 C5 C4 C3 174.80(15) . . . . ?
N2 C5 C6 C7 3.4(2) . . . . ?
N2 C5 C6 C1 -175.86(16) . . . . ?
N1 C4 C3 C2 179.74(16) . . . . ?
C5 N2 C9 C8 -1.8(3) . . . . ?
C5 C4 C3 C2 2.3(3) . . . . ?
C5 C6 C7 C8 -2.9(2) . . . . ?
C5 C6 C7 C10 177.91(15) . . . . ?
C5 C6 C1 C2 -0.1(3) . . . . ?
C4 N1 C17 O1 3.4(3) . . . . ?
C4 N1 C17 C18 -175.76(15) . . . . ?
C4 C5 C6 C7 -177.49(15) . . . . ?
C4 C5 C6 C1 3.3(2) . . . . ?
C4 C3 C2 C1 1.0(3) . . . . ?
C11 C16 C15 C14 -0.5(3) . . . . ?
C6 C5 C4 N1 177.88(15) . . . . ?
C6 C5 C4 C3 -4.4(2) . . . . ?
C6 C7 C8 C9 0.4(3) . . . . ?
C6 C7 C10 F1 62.9(2) . . . . ?
C6 C7 C10 F2 175.29(15) . . . . ?
C6 C7 C10 C11 -62.3(2) . . . . ?
C6 C1 C2 C3 -2.1(3) . . . . ?
C14 C13 C12 C11 0.1(3) . . . . ?
C7 C6 C1 C2 -179.27(17) . . . . ?
C7 C8 C9 N2 2.2(3) . . . . ?
C20 C19 C18 C23 -0.9(2) . . . . ?
C20 C19 C18 C17 -179.85(15) . . . . ?
C20 C21 C22 C23 -0.4(3) . . . . ?
C16 C11 C12 C13 0.4(3) . . . . ?
C16 C11 C10 F1 -179.60(15) . . . . ?
C16 C11 C10 F2 67.1(2) . . . . ?
C16 C11 C10 C7 -55.2(2) . . . . ?
C19 C20 C21 C22 0.8(3) . . . . ?
C19 C18 C17 N1 -170.61(14) . . . . ?
C19 C18 C17 O1 10.3(2) . . . . ?
C8 C7 C10 F1 -116.28(17) . . . . ?
C8 C7 C10 F2 -3.9(2) . . . . ?
C8 C7 C10 C11 118.49(18) . . . . ?
C24 O2 C14 C13 -15.6(2) . . . . ?
C24 O2 C14 C15 163.29(16) . . . . ?
C23 C18 C17 N1 10.5(2) . . . . ?
C23 C18 C17 O1 -168.61(16) . . . . ?
C9 N2 C5 C4 179.77(15) . . . . ?
C9 N2 C5 C6 -1.1(2) . . . . ?
C13 C14 C15 C16 1.1(3) . . . . ?
C12 C11 C16 C15 -0.2(3) . . . . ?
C12 C11 C10 F1 1.7(2) . . . . ?
C12 C11 C10 F2 -111.65(17) . . . . ?
C12 C11 C10 C7 126.03(17) . . . . ?
C15 C14 C13 C12 -0.9(3) . . . . ?
C21 C20 C19 C18 -0.1(3) . . . . ?
C22 C23 C18 C19 1.3(2) . . . . ?
C22 C23 C18 C17 -179.87(15) . . . . ?
C18 C23 C22 C21 -0.6(3) . . . . ?
C1 C6 C7 C8 176.29(17) . . . . ?
C1 C6 C7 C10 -2.9(3) . . . . ?
C17 N1 C4 C5 -170.21(15) . . . . ?
C17 N1 C4 C3 12.2(3) . . . . ?
C10 C11 C16 C15 -178.96(16) . . . . ?
C10 C11 C12 C13 179.18(15) . . . . ?
C10 C7 C8 C9 179.56(16) . . . . ?

