# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_z
_database_code_depnum_ccdc_archive 'CCDC 2055674'
loop_
_audit_author_name
_audit_author_address
'Liang-Jin Xu'
;Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2021-01-13 deposited with the CCDC.	2021-03-26 downloaded from the CCDC.
;
_audit_creation_date             2020-12-23
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C92 H92 Ag2 O4 P6 Pt, 2(Cl O4), 4(C H2 Cl2)'
_chemical_formula_sum            'C96 H100 Ag2 Cl10 O12 P6 Pt'
_chemical_formula_weight         2396.90
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.9220(9)
_cell_length_b                   15.4161(10)
_cell_length_c                   15.5171(11)
_cell_angle_alpha                114.362(2)
_cell_angle_beta                 92.751(3)
_cell_angle_gamma                113.221(2)
_cell_volume                     2504.5(3)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    9854
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.44
_cell_measurement_theta_min      2.52
_shelx_estimated_absorpt_T_max   0.810
_shelx_estimated_absorpt_T_min   0.667
_exptl_absorpt_coefficient_mu    2.201
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.5001
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1273 before and 0.0703 after correction.
The Ratio of minimum to maximum transmission is 0.6711.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic yellowish yellow'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   yellowish
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.589
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1204
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0432
_diffrn_reflns_av_unetI/netI     0.0521
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.982
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            24605
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.494
_diffrn_reflns_theta_min         2.638
_diffrn_ambient_temperature      100.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8069
_reflns_number_total             9151
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         3.142
_refine_diff_density_min         -2.774
_refine_diff_density_rms         0.180
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     580
_refine_ls_number_reflns         9151
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0623
_refine_ls_R_factor_gt           0.0527
_refine_ls_restrained_S_all      1.051
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0784P)²+12.2150P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1366
_refine_ls_wR_factor_ref         0.1486
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C45(H45A,H45B), C46(H46A,H46B), C47(H47A,H47B), C48(H48A,H48B)
2.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C10(H10), C11(H11), C12(H12), C13(H13),
 C15(H15), C16(H16), C17(H17), C18(H18), C19(H19), C23(H23), C24(H24), C25(H25),
  C26(H26), C30(H30), C31(H31), C32(H32), C33(H33), C38(H38), C40(H40), C41(H41)
2.c Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C8(H8A,H8B,H8C), C21(H21A,H21B,H21C), C28(H28A,H28B,H28C),
 C35(H35A,H35B,H35C), C36(H36A,H36B,H36C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.500000 0.000000 0.500000 0.02049(11) Uani 1 2 d S . P . .
Ag1 Ag 0.59981(4) 0.00192(3) 0.67189(3) 0.02986(14) Uani 1 1 d . . . . .
P1 P 0.76085(13) 0.17815(12) 0.73019(11) 0.0222(3) Uani 1 1 d . . . . .
P2 P 0.65190(13) 0.16741(11) 0.54422(11) 0.0200(3) Uani 1 1 d . . . . .
P3 P 0.50971(13) 0.19091(12) 0.39828(11) 0.0239(3) Uani 1 1 d . . . . .
O1 O 0.5017(5) 0.3495(4) 0.7483(4) 0.0482(13) Uani 1 1 d . . . . .
O2 O 0.2780(6) 0.3779(5) 0.9833(5) 0.0601(16) Uani 1 1 d . . . . .
C1 C 0.3679(7) 0.1804(6) 0.2237(5) 0.0446(18) Uani 1 1 d . . . . .
H1A H 0.442089 0.219321 0.212271 0.067 Uiso 1 1 calc R U . . .
H1B H 0.303532 0.163707 0.173941 0.067 Uiso 1 1 calc R U . . .
H1C H 0.363198 0.113781 0.219825 0.067 Uiso 1 1 calc R U . . .
C2 C 0.3602(6) 0.2483(5) 0.3233(5) 0.0349(15) Uani 1 1 d . . . . .
C3 C 0.2951(6) 0.3041(6) 0.3342(6) 0.0419(17) Uani 1 1 d . . . . .
H3 H 0.255297 0.298250 0.277528 0.050 Uiso 1 1 calc R U . . .
C4 C 0.2864(7) 0.3678(6) 0.4250(6) 0.0475(19) Uani 1 1 d . . . . .
H4 H 0.240635 0.404241 0.430063 0.057 Uiso 1 1 calc R U . . .
C5 C 0.3448(8) 0.3775(7) 0.5074(6) 0.052(2) Uani 1 1 d . . . . .
H5 H 0.340263 0.421842 0.569982 0.062 Uiso 1 1 calc R U . . .
C6 C 0.4098(7) 0.3234(6) 0.4999(5) 0.0401(16) Uani 1 1 d . . . . .
H6 H 0.447853 0.329059 0.557300 0.048 Uiso 1 1 calc R U . . .
C7 C 0.4204(5) 0.2603(5) 0.4089(5) 0.0284(13) Uani 1 1 d . . . . .
C8 C 0.6132(7) 0.0809(6) 0.2265(6) 0.0445(18) Uani 1 1 d . . . . .
H8A H 0.621587 0.057729 0.275300 0.067 Uiso 1 1 calc R U . . .
H8B H 0.655184 0.058409 0.177569 0.067 Uiso 1 1 calc R U . . .
H8C H 0.530647 0.048600 0.194337 0.067 Uiso 1 1 calc R U . . .
C9 C 0.6617(6) 0.1980(6) 0.2747(5) 0.0385(16) Uani 1 1 d . . . . .
C10 C 0.7549(7) 0.2589(7) 0.2456(6) 0.0447(18) Uani 1 1 d . . . . .
H10 H 0.783332 0.222260 0.194611 0.054 Uiso 1 1 calc R U . . .
C11 C 0.8036(7) 0.3663(7) 0.2880(6) 0.048(2) Uani 1 1 d . . . . .
H11 H 0.865325 0.403926 0.266592 0.058 Uiso 1 1 calc R U . . .
C12 C 0.7644(7) 0.4226(7) 0.3627(6) 0.0445(18) Uani 1 1 d . . . . .
H12 H 0.799300 0.498461 0.392631 0.053 Uiso 1 1 calc R U . . .
C13 C 0.6757(6) 0.3683(6) 0.3927(5) 0.0347(15) Uani 1 1 d . . . . .
H13 H 0.647716 0.406537 0.442947 0.042 Uiso 1 1 calc R U . . .
C14 C 0.6248(5) 0.2556(5) 0.3500(5) 0.0310(14) Uani 1 1 d . . . . .
C15 C 0.8440(6) 0.2920(6) 0.5028(5) 0.0333(14) Uani 1 1 d . . . . .
H15 H 0.822954 0.347427 0.536179 0.040 Uiso 1 1 calc R U . . .
C16 C 0.9407(6) 0.3136(6) 0.4672(6) 0.0417(17) Uani 1 1 d . . . . .
H16 H 0.985684 0.383368 0.474917 0.050 Uiso 1 1 calc R U . . .
C17 C 0.9732(6) 0.2341(7) 0.4198(6) 0.054(2) Uani 1 1 d . . . . .
H17 H 1.040636 0.249096 0.395303 0.064 Uiso 1 1 calc R U . . .
C18 C 0.9072(7) 0.1329(7) 0.4083(7) 0.053(2) Uani 1 1 d . . . . .
H18 H 0.929056 0.078165 0.374750 0.064 Uiso 1 1 calc R U . . .
C19 C 0.8096(6) 0.1096(6) 0.4449(5) 0.0363(15) Uani 1 1 d . . . . .
H19 H 0.766561 0.040260 0.438700 0.044 Uiso 1 1 calc R U . . .
C20 C 0.7753(5) 0.1890(5) 0.4908(4) 0.0268(13) Uani 1 1 d . . . . .
C21 C 0.8362(8) -0.0080(7) 0.6103(7) 0.057(2) Uani 1 1 d . . . . .
H21A H 0.805771 -0.018542 0.663752 0.085 Uiso 1 1 calc R U . . .
H21B H 0.872006 -0.055233 0.581840 0.085 Uiso 1 1 calc R U . . .
H21C H 0.772350 -0.024735 0.560007 0.085 Uiso 1 1 calc R U . . .
C22 C 0.9232(7) 0.1031(6) 0.6481(6) 0.0463(18) Uani 1 1 d . . . . .
C23 C 1.0355(7) 0.1261(8) 0.6341(7) 0.056(2) Uani 1 1 d . . . . .
H23 H 1.053389 0.068655 0.600514 0.067 Uiso 1 1 calc R U . . .
C24 C 1.1198(8) 0.2285(7) 0.6671(7) 0.057(2) Uani 1 1 d . . . . .
H24 H 1.194613 0.240526 0.655613 0.068 Uiso 1 1 calc R U . . .
C25 C 1.0989(7) 0.3143(7) 0.7165(7) 0.055(2) Uani 1 1 d . . . . .
H25 H 1.158466 0.384897 0.738407 0.066 Uiso 1 1 calc R U . . .
C26 C 0.9916(6) 0.2978(7) 0.7342(6) 0.0437(17) Uani 1 1 d . . . . .
H26 H 0.976771 0.356928 0.769079 0.052 Uiso 1 1 calc R U . . .
C27 C 0.9012(6) 0.1898(6) 0.6997(5) 0.0379(16) Uani 1 1 d . . . . .
C28 C 0.8585(8) 0.1449(7) 0.8940(6) 0.053(2) Uani 1 1 d . . . . .
H28A H 0.882852 0.138406 0.950876 0.080 Uiso 1 1 calc R U . . .
H28B H 0.916535 0.146122 0.855480 0.080 Uiso 1 1 calc R U . . .
H28C H 0.783105 0.083810 0.853504 0.080 Uiso 1 1 calc R U . . .
C29 C 0.8478(6) 0.2470(6) 0.9278(5) 0.0351(15) Uani 1 1 d . . . . .
C30 C 0.8799(7) 0.3183(6) 1.0264(5) 0.0418(17) Uani 1 1 d . . . . .
H30 H 0.908374 0.301719 1.072081 0.050 Uiso 1 1 calc R U . . .
C31 C 0.8720(7) 0.4123(6) 1.0602(5) 0.0423(17) Uani 1 1 d . . . . .
H31 H 0.895928 0.460280 1.128257 0.051 Uiso 1 1 calc R U . . .
C32 C 0.8292(7) 0.4371(6) 0.9948(5) 0.0456(18) Uani 1 1 d . . . . .
H32 H 0.822386 0.501612 1.017789 0.055 Uiso 1 1 calc R U . . .
C33 C 0.7961(6) 0.3667(5) 0.8948(5) 0.0363(15) Uani 1 1 d . . . . .
H33 H 0.766615 0.383474 0.849702 0.044 Uiso 1 1 calc R U . . .
C34 C 0.8058(6) 0.2720(5) 0.8605(4) 0.0282(13) Uani 1 1 d . . . . .
C35 C 0.5308(10) 0.4595(7) 0.7734(8) 0.069(3) Uani 1 1 d . . . . .
H35A H 0.459228 0.466730 0.767052 0.103 Uiso 1 1 calc R U . . .
H35B H 0.574841 0.479464 0.729306 0.103 Uiso 1 1 calc R U . . .
H35C H 0.578183 0.506594 0.840997 0.103 Uiso 1 1 calc R U . . .
C36 C 0.1969(10) 0.3303(8) 1.0291(8) 0.076(3) Uani 1 1 d . . . . .
H36A H 0.119973 0.283782 0.982999 0.114 Uiso 1 1 calc R U . . .
H36B H 0.192416 0.386496 1.086831 0.114 Uiso 1 1 calc R U . . .
H36C H 0.222566 0.287864 1.049001 0.114 Uiso 1 1 calc R U . . .
C37 C 0.4252(6) 0.3063(5) 0.7943(5) 0.0365(15) Uani 1 1 d . . . . .
C38 C 0.3876(7) 0.3635(6) 0.8681(6) 0.0423(17) Uani 1 1 d . . . . .
H38 H 0.416015 0.438096 0.890842 0.051 Uiso 1 1 calc R U . . .
C39 C 0.3079(7) 0.3124(6) 0.9099(6) 0.0433(17) Uani 1 1 d . . . . .
C40 C 0.2647(7) 0.2037(6) 0.8758(6) 0.0417(17) Uani 1 1 d . . . . .
H40 H 0.208848 0.168166 0.902792 0.050 Uiso 1 1 calc R U . . .
C41 C 0.3039(6) 0.1469(6) 0.8014(5) 0.0378(15) Uani 1 1 d . . . . .
H41 H 0.273681 0.072043 0.778222 0.045 Uiso 1 1 calc R U . . .
C42 C 0.3856(6) 0.1950(5) 0.7595(5) 0.0314(14) Uani 1 1 d . . . . .
C43 C 0.4247(5) 0.1343(5) 0.6830(5) 0.0280(13) Uani 1 1 d . . . . .
C44 C 0.4519(5) 0.0807(5) 0.6161(4) 0.0256(12) Uani 1 1 d . . . . .
C45 C 0.7171(5) 0.2469(5) 0.6758(4) 0.0231(12) Uani 1 1 d . . . . .
H45A H 0.786167 0.313279 0.688559 0.028 Uiso 1 1 calc R U . . .
H45B H 0.660425 0.267637 0.708354 0.028 Uiso 1 1 calc R U . . .
C46 C 0.5849(5) 0.2449(5) 0.5253(4) 0.0245(12) Uani 1 1 d . . . . .
H46A H 0.528603 0.248431 0.566028 0.029 Uiso 1 1 calc R U . . .
H46B H 0.646145 0.318915 0.548105 0.029 Uiso 1 1 calc R U . . .
Cl1 Cl 0.87945(13) 0.55483(13) 0.71919(12) 0.0327(3) Uani 1 1 d . . . . .
Cl01 Cl 0.4425(3) 0.6540(3) 0.8961(3) 0.0947(10) Uani 1 1 d . . . . .
Cl02 Cl 0.4661(4) 0.8684(2) 0.9820(2) 0.1060(12) Uani 1 1 d . . . . .
O4 O 0.9330(5) 0.5042(4) 0.7524(4) 0.0508(14) Uani 1 1 d . . . . .
O5 O 0.9180(6) 0.6609(5) 0.7889(5) 0.0686(19) Uani 1 1 d . . . . .
O3 O 0.9060(7) 0.5495(7) 0.6302(6) 0.081(2) Uani 1 1 d . . . . .
O6 O 0.7578(5) 0.4959(5) 0.6971(6) 0.075(2) Uani 1 1 d . . . . .
C47 C 0.4434(9) 0.7603(9) 1.0015(8) 0.074(3) Uani 1 1 d . . . . .
H47A H 0.368048 0.735460 1.018677 0.088 Uiso 1 1 calc R U . . .
H47B H 0.505660 0.782630 1.057053 0.088 Uiso 1 1 calc R U . . .
Cl03 Cl 0.9734(2) 0.95930(19) 0.8159(2) 0.0711(7) Uani 1 1 d . . . . .
Cl04 Cl 1.1716(3) 0.9845(2) 0.9426(2) 0.0742(7) Uani 1 1 d . . . . .
C48 C 1.0410(16) 0.9024(10) 0.8587(16) 0.167(10) Uani 1 1 d . . . . .
H48A H 0.986927 0.862754 0.887470 0.201 Uiso 1 1 calc R U . . .
H48B H 1.051817 0.849124 0.801614 0.201 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Ag1 2.8901(5) . ?
Pt1 Ag1 2.8901(5) 2_656 ?
Pt1 P2 2.3237(15) . ?
Pt1 P2 2.3237(15) 2_656 ?
Pt1 C44 2.012(6) 2_656 ?
Pt1 C44 2.012(6) . ?
Ag1 P1 2.4214(16) . ?
Ag1 P3 2.4268(16) 2_656 ?
P1 C27 1.855(7) . ?
P1 C34 1.825(6) . ?
P1 C45 1.822(6) . ?
P2 C20 1.810(6) . ?
P2 C45 1.827(6) . ?
P2 C46 1.829(6) . ?
P3 C7 1.831(6) . ?
P3 C14 1.822(7) . ?
P3 C46 1.829(6) . ?
O1 C35 1.451(10) . ?
O1 C37 1.368(9) . ?
O2 C36 1.427(10) . ?
O2 C39 1.367(8) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C1 C2 1.503(11) . ?
C2 C3 1.393(10) . ?
C2 C7 1.409(9) . ?
C3 H3 0.9500 . ?
C3 C4 1.386(11) . ?
C4 H4 0.9500 . ?
C4 C5 1.374(11) . ?
C5 H5 0.9500 . ?
C5 C6 1.377(10) . ?
C6 H6 0.9500 . ?
C6 C7 1.396(10) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C8 C9 1.470(11) . ?
C9 C10 1.430(11) . ?
C9 C14 1.383(10) . ?
C10 H10 0.9500 . ?
C10 C11 1.346(12) . ?
C11 H11 0.9500 . ?
C11 C12 1.388(12) . ?
C12 H12 0.9500 . ?
C12 C13 1.359(10) . ?
C13 H13 0.9500 . ?
C13 C14 1.413(10) . ?
C15 H15 0.9500 . ?
C15 C16 1.368(10) . ?
C15 C20 1.405(9) . ?
C16 H16 0.9500 . ?
C16 C17 1.383(12) . ?
C17 H17 0.9500 . ?
C17 C18 1.378(12) . ?
C18 H18 0.9500 . ?
C18 C19 1.387(10) . ?
C19 H19 0.9500 . ?
C19 C20 1.393(9) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C21 C22 1.460(12) . ?
C22 C23 1.402(11) . ?
C22 C27 1.395(10) . ?
C23 H23 0.9500 . ?
C23 C24 1.366(13) . ?
C24 H24 0.9500 . ?
C24 C25 1.369(12) . ?
C25 H25 0.9500 . ?
C25 C26 1.370(11) . ?
C26 H26 0.9500 . ?
C26 C27 1.447(11) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C28 C29 1.506(10) . ?
C29 C30 1.383(10) . ?
C29 C34 1.406(9) . ?
C30 H30 0.9500 . ?
C30 C31 1.371(11) . ?
C31 H31 0.9500 . ?
C31 C32 1.384(11) . ?
C32 H32 0.9500 . ?
C32 C33 1.397(10) . ?
C33 H33 0.9500 . ?
C33 C34 1.393(9) . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 C38 1.371(10) . ?
C37 C42 1.420(9) . ?
C38 H38 0.9500 . ?
C38 C39 1.396(10) . ?
C39 C40 1.379(10) . ?
C40 H40 0.9500 . ?
C40 C41 1.388(10) . ?
C41 H41 0.9500 . ?
C41 C42 1.390(10) . ?
C42 C43 1.434(9) . ?
C43 C44 1.201(9) . ?
C45 H45A 0.9900 . ?
C45 H45B 0.9900 . ?
C46 H46A 0.9900 . ?
C46 H46B 0.9900 . ?
Cl1 O4 1.440(5) . ?
Cl1 O5 1.393(6) . ?
Cl1 O3 1.416(7) . ?
Cl1 O6 1.407(6) . ?
Cl01 C47 1.771(12) . ?
Cl02 C47 1.730(12) . ?
C47 H47A 0.9900 . ?
C47 H47B 0.9900 . ?
Cl03 C48 1.732(14) . ?
Cl04 C48 1.700(16) . ?
C48 H48A 0.9900 . ?
C48 H48B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag1 Pt1 Ag1 180.0 2_656 . ?
P2 Pt1 Ag1 90.33(4) 2_656 2_656 ?
P2 Pt1 Ag1 89.67(4) 2_656 . ?
P2 Pt1 Ag1 89.67(4) . 2_656 ?
P2 Pt1 Ag1 90.33(4) . . ?
P2 Pt1 P2 180.0 . 2_656 ?
C44 Pt1 Ag1 110.05(17) 2_656 . ?
C44 Pt1 Ag1 69.95(17) 2_656 2_656 ?
C44 Pt1 Ag1 69.95(17) . . ?
C44 Pt1 Ag1 110.05(17) . 2_656 ?
C44 Pt1 P2 84.14(17) . . ?
C44 Pt1 P2 95.86(17) . 2_656 ?
C44 Pt1 P2 95.86(17) 2_656 . ?
C44 Pt1 P2 84.14(17) 2_656 2_656 ?
C44 Pt1 C44 180.0 . 2_656 ?
P1 Ag1 Pt1 93.68(4) . . ?
P1 Ag1 P3 160.86(6) . 2_656 ?
P3 Ag1 Pt1 91.99(4) 2_656 . ?
C27 P1 Ag1 119.0(2) . . ?
C34 P1 Ag1 118.8(2) . . ?
C34 P1 C27 102.8(3) . . ?
C45 P1 Ag1 107.6(2) . . ?
C45 P1 C27 104.1(3) . . ?
C45 P1 C34 102.6(3) . . ?
C20 P2 Pt1 124.0(2) . . ?
C20 P2 C45 104.1(3) . . ?
C20 P2 C46 106.5(3) . . ?
C45 P2 Pt1 113.2(2) . . ?
C45 P2 C46 100.4(3) . . ?
C46 P2 Pt1 106.0(2) . . ?
C7 P3 Ag1 114.6(2) . 2_656 ?
C14 P3 Ag1 122.9(2) . 2_656 ?
C14 P3 C7 102.7(3) . . ?
C14 P3 C46 102.6(3) . . ?
C46 P3 Ag1 108.63(19) . 2_656 ?
C46 P3 C7 103.2(3) . . ?
C37 O1 C35 115.3(6) . . ?
C39 O2 C36 117.4(7) . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
C3 C2 C1 120.7(6) . . ?
C3 C2 C7 117.6(7) . . ?
C7 C2 C1 121.7(6) . . ?
C2 C3 H3 118.8 . . ?
C4 C3 C2 122.3(7) . . ?
C4 C3 H3 118.8 . . ?
C3 C4 H4 120.4 . . ?
C5 C4 C3 119.2(7) . . ?
C5 C4 H4 120.4 . . ?
C4 C5 H5 119.8 . . ?
C4 C5 C6 120.4(8) . . ?
C6 C5 H5 119.8 . . ?
C5 C6 H6 119.6 . . ?
C5 C6 C7 120.7(7) . . ?
C7 C6 H6 119.6 . . ?
C2 C7 P3 119.1(5) . . ?
C6 C7 P3 121.1(5) . . ?
C6 C7 C2 119.8(6) . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C9 C8 H8A 109.5 . . ?
C9 C8 H8B 109.5 . . ?
C9 C8 H8C 109.5 . . ?
C10 C9 C8 119.6(7) . . ?
C14 C9 C8 124.0(7) . . ?
C14 C9 C10 116.4(7) . . ?
C9 C10 H10 118.9 . . ?
C11 C10 C9 122.2(7) . . ?
C11 C10 H10 118.9 . . ?
C10 C11 H11 119.7 . . ?
C10 C11 C12 120.6(7) . . ?
C12 C11 H11 119.7 . . ?
C11 C12 H12 120.3 . . ?
C13 C12 C11 119.4(8) . . ?
C13 C12 H12 120.3 . . ?
C12 C13 H13 119.6 . . ?
C12 C13 C14 120.7(7) . . ?
C14 C13 H13 119.6 . . ?
C9 C14 P3 122.1(5) . . ?
C9 C14 C13 120.7(6) . . ?
C13 C14 P3 117.3(5) . . ?
C16 C15 H15 119.6 . . ?
C16 C15 C20 120.8(7) . . ?
C20 C15 H15 119.6 . . ?
C15 C16 H16 119.9 . . ?
C15 C16 C17 120.1(7) . . ?
C17 C16 H16 119.9 . . ?
C16 C17 H17 120.2 . . ?
C18 C17 C16 119.6(7) . . ?
C18 C17 H17 120.2 . . ?
C17 C18 H18 119.4 . . ?
C17 C18 C19 121.2(8) . . ?
C19 C18 H18 119.4 . . ?
C18 C19 H19 120.4 . . ?
C18 C19 C20 119.3(7) . . ?
C20 C19 H19 120.4 . . ?
C15 C20 P2 118.5(5) . . ?
C19 C20 P2 122.5(5) . . ?
C19 C20 C15 118.9(6) . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C22 C21 H21A 109.5 . . ?
C22 C21 H21B 109.5 . . ?
C22 C21 H21C 109.5 . . ?
C23 C22 C21 119.6(8) . . ?
C27 C22 C21 123.2(7) . . ?
C27 C22 C23 117.2(8) . . ?
C22 C23 H23 119.0 . . ?
C24 C23 C22 122.1(9) . . ?
C24 C23 H23 119.0 . . ?
C23 C24 H24 119.3 . . ?
C23 C24 C25 121.3(8) . . ?
C25 C24 H24 119.3 . . ?
C24 C25 H25 120.1 . . ?
C24 C25 C26 119.7(8) . . ?
C26 C25 H25 120.1 . . ?
C25 C26 H26 120.2 . . ?
C25 C26 C27 119.7(7) . . ?
C27 C26 H26 120.2 . . ?
C22 C27 P1 124.5(6) . . ?
C22 C27 C26 120.0(7) . . ?
C26 C27 P1 115.6(5) . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C29 C28 H28A 109.5 . . ?
C29 C28 H28B 109.5 . . ?
C29 C28 H28C 109.5 . . ?
C30 C29 C28 120.2(6) . . ?
C30 C29 C34 118.8(6) . . ?
C34 C29 C28 121.1(6) . . ?
C29 C30 H30 119.0 . . ?
C31 C30 C29 122.0(7) . . ?
C31 C30 H30 119.0 . . ?
C30 C31 H31 120.1 . . ?
C30 C31 C32 119.8(7) . . ?
C32 C31 H31 120.1 . . ?
C31 C32 H32 120.3 . . ?
C31 C32 C33 119.5(7) . . ?
C33 C32 H32 120.3 . . ?
C32 C33 H33 119.7 . . ?
C34 C33 C32 120.6(6) . . ?
C34 C33 H33 119.7 . . ?
C29 C34 P1 119.5(5) . . ?
C33 C34 P1 121.1(5) . . ?
C33 C34 C29 119.3(6) . . ?
O1 C35 H35A 109.5 . . ?
O1 C35 H35B 109.5 . . ?
O1 C35 H35C 109.5 . . ?
H35A C35 H35B 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
O2 C36 H36A 109.5 . . ?
O2 C36 H36B 109.5 . . ?
O2 C36 H36C 109.5 . . ?
H36A C36 H36B 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
O1 C37 C38 124.1(6) . . ?
O1 C37 C42 114.6(6) . . ?
C38 C37 C42 121.2(7) . . ?
C37 C38 H38 119.9 . . ?
C37 C38 C39 120.2(7) . . ?
C39 C38 H38 119.9 . . ?
O2 C39 C38 114.8(7) . . ?
O2 C39 C40 125.1(7) . . ?
C40 C39 C38 120.1(6) . . ?
C39 C40 H40 120.5 . . ?
C39 C40 C41 119.0(7) . . ?
C41 C40 H40 120.5 . . ?
C40 C41 H41 118.6 . . ?
C40 C41 C42 122.8(7) . . ?
C42 C41 H41 118.6 . . ?
C37 C42 C43 121.9(6) . . ?
C41 C42 C37 116.5(6) . . ?
C41 C42 C43 121.6(6) . . ?
C44 C43 C42 176.8(7) . . ?
C43 C44 Pt1 175.1(5) . . ?
P1 C45 P2 114.1(3) . . ?
P1 C45 H45A 108.7 . . ?
P1 C45 H45B 108.7 . . ?
P2 C45 H45A 108.7 . . ?
P2 C45 H45B 108.7 . . ?
H45A C45 H45B 107.6 . . ?
P2 C46 H46A 108.7 . . ?
P2 C46 H46B 108.7 . . ?
P3 C46 P2 114.3(3) . . ?
P3 C46 H46A 108.7 . . ?
P3 C46 H46B 108.7 . . ?
H46A C46 H46B 107.6 . . ?
O5 Cl1 O4 110.9(4) . . ?
O5 Cl1 O3 110.1(5) . . ?
O5 Cl1 O6 111.6(4) . . ?
O3 Cl1 O4 109.2(4) . . ?
O6 Cl1 O4 108.9(4) . . ?
O6 Cl1 O3 105.9(5) . . ?
Cl01 C47 H47A 109.4 . . ?
Cl01 C47 H47B 109.4 . . ?
Cl02 C47 Cl01 111.0(6) . . ?
Cl02 C47 H47A 109.4 . . ?
Cl02 C47 H47B 109.4 . . ?
H47A C47 H47B 108.0 . . ?
Cl03 C48 H48A 107.8 . . ?
Cl03 C48 H48B 107.8 . . ?
Cl04 C48 Cl03 118.2(7) . . ?
Cl04 C48 H48A 107.8 . . ?
Cl04 C48 H48B 107.8 . . ?
H48A C48 H48B 107.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 P2 C20 C15 162.7(4) . . . . ?
Pt1 P2 C20 C19 -22.2(6) . . . . ?
Pt1 P2 C45 P1 52.3(4) . . . . ?
Pt1 P2 C46 P3 -62.7(3) . . . . ?
Ag1 P1 C27 C22 -2.9(7) . . . . ?
Ag1 P1 C27 C26 177.9(4) . . . . ?
Ag1 P1 C34 C29 62.5(6) . . . . ?
Ag1 P1 C34 C33 -115.6(5) . . . . ?
Ag1 P1 C45 P2 -47.9(3) . . . . ?
Ag1 P3 C7 C2 -69.9(5) 2_656 . . . ?
Ag1 P3 C7 C6 109.2(5) 2_656 . . . ?
Ag1 P3 C14 C9 -4.8(6) 2_656 . . . ?
Ag1 P3 C14 C13 175.2(4) 2_656 . . . ?
Ag1 P3 C46 P2 42.5(4) 2_656 . . . ?
O1 C37 C38 C39 179.0(7) . . . . ?
O1 C37 C42 C41 -177.3(6) . . . . ?
O1 C37 C42 C43 0.7(10) . . . . ?
O2 C39 C40 C41 -179.1(8) . . . . ?
C1 C2 C3 C4 -179.7(7) . . . . ?
C1 C2 C7 P3 -0.3(9) . . . . ?
C1 C2 C7 C6 -179.4(7) . . . . ?
C2 C3 C4 C5 0.7(12) . . . . ?
C3 C2 C7 P3 -178.6(5) . . . . ?
C3 C2 C7 C6 2.3(9) . . . . ?
C3 C4 C5 C6 -0.9(13) . . . . ?
C4 C5 C6 C7 1.9(13) . . . . ?
C5 C6 C7 P3 178.3(6) . . . . ?
