# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_lw239c_review_0m_d_pl
_database_code_depnum_ccdc_archive 'CCDC 2178883'
loop_
_audit_author_name
_audit_author_address
'Logan T. Maltz'
;Texas A and M University
United States of America
;
_audit_update_record             
;
2022-07-21 deposited with the CCDC.	2022-07-25 downloaded from the CCDC.
;
_audit_creation_date             2022-07-21
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C31 H25 Au Cl O P'
_chemical_formula_sum            'C31 H25 Au Cl O P'
_chemical_formula_weight         676.89
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   10.7463(12)
_cell_length_b                   16.4340(18)
_cell_length_c                   14.4097(16)
_cell_angle_alpha                90
_cell_angle_beta                 90.654(4)
_cell_angle_gamma                90
_cell_volume                     2544.7(5)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9832
_cell_measurement_temperature    110.15
_cell_measurement_theta_max      30.07
_cell_measurement_theta_min      2.48
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.972
_exptl_absorpt_correction_T_max  0.3807
_exptl_absorpt_correction_T_min  0.3031
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0919 before and 0.0488 after correction.
The Ratio of minimum to maximum transmission is 0.7962.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.767
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1320
_exptl_crystal_size_max          0.175
_exptl_crystal_size_mid          0.155
_exptl_crystal_size_min          0.145
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0316
_diffrn_reflns_av_unetI/netI     0.0196
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            31722
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        24.999
_diffrn_reflns_theta_max         24.999
_diffrn_reflns_theta_min         2.265
_diffrn_ambient_temperature      110.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4075
_reflns_number_total             4478
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       'SAINT V8.38A (Bruker, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.369
_refine_diff_density_min         -0.396
_refine_diff_density_rms         0.080
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     317
_refine_ls_number_reflns         4478
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0224
_refine_ls_R_factor_gt           0.0180
_refine_ls_restrained_S_all      1.084
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0089P)²+5.4047P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0398
_refine_ls_wR_factor_ref         0.0418
_refine_special_details          ?
_olex2_refinement_description    
;
1.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11), C12(H12),
 C14(H14), C15(H15), C16(H16), C17(H17), C18(H18), C20(H20), C21(H21), C22(H22),
  C23(H23), C24(H24), C26(H26), C27(H27), C28(H28), C29(H29), C30(H30)
1.b Idealised tetrahedral OH refined as rotating group:
 O1(H1)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.37432(2) 0.38082(2) 0.55882(2) 0.01948(4) Uani 1 1 d . . . . .
Cl1 Cl 0.37275(8) 0.48393(5) 0.66531(7) 0.0348(2) Uani 1 1 d . . . . .
P1 P 0.37795(7) 0.27222(5) 0.46570(5) 0.01674(16) Uani 1 1 d . . . . .
O1 O 0.4013(2) 0.39386(14) 0.34960(16) 0.0262(5) Uani 1 1 d . . . . .
H1 H 0.446145 0.434522 0.338572 0.039 Uiso 1 1 calc R U . . .
C1 C 0.2535(3) 0.25998(18) 0.3785(2) 0.0173(6) Uani 1 1 d . . . . .
C2 C 0.2257(3) 0.31650(19) 0.3079(2) 0.0185(7) Uani 1 1 d . . . . .
C3 C 0.1337(3) 0.2966(2) 0.2428(2) 0.0223(7) Uani 1 1 d . . . . .
H3 H 0.115033 0.334156 0.194477 0.027 Uiso 1 1 calc R U . . .
C4 C 0.0687(3) 0.2242(2) 0.2459(2) 0.0232(7) Uani 1 1 d . . . . .
H4 H 0.006625 0.212499 0.200415 0.028 Uiso 1 1 calc R U . . .
C5 C 0.0946(3) 0.16903(19) 0.3155(2) 0.0219(7) Uani 1 1 d . . . . .
H5 H 0.049890 0.119259 0.318774 0.026 Uiso 1 1 calc R U . . .
C6 C 0.1863(3) 0.18679(19) 0.3805(2) 0.0191(7) Uani 1 1 d . . . . .
H6 H 0.204248 0.148300 0.428026 0.023 Uiso 1 1 calc R U . . .
C7 C 0.3215(3) 0.41131(19) 0.1945(2) 0.0207(7) Uani 1 1 d . . . . .
C8 C 0.4057(3) 0.3574(2) 0.1551(2) 0.0296(8) Uani 1 1 d . . . . .
H8 H 0.442994 0.316427 0.192763 0.036 Uiso 1 1 calc R U . . .
C9 C 0.4362(4) 0.3623(2) 0.0624(3) 0.0354(9) Uani 1 1 d . . . . .
H9 H 0.494059 0.325002 0.036805 0.043 Uiso 1 1 calc R U . . .
C10 C 0.3823(3) 0.4216(2) 0.0070(2) 0.0293(8) Uani 1 1 d . . . . .
H10 H 0.402100 0.424896 -0.057000 0.035 Uiso 1 1 calc R U . . .
C11 C 0.3002(3) 0.4757(2) 0.0449(2) 0.0260(8) Uani 1 1 d . . . . .
H11 H 0.264034 0.516876 0.007011 0.031 Uiso 1 1 calc R U . . .
C12 C 0.2691(3) 0.47088(19) 0.1381(2) 0.0223(7) Uani 1 1 d . . . . .
H12 H 0.211658 0.508601 0.163267 0.027 Uiso 1 1 calc R U . . .
C13 C 0.2064(3) 0.46861(19) 0.3349(2) 0.0218(7) Uani 1 1 d . . . . .
C14 C 0.0809(3) 0.4590(2) 0.3551(2) 0.0257(7) Uani 1 1 d . . . . .
H14 H 0.042908 0.407171 0.347268 0.031 Uiso 1 1 calc R U . . .
C15 C 0.0108(3) 0.5237(2) 0.3863(2) 0.0306(8) Uani 1 1 d . . . . .
H15 H -0.074377 0.515883 0.400607 0.037 Uiso 1 1 calc R U . . .
C16 C 0.0640(4) 0.6001(2) 0.3968(2) 0.0310(8) Uani 1 1 d . . . . .
H16 H 0.015560 0.644619 0.417794 0.037 Uiso 1 1 calc R U . . .
C17 C 0.1881(4) 0.6107(2) 0.3764(2) 0.0316(8) Uani 1 1 d . . . . .
H17 H 0.225084 0.662907 0.382669 0.038 Uiso 1 1 calc R U . . .
C18 C 0.2589(3) 0.5455(2) 0.3468(2) 0.0255(7) Uani 1 1 d . . . . .
H18 H 0.344733 0.553247 0.334438 0.031 Uiso 1 1 calc R U . . .
C19 C 0.5219(3) 0.25108(18) 0.4063(2) 0.0192(7) Uani 1 1 d . . . . .
C20 C 0.6311(3) 0.2891(2) 0.4358(2) 0.0275(8) Uani 1 1 d . . . . .
H20 H 0.629040 0.329219 0.483199 0.033 Uiso 1 1 calc R U . . .
C21 C 0.7428(3) 0.2679(2) 0.3953(3) 0.0357(9) Uani 1 1 d . . . . .
H21 H 0.817735 0.293522 0.415259 0.043 Uiso 1 1 calc R U . . .
C22 C 0.7458(3) 0.2099(2) 0.3262(3) 0.0350(9) Uani 1 1 d . . . . .
H22 H 0.823041 0.194900 0.299802 0.042 Uiso 1 1 calc R U . . .
C23 C 0.6375(3) 0.1734(2) 0.2953(2) 0.0281(8) Uani 1 1 d . . . . .
H23 H 0.639871 0.134319 0.246826 0.034 Uiso 1 1 calc R U . . .
C24 C 0.5250(3) 0.19413(19) 0.3352(2) 0.0228(7) Uani 1 1 d . . . . .
H24 H 0.450066 0.169345 0.313879 0.027 Uiso 1 1 calc R U . . .
C25 C 0.3631(3) 0.18480(18) 0.5429(2) 0.0181(7) Uani 1 1 d . . . . .
C26 C 0.2684(3) 0.1858(2) 0.6082(2) 0.0234(7) Uani 1 1 d . . . . .
H26 H 0.211690 0.230087 0.609125 0.028 Uiso 1 1 calc R U . . .
C27 C 0.2555(3) 0.1233(2) 0.6717(2) 0.0253(7) Uani 1 1 d . . . . .
H27 H 0.189374 0.124262 0.714849 0.030 Uiso 1 1 calc R U . . .
C28 C 0.3396(3) 0.0593(2) 0.6721(2) 0.0253(7) Uani 1 1 d . . . . .
H28 H 0.331774 0.016440 0.715887 0.030 Uiso 1 1 calc R U . . .
C29 C 0.4343(3) 0.0581(2) 0.6087(2) 0.0244(7) Uani 1 1 d . . . . .
H29 H 0.491867 0.014191 0.609002 0.029 Uiso 1 1 calc R U . . .
C30 C 0.4466(3) 0.12037(19) 0.5442(2) 0.0214(7) Uani 1 1 d . . . . .
H30 H 0.512478 0.118846 0.500855 0.026 Uiso 1 1 calc R U . . .
C31 C 0.2886(3) 0.39958(18) 0.2972(2) 0.0192(7) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Cl1 2.2863(9) . ?
Au1 P1 2.2335(8) . ?
Au1 H1 3.3916 . ?
P1 C1 1.836(3) . ?
P1 C19 1.810(3) . ?
P1 C25 1.825(3) . ?
O1 H1 0.8400 . ?
O1 C31 1.423(4) . ?
C1 C2 1.407(4) . ?
C1 C6 1.404(4) . ?
C2 C3 1.395(4) . ?
C2 C31 1.532(4) . ?
C3 H3 0.9500 . ?
C3 C4 1.380(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.378(5) . ?
C5 H5 0.9500 . ?
C5 C6 1.383(4) . ?
C6 H6 0.9500 . ?
C7 C8 1.392(5) . ?
C7 C12 1.388(4) . ?
C7 C31 1.537(4) . ?
C8 H8 0.9500 . ?
C8 C9 1.382(5) . ?
C9 H9 0.9500 . ?
C9 C10 1.384(5) . ?
C10 H10 0.9500 . ?
C10 C11 1.370(5) . ?
C11 H11 0.9500 . ?
C11 C12 1.389(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.392(5) . ?
C13 C18 1.393(5) . ?
C13 C31 1.540(4) . ?
C14 H14 0.9500 . ?
C14 C15 1.382(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.386(5) . ?
C16 H16 0.9500 . ?
C16 C17 1.380(5) . ?
C17 H17 0.9500 . ?
C17 C18 1.384(5) . ?
C18 H18 0.9500 . ?
C19 C20 1.391(5) . ?
C19 C24 1.388(4) . ?
C20 H20 0.9500 . ?
C20 C21 1.385(5) . ?
C21 H21 0.9500 . ?
C21 C22 1.380(5) . ?
C22 H22 0.9500 . ?
C22 C23 1.379(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.387(5) . ?
C24 H24 0.9500 . ?
C25 C26 1.394(4) . ?
C25 C30 1.388(4) . ?
C26 H26 0.9500 . ?
C26 C27 1.382(5) . ?
C27 H27 0.9500 . ?
C27 C28 1.387(5) . ?
C28 H28 0.9500 . ?
