 121
 digermylene 5a M06-2X/Def2-TZVP
 Ge                 1.84364200    0.55902300   -1.24874800
 Ge                 1.98660900   -0.23596400    1.23344300
 Si                -0.14763500   -0.04254600    0.04871200
 C                  1.74400100    2.59617900   -0.87892100
 C                  2.28311800   -2.25335900    0.85786600
 C                 -1.32183800   -1.16830000   -0.85004200
 C                 -1.48893400    0.89359500    0.93255500
 N                  0.79099000    3.42727100   -1.35996600
 N                  2.67595000    3.39828100   -0.32036200
 N                  3.32549800   -2.84921800    0.23935000
 N                  1.55132800   -3.26108200    1.38598700
 Si                -0.94339500   -2.35766300   -2.23421900
 C                 -2.57333700   -0.75861600   -0.47466000
 Si                -1.29675500    2.11988700    2.32095500
 C                 -2.66091800    0.30637100    0.53724400
 C                  1.12151400    4.74847300   -1.09771700
 C                 -0.37095300    2.94973600   -2.13150800
 C                  2.30975700    4.73071700   -0.44066500
 C                  3.93276800    2.87657000    0.23675300
 C                  3.24601600   -4.22802800    0.36538200
 C                  4.41598200   -2.08225400   -0.38174300
 C                  2.12632600   -4.48766600    1.08799800
 C                  0.36269400   -3.03178000    2.22595000
 C                  0.77594900   -3.08362800   -2.00671800
 C                 -0.94742100   -1.45556100   -3.88318000
 C                 -2.14266100   -3.80587800   -2.32843100
 C                 -3.82551300   -1.31869200   -1.05670900
 C                  0.26719400    3.13447000    2.08009100
 C                 -1.10702900    1.20670200    3.95302100
 C                 -2.71758200    3.34761400    2.46545900
 C                 -3.99599200    0.68141500    1.08256000
 C                  0.26246000    5.92114400   -1.42320600
 H                 -0.38136300    1.87562400   -1.95311800
 C                 -1.69584400    3.49420500   -1.61543700
 C                 -0.15110100    3.17587800   -3.62015600
 C                  3.07334000    5.87756800    0.12472700
 H                  3.74859800    1.80740000    0.32919500
 C                  4.23324700    3.40152600    1.63516200
 C                  5.07717600    3.08271300   -0.74603600
 C                  4.19936800   -5.19428600   -0.24739700
 H                  4.00688400   -1.07673700   -0.46577900
 C                  5.62392200   -2.03089800    0.54357400
 C                  4.75096500   -2.54980300   -1.79213300
 C                  1.53858800   -5.81143100    1.43699300
 C                  0.68919600   -3.25951900    3.69508100
 H                  0.15008700   -1.97245600    2.09355400
 C                 -0.86118200   -3.79587700    1.74016800
 H                  1.52267500   -2.29019000   -1.93379400
 H                  1.02737300   -3.71060300   -2.86661400
 H                  0.84233000   -3.70078800   -1.10787900
 H                 -1.94673600   -1.10167600   -4.14159000
 H                 -0.60630100   -2.11583300   -4.68439800
 H                 -0.27210100   -0.59764300   -3.83601600
 H                 -2.25355200   -4.30170000   -1.36140500
 H                 -1.75817500   -4.54154300   -3.04028800
 H                 -3.13780100   -3.50120400   -2.65705100
 C                 -4.26427100   -0.91297100   -2.31458500
 C                 -4.56668100   -2.27672400   -0.36917800
 H                  0.19672000    3.80056500    1.21695600
 H                  1.13285700    2.48286600    1.94355900
 H                  0.44230200    3.75071300    2.96644500
 H                 -0.91683100    1.90854300    4.76882900
 H                 -0.26158800    0.51693600    3.89008600
 H                 -2.00333000    0.63639000    4.20143300
 H                 -2.91721100    3.84990500    1.51617700
 H                 -2.44648500    4.11388600    3.19715700
 H                 -3.64743800    2.87930600    2.79135800
 C                 -4.85524300    1.49726300    0.34978000
 C                 -4.40655500    0.23990100    2.33818000
 H                 -0.10195200    5.89096300   -2.44887100
 H                  0.83486200    6.83818000   -1.30145200
 H                 -0.60299300    5.97612800   -0.76037800
 H                 -1.73403500    3.44481100   -0.52642100
 H                 -2.49450700    2.85688000   -1.99730300
 H                 -1.89741400    4.51319000   -1.94276100
 H                 -0.08784400    4.23610300   -3.86990700
 H                 -0.98372100    2.74518400   -4.17788400
 H                  0.76738200    2.68256900   -3.94113000
 H                  2.97559800    5.92366600    1.21062800
 H                  2.68808600    6.80889000   -0.28476100
 H                  4.13424800    5.82412100   -0.11610400
 H                  4.66529600    4.40151600    1.62759200
 H                  4.95482800    2.73201900    2.10419900
 H                  3.33218100    3.40422200    2.24929700
 H                  4.84426900    2.61055400   -1.70134600
 H                  5.98594400    2.62911600   -0.34788400
 H                  5.27813800    4.14070400   -0.92107900
 H                  4.06899100   -5.25309400   -1.32912600
 H                  4.02705200   -6.18629400    0.16453800
 H                  5.23682000   -4.92944100   -0.04630800
 H                  5.33755400   -1.62199200    1.51360000
 H                  6.38931000   -1.38646500    0.10856700
 H                  6.06212800   -3.01848500    0.69680600
 H                  5.39124800   -3.43084200   -1.80433600
 H                  5.28225400   -1.74622200   -2.30275500
 H                  3.84156600   -2.75952400   -2.35628400
 H                  1.21383400   -5.85830800    2.47487400
 H                  2.28224500   -6.59125900    1.28772200
 H                  0.67928400   -6.04336400    0.80509100
 H                  0.93858500   -4.29965600    3.90819700
 H                 -0.17582900   -2.98877300    4.30174700
 H                  1.52774800   -2.62966700    3.99442300
 H                 -0.96708500   -3.70250300    0.65818000
 H                 -1.74647900   -3.34905500    2.19467300
 H                 -0.84186400   -4.85002400    2.01457900
 H                 -3.70113700   -0.15441600   -2.84593900
 C                 -5.39795800   -1.47303200   -2.88779200
 C                 -5.69819500   -2.84100000   -0.93879100
 H                 -4.23782100   -2.58924500    0.61500600
 H                 -4.54893700    1.83215300   -0.63410700
 C                 -6.07964400    1.88820300    0.86951900
 C                 -5.63261200    0.62749600    2.86185900
 H                 -3.75038300   -0.40844000    2.90729700
 H                 -5.72120700   -1.15165600   -3.86999900
 C                 -6.11411900   -2.44541100   -2.20358200
 H                 -6.25534700   -3.59487400   -0.39693000
 H                 -6.73059100    2.53039500    0.28954800
 C                 -6.47021600    1.45884900    2.13136300
 H                 -5.93404400    0.28143200    3.84263000
 H                 -6.99481300   -2.88848900   -2.65030100
 H                 -7.42446900    1.76614900    2.53959100

