# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 991880'
loop_
_audit_author_name
_audit_author_address
'Yu-Quan Feng'
;Nanyang Normal University
China
;
_audit_update_record             
;
2020-08-02 deposited with the CCDC.	2021-06-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C43 H31 Cl2 N3 Pt'
_chemical_formula_weight         855.70

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   'P-1   '

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.7701(11)
_cell_length_b                   10.2927(11)
_cell_length_c                   19.673(2)
_cell_angle_alpha                84.915(2)
_cell_angle_beta                 89.387(2)
_cell_angle_gamma                62.404(2)
_cell_volume                     1745.3(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3473
_cell_measurement_theta_min      2.35
_cell_measurement_theta_max      23.13

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.12
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.628
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             844
_exptl_absorpt_coefficient_mu    4.209
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.4865
_exptl_absorpt_correction_T_max  0.6321
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            8919
_diffrn_reflns_av_R_equivalents  0.0246
_diffrn_reflns_av_sigmaI/netI    0.0517
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.08
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6124
_reflns_number_gt                5127
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0381P)²+0.4528P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6124
_refine_ls_number_parameters     442
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0499
_refine_ls_R_factor_gt           0.0372
_refine_ls_wR_factor_ref         0.0841
_refine_ls_wR_factor_gt          0.0803
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_restrained_S_all      1.084
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.19058(3) 0.62216(2) -0.051958(11) 0.03726(9) Uani 1 1 d . . .
C1 C 0.4793(8) 0.4777(7) -0.1414(3) 0.0513(16) Uani 1 1 d . . .
H1 H 0.4300 0.5591 -0.1732 0.062 Uiso 1 1 calc R . .
C2 C 0.6196(8) 0.3653(8) -0.1557(3) 0.0609(19) Uani 1 1 d . . .
H2 H 0.6623 0.3684 -0.1979 0.073 Uiso 1 1 calc R . .
C3 C 0.6983(8) 0.2466(8) -0.1071(4) 0.0613(19) Uani 1 1 d . . .
H3 H 0.7945 0.1706 -0.1160 0.074 Uiso 1 1 calc R . .
C4 C 0.6307(7) 0.2440(7) -0.0453(3) 0.0457(15) Uani 1 1 d . . .
H4 H 0.6825 0.1673 -0.0115 0.055 Uiso 1 1 calc R . .
C5 C 0.4862(6) 0.3555(6) -0.0338(3) 0.0349(13) Uani 1 1 d . . .
C6 C 0.4004(6) 0.3544(6) 0.0289(3) 0.0345(13) Uani 1 1 d . . .
C7 C 0.4501(6) 0.2487(6) 0.0836(3) 0.0362(13) Uani 1 1 d . . .
H7 H 0.5509 0.1727 0.0862 0.043 Uiso 1 1 calc R . .
C8 C 0.3489(6) 0.2559(6) 0.1352(3) 0.0377(13) Uani 1 1 d . . .
C9 C 0.2007(6) 0.3767(6) 0.1317(3) 0.0380(13) Uani 1 1 d . . .
H9 H 0.1319 0.3848 0.1661 0.046 Uiso 1 1 calc R . .
C10 C 0.1566(6) 0.4840(6) 0.0771(3) 0.0342(12) Uani 1 1 d . . .
C11 C 0.0084(6) 0.6177(6) 0.0637(3) 0.0364(13) Uani 1 1 d . . .
C16 C -0.0021(7) 0.7066(6) 0.0031(3) 0.0380(13) Uani 1 1 d . . .
C15 C -0.1424(7) 0.8319(6) -0.0119(3) 0.0490(16) Uani 1 1 d . . .
H15 H -0.1539 0.8929 -0.0516 0.059 Uiso 1 1 calc R . .
C14 C -0.2656(7) 0.8677(7) 0.0310(3) 0.0516(16) Uani 1 1 d . . .
H14 H -0.3581 0.9521 0.0196 0.062 Uiso 1 1 calc R . .
C13 C -0.2535(7) 0.7806(6) 0.0905(3) 0.0484(15) Uani 1 1 d . . .
