# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_mx9360
_database_code_depnum_ccdc_archive 'CCDC 2090830'
loop_
_audit_author_name
_audit_author_address
'Hui Peng'
;Beijing Institute of Technology
China
;
_audit_update_record             
;
2021-06-18 deposited with the CCDC.	2021-07-25 downloaded from the CCDC.
;
_audit_creation_date             2021-05-11
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Cl5 Sb, 2(C12 H28 N)'
_chemical_formula_sum            'C24 H56 Cl5 N2 Sb'
_chemical_formula_weight         671.70
_chemical_melting_point          ?
_chemical_oxdiff_formula         CHNClSb
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.6100(2)
_cell_length_b                   10.7418(2)
_cell_length_c                   16.2363(3)
_cell_angle_alpha                76.000(2)
_cell_angle_beta                 74.827(2)
_cell_angle_gamma                72.614(2)
_cell_volume                     1677.22(6)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    17957
_cell_measurement_temperature    170.0(3)
_cell_measurement_theta_max      31.0330
_cell_measurement_theta_min      1.9680
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.235
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.84926
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.45i (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.330
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             700
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.15
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0289
_diffrn_reflns_av_unetI/netI     0.0311
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.843
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            25968
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.843
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.973
_diffrn_reflns_theta_min         2.019
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      170.0(3)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.843
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -51.00  58.00   0.50    1.00    --  -11.60  45.00 -19.30  218
  2  ω    -69.00 -37.00   0.50    1.00    --  -11.60  45.00  53.75   64
  3  ω    -27.00  77.00   0.50    1.00    --  -11.60  45.00  53.75  208
  4  ω    -73.00  21.00   0.50    1.00    --  -11.60  45.00 120.00  188
  5  ω     41.00  67.00   0.50    1.00    --  -11.60  45.00 120.00   52
  6  ω   -101.00 -62.00   0.50    1.00    --  -11.60  45.00 150.00   78
  7  ω    -45.00  77.00   0.50    1.00    --  -11.60  45.00 175.91  244
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC10 (RCD3): fixed-chi single'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0161734000
_diffrn_orient_matrix_UB_12      0.0097650000
_diffrn_orient_matrix_UB_13      -0.0411912000
_diffrn_orient_matrix_UB_21      0.0583408000
_diffrn_orient_matrix_UB_22      0.0238202000
_diffrn_orient_matrix_UB_23      -0.0199402000
_diffrn_orient_matrix_UB_31      0.0381645000
_diffrn_orient_matrix_UB_32      -0.0654305000
_diffrn_orient_matrix_UB_33      -0.0046205000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8378
_reflns_number_total             8994
_reflns_odcompleteness_completeness 99.87
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     27.42
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.45i (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.45i (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.45i (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.420
_refine_diff_density_min         -0.426
_refine_diff_density_rms         0.057
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     297
_refine_ls_number_reflns         8994
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0255
_refine_ls_R_factor_gt           0.0230
_refine_ls_restrained_S_all      1.026
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0098P)²+0.8318P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0530
_refine_ls_wR_factor_ref         0.0543
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C2(H2A,H2B), C4(H4A,H4B), C5(H5A,H5B), C7(H7A,H7B), C8(H8A,H8B),
 C10(H10A,H10B), C11(H11A,H11B), C13(H13A,H13B), C14(H14A,H14B), C16(H16A,H16B),
  C17(H17A,H17B), C19(H19A,H19B), C20(H20A,H20B), C22(H22A,H22B), C23(H23A,H23B)
2.b Idealised Me refined as rotating group:
 C3(H3A,H3B,H3C), C6(H6A,H6B,H6C), C9(H9A,H9B,H9C), C12(H12A,H12B,H12C),
 C15(H15A,H15B,H15C), C18(H18A,H18B,H18C), C21(H21A,H21B,H21C), C24(H24A,H24B,
 H24C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.63709(2) 0.37780(2) 0.77695(2) 0.02238(3) Uani 1 1 d . . . . .
Cl1 Cl 0.79933(4) 0.52460(4) 0.67543(2) 0.03014(8) Uani 1 1 d . . . . .
Cl2 Cl 0.42164(4) 0.57380(4) 0.76689(3) 0.04206(10) Uani 1 1 d . . . . .
Cl3 Cl 0.62642(4) 0.32656(5) 0.64606(2) 0.03697(9) Uani 1 1 d . . . . .
Cl4 Cl 0.48315(4) 0.22270(4) 0.85627(2) 0.03090(8) Uani 1 1 d . . . . .
