# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_tian36_a
_database_code_depnum_ccdc_archive 'CCDC 2156179'
loop_
_audit_author_name
_audit_author_address
'Marie Cordier'
;Institut des Sciences Chimiques de Rennes
France
;
_audit_update_record             
;
2022-03-03 deposited with the CCDC.	2022-04-18 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C34 H26 N P2, F6 P'
_chemical_formula_sum            'C34 H26 F6 N P3'
_chemical_formula_weight         655.47

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_H-M_alt        'P 1'
_space_group_name_Hall           'P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'

_cell_length_a                   8.2282(7)
_cell_length_b                   9.5081(8)
_cell_length_c                   10.7126(8)
_cell_angle_alpha                101.997(2)
_cell_angle_beta                 91.033(2)
_cell_angle_gamma                111.831(2)
_cell_volume                     756.79(11)
_cell_formula_units_Z            1
_cell_measurement_temperature    150.0(1)
_cell_measurement_reflns_used    7940
_cell_measurement_theta_min      2.3718
_cell_measurement_theta_max      26.7171

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.438
_exptl_crystal_F_000             336
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.180
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    0.260
_shelx_estimated_absorpt_T_min   0.955
_shelx_estimated_absorpt_T_max   0.974
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6382
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Kappa APEX II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            19925
_diffrn_reflns_av_unetI/netI     0.0513
_diffrn_reflns_av_R_equivalents  0.0498
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         1.954
_diffrn_reflns_theta_max         26.984
_diffrn_reflns_theta_full        25.240
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             6488
_reflns_number_gt                5891
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         1.000
_reflns_Friedel_fraction_max     0.991
_reflns_Friedel_fraction_full    0.999

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    SHELXT(Sheldrick,2014)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    'PLATON (Spek, 2009)'
_computing_publication_material  ?
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0420P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   -0.02(8)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         6488
_refine_ls_number_parameters     398
_refine_ls_number_restraints     3
_refine_ls_R_factor_all          0.0388
_refine_ls_R_factor_gt           0.0312
_refine_ls_wR_factor_ref         0.0774
_refine_ls_wR_factor_gt          0.0739
_refine_ls_goodness_of_fit_ref   1.008
_refine_ls_restrained_S_all      1.007
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.69874(8) 0.49686(8) 0.27357(7) 0.01853(16) Uani 1 1 d . . . . .
P2 P 0.67813(8) 0.47416(8) 0.51823(7) 0.01789(16) Uani 1 1 d . . . . .
N1 N 0.7871(3) 0.4676(3) 0.3948(2) 0.0214(5) Uani 1 1 d . . . . .
C1 C 0.5039(3) 0.5217(3) 0.3313(3) 0.0185(6) Uani 1 1 d . . . . .
C2 C 0.4947(3) 0.5129(3) 0.4598(3) 0.0174(6) Uani 1 1 d . . . . .
C3 C 0.3582(3) 0.5364(3) 0.5253(3) 0.0227(6) Uani 1 1 d . . . . .
H3 H 0.3516 0.5319 0.6129 0.027 Uiso 1 1 calc R U . . .
C4 C 0.2331(4) 0.5663(4) 0.4596(3) 0.0260(6) Uani 1 1 d . . . . .
H4 H 0.1402 0.5836 0.5030 0.031 Uiso 1 1 calc R U . . .
C5 C 0.2412(4) 0.5715(4) 0.3308(3) 0.0291(7) Uani 1 1 d . . . . .
H5 H 0.1520 0.5895 0.2869 0.035 Uiso 1 1 calc R U . . .
C6 C 0.3772(4) 0.5507(4) 0.2660(3) 0.0245(6) Uani 1 1 d . . . . .
H6 H 0.3838 0.5562 0.1786 0.029 Uiso 1 1 calc R U . . .
C7 C 0.8218(4) 0.6601(4) 0.2067(3) 0.0228(6) Uani 1 1 d . . . . .
