# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_z
_audit_block_doi                 10.5517/ccdc.csd.cc256yn0
_database_code_depnum_ccdc_archive 'CCDC 2002682'
loop_
_citation_id
_citation_doi
_citation_year
1 10.1039/D0DT02730H 2020
_audit_update_record             
;
2020-09-24 deposited with the CCDC.	2021-02-15 downloaded from the CCDC.
;
_audit_creation_date             2020-09-23
_audit_creation_method           
;
Olex2 1.3-dev
(compiled 2020.09.11 svn.rc89507dd for OlexSys, GUI svn.r5830)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         
'C29 H11 Eu N O13 Zn, 1[C3H7NO], 1[C3H7NO], 1[H2O]'
_chemical_formula_sum            'C35 H27 Eu N3 O16 Zn'
_chemical_formula_weight         962.92
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           166
_space_group_name_H-M_alt        'R -3 m'
_space_group_name_Hall           '-R 3 2"'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+1/3'
'x-y+2/3, -y+1/3, -z+1/3'
'-x+2/3, -x+y+1/3, -z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+2/3'
'x-y+1/3, -y+2/3, -z+2/3'
'-x+1/3, -x+y+2/3, -z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z'
'-x+y, y, z'
'x, x-y, z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-y+2/3, -x+1/3, z+1/3'
'-x+y+2/3, y+1/3, z+1/3'
'x+2/3, x-y+1/3, z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-y+1/3, -x+2/3, z+2/3'
'-x+y+1/3, y+2/3, z+2/3'
'x+1/3, x-y+2/3, z+2/3'

_cell_length_a                   47.9882(19)
_cell_length_b                   47.9882(19)
_cell_length_c                   13.3456(10)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     26616(3)
_cell_formula_units_Z            18
_cell_measurement_reflns_used    9723
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.33
_cell_measurement_theta_min      2.94
_shelx_estimated_absorpt_T_max   0.889
_shelx_estimated_absorpt_T_min   0.840
_exptl_absorpt_coefficient_mu    1.505
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.3931
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1366 before and 0.0798 after correction. The Ratio of minimum to maximum transmission is 0.5272. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.081
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             8622
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.08
_exptl_special_details           
;
 ? 
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0715
_diffrn_reflns_av_unetI/netI     0.0251
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       57
_diffrn_reflns_limit_h_min       -57
_diffrn_reflns_limit_k_max       57
_diffrn_reflns_limit_k_min       -57
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            119786
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.099
_diffrn_reflns_theta_max         25.099
_diffrn_reflns_theta_min         2.941
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4757
_reflns_number_total             5475
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 1.3-dev (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3-dev (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.401
_refine_diff_density_min         -1.302
_refine_diff_density_rms         0.085
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.093
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     244
_refine_ls_number_reflns         5475
_refine_ls_number_restraints     126
_refine_ls_R_factor_all          0.0544
_refine_ls_R_factor_gt           0.0469
_refine_ls_restrained_S_all      1.093
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0471P)²+210.8381P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1116
_refine_ls_wR_factor_ref         0.1159
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Restrained distances
 C18-O1 = C18-O2
 1.226 with sigma of 0.001
 C17-C18
 1.514 with sigma of 0.001
3. Uiso/Uaniso restraints and constraints
Uanis(C17) \\sim Ueq, Uanis(C16) \\sim Ueq, Uanis(C13) \\sim Ueq, Uanis(C14)
\\sim Ueq, Uanis(O5) \\sim Ueq, Uanis(O1) \\sim Ueq: with sigma of 0.01 and
sigma for terminal atoms of 0.02
4. Rigid body (RIGU) restrains
 C17, O2, C18, O1
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 C17, C13, C12, C14, C15, C16, C19, O3, O4, C11
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
5. Others
 Fixed Sof: C12(0.5) C17(0.5) C16(0.5) H16(0.5) C15(0.5) C14(0.5) H14(0.5)
 C13(0.5) H13(0.5) O2(0.5) C18(0.5) O1(0.5)
6.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C6(H6), C10(H10), C16(H16), C14(H14), C13(H13)
6.b Fitted hexagon refined as free rotating group:
 C12(C17,C16,C15,C14,C13)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.49631(12) 0.64914(12) 0.4358(3) 0.0490(12) Uani 1 1 d . . . . .
C2 C 0.51403(14) 0.66409(14) 0.5206(4) 0.0637(16) Uani 1 1 d . . . . .
H2 H 0.513321 0.651858 0.575641 0.076 Uiso 1 1 calc R U . . .
C3 C 0.53260(14) 0.69684(14) 0.5237(4) 0.0656(16) Uani 1 1 d . . . . .