 86
 NHC-stabilized silylene 6a M06-2X/Def2-TZVP
 Si                 0.76688200   -0.10951100   -1.19647300
 C                 -0.26064800    1.31434400   -0.57084300
 C                 -0.43743500   -1.37952200   -0.53034800
 C                  2.32026000   -0.12797000    0.00400300
 C                 -1.49425500    0.78616100   -0.28441200
 C                 -1.59266300   -0.67795500   -0.27177400
 N                  2.34019500   -0.20359400    1.35028400
 N                  3.61445500   -0.06012700   -0.37866900
 C                 -2.69622500    1.61887000   -0.01245200
 C                 -2.91852600   -1.33053000   -0.09495900
 C                  1.10897400   -0.19932000    2.16527200
 C                  3.64120400   -0.19222700    1.81740100
 C                  4.03724900    0.03522200   -1.78998000
 C                  4.44756400   -0.10411600    0.72471000
 C                 -3.19730400    2.48572600   -0.98137500
 C                 -3.33082700    1.56935300    1.22781400
 C                 -3.16684000   -2.17061400    0.98714000
 C                 -3.93544800   -1.13302700   -1.03018000
 H                  0.31430000   -0.33038600    1.43586200
 C                  1.06024200   -1.37601700    3.13020800
 C                  0.90696000    1.14727000    2.84407700
 C                  4.04154800   -0.30101800    3.24938300
 H                  3.11679600    0.28605200   -2.31817900
 C                  4.51812700   -1.31271800   -2.30601300
 C                  5.04656000    1.15391800   -2.02385300
 C                  5.93729900   -0.06344700    0.68395900
 H                 -2.72513200    2.50526000   -1.95647200
 C                 -4.28701800    3.30234700   -0.71146400
 C                 -4.41529800    2.38782200    1.50373600
 H                 -2.96146500    0.88171000    1.98043700
 H                 -2.39110100   -2.31084200    1.73119500
 C                 -4.38824100   -2.81883000    1.12157200
 C                 -5.15415300   -1.77942200   -0.90090400
 H                 -3.75631700   -0.47221300   -1.87002200
 H                  1.38403800   -2.29360700    2.63784200
 H                  0.02918800   -1.51477000    3.45752100
 H                  1.66993100   -1.21624100    4.01913500
 H                  1.62438600    1.32656800    3.64557700
 H                 -0.09483500    1.18123700    3.27452300
 H                  0.98380200    1.95063800    2.11337100
 H                  5.08375500   -0.00982800    3.35944900
 H                  3.93357700   -1.32157000    3.61932600
 H                  3.45048100    0.35142200    3.88829200
 H                  5.41252900   -1.65123400   -1.78159900
 H                  4.76144300   -1.22617700   -3.36560200
 H                  3.73951100   -2.06549500   -2.19061600
 H                  4.79645700    2.04218200   -1.44325600
 H                  5.02386900    1.42326900   -3.08002300
 H                  6.06534200    0.85049100   -1.78704800
 H                  6.31243900    0.94330000    0.49668500
 H                  6.34044800   -0.72123800   -0.08379600
 H                  6.33307100   -0.39902400    1.64001000
 H                 -4.66351000    3.96997800   -1.47654000
 C                 -4.89489800    3.26151600    0.53561400
 H                 -4.88978100    2.34346000    2.47604500
 H                 -4.56295100   -3.47009600    1.96913700
 C                 -5.38407300   -2.62894800    0.17451800
 H                 -5.92742600   -1.62247900   -1.64229600
 H                 -5.74246700    3.89951700    0.75069100
 H                 -6.33637500   -3.13328800    0.27645100
 C                 -0.55047800    4.13175600    0.73935600
 H                 -1.61551400    4.27601800    0.54808700
 H                 -0.45537500    3.66668700    1.72191800
 H                 -0.07743500    5.11611500    0.78356900
 C                 -0.10128700    3.92943700   -2.27159300
 H                 -1.16273800    4.13814900   -2.40797700
 H                  0.43615200    4.87902800   -2.33541400
 H                  0.23082100    3.29366600   -3.09486300
 C                  2.12055500    3.15267800   -0.42401100
 H                  2.47713200    2.69266100    0.50122100
 H                  2.57792400    2.61971200   -1.26275800
 H                  2.48249000    4.18309700   -0.45128400
 C                 -1.50781700   -3.85606300   -2.06500900
 H                 -2.53492300   -3.73668400   -1.71267100
 H                 -1.40776000   -3.31080800   -3.00530200
 H                 -1.33603800   -4.91695800   -2.26330000
 C                 -0.51485300   -4.24846500    0.77527300
 H                 -0.07018300   -3.77894200    1.65418100
 H                 -1.57031900   -4.42538100    0.98410100
 H                 -0.03610400   -5.22134500    0.63722500
 C                  1.46142900   -3.54781200   -1.39411100
 H                  1.63075500   -3.06942700   -2.36078800
 H                  2.19379300   -3.15162700   -0.68324700
 H                  1.64637800   -4.61850300   -1.50396000
 Si                 0.24193400    3.10030800   -0.61848300
 Si                -0.28979600   -3.21625400   -0.78866500

