# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_MHT-1
_database_code_depnum_ccdc_archive 'CCDC 2048935'
loop_
_audit_author_name
_audit_author_address
MHT
;Nankai University
China
;
_audit_update_record             
;
2020-12-08 deposited with the CCDC.	2021-06-17 downloaded from the CCDC.
;
_audit_creation_date             2020-12-08
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C27 H21 Eu O9'
_chemical_formula_sum            'C27 H21 Eu O9'
_chemical_formula_weight         641.40
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C Eu'
_chemical_oxdiff_usercomment     xh-1124-100-8
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'

_cell_length_a                   26.9686(10)
_cell_length_b                   7.3840(4)
_cell_length_c                   34.6549(13)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     6901.0(5)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    6317
_cell_measurement_temperature    123.1(2)
_cell_measurement_theta_max      27.7700
_cell_measurement_theta_min      3.2780
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.857
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.79991
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.235
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             2544
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0446
_diffrn_reflns_av_unetI/netI     0.0511
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -41
_diffrn_reflns_number            20462
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        24.996
_diffrn_reflns_theta_max         24.996
_diffrn_reflns_theta_min         2.920
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      123.1(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.2116
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω      1.00  52.00   1.00   70.00    --   18.94  57.00   0.00   51
  2  ω    -11.00  36.00   1.00   70.00    --  -19.25  19.00 -90.00   47
  3  ω      1.00  28.00   1.00   70.00    --   18.94 -99.00  90.00   27
  4  ω    -20.00  45.00   1.00   70.00    --   18.94 -37.00  90.00   65
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Single source at offset, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0229601000
_diffrn_orient_matrix_UB_12      0.0098532000
_diffrn_orient_matrix_UB_13      0.0097840000
_diffrn_orient_matrix_UB_21      0.0128672000
_diffrn_orient_matrix_UB_22      -0.0192413000
_diffrn_orient_matrix_UB_23      -0.0173727000
_diffrn_orient_matrix_UB_31      0.0002050000
_diffrn_orient_matrix_UB_32      0.0936132000
_diffrn_orient_matrix_UB_33      -0.0045919000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4877
_reflns_number_total             6059
_reflns_odcompleteness_completeness 99.39
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    ?
_refine_diff_density_max         1.252
_refine_diff_density_min         -2.606
_refine_diff_density_rms         0.141
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.145
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     335
_refine_ls_number_reflns         6059
_refine_ls_number_restraints     114
_refine_ls_R_factor_all          0.0672
_refine_ls_R_factor_gt           0.0531
_refine_ls_restrained_S_all      1.138
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0222P)²+55.2950P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1050
_refine_ls_wR_factor_ref         0.1110
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
C16 \\sim C18 \\sim C17 \\sim C14 \\sim C15: within 2A with sigma of 0.005 and
sigma for terminal atoms of 3.8
C26 \\sim C23 \\sim C22 \\sim C21 \\sim C24 \\sim C25 \\sim C10 \\sim C9 \\sim
C11 \\sim C12 \\sim C13 \\sim C8: within 2A with sigma of 0.005 and sigma for
terminal atoms of 3.8
C2 \\sim C5 \\sim C3: within 2A with sigma of 0.005 and sigma for terminal
atoms of 3.8
3.a Riding coordinates:
 O8(H8A,H8B), O9(H9B,H9A)
3.b Rotating group:
 O7(H7A,H7B)
3.c Aromatic/amide H refined with riding coordinates:
 C25(H25), C22(H22), C24(H24), C23(H23), C9(H9), C13(H13), C3(H3), C5(H5),
 C16(H16), C18(H18), C17(H17), C15(H15), C11(H11), C4(H4), C6(H6)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu -0.15360(2) -0.15064(4) -0.12220(2) 0.01116(10) Uani 1 1 d . . . . .
O5 O 0.34722(16) 0.6451(7) 0.05078(11) 0.0184(10) Uani 1 1 d . . . . .
O4 O 0.34347(16) 0.7111(6) -0.31386(11) 0.0165(10) Uani 1 1 d . . . . .
O7 O -0.17733(17) 0.1493(6) -0.14214(12) 0.0219(10) Uani 1 1 d . . . . .
