# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_dzw130
_database_code_depnum_ccdc_archive 'CCDC 1893832'
loop_
_audit_author_name
_audit_author_address
'Zhaowen Dong'
;Carl von Ossietzky University of Oldenburg
Germany
;
_audit_update_record             
;
2019-01-27 deposited with the CCDC.	2021-03-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_structural     
'SiC4(C6H5)2(Si(C2H5)3)2Ge2(C11H20N2)2 *0.5C7H8'
_chemical_formula_sum            'C53.50 H84 Ge2 N4 Si3'
_chemical_formula_weight         1012.69

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.7931(5)
_cell_length_b                   14.4290(6)
_cell_length_c                   17.6548(6)
_cell_angle_alpha                92.7304(15)
_cell_angle_beta                 91.3450(16)
_cell_angle_gamma                111.8890(15)
_cell_volume                     2781.69(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9831
_cell_measurement_theta_min      2.23
_cell_measurement_theta_max      31.48

_exptl_crystal_description       plate
_exptl_crystal_colour            'metallic green red'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.209
_exptl_crystal_F_000             1078
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.080
_exptl_absorpt_coefficient_mu    1.182
_shelx_estimated_absorpt_T_min   0.765
_shelx_estimated_absorpt_T_max   0.911
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.7849
_exptl_absorpt_correction_T_max  0.9272
_exptl_absorpt_process_details   'SADABS-2016/2 (Sheldrick)'
_exptl_absorpt_special_details   
;
 numerical absorption correction followed by correction based on
 symmetry-related measurements (multi-scan)
;
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            119718
_diffrn_reflns_av_unetI/netI     0.0371
_diffrn_reflns_av_R_equivalents  0.0467
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         1.524
_diffrn_reflns_theta_max         32.031
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             19379
_reflns_number_gt                14851
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT V8.37A'
_computing_data_reduction        'Bruker SAINT V8.37A'
_computing_structure_solution    'SHELXS-2013/1 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0400P)²+1.2000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   difmap
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         19379
_refine_ls_number_parameters     602
_refine_ls_number_restraints     45
_refine_ls_R_factor_all          0.0564
_refine_ls_R_factor_gt           0.0350
_refine_ls_wR_factor_ref         0.0870
_refine_ls_wR_factor_gt          0.0793
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_restrained_S_all      1.032
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.09646(2) 0.14420(2) 0.21876(2) 0.01539(4) Uani 1 1 d . . . . .
Ge2 Ge 0.21793(2) 0.14757(2) 0.34267(2) 0.01461(4) Uani 1 1 d . . . . .
Si1 Si 0.28647(4) 0.28538(3) 0.25687(2) 0.01440(8) Uani 1 1 d . . . . .
Si2 Si 0.14604(4) 0.44967(3) 0.24990(3) 0.01701(8) Uani 1 1 d . . . . .
Si3 Si 0.54338(4) 0.24491(3) 0.24173(2) 0.01564(8) Uani 1 1 d . . . . .
N1 N 0.19895(12) 0.07521(10) 0.08040(7) 0.0187(3) Uani 1 1 d . . . . .
N2 N 0.14570(12) -0.04102(9) 0.16037(8) 0.0198(3) Uani 1 1 d . . . . .
N3 N -0.00831(11) 0.15053(9) 0.42624(7) 0.0167(2) Uani 1 1 d . . . . .
N4 N 0.16005(12) 0.26377(9) 0.47359(7) 0.0171(2) Uani 1 1 d . . . . .
C1 C 0.27963(13) 0.41059(11) 0.24158(8) 0.0155(3) Uani 1 1 d . . . . .
C2 C 0.39235(13) 0.46682(10) 0.21497(8) 0.0149(3) Uani 1 1 d . . . . .
C3 C 0.48411(13) 0.42016(11) 0.20967(8) 0.0150(3) Uani 1 1 d . . . . .
C4 C 0.44813(13) 0.32172(11) 0.22820(8) 0.0149(3) Uani 1 1 d . . . . .
C5 C 0.42452(14) 0.57117(11) 0.19081(9) 0.0178(3) Uani 1 1 d . . . . .
C6 C 0.37173(17) 0.58883(13) 0.12463(10) 0.0255(3) Uani 1 1 d . . . . .
H6 H 0.3168 0.5340 0.0938 0.031 Uiso 1 1 calc R U . . .
C7 C 0.3985(2) 0.68616(15) 0.10289(12) 0.0367(5) Uani 1 1 d . . . . .
H7 H 0.3618 0.6973 0.0575 0.044 Uiso 1 1 calc R U . . .
C8 C 0.4782(2) 0.76621(14) 0.14726(13) 0.0407(5) Uani 1 1 d . . . . .
H8 H 0.4957 0.8325 0.1327 0.049 Uiso 1 1 calc R U . . .
C9 C 0.5323(2) 0.75016(13) 0.21253(13) 0.0374(5) Uani 1 1 d . . . . .
H9 H 0.5876 0.8054 0.2429 0.045 Uiso 1 1 calc R U . . .
C10 C 0.50653(16) 0.65307(12) 0.23432(11) 0.0258(3) Uani 1 1 d . . . . .
H10 H 0.5451 0.6425 0.2792 0.031 Uiso 1 1 calc R U . . .
C11 C 0.60731(14) 0.47991(11) 0.18188(9) 0.0164(3) Uani 1 1 d . . . . .
C12 C 0.62242(16) 0.49572(13) 0.10498(10) 0.0261(3) Uani 1 1 d . . . . .
H12 H 0.5532 0.4714 0.0705 0.031 Uiso 1 1 calc R U . . .
C13 C 0.73764(18) 0.54674(14) 0.07797(11) 0.0335(4) Uani 1 1 d . . . . .
H13 H 0.7464 0.5569 0.0253 0.040 Uiso 1 1 calc R U . . .
C14 C 0.83921(16) 0.58269(13) 0.12694(11) 0.0299(4) Uani 1 1 d . . . . .
H14 H 0.9181 0.6154 0.1080 0.036 Uiso 1 1 calc R U . . .
C15 C 0.82570(15) 0.57086(13) 0.20376(11) 0.0267(4) Uani 1 1 d . . . . .
H15 H 0.8951 0.5973 0.2380 0.032 Uiso 1 1 calc R U . . .
C16 C 0.71025(14) 0.52009(12) 0.23105(10) 0.0216(3) Uani 1 1 d . . . . .
H16 H 0.7016 0.5128 0.2840 0.026 Uiso 1 1 calc R U . . .
C17 C 0.03686(15) 0.36326(12) 0.31488(10) 0.0221(3) Uani 1 1 d . . . . .
H17A H -0.0065 0.2983 0.2863 0.027 Uiso 1 1 calc R U . . .
H17B H 0.0853 0.3511 0.3571 0.027 Uiso 1 1 calc R U . . .
C18 C -0.05875(16) 0.39906(14) 0.34881(11) 0.0270(4) Uani 1 1 d . . . . .
H18A H -0.1030 0.4171 0.3080 0.040 Uiso 1 1 calc R U . . .
H18B H -0.0181 0.4577 0.3838 0.040 Uiso 1 1 calc R U . . .
H18C H -0.1165 0.3454 0.3765 0.040 Uiso 1 1 calc R U . . .
C19 C 0.18734(15) 0.58361(12) 0.28812(10) 0.0236(3) Uani 1 1 d . . . . .
H19A H 0.2397 0.6281 0.2512 0.028 Uiso 1 1 calc R U . . .
H19B H 0.1110 0.5971 0.2899 0.028 Uiso 1 1 calc R U . . .
C20 C 0.25281(18) 0.61352(14) 0.36619(12) 0.0329(4) Uani 1 1 d . . . . .
H20A H 0.3299 0.6025 0.3655 0.049 Uiso 1 1 calc R U . . .
H20B H 0.2008 0.5728 0.4042 0.049 Uiso 1 1 calc R U . . .
H20C H 0.2698 0.6844 0.3790 0.049 Uiso 1 1 calc R U . . .
C21 C 0.06202(16) 0.44372(13) 0.15639(10) 0.0253(3) Uani 1 1 d . . . . .
H21A H -0.0208 0.4419 0.1673 0.030 Uiso 1 1 calc R U . . .
H21B H 0.1051 0.5066 0.1314 0.030 Uiso 1 1 calc R U . . .
C22 C 0.04778(18) 0.35605(14) 0.09965(11) 0.0304(4) Uani 1 1 d . . . . .
H22A H 0.0053 0.3625 0.0530 0.046 Uiso 1 1 calc R U . . .
H22B H 0.0002 0.2930 0.1218 0.046 Uiso 1 1 calc R U . . .
H22C H 0.1288 0.3566 0.0878 0.046 Uiso 1 1 calc R U . . .
C23 C 0.45132(15) 0.11070(11) 0.20966(10) 0.0207(3) Uani 1 1 d . . . . .
H23A H 0.3766 0.0867 0.2392 0.025 Uiso 1 1 calc R U . . .
H23B H 0.4252 0.1079 0.1556 0.025 Uiso 1 1 calc R U . . .
C24 C 0.51964(18) 0.03957(13) 0.21831(13) 0.0343(4) Uani 1 1 d . . . . .
H24A H 0.5911 0.0601 0.1867 0.051 Uiso 1 1 calc R U . . .
H24B H 0.4650 -0.0288 0.2021 0.051 Uiso 1 1 calc R U . . .
H24C H 0.5464 0.0419 0.2716 0.051 Uiso 1 1 calc R U . . .
C25 C 0.57943(15) 0.24667(12) 0.34690(9) 0.0211(3) Uani 1 1 d . . . . .
H25A H 0.5074 0.1971 0.3694 0.025 Uiso 1 1 calc R U . . .
H25B H 0.6480 0.2234 0.3530 0.025 Uiso 1 1 calc R U . . .
C26 C 0.61321(16) 0.34618(13) 0.39340(10) 0.0247(3) Uani 1 1 d . . . . .
H26A H 0.5495 0.3734 0.3852 0.037 Uiso 1 1 calc R U . . .
H26B H 0.6915 0.3936 0.3774 0.037 Uiso 1 1 calc R U . . .
H26C H 0.6202 0.3353 0.4474 0.037 Uiso 1 1 calc R U . . .
C27 C 0.69016(15) 0.28104(12) 0.18979(10) 0.0226(3) Uani 1 1 d . . . . .
H27A H 0.7397 0.3523 0.2035 0.027 Uiso 1 1 calc R U . . .
H27B H 0.7368 0.2412 0.2079 0.027 Uiso 1 1 calc R U . . .
C28 C 0.67489(18) 0.26646(15) 0.10334(11) 0.0313(4) Uani 1 1 d . . . . .
H28A H 0.7556 0.2861 0.0815 0.047 Uiso 1 1 calc R U . . .
H28B H 0.6323 0.3080 0.0843 0.047 Uiso 1 1 calc R U . . .
H28C H 0.6270 0.1959 0.0887 0.047 Uiso 1 1 calc R U . . .
C29 C 0.15833(14) 0.05542(11) 0.15143(9) 0.0167(3) Uani 1 1 d . . . . .
C30 C 0.21268(15) -0.00854(13) 0.04522(10) 0.0246(3) Uani 1 1 d . . . . .
C31 C 0.17894(15) -0.08111(12) 0.09521(10) 0.0242(3) Uani 1 1 d . . . . .
C32 C 0.2550(2) -0.01395(17) -0.03379(12) 0.0430(5) Uani 1 1 d . . . . .
H32A H 0.2036 0.0050 -0.0695 0.064 Uiso 1 1 calc R U . . .
H32B H 0.2486 -0.0824 -0.0474 0.064 Uiso 1 1 calc R U . . .
H32C H 0.3402 0.0320 -0.0361 0.064 Uiso 1 1 calc R U . . .
C33 C 0.17349(19) -0.18621(14) 0.08471(13) 0.0367(5) Uani 1 1 d . . . . .
H33A H 0.2410 -0.1930 0.1143 0.055 Uiso 1 1 calc R U . . .
H33B H 0.1804 -0.2022 0.0309 0.055 Uiso 1 1 calc R U . . .
H33C H 0.0954 -0.2324 0.1021 0.055 Uiso 1 1 calc R U . . .
C34 C 0.21428(15) 0.17116(12) 0.04714(9) 0.0218(3) Uani 1 1 d . . . . .
H34 H 0.2012 0.2147 0.0891 0.026 Uiso 1 1 calc R U . . .
C35 C 0.34234(19) 0.22612(17) 0.02193(15) 0.0437(5) Uani 1 1 d . . . . .
H35A H 0.4013 0.2333 0.0640 0.066 Uiso 1 1 calc R U . . .
H35B H 0.3501 0.2925 0.0065 0.066 Uiso 1 1 calc R U . . .
H35C H 0.3587 0.1882 -0.0211 0.066 Uiso 1 1 calc R U . . .
C36 C 0.1146(2) 0.15636(18) -0.01258(15) 0.0525(7) Uani 1 1 d . . . . .
H36A H 0.1233 0.1142 -0.0555 0.079 Uiso 1 1 calc R U . . .
H36B H 0.1210 0.2215 -0.0301 0.079 Uiso 1 1 calc R U . . .
H36C H 0.0346 0.1238 0.0091 0.079 Uiso 1 1 calc R U . . .
C37 C 0.09570(19) -0.09177(12) 0.22997(10) 0.0286(4) Uani 1 1 d . . . . .
H37 H 0.1062 -0.0372 0.2698 0.034 Uiso 1 1 calc R U . . .
C38 C 0.1658(3) -0.15246(17) 0.26040(15) 0.0523(6) Uani 1 1 d . . . . .
H38A H 0.1422 -0.2161 0.2302 0.078 Uiso 1 1 calc R U . . .
H38B H 0.1466 -0.1656 0.3135 0.078 Uiso 1 1 calc R U . . .
H38C H 0.2538 -0.1149 0.2571 0.078 Uiso 1 1 calc R U . . .
C39 C -0.0409(2) -0.15014(14) 0.21970(12) 0.0363(4) Uani 1 1 d . . . . .
H39A H -0.0813 -0.1055 0.2039 0.054 Uiso 1 1 calc R U . . .
H39B H -0.0730 -0.1780 0.2678 0.054 Uiso 1 1 calc R U . . .
H39C H -0.0566 -0.2047 0.1808 0.054 Uiso 1 1 calc R U . . .
C40 C 0.11389(13) 0.19141(10) 0.41652(8) 0.0150(3) Uani 1 1 d . . . . .
C41 C -0.03940(15) 0.19926(12) 0.48773(9) 0.0206(3) Uani 1 1 d . . . . .
C42 C 0.06586(15) 0.27060(12) 0.51718(9) 0.0210(3) Uani 1 1 d . . . . .
C43 C -0.16685(17) 0.17566(16) 0.51265(11) 0.0337(4) Uani 1 1 d . . . . .
H43A H -0.2142 0.1938 0.4737 0.051 Uiso 1 1 calc R U . . .
H43B H -0.1646 0.2138 0.5605 0.051 Uiso 1 1 calc R U . . .
H43C H -0.2053 0.1039 0.5201 0.051 Uiso 1 1 calc R U . . .
C44 C 0.08255(19) 0.34455(15) 0.58302(11) 0.0348(4) Uani 1 1 d . . . . .
H44A H 0.1220 0.3263 0.6262 0.052 Uiso 1 1 calc R U . . .
H44B H 0.0026 0.3442 0.5973 0.052 Uiso 1 1 calc R U . . .
H44C H 0.1340 0.4116 0.5687 0.052 Uiso 1 1 calc R U . . .
C45 C -0.09027(14) 0.06198(11) 0.37924(9) 0.0193(3) Uani 1 1 d . . . . .
H45 H -0.0410 0.0522 0.3365 0.023 Uiso 1 1 calc R U . . .
C46 C -0.12629(17) -0.03261(13) 0.42293(11) 0.0276(4) Uani 1 1 d . . . . .
H46A H -0.0526 -0.0442 0.4385 0.041 Uiso 1 1 calc R U . . .
H46B H -0.1800 -0.0898 0.3904 0.041 Uiso 1 1 calc R U . . .
H46C H -0.1694 -0.0246 0.4681 0.041 Uiso 1 1 calc R U . . .
C47 C -0.19943(17) 0.07797(15) 0.34297(12) 0.0323(4) Uani 1 1 d . . . . .
H47A H -0.2603 0.0724 0.3811 0.048 Uiso 1 1 calc R U . . .
H47B H -0.2360 0.0271 0.3014 0.048 Uiso 1 1 calc R U . . .
H47C H -0.1723 0.1447 0.3230 0.048 Uiso 1 1 calc R U . . .
C48 C 0.29294(14) 0.32412(12) 0.48365(9) 0.0207(3) Uani 1 1 d . . . . .
H48 H 0.3349 0.2913 0.4492 0.025 Uiso 1 1 calc R U . . .
C49 C 0.34311(17) 0.32319(14) 0.56372(10) 0.0293(4) Uani 1 1 d . . . . .
H49A H 0.3180 0.3666 0.5982 0.044 Uiso 1 1 calc R U . . .