C5 C6 C7 C2 -2.6(11) . . . . ?
C7 P3 C14 C9 -135.6(5) . . . . ?
C7 P3 C14 C13 44.4(5) . . . . ?
C7 P3 C46 P2 164.5(3) . . . . ?
C7 C2 C3 C4 -1.4(11) . . . . ?
C8 C9 C10 C11 -179.1(7) . . . . ?
C8 C9 C14 P3 0.0(9) . . . . ?
C8 C9 C14 C13 180.0(6) . . . . ?
C9 C10 C11 C12 0.0(11) . . . . ?
C10 C9 C14 P3 -178.3(5) . . . . ?
C10 C9 C14 C13 1.7(9) . . . . ?
C10 C11 C12 C13 -0.3(11) . . . . ?
C11 C12 C13 C14 1.2(10) . . . . ?
C12 C13 C14 P3 178.0(5) . . . . ?
C12 C13 C14 C9 -2.0(10) . . . . ?
C14 P3 C7 C2 65.7(5) . . . . ?
C14 P3 C7 C6 -115.2(6) . . . . ?
C14 P3 C46 P2 -89.0(4) . . . . ?
C14 C9 C10 C11 -0.7(10) . . . . ?
C15 C16 C17 C18 0.4(12) . . . . ?
C16 C15 C20 P2 177.5(5) . . . . ?
C16 C15 C20 C19 2.3(10) . . . . ?
C16 C17 C18 C19 -1.1(13) . . . . ?
C17 C18 C19 C20 2.4(12) . . . . ?
C18 C19 C20 P2 -178.0(6) . . . . ?
C18 C19 C20 C15 -3.0(10) . . . . ?
C20 P2 C45 P1 -85.1(4) . . . . ?
C20 P2 C46 P3 71.0(4) . . . . ?
C20 C15 C16 C17 -1.0(11) . . . . ?
C21 C22 C23 C24 179.4(9) . . . . ?
C21 C22 C27 P1 1.3(11) . . . . ?
C21 C22 C27 C26 -179.5(8) . . . . ?
C22 C23 C24 C25 0.5(14) . . . . ?
C23 C22 C27 P1 -177.9(6) . . . . ?
C23 C22 C27 C26 1.3(11) . . . . ?
C23 C24 C25 C26 0.6(14) . . . . ?
C24 C25 C26 C27 -0.7(13) . . . . ?
C25 C26 C27 P1 178.9(6) . . . . ?
C25 C26 C27 C22 -0.3(11) . . . . ?
C27 P1 C34 C29 -71.3(6) . . . . ?
C27 P1 C34 C33 110.6(6) . . . . ?
C27 P1 C45 P2 79.2(4) . . . . ?
C27 C22 C23 C24 -1.4(13) . . . . ?
C28 C29 C30 C31 179.7(8) . . . . ?
C28 C29 C34 P1 1.2(10) . . . . ?
C28 C29 C34 C33 179.4(7) . . . . ?
C29 C30 C31 C32 1.0(12) . . . . ?
C30 C29 C34 P1 -179.1(6) . . . . ?
C30 C29 C34 C33 -1.0(10) . . . . ?
C30 C31 C32 C33 -1.0(12) . . . . ?
C31 C32 C33 C34 0.0(12) . . . . ?
C32 C33 C34 P1 179.1(6) . . . . ?
C32 C33 C34 C29 1.0(11) . . . . ?
C34 P1 C27 C22 130.7(6) . . . . ?
C34 P1 C27 C26 -48.5(6) . . . . ?
C34 P1 C45 P2 -173.9(3) . . . . ?
C34 C29 C30 C31 0.0(12) . . . . ?
C35 O1 C37 C38 -7.8(12) . . . . ?
C35 O1 C37 C42 172.0(8) . . . . ?
C36 O2 C39 C38 -179.8(9) . . . . ?
C36 O2 C39 C40 0.9(13) . . . . ?
C37 C38 C39 O2 179.4(7) . . . . ?
C37 C38 C39 C40 -1.3(13) . . . . ?
C38 C37 C42 C41 2.5(11) . . . . ?
C38 C37 C42 C43 -179.5(7) . . . . ?
C38 C39 C40 C41 1.6(12) . . . . ?
C39 C40 C41 C42 0.1(12) . . . . ?
C40 C41 C42 C37 -2.1(11) . . . . ?
C40 C41 C42 C43 179.9(7) . . . . ?
C42 C37 C38 C39 -0.8(12) . . . . ?
C45 P1 C27 C22 -122.6(6) . . . . ?
C45 P1 C27 C26 58.2(6) . . . . ?
C45 P1 C34 C29 -179.1(5) . . . . ?
C45 P1 C34 C33 2.7(6) . . . . ?
C45 P2 C20 C15 -66.0(5) . . . . ?
C45 P2 C20 C19 109.0(6) . . . . ?
C45 P2 C46 P3 179.3(3) . . . . ?
C46 P2 C20 C15 39.6(6) . . . . ?
C46 P2 C20 C19 -145.3(5) . . . . ?
C46 P2 C45 P1 164.8(3) . . . . ?
C46 P3 C7 C2 172.2(5) . . . . ?
C46 P3 C7 C6 -8.7(6) . . . . ?
C46 P3 C14 C9 117.6(5) . . . . ?
C46 P3 C14 C13 -62.4(5) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_w
_database_code_depnum_ccdc_archive 'CCDC 2055675'
loop_
_audit_author_name
_audit_author_address
'Liang-Jin Xu'
;Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2021-01-13 deposited with the CCDC.	2021-03-26 downloaded from the CCDC.
;
_audit_creation_date             2020-12-23
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'C100 H88 Ag2 O4 P6 Pt S2, 2(Cl O4), 4(C H2 Cl2)'
_chemical_formula_sum            'C104 H96 Ag2 Cl10 O12 P6 Pt S2'
_chemical_formula_weight         2553.07
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.2447(10)
_cell_length_b                   14.3052(11)
_cell_length_c                   14.6279(11)
_cell_angle_alpha                107.774(3)
_cell_angle_beta                 109.179(2)
_cell_angle_gamma                91.196(2)
_cell_volume                     2656.5(3)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    9854
_cell_measurement_temperature    179.68
_cell_measurement_theta_max      25.41
_cell_measurement_theta_min      2.50
_shelx_estimated_absorpt_T_max   0.785
_shelx_estimated_absorpt_T_min   0.677
_exptl_absorpt_coefficient_mu    2.118
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.2851
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1382 before and 0.0769 after correction.
The Ratio of minimum to maximum transmission is 0.3826.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic yellowish yellow'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   yellowish
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.596
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1280
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0454
_diffrn_reflns_av_unetI/netI     0.0409
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            37215
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.384
_diffrn_reflns_theta_min         2.540
_diffrn_ambient_temperature      179.68
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9423
_reflns_number_total             9686
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_refine_diff_density_max         1.627
_refine_diff_density_min         -1.175
_refine_diff_density_rms         0.115
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.081
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     623
_refine_ls_number_reflns         9686
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0369
_refine_ls_R_factor_gt           0.0360
_refine_ls_restrained_S_all      1.081
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0484P)²+4.7772P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0952
_refine_ls_wR_factor_ref         0.0961
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C35(H35A,H35B), C36(H36A,H36B), C52(H52A,H52B), C51(H51A,H51B)
2.b Aromatic/amide H refined with riding coordinates:
 C20(H20), C44(H44), C29(H29), C22(H22), C47(H47), C41(H41), C30(H30),
 C48(H48), C3(H3), C49(H49), C23(H23), C17(H17), C9(H9), C24(H24), C32(H32),
 C31(H31), C25(H25), C5(H5), C12(H12), C4(H4), C11(H11), C10(H10), C2(H2),
 C40(H40), C19(H19), C16(H16), C18(H18), C46(H46)
2.c Idealised Me refined as rotating group:
 C14(H14A,H14B,H14C), C34(H34A,H34B,H34C), C7(H7A,H7B,H7C), C27(H27A,H27B,H27C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.500000 0.500000 0.000000 0.01540(7) Uani 1 2 d S . P . .
Ag1 Ag 0.30550(2) 0.56976(2) -0.04660(2) 0.02653(9) Uani 1 1 d . . . . .
P2 P 0.50841(7) 0.51742(7) 0.16625(7) 0.01746(18) Uani 1 1 d . . . . .
P3 P 0.73094(7) 0.47477(7) 0.22936(7) 0.0211(2) Uani 1 1 d . . . . .
Cl1 Cl 0.61724(8) 0.75471(7) 0.48864(7) 0.0305(2) Uani 1 1 d . . . . .
P1 P 0.32164(7) 0.62572(7) 0.13186(8) 0.0221(2) Uani 1 1 d . . . . .
S1 S 0.89318(7) 0.96207(7) 0.08009(7) 0.0248(2) Uani 1 1 d . . . . .
Cl4 Cl 0.60294(14) 1.09309(14) 0.47538(14) 0.0737(5) Uani 1 1 d . . . . .
Cl5 Cl 0.81747(17) 1.08494(15) 0.54654(15) 0.0868(6) Uani 1 1 d . . . . .
O3 O 0.6283(3) 0.7818(2) 0.4048(2) 0.0411(8) Uani 1 1 d . . . . .
O6 O 0.6853(3) 0.6843(2) 0.5107(3) 0.0441(8) Uani 1 1 d . . . . .
O4 O 0.6417(3) 0.8407(2) 0.5788(2) 0.0434(8) Uani 1 1 d . . . . .
O5 O 0.5169(2) 0.7085(3) 0.4602(3) 0.0495(9) Uani 1 1 d . . . . .
Cl3 Cl 0.5174(3) 0.9860(3) 0.1354(3) 0.1707(17) Uani 1 1 d . . . . .
Cl2 Cl 0.4049(4) 0.80478(17) -0.0012(3) 0.197(2) Uani 1 1 d . . . . .
O1 O 0.8222(2) 1.0147(2) 0.0276(3) 0.0384(7) Uani 1 1 d . . . . .
O2 O 0.9421(2) 0.8936(2) 0.0219(2) 0.0349(7) Uani 1 1 d . . . . .
C15 C 0.4547(3) 0.4195(3) 0.1960(3) 0.0267(8) Uani 1 1 d . . . . .
C35 C 0.6364(3) 0.5503(3) 0.2623(3) 0.0206(7) Uani 1 1 d . . . . .
H35A H 0.659573 0.620342 0.274990 0.025 Uiso 1 1 calc R U . . .
H35B H 0.633318 0.545579 0.327447 0.025 Uiso 1 1 calc R U . . .
C20 C 0.4475(4) 0.3216(3) 0.1372(3) 0.0374(10) Uani 1 1 d . . . . .
H20 H 0.463857 0.305421 0.076746 0.045 Uiso 1 1 calc R U . . .
C44 C 0.7672(3) 0.8219(3) 0.0995(3) 0.0253(8) Uani 1 1 d . . . . .
H44 H 0.738879 0.793662 0.026961 0.030 Uiso 1 1 calc R U . . .
C14 C 0.8602(6) 0.5501(5) 0.4768(6) 0.081(2) Uani 1 1 d . . . . .
H14A H 0.789637 0.559639 0.463899 0.121 Uiso 1 1 calc R U . . .
H14B H 0.900354 0.588093 0.548111 0.121 Uiso 1 1 calc R U . . .
H14C H 0.866490 0.479618 0.464375 0.121 Uiso 1 1 calc R U . . .
C37 C 0.6010(3) 0.6216(3) 0.0692(3) 0.0220(7) Uani 1 1 d . . . . .
C36 C 0.4521(3) 0.6279(3) 0.2109(3) 0.0215(7) Uani 1 1 d . . . . .
H36A H 0.492806 0.686305 0.213604 0.026 Uiso 1 1 calc R U . . .
H36B H 0.455252 0.636582 0.281700 0.026 Uiso 1 1 calc R U . . .
C38 C 0.6620(3) 0.6960(3) 0.1168(3) 0.0249(8) Uani 1 1 d . . . . .
C39 C 0.7349(3) 0.7822(3) 0.1633(3) 0.0251(8) Uani 1 1 d . . . . .
C29 C 0.3720(3) 0.8272(3) 0.2493(3) 0.0311(9) Uani 1 1 d . . . . .
H29 H 0.436493 0.810832 0.280102 0.037 Uiso 1 1 calc R U . . .
C22 C 0.2086(4) 0.4477(4) 0.0854(5) 0.0503(13) Uani 1 1 d . . . . .
H22 H 0.222427 0.433927 0.023718 0.060 Uiso 1 1 calc R U . . .
C1 C 0.7319(3) 0.3697(3) 0.2756(3) 0.0305(9) Uani 1 1 d . . . . .
C28 C 0.2965(3) 0.7532(3) 0.1771(3) 0.0266(8) Uani 1 1 d . . . . .
C47 C 1.0999(3) 1.1606(3) 0.3891(4) 0.0339(10) Uani 1 1 d . . . . .
H47 H 1.141363 1.201701 0.455721 0.041 Uiso 1 1 calc R U . . .
C45 C 0.9660(3) 1.0288(3) 0.2805(3) 0.0237(8) Uani 1 1 d . . . . .
C8 C 0.8492(3) 0.5569(3) 0.3086(4) 0.0369(10) Uani 1 1 d . . . . .
C34 C 0.1130(3) 0.6987(4) 0.0563(4) 0.0452(12) Uani 1 1 d . . . . .
H34A H 0.134132 0.655443 0.002448 0.068 Uiso 1 1 calc R U . . .
H34B H 0.057040 0.731085 0.025537 0.068 Uiso 1 1 calc R U . . .
H34C H 0.091550 0.659074 0.091832 0.068 Uiso 1 1 calc R U . . .
C41 C 0.8518(3) 0.9089(3) 0.3138(3) 0.0308(9) Uani 1 1 d . . . . .
H41 H 0.879868 0.938463 0.386229 0.037 Uiso 1 1 calc R U . . .
C30 C 0.3541(4) 0.9260(3) 0.2771(4) 0.0393(10) Uani 1 1 d . . . . .
H30 H 0.406136 0.976522 0.326752 0.047 Uiso 1 1 calc R U . . .
C48 C 1.1141(3) 1.1734(3) 0.3031(3) 0.0314(9) Uani 1 1 d . . . . .
H48 H 1.165662 1.222077 0.312084 0.038 Uiso 1 1 calc R U . . .
C42 C 0.8852(3) 0.9468(3) 0.2510(3) 0.0248(8) Uani 1 1 d . . . . .
C6 C 0.7939(5) 0.2978(4) 0.2520(5) 0.0553(15) Uani 1 1 d . . . . .
C3 C 0.6674(4) 0.2732(4) 0.3578(4) 0.0495(13) Uani 1 1 d . . . . .
H3 H 0.624673 0.265123 0.393641 0.059 Uiso 1 1 calc R U . . .
C49 C 1.0533(3) 1.1154(3) 0.2050(3) 0.0285(8) Uani 1 1 d . . . . .
H49 H 1.061196 1.124409 0.146123 0.034 Uiso 1 1 calc R U . . .
C23 C 0.1541(4) 0.3762(4) 0.0982(5) 0.0604(16) Uani 1 1 d . . . . .
H23 H 0.131776 0.312160 0.048107 0.072 Uiso 1 1 calc R U . . .
C17 C 0.3981(4) 0.3655(5) 0.3128(5) 0.0544(15) Uani 1 1 d . . . . .
H17 H 0.380524 0.380661 0.372429 0.065 Uiso 1 1 calc R U . . .
C9 C 0.8946(5) 0.5986(4) 0.2516(7) 0.079(2) Uani 1 1 d . . . . .
H9 H 0.863018 0.577259 0.179113 0.095 Uiso 1 1 calc R U . . .
C24 C 0.1327(4) 0.4020(5) 0.1886(5) 0.0603(15) Uani 1 1 d . . . . .
H24 H 0.092791 0.353846 0.197571 0.072 Uiso 1 1 calc R U . . .
C32 C 0.1844(4) 0.8757(4) 0.1604(4) 0.0447(12) Uani 1 1 d . . . . .
H32 H 0.120311 0.893026 0.129942 0.054 Uiso 1 1 calc R U . . .
C31 C 0.2605(4) 0.9498(4) 0.2321(4) 0.0460(12) Uani 1 1 d . . . . .
H31 H 0.248241 1.016834 0.250212 0.055 Uiso 1 1 calc R U . . .
C7 C 0.8630(6) 0.3072(6) 0.1957(7) 0.090(3) Uani 1 1 d . . . . .
H7A H 0.823261 0.302335 0.125208 0.135 Uiso 1 1 calc R U . . .
H7B H 0.905266 0.254016 0.194819 0.135 Uiso 1 1 calc R U . . .
H7C H 0.905570 0.371533 0.230503 0.135 Uiso 1 1 calc R U . . .
C52 C 0.4017(5) 0.9260(5) 0.0518(6) 0.0682(17) Uani 1 1 d . . . . .
H52A H 0.353632 0.934341 0.088609 0.082 Uiso 1 1 calc R U . . .
H52B H 0.377861 0.955998 -0.003026 0.082 Uiso 1 1 calc R U . . .
C27 C 0.2603(4) 0.6595(4) 0.3357(4) 0.0546(14) Uani 1 1 d . . . . .
H27A H 0.225777 0.712260 0.314836 0.082 Uiso 1 1 calc R U . . .
H27B H 0.332637 0.675509 0.353262 0.082 Uiso 1 1 calc R U . . .
H27C H 0.247040 0.653818 0.395502 0.082 Uiso 1 1 calc R U . . .
C25 C 0.1648(4) 0.4904(4) 0.2643(5) 0.0575(15) Uani 1 1 d . . . . .
H25 H 0.148976 0.502959 0.324890 0.069 Uiso 1 1 calc R U . . .
C26 C 0.2236(4) 0.5657(4) 0.2512(4) 0.0474(12) Uani 1 1 d . . . . .
C13 C 0.8937(4) 0.5821(5) 0.4125(4) 0.0619(17) Uani 1 1 d . . . . .
C5 C 0.7886(6) 0.2148(5) 0.2828(7) 0.085(2) Uani 1 1 d . . . . .
H5 H 0.829690 0.165133 0.267755 0.102 Uiso 1 1 calc R U . . .
C12 C 0.9921(5) 0.6527(5) 0.4601(6) 0.082(2) Uani 1 1 d . . . . .
H12 H 1.030036 0.674054 0.531473 0.099 Uiso 1 1 calc R U . . .
C51 C 0.6970(8) 1.0180(5) 0.4902(7) 0.100(3) Uani 1 1 d . . . . .
H51A H 0.690034 0.970588 0.422179 0.120 Uiso 1 1 calc R U . . .
H51B H 0.688572 0.979180 0.533321 0.120 Uiso 1 1 calc R U . . .
C4 C 0.7267(6) 0.2024(4) 0.3334(6) 0.0715(19) Uani 1 1 d . . . . .
H4 H 0.724654 0.144406 0.351889 0.086 Uiso 1 1 calc R U . . .
C11 C 1.0211(6) 0.6826(6) 0.3931(7) 0.081(2) Uani 1 1 d . . . . .
H11 H 1.083926 0.723701 0.422661 0.097 Uiso 1 1 calc R U . . .
C10 C 0.9769(6) 0.6642(6) 0.2930(10) 0.105(3) Uani 1 1 d . . . . .
H10 H 1.001631 0.694943 0.254838 0.127 Uiso 1 1 calc R U . . .
C2 C 0.6708(3) 0.3569(3) 0.3291(4) 0.0353(10) Uani 1 1 d . . . . .
H2 H 0.630416 0.406595 0.346529 0.042 Uiso 1 1 calc R U . . .
C21 C 0.2462(3) 0.5448(3) 0.1643(4) 0.0362(10) Uani 1 1 d . . . . .
C40 C 0.7772(3) 0.8275(3) 0.2698(3) 0.0326(9) Uani 1 1 d . . . . .
H40 H 0.754458 0.802173 0.312909 0.039 Uiso 1 1 calc R U . . .
C19 C 0.4158(5) 0.2466(4) 0.1676(4) 0.0578(16) Uani 1 1 d . . . . .
H19 H 0.411102 0.179352 0.127431 0.069 Uiso 1 1 calc R U . . .
C50 C 0.9807(3) 1.0440(3) 0.1962(3) 0.0242(8) Uani 1 1 d . . . . .
C16 C 0.4308(3) 0.4418(4) 0.2848(4) 0.0381(10) Uani 1 1 d . . . . .
H16 H 0.436685 0.508888 0.326244 0.046 Uiso 1 1 calc R U . . .
C18 C 0.3915(4) 0.2684(5) 0.2539(5) 0.0614(17) Uani 1 1 d . . . . .
H18 H 0.369953 0.216419 0.273284 0.074 Uiso 1 1 calc R U . . .
C46 C 1.0260(3) 1.0889(3) 0.3785(3) 0.0300(9) Uani 1 1 d . . . . .
H46 H 1.016764 1.081061 0.437311 0.036 Uiso 1 1 calc R U . . .
C33 C 0.1994(3) 0.7761(3) 0.1319(3) 0.0339(9) Uani 1 1 d . . . . .
C43 C 0.8408(3) 0.9026(3) 0.1455(3) 0.0233(8) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Ag1 2.9030(3) 2_665 ?
Pt1 Ag1 2.9029(3) . ?
Pt1 P2 2.3298(9) . ?
Pt1 P2 2.3298(9) 2_665 ?
Pt1 C37 1.996(4) . ?
Pt1 C37 1.996(4) 2_665 ?
Ag1 P3 2.4201(10) 2_665 ?
Ag1 P1 2.4146(10) . ?
P2 C15 1.813(4) . ?
P2 C35 1.844(4) . ?
P2 C36 1.827(4) . ?
P3 C35 1.839(4) . ?
P3 C1 1.825(4) . ?
P3 C8 1.834(4) . ?
Cl1 O3 1.446(3) . ?
Cl1 O6 1.447(4) . ?
Cl1 O4 1.437(3) . ?
Cl1 O5 1.434(3) . ?
P1 C36 1.832(4) . ?
P1 C28 1.827(4) . ?
P1 C21 1.827(4) . ?
S1 O1 1.433(3) . ?
S1 O2 1.442(3) . ?
S1 C50 1.773(4) . ?
S1 C43 1.770(4) . ?
Cl4 C51 1.735(9) . ?
Cl5 C51 1.750(10) . ?
Cl3 C52 1.710(8) . ?
Cl2 C52 1.677(7) . ?
C15 C20 1.383(6) . ?
C15 C16 1.396(6) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C20 H20 0.9500 . ?
C20 C19 1.397(6) . ?
C44 H44 0.9500 . ?
C44 C39 1.413(6) . ?
C44 C43 1.377(5) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C14 C13 1.368(10) . ?
C37 C38 1.218(5) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C38 C39 1.426(5) . ?
C39 C40 1.400(6) . ?
C29 H29 0.9500 . ?
C29 C28 1.384(6) . ?
C29 C30 1.401(6) . ?
C22 H22 0.9500 . ?
C22 C23 1.365(8) . ?
C22 C21 1.460(7) . ?
C1 C6 1.407(6) . ?
C1 C2 1.391(6) . ?
C28 C33 1.417(6) . ?
C47 H47 0.9500 . ?
C47 C48 1.400(6) . ?
C47 C46 1.391(6) . ?
C45 C42 1.481(5) . ?
C45 C50 1.394(6) . ?
C45 C46 1.392(6) . ?
C8 C9 1.453(9) . ?
C8 C13 1.365(8) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C34 C33 1.505(7) . ?
C41 H41 0.9500 . ?
C41 C42 1.394(6) . ?
C41 C40 1.394(6) . ?
C30 H30 0.9500 . ?
C30 C31 1.380(7) . ?
C48 H48 0.9500 . ?
C48 C49 1.387(6) . ?
C42 C43 1.388(6) . ?
C6 C7 1.503(8) . ?
C6 C5 1.402(8) . ?
C3 H3 0.9500 . ?
C3 C4 1.371(9) . ?
C3 C2 1.389(6) . ?
C49 H49 0.9500 . ?
C49 C50 1.386(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.396(9) . ?
C17 H17 0.9500 . ?
C17 C16 1.397(6) . ?
C17 C18 1.375(9) . ?
C9 H9 0.9500 . ?
C9 C10 1.327(10) . ?
C24 H24 0.9500 . ?
C24 C25 1.350(9) . ?
C32 H32 0.9500 . ?
C32 C31 1.388(8) . ?
C32 C33 1.400(6) . ?
C31 H31 0.9500 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C52 H52A 0.9900 . ?
C52 H52B 0.9900 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C27 C26 1.461(8) . ?
C25 H25 0.9500 . ?
C25 C26 1.447(7) . ?
C26 C21 1.361(7) . ?
C13 C12 1.531(10) . ?
C5 H5 0.9500 . ?
C5 C4 1.364(10) . ?
C12 H12 0.9500 . ?
C12 C11 1.352(12) . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C4 H4 0.9500 . ?
C11 H11 0.9500 . ?
C11 C10 1.327(13) . ?
C10 H10 0.9500 . ?
C2 H2 0.9500 . ?
C40 H40 0.9500 . ?
C19 H19 0.9500 . ?
C19 C18 1.365(9) . ?
C16 H16 0.9500 . ?
C18 H18 0.9500 . ?
C46 H46 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag1 Pt1 Ag1 180.000(12) . 2_665 ?
P2 Pt1 Ag1 91.50(2) . . ?
P2 Pt1 Ag1 88.50(2) 2_665 . ?
P2 Pt1 Ag1 91.50(2) 2_665 2_665 ?
P2 Pt1 Ag1 88.50(2) . 2_665 ?
P2 Pt1 P2 180.0 . 2_665 ?
C37 Pt1 Ag1 105.74(11) . . ?
C37 Pt1 Ag1 74.26(11) . 2_665 ?
C37 Pt1 Ag1 105.74(11) 2_665 2_665 ?
C37 Pt1 Ag1 74.26(11) 2_665 . ?
C37 Pt1 P2 96.15(11) 2_665 . ?
C37 Pt1 P2 83.85(11) . . ?
C37 Pt1 P2 83.85(11) 2_665 2_665 ?
C37 Pt1 P2 96.15(11) . 2_665 ?
C37 Pt1 C37 180.0 . 2_665 ?
P3 Ag1 Pt1 95.97(2) 2_665 . ?
P1 Ag1 Pt1 91.82(2) . . ?
P1 Ag1 P3 172.11(3) . 2_665 ?
C15 P2 Pt1 121.82(14) . . ?
C15 P2 C35 102.97(17) . . ?
C15 P2 C36 106.98(19) . . ?
C35 P2 Pt1 114.41(12) . . ?
C36 P2 Pt1 107.50(13) . . ?
C36 P2 C35 101.07(17) . . ?
C35 P3 Ag1 108.48(12) . 2_665 ?
C1 P3 Ag1 114.64(14) . 2_665 ?
C1 P3 C35 108.47(19) . . ?
C1 P3 C8 107.3(2) . . ?
C8 P3 Ag1 114.26(17) . 2_665 ?
C8 P3 C35 102.94(17) . . ?
O3 Cl1 O6 108.9(2) . . ?
O4 Cl1 O3 110.1(2) . . ?
O4 Cl1 O6 108.7(2) . . ?
O5 Cl1 O3 110.1(2) . . ?
O5 Cl1 O6 108.3(2) . . ?
O5 Cl1 O4 110.7(2) . . ?
C36 P1 Ag1 109.16(12) . . ?
C28 P1 Ag1 113.31(13) . . ?
C28 P1 C36 104.38(18) . . ?
C21 P1 Ag1 113.80(17) . . ?
C21 P1 C36 105.92(19) . . ?
C21 P1 C28 109.6(2) . . ?
O1 S1 O2 117.7(2) . . ?
O1 S1 C50 111.09(19) . . ?
O1 S1 C43 111.15(18) . . ?
O2 S1 C50 111.67(18) . . ?
O2 S1 C43 109.85(18) . . ?
C43 S1 C50 92.53(18) . . ?
C20 C15 P2 120.1(3) . . ?
C20 C15 C16 119.6(4) . . ?
C16 C15 P2 119.9(3) . . ?
P2 C35 H35A 108.2 . . ?
P2 C35 H35B 108.2 . . ?
P3 C35 P2 116.2(2) . . ?
P3 C35 H35A 108.2 . . ?
P3 C35 H35B 108.2 . . ?
H35A C35 H35B 107.4 . . ?
C15 C20 H20 120.4 . . ?
C15 C20 C19 119.3(5) . . ?
C19 C20 H20 120.4 . . ?
C39 C44 H44 120.9 . . ?
C43 C44 H44 120.9 . . ?
C43 C44 C39 118.2(4) . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
C38 C37 Pt1 176.2(3) . . ?
P2 C36 P1 114.8(2) . . ?
P2 C36 H36A 108.6 . . ?
P2 C36 H36B 108.6 . . ?
P1 C36 H36A 108.6 . . ?
P1 C36 H36B 108.6 . . ?
H36A C36 H36B 107.5 . . ?
C37 C38 C39 174.3(4) . . ?
C44 C39 C38 118.7(4) . . ?
C40 C39 C44 119.0(3) . . ?
C40 C39 C38 122.3(4) . . ?
C28 C29 H29 119.8 . . ?
C28 C29 C30 120.4(4) . . ?
C30 C29 H29 119.8 . . ?
C23 C22 H22 119.2 . . ?
C23 C22 C21 121.6(6) . . ?
C21 C22 H22 119.2 . . ?
C6 C1 P3 118.2(4) . . ?
C2 C1 P3 122.2(3) . . ?
C2 C1 C6 119.6(4) . . ?
C29 C28 P1 120.9(3) . . ?
C29 C28 C33 120.5(4) . . ?
C33 C28 P1 118.5(3) . . ?
C48 C47 H47 119.4 . . ?
C46 C47 H47 119.4 . . ?
C46 C47 C48 121.1(4) . . ?
C50 C45 C42 112.8(3) . . ?
C46 C45 C42 128.4(4) . . ?
C46 C45 C50 118.7(4) . . ?
C9 C8 P3 114.1(4) . . ?
C13 C8 P3 125.9(5) . . ?
C13 C8 C9 119.9(6) . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
C42 C41 H41 120.2 . . ?
C42 C41 C40 119.7(4) . . ?
C40 C41 H41 120.2 . . ?
C29 C30 H30 120.1 . . ?
C31 C30 C29 119.8(4) . . ?
C31 C30 H30 120.1 . . ?
C47 C48 H48 119.8 . . ?