H7A H -0.1645 0.2316 -0.1266 0.033 Uiso 1 1 d GR . . . .
H7B H -0.2095 0.1653 -0.1392 0.033 Uiso 1 1 d GR . . . .
O1 O -0.08016(16) -0.0302(6) -0.15917(12) 0.0199(10) Uani 1 1 d . . . . .
O3 O 0.27054(16) 0.7903(6) -0.33680(11) 0.0152(10) Uani 1 1 d . . . . .
C25 C 0.2267(2) 0.5636(9) 0.00801(17) 0.0160(12) Uani 1 1 d . U . . .
H25 H 0.2073 0.5851 0.0297 0.019 Uiso 1 1 calc R . . . .
O8 O -0.08556(16) -0.3663(7) -0.11072(13) 0.0231(11) Uani 1 1 d . . . . .
H8A H -0.0701 -0.3564 -0.1332 0.035 Uiso 1 1 d R . . . .
H8B H -0.0676 -0.2855 -0.0979 0.035 Uiso 1 1 d R . . . .
C22 C 0.2841(2) 0.4936(9) -0.05659(17) 0.0158(12) Uani 1 1 d . U . . .
H22 H 0.3036 0.4686 -0.0781 0.019 Uiso 1 1 calc R . . . .
C27 C 0.3023(2) 0.5969(8) 0.04921(17) 0.0144(14) Uani 1 1 d . . . . .
O9 O -0.18575(16) -0.4512(6) -0.10445(12) 0.0187(10) Uani 1 1 d . . . . .
H9B H -0.2030 -0.4823 -0.1249 0.028 Uiso 1 1 d R . . . .
H9A H -0.2089 -0.4190 -0.0882 0.028 Uiso 1 1 d R . . . .
C26 C 0.2780(2) 0.5647(9) 0.01128(17) 0.0153(12) Uani 1 1 d . U . . .
C21 C 0.2323(2) 0.4945(8) -0.06007(16) 0.0126(11) Uani 1 1 d . U . . .
C24 C 0.2043(2) 0.5308(9) -0.02707(16) 0.0146(12) Uani 1 1 d . U . . .
H24 H 0.1699 0.5330 -0.0288 0.018 Uiso 1 1 calc R . . . .
C23 C 0.3066(2) 0.5298(9) -0.02110(17) 0.0179(12) Uani 1 1 d . U . . .
H23 H 0.3410 0.5305 -0.0192 0.021 Uiso 1 1 calc R . . . .
C9 C 0.1608(2) 0.3809(8) -0.09835(16) 0.0140(12) Uani 1 1 d . U . . .
H9 H 0.1464 0.3432 -0.0753 0.017 Uiso 1 1 calc R . . . .
C10 C 0.2076(2) 0.4611(9) -0.09769(16) 0.0125(11) Uani 1 1 d . U . . .
C8 C 0.1351(2) 0.3559(9) -0.13319(16) 0.0131(11) Uani 1 1 d . U . . .
C13 C 0.1591(2) 0.4047(8) -0.16771(16) 0.0121(12) Uani 1 1 d . U . . .
H13 H 0.1432 0.3844 -0.1911 0.015 Uiso 1 1 calc R . . . .
O2 O -0.08793(17) 0.0564(7) -0.09883(12) 0.0223(11) Uani 1 1 d . . . . .
C3 C 0.0067(3) 0.2195(9) -0.09877(18) 0.0190(14) Uani 1 1 d . U . . .
H3 H -0.0115 0.2219 -0.0760 0.023 Uiso 1 1 calc R . . . .
C1 C -0.0636(3) 0.0524(9) -0.13020(18) 0.0202(15) Uani 1 1 d . . . . .
C5 C 0.0136(2) 0.1450(10) -0.16597(19) 0.0224(14) Uani 1 1 d . U . . .
H5 H -0.0003 0.0984 -0.1884 0.027 Uiso 1 1 calc R . . . .
C2 C -0.0139(2) 0.1450(10) -0.13190(18) 0.0206(12) Uani 1 1 d . U . . .
O6 O 0.27721(16) 0.5761(6) 0.08013(11) 0.0174(10) Uani 1 1 d . . . . .
