# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
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# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_cu_201020_wyj_5_135_l_0m
_database_code_depnum_ccdc_archive 'CCDC 2040388'
loop_
_audit_author_name
_audit_author_address
'Yongjie Wu'
;Zhejiang University
China
;
_audit_update_record             
;
2020-10-24 deposited with the CCDC.	2021-06-02 downloaded from the CCDC.
;
_audit_creation_date             2020-10-21
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C24 H25 N3 O6'
_chemical_formula_sum            'C24 H25 N3 O6'
_chemical_formula_weight         451.47
_chemical_absolute_configuration ad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   9.3386(3)
_cell_length_b                   10.3729(3)
_cell_length_c                   24.4089(7)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2364.45(12)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9836
_cell_measurement_temperature    170(2)
_cell_measurement_theta_max      68.25
_cell_measurement_theta_min      3.62
_shelx_estimated_absorpt_T_max   0.894
_shelx_estimated_absorpt_T_min   0.755
_exptl_absorpt_coefficient_mu    0.764
_exptl_absorpt_correction_T_max  0.7531
_exptl_absorpt_correction_T_min  0.6760
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1432 before and 0.0400 after correction.
The Ratio of minimum to maximum transmission is 0.8976.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.268
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             952
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.15
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0239
_diffrn_reflns_av_unetI/netI     0.0147
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            28511
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         68.241
_diffrn_reflns_theta_min         3.621
_diffrn_ambient_temperature      170.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'zju Bruker D8 Venture Ims3.0'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.744
_reflns_Friedel_fraction_full    0.999
_reflns_Friedel_fraction_max     0.998
_reflns_number_gt                4312
_reflns_number_total             4334
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_data_collection       'Bruker Instrument Service vV6.2.10'
_computing_data_reduction        'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.196
_refine_diff_density_min         -0.240
_refine_diff_density_rms         0.044
_refine_ls_abs_structure_details 
;
 Flack x determined using 1831 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.05(3)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     322
_refine_ls_number_reflns         4334
_refine_ls_number_restraints     45
_refine_ls_R_factor_all          0.0288
_refine_ls_R_factor_gt           0.0287
_refine_ls_restrained_S_all      1.075
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0430P)²+0.3698P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0733
_refine_ls_wR_factor_ref         0.0734
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 O6-C23 \\sim O6A-C23
 with sigma of 0.02
 O6-C24 \\sim O6A-C24A
 with sigma of 0.02
 C23-C24 \\sim C23-C24A
 with sigma of 0.04
3. Uiso/Uaniso restraints and constraints
C23 \\sim O6 \\sim C24 \\sim O6A \\sim C24A: within 1.7A with sigma of 0.02 and
sigma for terminal atoms of 0.04
4. Others
 Sof(O6A)=Sof(C24A)=Sof(H24D)=Sof(H24E)=Sof(H24F)=1-FVAR(1)
 Sof(O6)=Sof(C24)=Sof(H24A)=Sof(H24B)=Sof(H24C)=FVAR(1)
5.a Ternary CH refined with riding coordinates:
 C9(H9)
5.b Secondary CH2 refined with riding coordinates:
 C20(H20A,H20B), C22(H22A,H22B)
5.c Aromatic/amide H refined with riding coordinates:
 N3(H3), C3(H3A), C4(H4), C5(H5), C14(H14), C15(H15), C17(H17)
5.d Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), C19(H19A,H19B,H19C), C24(H24A,H24B,
 H24C), C24A(H24D,H24E,H24F)
5.e :
 C8(H8)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.20084(12) 0.00301(11) 0.44213(5) 0.0285(3) Uani 1 1 d . . . . .
O2 O 0.03383(19) 0.12232(16) 0.16210(6) 0.0504(4) Uani 1 1 d . . . . .
O3 O -0.03339(16) -0.08261(14) 0.17576(5) 0.0410(3) Uani 1 1 d . . . . .
O4 O 0.24073(12) 0.27411(11) 0.48246(4) 0.0250(2) Uani 1 1 d . . . . .
O5 O 0.38029(19) 0.55344(14) 0.47760(7) 0.0518(4) Uani 1 1 d . . . . .
N1 N 0.39933(13) 0.10768(13) 0.41135(5) 0.0208(3) Uani 1 1 d . . . . .