C49 C48 C47 120.5(4) . . ?
C49 C48 H48 119.8 . . ?
C41 C42 C45 128.9(4) . . ?
C43 C42 C45 112.8(3) . . ?
C43 C42 C41 118.3(4) . . ?
C1 C6 C7 122.6(5) . . ?
C5 C6 C1 117.1(5) . . ?
C5 C6 C7 120.3(5) . . ?
C4 C3 H3 120.5 . . ?
C4 C3 C2 118.9(5) . . ?
C2 C3 H3 120.5 . . ?
C48 C49 H49 121.2 . . ?
C50 C49 C48 117.5(4) . . ?
C50 C49 H49 121.2 . . ?
C22 C23 H23 121.7 . . ?
C22 C23 C24 116.6(6) . . ?
C24 C23 H23 121.7 . . ?
C16 C17 H17 120.0 . . ?
C18 C17 H17 120.0 . . ?
C18 C17 C16 120.0(5) . . ?
C8 C9 H9 117.5 . . ?
C10 C9 C8 125.0(9) . . ?
C10 C9 H9 117.5 . . ?
C23 C24 H24 117.6 . . ?
C25 C24 C23 124.7(6) . . ?
C25 C24 H24 117.6 . . ?
C31 C32 H32 119.1 . . ?
C31 C32 C33 121.8(4) . . ?
C33 C32 H32 119.1 . . ?
C30 C31 C32 119.9(4) . . ?
C30 C31 H31 120.0 . . ?
C32 C31 H31 120.0 . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Cl3 C52 H52A 109.3 . . ?
Cl3 C52 H52B 109.3 . . ?
Cl2 C52 Cl3 111.5(4) . . ?
Cl2 C52 H52A 109.3 . . ?
Cl2 C52 H52B 109.3 . . ?
H52A C52 H52B 108.0 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C26 C27 H27A 109.5 . . ?
C26 C27 H27B 109.5 . . ?
C26 C27 H27C 109.5 . . ?
C24 C25 H25 120.7 . . ?
C24 C25 C26 118.5(6) . . ?
C26 C25 H25 120.7 . . ?
C25 C26 C27 117.5(5) . . ?
C21 C26 C27 123.2(5) . . ?
C21 C26 C25 119.2(5) . . ?
C14 C13 C12 117.6(6) . . ?
C8 C13 C14 127.0(6) . . ?
C8 C13 C12 115.4(7) . . ?
C6 C5 H5 118.7 . . ?
C4 C5 C6 122.6(6) . . ?
C4 C5 H5 118.7 . . ?
C13 C12 H12 122.5 . . ?
C11 C12 C13 115.0(7) . . ?
C11 C12 H12 122.5 . . ?
Cl4 C51 Cl5 112.9(4) . . ?
Cl4 C51 H51A 109.0 . . ?
Cl4 C51 H51B 109.0 . . ?
Cl5 C51 H51A 109.0 . . ?
Cl5 C51 H51B 109.0 . . ?
H51A C51 H51B 107.8 . . ?
C3 C4 H4 119.9 . . ?
C5 C4 C3 120.3(5) . . ?
C5 C4 H4 119.9 . . ?
C12 C11 H11 114.5 . . ?
C10 C11 C12 131.1(8) . . ?
C10 C11 H11 114.5 . . ?
C9 C10 H10 123.4 . . ?
C11 C10 C9 113.3(10) . . ?
C11 C10 H10 123.4 . . ?
C1 C2 H2 119.3 . . ?
C3 C2 C1 121.5(4) . . ?
C3 C2 H2 119.3 . . ?
C22 C21 P1 113.5(4) . . ?
C26 C21 P1 127.3(4) . . ?
C26 C21 C22 119.2(4) . . ?
C39 C40 H40 119.3 . . ?
C41 C40 C39 121.3(4) . . ?
C41 C40 H40 119.3 . . ?
C20 C19 H19 119.4 . . ?
C18 C19 C20 121.2(5) . . ?
C18 C19 H19 119.4 . . ?
C45 C50 S1 110.7(3) . . ?
C49 C50 S1 126.1(3) . . ?
C49 C50 C45 123.1(4) . . ?
C15 C16 C17 119.9(5) . . ?
C15 C16 H16 120.0 . . ?
C17 C16 H16 120.0 . . ?
C17 C18 H18 120.0 . . ?
C19 C18 C17 119.9(5) . . ?
C19 C18 H18 120.0 . . ?
C47 C46 C45 119.0(4) . . ?
C47 C46 H46 120.5 . . ?
C45 C46 H46 120.5 . . ?
C28 C33 C34 123.1(4) . . ?
C32 C33 C28 117.6(4) . . ?
C32 C33 C34 119.3(4) . . ?
C44 C43 S1 125.4(3) . . ?
C44 C43 C42 123.5(4) . . ?
C42 C43 S1 111.1(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 P2 C15 C20 28.5(4) . . . . ?
Pt1 P2 C15 C16 -158.6(3) . . . . ?
Pt1 P2 C35 P3 -49.2(2) . . . . ?
Pt1 P2 C36 P1 58.5(2) . . . . ?
Ag1 P3 C35 P2 35.3(2) 2_665 . . . ?
Ag1 P3 C1 C6 54.1(4) 2_665 . . . ?
Ag1 P3 C1 C2 -123.2(3) 2_665 . . . ?
Ag1 P3 C8 C9 11.2(4) 2_665 . . . ?
Ag1 P3 C8 C13 -170.7(4) 2_665 . . . ?
Ag1 P1 C36 P2 -46.2(2) . . . . ?
Ag1 P1 C28 C29 -113.3(3) . . . . ?
Ag1 P1 C28 C33 62.6(4) . . . . ?
Ag1 P1 C21 C22 14.8(4) . . . . ?
Ag1 P1 C21 C26 -165.8(4) . . . . ?
P2 C15 C20 C19 173.3(4) . . . . ?
P2 C15 C16 C17 -174.1(4) . . . . ?
P3 C1 C6 C7 3.5(9) . . . . ?
P3 C1 C6 C5 -176.1(6) . . . . ?
P3 C1 C2 C3 175.6(4) . . . . ?
P3 C8 C9 C10 175.9(6) . . . . ?
P3 C8 C13 C14 1.4(9) . . . . ?
P3 C8 C13 C12 -179.6(4) . . . . ?
P1 C28 C33 C34 6.7(6) . . . . ?
P1 C28 C33 C32 -174.0(4) . . . . ?
O1 S1 C50 C45 110.9(3) . . . . ?
O1 S1 C50 C49 -67.8(4) . . . . ?
O1 S1 C43 C44 70.2(4) . . . . ?
O1 S1 C43 C42 -111.0(3) . . . . ?
O2 S1 C50 C45 -115.4(3) . . . . ?
O2 S1 C50 C49 65.8(4) . . . . ?
O2 S1 C43 C44 -61.9(4) . . . . ?
O2 S1 C43 C42 116.9(3) . . . . ?
C15 P2 C35 P3 85.1(2) . . . . ?
C15 P2 C36 P1 -73.9(2) . . . . ?
C15 C20 C19 C18 0.3(8) . . . . ?
C35 P2 C15 C20 -101.5(4) . . . . ?
C35 P2 C15 C16 71.5(4) . . . . ?
C35 P2 C36 P1 178.7(2) . . . . ?
C35 P3 C1 C6 175.5(4) . . . . ?
C35 P3 C1 C2 -1.9(4) . . . . ?
C35 P3 C8 C9 -106.3(4) . . . . ?
C35 P3 C8 C13 71.9(4) . . . . ?
C20 C15 C16 C17 -1.1(7) . . . . ?
C20 C19 C18 C17 -0.1(9) . . . . ?
C44 C39 C40 C41 -1.7(6) . . . . ?
C14 C13 C12 C11 -179.5(6) . . . . ?
C36 P2 C15 C20 152.5(3) . . . . ?
C36 P2 C15 C16 -34.5(4) . . . . ?
C36 P2 C35 P3 -164.4(2) . . . . ?
C36 P1 C28 C29 5.3(4) . . . . ?
C36 P1 C28 C33 -178.8(3) . . . . ?
C36 P1 C21 C22 -105.2(3) . . . . ?
C36 P1 C21 C26 74.3(4) . . . . ?
C38 C39 C40 C41 176.9(4) . . . . ?
C39 C44 C43 S1 178.9(3) . . . . ?
C39 C44 C43 C42 0.2(6) . . . . ?
C29 C28 C33 C34 -177.4(4) . . . . ?
C29 C28 C33 C32 1.9(6) . . . . ?
C29 C30 C31 C32 0.7(8) . . . . ?
C22 C23 C24 C25 -2.2(10) . . . . ?
C1 P3 C35 P2 -89.9(2) . . . . ?
C1 P3 C8 C9 139.4(4) . . . . ?
C1 P3 C8 C13 -42.4(5) . . . . ?
C1 C6 C5 C4 0.0(12) . . . . ?
C28 P1 C36 P2 -167.6(2) . . . . ?
C28 P1 C21 C22 142.8(3) . . . . ?
C28 P1 C21 C26 -37.8(5) . . . . ?
C28 C29 C30 C31 -0.2(7) . . . . ?
C47 C48 C49 C50 -1.5(6) . . . . ?
C45 C42 C43 S1 -1.9(4) . . . . ?
C45 C42 C43 C44 176.9(3) . . . . ?
C8 P3 C35 P2 156.7(2) . . . . ?
C8 P3 C1 C6 -74.0(5) . . . . ?
C8 P3 C1 C2 108.7(4) . . . . ?
C8 C9 C10 C11 6.0(11) . . . . ?
C8 C13 C12 C11 1.3(8) . . . . ?
C41 C42 C43 S1 179.6(3) . . . . ?
C41 C42 C43 C44 -1.6(6) . . . . ?
C30 C29 C28 P1 174.6(3) . . . . ?
C30 C29 C28 C33 -1.2(7) . . . . ?
C48 C47 C46 C45 0.3(6) . . . . ?
C48 C49 C50 S1 179.1(3) . . . . ?
C48 C49 C50 C45 0.5(6) . . . . ?
C42 C45 C50 S1 2.3(4) . . . . ?
C42 C45 C50 C49 -178.9(4) . . . . ?
C42 C45 C46 C47 178.4(4) . . . . ?
C42 C41 C40 C39 0.3(7) . . . . ?
C6 C1 C2 C3 -1.7(7) . . . . ?
C6 C5 C4 C3 -1.0(13) . . . . ?
C23 C22 C21 P1 177.4(4) . . . . ?
C23 C22 C21 C26 -2.1(7) . . . . ?
C23 C24 C25 C26 1.5(10) . . . . ?
C9 C8 C13 C14 179.4(6) . . . . ?
C9 C8 C13 C12 -1.5(7) . . . . ?
C24 C25 C26 C27 -178.0(5) . . . . ?
C24 C25 C26 C21 -1.0(8) . . . . ?
C31 C32 C33 C28 -1.4(7) . . . . ?
C31 C32 C33 C34 178.0(5) . . . . ?
C7 C6 C5 C4 -179.6(8) . . . . ?
C27 C26 C21 P1 -1.4(8) . . . . ?
C27 C26 C21 C22 178.1(5) . . . . ?
C25 C26 C21 P1 -178.2(4) . . . . ?
C25 C26 C21 C22 1.2(7) . . . . ?
C13 C8 C9 C10 -2.4(9) . . . . ?
C13 C12 C11 C10 3.0(12) . . . . ?
C12 C11 C10 C9 -6.6(13) . . . . ?
C4 C3 C2 C1 0.7(8) . . . . ?
C2 C1 C6 C7 -179.1(6) . . . . ?
C2 C1 C6 C5 1.3(9) . . . . ?
C2 C3 C4 C5 0.6(11) . . . . ?
C21 P1 C36 P2 76.8(3) . . . . ?
C21 P1 C28 C29 118.4(4) . . . . ?
C21 P1 C28 C33 -65.7(4) . . . . ?
C21 C22 C23 C24 2.4(8) . . . . ?
C40 C41 C42 C45 -176.9(4) . . . . ?
C40 C41 C42 C43 1.2(6) . . . . ?
C50 S1 C43 C44 -176.0(4) . . . . ?
C50 S1 C43 C42 2.8(3) . . . . ?
C50 C45 C42 C41 178.0(4) . . . . ?
C50 C45 C42 C43 -0.2(5) . . . . ?
C50 C45 C46 C47 -1.3(6) . . . . ?
C16 C15 C20 C19 0.3(7) . . . . ?
C16 C17 C18 C19 -0.7(9) . . . . ?
C18 C17 C16 C15 1.3(8) . . . . ?
C46 C47 C48 C49 1.1(6) . . . . ?
C46 C45 C42 C41 -1.8(7) . . . . ?
C46 C45 C42 C43 -180.0(4) . . . . ?
C46 C45 C50 S1 -178.0(3) . . . . ?
C46 C45 C50 C49 0.9(6) . . . . ?
C33 C32 C31 C30 0.1(8) . . . . ?
C43 S1 C50 C45 -2.9(3) . . . . ?
C43 S1 C50 C49 178.3(4) . . . . ?
C43 C44 C39 C38 -177.2(4) . . . . ?
C43 C44 C39 C40 1.4(6) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mo_2019083102_0m
_database_code_depnum_ccdc_archive 'CCDC 2055676'
loop_
_audit_author_name
_audit_author_address
'Liang-Jin Xu'
;Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2021-01-13 deposited with the CCDC.	2021-03-26 downloaded from the CCDC.
;
_audit_creation_date             2020-12-23
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'C118 H102 Ag2 N6 P6 Pt, 2(C F3 O3 S), 6(C H2 Cl2)'
_chemical_formula_sum            'C126 H114 Ag2 Cl12 F6 N6 O6 P6 Pt S2'
_chemical_formula_weight         3008.40
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.2767(10)
_cell_length_b                   14.9810(11)
_cell_length_c                   15.3107(10)
_cell_angle_alpha                86.910(3)
_cell_angle_beta                 84.744(2)
_cell_angle_gamma                74.999(3)
_cell_volume                     3148.2(4)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    9334
_cell_measurement_temperature    100.04
_cell_measurement_theta_max      25.39
_cell_measurement_theta_min      2.31
_shelx_estimated_absorpt_T_max   0.795
_shelx_estimated_absorpt_T_min   0.709
_exptl_absorpt_coefficient_mu    1.846
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.4412
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1058 before and 0.0563 after correction.
The Ratio of minimum to maximum transmission is 0.5921.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic greenish green'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   greenish
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    1.587
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1512
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.13
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0326
_diffrn_reflns_av_unetI/netI     0.0292
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            41949
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.393
_diffrn_reflns_theta_min         2.310
_diffrn_ambient_temperature      100.04
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                10904
_reflns_number_total             11506
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.453
_refine_diff_density_min         -1.577
_refine_diff_density_rms         0.087
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     758
_refine_ls_number_reflns         11506
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0322
_refine_ls_R_factor_gt           0.0293
_refine_ls_restrained_S_all      1.035
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0253P)²+8.2798P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0705
_refine_ls_wR_factor_ref         0.0732
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C35(H35A,H35B), C36(H36A,H36B), C63(H63A,H63B), C62(H62A,H62B), C61(H61A,H61B)
2.b Aromatic/amide H refined with riding coordinates:
 C16(H16), C20(H20), C44(H44), C43(H43), C17(H17), C18(H18), C41(H41),
 C53(H53), C55(H55), C23(H23), C29(H29), C11(H11), C59(H59), C12(H12), C10(H10),
  C24(H24), C52(H52), C31(H31), C50(H50), C49(H49), C4(H4), C22(H22), C40(H40),
 C9(H9), C2(H2), C19(H19), C30(H30), C32(H32), C56(H56), C25(H25), C58(H58),
 C3(H3), C51(H51), C5(H5), C57(H57)
2.c Idealised Me refined as rotating group:
 C27(H27A,H27B,H27C), C7(H7A,H7B,H7C), C34(H34A,H34B,H34C), C14(H14A,H14B,H14C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.500000 1.000000 0.500000 0.01072(5) Uani 1 2 d S . P . .
Ag1 Ag 0.50598(2) 0.84318(2) 0.39603(2) 0.01832(6) Uani 1 1 d . . . . .
P2 P 0.66603(5) 0.95865(5) 0.51462(5) 0.01161(15) Uani 1 1 d . . . . .
S1 S 0.91506(6) 0.76824(6) 0.67524(6) 0.02566(18) Uani 1 1 d . . . . .
Cl1 Cl 0.43481(8) 0.65397(7) 0.47988(7) 0.0385(2) Uani 1 1 d . . . . .
Cl2 Cl 0.50194(9) 0.67687(8) 0.64896(7) 0.0503(3) Uani 1 1 d . . . . .
Cl4 Cl 0.93881(8) 0.64775(10) 0.97627(10) 0.0614(3) Uani 1 1 d . . . . .
Cl3 Cl 0.77673(10) 0.80967(11) 0.96392(14) 0.0898(6) Uani 1 1 d . . . . .
Cl5 Cl 1.08613(13) 0.83498(13) 1.04346(11) 0.0836(5) Uani 1 1 d . . . . .
P1 P 0.67603(6) 0.77938(5) 0.41901(5) 0.01467(16) Uani 1 1 d . . . . .
P3 P 0.64899(6) 1.09423(5) 0.66522(5) 0.01418(15) Uani 1 1 d . . . . .
Cl6 Cl 1.10671(17) 0.92123(17) 0.87464(11) 0.1086(7) Uani 1 1 d . . . . .
C37 C 0.4892(2) 0.9423(2) 0.6202(2) 0.0154(6) Uani 1 1 d . . . . .
C16 C 0.7065(2) 1.1073(2) 0.4203(2) 0.0185(6) Uani 1 1 d . . . . .
H16 H 0.640845 1.137674 0.437616 0.022 Uiso 1 1 calc R U . . .
N3 N 0.4886(2) 0.52801(18) 1.11565(17) 0.0199(6) Uani 1 1 d . . . . .
C15 C 0.7424(2) 1.0136(2) 0.44084(19) 0.0154(6) Uani 1 1 d . . . . .
N2 N 0.5687(2) 0.62311(18) 1.02416(17) 0.0193(6) Uani 1 1 d . . . . .
C35 C 0.7128(2) 0.8327(2) 0.51089(19) 0.0141(6) Uani 1 1 d . . . . .
H35A H 0.690382 0.804879 0.566431 0.017 Uiso 1 1 calc R U . . .
H35B H 0.784733 0.817403 0.507630 0.017 Uiso 1 1 calc R U . . .
N1 N 0.3977(2) 0.64667(18) 1.02487(17) 0.0180(5) Uani 1 1 d . . . . .
C36 C 0.7004(2) 0.9775(2) 0.62370(19) 0.0141(6) Uani 1 1 d . . . . .
H36A H 0.679684 0.932637 0.666072 0.017 Uiso 1 1 calc R U . . .
H36B H 0.772185 0.963890 0.621541 0.017 Uiso 1 1 calc R U . . .
O3 O 0.82302(18) 0.74587(19) 0.69062(17) 0.0334(6) Uani 1 1 d . . . . .
O1 O 0.91754(18) 0.84055(19) 0.60954(19) 0.0365(7) Uani 1 1 d . . . . .
O2 O 0.95962(19) 0.7780(2) 0.75431(18) 0.0352(6) Uani 1 1 d . . . . .
F3 F 1.0030(2) 0.59242(17) 0.67756(19) 0.0566(7) Uani 1 1 d . . . . .
F2 F 1.08944(17) 0.68020(17) 0.61628(18) 0.0473(6) Uani 1 1 d . . . . .
C38 C 0.4866(2) 0.9047(2) 0.6922(2) 0.0170(6) Uani 1 1 d . . . . .
F1 F 0.9743(2) 0.6531(2) 0.54945(18) 0.0601(8) Uani 1 1 d . . . . .
C8 C 0.7079(2) 0.6562(2) 0.4469(2) 0.0180(6) Uani 1 1 d . . . . .
C21 C 0.7418(2) 1.1585(2) 0.6447(2) 0.0170(6) Uani 1 1 d . . . . .
C20 C 0.8382(2) 0.9692(2) 0.4137(2) 0.0205(7) Uani 1 1 d . . . . .
H20 H 0.863090 0.905345 0.427426 0.025 Uiso 1 1 calc R U . . .
C44 C 0.3954(2) 0.8364(2) 0.8115(2) 0.0178(6) Uani 1 1 d . . . . .
H44 H 0.336180 0.866028 0.786652 0.021 Uiso 1 1 calc R U . . .
C39 C 0.4832(2) 0.8522(2) 0.7731(2) 0.0182(6) Uani 1 1 d . . . . .
C43 C 0.3937(2) 0.7786(2) 0.8848(2) 0.0182(6) Uani 1 1 d . . . . .
H43 H 0.333665 0.768941 0.910012 0.022 Uiso 1 1 calc R U . . .
C1 C 0.7523(3) 0.8015(2) 0.3226(2) 0.0246(7) Uani 1 1 d . . . . .
C17 C 0.7669(2) 1.1566(2) 0.3745(2) 0.0224(7) Uani 1 1 d . . . . .
H17 H 0.742842 1.220799 0.361761 0.027 Uiso 1 1 calc R U . . .
C18 C 0.8618(3) 1.1121(3) 0.3477(2) 0.0274(8) Uani 1 1 d . . . . .
H18 H 0.902872 1.145633 0.316142 0.033 Uiso 1 1 calc R U . . .
C48 C 0.3143(3) 0.5524(2) 1.1202(2) 0.0214(7) Uani 1 1 d . . . . .
C28 C 0.6322(3) 1.0778(2) 0.7840(2) 0.0207(7) Uani 1 1 d . . . . .
C41 C 0.5674(2) 0.7521(2) 0.8858(2) 0.0229(7) Uani 1 1 d . . . . .
H41 H 0.626326 0.723692 0.911622 0.028 Uiso 1 1 calc R U . . .
C27 C 0.6334(3) 1.2888(2) 0.7382(2) 0.0285(8) Uani 1 1 d . . . . .
H27A H 0.577455 1.273533 0.715727 0.043 Uiso 1 1 calc R U . . .
H27B H 0.623105 1.356068 0.737141 0.043 Uiso 1 1 calc R U . . .
H27C H 0.640344 1.264373 0.798600 0.043 Uiso 1 1 calc R U . . .
C26 C 0.7246(2) 1.2461(2) 0.6813(2) 0.0220(7) Uani 1 1 d . . . . .
C53 C 0.3181(3) 0.4778(2) 1.1797(2) 0.0272(8) Uani 1 1 d . . . . .
H53 H 0.378921 0.442785 1.198144 0.033 Uiso 1 1 calc R U . . .
C55 C 0.7458(3) 0.5335(3) 1.0962(2) 0.0292(8) Uani 1 1 d . . . . .
H55 H 0.742220 0.590095 1.063864 0.035 Uiso 1 1 calc R U . . .
C23 C 0.8952(3) 1.1755(3) 0.5736(2) 0.0276(8) Uani 1 1 d . . . . .
H23 H 0.952159 1.152436 0.535999 0.033 Uiso 1 1 calc R U . . .
C33 C 0.7085(3) 1.0457(2) 0.8385(2) 0.0274(8) Uani 1 1 d . . . . .
C29 C 0.5359(3) 1.1039(3) 0.8208(2) 0.0283(8) Uani 1 1 d . . . . .
H29 H 0.484816 1.125847 0.783252 0.034 Uiso 1 1 calc R U . . .
C13 C 0.6900(2) 0.5948(2) 0.3873(2) 0.0221(7) Uani 1 1 d . . . . .
C6 C 0.8462(3) 0.7510(3) 0.2964(3) 0.0328(8) Uani 1 1 d . . . . .
C11 C 0.7554(3) 0.4663(2) 0.4863(3) 0.0317(8) Uani 1 1 d . . . . .
H11 H 0.771588 0.401690 0.499319 0.038 Uiso 1 1 calc R U . . .
C59 C 0.6693(3) 0.4183(2) 1.1628(2) 0.0254(7) Uani 1 1 d . . . . .
H59 H 0.612816 0.396399 1.176795 0.030 Uiso 1 1 calc R U . . .
C12 C 0.7151(3) 0.5007(2) 0.4084(3) 0.0283(8) Uani 1 1 d . . . . .
H12 H 0.704331 0.458735 0.368375 0.034 Uiso 1 1 calc R U . . .
C7 C 0.8995(3) 0.6648(3) 0.3427(3) 0.0386(9) Uani 1 1 d . . . . .
H7A H 0.896902 0.675757 0.405524 0.058 Uiso 1 1 calc R U . . .
H7B H 0.967522 0.647524 0.318591 0.058 Uiso 1 1 calc R U . . .
H7C H 0.869064 0.614606 0.334325 0.058 Uiso 1 1 calc R U . . .
C10 C 0.7718(3) 0.5267(2) 0.5448(3) 0.0292(8) Uani 1 1 d . . . . .
H10 H 0.799282 0.503608 0.598290 0.035 Uiso 1 1 calc R U . . .
C24 C 0.8790(3) 1.2608(3) 0.6113(3) 0.0331(9) Uani 1 1 d . . . . .
H24 H 0.925859 1.295805 0.600453 0.040 Uiso 1 1 calc R U . . .
C63 C 0.5018(3) 0.5982(2) 0.5681(3) 0.0319(8) Uani 1 1 d . . . . .
H63A H 0.472741 0.548628 0.594317 0.038 Uiso 1 1 calc R U . . .
H63B H 0.569596 0.569224 0.545812 0.038 Uiso 1 1 calc R U . . .
C34 C 0.8137(3) 1.0159(3) 0.8058(3) 0.0427(10) Uani 1 1 d . . . . .
H34A H 0.822307 0.969136 0.761317 0.064 Uiso 1 1 calc R U . . .
H34B H 0.852724 0.989567 0.854807 0.064 Uiso 1 1 calc R U . . .
H34C H 0.834787 1.069385 0.779815 0.064 Uiso 1 1 calc R U . . .
C52 C 0.2326(3) 0.4550(3) 1.2120(2) 0.0335(9) Uani 1 1 d . . . . .
H52 H 0.235312 0.403856 1.252022 0.040 Uiso 1 1 calc R U . . .
C31 C 0.5881(3) 1.0677(3) 0.9644(2) 0.0354(9) Uani 1 1 d . . . . .
H31 H 0.573659 1.064205 1.026150 0.042 Uiso 1 1 calc R U . . .
C62 C 0.8380(3) 0.7046(3) 0.9202(3) 0.0377(9) Uani 1 1 d . . . . .
H62A H 0.859715 0.714770 0.858056 0.045 Uiso 1 1 calc R U . . .
H62B H 0.792567 0.664426 0.921582 0.045 Uiso 1 1 calc R U . . .
C50 C 0.1401(3) 0.5805(3) 1.1270(3) 0.0389(9) Uani 1 1 d . . . . .
H50 H 0.078985 0.615878 1.109400 0.047 Uiso 1 1 calc R U . . .
C49 C 0.2248(3) 0.6033(3) 1.0935(2) 0.0303(8) Uani 1 1 d . . . . .
H49 H 0.221821 0.653589 1.052472 0.036 Uiso 1 1 calc R U . . .
C4 C 0.8496(4) 0.8599(4) 0.1738(3) 0.0533(12) Uani 1 1 d . . . . .
H4 H 0.883777 0.879123 0.123051 0.064 Uiso 1 1 calc R U . . .
C60 C 0.9982(3) 0.6689(3) 0.6276(3) 0.0361(9) Uani 1 1 d . . . . .
C61 C 1.0516(6) 0.8465(6) 0.9389(4) 0.088(2) Uani 1 1 d . . . . .
H61A H 0.980028 0.870544 0.940363 0.105 Uiso 1 1 calc R U . . .
H61B H 1.069326 0.785096 0.912170 0.105 Uiso 1 1 calc R U . . .
C47 C 0.5682(2) 0.5541(2) 1.0837(2) 0.0189(7) Uani 1 1 d . . . . .
C22 C 0.8270(2) 1.1240(2) 0.5917(2) 0.0202(7) Uani 1 1 d . . . . .
H22 H 0.838597 1.064643 0.567547 0.024 Uiso 1 1 calc R U . . .
C40 C 0.5690(2) 0.8107(2) 0.8130(2) 0.0231(7) Uani 1 1 d . . . . .
H40 H 0.628643 0.822850 0.789907 0.028 Uiso 1 1 calc R U . . .
C9 C 0.7479(2) 0.6214(2) 0.5253(2) 0.0227(7) Uani 1 1 d . . . . .
H9 H 0.759095 0.662699 0.565758 0.027 Uiso 1 1 calc R U . . .
C46 C 0.4050(2) 0.5773(2) 1.0854(2) 0.0189(6) Uani 1 1 d . . . . .
C42 C 0.4806(2) 0.7342(2) 0.9218(2) 0.0165(6) Uani 1 1 d . . . . .
C2 C 0.7079(3) 0.8818(3) 0.2725(2) 0.0304(8) Uani 1 1 d . . . . .
H2 H 0.643782 0.916185 0.290376 0.037 Uiso 1 1 calc R U . . .
C19 C 0.8971(2) 1.0183(3) 0.3668(2) 0.0272(8) Uani 1 1 d . . . . .
H19 H 0.962129 0.987576 0.347592 0.033 Uiso 1 1 calc R U . . .
C45 C 0.4819(2) 0.6651(2) 0.99498(19) 0.0167(6) Uani 1 1 d . . . . .
C54 C 0.6627(2) 0.5016(2) 1.1145(2) 0.0212(7) Uani 1 1 d . . . . .
C30 C 0.5133(3) 1.0985(3) 0.9103(2) 0.0356(9) Uani 1 1 d . . . . .
H30 H 0.447618 1.115713 0.934175 0.043 Uiso 1 1 calc R U . . .
C32 C 0.6834(3) 1.0419(3) 0.9299(2) 0.0366(9) Uani 1 1 d . . . . .
H32 H 0.733587 1.020918 0.968479 0.044 Uiso 1 1 calc R U . . .
C56 C 0.8338(3) 0.4831(3) 1.1249(3) 0.0382(9) Uani 1 1 d . . . . .
H56 H 0.890290 0.505523 1.112648 0.046 Uiso 1 1 calc R U . . .
C25 C 0.7952(3) 1.2953(2) 0.6645(2) 0.0302(8) Uani 1 1 d . . . . .
H25 H 0.785467 1.353686 0.690036 0.036 Uiso 1 1 calc R U . . .
C14 C 0.6482(3) 0.6282(3) 0.3013(2) 0.0301(8) Uani 1 1 d . . . . .