H13 H -0.3364 0.8060 0.1192 0.058 Uiso 1 1 calc R . .
C12 C -0.1167(7) 0.6556(6) 0.1063(3) 0.0446(14) Uani 1 1 d . . .
H12 H -0.1073 0.5954 0.1460 0.054 Uiso 1 1 calc R . .
C17 C 0.3959(6) 0.1365(6) 0.1919(3) 0.0374(13) Uani 1 1 d . . .
C18 C 0.2897(7) 0.0962(7) 0.2220(3) 0.0479(16) Uani 1 1 d . . .
H18 H 0.1869 0.1461 0.2067 0.057 Uiso 1 1 calc R . .
C19 C 0.3331(7) -0.0150(7) 0.2737(3) 0.0530(17) Uani 1 1 d . . .
H19 H 0.2601 -0.0402 0.2926 0.064 Uiso 1 1 calc R . .
C20 C 0.4872(7) -0.0909(6) 0.2981(3) 0.0474(15) Uani 1 1 d . . .
C21 C 0.5938(7) -0.0516(7) 0.2679(3) 0.0467(15) Uani 1 1 d . . .
H21 H 0.6966 -0.1008 0.2832 0.056 Uiso 1 1 calc R . .
C22 C 0.5489(7) 0.0591(6) 0.2156(3) 0.0429(14) Uani 1 1 d . . .
H22 H 0.6222 0.0827 0.1957 0.052 Uiso 1 1 calc R . .
C23 C 0.6723(7) -0.3377(7) 0.3475(3) 0.0503(16) Uani 1 1 d . . .
C24 C 0.7107(8) -0.4033(7) 0.2879(4) 0.0601(18) Uani 1 1 d . . .
H24 H 0.6469 -0.3585 0.2492 0.072 Uiso 1 1 calc R . .
C25 C 0.8432(10) -0.5354(8) 0.2846(5) 0.074(2) Uani 1 1 d . . .
H25 H 0.8664 -0.5799 0.2439 0.089 Uiso 1 1 calc R . .
C26 C 0.9404(9) -0.6009(8) 0.3408(5) 0.079(2) Uani 1 1 d . . .
H26 H 1.0303 -0.6891 0.3385 0.095 Uiso 1 1 calc R . .
C27 C 0.9033(9) -0.5344(9) 0.4004(5) 0.078(2) Uani 1 1 d . . .
H27 H 0.9685 -0.5783 0.4389 0.093 Uiso 1 1 calc R . .
C28 C 0.7701(8) -0.4030(8) 0.4041(4) 0.0617(19) Uani 1 1 d . . .
H28 H 0.7465 -0.3586 0.4448 0.074 Uiso 1 1 calc R . .
C29 C 0.4319(7) -0.1923(7) 0.4068(3) 0.0499(16) Uani 1 1 d . . .
C34 C 0.3570(9) -0.0620(8) 0.4365(4) 0.073(2) Uani 1 1 d . . .
H34 H 0.3727 0.0182 0.4214 0.088 Uiso 1 1 calc R . .
C33 C 0.2579(10) -0.0517(9) 0.4891(4) 0.088(3) Uani 1 1 d . . .
H33 H 0.2057 0.0366 0.5088 0.106 Uiso 1 1 calc R . .
C32 C 0.2357(10) -0.1689(10) 0.5125(4) 0.081(3) Uani 1 1 d . . .
H32 H 0.1690 -0.1608 0.5478 0.097 Uiso 1 1 calc R . .
C31 C 0.3121(9) -0.2976(9) 0.4837(4) 0.068(2) Uani 1 1 d . . .
H31 H 0.2987 -0.3785 0.5001 0.081 Uiso 1 1 calc R . .
C30 C 0.4096(8) -0.3103(7) 0.4302(3) 0.0570(17) Uani 1 1 d . . .
H30 H 0.4598 -0.3985 0.4102 0.068 Uiso 1 1 calc R . .
C35 C 0.1310(7) 0.7781(6) -0.1282(3) 0.0444(14) Uani 1 1 d . . .
