# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_last-1
_database_code_depnum_ccdc_archive 'CCDC 1521675'
_audit_update_record             
;
2017-04-24 deposited with the CCDC.	2021-09-20 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H18 Eu2 N6 O10'
_chemical_formula_weight         854.38

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 2(1)/n'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   7.4220(3)
_cell_length_b                   25.7340(10)
_cell_length_c                   13.2847(8)
_cell_angle_alpha                90.00
_cell_angle_beta                 100.008(5)
_cell_angle_gamma                90.00
_cell_volume                     2498.7(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    180(2)
_cell_measurement_reflns_used    2537
_cell_measurement_theta_min      3.1600
_cell_measurement_theta_max      27.0120

_exptl_crystal_description       column
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.111
_exptl_crystal_size_mid          0.029
_exptl_crystal_size_min          0.018
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.276
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1648
_exptl_absorpt_coefficient_mu    5.048
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_correction_T_min  0.760
_exptl_absorpt_correction_T_max  0.926
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      180(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, AtlasCCD'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            9563
_diffrn_reflns_av_R_equivalents  0.0594
_diffrn_reflns_av_sigmaI/netI    0.0970
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_theta_min         3.49
_diffrn_reflns_theta_max         25.03
_reflns_number_total             4385
_reflns_number_gt                3212
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0408P)²+1.2013P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4385
_refine_ls_number_parameters     175
_refine_ls_number_restraints     7
_refine_ls_R_factor_all          0.0880
_refine_ls_R_factor_gt           0.0543
_refine_ls_wR_factor_ref         0.1199
_refine_ls_wR_factor_gt          0.1054
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_restrained_S_all      1.090
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu -0.07436(6) 0.45705(2) 0.10317(4) 0.01314(17) Uani 1 1 d . . .
Eu2 Eu 0.38312(6) 0.43531(2) 0.02762(4) 0.01275(17) Uani 1 1 d . . .
O1 O 0.1462(8) 0.3846(3) 0.1089(6) 0.0169(6) Uani 1 1 d . . .
O2 O 0.5007(8) 0.3649(3) 0.1279(6) 0.0169(6) Uani 1 1 d . . .
O3 O -0.0031(9) 0.4985(3) 0.2719(6) 0.0251(18) Uani 1 1 d U . .
O4 O 0.2501(8) 0.4826(3) 0.1562(6) 0.0169(6) Uani 1 1 d . . .
O5 O 0.3664(8) 0.3769(3) -0.1118(6) 0.0169(6) Uani 1 1 d . . .
O6 O 0.6834(8) 0.4192(3) -0.0240(6) 0.0169(6) Uani 1 1 d . . .
O7 O -0.0755(9) 0.5427(3) 0.0409(5) 0.0169(6) Uani 1 1 d . . .
O8 O -0.3789(8) 0.4921(3) 0.0997(6) 0.0169(6) Uani 1 1 d . . .
O9 O -0.1714(9) 0.3951(3) 0.2183(5) 0.0169(6) Uani 1 1 d . . .
H9 H -0.2861 0.3932 0.2072 0.025 Uiso 1 1 calc R . .
N1 N 0.1205(11) 0.3304(3) 0.2420(7) 0.0198(8) Uani 1 1 d . . .
H1A H 0.0042 0.3383 0.2386 0.024 Uiso 1 1 calc R . .
N2 N 0.4875(11) 0.3027(3) 0.2485(7) 0.0198(8) Uani 1 1 d . . .
H2A H 0.6015 0.2934 0.2482 0.024 Uiso 1 1 calc R . .
N3 N 0.2066(13) 0.5341(3) 0.3965(7) 0.0266(9) Uani 1 1 d . . .
H3A H 0.1243 0.5383 0.4361 0.032 Uiso 1 1 calc R . .
N4 N 0.4704(13) 0.5219(4) 0.2754(7) 0.0266(9) Uani 1 1 d . . .