C8 C 0.8150(4) 0.6016(4) 0.0805(3) 0.0290(7) Uani 1 1 d . . . . .
H8 H 0.8647 0.6664 0.0233 0.035 Uiso 1 1 calc R U . . .
C9 C 0.7270(4) 0.4326(4) 0.0360(3) 0.0289(7) Uani 1 1 d . . . . .
H9 H 0.7199 0.3815 -0.0513 0.035 Uiso 1 1 calc R U . . .
C10 C 0.6568(4) 0.3536(4) 0.1248(3) 0.0221(6) Uani 1 1 d . . . . .
C11 C 0.8973(4) 0.8237(4) 0.2778(3) 0.0264(7) Uani 1 1 d . . . . .
C12 C 0.9739(4) 0.8649(4) 0.4044(3) 0.0341(8) Uani 1 1 d . . . . .
H12 H 0.9731 0.7862 0.4467 0.041 Uiso 1 1 calc R U . . .
C13 C 1.0505(5) 1.0192(5) 0.4680(4) 0.0488(10) Uani 1 1 d . . . . .
H13 H 1.1040 1.0468 0.5535 0.059 Uiso 1 1 calc R U . . .
C14 C 1.0498(5) 1.1339(4) 0.4077(5) 0.0538(11) Uani 1 1 d . . . . .
H14 H 1.1014 1.2401 0.4524 0.065 Uiso 1 1 calc R U . . .
C15 C 0.9744(5) 1.0951(5) 0.2828(5) 0.0515(11) Uani 1 1 d . . . . .
H15 H 0.9756 1.1745 0.2413 0.062 Uiso 1 1 calc R U . . .
C16 C 0.8979(4) 0.9415(4) 0.2188(4) 0.0372(8) Uani 1 1 d . . . . .
H16 H 0.8446 0.9151 0.1333 0.045 Uiso 1 1 calc R U . . .
C17 C 0.5689(4) 0.1843(4) 0.1097(3) 0.0242(7) Uani 1 1 d . . . . .
C18 C 0.4387(4) 0.1208(4) 0.1855(3) 0.0334(7) Uani 1 1 d . . . . .
H18 H 0.4064 0.1881 0.2496 0.040 Uiso 1 1 calc R U . . .
C19 C 0.3554(5) -0.0383(4) 0.1693(4) 0.0409(9) Uani 1 1 d . . . . .
H19 H 0.2658 -0.0801 0.2214 0.049 Uiso 1 1 calc R U . . .
C20 C 0.4030(5) -0.1361(4) 0.0772(3) 0.0390(9) Uani 1 1 d . . . . .
H20 H 0.3470 -0.2457 0.0666 0.047 Uiso 1 1 calc R U . . .
C21 C 0.5308(5) -0.0762(4) 0.0006(4) 0.0387(8) Uani 1 1 d . . . . .
H21 H 0.5611 -0.1446 -0.0639 0.046 Uiso 1 1 calc R U . . .
C22 C 0.6159(4) 0.0834(4) 0.0166(3) 0.0313(7) Uani 1 1 d . . . . .
H22 H 0.7059 0.1243 -0.0355 0.038 Uiso 1 1 calc R U . . .
C23 C 0.8004(4) 0.6288(3) 0.6526(3) 0.0203(6) Uani 1 1 d . . . . .
C24 C 0.9332(4) 0.6124(4) 0.7228(3) 0.0255(6) Uani 1 1 d . . . . .
H24 H 0.9479 0.5160 0.7068 0.031 Uiso 1 1 calc R U . . .
C25 C 1.0445(4) 0.7383(4) 0.8164(3) 0.0312(7) Uani 1 1 d . . . . .
H25 H 1.1368 0.7283 0.8638 0.037 Uiso 1 1 calc R U . . .
C26 C 1.0216(4) 0.8781(4) 0.8410(3) 0.0328(7) Uani 1 1 d . . . . .