C36 C 0.0999(7) 0.8736(7) -0.1739(3) 0.0459(15) Uani 1 1 d . . .
C37 C 0.0582(6) 0.9912(6) -0.2272(3) 0.0403(14) Uani 1 1 d . . .
C42 C 0.0221(7) 1.1333(7) -0.2113(3) 0.0483(15) Uani 1 1 d . . .
H42 H 0.0279 1.1501 -0.1660 0.058 Uiso 1 1 calc R . .
C41 C -0.0221(8) 1.2498(7) -0.2620(4) 0.0621(19) Uani 1 1 d . . .
H41 H -0.0451 1.3433 -0.2504 0.075 Uiso 1 1 calc R . .
C40 C -0.0319(8) 1.2266(8) -0.3289(4) 0.063(2) Uani 1 1 d . . .
H40 H -0.0627 1.3044 -0.3628 0.075 Uiso 1 1 calc R . .
C39 C 0.0040(8) 1.0885(8) -0.3454(3) 0.0634(19) Uani 1 1 d . . .
H39 H -0.0030 1.0734 -0.3909 0.076 Uiso 1 1 calc R . .
C38 C 0.0505(7) 0.9708(7) -0.2960(3) 0.0526(16) Uani 1 1 d . . .
H38 H 0.0769 0.8774 -0.3086 0.063 Uiso 1 1 calc R . .
C43 C 0.4391(17) 0.2808(14) 0.3533(6) 0.159(5) Uani 1 1 d U . .
H43A H 0.3846 0.2656 0.3164 0.191 Uiso 1 1 calc R . .
H43B H 0.5143 0.1837 0.3726 0.191 Uiso 1 1 calc R . .
N2 N 0.2575(5) 0.4674(5) 0.0263(2) 0.0359(11) Uani 1 1 d . . .
N1 N 0.4112(6) 0.4717(5) -0.0816(2) 0.0432(12) Uani 1 1 d . . .
N3 N 0.5328(6) -0.2046(6) 0.3522(3) 0.0579(15) Uani 1 1 d . . .
Cl1 Cl 0.5411(4) 0.3614(4) 0.31664(14) 0.1385(12) Uani 1 1 d . . .
Cl2 Cl 0.3174(4) 0.3482(4) 0.4101(2) 0.1577(14) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C35 1.973(6) . ?
Pt1 N2 1.989(4) . ?
Pt1 C16 2.020(6) . ?
Pt1 N1 2.104(5) . ?
C1 C2 1.370(9) . ?
C1 N1 1.357(7) . ?
C1 H1 0.9300 . ?
C2 C3 1.391(9) . ?
C2 H2 0.9300 . ?
C3 C4 1.382(8) . ?
C3 H3 0.9300 . ?
C4 C5 1.377(8) . ?
C4 H4 0.9300 . ?
C5 N1 1.361(7) . ?
C5 C6 1.487(7) . ?
C6 N2 1.338(7) . ?
C6 C7 1.376(7) . ?
C7 C8 1.392(7) . ?
C7 H7 0.9300 . ?
C8 C9 1.402(8) . ?
C8 C17 1.486(7) . ?
C9 C10 1.385(7) . ?
C9 H9 0.9300 . ?
C10 N2 1.361(7) . ?
C10 C11 1.469(7) . ?
C11 C12 1.394(8) . ?
C11 C16 1.410(7) . ?
C16 C15 1.391(8) . ?
C15 C14 1.386(9) . ?
C15 H15 0.9300 . ?
C14 C13 1.380(8) . ?
C14 H14 0.9300 . ?
C13 C12 1.372(8) . ?
C13 H13 0.9300 . ?
C12 H12 0.9300 . ?
C17 C22 1.390(8) . ?
C17 C18 1.393(7) . ?
C18 C19 1.369(8) . ?
C18 H18 0.9300 . ?
C19 C20 1.402(8) . ?
C19 H19 0.9300 . ?
C20 C21 1.392(8) . ?
C20 N3 1.417(7) . ?
C21 C22 1.373(7) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C23 C24 1.366(9) . ?
C23 C28 1.378(9) . ?