C28 C29 1.375(5) . ?
C29 H29 0.9500 . ?
C29 C30 1.390(4) . ?
C30 H30 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1 Au1 H1 116.0 . . ?
P1 Au1 Cl1 174.75(3) . . ?
P1 Au1 H1 68.9 . . ?
C1 P1 Au1 118.76(10) . . ?
C19 P1 Au1 117.27(11) . . ?
C19 P1 C1 105.97(14) . . ?
C19 P1 C25 102.61(14) . . ?
C25 P1 Au1 105.10(10) . . ?
C25 P1 C1 105.26(14) . . ?
C31 O1 H1 109.5 . . ?
C2 C1 P1 124.7(2) . . ?
C6 C1 P1 116.8(2) . . ?
C6 C1 C2 118.4(3) . . ?
C1 C2 C31 124.8(3) . . ?
C3 C2 C1 118.3(3) . . ?
C3 C2 C31 116.9(3) . . ?
C2 C3 H3 118.8 . . ?
C4 C3 C2 122.4(3) . . ?
C4 C3 H3 118.8 . . ?
C3 C4 H4 120.2 . . ?
C5 C4 C3 119.6(3) . . ?
C5 C4 H4 120.2 . . ?
C4 C5 H5 120.3 . . ?
C4 C5 C6 119.4(3) . . ?
C6 C5 H5 120.3 . . ?
C1 C6 H6 119.0 . . ?
C5 C6 C1 122.0(3) . . ?
C5 C6 H6 119.0 . . ?
C8 C7 C31 118.1(3) . . ?
C12 C7 C8 118.1(3) . . ?
C12 C7 C31 123.8(3) . . ?
C7 C8 H8 119.3 . . ?
C9 C8 C7 121.3(3) . . ?
C9 C8 H8 119.3 . . ?
C8 C9 H9 120.1 . . ?
C8 C9 C10 119.8(3) . . ?
C10 C9 H9 120.1 . . ?
C9 C10 H10 120.2 . . ?
C11 C10 C9 119.6(3) . . ?
C11 C10 H10 120.2 . . ?
C10 C11 H11 119.6 . . ?
C10 C11 C12 120.8(3) . . ?
C12 C11 H11 119.6 . . ?
C7 C12 C11 120.4(3) . . ?
C7 C12 H12 119.8 . . ?
C11 C12 H12 119.8 . . ?
C14 C13 C18 118.0(3) . . ?
C14 C13 C31 123.4(3) . . ?
C18 C13 C31 118.6(3) . . ?
C13 C14 H14 119.6 . . ?
C15 C14 C13 120.9(3) . . ?
C15 C14 H14 119.6 . . ?
C14 C15 H15 119.8 . . ?
C14 C15 C16 120.5(3) . . ?
C16 C15 H15 119.8 . . ?
C15 C16 H16 120.4 . . ?
C17 C16 C15 119.3(3) . . ?
C17 C16 H16 120.4 . . ?
C16 C17 H17 119.9 . . ?
C16 C17 C18 120.3(3) . . ?
C18 C17 H17 119.9 . . ?
C13 C18 H18 119.4 . . ?
C17 C18 C13 121.1(3) . . ?
C17 C18 H18 119.4 . . ?
C20 C19 P1 119.5(3) . . ?
C24 C19 P1 120.4(2) . . ?
C24 C19 C20 120.1(3) . . ?
C19 C20 H20 120.3 . . ?
C21 C20 C19 119.4(3) . . ?
C21 C20 H20 120.3 . . ?
C20 C21 H21 119.8 . . ?
C22 C21 C20 120.3(3) . . ?
C22 C21 H21 119.8 . . ?
C21 C22 H22 119.8 . . ?
C23 C22 C21 120.5(3) . . ?
C23 C22 H22 119.8 . . ?
C22 C23 H23 120.1 . . ?
C22 C23 C24 119.8(3) . . ?
C24 C23 H23 120.1 . . ?
C19 C24 H24 120.0 . . ?
C23 C24 C19 119.9(3) . . ?
C23 C24 H24 120.0 . . ?
C26 C25 P1 118.2(2) . . ?
C30 C25 P1 123.2(2) . . ?
C30 C25 C26 118.4(3) . . ?
C25 C26 H26 119.4 . . ?
C27 C26 C25 121.2(3) . . ?
C27 C26 H26 119.4 . . ?
C26 C27 H27 120.1 . . ?
C26 C27 C28 119.7(3) . . ?
C28 C27 H27 120.1 . . ?
C27 C28 H28 120.2 . . ?
C29 C28 C27 119.7(3) . . ?
C29 C28 H28 120.2 . . ?
C28 C29 H29 119.7 . . ?
C28 C29 C30 120.7(3) . . ?
C30 C29 H29 119.7 . . ?
C25 C30 C29 120.3(3) . . ?
C25 C30 H30 119.8 . . ?
C29 C30 H30 119.8 . . ?
O1 C31 C2 105.2(2) . . ?
O1 C31 C7 108.4(3) . . ?
O1 C31 C13 110.5(3) . . ?
C2 C31 C7 108.4(3) . . ?
C2 C31 C13 111.4(3) . . ?
C7 C31 C13 112.7(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P1 C1 C2 58.9(3) . . . . ?
Au1 P1 C1 C6 -124.5(2) . . . . ?
Au1 P1 C19 C20 15.1(3) . . . . ?
Au1 P1 C19 C24 -168.4(2) . . . . ?
Au1 P1 C25 C26 49.3(3) . . . . ?
Au1 P1 C25 C30 -126.0(2) . . . . ?
P1 C1 C2 C3 175.8(2) . . . . ?
P1 C1 C2 C31 -4.7(5) . . . . ?
P1 C1 C6 C5 -176.7(2) . . . . ?
P1 C19 C20 C21 174.7(3) . . . . ?
P1 C19 C24 C23 -174.7(2) . . . . ?
P1 C25 C26 C27 -176.9(3) . . . . ?
P1 C25 C30 C29 176.0(2) . . . . ?
C1 P1 C19 C20 150.4(3) . . . . ?
C1 P1 C19 C24 -33.1(3) . . . . ?
C1 P1 C25 C26 -76.9(3) . . . . ?
C1 P1 C25 C30 107.8(3) . . . . ?
C1 C2 C3 C4 0.7(5) . . . . ?
C1 C2 C31 O1 19.1(4) . . . . ?
C1 C2 C31 C7 134.8(3) . . . . ?
C1 C2 C31 C13 -100.6(3) . . . . ?
C2 C1 C6 C5 0.1(5) . . . . ?
C2 C3 C4 C5 0.0(5) . . . . ?
C3 C2 C31 O1 -161.4(3) . . . . ?
C3 C2 C31 C7 -45.7(4) . . . . ?
C3 C2 C31 C13 78.9(3) . . . . ?
C3 C4 C5 C6 -0.7(5) . . . . ?
C4 C5 C6 C1 0.6(5) . . . . ?
C6 C1 C2 C3 -0.7(4) . . . . ?
C6 C1 C2 C31 178.8(3) . . . . ?
C7 C8 C9 C10 -0.1(6) . . . . ?
C8 C7 C12 C11 0.3(5) . . . . ?
C8 C7 C31 O1 51.0(4) . . . . ?
C8 C7 C31 C2 -62.7(4) . . . . ?
C8 C7 C31 C13 173.5(3) . . . . ?
C8 C9 C10 C11 0.8(6) . . . . ?
C9 C10 C11 C12 -0.9(5) . . . . ?
C10 C11 C12 C7 0.3(5) . . . . ?
C12 C7 C8 C9 -0.4(5) . . . . ?
C12 C7 C31 O1 -131.2(3) . . . . ?
C12 C7 C31 C2 115.2(3) . . . . ?
C12 C7 C31 C13 -8.6(4) . . . . ?
C13 C14 C15 C16 1.0(5) . . . . ?
C14 C13 C18 C17 -1.0(5) . . . . ?
C14 C13 C31 O1 -130.7(3) . . . . ?
C14 C13 C31 C2 -14.2(4) . . . . ?
C14 C13 C31 C7 107.9(3) . . . . ?
C14 C15 C16 C17 -0.5(5) . . . . ?
C15 C16 C17 C18 -0.8(5) . . . . ?
C16 C17 C18 C13 1.5(5) . . . . ?
C18 C13 C14 C15 -0.2(5) . . . . ?
C18 C13 C31 O1 51.4(4) . . . . ?
C18 C13 C31 C2 167.9(3) . . . . ?
C18 C13 C31 C7 -70.0(4) . . . . ?
C19 P1 C1 C2 -75.6(3) . . . . ?
C19 P1 C1 C6 101.0(3) . . . . ?
C19 P1 C25 C26 172.4(2) . . . . ?
C19 P1 C25 C30 -2.8(3) . . . . ?
C19 C20 C21 C22 0.2(5) . . . . ?
C20 C19 C24 C23 1.8(5) . . . . ?
C20 C21 C22 C23 1.3(6) . . . . ?
C21 C22 C23 C24 -1.3(5) . . . . ?
C22 C23 C24 C19 -0.3(5) . . . . ?
C24 C19 C20 C21 -1.8(5) . . . . ?
C25 P1 C1 C2 176.1(3) . . . . ?
C25 P1 C1 C6 -7.2(3) . . . . ?
C25 P1 C19 C20 -99.4(3) . . . . ?
C25 P1 C19 C24 77.1(3) . . . . ?
C25 C26 C27 C28 1.4(5) . . . . ?
C26 C25 C30 C29 0.8(5) . . . . ?
C26 C27 C28 C29 -0.6(5) . . . . ?
C27 C28 C29 C30 0.0(5) . . . . ?
C28 C29 C30 C25 -0.1(5) . . . . ?
C30 C25 C26 C27 -1.4(5) . . . . ?
C31 C2 C3 C4 -178.8(3) . . . . ?
C31 C7 C8 C9 177.6(3) . . . . ?
C31 C7 C12 C11 -177.5(3) . . . . ?
C31 C13 C14 C15 -178.1(3) . . . . ?
C31 C13 C18 C17 177.0(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ltm_auph_review_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2178884'
loop_
_audit_author_name
_audit_author_address
'Logan T. Maltz'
;Texas A and M University
United States of America
;
_audit_update_record             
;
2022-07-21 deposited with the CCDC.	2022-07-25 downloaded from the CCDC.
;
_audit_creation_date             2022-07-21
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C37 H30 Au O P'
_chemical_formula_sum            'C37 H30 Au O P'
_chemical_formula_weight         718.54
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.5116(16)
_cell_length_b                   12.370(2)
_cell_length_c                   12.454(2)
_cell_angle_alpha                91.290(7)
_cell_angle_beta                 98.003(7)
_cell_angle_gamma                97.943(7)
_cell_volume                     1435.9(4)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9853
_cell_measurement_temperature    110.00
_cell_measurement_theta_max      29.78
_cell_measurement_theta_min      2.29
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.207
_exptl_absorpt_correction_T_max  0.3807
_exptl_absorpt_correction_T_min  0.2441
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1128 before and 0.0717 after correction.