N2 N 0.24338(16) 0.12707(15) 0.31209(6) 0.0298(3) Uani 1 1 d . . . . .
N3 N 0.44524(14) 0.31733(13) 0.52794(6) 0.0240(3) Uani 1 1 d . . . . .
H3 H 0.536112 0.297835 0.532669 0.029 Uiso 1 1 calc R . . . .
C1 C 0.51038(16) 0.10768(16) 0.37039(6) 0.0229(3) Uani 1 1 d . . . . .
C2 C 0.56432(18) -0.01249(17) 0.35316(7) 0.0285(4) Uani 1 1 d . . . . .
C3 C 0.6745(2) -0.0164(2) 0.31449(8) 0.0389(4) Uani 1 1 d . . . . .
H3A H 0.711553 -0.096827 0.302467 0.047 Uiso 1 1 calc R . . . .
C4 C 0.7292(2) 0.0969(2) 0.29390(9) 0.0455(5) Uani 1 1 d . . . . .
H4 H 0.802848 0.094417 0.267050 0.055 Uiso 1 1 calc R . . . .
C5 C 0.6779(2) 0.2140(2) 0.31200(8) 0.0384(4) Uani 1 1 d . . . . .
H5 H 0.718369 0.291091 0.297773 0.046 Uiso 1 1 calc R . . . .
C6 C 0.56798(18) 0.22265(17) 0.35063(7) 0.0264(3) Uani 1 1 d . . . . .
C7 C 0.5081(2) -0.12951(17) 0.37562(8) 0.0342(4) Uani 1 1 d . . . . .
C8 C 0.4600(3) -0.2252(2) 0.39504(10) 0.0485(5) Uani 1 1 d . . . . .
H8 H 0.421584 -0.301687 0.410581 0.058 Uiso 1 1 calc R . . . .
C9 C 0.5169(2) 0.35461(16) 0.36878(7) 0.0289(4) Uani 1 1 d . . . . .
H9 H 0.437134 0.341950 0.395598 0.035 Uiso 1 1 calc R . . . .
C10 C 0.6368(2) 0.42800(19) 0.39784(9) 0.0388(4) Uani 1 1 d . . . . .
H10A H 0.671154 0.377292 0.429058 0.058 Uiso 1 1 calc GR . . . .
H10B H 0.600223 0.511065 0.410883 0.058 Uiso 1 1 calc GR . . . .
H10C H 0.715875 0.442699 0.372196 0.058 Uiso 1 1 calc GR . . . .
C11 C 0.4580(3) 0.4308(2) 0.32030(9) 0.0443(5) Uani 1 1 d . . . . .
H11A H 0.534347 0.444694 0.293403 0.066 Uiso 1 1 calc GR . . . .
H11B H 0.422120 0.514344 0.333138 0.066 Uiso 1 1 calc GR . . . .
H11C H 0.379653 0.382475 0.303235 0.066 Uiso 1 1 calc GR . . . .
C12 C 0.27356(17) 0.04253(15) 0.40397(6) 0.0229(3) Uani 1 1 d . . . . .
C13 C 0.21914(17) 0.02858(16) 0.34612(7) 0.0238(3) Uani 1 1 d . . . . .
C14 C 0.13759(19) -0.07894(17) 0.33251(7) 0.0293(4) Uani 1 1 d . . . . .
H14 H 0.123859 -0.146923 0.358052 0.035 Uiso 1 1 calc R . . . .
C15 C 0.07700(19) -0.08442(17) 0.28087(7) 0.0304(4) Uani 1 1 d . . . . .
H15 H 0.021982 -0.157032 0.269947 0.037 Uiso 1 1 calc R . . . .
C16 C 0.09819(17) 0.01845(17) 0.24525(7) 0.0280(4) Uani 1 1 d . . . . .
C17 C 0.18287(19) 0.12073(18) 0.26262(7) 0.0316(4) Uani 1 1 d . . . . .
H17 H 0.198596 0.190033 0.237901 0.038 Uiso 1 1 calc R . . . .
C18 C 0.03097(19) 0.02705(19) 0.18992(7) 0.0322(4) Uani 1 1 d . . . . .
C19 C -0.1004(3) -0.0837(3) 0.12192(8) 0.0511(6) Uani 1 1 d . . . . .
H19A H -0.026258 -0.079188 0.093572 0.077 Uiso 1 1 calc GR . . . .