H49B H 0.4326 0.3477 0.5641 0.044 Uiso 1 1 calc R U . . .
H49C H 0.3110 0.2547 0.5804 0.044 Uiso 1 1 calc R U . . .
C50 C 0.32374(17) 0.42919(13) 0.45768(11) 0.0286(4) Uani 1 1 d . . . . .
H50A H 0.2923 0.4256 0.4053 0.043 Uiso 1 1 calc R U . . .
H50B H 0.4127 0.4648 0.4602 0.043 Uiso 1 1 calc R U . . .
H50C H 0.2861 0.4651 0.4908 0.043 Uiso 1 1 calc R U . . .
C51 C 0.4901(4) 0.0199(3) 0.4948(3) 0.102(2) Uani 0.5 1 d G U P A -1
C52 C 0.4403(3) -0.0081(3) 0.4212(2) 0.0671(16) Uani 0.5 1 d G U P A -1
H52 H 0.3996 0.0292 0.3975 0.081 Uiso 0.5 1 calc R U P A -1
C53 C 0.4501(4) -0.0908(3) 0.3825(2) 0.110(2) Uani 0.5 1 d G U P A -1
H53 H 0.4161 -0.1099 0.3322 0.132 Uiso 0.5 1 calc R U P A -1
C54 C 0.5098(4) -0.1454(3) 0.4173(3) 0.0773(19) Uani 0.5 1 d G U P A -1
H54 H 0.5165 -0.2019 0.3908 0.093 Uiso 0.5 1 calc R U P A -1
C55 C 0.5595(4) -0.1174(3) 0.4908(3) 0.0708(18) Uani 0.5 1 d G U P A -1
H55 H 0.6003 -0.1547 0.5146 0.085 Uiso 0.5 1 calc R U P A -1
C56 C 0.5497(3) -0.0348(3) 0.5296(2) 0.0507(13) Uani 0.5 1 d G U P A -1
H56 H 0.5838 -0.0156 0.5799 0.061 Uiso 0.5 1 calc R U P A -1
C57 C 0.4924(7) 0.1107(5) 0.5437(7) 0.111(3) Uani 0.5 1 d . U P A -1
H57A H 0.5455 0.1720 0.5215 0.166 Uiso 0.5 1 calc R U P A -1
H57B H 0.5239 0.1080 0.5951 0.166 Uiso 0.5 1 calc R U P A -1
H57C H 0.4093 0.1104 0.5460 0.166 Uiso 0.5 1 calc R U P A -1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 C29 2.0443(15) . ?
Ge1 Si1 2.4533(4) . ?
Ge1 Ge2 2.5750(2) . ?
Ge2 C40 2.0447(14) . ?
Ge2 Si1 2.4592(4) . ?
Si1 C4 1.8684(15) . ?
Si1 C1 1.8701(15) . ?
Si2 C1 1.8674(15) . ?
Si2 C17 1.8807(16) . ?
Si2 C21 1.8870(18) . ?
Si2 C19 1.8936(16) . ?
Si3 C4 1.8675(15) . ?
Si3 C23 1.8838(16) . ?
Si3 C27 1.8858(16) . ?
Si3 C25 1.8919(17) . ?
N1 C29 1.358(2) . ?
N1 C30 1.397(2) . ?
N1 C34 1.480(2) . ?
N2 C29 1.3605(19) . ?
N2 C31 1.392(2) . ?
N2 C37 1.481(2) . ?
N3 C40 1.3570(19) . ?
N3 C41 1.3948(19) . ?
N3 C45 1.482(2) . ?
N4 C40 1.3608(18) . ?
N4 C42 1.3964(19) . ?
N4 C48 1.483(2) . ?
C1 C2 1.381(2) . ?
C2 C3 1.475(2) . ?
C2 C5 1.495(2) . ?
C3 C4 1.381(2) . ?
C3 C11 1.495(2) . ?
C5 C6 1.389(2) . ?
C5 C10 1.396(2) . ?
C6 C7 1.395(2) . ?
C6 H6 0.9500 . ?
C7 C8 1.379(3) . ?
C7 H7 0.9500 . ?
C8 C9 1.375(3) . ?
C8 H8 0.9500 . ?
C9 C10 1.394(2) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 C12 1.392(2) . ?
C11 C16 1.393(2) . ?
C12 C13 1.391(2) . ?
C12 H12 0.9500 . ?
C13 C14 1.377(3) . ?
C13 H13 0.9500 . ?
C14 C15 1.381(3) . ?
C14 H14 0.9500 . ?
C15 C16 1.394(2) . ?
C15 H15 0.9500 . ?
C16 H16 0.9500 . ?
C17 C18 1.528(2) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.525(3) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C22 1.531(2) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 C24 1.533(2) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 C26 1.530(2) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 C28 1.528(3) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C30 C31 1.352(3) . ?
C30 C32 1.501(3) . ?
C31 C33 1.496(2) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 C36 1.508(3) . ?
C34 C35 1.510(2) . ?
C34 H34 1.0000 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 C39 1.515(3) . ?
C37 C38 1.517(3) . ?
C37 H37 1.0000 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C41 C42 1.355(2) . ?
C41 C43 1.494(2) . ?
C42 C44 1.498(2) . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 C47 1.522(2) . ?
C45 C46 1.524(2) . ?
C45 H45 1.0000 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 C50 1.518(2) . ?
C48 C49 1.522(2) . ?
C48 H48 1.0000 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 C52 1.3900 . ?
C51 C56 1.3900 . ?
C51 C57 1.526(9) . ?
C52 C53 1.3900 . ?
C52 H52 0.9500 . ?
C53 C54 1.3900 . ?
C53 H53 0.9500 . ?
C54 C55 1.3900 . ?
C54 H54 0.9500 . ?
C55 C56 1.3900 . ?
C55 H55 0.9500 . ?
C56 H56 0.9500 . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C29 Ge1 Si1 102.10(4) . . ?
C29 Ge1 Ge2 98.83(4) . . ?
Si1 Ge1 Ge2 58.500(11) . . ?
C40 Ge2 Si1 103.06(4) . . ?
C40 Ge2 Ge1 98.30(4) . . ?
Si1 Ge2 Ge1 58.276(11) . . ?
C4 Si1 C1 94.54(6) . . ?
C4 Si1 Ge1 133.28(5) . . ?
C1 Si1 Ge1 113.83(5) . . ?
C4 Si1 Ge2 115.01(5) . . ?
C1 Si1 Ge2 141.71(5) . . ?
Ge1 Si1 Ge2 63.224(11) . . ?
C1 Si2 C17 107.52(7) . . ?
C1 Si2 C21 113.68(7) . . ?
C17 Si2 C21 108.56(8) . . ?
C1 Si2 C19 114.13(7) . . ?
C17 Si2 C19 109.12(7) . . ?
C21 Si2 C19 103.66(8) . . ?
C4 Si3 C23 109.37(7) . . ?
C4 Si3 C27 117.10(7) . . ?
C23 Si3 C27 106.01(7) . . ?
C4 Si3 C25 108.22(7) . . ?
C23 Si3 C25 106.63(7) . . ?
C27 Si3 C25 109.04(8) . . ?
C29 N1 C30 110.29(13) . . ?
C29 N1 C34 121.65(13) . . ?
C30 N1 C34 127.87(14) . . ?
C29 N2 C31 110.35(14) . . ?
C29 N2 C37 121.34(13) . . ?
C31 N2 C37 128.21(14) . . ?
C40 N3 C41 110.41(13) . . ?
C40 N3 C45 122.09(12) . . ?
C41 N3 C45 127.38(13) . . ?
C40 N4 C42 110.30(13) . . ?
C40 N4 C48 121.82(12) . . ?
C42 N4 C48 127.87(13) . . ?
C2 C1 Si2 126.21(11) . . ?
C2 C1 Si1 105.10(10) . . ?
Si2 C1 Si1 128.40(8) . . ?
C1 C2 C3 117.67(13) . . ?
C1 C2 C5 123.28(13) . . ?
C3 C2 C5 119.05(12) . . ?
C4 C3 C2 117.12(13) . . ?
C4 C3 C11 124.15(13) . . ?
C2 C3 C11 118.69(12) . . ?
C3 C4 Si3 128.99(11) . . ?
C3 C4 Si1 105.49(10) . . ?
Si3 C4 Si1 124.52(8) . . ?
C6 C5 C10 118.38(15) . . ?
C6 C5 C2 120.43(14) . . ?
C10 C5 C2 121.18(15) . . ?
C5 C6 C7 120.78(18) . . ?
C5 C6 H6 119.6 . . ?
C7 C6 H6 119.6 . . ?
C8 C7 C6 120.00(19) . . ?
C8 C7 H7 120.0 . . ?
C6 C7 H7 120.0 . . ?
C9 C8 C7 120.06(17) . . ?
C9 C8 H8 120.0 . . ?
C7 C8 H8 120.0 . . ?
C8 C9 C10 120.21(19) . . ?
C8 C9 H9 119.9 . . ?
C10 C9 H9 119.9 . . ?
C9 C10 C5 120.55(18) . . ?
C9 C10 H10 119.7 . . ?
C5 C10 H10 119.7 . . ?
C12 C11 C16 117.94(14) . . ?
C12 C11 C3 120.31(14) . . ?
C16 C11 C3 121.74(14) . . ?
C13 C12 C11 120.80(17) . . ?
C13 C12 H12 119.6 . . ?
C11 C12 H12 119.6 . . ?
C14 C13 C12 120.53(17) . . ?
C14 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
C13 C14 C15 119.59(16) . . ?
C13 C14 H14 120.2 . . ?
C15 C14 H14 120.2 . . ?
C14 C15 C16 119.98(17) . . ?
C14 C15 H15 120.0 . . ?
C16 C15 H15 120.0 . . ?
C11 C16 C15 121.07(16) . . ?
C11 C16 H16 119.5 . . ?
C15 C16 H16 119.5 . . ?
C18 C17 Si2 116.34(12) . . ?
C18 C17 H17A 108.2 . . ?
Si2 C17 H17A 108.2 . . ?
C18 C17 H17B 108.2 . . ?
Si2 C17 H17B 108.2 . . ?
H17A C17 H17B 107.4 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 Si2 117.57(12) . . ?
C20 C19 H19A 107.9 . . ?
Si2 C19 H19A 107.9 . . ?
C20 C19 H19B 107.9 . . ?
Si2 C19 H19B 107.9 . . ?
H19A C19 H19B 107.2 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C22 C21 Si2 117.25(12) . . ?
C22 C21 H21A 108.0 . . ?
Si2 C21 H21A 108.0 . . ?
C22 C21 H21B 108.0 . . ?
Si2 C21 H21B 108.0 . . ?
H21A C21 H21B 107.2 . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C24 C23 Si3 114.41(12) . . ?
C24 C23 H23A 108.7 . . ?
Si3 C23 H23A 108.7 . . ?
C24 C23 H23B 108.7 . . ?
Si3 C23 H23B 108.7 . . ?
H23A C23 H23B 107.6 . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C26 C25 Si3 117.70(12) . . ?
C26 C25 H25A 107.9 . . ?
Si3 C25 H25A 107.9 . . ?
C26 C25 H25B 107.9 . . ?
Si3 C25 H25B 107.9 . . ?
H25A C25 H25B 107.2 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C28 C27 Si3 115.40(12) . . ?
C28 C27 H27A 108.4 . . ?
Si3 C27 H27A 108.4 . . ?
C28 C27 H27B 108.4 . . ?
Si3 C27 H27B 108.4 . . ?
H27A C27 H27B 107.5 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N1 C29 N2 105.50(13) . . ?
N1 C29 Ge1 125.20(11) . . ?
N2 C29 Ge1 128.14(11) . . ?
C31 C30 N1 106.85(14) . . ?
C31 C30 C32 128.20(16) . . ?
N1 C30 C32 124.94(17) . . ?
C30 C31 N2 107.00(14) . . ?
C30 C31 C33 128.32(17) . . ?
N2 C31 C33 124.66(17) . . ?
C30 C32 H32A 109.5 . . ?
C30 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C30 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
N1 C34 C36 110.57(15) . . ?
N1 C34 C35 113.01(15) . . ?
C36 C34 C35 114.60(18) . . ?
N1 C34 H34 106.0 . . ?
C36 C34 H34 106.0 . . ?
C35 C34 H34 106.0 . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C34 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C34 C36 H36A 109.5 . . ?
C34 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C34 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N2 C37 C39 111.05(15) . . ?
N2 C37 C38 113.64(18) . . ?
C39 C37 C38 113.56(17) . . ?
N2 C37 H37 105.9 . . ?
C39 C37 H37 105.9 . . ?
C38 C37 H37 105.9 . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C37 C39 H39A 109.5 . . ?
C37 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C37 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
N3 C40 N4 105.55(12) . . ?
N3 C40 Ge2 129.61(11) . . ?
N4 C40 Ge2 124.42(11) . . ?
C42 C41 N3 106.93(13) . . ?
C42 C41 C43 128.51(15) . . ?
N3 C41 C43 124.54(15) . . ?
C41 C42 N4 106.76(13) . . ?
C41 C42 C44 128.30(15) . . ?
N4 C42 C44 124.94(15) . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C42 C44 H44A 109.5 . . ?
C42 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C42 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
N3 C45 C47 113.00(14) . . ?
N3 C45 C46 111.36(13) . . ?
C47 C45 C46 113.20(14) . . ?
N3 C45 H45 106.2 . . ?
C47 C45 H45 106.2 . . ?
C46 C45 H45 106.2 . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C45 C47 H47A 109.5 . . ?
C45 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C45 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
N4 C48 C50 111.52(14) . . ?
N4 C48 C49 112.64(13) . . ?
C50 C48 C49 112.77(14) . . ?
N4 C48 H48 106.5 . . ?
C50 C48 H48 106.5 . . ?
C49 C48 H48 106.5 . . ?
C48 C49 H49A 109.5 . . ?
C48 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C48 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C48 C50 H50A 109.5 . . ?
C48 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C48 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C52 C51 C56 120.0 . . ?
C52 C51 C57 126.6(5) . . ?
C56 C51 C57 113.3(5) . . ?
C51 C52 C53 120.0 . . ?
C51 C52 H52 120.0 . . ?
C53 C52 H52 120.0 . . ?
C52 C53 C54 120.0 . . ?
C52 C53 H53 120.0 . . ?
C54 C53 H53 120.0 . . ?
C55 C54 C53 120.0 . . ?
C55 C54 H54 120.0 . . ?
C53 C54 H54 120.0 . . ?
C56 C55 C54 120.0 . . ?
C56 C55 H55 120.0 . . ?
C54 C55 H55 120.0 . . ?
C55 C56 C51 120.0 . . ?
C55 C56 H56 120.0 . . ?
C51 C56 H56 120.0 . . ?
C51 C57 H57A 109.5 . . ?
C51 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C51 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C17 Si2 C1 C2 -163.39(13) . . . . ?
C21 Si2 C1 C2 76.42(15) . . . . ?
C19 Si2 C1 C2 -42.20(16) . . . . ?
C17 Si2 C1 Si1 23.70(13) . . . . ?
C21 Si2 C1 Si1 -96.49(12) . . . . ?
C19 Si2 C1 Si1 144.89(10) . . . . ?
C4 Si1 C1 C2 1.83(11) . . . . ?
Ge1 Si1 C1 C2 -140.07(9) . . . . ?
Ge2 Si1 C1 C2 143.54(8) . . . . ?
C4 Si1 C1 Si2 175.91(10) . . . . ?
Ge1 Si1 C1 Si2 34.02(12) . . . . ?
Ge2 Si1 C1 Si2 -42.37(15) . . . . ?
Si2 C1 C2 C3 -177.25(11) . . . . ?
Si1 C1 C2 C3 -2.99(16) . . . . ?
Si2 C1 C2 C5 2.1(2) . . . . ?
Si1 C1 C2 C5 176.33(12) . . . . ?
C1 C2 C3 C4 3.2(2) . . . . ?
C5 C2 C3 C4 -176.19(14) . . . . ?
C1 C2 C3 C11 -179.30(13) . . . . ?
C5 C2 C3 C11 1.3(2) . . . . ?
C2 C3 C4 Si3 -170.20(11) . . . . ?
C11 C3 C4 Si3 12.4(2) . . . . ?
C2 C3 C4 Si1 -1.38(16) . . . . ?
C11 C3 C4 Si1 -178.77(12) . . . . ?
C23 Si3 C4 C3 -146.86(14) . . . . ?
C27 Si3 C4 C3 -26.30(17) . . . . ?
C25 Si3 C4 C3 97.36(15) . . . . ?
C23 Si3 C4 Si1 46.25(11) . . . . ?
C27 Si3 C4 Si1 166.81(9) . . . . ?
C25 Si3 C4 Si1 -69.54(11) . . . . ?
C1 Si1 C4 C3 -0.27(11) . . . . ?
Ge1 Si1 C4 C3 128.89(9) . . . . ?
Ge2 Si1 C4 C3 -155.21(9) . . . . ?
C1 Si1 C4 Si3 169.19(9) . . . . ?
Ge1 Si1 C4 Si3 -61.65(12) . . . . ?
