# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_PMOF-2
_database_code_depnum_ccdc_archive 'CCDC 2126492'
loop_
_audit_author_name
_audit_author_address
'yuhe sun'
; Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
China
;
_audit_update_record             
;
2022-02-22 deposited with the CCDC.	2022-02-25 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C75 H79 Eu3 N8 O39'
_chemical_formula_weight         2172.34

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.3027(7)
_cell_length_b                   17.1267(5)
_cell_length_c                   19.0402(7)
_cell_angle_alpha                88.509(3)
_cell_angle_beta                 83.110(3)
_cell_angle_gamma                70.595(4)
_cell_volume                     4366.9(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    12693
_cell_measurement_theta_min      3.724
_cell_measurement_theta_max      25.712

_exptl_crystal_description       plate-like
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.652
_exptl_crystal_F_000             2172
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    2.223
_shelx_estimated_absorpt_T_min   0.665
_shelx_estimated_absorpt_T_max   0.897
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.97151
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_process_details   'Sphere (Rigaku CrystalClear)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            71622
_diffrn_reflns_av_unetI/netI     0.0916
_diffrn_reflns_av_R_equivalents  0.0813
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         3.452
_diffrn_reflns_theta_max         26.372
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measured_fraction_theta_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_point_group_measured_fraction_full 0.994
_reflns_number_total             17673
_reflns_number_gt                11028
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)'
_computing_cell_refinement       'CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)'
_computing_data_reduction        'CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0755P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         17673
_refine_ls_number_parameters     1221
_refine_ls_number_restraints     125
_refine_ls_R_factor_all          0.0992
_refine_ls_R_factor_gt           0.0543
_refine_ls_wR_factor_ref         0.1494
_refine_ls_wR_factor_gt          0.1302
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_restrained_S_all      1.028
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.43533(3) 0.50521(2) 0.78556(2) 0.03219(11) Uani 1 1 d . . . . .
Eu2 Eu 0.51737(3) 0.74911(2) 0.28565(2) 0.03794(12) Uani 1 1 d . . . . .
Eu3 Eu 0.48241(3) 1.00964(2) 0.21957(2) 0.04193(12) Uani 1 1 d . . . . .
O1 O 0.5675(4) 0.2654(3) 0.8097(2) 0.0477(13) Uani 1 1 d . . . . .
O2 O 0.5370(4) 0.3941(3) 0.8469(2) 0.0460(13) Uani 1 1 d . . . . .
O3 O 0.6128(4) 0.3475(3) 1.1685(2) 0.0450(13) Uani 1 1 d . . . . .
O4 O 0.5627(4) 0.4487(3) 1.0934(2) 0.0501(14) Uani 1 1 d . . . . .
O5 O 0.3779(4) 0.3907(3) 0.7625(3) 0.0402(12) Uani 1 1 d . . . . .
O6 O 0.3060(4) 0.3313(3) 0.6935(3) 0.0567(14) Uani 1 1 d . . . . .
O7 O 0.2659(4) 0.5391(4) 0.8338(3) 0.0559(14) Uani 1 1 d . . . . .
O8 O 0.1040(5) 0.6139(5) 0.8456(4) 0.097(2) Uani 1 1 d . . . . .
O9 O 0.5721(5) 0.8401(3) -0.1777(3) 0.0599(16) Uani 1 1 d . . . . .
O10 O 0.5136(5) 0.9385(3) -0.0980(3) 0.0623(16) Uani 1 1 d . . . . .
O11 O 0.6221(4) 0.7738(3) 0.1913(2) 0.0429(12) Uani 1 1 d . . . . .
O12 O 0.5771(5) 0.8985(3) 0.1439(3) 0.0624(16) Uani 1 1 d . . . . .
O13 O 0.4534(4) 0.5774(3) 0.3126(2) 0.0485(13) Uani 1 1 d . . . . .
O14 O 0.4889(4) 0.6653(3) 0.3805(3) 0.0544(14) Uani 1 1 d . . . . .
O15 O 0.3582(4) 0.5628(3) 0.6875(3) 0.0561(15) Uani 1 1 d . . . . .
O16 O 0.3960(8) 0.6676(6) 0.6400(3) 0.143(4) Uani 1 1 d . . . . .
O17 O 0.4208(4) 1.0695(3) 0.6936(3) 0.0481(13) Uani 1 1 d . . . . .
O18 O 0.4523(4) 1.1687(3) 0.6276(3) 0.0543(15) Uani 1 1 d . . . . .
O19 O 0.3869(4) 1.0666(3) 0.3234(3) 0.0586(15) Uani 1 1 d . . . . .
O20 O 0.4226(8) 1.1676(6) 0.3692(4) 0.134(4) Uani 1 1 d . . . . .
N1 N 0.9151(5) -0.3450(4) 1.0619(4) 0.0614(19) Uani 1 1 d . . . . .
N2 N 0.7145(4) 0.0845(3) 1.0113(3) 0.0319(13) Uani 1 1 d . . . . .
N3 N 0.9222(6) 0.1490(4) -0.0916(5) 0.070(2) Uani 1 1 d . . . . .
N4 N 0.7075(4) 0.5796(3) -0.0254(3) 0.0331(13) Uani 1 1 d . . . . .
N5 N 0.0813(7) 0.1044(6) 0.4448(8) 0.096(3) Uani 1 1 d . . . . .
N6 N 0.2825(4) 0.4212(3) 0.4814(3) 0.0380(14) Uani 1 1 d . . . . .
N7 N 0.0680(6) 0.6006(5) 0.5894(6) 0.080(3) Uani 1 1 d . . . . .
N8 N 0.2753(4) 0.9197(3) 0.5343(3) 0.0371(14) Uani 1 1 d . . . . .
C1 C 0.8991(6) -0.3123(5) 0.9967(5) 0.053(2) Uani 1 1 d . . . . .
H1A H 0.914097 -0.348723 0.958311 0.064 Uiso 1 1 calc R U . . .
C2 C 0.8926(7) -0.2904(5) 1.1159(5) 0.064(2) Uani 1 1 d . . . . .
H2 H 0.901910 -0.310865 1.161190 0.076 Uiso 1 1 calc R U . . .
C3 C 0.8620(6) -0.2287(4) 0.9840(4) 0.0454(19) Uani 1 1 d . . . . .
H3A H 0.852205 -0.209785 0.938384 0.055 Uiso 1 1 calc R U . . .
C4 C 0.8563(6) -0.2056(5) 1.1078(4) 0.049(2) Uani 1 1 d . . . . .
H4 H 0.843217 -0.170262 1.146743 0.059 Uiso 1 1 calc R U . . .
C5 C 0.8395(6) -0.1734(4) 1.0401(4) 0.0429(18) Uani 1 1 d . . . . .
C6 C 0.7983(5) -0.0833(4) 1.0299(4) 0.0385(17) Uani 1 1 d . . . . .
C7 C 0.7314(6) -0.0520(5) 0.9807(4) 0.0471(19) Uani 1 1 d . . . . .
H7 H 0.715174 -0.088262 0.952790 0.056 Uiso 1 1 calc R U . . .
C8 C 0.8218(6) -0.0273(4) 1.0692(4) 0.052(2) Uani 1 1 d . . . . .
H8 H 0.865923 -0.046300 1.102880 0.062 Uiso 1 1 calc R U . . .
C9 C 0.6892(6) 0.0315(4) 0.9728(4) 0.0475(19) Uani 1 1 d . . . . .
H9 H 0.642919 0.051721 0.940678 0.057 Uiso 1 1 calc R U . . .
C10 C 0.7809(6) 0.0561(4) 1.0590(4) 0.0461(19) Uani 1 1 d . . . . .
