# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Co-MOF
_database_code_depnum_ccdc_archive 'CCDC 2072472'
loop_
_audit_author_name
_audit_author_address
Co-MOF
;Qingdao University
China
;
_audit_update_record             
;
2021-09-01 deposited with the CCDC.	2021-09-14 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C19 H15 Co N5 O5'
_chemical_formula_weight         452.29

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.4357(9)
_cell_length_b                   9.7799(8)
_cell_length_c                   12.6121(13)
_cell_angle_alpha                68.832(9)
_cell_angle_beta                 89.761(9)
_cell_angle_gamma                77.900(8)
_cell_volume                     945.81(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    5767
_cell_measurement_theta_min      3.0040
_cell_measurement_theta_max      32.3550

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.588
_exptl_crystal_F_000             462
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_absorpt_coefficient_mu    0.951
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.77238
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'XtaLAB Mini (ROW)'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            10653
_diffrn_reflns_av_unetI/netI     0.0844
_diffrn_reflns_av_R_equivalents  0.0995
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         2.912
_diffrn_reflns_theta_max         25.199
_diffrn_reflns_theta_full        25.199
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             3396
_reflns_number_gt                2593
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrysAlisPro 1.171.39.16b (Rigaku OD, 2015)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.16b (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.39.16b (Rigaku OD, 2015)'
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0451P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         3396
_refine_ls_number_parameters     279
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0687
_refine_ls_R_factor_gt           0.0410
_refine_ls_wR_factor_ref         0.0947
_refine_ls_wR_factor_gt          0.0884
_refine_ls_goodness_of_fit_ref   0.973
_refine_ls_restrained_S_all      0.973
_refine_ls_shift/su_max          0.014
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3155(4) 0.6455(3) 0.1339(3) 0.0322(8) Uani 1 1 d . . . . .
H1 H 0.2829 0.6140 0.0778 0.039 Uiso 1 1 calc R U . . .
C2 C 0.4436(4) 0.6543(3) 0.2762(3) 0.0338(8) Uani 1 1 d . . . . .
H2 H 0.5185 0.6276 0.3382 0.041 Uiso 1 1 calc R U . . .
C3 C 0.3264(4) 0.7811(4) 0.2375(3) 0.0378(8) Uani 1 1 d . . . . .
H3 H 0.3055 0.8573 0.2667 0.045 Uiso 1 1 calc R U . . .
C4 C 0.1154(4) 0.8892(4) 0.0718(3) 0.0352(8) Uani 1 1 d . . . . .
C5 C 0.0616(4) 0.8782(4) -0.0271(3) 0.0459(10) Uani 1 1 d . . . . .
C6 C 0.0555(4) 1.0091(4) 0.0994(3) 0.0459(8) Uani 0.5 1 d . . P . .
H6 H 0.0932 1.0150 0.1664 0.055 Uiso 0.5 1 calc R U P . .
N6 N 0.0555(4) 1.0091(4) 0.0994(3) 0.0459(8) Uani 0.5 1 d . . P . .
C7 C 0.3128(4) 0.2081(3) 0.3586(3) 0.0304(7) Uani 1 1 d . . . . .
H7 H 0.2591 0.2246 0.2894 0.036 Uiso 1 1 calc R U . . .
C8 C 0.3723(4) 0.1349(4) 0.5424(3) 0.0369(8) Uani 1 1 d . . . . .
H8 H 0.3701 0.0936 0.6213 0.044 Uiso 1 1 calc R U . . .
C9 C 0.4837(4) 0.2069(4) 0.4840(3) 0.0337(7) Uani 1 1 d . . . . .
H9 H 0.5730 0.2233 0.5167 0.040 Uiso 1 1 calc R U . . .
C10 C 0.1277(4) 0.0661(3) 0.4816(3) 0.0304(7) Uani 1 1 d . . . . .
C11 C 0.0636(5) 0.0287(4) 0.5866(3) 0.0454(9) Uani 1 1 d . . . . .
C12 C 0.0662(4) 0.0371(4) 0.3962(3) 0.0468(9) Uani 0.5 1 d . . P . .
H12 H 0.1115 0.0616 0.3263 0.056 Uiso 0.5 1 calc R U P . .
N12 N 0.0662(4) 0.0371(4) 0.3962(3) 0.0468(9) Uani 0.5 1 d . . P . .
C13 C 0.5324(4) 0.1876(3) 0.1288(2) 0.0257(7) Uani 1 1 d . . . . .
C14 C 0.5131(4) 0.0901(3) 0.0625(2) 0.0251(7) Uani 1 1 d . . . . .
C15 C 0.6212(4) -0.0480(3) 0.0882(3) 0.0298(7) Uani 1 1 d . . . . .
H15 H 0.7022 -0.0809 0.1472 0.036 Uiso 1 1 calc R U . . .