H26 H 1.0977 0.9636 0.9054 0.039 Uiso 1 1 calc R U . . .
C27 C 0.8885(4) 0.8935(4) 0.7722(3) 0.0343(8) Uani 1 1 d . . . . .
H27 H 0.8724 0.9894 0.7898 0.041 Uiso 1 1 calc R U . . .
C28 C 0.7786(4) 0.7699(4) 0.6778(3) 0.0296(7) Uani 1 1 d . . . . .
H28 H 0.6877 0.7812 0.6299 0.036 Uiso 1 1 calc R U . . .
C29 C 0.6104(4) 0.2937(3) 0.5675(3) 0.0213(6) Uani 1 1 d . . . . .
C30 C 0.6332(5) 0.1668(4) 0.4902(3) 0.0341(8) Uani 1 1 d . . . . .
H30 H 0.6883 0.1772 0.4136 0.041 Uiso 1 1 calc R U . . .
C31 C 0.5755(6) 0.0259(4) 0.5249(4) 0.0464(10) Uani 1 1 d . . . . .
H31 H 0.5903 -0.0611 0.4721 0.056 Uiso 1 1 calc R U . . .
C32 C 0.4959(5) 0.0110(4) 0.6367(4) 0.0415(9) Uani 1 1 d . . . . .
H32 H 0.4564 -0.0864 0.6602 0.050 Uiso 1 1 calc R U . . .
C33 C 0.4734(4) 0.1358(4) 0.7142(4) 0.0330(8) Uani 1 1 d . . . . .
H33 H 0.4189 0.1247 0.7909 0.040 Uiso 1 1 calc R U . . .
C34 C 0.5306(4) 0.2782(4) 0.6798(3) 0.0252(6) Uani 1 1 d . . . . .
H34 H 0.5152 0.3647 0.7329 0.030 Uiso 1 1 calc R U . . .
P3 P 0.14904(10) 0.36351(9) 0.89286(8) 0.02499(18) Uani 1 1 d . . . . .
F1 F 0.1229(2) 0.4944(2) 1.00068(19) 0.0394(5) Uani 1 1 d . . . . .
F2 F 0.2154(3) 0.4837(3) 0.8031(2) 0.0509(6) Uani 1 1 d . . . . .
F3 F 0.3471(3) 0.4177(3) 0.9523(2) 0.0537(6) Uani 1 1 d . . . . .
F4 F 0.0817(3) 0.2445(3) 0.9830(2) 0.0561(6) Uani 1 1 d . . . . .
F5 F -0.0487(2) 0.3103(3) 0.8315(2) 0.0449(5) Uani 1 1 d . . . . .
F6 F 0.1741(3) 0.2322(3) 0.7853(2) 0.0513(6) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 N1 1.600(2) . ?
P1 C10 1.801(3) . ?
P1 C1 1.807(3) . ?
P1 C7 1.808(3) . ?
P1 P2 2.6775(10) . ?
P2 N1 1.614(2) . ?
P2 C29 1.791(3) . ?
P2 C23 1.792(3) . ?
P2 C2 1.811(3) . ?
C1 C6 1.386(4) . ?
C1 C2 1.398(4) . ?
C2 C3 1.398(4) . ?
C3 C4 1.382(4) . ?
C3 H3 0.9500 . ?
C4 C5 1.393(5) . ?
C4 H4 0.9500 . ?
C5 C6 1.382(4) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.342(4) . ?
C7 C11 1.469(4) . ?
C8 C9 1.462(4) . ?
C8 H8 0.9500 . ?
C9 C10 1.341(4) . ?
C9 H9 0.9500 . ?
C10 C17 1.470(4) . ?
C11 C16 1.394(5) . ?
C11 C12 1.398(5) . ?
C12 C13 1.377(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.379(6) . ?
C13 H13 0.9500 . ?