C20 C 0.2967(2) 0.7236(9) -0.31017(17) 0.0134(14) Uani 1 1 d . . . . .
C16 C 0.3025(2) 0.5969(8) -0.24348(16) 0.0144(13) Uani 1 1 d . U . . .
H16 H 0.3368 0.5931 -0.2464 0.017 Uiso 1 1 calc R . . . .
C19 C 0.2732(2) 0.6603(9) -0.27343(16) 0.0149(14) Uani 1 1 d . . . . .
C18 C 0.2220(2) 0.6631(9) -0.26869(17) 0.0174(13) Uani 1 1 d . U . . .
H18 H 0.2020 0.7069 -0.2885 0.021 Uiso 1 1 calc R . . . .
C17 C 0.2004(3) 0.6018(8) -0.23514(16) 0.0154(12) Uani 1 1 d . U . . .
H17 H 0.1660 0.6017 -0.2329 0.019 Uiso 1 1 calc R . . . .
C15 C 0.2813(2) 0.5391(9) -0.20935(17) 0.0151(12) Uani 1 1 d . U . . .
H15 H 0.3015 0.4994 -0.1894 0.018 Uiso 1 1 calc R . . . .
C14 C 0.2295(2) 0.5395(9) -0.20434(16) 0.0139(12) Uani 1 1 d . U . . .
C12 C 0.2062(2) 0.4828(8) -0.16758(16) 0.0120(11) Uani 1 1 d . U . . .
C11 C 0.2301(2) 0.5105(8) -0.13254(16) 0.0130(12) Uani 1 1 d . U . . .
H11 H 0.2614 0.5628 -0.1322 0.016 Uiso 1 1 calc R . . . .
C4 C 0.0548(2) 0.2911(9) -0.09957(17) 0.0184(15) Uani 1 1 d . . . . .
H4 H 0.0679 0.3433 -0.0774 0.022 Uiso 1 1 calc R . . . .
C6 C 0.0616(3) 0.2139(9) -0.16680(18) 0.0194(15) Uani 1 1 d . . . . .
H6 H 0.0795 0.2127 -0.1897 0.023 Uiso 1 1 calc R . . . .
C7 C 0.0833(2) 0.2853(9) -0.13316(17) 0.0163(15) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O5 2.475(4) 3_455 ?
Eu1 O4 2.441(4) 6_545 ?
Eu1 O7 2.407(5) . ?
Eu1 O1 2.521(4) . ?
Eu1 O3 2.529(4) 6_545 ?
Eu1 O8 2.462(5) . ?
Eu1 C27 2.823(6) 3_455 ?
Eu1 O9 2.461(4) . ?
Eu1 O2 2.476(5) . ?
Eu1 C1 2.866(7) . ?
Eu1 O6 2.431(4) 3_455 ?
Eu1 C20 2.855(6) 6_545 ?
O5 Eu1 2.475(4) 3 ?
O5 C27 1.264(8) . ?
O4 Eu1 2.441(4) 6_665 ?
O4 C20 1.271(7) . ?
O1 C1 1.256(8) . ?
O3 Eu1 2.529(4) 6_665 ?
O3 C20 1.262(7) . ?
C25 C26 1.388(9) . ?
C25 C24 1.379(8) . ?
C22 C21 1.403(9) . ?
C22 C23 1.397(8) . ?
C27 Eu1 2.823(6) 3 ?
C27 C26 1.487(8) . ?
C27 O6 1.276(7) . ?
C26 C23 1.386(9) . ?
C21 C24 1.396(8) . ?
C21 C10 1.484(8) . ?
C9 C10 1.394(9) . ?
C9 C8 1.405(8) . ?
C10 C11 1.400(8) . ?
C8 C13 1.407(8) . ?
C8 C7 1.490(8) . ?
C13 C12 1.397(8) . ?
O2 C1 1.270(8) . ?
C3 C2 1.389(9) . ?
C3 C4 1.400(9) . ?
C1 C2 1.508(9) . ?
C5 C2 1.394(9) . ?
C5 C6 1.391(9) . ?
O6 Eu1 2.431(4) 3 ?