H19B H -0.164423 -0.009252 0.118493 0.077 Uiso 1 1 calc GR . . . .
H19C H -0.155651 -0.163310 0.117444 0.077 Uiso 1 1 calc GR . . . .
C20 C 0.44254(16) 0.13283(15) 0.46792(6) 0.0221(3) Uani 1 1 d . . . . .
H20A H 0.547260 0.147442 0.469091 0.027 Uiso 1 1 calc R . . . .
H20B H 0.421174 0.055965 0.490533 0.027 Uiso 1 1 calc R . . . .
C21 C 0.36663(16) 0.24931(15) 0.49232(6) 0.0201(3) Uani 1 1 d . . . . .
C22 C 0.38298(18) 0.42231(17) 0.55873(7) 0.0300(4) Uani 1 1 d . . . . .
H22A H 0.443678 0.439714 0.591156 0.036 Uiso 1 1 calc R . . . .
H22B H 0.287405 0.395557 0.572099 0.036 Uiso 1 1 calc R . . . .
C23 C 0.3676(2) 0.54304(19) 0.52672(10) 0.0433(5) Uani 1 1 d D U . . .
O6 O 0.3444(4) 0.6397(2) 0.56324(12) 0.0482(8) Uani 0.778(10) 1 d D U P A 1
C24 C 0.3227(6) 0.7647(3) 0.5387(2) 0.0687(14) Uani 0.778(10) 1 d D U P A 1
H24A H 0.303146 0.828212 0.567492 0.103 Uiso 0.778(10) 1 calc GR . P A 1
H24B H 0.241262 0.760856 0.513467 0.103 Uiso 0.778(10) 1 calc GR . P A 1
H24C H 0.409018 0.789993 0.518563 0.103 Uiso 0.778(10) 1 calc GR . P A 1
O6A O 0.268(2) 0.6306(11) 0.5409(7) 0.078(5) Uani 0.222(10) 1 d D U P A 2
C24A C 0.231(3) 0.7455(19) 0.5081(10) 0.113(9) Uani 0.222(10) 1 d D U P A 2
H24D H 0.164851 0.721141 0.478801 0.170 Uiso 0.222(10) 1 calc GR . P A 2
H24E H 0.318633 0.781592 0.492104 0.170 Uiso 0.222(10) 1 calc GR . P A 2
H24F H 0.185888 0.810102 0.531759 0.170 Uiso 0.222(10) 1 calc GR . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C12 1.223(2) . ?
O2 C18 1.199(2) . ?
O3 C18 1.332(2) . ?
O3 C19 1.456(2) . ?
O4 C21 1.227(2) . ?
O5 C23 1.209(3) . ?
N1 C1 1.441(2) . ?
N1 C12 1.367(2) . ?
N1 C20 1.4620(19) . ?
N2 C13 1.336(2) . ?
N2 C17 1.335(2) . ?
N3 H3 0.8800 . ?
N3 C21 1.339(2) . ?
N3 C22 1.445(2) . ?
C1 C2 1.409(2) . ?
C1 C6 1.394(2) . ?
C2 C3 1.397(3) . ?
C2 C7 1.432(3) . ?
C3 H3A 0.9500 . ?
C3 C4 1.377(3) . ?
C4 H4 0.9500 . ?
C4 C5 1.379(3) . ?
C5 H5 0.9500 . ?
C5 C6 1.397(2) . ?
C6 C9 1.516(2) . ?
C7 C8 1.188(3) . ?
C8 H8 0.9500 . ?
C9 H9 1.0000 . ?
C9 C10 1.529(3) . ?
C9 C11 1.526(3) . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 C13 1.508(2) . ?
C13 C14 1.391(2) . ?
C14 H14 0.9500 . ?
C14 C15 1.383(2) . ?
C15 H15 0.9500 . ?
C15 C16 1.391(3) . ?
C16 C17 1.390(3) . ?
C16 C18 1.492(2) . ?
C17 H17 0.9500 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C20 C21 1.522(2) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C22 C23 1.483(3) . ?
C23 O6 1.359(3) . ?
C23 O6A 1.348(9) . ?
O6 C24 1.443(4) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
O6A C24A 1.474(14) . ?
C24A H24D 0.9800 . ?
C24A H24E 0.9800 . ?