N5 N 0.5025(11) 0.3406(3) -0.2345(7) 0.0170(8) Uani 1 1 d . . .
H5A H 0.4026 0.3230 -0.2584 0.020 Uiso 1 1 calc R . .
N6 N 0.8266(11) 0.3893(3) -0.1531(7) 0.0170(8) Uani 1 1 d . . .
H6A H 0.9302 0.4046 -0.1266 0.020 Uiso 1 1 calc R . .
C1 C 0.2152(13) 0.3510(4) 0.1800(9) 0.0198(8) Uani 1 1 d . . .
C2 C 0.4091(13) 0.3381(4) 0.1855(9) 0.0198(8) Uani 1 1 d . . .
C3 C 0.3900(13) 0.2801(4) 0.3151(9) 0.0198(8) Uani 1 1 d . . .
C4 C 0.2065(13) 0.2952(4) 0.3145(9) 0.0198(8) Uani 1 1 d . . .
C5 C 0.1137(14) 0.2749(4) 0.3892(9) 0.0198(8) Uani 1 1 d . . .
H5B H -0.0060 0.2869 0.3930 0.024 Uiso 1 1 calc R . .
C6 C 0.1946(13) 0.2381(4) 0.4568(9) 0.0198(8) Uani 1 1 d . . .
H6B H 0.1291 0.2232 0.5052 0.024 Uiso 1 1 calc R . .
C7 C 0.3722(13) 0.2226(4) 0.4542(9) 0.0198(8) Uani 1 1 d . . .
H7B H 0.4281 0.1972 0.5015 0.024 Uiso 1 1 calc R . .
C8 C 0.4682(14) 0.2428(4) 0.3857(9) 0.0198(8) Uani 1 1 d . . .
H8B H 0.5900 0.2315 0.3856 0.024 Uiso 1 1 calc R . .
C9 C 0.1536(16) 0.5121(4) 0.3061(9) 0.0266(9) Uani 1 1 d U . .
C10 C 0.3082(16) 0.5058(4) 0.2446(9) 0.0266(9) Uani 1 1 d . . .
C11 C 0.5120(16) 0.5452(4) 0.3704(9) 0.0266(9) Uani 1 1 d . . .
C12 C 0.3828(16) 0.5511(4) 0.4327(9) 0.0266(9) Uani 1 1 d . . .
C13 C 0.4235(16) 0.5754(4) 0.5286(9) 0.0266(9) Uani 1 1 d . . .
H13A H 0.3315 0.5800 0.5694 0.032 Uiso 1 1 calc R . .
C14 C 0.5951(15) 0.5921(4) 0.5614(9) 0.0266(9) Uani 1 1 d . . .
H14A H 0.6263 0.6073 0.6273 0.032 Uiso 1 1 calc R . .
C15 C 0.7269(16) 0.5874(4) 0.4997(9) 0.0266(9) Uani 1 1 d . . .
H15A H 0.8465 0.6005 0.5230 0.032 Uiso 1 1 calc R . .
C16 C 0.6870(16) 0.5636(4) 0.4040(9) 0.0266(9) Uani 1 1 d . . .
H16A H 0.7787 0.5602 0.3627 0.032 Uiso 1 1 calc R . .
C17 C 0.5054(13) 0.3696(4) -0.1534(8) 0.0170(8) Uani 1 1 d . . .
C18 C 0.6852(13) 0.3936(4) -0.1076(8) 0.0170(8) Uani 1 1 d . . .
C19 C 0.8152(13) 0.3614(4) -0.2414(8) 0.0170(8) Uani 1 1 d . . .
C20 C 0.6535(13) 0.3366(4) -0.2848(9) 0.0170(8) Uani 1 1 d . . .
C21 C 0.6434(13) 0.3066(4) -0.3734(8) 0.0170(8) Uani 1 1 d . . .
H21A H 0.5337 0.2890 -0.4016 0.020 Uiso 1 1 calc R . .