H10 H 0.798676 0.093257 1.084865 0.055 Uiso 1 1 calc R U . . .
C11 C 0.6694(5) 0.1740(4) 1.0009(3) 0.0319(15) Uani 1 1 d . . . . .
C12 C 0.6443(5) 0.2023(4) 0.9355(3) 0.0333(16) Uani 1 1 d . . . . .
H12 H 0.658053 0.165151 0.897769 0.040 Uiso 1 1 calc R U . . .
C13 C 0.6522(5) 0.2281(4) 1.0575(3) 0.0323(15) Uani 1 1 d . . . . .
H13 H 0.668520 0.208093 1.101888 0.039 Uiso 1 1 calc R U . . .
C14 C 0.5983(5) 0.2866(4) 0.9254(3) 0.0294(15) Uani 1 1 d . . . . .
C15 C 0.6104(5) 0.3121(4) 1.0474(3) 0.0297(15) Uani 1 1 d . . . . .
C16 C 0.5825(5) 0.3412(4) 0.9815(3) 0.0304(15) Uani 1 1 d . . . . .
H16 H 0.553059 0.397761 0.975042 0.037 Uiso 1 1 calc R U . . .
C17 C 0.5657(5) 0.3179(4) 0.8546(3) 0.0340(16) Uani 1 1 d . . . . .
C18 C 0.5946(5) 0.3715(4) 1.1067(3) 0.0347(16) Uani 1 1 d . . . . .
C19 C 0.8873(7) 0.2014(6) -0.1417(6) 0.073(3) Uani 1 1 d . . . . .
H19 H 0.891344 0.179416 -0.186557 0.087 Uiso 1 1 calc R U . . .
C20 C 0.9155(6) 0.1829(5) -0.0285(6) 0.063(3) Uani 1 1 d . . . . .
H20 H 0.938659 0.147661 0.008280 0.076 Uiso 1 1 calc R U . . .
C21 C 0.8456(6) 0.2853(5) -0.1332(5) 0.058(2) Uani 1 1 d . . . . .
H21A H 0.821553 0.318567 -0.170910 0.070 Uiso 1 1 calc R U . . .
C22 C 0.8766(5) 0.2665(4) -0.0135(5) 0.0472(19) Uani 1 1 d . . . . .
H22 H 0.875033 0.286750 0.031644 0.057 Uiso 1 1 calc R U . . .
C23 C 0.8399(6) 0.3197(5) -0.0672(5) 0.048(2) Uani 1 1 d . . . . .
C24 C 0.7939(5) 0.4108(4) -0.0534(4) 0.0367(16) Uani 1 1 d . . . . .
C25 C 0.7146(6) 0.4597(4) -0.0884(4) 0.0462(19) Uani 1 1 d . . . . .
H25 H 0.689912 0.435501 -0.121783 0.055 Uiso 1 1 calc R U . . .
C26 C 0.8260(5) 0.4513(4) -0.0030(4) 0.0411(17) Uani 1 1 d . . . . .
H26 H 0.877058 0.421159 0.022862 0.049 Uiso 1 1 calc R U . . .
C27 C 0.6732(6) 0.5426(4) -0.0742(4) 0.0431(18) Uani 1 1 d . . . . .
H27 H 0.620688 0.574230 -0.098167 0.052 Uiso 1 1 calc R U . . .
C28 C 0.7835(5) 0.5341(4) 0.0083(4) 0.0393(17) Uani 1 1 d . . . . .
H28 H 0.807992 0.559901 0.040606 0.047 Uiso 1 1 calc R U . . .
C29 C 0.6647(5) 0.6685(4) -0.0129(3) 0.0303(15) Uani 1 1 d . . . . .
C30 C 0.6358(5) 0.7206(4) -0.0691(3) 0.0371(17) Uani 1 1 d . . . . .
H30 H 0.645295 0.699052 -0.114742 0.045 Uiso 1 1 calc R U . . .
C31 C 0.6530(5) 0.6995(4) 0.0554(3) 0.0323(15) Uani 1 1 d . . . . .
H31 H 0.670787 0.663826 0.092856 0.039 Uiso 1 1 calc R U . . .
C32 C 0.5932(5) 0.8040(4) -0.0566(3) 0.0340(16) Uani 1 1 d . . . . .
C33 C 0.6143(5) 0.7847(4) 0.0672(3) 0.0334(16) Uani 1 1 d . . . . .
C34 C 0.5822(5) 0.8365(4) 0.0112(3) 0.0347(16) Uani 1 1 d . . . . .
H34 H 0.553071 0.893285 0.019115 0.042 Uiso 1 1 calc R U . . .
C35 C 0.5586(6) 0.8640(5) -0.1143(4) 0.0450(19) Uani 1 1 d . . . . .
C36 C 0.6036(5) 0.8212(4) 0.1405(4) 0.0370(16) Uani 1 1 d . . . . .
C37 C 0.1110(8) 0.1422(6) 0.3890(8) 0.091(4) Uani 1 1 d . . . . .
H37 H 0.106992 0.124277 0.344097 0.110 Uiso 1 1 calc R U . . .
C38 C 0.0897(8) 0.1308(7) 0.5073(8) 0.093(4) Uani 1 1 d . . . . .
H38 H 0.070020 0.104269 0.546705 0.112 Uiso 1 1 calc R U . . .
C39 C 0.1476(6) 0.2066(5) 0.3944(5) 0.064(2) Uani 1 1 d . . . . .
H39 H 0.166818 0.231766 0.353908 0.077 Uiso 1 1 calc R U . . .
C40 C 0.1249(6) 0.1938(5) 0.5196(5) 0.066(3) Uani 1 1 d . . . . .
H40 H 0.128337 0.209477 0.565390 0.079 Uiso 1 1 calc R U . . .
C41 C 0.1554(6) 0.2336(5) 0.4610(5) 0.052(2) Uani 1 1 d . . . . .
C42 C 0.1974(5) 0.2992(4) 0.4687(4) 0.0441(19) Uani 1 1 d . . . . .
C43 C 0.1854(6) 0.3644(5) 0.4216(4) 0.051(2) Uani 1 1 d . . . . .
H43 H 0.148488 0.366940 0.384027 0.062 Uiso 1 1 calc R U . . .
C44 C 0.2551(6) 0.2995(5) 0.5233(4) 0.050(2) Uani 1 1 d . . . . .
H44 H 0.264429 0.258015 0.556860 0.060 Uiso 1 1 calc R U . . .
C45 C 0.2261(6) 0.4238(5) 0.4291(4) 0.0458(19) Uani 1 1 d . . . . .
H45 H 0.215059 0.467463 0.397537 0.055 Uiso 1 1 calc R U . . .
C46 C 0.2977(6) 0.3591(4) 0.5283(4) 0.0466(19) Uani 1 1 d . . . . .
H46 H 0.337376 0.356936 0.564036 0.056 Uiso 1 1 calc R U . . .
C47 C 0.3271(5) 0.4847(4) 0.4889(3) 0.0312(15) Uani 1 1 d . . . . .
C48 C 0.3674(5) 0.5148(4) 0.4292(3) 0.0347(16) Uani 1 1 d . . . . .
H48 H 0.365641 0.494484 0.384713 0.042 Uiso 1 1 calc R U . . .
C49 C 0.3293(5) 0.5132(4) 0.5560(3) 0.0337(16) Uani 1 1 d . . . . .
H49 H 0.302806 0.491503 0.595792 0.040 Uiso 1 1 calc R U . . .
C50 C 0.4107(5) 0.5758(4) 0.4356(3) 0.0311(15) Uani 1 1 d . . . . .
C51 C 0.3713(5) 0.5740(4) 0.5634(3) 0.0319(15) Uani 1 1 d . . . . .