The Ratio of minimum to maximum transmission is 0.6412.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.662
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             708
_exptl_crystal_size_max          0.216
_exptl_crystal_size_mid          0.148
_exptl_crystal_size_min          0.127
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0727
_diffrn_reflns_av_unetI/netI     0.0604
_diffrn_reflns_Laue_measured_fraction_full 0.946
_diffrn_reflns_Laue_measured_fraction_max 0.960
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            31186
_diffrn_reflns_point_group_measured_fraction_full 0.946
_diffrn_reflns_point_group_measured_fraction_max 0.960
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.126
_diffrn_reflns_theta_min         2.295
_diffrn_ambient_temperature      110.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.946
_diffrn_measured_fraction_theta_max 0.960
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6346
_reflns_number_total             7405
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       'SAINT V8.38A (Bruker, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         1.987
_refine_diff_density_min         -1.631
_refine_diff_density_rms         0.146
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.008
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     365
_refine_ls_number_reflns         7405
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0402
_refine_ls_R_factor_gt           0.0316
_refine_ls_restrained_S_all      1.008
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0200P)²+1.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0635
_refine_ls_wR_factor_ref         0.0651
_refine_special_details          ?
_olex2_refinement_description    
;
1.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11), C12(H12),
 C14(H14), C15(H15), C16(H16), C17(H17), C18(H18), C20(H20), C21(H21), C22(H22),
  C23(H23), C24(H24), C26(H26), C27(H27), C28(H28), C29(H29), C30(H30),
 C33(H33), C34(H34), C35(H35), C36(H36), C37(H37)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.53665(2) 0.25191(2) 0.54938(2) 0.01568(5) Uani 1 1 d . . . . .
P1 P 0.43457(10) 0.33073(7) 0.68310(6) 0.01402(17) Uani 1 1 d . . . . .
O1 O 0.7201(3) 0.3282(2) 0.7745(2) 0.0185(5) Uani 1 1 d . . . . .
H1 H 0.682(6) 0.291(4) 0.720(4) 0.035(13) Uiso 1 1 d . . . . .
C1 C 0.4276(4) 0.2523(3) 0.8072(3) 0.0155(7) Uani 1 1 d . . . . .
C2 C 0.5471(4) 0.2158(3) 0.8680(3) 0.0138(6) Uani 1 1 d . . . . .
C3 C 0.5239(4) 0.1524(3) 0.9578(3) 0.0179(7) Uani 1 1 d . . . . .
H3 H 0.603640 0.127870 0.999883 0.021 Uiso 1 1 calc R U . . .
C4 C 0.3888(4) 0.1245(3) 0.9872(3) 0.0178(7) Uani 1 1 d . . . . .
H4 H 0.376642 0.080248 1.047492 0.021 Uiso 1 1 calc R U . . .
C5 C 0.2715(4) 0.1613(3) 0.9282(3) 0.0193(7) Uani 1 1 d . . . . .
H5 H 0.178401 0.143097 0.947832 0.023 Uiso 1 1 calc R U . . .
C6 C 0.2925(4) 0.2255(3) 0.8397(3) 0.0168(7) Uani 1 1 d . . . . .
H6 H 0.212330 0.251833 0.800033 0.020 Uiso 1 1 calc R U . . .
C7 C 0.8032(4) 0.2760(3) 0.9497(3) 0.0179(7) Uani 1 1 d . . . . .
C8 C 0.8082(4) 0.3838(3) 0.9877(3) 0.0229(8) Uani 1 1 d . . . . .
H8 H 0.748472 0.430127 0.949685 0.028 Uiso 1 1 calc R U . . .
C9 C 0.9001(5) 0.4234(4) 1.0808(3) 0.0305(9) Uani 1 1 d . . . . .
H9 H 0.901777 0.496372 1.106948 0.037 Uiso 1 1 calc R U . . .
C10 C 0.9885(5) 0.3581(4) 1.1355(3) 0.0349(11) Uani 1 1 d . . . . .
H10 H 1.053800 0.386698 1.197578 0.042 Uiso 1 1 calc R U . . .
C11 C 0.9829(4) 0.2514(4) 1.1005(3) 0.0294(9) Uani 1 1 d . . . . .
H11 H 1.042369 0.205769 1.139837 0.035 Uiso 1 1 calc R U . . .
C12 C 0.8908(4) 0.2098(3) 1.0081(3) 0.0235(8) Uani 1 1 d . . . . .
H12 H 0.887399 0.135803 0.984557 0.028 Uiso 1 1 calc R U . . .
C13 C 0.7489(4) 0.1385(3) 0.7897(3) 0.0152(7) Uani 1 1 d . . . . .
C14 C 0.6585(4) 0.0404(3) 0.7620(3) 0.0176(7) Uani 1 1 d . . . . .
H14 H 0.562957 0.032072 0.778098 0.021 Uiso 1 1 calc R U . . .
C15 C 0.7075(4) -0.0453(3) 0.7111(3) 0.0215(8) Uani 1 1 d . . . . .
H15 H 0.644727 -0.111584 0.691623 0.026 Uiso 1 1 calc R U . . .
C16 C 0.8460(4) -0.0349(3) 0.6886(3) 0.0216(8) Uani 1 1 d . . . . .
H16 H 0.879422 -0.094650 0.655642 0.026 Uiso 1 1 calc R U . . .
C17 C 0.9373(4) 0.0626(3) 0.7139(3) 0.0233(8) Uani 1 1 d . . . . .
H17 H 1.032636 0.070319 0.697428 0.028 Uiso 1 1 calc R U . . .
C18 C 0.8883(4) 0.1485(3) 0.7632(3) 0.0213(8) Uani 1 1 d . . . . .
H18 H 0.950410 0.215574 0.779532 0.026 Uiso 1 1 calc R U . . .
C19 C 0.5126(4) 0.4688(3) 0.7304(2) 0.0139(6) Uani 1 1 d . . . . .
C20 C 0.4936(4) 0.5102(3) 0.8326(3) 0.0182(7) Uani 1 1 d . . . . .
H20 H 0.437272 0.466790 0.877284 0.022 Uiso 1 1 calc R U . . .
C21 C 0.5578(4) 0.6151(3) 0.8678(3) 0.0203(7) Uani 1 1 d . . . . .
H21 H 0.544607 0.643725 0.936556 0.024 Uiso 1 1 calc R U . . .
C22 C 0.6406(4) 0.6780(3) 0.8033(3) 0.0216(8) Uani 1 1 d . . . . .
H22 H 0.685464 0.749242 0.828421 0.026 Uiso 1 1 calc R U . . .
C23 C 0.6587(4) 0.6375(3) 0.7016(3) 0.0211(8) Uani 1 1 d . . . . .
H23 H 0.714587 0.681429 0.657085 0.025 Uiso 1 1 calc R U . . .
C24 C 0.5953(4) 0.5333(3) 0.6656(3) 0.0196(7) Uani 1 1 d . . . . .
H24 H 0.608094 0.505685 0.596418 0.024 Uiso 1 1 calc R U . . .
C25 C 0.2477(4) 0.3422(3) 0.6331(3) 0.0164(7) Uani 1 1 d . . . . .
C26 C 0.1773(4) 0.4274(3) 0.6665(3) 0.0199(7) Uani 1 1 d . . . . .
H26 H 0.227613 0.482612 0.717410 0.024 Uiso 1 1 calc R U . . .
C27 C 0.0365(4) 0.4311(3) 0.6260(3) 0.0246(8) Uani 1 1 d . . . . .
H27 H -0.009312 0.489065 0.649524 0.030 Uiso 1 1 calc R U . . .
C28 C -0.0404(4) 0.3522(3) 0.5516(3) 0.0255(8) Uani 1 1 d . . . . .
H28 H -0.138056 0.355613 0.524506 0.031 Uiso 1 1 calc R U . . .
C29 C 0.0280(4) 0.2679(3) 0.5173(3) 0.0241(8) Uani 1 1 d . . . . .
H29 H -0.023231 0.213185 0.466323 0.029 Uiso 1 1 calc R U . . .
C30 C 0.1683(4) 0.2635(3) 0.5567(3) 0.0196(7) Uani 1 1 d . . . . .
H30 H 0.213543 0.205761 0.531879 0.023 Uiso 1 1 calc R U . . .
C31 C 0.7026(4) 0.2378(3) 0.8443(3) 0.0151(7) Uani 1 1 d . . . . .
C32 C 0.6277(4) 0.1831(3) 0.4305(3) 0.0175(7) Uani 1 1 d . . . . .
C33 C 0.6589(4) 0.0763(3) 0.4341(3) 0.0193(7) Uani 1 1 d . . . . .
H33 H 0.639980 0.034368 0.494784 0.023 Uiso 1 1 calc R U . . .
C34 C 0.7173(4) 0.0297(3) 0.3504(3) 0.0228(8) Uani 1 1 d . . . . .
H34 H 0.739793 -0.042632 0.355506 0.027 Uiso 1 1 calc R U . . .
C35 C 0.7424(5) 0.0885(3) 0.2603(3) 0.0257(8) Uani 1 1 d . . . . .
H35 H 0.779509 0.056027 0.202450 0.031 Uiso 1 1 calc R U . . .
C36 C 0.7130(4) 0.1958(3) 0.2548(3) 0.0226(8) Uani 1 1 d . . . . .
H36 H 0.730582 0.236861 0.193337 0.027 Uiso 1 1 calc R U . . .
C37 C 0.6580(4) 0.2424(3) 0.3395(3) 0.0188(7) Uani 1 1 d . . . . .
H37 H 0.640366 0.316097 0.335775 0.023 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.3035(9) . ?
Au1 H1 2.37(5) . ?
Au1 C32 2.042(3) . ?
P1 C1 1.848(3) . ?
P1 C19 1.816(3) . ?
P1 C25 1.826(4) . ?
O1 H1 0.82(5) . ?
O1 C31 1.438(4) . ?
C1 C2 1.410(5) . ?
C1 C6 1.399(5) . ?
C2 C3 1.406(5) . ?
C2 C31 1.537(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.385(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.385(5) . ?
C5 H5 0.9500 . ?
C5 C6 1.394(5) . ?
C6 H6 0.9500 . ?
C7 C8 1.398(5) . ?
C7 C12 1.392(5) . ?
C7 C31 1.536(5) . ?
C8 H8 0.9500 . ?
C8 C9 1.386(5) . ?
C9 H9 0.9500 . ?
C9 C10 1.369(6) . ?
C10 H10 0.9500 . ?
C10 C11 1.372(6) . ?
C11 H11 0.9500 . ?
C11 C12 1.388(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.393(5) . ?
C13 C18 1.400(5) . ?
C13 C31 1.537(5) . ?
C14 H14 0.9500 . ?
C14 C15 1.391(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.374(5) . ?
C16 H16 0.9500 . ?
C16 C17 1.388(5) . ?
C17 H17 0.9500 . ?
C17 C18 1.382(5) . ?
C18 H18 0.9500 . ?
C19 C20 1.405(4) . ?
C19 C24 1.393(5) . ?
C20 H20 0.9500 . ?
C20 C21 1.389(5) . ?
C21 H21 0.9500 . ?
C21 C22 1.380(5) . ?
C22 H22 0.9500 . ?
C22 C23 1.393(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.381(5) . ?
C24 H24 0.9500 . ?
C25 C26 1.409(5) . ?
C25 C30 1.407(5) . ?
C26 H26 0.9500 . ?
C26 C27 1.370(5) . ?
C27 H27 0.9500 . ?
C27 C28 1.385(5) . ?