H14A H 0.594496 0.683635 0.310461 0.045 Uiso 1 1 calc R U . . .
H14B H 0.624020 0.579679 0.277656 0.045 Uiso 1 1 calc R U . . .
H14C H 0.698857 0.643049 0.259817 0.045 Uiso 1 1 calc R U . . .
C58 C 0.7579(3) 0.3679(3) 1.1903(2) 0.0325(9) Uani 1 1 d . . . . .
H58 H 0.762202 0.310992 1.222135 0.039 Uiso 1 1 calc R U . . .
C3 C 0.7558(4) 0.9103(3) 0.1992(3) 0.0438(10) Uani 1 1 d . . . . .
H3 H 0.725308 0.963725 0.166122 0.053 Uiso 1 1 calc R U . . .
C51 C 0.1442(3) 0.5061(3) 1.1860(3) 0.0375(10) Uani 1 1 d . . . . .
H51 H 0.085974 0.490552 1.208493 0.045 Uiso 1 1 calc R U . . .
C5 C 0.8928(3) 0.7835(3) 0.2209(3) 0.0461(11) Uani 1 1 d . . . . .
H5 H 0.957124 0.750439 0.202218 0.055 Uiso 1 1 calc R U . . .
C57 C 0.8400(3) 0.3999(3) 1.1717(3) 0.0386(10) Uani 1 1 d . . . . .
H57 H 0.900643 0.365200 1.190743 0.046 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Ag1 2.8871(3) 2_676 ?
Pt1 Ag1 2.8870(3) . ?
Pt1 P2 2.3183(8) . ?
Pt1 P2 2.3183(8) 2_676 ?
Pt1 C37 2.001(3) . ?
Pt1 C37 2.001(3) 2_676 ?
Ag1 P1 2.4187(8) . ?
Ag1 P3 2.4217(8) 2_676 ?
P2 C15 1.811(3) . ?
P2 C35 1.833(3) . ?
P2 C36 1.839(3) . ?
S1 O3 1.434(3) . ?
S1 O1 1.443(3) . ?
S1 O2 1.449(3) . ?
S1 C60 1.789(4) . ?
Cl1 C63 1.772(4) . ?
Cl2 C63 1.755(4) . ?
Cl4 C62 1.746(4) . ?
Cl3 C62 1.728(4) . ?
Cl5 C61 1.704(7) . ?
P1 C35 1.835(3) . ?
P1 C8 1.819(3) . ?
P1 C1 1.821(3) . ?
P3 C36 1.836(3) . ?
P3 C21 1.826(3) . ?
P3 C28 1.824(3) . ?
Cl6 C61 1.742(6) . ?
C37 C38 1.212(4) . ?
C16 H16 0.9500 . ?
C16 C15 1.394(4) . ?
C16 C17 1.395(4) . ?
N3 C47 1.339(4) . ?
N3 C46 1.338(4) . ?
C15 C20 1.393(4) . ?
N2 C47 1.342(4) . ?
N2 C45 1.342(4) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
N1 C46 1.345(4) . ?
N1 C45 1.338(4) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
F3 C60 1.334(5) . ?
F2 C60 1.351(5) . ?
C38 C39 1.436(4) . ?
F1 C60 1.323(5) . ?
C8 C13 1.413(4) . ?
C8 C9 1.393(5) . ?
C21 C26 1.408(4) . ?
C21 C22 1.396(5) . ?
C20 H20 0.9500 . ?
C20 C19 1.384(5) . ?
C44 H44 0.9500 . ?
C44 C39 1.406(4) . ?
C44 C43 1.382(4) . ?
C39 C40 1.400(5) . ?
C43 H43 0.9500 . ?
C43 C42 1.402(4) . ?
C1 C6 1.392(5) . ?
C1 C2 1.426(5) . ?
C17 H17 0.9500 . ?
C17 C18 1.381(5) . ?
C18 H18 0.9500 . ?
C18 C19 1.391(5) . ?
C48 C53 1.396(5) . ?
C48 C49 1.391(5) . ?
C48 C46 1.484(5) . ?
C28 C33 1.403(5) . ?
C28 C29 1.402(5) . ?
C41 H41 0.9500 . ?
C41 C40 1.383(5) . ?
C41 C42 1.394(4) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C27 C26 1.511(5) . ?
C26 C25 1.393(5) . ?
C53 H53 0.9500 . ?
C53 C52 1.392(5) . ?
C55 H55 0.9500 . ?
C55 C54 1.392(5) . ?
C55 C56 1.384(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.386(5) . ?
C23 C22 1.391(5) . ?
C33 C34 1.498(6) . ?
C33 C32 1.413(5) . ?
C29 H29 0.9500 . ?
C29 C30 1.382(5) . ?
C13 C12 1.390(5) . ?
C13 C14 1.503(5) . ?
C6 C7 1.498(6) . ?
C6 C5 1.408(6) . ?
C11 H11 0.9500 . ?
C11 C12 1.387(5) . ?
C11 C10 1.382(5) . ?
C59 H59 0.9500 . ?
C59 C54 1.401(5) . ?
C59 C58 1.384(5) . ?
C12 H12 0.9500 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C10 H10 0.9500 . ?
C10 C9 1.394(5) . ?
C24 H24 0.9500 . ?
C24 C25 1.381(6) . ?
C63 H63A 0.9900 . ?
C63 H63B 0.9900 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C52 H52 0.9500 . ?
C52 C51 1.378(6) . ?
C31 H31 0.9500 . ?
C31 C30 1.379(6) . ?
C31 C32 1.378(6) . ?
C62 H62A 0.9900 . ?
C62 H62B 0.9900 . ?
C50 H50 0.9500 . ?
C50 C49 1.387(5) . ?
C50 C51 1.389(6) . ?
C49 H49 0.9500 . ?
C4 H4 0.9500 . ?
C4 C3 1.389(7) . ?
C4 C5 1.356(7) . ?
C61 H61A 0.9900 . ?
C61 H61B 0.9900 . ?
C47 C54 1.479(5) . ?
C22 H22 0.9500 . ?
C40 H40 0.9500 . ?
C9 H9 0.9500 . ?
C42 C45 1.481(4) . ?
C2 H2 0.9500 . ?
C2 C3 1.366(6) . ?
C19 H19 0.9500 . ?
C30 H30 0.9500 . ?
C32 H32 0.9500 . ?
C56 H56 0.9500 . ?
C56 C57 1.390(6) . ?
C25 H25 0.9500 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C58 H58 0.9500 . ?
C58 C57 1.378(6) . ?
C3 H3 0.9500 . ?
C51 H51 0.9500 . ?
C5 H5 0.9500 . ?
C57 H57 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag1 Pt1 Ag1 180.0 . 2_676 ?
P2 Pt1 Ag1 85.948(19) . 2_676 ?
P2 Pt1 Ag1 94.051(19) 2_676 2_676 ?
P2 Pt1 Ag1 94.052(19) . . ?
P2 Pt1 Ag1 85.949(19) 2_676 . ?
P2 Pt1 P2 180.0 . 2_676 ?
C37 Pt1 Ag1 99.54(8) 2_676 2_676 ?
C37 Pt1 Ag1 99.55(8) . . ?
C37 Pt1 Ag1 80.45(8) . 2_676 ?
C37 Pt1 Ag1 80.46(8) 2_676 . ?
C37 Pt1 P2 94.95(9) . 2_676 ?
C37 Pt1 P2 94.95(9) 2_676 . ?
C37 Pt1 P2 85.05(9) . . ?
C37 Pt1 P2 85.05(9) 2_676 2_676 ?
C37 Pt1 C37 180.0 2_676 . ?
P1 Ag1 Pt1 90.668(19) . . ?
P1 Ag1 P3 165.64(3) . 2_676 ?
P3 Ag1 Pt1 96.74(2) 2_676 . ?
C15 P2 Pt1 118.07(10) . . ?
C15 P2 C35 109.59(14) . . ?
C15 P2 C36 103.25(14) . . ?
C35 P2 Pt1 110.00(10) . . ?
C35 P2 C36 99.60(13) . . ?
C36 P2 Pt1 114.62(10) . . ?
O3 S1 O1 114.67(15) . . ?
O3 S1 O2 114.35(16) . . ?
O3 S1 C60 106.35(18) . . ?
O1 S1 O2 113.95(17) . . ?
O1 S1 C60 103.21(18) . . ?
O2 S1 C60 102.48(18) . . ?
C35 P1 Ag1 111.83(10) . . ?
C8 P1 Ag1 114.12(10) . . ?
C8 P1 C35 104.45(14) . . ?
C8 P1 C1 109.29(15) . . ?
C1 P1 Ag1 110.40(12) . . ?
C1 P1 C35 106.32(15) . . ?
C36 P3 Ag1 107.88(10) . 2_676 ?
C21 P3 Ag1 118.03(10) . 2_676 ?
C21 P3 C36 107.94(14) . . ?
C28 P3 Ag1 110.79(12) . 2_676 ?
C28 P3 C36 104.99(14) . . ?
C28 P3 C21 106.43(14) . . ?
C38 C37 Pt1 177.2(3) . . ?
C15 C16 H16 120.0 . . ?
C15 C16 C17 120.1(3) . . ?
C17 C16 H16 120.0 . . ?
C46 N3 C47 115.4(3) . . ?
C16 C15 P2 117.4(2) . . ?
C20 C15 P2 122.5(2) . . ?
C20 C15 C16 119.5(3) . . ?
C45 N2 C47 115.2(3) . . ?
P2 C35 P1 114.93(16) . . ?
P2 C35 H35A 108.5 . . ?
P2 C35 H35B 108.5 . . ?
P1 C35 H35A 108.5 . . ?
P1 C35 H35B 108.5 . . ?
H35A C35 H35B 107.5 . . ?
C45 N1 C46 115.1(3) . . ?
P2 C36 H36A 108.4 . . ?
P2 C36 H36B 108.4 . . ?
P3 C36 P2 115.38(16) . . ?
P3 C36 H36A 108.4 . . ?
P3 C36 H36B 108.4 . . ?
H36A C36 H36B 107.5 . . ?
C37 C38 C39 174.3(3) . . ?
C13 C8 P1 118.5(2) . . ?
C9 C8 P1 121.9(2) . . ?
C9 C8 C13 119.6(3) . . ?
C26 C21 P3 118.7(2) . . ?
C22 C21 P3 121.4(2) . . ?
C22 C21 C26 119.9(3) . . ?
C15 C20 H20 120.0 . . ?
C19 C20 C15 120.0(3) . . ?
C19 C20 H20 120.0 . . ?
C39 C44 H44 119.4 . . ?
C43 C44 H44 119.4 . . ?
C43 C44 C39 121.1(3) . . ?
C44 C39 C38 121.2(3) . . ?
C40 C39 C38 120.3(3) . . ?
C40 C39 C44 118.4(3) . . ?
C44 C43 H43 120.0 . . ?
C44 C43 C42 120.0(3) . . ?
C42 C43 H43 120.0 . . ?
C6 C1 P1 127.2(3) . . ?
C6 C1 C2 119.5(3) . . ?
C2 C1 P1 113.3(3) . . ?
C16 C17 H17 120.0 . . ?
C18 C17 C16 120.1(3) . . ?
C18 C17 H17 120.0 . . ?
C17 C18 H18 120.1 . . ?
C17 C18 C19 119.9(3) . . ?
C19 C18 H18 120.1 . . ?
C53 C48 C46 120.2(3) . . ?
C49 C48 C53 119.6(3) . . ?
C49 C48 C46 120.2(3) . . ?
C33 C28 P3 124.3(3) . . ?
C29 C28 P3 115.7(3) . . ?
C29 C28 C33 119.9(3) . . ?
C40 C41 H41 119.5 . . ?
C40 C41 C42 120.9(3) . . ?
C42 C41 H41 119.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C26 C27 H27A 109.5 . . ?
C26 C27 H27B 109.5 . . ?
C26 C27 H27C 109.5 . . ?
C21 C26 C27 122.9(3) . . ?
C25 C26 C21 118.4(3) . . ?
C25 C26 C27 118.7(3) . . ?
C48 C53 H53 120.1 . . ?
C52 C53 C48 119.9(4) . . ?
C52 C53 H53 120.1 . . ?
C54 C55 H55 119.9 . . ?
C56 C55 H55 119.9 . . ?
C56 C55 C54 120.2(3) . . ?
C24 C23 H23 120.4 . . ?
C24 C23 C22 119.1(3) . . ?
C22 C23 H23 120.4 . . ?
C28 C33 C34 124.0(3) . . ?
C28 C33 C32 117.2(4) . . ?
C32 C33 C34 118.8(3) . . ?
C28 C29 H29 119.2 . . ?
C30 C29 C28 121.7(4) . . ?
C30 C29 H29 119.2 . . ?
C8 C13 C14 122.0(3) . . ?
C12 C13 C8 118.4(3) . . ?
C12 C13 C14 119.6(3) . . ?
C1 C6 C7 124.3(3) . . ?
C1 C6 C5 117.2(4) . . ?
C5 C6 C7 118.5(4) . . ?
C12 C11 H11 120.2 . . ?
C10 C11 H11 120.2 . . ?
C10 C11 C12 119.6(3) . . ?
C54 C59 H59 119.9 . . ?
C58 C59 H59 119.9 . . ?
C58 C59 C54 120.2(4) . . ?
C13 C12 H12 119.1 . . ?
C11 C12 C13 121.8(3) . . ?
C11 C12 H12 119.1 . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C11 C10 H10 120.0 . . ?
C11 C10 C9 119.9(3) . . ?
C9 C10 H10 120.0 . . ?
C23 C24 H24 119.8 . . ?
C25 C24 C23 120.5(3) . . ?
C25 C24 H24 119.8 . . ?
Cl1 C63 H63A 109.4 . . ?
Cl1 C63 H63B 109.4 . . ?
Cl2 C63 Cl1 111.1(2) . . ?
Cl2 C63 H63A 109.4 . . ?
Cl2 C63 H63B 109.4 . . ?
H63A C63 H63B 108.0 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C53 C52 H52 119.9 . . ?
C51 C52 C53 120.3(4) . . ?
C51 C52 H52 119.9 . . ?
C30 C31 H31 119.7 . . ?
C32 C31 H31 119.7 . . ?
C32 C31 C30 120.7(3) . . ?
Cl4 C62 H62A 109.0 . . ?
Cl4 C62 H62B 109.0 . . ?
Cl3 C62 Cl4 113.1(2) . . ?
Cl3 C62 H62A 109.0 . . ?
Cl3 C62 H62B 109.0 . . ?
H62A C62 H62B 107.8 . . ?
C49 C50 H50 119.9 . . ?
C49 C50 C51 120.3(4) . . ?
C51 C50 H50 119.9 . . ?
C48 C49 H49 120.0 . . ?
C50 C49 C48 120.0(4) . . ?
C50 C49 H49 120.0 . . ?
C3 C4 H4 119.8 . . ?
C5 C4 H4 119.8 . . ?
C5 C4 C3 120.4(4) . . ?
F3 C60 S1 112.5(3) . . ?
F3 C60 F2 106.5(3) . . ?
F2 C60 S1 111.2(3) . . ?
F1 C60 S1 111.8(3) . . ?
F1 C60 F3 107.7(3) . . ?
F1 C60 F2 106.9(3) . . ?
Cl5 C61 Cl6 111.7(3) . . ?
Cl5 C61 H61A 109.3 . . ?
Cl5 C61 H61B 109.3 . . ?
Cl6 C61 H61A 109.3 . . ?
Cl6 C61 H61B 109.3 . . ?
H61A C61 H61B 107.9 . . ?
N3 C47 N2 124.6(3) . . ?
N3 C47 C54 117.7(3) . . ?
N2 C47 C54 117.7(3) . . ?
C21 C22 H22 119.6 . . ?
C23 C22 C21 120.8(3) . . ?
C23 C22 H22 119.6 . . ?
C39 C40 H40 119.8 . . ?
C41 C40 C39 120.5(3) . . ?
C41 C40 H40 119.8 . . ?
C8 C9 C10 120.7(3) . . ?
C8 C9 H9 119.7 . . ?
C10 C9 H9 119.7 . . ?
N3 C46 N1 124.7(3) . . ?
N3 C46 C48 117.6(3) . . ?
N1 C46 C48 117.8(3) . . ?
C43 C42 C45 120.9(3) . . ?
C41 C42 C43 119.1(3) . . ?
C41 C42 C45 119.9(3) . . ?
C1 C2 H2 119.4 . . ?
C3 C2 C1 121.2(4) . . ?
C3 C2 H2 119.4 . . ?
C20 C19 C18 120.4(3) . . ?
C20 C19 H19 119.8 . . ?
C18 C19 H19 119.8 . . ?
N2 C45 C42 117.1(3) . . ?
N1 C45 N2 124.8(3) . . ?
N1 C45 C42 118.1(3) . . ?
C55 C54 C59 119.1(3) . . ?
C55 C54 C47 120.9(3) . . ?
C59 C54 C47 120.0(3) . . ?
C29 C30 H30 120.6 . . ?
C31 C30 C29 118.8(4) . . ?
C31 C30 H30 120.6 . . ?
C33 C32 H32 119.1 . . ?
C31 C32 C33 121.8(4) . . ?
C31 C32 H32 119.1 . . ?
C55 C56 H56 119.9 . . ?
C55 C56 C57 120.3(4) . . ?
C57 C56 H56 119.9 . . ?
C26 C25 H25 119.3 . . ?
C24 C25 C26 121.3(3) . . ?
C24 C25 H25 119.3 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C59 C58 H58 119.8 . . ?
C57 C58 C59 120.3(3) . . ?
C57 C58 H58 119.8 . . ?
C4 C3 H3 120.5 . . ?
C2 C3 C4 119.0(4) . . ?
C2 C3 H3 120.5 . . ?
C52 C51 C50 120.0(4) . . ?
C52 C51 H51 120.0 . . ?
C50 C51 H51 120.0 . . ?
C6 C5 H5 118.6 . . ?
C4 C5 C6 122.7(4) . . ?
C4 C5 H5 118.6 . . ?
C56 C57 H57 120.1 . . ?
C58 C57 C56 119.9(4) . . ?
C58 C57 H57 120.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 P2 C15 C16 39.2(3) . . . . ?
Pt1 P2 C15 C20 -149.1(2) . . . . ?
Pt1 P2 C35 P1 49.33(18) . . . . ?
Pt1 P2 C36 P3 -52.54(18) . . . . ?
Ag1 P1 C35 P2 -43.14(18) . . . . ?
Ag1 P1 C8 C13 58.7(3) . . . . ?
Ag1 P1 C8 C9 -120.5(3) . . . . ?
Ag1 P1 C1 C6 -155.1(3) . . . . ?
Ag1 P1 C1 C2 26.8(3) . . . . ?
Ag1 P3 C36 P2 29.72(18) 2_676 . . . ?
Ag1 P3 C21 C26 66.0(3) 2_676 . . . ?
Ag1 P3 C21 C22 -111.9(2) 2_676 . . . ?
Ag1 P3 C28 C33 -177.6(2) 2_676 . . . ?
Ag1 P3 C28 C29 -0.7(3) 2_676 . . . ?
P2 C15 C20 C19 -171.5(3) . . . . ?
P1 C8 C13 C12 179.5(3) . . . . ?
P1 C8 C13 C14 1.6(4) . . . . ?
P1 C8 C9 C10 -179.9(3) . . . . ?
P1 C1 C6 C7 3.1(6) . . . . ?
P1 C1 C6 C5 -177.5(3) . . . . ?
P1 C1 C2 C3 178.2(3) . . . . ?
P3 C21 C26 C27 1.1(4) . . . . ?
P3 C21 C26 C25 -179.2(3) . . . . ?
P3 C21 C22 C23 177.3(3) . . . . ?
P3 C28 C33 C34 -3.4(5) . . . . ?
P3 C28 C33 C32 176.5(3) . . . . ?
P3 C28 C29 C30 -177.4(3) . . . . ?
C16 C15 C20 C19 0.0(5) . . . . ?
C16 C17 C18 C19 -0.4(5) . . . . ?
N3 C47 C54 C55 -169.1(3) . . . . ?
N3 C47 C54 C59 11.0(4) . . . . ?
C15 P2 C35 P1 -82.05(19) . . . . ?
C15 P2 C36 P3 77.23(19) . . . . ?
C15 C16 C17 C18 1.4(5) . . . . ?
C15 C20 C19 C18 1.0(5) . . . . ?
N2 C47 C54 C55 12.4(5) . . . . ?
N2 C47 C54 C59 -167.5(3) . . . . ?
C35 P2 C15 C16 166.2(2) . . . . ?
C35 P2 C15 C20 -22.1(3) . . . . ?
C35 P2 C36 P3 -169.87(16) . . . . ?
C35 P1 C8 C13 -178.9(2) . . . . ?
C35 P1 C8 C9 1.9(3) . . . . ?
C35 P1 C1 C6 83.4(3) . . . . ?
C35 P1 C1 C2 -94.7(3) . . . . ?
C36 P2 C15 C16 -88.4(3) . . . . ?
C36 P2 C15 C20 83.3(3) . . . . ?
C36 P2 C35 P1 170.07(16) . . . . ?
C36 P3 C21 C26 -171.5(2) . . . . ?
C36 P3 C21 C22 10.6(3) . . . . ?
C36 P3 C28 C33 66.2(3) . . . . ?
C36 P3 C28 C29 -116.9(3) . . . . ?
O3 S1 C60 F3 -56.1(3) . . . . ?
O3 S1 C60 F2 -175.5(3) . . . . ?
O3 S1 C60 F1 65.2(3) . . . . ?
O1 S1 C60 F3 -177.2(3) . . . . ?
O1 S1 C60 F2 63.5(3) . . . . ?
O1 S1 C60 F1 -55.9(3) . . . . ?
O2 S1 C60 F3 64.2(3) . . . . ?
O2 S1 C60 F2 -55.2(3) . . . . ?
O2 S1 C60 F1 -174.5(3) . . . . ?
C38 C39 C40 C41 -173.2(3) . . . . ?
C8 P1 C35 P2 -167.05(16) . . . . ?
C8 P1 C1 C6 -28.8(4) . . . . ?
C8 P1 C1 C2 153.1(3) . . . . ?
C8 C13 C12 C11 1.0(5) . . . . ?
C21 P3 C36 P2 -98.85(18) . . . . ?
C21 P3 C28 C33 -48.1(3) . . . . ?
C21 P3 C28 C29 128.8(3) . . . . ?
C21 C26 C25 C24 1.8(5) . . . . ?
C44 C39 C40 C41 3.1(5) . . . . ?
C44 C43 C42 C41 2.5(5) . . . . ?
C44 C43 C42 C45 -174.2(3) . . . . ?
C39 C44 C43 C42 -0.3(5) . . . . ?
C43 C44 C39 C38 173.8(3) . . . . ?
C43 C44 C39 C40 -2.5(5) . . . . ?
C43 C42 C45 N2 177.3(3) . . . . ?
C43 C42 C45 N1 -0.2(4) . . . . ?
C1 P1 C35 P2 77.4(2) . . . . ?
C1 P1 C8 C13 -65.4(3) . . . . ?
C1 P1 C8 C9 115.4(3) . . . . ?
C1 C6 C5 C4 -0.6(7) . . . . ?
C1 C2 C3 C4 -0.3(6) . . . . ?
C17 C16 C15 P2 170.7(2) . . . . ?
C17 C16 C15 C20 -1.3(5) . . . . ?
C17 C18 C19 C20 -0.9(5) . . . . ?
C48 C53 C52 C51 -0.6(5) . . . . ?
C28 P3 C36 P2 147.92(17) . . . . ?
C28 P3 C21 C26 -59.2(3) . . . . ?
C28 P3 C21 C22 122.9(3) . . . . ?
C28 C33 C32 C31 0.5(5) . . . . ?
C28 C29 C30 C31 0.8(5) . . . . ?
C41 C42 C45 N2 0.7(4) . . . . ?
C41 C42 C45 N1 -176.8(3) . . . . ?
C27 C26 C25 C24 -178.5(3) . . . . ?
C26 C21 C22 C23 -0.6(5) . . . . ?
C53 C48 C49 C50 0.8(5) . . . . ?
C53 C48 C46 N3 -2.4(4) . . . . ?
C53 C48 C46 N1 176.7(3) . . . . ?
C53 C52 C51 C50 0.4(6) . . . . ?
C55 C56 C57 C58 -0.7(6) . . . . ?
C23 C24 C25 C26 -0.4(6) . . . . ?
C33 C28 C29 C30 -0.3(5) . . . . ?
C29 C28 C33 C34 179.8(4) . . . . ?
C29 C28 C33 C32 -0.3(5) . . . . ?
C13 C8 C9 C10 0.9(5) . . . . ?
C6 C1 C2 C3 -0.1(6) . . . . ?
C11 C10 C9 C8 -0.2(5) . . . . ?
C59 C58 C57 C56 -0.1(6) . . . . ?
C12 C11 C10 C9 -0.1(6) . . . . ?
C7 C6 C5 C4 178.8(4) . . . . ?
C10 C11 C12 C13 -0.3(6) . . . . ?
C24 C23 C22 C21 1.9(5) . . . . ?
C34 C33 C32 C31 -179.6(4) . . . . ?
C49 C48 C53 C52 -0.1(5) . . . . ?
C49 C48 C46 N3 177.7(3) . . . . ?
C49 C48 C46 N1 -3.2(4) . . . . ?
C49 C50 C51 C52 0.3(6) . . . . ?
C47 N3 C46 N1 2.3(4) . . . . ?
C47 N3 C46 C48 -178.7(3) . . . . ?
C47 N2 C45 N1 4.3(4) . . . . ?
C47 N2 C45 C42 -173.0(3) . . . . ?
C22 C21 C26 C27 179.0(3) . . . . ?
C22 C21 C26 C25 -1.2(5) . . . . ?
C22 C23 C24 C25 -1.4(6) . . . . ?
C40 C41 C42 C43 -1.9(5) . . . . ?
C40 C41 C42 C45 174.8(3) . . . . ?
C9 C8 C13 C12 -1.3(5) . . . . ?
C9 C8 C13 C14 -179.1(3) . . . . ?
C46 N3 C47 N2 -1.3(4) . . . . ?
C46 N3 C47 C54 -179.6(3) . . . . ?
C46 N1 C45 N2 -3.4(4) . . . . ?
C46 N1 C45 C42 173.9(3) . . . . ?
C46 C48 C53 C52 -179.9(3) . . . . ?
C46 C48 C49 C50 -179.3(3) . . . . ?
C42 C41 C40 C39 -1.0(5) . . . . ?
C2 C1 C6 C7 -178.8(4) . . . . ?
C2 C1 C6 C5 0.5(5) . . . . ?
C45 N2 C47 N3 -1.8(4) . . . . ?
C45 N2 C47 C54 176.6(3) . . . . ?
C45 N1 C46 N3 -0.1(4) . . . . ?
C45 N1 C46 C48 -179.1(3) . . . . ?
C54 C55 C56 C57 0.5(6) . . . . ?
C54 C59 C58 C57 1.1(5) . . . . ?
C30 C31 C32 C33 -0.1(6) . . . . ?
C32 C31 C30 C29 -0.6(6) . . . . ?
C56 C55 C54 C59 0.4(5) . . . . ?
C56 C55 C54 C47 -179.5(3) . . . . ?
C14 C13 C12 C11 178.9(3) . . . . ?
C58 C59 C54 C55 -1.3(5) . . . . ?
C58 C59 C54 C47 178.7(3) . . . . ?
C3 C4 C5 C6 0.3(8) . . . . ?
C51 C50 C49 C48 -1.0(6) . . . . ?
C5 C4 C3 C2 0.2(7) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_z_CCDC1
_database_code_depnum_ccdc_archive 'CCDC 2055678'
loop_
_audit_author_name
_audit_author_address
'Liang-Jin Xu'
;Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2021-01-13 deposited with the CCDC.	2021-03-26 downloaded from the CCDC.
;
_audit_creation_date             2020-12-29
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'C104 H92 Ag2 N4 O2 P6 Pt, 2(Cl O4), 3(C H Cl3), (H2 O)'
_chemical_formula_sum            'C107 H97 Ag2 Cl11 N4 O11 P6 Pt'
_chemical_formula_weight         2599.46
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   15.2948(17)
_cell_length_b                   18.341(2)
_cell_length_c                   22.261(3)
_cell_angle_alpha                72.206(4)
_cell_angle_beta                 73.763(4)
_cell_angle_gamma                72.834(4)
_cell_volume                     5556.7(11)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9801
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      25.36
_cell_measurement_theta_min      2.36
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.014
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.5781
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.554
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2604
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0509
_diffrn_reflns_av_unetI/netI     0.0711
_diffrn_reflns_Laue_measured_fraction_full 0.979
_diffrn_reflns_Laue_measured_fraction_max 0.972
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            45511
_diffrn_reflns_point_group_measured_fraction_full 0.979
_diffrn_reflns_point_group_measured_fraction_max 0.972
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.434
_diffrn_reflns_theta_min         2.657
_diffrn_ambient_temperature      149.99
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                15423
_reflns_number_total             19971
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.783
_refine_diff_density_min         -1.385
_refine_diff_density_rms         0.140
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1275
_refine_ls_number_reflns         19971
_refine_ls_number_restraints     171
_refine_ls_R_factor_all          0.0793
_refine_ls_R_factor_gt           0.0582
_refine_ls_restrained_S_all      1.054
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0671P)²+26.7548P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1457
_refine_ls_wR_factor_ref         0.1597
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C79-C80 = C80-C81 = C81-C82 = C82-C83 = C83-C84 = C84-C79
 1.385 with sigma of 0.01
3. Restrained planarity
 C79, C80, C81, C82, C83, C84
 with sigma of 0.01
4. Rigid bond restraints
 C8, C9, C10, C11, C12, C13, C14
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 C78, C79, C80, C81, C82, C83, C84
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
5. Uiso/Uaniso restraints and constraints
C8 \\sim C9 \\sim C10 \\sim C11 \\sim C12 \\sim C13 \\sim C14: within 2A with
sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C78 \\sim C79 \\sim C80 \\sim C81 \\sim C82 \\sim C83 \\sim C84: within 2A with
sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
Uanis(C8) \\sim Ueq, Uanis(C9) \\sim Ueq, Uanis(C10) \\sim Ueq, Uanis(C11)
\\sim Ueq, Uanis(C12) \\sim Ueq, Uanis(C13) \\sim Ueq, Uanis(C14) \\sim Ueq:
with sigma of 0.1 and sigma for terminal atoms of 0.2
Uanis(O11) \\sim Ueq: with sigma of 0.04 and sigma for terminal atoms of 0.08
6.a Ternary CH refined with riding coordinates:
 C105(H105), C106(H106), C107(H107)
6.b Secondary CH2 refined with riding coordinates:
 C101(H10A,H10B), C102(H10C,H10D), C103(H10E,H10F), C104(H10G,H10H)
6.c Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C9(H9), C12(H12), C11(H11), C10(H10),
 C16(H16), C17(H17), C18(H18), C19(H19), C20(H20), C22(H22), C23(H23), C24(H24),
  C25(H25), C29(H29), C30(H30), C31(H31), C32(H32), C36(H36), C37(H37),
 C38(H38), C39(H39), C43(H43), C44(H44), C45(H45), C46(H46), C50(H50), C51(H51),
  C52(H52), C53(H53), C54(H54), C56(H56), C57(H57), C58(H58), C59(H59),
 C63(H63), C64(H64), C65(H65), C66(H66), C72(H72), C73(H73), C75(H75), C76(H76),
  C80(H80), C81(H81), C82(H82), C83(H83), C84(H84), C88(H88), C89(H89),
 C91(H91), C92(H92), C96(H96), C97(H97), C98(H98), C99(H99), C100(H100)
6.d Fitted hexagon refined as free rotating group:
 C9(C8,C13,C12,C11,C10)
6.e Idealised Me refined as rotating group:
 C7(H7A,H7B,H7C), C14(H14A,H14B,H14C), C27(H27A,H27B,H27C), C34(H34A,H34B,
 H34C), C41(H41A,H41B,H41C), C48(H48A,H48B,H48C), C61(H61A,H61B,H61C), C68(H68A,
 H68B,H68C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 1.62460(2) 0.32242(2) 0.72316(2) 0.02746(9) Uani 1 1 d . . . . .