 87
 NHC-stabilized silagermylidene 7 M06-2X/Def2-TZVP
 Ge                -1.81075000   -2.03580700   -0.12588400
 Si                 0.03256500   -0.71765400   -0.04233600
 C                 -3.27912400   -0.57533800   -0.05188700
 C                  1.71824000   -1.49286500   -0.07257600
 C                  0.65140300    1.03288700    0.06853000
 N                 -3.82833900    0.07169200   -1.09838600
 N                 -4.08363000   -0.32674100    0.99953100
 Si                 2.18141100   -3.28893600   -0.32721400
 C                  2.59368100   -0.44873300    0.01888100
 Si                -0.26471100    2.63441000    0.33589900
 C                  2.01566500    0.91425500    0.05883800
 C                 -4.99092200    0.72307500   -0.70966500
 C                 -3.24208600    0.02047500   -2.44891100
 C                 -5.15235800    0.46968200    0.61581200
 C                 -3.81580200   -0.89912100    2.33145600
 C                  0.83735300   -4.16590900   -1.30356200
 C                  2.35404400   -4.19051100    1.31294400
 C                  3.76387900   -3.48177500   -1.32447400
 C                  4.06892700   -0.62133200    0.08837000
 C                 -1.98282900    2.24329500    0.99863100
 C                 -0.48705400    3.63970000   -1.24674900
 C                  0.56825400    3.72625000    1.61803700
 C                  2.91647600    2.09646500    0.07640900
 C                 -5.83917200    1.55917600   -1.60521300
 H                 -2.23840700   -0.37121600   -2.28043400
 C                 -3.99945600   -0.96485800   -3.32691600
 C                 -3.09032700    1.40088900   -3.07463200
 C                 -6.23845100    0.93578700    1.52200500
 H                 -2.75452400   -1.15288100    2.29567600
 C                 -4.62024400   -2.17608200    2.52894200
 C                 -4.01001100    0.09779300    3.46809700
 H                  1.19116000   -5.16232500   -1.58094900
 H                  0.59029600   -3.62555000   -2.21906800
 H                 -0.08257400   -4.28713600   -0.73010600
 H                  2.44779300   -5.26538100    1.14020300
 H                  1.47127800   -4.02231100    1.93354200
 H                  3.23284200   -3.86245500    1.86948400
 H                  3.86511500   -4.52717200   -1.62763500
 H                  4.66027000   -3.19864300   -0.77200300
 H                  3.72460200   -2.87368200   -2.23098600
 C                  4.63910000   -1.27105200    1.18081900
 C                  4.90429200   -0.16556700   -0.93005200
 H                 -2.40896700    3.12814700    1.47837600
 H                 -1.92732100    1.43849200    1.73440800
 H                 -2.66587900    1.93192200    0.20658600
 H                 -1.41100000    4.22241800   -1.20360600
 H                 -0.52918800    2.99754900   -2.12860200
 H                  0.33993600    4.33858200   -1.38102200
 H                  1.50979600    4.14565600    1.26038500
 H                  0.77544400    3.16658200    2.53263800
 H                 -0.09786400    4.55469700    1.87303600
 C                  3.79941800    2.32966800    1.13032200
 C                  2.86345300    3.01697000   -0.96773300
 H                 -5.38622600    2.53374400   -1.79333800
 H                 -6.80772300    1.72603000   -1.13865900
 H                 -6.01408700    1.07780900   -2.56602900
 H                 -4.01254600   -1.95225700   -2.86389100
 H                 -3.50370600   -1.04623100   -4.29468600
 H                 -5.02793400   -0.64473900   -3.49899700
 H                 -4.01852500    1.77075000   -3.50749700
 H                 -2.35500200    1.33774200   -3.87712700
 H                 -2.72547500    2.12317300   -2.34286800
 H                 -6.65096100    0.11644700    2.11047600
 H                 -7.04769900    1.35728200    0.92988500
 H                 -5.89148700    1.70697500    2.21044400
 H                 -5.69162400   -1.96717600    2.52370400
 H                 -4.36620300   -2.62545200    3.48944600
 H                 -4.39743700   -2.89611500    1.74102500
 H                 -3.63127100    1.08403200    3.20060100
 H                 -3.45059100   -0.25664400    4.33383500
 H                 -5.05315500    0.18610600    3.76764600
 H                  3.99321700   -1.60559900    1.98377400
 C                  6.00888300   -1.48686000    1.24389300
 C                  6.27135000   -0.38758500   -0.87426500
 H                  4.47096700    0.35402900   -1.77644300
 H                  3.86284900    1.61061800    1.93799500
 C                  4.57691600    3.47685800    1.15743900
 C                  3.64679900    4.16301000   -0.94669700
 H                  2.19981600    2.82321300   -1.80178400
 H                  6.43647300   -1.99578600    2.09871300
 C                  6.82812000   -1.05262300    0.21133700
 H                  6.90579800   -0.04294500   -1.68097400
 H                  5.24675000    3.65251700    1.98958900
 C                  4.49931000    4.40058800    0.12164400
 H                  3.59123900    4.86935500   -1.76567600
 H                  7.89572200   -1.22573600    0.25357800
 H                  5.10773800    5.29555600    0.14426500