Cl5 Cl 0.84332(4) 0.17485(4) 0.79510(3) 0.03811(9) Uani 1 1 d . . . . .
N1 N 0.67970(14) 0.78957(12) 0.85466(8) 0.0272(3) Uani 1 1 d . . . . .
C1 C 0.68846(18) 0.64174(14) 0.87932(10) 0.0296(3) Uani 1 1 d . . . . .
H1A H 0.607517 0.627263 0.870226 0.036 Uiso 1 1 calc R U . . .
H1B H 0.764337 0.596691 0.839814 0.036 Uiso 1 1 calc R U . . .
C2 C 0.70414(19) 0.57714(16) 0.97090(10) 0.0340(3) Uani 1 1 d . . . . .
H2A H 0.630900 0.622384 1.011777 0.041 Uiso 1 1 calc R U . . .
H2B H 0.788475 0.583702 0.980118 0.041 Uiso 1 1 calc R U . . .
C3 C 0.70281(19) 0.43172(16) 0.98588(11) 0.0363(4) Uani 1 1 d . . . . .
H3A H 0.776115 0.387100 0.945781 0.054 Uiso 1 1 calc R U . . .
H3B H 0.618906 0.425724 0.977139 0.054 Uiso 1 1 calc R U . . .
H3C H 0.712578 0.390816 1.044139 0.054 Uiso 1 1 calc R U . . .
C4 C 0.79171(17) 0.82343(16) 0.87956(10) 0.0324(3) Uani 1 1 d . . . . .
H4A H 0.779271 0.918789 0.864961 0.039 Uiso 1 1 calc R U . . .
H4B H 0.782543 0.798703 0.941990 0.039 Uiso 1 1 calc R U . . .
C5 C 0.93358(19) 0.7587(2) 0.83771(14) 0.0458(4) Uani 1 1 d . . . . .
H5A H 0.947585 0.788470 0.775406 0.055 Uiso 1 1 calc R U . . .
H5B H 0.947020 0.663239 0.849322 0.055 Uiso 1 1 calc R U . . .
C6 C 1.0341(2) 0.7947(3) 0.87358(16) 0.0609(6) Uani 1 1 d . . . . .
H6A H 1.124182 0.754321 0.846313 0.091 Uiso 1 1 calc R U . . .
H6B H 1.021265 0.763268 0.935036 0.091 Uiso 1 1 calc R U . . .
H6C H 1.020323 0.889246 0.862059 0.091 Uiso 1 1 calc R U . . .
C7 C 0.54797(17) 0.86881(15) 0.90178(10) 0.0302(3) Uani 1 1 d . . . . .
H7A H 0.539972 0.834548 0.963442 0.036 Uiso 1 1 calc R U . . .
H7B H 0.553431 0.959891 0.892376 0.036 Uiso 1 1 calc R U . . .
C8 C 0.42043(19) 0.86929(19) 0.87660(13) 0.0413(4) Uani 1 1 d . . . . .
H8A H 0.416945 0.778965 0.879875 0.050 Uiso 1 1 calc R U . . .
H8B H 0.419647 0.915525 0.817416 0.050 Uiso 1 1 calc R U . . .
C9 C 0.2990(2) 0.9378(2) 0.93757(15) 0.0535(5) Uani 1 1 d . . . . .
H9A H 0.217898 0.940152 0.920783 0.080 Uiso 1 1 calc R U . . .
H9B H 0.303669 1.026623 0.934757 0.080 Uiso 1 1 calc R U . . .
H9C H 0.298558 0.889871 0.995773 0.080 Uiso 1 1 calc R U . . .
C10 C 0.68981(19) 0.82343(15) 0.75732(9) 0.0316(3) Uani 1 1 d . . . . .
H10A H 0.616079 0.800932 0.744197 0.038 Uiso 1 1 calc R U . . .
H10B H 0.773264 0.768004 0.730128 0.038 Uiso 1 1 calc R U . . .
C11 C 0.6862(2) 0.96691(16) 0.71666(10) 0.0369(4) Uani 1 1 d . . . . .
H11A H 0.599096 1.023562 0.737693 0.044 Uiso 1 1 calc R U . . .
H11B H 0.755181 0.993683 0.732326 0.044 Uiso 1 1 calc R U . . .
C12 C 0.7108(3) 0.98063(19) 0.61951(11) 0.0566(6) Uani 1 1 d . . . . .
H12A H 0.712181 1.070500 0.592972 0.085 Uiso 1 1 calc R U . . .
H12B H 0.640034 0.957794 0.604329 0.085 Uiso 1 1 calc R U . . .