C22 C 0.7965(13) 0.3033(4) -0.4188(9) 0.0170(8) Uani 1 1 d . . .
H22A H 0.7907 0.2838 -0.4801 0.020 Uiso 1 1 calc R . .
C23 C 0.9585(13) 0.3277(4) -0.3771(8) 0.0170(8) Uani 1 1 d . . .
H23A H 1.0629 0.3245 -0.4091 0.020 Uiso 1 1 calc R . .
C24 C 0.9683(13) 0.3565(4) -0.2892(8) 0.0170(8) Uani 1 1 d . . .
H24A H 1.0796 0.3732 -0.2607 0.020 Uiso 1 1 calc R . .
O10 O 0.2945(9) 0.2523(3) -0.2957(6) 0.0256(19) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O7 2.353(7) . ?
Eu1 O7 2.375(7) 3_565 ?
Eu1 O9 2.405(7) . ?
Eu1 O8 2.427(6) . ?
Eu1 O6 2.445(7) 1_455 ?
Eu1 O3 2.456(7) . ?
Eu1 O1 2.473(7) . ?
Eu1 O4 2.478(6) . ?
Eu1 C9 3.249(11) . ?
Eu1 Eu2 3.7461(7) . ?
Eu1 Eu2 3.8158(7) 3_565 ?
Eu1 Eu1 3.8303(11) 3_565 ?
Eu2 O2 2.327(7) . ?
Eu2 O8 2.363(6) 1_655 ?
Eu2 O5 2.372(7) . ?
Eu2 O7 2.375(6) 3_565 ?
Eu2 O4 2.441(7) . ?
Eu2 O6 2.478(7) . ?
Eu2 O8 2.517(7) 3_565 ?
Eu2 O1 2.573(7) . ?
Eu2 C17 3.198(11) . ?
Eu2 C2 3.248(11) . ?
Eu2 Eu1 3.8158(7) 3_565 ?
O1 C1 1.317(12) . ?
O2 C2 1.305(13) . ?
O3 C9 1.224(13) . ?
O4 C10 1.320(13) . ?
O5 C17 1.267(12) . ?
O6 C18 1.293(12) . ?
O6 Eu1 2.445(7) 1_655 ?
O7 Eu2 2.375(6) 3_565 ?
O7 Eu1 2.375(7) 3_565 ?
O8 Eu2 2.363(6) 1_455 ?
O8 Eu2 2.517(7) 3_565 ?
O9 H9 0.8400 . ?
N1 C1 1.287(14) . ?
N1 C4 1.394(13) . ?
N1 H1A 0.8800 . ?
N2 C2 1.304(13) . ?
N2 C3 1.366(14) . ?
N2 H2A 0.8800 . ?
N3 C9 1.324(14) . ?
N3 C12 1.383(14) . ?
N3 H3A 0.8800 . ?
N4 C10 1.272(14) . ?
N4 C11 1.382(14) . ?
N5 C17 1.308(13) . ?
N5 C20 1.404(13) . ?
N5 H5A 0.8800 . ?
N6 C18 1.303(13) . ?
N6 C19 1.366(14) . ?
N6 H6A 0.8800 . ?
C1 C2 1.466(14) . ?
C3 C8 1.395(15) . ?
C3 C4 1.414(14) . ?
C4 C5 1.402(15) . ?
C5 C6 1.371(15) . ?
C5 H5B 0.9500 . ?
C6 C7 1.383(14) . ?
C6 H6B 0.9500 . ?
C7 C8 1.354(15) . ?
C7 H7B 0.9500 . ?
C8 H8B 0.9500 . ?
C9 C10 1.529(18) . ?
C11 C16 1.382(16) . ?
C11 C12 1.380(17) . ?
C12 C13 1.405(16) . ?
C13 C14 1.343(15) . ?
C13 H13A 0.9500 . ?
C14 C15 1.387(17) . ?
C14 H14A 0.9500 . ?
C15 C16 1.395(16) . ?