C20 Eu1 2.855(6) 6_665 ?
C20 C19 1.497(8) . ?
C16 C19 1.386(9) . ?
C16 C15 1.382(8) . ?
C19 C18 1.393(9) . ?
C18 C17 1.377(8) . ?
C17 C14 1.404(8) . ?
C15 C14 1.405(9) . ?
C14 C12 1.481(8) . ?
C12 C11 1.389(8) . ?
C4 C7 1.396(8) . ?
C6 C7 1.407(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Eu1 O1 119.69(14) 3_455 . ?
O5 Eu1 O3 124.88(14) 3_455 6_545 ?
O5 Eu1 C27 26.57(16) 3_455 3_455 ?
O5 Eu1 C1 94.62(16) 3_455 . ?
O5 Eu1 C20 146.13(16) 3_455 6_545 ?
O4 Eu1 O5 156.19(16) 6_545 3_455 ?
O4 Eu1 O1 73.24(14) 6_545 . ?
O4 Eu1 O3 52.52(14) 6_545 6_545 ?
O4 Eu1 O8 84.28(15) 6_545 . ?
O4 Eu1 C27 149.14(17) 6_545 3_455 ?
O4 Eu1 O9 80.70(14) 6_545 . ?
O4 Eu1 O2 125.34(14) 6_545 . ?
O4 Eu1 C1 99.12(16) 6_545 . ?
O4 Eu1 C20 26.31(16) 6_545 6_545 ?
O7 Eu1 O5 105.91(15) . 3_455 ?
O7 Eu1 O4 96.64(15) . 6_545 ?
O7 Eu1 O1 74.82(15) . . ?
O7 Eu1 O3 77.43(14) . 6_545 ?
O7 Eu1 O8 147.12(15) . . ?
O7 Eu1 C27 90.91(17) . 3_455 ?
O7 Eu1 O9 143.90(15) . . ?
O7 Eu1 O2 73.50(15) . . ?
O7 Eu1 C1 73.49(17) . . ?
O7 Eu1 O6 76.10(15) . 3_455 ?
O7 Eu1 C20 86.50(17) . 6_545 ?
O1 Eu1 O3 114.26(13) . 6_545 ?
O1 Eu1 C27 137.45(16) . 3_455 ?
O1 Eu1 C1 25.98(16) . . ?
O1 Eu1 C20 93.81(16) . 6_545 ?
O3 Eu1 C27 100.76(16) 6_545 3_455 ?
O3 Eu1 C1 136.13(16) 6_545 . ?
O3 Eu1 C20 26.22(16) 6_545 6_545 ?
O8 Eu1 O5 80.95(15) . 3_455 ?
O8 Eu1 O1 74.03(15) . . ?
O8 Eu1 O3 125.61(15) . 6_545 ?
O8 Eu1 C27 105.08(17) . 3_455 ?
O8 Eu1 O2 79.24(16) . . ?
O8 Eu1 C1 73.92(18) . . ?
O8 Eu1 C20 105.79(17) . 6_545 ?
C27 Eu1 C1 111.71(18) 3_455 . ?
C27 Eu1 C20 125.69(18) 3_455 6_545 ?
O9 Eu1 O5 76.60(15) . 3_455 ?
O9 Eu1 O1 136.23(15) . . ?
O9 Eu1 O3 72.53(14) . 6_545 ?
O9 Eu1 O8 68.83(15) . . ?
O9 Eu1 C27 75.78(16) . 3_455 ?
O9 Eu1 O2 136.65(15) . . ?
O9 Eu1 C1 142.60(17) . . ?
O9 Eu1 C20 75.31(16) . 6_545 ?
O2 Eu1 O5 69.90(15) . 3_455 ?
O2 Eu1 O1 52.15(14) . . ?
O2 Eu1 O3 150.35(15) . 6_545 ?
O2 Eu1 C27 85.50(16) . 3_455 ?
O2 Eu1 C1 26.22(16) . . ?
O2 Eu1 C20 143.63(16) . 6_545 ?
O6 Eu1 O5 53.38(14) 3_455 3_455 ?
O6 Eu1 O4 127.89(14) 3_455 6_545 ?