H12C H 0.795981 0.922316 0.599362 0.085 Uiso 1 1 calc R U . . .
N2 N 0.22353(12) 0.32342(13) 0.62652(8) 0.0266(3) Uani 1 1 d . . . . .
C13 C 0.23204(16) 0.32896(17) 0.71750(9) 0.0308(3) Uani 1 1 d . . . . .
H13A H 0.276107 0.241115 0.744144 0.037 Uiso 1 1 calc R U . . .
H13B H 0.288573 0.387446 0.713128 0.037 Uiso 1 1 calc R U . . .
C14 C 0.09803(17) 0.37605(19) 0.77648(10) 0.0356(4) Uani 1 1 d . . . . .
H14A H 0.040393 0.318001 0.782294 0.043 Uiso 1 1 calc R U . . .
H14B H 0.053420 0.464871 0.751649 0.043 Uiso 1 1 calc R U . . .
C15 C 0.12085(19) 0.3759(2) 0.86496(11) 0.0451(4) Uani 1 1 d . . . . .
H15A H 0.176722 0.434605 0.859024 0.068 Uiso 1 1 calc R U . . .
H15B H 0.164638 0.287809 0.889402 0.068 Uiso 1 1 calc R U . . .
H15C H 0.035632 0.405373 0.902408 0.068 Uiso 1 1 calc R U . . .
C16 C 0.14912(16) 0.45611(16) 0.58239(10) 0.0296(3) Uani 1 1 d . . . . .
H16A H 0.153001 0.449342 0.523226 0.035 Uiso 1 1 calc R U . . .
H16B H 0.054993 0.472891 0.611632 0.035 Uiso 1 1 calc R U . . .
C17 C 0.2001(2) 0.57482(18) 0.57983(12) 0.0424(4) Uani 1 1 d . . . . .
H17A H 0.290568 0.565813 0.544690 0.051 Uiso 1 1 calc R U . . .
H17B H 0.202912 0.580723 0.637970 0.051 Uiso 1 1 calc R U . . .
C18 C 0.1049(2) 0.6987(2) 0.54121(16) 0.0583(6) Uani 1 1 d . . . . .
H18A H 0.102533 0.691921 0.483796 0.087 Uiso 1 1 calc R U . . .
H18B H 0.136196 0.775033 0.538598 0.087 Uiso 1 1 calc R U . . .
H18C H 0.015989 0.707560 0.576829 0.087 Uiso 1 1 calc R U . . .
C19 C 0.14546(17) 0.22466(17) 0.62899(11) 0.0342(3) Uani 1 1 d . . . . .
H19A H 0.053800 0.254954 0.660188 0.041 Uiso 1 1 calc R U . . .
H19B H 0.141055 0.225121 0.569993 0.041 Uiso 1 1 calc R U . . .
C20 C 0.2018(2) 0.0829(2) 0.67039(15) 0.0529(5) Uani 1 1 d . . . . .
H20A H 0.185517 0.075941 0.732777 0.064 Uiso 1 1 calc R U . . .
H20B H 0.298485 0.056623 0.648803 0.064 Uiso 1 1 calc R U . . .
C21 C 0.1340(3) -0.0080(2) 0.64875(17) 0.0662(7) Uani 1 1 d . . . . .
H21A H 0.153743 -0.003677 0.587098 0.099 Uiso 1 1 calc R U . . .
H21B H 0.038152 0.019849 0.668932 0.099 Uiso 1 1 calc R U . . .
H21C H 0.167162 -0.097372 0.676541 0.099 Uiso 1 1 calc R U . . .
C22 C 0.36746(15) 0.28421(17) 0.57675(10) 0.0309(3) Uani 1 1 d . . . . .
H22A H 0.410790 0.353819 0.572745 0.037 Uiso 1 1 calc R U . . .
H22B H 0.414933 0.204499 0.610109 0.037 Uiso 1 1 calc R U . . .
C23 C 0.38463(19) 0.2593(2) 0.48680(12) 0.0505(5) Uani 1 1 d . . . . .
H23A H 0.339791 0.191342 0.489659 0.061 Uiso 1 1 calc R U . . .
H23B H 0.341667 0.339779 0.451773 0.061 Uiso 1 1 calc R U . . .
C24 C 0.52885(19) 0.2165(2) 0.44449(12) 0.0486(5) Uani 1 1 d . . . . .
H24A H 0.535170 0.206730 0.386206 0.073 Uiso 1 1 calc R U . . .
H24B H 0.570107 0.133230 0.476456 0.073 Uiso 1 1 calc R U . . .