Ag1 Ag 1.49955(4) 0.45545(3) 0.77589(3) 0.03245(14) Uani 1 1 d . . . . .
P1 P 1.39600(13) 0.38019(11) 0.85844(9) 0.0293(4) Uani 1 1 d . . . . .
O1 O 1.8960(4) 0.3713(3) 1.0408(2) 0.0428(13) Uani 1 1 d . . . . .
N1 N 1.5233(14) 0.0528(8) 0.3775(6) 0.144(7) Uani 1 1 d . . . . .
C1 C 1.9814(5) 0.2009(5) 0.7349(4) 0.0391(18) Uani 1 1 d . . . . .
Ag2 Ag 1.76677(4) 0.17897(3) 0.73171(3) 0.03678(14) Uani 1 1 d . . . . .
P2 P 1.50402(12) 0.25966(11) 0.77825(8) 0.0271(4) Uani 1 1 d . . . . .
O2 O 1.6284(7) 0.1213(4) 0.3686(4) 0.087(3) Uani 1 1 d . . . . .
N2 N 1.5114(13) 0.0733(7) 0.4336(6) 0.140(6) Uani 1 1 d . . . . .
C2 C 1.9948(5) 0.2397(5) 0.7747(4) 0.0418(19) Uani 1 1 d . . . . .
H2 H 1.962696 0.293062 0.772359 0.050 Uiso 1 1 calc R U . . .
P3 P 1.65639(13) 0.10837(11) 0.80942(9) 0.0305(4) Uani 1 1 d . . . . .
N3 N 1.7868(5) 0.3203(5) 1.1170(3) 0.0515(19) Uani 1 1 d . . . . .
C3 C 2.0534(6) 0.2033(6) 0.8176(4) 0.051(2) Uani 1 1 d . . . . .
H3 H 2.060434 0.230736 0.845223 0.062 Uiso 1 1 calc R U . . .
P4 P 1.89377(13) 0.24435(12) 0.68518(9) 0.0335(4) Uani 1 1 d . . . . .
N4 N 1.8529(5) 0.3288(5) 1.1462(3) 0.0514(19) Uani 1 1 d . . . . .
C4 C 2.1014(7) 0.1266(6) 0.8197(5) 0.064(3) Uani 1 1 d . . . . .
H4 H 2.144430 0.101743 0.847519 0.077 Uiso 1 1 calc R U . . .
P5 P 1.73798(12) 0.39516(11) 0.66853(8) 0.0284(4) Uani 1 1 d . . . . .
C5 C 2.0881(8) 0.0861(6) 0.7825(6) 0.071(3) Uani 1 1 d . . . . .
H5 H 2.119381 0.032235 0.786806 0.085 Uiso 1 1 calc R U . . .
P6 P 1.59245(13) 0.54393(11) 0.70029(9) 0.0288(4) Uani 1 1 d . . . . .
C6 C 2.0294(6) 0.1214(6) 0.7375(5) 0.055(2) Uani 1 1 d . . . . .
C7 C 2.0162(9) 0.0736(7) 0.6985(7) 0.093(5) Uani 1 1 d . . . . .
H7A H 1.949598 0.074948 0.706067 0.139 Uiso 1 1 calc R U . . .
H7B H 2.051092 0.019144 0.711283 0.139 Uiso 1 1 calc R U . . .
H7C H 2.039424 0.095480 0.652663 0.139 Uiso 1 1 calc R U . . .
C9 C 1.9030(5) 0.2313(5) 0.5648(4) 0.095(3) Uani 1 1 d G U . . .
H9 H 1.850038 0.209433 0.586276 0.114 Uiso 1 1 calc R U . . .
C8 C 1.9490(6) 0.2534(5) 0.5997(3) 0.066(2) Uani 1 1 d G U . . .
C13 C 2.0265(6) 0.2854(5) 0.5683(4) 0.095(3) Uani 1 1 d G U . . .
C12 C 2.0579(6) 0.2952(6) 0.5021(4) 0.114(4) Uani 1 1 d G U . . .
H12 H 2.110873 0.317006 0.480635 0.137 Uiso 1 1 calc R U . . .
C11 C 2.0119(7) 0.2730(6) 0.4672(3) 0.129(4) Uani 1 1 d G U . . .
H11 H 2.033351 0.279726 0.421893 0.155 Uiso 1 1 calc R U . . .
C10 C 1.9344(7) 0.2411(6) 0.4986(4) 0.120(4) Uani 1 1 d G U . . .
H10 H 1.902933 0.225940 0.474712 0.145 Uiso 1 1 calc R U . . .
C14 C 2.0776(12) 0.3022(9) 0.5980(8) 0.114(4) Uani 1 1 d . U . . .
H14A H 2.113056 0.253463 0.621843 0.171 Uiso 1 1 calc R U . . .
H14B H 2.037041 0.333661 0.628199 0.171 Uiso 1 1 calc R U . . .
H14C H 2.121077 0.332317 0.566342 0.171 Uiso 1 1 calc R U . . .
C15 C 1.7701(5) 0.4237(4) 0.5812(3) 0.0328(16) Uani 1 1 d . . . . .
C16 C 1.7224(6) 0.4100(5) 0.5426(4) 0.0422(19) Uani 1 1 d . . . . .
H16 H 1.669239 0.387763 0.561280 0.051 Uiso 1 1 calc R U . . .
C17 C 1.7538(6) 0.4293(6) 0.4760(4) 0.051(2) Uani 1 1 d . . . . .
H17 H 1.721445 0.419929 0.449357 0.061 Uiso 1 1 calc R U . . .
C18 C 1.8300(6) 0.4613(5) 0.4478(4) 0.048(2) Uani 1 1 d . . . . .
H18 H 1.850833 0.472779 0.402238 0.058 Uiso 1 1 calc R U . . .
C19 C 1.8765(6) 0.4771(6) 0.4857(4) 0.049(2) Uani 1 1 d . . . . .
H19 H 1.928539 0.500616 0.466334 0.058 Uiso 1 1 calc R U . . .
C20 C 1.8462(6) 0.4581(5) 0.5529(4) 0.0423(19) Uani 1 1 d . . . . .
H20 H 1.877930 0.468681 0.579205 0.051 Uiso 1 1 calc R U . . .
C21 C 1.5701(5) 0.5778(5) 0.6189(3) 0.0355(17) Uani 1 1 d . . . . .
C22 C 1.5038(6) 0.5445(5) 0.6098(4) 0.0440(19) Uani 1 1 d . . . . .
H22 H 1.472786 0.510468 0.645304 0.053 Uiso 1 1 calc R U . . .
C23 C 1.4838(6) 0.5615(6) 0.5494(4) 0.052(2) Uani 1 1 d . . . . .
H23 H 1.439012 0.539276 0.543315 0.063 Uiso 1 1 calc R U . . .
C24 C 1.5289(7) 0.6102(6) 0.4986(4) 0.055(2) Uani 1 1 d . . . . .
H24 H 1.515415 0.621503 0.457145 0.066 Uiso 1 1 calc R U . . .
C25 C 1.5932(7) 0.6432(5) 0.5065(4) 0.052(2) Uani 1 1 d . . . . .
H25 H 1.623024 0.677090 0.470190 0.063 Uiso 1 1 calc R U . . .
C26 C 1.6166(6) 0.6283(5) 0.5670(4) 0.0434(19) Uani 1 1 d . . . . .
C27 C 1.6857(8) 0.6670(6) 0.5720(5) 0.064(3) Uani 1 1 d . . . . .
H27A H 1.657863 0.696493 0.605410 0.096 Uiso 1 1 calc R U . . .
H27B H 1.703740 0.703202 0.530477 0.096 Uiso 1 1 calc R U . . .
H27C H 1.741157 0.627075 0.583303 0.096 Uiso 1 1 calc R U . . .
C28 C 1.5919(5) 0.6282(4) 0.7276(3) 0.0322(16) Uani 1 1 d . . . . .
C29 C 1.6717(6) 0.6390(5) 0.7376(4) 0.0393(18) Uani 1 1 d . . . . .
H29 H 1.729111 0.601858 0.729278 0.047 Uiso 1 1 calc R U . . .
C30 C 1.6710(7) 0.7020(5) 0.7593(4) 0.048(2) Uani 1 1 d . . . . .
H30 H 1.727579 0.708544 0.764575 0.058 Uiso 1 1 calc R U . . .
C31 C 1.5886(7) 0.7553(5) 0.7732(4) 0.051(2) Uani 1 1 d . . . . .
H31 H 1.587275 0.799056 0.788022 0.061 Uiso 1 1 calc R U . . .
C32 C 1.5074(6) 0.7440(5) 0.7652(4) 0.049(2) Uani 1 1 d . . . . .
H32 H 1.450199 0.780393 0.775687 0.059 Uiso 1 1 calc R U . . .
C33 C 1.5054(6) 0.6821(5) 0.7425(4) 0.0406(18) Uani 1 1 d . . . . .
C34 C 1.4148(6) 0.6759(5) 0.7323(5) 0.051(2) Uani 1 1 d . . . . .
H34A H 1.362103 0.705096 0.758962 0.076 Uiso 1 1 calc R U . . .
H34B H 1.411808 0.620463 0.744574 0.076 Uiso 1 1 calc R U . . .
H34C H 1.411523 0.698044 0.686766 0.076 Uiso 1 1 calc R U . . .
C35 C 1.2732(5) 0.3948(5) 0.8565(3) 0.0345(16) Uani 1 1 d . . . . .
C36 C 1.2233(5) 0.3412(5) 0.8993(4) 0.0334(16) Uani 1 1 d . . . . .
H36 H 1.252773 0.299837 0.930123 0.040 Uiso 1 1 calc R U . . .
C37 C 1.1305(6) 0.3462(5) 0.8983(4) 0.047(2) Uani 1 1 d . . . . .
H37 H 1.097032 0.309497 0.928439 0.056 Uiso 1 1 calc R U . . .
C38 C 1.0889(6) 0.4054(6) 0.8527(4) 0.050(2) Uani 1 1 d . . . . .
H38 H 1.026647 0.408649 0.850445 0.059 Uiso 1 1 calc R U . . .
C39 C 1.1368(6) 0.4599(6) 0.8103(4) 0.053(2) Uani 1 1 d . . . . .
H39 H 1.106607 0.500612 0.779479 0.063 Uiso 1 1 calc R U . . .
C40 C 1.2286(5) 0.4569(5) 0.8113(4) 0.0412(18) Uani 1 1 d . . . . .
C41 C 1.2727(6) 0.5210(5) 0.7637(4) 0.050(2) Uani 1 1 d . . . . .
H41A H 1.282775 0.554488 0.786911 0.075 Uiso 1 1 calc R U . . .
H41B H 1.231254 0.552908 0.734024 0.075 Uiso 1 1 calc R U . . .
H41C H 1.332905 0.497412 0.739221 0.075 Uiso 1 1 calc R U . . .
C42 C 1.3973(5) 0.3813(4) 0.9405(3) 0.0317(16) Uani 1 1 d . . . . .
C43 C 1.3942(5) 0.3129(5) 0.9906(4) 0.0372(17) Uani 1 1 d . . . . .
H43 H 1.388590 0.267014 0.982036 0.045 Uiso 1 1 calc R U . . .
C44 C 1.3992(6) 0.3111(5) 1.0516(4) 0.0418(19) Uani 1 1 d . . . . .
H44 H 1.397793 0.264050 1.084822 0.050 Uiso 1 1 calc R U . . .
C45 C 1.4062(6) 0.3780(5) 1.0646(4) 0.0426(19) Uani 1 1 d . . . . .
H45 H 1.409495 0.377058 1.106837 0.051 Uiso 1 1 calc R U . . .
C46 C 1.4084(5) 0.4461(5) 1.0163(4) 0.0396(18) Uani 1 1 d . . . . .
H46 H 1.412147 0.491839 1.026089 0.048 Uiso 1 1 calc R U . . .
C47 C 1.4052(5) 0.4496(5) 0.9531(4) 0.0377(17) Uani 1 1 d . . . . .
C48 C 1.4141(7) 0.5245(5) 0.9018(4) 0.047(2) Uani 1 1 d . . . . .
H48A H 1.469982 0.513875 0.868289 0.071 Uiso 1 1 calc R U . . .
H48B H 1.419531 0.563871 0.921258 0.071 Uiso 1 1 calc R U . . .
H48C H 1.358585 0.544530 0.882685 0.071 Uiso 1 1 calc R U . . .
C49 C 1.4056(5) 0.2908(4) 0.7384(3) 0.0315(16) Uani 1 1 d . . . . .
C50 C 1.3993(5) 0.3574(5) 0.6874(3) 0.0368(17) Uani 1 1 d . . . . .
H50 H 1.448851 0.384090 0.671299 0.044 Uiso 1 1 calc R U . . .
C51 C 1.3209(6) 0.3851(5) 0.6597(4) 0.045(2) Uani 1 1 d . . . . .
H51 H 1.316439 0.430673 0.624961 0.054 Uiso 1 1 calc R U . . .
C52 C 1.2493(6) 0.3453(6) 0.6836(4) 0.056(2) Uani 1 1 d . . . . .
H52 H 1.195113 0.363663 0.665460 0.067 Uiso 1 1 calc R U . . .
C53 C 1.2569(7) 0.2794(7) 0.7334(5) 0.068(3) Uani 1 1 d . . . . .
H53 H 1.208098 0.251942 0.748771 0.082 Uiso 1 1 calc R U . . .
C54 C 1.3335(6) 0.2520(6) 0.7617(4) 0.052(2) Uani 1 1 d . . . . .
H54 H 1.336712 0.206820 0.796925 0.062 Uiso 1 1 calc R U . . .
C55 C 1.6841(5) 0.0042(4) 0.8110(3) 0.0315(15) Uani 1 1 d . . . . .
C56 C 1.6956(5) -0.0514(4) 0.8682(4) 0.0366(17) Uani 1 1 d . . . . .
H56 H 1.681795 -0.034724 0.906908 0.044 Uiso 1 1 calc R U . . .
C57 C 1.7271(6) -0.1310(5) 0.8700(4) 0.0437(19) Uani 1 1 d . . . . .
H57 H 1.735222 -0.168472 0.909543 0.052 Uiso 1 1 calc R U . . .
C58 C 1.7462(7) -0.1549(5) 0.8141(4) 0.052(2) Uani 1 1 d . . . . .
H58 H 1.768131 -0.209307 0.815046 0.063 Uiso 1 1 calc R U . . .
C59 C 1.7340(7) -0.1010(5) 0.7564(4) 0.053(2) Uani 1 1 d . . . . .
H59 H 1.745563 -0.119073 0.718604 0.063 Uiso 1 1 calc R U . . .
C60 C 1.7052(6) -0.0210(5) 0.7528(4) 0.0425(19) Uani 1 1 d . . . . .
C61 C 1.6954(9) 0.0356(6) 0.6881(4) 0.070(3) Uani 1 1 d . . . . .
H61A H 1.631357 0.045751 0.682316 0.105 Uiso 1 1 calc R U . . .
H61B H 1.739366 0.012570 0.653646 0.105 Uiso 1 1 calc R U . . .
H61C H 1.709282 0.085146 0.686441 0.105 Uiso 1 1 calc R U . . .
C62 C 1.6371(5) 0.1123(4) 0.8933(4) 0.0332(16) Uani 1 1 d . . . . .
C63 C 1.5537(5) 0.0980(4) 0.9348(3) 0.0355(17) Uani 1 1 d . . . . .
H63 H 1.510230 0.084361 0.919244 0.043 Uiso 1 1 calc R U . . .
C64 C 1.5331(6) 0.1031(5) 0.9979(4) 0.045(2) Uani 1 1 d . . . . .
H64 H 1.476110 0.092752 1.025759 0.054 Uiso 1 1 calc R U . . .
C65 C 1.5958(7) 0.1234(5) 1.0204(4) 0.050(2) Uani 1 1 d . . . . .
H65 H 1.581054 0.129422 1.063291 0.060 Uiso 1 1 calc R U . . .
C66 C 1.6797(7) 0.1349(5) 0.9806(4) 0.050(2) Uani 1 1 d . . . . .
H66 H 1.723187 0.146652 0.997406 0.060 Uiso 1 1 calc R U . . .
C67 C 1.7036(6) 0.1299(4) 0.9168(4) 0.0369(17) Uani 1 1 d . . . . .
C68 C 1.7974(6) 0.1408(6) 0.8775(4) 0.051(2) Uani 1 1 d . . . . .
H68A H 1.824426 0.100970 0.852422 0.077 Uiso 1 1 calc R U . . .
H68B H 1.838516 0.135343 0.906172 0.077 Uiso 1 1 calc R U . . .
H68C H 1.790776 0.193383 0.848186 0.077 Uiso 1 1 calc R U . . .
C69 C 1.6192(5) 0.2816(5) 0.6516(3) 0.0347(17) Uani 1 1 d . . . . .
C70 C 1.6117(6) 0.2482(5) 0.6143(4) 0.0394(18) Uani 1 1 d . . . . .
C71 C 1.6011(6) 0.2134(5) 0.5669(4) 0.0438(19) Uani 1 1 d . . . . .
C72 C 1.5333(9) 0.1703(6) 0.5831(5) 0.069(3) Uani 1 1 d . . . . .
H72 H 1.494563 0.162921 0.625056 0.083 Uiso 1 1 calc R U . . .
C73 C 1.5227(9) 0.1373(6) 0.5363(6) 0.078(4) Uani 1 1 d . . . . .
H73 H 1.477837 0.106566 0.546830 0.094 Uiso 1 1 calc R U . . .
C74 C 1.5790(9) 0.1508(6) 0.4748(5) 0.068(3) Uani 1 1 d . . . . .
C75 C 1.6413(8) 0.1946(7) 0.4595(5) 0.071(3) Uani 1 1 d . . . . .
H75 H 1.677113 0.204876 0.416690 0.085 Uiso 1 1 calc R U . . .
C76 C 1.6545(7) 0.2250(6) 0.5046(5) 0.060(3) Uani 1 1 d . . . . .
H76 H 1.700949 0.254511 0.492967 0.072 Uiso 1 1 calc R U . . .
C77 C 1.5672(10) 0.1128(7) 0.4272(6) 0.079(3) Uani 1 1 d . . . . .
C78 C 1.5967(16) 0.0796(8) 0.3402(8) 0.125(4) Uani 1 1 d . U . . .
C79 C 1.6528(11) 0.0746(6) 0.2716(7) 0.127(4) Uani 1 1 d D U . . .
C80 C 1.6239(10) 0.0308(6) 0.2426(6) 0.144(4) Uani 1 1 d D U . . .
H80 H 1.577084 0.002399 0.266013 0.173 Uiso 1 1 calc R U . . .
C81 C 1.6649(11) 0.0297(8) 0.1788(6) 0.147(5) Uani 1 1 d D U . . .
H81 H 1.646718 0.000432 0.157639 0.177 Uiso 1 1 calc R U . . .
C82 C 1.7331(12) 0.0720(7) 0.1465(8) 0.154(5) Uani 1 1 d D U . . .
H82 H 1.761155 0.070985 0.102890 0.185 Uiso 1 1 calc R U . . .
C83 C 1.7621(11) 0.1158(8) 0.1750(6) 0.145(4) Uani 1 1 d D U . . .
H83 H 1.808834 0.144212 0.151301 0.174 Uiso 1 1 calc R U . . .
C84 C 1.7214(11) 0.1173(8) 0.2391(6) 0.137(4) Uani 1 1 d D U . . .
H84 H 1.739829 0.146620 0.260076 0.164 Uiso 1 1 calc R U . . .
C85 C 1.6403(5) 0.3447(4) 0.8026(3) 0.0312(16) Uani 1 1 d . . . . .
C86 C 1.6624(5) 0.3504(4) 0.8494(3) 0.0316(16) Uani 1 1 d . . . . .
C87 C 1.6970(5) 0.3538(4) 0.9014(3) 0.0323(16) Uani 1 1 d . . . . .
C88 C 1.6563(5) 0.3232(4) 0.9654(3) 0.0346(16) Uani 1 1 d . . . . .
H88 H 1.602159 0.303217 0.974444 0.042 Uiso 1 1 calc R U . . .
C89 C 1.6935(5) 0.3216(5) 1.0155(3) 0.0362(17) Uani 1 1 d . . . . .
H89 H 1.664620 0.301065 1.058736 0.043 Uiso 1 1 calc R U . . .
C90 C 1.7739(6) 0.3503(5) 1.0029(4) 0.0393(18) Uani 1 1 d . . . . .
C91 C 1.8134(6) 0.3825(5) 0.9398(4) 0.045(2) Uani 1 1 d . . . . .
H91 H 1.866857 0.403334 0.931186 0.054 Uiso 1 1 calc R U . . .
C92 C 1.7758(6) 0.3847(5) 0.8887(4) 0.0421(19) Uani 1 1 d . . . . .
H92 H 1.803436 0.407027 0.845584 0.051 Uiso 1 1 calc R U . . .
C93 C 1.8159(6) 0.3456(5) 1.0561(4) 0.0411(18) Uani 1 1 d . . . . .
C94 C 1.9150(6) 0.3578(5) 1.1005(4) 0.046(2) Uani 1 1 d . . . . .
C95 C 1.9990(6) 0.3774(6) 1.1040(4) 0.047(2) Uani 1 1 d . . . . .
C96 C 2.0154(7) 0.3681(6) 1.1645(5) 0.057(2) Uani 1 1 d . . . . .
H96 H 1.972702 0.349384 1.202346 0.068 Uiso 1 1 calc R U . . .
C97 C 2.0949(7) 0.3863(6) 1.1692(5) 0.062(3) Uani 1 1 d . . . . .
H97 H 2.106929 0.379781 1.210376 0.075 Uiso 1 1 calc R U . . .
C98 C 2.1560(7) 0.4137(6) 1.1144(6) 0.069(3) Uani 1 1 d . . . . .
H98 H 2.209571 0.427072 1.117838 0.083 Uiso 1 1 calc R U . . .
C99 C 2.1400(7) 0.4222(8) 1.0537(5) 0.073(3) Uani 1 1 d . . . . .
H99 H 2.183378 0.440037 1.015948 0.088 Uiso 1 1 calc R U . . .
C100 C 2.0611(7) 0.4045(7) 1.0486(5) 0.060(3) Uani 1 1 d . . . . .
H100 H 2.049394 0.410944 1.007383 0.072 Uiso 1 1 calc R U . . .
C101 C 1.4500(5) 0.2761(4) 0.8584(3) 0.0319(16) Uani 1 1 d . . . . .
H10A H 1.498106 0.256316 0.885042 0.038 Uiso 1 1 calc R U . . .
H10B H 1.401462 0.245248 0.878764 0.038 Uiso 1 1 calc R U . . .
C102 C 1.5405(5) 0.1530(4) 0.7882(3) 0.0293(15) Uani 1 1 d . . . . .
H10C H 1.541655 0.141003 0.747479 0.035 Uiso 1 1 calc R U . . .
H10D H 1.493226 0.128379 0.822328 0.035 Uiso 1 1 calc R U . . .
C103 C 1.7140(5) 0.4876(4) 0.6936(3) 0.0323(16) Uani 1 1 d . . . . .
H10E H 1.731244 0.474802 0.735961 0.039 Uiso 1 1 calc R U . . .
H10F H 1.754742 0.521253 0.662131 0.039 Uiso 1 1 calc R U . . .
C104 C 1.8469(5) 0.3448(4) 0.6963(4) 0.0323(16) Uani 1 1 d . . . . .
H10G H 1.836229 0.342756 0.742642 0.039 Uiso 1 1 calc R U . . .
H10H H 1.894460 0.376016 0.672714 0.039 Uiso 1 1 calc R U . . .
Cl1 Cl 0.95406(13) 0.51553(13) 0.68950(9) 0.0416(5) Uani 1 1 d . . . . .
O3 O 1.0105(6) 0.4496(5) 0.6652(4) 0.088(3) Uani 1 1 d . . . . .
O4 O 1.0110(5) 0.5615(4) 0.6941(3) 0.0607(18) Uani 1 1 d . . . . .
O5 O 0.8943(4) 0.4901(4) 0.7503(3) 0.0594(17) Uani 1 1 d . . . . .
O6 O 0.8980(5) 0.5602(6) 0.6431(4) 0.093(3) Uani 1 1 d . . . . .
Cl2 Cl 0.28261(14) 0.11193(12) 0.94393(9) 0.0405(4) Uani 1 1 d . . . . .
O7 O 0.3598(5) 0.0849(4) 0.8948(3) 0.0620(18) Uani 1 1 d . . . . .
O8 O 0.2072(5) 0.1620(4) 0.9143(3) 0.0618(18) Uani 1 1 d . . . . .
O9 O 0.3146(4) 0.1551(4) 0.9746(3) 0.0512(15) Uani 1 1 d . . . . .
O10 O 0.2530(4) 0.0466(3) 0.9908(3) 0.0548(16) Uani 1 1 d . . . . .
Cl3 Cl 1.9955(4) -0.0306(3) 0.9203(4) 0.239(4) Uani 1 1 d . . . . .
Cl4 Cl 2.0581(2) -0.1775(2) 1.00532(18) 0.0984(10) Uani 1 1 d . . . . .
Cl5 Cl 1.9540(4) -0.1695(5) 0.9175(3) 0.202(3) Uani 1 1 d . . . . .
C105 C 1.9703(9) -0.1162(7) 0.9632(6) 0.085(4) Uani 1 1 d . . . . .
H105 H 1.910972 -0.105203 0.995646 0.102 Uiso 1 1 calc R U . . .
Cl6 Cl 2.2638(6) 0.1151(5) 0.5485(4) 0.221(3) Uani 1 1 d . . . . .
Cl7 Cl 2.2207(6) 0.0111(5) 0.4955(5) 0.254(4) Uani 1 1 d . . . . .
Cl8 Cl 2.2675(6) 0.1512(4) 0.4122(3) 0.211(3) Uani 1 1 d . . . . .
C106 C 2.293(2) 0.0771(11) 0.4787(11) 0.178(10) Uani 1 1 d . . . . .
H106 H 2.360056 0.049208 0.470596 0.214 Uiso 1 1 calc R U . . .
Cl9 Cl 2.0186(6) 0.1678(5) 0.2688(5) 0.288(6) Uani 1 1 d . . . . .
Cl10 Cl 1.8814(7) 0.2788(4) 0.3348(3) 0.225(4) Uani 1 1 d . . . . .
Cl11 Cl 1.8512(6) 0.1360(5) 0.3353(4) 0.229(4) Uani 1 1 d . . . . .
C107 C 1.9075(14) 0.2085(12) 0.2910(9) 0.137(7) Uani 1 1 d . . . . .
H107 H 1.881498 0.234052 0.251113 0.164 Uiso 1 1 calc R U . . .
O11 O 1.0155(18) 0.029(2) 0.4296(16) 0.394(19) Uani 1 1 d . U . A -1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Ag1 2.9545(7) . ?
Pt1 Ag2 2.8697(7) . ?
Pt1 P2 2.3142(18) . ?
Pt1 P5 2.3368(18) . ?
Pt1 C69 1.986(7) . ?
Pt1 C85 2.022(7) . ?
Ag1 P1 2.4296(19) . ?
Ag1 P6 2.4166(19) . ?
Ag1 C85 2.552(7) . ?
P1 C35 1.828(8) . ?
P1 C42 1.840(7) . ?
P1 C101 1.843(7) . ?
O1 C93 1.359(9) . ?
O1 C94 1.374(9) . ?
N1 N2 1.361(16) . ?
N1 C78 1.32(2) . ?
C1 C2 1.380(11) . ?
C1 P4 1.821(8) . ?
C1 C6 1.417(12) . ?
Ag2 P3 2.410(2) . ?
Ag2 P4 2.403(2) . ?
P2 C49 1.819(7) . ?
P2 C101 1.821(7) . ?
P2 C102 1.829(7) . ?
O2 C77 1.371(15) . ?
O2 C78 1.380(16) . ?
N2 C77 1.229(17) . ?
C2 H2 0.9500 . ?
C2 C3 1.377(11) . ?
P3 C55 1.823(8) . ?
P3 C62 1.828(7) . ?
P3 C102 1.848(7) . ?
N3 N4 1.412(9) . ?
N3 C93 1.286(10) . ?
C3 H3 0.9500 . ?
C3 C4 1.374(13) . ?
P4 C8 1.831(6) . ?
P4 C104 1.835(7) . ?
N4 C94 1.284(11) . ?
C4 H4 0.9500 . ?
C4 C5 1.357(14) . ?
P5 C15 1.815(7) . ?
P5 C103 1.849(7) . ?
P5 C104 1.825(7) . ?
C5 H5 0.9500 . ?
C5 C6 1.411(13) . ?