C14 C15 1.380(6) . ?
C14 H14 0.9500 . ?
C15 C16 1.373(5) . ?
C15 H15 0.9500 . ?
C16 H16 0.9500 . ?
C17 C18 1.387(4) . ?
C17 C22 1.399(4) . ?
C18 C19 1.380(5) . ?
C18 H18 0.9500 . ?
C19 C20 1.376(5) . ?
C19 H19 0.9500 . ?
C20 C21 1.373(5) . ?
C20 H20 0.9500 . ?
C21 C22 1.386(5) . ?
C21 H21 0.9500 . ?
C22 H22 0.9500 . ?
C23 C24 1.389(4) . ?
C23 C28 1.392(4) . ?
C24 C25 1.389(4) . ?
C24 H24 0.9500 . ?
C25 C26 1.384(5) . ?
C25 H25 0.9500 . ?
C26 C27 1.378(5) . ?
C26 H26 0.9500 . ?
C27 C28 1.380(5) . ?
C27 H27 0.9500 . ?
C28 H28 0.9500 . ?
C29 C34 1.389(4) . ?
C29 C30 1.391(4) . ?
C30 C31 1.378(5) . ?
C30 H30 0.9500 . ?
C31 C32 1.382(6) . ?
C31 H31 0.9500 . ?
C32 C33 1.375(5) . ?
C32 H32 0.9500 . ?
C33 C34 1.389(4) . ?
C33 H33 0.9500 . ?
C34 H34 0.9500 . ?
P3 F4 1.590(2) . ?
P3 F3 1.590(2) . ?
P3 F6 1.591(2) . ?
P3 F1 1.594(2) . ?
P3 F2 1.594(2) . ?
P3 F5 1.595(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 P1 C10 116.91(13) . . ?
N1 P1 C1 103.10(12) . . ?
C10 P1 C1 114.03(13) . . ?
N1 P1 C7 119.33(13) . . ?
C10 P1 C7 94.84(14) . . ?
C1 P1 C7 108.95(13) . . ?
N1 P1 P2 33.75(8) . . ?
C10 P1 P2 132.46(10) . . ?
C1 P1 P2 69.35(9) . . ?
C7 P1 P2 130.35(11) . . ?
N1 P2 C29 110.60(13) . . ?
N1 P2 C23 113.14(13) . . ?
C29 P2 C23 108.50(14) . . ?
N1 P2 C2 102.64(12) . . ?
C29 P2 C2 112.91(12) . . ?
C23 P2 C2 109.03(13) . . ?
N1 P2 P1 33.42(8) . . ?
C29 P2 P1 124.01(10) . . ?
C23 P2 P1 123.93(10) . . ?
C2 P2 P1 69.22(9) . . ?
P1 N1 P2 112.83(13) . . ?
C6 C1 C2 121.0(3) . . ?
C6 C1 P1 128.2(2) . . ?
C2 C1 P1 110.72(19) . . ?
C3 C2 C1 120.1(3) . . ?
C3 C2 P2 129.2(2) . . ?
C1 C2 P2 110.7(2) . . ?
C4 C3 C2 118.4(3) . . ?
C4 C3 H3 120.8 . . ?
C2 C3 H3 120.8 . . ?
C3 C4 C5 121.1(3) . . ?
C3 C4 H4 119.5 . . ?
C5 C4 H4 119.5 . . ?
C6 C5 C4 120.8(3) . . ?
C6 C5 H5 119.6 . . ?
C4 C5 H5 119.6 . . ?
C5 C6 C1 118.6(3) . . ?
C5 C6 H6 120.7 . . ?
C1 C6 H6 120.7 . . ?
C8 C7 C11 128.6(3) . . ?
C8 C7 P1 106.0(2) . . ?
C11 C7 P1 125.3(2) . . ?
C7 C8 C9 116.4(3) . . ?
C7 C8 H8 121.8 . . ?
C9 C8 H8 121.8 . . ?