H24C H 0.574469 0.281926 0.443452 0.073 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 Cl1 2.6543(4) . ?
Sb1 Cl2 2.6150(4) . ?
Sb1 Cl3 2.3582(4) . ?
Sb1 Cl4 2.5669(4) . ?
Sb1 Cl5 2.6082(4) . ?
N1 C1 1.5212(19) . ?
N1 C4 1.513(2) . ?
N1 C7 1.519(2) . ?
N1 C10 1.5161(18) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C1 C2 1.510(2) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C2 C3 1.525(2) . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C4 C5 1.509(3) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C5 C6 1.518(3) . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C7 C8 1.511(2) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 C9 1.516(3) . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C10 C11 1.516(2) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 C12 1.508(2) . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
N2 C13 1.5196(19) . ?
N2 C16 1.516(2) . ?
N2 C19 1.517(2) . ?
N2 C22 1.5155(19) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C13 C14 1.512(2) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C14 C15 1.518(2) . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 C17 1.515(2) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C17 C18 1.519(3) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 C20 1.517(3) . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 C21 1.520(3) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C22 C23 1.503(2) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C23 C24 1.485(3) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl2 Sb1 Cl1 92.716(13) . . ?
Cl3 Sb1 Cl1 84.465(13) . . ?
Cl3 Sb1 Cl2 90.301(16) . . ?
Cl3 Sb1 Cl4 87.676(14) . . ?
Cl3 Sb1 Cl5 90.974(16) . . ?
Cl4 Sb1 Cl1 172.012(12) . . ?
Cl4 Sb1 Cl2 88.744(14) . . ?
Cl4 Sb1 Cl5 88.067(13) . . ?
Cl5 Sb1 Cl1 90.636(13) . . ?
Cl5 Sb1 Cl2 176.514(14) . . ?
C4 N1 C1 111.53(12) . . ?
C4 N1 C7 106.46(11) . . ?
C4 N1 C10 111.01(12) . . ?
C7 N1 C1 110.99(12) . . ?
C10 N1 C1 105.75(11) . . ?
C10 N1 C7 111.19(12) . . ?
N1 C1 H1A 108.1 . . ?
N1 C1 H1B 108.1 . . ?
H1A C1 H1B 107.3 . . ?
C2 C1 N1 116.63(12) . . ?
C2 C1 H1A 108.1 . . ?
C2 C1 H1B 108.1 . . ?
C1 C2 H2A 109.8 . . ?
C1 C2 H2B 109.8 . . ?
C1 C2 C3 109.55(13) . . ?
H2A C2 H2B 108.2 . . ?
C3 C2 H2A 109.8 . . ?
C3 C2 H2B 109.8 . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
N1 C4 H4A 108.3 . . ?
N1 C4 H4B 108.3 . . ?
H4A C4 H4B 107.4 . . ?
C5 C4 N1 115.92(14) . . ?
C5 C4 H4A 108.3 . . ?
C5 C4 H4B 108.3 . . ?
C4 C5 H5A 109.7 . . ?
C4 C5 H5B 109.7 . . ?
C4 C5 C6 109.67(18) . . ?
H5A C5 H5B 108.2 . . ?
C6 C5 H5A 109.7 . . ?
C6 C5 H5B 109.7 . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
N1 C7 H7A 108.1 . . ?
N1 C7 H7B 108.1 . . ?
H7A C7 H7B 107.3 . . ?
C8 C7 N1 116.72(13) . . ?
C8 C7 H7A 108.1 . . ?
C8 C7 H7B 108.1 . . ?
C7 C8 H8A 109.8 . . ?
C7 C8 H8B 109.8 . . ?
C7 C8 C9 109.34(16) . . ?
H8A C8 H8B 108.3 . . ?
C9 C8 H8A 109.8 . . ?
C9 C8 H8B 109.8 . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N1 C10 H10A 108.4 . . ?
N1 C10 H10B 108.4 . . ?
N1 C10 C11 115.65(12) . . ?
H10A C10 H10B 107.4 . . ?
C11 C10 H10A 108.4 . . ?
C11 C10 H10B 108.4 . . ?
C10 C11 H11A 109.9 . . ?
C10 C11 H11B 109.9 . . ?
H11A C11 H11B 108.3 . . ?
C12 C11 C10 108.78(14) . . ?
C12 C11 H11A 109.9 . . ?
C12 C11 H11B 109.9 . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C16 N2 C13 111.48(12) . . ?
C16 N2 C19 106.28(12) . . ?
C19 N2 C13 110.83(12) . . ?
C22 N2 C13 106.55(11) . . ?