C28 H28 0.9500 . ?
C28 C29 1.392(5) . ?
C29 H29 0.9500 . ?
C29 C30 1.365(5) . ?
C30 H30 0.9500 . ?
C32 C33 1.393(5) . ?
C32 C37 1.407(5) . ?
C33 H33 0.9500 . ?
C33 C34 1.396(5) . ?
C34 H34 0.9500 . ?
C34 C35 1.382(5) . ?
C35 H35 0.9500 . ?
C35 C36 1.395(5) . ?
C36 H36 0.9500 . ?
C36 C37 1.388(5) . ?
C37 H37 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 H1 63.5(11) . . ?
C32 Au1 P1 179.61(11) . . ?
C32 Au1 H1 116.5(11) . . ?
C1 P1 Au1 115.01(11) . . ?
C19 P1 Au1 116.80(11) . . ?
C19 P1 C1 105.22(15) . . ?
C19 P1 C25 104.07(16) . . ?
C25 P1 Au1 109.78(11) . . ?
C25 P1 C1 104.77(16) . . ?
C31 O1 H1 93(3) . . ?
C2 C1 P1 124.5(3) . . ?
C6 C1 P1 116.6(3) . . ?
C6 C1 C2 118.9(3) . . ?
C1 C2 C31 125.8(3) . . ?
C3 C2 C1 118.0(3) . . ?
C3 C2 C31 116.2(3) . . ?
C2 C3 H3 118.8 . . ?
C4 C3 C2 122.3(3) . . ?
C4 C3 H3 118.8 . . ?
C3 C4 H4 120.1 . . ?
C3 C4 C5 119.7(3) . . ?
C5 C4 H4 120.1 . . ?
C4 C5 H5 120.6 . . ?
C4 C5 C6 118.9(3) . . ?
C6 C5 H5 120.6 . . ?
C1 C6 H6 118.9 . . ?
C5 C6 C1 122.2(3) . . ?
C5 C6 H6 118.9 . . ?
C8 C7 C31 117.8(3) . . ?
C12 C7 C8 118.5(3) . . ?
C12 C7 C31 123.7(3) . . ?
C7 C8 H8 119.9 . . ?
C9 C8 C7 120.2(4) . . ?
C9 C8 H8 119.9 . . ?
C8 C9 H9 119.7 . . ?
C10 C9 C8 120.5(4) . . ?
C10 C9 H9 119.7 . . ?
C9 C10 H10 120.0 . . ?
C9 C10 C11 120.0(4) . . ?
C11 C10 H10 120.0 . . ?
C10 C11 H11 119.8 . . ?
C10 C11 C12 120.4(4) . . ?
C12 C11 H11 119.8 . . ?
C7 C12 H12 119.8 . . ?
C11 C12 C7 120.3(4) . . ?
C11 C12 H12 119.8 . . ?
C14 C13 C18 118.3(3) . . ?
C14 C13 C31 123.6(3) . . ?
C18 C13 C31 118.1(3) . . ?
C13 C14 H14 119.9 . . ?
C15 C14 C13 120.3(3) . . ?
C15 C14 H14 119.9 . . ?
C14 C15 H15 119.8 . . ?
C16 C15 C14 120.5(3) . . ?
C16 C15 H15 119.8 . . ?
C15 C16 H16 119.9 . . ?
C15 C16 C17 120.2(3) . . ?
C17 C16 H16 119.9 . . ?
C16 C17 H17 120.3 . . ?
C18 C17 C16 119.5(3) . . ?
C18 C17 H17 120.3 . . ?
C13 C18 H18 119.4 . . ?
C17 C18 C13 121.3(3) . . ?
C17 C18 H18 119.4 . . ?
C20 C19 P1 120.9(3) . . ?
C24 C19 P1 119.5(2) . . ?
C24 C19 C20 119.6(3) . . ?
C19 C20 H20 120.2 . . ?
C21 C20 C19 119.6(3) . . ?
C21 C20 H20 120.2 . . ?
C20 C21 H21 119.9 . . ?
C22 C21 C20 120.3(3) . . ?
C22 C21 H21 119.9 . . ?
C21 C22 H22 119.9 . . ?
C21 C22 C23 120.3(3) . . ?
C23 C22 H22 119.9 . . ?
C22 C23 H23 120.0 . . ?
C24 C23 C22 120.0(3) . . ?
C24 C23 H23 120.0 . . ?
C19 C24 H24 119.9 . . ?
C23 C24 C19 120.2(3) . . ?
C23 C24 H24 119.9 . . ?
C26 C25 P1 123.3(3) . . ?
C30 C25 P1 119.4(3) . . ?
C30 C25 C26 117.4(3) . . ?
C25 C26 H26 119.8 . . ?
C27 C26 C25 120.3(3) . . ?
C27 C26 H26 119.8 . . ?
C26 C27 H27 119.2 . . ?
C26 C27 C28 121.5(4) . . ?
C28 C27 H27 119.2 . . ?
C27 C28 H28 120.6 . . ?
C27 C28 C29 118.8(4) . . ?
C29 C28 H28 120.6 . . ?
C28 C29 H29 119.8 . . ?
C30 C29 C28 120.3(4) . . ?
C30 C29 H29 119.8 . . ?
C25 C30 H30 119.2 . . ?
C29 C30 C25 121.7(3) . . ?
C29 C30 H30 119.2 . . ?
O1 C31 C2 110.4(3) . . ?
O1 C31 C7 104.4(3) . . ?
O1 C31 C13 108.2(2) . . ?
C7 C31 C2 109.5(3) . . ?
C7 C31 C13 111.5(3) . . ?
C13 C31 C2 112.6(3) . . ?
C33 C32 Au1 122.3(3) . . ?
C33 C32 C37 117.4(3) . . ?
C37 C32 Au1 120.3(3) . . ?
C32 C33 H33 119.3 . . ?
C32 C33 C34 121.4(3) . . ?
C34 C33 H33 119.3 . . ?
C33 C34 H34 119.9 . . ?
C35 C34 C33 120.2(4) . . ?
C35 C34 H34 119.9 . . ?
C34 C35 H35 120.2 . . ?
C34 C35 C36 119.6(3) . . ?
C36 C35 H35 120.2 . . ?
C35 C36 H36 120.1 . . ?
C37 C36 C35 119.8(3) . . ?
C37 C36 H36 120.1 . . ?
C32 C37 H37 119.3 . . ?
C36 C37 C32 121.5(3) . . ?
C36 C37 H37 119.3 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P1 C1 C2 53.7(3) . . . . ?
Au1 P1 C1 C6 -124.3(2) . . . . ?
Au1 P1 C19 C20 -158.4(2) . . . . ?
Au1 P1 C19 C24 20.0(3) . . . . ?
Au1 P1 C25 C26 -147.9(3) . . . . ?
Au1 P1 C25 C30 31.5(3) . . . . ?
Au1 C32 C33 C34 178.1(3) . . . . ?
Au1 C32 C37 C36 -176.7(3) . . . . ?
P1 C1 C2 C3 -177.0(2) . . . . ?
P1 C1 C2 C31 2.2(5) . . . . ?
P1 C1 C6 C5 176.3(3) . . . . ?
P1 C19 C20 C21 178.3(3) . . . . ?
P1 C19 C24 C23 -178.2(3) . . . . ?
P1 C25 C26 C27 -179.8(3) . . . . ?
P1 C25 C30 C29 179.5(3) . . . . ?
C1 P1 C19 C20 -29.5(3) . . . . ?
C1 P1 C19 C24 148.9(3) . . . . ?
C1 P1 C25 C26 88.1(3) . . . . ?
C1 P1 C25 C30 -92.5(3) . . . . ?
C1 C2 C3 C4 0.6(5) . . . . ?
C1 C2 C31 O1 18.5(4) . . . . ?
C1 C2 C31 C7 132.9(3) . . . . ?
C1 C2 C31 C13 -102.5(4) . . . . ?
C2 C1 C6 C5 -1.8(5) . . . . ?
C2 C3 C4 C5 -1.3(5) . . . . ?
C3 C2 C31 O1 -162.3(3) . . . . ?
C3 C2 C31 C7 -47.9(4) . . . . ?
C3 C2 C31 C13 76.8(4) . . . . ?
C3 C4 C5 C6 0.4(5) . . . . ?
C4 C5 C6 C1 1.1(5) . . . . ?
C6 C1 C2 C3 0.9(5) . . . . ?
C6 C1 C2 C31 -179.9(3) . . . . ?
C7 C8 C9 C10 1.1(6) . . . . ?
C8 C7 C12 C11 -1.4(5) . . . . ?
C8 C7 C31 O1 41.3(4) . . . . ?
C8 C7 C31 C2 -76.9(4) . . . . ?
C8 C7 C31 C13 157.8(3) . . . . ?
C8 C9 C10 C11 -2.4(6) . . . . ?
C9 C10 C11 C12 1.8(6) . . . . ?
C10 C11 C12 C7 0.1(6) . . . . ?
C12 C7 C8 C9 0.8(5) . . . . ?
C12 C7 C31 O1 -137.7(3) . . . . ?
C12 C7 C31 C2 104.1(4) . . . . ?
C12 C7 C31 C13 -21.2(5) . . . . ?
C13 C14 C15 C16 0.8(5) . . . . ?
C14 C13 C18 C17 -1.9(5) . . . . ?
C14 C13 C31 O1 -120.6(3) . . . . ?
C14 C13 C31 C2 1.6(4) . . . . ?
C14 C13 C31 C7 125.2(3) . . . . ?
C14 C15 C16 C17 -1.8(5) . . . . ?
C15 C16 C17 C18 0.9(6) . . . . ?
C16 C17 C18 C13 0.9(6) . . . . ?
C18 C13 C14 C15 1.0(5) . . . . ?
C18 C13 C31 O1 57.3(4) . . . . ?
C18 C13 C31 C2 179.6(3) . . . . ?
C18 C13 C31 C7 -56.9(4) . . . . ?
C19 P1 C1 C2 -76.3(3) . . . . ?
C19 P1 C1 C6 105.7(3) . . . . ?
C19 P1 C25 C26 -22.1(3) . . . . ?
C19 P1 C25 C30 157.3(3) . . . . ?
C19 C20 C21 C22 -0.5(5) . . . . ?
C20 C19 C24 C23 0.2(5) . . . . ?
C20 C21 C22 C23 1.0(6) . . . . ?
C21 C22 C23 C24 -0.9(6) . . . . ?
C22 C23 C24 C19 0.3(6) . . . . ?
C24 C19 C20 C21 -0.1(5) . . . . ?
C25 P1 C1 C2 174.3(3) . . . . ?
C25 P1 C1 C6 -3.7(3) . . . . ?
C25 P1 C19 C20 80.5(3) . . . . ?
C25 P1 C19 C24 -101.2(3) . . . . ?
C25 C26 C27 C28 -0.1(6) . . . . ?
C26 C25 C30 C29 -1.0(5) . . . . ?
C26 C27 C28 C29 -0.3(6) . . . . ?
C27 C28 C29 C30 0.0(6) . . . . ?
C28 C29 C30 C25 0.6(6) . . . . ?
C30 C25 C26 C27 0.7(5) . . . . ?
C31 C2 C3 C4 -178.7(3) . . . . ?
C31 C7 C8 C9 -178.2(3) . . . . ?