H3 H 0.544392 0.706566 0.581266 0.079 Uiso 1 1 calc R U . . .
C4 C 0.53438(11) 0.71613(13) 0.4429(3) 0.0477(12) Uani 1 1 d . . . . .
C5 C 0.51667(11) 0.70066(12) 0.3566(3) 0.0455(11) Uani 1 1 d . . . . .
C6 C 0.49814(12) 0.66785(12) 0.3541(3) 0.0480(12) Uani 1 1 d . . . . .
H6 H 0.486536 0.657890 0.296476 0.058 Uiso 1 1 calc R U . . .
C7 C 0.51910(11) 0.71960(12) 0.2636(3) 0.0442(11) Uani 1 1 d . . . . .
C9 C 0.55236(11) 0.75136(13) 0.4538(3) 0.0444(11) Uani 1 1 d . . . . .
C10 C 0.58388(10) 0.76701(11) 0.4830(3) 0.0389(10) Uani 1 1 d . . . . .
H10 H 0.594551 0.755547 0.493277 0.047 Uiso 1 1 calc R U . . .
C11 C 0.59982(14) 0.79991(7) 0.4972(4) 0.0433(16) Uani 1 2 d S T P . .
C12 C 0.63335(7) 0.81647(18) 0.5338(3) 0.0439(16) Uani 0.5 1 d G . P A -1
C17 C 0.64029(9) 0.82939(16) 0.6299(3) 0.0381(19) Uani 0.5 1 d DG U P A -1
C16 C 0.67193(10) 0.84570(14) 0.6635(3) 0.042(2) Uani 0.5 1 d G U P A -1
H16 H 0.676580 0.854348 0.727783 0.050 Uiso 0.5 1 calc R U P A -1
C15 C 0.69664(7) 0.84910(19) 0.6011(3) 0.0450(16) Uani 0.5 1 d G . P A -1
C14 C 0.68969(9) 0.83618(17) 0.5051(3) 0.047(3) Uani 0.5 1 d G U P A -1
H14 H 0.706223 0.838447 0.463331 0.057 Uiso 0.5 1 calc R U P A -1
C13 C 0.65805(10) 0.81987(16) 0.4714(3) 0.048(3) Uani 0.5 1 d G U P A -1
H13 H 0.653404 0.811223 0.407139 0.058 Uiso 0.5 1 calc R U P A -1
C19 C 0.73072(15) 0.86536(7) 0.6406(5) 0.0489(17) Uani 1 2 d S T P . .
C8 C 0.47600(12) 0.61346(12) 0.4303(3) 0.0443(11) Uani 1 1 d . . . . .
Eu1 Eu 0.42913(2) 0.57087(2) 0.22254(2) 0.03502(12) Uani 1 2 d S T P . .
N1 N 0.53595(15) 0.76797(8) 0.4390(4) 0.0594(17) Uani 1 2 d S T P . .
O3 O 0.73363(11) 0.86681(6) 0.7338(4) 0.083(2) Uani 1 2 d S T P A .
O4 O 0.75269(11) 0.87634(5) 0.5783(3) 0.0630(15) Uani 1 2 d S T P A .
O5 O 0.49488(9) 0.71330(11) 0.2151(3) 0.0883(15) Uani 1 1 d . U . . .
O6 O 0.54590(9) 0.74062(11) 0.2349(3) 0.0714(12) Uani 1 1 d . . . . .
O7 O 0.46453(10) 0.60107(9) 0.3477(3) 0.0658(11) Uani 1 1 d . . . . .
O8 O 0.47185(10) 0.59761(9) 0.5087(2) 0.0583(9) Uani 1 1 d . . . . .
O1W O 0.40248(7) 0.59752(7) 0.2914(4) 0.086(2) Uani 1 2 d S T P . .
Zn1 Zn 0.76719(2) 0.88359(2) 0.83288(5) 0.0422(2) Uani 1 2 d S T P . .
O2 O 0.59188(10) 0.7963(2) 0.7120(3) 0.0534(13) Uani 0.5 1 d D . P A -1
C18 C 0.61415(14) 0.82406(18) 0.7038(5) 0.048(2) Uani 0.5 1 d D . P A -1
O1 O 0.6174(2) 0.84749(19) 0.7506(8) 0.101(3) Uani 0.5 1 d D U P A -1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.382(6) . ?
C1 C6 1.387(6) . ?
C1 C8 1.489(7) . ?
C2 H2 0.9300 . ?
C2 C3 1.366(8) . ?
C3 H3 0.9300 . ?
C3 C4 1.395(7) . ?
C4 C5 1.403(6) . ?
C4 C9 1.472(7) . ?
C5 C6 1.368(7) . ?
C5 C7 1.508(6) . ?
C6 H6 0.9300 . ?