C22 N2 C16 110.44(12) . . ?
C22 N2 C19 111.33(12) . . ?
N2 C13 H13A 108.5 . . ?
N2 C13 H13B 108.5 . . ?
H13A C13 H13B 107.5 . . ?
C14 C13 N2 115.03(12) . . ?
C14 C13 H13A 108.5 . . ?
C14 C13 H13B 108.5 . . ?
C13 C14 H14A 109.8 . . ?
C13 C14 H14B 109.8 . . ?
C13 C14 C15 109.60(14) . . ?
H14A C14 H14B 108.2 . . ?
C15 C14 H14A 109.8 . . ?
C15 C14 H14B 109.8 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
N2 C16 H16A 108.2 . . ?
N2 C16 H16B 108.2 . . ?
H16A C16 H16B 107.3 . . ?
C17 C16 N2 116.41(13) . . ?
C17 C16 H16A 108.2 . . ?
C17 C16 H16B 108.2 . . ?
C16 C17 H17A 110.0 . . ?
C16 C17 H17B 110.0 . . ?
C16 C17 C18 108.31(16) . . ?
H17A C17 H17B 108.4 . . ?
C18 C17 H17A 110.0 . . ?
C18 C17 H17B 110.0 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N2 C19 H19A 108.3 . . ?
N2 C19 H19B 108.3 . . ?
H19A C19 H19B 107.4 . . ?
C20 C19 N2 115.99(15) . . ?
C20 C19 H19A 108.3 . . ?
C20 C19 H19B 108.3 . . ?
C19 C20 H20A 109.8 . . ?
C19 C20 H20B 109.8 . . ?
C19 C20 C21 109.28(19) . . ?
H20A C20 H20B 108.3 . . ?
C21 C20 H20A 109.8 . . ?
C21 C20 H20B 109.8 . . ?
C20 C21 H21A 109.5 . . ?
C20 C21 H21B 109.5 . . ?
C20 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
N2 C22 H22A 108.2 . . ?
N2 C22 H22B 108.2 . . ?
H22A C22 H22B 107.4 . . ?
C23 C22 N2 116.18(13) . . ?
C23 C22 H22A 108.2 . . ?
C23 C22 H22B 108.2 . . ?
C22 C23 H23A 109.1 . . ?
C22 C23 H23B 109.1 . . ?
H23A C23 H23B 107.9 . . ?
C24 C23 C22 112.29(15) . . ?
C24 C23 H23A 109.1 . . ?
C24 C23 H23B 109.1 . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 176.66(14) . . . . ?
N1 C4 C5 C6 -176.17(15) . . . . ?
N1 C7 C8 C9 172.82(14) . . . . ?
N1 C10 C11 C12 174.55(17) . . . . ?
C1 N1 C4 C5 60.66(18) . . . . ?
C1 N1 C7 C8 -67.92(17) . . . . ?
C1 N1 C10 C11 -178.83(15) . . . . ?
C4 N1 C1 C2 49.38(19) . . . . ?
C4 N1 C7 C8 170.53(14) . . . . ?
C4 N1 C10 C11 -57.71(19) . . . . ?
C7 N1 C1 C2 -69.15(18) . . . . ?
C7 N1 C4 C5 -178.14(14) . . . . ?
C7 N1 C10 C11 60.61(19) . . . . ?
C10 N1 C1 C2 170.16(15) . . . . ?
C10 N1 C4 C5 -56.99(18) . . . . ?
C10 N1 C7 C8 49.50(18) . . . . ?
N2 C13 C14 C15 179.61(15) . . . . ?
N2 C16 C17 C18 -174.61(15) . . . . ?
N2 C19 C20 C21 -166.51(16) . . . . ?
N2 C22 C23 C24 -177.80(17) . . . . ?
C13 N2 C16 C17 53.34(18) . . . . ?
C13 N2 C19 C20 -58.99(19) . . . . ?
C13 N2 C22 C23 174.23(16) . . . . ?
C16 N2 C13 C14 55.34(18) . . . . ?
C16 N2 C19 C20 179.72(15) . . . . ?
C16 N2 C22 C23 -64.5(2) . . . . ?
C19 N2 C13 C14 -62.83(18) . . . . ?
C19 N2 C16 C17 174.21(14) . . . . ?
C19 N2 C22 C23 53.3(2) . . . . ?
C22 N2 C13 C14 175.91(14) . . . . ?
C22 N2 C16 C17 -64.92(17) . . . . ?
C22 N2 C19 C20 59.41(18) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.408
_oxdiff_exptl_absorpt_empirical_full_min 0.741