Ge2 Si1 C4 Si3 14.25(11) . . . . ?
C1 C2 C5 C6 -70.5(2) . . . . ?
C3 C2 C5 C6 108.85(17) . . . . ?
C1 C2 C5 C10 108.65(18) . . . . ?
C3 C2 C5 C10 -72.03(19) . . . . ?
C10 C5 C6 C7 -1.1(2) . . . . ?
C2 C5 C6 C7 178.09(15) . . . . ?
C5 C6 C7 C8 0.0(3) . . . . ?
C6 C7 C8 C9 0.7(3) . . . . ?
C7 C8 C9 C10 -0.3(3) . . . . ?
C8 C9 C10 C5 -0.7(3) . . . . ?
C6 C5 C10 C9 1.4(2) . . . . ?
C2 C5 C10 C9 -177.71(15) . . . . ?
C4 C3 C11 C12 101.73(19) . . . . ?
C2 C3 C11 C12 -75.62(19) . . . . ?
C4 C3 C11 C16 -77.3(2) . . . . ?
C2 C3 C11 C16 105.32(17) . . . . ?
C16 C11 C12 C13 2.4(2) . . . . ?
C3 C11 C12 C13 -176.66(16) . . . . ?
C11 C12 C13 C14 0.0(3) . . . . ?
C12 C13 C14 C15 -2.2(3) . . . . ?
C13 C14 C15 C16 2.0(3) . . . . ?
C12 C11 C16 C15 -2.7(2) . . . . ?
C3 C11 C16 C15 176.38(14) . . . . ?
C14 C15 C16 C11 0.5(3) . . . . ?
C1 Si2 C17 C18 162.22(13) . . . . ?
C21 Si2 C17 C18 -74.39(15) . . . . ?
C19 Si2 C17 C18 37.94(16) . . . . ?
C1 Si2 C19 C20 -58.32(15) . . . . ?
C17 Si2 C19 C20 61.97(15) . . . . ?
C21 Si2 C19 C20 177.50(13) . . . . ?
C1 Si2 C21 C22 38.18(16) . . . . ?
C17 Si2 C21 C22 -81.42(15) . . . . ?
C19 Si2 C21 C22 162.66(13) . . . . ?
C4 Si3 C23 C24 -179.72(13) . . . . ?
C27 Si3 C23 C24 53.17(15) . . . . ?
C25 Si3 C23 C24 -62.93(15) . . . . ?
C4 Si3 C25 C26 -41.62(14) . . . . ?
C23 Si3 C25 C26 -159.18(12) . . . . ?
C27 Si3 C25 C26 86.77(13) . . . . ?
C4 Si3 C27 C28 -66.51(14) . . . . ?
C23 Si3 C27 C28 55.80(14) . . . . ?
C25 Si3 C27 C28 170.25(12) . . . . ?
C30 N1 C29 N2 -0.50(17) . . . . ?
C34 N1 C29 N2 174.95(13) . . . . ?
C30 N1 C29 Ge1 -168.99(11) . . . . ?
C34 N1 C29 Ge1 6.5(2) . . . . ?
C31 N2 C29 N1 0.30(17) . . . . ?
C37 N2 C29 N1 -176.36(14) . . . . ?
C31 N2 C29 Ge1 168.33(12) . . . . ?
C37 N2 C29 Ge1 -8.3(2) . . . . ?
C29 N1 C30 C31 0.53(19) . . . . ?
C34 N1 C30 C31 -174.57(15) . . . . ?
C29 N1 C30 C32 179.50(18) . . . . ?
C34 N1 C30 C32 4.4(3) . . . . ?
N1 C30 C31 N2 -0.33(19) . . . . ?
C32 C30 C31 N2 -179.25(19) . . . . ?
N1 C30 C31 C33 178.17(17) . . . . ?
C32 C30 C31 C33 -0.8(3) . . . . ?
C29 N2 C31 C30 0.03(19) . . . . ?
C37 N2 C31 C30 176.39(16) . . . . ?
C29 N2 C31 C33 -178.54(16) . . . . ?
C37 N2 C31 C33 -2.2(3) . . . . ?
C29 N1 C34 C36 -106.5(2) . . . . ?
C30 N1 C34 C36 68.1(2) . . . . ?
C29 N1 C34 C35 123.55(18) . . . . ?
C30 N1 C34 C35 -61.8(2) . . . . ?
C29 N2 C37 C39 94.04(18) . . . . ?
C31 N2 C37 C39 -82.0(2) . . . . ?
C29 N2 C37 C38 -136.47(17) . . . . ?
C31 N2 C37 C38 47.5(2) . . . . ?
C41 N3 C40 N4 1.95(17) . . . . ?
C45 N3 C40 N4 -174.18(13) . . . . ?
C41 N3 C40 Ge2 174.67(11) . . . . ?
C45 N3 C40 Ge2 -1.5(2) . . . . ?
C42 N4 C40 N3 -2.29(17) . . . . ?
C48 N4 C40 N3 178.19(13) . . . . ?
C42 N4 C40 Ge2 -175.50(11) . . . . ?
C48 N4 C40 Ge2 5.0(2) . . . . ?
C40 N3 C41 C42 -0.88(18) . . . . ?
C45 N3 C41 C42 174.98(14) . . . . ?
C40 N3 C41 C43 177.77(16) . . . . ?
C45 N3 C41 C43 -6.4(3) . . . . ?
N3 C41 C42 N4 -0.54(18) . . . . ?
C43 C41 C42 N4 -179.13(17) . . . . ?
N3 C41 C42 C44 179.00(17) . . . . ?
C43 C41 C42 C44 0.4(3) . . . . ?
C40 N4 C42 C41 1.80(18) . . . . ?
C48 N4 C42 C41 -178.72(15) . . . . ?
C40 N4 C42 C44 -177.76(17) . . . . ?
C48 N4 C42 C44 1.7(3) . . . . ?
C40 N3 C45 C47 -127.69(16) . . . . ?
C41 N3 C45 C47 56.9(2) . . . . ?
C40 N3 C45 C46 103.60(17) . . . . ?
C41 N3 C45 C46 -71.8(2) . . . . ?
C40 N4 C48 C50 104.81(17) . . . . ?
C42 N4 C48 C50 -74.6(2) . . . . ?
C40 N4 C48 C49 -127.22(16) . . . . ?
C42 N4 C48 C49 53.4(2) . . . . ?
C56 C51 C52 C53 0.0 . . . . ?
C57 C51 C52 C53 177.1(5) . . . . ?
C51 C52 C53 C54 0.0 . . . . ?
C52 C53 C54 C55 0.0 . . . . ?
C53 C54 C55 C56 0.0 . . . . ?
C54 C55 C56 C51 0.0 . . . . ?
C52 C51 C56 C55 0.0 . . . . ?
C57 C51 C56 C55 -177.4(5) . . . . ?

_refine_diff_density_max         1.543
_refine_diff_density_min         -0.769
_refine_diff_density_rms         0.071



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_dzw165a
_database_code_depnum_ccdc_archive 'CCDC 1893833'
loop_
_audit_author_name
_audit_author_address
'Zhaowen Dong'
;Carl von Ossietzky University of Oldenburg
Germany
;
_audit_update_record             
;
2019-01-27 deposited with the CCDC.	2021-03-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_structural     
'SiC4(C6H5)2(Si(CH3)3)2Ge2(C11H20N2)2 *2O(C2H5)2'
_chemical_formula_sum            'C52 H88 Ge2 N4 O2 Si3'
_chemical_formula_weight         1030.71

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.5456(15)
_cell_length_b                   14.7302(18)
_cell_length_c                   15.0458(18)
_cell_angle_alpha                70.717(3)
_cell_angle_beta                 84.150(3)
_cell_angle_gamma                76.059(3)
_cell_volume                     2952.3(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    4182
_cell_measurement_theta_min      2.30
_cell_measurement_theta_max      20.43

_exptl_crystal_description       rod
_exptl_crystal_colour            green
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.159
_exptl_crystal_F_000             1100
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.070
_exptl_crystal_size_min          0.060
_exptl_absorpt_coefficient_mu    1.117
_shelx_estimated_absorpt_T_min   0.807
_shelx_estimated_absorpt_T_max   0.936
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8847
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   'SADABS-2016/2 (Sheldrick)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            56657
_diffrn_reflns_av_unetI/netI     0.0964
_diffrn_reflns_av_R_equivalents  0.1238
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         1.434
_diffrn_reflns_theta_max         23.256
_diffrn_reflns_theta_full        23.256
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             8484
_reflns_number_gt                5580
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT V8.37A'
_computing_data_reduction        'Bruker SAINT V8.37A'
_computing_structure_solution    'SHELXS-2013/1 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0600P)²+16.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   difmap
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         8484
_refine_ls_number_parameters     590
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1152
_refine_ls_R_factor_gt           0.0665
_refine_ls_wR_factor_ref         0.1782
_refine_ls_wR_factor_gt          0.1564
_refine_ls_goodness_of_fit_ref   1.076
_refine_ls_restrained_S_all      1.076
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.38180(5) 0.28104(6) 0.11961(6) 0.0199(2) Uani 1 1 d . . . . .
Ge2 Ge 0.41100(5) 0.19455(6) 0.29802(6) 0.0190(2) Uani 1 1 d . . . . .
Si1 Si 0.26444(14) 0.20472(15) 0.22796(15) 0.0195(5) Uani 1 1 d . . . . .
Si2 Si 0.26897(15) 0.05425(16) 0.10397(16) 0.0240(5) Uani 1 1 d . . . . .
Si3 Si 0.14177(14) 0.31904(16) 0.37366(15) 0.0233(5) Uani 1 1 d . . . . .
N1 N 0.2617(4) 0.4885(5) 0.0893(4) 0.0246(15) Uani 1 1 d . . . . .
N2 N 0.3966(4) 0.4743(5) 0.1459(4) 0.0245(15) Uani 1 1 d . . . . .
N3 N 0.5808(4) 0.0401(4) 0.2658(4) 0.0167(14) Uani 1 1 d . . . . .
N4 N 0.4740(4) -0.0287(4) 0.3547(4) 0.0179(14) Uani 1 1 d . . . . .
C1 C 0.2142(5) 0.1207(5) 0.1883(5) 0.0203(18) Uani 1 1 d . . . . .
C2 C 0.1205(5) 0.1344(5) 0.2194(5) 0.0188(17) Uani 1 1 d . . . . .
C3 C 0.0901(4) 0.2001(5) 0.2748(5) 0.0158(16) Uani 1 1 d . . . . .
C4 C 0.1535(5) 0.2502(5) 0.2880(5) 0.0197(17) Uani 1 1 d . . . . .
C5 C 0.0507(5) 0.0878(5) 0.1933(5) 0.0215(18) Uani 1 1 d . . . . .
C6 C 0.0110(5) 0.1263(6) 0.1060(6) 0.034(2) Uani 1 1 d . . . . .
H6 H 0.023854 0.186306 0.064012 0.041 Uiso 1 1 calc R U . . .
C7 C -0.0478(6) 0.0793(7) 0.0772(8) 0.047(3) Uani 1 1 d . . . . .
H7 H -0.073849 0.106240 0.016186 0.056 Uiso 1 1 calc R U . . .
C8 C -0.0673(6) -0.0071(7) 0.1393(9) 0.049(3) Uani 1 1 d . . . . .
H8 H -0.106776 -0.039863 0.120294 0.059 Uiso 1 1 calc R U . . .
C9 C -0.0309(6) -0.0463(7) 0.2277(8) 0.051(3) Uani 1 1 d . . . . .
H9 H -0.045157 -0.105447 0.270104 0.062 Uiso 1 1 calc R U . . .
C10 C 0.0281(5) 0.0025(6) 0.2547(7) 0.038(2) Uani 1 1 d . . . . .
H10 H 0.052904 -0.023642 0.316256 0.046 Uiso 1 1 calc R U . . .
C11 C -0.0100(5) 0.2107(6) 0.3176(5) 0.0203(17) Uani 1 1 d . . . . .
C12 C -0.0836(5) 0.2797(6) 0.2697(6) 0.0271(19) Uani 1 1 d . . . . .
H12 H -0.072780 0.320569 0.207637 0.033 Uiso 1 1 calc R U . . .
C13 C -0.1734(5) 0.2916(6) 0.3092(6) 0.033(2) Uani 1 1 d . . . . .
H13 H -0.223605 0.340278 0.274074 0.039 Uiso 1 1 calc R U . . .
C14 C -0.1913(6) 0.2345(7) 0.3979(7) 0.040(2) Uani 1 1 d . . . . .
H14 H -0.253525 0.243165 0.424779 0.048 Uiso 1 1 calc R U . . .
C15 C -0.1182(6) 0.1640(7) 0.4483(6) 0.041(2) Uani 1 1 d . . . . .
H15 H -0.129619 0.124513 0.510774 0.050 Uiso 1 1 calc R U . . .
C16 C -0.0278(6) 0.1504(6) 0.4079(6) 0.039(2) Uani 1 1 d . . . . .
H16 H 0.021968 0.100006 0.441793 0.046 Uiso 1 1 calc R U . . .
C17 C 0.4013(5) 0.0251(6) 0.1086(5) 0.0265(19) Uani 1 1 d . . . . .
H17A H 0.423148 0.086143 0.096435 0.040 Uiso 1 1 calc R U . . .
H17B H 0.428583 -0.005995 0.060628 0.040 Uiso 1 1 calc R U . . .
H17C H 0.421307 -0.020030 0.171031 0.040 Uiso 1 1 calc R U . . .
C18 C 0.2371(6) 0.1347(6) -0.0177(6) 0.038(2) Uani 1 1 d . . . . .
H18A H 0.171290 0.136750 -0.028597 0.058 Uiso 1 1 calc R U . . .
H18B H 0.279099 0.108451 -0.062880 0.058 Uiso 1 1 calc R U . . .
H18C H 0.244213 0.201541 -0.025808 0.058 Uiso 1 1 calc R U . . .
C19 C 0.2329(6) -0.0648(6) 0.1246(6) 0.032(2) Uani 1 1 d . . . . .
H19A H 0.243088 -0.105501 0.190574 0.048 Uiso 1 1 calc R U . . .
H19B H 0.271040 -0.099916 0.083530 0.048 Uiso 1 1 calc R U . . .
H19C H 0.165720 -0.051362 0.110570 0.048 Uiso 1 1 calc R U . . .
C20 C 0.2252(5) 0.4044(6) 0.3433(6) 0.029(2) Uani 1 1 d . . . . .
H20A H 0.211424 0.452076 0.280423 0.043 Uiso 1 1 calc R U . . .
H20B H 0.290521 0.366201 0.343915 0.043 Uiso 1 1 calc R U . . .
H20C H 0.217257 0.439497 0.389630 0.043 Uiso 1 1 calc R U . . .
C21 C 0.1736(6) 0.2279(6) 0.4922(6) 0.037(2) Uani 1 1 d . . . . .
H21A H 0.170147 0.262861 0.538057 0.056 Uiso 1 1 calc R U . . .
H21B H 0.238144 0.188975 0.489318 0.056 Uiso 1 1 calc R U . . .
H21C H 0.129193 0.183865 0.511386 0.056 Uiso 1 1 calc R U . . .
C22 C 0.0206(5) 0.3958(6) 0.3841(6) 0.033(2) Uani 1 1 d . . . . .
H22A H 0.000377 0.441312 0.321814 0.050 Uiso 1 1 calc R U . . .
H22B H 0.022091 0.433501 0.426563 0.050 Uiso 1 1 calc R U . . .
H22C H -0.024182 0.352689 0.409406 0.050 Uiso 1 1 calc R U . . .
C23 C 0.3404(5) 0.4212(5) 0.1259(5) 0.0185(17) Uani 1 1 d . . . . .
C24 C 0.2669(5) 0.5835(5) 0.0867(6) 0.0262(19) Uani 1 1 d . . . . .
C25 C 0.3516(6) 0.5734(5) 0.1219(6) 0.029(2) Uani 1 1 d . . . . .
C26 C 0.1923(6) 0.6744(6) 0.0484(8) 0.053(3) Uani 1 1 d . . . . .
H26A H 0.182434 0.683988 -0.017805 0.080 Uiso 1 1 calc R U . . .
H26B H 0.212480 0.731365 0.053377 0.080 Uiso 1 1 calc R U . . .
H26C H 0.133022 0.667556 0.084604 0.080 Uiso 1 1 calc R U . . .
C27 C 0.3931(6) 0.6534(6) 0.1319(7) 0.042(2) Uani 1 1 d . . . . .
H27A H 0.410542 0.636995 0.197441 0.063 Uiso 1 1 calc R U . . .
H27B H 0.346243 0.716081 0.113838 0.063 Uiso 1 1 calc R U . . .
H27C H 0.449624 0.659238 0.090810 0.063 Uiso 1 1 calc R U . . .
C28 C 0.1841(5) 0.4597(6) 0.0544(6) 0.031(2) Uani 1 1 d . . . . .
H28 H 0.197449 0.386021 0.077263 0.037 Uiso 1 1 calc R U . . .