C15 H15A 0.9500 . ?
C16 H16A 0.9500 . ?
C17 C18 1.500(14) . ?
C19 C24 1.401(14) . ?
C19 C20 1.392(13) . ?
C20 C21 1.399(15) . ?
C21 C22 1.379(14) . ?
C21 H21A 0.9500 . ?
C22 C23 1.385(14) . ?
C22 H22A 0.9500 . ?
C23 C24 1.374(15) . ?
C23 H23A 0.9500 . ?
C24 H24A 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O7 Eu1 O7 71.8(3) . 3_565 ?
O7 Eu1 O9 149.4(2) . . ?
O7 Eu1 O9 138.5(2) 3_565 . ?
O7 Eu1 O8 72.5(2) . . ?
O7 Eu1 O8 123.3(2) 3_565 . ?
O9 Eu1 O8 83.0(2) . . ?
O7 Eu1 O6 100.0(2) . 1_455 ?
O7 Eu1 O6 80.5(2) 3_565 1_455 ?
O9 Eu1 O6 84.8(2) . 1_455 ?
O8 Eu1 O6 64.2(2) . 1_455 ?
O7 Eu1 O3 84.3(3) . . ?
O7 Eu1 O3 132.7(2) 3_565 . ?
O9 Eu1 O3 75.4(2) . . ?
O8 Eu1 O3 84.7(2) . . ?
O6 Eu1 O3 145.0(2) 1_455 . ?
O7 Eu1 O1 132.7(2) . . ?
O7 Eu1 O1 68.1(2) 3_565 . ?
O9 Eu1 O1 75.6(2) . . ?
O8 Eu1 O1 152.9(2) . . ?
O6 Eu1 O1 97.1(2) 1_455 . ?
O3 Eu1 O1 105.2(2) . . ?
O7 Eu1 O4 78.2(2) . . ?
O7 Eu1 O4 70.1(2) 3_565 . ?
O9 Eu1 O4 112.3(2) . . ?
O8 Eu1 O4 139.7(2) . . ?
O6 Eu1 O4 149.7(2) 1_455 . ?
O3 Eu1 O4 65.2(2) . . ?
O1 Eu1 O4 65.5(2) . . ?
O7 Eu1 C9 81.5(3) . . ?
O7 Eu1 C9 114.7(3) 3_565 . ?
O9 Eu1 C9 86.1(3) . . ?
O8 Eu1 C9 101.7(3) . . ?
O6 Eu1 C9 164.0(3) 1_455 . ?
O3 Eu1 C9 19.0(3) . . ?
O1 Eu1 C9 93.2(3) . . ?
O4 Eu1 C9 46.2(3) . . ?
O7 Eu1 Eu2 89.64(16) . . ?
O7 Eu1 Eu2 37.94(16) 3_565 . ?
O9 Eu1 Eu2 117.19(15) . . ?
O8 Eu1 Eu2 159.24(17) . . ?
O6 Eu1 Eu2 110.32(17) 1_455 . ?
O3 Eu1 Eu2 104.36(16) . . ?
O1 Eu1 Eu2 43.10(16) . . ?
O4 Eu1 Eu2 40.04(17) . . ?
C9 Eu1 Eu2 85.5(2) . . ?
O7 Eu1 Eu2 36.39(15) . 3_565 ?
O7 Eu1 Eu2 87.65(16) 3_565 3_565 ?
O9 Eu1 Eu2 123.26(15) . 3_565 ?
O8 Eu1 Eu2 40.34(17) . 3_565 ?
O6 Eu1 Eu2 70.34(16) 1_455 3_565 ?
O3 Eu1 Eu2 96.72(18) . 3_565 ?
O1 Eu1 Eu2 154.58(17) . 3_565 ?
O4 Eu1 Eu2 114.44(16) . 3_565 ?
C9 Eu1 Eu2 104.3(2) . 3_565 ?
Eu2 Eu1 Eu2 119.143(16) . 3_565 ?