P6 C21 1.822(7) . ?
P6 C28 1.822(7) . ?
P6 C103 1.830(8) . ?
C6 C7 1.492(13) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C9 H9 0.9500 . ?
C9 C8 1.3900 . ?
C9 C10 1.3900 . ?
C8 C13 1.3900 . ?
C13 C12 1.3900 . ?
C13 C14 1.304(17) . ?
C12 H12 0.9500 . ?
C12 C11 1.3900 . ?
C11 H11 0.9500 . ?
C11 C10 1.3900 . ?
C10 H10 0.9500 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C16 1.388(10) . ?
C15 C20 1.389(10) . ?
C16 H16 0.9500 . ?
C16 C17 1.391(11) . ?
C17 H17 0.9500 . ?
C17 C18 1.366(12) . ?
C18 H18 0.9500 . ?
C18 C19 1.381(12) . ?
C19 H19 0.9500 . ?
C19 C20 1.401(11) . ?
C20 H20 0.9500 . ?
C21 C22 1.413(11) . ?
C21 C26 1.405(11) . ?
C22 H22 0.9500 . ?
C22 C23 1.385(11) . ?
C23 H23 0.9500 . ?
C23 C24 1.365(13) . ?
C24 H24 0.9500 . ?
C24 C25 1.369(13) . ?
C25 H25 0.9500 . ?
C25 C26 1.416(11) . ?
C26 C27 1.480(12) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 C29 1.380(10) . ?
C28 C33 1.421(11) . ?
C29 H29 0.9500 . ?
C29 C30 1.378(11) . ?
C30 H30 0.9500 . ?
C30 C31 1.370(13) . ?
C31 H31 0.9500 . ?
C31 C32 1.385(12) . ?
C32 H32 0.9500 . ?
C32 C33 1.386(11) . ?
C33 C34 1.508(11) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 C36 1.387(10) . ?
C35 C40 1.415(11) . ?
C36 H36 0.9500 . ?
C36 C37 1.400(11) . ?
C37 H37 0.9500 . ?
C37 C38 1.376(12) . ?
C38 H38 0.9500 . ?
C38 C39 1.378(13) . ?
C39 H39 0.9500 . ?
C39 C40 1.394(11) . ?
C40 C41 1.506(11) . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C42 C43 1.403(10) . ?
C42 C47 1.408(10) . ?
C43 H43 0.9500 . ?
C43 C44 1.371(10) . ?
C44 H44 0.9500 . ?
C44 C45 1.384(11) . ?
C45 H45 0.9500 . ?
C45 C46 1.378(11) . ?
C46 H46 0.9500 . ?
C46 C47 1.403(10) . ?
C47 C48 1.508(11) . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 C50 1.391(10) . ?
C49 C54 1.382(11) . ?
C50 H50 0.9500 . ?
C50 C51 1.392(10) . ?
C51 H51 0.9500 . ?
C51 C52 1.387(12) . ?
C52 H52 0.9500 . ?
C52 C53 1.368(13) . ?
C53 H53 0.9500 . ?
C53 C54 1.376(12) . ?
C54 H54 0.9500 . ?
C55 C56 1.385(10) . ?
C55 C60 1.428(10) . ?
C56 H56 0.9500 . ?
C56 C57 1.386(11) . ?
C57 H57 0.9500 . ?
C57 C58 1.372(12) . ?
C58 H58 0.9500 . ?
C58 C59 1.382(13) . ?
C59 H59 0.9500 . ?
C59 C60 1.385(12) . ?
C60 C61 1.514(12) . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 C63 1.393(10) . ?
C62 C67 1.416(10) . ?
C63 H63 0.9500 . ?
C63 C64 1.379(11) . ?
C64 H64 0.9500 . ?
C64 C65 1.380(12) . ?
C65 H65 0.9500 . ?
C65 C66 1.373(13) . ?
C66 H66 0.9500 . ?
C66 C67 1.388(11) . ?
C67 C68 1.491(12) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
C69 C70 1.217(10) . ?
C70 C71 1.456(10) . ?
C71 C72 1.389(13) . ?
C71 C76 1.387(13) . ?
C72 H72 0.9500 . ?
C72 C73 1.419(14) . ?
C73 H73 0.9500 . ?
C73 C74 1.392(16) . ?
C74 C75 1.330(15) . ?
C74 C77 1.509(14) . ?
C75 H75 0.9500 . ?
C75 C76 1.373(12) . ?
C76 H76 0.9500 . ?
C78 C79 1.54(2) . ?
C79 C80 1.393(9) . ?
C79 C84 1.399(9) . ?
C80 H80 0.9500 . ?
C80 C81 1.386(9) . ?
C81 H81 0.9500 . ?
C81 C82 1.387(10) . ?
C82 H82 0.9500 . ?
C82 C83 1.387(9) . ?
C83 H83 0.9500 . ?
C83 C84 1.392(9) . ?
C84 H84 0.9500 . ?
C85 C86 1.222(9) . ?
C86 C87 1.426(9) . ?
C87 C88 1.398(10) . ?
C87 C92 1.403(10) . ?
C88 H88 0.9500 . ?
C88 C89 1.376(10) . ?
C89 H89 0.9500 . ?
C89 C90 1.402(11) . ?
C90 C91 1.383(11) . ?
C90 C93 1.469(10) . ?
C91 H91 0.9500 . ?
C91 C92 1.397(10) . ?
C92 H92 0.9500 . ?
C94 C95 1.460(11) . ?
C95 C96 1.388(11) . ?
C95 C100 1.385(13) . ?
C96 H96 0.9500 . ?
C96 C97 1.391(13) . ?
C97 H97 0.9500 . ?
C97 C98 1.370(15) . ?
C98 H98 0.9500 . ?
C98 C99 1.394(14) . ?
C99 H99 0.9500 . ?
C99 C100 1.380(13) . ?
C100 H100 0.9500 . ?
C101 H10A 0.9900 . ?
C101 H10B 0.9900 . ?
C102 H10C 0.9900 . ?
C102 H10D 0.9900 . ?
C103 H10E 0.9900 . ?
C103 H10F 0.9900 . ?
C104 H10G 0.9900 . ?
C104 H10H 0.9900 . ?
Cl1 O3 1.423(8) . ?
Cl1 O4 1.419(6) . ?
Cl1 O5 1.434(6) . ?
Cl1 O6 1.427(7) . ?
Cl2 O7 1.448(6) . ?
Cl2 O8 1.428(6) . ?
Cl2 O9 1.442(6) . ?
Cl2 O10 1.422(6) . ?
Cl3 C105 1.661(13) . ?
Cl4 C105 1.765(13) . ?
Cl5 C105 1.716(14) . ?
C105 H105 1.0000 . ?
Cl6 C106 1.79(2) . ?
Cl7 C106 1.76(2) . ?
Cl8 C106 1.723(19) . ?
C106 H106 1.0000 . ?
Cl9 C107 1.64(2) . ?
Cl10 C107 1.738(19) . ?
Cl11 C107 1.697(17) . ?
C107 H107 1.0000 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Pt1 Ag1 152.111(19) . . ?
P2 Pt1 Ag1 83.95(5) . . ?
P2 Pt1 Ag2 93.97(5) . . ?
P2 Pt1 P5 175.47(7) . . ?
P5 Pt1 Ag1 91.68(5) . . ?
P5 Pt1 Ag2 90.45(5) . . ?
C69 Pt1 Ag1 130.4(2) . . ?
C69 Pt1 Ag2 76.5(2) . . ?
C69 Pt1 P2 82.9(2) . . ?
C69 Pt1 P5 99.1(2) . . ?
C69 Pt1 C85 170.2(3) . . ?
C85 Pt1 Ag1 58.1(2) . . ?
C85 Pt1 Ag2 94.4(2) . . ?
C85 Pt1 P2 94.2(2) . . ?
C85 Pt1 P5 84.4(2) . . ?
P1 Ag1 Pt1 96.64(5) . . ?
P1 Ag1 C85 89.88(17) . . ?
P6 Ag1 Pt1 90.54(5) . . ?
P6 Ag1 P1 172.72(7) . . ?
P6 Ag1 C85 94.63(17) . . ?
C85 Ag1 Pt1 42.30(15) . . ?
C35 P1 Ag1 122.5(3) . . ?
C35 P1 C42 106.1(3) . . ?
C35 P1 C101 105.9(3) . . ?
C42 P1 Ag1 112.6(2) . . ?
C42 P1 C101 101.5(3) . . ?
C101 P1 Ag1 106.0(2) . . ?
C93 O1 C94 101.9(6) . . ?
C78 N1 N2 103.9(12) . . ?
C2 C1 P4 122.3(6) . . ?
C2 C1 C6 119.6(7) . . ?
C6 C1 P4 117.8(6) . . ?
P3 Ag2 Pt1 90.33(5) . . ?
P4 Ag2 Pt1 94.23(5) . . ?
P4 Ag2 P3 161.49(7) . . ?
C49 P2 Pt1 113.8(2) . . ?
C49 P2 C101 103.2(3) . . ?
C49 P2 C102 104.8(3) . . ?
C101 P2 Pt1 114.7(2) . . ?
C101 P2 C102 106.6(3) . . ?
C102 P2 Pt1 112.7(2) . . ?
C77 O2 C78 99.3(13) . . ?
C77 N2 N1 109.6(15) . . ?
C1 C2 H2 119.0 . . ?
C3 C2 C1 122.0(8) . . ?
C3 C2 H2 119.0 . . ?
C55 P3 Ag2 113.8(2) . . ?
C55 P3 C62 105.6(3) . . ?
C55 P3 C102 107.6(3) . . ?
C62 P3 Ag2 116.8(2) . . ?
C62 P3 C102 104.4(3) . . ?
C102 P3 Ag2 107.9(2) . . ?
C93 N3 N4 105.1(7) . . ?
C2 C3 H3 120.6 . . ?
C4 C3 C2 118.8(9) . . ?
C4 C3 H3 120.6 . . ?
C1 P4 Ag2 108.5(3) . . ?
C1 P4 C8 110.6(4) . . ?
C1 P4 C104 104.3(4) . . ?
C8 P4 Ag2 119.7(3) . . ?
C8 P4 C104 106.7(3) . . ?
C104 P4 Ag2 106.0(2) . . ?
C94 N4 N3 107.0(6) . . ?
C3 C4 H4 119.6 . . ?
C5 C4 C3 120.7(9) . . ?
C5 C4 H4 119.6 . . ?
C15 P5 Pt1 122.5(2) . . ?
C15 P5 C103 104.4(3) . . ?
C15 P5 C104 106.0(3) . . ?
C103 P5 Pt1 112.6(2) . . ?
C104 P5 Pt1 109.4(2) . . ?
C104 P5 C103 99.2(3) . . ?
C4 C5 H5 118.9 . . ?
C4 C5 C6 122.1(10) . . ?
C6 C5 H5 118.9 . . ?
C21 P6 Ag1 115.4(3) . . ?
C21 P6 C28 109.2(3) . . ?
C21 P6 C103 106.5(3) . . ?
C28 P6 Ag1 115.1(2) . . ?
C28 P6 C103 103.8(3) . . ?
C103 P6 Ag1 105.7(2) . . ?
C1 C6 C7 123.4(8) . . ?
C5 C6 C1 116.7(9) . . ?
C5 C6 C7 119.8(9) . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C8 C9 H9 120.0 . . ?
C8 C9 C10 120.0 . . ?
C10 C9 H9 120.0 . . ?
C9 C8 P4 114.8(5) . . ?
C9 C8 C13 120.0 . . ?
C13 C8 P4 125.0(5) . . ?
C8 C13 C12 120.0 . . ?
C14 C13 C8 123.8(10) . . ?
C14 C13 C12 116.0(10) . . ?
C13 C12 H12 120.0 . . ?
C11 C12 C13 120.0 . . ?
C11 C12 H12 120.0 . . ?
C12 C11 H11 120.0 . . ?
C12 C11 C10 120.0 . . ?
C10 C11 H11 120.0 . . ?
C9 C10 H10 120.0 . . ?
C11 C10 C9 120.0 . . ?
C11 C10 H10 120.0 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 P5 121.7(6) . . ?
C16 C15 C20 119.8(7) . . ?
C20 C15 P5 118.5(6) . . ?
C15 C16 H16 120.6 . . ?
C15 C16 C17 118.8(7) . . ?
C17 C16 H16 120.6 . . ?
C16 C17 H17 119.1 . . ?
C18 C17 C16 121.9(8) . . ?
C18 C17 H17 119.1 . . ?
C17 C18 H18 120.1 . . ?
C17 C18 C19 119.8(7) . . ?
C19 C18 H18 120.1 . . ?
C18 C19 H19 120.3 . . ?
C18 C19 C20 119.3(8) . . ?
C20 C19 H19 120.3 . . ?
C15 C20 C19 120.4(7) . . ?
C15 C20 H20 119.8 . . ?
C19 C20 H20 119.8 . . ?
C22 C21 P6 113.9(6) . . ?
C26 C21 P6 125.3(6) . . ?
C26 C21 C22 120.7(7) . . ?
C21 C22 H22 119.9 . . ?
C23 C22 C21 120.2(8) . . ?
C23 C22 H22 119.9 . . ?
C22 C23 H23 120.2 . . ?
C24 C23 C22 119.5(8) . . ?
C24 C23 H23 120.2 . . ?
C23 C24 H24 119.4 . . ?
C23 C24 C25 121.1(8) . . ?
C25 C24 H24 119.4 . . ?
C24 C25 H25 119.0 . . ?
C24 C25 C26 122.1(8) . . ?
C26 C25 H25 119.0 . . ?
C21 C26 C25 116.4(8) . . ?
C21 C26 C27 124.6(7) . . ?
C25 C26 C27 119.0(8) . . ?
C26 C27 H27A 109.5 . . ?
C26 C27 H27B 109.5 . . ?
C26 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C29 C28 P6 122.2(6) . . ?
C29 C28 C33 118.9(7) . . ?
C33 C28 P6 118.9(6) . . ?
C28 C29 H29 118.9 . . ?
C30 C29 C28 122.2(8) . . ?
C30 C29 H29 118.9 . . ?
C29 C30 H30 120.1 . . ?
C31 C30 C29 119.9(8) . . ?
C31 C30 H30 120.1 . . ?
C30 C31 H31 120.7 . . ?
C30 C31 C32 118.6(8) . . ?
C32 C31 H31 120.7 . . ?
C31 C32 H32 118.4 . . ?
C31 C32 C33 123.2(8) . . ?
C33 C32 H32 118.4 . . ?
C28 C33 C34 122.8(7) . . ?
C32 C33 C28 117.2(7) . . ?
C32 C33 C34 120.0(7) . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C36 C35 P1 118.7(6) . . ?
C36 C35 C40 118.9(7) . . ?
C40 C35 P1 122.4(6) . . ?
C35 C36 H36 119.1 . . ?
C35 C36 C37 121.8(7) . . ?
C37 C36 H36 119.1 . . ?
C36 C37 H37 120.6 . . ?
C38 C37 C36 118.8(8) . . ?
C38 C37 H37 120.6 . . ?
C37 C38 H38 119.8 . . ?
C37 C38 C39 120.4(8) . . ?
C39 C38 H38 119.8 . . ?
C38 C39 H39 119.1 . . ?
C38 C39 C40 121.8(8) . . ?
C40 C39 H39 119.1 . . ?
C35 C40 C41 124.8(7) . . ?
C39 C40 C35 118.3(8) . . ?
C39 C40 C41 116.9(8) . . ?
C40 C41 H41A 109.5 . . ?
C40 C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C43 C42 P1 120.0(6) . . ?
C43 C42 C47 119.5(7) . . ?
C47 C42 P1 120.4(6) . . ?
C42 C43 H43 119.4 . . ?
C44 C43 C42 121.3(7) . . ?
C44 C43 H43 119.4 . . ?
C43 C44 H44 120.2 . . ?
C43 C44 C45 119.7(8) . . ?
C45 C44 H44 120.2 . . ?
C44 C45 H45 120.0 . . ?
C46 C45 C44 120.0(7) . . ?
C46 C45 H45 120.0 . . ?
C45 C46 H46 119.1 . . ?
C45 C46 C47 121.8(7) . . ?
C47 C46 H46 119.1 . . ?
C42 C47 C48 123.5(7) . . ?
C46 C47 C42 117.7(7) . . ?
C46 C47 C48 118.8(7) . . ?
C47 C48 H48A 109.5 . . ?
C47 C48 H48B 109.5 . . ?
C47 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C50 C49 P2 119.9(5) . . ?
C54 C49 P2 120.2(6) . . ?
C54 C49 C50 119.7(7) . . ?
C49 C50 H50 119.8 . . ?
C49 C50 C51 120.4(7) . . ?
C51 C50 H50 119.8 . . ?
C50 C51 H51 120.5 . . ?
C52 C51 C50 119.1(8) . . ?
C52 C51 H51 120.5 . . ?
C51 C52 H52 120.1 . . ?
C53 C52 C51 119.8(8) . . ?
C53 C52 H52 120.1 . . ?
C52 C53 H53 119.1 . . ?
C52 C53 C54 121.7(9) . . ?
C54 C53 H53 119.1 . . ?
C49 C54 H54 120.4 . . ?
C53 C54 C49 119.2(8) . . ?
C53 C54 H54 120.4 . . ?
C56 C55 P3 119.4(6) . . ?
C56 C55 C60 119.3(7) . . ?
C60 C55 P3 120.9(6) . . ?
C55 C56 H56 119.4 . . ?
C55 C56 C57 121.3(7) . . ?
C57 C56 H56 119.4 . . ?
C56 C57 H57 120.4 . . ?
C58 C57 C56 119.1(8) . . ?
C58 C57 H57 120.4 . . ?
C57 C58 H58 119.5 . . ?
C57 C58 C59 121.0(8) . . ?
C59 C58 H58 119.5 . . ?
C58 C59 H59 119.5 . . ?
C58 C59 C60 121.0(8) . . ?
C60 C59 H59 119.5 . . ?
C55 C60 C61 122.9(7) . . ?
C59 C60 C55 118.2(7) . . ?
C59 C60 C61 118.9(7) . . ?
C60 C61 H61A 109.5 . . ?
C60 C61 H61B 109.5 . . ?
C60 C61 H61C 109.5 . . ?
H61A C61 H61B 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C63 C62 P3 118.2(5) . . ?
C63 C62 C67 119.6(7) . . ?
C67 C62 P3 122.2(6) . . ?
C62 C63 H63 119.4 . . ?
C64 C63 C62 121.2(7) . . ?
C64 C63 H63 119.4 . . ?
C63 C64 H64 120.3 . . ?
C63 C64 C65 119.5(8) . . ?
C65 C64 H64 120.3 . . ?
C64 C65 H65 120.1 . . ?
C66 C65 C64 119.7(8) . . ?
C66 C65 H65 120.1 . . ?
C65 C66 H66 118.6 . . ?
C65 C66 C67 122.7(8) . . ?
C67 C66 H66 118.6 . . ?
C62 C67 C68 123.6(7) . . ?
C66 C67 C62 117.2(8) . . ?
C66 C67 C68 119.2(7) . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68B 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C70 C69 Pt1 171.1(7) . . ?
C69 C70 C71 176.2(9) . . ?
C72 C71 C70 119.6(8) . . ?
C76 C71 C70 121.5(8) . . ?
C76 C71 C72 118.9(8) . . ?
C71 C72 H72 120.4 . . ?
C71 C72 C73 119.2(10) . . ?
C73 C72 H72 120.4 . . ?
C72 C73 H73 120.5 . . ?
C74 C73 C72 119.0(10) . . ?
C74 C73 H73 120.5 . . ?
C73 C74 C77 117.2(10) . . ?
C75 C74 C73 120.9(9) . . ?
C75 C74 C77 121.9(11) . . ?
C74 C75 H75 119.5 . . ?
C74 C75 C76 120.9(11) . . ?
C76 C75 H75 119.5 . . ?
C71 C76 H76 119.5 . . ?
C75 C76 C71 121.0(10) . . ?
C75 C76 H76 119.5 . . ?
O2 C77 C74 116.4(11) . . ?
N2 C77 O2 114.2(12) . . ?
N2 C77 C74 129.3(13) . . ?
N1 C78 O2 112.7(14) . . ?
N1 C78 C79 133.1(14) . . ?
O2 C78 C79 114.1(18) . . ?
C80 C79 C78 115.3(15) . . ?
C80 C79 C84 122.7(15) . . ?
C84 C79 C78 121.8(12) . . ?
C79 C80 H80 120.7 . . ?
C81 C80 C79 118.7(14) . . ?
C81 C80 H80 120.7 . . ?
C80 C81 H81 120.7 . . ?
C80 C81 C82 118.6(16) . . ?
C82 C81 H81 120.7 . . ?
C81 C82 H82 118.5 . . ?
C81 C82 C83 123.1(18) . . ?
C83 C82 H82 118.5 . . ?
C82 C83 H83 120.6 . . ?
C82 C83 C84 118.8(17) . . ?
C84 C83 H83 120.6 . . ?
C79 C84 H84 120.9 . . ?
C83 C84 C79 118.2(16) . . ?
C83 C84 H84 120.9 . . ?
Pt1 C85 Ag1 79.6(2) . . ?
C86 C85 Pt1 170.4(7) . . ?
C86 C85 Ag1 109.7(6) . . ?
C85 C86 C87 174.6(8) . . ?
C88 C87 C86 120.9(7) . . ?
C88 C87 C92 119.0(6) . . ?
C92 C87 C86 120.1(7) . . ?
C87 C88 H88 119.5 . . ?
C89 C88 C87 121.0(7) . . ?
C89 C88 H88 119.5 . . ?
C88 C89 H89 119.9 . . ?
C88 C89 C90 120.1(7) . . ?
C90 C89 H89 119.9 . . ?
C89 C90 C93 120.2(7) . . ?
C91 C90 C89 119.4(7) . . ?
C91 C90 C93 120.5(7) . . ?
C90 C91 H91 119.6 . . ?
C90 C91 C92 120.8(7) . . ?
C92 C91 H91 119.6 . . ?
C87 C92 H92 120.2 . . ?
C91 C92 C87 119.6(7) . . ?
C91 C92 H92 120.2 . . ?
O1 C93 C90 117.6(7) . . ?
N3 C93 O1 113.8(7) . . ?
N3 C93 C90 128.5(8) . . ?
O1 C94 C95 118.3(8) . . ?
N4 C94 O1 112.2(7) . . ?
N4 C94 C95 129.5(7) . . ?
C96 C95 C94 118.2(8) . . ?
C100 C95 C94 121.2(7) . . ?
C100 C95 C96 120.6(8) . . ?
C95 C96 H96 120.3 . . ?
C95 C96 C97 119.4(10) . . ?
C97 C96 H96 120.3 . . ?
C96 C97 H97 120.0 . . ?
C98 C97 C96 120.0(9) . . ?
C98 C97 H97 120.0 . . ?
C97 C98 H98 119.8 . . ?
C97 C98 C99 120.5(9) . . ?
C99 C98 H98 119.8 . . ?
C98 C99 H99 120.1 . . ?
C100 C99 C98 119.9(10) . . ?
C100 C99 H99 120.1 . . ?
C95 C100 H100 120.2 . . ?
C99 C100 C95 119.6(9) . . ?
C99 C100 H100 120.2 . . ?
P1 C101 H10A 108.8 . . ?
P1 C101 H10B 108.8 . . ?
P2 C101 P1 113.7(4) . . ?
P2 C101 H10A 108.8 . . ?
P2 C101 H10B 108.8 . . ?
H10A C101 H10B 107.7 . . ?
P2 C102 P3 114.1(3) . . ?
P2 C102 H10C 108.7 . . ?
P2 C102 H10D 108.7 . . ?
P3 C102 H10C 108.7 . . ?
P3 C102 H10D 108.7 . . ?
H10C C102 H10D 107.6 . . ?
P5 C103 H10E 108.6 . . ?
P5 C103 H10F 108.6 . . ?
P6 C103 P5 114.9(4) . . ?
P6 C103 H10E 108.6 . . ?
P6 C103 H10F 108.6 . . ?
H10E C103 H10F 107.5 . . ?
P4 C104 H10G 108.7 . . ?
P4 C104 H10H 108.7 . . ?
P5 C104 P4 114.2(4) . . ?
P5 C104 H10G 108.7 . . ?
P5 C104 H10H 108.7 . . ?
H10G C104 H10H 107.6 . . ?
O3 Cl1 O5 110.3(5) . . ?
O3 Cl1 O6 105.1(6) . . ?
O4 Cl1 O3 110.4(4) . . ?
O4 Cl1 O5 111.9(4) . . ?
O4 Cl1 O6 109.7(5) . . ?
O6 Cl1 O5 109.2(4) . . ?
O8 Cl2 O7 109.2(4) . . ?
O8 Cl2 O9 110.0(4) . . ?
O9 Cl2 O7 108.1(4) . . ?
O10 Cl2 O7 110.1(4) . . ?
O10 Cl2 O8 110.1(4) . . ?
O10 Cl2 O9 109.3(4) . . ?
Cl3 C105 Cl4 112.6(8) . . ?
Cl3 C105 Cl5 113.4(9) . . ?
Cl3 C105 H105 108.0 . . ?
Cl4 C105 H105 108.0 . . ?
Cl5 C105 Cl4 106.7(7) . . ?
Cl5 C105 H105 108.0 . . ?
Cl6 C106 H106 110.4 . . ?
Cl7 C106 Cl6 106.1(15) . . ?
Cl7 C106 H106 110.4 . . ?
Cl8 C106 Cl6 110.8(12) . . ?
Cl8 C106 Cl7 108.5(15) . . ?
Cl8 C106 H106 110.4 . . ?
Cl9 C107 Cl10 116.8(11) . . ?
Cl9 C107 Cl11 108.2(13) . . ?
Cl9 C107 H107 107.7 . . ?
Cl10 C107 H107 107.7 . . ?
Cl11 C107 Cl10 108.4(11) . . ?
Cl11 C107 H107 107.7 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 P2 C49 C50 -12.3(7) . . . . ?
Pt1 P2 C49 C54 172.4(6) . . . . ?
Pt1 P2 C101 P1 61.0(4) . . . . ?
Pt1 P2 C102 P3 41.7(4) . . . . ?
Pt1 P5 C15 C16 6.2(8) . . . . ?
Pt1 P5 C15 C20 -171.9(5) . . . . ?
Pt1 P5 C103 P6 -44.9(4) . . . . ?
Pt1 P5 C104 P4 58.3(4) . . . . ?
Ag1 P1 C35 C36 169.6(5) . . . . ?
Ag1 P1 C35 C40 -7.7(8) . . . . ?
Ag1 P1 C42 C43 -140.8(5) . . . . ?
Ag1 P1 C42 C47 36.7(7) . . . . ?
Ag1 P1 C101 P2 -38.2(4) . . . . ?
Ag1 P6 C21 C22 -2.9(7) . . . . ?
Ag1 P6 C21 C26 -178.9(6) . . . . ?
Ag1 P6 C28 C29 116.0(6) . . . . ?
Ag1 P6 C28 C33 -60.4(6) . . . . ?
Ag1 P6 C103 P5 56.9(4) . . . . ?
P1 C35 C36 C37 -176.5(6) . . . . ?
P1 C35 C40 C39 175.1(6) . . . . ?
P1 C35 C40 C41 -5.0(11) . . . . ?
P1 C42 C43 C44 177.2(6) . . . . ?
P1 C42 C47 C46 -178.3(6) . . . . ?
P1 C42 C47 C48 -0.9(11) . . . . ?
O1 C94 C95 C96 176.4(8) . . . . ?
O1 C94 C95 C100 -3.7(13) . . . . ?
N1 N2 C77 O2 -3.7(19) . . . . ?
N1 N2 C77 C74 178.0(13) . . . . ?
N1 C78 C79 C80 -3(2) . . . . ?
N1 C78 C79 C84 171.4(16) . . . . ?
C1 C2 C3 C4 1.5(14) . . . . ?
C1 P4 C8 C9 136.5(5) . . . . ?
C1 P4 C8 C13 -48.6(6) . . . . ?
C1 P4 C104 P5 -165.5(4) . . . . ?
Ag2 P3 C55 C56 122.9(6) . . . . ?
Ag2 P3 C55 C60 -49.4(7) . . . . ?
Ag2 P3 C62 C63 157.4(5) . . . . ?
Ag2 P3 C62 C67 -22.2(7) . . . . ?
Ag2 P3 C102 P2 -52.4(4) . . . . ?
Ag2 P4 C8 C9 9.3(5) . . . . ?
Ag2 P4 C8 C13 -175.7(4) . . . . ?
Ag2 P4 C104 P5 -51.1(4) . . . . ?
P2 C49 C50 C51 -175.2(6) . . . . ?
P2 C49 C54 C53 176.0(8) . . . . ?
O2 C78 C79 C80 178.3(8) . . . . ?
O2 C78 C79 C84 -7.7(15) . . . . ?
N2 N1 C78 O2 -4.3(19) . . . . ?
N2 N1 C78 C79 176.7(14) . . . . ?
C2 C1 P4 Ag2 -106.9(7) . . . . ?
C2 C1 P4 C8 120.0(7) . . . . ?
C2 C1 P4 C104 5.7(8) . . . . ?
C2 C1 C6 C5 0.9(13) . . . . ?
C2 C1 C6 C7 177.3(10) . . . . ?
C2 C3 C4 C5 -3.2(16) . . . . ?
P3 C55 C56 C57 -172.6(6) . . . . ?
P3 C55 C60 C59 174.2(7) . . . . ?
P3 C55 C60 C61 -7.2(12) . . . . ?
P3 C62 C63 C64 -177.4(6) . . . . ?
P3 C62 C67 C66 177.1(6) . . . . ?
P3 C62 C67 C68 -4.7(11) . . . . ?
N3 N4 C94 O1 0.8(10) . . . . ?
N3 N4 C94 C95 -179.3(9) . . . . ?
C3 C4 C5 C6 3.8(18) . . . . ?
P4 C1 C2 C3 172.4(7) . . . . ?
P4 C1 C6 C5 -172.2(8) . . . . ?
P4 C1 C6 C7 4.1(14) . . . . ?
P4 C8 C13 C12 -174.7(6) . . . . ?
P4 C8 C13 C14 10.5(11) . . . . ?
N4 N3 C93 O1 -0.4(10) . . . . ?
N4 N3 C93 C90 180.0(8) . . . . ?
N4 C94 C95 C96 -3.6(15) . . . . ?
N4 C94 C95 C100 176.3(10) . . . . ?