C31 C7 C12 C11 177.6(3) . . . . ?
C31 C13 C14 C15 178.9(3) . . . . ?
C31 C13 C18 C17 -179.9(3) . . . . ?
C32 C33 C34 C35 -1.5(6) . . . . ?
C33 C32 C37 C36 1.8(5) . . . . ?
C33 C34 C35 C36 1.9(6) . . . . ?
C34 C35 C36 C37 -0.4(6) . . . . ?
C35 C36 C37 C32 -1.5(6) . . . . ?
C37 C32 C33 C34 -0.3(5) . . . . ?

# end Validation Reply Form
_olex2_submission_special_instructions 'No special instructions were received'
# start Validation Reply Form
_vrf_PLAT420_ltm_auph_review_0m_a 
;
PROBLEM: D-H Bond Without Acceptor  O1       --H1       .     Please Check 
RESPONSE: Au1 serves as the hydrogen bond acceptor
;
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ltm_auph05052022_0ma_a
_database_code_depnum_ccdc_archive 'CCDC 2178885'
loop_
_audit_author_name
_audit_author_address
'Logan T. Maltz'
;Texas A and M University
United States of America
;
_audit_update_record             
;
2022-07-21 deposited with the CCDC.	2022-07-25 downloaded from the CCDC.
;
_audit_creation_date             2022-07-21
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C37 H30 Au O P'
_chemical_formula_sum            'C37 H30 Au O P'
_chemical_formula_weight         718.54
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.2905(5)
_cell_length_b                   23.3377(9)
_cell_length_c                   11.8527(4)
_cell_angle_alpha                90
_cell_angle_beta                 112.1470(10)
_cell_angle_gamma                90
_cell_volume                     2892.7(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9959
_cell_measurement_temperature    110.0
_cell_measurement_theta_max      33.98
_cell_measurement_theta_min      2.55
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.170
_exptl_absorpt_correction_T_max  0.3807
_exptl_absorpt_correction_T_min  0.2126
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1055 before and 0.0515 after correction.
The Ratio of minimum to maximum transmission is 0.5556.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.650
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1416
_exptl_crystal_size_max          0.246
_exptl_crystal_size_mid          0.229
_exptl_crystal_size_min          0.148
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0438
_diffrn_reflns_av_unetI/netI     0.0249
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            79813
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.579
_diffrn_reflns_theta_min         2.050
_diffrn_ambient_temperature      110.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7117
_reflns_number_total             8117
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       'SAINT V8.38A (Bruker, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.919
_refine_diff_density_min         -1.530
_refine_diff_density_rms         0.113
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     365
_refine_ls_number_reflns         8117
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0278
_refine_ls_R_factor_gt           0.0222
_refine_ls_restrained_S_all      1.083
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+5.4033P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0434
_refine_ls_wR_factor_ref         0.0444
_refine_special_details          ?
_olex2_refinement_description    
;
1.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11), C12(H12),
 C14(H14), C15(H15), C16(H16), C17(H17), C18(H18), C20(H20), C21(H21), C22(H22),
  C23(H23), C24(H24), C26(H26), C27(H27), C28(H28), C29(H29), C30(H30),
 C33(H33), C34(H34), C35(H35), C36(H36), C37(H37)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.37417(2) 0.36026(2) 0.58264(2) 0.01404(3) Uani 1 1 d . . . . .
P1 P 0.40909(5) 0.41975(3) 0.74662(5) 0.01229(11) Uani 1 1 d . . . . .
O1 O 0.16391(17) 0.44288(7) 0.61106(16) 0.0152(3) Uani 1 1 d . . . . .
H1 H 0.136(3) 0.4433(15) 0.547(3) 0.031(10) Uiso 1 1 d . . . . .
C1 C 0.3153(2) 0.40377(9) 0.8409(2) 0.0119(4) Uani 1 1 d . . . . .
C2 C 0.1809(2) 0.39922(10) 0.7972(2) 0.0136(4) Uani 1 1 d . . . . .
C3 C 0.1236(2) 0.38225(11) 0.8779(2) 0.0169(5) Uani 1 1 d . . . . .
H3 H 0.033083 0.379185 0.848676 0.020 Uiso 1 1 calc R U . . .
C4 C 0.1944(2) 0.36980(10) 0.9988(2) 0.0189(5) Uani 1 1 d . . . . .
H4 H 0.153005 0.357420 1.050987 0.023 Uiso 1 1 calc R U . . .
C5 C 0.3257(2) 0.37549(10) 1.0431(2) 0.0176(5) Uani 1 1 d . . . . .
H5 H 0.375261 0.367981 1.126418 0.021 Uiso 1 1 calc R U . . .
C6 C 0.3848(2) 0.39228(10) 0.9648(2) 0.0143(4) Uani 1 1 d . . . . .
H6 H 0.475251 0.396142 0.995933 0.017 Uiso 1 1 calc R U . . .
C7 C -0.0197(2) 0.44966(10) 0.6673(2) 0.0148(4) Uani 1 1 d . . . . .
C8 C 0.0015(2) 0.50858(10) 0.6819(2) 0.0175(5) Uani 1 1 d . . . . .
H8 H 0.080273 0.524063 0.684286 0.021 Uiso 1 1 calc R U . . .
C9 C -0.0913(3) 0.54495(11) 0.6929(2) 0.0245(6) Uani 1 1 d . . . . .
H9 H -0.075717 0.585009 0.702482 0.029 Uiso 1 1 calc R U . . .
C10 C -0.2064(3) 0.52275(12) 0.6899(2) 0.0266(6) Uani 1 1 d . . . . .
H10 H -0.269753 0.547489 0.697600 0.032 Uiso 1 1 calc R U . . .
C11 C -0.2285(3) 0.46433(12) 0.6755(2) 0.0240(5) Uani 1 1 d . . . . .
H11 H -0.307274 0.448963 0.673344 0.029 Uiso 1 1 calc R U . . .
C12 C -0.1360(2) 0.42816(11) 0.6642(2) 0.0187(5) Uani 1 1 d . . . . .
H12 H -0.152211 0.388166 0.654093 0.022 Uiso 1 1 calc R U . . .
C13 C 0.0435(2) 0.35556(10) 0.5922(2) 0.0143(4) Uani 1 1 d . . . . .
C14 C 0.1047(2) 0.30312(10) 0.6312(2) 0.0184(5) Uani 1 1 d . . . . .
H14 H 0.174997 0.300859 0.707047 0.022 Uiso 1 1 calc R U . . .
C15 C 0.0641(3) 0.25425(11) 0.5603(2) 0.0232(5) Uani 1 1 d . . . . .
H15 H 0.106065 0.218747 0.588240 0.028 Uiso 1 1 calc R U . . .
C16 C -0.0373(3) 0.25701(11) 0.4491(3) 0.0237(5) Uani 1 1 d . . . . .
H16 H -0.065833 0.223424 0.401197 0.028 Uiso 1 1 calc R U . . .
C17 C -0.0968(3) 0.30887(11) 0.4082(2) 0.0228(5) Uani 1 1 d . . . . .
H17 H -0.165110 0.311102 0.331058 0.027 Uiso 1 1 calc R U . . .
C18 C -0.0574(2) 0.35775(11) 0.4791(2) 0.0192(5) Uani 1 1 d . . . . .
H18 H -0.099520 0.393126 0.450286 0.023 Uiso 1 1 calc R U . . .
C19 C 0.3956(2) 0.49645(10) 0.7189(2) 0.0127(4) Uani 1 1 d . . . . .
C20 C 0.3491(2) 0.53258(10) 0.7860(2) 0.0155(4) Uani 1 1 d . . . . .
H20 H 0.320069 0.516986 0.845111 0.019 Uiso 1 1 calc R U . . .
C21 C 0.3449(2) 0.59137(10) 0.7669(2) 0.0172(5) Uani 1 1 d . . . . .
H21 H 0.312278 0.615891 0.812378 0.021 Uiso 1 1 calc R U . . .
C22 C 0.3882(2) 0.61436(11) 0.6815(2) 0.0188(5) Uani 1 1 d . . . . .
H22 H 0.385743 0.654608 0.668791 0.023 Uiso 1 1 calc R U . . .
C23 C 0.4350(2) 0.57857(11) 0.6148(2) 0.0197(5) Uani 1 1 d . . . . .
H23 H 0.465330 0.594312 0.556774 0.024 Uiso 1 1 calc R U . . .
C24 C 0.4378(2) 0.51964(10) 0.6327(2) 0.0170(5) Uani 1 1 d . . . . .
H24 H 0.468569 0.495140 0.585760 0.020 Uiso 1 1 calc R U . . .
C25 C 0.5769(2) 0.41354(10) 0.8508(2) 0.0143(4) Uani 1 1 d . . . . .
C26 C 0.6498(2) 0.46072(10) 0.9113(2) 0.0167(5) Uani 1 1 d . . . . .
H26 H 0.611193 0.497486 0.902565 0.020 Uiso 1 1 calc R U . . .
C27 C 0.7782(2) 0.45399(11) 0.9840(2) 0.0199(5) Uani 1 1 d . . . . .
H27 H 0.827431 0.486345 1.023523 0.024 Uiso 1 1 calc R U . . .
C28 C 0.8348(2) 0.40052(12) 0.9993(2) 0.0239(5) Uani 1 1 d . . . . .
H28 H 0.922260 0.396086 1.050660 0.029 Uiso 1 1 calc R U . . .
C29 C 0.7640(3) 0.35330(12) 0.9396(2) 0.0246(5) Uani 1 1 d . . . . .
H29 H 0.802674 0.316519 0.949595 0.030 Uiso 1 1 calc R U . . .
C30 C 0.6359(2) 0.36027(11) 0.8649(2) 0.0192(5) Uani 1 1 d . . . . .
H30 H 0.587916 0.328092 0.822806 0.023 Uiso 1 1 calc R U . . .
C31 C 0.0899(2) 0.41116(10) 0.6647(2) 0.0129(4) Uani 1 1 d . . . . .
C32 C 0.3440(2) 0.30902(10) 0.4348(2) 0.0168(5) Uani 1 1 d . . . . .
C33 C 0.2204(3) 0.30125(11) 0.3464(2) 0.0214(5) Uani 1 1 d . . . . .
H33 H 0.149770 0.317987 0.359234 0.026 Uiso 1 1 calc R U . . .
C34 C 0.1983(3) 0.26967(11) 0.2403(2) 0.0286(6) Uani 1 1 d . . . . .
H34 H 0.113620 0.265090 0.182297 0.034 Uiso 1 1 calc R U . . .
C35 C 0.2999(4) 0.24504(12) 0.2198(3) 0.0338(7) Uani 1 1 d . . . . .
H35 H 0.285585 0.224308 0.146853 0.041 Uiso 1 1 calc R U . . .
C36 C 0.4222(3) 0.25079(11) 0.3061(3) 0.0296(6) Uani 1 1 d . . . . .
H36 H 0.491942 0.233353 0.292900 0.036 Uiso 1 1 calc R U . . .
C37 C 0.4442(3) 0.28209(10) 0.4126(2) 0.0209(5) Uani 1 1 d . . . . .
H37 H 0.528923 0.285205 0.471285 0.025 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.2985(6) . ?
Au1 H1 3.22(3) . ?
Au1 C32 2.041(2) . ?