O7 Eu1 Eu1 36.09(17) . 3_565 ?
O7 Eu1 Eu1 35.70(17) 3_565 3_565 ?
O9 Eu1 Eu1 173.33(17) . 3_565 ?
O8 Eu1 Eu1 98.93(17) . 3_565 ?
O6 Eu1 Eu1 90.25(17) 1_455 3_565 ?
O3 Eu1 Eu1 111.06(18) . 3_565 ?
O1 Eu1 Eu1 100.70(17) . 3_565 ?
O4 Eu1 Eu1 70.33(17) . 3_565 ?
C9 Eu1 Eu1 99.7(2) . 3_565 ?
Eu2 Eu1 Eu1 60.470(15) . 3_565 ?
Eu2 Eu1 Eu1 58.673(15) 3_565 3_565 ?
O2 Eu2 O8 94.0(2) . 1_655 ?
O2 Eu2 O5 85.2(2) . . ?
O8 Eu2 O5 130.0(2) 1_655 . ?
O2 Eu2 O7 130.2(2) . 3_565 ?
O8 Eu2 O7 127.5(2) 1_655 3_565 ?
O5 Eu2 O7 86.3(2) . 3_565 ?
O2 Eu2 O4 98.3(2) . . ?
O8 Eu2 O4 76.8(2) 1_655 . ?
O5 Eu2 O4 152.8(2) . . ?
O7 Eu2 O4 70.8(2) 3_565 . ?
O2 Eu2 O6 76.2(2) . . ?
O8 Eu2 O6 64.6(2) 1_655 . ?
O5 Eu2 O6 66.8(2) . . ?
O7 Eu2 O6 141.7(2) 3_565 . ?
O4 Eu2 O6 140.3(2) . . ?
O2 Eu2 O8 157.3(2) . 3_565 ?
O8 Eu2 O8 74.6(3) 1_655 3_565 ?
O5 Eu2 O8 87.3(2) . 3_565 ?
O7 Eu2 O8 70.5(2) 3_565 3_565 ?
O4 Eu2 O8 98.1(2) . 3_565 ?
O6 Eu2 O8 81.1(2) . 3_565 ?
O2 Eu2 O1 65.2(2) . . ?
O8 Eu2 O1 131.3(2) 1_655 . ?
O5 Eu2 O1 93.4(2) . . ?
O7 Eu2 O1 66.5(2) 3_565 . ?
O4 Eu2 O1 64.5(2) . . ?
O6 Eu2 O1 138.1(2) . . ?
O8 Eu2 O1 136.8(2) 3_565 . ?
O2 Eu2 C17 83.8(3) . . ?
O8 Eu2 C17 110.0(2) 1_655 . ?
O5 Eu2 C17 20.1(2) . . ?
O7 Eu2 C17 102.6(2) 3_565 . ?
O4 Eu2 C17 172.8(2) . . ?
O6 Eu2 C17 46.9(2) . . ?
O8 Eu2 C17 81.9(3) 3_565 . ?
O1 Eu2 C17 110.6(2) . . ?
O2 Eu2 C2 19.4(2) . . ?
O8 Eu2 C2 105.0(2) 1_655 . ?
O5 Eu2 C2 90.3(3) . . ?
O7 Eu2 C2 112.1(2) 3_565 . ?
O4 Eu2 C2 85.3(3) . . ?
O6 Eu2 C2 95.4(2) . . ?
O8 Eu2 C2 176.3(3) 3_565 . ?
O1 Eu2 C2 46.1(2) . . ?
C17 Eu2 C2 94.9(3) . . ?
O2 Eu2 Eu1 103.30(17) . . ?
O8 Eu2 Eu1 116.57(17) 1_655 . ?
O5 Eu2 Eu1 112.14(15) . . ?
O7 Eu2 Eu1 37.95(18) 3_565 . ?
O4 Eu2 Eu1 40.76(15) . . ?