 174
 disiladigermetane 8 M06-2X/Def2-TZVP
 Ge                 0.11131100   -1.12084500   -1.28310800
 Si                 1.88880700   -0.00002100   -0.00014700
 Si                -1.63295400   -0.00006100   -0.00005800
 C                 -0.20788700   -3.10159600   -0.92611800
 Ge                 0.11128400    1.12076300    1.28290500
 C                  3.20149200    0.39954000   -1.31297400
 C                  3.20150000   -0.39942100    1.31273300
 C                 -2.93940400   -0.78950900    1.11005600
 C                 -2.93943100    0.78940000   -1.11009300
 N                 -1.31395600   -3.75528300   -1.34137800
 N                  0.64215100   -4.04946500   -0.48106600
 C                 -0.20792700    3.10154300    0.92622000
 Si                 3.02612000    0.75369100   -3.15109700
 C                  4.40422500    0.16822200   -0.72426700
 Si                 3.02621000   -0.75385800    3.15081300
 C                  4.40422600   -0.16785700    0.72407500
 Si                -2.65316400   -1.92610700    2.56693500
 C                 -4.15026100   -0.39809600    0.62972400
 Si                -2.65329900    1.92598800   -2.56698900
 C                 -4.15027400    0.39808600   -0.62965800
 C                 -1.15270400   -5.12340100   -1.17769200
 C                 -2.45912400   -3.05907500   -1.95377200
 C                  0.08351000   -5.31108300   -0.64564800
 C                  1.93155600   -3.68435800    0.13573200
 N                  0.64214400    4.04945000    0.48133100
 N                 -1.31405300    3.75519100    1.34139800
 C                  1.47630200    1.74046400   -3.51857800
 C                  2.91675300   -0.83400800   -4.15282200
 C                  4.44910700    1.78474200   -3.83311700
 C                  5.70850200    0.15921100   -1.44535400
 C                  1.47630100   -1.74052700    3.51831700
 C                  2.91677100    0.83360900    4.15292600
 C                  4.44920900   -1.78514500    3.83242300
 C                  5.70844500   -0.15884100    1.44528300
 C                 -2.18382800   -0.93054500    4.08987900
 C                 -1.28009400   -3.13001400    2.11695500
 C                 -4.12268500   -3.02545500    2.99211400
 C                 -5.43934900   -0.65853300    1.32742900
 C                 -2.18396500    0.93038100   -4.08990100
 C                 -1.28028800    3.12994700   -2.11698500
 C                 -4.12282600    3.02529100   -2.99222200
 C                 -5.43936900    0.65861700   -1.32730600
 C                 -2.18594200   -6.14317500   -1.51273600
 H                 -2.30543800   -2.00956300   -1.70665000
 C                 -2.41959900   -3.18908600   -3.46999200
 C                 -3.79558300   -3.45483300   -1.34179600
 C                  0.77062300   -6.59856300   -0.34491400
 H                  1.73796700   -2.70514500    0.57472600
 C                  3.01694600   -3.51867600   -0.91720500
 C                  2.35293300   -4.59976000    1.27504600
 C                  0.08346200    5.31105200    0.64588700
 C                  1.93169600    3.68445100   -0.13518800
 C                 -1.15281100    5.12333000    1.17778000
 C                 -2.45929400    3.05895500    1.95362400
 H                  1.39265900    1.87111900   -4.60138300
 H                  1.50388200    2.73422900   -3.06941800
 H                  0.57842100    1.22948400   -3.17271000
 H                  2.76961400   -0.58388800   -5.20696700
 H                  2.06586700   -1.43743600   -3.83022400
 H                  3.82548100   -1.43191000   -4.07592900
 H                  4.14455100    2.18288600   -4.80507800
 H                  5.36857800    1.21464200   -3.97209000
 H                  4.68297100    2.63210400   -3.18465400
 C                  6.03277400   -0.91751300   -2.26634600
 C                  6.62167700    1.20331700   -1.31828900
 H                  1.39216100   -1.87033900    4.60118400
 H                  1.50402400   -2.73462900    3.06989000
 H                  0.57856400   -1.22975000    3.17173800
 H                  2.77081800    0.58312200    5.20716700
 H                  2.06501200    1.43631000    3.83125400
 H                  3.82486000    1.43236000    4.07534200
 H                  5.36859400   -1.21500800    3.97185500
 H                  4.68325200   -2.63205400    3.18343600
 H                  4.14454900   -2.18395300    4.80408000
 C                  6.62173600   -1.20284700    1.31807200
 C                  6.03254200    0.91769400    2.26656300
 H                 -3.06592400   -0.42818000    4.49460000
 H                 -1.43404700   -0.17194000    3.85303800
 H                 -1.77950900   -1.57998400    4.87003200
 H                 -0.97179900   -3.69409400    3.00146100
 H                 -0.40645400   -2.62059100    1.71237300
 H                 -1.63722900   -3.84145600    1.36511000
 H                 -4.52913800   -3.50658800    2.09946000
 H                 -4.94008100   -2.49621000    3.48136400
 H                 -3.77473200   -3.81370700    3.66576000
 C                 -5.67015300   -0.06629800    2.56838200
 C                 -6.43348400   -1.46982400    0.78344300
 H                 -1.43430300    0.17167400   -3.85298400
 H                 -1.77951500    1.57972100   -4.87006600
 H                 -3.06609500    0.42809800   -4.49464400
 H                 -0.40654000    2.62048900   -1.71265300
 H                 -1.63734600    3.84119300   -1.36493400
 H                 -0.97220000    3.69426400   -3.00141900
 H                 -3.77492200    3.81317300   -3.66633000
 H                 -4.52888300    3.50691700   -2.09964600
 H                 -4.94047100    2.49598700   -3.48097300
 C                 -6.43333800    1.47019300   -0.78345400
 C                 -5.67031300    0.06618500   -2.56813900
 H                 -2.99908900   -6.14226200   -0.78526300
 H                 -1.73718500   -7.13407100   -1.50675400
 H                 -2.61797500   -5.98004100   -2.49919200
 H                 -1.46500000   -2.82624700   -3.85311000
 H                 -3.21473700   -2.58283300   -3.90662100
 H                 -2.56331100   -4.22095900   -3.79349700
 H                 -4.16723800   -4.40959700   -1.71204700
 H                 -4.52464300   -2.68627800   -1.60559900
 H                 -3.73062800   -3.48394200   -0.25272400
 H                  1.77878400   -6.61267900   -0.75991700
 H                  0.21663800   -7.41621700   -0.80094500
 H                  0.84157300   -6.79660200    0.72440400
 H                  3.25529300   -4.47408400   -1.39093400
 H                  3.91779000   -3.12454800   -0.44165500
 H                  2.70632200   -2.80833000   -1.68667800
 H                  1.51307100   -4.82049700    1.93615800
 H                  3.10847700   -4.06996500    1.85730400
 H                  2.79663400   -5.53229500    0.93058900
 C                  0.77058900    6.59854800    0.34523500
 H                  1.73835900    2.70508300   -0.57391900
 C                  2.35300900    4.59967200   -1.27467100
 C                  3.01695200    3.51919800    0.91797700
 C                 -2.18611800    6.14304600    1.51276000
 H                 -2.30560100    2.00944200    1.70649800
 C                 -3.79567100    3.45473200    1.34150300
 C                 -2.41995500    3.18897000    3.46984900
 H                  5.33537800   -1.74330800   -2.34716100
 C                  7.22586000   -0.93607900   -2.97608600
 C                  7.81229500    1.18996500   -2.02795700
 H                  6.38725000    2.03592700   -0.66490300
 H                  6.38747600   -2.03531700    0.66444900
 C                  7.81224600   -1.18958000    2.02790000
 C                  7.22553600    0.93617500    2.97648900
 H                  5.33511400    1.74346200    2.34746500
 H                 -4.90142000    0.57025800    2.99372800
 C                 -6.85242500   -0.29257500    3.25944500
 C                 -7.60928100   -1.71059900    1.47733300
 H                 -6.28069100   -1.91692200   -0.19149800
 H                 -6.28044200    1.91748700    0.19137900
 C                 -7.60911800    1.71103100   -1.47735800
 C                 -6.85256500    0.29253200   -3.25921500
 H                 -4.90169900   -0.57058600   -2.99338900
 H                  1.77871000    6.61266300    0.76036400
 H                  0.21651500    7.41620700    0.80114400
 H                  0.84168700    6.79657200   -0.72407100
 H                  2.79683800    5.53221400   -0.93036000
 H                  1.51305400    4.82041000   -1.93566500
 H                  3.10841600    4.06975400   -1.85697500
 H                  3.25501700    4.47470300    1.39164600
 H                  3.91798100    3.12526100    0.44261800
 H                  2.70633500    2.80886500    1.68746400
 H                 -2.99919900    6.14216700    0.78521000
 H                 -1.73738200    7.13395600    1.50691400
 H                 -2.61824200    5.97983600    2.49916000
 H                 -4.52482100    2.68631000    1.60541800
 H                 -3.73065300    3.48362000    0.25242400
 H                 -4.16725600    4.40961500    1.71152700
 H                 -2.56357300    4.22086900    3.79332100
 H                 -1.46544300    2.82604100    3.85309800
 H                 -3.21522300    2.58282400    3.90638600
 H                  7.45968900   -1.77667000   -3.61735400
 C                  8.11504900    0.12328100   -2.86530600
 H                  8.50664500    2.01483800   -1.93060400
 H                  8.50666400   -2.01438500    1.93043600
 C                  8.11481100   -0.12308600    2.86557700
 H                  7.45919100    1.77663300    3.61799400
 H                 -7.01190600    0.17365000    4.22375200
 C                 -7.82323300   -1.12308500    2.71814100
 H                 -8.36431000   -2.35624900    1.04703000
 H                 -8.36399900    2.35692600   -1.04716500
 C                 -7.82321800    1.12331200   -2.71804300
 H                 -7.01214400   -0.17385100   -4.22343100
 H                  9.04285000    0.11569300   -3.42256300
 H                  9.04253800   -0.11556600    3.42295900
 H                 -8.74377500   -1.30901500    3.25613800
 H                 -8.74373800    1.30930400   -3.25605000