P1 C1 1.844(2) . ?
P1 C19 1.816(2) . ?
P1 C25 1.837(2) . ?
O1 H1 0.70(3) . ?
O1 C31 1.432(3) . ?
C1 C2 1.410(3) . ?
C1 C6 1.405(3) . ?
C2 C3 1.398(3) . ?
C2 C31 1.544(3) . ?
C3 H3 0.9500 . ?
C3 C4 1.384(3) . ?
C4 H4 0.9500 . ?
C4 C5 1.380(3) . ?
C5 H5 0.9500 . ?
C5 C6 1.388(3) . ?
C6 H6 0.9500 . ?
C7 C8 1.395(3) . ?
C7 C12 1.393(3) . ?
C7 C31 1.539(3) . ?
C8 H8 0.9500 . ?
C8 C9 1.392(4) . ?
C9 H9 0.9500 . ?
C9 C10 1.387(4) . ?
C10 H10 0.9500 . ?
C10 C11 1.385(4) . ?
C11 H11 0.9500 . ?
C11 C12 1.389(3) . ?
C12 H12 0.9500 . ?
C13 C14 1.396(3) . ?
C13 C18 1.394(3) . ?
C13 C31 1.535(3) . ?
C14 H14 0.9500 . ?
C14 C15 1.388(3) . ?
C15 H15 0.9500 . ?
C15 C16 1.383(4) . ?
C16 H16 0.9500 . ?
C16 C17 1.380(4) . ?
C17 H17 0.9500 . ?
C17 C18 1.387(3) . ?
C18 H18 0.9500 . ?
C19 C20 1.392(3) . ?
C19 C24 1.389(3) . ?
C20 H20 0.9500 . ?
C20 C21 1.389(3) . ?
C21 H21 0.9500 . ?
C21 C22 1.388(3) . ?
C22 H22 0.9500 . ?
C22 C23 1.385(4) . ?
C23 H23 0.9500 . ?
C23 C24 1.390(3) . ?
C24 H24 0.9500 . ?
C25 C26 1.399(3) . ?
C25 C30 1.390(3) . ?
C26 H26 0.9500 . ?
C26 C27 1.388(3) . ?
C27 H27 0.9500 . ?
C27 C28 1.383(4) . ?
C28 H28 0.9500 . ?
C28 C29 1.389(4) . ?
C29 H29 0.9500 . ?
C29 C30 1.392(3) . ?
C30 H30 0.9500 . ?
C32 C33 1.406(4) . ?
C32 C37 1.403(3) . ?
C33 H33 0.9500 . ?
C33 C34 1.397(4) . ?
C34 H34 0.9500 . ?
C34 C35 1.384(5) . ?
C35 H35 0.9500 . ?
C35 C36 1.380(5) . ?
C36 H36 0.9500 . ?
C36 C37 1.397(4) . ?
C37 H37 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 H1 67.3(6) . . ?
C32 Au1 P1 178.65(7) . . ?
C32 Au1 H1 112.4(6) . . ?
C1 P1 Au1 115.82(7) . . ?
C19 P1 Au1 117.80(7) . . ?
C19 P1 C1 106.32(10) . . ?
C19 P1 C25 101.20(11) . . ?
C25 P1 Au1 109.01(7) . . ?
C25 P1 C1 105.02(10) . . ?
C31 O1 H1 112(3) . . ?
C2 C1 P1 125.23(17) . . ?
C6 C1 P1 116.70(17) . . ?
C6 C1 C2 118.0(2) . . ?
C1 C2 C31 124.8(2) . . ?
C3 C2 C1 118.8(2) . . ?
C3 C2 C31 116.4(2) . . ?
C2 C3 H3 118.9 . . ?
C4 C3 C2 122.1(2) . . ?
C4 C3 H3 118.9 . . ?
C3 C4 H4 120.3 . . ?
C5 C4 C3 119.5(2) . . ?
C5 C4 H4 120.3 . . ?
C4 C5 H5 120.3 . . ?
C4 C5 C6 119.4(2) . . ?
C6 C5 H5 120.3 . . ?
C1 C6 H6 118.9 . . ?
C5 C6 C1 122.2(2) . . ?
C5 C6 H6 118.9 . . ?
C8 C7 C31 118.4(2) . . ?
C12 C7 C8 118.3(2) . . ?
C12 C7 C31 123.1(2) . . ?
C7 C8 H8 119.6 . . ?
C9 C8 C7 120.8(2) . . ?
C9 C8 H8 119.6 . . ?
C8 C9 H9 120.0 . . ?
C10 C9 C8 120.1(2) . . ?
C10 C9 H9 120.0 . . ?
C9 C10 H10 120.2 . . ?
C11 C10 C9 119.6(2) . . ?
C11 C10 H10 120.2 . . ?
C10 C11 H11 119.9 . . ?
C10 C11 C12 120.2(3) . . ?
C12 C11 H11 119.9 . . ?
C7 C12 H12 119.5 . . ?
C11 C12 C7 121.0(2) . . ?
C11 C12 H12 119.5 . . ?
C14 C13 C31 122.2(2) . . ?
C18 C13 C14 118.3(2) . . ?
C18 C13 C31 119.3(2) . . ?
C13 C14 H14 119.7 . . ?
C15 C14 C13 120.7(2) . . ?
C15 C14 H14 119.7 . . ?
C14 C15 H15 119.8 . . ?
C16 C15 C14 120.3(2) . . ?
C16 C15 H15 119.8 . . ?
C15 C16 H16 120.2 . . ?
C17 C16 C15 119.6(2) . . ?
C17 C16 H16 120.2 . . ?
C16 C17 H17 119.8 . . ?
C16 C17 C18 120.4(2) . . ?
C18 C17 H17 119.8 . . ?
C13 C18 H18 119.6 . . ?
C17 C18 C13 120.8(2) . . ?
C17 C18 H18 119.6 . . ?
C20 C19 P1 121.18(17) . . ?
C24 C19 P1 119.25(17) . . ?
C24 C19 C20 119.5(2) . . ?
C19 C20 H20 119.9 . . ?
C21 C20 C19 120.2(2) . . ?
C21 C20 H20 119.9 . . ?
C20 C21 H21 120.0 . . ?
C22 C21 C20 120.1(2) . . ?
C22 C21 H21 120.0 . . ?
C21 C22 H22 120.0 . . ?
C23 C22 C21 119.9(2) . . ?
C23 C22 H22 120.0 . . ?
C22 C23 H23 120.0 . . ?
C22 C23 C24 120.1(2) . . ?
C24 C23 H23 120.0 . . ?
C19 C24 C23 120.2(2) . . ?
C19 C24 H24 119.9 . . ?
C23 C24 H24 119.9 . . ?
C26 C25 P1 122.72(18) . . ?
C30 C25 P1 118.49(18) . . ?
C30 C25 C26 118.7(2) . . ?
C25 C26 H26 119.9 . . ?
C27 C26 C25 120.2(2) . . ?
C27 C26 H26 119.9 . . ?
C26 C27 H27 119.8 . . ?
C28 C27 C26 120.5(2) . . ?
C28 C27 H27 119.8 . . ?
C27 C28 H28 120.0 . . ?
C27 C28 C29 120.0(2) . . ?
C29 C28 H28 120.0 . . ?
C28 C29 H29 120.3 . . ?
C28 C29 C30 119.5(2) . . ?
C30 C29 H29 120.3 . . ?
C25 C30 C29 121.1(2) . . ?
C25 C30 H30 119.4 . . ?
C29 C30 H30 119.4 . . ?
O1 C31 C2 105.60(18) . . ?
O1 C31 C7 108.38(18) . . ?
O1 C31 C13 108.77(18) . . ?
C7 C31 C2 108.43(18) . . ?
C13 C31 C2 111.89(18) . . ?
C13 C31 C7 113.41(18) . . ?
C33 C32 Au1 120.85(18) . . ?
C37 C32 Au1 122.56(19) . . ?
C37 C32 C33 116.5(2) . . ?
C32 C33 H33 119.0 . . ?
C34 C33 C32 122.0(3) . . ?
C34 C33 H33 119.0 . . ?
C33 C34 H34 120.0 . . ?
C35 C34 C33 119.9(3) . . ?
C35 C34 H34 120.0 . . ?
C34 C35 H35 120.2 . . ?
C36 C35 C34 119.6(2) . . ?
C36 C35 H35 120.2 . . ?
C35 C36 H36 119.8 . . ?
C35 C36 C37 120.5(3) . . ?
C37 C36 H36 119.8 . . ?
C32 C37 H37 119.2 . . ?
C36 C37 C32 121.5(3) . . ?
C36 C37 H37 119.2 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P1 C1 C2 -54.7(2) . . . . ?
Au1 P1 C1 C6 121.72(16) . . . . ?
Au1 P1 C19 C20 145.93(17) . . . . ?
Au1 P1 C19 C24 -36.9(2) . . . . ?
Au1 P1 C25 C26 140.38(17) . . . . ?
Au1 P1 C25 C30 -36.0(2) . . . . ?
Au1 C32 C33 C34 175.48(19) . . . . ?
Au1 C32 C37 C36 -175.01(19) . . . . ?
P1 C1 C2 C3 174.84(18) . . . . ?
P1 C1 C2 C31 -4.6(3) . . . . ?
P1 C1 C6 C5 -175.07(18) . . . . ?
P1 C19 C20 C21 177.17(18) . . . . ?
P1 C19 C24 C23 -176.39(19) . . . . ?
P1 C25 C26 C27 -176.56(18) . . . . ?
P1 C25 C30 C29 177.9(2) . . . . ?
C1 P1 C19 C20 14.1(2) . . . . ?
C1 P1 C19 C24 -168.74(18) . . . . ?
C1 P1 C25 C26 -94.9(2) . . . . ?
C1 P1 C25 C30 88.7(2) . . . . ?
C1 C2 C3 C4 0.0(4) . . . . ?
C1 C2 C31 O1 -16.9(3) . . . . ?
C1 C2 C31 C7 -132.9(2) . . . . ?
C1 C2 C31 C13 101.3(2) . . . . ?
C2 C1 C6 C5 1.6(3) . . . . ?
C2 C3 C4 C5 1.6(4) . . . . ?
C3 C2 C31 O1 163.7(2) . . . . ?
C3 C2 C31 C7 47.7(3) . . . . ?
C3 C2 C31 C13 -78.1(3) . . . . ?
C3 C4 C5 C6 -1.6(4) . . . . ?
C4 C5 C6 C1 -0.1(4) . . . . ?
C6 C1 C2 C3 -1.5(3) . . . . ?
C6 C1 C2 C31 179.0(2) . . . . ?
C7 C8 C9 C10 0.2(4) . . . . ?
C8 C7 C12 C11 -0.2(3) . . . . ?
C8 C7 C31 O1 -32.2(3) . . . . ?
C8 C7 C31 C2 82.0(2) . . . . ?
C8 C7 C31 C13 -153.0(2) . . . . ?
C8 C9 C10 C11 -0.2(4) . . . . ?
C9 C10 C11 C12 0.0(4) . . . . ?
C10 C11 C12 C7 0.2(4) . . . . ?
C12 C7 C8 C9 0.0(3) . . . . ?
C12 C7 C31 O1 152.3(2) . . . . ?
C12 C7 C31 C2 -93.5(3) . . . . ?