C23 N3 1.426(8) . ?
C24 C25 1.383(10) . ?
C24 H24 0.9300 . ?
C25 C26 1.370(11) . ?
C25 H25 0.9300 . ?
C26 C27 1.371(11) . ?
C26 H26 0.9300 . ?
C27 C28 1.384(10) . ?
C27 H27 0.9300 . ?
C28 H28 0.9300 . ?
C29 C30 1.371(8) . ?
C29 C34 1.377(9) . ?
C29 N3 1.424(7) . ?
C34 C33 1.387(10) . ?
C34 H34 0.9300 . ?
C33 C32 1.361(11) . ?
C33 H33 0.9300 . ?
C32 C31 1.357(10) . ?
C32 H32 0.9300 . ?
C31 C30 1.386(9) . ?
C31 H31 0.9300 . ?
C30 H30 0.9300 . ?
C35 C36 1.199(8) . ?
C36 C37 1.435(8) . ?
C37 C38 1.395(8) . ?
C37 C42 1.401(8) . ?
C42 C41 1.391(8) . ?
C42 H42 0.9300 . ?
C41 C40 1.371(10) . ?
C41 H41 0.9300 . ?
C40 C39 1.366(10) . ?
C40 H40 0.9300 . ?
C39 C38 1.382(8) . ?
C39 H39 0.9300 . ?
C38 H38 0.9300 . ?
C43 Cl2 1.577(11) . ?
C43 Cl1 1.688(11) . ?
C43 H43A 0.9700 . ?
C43 H43B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C35 Pt1 N2 177.5(2) . . ?
C35 Pt1 C16 100.2(2) . . ?
N2 Pt1 C16 80.72(19) . . ?
C35 Pt1 N1 100.5(2) . . ?
N2 Pt1 N1 78.68(18) . . ?
C16 Pt1 N1 159.25(19) . . ?
C2 C1 N1 120.8(6) . . ?
C2 C1 H1 119.6 . . ?
N1 C1 H1 119.6 . . ?
C1 C2 C3 120.1(6) . . ?
C1 C2 H2 119.9 . . ?
C3 C2 H2 119.9 . . ?
C4 C3 C2 118.6(6) . . ?
C4 C3 H3 120.7 . . ?
C2 C3 H3 120.7 . . ?
C5 C4 C3 119.8(6) . . ?
C5 C4 H4 120.1 . . ?
C3 C4 H4 120.1 . . ?
N1 C5 C4 120.9(5) . . ?
N1 C5 C6 116.0(5) . . ?
C4 C5 C6 123.0(5) . . ?
N2 C6 C7 120.5(5) . . ?
N2 C6 C5 112.4(4) . . ?
C7 C6 C5 127.0(5) . . ?
C6 C7 C8 119.8(5) . . ?
C6 C7 H7 120.1 . . ?
C8 C7 H7 120.1 . . ?
C7 C8 C9 118.4(5) . . ?
C7 C8 C17 120.7(5) . . ?
C9 C8 C17 120.9(5) . . ?
C10 C9 C8 120.2(5) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
N2 C10 C9 118.9(5) . . ?
N2 C10 C11 112.4(4) . . ?
C9 C10 C11 128.7(5) . . ?
C12 C11 C16 121.0(5) . . ?
C12 C11 C10 123.4(5) . . ?
C16 C11 C10 115.6(5) . . ?
C15 C16 C11 117.0(5) . . ?
C15 C16 Pt1 129.7(4) . . ?
C11 C16 Pt1 113.2(4) . . ?
C16 C15 C14 121.2(6) . . ?
C16 C15 H15 119.4 . . ?
C14 C15 H15 119.4 . . ?
C15 C14 C13 121.3(6) . . ?
C15 C14 H14 119.4 . . ?
C13 C14 H14 119.4 . . ?
C12 C13 C14 118.7(6) . . ?
C12 C13 H13 120.7 . . ?
C14 C13 H13 120.7 . . ?
C13 C12 C11 120.9(6) . . ?
C13 C12 H12 119.6 . . ?
C11 C12 H12 119.6 . . ?