O6 Eu1 O1 145.88(15) 3_455 . ?
O6 Eu1 O3 75.82(14) 3_455 6_545 ?
O6 Eu1 O8 128.43(14) 3_455 . ?
O6 Eu1 C27 26.81(16) 3_455 3_455 ?
O6 Eu1 O9 77.51(15) 3_455 . ?
O6 Eu1 O2 102.31(15) 3_455 . ?
O6 Eu1 C1 126.12(17) 3_455 . ?
O6 Eu1 C20 101.86(16) 3_455 6_545 ?
C20 Eu1 C1 119.23(17) 6_545 . ?
C27 O5 Eu1 92.2(3) . 3 ?
C20 O4 Eu1 95.3(4) . 6_665 ?
C1 O1 Eu1 92.5(4) . . ?
C20 O3 Eu1 91.5(4) . 6_665 ?
C24 C25 C26 120.6(6) . . ?
C23 C22 C21 120.5(6) . . ?
O5 C27 Eu1 61.2(3) . 3 ?
O5 C27 C26 120.3(6) . . ?
O5 C27 O6 120.4(5) . . ?
C26 C27 Eu1 178.3(5) . 3 ?
O6 C27 Eu1 59.2(3) . 3 ?
O6 C27 C26 119.3(6) . . ?
C25 C26 C27 120.8(6) . . ?
C23 C26 C25 119.2(6) . . ?
C23 C26 C27 120.0(6) . . ?
C22 C21 C10 121.4(5) . . ?
C24 C21 C22 118.0(6) . . ?
C24 C21 C10 120.6(6) . . ?
C25 C24 C21 121.3(6) . . ?
C26 C23 C22 120.4(6) . . ?
C10 C9 C8 121.1(5) . . ?
C9 C10 C21 119.4(5) . . ?
C9 C10 C11 119.2(5) . . ?
C11 C10 C21 121.4(5) . . ?
C9 C8 C13 118.0(5) . . ?
C9 C8 C7 120.6(5) . . ?
C13 C8 C7 121.4(5) . . ?
C12 C13 C8 121.5(5) . . ?
C1 O2 Eu1 94.3(4) . . ?
C2 C3 C4 120.2(6) . . ?
O1 C1 Eu1 61.5(3) . . ?
O1 C1 O2 120.8(6) . . ?
O1 C1 C2 120.3(6) . . ?
O2 C1 Eu1 59.5(3) . . ?
O2 C1 C2 118.9(6) . . ?
C2 C1 Eu1 174.2(5) . . ?
C6 C5 C2 120.8(6) . . ?
C3 C2 C1 120.2(6) . . ?
C3 C2 C5 119.2(6) . . ?
C5 C2 C1 120.4(6) . . ?
C27 O6 Eu1 94.0(4) . 3 ?
O4 C20 Eu1 58.4(3) . 6_665 ?
O4 C20 C19 118.8(6) . . ?
O3 C20 Eu1 62.3(3) . 6_665 ?
O3 C20 O4 120.7(5) . . ?
O3 C20 C19 120.5(6) . . ?
C19 C20 Eu1 176.7(4) . 6_665 ?
C15 C16 C19 120.6(6) . . ?
C16 C19 C20 120.1(6) . . ?
C16 C19 C18 118.9(6) . . ?
C18 C19 C20 121.0(6) . . ?
C17 C18 C19 121.0(6) . . ?
C18 C17 C14 120.8(6) . . ?
C16 C15 C14 121.1(6) . . ?
C17 C14 C15 117.6(6) . . ?
C17 C14 C12 120.6(6) . . ?
C15 C14 C12 121.8(6) . . ?
C13 C12 C14 120.0(5) . . ?
C11 C12 C13 119.0(5) . . ?
C11 C12 C14 120.9(5) . . ?
C12 C11 C10 121.0(6) . . ?
C7 C4 C3 121.0(6) . . ?
C5 C6 C7 120.5(6) . . ?
C4 C7 C8 120.4(6) . . ?
C4 C7 C6 118.2(6) . . ?
C6 C7 C8 121.3(6) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.546
_oxdiff_exptl_absorpt_empirical_full_min 0.830