C16 C 0.3920(4) 0.1372(3) -0.0251(3) 0.0292(7) Uani 1 1 d . . . . .
H16 H 0.3188 0.2292 -0.0420 0.035 Uiso 1 1 calc R U . . .
C17 C 0.8649(4) 0.4320(4) 0.3176(3) 0.0333(8) Uani 1 1 d . . . . .
C18 C 0.9357(4) 0.4667(3) 0.4124(2) 0.0285(7) Uani 1 1 d . . . . .
C19 C 0.8678(4) 0.4361(4) 0.5166(3) 0.0390(9) Uani 1 1 d . . . . .
H19 H 0.7785 0.3921 0.5288 0.047 Uiso 1 1 calc R U . . .
C20 C 1.0688(4) 0.5298(4) 0.3972(3) 0.0430(9) Uani 1 1 d . . . . .
H20 H 1.1170 0.5498 0.3284 0.052 Uiso 1 1 calc R U . . .
Co1 Co 0.57790(5) 0.35758(4) 0.23050(3) 0.02180(14) Uani 1 1 d . . . . .
N1 N 0.4357(3) 0.5700(3) 0.2100(2) 0.0276(6) Uani 1 1 d . . . . .
N2 N 0.2433(3) 0.7756(3) 0.1458(2) 0.0300(6) Uani 1 1 d . . . . .
N3 N 0.4456(3) 0.2525(3) 0.3682(2) 0.0266(6) Uani 1 1 d . . . . .
N4 N 0.2627(3) 0.1350(3) 0.4622(2) 0.0285(6) Uani 1 1 d . . . . .
O1 O 0.6468(3) 0.1442(2) 0.20468(17) 0.0299(5) Uani 1 1 d . . . . .
O2 O 0.4324(3) 0.3130(2) 0.10644(17) 0.0300(5) Uani 1 1 d . . . . .
O3 O 0.7471(2) 0.3684(2) 0.33987(17) 0.0309(5) Uani 1 1 d . . . . .
O4 O 0.9267(3) 0.4693(4) 0.2249(2) 0.0734(10) Uani 1 1 d . . . . .
O5 O 0.7161(3) 0.4456(2) 0.08756(16) 0.0302(5) Uani 1 1 d . . . . .
H5C H 0.8076 0.4483 0.1138 0.036 Uiso 1 1 d R U . . .
H5B H 0.6744 0.5325 0.0389 0.036 Uiso 1 1 d R U . . .
H5 H 0.104(5) 0.809(5) -0.053(3) 0.078(14) Uiso 1 1 d . . . . .
H11 H 0.125(5) 0.047(4) 0.651(3) 0.078(13) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.295(4) . ?
C1 N2 1.351(3) . ?
C1 H1 0.9300 . ?
C2 C3 1.344(4) . ?
C2 N1 1.380(3) . ?
C2 H2 0.9300 . ?
C3 N2 1.378(4) . ?
C3 H3 0.9300 . ?
C4 C6 1.341(4) . ?
C4 C5 1.376(5) . ?
C4 N2 1.423(4) . ?
C5 N6 1.359(5) 2_575 ?
C5 C6 1.359(5) 2_575 ?
C5 H5 0.86(4) . ?
C6 C5 1.359(5) 2_575 ?
C6 H6 0.9300 . ?
C7 N3 1.304(4) . ?
C7 N4 1.358(4) . ?
C7 H7 0.9300 . ?
C8 C9 1.349(4) . ?
C8 N4 1.374(4) . ?
C8 H8 0.9300 . ?
C9 N3 1.380(4) . ?
C9 H9 0.9300 . ?
C10 C12 1.339(4) . ?
C10 C11 1.382(4) . ?
C10 N4 1.418(4) . ?
C11 N12 1.361(4) 2_556 ?
C11 C12 1.361(4) 2_556 ?
C11 H11 1.06(4) . ?
C12 C11 1.361(4) 2_556 ?
C12 H12 0.9300 . ?
C13 O1 1.253(4) . ?
C13 O2 1.270(3) . ?
C13 C14 1.509(4) . ?
C14 C16 1.386(4) . ?
C14 C15 1.389(4) . ?
C15 C16 1.397(4) 2_655 ?
C15 H15 0.9300 . ?
C16 C15 1.397(4) 2_655 ?
C16 H16 0.9300 . ?
C17 O4 1.240(4) . ?
C17 O3 1.259(4) . ?
C17 C18 1.512(4) . ?
C18 C20 1.371(4) . ?
C18 C19 1.388(4) . ?
C19 C20 1.386(4) 2_766 ?
C19 H19 0.9300 . ?
C20 C19 1.386(4) 2_766 ?
C20 H20 0.9300 . ?
Co1 O3 2.034(2) . ?