C7 Eu1 2.810(4) 27 ?
C7 O5 1.229(6) . ?
C7 O6 1.233(6) . ?
C9 C10 1.367(6) . ?
C9 N1 1.387(6) . ?
C10 H10 0.9300 . ?
C10 C11 1.381(5) . ?
C11 C12 1.476(6) . ?
C12 C17 1.3900 . ?
C12 C13 1.3900 . ?
C17 C16 1.3900 . ?
C17 C18 1.5136(10) . ?
C16 H16 0.9300 . ?
C16 C15 1.3900 . ?
C15 C14 1.3900 . ?
C15 C19 1.512(7) . ?
C14 H14 0.9300 . ?
C14 C13 1.3900 . ?
C13 H13 0.9300 . ?
C19 O3 1.250(8) . ?
C19 O4 1.235(8) . ?
C8 O7 1.243(5) . ?
C8 O8 1.249(5) . ?
Eu1 O4 2.335(4) 14_654 ?
Eu1 O5 2.487(4) 11_565 ?
Eu1 O5 2.487(4) 26_455 ?
Eu1 O6 2.431(4) 26_455 ?
Eu1 O6 2.431(4) 11_565 ?
Eu1 O7 2.305(3) . ?
Eu1 O7 2.305(3) 22_665 ?
Eu1 O1W 2.398(5) . ?
O3 Zn1 1.922(5) . ?
O8 Zn1 1.973(4) 14_654 ?
O2 C18 1.2260(10) . ?
C18 O1 1.2258(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 118.9(5) . . ?
C2 C1 C8 121.1(4) . . ?
C6 C1 C8 120.0(4) . . ?
C1 C2 H2 120.0 . . ?
C3 C2 C1 120.0(5) . . ?
C3 C2 H2 120.0 . . ?
C2 C3 H3 119.0 . . ?
C2 C3 C4 121.9(5) . . ?
C4 C3 H3 119.0 . . ?
C3 C4 C5 117.6(5) . . ?
C3 C4 C9 119.5(4) . . ?
C5 C4 C9 122.8(4) . . ?
C4 C5 C7 120.9(4) . . ?
C6 C5 C4 120.1(4) . . ?
C6 C5 C7 118.9(4) . . ?
C1 C6 H6 119.3 . . ?
C5 C6 C1 121.4(4) . . ?
C5 C6 H6 119.3 . . ?
C5 C7 Eu1 171.1(3) . 27 ?
O5 C7 C5 120.4(4) . . ?
O5 C7 Eu1 62.2(3) . 27 ?
O5 C7 O6 120.6(4) . . ?
O6 C7 C5 118.9(4) . . ?
O6 C7 Eu1 59.6(3) . 27 ?
C10 C9 C4 120.8(4) . . ?
C10 C9 N1 121.0(5) . . ?
N1 C9 C4 118.1(4) . . ?
C9 C10 H10 120.1 . . ?
C9 C10 C11 119.7(5) . . ?
C11 C10 H10 120.1 . . ?
C10 C11 C10 120.1(5) . 24_565 ?
C10 C11 C12 119.5(4) . . ?
C10 C11 C12 120.2(4) 24_565 . ?
C17 C12 C11 119.9(4) . . ?
C17 C12 C13 120.0 . . ?
C13 C12 C11 120.1(4) . . ?
C12 C17 C18 122.2(4) . . ?
C16 C17 C12 120.0 . . ?
C16 C17 C18 117.7(4) . . ?
C17 C16 H16 120.0 . . ?
C17 C16 C15 120.0 . . ?
C15 C16 H16 120.0 . . ?
C16 C15 C19 119.4(4) . . ?
C14 C15 C16 120.0 . . ?
C14 C15 C19 120.5(4) . . ?
C15 C14 H14 120.0 . . ?
C15 C14 C13 120.0 . . ?
C13 C14 H14 120.0 . . ?
C12 C13 H13 120.0 . . ?
C14 C13 C12 120.0 . . ?
C14 C13 H13 120.0 . . ?
O3 C19 C15 115.9(5) . . ?
O4 C19 C15 117.3(5) . . ?
O4 C19 O3 126.8(6) . . ?
O7 C8 C1 118.2(4) . . ?
O7 C8 O8 123.6(5) . . ?
O8 C8 C1 118.2(4) . . ?
C7 Eu1 C7 86.1(2) 26_455 11_565 ?
O4 Eu1 C7 100.30(13) 14_654 11_565 ?
O4 Eu1 C7 100.30(13) 14_654 26_455 ?
O4 Eu1 O5 124.76(12) 14_654 11_565 ?
O4 Eu1 O5 124.76(12) 14_654 26_455 ?