C22 C17 C18 117.8(5) . . ?
C22 C17 C8 120.8(5) . . ?
C18 C17 C8 121.5(5) . . ?
C19 C18 C17 121.6(6) . . ?
C19 C18 H18 119.2 . . ?
C17 C18 H18 119.2 . . ?
C18 C19 C20 120.3(5) . . ?
C18 C19 H19 119.9 . . ?
C20 C19 H19 119.9 . . ?
C21 C20 C19 118.3(5) . . ?
C21 C20 N3 121.0(6) . . ?
C19 C20 N3 120.7(5) . . ?
C22 C21 C20 120.7(6) . . ?
C22 C21 H21 119.6 . . ?
C20 C21 H21 119.6 . . ?
C21 C22 C17 121.3(5) . . ?
C21 C22 H22 119.4 . . ?
C17 C22 H22 119.4 . . ?
C24 C23 C28 119.1(6) . . ?
C24 C23 N3 121.2(6) . . ?
C28 C23 N3 119.8(6) . . ?
C23 C24 C25 120.8(7) . . ?
C23 C24 H24 119.6 . . ?
C25 C24 H24 119.6 . . ?
C24 C25 C26 120.3(8) . . ?
C24 C25 H25 119.8 . . ?
C26 C25 H25 119.8 . . ?
C27 C26 C25 119.0(7) . . ?
C27 C26 H26 120.5 . . ?
C25 C26 H26 120.5 . . ?
C26 C27 C28 120.8(8) . . ?
C26 C27 H27 119.6 . . ?
C28 C27 H27 119.6 . . ?
C23 C28 C27 120.0(7) . . ?
C23 C28 H28 120.0 . . ?
C27 C28 H28 120.0 . . ?
C30 C29 C34 119.8(6) . . ?
C30 C29 N3 120.1(6) . . ?
C34 C29 N3 120.1(6) . . ?
C29 C34 C33 119.2(7) . . ?
C29 C34 H34 120.4 . . ?
C33 C34 H34 120.4 . . ?
C34 C33 C32 121.1(8) . . ?
C34 C33 H33 119.5 . . ?
C32 C33 H33 119.5 . . ?
C31 C32 C33 119.3(7) . . ?
C31 C32 H32 120.4 . . ?
C33 C32 H32 120.4 . . ?
C32 C31 C30 120.9(7) . . ?
C32 C31 H31 119.5 . . ?
C30 C31 H31 119.5 . . ?
C29 C30 C31 119.7(7) . . ?
C29 C30 H30 120.2 . . ?
C31 C30 H30 120.2 . . ?
C36 C35 Pt1 177.3(6) . . ?
C35 C36 C37 178.0(7) . . ?
C38 C37 C42 117.3(5) . . ?
C38 C37 C36 122.5(6) . . ?
C42 C37 C36 120.2(6) . . ?
C37 C42 C41 121.3(6) . . ?
C37 C42 H42 119.3 . . ?
C41 C42 H42 119.3 . . ?
C40 C41 C42 119.8(6) . . ?
C40 C41 H41 120.1 . . ?
C42 C41 H41 120.1 . . ?
C41 C40 C39 119.7(6) . . ?
C41 C40 H40 120.2 . . ?
C39 C40 H40 120.2 . . ?
C40 C39 C38 121.3(7) . . ?
C40 C39 H39 119.3 . . ?
C38 C39 H39 119.3 . . ?
C37 C38 C39 120.5(6) . . ?
C37 C38 H38 119.8 . . ?
C39 C38 H38 119.8 . . ?
Cl2 C43 Cl1 124.1(8) . . ?
Cl2 C43 H43A 106.3 . . ?
Cl1 C43 H43A 106.3 . . ?
Cl2 C43 H43B 106.3 . . ?
Cl1 C43 H43B 106.3 . . ?
H43A C43 H43B 106.4 . . ?
C6 N2 C10 122.2(4) . . ?
C6 N2 Pt1 119.7(3) . . ?
C10 N2 Pt1 118.1(4) . . ?
C5 N1 C1 119.6(5) . . ?
C5 N1 Pt1 112.9(3) . . ?