C10 C9 C8 116.5(3) . . ?
C10 C9 H9 121.7 . . ?
C8 C9 H9 121.7 . . ?
C9 C10 C17 128.6(3) . . ?
C9 C10 P1 106.2(2) . . ?
C17 C10 P1 125.3(2) . . ?
C16 C11 C12 118.7(3) . . ?
C16 C11 C7 120.4(3) . . ?
C12 C11 C7 120.9(3) . . ?
C13 C12 C11 120.2(4) . . ?
C13 C12 H12 119.9 . . ?
C11 C12 H12 119.9 . . ?
C12 C13 C14 120.2(4) . . ?
C12 C13 H13 119.9 . . ?
C14 C13 H13 119.9 . . ?
C13 C14 C15 120.4(4) . . ?
C13 C14 H14 119.8 . . ?
C15 C14 H14 119.8 . . ?
C16 C15 C14 119.8(4) . . ?
C16 C15 H15 120.1 . . ?
C14 C15 H15 120.1 . . ?
C15 C16 C11 120.8(4) . . ?
C15 C16 H16 119.6 . . ?
C11 C16 H16 119.6 . . ?
C18 C17 C22 118.6(3) . . ?
C18 C17 C10 121.6(3) . . ?
C22 C17 C10 119.8(3) . . ?
C19 C18 C17 121.2(3) . . ?
C19 C18 H18 119.4 . . ?
C17 C18 H18 119.4 . . ?
C20 C19 C18 119.6(3) . . ?
C20 C19 H19 120.2 . . ?
C18 C19 H19 120.2 . . ?
C21 C20 C19 120.4(3) . . ?
C21 C20 H20 119.8 . . ?
C19 C20 H20 119.8 . . ?
C20 C21 C22 120.5(3) . . ?
C20 C21 H21 119.8 . . ?
C22 C21 H21 119.8 . . ?
C21 C22 C17 119.8(3) . . ?
C21 C22 H22 120.1 . . ?
C17 C22 H22 120.1 . . ?
C24 C23 C28 119.8(3) . . ?
C24 C23 P2 118.5(2) . . ?
C28 C23 P2 121.2(2) . . ?
C23 C24 C25 119.5(3) . . ?
C23 C24 H24 120.3 . . ?
C25 C24 H24 120.3 . . ?
C26 C25 C24 120.3(3) . . ?
C26 C25 H25 119.9 . . ?
C24 C25 H25 119.9 . . ?
C27 C26 C25 120.2(3) . . ?
C27 C26 H26 119.9 . . ?
C25 C26 H26 119.9 . . ?
C26 C27 C28 120.1(3) . . ?
C26 C27 H27 120.0 . . ?
C28 C27 H27 120.0 . . ?
C27 C28 C23 120.2(3) . . ?
C27 C28 H28 119.9 . . ?
C23 C28 H28 119.9 . . ?
C34 C29 C30 119.9(3) . . ?
C34 C29 P2 120.7(2) . . ?
C30 C29 P2 119.4(2) . . ?
C31 C30 C29 119.8(3) . . ?
C31 C30 H30 120.1 . . ?
C29 C30 H30 120.1 . . ?
C30 C31 C32 120.1(3) . . ?
C30 C31 H31 120.0 . . ?
C32 C31 H31 120.0 . . ?
C33 C32 C31 120.6(3) . . ?
C33 C32 H32 119.7 . . ?
C31 C32 H32 119.7 . . ?
C32 C33 C34 119.8(3) . . ?
C32 C33 H33 120.1 . . ?
C34 C33 H33 120.1 . . ?
C33 C34 C29 119.8(3) . . ?
C33 C34 H34 120.1 . . ?
C29 C34 H34 120.1 . . ?
F4 P3 F3 91.22(14) . . ?
F4 P3 F6 90.45(14) . . ?
F3 P3 F6 90.09(12) . . ?