Co1 N1 2.095(2) . ?
Co1 N3 2.120(2) . ?
Co1 O5 2.1526(19) . ?
Co1 O1 2.1865(18) . ?
Co1 O2 2.209(2) . ?
O5 H5C 0.8499 . ?
O5 H5B 0.8500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 N2 111.8(3) . . ?
N1 C1 H1 124.1 . . ?
N2 C1 H1 124.1 . . ?
C3 C2 N1 109.5(3) . . ?
C3 C2 H2 125.2 . . ?
N1 C2 H2 125.2 . . ?
C2 C3 N2 106.3(2) . . ?
C2 C3 H3 126.9 . . ?
N2 C3 H3 126.9 . . ?
C6 C4 C5 121.7(3) . . ?
C6 C4 N2 117.6(3) . . ?
C5 C4 N2 120.6(3) . . ?
N6 C5 C6 0.0 2_575 2_575 ?
N6 C5 C4 119.9(3) 2_575 . ?
C6 C5 C4 119.9(3) 2_575 . ?
N6 C5 H5 115(3) 2_575 . ?
C6 C5 H5 115(3) 2_575 . ?
C4 C5 H5 125(3) . . ?
C4 C6 C5 118.4(3) . 2_575 ?
C4 C6 H6 120.8 . . ?
C5 C6 H6 120.8 2_575 . ?
N3 C7 N4 111.6(3) . . ?
N3 C7 H7 124.2 . . ?
N4 C7 H7 124.2 . . ?
C9 C8 N4 106.2(3) . . ?
C9 C8 H8 126.9 . . ?
N4 C8 H8 126.9 . . ?
C8 C9 N3 109.9(3) . . ?
C8 C9 H9 125.0 . . ?
N3 C9 H9 125.0 . . ?
C12 C10 C11 121.4(3) . . ?
C12 C10 N4 118.3(3) . . ?
C11 C10 N4 120.3(3) . . ?
N12 C11 C12 0.0 2_556 2_556 ?
N12 C11 C10 119.6(3) 2_556 . ?
C12 C11 C10 119.6(3) 2_556 . ?
N12 C11 H11 124(2) 2_556 . ?
C12 C11 H11 124(2) 2_556 . ?
C10 C11 H11 117(2) . . ?
C10 C12 C11 119.1(3) . 2_556 ?
C10 C12 H12 120.5 . . ?
C11 C12 H12 120.5 2_556 . ?
O1 C13 O2 121.0(2) . . ?
O1 C13 C14 119.7(3) . . ?
O2 C13 C14 119.4(3) . . ?
C16 C14 C15 119.5(2) . . ?
C16 C14 C13 121.2(3) . . ?
C15 C14 C13 119.3(3) . . ?
C14 C15 C16 119.9(3) . 2_655 ?
C14 C15 H15 120.0 . . ?
C16 C15 H15 120.0 2_655 . ?
C14 C16 C15 120.6(3) . 2_655 ?
C14 C16 H16 119.7 . . ?
C15 C16 H16 119.7 2_655 . ?
O4 C17 O3 125.7(3) . . ?
O4 C17 C18 117.5(3) . . ?
O3 C17 C18 116.7(2) . . ?
C20 C18 C19 118.4(3) . . ?
C20 C18 C17 120.6(3) . . ?
C19 C18 C17 121.0(3) . . ?
C18 C19 C20 121.0(3) . 2_766 ?
C18 C19 H19 119.5 . . ?
C20 C19 H19 119.5 2_766 . ?
C18 C20 C19 120.7(3) . 2_766 ?
C18 C20 H20 119.7 . . ?
C19 C20 H20 119.7 2_766 . ?
O3 Co1 N1 93.21(9) . . ?
O3 Co1 N3 91.04(9) . . ?
N1 Co1 N3 91.05(9) . . ?
O3 Co1 O5 91.20(8) . . ?
N1 Co1 O5 93.53(8) . . ?
N3 Co1 O5 174.78(8) . . ?
O3 Co1 O1 109.74(8) . . ?
N1 Co1 O1 157.05(9) . . ?
N3 Co1 O1 88.63(8) . . ?
O5 Co1 O1 86.17(7) . . ?
O3 Co1 O2 168.87(8) . . ?
N1 Co1 O2 97.16(9) . . ?
N3 Co1 O2 92.80(9) . . ?
O5 Co1 O2 84.14(7) . . ?
O1 Co1 O2 59.95(7) . . ?
C1 N1 C2 106.0(2) . . ?
C1 N1 Co1 125.83(19) . . ?
C2 N1 Co1 128.1(2) . . ?
C1 N2 C3 106.4(3) . . ?
C1 N2 C4 126.1(3) . . ?
C3 N2 C4 127.3(2) . . ?