C52 C 0.4112(5) 0.6056(4) 0.5035(3) 0.0292(15) Uani 1 1 d . . . . .
H52 H 0.438602 0.647041 0.508462 0.035 Uiso 1 1 calc R U . . .
C53 C 0.4537(5) 0.6082(4) 0.3713(3) 0.0338(16) Uani 1 1 d . . . . .
C54 C 0.3781(6) 0.6040(5) 0.6364(4) 0.048(2) Uani 1 1 d . . . . .
C55 C 0.0873(7) 0.6386(6) 0.6436(6) 0.072(3) Uani 1 1 d . . . . .
H55 H 0.074558 0.621135 0.689321 0.086 Uiso 1 1 calc R U . . .
C56 C 0.0864(6) 0.6271(5) 0.5238(6) 0.066(3) Uani 1 1 d . . . . .
H56 H 0.073134 0.601346 0.485606 0.079 Uiso 1 1 calc R U . . .
C57 C 0.1260(6) 0.7042(5) 0.6340(5) 0.061(2) Uani 1 1 d . . . . .
H57 H 0.138564 0.729455 0.672806 0.073 Uiso 1 1 calc R U . . .
C58 C 0.1248(6) 0.6924(5) 0.5108(5) 0.056(2) Uani 1 1 d . . . . .
H58 H 0.136226 0.709519 0.464735 0.067 Uiso 1 1 calc R U . . .
C59 C 0.1453(5) 0.7306(4) 0.5663(5) 0.0448(19) Uani 1 1 d . . . . .
C60 C 0.1881(6) 0.7975(4) 0.5552(4) 0.0445(18) Uani 1 1 d . . . . .
C61 C 0.1661(7) 0.8621(5) 0.6028(4) 0.058(2) Uani 1 1 d . . . . .
H61 H 0.122053 0.863685 0.643301 0.070 Uiso 1 1 calc R U . . .
C62 C 0.2536(6) 0.7983(5) 0.4960(4) 0.052(2) Uani 1 1 d . . . . .
H62 H 0.267427 0.757835 0.460936 0.062 Uiso 1 1 calc R U . . .
C63 C 0.2062(6) 0.9231(5) 0.5926(4) 0.056(2) Uani 1 1 d . . . . .
H63 H 0.187609 0.967158 0.624637 0.067 Uiso 1 1 calc R U . . .
C64 C 0.2986(6) 0.8578(4) 0.4879(4) 0.0487(19) Uani 1 1 d . . . . .
H64 H 0.346247 0.854708 0.449307 0.058 Uiso 1 1 calc R U . . .
C65 C 0.3217(5) 0.9841(4) 0.5248(4) 0.0351(16) Uani 1 1 d . . . . .
C66 C 0.3492(5) 1.0130(4) 0.5826(4) 0.0344(16) Uani 1 1 d . . . . .
H66 H 0.338299 0.992246 0.627344 0.041 Uiso 1 1 calc R U . . .
C67 C 0.3365(5) 1.0131(4) 0.4582(3) 0.0340(16) Uani 1 1 d . . . . .
H67 H 0.317767 0.991692 0.419907 0.041 Uiso 1 1 calc R U . . .
C68 C 0.3940(5) 1.0747(4) 0.5733(3) 0.0326(16) Uani 1 1 d . . . . .
C69 C 0.3795(5) 1.0744(4) 0.4482(3) 0.0360(16) Uani 1 1 d . . . . .
C70 C 0.4081(5) 1.1046(4) 0.5062(3) 0.0329(16) Uani 1 1 d . . . . .
H70 H 0.437383 1.145664 0.499729 0.039 Uiso 1 1 calc R U . . .
C71 C 0.4257(5) 1.1059(4) 0.6361(4) 0.0359(16) Uani 1 1 d . . . . .
C72 C 0.3997(6) 1.1052(5) 0.3750(4) 0.051(2) Uani 1 1 d . . . . .
C74 C 0.1938(9) 0.6022(7) 0.8249(5) 0.070(3) Uani 1 1 d . . . . .
H74 H 0.208381 0.645094 0.800230 0.085 Uiso 1 1 calc R U . . .
C75 C 0.3024(7) 0.3899(5) 0.7331(4) 0.057(2) Uani 1 1 d . . . . .
H75A H 0.243037 0.434098 0.741377 0.068 Uiso 1 1 calc R U . . .
O1W O 1.0019(6) -0.5098(4) 1.1130(4) 0.107(3) Uani 1 1 d . . . . .
H1C H 0.983693 -0.468270 1.088875 0.161 Uiso 1 1 d R U . . .
H1D H 0.960873 -0.513980 1.145553 0.161 Uiso 1 1 d R U . . .
O3W O 0.6092(6) 0.6982(4) 0.7375(4) 0.106(3) Uani 1 1 d . . . . .
H3C H 0.592748 0.695521 0.698053 0.159 Uiso 1 1 d R U . . .
H3D H 0.583878 0.743071 0.758063 0.159 Uiso 1 1 d R U . . .
O4W O 0.7732(6) 0.4494(5) 0.7163(4) 0.110(3) Uani 1 1 d . . . . .
H4C H 0.742851 0.416269 0.722746 0.165 Uiso 1 1 d R U . . .
H4D H 0.739302 0.497439 0.709676 0.165 Uiso 1 1 d R U . . .
O5W O 0.5810(4) 0.5486(3) 0.7687(3) 0.0553(14) Uani 1 1 d . . . . .
H5 H 0.562984 0.600075 0.759835 0.083 Uiso 1 1 d R U . . .
O7W O 0.9610(9) -0.0272(6) -0.0977(7) 0.180(5) Uani 1 1 d . . . . .
H7C H 0.908279 -0.018549 -0.114373 0.269 Uiso 1 1 d R U . . .
H7D H 0.985999 0.009531 -0.103063 0.269 Uiso 1 1 d R U . . .
O10W O 0.6558(6) 1.2025(5) 0.2481(4) 0.113(3) Uani 1 1 d . . . . .
H10C H 0.646316 1.198419 0.291207 0.170 Uiso 1 1 d R U . . .
H10D H 0.639906 1.249819 0.233027 0.170 Uiso 1 1 d R U . . .
O11W O 0.6250(5) 1.0545(4) 0.2180(3) 0.0754(18) Uani 1 1 d . . . . .
H11C H 0.678481 1.017492 0.211912 0.113 Uiso 1 1 d R U . . .
H11D H 0.619201 1.092752 0.244482 0.113 Uiso 1 1 d R U . . .
O13W O 0.0125(9) 0.4561(7) 0.6021(8) 0.205(5) Uani 1 1 d . U . . .
H13C H 0.022313 0.449430 0.643786 0.307 Uiso 1 1 d R U . . .
H13D H -0.003807 0.507620 0.593656 0.307 Uiso 1 1 d R U . . .
O2W O 0.8107(14) 0.6702(16) 0.7601(10) 0.181(8) Uani 0.530(13) 1 d . U P A 1
H2C H 0.806558 0.716105 0.775855 0.271 Uiso 0.530(13) 1 d R U P A 1
H2D H 0.804068 0.635005 0.794855 0.271 Uiso 0.530(13) 1 d R U P A 1
O2B O 0.9053(15) 0.4939(17) 0.7699(10) 0.168(8) Uani 0.470(13) 1 d . U P A 2
H2E H 0.958857 0.462205 0.779936 0.252 Uiso 0.470(13) 1 d R U P A 2
H2F H 0.876707 0.532715 0.797566 0.252 Uiso 0.470(13) 1 d R U P A 2
O6W O 1.1461(10) -0.1569(8) -0.1734(7) 0.211(6) Uani 1 1 d . . . . .