C29 C 0.0869(5) 0.4953(7) 0.0954(6) 0.041(2) Uani 1 1 d . . . . .
H29A H 0.091760 0.482417 0.163185 0.062 Uiso 1 1 calc R U . . .
H29B H 0.041962 0.460015 0.085038 0.062 Uiso 1 1 calc R U . . .
H29C H 0.064699 0.566226 0.064408 0.062 Uiso 1 1 calc R U . . .
C30 C 0.1868(6) 0.4910(7) -0.0529(6) 0.042(2) Uani 1 1 d . . . . .
H30A H 0.184006 0.562039 -0.078611 0.063 Uiso 1 1 calc R U . . .
H30B H 0.132479 0.476175 -0.074513 0.063 Uiso 1 1 calc R U . . .
H30C H 0.245687 0.455027 -0.074687 0.063 Uiso 1 1 calc R U . . .
C31 C 0.4921(5) 0.4256(6) 0.1875(6) 0.0268(19) Uani 1 1 d . . . . .
H31 H 0.498852 0.353141 0.200993 0.032 Uiso 1 1 calc R U . . .
C32 C 0.5006(6) 0.4405(7) 0.2814(6) 0.042(2) Uani 1 1 d . . . . .
H32A H 0.501230 0.509635 0.270959 0.064 Uiso 1 1 calc R U . . .
H32B H 0.559540 0.398099 0.311107 0.064 Uiso 1 1 calc R U . . .
H32C H 0.446515 0.423372 0.322625 0.064 Uiso 1 1 calc R U . . .
C33 C 0.5688(5) 0.4547(6) 0.1158(6) 0.032(2) Uani 1 1 d . . . . .
H33A H 0.561956 0.437072 0.059900 0.049 Uiso 1 1 calc R U . . .
H33B H 0.631005 0.419988 0.142983 0.049 Uiso 1 1 calc R U . . .
H33C H 0.563444 0.526037 0.098075 0.049 Uiso 1 1 calc R U . . .
C34 C 0.4896(5) 0.0601(5) 0.2978(5) 0.0192(17) Uani 1 1 d . . . . .
C35 C 0.6211(5) -0.0593(5) 0.3023(5) 0.0212(18) Uani 1 1 d . . . . .
C36 C 0.5551(5) -0.1027(5) 0.3591(5) 0.0214(18) Uani 1 1 d . . . . .
C37 C 0.7209(5) -0.1078(6) 0.2814(6) 0.029(2) Uani 1 1 d . . . . .
H37A H 0.731361 -0.091629 0.213047 0.044 Uiso 1 1 calc R U . . .
H37B H 0.730338 -0.179435 0.310043 0.044 Uiso 1 1 calc R U . . .
H37C H 0.765855 -0.083832 0.307403 0.044 Uiso 1 1 calc R U . . .
C38 C 0.5645(5) -0.2083(5) 0.4195(6) 0.031(2) Uani 1 1 d . . . . .
H38A H 0.541075 -0.210936 0.483519 0.047 Uiso 1 1 calc R U . . .
H38B H 0.631278 -0.242824 0.421316 0.047 Uiso 1 1 calc R U . . .
H38C H 0.527299 -0.240217 0.393113 0.047 Uiso 1 1 calc R U . . .
C39 C 0.6231(5) 0.1189(6) 0.1983(5) 0.0261(19) Uani 1 1 d . . . . .
H39 H 0.572038 0.180465 0.184061 0.031 Uiso 1 1 calc R U . . .
C40 C 0.7023(6) 0.1392(6) 0.2414(6) 0.034(2) Uani 1 1 d . . . . .
H40A H 0.678451 0.156402 0.298416 0.051 Uiso 1 1 calc R U . . .
H40B H 0.725914 0.194225 0.196049 0.051 Uiso 1 1 calc R U . . .
H40C H 0.753953 0.080322 0.257679 0.051 Uiso 1 1 calc R U . . .
C41 C 0.6517(5) 0.0996(6) 0.1054(5) 0.031(2) Uani 1 1 d . . . . .
H41A H 0.706379 0.043800 0.114555 0.047 Uiso 1 1 calc R U . . .
H41B H 0.668501 0.158389 0.059421 0.047 Uiso 1 1 calc R U . . .
H41C H 0.598648 0.084187 0.082228 0.047 Uiso 1 1 calc R U . . .
C42 C 0.3823(5) -0.0505(6) 0.5052(5) 0.029(2) Uani 1 1 d . . . . .
H42A H 0.425624 -0.112859 0.536778 0.044 Uiso 1 1 calc R U . . .
H42B H 0.318424 -0.051200 0.532994 0.044 Uiso 1 1 calc R U . . .
H42C H 0.403998 0.004327 0.513182 0.044 Uiso 1 1 calc R U . . .
C43 C 0.3805(5) -0.0379(6) 0.4024(5) 0.0244(18) Uani 1 1 d . . . . .
H43 H 0.335217 0.026073 0.373481 0.029 Uiso 1 1 calc R U . . .
C44 C 0.3430(6) -0.1179(6) 0.3827(6) 0.037(2) Uani 1 1 d . . . . .
H44A H 0.361065 -0.118251 0.318291 0.055 Uiso 1 1 calc R U . . .
H44B H 0.273799 -0.104178 0.390034 0.055 Uiso 1 1 calc R U . . .
H44C H 0.370157 -0.182349 0.427320 0.055 Uiso 1 1 calc R U . . .
O1 O 0.3391(5) 0.3518(6) -0.2839(6) 0.072(2) Uani 1 1 d . . . . .
C45 C 0.4376(8) 0.2232(8) -0.1653(8) 0.069(3) Uani 1 1 d . . . . .
H45A H 0.447775 0.199395 -0.097282 0.104 Uiso 1 1 calc R U . . .
H45B H 0.497247 0.233895 -0.199122 0.104 Uiso 1 1 calc R U . . .
H45C H 0.415344 0.174087 -0.183226 0.104 Uiso 1 1 calc R U . . .
C46 C 0.3638(7) 0.3195(7) -0.1903(8) 0.058(3) Uani 1 1 d . . . . .
H46A H 0.306470 0.310496 -0.149877 0.069 Uiso 1 1 calc R U . . .
H46B H 0.388969 0.370537 -0.177398 0.069 Uiso 1 1 calc R U . . .
C47 C 0.2771(9) 0.4445(8) -0.3100(9) 0.076(4) Uani 1 1 d . . . . .
H47A H 0.308587 0.495118 -0.304997 0.092 Uiso 1 1 calc R U . . .
H47B H 0.220140 0.443810 -0.267938 0.092 Uiso 1 1 calc R U . . .
C48 C 0.2498(12) 0.4673(11) -0.4093(9) 0.134(7) Uani 1 1 d . . . . .
H48A H 0.213418 0.420448 -0.412348 0.201 Uiso 1 1 calc R U . . .
H48B H 0.307074 0.461933 -0.449357 0.201 Uiso 1 1 calc R U . . .
H48C H 0.211028 0.534491 -0.431419 0.201 Uiso 1 1 calc R U . . .
O2 O 0.0729(7) 0.6808(6) 0.2827(6) 0.096(3) Uani 1 1 d . . . . .
C49 C -0.0714(8) 0.6967(9) 0.2100(9) 0.081(4) Uani 1 1 d . . . . .
H49A H -0.055309 0.754302 0.161445 0.121 Uiso 1 1 calc R U . . .
H49B H -0.140323 0.707212 0.219169 0.121 Uiso 1 1 calc R U . . .
H49C H -0.047516 0.638014 0.190236 0.121 Uiso 1 1 calc R U . . .
C50 C -0.0274(9) 0.6823(8) 0.2997(9) 0.077(4) Uani 1 1 d . . . . .
H50A H -0.058182 0.736586 0.325076 0.092 Uiso 1 1 calc R U . . .
H50B H -0.036004 0.619347 0.346620 0.092 Uiso 1 1 calc R U . . .
C51 C 0.1236(12) 0.6711(9) 0.3688(9) 0.097(5) Uani 1 1 d . . . . .
H51A H 0.118565 0.608345 0.418079 0.116 Uiso 1 1 calc R U . . .
H51B H 0.092764 0.725793 0.393620 0.116 Uiso 1 1 calc R U . . .
C52 C 0.2267(12) 0.6733(10) 0.3472(10) 0.110(5) Uani 1 1 d . . . . .
H52A H 0.232000 0.738339 0.304045 0.165 Uiso 1 1 calc R U . . .
H52B H 0.256216 0.622726 0.317706 0.165 Uiso 1 1 calc R U . . .
H52C H 0.258872 0.660128 0.405717 0.165 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 C23 2.037(7) . ?
Ge1 Si1 2.446(2) . ?
Ge1 Ge2 2.5926(11) . ?
Ge2 C34 2.035(7) . ?
Ge2 Si1 2.425(2) . ?
Si1 C1 1.854(7) . ?
Si1 C4 1.858(7) . ?
Si2 C1 1.854(8) . ?
Si2 C18 1.856(8) . ?
Si2 C19 1.870(8) . ?
Si2 C17 1.871(7) . ?
Si3 C4 1.858(7) . ?
Si3 C21 1.867(8) . ?
Si3 C20 1.872(8) . ?
Si3 C22 1.874(8) . ?
N1 C23 1.349(9) . ?
N1 C24 1.407(9) . ?
N1 C28 1.492(9) . ?
N2 C23 1.373(9) . ?
N2 C25 1.389(9) . ?
N2 C31 1.496(9) . ?
N3 C34 1.361(9) . ?
N3 C35 1.381(9) . ?
N3 C39 1.482(9) . ?
N4 C34 1.364(9) . ?
N4 C36 1.391(9) . ?
N4 C43 1.485(9) . ?
C1 C2 1.384(10) . ?
C2 C3 1.442(10) . ?
C2 C5 1.500(10) . ?
C3 C4 1.377(10) . ?
C3 C11 1.525(9) . ?
C5 C6 1.373(11) . ?
C5 C10 1.382(11) . ?
C6 C7 1.399(11) . ?
C6 H6 0.9500 . ?
C7 C8 1.380(13) . ?
C7 H7 0.9500 . ?
C8 C9 1.368(14) . ?
C8 H8 0.9500 . ?
C9 C10 1.407(12) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 C12 1.360(10) . ?
C11 C16 1.393(11) . ?
C12 C13 1.375(10) . ?
C12 H12 0.9500 . ?
C13 C14 1.360(12) . ?
C13 H13 0.9500 . ?
C14 C15 1.377(12) . ?
C14 H14 0.9500 . ?
C15 C16 1.389(11) . ?
C15 H15 0.9500 . ?
C16 H16 0.9500 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C24 C25 1.347(11) . ?
C24 C26 1.490(11) . ?
C25 C27 1.500(11) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 C30 1.526(11) . ?
C28 C29 1.527(11) . ?
C28 H28 1.0000 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C33 1.507(10) . ?
C31 C32 1.521(11) . ?
C31 H31 1.0000 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C35 C36 1.352(10) . ?
C35 C37 1.507(10) . ?
C36 C38 1.502(10) . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C40 1.512(10) . ?
C39 C41 1.514(10) . ?
C39 H39 1.0000 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C42 C43 1.498(10) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 C44 1.532(10) . ?
C43 H43 1.0000 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
O1 C46 1.385(12) . ?
O1 C47 1.398(12) . ?
C45 C46 1.517(14) . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 H46A 0.9900 . ?
C46 H46B 0.9900 . ?
C47 C48 1.493(16) . ?
C47 H47A 0.9900 . ?
C47 H47B 0.9900 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
O2 C50 1.450(14) . ?
O2 C51 1.505(15) . ?
C49 C50 1.482(16) . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C51 C52 1.507(18) . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C23 Ge1 Si1 100.0(2) . . ?
C23 Ge1 Ge2 96.6(2) . . ?
Si1 Ge1 Ge2 57.44(5) . . ?
C34 Ge2 Si1 102.9(2) . . ?
C34 Ge2 Ge1 101.0(2) . . ?
Si1 Ge2 Ge1 58.24(5) . . ?
C1 Si1 C4 94.9(3) . . ?
C1 Si1 Ge2 135.8(2) . . ?
C4 Si1 Ge2 116.0(2) . . ?
C1 Si1 Ge1 114.9(2) . . ?
C4 Si1 Ge1 135.4(2) . . ?
Ge2 Si1 Ge1 64.32(5) . . ?
C1 Si2 C18 109.3(4) . . ?
C1 Si2 C19 114.1(3) . . ?
C18 Si2 C19 108.4(4) . . ?
C1 Si2 C17 111.0(3) . . ?
C18 Si2 C17 106.8(4) . . ?
C19 Si2 C17 107.0(4) . . ?
C4 Si3 C21 108.2(4) . . ?
C4 Si3 C20 111.5(3) . . ?
C21 Si3 C20 107.5(4) . . ?
C4 Si3 C22 115.0(3) . . ?
C21 Si3 C22 107.9(4) . . ?
C20 Si3 C22 106.5(4) . . ?
C23 N1 C24 111.2(6) . . ?
C23 N1 C28 121.1(6) . . ?
C24 N1 C28 127.6(6) . . ?
C23 N2 C25 110.4(6) . . ?
C23 N2 C31 121.3(6) . . ?
C25 N2 C31 128.2(6) . . ?
C34 N3 C35 110.6(6) . . ?
C34 N3 C39 120.9(6) . . ?
C35 N3 C39 128.5(6) . . ?
C34 N4 C36 110.5(6) . . ?
C34 N4 C43 121.3(6) . . ?
C36 N4 C43 128.2(6) . . ?
C2 C1 Si1 104.8(5) . . ?
C2 C1 Si2 126.8(5) . . ?
Si1 C1 Si2 127.2(4) . . ?
C1 C2 C3 117.4(6) . . ?
C1 C2 C5 122.4(7) . . ?
C3 C2 C5 120.2(6) . . ?
C4 C3 C2 118.4(6) . . ?
C4 C3 C11 122.3(6) . . ?
C2 C3 C11 119.2(6) . . ?
C3 C4 Si1 104.4(5) . . ?
C3 C4 Si3 127.0(5) . . ?
Si1 C4 Si3 126.6(4) . . ?
C6 C5 C10 118.2(7) . . ?
C6 C5 C2 120.8(7) . . ?
C10 C5 C2 120.9(7) . . ?
C5 C6 C7 121.7(9) . . ?
C5 C6 H6 119.2 . . ?
C7 C6 H6 119.2 . . ?
C8 C7 C6 118.7(9) . . ?
C8 C7 H7 120.6 . . ?
C6 C7 H7 120.6 . . ?
C9 C8 C7 121.2(8) . . ?
C9 C8 H8 119.4 . . ?
C7 C8 H8 119.4 . . ?
C8 C9 C10 118.8(9) . . ?
C8 C9 H9 120.6 . . ?
C10 C9 H9 120.6 . . ?
C5 C10 C9 121.3(9) . . ?
C5 C10 H10 119.4 . . ?
C9 C10 H10 119.4 . . ?
C12 C11 C16 118.4(7) . . ?
C12 C11 C3 121.1(7) . . ?
C16 C11 C3 120.5(7) . . ?
C11 C12 C13 121.3(8) . . ?
C11 C12 H12 119.3 . . ?
C13 C12 H12 119.3 . . ?
C14 C13 C12 120.8(8) . . ?
C14 C13 H13 119.6 . . ?
C12 C13 H13 119.6 . . ?
C13 C14 C15 119.2(8) . . ?
C13 C14 H14 120.4 . . ?
C15 C14 H14 120.4 . . ?
C14 C15 C16 120.0(8) . . ?
C14 C15 H15 120.0 . . ?
C16 C15 H15 120.0 . . ?
C15 C16 C11 120.2(8) . . ?
C15 C16 H16 119.9 . . ?
C11 C16 H16 119.9 . . ?
Si2 C17 H17A 109.5 . . ?
Si2 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si2 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si2 C18 H18A 109.5 . . ?
Si2 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si2 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si2 C19 H19A 109.5 . . ?
Si2 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si2 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si3 C20 H20A 109.5 . . ?
Si3 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si3 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si3 C21 H21A 109.5 . . ?
Si3 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si3 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si3 C22 H22A 109.5 . . ?
Si3 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si3 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
N1 C23 N2 104.8(6) . . ?
N1 C23 Ge1 126.8(5) . . ?
N2 C23 Ge1 126.5(5) . . ?
C25 C24 N1 106.1(6) . . ?
C25 C24 C26 129.3(7) . . ?
N1 C24 C26 124.6(7) . . ?
C24 C25 N2 107.5(6) . . ?
C24 C25 C27 127.4(7) . . ?
N2 C25 C27 125.1(7) . . ?
C24 C26 H26A 109.5 . . ?
C24 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C24 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
N1 C28 C30 110.8(6) . . ?
N1 C28 C29 112.7(7) . . ?
C30 C28 C29 113.1(6) . . ?
N1 C28 H28 106.6 . . ?
C30 C28 H28 106.6 . . ?
C29 C28 H28 106.6 . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
N2 C31 C33 110.3(6) . . ?