C4 C5 C6 C1 -2.6(17) . . . . ?
C4 C5 C6 C7 -179.1(12) . . . . ?
P5 C15 C16 C17 -176.4(7) . . . . ?
P5 C15 C20 C19 176.5(7) . . . . ?
P6 C21 C22 C23 -176.3(7) . . . . ?
P6 C21 C26 C25 175.8(6) . . . . ?
P6 C21 C26 C27 -5.4(13) . . . . ?
P6 C28 C29 C30 -178.9(6) . . . . ?
P6 C28 C33 C32 178.0(6) . . . . ?
P6 C28 C33 C34 -4.4(11) . . . . ?
C6 C1 C2 C3 -0.5(13) . . . . ?
C6 C1 P4 Ag2 66.0(7) . . . . ?
C6 C1 P4 C8 -67.0(8) . . . . ?
C6 C1 P4 C104 178.7(7) . . . . ?
C9 C8 C13 C12 0.0 . . . . ?
C9 C8 C13 C14 -174.8(12) . . . . ?
C8 P4 C104 P5 77.5(5) . . . . ?
C8 C9 C10 C11 0.0 . . . . ?
C8 C13 C12 C11 0.0 . . . . ?
C13 C12 C11 C10 0.0 . . . . ?
C12 C11 C10 C9 0.0 . . . . ?
C10 C9 C8 P4 175.2(5) . . . . ?
C10 C9 C8 C13 0.0 . . . . ?
C14 C13 C12 C11 175.2(11) . . . . ?
C15 P5 C103 P6 90.2(4) . . . . ?
C15 P5 C104 P4 -75.7(5) . . . . ?
C15 C16 C17 C18 -0.1(14) . . . . ?
C16 C15 C20 C19 -1.6(13) . . . . ?
C16 C17 C18 C19 -1.6(15) . . . . ?
C17 C18 C19 C20 1.6(14) . . . . ?
C18 C19 C20 C15 -0.1(14) . . . . ?
C20 C15 C16 C17 1.6(13) . . . . ?
C21 P6 C28 C29 -112.3(7) . . . . ?
C21 P6 C28 C33 71.3(7) . . . . ?
C21 P6 C103 P5 -66.3(5) . . . . ?
C21 C22 C23 C24 0.3(14) . . . . ?
C22 C21 C26 C25 0.0(12) . . . . ?
C22 C21 C26 C27 178.8(9) . . . . ?
C22 C23 C24 C25 -0.4(15) . . . . ?
C23 C24 C25 C26 0.4(15) . . . . ?
C24 C25 C26 C21 -0.2(13) . . . . ?
C24 C25 C26 C27 -179.0(10) . . . . ?
C26 C21 C22 C23 0.0(13) . . . . ?
C28 P6 C21 C22 -134.4(6) . . . . ?
C28 P6 C21 C26 49.5(8) . . . . ?
C28 P6 C103 P5 178.4(4) . . . . ?
C28 C29 C30 C31 1.7(13) . . . . ?
C29 C28 C33 C32 1.4(11) . . . . ?
C29 C28 C33 C34 179.0(8) . . . . ?
C29 C30 C31 C32 0.2(14) . . . . ?
C30 C31 C32 C33 -1.3(14) . . . . ?
C31 C32 C33 C28 0.4(13) . . . . ?
C31 C32 C33 C34 -177.2(9) . . . . ?
C33 C28 C29 C30 -2.5(12) . . . . ?
C35 P1 C42 C43 82.6(7) . . . . ?
C35 P1 C42 C47 -99.9(6) . . . . ?
C35 P1 C101 P2 93.4(4) . . . . ?
C35 C36 C37 C38 1.2(12) . . . . ?
C36 C35 C40 C39 -2.2(11) . . . . ?
C36 C35 C40 C41 177.7(8) . . . . ?
C36 C37 C38 C39 -2.0(13) . . . . ?
C37 C38 C39 C40 0.7(14) . . . . ?
C38 C39 C40 C35 1.4(13) . . . . ?
C38 C39 C40 C41 -178.5(8) . . . . ?
C40 C35 C36 C37 0.9(11) . . . . ?
C42 P1 C35 C36 -59.2(7) . . . . ?
C42 P1 C35 C40 123.5(6) . . . . ?
C42 P1 C101 P2 -156.0(4) . . . . ?
C42 C43 C44 C45 0.8(12) . . . . ?
C43 C42 C47 C46 -0.8(11) . . . . ?
C43 C42 C47 C48 176.7(8) . . . . ?
C43 C44 C45 C46 -0.1(13) . . . . ?
C44 C45 C46 C47 -1.0(12) . . . . ?
C45 C46 C47 C42 1.5(12) . . . . ?
C45 C46 C47 C48 -176.1(8) . . . . ?
C47 C42 C43 C44 -0.4(11) . . . . ?
C49 P2 C101 P1 -63.4(5) . . . . ?
C49 P2 C102 P3 166.0(4) . . . . ?
C49 C50 C51 C52 -0.2(13) . . . . ?
C50 C49 C54 C53 0.8(14) . . . . ?
C50 C51 C52 C53 -0.5(15) . . . . ?
C51 C52 C53 C54 1.3(17) . . . . ?
C52 C53 C54 C49 -1.5(17) . . . . ?
C54 C49 C50 C51 0.1(12) . . . . ?
C55 P3 C62 C63 -74.9(6) . . . . ?
C55 P3 C62 C67 105.5(6) . . . . ?
C55 P3 C102 P2 -175.7(4) . . . . ?
C55 C56 C57 C58 -0.6(12) . . . . ?
C56 C55 C60 C59 2.0(12) . . . . ?
C56 C55 C60 C61 -179.5(9) . . . . ?
C56 C57 C58 C59 -0.4(14) . . . . ?
C57 C58 C59 C60 2.3(15) . . . . ?
C58 C59 C60 C55 -3.0(14) . . . . ?
C58 C59 C60 C61 178.4(10) . . . . ?
C60 C55 C56 C57 -0.2(11) . . . . ?
C62 P3 C55 C56 -6.5(7) . . . . ?
C62 P3 C55 C60 -178.7(6) . . . . ?
C62 P3 C102 P2 72.5(4) . . . . ?
C62 C63 C64 C65 0.5(12) . . . . ?
C63 C62 C67 C66 -2.4(11) . . . . ?
C63 C62 C67 C68 175.7(7) . . . . ?
C63 C64 C65 C66 -2.8(13) . . . . ?
C64 C65 C66 C67 2.6(13) . . . . ?
C65 C66 C67 C62 0.1(12) . . . . ?
C65 C66 C67 C68 -178.2(8) . . . . ?
C67 C62 C63 C64 2.2(11) . . . . ?
C70 C71 C72 C73 179.2(9) . . . . ?
C70 C71 C76 C75 -177.3(9) . . . . ?
C71 C72 C73 C74 -1.6(17) . . . . ?
C72 C71 C76 C75 -0.1(15) . . . . ?
C72 C73 C74 C75 -0.7(18) . . . . ?
C72 C73 C74 C77 178.3(11) . . . . ?
C73 C74 C75 C76 2.7(18) . . . . ?
C73 C74 C77 O2 -174.8(10) . . . . ?
C73 C74 C77 N2 3(2) . . . . ?
C74 C75 C76 C71 -2.2(17) . . . . ?
C75 C74 C77 O2 4.2(17) . . . . ?
C75 C74 C77 N2 -177.5(15) . . . . ?
C76 C71 C72 C73 2.0(15) . . . . ?
C77 O2 C78 N1 2.2(16) . . . . ?
C77 O2 C78 C79 -178.5(10) . . . . ?
C77 C74 C75 C76 -176.4(11) . . . . ?
C78 N1 N2 C77 5(2) . . . . ?
C78 O2 C77 N2 1.0(16) . . . . ?
C78 O2 C77 C74 179.5(11) . . . . ?
C78 C79 C80 C81 174.0(9) . . . . ?
C78 C79 C84 C83 -173.6(10) . . . . ?
C79 C80 C81 C82 0.0(3) . . . . ?
C80 C79 C84 C83 0.1(6) . . . . ?
C80 C81 C82 C83 -0.2(6) . . . . ?
C81 C82 C83 C84 0.2(8) . . . . ?
C82 C83 C84 C79 -0.2(8) . . . . ?
C84 C79 C80 C81 0.0(3) . . . . ?
C86 C87 C88 C89 175.6(7) . . . . ?
C86 C87 C92 C91 -175.3(8) . . . . ?
C87 C88 C89 C90 -0.6(12) . . . . ?
C88 C87 C92 C91 1.7(12) . . . . ?
C88 C89 C90 C91 2.1(12) . . . . ?
C88 C89 C90 C93 -177.4(7) . . . . ?
C89 C90 C91 C92 -1.8(13) . . . . ?
C89 C90 C93 O1 177.3(7) . . . . ?
C89 C90 C93 N3 -3.1(14) . . . . ?
C90 C91 C92 C87 -0.1(13) . . . . ?
C91 C90 C93 O1 -2.2(12) . . . . ?
C91 C90 C93 N3 177.3(9) . . . . ?
C92 C87 C88 C89 -1.4(12) . . . . ?
C93 O1 C94 N4 -1.0(9) . . . . ?
C93 O1 C94 C95 179.1(8) . . . . ?
C93 N3 N4 C94 -0.2(10) . . . . ?
C93 C90 C91 C92 177.7(8) . . . . ?
C94 O1 C93 N3 0.9(10) . . . . ?
C94 O1 C93 C90 -179.5(7) . . . . ?
C94 C95 C96 C97 -180.0(9) . . . . ?
C94 C95 C100 C99 -179.7(10) . . . . ?
C95 C96 C97 C98 0.4(15) . . . . ?
C96 C95 C100 C99 0.2(16) . . . . ?
C96 C97 C98 C99 -1.2(16) . . . . ?
C97 C98 C99 C100 1.5(17) . . . . ?
C98 C99 C100 C95 -1.0(17) . . . . ?
C100 C95 C96 C97 0.1(15) . . . . ?
C101 P1 C35 C36 48.1(7) . . . . ?
C101 P1 C35 C40 -129.2(6) . . . . ?
C101 P1 C42 C43 -27.9(7) . . . . ?
C101 P1 C42 C47 149.6(6) . . . . ?
C101 P2 C49 C50 112.6(6) . . . . ?
C101 P2 C49 C54 -62.6(8) . . . . ?
C101 P2 C102 P3 -85.1(4) . . . . ?
C102 P2 C49 C50 -136.0(6) . . . . ?
C102 P2 C49 C54 48.8(8) . . . . ?
C102 P2 C101 P1 -173.5(4) . . . . ?
C102 P3 C55 C56 -117.6(6) . . . . ?
C102 P3 C55 C60 70.2(7) . . . . ?
C102 P3 C62 C63 38.4(7) . . . . ?
C102 P3 C62 C67 -141.2(6) . . . . ?
C103 P5 C15 C16 -123.2(7) . . . . ?
C103 P5 C15 C20 58.7(7) . . . . ?
C103 P5 C104 P4 176.3(4) . . . . ?
C103 P6 C21 C22 114.1(6) . . . . ?
C103 P6 C21 C26 -62.0(8) . . . . ?
C103 P6 C28 C29 1.1(7) . . . . ?
C103 P6 C28 C33 -175.4(6) . . . . ?
C104 P4 C8 C9 -110.8(5) . . . . ?
C104 P4 C8 C13 64.2(5) . . . . ?
C104 P5 C15 C16 132.6(7) . . . . ?
C104 P5 C15 C20 -45.5(7) . . . . ?
C104 P5 C103 P6 -160.5(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_z_CCDC2
_database_code_depnum_ccdc_archive 'CCDC 2055677'
loop_
_audit_author_name
_audit_author_address
'Liang-Jin Xu'
;Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2021-01-13 deposited with the CCDC.	2021-03-26 downloaded from the CCDC.
;
_audit_creation_date             2020-12-23
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'C114 H106 Ag2 N2 P6 Pt, 4(C H2 Cl2), 2(C F3 O3 S)'
_chemical_formula_sum            'C120 H114 Ag2 Cl8 F6 N2 O6 P6 Pt S2'
_chemical_formula_weight         2738.50
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.3798(12)
_cell_length_b                   15.1217(13)
_cell_length_c                   15.9141(15)
_cell_angle_alpha                111.210(3)
_cell_angle_beta                 95.400(3)
_cell_angle_gamma                110.171(3)
_cell_volume                     2932.0(5)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    9864
_cell_measurement_temperature    100.0
_cell_measurement_theta_max      25.38
_cell_measurement_theta_min      2.39
_shelx_estimated_absorpt_T_max   0.778
_shelx_estimated_absorpt_T_min   0.704
_exptl_absorpt_coefficient_mu    1.885
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.6194
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1080 before and 0.0655 after correction.
The Ratio of minimum to maximum transmission is 0.8312.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic yellowish yellow'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   yellowish
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.551
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1380
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.14
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0725
_diffrn_reflns_av_unetI/netI     0.0510
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            43647
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.388
_diffrn_reflns_theta_min         2.600
_diffrn_ambient_temperature      100.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9673
_reflns_number_total             10741
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.192
_refine_diff_density_min         -0.963
_refine_diff_density_rms         0.087
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     749
_refine_ls_number_reflns         10741
_refine_ls_number_restraints     166
_refine_ls_R_factor_all          0.0346
_refine_ls_R_factor_gt           0.0282
_refine_ls_restrained_S_all      1.071
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0285P)²+0.9540P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0705
_refine_ls_wR_factor_ref         0.0731
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 P1-C28A \\sim P1-C21 \\sim P2-C15 \\sim P3-C8 \\sim P3-C1
 with sigma of 0.01
3. Rigid bond restraints
 C28A, C32A, C31A, C29A, C30A, C33A, C34A
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 C28, C29, C34, C32, C30, C33, C31
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
C28A \\sim C32A \\sim C31A \\sim C29A \\sim C30A \\sim C33A \\sim C34A: within
2A with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
C28 \\sim C29 \\sim C34 \\sim C32 \\sim C30 \\sim C33 \\sim C31: within 2A with
sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
Uanis(C28A) \\sim Ueq, Uanis(C33A) \\sim Ueq, Uanis(C32A) \\sim Ueq,
Uanis(C34A) \\sim Ueq, Uanis(C31A) \\sim Ueq, Uanis(C29A) \\sim Ueq,
Uanis(C30A) \\sim Ueq: with sigma of 0.1 and sigma for terminal atoms of 0.2
5. Others
 Sof(C28A)=Sof(C32A)=Sof(C31A)=Sof(H31A)=Sof(C29A)=Sof(H29A)=Sof(C30A)=
 Sof(H30A)=Sof(C33A)=Sof(H33A)=Sof(C34A)=Sof(H34D)=Sof(H34E)=Sof(H34F)=1-FVAR(1)
 Sof(C28)=Sof(C29)=Sof(H29)=Sof(C30)=Sof(H30)=Sof(C31)=Sof(H31)=Sof(C32)=
 Sof(H32)=Sof(C33)=Sof(C34)=Sof(H34A)=Sof(H34B)=Sof(H34C)=FVAR(1)
6.a Secondary CH2 refined with riding coordinates:
 C35(H35A,H35B), C36(H36A,H36B), C58(H58A,H58B), C59(H59A,H59B)
6.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C9(H9), C10(H10), C11(H11), C12(H12),
 C16(H16), C17(H17), C18(H18), C19(H19), C20(H20), C22(H22), C23(H23), C24(H24),
  C25(H25), C29(H29), C30(H30), C31(H31), C32(H32), C40(H40), C41(H41),
 C43(H43), C47(H47), C48(H48), C49(H49), C50(H50), C51(H51), C53(H53), C54(H54),
  C55(H55), C56(H56), C57(H57), C31A(H31A), C29A(H29A), C30A(H30A), C33A(H33A)
6.c Fitted hexagon refined as free rotating group:
 C28A(C32A,C31A,C29A,C30A,C33A)
6.d Idealised Me refined as rotating group:
 C7(H7A,H7B,H7C), C14(H14A,H14B,H14C), C27(H27A,H27B,H27C), C34(H34A,H34B,
 H34C), C45(H45A,H45B,H45C), C34A(H34D,H34E,H34F)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.49262(2) 0.61009(2) 0.18984(2) 0.02150(6) Uani 1 1 d . . . . .
C1 C 0.2827(2) 0.6759(2) 0.1719(2) 0.0217(6) Uani 1 1 d D . . . .
C2 C 0.1901(3) 0.6100(3) 0.1063(2) 0.0311(7) Uani 1 1 d . . . . .
H2 H 0.189017 0.583042 0.042065 0.037 Uiso 1 1 calc R U . . .
C3 C 0.0991(3) 0.5830(3) 0.1332(3) 0.0425(9) Uani 1 1 d . . . . .
H3 H 0.036223 0.536841 0.087775 0.051 Uiso 1 1 calc R U . . .
C4 C 0.1007(3) 0.6238(3) 0.2265(3) 0.0418(9) Uani 1 1 d . . . . .
H4 H 0.038728 0.605717 0.245467 0.050 Uiso 1 1 calc R U . . .
C5 C 0.1918(3) 0.6905(3) 0.2919(2) 0.0359(8) Uani 1 1 d . . . . .
H5 H 0.191496 0.718461 0.355794 0.043 Uiso 1 1 calc R U . . .
C6 C 0.2842(3) 0.7182(2) 0.2674(2) 0.0280(7) Uani 1 1 d . . . . .
C7 C 0.3817(3) 0.7916(3) 0.3420(2) 0.0329(8) Uani 1 1 d . . . . .
H7A H 0.434478 0.764599 0.330791 0.049 Uiso 1 1 calc R U . . .
H7B H 0.369415 0.798115 0.403012 0.049 Uiso 1 1 calc R U . . .
H7C H 0.404839 0.860006 0.340597 0.049 Uiso 1 1 calc R U . . .
C8 C 0.4651(2) 0.8411(2) 0.17767(19) 0.0199(6) Uani 1 1 d D . . . .
C9 C 0.4038(3) 0.8863(2) 0.1531(2) 0.0263(7) Uani 1 1 d . . . . .
H9 H 0.333569 0.844958 0.122093 0.032 Uiso 1 1 calc R U . . .
C10 C 0.4450(3) 0.9917(3) 0.1739(2) 0.0339(8) Uani 1 1 d . . . . .
H10 H 0.403403 1.022211 0.156307 0.041 Uiso 1 1 calc R U . . .
C11 C 0.5467(3) 1.0517(3) 0.2202(2) 0.0357(8) Uani 1 1 d . . . . .
H11 H 0.575212 1.123613 0.233978 0.043 Uiso 1 1 calc R U . . .
C12 C 0.6077(3) 1.0077(3) 0.2467(2) 0.0321(7) Uani 1 1 d . . . . .
H12 H 0.677238 1.050502 0.279739 0.038 Uiso 1 1 calc R U . . .
C13 C 0.5690(2) 0.9019(2) 0.2259(2) 0.0245(6) Uani 1 1 d . . . . .
C14 C 0.6391(2) 0.8583(3) 0.2549(2) 0.0301(7) Uani 1 1 d . . . . .
H14A H 0.611231 0.825610 0.295250 0.045 Uiso 1 1 calc R U . . .
H14B H 0.706884 0.914471 0.288745 0.045 Uiso 1 1 calc R U . . .
H14C H 0.645057 0.806355 0.199465 0.045 Uiso 1 1 calc R U . . .
C15 C 0.5751(2) 0.7533(2) -0.00674(19) 0.0196(6) Uani 1 1 d D . . . .
C16 C 0.5479(2) 0.8337(2) -0.0065(2) 0.0232(6) Uani 1 1 d . . . . .
H16 H 0.477882 0.820857 -0.023960 0.028 Uiso 1 1 calc R U . . .
C17 C 0.6235(3) 0.9324(2) 0.0192(2) 0.0286(7) Uani 1 1 d . . . . .
H17 H 0.605262 0.987486 0.020441 0.034 Uiso 1 1 calc R U . . .
C18 C 0.7259(3) 0.9503(3) 0.0431(2) 0.0326(8) Uani 1 1 d . . . . .
H18 H 0.777429 1.018217 0.062533 0.039 Uiso 1 1 calc R U . . .
C19 C 0.7532(2) 0.8699(3) 0.0387(2) 0.0287(7) Uani 1 1 d . . . . .
H19 H 0.823442 0.882052 0.052485 0.034 Uiso 1 1 calc R U . . .
C20 C 0.6779(2) 0.7712(2) 0.0141(2) 0.0231(6) Uani 1 1 d . . . . .
H20 H 0.696715 0.716053 0.011435 0.028 Uiso 1 1 calc R U . . .
C21 C 0.4108(2) 0.4705(2) -0.35613(19) 0.0242(7) Uani 1 1 d D . . . .
C22 C 0.3189(3) 0.4808(2) -0.3703(2) 0.0300(7) Uani 1 1 d . . . . .
H22 H 0.299546 0.519636 -0.318764 0.036 Uiso 1 1 calc R U . . .
C23 C 0.2551(3) 0.4346(3) -0.4594(2) 0.0387(9) Uani 1 1 d . . . . .
H23 H 0.192303 0.441820 -0.468493 0.046 Uiso 1 1 calc R U . . .
C24 C 0.2828(3) 0.3787(3) -0.5343(2) 0.0442(10) Uani 1 1 d . . . . .
H24 H 0.238920 0.346336 -0.595081 0.053 Uiso 1 1 calc R U . . .
C25 C 0.3744(3) 0.3697(3) -0.5207(2) 0.0441(10) Uani 1 1 d . . . . .
H25 H 0.393278 0.331800 -0.573114 0.053 Uiso 1 1 calc R U . . .
C26 C 0.4405(3) 0.4144(3) -0.4326(2) 0.0318(8) Uani 1 1 d . . . . .
C27 C 0.5401(3) 0.4009(3) -0.4216(2) 0.0410(9) Uani 1 1 d . . . . .
H27A H 0.597894 0.468837 -0.397703 0.061 Uiso 1 1 calc R U . . .
H27B H 0.544038 0.355641 -0.482144 0.061 Uiso 1 1 calc R U . . .
H27C H 0.542579 0.369409 -0.377791 0.061 Uiso 1 1 calc R U . . .
C28 C 0.6113(6) 0.6199(7) -0.2244(7) 0.0259(18) Uani 0.629(8) 1 d . U P A 1
C29 C 0.6970(5) 0.6021(6) -0.1979(5) 0.0328(15) Uani 0.629(8) 1 d . U P A 1
H29 H 0.687985 0.539445 -0.192301 0.039 Uiso 0.629(8) 1 calc R U P A 1
C30 C 0.7934(5) 0.6755(6) -0.1804(4) 0.0455(17) Uani 0.629(8) 1 d . U P A 1
H30 H 0.851531 0.663857 -0.162675 0.055 Uiso 0.629(8) 1 calc R U P A 1
C31 C 0.8061(6) 0.7675(7) -0.1885(5) 0.043(2) Uani 0.629(8) 1 d . U P A 1
H31 H 0.873116 0.818469 -0.175936 0.052 Uiso 0.629(8) 1 calc R U P A 1
C32 C 0.7217(6) 0.7856(6) -0.2150(5) 0.0382(17) Uani 0.629(8) 1 d . U P A 1
H32 H 0.731986 0.848888 -0.219856 0.046 Uiso 0.629(8) 1 calc R U P A 1
C33 C 0.6230(6) 0.7125(6) -0.2342(6) 0.0279(15) Uani 0.629(8) 1 d . U P A 1
C34 C 0.5350(5) 0.7352(4) -0.2629(4) 0.0323(14) Uani 0.629(8) 1 d . U P A 1
H34A H 0.480988 0.671486 -0.311386 0.048 Uiso 0.629(8) 1 calc R U P A 1
H34B H 0.558054 0.787975 -0.287117 0.048 Uiso 0.629(8) 1 calc R U P A 1
H34C H 0.508263 0.760991 -0.208927 0.048 Uiso 0.629(8) 1 calc R U P A 1
C35 C 0.3714(2) 0.6474(2) 0.01272(18) 0.0184(6) Uani 1 1 d . . . . .
H35A H 0.310313 0.580709 -0.012210 0.022 Uiso 1 1 calc R U . . .
H35B H 0.353176 0.695997 -0.006319 0.022 Uiso 1 1 calc R U . . .
C36 C 0.4198(2) 0.5800(2) -0.16271(18) 0.0194(6) Uani 1 1 d . . . . .
H36A H 0.418862 0.639677 -0.174473 0.023 Uiso 1 1 calc R U . . .
H36B H 0.348070 0.529126 -0.179340 0.023 Uiso 1 1 calc R U . . .
C37 C 0.6342(2) 0.5971(2) 0.09517(19) 0.0188(6) Uani 1 1 d . . . . .
C38 C 0.7114(2) 0.6493(2) 0.1575(2) 0.0221(6) Uani 1 1 d . . . . .
C39 C 0.8017(2) 0.7093(2) 0.2339(2) 0.0226(6) Uani 1 1 d . . . . .
C40 C 0.7927(2) 0.7397(2) 0.3263(2) 0.0256(7) Uani 1 1 d . . . . .
H40 H 0.726586 0.722078 0.337803 0.031 Uiso 1 1 calc R U . . .
C41 C 0.8780(2) 0.7945(2) 0.4005(2) 0.0278(7) Uani 1 1 d . . . . .
H41 H 0.869960 0.813739 0.462268 0.033 Uiso 1 1 calc R U . . .
C42 C 0.9762(2) 0.8218(3) 0.3853(2) 0.0287(7) Uani 1 1 d . . . . .
C43 C 0.9854(2) 0.7920(3) 0.2934(2) 0.0307(7) Uani 1 1 d . . . . .
H43 H 1.051698 0.809906 0.282228 0.037 Uiso 1 1 calc R U . . .
C44 C 0.8999(2) 0.7368(3) 0.2181(2) 0.0280(7) Uani 1 1 d . . . . .
C45 C 0.9124(3) 0.7029(3) 0.1198(2) 0.0424(9) Uani 1 1 d . . . . .
H45A H 0.871356 0.628132 0.084652 0.064 Uiso 1 1 calc R U . . .
H45B H 0.984600 0.718012 0.121020 0.064 Uiso 1 1 calc R U . . .
H45C H 0.889284 0.740675 0.089854 0.064 Uiso 1 1 calc R U . . .
C46 C 1.1591(2) 0.9451(3) 0.4565(2) 0.0318(7) Uani 1 1 d . . . . .
C47 C 1.1631(3) 1.0084(3) 0.4104(2) 0.0361(8) Uani 1 1 d . . . . .
H47 H 1.101598 1.005256 0.379278 0.043 Uiso 1 1 calc R U . . .
C48 C 1.2570(3) 1.0762(3) 0.4099(3) 0.0476(10) Uani 1 1 d . . . . .
H48 H 1.259281 1.120003 0.379144 0.057 Uiso 1 1 calc R U . . .
C49 C 1.3479(3) 1.0806(4) 0.4540(3) 0.0549(11) Uani 1 1 d . . . . .
H49 H 1.412084 1.126198 0.452619 0.066 Uiso 1 1 calc R U . . .
C50 C 1.3433(3) 1.0175(3) 0.4998(3) 0.0500(11) Uani 1 1 d . . . . .
H50 H 1.405040 1.020956 0.531023 0.060 Uiso 1 1 calc R U . . .
C51 C 1.2501(3) 0.9492(3) 0.5010(2) 0.0385(8) Uani 1 1 d . . . . .
H51 H 1.248144 0.905514 0.531864 0.046 Uiso 1 1 calc R U . . .
C52 C 1.0551(2) 0.8739(3) 0.5491(2) 0.0329(8) Uani 1 1 d . . . . .
C53 C 1.0844(3) 0.9643(3) 0.6282(2) 0.0372(8) Uani 1 1 d . . . . .
H53 H 1.110530 1.029251 0.624398 0.045 Uiso 1 1 calc R U . . .
C54 C 1.0764(3) 0.9617(4) 0.7131(3) 0.0499(11) Uani 1 1 d . . . . .
H54 H 1.096737 1.024678 0.767299 0.060 Uiso 1 1 calc R U . . .
C55 C 1.0392(3) 0.8688(4) 0.7194(3) 0.0568(12) Uani 1 1 d . . . . .
H55 H 1.034584 0.867403 0.778055 0.068 Uiso 1 1 calc R U . . .
C56 C 1.0082(3) 0.7765(4) 0.6403(3) 0.0556(12) Uani 1 1 d . . . . .
H56 H 0.981503 0.711824 0.644551 0.067 Uiso 1 1 calc R U . . .
C57 C 1.0166(3) 0.7794(3) 0.5548(3) 0.0444(9) Uani 1 1 d . . . . .
H57 H 0.995813 0.716540 0.500378 0.053 Uiso 1 1 calc R U . . .
N1 N 1.0635(2) 0.8771(2) 0.46081(19) 0.0343(7) Uani 1 1 d . . . . .
P1 P 0.48940(6) 0.51925(6) -0.23863(5) 0.02080(16) Uani 1 1 d D . . . .
P2 P 0.47446(6) 0.62552(6) -0.03857(5) 0.01654(15) Uani 1 1 d D . . . .
P3 P 0.40543(6) 0.70080(6) 0.14073(5) 0.01789(15) Uani 1 1 d D . . . .
Pt1 Pt 0.500000 0.500000 0.000000 0.01518(5) Uani 1 2 d S . P . .
C58 C 0.7983(4) 1.3347(4) 0.4276(3) 0.0594(12) Uani 1 1 d . . . . .
H58A H 0.783035 1.371163 0.391135 0.071 Uiso 1 1 calc R U . . .
H58B H 0.828514 1.288307 0.391277 0.071 Uiso 1 1 calc R U . . .
Cl3 Cl 0.88749(11) 1.42688(10) 0.53426(9) 0.0778(4) Uani 1 1 d . . . . .
Cl4 Cl 0.68497(10) 1.26042(10) 0.44474(8) 0.0624(3) Uani 1 1 d . . . . .
C59 C 1.1247(4) 0.8621(4) 0.0504(3) 0.0613(12) Uani 1 1 d . . . . .
H59A H 1.185243 0.880503 0.024979 0.074 Uiso 1 1 calc R U . . .
H59B H 1.093266 0.785608 0.028017 0.074 Uiso 1 1 calc R U . . .
Cl1 Cl 1.03635(9) 0.90231(12) 0.00941(9) 0.0715(4) Uani 1 1 d . . . . .
Cl2 Cl 1.16412(8) 0.92044(8) 0.17310(8) 0.0535(3) Uani 1 1 d . . . . .