 29
 siladigermirane 12 M06-2X/Def2-TZVP
 Ge                 0.47548600   -0.77233400   -1.21955600
 Ge                -0.47558800   -0.77248000    1.21942300
 Si                 0.00007100    1.29560000    0.00008400
 C                  2.36029600   -0.78398300   -0.39534100
 C                 -2.36040300   -0.78375900    0.39518600
 C                 -1.13785000    2.57647400   -0.69485400
 C                  1.13825900    2.57620600    0.69508900
 N                  3.21830900    0.23698900   -0.22368500
 N                  3.08015500   -1.86615400   -0.03674900
 N                 -3.08046000   -1.86592000    0.03695200
 N                 -3.21825800    0.23729800    0.22331500
 C                 -0.61350600    3.79332500   -0.38851800
 C                  0.61417500    3.79317900    0.38880200
 C                  4.44493300   -0.18842200    0.23934600
 C                  4.35825100   -1.53003000    0.35879800
 C                 -4.35854800   -1.52970700   -0.35853300
 C                 -4.44500100   -0.18804900   -0.23944900
 H                 -2.00857800    2.48204600   -1.33258900
 H                 -1.05327900    4.73147200   -0.71278600
 H                  1.05414600    4.73122500    0.71309500
 H                  2.00895700    2.48153600    1.33282700
 H                  2.92557500    1.19246900   -0.39028800
 H                  2.68244200   -2.79091300   -0.03119700
 H                  5.07854100   -2.25568100    0.68932100
 H                  5.25662300    0.48474800    0.44534000
 H                 -2.68294500   -2.79076400    0.03186900
 H                 -2.92542900    1.19276900    0.38979200
 H                 -5.25664200    0.48517300   -0.44547300
 H                 -5.07898400   -2.25532000   -0.68882300

 26
 digermane 13 M06-2X/Def2-TZVP
 Ge                -1.22928600   -0.00001600    0.00001000
 Ge                 1.22928600    0.00001400   -0.00001100
 C                 -1.91793100    0.35177800   -1.81862800
 H                 -1.57768800   -0.41388800   -2.51625000
 H                 -3.00886600    0.35197500   -1.81570300
 H                 -1.57645900    1.32167200   -2.18110600
 C                 -1.91781100   -1.75093900    0.60469700
 H                 -1.57723300   -1.97241600    1.61644900
 H                 -3.00874400   -1.74852500    0.60340200
 H                 -1.57652400   -2.54967400   -0.05427000
 C                 -1.91786000    1.39912400    1.21399200
 H                 -1.57549200    2.38586500    0.90124200
 H                 -3.00879500    1.39822500    1.21077400
 H                 -1.57850200    1.22661000    2.23563800
 C                  1.91780500    1.75098400   -0.60457000
 H                  1.57652800    2.54966700    0.05446600
 H                  3.00873800    1.74856900   -0.60329100
 H                  1.57721300    1.97254400   -1.61629900
 C                  1.91787300   -1.39903600   -1.21409000
 H                  3.00880800   -1.39814500   -1.21085200
 H                  1.57549200   -2.38579800   -0.90142300
 H                  1.57853400   -1.22644000   -2.23572900
 C                  1.91792500   -0.35190600    1.81860500
 H                  1.57647300   -1.32183800    2.18100200
 H                  3.00886000   -0.35207400    1.81568900
 H                  1.57765500    0.41369600    2.51628500

 27
 siladigermirane 14 M06-2X/Def2-TZVP
 Ge                -0.86805100   -1.22586900   -0.00081200
 Ge                -0.86783900    1.22596900    0.00088500
 Si                 1.21810600   -0.00013300   -0.00012400
 C                  2.48987300    0.00269000   -1.34868400
 C                  2.48978900   -0.00300800    1.34851900
 C                  3.68974700    0.00139800   -0.73659700
 C                  3.68970300   -0.00172500    0.73651000
 H                  2.38177800    0.00497500   -2.42366800
 H                  4.63292000    0.00256000   -1.27389400
 H                  4.63284200   -0.00288100    1.27386500
 H                  2.38162600   -0.00528200    2.42349700
 C                 -1.35215000   -2.20616900   -1.64143000
 H                 -0.82317700   -3.15795500   -1.67557600
 H                 -2.42525700   -2.39405400   -1.66194200
 H                 -1.08126900   -1.62544200   -2.52183700
 C                 -1.34824000    2.20588600   -1.64110500
 H                 -2.42120900    2.39433000   -1.66379700
 H                 -0.81868400    3.15736400   -1.67471300
 H                 -1.07601500    1.62461200   -2.52074900
 C                 -1.35141300    2.20653600    1.64149500
 H                 -0.82209300    3.15813400    1.67553200
 H                 -2.42445100    2.39480800    1.66210200
 H                 -1.08065600    1.62576000    2.52190700
 C                 -1.34823900   -2.20590900    1.64116500
 H                 -2.42123700   -2.39416200    1.66408200
 H                 -0.81884600   -3.15748500    1.67452300
 H                 -1.07570300   -1.62479300    2.52081900

 19
 siladigermene 15 M06-2X/Def2-TZVP
 Ge                 0.99948900    1.12021300    0.03809600
 Ge                 1.00034600   -1.11988900   -0.04028100
 Si                -1.07261600   -0.00064100    0.00076000
 C                 -2.37382600   -0.06571600   -1.34174700
 C                 -2.37455000    0.06343800    1.34256900
 C                 -3.57170100   -0.03622900   -0.74182600
 C                 -3.57207700    0.03375700    0.74192000
 H                 -2.25195000   -0.11574100   -2.41472000
 H                 -4.51740400   -0.06124300   -1.27465400
 H                 -4.51807400    0.05867100    1.27423200
 H                 -2.25351100    0.11354200    2.41563100
 C                  1.94117400   -2.84407500    0.08943400
 H                  1.54526900   -3.52720100   -0.65973800
 H                  3.00464300   -2.69188700   -0.08147000
 H                  1.78726500   -3.26942200    1.07934400
 C                  1.93560200    2.84753200   -0.08434200
 H                  1.65570200    3.46839500    0.76483700
 H                  3.01032700    2.67998900   -0.07397100
 H                  1.65189300    3.35125600   -1.00624900