H6C H 1.171886 -0.195774 -0.201372 0.316 Uiso 1 1 d R U . . .
H6D H 1.088696 -0.150834 -0.156202 0.316 Uiso 1 1 d R U . . .
O8W O 0.8151(15) 0.7772(13) 0.3022(9) 0.147(7) Uani 0.534(13) 1 d . U P B 1
H8C H 0.828796 0.818236 0.288234 0.220 Uiso 0.534(13) 1 d R U P B 1
H8D H 0.776476 0.764186 0.280194 0.220 Uiso 0.534(13) 1 d R U P B 1
O8B O 0.895(2) 0.6704(17) 0.3114(12) 0.171(8) Uani 0.466(13) 1 d . U P B 2
H8E H 0.898379 0.626657 0.293099 0.256 Uiso 0.466(13) 1 d R U P B 2
H8F H 0.948200 0.673627 0.320909 0.256 Uiso 0.466(13) 1 d R U P B 2
O9W O 0.8211(7) 0.9455(5) 0.2570(4) 0.126(3) Uani 1 1 d . . . . .
H9C H 0.789194 0.982081 0.285992 0.189 Uiso 1 1 d R U . . .
H9D H 0.879374 0.944081 0.251902 0.189 Uiso 1 1 d R U . . .
O14W O 0.0688(14) -0.0418(9) 0.3871(14) 0.227(11) Uani 0.612(14) 1 d . U P C 1
H14C H 0.083234 -0.080492 0.358860 0.341 Uiso 0.612(14) 1 d R U P C 1
H14D H 0.083804 -0.054092 0.427180 0.341 Uiso 0.612(14) 1 d R U P C 1
O14B O -0.020(3) 0.0028(17) 0.265(2) 0.248(13) Uani 0.388(14) 1 d . U P C 2
H14E H -0.028665 -0.034510 0.290090 0.372 Uiso 0.388(14) 1 d R U P C 2
H14F H 0.026935 0.017480 0.272100 0.372 Uiso 0.388(14) 1 d R U P C 2
O18W O 0.4717(19) 0.2766(16) 0.4246(14) 0.199(10) Uani 0.5 1 d . U P D 1
H18C H 0.428773 0.269991 0.402724 0.298 Uiso 0.5 1 d R U P D 1
H18D H 0.485023 0.247201 0.459174 0.298 Uiso 0.5 1 d R U P D 1
O17W O 0.0564(17) 0.2646(14) 0.1988(11) 0.162(8) Uani 0.5 1 d . U P E 1
H17C H 0.116532 0.237254 0.196445 0.243 Uiso 0.5 1 d R U P E 1
H17D H 0.042052 0.314344 0.206605 0.243 Uiso 0.5 1 d R U P E 1
O18B O 0.5747(18) 0.2068(13) 0.4020(14) 0.175(8) Uani 0.5 1 d . U P F 2
H18E H 0.563674 0.211892 0.445202 0.262 Uiso 0.5 1 d R U P F 2
H18F H 0.632394 0.181042 0.386092 0.262 Uiso 0.5 1 d R U P F 2
O17B O -0.0137(16) 0.2255(14) 0.1873(14) 0.171(9) Uani 0.5 1 d . U P G 2
H17E H -0.034447 0.190787 0.207879 0.257 Uiso 0.5 1 d R U P G 2
H17F H -0.029267 0.236867 0.147239 0.257 Uiso 0.5 1 d R U P G 2
O22 O 0.4251(11) 0.8892(18) 0.2528(15) 0.040(4) Uani 0.633(10) 1 d D . P H 1
O21 O 0.3433(11) 0.8256(7) 0.3242(8) 0.051(3) Uani 0.633(10) 1 d D U P H 1
C73 C 0.3460(10) 0.8849(7) 0.2881(6) 0.048(3) Uani 0.633(10) 1 d D U P H 1
H73A H 0.287131 0.929074 0.286367 0.058 Uiso 0.633(10) 1 calc R U P H 1
O12W O 0.3134(16) 1.0448(9) 0.1853(9) 0.072(4) Uani 0.633(10) 1 d . U P H 1
H12A H 0.258386 1.069453 0.218263 0.086 Uiso 0.633(10) 1 d R U P H 1
O15W O 0.2109(14) 0.7316(13) 0.3261(10) 0.193(8) Uani 0.633(10) 1 d . U P H 1
H15C H 0.261532 0.722841 0.298039 0.290 Uiso 0.633(10) 1 d R U P H 1
H15D H 0.181492 0.780101 0.337889 0.290 Uiso 0.633(10) 1 d R U P H 1
O21B O 0.326(2) 1.0092(14) 0.1949(15) 0.065(6) Uani 0.367(10) 1 d D U P H 2
O22B O 0.411(2) 0.901(3) 0.255(3) 0.048(8) Uani 0.367(10) 1 d D U P H 2
C73B C 0.3375(19) 0.9402(13) 0.2254(13) 0.071(6) Uani 0.367(10) 1 d D U P H 2
H73B H 0.286723 0.917590 0.225583 0.085 Uiso 0.367(10) 1 calc R U P H 2
O12B O 0.341(2) 0.7896(15) 0.3289(14) 0.069(7) Uani 0.367(10) 1 d . U P H 2
H12D H 0.320260 0.767926 0.370947 0.083 Uiso 0.367(10) 1 d R U P H 2
O15B O 0.1599(15) 1.1079(14) 0.1816(10) 0.112(8) Uani 0.367(10) 1 d . U P H 2
H15E H 0.183492 1.144884 0.185787 0.167 Uiso 0.367(10) 1 d R U P H 2
H15F H 0.194352 1.061385 0.192157 0.167 Uiso 0.367(10) 1 d R U P H 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O15 2.313(5) . ?
Eu1 O2 2.357(5) . ?
Eu1 O7 2.369(6) . ?
Eu1 O5W 2.420(5) . ?
Eu1 O5 2.431(4) . ?
Eu1 O13 2.441(5) 2_666 ?
Eu1 O4 2.462(4) 2_667 ?
Eu1 O3 2.533(4) 2_667 ?
Eu1 Eu2 4.4043(5) 2_666 ?
Eu2 O11 2.320(4) . ?
Eu2 O14 2.358(5) . ?
Eu2 O1 2.363(4) 2_666 ?
Eu2 O18 2.365(4) 2_676 ?
Eu2 O21 2.428(14) . ?
Eu2 O22 2.43(2) . ?
Eu2 O12B 2.43(3) . ?
Eu2 O5 2.494(5) 2_666 ?
Eu2 O6 2.517(6) 2_666 ?
Eu2 O22B 2.63(4) . ?
Eu3 O19 2.301(5) . ?
Eu3 O21B 2.34(3) . ?
Eu3 O12 2.344(5) . ?
Eu3 O17 2.382(5) 2_676 ?
Eu3 O11W 2.403(6) . ?
Eu3 O22B 2.45(5) . ?
Eu3 O12W 2.45(2) . ?
Eu3 O10 2.458(5) 2_675 ?
Eu3 O22 2.50(3) . ?
Eu3 O9 2.564(5) 2_675 ?
O1 C17 1.248(7) . ?
O2 C17 1.241(7) . ?
O3 C18 1.265(7) . ?
O4 C18 1.276(8) . ?
O5 C75 1.278(9) . ?
O6 C75 1.255(9) . ?
O7 C74 1.246(11) . ?
O8 C74 1.246(11) . ?
O9 C35 1.258(8) . ?
O10 C35 1.251(9) . ?
O11 C36 1.243(7) . ?
O12 C36 1.251(8) . ?
O13 C53 1.250(8) . ?
O14 C53 1.263(8) . ?
O15 C54 1.247(8) . ?