C24A H24F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C18 O3 C19 115.76(17) . . ?
C1 N1 C20 117.19(12) . . ?
C12 N1 C1 121.81(12) . . ?
C12 N1 C20 116.73(13) . . ?
C17 N2 C13 116.93(15) . . ?
C21 N3 H3 119.5 . . ?
C21 N3 C22 120.95(13) . . ?
C22 N3 H3 119.5 . . ?
C2 C1 N1 117.68(15) . . ?
C6 C1 N1 121.18(14) . . ?
C6 C1 C2 121.04(14) . . ?
C1 C2 C7 120.32(15) . . ?
C3 C2 C1 119.37(17) . . ?
C3 C2 C7 120.30(16) . . ?
C2 C3 H3A 120.1 . . ?
C4 C3 C2 119.72(17) . . ?
C4 C3 H3A 120.1 . . ?
C3 C4 H4 119.8 . . ?
C3 C4 C5 120.39(17) . . ?
C5 C4 H4 119.8 . . ?
C4 C5 H5 119.0 . . ?
C4 C5 C6 121.91(19) . . ?
C6 C5 H5 119.0 . . ?
C1 C6 C5 117.53(16) . . ?
C1 C6 C9 123.35(14) . . ?
C5 C6 C9 119.12(16) . . ?
C8 C7 C2 178.7(2) . . ?
C7 C8 H8 180.0 . . ?
C6 C9 H9 107.9 . . ?
C6 C9 C10 110.77(15) . . ?
C6 C9 C11 110.78(15) . . ?
C10 C9 H9 107.9 . . ?
C11 C9 H9 107.9 . . ?
C11 C9 C10 111.45(16) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
O1 C12 N1 122.84(14) . . ?
O1 C12 C13 119.59(14) . . ?
N1 C12 C13 117.42(13) . . ?
N2 C13 C12 116.85(14) . . ?
N2 C13 C14 123.89(15) . . ?
C14 C13 C12 119.03(15) . . ?
C13 C14 H14 120.8 . . ?
C15 C14 C13 118.34(16) . . ?
C15 C14 H14 120.8 . . ?
C14 C15 H15 120.7 . . ?
C14 C15 C16 118.70(16) . . ?
C16 C15 H15 120.7 . . ?
C15 C16 C18 123.50(16) . . ?
C17 C16 C15 118.42(15) . . ?
C17 C16 C18 118.04(16) . . ?
N2 C17 C16 123.69(17) . . ?
N2 C17 H17 118.2 . . ?
C16 C17 H17 118.2 . . ?
O2 C18 O3 124.53(17) . . ?
O2 C18 C16 123.53(17) . . ?
O3 C18 C16 111.94(16) . . ?
O3 C19 H19A 109.5 . . ?
O3 C19 H19B 109.5 . . ?
O3 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
N1 C20 H20A 109.1 . . ?
N1 C20 H20B 109.1 . . ?
N1 C20 C21 112.50(12) . . ?
H20A C20 H20B 107.8 . . ?
C21 C20 H20A 109.1 . . ?
C21 C20 H20B 109.1 . . ?
O4 C21 N3 122.82(15) . . ?
O4 C21 C20 122.40(14) . . ?
N3 C21 C20 114.65(13) . . ?
N3 C22 H22A 108.8 . . ?
N3 C22 H22B 108.8 . . ?
N3 C22 C23 113.65(15) . . ?
H22A C22 H22B 107.7 . . ?
C23 C22 H22A 108.8 . . ?
C23 C22 H22B 108.8 . . ?
O5 C23 C22 126.02(18) . . ?
O5 C23 O6 126.9(2) . . ?
O5 C23 O6A 105.2(7) . . ?
O6 C23 C22 107.0(2) . . ?
O6A C23 C22 120.1(4) . . ?
C23 O6 C24 114.4(2) . . ?
O6 C24 H24A 109.5 . . ?
O6 C24 H24B 109.5 . . ?
O6 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C23 O6A C24A 124.4(9) . . ?
O6A C24A H24D 109.5 . . ?
O6A C24A H24E 109.5 . . ?
O6A C24A H24F 109.5 . . ?
H24D C24A H24E 109.5 . . ?
H24D C24A H24F 109.5 . . ?
H24E C24A H24F 109.5 . . ?

_olex2_submission_special_instructions 'No special instructions were received'