 11
 digermylene 16 M06-2X/Def2-TZVP
 Ge                 1.27934900    0.00000000   -1.31247400
 Ge                -1.27934900    0.00000000   -1.31247400
 Si                 0.00000000    0.00000000    0.71285300
 C                  0.00000000    1.34964100    1.98509900
 C                  0.00000000   -1.34964100    1.98509900
 C                  0.00000000    0.73688800    3.18427200
 C                  0.00000000   -0.73688800    3.18427200
 H                  0.00000000    2.42312500    1.86434300
 H                  0.00000000    1.27152400    4.12862600
 H                  0.00000000   -1.27152400    4.12862600
 H                  0.00000000   -2.42312500    1.86434300

 53
 silylene 17 M06-2X/Def2-TZVP
 Si                -0.05492400   -2.46160300   -0.52378800
 C                 -1.39905600   -1.26869600    0.04131500
 C                  1.32824300   -1.32082500    0.08000000
 Si                -3.21526000   -1.66120100    0.21891800
 C                 -0.77731800   -0.06750700    0.03677800
 Si                 3.15804200   -1.70370000   -0.06084500
 C                  0.73963100   -0.09935200    0.07146500
 C                 -3.28018400   -3.34068300    1.05513100
 C                 -4.08220000   -1.80679000   -1.43967700
 C                 -4.08808400   -0.41082200    1.30824300
 C                 -1.48469300    1.23593400   -0.02791200
 C                  3.29826500   -3.45051600   -0.73166600
 C                  3.98215200   -1.67886200    1.62670800
 C                  4.06331700   -0.54287000   -1.22323700
 C                  1.50334300    1.17310800    0.04830800
 H                 -4.31116200   -3.66611500    1.20849700
 H                 -2.78982900   -3.30978900    2.03054000
 H                 -2.77877700   -4.10050900    0.45027400
 H                 -5.06866200   -2.25738900   -1.30752700
 H                 -3.51202500   -2.44133700   -2.12137000
 H                 -4.22019500   -0.83370800   -1.91271000
 H                 -5.09012200   -0.77258100    1.55126100
 H                 -4.18536400    0.56469300    0.82998000
 H                 -3.54607000   -0.27202200    2.24597300
 C                 -2.36161800    1.50159000   -1.07686600
 C                 -1.31754800    2.19395500    0.97160700
 H                  4.34670600   -3.75150200   -0.78903400
 H                  2.86589900   -3.53628400   -1.73033400
 H                  2.77977500   -4.16433300   -0.08693500
 H                  4.97057900   -2.13913300    1.55525600
 H                  3.40221700   -2.24371500    2.35899000
 H                  4.11644100   -0.66506200    2.00488800
 H                  4.13864600    0.46957800   -0.82351100
 H                  3.55546400   -0.48684300   -2.18838500
 H                  5.07542600   -0.91639700   -1.39813600
 C                  1.42904900    2.05176100   -1.03099000
 C                  2.34140800    1.48366900    1.11682600
 H                 -2.47565500    0.76481500   -1.86301300
 C                 -3.07492100    2.69103000   -1.11926100
 C                 -2.04377400    3.37405500    0.93998300
 H                 -0.62450200    2.00394000    1.78227500
 H                  0.76661800    1.82727700   -1.85855500
 C                  2.20945200    3.19687100   -1.05666600
 C                  3.11144600    2.63789100    1.09847800
 H                  2.37556600    0.81476300    1.96782100
 H                 -3.75130400    2.88553200   -1.94180400
 C                 -2.92453400    3.62575600   -0.10462600
 H                 -1.91977800    4.10243800    1.73091300
 H                  2.15782100    3.86309700   -1.90813100
 C                  3.05451600    3.49196800    0.00619100
 H                  3.75686500    2.86892400    1.93637700
 H                 -3.48649000    4.55032900   -0.12972700
 H                  3.66055300    4.38839900   -0.01466700

 33
 iprNHC M06-2X/Def2-TZVP
 C                 -0.67706400    1.25578000   -0.18238400
 C                  0.67710700    1.25576600   -0.18235400
 N                 -1.05530000   -0.08336200   -0.17600900
 N                  1.05530300   -0.08336800   -0.17600800
 C                 -2.44473300   -0.53064800   -0.06553800
 H                 -3.05950200    0.25176300   -0.51683800
 C                 -1.64743400    2.38381500   -0.21783600
 H                 -2.35289400    2.33551400    0.61467600
 H                 -1.11960200    3.33355000   -0.15194300
 H                 -2.22828300    2.38925800   -1.14304600
 C                  1.64742100    2.38385600   -0.21764700
 H                  1.11945400    3.33354300   -0.15212600
 H                  2.35259200    2.33577300    0.61512200
 H                  2.22860300    2.38922200   -1.14265300
 C                 -0.00000700   -0.93242000   -0.15026000
 C                  2.44473600   -0.53061000   -0.06548100
 H                  3.05948900    0.25192200   -0.51658700
 C                 -2.66442900   -1.82388700   -0.83251500
 H                 -3.71918600   -2.09889100   -0.78707500
 H                 -2.37200900   -1.70985800   -1.87604700
 H                 -2.06419900   -2.62301200   -0.40105600
 C                 -2.82379100   -0.67610900    1.40378400
 H                 -2.20390600   -1.45046600    1.85861700
 H                 -2.65966700    0.25655500    1.94591800
 H                 -3.87281800   -0.95767600    1.50571800
 C                  2.66454400   -1.82371700   -0.83265900
 H                  2.06420600   -2.62288600   -0.40143500
 H                  2.37230300   -1.70949300   -1.87622500
 H                  3.71928200   -2.09876000   -0.78710000
 C                  2.82367600   -0.67627700    1.40384900
 H                  2.65930000    0.25625200    1.94613800
 H                  2.20391500   -1.45085000    1.85848300
 H                  3.87275100   -0.95764500    1.50582600

 9
 HNHC M06-2X/Def2-TZVP
 C                 -0.67361200    0.93219100    0.00001000
 C                  0.67361600    0.93218800   -0.00000600
 N                 -1.04443900   -0.40116500   -0.00001200
 N                  1.04443800   -0.40116900    0.00004000
 C                 -0.00000200   -1.26932300   -0.00000200
 H                  1.99595100   -0.72279500   -0.00015100
 H                  1.37619600    1.74578800   -0.00003900
 H                 -1.37618900    1.74579400   -0.00000500
 H                 -1.99595400   -0.72278600   -0.00001600