C12 C7 C31 C13 31.4(3) . . . . ?
C13 C14 C15 C16 0.6(4) . . . . ?
C14 C13 C18 C17 0.9(4) . . . . ?
C14 C13 C31 O1 99.3(2) . . . . ?
C14 C13 C31 C2 -17.0(3) . . . . ?
C14 C13 C31 C7 -140.0(2) . . . . ?
C14 C15 C16 C17 0.9(4) . . . . ?
C15 C16 C17 C18 -1.5(4) . . . . ?
C16 C17 C18 C13 0.6(4) . . . . ?
C18 C13 C14 C15 -1.5(4) . . . . ?
C18 C13 C31 O1 -75.9(3) . . . . ?
C18 C13 C31 C2 167.9(2) . . . . ?
C18 C13 C31 C7 44.8(3) . . . . ?
C19 P1 C1 C2 78.3(2) . . . . ?
C19 P1 C1 C6 -105.32(18) . . . . ?
C19 P1 C25 C26 15.6(2) . . . . ?
C19 P1 C25 C30 -160.79(19) . . . . ?
C19 C20 C21 C22 -0.6(4) . . . . ?
C20 C19 C24 C23 0.9(4) . . . . ?
C20 C21 C22 C23 0.4(4) . . . . ?
C21 C22 C23 C24 0.5(4) . . . . ?
C22 C23 C24 C19 -1.1(4) . . . . ?
C24 C19 C20 C21 0.0(3) . . . . ?
C25 P1 C1 C2 -174.99(19) . . . . ?
C25 P1 C1 C6 1.4(2) . . . . ?
C25 P1 C19 C20 -95.4(2) . . . . ?
C25 P1 C19 C24 81.8(2) . . . . ?
C25 C26 C27 C28 -1.2(4) . . . . ?
C26 C25 C30 C29 1.4(4) . . . . ?
C26 C27 C28 C29 1.4(4) . . . . ?
C27 C28 C29 C30 -0.2(4) . . . . ?
C28 C29 C30 C25 -1.2(4) . . . . ?
C30 C25 C26 C27 -0.2(3) . . . . ?
C31 C2 C3 C4 179.4(2) . . . . ?
C31 C7 C8 C9 -175.8(2) . . . . ?
C31 C7 C12 C11 175.4(2) . . . . ?
C31 C13 C14 C15 -176.7(2) . . . . ?
C31 C13 C18 C17 176.3(2) . . . . ?
C32 C33 C34 C35 -0.1(4) . . . . ?
C33 C32 C37 C36 2.0(4) . . . . ?
C33 C34 C35 C36 1.5(4) . . . . ?
C34 C35 C36 C37 -1.1(4) . . . . ?
C35 C36 C37 C32 -0.7(4) . . . . ?
C37 C32 C33 C34 -1.6(4) . . . . ?

# end Validation Reply Form
_olex2_submission_special_instructions 'No special instructions were received'
# start Validation Reply Form
_vrf_PLAT420_ltm_auph05052022_0ma_a 
;
PROBLEM: D-H Bond Without Acceptor  O1       --H1       .     Please Check 
RESPONSE: Au1 is intended to serve as the hydrogen bond acceptor, though the 
Au1-H1 distance falls outside the sum of the van der Waals radii, 
indicating loss of the hydrogen bond. The structure has been checked
 to verify that there is no other hydrogen bond acceptor present.
;
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ltm_auph_revision_cold2_retryagain
_database_code_depnum_ccdc_archive 'CCDC 2191898'
loop_
_audit_author_name
_audit_author_address
'Logan T. Maltz'
;Texas A and M University
United States of America
;
_audit_update_record             
;
2022-07-21 deposited with the CCDC.	2022-07-25 downloaded from the CCDC.
;
_audit_creation_date             2022-07-21
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C37 H30 Au O P, C0.5 H Cl'
_chemical_formula_sum            'C37.50 H31 Au Cl O P'
_chemical_formula_weight         761.01
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C37 H30 Au1 O1 P1'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'I 1 2/a 1'
_space_group_name_Hall           '-I 2ya'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'

_cell_length_a                   18.9800(3)
_cell_length_b                   10.22910(10)
_cell_length_c                   31.7739(3)
_cell_angle_alpha                90
_cell_angle_beta                 101.4180(10)
_cell_angle_gamma                90
_cell_volume                     6046.76(13)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    32418
_cell_measurement_temperature    110.00(10)
_cell_measurement_theta_max      31.4120
_cell_measurement_theta_min      2.0740
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    5.037
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.66999
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.42.61a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.672
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3000
_exptl_crystal_size_max          0.275
_exptl_crystal_size_mid          0.249
_exptl_crystal_size_min          0.083
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0551
_diffrn_reflns_av_unetI/netI     0.0290
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.952
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       48
_diffrn_reflns_limit_l_min       -48
_diffrn_reflns_number            125551
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.952
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.158
_diffrn_reflns_theta_min         2.096
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      110.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.952
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -97.14 153.86   1.00   10.00    --  -35.80  73.83  54.22  251
  2  ω    -97.14 153.86   1.00   10.00    --  -35.80  73.83-145.78  251
  3  ω    -97.14 153.86   1.00   10.00    --  -35.80  73.83 -65.78  251
  4  ω    -97.14 153.86   1.00   10.00    --  -35.80  73.83 -25.78  251
  5  ω    -86.89 164.11   1.00   10.00    --  -25.56  73.83  94.22  251
  6  ω    -86.89 164.11   1.00   10.00    --  -25.56  73.83-105.78  251
  7  ω    -97.14 153.86   1.00   10.00    --  -35.80  73.83 174.22  251
  8  ω    -97.14 153.86   1.00   10.00    --  -35.80  73.83  14.22  251
;
_diffrn_measurement_device       'abstract diffractometer'
_diffrn_measurement_device_type  
'Saxi-CrysAlisPro-abstract goniometer imported SAXI images'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0162268000
_diffrn_orient_matrix_UB_12      -0.0626041000
_diffrn_orient_matrix_UB_13      -0.0009114000
_diffrn_orient_matrix_UB_21      0.0342749000
_diffrn_orient_matrix_UB_22      -0.0290043000
_diffrn_orient_matrix_UB_23      0.0069121000
_diffrn_orient_matrix_UB_31      -0.0036977000
_diffrn_orient_matrix_UB_32      0.0066010000
_diffrn_orient_matrix_UB_33      0.0217026000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7709
_reflns_number_total             10969
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.42.61a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.61a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.61a (Rigaku OD, 2022)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.214
_refine_diff_density_min         -1.881
_refine_diff_density_rms         0.109
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     389
_refine_ls_number_reflns         10969
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0656
_refine_ls_R_factor_gt           0.0330
_refine_ls_restrained_S_all      1.059
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0315P)²+15.3664P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0696
_refine_ls_wR_factor_ref         0.0831
_refine_special_details          ?
_olex2_refinement_description    
;
1. Restrained distances
 Cl1A-C38 \\sim C38-Cl1B
 with sigma of 0.02
2. Uiso/Uaniso restraints and constraints
Cl1A \\sim Cl1B: within 2A with sigma of 0.02 and sigma for terminal atoms of
0.04 within 2A
3. Others
 Sof(Cl1B)=1-FVAR(1)
 Sof(Cl1A)=FVAR(1)
 Fixed Sof: H38A(0.5) H38B(0.5)
4.a Secondary CH2 refined with riding coordinates:
 C38(H38A,H38B)
4.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11), C12(H12),
 C14(H14), C15(H15), C16(H16), C17(H17), C18(H18), C20(H20), C21(H21), C22(H22),
  C23(H23), C24(H24), C26(H26), C27(H27), C28(H28), C29(H29), C30(H30),
 C33(H33), C34(H34), C35(H35), C36(H36), C37(H37)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.51478(2) 0.27281(2) 0.33916(2) 0.04153(5) Uani 1 1 d . . . . .
P1 P 0.59216(5) 0.40722(8) 0.38501(3) 0.03944(18) Uani 1 1 d . . . . .
O1 O 0.65609(17) 0.1582(3) 0.40427(9) 0.0488(6) Uani 1 1 d . . . . .
H1 H 0.622(2) 0.139(4) 0.3912(13) 0.045(13) Uiso 1 1 d . . . . .
C1 C 0.68688(18) 0.4202(3) 0.37921(10) 0.0410(7) Uani 1 1 d . . . . .
C2 C 0.73284(19) 0.3122(3) 0.37606(10) 0.0426(7) Uani 1 1 d . . . . .
C3 C 0.80114(19) 0.3384(3) 0.36798(11) 0.0463(8) Uani 1 1 d . . . . .
H3 H 0.831969 0.267177 0.365160 0.056 Uiso 1 1 calc R U . . .
C4 C 0.82576(19) 0.4654(4) 0.36390(11) 0.0473(8) Uani 1 1 d . . . . .
H4 H 0.872407 0.479757 0.358171 0.057 Uiso 1 1 calc R U . . .
C5 C 0.78194(19) 0.5694(3) 0.36823(11) 0.0474(8) Uani 1 1 d . . . . .
H5 H 0.798590 0.656398 0.366301 0.057 Uiso 1 1 calc R U . . .
C6 C 0.71313(19) 0.5467(3) 0.37544(11) 0.0440(8) Uani 1 1 d . . . . .
H6 H 0.682948 0.619210 0.377893 0.053 Uiso 1 1 calc R U . . .
C7 C 0.7771(2) 0.0939(3) 0.40555(11) 0.0474(8) Uani 1 1 d . . . . .
C8 C 0.7935(2) 0.1135(4) 0.44988(13) 0.0577(10) Uani 1 1 d . . . . .
H8 H 0.762419 0.164529 0.463307 0.069 Uiso 1 1 calc R U . . .
C9 C 0.8553(3) 0.0588(4) 0.47455(15) 0.0695(13) Uani 1 1 d . . . . .
H9 H 0.866707 0.074253 0.504614 0.083 Uiso 1 1 calc R U . . .
C10 C 0.9005(3) -0.0184(4) 0.45542(17) 0.0688(12) Uani 1 1 d . . . . .
H10 H 0.942571 -0.056055 0.472252 0.083 Uiso 1 1 calc R U . . .
C11 C 0.8834(2) -0.0397(4) 0.41158(15) 0.0607(10) Uani 1 1 d . . . . .
H11 H 0.913684 -0.093308 0.398351 0.073 Uiso 1 1 calc R U . . .
C12 C 0.8226(2) 0.0164(4) 0.38674(13) 0.0537(9) Uani 1 1 d . . . . .
H12 H 0.811907 0.001732 0.356626 0.064 Uiso 1 1 calc R U . . .
C13 C 0.68536(18) 0.1054(3) 0.33528(11) 0.0434(7) Uani 1 1 d . . . . .
C14 C 0.6832(2) 0.1736(4) 0.29672(12) 0.0508(9) Uani 1 1 d . . . . .
H14 H 0.699965 0.261191 0.297537 0.061 Uiso 1 1 calc R U . . .
C15 C 0.6569(2) 0.1149(4) 0.25757(12) 0.0545(10) Uani 1 1 d . . . . .
H15 H 0.655822 0.162681 0.231802 0.065 Uiso 1 1 calc R U . . .
C16 C 0.63222(19) -0.0122(4) 0.25553(12) 0.0511(9) Uani 1 1 d . . . . .