C1 N1 Pt1 127.4(4) . . ?
C20 N3 C29 120.1(5) . . ?
C20 N3 C23 119.3(5) . . ?
C29 N3 C23 120.3(5) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 -3.5(10) . . . . ?
C1 C2 C3 C4 1.1(11) . . . . ?
C2 C3 C4 C5 1.9(10) . . . . ?
C3 C4 C5 N1 -2.7(9) . . . . ?
C3 C4 C5 C6 174.9(6) . . . . ?
N1 C5 C6 N2 3.0(7) . . . . ?
C4 C5 C6 N2 -174.7(5) . . . . ?
N1 C5 C6 C7 179.0(5) . . . . ?
C4 C5 C6 C7 1.3(9) . . . . ?
N2 C6 C7 C8 2.8(8) . . . . ?
C5 C6 C7 C8 -173.0(5) . . . . ?
C6 C7 C8 C9 -3.7(8) . . . . ?
C6 C7 C8 C17 175.0(5) . . . . ?
C7 C8 C9 C10 1.3(8) . . . . ?
C17 C8 C9 C10 -177.4(5) . . . . ?
C8 C9 C10 N2 2.0(8) . . . . ?
C8 C9 C10 C11 179.9(5) . . . . ?
N2 C10 C11 C12 176.7(5) . . . . ?
C9 C10 C11 C12 -1.3(9) . . . . ?
N2 C10 C11 C16 -2.0(7) . . . . ?
C9 C10 C11 C16 180.0(5) . . . . ?
C12 C11 C16 C15 -0.5(8) . . . . ?
C10 C11 C16 C15 178.3(5) . . . . ?
C12 C11 C16 Pt1 -176.9(4) . . . . ?
C10 C11 C16 Pt1 1.8(6) . . . . ?
C35 Pt1 C16 C15 5.6(6) . . . . ?
N2 Pt1 C16 C15 -176.8(6) . . . . ?
N1 Pt1 C16 C15 -170.0(5) . . . . ?
C35 Pt1 C16 C11 -178.5(4) . . . . ?
N2 Pt1 C16 C11 -0.9(4) . . . . ?
N1 Pt1 C16 C11 5.9(8) . . . . ?
C11 C16 C15 C14 0.4(9) . . . . ?
Pt1 C16 C15 C14 176.2(5) . . . . ?
C16 C15 C14 C13 0.1(10) . . . . ?
C15 C14 C13 C12 -0.6(9) . . . . ?
C14 C13 C12 C11 0.6(9) . . . . ?
C16 C11 C12 C13 0.0(9) . . . . ?
C10 C11 C12 C13 -178.7(5) . . . . ?
C7 C8 C17 C22 32.3(8) . . . . ?
C9 C8 C17 C22 -149.0(6) . . . . ?
C7 C8 C17 C18 -146.3(6) . . . . ?
C9 C8 C17 C18 32.4(8) . . . . ?
C22 C17 C18 C19 0.5(9) . . . . ?
C8 C17 C18 C19 179.2(6) . . . . ?
C17 C18 C19 C20 0.5(10) . . . . ?
C18 C19 C20 C21 -0.9(10) . . . . ?
C18 C19 C20 N3 179.0(6) . . . . ?
C19 C20 C21 C22 0.1(10) . . . . ?
N3 C20 C21 C22 -179.7(6) . . . . ?
C20 C21 C22 C17 0.9(10) . . . . ?
C18 C17 C22 C21 -1.2(9) . . . . ?
C8 C17 C22 C21 -179.9(6) . . . . ?
C28 C23 C24 C25 1.8(10) . . . . ?
N3 C23 C24 C25 -177.5(6) . . . . ?
C23 C24 C25 C26 -1.6(11) . . . . ?
C24 C25 C26 C27 0.7(11) . . . . ?
C25 C26 C27 C28 -0.2(12) . . . . ?
C24 C23 C28 C27 -1.2(10) . . . . ?
N3 C23 C28 C27 178.1(6) . . . . ?
C26 C27 C28 C23 0.4(11) . . . . ?