 21
 18 M06-2X/Def2-TZVP
 Ge                -1.01483500   -1.22762200   -0.35600500
 Ge                -1.01452800    1.22778300   -0.35619800
 Si                 1.04842900   -0.00016800   -0.21347800
 C                  2.58578200   -0.00048000   -1.24374600
 C                  1.98321800    0.00009500    1.39013900
 C                  3.61504000   -0.00037300   -0.37668600
 C                  3.28809900   -0.00005300    1.06140800
 H                  2.71730100   -0.00070500   -2.31538300
 H                  4.65452600   -0.00050800   -0.68979600
 H                  4.08953900    0.00007200    1.79325900
 H                  1.63897900    0.00033900    2.41456600
 H                 -1.36040200    1.85654100   -1.72437100
 H                 -1.36060000   -1.85631500   -1.72424600
 C                 -1.57385100    2.32110800    1.18245400
 H                 -1.07929700    3.29036300    1.14725500
 H                 -2.65246800    2.46810800    1.16926200
 H                 -1.29645600    1.81926600    2.10766200
 C                 -1.57469600   -2.32081900    1.18253700
 H                 -2.65337400   -2.46736400    1.16927300
 H                 -1.08054700   -3.29027800    1.14727000
 H                 -1.29713400   -1.81918200    2.10780700

 23
 19 M06-2X/Def2-TZVP
 Ge                 2.02802300   -1.00183500    0.00001300
 Ge                -2.02802500   -1.00182900   -0.00001500
 Si                 0.00000000    0.27588500   -0.00002500
 C                  0.00001700    1.57363000   -1.34208400
 C                 -0.00001000    1.57358900    1.34207800
 C                  0.00001400    2.77496600   -0.73759800
 C                  0.00000000    2.77494400    0.73763000
 H                  0.00002600    1.46862400   -2.41841100
 H                  0.00002100    3.71727000   -1.27663500
 H                 -0.00000100    3.71723100    1.27669600
 H                 -0.00001900    1.46854500    2.41840100
 H                 -2.06965900   -1.91521900   -1.25257300
 H                  2.06963600   -1.91526200   -1.25252000
 C                 -3.57223900    0.21896200    0.00003000
 H                 -3.54394300    0.85455200   -0.88384200
 H                 -4.50537300   -0.34259000    0.00031300
 H                 -3.54360800    0.85488900    0.88364900
 C                  3.57223200    0.21896100   -0.00001600
 H                  4.50537100   -0.34258200    0.00015900
 H                  3.54385000    0.85458800   -0.88385900
 H                  3.54367600    0.85485000    0.88363300
 H                 -2.06959600   -1.91519700    1.25256100
 H                  2.06961000   -1.91516700    1.25261500

 20
 20 M06-2X/Def2-TZVP
 Ge                -1.22796800   -0.56868400    0.00920700
 Ge                 1.22798900   -0.56868700   -0.00920300
 Si                -1.96714700    1.51948000    0.92120500
 H                 -3.43135700    1.54670300    1.13586000
 H                 -1.29438500    1.78557300    2.21277300
 H                 -1.60904400    2.60539400   -0.02014900
 Si                 1.96712400    1.51947500   -0.92123600
 H                  1.29465100    1.78537800   -2.21299500
 H                  1.60859100    2.60541600    0.01993900
 H                  3.43138200    1.54691900   -1.13552200
 H                 -1.73138800   -1.73546900    0.90311900
 H                  1.73142500   -1.73554100   -0.90301700
 C                 -1.92630300   -0.79465500   -1.82557200
 H                 -1.56195700   -1.72753500   -2.25365500
 H                 -3.01522900   -0.81226000   -1.82278000
 H                 -1.59280600    0.03047400   -2.45417400
 C                  1.92628300   -0.79458400    1.82560200
 H                  1.56172800   -1.72733500    2.25378800
 H                  3.01520500   -0.81244700    1.82280200
 H                  1.59298700    0.03069300    2.45411800

 11
 21 M06-2X/Def2-TZVP
 Ge                -0.46430600   -0.43465800    0.00002200
 Si                 1.81331500    0.30745900    0.00013600
 H                  2.74428500   -0.84060800    0.04086400
 H                  2.09125100    1.09688000   -1.22021000
 H                  2.07012800    1.16592600    1.17765400
 H                 -0.72606800   -1.31041200    1.25160100
 C                 -1.69732800    1.10175600   -0.00014400
 H                 -2.73107600    0.75957000   -0.00997700
 H                 -1.54122200    1.71056200    0.88940000
 H                 -1.52829700    1.72255400   -0.87895200
 H                 -0.72364300   -1.31037200   -1.25213100

 31
 22 M06-2X/Def2-TZVP
 Ge                -2.00639300   -1.66673400    0.38480100
 Ge                 2.00640500   -1.66674200   -0.38480800
 Si                 0.00000100   -0.29974300   -0.00003900
 C                 -3.20138600   -0.02185000    0.05716500
 C                  3.20137900   -0.02185400   -0.05712700
 C                  0.14621600    1.03878100    1.31288700
 C                 -0.14620400    1.03876700   -1.31298100
 N                 -3.04967500    1.22169200    0.53921900
 N                 -4.39724200    0.01508700   -0.56207500
 N                  4.39719700    0.01510100    0.56218500
 N                  3.04969600    1.22167600   -0.53922300
 C                  0.09185900    2.26128300    0.72819400
 C                 -0.09183700    2.26127500   -0.72830100
 C                 -4.11897800    2.03054700    0.22016600
 C                 -4.98127000    1.26402300   -0.47926600
 C                  4.98122800    1.26403700    0.47938000
 C                  4.11897700    2.03054200   -0.22012500
 H                  0.30044000    0.92702600    2.37979800
 H                  0.18948100    3.20020000    1.26775500
 H                 -0.18945100    3.20018600   -1.26787400
 H                 -0.30042900    0.92700200   -2.37989100
 H                 -2.18654300    1.51572200    0.98775800
 H                 -4.78041200   -0.78591400   -1.03578800
 H                 -5.93561400    1.49294400   -0.91647000
 H                 -4.17105700    3.06486500    0.50674000
 H                  4.78033900   -0.78588600    1.03594300
 H                  2.18658900    1.51569400   -0.98781900
 H                  4.17107200    3.06485200   -0.50672200
 H                  5.93554400    1.49297100    0.91663500
 H                  2.17085800   -2.07511500    1.15179600
 H                 -2.17092700   -2.07511800   -1.15179200