C60 C 0.8706(3) 0.3787(3) 0.1884(3) 0.0453(9) Uani 1 1 d . . . . .
F1 F 0.91664(19) 0.43337(19) 0.27901(16) 0.0622(7) Uani 1 1 d . . . . .
F2 F 0.94141(19) 0.3603(2) 0.1451(2) 0.0751(8) Uani 1 1 d . . . . .
F3 F 0.84192(19) 0.44103(18) 0.16011(17) 0.0604(7) Uani 1 1 d . . . . .
O1 O 0.72244(19) 0.21441(19) 0.06618(16) 0.0382(6) Uani 1 1 d . . . . .
O2 O 0.69728(19) 0.29586(19) 0.21858(17) 0.0372(6) Uani 1 1 d . . . . .
O3 O 0.8081(2) 0.2040(2) 0.19942(19) 0.0490(7) Uani 1 1 d . . . . .
S06 S 0.76213(6) 0.25885(6) 0.16545(6) 0.02977(18) Uani 1 1 d . . . . .
C28A C 0.6072(5) 0.6340(7) -0.2243(10) 0.025(3) Uani 0.371(8) 1 d DG U P A 2
C32A C 0.7067(7) 0.6432(6) -0.2007(8) 0.027(2) Uani 0.371(8) 1 d G U P A 2
C31A C 0.7888(5) 0.7299(7) -0.1941(7) 0.033(3) Uani 0.371(8) 1 d G U P A 2
H31A H 0.856775 0.736143 -0.177939 0.040 Uiso 0.371(8) 1 calc R U P A 2
C29A C 0.7713(6) 0.8074(5) -0.2112(6) 0.031(3) Uani 0.371(8) 1 d G U P A 2
H29A H 0.827350 0.866640 -0.206701 0.037 Uiso 0.371(8) 1 calc R U P A 2
C30A C 0.6718(7) 0.7982(5) -0.2349(5) 0.030(2) Uani 0.371(8) 1 d G U P A 2
H30A H 0.659841 0.851181 -0.246532 0.036 Uiso 0.371(8) 1 calc R U P A 2
C33A C 0.5898(5) 0.7115(8) -0.2414(9) 0.026(3) Uani 0.371(8) 1 d G U P A 2
H33A H 0.521756 0.705224 -0.257602 0.031 Uiso 0.371(8) 1 calc R U P A 2
C34A C 0.7349(8) 0.5642(8) -0.1799(7) 0.038(3) Uani 0.371(8) 1 d . U P A 2
H34D H 0.718510 0.563761 -0.121644 0.057 Uiso 0.371(8) 1 calc R U P A 2
H34E H 0.808357 0.582568 -0.173883 0.057 Uiso 0.371(8) 1 calc R U P A 2
H34F H 0.696150 0.495012 -0.230840 0.057 Uiso 0.371(8) 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C37 2.663(3) . ?
Ag1 P1 2.4300(8) 2_665 ?
Ag1 P3 2.4169(7) . ?
Ag1 Pt1 2.9074(3) . ?
C1 C2 1.388(4) . ?
C1 C6 1.415(4) . ?
C1 P3 1.828(3) . ?
C2 H2 0.9500 . ?
C2 C3 1.388(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.381(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.375(5) . ?
C5 H5 0.9500 . ?
C5 C6 1.387(5) . ?
C6 C7 1.506(4) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 C9 1.393(4) . ?
C8 C13 1.411(4) . ?
C8 P3 1.825(3) . ?
C9 H9 0.9500 . ?
C9 C10 1.389(4) . ?
C10 H10 0.9500 . ?
C10 C11 1.380(5) . ?
C11 H11 0.9500 . ?
C11 C12 1.387(5) . ?
C12 H12 0.9500 . ?
C12 C13 1.395(4) . ?
C13 C14 1.503(4) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C16 1.399(4) . ?
C15 C20 1.391(4) . ?
C15 P2 1.819(3) . ?
C16 H16 0.9500 . ?
C16 C17 1.390(4) . ?
C17 H17 0.9500 . ?
C17 C18 1.389(5) . ?
C18 H18 0.9500 . ?
C18 C19 1.382(5) . ?
C19 H19 0.9500 . ?
C19 C20 1.392(4) . ?
C20 H20 0.9500 . ?
C21 C22 1.389(5) . ?
C21 C26 1.408(4) . ?
C21 P1 1.830(3) . ?
C22 H22 0.9500 . ?
C22 C23 1.393(4) . ?
C23 H23 0.9500 . ?
C23 C24 1.373(5) . ?
C24 H24 0.9500 . ?
C24 C25 1.375(6) . ?
C25 H25 0.9500 . ?
C25 C26 1.396(5) . ?
C26 C27 1.518(5) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 C29 1.409(10) . ?
C28 C33 1.418(9) . ?
C28 P1 1.810(7) . ?
C29 H29 0.9500 . ?
C29 C30 1.368(9) . ?
C30 H30 0.9500 . ?
C30 C31 1.395(10) . ?
C31 H31 0.9500 . ?
C31 C32 1.392(11) . ?
C32 H32 0.9500 . ?
C32 C33 1.387(9) . ?
C33 C34 1.493(9) . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C35 P2 1.828(3) . ?
C35 P3 1.842(3) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C36 P1 1.834(3) . ?
C36 P2 1.829(3) . ?
C37 C38 1.209(4) . ?
C37 Pt1 2.015(3) . ?
C38 C39 1.442(4) . ?
C39 C40 1.406(4) . ?
C39 C44 1.403(4) . ?
C40 H40 0.9500 . ?
C40 C41 1.380(4) . ?
C41 H41 0.9500 . ?
C41 C42 1.400(5) . ?
C42 C43 1.399(5) . ?
C42 N1 1.408(4) . ?
C43 H43 0.9500 . ?
C43 C44 1.392(4) . ?
C44 C45 1.509(5) . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 C47 1.390(5) . ?
C46 C51 1.399(5) . ?
C46 N1 1.431(4) . ?
C47 H47 0.9500 . ?
C47 C48 1.388(5) . ?
C48 H48 0.9500 . ?
C48 C49 1.392(6) . ?
C49 H49 0.9500 . ?
C49 C50 1.385(6) . ?
C50 H50 0.9500 . ?
C50 C51 1.389(5) . ?
C51 H51 0.9500 . ?
C52 C53 1.373(5) . ?
C52 C57 1.384(5) . ?
C52 N1 1.438(4) . ?
C53 H53 0.9500 . ?
C53 C54 1.381(5) . ?
C54 H54 0.9500 . ?
C54 C55 1.364(6) . ?
C55 H55 0.9500 . ?
C55 C56 1.387(7) . ?
C56 H56 0.9500 . ?
C56 C57 1.393(6) . ?
C57 H57 0.9500 . ?
P1 C28A 1.884(5) . ?
P2 Pt1 2.3228(7) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C58 Cl3 1.765(5) . ?
C58 Cl4 1.742(5) . ?
C59 H59A 0.9900 . ?
C59 H59B 0.9900 . ?
C59 Cl1 1.753(5) . ?
C59 Cl2 1.764(5) . ?
C60 F1 1.335(4) . ?
C60 F2 1.333(5) . ?
C60 F3 1.342(4) . ?
C60 S06 1.821(4) . ?
O1 S06 1.439(2) . ?
O2 S06 1.436(3) . ?
O3 S06 1.432(2) . ?
C28A C32A 1.3900 . ?
C28A C33A 1.3900 . ?
C32A C31A 1.3900 . ?
C32A C34A 1.515(11) . ?
C31A H31A 0.9500 . ?
C31A C29A 1.3900 . ?
C29A H29A 0.9500 . ?
C29A C30A 1.3900 . ?
C30A H30A 0.9500 . ?
C30A C33A 1.3900 . ?
C33A H33A 0.9500 . ?
C34A H34D 0.9800 . ?
C34A H34E 0.9800 . ?
C34A H34F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C37 Ag1 Pt1 42.12(6) . . ?
P1 Ag1 C37 89.92(6) 2_665 . ?
P1 Ag1 Pt1 93.62(2) 2_665 . ?
P3 Ag1 C37 108.38(6) . . ?
P3 Ag1 P1 157.08(3) . 2_665 ?
P3 Ag1 Pt1 91.188(19) . . ?
C2 C1 C6 119.6(3) . . ?
C2 C1 P3 122.3(2) . . ?
C6 C1 P3 117.9(2) . . ?
C1 C2 H2 119.5 . . ?
C1 C2 C3 121.0(3) . . ?
C3 C2 H2 119.5 . . ?
C2 C3 H3 120.3 . . ?
C4 C3 C2 119.4(3) . . ?
C4 C3 H3 120.3 . . ?
C3 C4 H4 119.9 . . ?
C5 C4 C3 120.1(3) . . ?
C5 C4 H4 119.9 . . ?
C4 C5 H5 119.1 . . ?
C4 C5 C6 121.9(3) . . ?
C6 C5 H5 119.1 . . ?
C1 C6 C7 122.3(3) . . ?
C5 C6 C1 118.0(3) . . ?
C5 C6 C7 119.7(3) . . ?
C6 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
C6 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C9 C8 C13 120.6(3) . . ?
C9 C8 P3 116.7(2) . . ?
C13 C8 P3 122.7(2) . . ?
C8 C9 H9 119.9 . . ?
C10 C9 C8 120.3(3) . . ?
C10 C9 H9 119.9 . . ?
C9 C10 H10 120.2 . . ?
C11 C10 C9 119.6(3) . . ?
C11 C10 H10 120.2 . . ?
C10 C11 H11 119.7 . . ?
C10 C11 C12 120.5(3) . . ?
C12 C11 H11 119.7 . . ?
C11 C12 H12 119.4 . . ?
C11 C12 C13 121.2(3) . . ?
C13 C12 H12 119.4 . . ?
C8 C13 C14 123.3(3) . . ?
C12 C13 C8 117.8(3) . . ?
C12 C13 C14 118.9(3) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 P2 118.9(2) . . ?
C20 C15 C16 119.7(3) . . ?
C20 C15 P2 121.3(2) . . ?
C15 C16 H16 120.0 . . ?
C17 C16 C15 119.9(3) . . ?
C17 C16 H16 120.0 . . ?
C16 C17 H17 120.1 . . ?
C18 C17 C16 119.8(3) . . ?
C18 C17 H17 120.1 . . ?
C17 C18 H18 119.8 . . ?
C19 C18 C17 120.5(3) . . ?
C19 C18 H18 119.8 . . ?
C18 C19 H19 120.0 . . ?
C18 C19 C20 120.0(3) . . ?
C20 C19 H19 120.0 . . ?
C15 C20 C19 120.0(3) . . ?
C15 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C22 C21 C26 119.9(3) . . ?
C22 C21 P1 121.1(2) . . ?
C26 C21 P1 118.8(2) . . ?
C21 C22 H22 119.8 . . ?
C21 C22 C23 120.5(3) . . ?
C23 C22 H22 119.8 . . ?
C22 C23 H23 120.0 . . ?
C24 C23 C22 120.1(4) . . ?
C24 C23 H23 120.0 . . ?
C23 C24 H24 120.2 . . ?
C23 C24 C25 119.6(3) . . ?
C25 C24 H24 120.2 . . ?
C24 C25 H25 118.9 . . ?
C24 C25 C26 122.3(3) . . ?
C26 C25 H25 118.9 . . ?
C21 C26 C27 122.3(3) . . ?
C25 C26 C21 117.7(3) . . ?
C25 C26 C27 120.0(3) . . ?
C26 C27 H27A 109.5 . . ?
C26 C27 H27B 109.5 . . ?
C26 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C29 C28 C33 121.1(6) . . ?
C29 C28 P1 114.5(6) . . ?
C33 C28 P1 124.4(6) . . ?
C28 C29 H29 120.1 . . ?
C30 C29 C28 119.7(7) . . ?
C30 C29 H29 120.1 . . ?
C29 C30 H30 120.1 . . ?
C29 C30 C31 119.8(7) . . ?
C31 C30 H30 120.1 . . ?
C30 C31 H31 119.6 . . ?
C32 C31 C30 120.8(7) . . ?
C32 C31 H31 119.6 . . ?
C31 C32 H32 119.5 . . ?
C33 C32 C31 120.9(7) . . ?
C33 C32 H32 119.5 . . ?
C28 C33 C34 123.5(6) . . ?
C32 C33 C28 117.6(7) . . ?
C32 C33 C34 118.9(7) . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34B 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
H35A C35 H35B 107.7 . . ?
P2 C35 H35A 108.9 . . ?
P2 C35 H35B 108.9 . . ?
P2 C35 P3 113.21(14) . . ?
P3 C35 H35A 108.9 . . ?
P3 C35 H35B 108.9 . . ?
H36A C36 H36B 107.7 . . ?
P1 C36 H36A 108.8 . . ?
P1 C36 H36B 108.8 . . ?
P2 C36 H36A 108.8 . . ?
P2 C36 H36B 108.8 . . ?
P2 C36 P1 113.94(15) . . ?
C38 C37 Ag1 100.7(2) . . ?
C38 C37 Pt1 173.2(2) . . ?
Pt1 C37 Ag1 75.45(9) . . ?
C37 C38 C39 177.8(3) . . ?
C40 C39 C38 120.2(3) . . ?
C44 C39 C38 121.2(3) . . ?
C44 C39 C40 118.6(3) . . ?
C39 C40 H40 119.3 . . ?
C41 C40 C39 121.3(3) . . ?
C41 C40 H40 119.3 . . ?
C40 C41 H41 119.8 . . ?
C40 C41 C42 120.4(3) . . ?
C42 C41 H41 119.8 . . ?
C41 C42 N1 120.6(3) . . ?
C43 C42 C41 118.4(3) . . ?
C43 C42 N1 121.0(3) . . ?
C42 C43 H43 119.2 . . ?
C44 C43 C42 121.7(3) . . ?
C44 C43 H43 119.2 . . ?
C39 C44 C45 120.0(3) . . ?
C43 C44 C39 119.6(3) . . ?
C43 C44 C45 120.4(3) . . ?
C44 C45 H45A 109.5 . . ?
C44 C45 H45B 109.5 . . ?
C44 C45 H45C 109.5 . . ?
H45A C45 H45B 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C47 C46 C51 119.5(3) . . ?
C47 C46 N1 121.3(3) . . ?
C51 C46 N1 119.2(3) . . ?
C46 C47 H47 120.0 . . ?
C48 C47 C46 120.1(3) . . ?
C48 C47 H47 120.0 . . ?
C47 C48 H48 119.7 . . ?
C47 C48 C49 120.7(4) . . ?
C49 C48 H48 119.7 . . ?
C48 C49 H49 120.5 . . ?
C50 C49 C48 118.9(4) . . ?
C50 C49 H49 120.5 . . ?
C49 C50 H50 119.4 . . ?
C49 C50 C51 121.1(4) . . ?
C51 C50 H50 119.4 . . ?
C46 C51 H51 120.2 . . ?
C50 C51 C46 119.6(4) . . ?
C50 C51 H51 120.2 . . ?
C53 C52 C57 119.5(3) . . ?
C53 C52 N1 120.5(3) . . ?
C57 C52 N1 120.0(3) . . ?
C52 C53 H53 119.7 . . ?
C52 C53 C54 120.7(4) . . ?
C54 C53 H53 119.7 . . ?
C53 C54 H54 119.9 . . ?
C55 C54 C53 120.1(4) . . ?
C55 C54 H54 119.9 . . ?
C54 C55 H55 119.9 . . ?
C54 C55 C56 120.2(4) . . ?
C56 C55 H55 119.9 . . ?
C55 C56 H56 120.2 . . ?
C55 C56 C57 119.5(4) . . ?
C57 C56 H56 120.2 . . ?
C52 C57 C56 119.9(4) . . ?
C52 C57 H57 120.0 . . ?
C56 C57 H57 120.0 . . ?
C42 N1 C46 122.6(3) . . ?
C42 N1 C52 119.5(3) . . ?
C46 N1 C52 117.6(3) . . ?
C21 P1 Ag1 116.56(10) . 2_665 ?
C21 P1 C36 103.87(14) . . ?
C21 P1 C28A 106.1(4) . . ?
C28 P1 Ag1 112.8(3) . 2_665 ?
C28 P1 C21 108.7(3) . . ?
C28 P1 C36 108.1(3) . . ?
C36 P1 Ag1 106.07(9) . 2_665 ?
C36 P1 C28A 102.9(4) . . ?
C15 P2 C35 106.46(14) . . ?
C15 P2 C36 103.69(13) . . ?
C15 P2 Pt1 123.04(10) . . ?
C35 P2 C36 102.32(13) . . ?
C35 P2 Pt1 105.55(9) . . ?
C36 P2 Pt1 113.76(10) . . ?
C1 P3 Ag1 110.65(9) . . ?
C1 P3 C35 104.54(13) . . ?
C8 P3 Ag1 121.84(10) . . ?
C8 P3 C1 104.96(13) . . ?
C8 P3 C35 103.89(13) . . ?
C35 P3 Ag1 109.50(9) . . ?
Ag1 Pt1 Ag1 180.0 . 2_665 ?
C37 Pt1 Ag1 117.57(8) . 2_665 ?
C37 Pt1 Ag1 62.43(8) . . ?
C37 Pt1 Ag1 117.57(8) 2_665 . ?
C37 Pt1 Ag1 62.43(8) 2_665 2_665 ?
C37 Pt1 C37 180.00(16) 2_665 . ?
C37 Pt1 P2 84.12(8) . 2_665 ?
C37 Pt1 P2 95.88(8) 2_665 2_665 ?
C37 Pt1 P2 84.12(8) 2_665 . ?
C37 Pt1 P2 95.88(8) . . ?
P2 Pt1 Ag1 90.154(19) . 2_665 ?
P2 Pt1 Ag1 89.846(19) . . ?
P2 Pt1 Ag1 90.156(19) 2_665 . ?
P2 Pt1 Ag1 89.844(19) 2_665 2_665 ?
P2 Pt1 P2 180.0 2_665 . ?
H58A C58 H58B 108.0 . . ?
Cl3 C58 H58A 109.3 . . ?
Cl3 C58 H58B 109.3 . . ?
Cl4 C58 H58A 109.3 . . ?
Cl4 C58 H58B 109.3 . . ?
Cl4 C58 Cl3 111.7(2) . . ?
H59A C59 H59B 107.9 . . ?
Cl1 C59 H59A 109.3 . . ?
Cl1 C59 H59B 109.3 . . ?
Cl1 C59 Cl2 111.7(3) . . ?
Cl2 C59 H59A 109.3 . . ?
Cl2 C59 H59B 109.3 . . ?
F1 C60 F3 106.7(3) . . ?
F1 C60 S06 111.9(3) . . ?
F2 C60 F1 107.0(3) . . ?
F2 C60 F3 107.5(3) . . ?
F2 C60 S06 111.8(3) . . ?
F3 C60 S06 111.6(3) . . ?
O1 S06 C60 103.02(16) . . ?
O2 S06 C60 102.60(17) . . ?
O2 S06 O1 114.38(15) . . ?
O3 S06 C60 103.04(18) . . ?
O3 S06 O1 115.87(16) . . ?
O3 S06 O2 115.27(16) . . ?
C32A C28A P1 124.3(5) . . ?
C32A C28A C33A 120.0 . . ?
C33A C28A P1 115.7(5) . . ?
C28A C32A C34A 124.6(7) . . ?
C31A C32A C28A 120.0 . . ?
C31A C32A C34A 115.4(7) . . ?
C32A C31A H31A 120.0 . . ?
C32A C31A C29A 120.0 . . ?
C29A C31A H31A 120.0 . . ?
C31A C29A H29A 120.0 . . ?
C30A C29A C31A 120.0 . . ?
C30A C29A H29A 120.0 . . ?
C29A C30A H30A 120.0 . . ?
C33A C30A C29A 120.0 . . ?
C33A C30A H30A 120.0 . . ?
C28A C33A H33A 120.0 . . ?
C30A C33A C28A 120.0 . . ?
C30A C33A H33A 120.0 . . ?
C32A C34A H34D 109.5 . . ?
C32A C34A H34E 109.5 . . ?
C32A C34A H34F 109.5 . . ?
H34D C34A H34E 109.5 . . ?
H34D C34A H34F 109.5 . . ?
H34E C34A H34F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 P1 C28A C32A 10.4(10) 2_665 . . . ?
Ag1 P1 C28A C33A -171.2(3) 2_665 . . . ?
C1 C2 C3 C4 1.1(6) . . . . ?
C2 C1 C6 C5 0.8(4) . . . . ?
C2 C1 C6 C7 -178.9(3) . . . . ?
C2 C1 P3 Ag1 -105.3(2) . . . . ?
C2 C1 P3 C8 121.5(3) . . . . ?
C2 C1 P3 C35 12.5(3) . . . . ?
C2 C3 C4 C5 0.0(6) . . . . ?
C3 C4 C5 C6 -0.7(6) . . . . ?
C4 C5 C6 C1 0.3(5) . . . . ?
C4 C5 C6 C7 180.0(3) . . . . ?
C6 C1 C2 C3 -1.5(5) . . . . ?
C6 C1 P3 Ag1 68.6(2) . . . . ?
C6 C1 P3 C8 -64.5(2) . . . . ?
C6 C1 P3 C35 -173.6(2) . . . . ?
C8 C9 C10 C11 -0.9(5) . . . . ?
C9 C8 C13 C12 -0.8(4) . . . . ?
C9 C8 C13 C14 179.7(3) . . . . ?
C9 C8 P3 Ag1 -173.45(19) . . . . ?
C9 C8 P3 C1 -46.9(3) . . . . ?
C9 C8 P3 C35 62.6(3) . . . . ?
C9 C10 C11 C12 -0.5(5) . . . . ?
C10 C11 C12 C13 1.4(5) . . . . ?
C11 C12 C13 C8 -0.7(5) . . . . ?
C11 C12 C13 C14 178.9(3) . . . . ?
C13 C8 C9 C10 1.6(4) . . . . ?
C13 C8 P3 Ag1 8.8(3) . . . . ?
C13 C8 P3 C1 135.3(2) . . . . ?
C13 C8 P3 C35 -115.2(2) . . . . ?
C15 C16 C17 C18 1.1(4) . . . . ?
C16 C15 C20 C19 2.7(4) . . . . ?
C16 C15 P2 C35 -38.8(2) . . . . ?
C16 C15 P2 C36 68.7(2) . . . . ?
C16 C15 P2 Pt1 -160.55(18) . . . . ?
C16 C17 C18 C19 2.0(5) . . . . ?
C17 C18 C19 C20 -2.8(5) . . . . ?
C18 C19 C20 C15 0.4(4) . . . . ?
C20 C15 C16 C17 -3.4(4) . . . . ?
C20 C15 P2 C35 143.4(2) . . . . ?
C20 C15 P2 C36 -109.0(2) . . . . ?
C20 C15 P2 Pt1 21.7(3) . . . . ?
C21 C22 C23 C24 -0.2(5) . . . . ?
C21 P1 C28A C32A -123.8(7) . . . . ?
C21 P1 C28A C33A 54.6(6) . . . . ?
C22 C21 C26 C25 -0.8(5) . . . . ?
C22 C21 C26 C27 179.8(3) . . . . ?
C22 C21 P1 Ag1 113.9(2) . . . 2_665 ?
C22 C21 P1 C28 -117.3(4) . . . . ?
C22 C21 P1 C36 -2.4(3) . . . . ?
C22 C21 P1 C28A -110.5(5) . . . . ?
C22 C23 C24 C25 -0.8(6) . . . . ?
C23 C24 C25 C26 1.0(6) . . . . ?
C24 C25 C26 C21 -0.2(5) . . . . ?
C24 C25 C26 C27 179.2(3) . . . . ?
C26 C21 C22 C23 1.0(5) . . . . ?
C26 C21 P1 Ag1 -61.0(3) . . . 2_665 ?
C26 C21 P1 C28 67.9(4) . . . . ?
C26 C21 P1 C36 -177.2(2) . . . . ?
C26 C21 P1 C28A 74.7(5) . . . . ?
C28 C29 C30 C31 0.2(10) . . . . ?
C29 C28 C33 C32 -1.2(9) . . . . ?
C29 C28 C33 C34 179.4(8) . . . . ?
C29 C28 P1 Ag1 6.9(7) . . . 2_665 ?
C29 C28 P1 C21 -124.0(5) . . . . ?
C29 C28 P1 C36 123.9(5) . . . . ?
C29 C30 C31 C32 -0.4(11) . . . . ?
C30 C31 C32 C33 -0.3(11) . . . . ?
C31 C32 C33 C28 1.1(9) . . . . ?
C31 C32 C33 C34 -179.6(7) . . . . ?
C33 C28 C29 C30 0.6(9) . . . . ?
C33 C28 P1 Ag1 -170.2(5) . . . 2_665 ?
C33 C28 P1 C21 58.9(7) . . . . ?
C33 C28 P1 C36 -53.2(7) . . . . ?
C36 P1 C28A C32A 127.4(7) . . . . ?
C36 P1 C28A C33A -54.2(5) . . . . ?
C38 C39 C40 C41 178.1(3) . . . . ?
C38 C39 C44 C43 -178.0(3) . . . . ?
C38 C39 C44 C45 -0.4(5) . . . . ?
C39 C40 C41 C42 0.4(5) . . . . ?
C40 C39 C44 C43 0.7(4) . . . . ?
C40 C39 C44 C45 178.3(3) . . . . ?
C40 C41 C42 C43 -0.2(5) . . . . ?
C40 C41 C42 N1 -179.5(3) . . . . ?
C41 C42 C43 C44 0.3(5) . . . . ?
C41 C42 N1 C46 -151.8(3) . . . . ?
C41 C42 N1 C52 22.0(5) . . . . ?
C42 C43 C44 C39 -0.5(5) . . . . ?
C42 C43 C44 C45 -178.1(3) . . . . ?
C43 C42 N1 C46 28.9(5) . . . . ?
C43 C42 N1 C52 -157.3(3) . . . . ?
C44 C39 C40 C41 -0.6(4) . . . . ?
C46 C47 C48 C49 1.0(6) . . . . ?
C47 C46 C51 C50 0.9(5) . . . . ?
C47 C46 N1 C42 38.6(5) . . . . ?
C47 C46 N1 C52 -135.3(3) . . . . ?
C47 C48 C49 C50 -1.1(6) . . . . ?
C48 C49 C50 C51 1.1(6) . . . . ?
C49 C50 C51 C46 -1.1(6) . . . . ?
C51 C46 C47 C48 -0.9(5) . . . . ?
C51 C46 N1 C42 -142.6(3) . . . . ?
C51 C46 N1 C52 43.5(4) . . . . ?
C52 C53 C54 C55 0.1(6) . . . . ?
C53 C52 C57 C56 -0.3(5) . . . . ?
C53 C52 N1 C42 -124.2(3) . . . . ?
C53 C52 N1 C46 49.9(4) . . . . ?
C53 C54 C55 C56 -0.8(6) . . . . ?
C54 C55 C56 C57 0.8(6) . . . . ?
C55 C56 C57 C52 -0.3(6) . . . . ?
C57 C52 C53 C54 0.4(5) . . . . ?
C57 C52 N1 C42 55.2(4) . . . . ?
C57 C52 N1 C46 -130.7(3) . . . . ?
N1 C42 C43 C44 179.6(3) . . . . ?
N1 C46 C47 C48 177.9(3) . . . . ?
N1 C46 C51 C50 -177.8(3) . . . . ?
N1 C52 C53 C54 179.8(3) . . . . ?
N1 C52 C57 C56 -179.8(3) . . . . ?
P1 C21 C22 C23 -173.7(2) . . . . ?
P1 C21 C26 C25 174.1(2) . . . . ?
P1 C21 C26 C27 -5.4(4) . . . . ?
P1 C28 C29 C30 -176.6(6) . . . . ?
P1 C28 C33 C32 175.7(8) . . . . ?
P1 C28 C33 C34 -3.6(9) . . . . ?
P1 C36 P2 C15 84.11(18) . . . . ?
P1 C36 P2 C35 -165.30(15) . . . . ?
P1 C36 P2 Pt1 -51.97(17) . . . . ?
P1 C28A C32A C31A 178.4(11) . . . . ?
P1 C28A C32A C34A -2.1(10) . . . . ?
P1 C28A C33A C30A -178.5(10) . . . . ?
P2 C15 C16 C17 178.8(2) . . . . ?
P2 C15 C20 C19 -179.6(2) . . . . ?
P2 C35 P3 Ag1 -43.54(16) . . . . ?
P2 C35 P3 C1 -162.13(15) . . . . ?
P2 C35 P3 C8 88.07(17) . . . . ?
P2 C36 P1 Ag1 50.99(17) . . . 2_665 ?
P2 C36 P1 C21 174.38(15) . . . . ?
P2 C36 P1 C28 -70.2(3) . . . . ?
P2 C36 P1 C28A -75.2(4) . . . . ?
P3 C1 C2 C3 172.3(3) . . . . ?
P3 C1 C6 C5 -173.3(2) . . . . ?
P3 C1 C6 C7 7.0(4) . . . . ?
P3 C8 C9 C10 -176.3(2) . . . . ?
P3 C8 C13 C12 177.0(2) . . . . ?
P3 C8 C13 C14 -2.6(4) . . . . ?
P3 C35 P2 C15 -68.70(17) . . . . ?
P3 C35 P2 C36 -177.19(15) . . . . ?
P3 C35 P2 Pt1 63.54(15) . . . . ?
F1 C60 S06 O1 178.3(3) . . . . ?
F1 C60 S06 O2 59.2(3) . . . . ?
F1 C60 S06 O3 -60.8(3) . . . . ?
F2 C60 S06 O1 -61.7(3) . . . . ?
F2 C60 S06 O2 179.3(3) . . . . ?
F2 C60 S06 O3 59.2(3) . . . . ?
F3 C60 S06 O1 58.8(3) . . . . ?
F3 C60 S06 O2 -60.3(3) . . . . ?
F3 C60 S06 O3 179.6(3) . . . . ?
C28A C32A C31A C29A 0.0 . . . . ?
C32A C28A C33A C30A 0.0 . . . . ?
C32A C31A C29A C30A 0.0 . . . . ?
C31A C29A C30A C33A 0.0 . . . . ?
C29A C30A C33A C28A 0.0 . . . . ?
C33A C28A C32A C31A 0.0 . . . . ?
C33A C28A C32A C34A 179.5(10) . . . . ?
C34A C32A C31A C29A -179.6(9) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