C7 N3 C9 105.6(2) . . ?
C7 N3 Co1 125.2(2) . . ?
C9 N3 Co1 129.1(2) . . ?
C7 N4 C8 106.6(2) . . ?
C7 N4 C10 125.8(3) . . ?
C8 N4 C10 127.5(3) . . ?
C13 O1 Co1 90.18(16) . . ?
C13 O2 Co1 88.75(17) . . ?
C17 O3 Co1 128.9(2) . . ?
Co1 O5 H5C 107.6 . . ?
Co1 O5 H5B 116.9 . . ?
H5C O5 H5B 108.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C2 C3 N2 0.3(4) . . . . ?
C6 C4 C5 N6 -0.1(6) . . . 2_575 ?
N2 C4 C5 N6 -177.0(3) . . . 2_575 ?
C6 C4 C5 C6 -0.1(6) . . . 2_575 ?
N2 C4 C5 C6 -177.0(3) . . . 2_575 ?
C5 C4 C6 C5 0.1(6) . . . 2_575 ?
N2 C4 C6 C5 177.1(3) . . . 2_575 ?
N4 C8 C9 N3 0.2(3) . . . . ?
C12 C10 C11 N12 -0.9(6) . . . 2_556 ?
N4 C10 C11 N12 179.9(3) . . . 2_556 ?
C12 C10 C11 C12 -0.9(6) . . . 2_556 ?
N4 C10 C11 C12 179.9(3) . . . 2_556 ?
C11 C10 C12 C11 0.9(6) . . . 2_556 ?
N4 C10 C12 C11 -179.9(3) . . . 2_556 ?
O1 C13 C14 C16 -177.3(3) . . . . ?
O2 C13 C14 C16 2.4(4) . . . . ?
O1 C13 C14 C15 1.1(4) . . . . ?
O2 C13 C14 C15 -179.1(3) . . . . ?
C16 C14 C15 C16 0.6(5) . . . 2_655 ?
C13 C14 C15 C16 -177.9(2) . . . 2_655 ?
C15 C14 C16 C15 -0.6(5) . . . 2_655 ?
C13 C14 C16 C15 177.9(3) . . . 2_655 ?
O4 C17 C18 C20 -3.5(5) . . . . ?
O3 C17 C18 C20 177.1(3) . . . . ?
O4 C17 C18 C19 176.4(3) . . . . ?
O3 C17 C18 C19 -3.0(5) . . . . ?
C20 C18 C19 C20 0.9(6) . . . 2_766 ?
C17 C18 C19 C20 -179.0(3) . . . 2_766 ?
C19 C18 C20 C19 -0.9(6) . . . 2_766 ?
C17 C18 C20 C19 179.0(3) . . . 2_766 ?
N2 C1 N1 C2 0.1(3) . . . . ?
N2 C1 N1 Co1 177.18(18) . . . . ?
C3 C2 N1 C1 -0.2(4) . . . . ?
C3 C2 N1 Co1 -177.2(2) . . . . ?
N1 C1 N2 C3 0.1(3) . . . . ?
N1 C1 N2 C4 175.4(3) . . . . ?
C2 C3 N2 C1 -0.2(3) . . . . ?
C2 C3 N2 C4 -175.4(3) . . . . ?
C6 C4 N2 C1 178.0(3) . . . . ?
C5 C4 N2 C1 -4.9(5) . . . . ?
C6 C4 N2 C3 -7.6(5) . . . . ?
C5 C4 N2 C3 169.4(3) . . . . ?
N4 C7 N3 C9 -0.4(3) . . . . ?
N4 C7 N3 Co1 175.50(18) . . . . ?
C8 C9 N3 C7 0.1(3) . . . . ?
C8 C9 N3 Co1 -175.5(2) . . . . ?
N3 C7 N4 C8 0.5(3) . . . . ?
N3 C7 N4 C10 -176.5(2) . . . . ?
C9 C8 N4 C7 -0.4(3) . . . . ?
C9 C8 N4 C10 176.6(3) . . . . ?
C12 C10 N4 C7 17.1(4) . . . . ?
C11 C10 N4 C7 -163.7(3) . . . . ?
C12 C10 N4 C8 -159.3(3) . . . . ?
C11 C10 N4 C8 19.9(5) . . . . ?
O2 C13 O1 Co1 -4.1(3) . . . . ?
C14 C13 O1 Co1 175.6(2) . . . . ?
O1 C13 O2 Co1 4.0(3) . . . . ?
C14 C13 O2 Co1 -175.7(2) . . . . ?
O4 C17 O3 Co1 -19.3(5) . . . . ?
C18 C17 O3 Co1 160.1(2) . . . . ?

_refine_diff_density_max         0.593
_refine_diff_density_min         -0.320
_refine_diff_density_rms         0.069