 28
 23 M06-2X/Def2-TZVP
 Ge                 0.68735700   -0.00237900   -1.06505900
 Ge                -0.68730100   -0.00192500    1.06489600
 C                  2.35537000   -0.64288900   -0.07328500
 C                 -2.35531100   -0.64288900    0.07346300
 N                  3.64274800   -0.56406100   -0.46315700
 N                  2.40753600   -1.34921300    1.06829900
 N                 -2.40744300   -1.34996800   -1.06766100
 N                 -3.64270900   -0.56372400    0.46319500
 C                  4.48773700   -1.20227300    0.42244500
 C                  3.69884900   -1.70297300    1.39647900
 C                 -3.69875800   -1.70386100   -1.39569300
 C                 -4.48767900   -1.20246200   -0.42204500
 H                  3.91980500   -0.06058900   -1.29106400
 H                  1.56672300   -1.49850500    1.61809300
 H                  3.94396900   -2.26420800    2.27945200
 H                  5.55302900   -1.24095900    0.28803900
 H                 -1.56662200   -1.49963900   -1.61733100
 H                 -3.91978400   -0.05960400    1.29070400
 H                 -5.55298300   -1.24098700   -0.28768700
 H                 -3.94385400   -2.26566700   -2.27830800
 Si                 1.55727300    2.24915000   -1.17459600
 H                  2.97872500    2.22268900   -1.64479600
 H                  0.82458700    3.07680500   -2.16385800
 H                  1.57915600    3.02960200    0.09298700
 Si                -1.55748800    2.24953200    1.17404400
 H                 -0.82587000    3.07717300    2.16411600
 H                 -1.57852300    3.03024300   -0.09339400
 H                 -2.97932300    2.22265800    1.64308700

 15
 24 M06-2X/Def2-TZVP
 Ge                 1.18421300   -0.86604600   -0.24740000
 C                 -0.76009200   -0.22831800   -0.06658600
 N                 -1.44376700    0.59524400   -0.88404700
 N                 -1.68132700   -0.61573200    0.83332800
 C                 -2.76346000    0.72893800   -0.50026600
 C                 -2.91603100   -0.04494000    0.59332300
 H                 -1.00773600    1.06185600   -1.66319700
 H                 -1.44479300   -1.22804600    1.59721800
 H                 -3.77716800   -0.23421600    1.20734000
 H                 -3.46423100    1.35006500   -1.02682100
 Si                 1.81208400    1.40633800    0.38109800
 H                  1.24929300    1.94992500    1.64766200
 H                  3.27972500    1.61703700    0.44705800
 H                  1.31683000    2.32601800   -0.68712700
 H                  1.09722800   -1.40855900    1.25550500

 33
 25 M06-2X/Def2-TZVP
 Ge                 0.50019100   -0.87528700   -1.24258400
 Ge                -0.50044000   -0.87516600    1.24263400
 Si                 0.00009300    1.12355600    0.00002700
 C                  2.35345900   -0.84088400   -0.39810000
 C                 -2.35368000   -0.84053400    0.39810500
 C                 -1.28132000    2.41415500   -0.59262500
 C                  1.28194800    2.41374600    0.59262300
 N                  3.48979500   -0.37925800   -0.96161700
 N                  2.75796900   -1.28684400    0.80563000
 N                 -2.75827300   -1.28682600   -0.80547300
 N                 -3.48992600   -0.37849500    0.96146400
 C                 -0.46983300    3.72013400   -0.60653000
 C                  0.47097500    3.72004800    0.60629500
 C                  4.57810600   -0.52317200   -0.12563400
 C                  4.11011500   -1.10224200    1.00023000
 C                 -4.11038400   -1.10203500   -1.00013600
 C                 -4.57826400   -0.52249000    0.12553100
 H                 -2.09949500    2.49094300    0.12984000
 H                  0.13598000    3.75640300   -1.51771500
 H                 -0.13483700    3.75670700    1.51746600
 H                  1.71781200    2.18180200    1.56470200
 H                  3.49341800    0.03794900   -1.87801300
 H                  2.09346300   -1.68579500    1.45819200
 H                  4.61460900   -1.38795900    1.90491000
 H                  5.56906900   -0.20766300   -0.39542700
 H                 -2.09383300   -1.68609200   -1.45790900
 H                 -3.49346900    0.03902800    1.87771600
 H                 -5.56916800   -0.20669800    0.39521400
 H                 -4.61492600   -1.38796000   -1.90472400
 H                 -1.71734800    2.18224700   -1.56464000
 H                 -1.11041300    4.60581300   -0.60975900
 H                  1.11190600    4.60547100    0.60938700
 H                  2.10021000    2.49011300   -0.12978900

 35
 26 M06-2X/Def2-TZVP
 Ge                -1.23498700   -0.05489500    1.80232600
 Ge                 1.16610500   -0.37185200   -1.81898700
 Si                 0.03965400    0.94486100   -0.05778300
 C                 -2.53615600   -0.81662100    0.37838100
 C                  2.41970200   -1.02417900   -0.30422700
 C                  1.36089000    2.16669000    0.61925400
 C                 -1.05204300    2.33751100   -0.80917500
 N                 -3.86977800   -0.64702000    0.38552300
 N                 -2.30317200   -1.50825000   -0.74572300
 N                  2.15075600   -1.55889900    0.89569300
 N                  3.75795200   -0.89506100   -0.31011700
 C                  0.66719600    3.53531600    0.52631400
 C                 -0.13607600    3.57263900   -0.77715700
 C                 -4.46756400   -1.21891200   -0.71770400
 C                 -3.46361400   -1.76712700   -1.43778500
 C                  3.29367400   -1.75500900    1.63648800
 C                  4.32296400   -1.33300000    0.86927500
 H                  2.24771900    2.15579500   -0.02342200
 H                 -0.02537900    3.64516200    1.36737700
 H                  0.56116200    3.52579400   -1.62032700
 H                 -1.41191300    2.11918200   -1.81590900
 H                 -4.33648700   -0.16022100    1.13453200
 H                 -1.35314000   -1.71451000   -1.05805300
 H                 -3.47882000   -2.30774200   -2.36659200
 H                 -5.52731600   -1.18989800   -0.89132500
 H                  1.19175000   -1.68483200    1.22111900
 H                  4.24864400   -0.51917900   -1.10603400
 H                  5.38056400   -1.31017400    1.05632800
 H                  3.27977900   -2.16719600    2.62896900
 H                  0.28619500   -1.72520600   -1.66665500
 H                 -0.46010800   -1.47929700    1.83437900
 H                  1.68974400    1.93929800    1.63499300
 H                 -1.92801800    2.51033700   -0.17549600
 H                 -0.69647300    4.50638700   -0.87426200
 H                  1.37703800    4.36493800    0.58290000

 3
 GeH2 M06-2X/Def2-TZVP
 Ge                 0.00000000    0.00000000    0.06582800
 H                  0.00000000   -1.13792000   -1.05324600
 H                  0.00000000    1.13792000   -1.05324600

 5
 GeH4 M06-2X/Def2-TZVP
 Ge                 0.00000000    0.00000000    0.00000000
 H                  0.89027300    0.89027300    0.89027300
 H                 -0.89027300   -0.89027300    0.89027300
 H                 -0.89027300    0.89027300   -0.89027300
 H                  0.89027300   -0.89027300   -0.89027300