O16 C54 1.203(9) . ?
O17 C71 1.252(8) . ?
O18 C71 1.256(8) . ?
O19 C72 1.261(9) . ?
O20 C72 1.216(10) . ?
N1 C2 1.342(11) . ?
N1 C1 1.363(11) . ?
N2 C9 1.346(9) . ?
N2 C10 1.357(8) . ?
N2 C11 1.470(8) . ?
N3 C19 1.319(12) . ?
N3 C20 1.327(12) . ?
N4 C28 1.334(8) . ?
N4 C27 1.361(8) . ?
N4 C29 1.455(8) . ?
N5 C38 1.317(15) . ?
N5 C37 1.330(15) . ?
N6 C45 1.345(9) . ?
N6 C46 1.350(8) . ?
N6 C47 1.448(8) . ?
N7 C55 1.337(13) . ?
N7 C56 1.344(12) . ?
N8 C64 1.326(8) . ?
N8 C63 1.383(9) . ?
N8 C65 1.462(8) . ?
C1 C3 1.378(10) . ?
C1 H1A 0.9300 . ?
C2 C4 1.382(11) . ?
C2 H2 0.9300 . ?
C3 C5 1.381(10) . ?
C3 H3A 0.9300 . ?
C4 C5 1.405(10) . ?
C4 H4 0.9300 . ?
C5 C6 1.474(10) . ?
C6 C8 1.381(10) . ?
C6 C7 1.389(10) . ?
C7 C9 1.368(10) . ?
C7 H7 0.9300 . ?
C8 C10 1.370(10) . ?
C8 H8 0.9300 . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C11 C12 1.370(9) . ?
C11 C13 1.385(9) . ?
C12 C14 1.394(9) . ?
C12 H12 0.9300 . ?
C13 C15 1.381(9) . ?
C13 H13 0.9300 . ?
C14 C16 1.386(8) . ?
C14 C17 1.506(9) . ?
C15 C16 1.392(8) . ?
C15 C18 1.485(9) . ?
C16 H16 0.9300 . ?
C19 C21 1.367(11) . ?
C19 H19 0.9300 . ?
C20 C22 1.377(11) . ?
C20 H20 0.9300 . ?
C21 C23 1.384(11) . ?
C21 H21A 0.9300 . ?
C22 C23 1.383(10) . ?
C22 H22 0.9300 . ?
C23 C24 1.494(10) . ?
C24 C25 1.397(10) . ?
C24 C26 1.403(9) . ?
C25 C27 1.365(10) . ?
C25 H25 0.9300 . ?
C26 C28 1.355(9) . ?
C26 H26 0.9300 . ?
C27 H27 0.9300 . ?
C28 H28 0.9300 . ?
C29 C30 1.387(9) . ?
C29 C31 1.388(9) . ?
C30 C32 1.369(9) . ?
C30 H30 0.9300 . ?
C31 C33 1.391(9) . ?
C31 H31 0.9300 . ?
C32 C34 1.390(9) . ?
C32 C35 1.495(9) . ?
C33 C34 1.391(9) . ?
C33 C36 1.513(9) . ?
C34 H34 0.9300 . ?
C37 C39 1.380(12) . ?
C37 H37 0.9300 . ?
C38 C40 1.369(14) . ?
C38 H38 0.9300 . ?
C39 C41 1.391(12) . ?
C39 H39 0.9300 . ?
C40 C41 1.392(11) . ?
C40 H40 0.9300 . ?
C41 C42 1.459(10) . ?
C42 C43 1.392(10) . ?
C42 C44 1.403(11) . ?
C43 C45 1.349(10) . ?
C43 H43 0.9300 . ?
C44 C46 1.362(10) . ?
C44 H44 0.9300 . ?
C45 H45 0.9300 . ?
C46 H46 0.9300 . ?
C47 C48 1.379(9) . ?
C47 C49 1.388(9) . ?
C48 C50 1.395(9) . ?
C48 H48 0.9300 . ?
C49 C51 1.381(9) . ?
C49 H49 0.9300 . ?
C50 C52 1.402(8) . ?
C50 C53 1.482(9) . ?
C51 C52 1.391(9) . ?
C51 C54 1.521(9) . ?
C52 H52 0.9300 . ?
C55 C57 1.407(11) . ?
C55 H55 0.9300 . ?
C56 C58 1.405(11) . ?
C56 H56 0.9300 . ?
C57 C59 1.383(11) . ?
C57 H57 0.9300 . ?
C58 C59 1.366(11) . ?
C58 H58 0.9300 . ?
C59 C60 1.467(10) . ?
C60 C61 1.377(11) . ?
C60 C62 1.380(11) . ?
C61 C63 1.349(10) . ?
C61 H61 0.9300 . ?
C62 C64 1.372(10) . ?
C62 H62 0.9300 . ?
C63 H63 0.9300 . ?
C64 H64 0.9300 . ?
C65 C67 1.369(9) . ?
C65 C66 1.369(9) . ?
C66 C68 1.404(9) . ?
C66 H66 0.9300 . ?
C67 C69 1.381(9) . ?
C67 H67 0.9300 . ?
C68 C70 1.380(9) . ?
C68 C71 1.498(9) . ?
C69 C70 1.390(9) . ?
C69 C72 1.507(9) . ?
C70 H70 0.9300 . ?
C74 H74 0.9300 . ?
C75 H75A 0.9300 . ?
O1W H1C 0.8200 . ?
O1W H1D 0.8201 . ?
O3W H3C 0.8200 . ?
O3W H3D 0.8200 . ?
O4W H4C 0.8200 . ?
O4W H4D 0.8200 . ?
O5W H5 0.8499 . ?
O7W H7C 0.8201 . ?
O7W H7D 0.8199 . ?
O10W H10C 0.8200 . ?
O10W H10D 0.8200 . ?
O11W H11C 0.8125 . ?
O11W H11D 0.8137 . ?
O13W H13C 0.8201 . ?
O13W H13D 0.8500 . ?
O2W H2C 0.8299 . ?
O2W H2D 0.9005 . ?
O2B H2E 0.8200 . ?
O2B H2F 0.8200 . ?
O6W H6C 0.8201 . ?
O6W H6D 0.8200 . ?
O8W H8C 0.8199 . ?
O8W H8D 0.8201 . ?
O8B H8E 0.8201 . ?
O8B H8F 0.8199 . ?
O9W H9C 0.8202 . ?
O9W H9D 0.8200 . ?
O14W H14C 0.8200 . ?
O14W H14D 0.8200 . ?
O14B H14E 0.8199 . ?
O14B H14F 0.8201 . ?
O18W H18C 0.8200 . ?
O18W H18D 0.8198 . ?
O17W H17C 0.8274 . ?
O17W H17D 0.8201 . ?
O18B H18E 0.8201 . ?
O18B H18F 0.8200 . ?
O17B H17E 0.8201 . ?
O17B H17F 0.8201 . ?
O22 C73 1.268(19) . ?
O21 C73 1.220(13) . ?
C73 H73A 0.9300 . ?
O12W H12A 0.9300 . ?
O15W H15C 0.8200 . ?
O15W H15D 0.8201 . ?
O21B C73B 1.272(17) . ?
O22B C73B 1.234(19) . ?
C73B H73B 0.9300 . ?
O12B H12D 0.9300 . ?
O15B H15E 0.8198 . ?
O15B H15F 0.8201 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O15 Eu1 O2 152.74(18) . . ?
O15 Eu1 O7 80.13(19) . . ?
O2 Eu1 O7 110.43(19) . . ?
O15 Eu1 O5W 100.51(19) . . ?
O2 Eu1 O5W 84.44(18) . . ?
O7 Eu1 O5W 146.39(19) . . ?