O4 Eu1 O6 74.45(12) 14_654 26_455 ?
O4 Eu1 O6 74.46(12) 14_654 11_565 ?
O4 Eu1 O1W 150.11(18) 14_654 . ?
O5 Eu1 C7 25.92(12) 26_455 26_455 ?
O5 Eu1 C7 89.98(17) 26_455 11_565 ?
O5 Eu1 C7 25.92(12) 11_565 11_565 ?
O5 Eu1 C7 89.98(17) 11_565 26_455 ?
O5 Eu1 O5 82.4(3) 26_455 11_565 ?
O6 Eu1 C7 25.96(12) 11_565 11_565 ?
O6 Eu1 C7 88.38(14) 11_565 26_455 ?
O6 Eu1 C7 88.38(14) 26_455 11_565 ?
O6 Eu1 C7 25.96(12) 26_455 26_455 ?
O6 Eu1 O5 51.55(12) 26_455 26_455 ?
O6 Eu1 O5 102.64(16) 26_455 11_565 ?
O6 Eu1 O5 102.64(16) 11_565 26_455 ?
O6 Eu1 O5 51.55(12) 11_565 11_565 ?
O6 Eu1 O6 79.3(2) 26_455 11_565 ?
O7 Eu1 C7 93.91(14) . 11_565 ?
O7 Eu1 C7 93.91(14) 22_665 26_455 ?
O7 Eu1 C7 179.57(15) 22_665 11_565 ?
O7 Eu1 C7 179.57(15) . 26_455 ?
O7 Eu1 O4 79.28(13) 22_665 14_654 ?
O7 Eu1 O4 79.29(13) . 14_654 ?
O7 Eu1 O5 154.51(14) 22_665 11_565 ?
O7 Eu1 O5 90.18(16) . 11_565 ?
O7 Eu1 O5 90.18(16) 22_665 26_455 ?
O7 Eu1 O5 154.51(14) . 26_455 ?
O7 Eu1 O6 153.61(14) 22_665 11_565 ?
O7 Eu1 O6 153.62(14) . 26_455 ?
O7 Eu1 O6 91.41(15) . 11_565 ?
O7 Eu1 O6 91.40(15) 22_665 26_455 ?
O7 Eu1 O7 86.11(19) 22_665 . ?
O7 Eu1 O1W 78.99(15) . . ?
O7 Eu1 O1W 79.00(15) 22_665 . ?
O1W Eu1 C7 101.43(14) . 11_565 ?
O1W Eu1 C7 101.43(14) . 26_455 ?
O1W Eu1 O5 75.54(14) . 11_565 ?
O1W Eu1 O5 75.54(14) . 26_455 ?
O1W Eu1 O6 126.30(13) . 26_455 ?
O1W Eu1 O6 126.30(13) . 11_565 ?
C9 N1 C9 118.4(6) . 24_565 ?
C19 O3 Zn1 139.0(5) . . ?
C19 O4 Eu1 145.1(4) . 9_565 ?
C7 O5 Eu1 91.9(3) . 27 ?
C7 O6 Eu1 94.4(3) . 27 ?
C8 O7 Eu1 162.6(4) . . ?
C8 O8 Zn1 118.7(3) . 14_654 ?
O3 Zn1 O8 115.36(12) . 29 ?
O3 Zn1 O8 115.37(12) . 9_565 ?
O8 Zn1 O8 115.3(2) 9_565 29 ?
O2 C18 C17 116.1(4) . . ?
O1 C18 C17 117.5(6) . . ?
O1 C18 O2 126.4(6) . . ?

_platon_squeeze_details          ?
_platon_squeeze_special_details  
;
A solvent mask was calculated and 1413 electrons were 
found in a volume of 15637Å³ in 3 voids per unit cell. 
This is consistent with the presence of 1[DMF] in one void
and another  1[DMF] in another void -- there may also be 1[H2O]
per Formula Unit.  This accounts for 1620 electrons per unit cell,
which is not quite what has beem measured, but it is a good
estimate.
;
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 -0.004 1871 229 '6 DMF'
2 0.000 0.333 0.492 1671 121 '3.6 DMF'
3 0.000 0.667 -0.006 1671 121 '3.6 DMF'
4 0.333 0.667 0.681 1871 229 '6 DMF'
5 0.333 0.333 0.615 1669 121 '18 H2O'
6 0.333 1.000 0.552 1671 121 '3.6 DMF'
7 0.667 0.333 0.348 1871 229 '6 DMF'
8 0.667 0.667 0.218 1671 121 '3.6 DMF'
9 0.667 1.000 0.282 1671 121 '3.6 DMF'

_platon_squeeze_void_probe_radius 1.20
_olex2_submission_special_instructions 'No special instructions were received'