F4 P3 F1 89.33(13) . . ?
F3 P3 F1 90.15(11) . . ?
F6 P3 F1 179.69(13) . . ?
F4 P3 F2 179.45(14) . . ?
F3 P3 F2 89.04(13) . . ?
F6 P3 F2 90.03(13) . . ?
F1 P3 F2 90.18(12) . . ?
F4 P3 F5 89.56(13) . . ?
F3 P3 F5 179.18(15) . . ?
F6 P3 F5 89.67(12) . . ?
F1 P3 F5 90.10(11) . . ?
F2 P3 F5 90.18(13) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C10 P1 N1 P2 -127.09(15) . . . . ?
C1 P1 N1 P2 -1.16(17) . . . . ?
C7 P1 N1 P2 119.72(16) . . . . ?
C29 P2 N1 P1 121.01(15) . . . . ?
C23 P2 N1 P1 -117.03(16) . . . . ?
C2 P2 N1 P1 0.30(18) . . . . ?
N1 P1 C1 C6 179.9(3) . . . . ?
C10 P1 C1 C6 -52.4(3) . . . . ?
C7 P1 C1 C6 52.2(3) . . . . ?
P2 P1 C1 C6 179.2(3) . . . . ?
N1 P1 C1 C2 1.8(2) . . . . ?
C10 P1 C1 C2 129.6(2) . . . . ?
C7 P1 C1 C2 -125.9(2) . . . . ?
P2 P1 C1 C2 1.15(16) . . . . ?
C6 C1 C2 C3 -1.2(4) . . . . ?
P1 C1 C2 C3 177.0(2) . . . . ?
C6 C1 C2 P2 -179.9(2) . . . . ?
P1 C1 C2 P2 -1.7(2) . . . . ?
N1 P2 C2 C3 -177.6(3) . . . . ?
C29 P2 C2 C3 63.3(3) . . . . ?
C23 P2 C2 C3 -57.3(3) . . . . ?
P1 P2 C2 C3 -177.4(3) . . . . ?
N1 P2 C2 C1 1.0(2) . . . . ?
C29 P2 C2 C1 -118.1(2) . . . . ?
C23 P2 C2 C1 121.2(2) . . . . ?
P1 P2 C2 C1 1.15(16) . . . . ?
C1 C2 C3 C4 0.8(4) . . . . ?
P2 C2 C3 C4 179.2(2) . . . . ?
C2 C3 C4 C5 0.6(4) . . . . ?
C3 C4 C5 C6 -1.6(5) . . . . ?
C4 C5 C6 C1 1.2(5) . . . . ?
C2 C1 C6 C5 0.2(4) . . . . ?
P1 C1 C6 C5 -177.6(2) . . . . ?
N1 P1 C7 C8 128.3(2) . . . . ?
C10 P1 C7 C8 3.7(2) . . . . ?
C1 P1 C7 C8 -113.8(2) . . . . ?
P2 P1 C7 C8 167.61(17) . . . . ?
N1 P1 C7 C11 -56.8(3) . . . . ?
C10 P1 C7 C11 178.5(3) . . . . ?
C1 P1 C7 C11 61.1(3) . . . . ?
P2 P1 C7 C11 -17.5(3) . . . . ?
C11 C7 C8 C9 -178.5(3) . . . . ?
P1 C7 C8 C9 -3.9(3) . . . . ?
C7 C8 C9 C10 2.1(4) . . . . ?
C8 C9 C10 C17 -176.8(3) . . . . ?
C8 C9 C10 P1 0.9(3) . . . . ?
N1 P1 C10 C9 -129.0(2) . . . . ?
C1 P1 C10 C9 110.7(2) . . . . ?
C7 P1 C10 C9 -2.6(2) . . . . ?
P2 P1 C10 C9 -165.97(16) . . . . ?
N1 P1 C10 C17 48.7(3) . . . . ?
C1 P1 C10 C17 -71.6(3) . . . . ?