N2 C31 C32 112.4(6) . . ?
C33 C31 C32 114.5(6) . . ?
N2 C31 H31 106.3 . . ?
C33 C31 H31 106.3 . . ?
C32 C31 H31 106.3 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
N3 C34 N4 104.9(6) . . ?
N3 C34 Ge2 126.5(5) . . ?
N4 C34 Ge2 125.6(5) . . ?
C36 C35 N3 107.4(6) . . ?
C36 C35 C37 127.5(7) . . ?
N3 C35 C37 125.1(7) . . ?
C35 C36 N4 106.5(6) . . ?
C35 C36 C38 128.8(7) . . ?
N4 C36 C38 124.6(6) . . ?
C35 C37 H37A 109.5 . . ?
C35 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C35 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C36 C38 H38A 109.5 . . ?
C36 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C36 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
N3 C39 C40 111.9(6) . . ?
N3 C39 C41 112.2(6) . . ?
C40 C39 C41 113.1(6) . . ?
N3 C39 H39 106.4 . . ?
C40 C39 H39 106.4 . . ?
C41 C39 H39 106.4 . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C39 C41 H41A 109.5 . . ?
C39 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C39 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C43 C42 H42A 109.5 . . ?
C43 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C43 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
N4 C43 C42 112.1(6) . . ?
N4 C43 C44 111.3(6) . . ?
C42 C43 C44 113.3(7) . . ?
N4 C43 H43 106.6 . . ?
C42 C43 H43 106.6 . . ?
C44 C43 H43 106.6 . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C46 O1 C47 112.8(8) . . ?
C46 C45 H45A 109.5 . . ?
C46 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C46 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
O1 C46 C45 112.2(9) . . ?
O1 C46 H46A 109.2 . . ?
C45 C46 H46A 109.2 . . ?
O1 C46 H46B 109.2 . . ?
C45 C46 H46B 109.2 . . ?
H46A C46 H46B 107.9 . . ?
O1 C47 C48 107.7(10) . . ?
O1 C47 H47A 110.2 . . ?
C48 C47 H47A 110.2 . . ?
O1 C47 H47B 110.2 . . ?
C48 C47 H47B 110.2 . . ?
H47A C47 H47B 108.5 . . ?
C47 C48 H48A 109.5 . . ?
C47 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C47 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C50 O2 C51 113.5(10) . . ?
C50 C49 H49A 109.5 . . ?
C50 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C50 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
O2 C50 C49 109.2(10) . . ?
O2 C50 H50A 109.8 . . ?
C49 C50 H50A 109.8 . . ?
O2 C50 H50B 109.8 . . ?
C49 C50 H50B 109.8 . . ?
H50A C50 H50B 108.3 . . ?
O2 C51 C52 111.7(11) . . ?
O2 C51 H51A 109.3 . . ?
C52 C51 H51A 109.3 . . ?
O2 C51 H51B 109.3 . . ?
C52 C51 H51B 109.3 . . ?
H51A C51 H51B 107.9 . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C4 Si1 C1 C2 1.6(5) . . . . ?
Ge2 Si1 C1 C2 137.7(4) . . . . ?
Ge1 Si1 C1 C2 -144.3(4) . . . . ?
C4 Si1 C1 Si2 169.6(5) . . . . ?
Ge2 Si1 C1 Si2 -54.3(6) . . . . ?
Ge1 Si1 C1 Si2 23.7(5) . . . . ?
C18 Si2 C1 C2 78.0(7) . . . . ?
C19 Si2 C1 C2 -43.5(8) . . . . ?
C17 Si2 C1 C2 -164.5(6) . . . . ?
C18 Si2 C1 Si1 -87.4(5) . . . . ?
C19 Si2 C1 Si1 151.0(5) . . . . ?
C17 Si2 C1 Si1 30.1(6) . . . . ?
Si1 C1 C2 C3 -3.4(8) . . . . ?
Si2 C1 C2 C3 -171.5(5) . . . . ?
Si1 C1 C2 C5 173.4(6) . . . . ?
Si2 C1 C2 C5 5.4(10) . . . . ?
C1 C2 C3 C4 4.4(10) . . . . ?
C5 C2 C3 C4 -172.6(7) . . . . ?
C1 C2 C3 C11 -174.8(6) . . . . ?
C5 C2 C3 C11 8.3(10) . . . . ?
C2 C3 C4 Si1 -2.6(8) . . . . ?
C11 C3 C4 Si1 176.5(5) . . . . ?
C2 C3 C4 Si3 -167.1(5) . . . . ?
C11 C3 C4 Si3 12.0(10) . . . . ?
C1 Si1 C4 C3 0.5(5) . . . . ?
Ge2 Si1 C4 C3 -146.9(4) . . . . ?
Ge1 Si1 C4 C3 134.1(4) . . . . ?
C1 Si1 C4 Si3 165.1(5) . . . . ?
Ge2 Si1 C4 Si3 17.7(6) . . . . ?
Ge1 Si1 C4 Si3 -61.3(6) . . . . ?
C21 Si3 C4 C3 78.6(7) . . . . ?
C20 Si3 C4 C3 -163.4(6) . . . . ?
C22 Si3 C4 C3 -42.0(8) . . . . ?
C21 Si3 C4 Si1 -82.6(5) . . . . ?
C20 Si3 C4 Si1 35.4(6) . . . . ?
C22 Si3 C4 Si1 156.7(5) . . . . ?
C1 C2 C5 C6 -77.7(10) . . . . ?
C3 C2 C5 C6 99.1(9) . . . . ?
C1 C2 C5 C10 99.1(9) . . . . ?
C3 C2 C5 C10 -84.2(9) . . . . ?
C10 C5 C6 C7 -2.5(12) . . . . ?
C2 C5 C6 C7 174.3(7) . . . . ?
C5 C6 C7 C8 1.1(12) . . . . ?
C6 C7 C8 C9 0.5(13) . . . . ?
C7 C8 C9 C10 -0.5(13) . . . . ?
C6 C5 C10 C9 2.5(12) . . . . ?
C2 C5 C10 C9 -174.4(7) . . . . ?
C8 C9 C10 C5 -1.0(13) . . . . ?
C4 C3 C11 C12 91.1(9) . . . . ?
C2 C3 C11 C12 -89.8(9) . . . . ?
C4 C3 C11 C16 -88.0(9) . . . . ?
C2 C3 C11 C16 91.1(9) . . . . ?
C16 C11 C12 C13 1.1(12) . . . . ?
C3 C11 C12 C13 -178.0(7) . . . . ?
C11 C12 C13 C14 0.1(13) . . . . ?
C12 C13 C14 C15 -0.1(13) . . . . ?
C13 C14 C15 C16 -1.2(14) . . . . ?
C14 C15 C16 C11 2.5(14) . . . . ?
C12 C11 C16 C15 -2.4(13) . . . . ?
C3 C11 C16 C15 176.7(8) . . . . ?
C24 N1 C23 N2 -0.5(8) . . . . ?
C28 N1 C23 N2 177.3(6) . . . . ?
C24 N1 C23 Ge1 -165.6(5) . . . . ?
C28 N1 C23 Ge1 12.2(10) . . . . ?
C25 N2 C23 N1 0.4(8) . . . . ?
C31 N2 C23 N1 -179.5(6) . . . . ?
C25 N2 C23 Ge1 165.5(5) . . . . ?
C31 N2 C23 Ge1 -14.3(10) . . . . ?
C23 N1 C24 C25 0.5(9) . . . . ?
C28 N1 C24 C25 -177.1(7) . . . . ?
C23 N1 C24 C26 178.7(8) . . . . ?
C28 N1 C24 C26 1.0(12) . . . . ?
N1 C24 C25 N2 -0.3(9) . . . . ?
C26 C24 C25 N2 -178.3(8) . . . . ?
N1 C24 C25 C27 178.1(8) . . . . ?
C26 C24 C25 C27 0.1(15) . . . . ?
C23 N2 C25 C24 0.0(9) . . . . ?
C31 N2 C25 C24 179.8(7) . . . . ?
C23 N2 C25 C27 -178.5(8) . . . . ?
C31 N2 C25 C27 1.4(13) . . . . ?
C23 N1 C28 C30 -103.3(8) . . . . ?
C24 N1 C28 C30 74.1(10) . . . . ?
C23 N1 C28 C29 128.8(7) . . . . ?
C24 N1 C28 C29 -53.7(10) . . . . ?
C23 N2 C31 C33 109.5(8) . . . . ?
C25 N2 C31 C33 -70.3(10) . . . . ?
C23 N2 C31 C32 -121.4(8) . . . . ?
C25 N2 C31 C32 58.8(10) . . . . ?
C35 N3 C34 N4 -0.1(8) . . . . ?
C39 N3 C34 N4 177.7(6) . . . . ?
C35 N3 C34 Ge2 161.2(5) . . . . ?
C39 N3 C34 Ge2 -21.0(9) . . . . ?
C36 N4 C34 N3 1.0(8) . . . . ?
C43 N4 C34 N3 -179.1(6) . . . . ?
C36 N4 C34 Ge2 -160.5(5) . . . . ?
C43 N4 C34 Ge2 19.4(9) . . . . ?
C34 N3 C35 C36 -0.8(8) . . . . ?
C39 N3 C35 C36 -178.4(7) . . . . ?
C34 N3 C35 C37 179.5(7) . . . . ?
C39 N3 C35 C37 1.9(11) . . . . ?
N3 C35 C36 N4 1.4(8) . . . . ?
C37 C35 C36 N4 -178.9(7) . . . . ?
N3 C35 C36 C38 -176.4(7) . . . . ?
C37 C35 C36 C38 3.3(13) . . . . ?
C34 N4 C36 C35 -1.5(8) . . . . ?
C43 N4 C36 C35 178.6(6) . . . . ?
C34 N4 C36 C38 176.4(7) . . . . ?
C43 N4 C36 C38 -3.5(11) . . . . ?
C34 N3 C39 C40 114.1(7) . . . . ?
C35 N3 C39 C40 -68.5(9) . . . . ?
C34 N3 C39 C41 -117.6(7) . . . . ?
C35 N3 C39 C41 59.8(9) . . . . ?
C34 N4 C43 C42 -104.6(8) . . . . ?
C36 N4 C43 C42 75.3(9) . . . . ?
C34 N4 C43 C44 127.4(7) . . . . ?
C36 N4 C43 C44 -52.7(9) . . . . ?
C47 O1 C46 C45 -175.0(9) . . . . ?
C46 O1 C47 C48 -175.5(11) . . . . ?
C51 O2 C50 C49 177.4(9) . . . . ?
C50 O2 C51 C52 -178.1(10) . . . . ?

_refine_diff_density_max         1.430
_refine_diff_density_min         -0.670
_refine_diff_density_rms         0.111



####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_dzw165
_database_code_depnum_ccdc_archive 'CCDC 1893834'
loop_
_audit_author_name
_audit_author_address
'Zhaowen Dong'
;Carl von Ossietzky University of Oldenburg
Germany
;
_audit_update_record             
;
2019-01-27 deposited with the CCDC.	2021-03-22 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/1
_shelx_SHELXL_version_number     2018/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_structural     
'(SiC4(C6H5)2(Si(CH3)3)2)2Ge2(C11H20N2)2 *1.75O(C2H5)2'
_chemical_formula_sum            'C73 H113.50 Ge2 N4 O1.75 Si6'
_chemical_formula_weight         1388.89

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.9129(9)
_cell_length_b                   15.0880(11)
_cell_length_c                   22.7675(18)
_cell_angle_alpha                76.4735(19)
_cell_angle_beta                 84.561(2)
_cell_angle_gamma                80.734(2)
_cell_volume                     3919.9(5)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    5510
_cell_measurement_theta_min      2.38
_cell_measurement_theta_max      21.92

_exptl_crystal_description       block
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.177
_exptl_crystal_F_000             1483
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.160
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.060
_exptl_absorpt_coefficient_mu    0.901
_shelx_estimated_absorpt_T_min   0.869
_shelx_estimated_absorpt_T_max   0.948
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.8942
_exptl_absorpt_correction_T_max  0.9829
_exptl_absorpt_process_details   'SADABS-2016/2 (Sheldrick)'
_exptl_absorpt_special_details   
;
 numerical absorption correction followed by correction based on
 symmetry-related measurements (multi-scan)
;
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            76697
_diffrn_reflns_av_unetI/netI     0.0950
_diffrn_reflns_av_R_equivalents  0.1318
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         1.403
_diffrn_reflns_theta_max         23.256
_diffrn_reflns_theta_full        23.256
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             11249
_reflns_number_gt                7164
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT V8.37A'
_computing_data_reduction        'Bruker SAINT V8.37A'
_computing_structure_solution    'SHELXS-2013/1 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0500P)²+5.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   difmap
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         11249
_refine_ls_number_parameters     814
_refine_ls_number_restraints     21
_refine_ls_R_factor_all          0.1076
_refine_ls_R_factor_gt           0.0544
_refine_ls_wR_factor_ref         0.1329
_refine_ls_wR_factor_gt          0.1136
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_restrained_S_all      1.076
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.36038(5) 0.25446(4) 0.18619(3) 0.01889(17) Uani 1 1 d . . . . .
Ge2 Ge 0.40004(5) 0.28754(4) 0.32491(3) 0.01716(17) Uani 1 1 d . . . . .
Si1 Si 0.41687(13) 0.15052(10) 0.28261(7) 0.0172(4) Uani 1 1 d . . . . .
Si2 Si 0.62906(13) 0.07057(10) 0.18788(7) 0.0206(4) Uani 1 1 d . . . . .
Si3 Si 0.25043(13) 0.07665(10) 0.40977(7) 0.0197(4) Uani 1 1 d . . . . .
Si4 Si 0.34454(13) 0.38990(10) 0.22955(7) 0.0181(4) Uani 1 1 d . . . . .
Si5 Si 0.07582(14) 0.44956(11) 0.28119(8) 0.0257(4) Uani 1 1 d . . . . .
Si6 Si 0.57428(14) 0.46933(10) 0.14935(7) 0.0207(4) Uani 1 1 d . . . . .
N1 N 0.1484(4) 0.3124(3) 0.1177(2) 0.0264(12) Uani 1 1 d . . . . .
N2 N 0.1511(4) 0.1717(3) 0.1692(2) 0.0226(11) Uani 1 1 d . . . . .
N3 N 0.6464(4) 0.2715(3) 0.36095(19) 0.0175(11) Uani 1 1 d . . . . .
N4 N 0.5491(4) 0.4058(3) 0.35976(19) 0.0175(11) Uani 1 1 d . . . . .
C1 C 0.5288(4) 0.0603(3) 0.2566(2) 0.0165(13) Uani 1 1 d . . . . .
C2 C 0.5088(4) -0.0237(4) 0.2927(2) 0.0172(13) Uani 1 1 d . . . . .
C3 C 0.4155(4) -0.0225(3) 0.3409(2) 0.0162(13) Uani 1 1 d . . . . .
C4 C 0.3538(5) 0.0603(4) 0.3447(2) 0.0196(13) Uani 1 1 d . . . . .
C5 C 0.5733(5) -0.1138(3) 0.2846(3) 0.0205(14) Uani 1 1 d . . . . .
C6 C 0.5475(5) -0.1529(3) 0.2392(3) 0.0216(14) Uani 1 1 d . . . . .
H6 H 0.484910 -0.124171 0.215369 0.026 Uiso 1 1 calc R U . . .
C7 C 0.6110(5) -0.2333(4) 0.2278(3) 0.0298(15) Uani 1 1 d . . . . .
H7 H 0.592352 -0.258777 0.196245 0.036 Uiso 1 1 calc R U . . .
C8 C 0.7013(5) -0.2758(4) 0.2626(3) 0.0313(16) Uani 1 1 d . . . . .
H8 H 0.746355 -0.330141 0.254570 0.038 Uiso 1 1 calc R U . . .
C9 C 0.7260(5) -0.2387(4) 0.3093(3) 0.0322(16) Uani 1 1 d . . . . .
H9 H 0.787677 -0.268030 0.333699 0.039 Uiso 1 1 calc R U . . .
C10 C 0.6612(5) -0.1593(4) 0.3204(3) 0.0255(14) Uani 1 1 d . . . . .
H10 H 0.677500 -0.135511 0.353259 0.031 Uiso 1 1 calc R U . . .
C11 C 0.3995(5) -0.1141(4) 0.3814(2) 0.0197(13) Uani 1 1 d . . . . .
C12 C 0.3317(5) -0.1700(4) 0.3649(3) 0.0231(14) Uani 1 1 d . . . . .
H12 H 0.295023 -0.149637 0.327884 0.028 Uiso 1 1 calc R U . . .
C13 C 0.3168(5) -0.2548(4) 0.4016(3) 0.0277(15) Uani 1 1 d . . . . .
H13 H 0.269291 -0.291905 0.390027 0.033 Uiso 1 1 calc R U . . .
C14 C 0.3712(5) -0.2853(4) 0.4551(3) 0.0315(16) Uani 1 1 d . . . . .
H14 H 0.361358 -0.343666 0.480392 0.038 Uiso 1 1 calc R U . . .