O15 Eu1 O5 84.20(18) . . ?
O2 Eu1 O5 76.20(16) . . ?
O7 Eu1 O5 71.26(18) . . ?
O5W Eu1 O5 142.34(18) . . ?
O15 Eu1 O13 76.79(18) . 2_666 ?
O2 Eu1 O13 79.18(17) . 2_666 ?
O7 Eu1 O13 137.94(18) . 2_666 ?
O5W Eu1 O13 73.01(18) . 2_666 ?
O5 Eu1 O13 71.82(17) . 2_666 ?
O15 Eu1 O4 136.42(18) . 2_667 ?
O2 Eu1 O4 70.78(16) . 2_667 ?
O7 Eu1 O4 77.47(19) . 2_667 ?
O5W Eu1 O4 79.65(18) . 2_667 ?
O5 Eu1 O4 122.02(16) . 2_667 ?
O13 Eu1 O4 140.95(17) 2_666 2_667 ?
O15 Eu1 O3 86.05(17) . 2_667 ?
O2 Eu1 O3 120.58(15) . 2_667 ?
O7 Eu1 O3 75.35(18) . 2_667 ?
O5W Eu1 O3 71.19(18) . 2_667 ?
O5 Eu1 O3 146.34(17) . 2_667 ?
O13 Eu1 O3 136.39(17) 2_666 2_667 ?
O4 Eu1 O3 52.32(14) 2_667 2_667 ?
O15 Eu1 Eu2 92.75(14) . 2_666 ?
O2 Eu1 Eu2 61.51(11) . 2_666 ?
O7 Eu1 Eu2 97.90(14) . 2_666 ?
O5W Eu1 Eu2 115.55(13) . 2_666 ?
O5 Eu1 Eu2 26.97(12) . 2_666 ?
O13 Eu1 Eu2 49.33(12) 2_666 2_666 ?
O4 Eu1 Eu2 126.94(11) 2_667 2_666 ?
O3 Eu1 Eu2 173.25(12) 2_667 2_666 ?
C18 Eu1 Eu2 152.63(13) 2_667 2_666 ?
O11 Eu2 O14 149.83(18) . . ?
O11 Eu2 O1 79.80(18) . 2_666 ?
O14 Eu2 O1 110.29(18) . 2_666 ?
O11 Eu2 O18 98.43(18) . 2_676 ?
O14 Eu2 O18 85.83(17) . 2_676 ?
O1 Eu2 O18 151.05(17) 2_666 2_676 ?
O11 Eu2 O21 129.4(3) . . ?
O14 Eu2 O21 80.7(3) . . ?
O1 Eu2 O21 75.8(4) 2_666 . ?
O18 Eu2 O21 83.7(4) 2_676 . ?
O11 Eu2 O22 77.5(5) . . ?
O14 Eu2 O22 132.2(5) . . ?
O1 Eu2 O22 74.3(8) 2_666 . ?
O18 Eu2 O22 77.1(8) 2_676 . ?
O21 Eu2 O22 53.6(5) . . ?
O11 Eu2 O12B 139.8(6) . . ?
O14 Eu2 O12B 69.1(6) . . ?
O1 Eu2 O12B 72.6(6) 2_666 . ?
O18 Eu2 O12B 92.4(6) 2_676 . ?
O11 Eu2 O5 74.89(15) . 2_666 ?
O14 Eu2 O5 79.46(17) . 2_666 ?
O1 Eu2 O5 78.15(16) 2_666 2_666 ?
O18 Eu2 O5 129.67(18) 2_676 2_666 ?
O21 Eu2 O5 139.1(3) . 2_666 ?
O22 Eu2 O5 143.8(7) . 2_666 ?
O11 Eu2 O6 72.52(17) . 2_666 ?
O14 Eu2 O6 79.36(19) . 2_666 ?
O1 Eu2 O6 127.76(18) 2_666 2_666 ?
O18 Eu2 O6 77.67(19) 2_676 2_666 ?
O21 Eu2 O6 153.5(4) . 2_666 ?
O22 Eu2 O6 137.0(5) . 2_666 ?
O5 Eu2 O6 52.46(16) 2_666 2_666 ?
O11 Eu2 O22B 80.1(10) . . ?
O14 Eu2 O22B 129.6(10) . . ?
O1 Eu2 O22B 74.8(13) 2_666 . ?
O18 Eu2 O22B 76.5(13) 2_676 . ?
O12B Eu2 O22B 65.0(11) . . ?
O5 Eu2 O22B 145.8(13) 2_666 . ?
O6 Eu2 O22B 138.7(11) 2_666 . ?
O19 Eu3 O21B 80.0(8) . . ?
O19 Eu3 O12 153.55(18) . . ?
O21B Eu3 O12 96.2(7) . . ?
O19 Eu3 O17 77.89(19) . 2_676 ?
O12 Eu3 O17 83.94(18) . 2_676 ?
O19 Eu3 O11W 103.1(2) . . ?
O21B Eu3 O11W 158.7(5) . . ?
O12 Eu3 O11W 89.8(2) . . ?
O17 Eu3 O11W 73.77(18) 2_676 . ?
O19 Eu3 O22B 79.8(14) . . ?
O21B Eu3 O22B 55.3(6) . . ?
O12 Eu3 O22B 76.7(13) . . ?
O17 Eu3 O22B 73.7(8) 2_676 . ?
O11W Eu3 O22B 145.9(6) . . ?
O19 Eu3 O12W 78.9(5) . . ?
O12 Eu3 O12W 103.7(5) . . ?
O17 Eu3 O12W 139.0(3) 2_676 . ?
O11W Eu3 O12W 144.8(3) . . ?
O19 Eu3 O10 132.11(18) . 2_675 ?
O12 Eu3 O10 72.03(17) . 2_675 ?
O17 Eu3 O10 145.43(19) 2_676 2_675 ?
O11W Eu3 O10 81.5(2) . 2_675 ?
O12W Eu3 O10 72.5(4) . 2_675 ?
O19 Eu3 O22 83.6(7) . . ?
O12 Eu3 O22 72.3(6) . . ?
O17 Eu3 O22 70.8(5) 2_676 . ?
O11W Eu3 O22 141.6(4) . . ?
O12W Eu3 O22 73.5(5) . . ?
O10 Eu3 O22 122.0(7) 2_675 . ?
O19 Eu3 O9 83.82(18) . 2_675 ?
O12 Eu3 O9 122.26(17) . 2_675 ?
O17 Eu3 O9 137.46(17) 2_676 2_675 ?
O11W Eu3 O9 73.55(19) . 2_675 ?
O12W Eu3 O9 71.8(3) . 2_675 ?
O10 Eu3 O9 51.28(17) 2_675 2_675 ?
O22 Eu3 O9 144.7(4) . 2_675 ?
C17 O1 Eu2 140.4(4) . 2_666 ?
C17 O2 Eu1 145.0(4) . . ?
C18 O3 Eu1 92.2(4) . 2_667 ?
C18 O4 Eu1 95.3(4) . 2_667 ?
C75 O5 Eu1 130.2(5) . . ?
C75 O5 Eu2 93.0(5) . 2_666 ?
Eu1 O5 Eu2 126.8(2) . 2_666 ?
C75 O6 Eu2 92.5(5) . 2_666 ?
C74 O7 Eu1 129.1(6) . . ?
C35 O9 Eu3 90.9(4) . 2_675 ?
C35 O10 Eu3 96.1(4) . 2_675 ?
C36 O11 Eu2 130.9(5) . . ?
C36 O12 Eu3 140.7(5) . . ?
C53 O13 Eu1 142.1(5) . 2_666 ?
C53 O14 Eu2 120.8(4) . . ?