O6 Eu2 Eu1 178.81(16) . . ?
O8 Eu2 Eu1 99.40(15) 3_565 . ?
O1 Eu2 Eu1 41.06(15) . . ?
C17 Eu2 Eu1 132.02(17) . . ?
C2 Eu2 Eu1 84.08(18) . . ?
O2 Eu2 Eu1 164.10(16) . 3_565 ?
O8 Eu2 Eu1 94.76(16) 1_655 3_565 ?
O5 Eu2 Eu1 99.14(16) . 3_565 ?
O7 Eu2 Eu1 35.99(16) 3_565 3_565 ?
O4 Eu2 Eu1 70.89(16) . 3_565 ?
O6 Eu2 Eu1 119.58(16) . 3_565 ?
O8 Eu2 Eu1 38.63(15) 3_565 3_565 ?
O1 Eu2 Eu1 99.16(15) . 3_565 ?
C17 Eu2 Eu1 105.54(19) . 3_565 ?
C2 Eu2 Eu1 144.74(18) . 3_565 ?
Eu1 Eu2 Eu1 60.857(16) . 3_565 ?
C1 O1 Eu1 133.6(7) . . ?
C1 O1 Eu2 115.2(6) . . ?
Eu1 O1 Eu2 95.8(2) . . ?
C2 O2 Eu2 124.4(6) . . ?
C9 O3 Eu1 120.2(8) . . ?
C10 O4 Eu2 137.6(7) . . ?
C10 O4 Eu1 121.5(7) . . ?
Eu2 O4 Eu1 99.2(2) . . ?
C17 O5 Eu2 119.9(6) . . ?
C18 O6 Eu1 132.9(6) . 1_655 ?
C18 O6 Eu2 117.8(6) . . ?
Eu1 O6 Eu2 109.3(3) 1_655 . ?
Eu1 O7 Eu2 107.6(3) . 3_565 ?
Eu1 O7 Eu1 108.2(3) . 3_565 ?
Eu2 O7 Eu1 104.1(3) 3_565 3_565 ?
Eu2 O8 Eu1 113.9(3) 1_455 . ?
Eu2 O8 Eu2 105.4(3) 1_455 3_565 ?
Eu1 O8 Eu2 101.0(2) . 3_565 ?
Eu1 O9 H9 109.5 . . ?
C1 N1 C4 118.4(9) . . ?
C1 N1 H1A 120.8 . . ?
C4 N1 H1A 120.8 . . ?
C2 N2 C3 119.0(9) . . ?
C2 N2 H2A 120.5 . . ?
C3 N2 H2A 120.5 . . ?
C9 N3 C12 124.4(11) . . ?
C9 N3 H3A 117.8 . . ?
C12 N3 H3A 117.8 . . ?
C10 N4 C11 119.0(11) . . ?
C17 N5 C20 122.2(9) . . ?
C17 N5 H5A 118.9 . . ?
C20 N5 H5A 118.9 . . ?
C18 N6 C19 120.5(9) . . ?
C18 N6 H6A 119.7 . . ?
C19 N6 H6A 119.7 . . ?
N1 C1 O1 122.8(9) . . ?
N1 C1 C2 121.1(10) . . ?
O1 C1 C2 116.1(9) . . ?
N2 C2 O2 121.7(9) . . ?
N2 C2 C1 121.0(10) . . ?
O2 C2 C1 117.2(9) . . ?
N2 C2 Eu2 157.3(7) . . ?
O2 C2 Eu2 36.2(4) . . ?
C1 C2 Eu2 81.1(6) . . ?
N2 C3 C8 121.4(9) . . ?
N2 C3 C4 119.9(9) . . ?
C8 C3 C4 118.7(10) . . ?
N1 C4 C5 120.5(9) . . ?
N1 C4 C3 120.4(10) . . ?
C5 C4 C3 119.0(10) . . ?
C6 C5 C4 120.5(10) . . ?
C6 C5 H5B 119.7 . . ?