C15 C 0.4401(5) -0.2307(4) 0.4721(3) 0.0293(15) Uani 1 1 d . . . . .
H15 H 0.477671 -0.251417 0.508840 0.035 Uiso 1 1 calc R U . . .
C16 C 0.4536(5) -0.1461(4) 0.4349(2) 0.0252(14) Uani 1 1 d . . . . .
H16 H 0.501228 -0.108977 0.446374 0.030 Uiso 1 1 calc R U . . .
C17 C 0.6770(5) 0.1869(4) 0.1672(3) 0.0308(15) Uani 1 1 d . . . . .
H17A H 0.716839 0.195427 0.127026 0.046 Uiso 1 1 calc R U . . .
H17B H 0.728697 0.191439 0.197060 0.046 Uiso 1 1 calc R U . . .
H17C H 0.610598 0.234716 0.166695 0.046 Uiso 1 1 calc R U . . .
C18 C 0.5587(5) 0.0576(4) 0.1214(3) 0.0301(15) Uani 1 1 d . . . . .
H18A H 0.610968 0.067701 0.085360 0.045 Uiso 1 1 calc R U . . .
H18B H 0.489564 0.102814 0.114927 0.045 Uiso 1 1 calc R U . . .
H18C H 0.538352 -0.004714 0.128939 0.045 Uiso 1 1 calc R U . . .
C19 C 0.7619(5) -0.0150(4) 0.1971(3) 0.0258(14) Uani 1 1 d . . . . .
H19A H 0.813156 -0.002109 0.160856 0.039 Uiso 1 1 calc R U . . .
H19B H 0.742340 -0.077287 0.202875 0.039 Uiso 1 1 calc R U . . .
H19C H 0.799790 -0.010623 0.232489 0.039 Uiso 1 1 calc R U . . .
C20 C 0.1330(5) 0.1729(4) 0.3868(3) 0.0285(15) Uani 1 1 d . . . . .
H20A H 0.081580 0.180040 0.422188 0.043 Uiso 1 1 calc R U . . .
H20B H 0.090498 0.159285 0.355984 0.043 Uiso 1 1 calc R U . . .
H20C H 0.165090 0.230148 0.370239 0.043 Uiso 1 1 calc R U . . .
C21 C 0.3281(5) 0.1017(4) 0.4697(2) 0.0270(15) Uani 1 1 d . . . . .
H21A H 0.275519 0.107247 0.504915 0.041 Uiso 1 1 calc R U . . .
H21B H 0.359243 0.159568 0.454175 0.041 Uiso 1 1 calc R U . . .
H21C H 0.390420 0.051483 0.481694 0.041 Uiso 1 1 calc R U . . .
C22 C 0.1763(5) -0.0250(4) 0.4453(3) 0.0255(14) Uani 1 1 d . . . . .
H22A H 0.232132 -0.076698 0.463661 0.038 Uiso 1 1 calc R U . . .
H22B H 0.138429 -0.042590 0.414204 0.038 Uiso 1 1 calc R U . . .
H22C H 0.119368 -0.008819 0.476478 0.038 Uiso 1 1 calc R U . . .
C23 C 0.2126(5) 0.4747(4) 0.2396(2) 0.0197(13) Uani 1 1 d . . . . .
C24 C 0.2382(5) 0.5599(4) 0.2093(2) 0.0213(14) Uani 1 1 d . . . . .
C25 C 0.3492(5) 0.5629(4) 0.1740(2) 0.0208(14) Uani 1 1 d . . . . .
C26 C 0.4234(5) 0.4822(3) 0.1802(2) 0.0198(13) Uani 1 1 d . . . . .
C27 C 0.1630(5) 0.6482(4) 0.2136(3) 0.0262(15) Uani 1 1 d . . . . .
C28 C 0.1471(5) 0.6731(4) 0.2693(3) 0.0366(17) Uani 1 1 d . . . . .
H28 H 0.185286 0.634434 0.302882 0.044 Uiso 1 1 calc R U . . .
C29 C 0.0769(6) 0.7526(4) 0.2771(3) 0.0475(19) Uani 1 1 d . . . . .
H29 H 0.067340 0.768325 0.315501 0.057 Uiso 1 1 calc R U . . .
C30 C 0.0212(6) 0.8085(5) 0.2287(4) 0.053(2) Uani 1 1 d . . . . .
H30 H -0.027891 0.862642 0.233899 0.063 Uiso 1 1 calc R U . . .
C31 C 0.0357(6) 0.7868(5) 0.1727(4) 0.054(2) Uani 1 1 d . . . . .
H31 H -0.002424 0.826319 0.139399 0.065 Uiso 1 1 calc R U . . .
C32 C 0.1073(5) 0.7058(4) 0.1648(3) 0.0368(17) Uani 1 1 d . . . . .
H32 H 0.117485 0.690647 0.126216 0.044 Uiso 1 1 calc R U . . .
C33 C 0.3716(5) 0.6509(4) 0.1309(2) 0.0214(14) Uani 1 1 d . . . . .
C34 C 0.3814(5) 0.7304(4) 0.1509(3) 0.0278(15) Uani 1 1 d . . . . .
H34 H 0.370461 0.730575 0.192775 0.033 Uiso 1 1 calc R U . . .
C35 C 0.4073(6) 0.8093(4) 0.1089(3) 0.0391(18) Uani 1 1 d . . . . .
H35 H 0.414517 0.862829 0.122633 0.047 Uiso 1 1 calc R U . . .
C36 C 0.4225(7) 0.8104(4) 0.0485(3) 0.050(2) Uani 1 1 d . . . . .
H36 H 0.441195 0.864161 0.020541 0.060 Uiso 1 1 calc R U . . .
C37 C 0.4104(6) 0.7331(4) 0.0283(3) 0.0415(18) Uani 1 1 d . . . . .
H37 H 0.419552 0.733947 -0.013761 0.050 Uiso 1 1 calc R U . . .
C38 C 0.3851(5) 0.6546(4) 0.0693(3) 0.0293(15) Uani 1 1 d . . . . .
H38 H 0.376702 0.601938 0.054887 0.035 Uiso 1 1 calc R U . . .
C39 C 0.0884(5) 0.4336(4) 0.3646(3) 0.0315(16) Uani 1 1 d . . . . .
H39A H 0.090818 0.493358 0.373994 0.047 Uiso 1 1 calc R U . . .
H39B H 0.158386 0.391963 0.376684 0.047 Uiso 1 1 calc R U . . .
H39C H 0.022454 0.407117 0.386590 0.047 Uiso 1 1 calc R U . . .
C40 C 0.0375(5) 0.3436(4) 0.2625(3) 0.0292(15) Uani 1 1 d . . . . .
H40A H -0.028086 0.323870 0.288814 0.044 Uiso 1 1 calc R U . . .
H40B H 0.102469 0.294244 0.268926 0.044 Uiso 1 1 calc R U . . .
H40C H 0.018155 0.357569 0.220149 0.044 Uiso 1 1 calc R U . . .
C41 C -0.0517(5) 0.5386(4) 0.2598(3) 0.0382(17) Uani 1 1 d . . . . .
H41A H -0.057523 0.552240 0.215863 0.057 Uiso 1 1 calc R U . . .
H41B H -0.043314 0.594971 0.272327 0.057 Uiso 1 1 calc R U . . .
H41C H -0.120695 0.515091 0.280063 0.057 Uiso 1 1 calc R U . . .
C42 C 0.5819(5) 0.4186(4) 0.0812(2) 0.0250(14) Uani 1 1 d . . . . .
H42A H 0.536591 0.367754 0.089811 0.038 Uiso 1 1 calc R U . . .
H42B H 0.661366 0.395400 0.071148 0.038 Uiso 1 1 calc R U . . .
H42C H 0.551693 0.466022 0.046866 0.038 Uiso 1 1 calc R U . . .
C43 C 0.6653(5) 0.3927(4) 0.2085(2) 0.0261(14) Uani 1 1 d . . . . .
H43A H 0.629234 0.338007 0.227102 0.039 Uiso 1 1 calc R U . . .
H43B H 0.674088 0.425941 0.239621 0.039 Uiso 1 1 calc R U . . .
H43C H 0.740299 0.373867 0.190025 0.039 Uiso 1 1 calc R U . . .
C44 C 0.6419(5) 0.5775(4) 0.1294(3) 0.0304(15) Uani 1 1 d . . . . .
H44A H 0.723409 0.562184 0.119092 0.046 Uiso 1 1 calc R U . . .
H44B H 0.631955 0.606784 0.164026 0.046 Uiso 1 1 calc R U . . .
H44C H 0.605728 0.619842 0.094628 0.046 Uiso 1 1 calc R U . . .
C45 C 0.2069(5) 0.2460(4) 0.1606(2) 0.0222(14) Uani 1 1 d . . . . .
C46 C 0.0571(5) 0.2783(4) 0.1002(3) 0.0332(16) Uani 1 1 d . . . . .
C47 C 0.0598(5) 0.1892(4) 0.1327(3) 0.0324(16) Uani 1 1 d . . . . .
C48 C -0.0254(6) 0.3305(5) 0.0543(3) 0.053(2) Uani 1 1 d . . . . .
H48A H -0.076679 0.377215 0.071137 0.079 Uiso 1 1 calc R U . . .
H48B H -0.070034 0.287876 0.043760 0.079 Uiso 1 1 calc R U . . .
H48C H 0.016477 0.360639 0.017892 0.079 Uiso 1 1 calc R U . . .
C49 C -0.0182(5) 0.1236(4) 0.1294(3) 0.0437(18) Uani 1 1 d . . . . .
H49A H 0.026456 0.065102 0.124266 0.066 Uiso 1 1 calc R U . . .
H49B H -0.065943 0.149238 0.094973 0.066 Uiso 1 1 calc R U . . .
H49C H -0.066776 0.112903 0.166900 0.066 Uiso 1 1 calc R U . . .
C50 C 0.1886(5) 0.4019(4) 0.0925(3) 0.0325(16) Uani 1 1 d . . . . .
H50 H 0.246363 0.408115 0.119874 0.039 Uiso 1 1 calc R U . . .
C51 C 0.2500(6) 0.4015(5) 0.0308(3) 0.0467(19) Uani 1 1 d . . . . .
H51A H 0.310677 0.348650 0.034318 0.070 Uiso 1 1 calc R U . . .
H51B H 0.283143 0.458612 0.016039 0.070 Uiso 1 1 calc R U . . .
H51C H 0.195658 0.396958 0.002244 0.070 Uiso 1 1 calc R U . . .
C52 C 0.0943(6) 0.4835(4) 0.0914(3) 0.0453(19) Uani 1 1 d . . . . .
H52A H 0.042483 0.485867 0.059929 0.068 Uiso 1 1 calc R U . . .
H52B H 0.127991 0.540688 0.082657 0.068 Uiso 1 1 calc R U . . .
H52C H 0.051888 0.476474 0.130837 0.068 Uiso 1 1 calc R U . . .
C53 C 0.1884(5) 0.0843(4) 0.2119(3) 0.0276(15) Uani 1 1 d . . . . .
H53 H 0.248059 0.096849 0.235758 0.033 Uiso 1 1 calc R U . . .
C54 C 0.2451(5) 0.0107(4) 0.1791(3) 0.0371(17) Uani 1 1 d . . . . .
H54A H 0.189564 -0.003869 0.154947 0.056 Uiso 1 1 calc R U . . .
H54B H 0.273610 -0.044878 0.208689 0.056 Uiso 1 1 calc R U . . .
H54C H 0.308790 0.033318 0.152379 0.056 Uiso 1 1 calc R U . . .
C55 C 0.0921(5) 0.0522(4) 0.2576(3) 0.0355(16) Uani 1 1 d . . . . .
H55A H 0.046898 0.105560 0.270285 0.053 Uiso 1 1 calc R U . . .
H55B H 0.124766 0.008807 0.293029 0.053 Uiso 1 1 calc R U . . .
H55C H 0.043183 0.021808 0.238785 0.053 Uiso 1 1 calc R U . . .
C56 C 0.5453(5) 0.3234(4) 0.3450(2) 0.0182(13) Uani 1 1 d . . . . .
C57 C 0.7116(5) 0.3199(4) 0.3865(2) 0.0201(14) Uani 1 1 d . . . . .
C58 C 0.6517(5) 0.4042(4) 0.3851(2) 0.0201(13) Uani 1 1 d . . . . .
C59 C 0.8230(5) 0.2806(4) 0.4141(3) 0.0301(15) Uani 1 1 d . . . . .
H59A H 0.817357 0.219444 0.439876 0.045 Uiso 1 1 calc R U . . .
H59B H 0.841750 0.321161 0.438556 0.045 Uiso 1 1 calc R U . . .
H59C H 0.882849 0.275575 0.381938 0.045 Uiso 1 1 calc R U . . .
C60 C 0.6850(5) 0.4828(4) 0.4054(3) 0.0297(15) Uani 1 1 d . . . . .
H60A H 0.703842 0.530292 0.370030 0.045 Uiso 1 1 calc R U . . .
H60B H 0.751610 0.461033 0.429862 0.045 Uiso 1 1 calc R U . . .
H60C H 0.621551 0.508852 0.429805 0.045 Uiso 1 1 calc R U . . .
C61 C 0.6775(4) 0.1783(3) 0.3476(2) 0.0189(13) Uani 1 1 d . . . . .
H61 H 0.627589 0.176632 0.315025 0.023 Uiso 1 1 calc R U . . .
C62 C 0.7992(5) 0.1611(4) 0.3217(3) 0.0274(15) Uani 1 1 d . . . . .
H62A H 0.851722 0.149920 0.354106 0.041 Uiso 1 1 calc R U . . .
H62B H 0.815690 0.215115 0.290560 0.041 Uiso 1 1 calc R U . . .
H62C H 0.808636 0.107158 0.303706 0.041 Uiso 1 1 calc R U . . .
C63 C 0.6478(5) 0.1033(4) 0.4016(3) 0.0265(15) Uani 1 1 d . . . . .
H63A H 0.694866 0.101688 0.435017 0.040 Uiso 1 1 calc R U . . .
H63B H 0.662350 0.043604 0.390212 0.040 Uiso 1 1 calc R U . . .
H63C H 0.567153 0.116416 0.414443 0.040 Uiso 1 1 calc R U . . .
C64 C 0.4498(5) 0.4796(3) 0.3532(2) 0.0224(14) Uani 1 1 d . . . . .
H64 H 0.395810 0.462057 0.328316 0.027 Uiso 1 1 calc R U . . .
C65 C 0.4814(5) 0.5728(4) 0.3181(3) 0.0285(15) Uani 1 1 d . . . . .
H65A H 0.411821 0.615795 0.307215 0.043 Uiso 1 1 calc R U . . .
H65B H 0.527725 0.564858 0.281304 0.043 Uiso 1 1 calc R U . . .
H65C H 0.525004 0.597521 0.343491 0.043 Uiso 1 1 calc R U . . .
C66 C 0.3877(5) 0.4823(4) 0.4140(3) 0.0321(16) Uani 1 1 d . . . . .
H66A H 0.437407 0.499696 0.440100 0.048 Uiso 1 1 calc R U . . .
H66B H 0.367030 0.421351 0.432978 0.048 Uiso 1 1 calc R U . . .
H66C H 0.318583 0.527635 0.408415 0.048 Uiso 1 1 calc R U . . .
O1 O 0.0943(4) 0.2404(3) 0.5759(2) 0.0479(13) Uani 1 1 d D . . . .
C67 C 0.0830(5) 0.0831(4) 0.6184(3) 0.0451(18) Uani 1 1 d D . . . .
H67A H 0.073088 0.094334 0.659343 0.068 Uiso 1 1 calc R U . . .
H67B H 0.164404 0.068000 0.607691 0.068 Uiso 1 1 calc R U . . .
H67C H 0.043617 0.031545 0.616776 0.068 Uiso 1 1 calc R U . . .
C68 C 0.0336(6) 0.1686(4) 0.5739(3) 0.0426(18) Uani 1 1 d D . . . .
H68A H 0.040673 0.157180 0.532580 0.051 Uiso 1 1 calc R U . . .
H68B H -0.048108 0.185458 0.585021 0.051 Uiso 1 1 calc R U . . .
C69 C 0.0575(8) 0.3238(5) 0.5332(3) 0.079(3) Uani 1 1 d D . . . .
H69A H -0.024337 0.344512 0.541619 0.095 Uiso 1 1 calc R U . . .
H69B H 0.067853 0.312900 0.491672 0.095 Uiso 1 1 calc R U . . .
C70 C 0.1250(7) 0.3950(5) 0.5380(4) 0.073(3) Uani 1 1 d D . . . .
H70A H 0.105110 0.450447 0.506396 0.110 Uiso 1 1 calc R U . . .
H70B H 0.206255 0.372088 0.532996 0.110 Uiso 1 1 calc R U . . .
H70C H 0.108441 0.409993 0.577856 0.110 Uiso 1 1 calc R U . . .