C54 O15 Eu1 134.9(5) . . ?
C71 O17 Eu3 143.8(5) . 2_676 ?
C71 O18 Eu2 128.6(4) . 2_676 ?
C72 O19 Eu3 134.6(5) . . ?
C2 N1 C1 116.2(7) . . ?
C9 N2 C10 120.7(6) . . ?
C9 N2 C11 119.1(5) . . ?
C10 N2 C11 120.2(5) . . ?
C19 N3 C20 115.3(8) . . ?
C28 N4 C27 119.3(6) . . ?
C28 N4 C29 120.5(5) . . ?
C27 N4 C29 120.1(5) . . ?
C38 N5 C37 116.4(10) . . ?
C45 N6 C46 120.0(6) . . ?
C45 N6 C47 121.2(5) . . ?
C46 N6 C47 118.9(6) . . ?
C55 N7 C56 117.9(8) . . ?
C64 N8 C63 119.4(6) . . ?
C64 N8 C65 121.0(6) . . ?
C63 N8 C65 119.6(6) . . ?
N1 C1 C3 124.0(8) . . ?
N1 C1 H1A 118.0 . . ?
C3 C1 H1A 118.0 . . ?
N1 C2 C4 123.6(8) . . ?
N1 C2 H2 118.2 . . ?
C4 C2 H2 118.2 . . ?
C1 C3 C5 119.1(7) . . ?
C1 C3 H3A 120.4 . . ?
C5 C3 H3A 120.4 . . ?
C2 C4 C5 119.1(8) . . ?
C2 C4 H4 120.4 . . ?
C5 C4 H4 120.4 . . ?
C3 C5 C4 117.9(7) . . ?
C3 C5 C6 121.5(7) . . ?
C4 C5 C6 120.5(7) . . ?
C8 C6 C7 117.6(6) . . ?
C8 C6 C5 122.3(6) . . ?
C7 C6 C5 120.0(6) . . ?
C9 C7 C6 120.8(7) . . ?
C9 C7 H7 119.6 . . ?
C6 C7 H7 119.6 . . ?
C10 C8 C6 120.7(7) . . ?
C10 C8 H8 119.7 . . ?
C6 C8 H8 119.7 . . ?
N2 C9 C7 120.1(7) . . ?
N2 C9 H9 120.0 . . ?
C7 C9 H9 120.0 . . ?
N2 C10 C8 120.1(6) . . ?
N2 C10 H10 120.0 . . ?
C8 C10 H10 120.0 . . ?
C12 C11 C13 121.1(6) . . ?
C12 C11 N2 119.3(6) . . ?
C13 C11 N2 119.5(5) . . ?
C11 C12 C14 120.0(6) . . ?
C11 C12 H12 120.0 . . ?
C14 C12 H12 120.0 . . ?
C15 C13 C11 119.3(6) . . ?
C15 C13 H13 120.3 . . ?
C11 C13 H13 120.3 . . ?
C16 C14 C12 119.0(6) . . ?
C16 C14 C17 120.5(6) . . ?
C12 C14 C17 120.4(6) . . ?
C13 C15 C16 119.9(6) . . ?
C13 C15 C18 120.2(6) . . ?
C16 C15 C18 119.9(6) . . ?
C14 C16 C15 120.5(6) . . ?
C14 C16 H16 119.7 . . ?
C15 C16 H16 119.7 . . ?
O2 C17 O1 125.9(6) . . ?
O2 C17 C14 116.6(6) . . ?
O1 C17 C14 117.4(6) . . ?
O3 C18 O4 120.2(6) . . ?
O3 C18 C15 121.9(6) . . ?
O4 C18 C15 117.9(6) . . ?
O3 C18 Eu1 61.7(3) . 2_667 ?
O4 C18 Eu1 58.5(3) . 2_667 ?
C15 C18 Eu1 176.1(5) . 2_667 ?
N3 C19 C21 125.4(9) . . ?
N3 C19 H19 117.3 . . ?
C21 C19 H19 117.3 . . ?
N3 C20 C22 124.7(9) . . ?
N3 C20 H20 117.6 . . ?
C22 C20 H20 117.6 . . ?
C19 C21 C23 118.4(9) . . ?
C19 C21 H21A 120.8 . . ?
C23 C21 H21A 120.8 . . ?
C20 C22 C23 118.4(8) . . ?
C20 C22 H22 120.8 . . ?
C23 C22 H22 120.8 . . ?
C22 C23 C21 117.6(7) . . ?
C22 C23 C24 120.7(7) . . ?
C21 C23 C24 121.6(7) . . ?
C25 C24 C26 116.4(6) . . ?
C25 C24 C23 121.9(6) . . ?
C26 C24 C23 121.7(6) . . ?
C27 C25 C24 120.7(7) . . ?
C27 C25 H25 119.7 . . ?
C24 C25 H25 119.7 . . ?
C28 C26 C24 120.6(6) . . ?
C28 C26 H26 119.7 . . ?
C24 C26 H26 119.7 . . ?
N4 C27 C25 121.0(6) . . ?
N4 C27 H27 119.5 . . ?
C25 C27 H27 119.5 . . ?
N4 C28 C26 122.0(7) . . ?
N4 C28 H28 119.0 . . ?
C26 C28 H28 119.0 . . ?
C30 C29 C31 121.3(6) . . ?
C30 C29 N4 119.6(6) . . ?
C31 C29 N4 119.2(5) . . ?
C32 C30 C29 119.3(6) . . ?
C32 C30 H30 120.4 . . ?
C29 C30 H30 120.4 . . ?
C29 C31 C33 119.2(6) . . ?
C29 C31 H31 120.4 . . ?
C33 C31 H31 120.4 . . ?
C30 C32 C34 120.4(6) . . ?
C30 C32 C35 122.4(6) . . ?
C34 C32 C35 117.2(6) . . ?
C34 C33 C31 119.3(6) . . ?
C34 C33 C36 119.8(6) . . ?
C31 C33 C36 120.9(6) . . ?
C32 C34 C33 120.4(6) . . ?
C32 C34 H34 119.8 . . ?
C33 C34 H34 119.8 . . ?
O10 C35 O9 120.3(6) . . ?
O10 C35 C32 118.7(6) . . ?
O9 C35 C32 121.0(7) . . ?
O10 C35 Eu3 58.2(4) . 2_675 ?
O9 C35 Eu3 63.1(4) . 2_675 ?
C32 C35 Eu3 170.3(5) . 2_675 ?
O11 C36 O12 125.4(7) . . ?
O11 C36 C33 119.0(6) . . ?
O12 C36 C33 115.5(6) . . ?
N5 C37 C39 123.2(12) . . ?
N5 C37 H37 118.4 . . ?
C39 C37 H37 118.4 . . ?
N5 C38 C40 125.9(11) . . ?
N5 C38 H38 117.0 . . ?
C40 C38 H38 117.0 . . ?
C37 C39 C41 119.2(10) . . ?
C37 C39 H39 120.4 . . ?
C41 C39 H39 120.4 . . ?
C38 C40 C41 117.5(10) . . ?
C38 C40 H40 121.2 . . ?
C41 C40 H40 121.2 . . ?
C39 C41 C40 117.7(8) . . ?
C39 C41 C42 120.8(8) . . ?
C40 C41 C42 121.5(8) . . ?
C43 C42 C44 115.6(7) . . ?
C43 C42 C41 122.4(7) . . ?
C44 C42 C41 121.9(7) . . ?
C45 C43 C42 121.5(7) . . ?
C45 C43 H43 119.3 . . ?
C42 C43 H43 119.3 . . ?
C46 C44 C42 121.5(7) . . ?
C46 C44 H44 119.2 . . ?
C42 C44 H44 119.2 . . ?