C4 C5 H5B 119.7 . . ?
C5 C6 C7 119.5(11) . . ?
C5 C6 H6B 120.2 . . ?
C7 C6 H6B 120.2 . . ?
C8 C7 C6 121.5(10) . . ?
C8 C7 H7B 119.3 . . ?
C6 C7 H7B 119.3 . . ?
C7 C8 C3 120.6(10) . . ?
C7 C8 H8B 119.7 . . ?
C3 C8 H8B 119.7 . . ?
O3 C9 N3 124.9(12) . . ?
O3 C9 C10 121.6(11) . . ?
N3 C9 C10 113.4(10) . . ?
O3 C9 Eu1 40.8(6) . . ?
N3 C9 Eu1 165.7(9) . . ?
C10 C9 Eu1 80.8(6) . . ?
N4 C10 O4 125.3(11) . . ?
N4 C10 C9 123.3(11) . . ?
O4 C10 C9 111.4(9) . . ?
N4 C11 C16 119.5(12) . . ?
N4 C11 C12 121.8(10) . . ?
C16 C11 C12 118.7(11) . . ?
C11 C12 N3 118.1(11) . . ?
C11 C12 C13 122.0(11) . . ?
N3 C12 C13 119.8(11) . . ?
C14 C13 C12 118.6(12) . . ?
C14 C13 H13A 120.7 . . ?
C12 C13 H13A 120.7 . . ?
C13 C14 C15 120.4(12) . . ?
C13 C14 H14A 119.8 . . ?
C15 C14 H14A 119.8 . . ?
C16 C15 C14 121.2(11) . . ?
C16 C15 H15A 119.4 . . ?
C14 C15 H15A 119.4 . . ?
C11 C16 C15 118.9(12) . . ?
C11 C16 H16A 120.5 . . ?
C15 C16 H16A 120.5 . . ?
O5 C17 N5 123.1(9) . . ?
O5 C17 C18 119.8(10) . . ?
N5 C17 C18 117.1(9) . . ?
O5 C17 Eu2 40.0(5) . . ?
N5 C17 Eu2 162.8(7) . . ?
C18 C17 Eu2 80.0(6) . . ?
O6 C18 N6 124.8(9) . . ?
O6 C18 C17 114.7(9) . . ?
N6 C18 C17 120.5(10) . . ?
N6 C19 C24 120.2(9) . . ?
N6 C19 C20 121.1(10) . . ?
C24 C19 C20 118.7(10) . . ?
C19 C20 C21 121.2(10) . . ?
C19 C20 N5 118.1(10) . . ?
C21 C20 N5 120.6(9) . . ?
C22 C21 C20 118.4(9) . . ?
C22 C21 H21A 120.8 . . ?
C20 C21 H21A 120.8 . . ?
C23 C22 C21 121.4(11) . . ?
C23 C22 H22A 119.3 . . ?
C21 C22 H22A 119.3 . . ?
C24 C23 C22 119.9(10) . . ?
C24 C23 H23A 120.0 . . ?
C22 C23 H23A 120.0 . . ?
C23 C24 C19 120.5(9) . . ?
C23 C24 H24A 119.8 . . ?
C19 C24 H24A 119.8 . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N1 H1A O9 0.88 1.95 2.707(11) 143.9 .
N2 H2A O10 0.88 2.02 2.829(11) 153.1 4_666
N5 H5A O10 0.88 2.02 2.788(11) 145.9 .
N6 H6A O7 0.88 1.97 2.781(11) 152.9 3_665
C21 H21A O10 0.95 2.62 3.264(13) 125.0 .
C24 H24A O5 0.95 2.64 3.484(12) 147.7 1_655

_diffrn_measured_fraction_theta_max 0.991
_diffrn_reflns_theta_full        25.03
_diffrn_measured_fraction_theta_full 0.991
_refine_diff_density_max         1.835
_refine_diff_density_min         -1.275
_refine_diff_density_rms         0.262