O2 O 0.1611(19) 0.0862(14) -0.0207(11) 0.201(11) Uiso 0.5 1 d D . P A 1
C71 C 0.1396(19) -0.0906(13) 0.0104(10) 0.096(8) Uiso 0.5 1 d D . P A 1
H71A H 0.194909 -0.140825 0.031016 0.144 Uiso 0.5 1 calc R U P A 1
H71B H 0.067620 -0.088021 0.035003 0.144 Uiso 0.5 1 calc R U P A 1
H71C H 0.126585 -0.101535 -0.029059 0.144 Uiso 0.5 1 calc R U P A 1
C72 C 0.185(3) -0.0011(15) 0.0013(14) 0.155(14) Uiso 0.5 1 d D . P A 1
H72A H 0.202654 -0.001974 0.043133 0.186 Uiso 0.5 1 calc R U P A 1
H72B H 0.260353 -0.015198 -0.019554 0.186 Uiso 0.5 1 calc R U P A 1
C73 C 0.254(2) 0.1311(16) -0.0085(12) 0.167(11) Uiso 0.5 1 d D . P A 1
H73B H 0.248419 0.142053 0.032983 0.200 Uiso 0.5 1 calc R U P A 1
H73A H 0.330569 0.100614 -0.018752 0.200 Uiso 0.5 1 calc R U P A 1
C74 C 0.2155(19) 0.2063(13) -0.0510(10) 0.101(8) Uiso 0.5 1 d D . P A 1
H74A H 0.264276 0.253900 -0.054118 0.152 Uiso 0.5 1 calc R U P A 1
H74B H 0.217604 0.189424 -0.090123 0.152 Uiso 0.5 1 calc R U P A 1
H74C H 0.137071 0.230048 -0.039407 0.152 Uiso 0.5 1 calc R U P A 1
O2B O 0.1728(17) 0.0679(12) -0.0476(9) 0.051(6) Uiso 0.25 1 d D . P B 2
C71B C 0.146(4) -0.065(2) 0.0285(19) 0.106(17) Uiso 0.25 1 d D . P B 2
H71D H 0.164160 -0.094075 0.070356 0.159 Uiso 0.25 1 calc R U P B 2
H71E H 0.063635 -0.052809 0.025455 0.159 Uiso 0.25 1 calc R U P B 2
H71F H 0.180300 -0.105819 0.001870 0.159 Uiso 0.25 1 calc R U P B 2
C72B C 0.196(3) 0.027(2) 0.0092(10) 0.041(8) Uiso 0.25 1 d D . P B 2
H72C H 0.162243 0.067706 0.036393 0.049 Uiso 0.25 1 calc R U P B 2
H72D H 0.279066 0.014625 0.012777 0.049 Uiso 0.25 1 calc R U P B 2
C73B C 0.242(2) 0.1409(15) -0.0666(14) 0.065(9) Uiso 0.25 1 d D . P B 2
H73C H 0.297155 0.136837 -0.035837 0.078 Uiso 0.25 1 calc R U P B 2
H73D H 0.284793 0.136242 -0.105434 0.078 Uiso 0.25 1 calc R U P B 2
C74B C 0.169(3) 0.2231(15) -0.0732(15) 0.059(10) Uiso 0.25 1 d D . P B 2
H74E H 0.213109 0.274592 -0.086079 0.089 Uiso 0.25 1 calc R U P B 2
H74D H 0.114907 0.226302 -0.103714 0.089 Uiso 0.25 1 calc R U P B 2
H74F H 0.127215 0.226895 -0.034425 0.089 Uiso 0.25 1 calc R U P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 C45 2.002(6) . ?
Ge1 Si4 2.4434(16) . ?
Ge1 Si1 2.4620(16) . ?
Ge2 C56 2.016(5) . ?
Ge2 Si4 2.4311(16) . ?
Ge2 Si1 2.4501(16) . ?
Si1 C1 1.905(5) . ?
Si1 C4 1.909(5) . ?
Si2 C18 1.862(6) . ?
Si2 C1 1.867(5) . ?
Si2 C19 1.869(5) . ?
Si2 C17 1.875(5) . ?
Si3 C21 1.859(6) . ?
Si3 C20 1.863(6) . ?
Si3 C4 1.870(5) . ?
Si3 C22 1.873(5) . ?
Si4 C26 1.891(5) . ?
Si4 C23 1.892(5) . ?
Si5 C23 1.853(6) . ?
Si5 C39 1.874(6) . ?
Si5 C41 1.878(6) . ?
Si5 C40 1.879(6) . ?
Si6 C43 1.863(6) . ?
Si6 C26 1.863(6) . ?
Si6 C42 1.874(5) . ?
Si6 C44 1.877(5) . ?
N1 C45 1.374(7) . ?
N1 C46 1.402(7) . ?
N1 C50 1.476(7) . ?
N2 C45 1.360(7) . ?
N2 C47 1.386(7) . ?
N2 C53 1.475(7) . ?
N3 C56 1.357(7) . ?
N3 C57 1.395(6) . ?
N3 C61 1.489(6) . ?
N4 C56 1.369(6) . ?
N4 C58 1.394(7) . ?
N4 C64 1.481(7) . ?
C1 C2 1.382(7) . ?
C2 C3 1.487(7) . ?
C2 C5 1.492(7) . ?
C3 C4 1.361(7) . ?
C3 C11 1.501(7) . ?
C5 C10 1.378(8) . ?
C5 C6 1.384(7) . ?
C6 C7 1.387(7) . ?
C6 H6 0.9500 . ?
C7 C8 1.377(8) . ?
C7 H7 0.9500 . ?
C8 C9 1.386(8) . ?
C8 H8 0.9500 . ?
C9 C10 1.379(8) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 C16 1.379(7) . ?
C11 C12 1.389(7) . ?
C12 C13 1.382(7) . ?
C12 H12 0.9500 . ?
C13 C14 1.382(8) . ?
C13 H13 0.9500 . ?
C14 C15 1.388(8) . ?
C14 H14 0.9500 . ?
C15 C16 1.382(7) . ?
C15 H15 0.9500 . ?
C16 H16 0.9500 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 C24 1.377(7) . ?
C24 C25 1.483(7) . ?
C24 C27 1.499(7) . ?
C25 C26 1.371(7) . ?
C25 C33 1.500(7) . ?
C27 C32 1.390(8) . ?
C27 C28 1.393(8) . ?
C28 C29 1.385(8) . ?
C28 H28 0.9500 . ?
C29 C30 1.375(10) . ?
C29 H29 0.9500 . ?
C30 C31 1.378(10) . ?
C30 H30 0.9500 . ?
C31 C32 1.411(9) . ?
C31 H31 0.9500 . ?
C32 H32 0.9500 . ?
C33 C38 1.386(7) . ?
C33 C34 1.404(7) . ?
C34 C35 1.399(8) . ?
C34 H34 0.9500 . ?
C35 C36 1.367(8) . ?
C35 H35 0.9500 . ?
C36 C37 1.383(8) . ?
C36 H36 0.9500 . ?
C37 C38 1.382(8) . ?
C37 H37 0.9500 . ?
C38 H38 0.9500 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C46 C47 1.372(8) . ?
C46 C48 1.497(8) . ?
C47 C49 1.480(8) . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 C51 1.522(8) . ?
C50 C52 1.524(8) . ?
C50 H50 1.0000 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 C54 1.516(8) . ?
C53 C55 1.533(8) . ?
C53 H53 1.0000 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C57 C58 1.348(7) . ?
C57 C59 1.496(7) . ?
C58 C60 1.492(7) . ?
C59 H59A 0.9800 . ?
C59 H59B 0.9800 . ?
C59 H59C 0.9800 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 C62 1.518(7) . ?
C61 C63 1.521(7) . ?
C61 H61 1.0000 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 C66 1.513(7) . ?
C64 C65 1.531(7) . ?
C64 H64 1.0000 . ?
C65 H65A 0.9800 . ?
C65 H65B 0.9800 . ?
C65 H65C 0.9800 . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
O1 C68 1.406(7) . ?
O1 C69 1.433(8) . ?
C67 C68 1.514(8) . ?
C67 H67A 0.9800 . ?
C67 H67B 0.9800 . ?
C67 H67C 0.9800 . ?
C68 H68A 0.9900 . ?
C68 H68B 0.9900 . ?
C69 C70 1.470(9) . ?
C69 H69A 0.9900 . ?
C69 H69B 0.9900 . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
O2 C72 1.291(16) . ?
O2 C73 1.462(17) . ?
C71 C72 1.498(17) . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C72 H72A 0.9900 . ?
C72 H72B 0.9900 . ?
C73 C74 1.355(17) . ?
C73 H73B 0.9900 . ?
C73 H73A 0.9900 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
O2B C72B 1.330(17) . ?
O2B C73B 1.442(17) . ?
C71B C72B 1.538(19) . ?
C71B H71D 0.9800 . ?
C71B H71E 0.9800 . ?
C71B H71F 0.9800 . ?
C72B H72C 0.9900 . ?
C72B H72D 0.9900 . ?
C73B C74B 1.381(19) . ?
C73B H73C 0.9900 . ?
C73B H73D 0.9900 . ?
C74B H74E 0.9800 . ?
C74B H74D 0.9800 . ?
C74B H74F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C45 Ge1 Si4 108.55(16) . . ?
C45 Ge1 Si1 115.59(16) . . ?
Si4 Ge1 Si1 91.76(5) . . ?
C56 Ge2 Si4 106.90(15) . . ?
C56 Ge2 Si1 117.29(15) . . ?
Si4 Ge2 Si1 92.35(5) . . ?
C1 Si1 C4 92.5(2) . . ?
C1 Si1 Ge2 140.98(18) . . ?
C4 Si1 Ge2 105.18(17) . . ?
C1 Si1 Ge1 102.37(17) . . ?
C4 Si1 Ge1 138.00(18) . . ?
Ge2 Si1 Ge1 87.52(5) . . ?
C18 Si2 C1 111.0(3) . . ?
C18 Si2 C19 107.8(3) . . ?
C1 Si2 C19 114.0(2) . . ?
C18 Si2 C17 106.8(3) . . ?
C1 Si2 C17 110.8(2) . . ?
C19 Si2 C17 106.0(3) . . ?
C21 Si3 C20 109.2(3) . . ?
C21 Si3 C4 108.7(3) . . ?
C20 Si3 C4 111.9(3) . . ?
C21 Si3 C22 107.3(3) . . ?
C20 Si3 C22 104.5(3) . . ?
C4 Si3 C22 114.9(2) . . ?
C26 Si4 C23 93.0(2) . . ?
C26 Si4 Ge2 127.82(18) . . ?
C23 Si4 Ge2 112.11(17) . . ?
C26 Si4 Ge1 111.85(17) . . ?
C23 Si4 Ge1 127.81(18) . . ?
Ge2 Si4 Ge1 88.37(5) . . ?
C23 Si5 C39 110.2(3) . . ?
C23 Si5 C41 116.0(3) . . ?
C39 Si5 C41 107.2(3) . . ?
C23 Si5 C40 108.5(2) . . ?
C39 Si5 C40 111.4(3) . . ?
C41 Si5 C40 103.5(3) . . ?
C43 Si6 C26 109.2(3) . . ?
C43 Si6 C42 110.6(3) . . ?
C26 Si6 C42 108.4(3) . . ?
C43 Si6 C44 103.2(3) . . ?
C26 Si6 C44 115.7(2) . . ?
C42 Si6 C44 109.6(3) . . ?
C45 N1 C46 110.2(5) . . ?
C45 N1 C50 121.4(5) . . ?
C46 N1 C50 128.1(5) . . ?
C45 N2 C47 111.7(5) . . ?
C45 N2 C53 122.1(5) . . ?
C47 N2 C53 126.2(5) . . ?
C56 N3 C57 110.6(4) . . ?
C56 N3 C61 120.7(4) . . ?
C57 N3 C61 128.6(4) . . ?
C56 N4 C58 110.5(4) . . ?
C56 N4 C64 121.5(4) . . ?
C58 N4 C64 127.8(4) . . ?
C2 C1 Si2 122.7(4) . . ?
C2 C1 Si1 106.1(4) . . ?
Si2 C1 Si1 130.1(3) . . ?
C1 C2 C3 117.2(5) . . ?
C1 C2 C5 123.6(5) . . ?
C3 C2 C5 119.3(5) . . ?
C4 C3 C2 117.8(5) . . ?
C4 C3 C11 126.2(5) . . ?
C2 C3 C11 116.0(4) . . ?
C3 C4 Si3 123.1(4) . . ?
C3 C4 Si1 106.4(4) . . ?
Si3 C4 Si1 129.4(3) . . ?
C10 C5 C6 118.0(5) . . ?
C10 C5 C2 121.9(5) . . ?
C6 C5 C2 120.1(5) . . ?
C5 C6 C7 121.5(6) . . ?
C5 C6 H6 119.3 . . ?
C7 C6 H6 119.3 . . ?
C8 C7 C6 119.6(6) . . ?
C8 C7 H7 120.2 . . ?
C6 C7 H7 120.2 . . ?
C7 C8 C9 119.5(5) . . ?
C7 C8 H8 120.3 . . ?
C9 C8 H8 120.3 . . ?
C10 C9 C8 120.1(6) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C5 C10 C9 121.2(6) . . ?
C5 C10 H10 119.4 . . ?
C9 C10 H10 119.4 . . ?
C16 C11 C12 118.4(5) . . ?
C16 C11 C3 121.2(5) . . ?
C12 C11 C3 120.4(5) . . ?
C13 C12 C11 121.0(6) . . ?
C13 C12 H12 119.5 . . ?
C11 C12 H12 119.5 . . ?
C14 C13 C12 119.8(6) . . ?
C14 C13 H13 120.1 . . ?
C12 C13 H13 120.1 . . ?
C13 C14 C15 120.0(5) . . ?
C13 C14 H14 120.0 . . ?
C15 C14 H14 120.0 . . ?
C16 C15 C14 119.3(6) . . ?
C16 C15 H15 120.3 . . ?
C14 C15 H15 120.3 . . ?
C11 C16 C15 121.5(6) . . ?
C11 C16 H16 119.2 . . ?
C15 C16 H16 119.2 . . ?
Si2 C17 H17A 109.5 . . ?
Si2 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si2 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si2 C18 H18A 109.5 . . ?
Si2 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
Si2 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si2 C19 H19A 109.5 . . ?
Si2 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
Si2 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si3 C20 H20A 109.5 . . ?
Si3 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Si3 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si3 C21 H21A 109.5 . . ?
Si3 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
Si3 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si3 C22 H22A 109.5 . . ?
Si3 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
Si3 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C24 C23 Si5 126.4(4) . . ?
C24 C23 Si4 106.0(4) . . ?
Si5 C23 Si4 127.6(3) . . ?
C23 C24 C25 117.2(5) . . ?
C23 C24 C27 123.2(5) . . ?
C25 C24 C27 119.5(5) . . ?
C26 C25 C24 117.2(5) . . ?
C26 C25 C33 123.6(5) . . ?
C24 C25 C33 119.1(5) . . ?
C25 C26 Si6 126.1(4) . . ?
C25 C26 Si4 106.2(4) . . ?
Si6 C26 Si4 127.6(3) . . ?
C32 C27 C28 118.5(5) . . ?
C32 C27 C24 123.0(5) . . ?
C28 C27 C24 118.4(5) . . ?
C29 C28 C27 121.7(6) . . ?
C29 C28 H28 119.1 . . ?
C27 C28 H28 119.1 . . ?
C30 C29 C28 119.3(7) . . ?
C30 C29 H29 120.4 . . ?
C28 C29 H29 120.4 . . ?
C29 C30 C31 120.8(6) . . ?
C29 C30 H30 119.6 . . ?
C31 C30 H30 119.6 . . ?
C30 C31 C32 119.9(7) . . ?
C30 C31 H31 120.0 . . ?
C32 C31 H31 120.0 . . ?
C27 C32 C31 119.8(6) . . ?
C27 C32 H32 120.1 . . ?
C31 C32 H32 120.1 . . ?
C38 C33 C34 118.1(5) . . ?
C38 C33 C25 119.8(5) . . ?
C34 C33 C25 122.1(5) . . ?
C35 C34 C33 119.7(5) . . ?
C35 C34 H34 120.2 . . ?
C33 C34 H34 120.2 . . ?
C36 C35 C34 121.0(6) . . ?
C36 C35 H35 119.5 . . ?
C34 C35 H35 119.5 . . ?
C35 C36 C37 119.8(6) . . ?
C35 C36 H36 120.1 . . ?
C37 C36 H36 120.1 . . ?
C38 C37 C36 119.9(6) . . ?
C38 C37 H37 120.1 . . ?
C36 C37 H37 120.1 . . ?
C37 C38 C33 121.6(5) . . ?
C37 C38 H38 119.2 . . ?
C33 C38 H38 119.2 . . ?
Si5 C39 H39A 109.5 . . ?
Si5 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
Si5 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
Si5 C40 H40A 109.5 . . ?
Si5 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
Si5 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
Si5 C41 H41A 109.5 . . ?
Si5 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
Si5 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
Si6 C42 H42A 109.5 . . ?
Si6 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
Si6 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
Si6 C43 H43A 109.5 . . ?