N6 C45 C43 121.2(7) . . ?
N6 C45 H45 119.4 . . ?
C43 C45 H45 119.4 . . ?
N6 C46 C44 120.1(7) . . ?
N6 C46 H46 119.9 . . ?
C44 C46 H46 119.9 . . ?
C48 C47 C49 121.4(6) . . ?
C48 C47 N6 119.2(6) . . ?
C49 C47 N6 119.4(5) . . ?
C47 C48 C50 119.9(6) . . ?
C47 C48 H48 120.1 . . ?
C50 C48 H48 120.1 . . ?
C51 C49 C47 119.5(6) . . ?
C51 C49 H49 120.2 . . ?
C47 C49 H49 120.2 . . ?
C48 C50 C52 118.6(6) . . ?
C48 C50 C53 119.8(6) . . ?
C52 C50 C53 121.7(6) . . ?
C49 C51 C52 119.6(6) . . ?
C49 C51 C54 120.5(6) . . ?
C52 C51 C54 119.8(6) . . ?
C51 C52 C50 121.0(6) . . ?
C51 C52 H52 119.5 . . ?
C50 C52 H52 119.5 . . ?
O13 C53 O14 124.8(6) . . ?
O13 C53 C50 118.5(6) . . ?
O14 C53 C50 116.7(6) . . ?
O13 C53 Eu2 86.9(4) . . ?
O14 C53 Eu2 39.3(3) . . ?
C50 C53 Eu2 152.6(5) . . ?
O16 C54 O15 126.1(7) . . ?
O16 C54 C51 117.4(7) . . ?
O15 C54 C51 116.4(6) . . ?
N7 C55 C57 122.4(9) . . ?
N7 C55 H55 118.8 . . ?
C57 C55 H55 118.8 . . ?
N7 C56 C58 122.4(9) . . ?
N7 C56 H56 118.8 . . ?
C58 C56 H56 118.8 . . ?
C59 C57 C55 119.3(9) . . ?
C59 C57 H57 120.4 . . ?
C55 C57 H57 120.4 . . ?
C59 C58 C56 119.5(9) . . ?
C59 C58 H58 120.2 . . ?
C56 C58 H58 120.2 . . ?
C58 C59 C57 118.5(7) . . ?
C58 C59 C60 121.5(8) . . ?
C57 C59 C60 119.9(7) . . ?
C61 C60 C62 116.5(7) . . ?
C61 C60 C59 122.4(7) . . ?
C62 C60 C59 121.1(7) . . ?
C63 C61 C60 122.2(8) . . ?
C63 C61 H61 118.9 . . ?
C60 C61 H61 118.9 . . ?
C64 C62 C60 121.0(7) . . ?
C64 C62 H62 119.5 . . ?
C60 C62 H62 119.5 . . ?
C61 C63 N8 119.7(7) . . ?
C61 C63 H63 120.1 . . ?
N8 C63 H63 120.1 . . ?
N8 C64 C62 121.0(7) . . ?
N8 C64 H64 119.5 . . ?
C62 C64 H64 119.5 . . ?
C67 C65 C66 122.2(6) . . ?
C67 C65 N8 118.7(6) . . ?
C66 C65 N8 119.0(6) . . ?
C65 C66 C68 118.9(6) . . ?
C65 C66 H66 120.6 . . ?
C68 C66 H66 120.6 . . ?
C65 C67 C69 119.6(6) . . ?
C65 C67 H67 120.2 . . ?
C69 C67 H67 120.2 . . ?
C70 C68 C66 118.9(6) . . ?
C70 C68 C71 121.9(6) . . ?
C66 C68 C71 119.2(6) . . ?
C67 C69 C70 119.0(6) . . ?
C67 C69 C72 120.4(6) . . ?
C70 C69 C72 120.5(6) . . ?
C68 C70 C69 121.3(6) . . ?
C68 C70 H70 119.3 . . ?
C69 C70 H70 119.3 . . ?
O17 C71 O18 124.6(6) . . ?
O17 C71 C68 118.1(6) . . ?
O18 C71 C68 117.2(6) . . ?
O20 C72 O19 123.9(7) . . ?
O20 C72 C69 118.4(7) . . ?
O19 C72 C69 117.6(7) . . ?
O7 C74 O8 126.9(9) . . ?
O7 C74 H74 116.6 . . ?
O8 C74 H74 116.6 . . ?
O6 C75 O5 121.9(8) . . ?
O6 C75 Eu2 61.5(5) . 2_666 ?
O5 C75 Eu2 60.5(4) . 2_666 ?
O6 C75 H75A 119.0 . . ?
O5 C75 H75A 119.0 . . ?
Eu2 C75 H75A 177.2 2_666 . ?
H1C O1W H1D 115.6 . . ?
H3C O3W H3D 115.8 . . ?
H4C O4W H4D 116.0 . . ?
Eu1 O5W H5 109.1 . . ?
H7C O7W H7D 115.9 . . ?
H10C O10W H10D 115.8 . . ?
Eu3 O11W H11C 114.5 . . ?
Eu3 O11W H11D 116.6 . . ?
H11C O11W H11D 118.6 . . ?
H13C O13W H13D 108.3 . . ?
H2C O2W H2D 112.2 . . ?
H2E O2B H2F 116.0 . . ?
H6C O6W H6D 115.7 . . ?
H8C O8W H8D 116.1 . . ?
H8E O8B H8F 115.7 . . ?
H9C O9W H9D 108.5 . . ?
H14C O14W H14D 115.9 . . ?
H14E O14B H14F 115.9 . . ?
H18C O18W H18D 115.9 . . ?
H17C O17W H17D 115.6 . . ?
H18E O18B H18F 115.9 . . ?
H17E O17B H17F 115.9 . . ?
C73 O22 Eu2 90.9(13) . . ?
C73 O22 Eu3 131.7(18) . . ?
Eu2 O22 Eu3 130.9(7) . . ?
C73 O21 Eu2 92.2(9) . . ?
O21 C73 O22 123.2(15) . . ?
O21 C73 Eu2 61.6(8) . . ?
O22 C73 Eu2 61.8(11) . . ?
O21 C73 H73A 118.4 . . ?
O22 C73 H73A 118.4 . . ?
Eu2 C73 H73A 176.2 . . ?
Eu3 O12W H12A 119.7 . . ?
H15C O15W H15D 115.9 . . ?
C73B O21B Eu3 91.8(16) . . ?
C73B O22B Eu3 88(3) . . ?
C73B O22B Eu2 142(4) . . ?
Eu3 O22B Eu2 124.0(13) . . ?
O22B C73B O21B 125(3) . . ?
O22B C73B Eu3 65(3) . . ?
O21B C73B Eu3 60.1(15) . . ?
O22B C73B H73B 117.5 . . ?
O21B C73B H73B 117.5 . . ?
Eu3 C73B H73B 177.4 . . ?
Eu2 O12B H12D 119.7 . . ?
H15E O15B H15F 115.9 . . ?

_refine_diff_density_max         1.524
_refine_diff_density_min         -1.087
_refine_diff_density_rms         0.146


# start Validation Reply Form
_vrf_PLAT420_x                   
;
PROBLEM: D-H Bond Without Acceptor  O9W      --H9C      .     Please Check 
RESPONSE: This is due to that some lattice water molecules are disorder 
  which made it difficult to locate and refine accurately the position of 
  H atoms attached to O of lattice water.
  mole...
;
_vrf_PLAT910_x                   
;
PROBLEM: Missing # of FCF Reflection(s) Below Theta(Min).         44 Note  
RESPONSE:  This is probably due to that the experimental beamstop 
  Theta(min) limit  was set too high.
;
# end Validation Reply Form