C7 P1 C10 C17 175.2(2) . . . . ?
P2 P1 C10 C17 11.8(3) . . . . ?
C8 C7 C11 C16 30.7(5) . . . . ?
P1 C7 C11 C16 -143.0(3) . . . . ?
C8 C7 C11 C12 -147.6(3) . . . . ?
P1 C7 C11 C12 38.7(4) . . . . ?
C16 C11 C12 C13 -1.0(5) . . . . ?
C7 C11 C12 C13 177.3(3) . . . . ?
C11 C12 C13 C14 0.9(6) . . . . ?
C12 C13 C14 C15 -0.8(6) . . . . ?
C13 C14 C15 C16 0.8(6) . . . . ?
C14 C15 C16 C11 -0.9(6) . . . . ?
C12 C11 C16 C15 1.0(5) . . . . ?
C7 C11 C16 C15 -177.3(3) . . . . ?
C9 C10 C17 C18 -150.8(3) . . . . ?
P1 C10 C17 C18 32.0(4) . . . . ?
C9 C10 C17 C22 29.0(5) . . . . ?
P1 C10 C17 C22 -148.3(2) . . . . ?
C22 C17 C18 C19 -0.6(5) . . . . ?
C10 C17 C18 C19 179.1(3) . . . . ?
C17 C18 C19 C20 0.6(5) . . . . ?
C18 C19 C20 C21 -0.9(5) . . . . ?
C19 C20 C21 C22 1.2(5) . . . . ?
C20 C21 C22 C17 -1.3(5) . . . . ?
C18 C17 C22 C21 1.0(4) . . . . ?
C10 C17 C22 C21 -178.8(3) . . . . ?
N1 P2 C23 C24 -74.8(3) . . . . ?
C29 P2 C23 C24 48.3(3) . . . . ?
C2 P2 C23 C24 171.7(2) . . . . ?
P1 P2 C23 C24 -111.1(2) . . . . ?
N1 P2 C23 C28 97.6(3) . . . . ?
C29 P2 C23 C28 -139.3(2) . . . . ?
C2 P2 C23 C28 -15.9(3) . . . . ?
P1 P2 C23 C28 61.3(3) . . . . ?
C28 C23 C24 C25 -0.8(4) . . . . ?
P2 C23 C24 C25 171.6(2) . . . . ?
C23 C24 C25 C26 1.0(5) . . . . ?
C24 C25 C26 C27 -0.3(5) . . . . ?
C25 C26 C27 C28 -0.5(5) . . . . ?
C26 C27 C28 C23 0.7(5) . . . . ?
C24 C23 C28 C27 0.0(5) . . . . ?
P2 C23 C28 C27 -172.3(3) . . . . ?
N1 P2 C29 C34 173.3(2) . . . . ?
C23 P2 C29 C34 48.6(3) . . . . ?
C2 P2 C29 C34 -72.3(3) . . . . ?
P1 P2 C29 C34 -152.0(2) . . . . ?
N1 P2 C29 C30 -8.8(3) . . . . ?
C23 P2 C29 C30 -133.4(2) . . . . ?
C2 P2 C29 C30 105.6(3) . . . . ?
P1 P2 C29 C30 25.9(3) . . . . ?
C34 C29 C30 C31 0.4(5) . . . . ?
P2 C29 C30 C31 -177.6(3) . . . . ?
C29 C30 C31 C32 -0.3(5) . . . . ?
C30 C31 C32 C33 0.0(6) . . . . ?
C31 C32 C33 C34 0.2(5) . . . . ?
C32 C33 C34 C29 -0.1(5) . . . . ?
C30 C29 C34 C33 -0.2(4) . . . . ?
P2 C29 C34 C33 177.7(2) . . . . ?

_refine_diff_density_max         0.228
_refine_diff_density_min         -0.197
_refine_diff_density_rms         0.040



#===END