C30 C29 C34 C33 -1.0(12) . . . . ?
N3 C29 C34 C33 179.3(7) . . . . ?
C29 C34 C33 C32 1.1(13) . . . . ?
C34 C33 C32 C31 0.0(14) . . . . ?
C33 C32 C31 C30 -1.2(13) . . . . ?
C34 C29 C30 C31 -0.2(10) . . . . ?
N3 C29 C30 C31 179.6(6) . . . . ?
C32 C31 C30 C29 1.3(11) . . . . ?
N2 Pt1 C35 C36 9(16) . . . . ?
C16 Pt1 C35 C36 121(12) . . . . ?
N1 Pt1 C35 C36 -61(12) . . . . ?
Pt1 C35 C36 C37 -108(21) . . . . ?
C35 C36 C37 C38 -133(21) . . . . ?
C35 C36 C37 C42 47(21) . . . . ?
C38 C37 C42 C41 1.1(9) . . . . ?
C36 C37 C42 C41 -178.5(6) . . . . ?
C37 C42 C41 C40 0.4(10) . . . . ?
C42 C41 C40 C39 -0.9(10) . . . . ?
C41 C40 C39 C38 -0.1(11) . . . . ?
C42 C37 C38 C39 -2.1(9) . . . . ?
C36 C37 C38 C39 177.5(6) . . . . ?
C40 C39 C38 C37 1.7(10) . . . . ?
C7 C6 N2 C10 0.7(8) . . . . ?
C5 C6 N2 C10 177.0(5) . . . . ?
C7 C6 N2 Pt1 178.1(4) . . . . ?
C5 C6 N2 Pt1 -5.6(6) . . . . ?
C9 C10 N2 C6 -3.1(8) . . . . ?
C11 C10 N2 C6 178.6(5) . . . . ?
C9 C10 N2 Pt1 179.5(4) . . . . ?
C11 C10 N2 Pt1 1.3(6) . . . . ?
C35 Pt1 N2 C6 -65(5) . . . . ?
C16 Pt1 N2 C6 -177.7(4) . . . . ?
N1 Pt1 N2 C6 4.7(4) . . . . ?
C35 Pt1 N2 C10 112(5) . . . . ?
C16 Pt1 N2 C10 -0.2(4) . . . . ?
N1 Pt1 N2 C10 -177.8(4) . . . . ?
C4 C5 N1 C1 0.3(8) . . . . ?
C6 C5 N1 C1 -177.4(5) . . . . ?
C4 C5 N1 Pt1 178.4(4) . . . . ?
C6 C5 N1 Pt1 0.7(6) . . . . ?
C2 C1 N1 C5 2.8(9) . . . . ?
C2 C1 N1 Pt1 -175.0(5) . . . . ?
C35 Pt1 N1 C5 174.9(4) . . . . ?
N2 Pt1 N1 C5 -2.7(4) . . . . ?
C16 Pt1 N1 C5 -9.5(8) . . . . ?
C35 Pt1 N1 C1 -7.2(5) . . . . ?
N2 Pt1 N1 C1 175.2(5) . . . . ?
C16 Pt1 N1 C1 168.4(6) . . . . ?
C21 C20 N3 C29 143.1(7) . . . . ?
C19 C20 N3 C29 -36.8(9) . . . . ?
C21 C20 N3 C23 -43.8(9) . . . . ?
C19 C20 N3 C23 136.3(7) . . . . ?
C30 C29 N3 C20 135.1(7) . . . . ?
C34 C29 N3 C20 -45.1(10) . . . . ?
C30 C29 N3 C23 -37.9(9) . . . . ?
C34 C29 N3 C23 141.9(7) . . . . ?
C24 C23 N3 C20 -42.4(9) . . . . ?
C28 C23 N3 C20 138.3(6) . . . . ?
C24 C23 N3 C29 130.7(7) . . . . ?
C28 C23 N3 C29 -48.6(9) . . . . ?

_diffrn_measured_fraction_theta_max 0.993
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.993
_refine_diff_density_max         1.402
_refine_diff_density_min         -1.209
_refine_diff_density_rms         0.111