Si6 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
Si6 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
Si6 C44 H44A 109.5 . . ?
Si6 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
Si6 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
N2 C45 N1 104.9(5) . . ?
N2 C45 Ge1 129.7(4) . . ?
N1 C45 Ge1 123.9(4) . . ?
C47 C46 N1 106.7(5) . . ?
C47 C46 C48 127.6(6) . . ?
N1 C46 C48 125.6(6) . . ?
C46 C47 N2 106.4(5) . . ?
C46 C47 C49 127.3(6) . . ?
N2 C47 C49 126.3(6) . . ?
C46 C48 H48A 109.5 . . ?
C46 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C46 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C47 C49 H49A 109.5 . . ?
C47 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C47 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
N1 C50 C51 109.8(5) . . ?
N1 C50 C52 113.0(5) . . ?
C51 C50 C52 112.9(5) . . ?
N1 C50 H50 106.9 . . ?
C51 C50 H50 106.9 . . ?
C52 C50 H50 106.9 . . ?
C50 C51 H51A 109.5 . . ?
C50 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C50 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C50 C52 H52A 109.5 . . ?
C50 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C50 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
N2 C53 C54 111.6(5) . . ?
N2 C53 C55 112.3(5) . . ?
C54 C53 C55 112.8(5) . . ?
N2 C53 H53 106.6 . . ?
C54 C53 H53 106.6 . . ?
C55 C53 H53 106.6 . . ?
C53 C54 H54A 109.5 . . ?
C53 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C53 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C53 C55 H55A 109.5 . . ?
C53 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C53 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
N3 C56 N4 104.9(4) . . ?
N3 C56 Ge2 130.8(4) . . ?
N4 C56 Ge2 122.6(4) . . ?
C58 C57 N3 107.2(5) . . ?
C58 C57 C59 127.8(5) . . ?
N3 C57 C59 124.8(5) . . ?
C57 C58 N4 106.7(5) . . ?
C57 C58 C60 128.4(5) . . ?
N4 C58 C60 124.8(5) . . ?
C57 C59 H59A 109.5 . . ?
C57 C59 H59B 109.5 . . ?
H59A C59 H59B 109.5 . . ?
C57 C59 H59C 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?
C58 C60 H60A 109.5 . . ?
C58 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C58 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
N3 C61 C62 113.1(4) . . ?
N3 C61 C63 111.4(4) . . ?
C62 C61 C63 113.6(4) . . ?
N3 C61 H61 106.0 . . ?
C62 C61 H61 106.0 . . ?
C63 C61 H61 106.0 . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C61 C63 H63A 109.5 . . ?
C61 C63 H63B 109.5 . . ?
H63A C63 H63B 109.5 . . ?
C61 C63 H63C 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
N4 C64 C66 110.6(5) . . ?
N4 C64 C65 112.5(4) . . ?
C66 C64 C65 113.9(4) . . ?
N4 C64 H64 106.4 . . ?
C66 C64 H64 106.4 . . ?
C65 C64 H64 106.4 . . ?
C64 C65 H65A 109.5 . . ?
C64 C65 H65B 109.5 . . ?
H65A C65 H65B 109.5 . . ?
C64 C65 H65C 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?
C64 C66 H66A 109.5 . . ?
C64 C66 H66B 109.5 . . ?
H66A C66 H66B 109.5 . . ?
C64 C66 H66C 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
C68 O1 C69 112.5(5) . . ?
C68 C67 H67A 109.5 . . ?
C68 C67 H67B 109.5 . . ?
H67A C67 H67B 109.5 . . ?
C68 C67 H67C 109.5 . . ?
H67A C67 H67C 109.5 . . ?
H67B C67 H67C 109.5 . . ?
O1 C68 C67 108.0(5) . . ?
O1 C68 H68A 110.1 . . ?
C67 C68 H68A 110.1 . . ?
O1 C68 H68B 110.1 . . ?
C67 C68 H68B 110.1 . . ?
H68A C68 H68B 108.4 . . ?
O1 C69 C70 109.1(6) . . ?
O1 C69 H69A 109.9 . . ?
C70 C69 H69A 109.9 . . ?
O1 C69 H69B 109.9 . . ?
C70 C69 H69B 109.9 . . ?
H69A C69 H69B 108.3 . . ?
C69 C70 H70A 109.5 . . ?
C69 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C69 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
C72 O2 C73 108(2) . . ?
C72 C71 H71A 109.5 . . ?
C72 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C72 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
O2 C72 C71 143(3) . . ?
O2 C72 H72A 101.3 . . ?
C71 C72 H72A 101.3 . . ?
O2 C72 H72B 101.3 . . ?
C71 C72 H72B 101.3 . . ?
H72A C72 H72B 104.5 . . ?
C74 C73 O2 88.8(16) . . ?
C74 C73 H73B 113.9 . . ?
O2 C73 H73B 113.9 . . ?
C74 C73 H73A 113.9 . . ?
O2 C73 H73A 113.9 . . ?
H73B C73 H73A 111.1 . . ?
C73 C74 H74A 109.5 . . ?
C73 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C73 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C72B O2B C73B 107.2(18) . . ?
C72B C71B H71D 109.5 . . ?
C72B C71B H71E 109.5 . . ?
H71D C71B H71E 109.5 . . ?
C72B C71B H71F 109.5 . . ?
H71D C71B H71F 109.5 . . ?
H71E C71B H71F 109.5 . . ?
O2B C72B C71B 111(2) . . ?
O2B C72B H72C 109.5 . . ?
C71B C72B H72C 109.5 . . ?
O2B C72B H72D 109.5 . . ?
C71B C72B H72D 109.5 . . ?
H72C C72B H72D 108.1 . . ?
C74B C73B O2B 107.1(19) . . ?
C74B C73B H73C 110.3 . . ?
O2B C73B H73C 110.3 . . ?
C74B C73B H73D 110.3 . . ?
O2B C73B H73D 110.3 . . ?
H73C C73B H73D 108.6 . . ?
C73B C74B H74E 109.5 . . ?
C73B C74B H74D 109.5 . . ?
H74E C74B H74D 109.5 . . ?
C73B C74B H74F 109.5 . . ?
H74E C74B H74F 109.5 . . ?
H74D C74B H74F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C18 Si2 C1 C2 82.6(5) . . . . ?
C19 Si2 C1 C2 -39.4(5) . . . . ?
C17 Si2 C1 C2 -158.9(5) . . . . ?
C18 Si2 C1 Si1 -84.0(4) . . . . ?
C19 Si2 C1 Si1 154.1(3) . . . . ?
C17 Si2 C1 Si1 34.6(5) . . . . ?
Si2 C1 C2 C3 -171.8(4) . . . . ?
Si1 C1 C2 C3 -2.5(6) . . . . ?
Si2 C1 C2 C5 6.7(8) . . . . ?
Si1 C1 C2 C5 176.0(4) . . . . ?
C1 C2 C3 C4 2.4(7) . . . . ?
C5 C2 C3 C4 -176.2(5) . . . . ?
C1 C2 C3 C11 -177.0(5) . . . . ?
C5 C2 C3 C11 4.5(7) . . . . ?
C2 C3 C4 Si3 -169.7(4) . . . . ?
C11 C3 C4 Si3 9.6(8) . . . . ?
C2 C3 C4 Si1 -0.8(6) . . . . ?
C11 C3 C4 Si1 178.5(4) . . . . ?
C21 Si3 C4 C3 88.0(5) . . . . ?
C20 Si3 C4 C3 -151.3(5) . . . . ?
C22 Si3 C4 C3 -32.3(6) . . . . ?
C21 Si3 C4 Si1 -78.2(4) . . . . ?
C20 Si3 C4 Si1 42.5(5) . . . . ?
C22 Si3 C4 Si1 161.5(3) . . . . ?
C1 C2 C5 C10 100.0(7) . . . . ?
C3 C2 C5 C10 -81.5(7) . . . . ?
C1 C2 C5 C6 -78.3(7) . . . . ?
C3 C2 C5 C6 100.1(6) . . . . ?
C10 C5 C6 C7 -3.0(8) . . . . ?
C2 C5 C6 C7 175.4(5) . . . . ?
C5 C6 C7 C8 0.5(9) . . . . ?
C6 C7 C8 C9 1.3(9) . . . . ?
C7 C8 C9 C10 -0.7(9) . . . . ?
C6 C5 C10 C9 3.7(8) . . . . ?
C2 C5 C10 C9 -174.7(5) . . . . ?
C8 C9 C10 C5 -1.9(9) . . . . ?
C4 C3 C11 C16 -87.4(7) . . . . ?
C2 C3 C11 C16 91.9(6) . . . . ?
C4 C3 C11 C12 94.3(7) . . . . ?
C2 C3 C11 C12 -86.4(6) . . . . ?
C16 C11 C12 C13 1.2(8) . . . . ?
C3 C11 C12 C13 179.6(5) . . . . ?
C11 C12 C13 C14 -0.9(8) . . . . ?
C12 C13 C14 C15 0.3(9) . . . . ?
C13 C14 C15 C16 0.0(9) . . . . ?
C12 C11 C16 C15 -1.0(8) . . . . ?
C3 C11 C16 C15 -179.3(5) . . . . ?
C14 C15 C16 C11 0.4(9) . . . . ?
C39 Si5 C23 C24 -101.1(5) . . . . ?
C41 Si5 C23 C24 20.9(6) . . . . ?
C40 Si5 C23 C24 136.8(5) . . . . ?
C39 Si5 C23 Si4 79.4(4) . . . . ?
C41 Si5 C23 Si4 -158.7(3) . . . . ?
C40 Si5 C23 Si4 -42.8(4) . . . . ?
C26 Si4 C23 C24 -2.2(4) . . . . ?
Ge2 Si4 C23 C24 131.0(3) . . . . ?
Ge1 Si4 C23 C24 -123.0(3) . . . . ?
C26 Si4 C23 Si5 177.5(4) . . . . ?
Ge2 Si4 C23 Si5 -49.4(4) . . . . ?
Ge1 Si4 C23 Si5 56.7(4) . . . . ?
Si5 C23 C24 C25 -174.1(4) . . . . ?
Si4 C23 C24 C25 5.5(6) . . . . ?
Si5 C23 C24 C27 9.8(8) . . . . ?
Si4 C23 C24 C27 -170.6(5) . . . . ?
C23 C24 C25 C26 -7.7(8) . . . . ?
C27 C24 C25 C26 168.6(5) . . . . ?
C23 C24 C25 C33 168.4(5) . . . . ?
C27 C24 C25 C33 -15.4(8) . . . . ?
C24 C25 C26 Si6 -171.7(4) . . . . ?
C33 C25 C26 Si6 12.5(8) . . . . ?
C24 C25 C26 Si4 5.2(6) . . . . ?
C33 C25 C26 Si4 -170.7(4) . . . . ?
C43 Si6 C26 C25 135.4(5) . . . . ?
C42 Si6 C26 C25 -104.0(5) . . . . ?
C44 Si6 C26 C25 19.6(6) . . . . ?
C43 Si6 C26 Si4 -40.7(4) . . . . ?
C42 Si6 C26 Si4 79.9(4) . . . . ?
C44 Si6 C26 Si4 -156.6(3) . . . . ?
C23 Si4 C26 C25 -1.7(4) . . . . ?
Ge2 Si4 C26 C25 -122.9(3) . . . . ?
Ge1 Si4 C26 C25 131.3(3) . . . . ?
C23 Si4 C26 Si6 175.1(4) . . . . ?
Ge2 Si4 C26 Si6 53.9(4) . . . . ?
Ge1 Si4 C26 Si6 -51.9(4) . . . . ?
C23 C24 C27 C32 -114.4(7) . . . . ?
C25 C24 C27 C32 69.6(8) . . . . ?
C23 C24 C27 C28 64.7(8) . . . . ?
C25 C24 C27 C28 -111.3(6) . . . . ?
C32 C27 C28 C29 0.6(10) . . . . ?
C24 C27 C28 C29 -178.6(6) . . . . ?
C27 C28 C29 C30 0.2(10) . . . . ?
C28 C29 C30 C31 -0.9(11) . . . . ?
C29 C30 C31 C32 0.8(11) . . . . ?
C28 C27 C32 C31 -0.6(9) . . . . ?
C24 C27 C32 C31 178.5(6) . . . . ?
C30 C31 C32 C27 -0.1(11) . . . . ?
C26 C25 C33 C38 61.3(8) . . . . ?
C24 C25 C33 C38 -114.5(6) . . . . ?
C26 C25 C33 C34 -117.6(6) . . . . ?
C24 C25 C33 C34 66.6(7) . . . . ?
C38 C33 C34 C35 -1.8(9) . . . . ?
C25 C33 C34 C35 177.1(5) . . . . ?
C33 C34 C35 C36 0.5(10) . . . . ?
C34 C35 C36 C37 1.0(11) . . . . ?
C35 C36 C37 C38 -1.1(11) . . . . ?
C36 C37 C38 C33 -0.2(10) . . . . ?
C34 C33 C38 C37 1.6(9) . . . . ?
C25 C33 C38 C37 -177.3(6) . . . . ?
C47 N2 C45 N1 0.4(6) . . . . ?
C53 N2 C45 N1 179.3(5) . . . . ?
C47 N2 C45 Ge1 -165.6(4) . . . . ?
C53 N2 C45 Ge1 13.3(7) . . . . ?
C46 N1 C45 N2 -0.1(6) . . . . ?
C50 N1 C45 N2 -175.1(5) . . . . ?
C46 N1 C45 Ge1 167.0(4) . . . . ?
C50 N1 C45 Ge1 -8.1(7) . . . . ?
C45 N1 C46 C47 -0.3(7) . . . . ?
C50 N1 C46 C47 174.4(5) . . . . ?
C45 N1 C46 C48 -179.8(6) . . . . ?
C50 N1 C46 C48 -5.2(10) . . . . ?
N1 C46 C47 N2 0.5(7) . . . . ?
C48 C46 C47 N2 -180.0(6) . . . . ?
N1 C46 C47 C49 -179.0(6) . . . . ?
C48 C46 C47 C49 0.6(11) . . . . ?
C45 N2 C47 C46 -0.6(7) . . . . ?
C53 N2 C47 C46 -179.4(5) . . . . ?
C45 N2 C47 C49 178.9(6) . . . . ?
C53 N2 C47 C49 0.0(9) . . . . ?
C45 N1 C50 C51 100.4(6) . . . . ?
C46 N1 C50 C51 -73.7(7) . . . . ?
C45 N1 C50 C52 -132.6(6) . . . . ?
C46 N1 C50 C52 53.3(8) . . . . ?
C45 N2 C53 C54 -106.0(6) . . . . ?
C47 N2 C53 C54 72.7(7) . . . . ?
C45 N2 C53 C55 126.2(5) . . . . ?
C47 N2 C53 C55 -55.0(7) . . . . ?
C57 N3 C56 N4 1.3(6) . . . . ?
C61 N3 C56 N4 -175.6(4) . . . . ?
C57 N3 C56 Ge2 -163.7(4) . . . . ?
C61 N3 C56 Ge2 19.4(7) . . . . ?
C58 N4 C56 N3 -0.5(5) . . . . ?
C64 N4 C56 N3 -175.6(4) . . . . ?
C58 N4 C56 Ge2 166.0(4) . . . . ?
C64 N4 C56 Ge2 -9.0(7) . . . . ?
C56 N3 C57 C58 -1.7(6) . . . . ?
C61 N3 C57 C58 174.9(5) . . . . ?
C56 N3 C57 C59 174.3(5) . . . . ?
C61 N3 C57 C59 -9.1(8) . . . . ?
N3 C57 C58 N4 1.3(6) . . . . ?
C59 C57 C58 N4 -174.5(5) . . . . ?
N3 C57 C58 C60 -178.2(5) . . . . ?
C59 C57 C58 C60 6.0(9) . . . . ?
C56 N4 C58 C57 -0.5(6) . . . . ?
C64 N4 C58 C57 174.2(5) . . . . ?
C56 N4 C58 C60 179.0(5) . . . . ?
C64 N4 C58 C60 -6.3(8) . . . . ?
C56 N3 C61 C62 135.3(5) . . . . ?
C57 N3 C61 C62 -40.9(7) . . . . ?
C56 N3 C61 C63 -95.4(6) . . . . ?
C57 N3 C61 C63 88.4(6) . . . . ?
C56 N4 C64 C66 101.9(6) . . . . ?
C58 N4 C64 C66 -72.2(6) . . . . ?
C56 N4 C64 C65 -129.5(5) . . . . ?
C58 N4 C64 C65 56.4(7) . . . . ?
C69 O1 C68 C67 177.2(6) . . . . ?
C68 O1 C69 C70 -179.9(6) . . . . ?
C73 O2 C72 C71 177(4) . . . . ?
C72 O2 C73 C74 163(3) . . . . ?
C73B O2B C72B C71B -167(3) . . . . ?
C72B O2B C73B C74B -112(3) . . . . ?

_refine_diff_density_max         0.737
_refine_diff_density_min         -0.657
_refine_diff_density_rms         0.090