H16 H 0.614019 -0.051643 0.228495 0.061 Uiso 1 1 calc R U . . .
C17 C 0.63412(18) -0.0824(4) 0.29327(12) 0.0483(8) Uani 1 1 d . . . . .
H17 H 0.617565 -0.170221 0.292122 0.058 Uiso 1 1 calc R U . . .
C18 C 0.66039(17) -0.0233(3) 0.33268(11) 0.0448(8) Uani 1 1 d . . . . .
H18 H 0.661354 -0.071473 0.358352 0.054 Uiso 1 1 calc R U . . .
C19 C 0.59011(17) 0.3819(3) 0.44142(9) 0.0352(6) Uani 1 1 d . . . . .
C20 C 0.64614(17) 0.4174(3) 0.47452(10) 0.0395(7) Uani 1 1 d . . . . .
H20 H 0.690207 0.447383 0.468101 0.047 Uiso 1 1 calc R U . . .
C21 C 0.63816(17) 0.4094(3) 0.51706(10) 0.0399(7) Uani 1 1 d . . . . .
H21 H 0.676650 0.434177 0.539566 0.048 Uiso 1 1 calc R U . . .
C22 C 0.57411(17) 0.3654(3) 0.52657(10) 0.0381(6) Uani 1 1 d . . . . .
H22 H 0.568573 0.360433 0.555597 0.046 Uiso 1 1 calc R U . . .
C23 C 0.51812(17) 0.3285(3) 0.49379(9) 0.0383(7) Uani 1 1 d . . . . .
H23 H 0.474378 0.297515 0.500386 0.046 Uiso 1 1 calc R U . . .
C24 C 0.52580(17) 0.3367(3) 0.45126(10) 0.0382(7) Uani 1 1 d . . . . .
H24 H 0.487256 0.311464 0.428846 0.046 Uiso 1 1 calc R U . . .
C25 C 0.55738(18) 0.5754(3) 0.37732(11) 0.0430(7) Uani 1 1 d . . . . .
C26 C 0.5666(2) 0.6674(4) 0.41064(12) 0.0600(11) Uani 1 1 d . . . . .
H26 H 0.591926 0.643554 0.438424 0.072 Uiso 1 1 calc R U . . .
C27 C 0.5390(3) 0.7934(4) 0.40351(15) 0.0660(12) Uani 1 1 d . . . . .
H27 H 0.545790 0.855151 0.426281 0.079 Uiso 1 1 calc R U . . .
C28 C 0.5016(2) 0.8283(4) 0.36314(16) 0.0627(11) Uani 1 1 d . . . . .
H28 H 0.482247 0.913855 0.358172 0.075 Uiso 1 1 calc R U . . .
C29 C 0.4927(3) 0.7385(5) 0.3302(2) 0.0753(16) Uani 1 1 d . . . . .
H29 H 0.467528 0.762784 0.302370 0.090 Uiso 1 1 calc R U . . .
C30 C 0.5202(2) 0.6122(4) 0.33727(14) 0.0608(11) Uani 1 1 d . . . . .
H30 H 0.513230 0.550968 0.314332 0.073 Uiso 1 1 calc R U . . .
C31 C 0.71200(19) 0.1672(3) 0.37944(11) 0.0444(8) Uani 1 1 d . . . . .
C32 C 0.43849(18) 0.1622(3) 0.30071(9) 0.0370(6) Uani 1 1 d . . . . .
C33 C 0.4539(2) 0.0611(4) 0.27513(13) 0.0573(10) Uani 1 1 d . . . . .
H33 H 0.502810 0.039553 0.275721 0.069 Uiso 1 1 calc R U . . .
C34 C 0.4007(2) -0.0098(4) 0.24865(13) 0.0606(11) Uani 1 1 d . . . . .
H34 H 0.413799 -0.078450 0.231580 0.073 Uiso 1 1 calc R U . . .
C35 C 0.32956(18) 0.0176(3) 0.24672(11) 0.0417(7) Uani 1 1 d . . . . .
H35 H 0.293144 -0.031973 0.228816 0.050 Uiso 1 1 calc R U . . .
C36 C 0.3123(2) 0.1173(4) 0.27103(17) 0.0686(13) Uani 1 1 d . . . . .
H36 H 0.263281 0.139443 0.269648 0.082 Uiso 1 1 calc R U . . .
C37 C 0.3658(2) 0.1868(4) 0.29784(17) 0.0715(15) Uani 1 1 d . . . . .
H37 H 0.352028 0.254494 0.315050 0.086 Uiso 1 1 calc R U . . .
C38 C 0.750000 -0.1820(7) 0.500000 0.108(3) Uani 1 2 d DS T P . .
H38A H 0.789009 -0.124991 0.515215 0.130 Uiso 0.5 1 calc R U P A 1
H38B H 0.710990 -0.124995 0.484785 0.130 Uiso 0.5 1 calc R U P A 1
Cl1A Cl 0.78210(13) -0.27464(15) 0.46331(8) 0.0996(9) Uani 0.818(6) 1 d D . P B
1
Cl1B Cl 0.8127(14) -0.1988(16) 0.5485(4) 0.30(2) Uani 0.182(6) 1 d D . P B -1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.3071(9) . ?
Au1 H1 2.72(4) . ?
Au1 C32 2.042(3) . ?
P1 C1 1.848(3) . ?
P1 C19 1.819(3) . ?
P1 C25 1.842(4) . ?
O1 H1 0.73(4) . ?
O1 C31 1.445(4) . ?
C1 C2 1.423(5) . ?
C1 C6 1.400(4) . ?
C2 C3 1.396(4) . ?
C2 C31 1.544(5) . ?
C3 H3 0.9500 . ?
C3 C4 1.395(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.375(5) . ?
C5 H5 0.9500 . ?
C5 C6 1.390(4) . ?
C6 H6 0.9500 . ?
C7 C8 1.396(5) . ?
C7 C12 1.392(5) . ?
C7 C31 1.540(5) . ?
C8 H8 0.9500 . ?
C8 C9 1.393(6) . ?
C9 H9 0.9500 . ?
C9 C10 1.391(7) . ?
C10 H10 0.9500 . ?
C10 C11 1.384(7) . ?
C11 H11 0.9500 . ?
C11 C12 1.387(6) . ?
C12 H12 0.9500 . ?
C13 C14 1.403(4) . ?
C13 C18 1.396(5) . ?
C13 C31 1.531(5) . ?
C14 H14 0.9500 . ?
C14 C15 1.382(6) . ?
C15 H15 0.9500 . ?
C15 C16 1.379(6) . ?
C16 H16 0.9500 . ?
C16 C17 1.392(5) . ?
C17 H17 0.9500 . ?
C17 C18 1.391(5) . ?
C18 H18 0.9500 . ?
C19 C20 1.388(5) . ?
C19 C24 1.397(4) . ?
C20 H20 0.9500 . ?
C20 C21 1.392(4) . ?
C21 H21 0.9500 . ?
C21 C22 1.385(4) . ?
C22 H22 0.9500 . ?
C22 C23 1.385(5) . ?
C23 H23 0.9500 . ?
C23 C24 1.390(4) . ?
C24 H24 0.9500 . ?
C25 C26 1.401(5) . ?
C25 C30 1.380(5) . ?
C26 H26 0.9500 . ?
C26 C27 1.392(6) . ?
C27 H27 0.9500 . ?
C27 C28 1.384(7) . ?
C28 H28 0.9500 . ?
C28 C29 1.379(7) . ?
C29 H29 0.9500 . ?
C29 C30 1.395(6) . ?
C30 H30 0.9500 . ?
C32 C33 1.382(5) . ?
C32 C37 1.388(5) . ?
C33 H33 0.9500 . ?
C33 C34 1.385(5) . ?
C34 H34 0.9500 . ?
C34 C35 1.369(5) . ?
C35 H35 0.9500 . ?
C35 C36 1.358(5) . ?
C36 H36 0.9500 . ?
C36 C37 1.385(6) . ?
C37 H37 0.9500 . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C38 Cl1A 1.706(4) 2_656 ?
C38 Cl1A 1.706(4) . ?
C38 Cl1B 1.758(16) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 H1 67.1(9) . . ?
C32 Au1 P1 174.54(8) . . ?
C32 Au1 H1 116.1(9) . . ?
C1 P1 Au1 119.35(11) . . ?
C19 P1 Au1 113.72(10) . . ?
C19 P1 C1 108.64(15) . . ?
C19 P1 C25 100.76(14) . . ?
C25 P1 Au1 107.84(12) . . ?
C25 P1 C1 104.47(14) . . ?
C31 O1 H1 112(3) . . ?
C2 C1 P1 125.0(2) . . ?
C6 C1 P1 116.4(2) . . ?
C6 C1 C2 118.5(3) . . ?
C1 C2 C31 124.9(3) . . ?
C3 C2 C1 117.9(3) . . ?
C3 C2 C31 117.2(3) . . ?
C2 C3 H3 118.8 . . ?
C4 C3 C2 122.4(3) . . ?
C4 C3 H3 118.8 . . ?
C3 C4 H4 120.3 . . ?
C5 C4 C3 119.4(3) . . ?
C5 C4 H4 120.3 . . ?
C4 C5 H5 120.2 . . ?
C4 C5 C6 119.6(3) . . ?
C6 C5 H5 120.2 . . ?
C1 C6 H6 119.0 . . ?
C5 C6 C1 122.1(3) . . ?
C5 C6 H6 119.0 . . ?
C8 C7 C31 118.0(3) . . ?
C12 C7 C8 118.8(4) . . ?
C12 C7 C31 123.1(3) . . ?
C7 C8 H8 119.8 . . ?
C9 C8 C7 120.4(4) . . ?
C9 C8 H8 119.8 . . ?
C8 C9 H9 119.8 . . ?
C10 C9 C8 120.4(4) . . ?
C10 C9 H9 119.8 . . ?
C9 C10 H10 120.4 . . ?
C11 C10 C9 119.2(4) . . ?
C11 C10 H10 120.4 . . ?
C10 C11 H11 119.7 . . ?
C10 C11 C12 120.7(4) . . ?
C12 C11 H11 119.7 . . ?
C7 C12 H12 119.7 . . ?
C11 C12 C7 120.6(4) . . ?
C11 C12 H12 119.7 . . ?
C14 C13 C31 122.8(3) . . ?
C18 C13 C14 117.8(3) . . ?
C18 C13 C31 119.4(3) . . ?
C13 C14 H14 119.6 . . ?
C15 C14 C13 120.9(4) . . ?
C15 C14 H14 119.6 . . ?
C14 C15 H15 119.7 . . ?
C16 C15 C14 120.7(3) . . ?
C16 C15 H15 119.7 . . ?
C15 C16 H16 120.2 . . ?
C15 C16 C17 119.7(4) . . ?
C17 C16 H16 120.2 . . ?
C16 C17 H17 120.2 . . ?
C18 C17 C16 119.7(4) . . ?
C18 C17 H17 120.2 . . ?
C13 C18 H18 119.3 . . ?
C17 C18 C13 121.3(3) . . ?
C17 C18 H18 119.3 . . ?
C20 C19 P1 123.1(2) . . ?
C20 C19 C24 119.3(3) . . ?
C24 C19 P1 117.2(2) . . ?
C19 C20 H20 119.8 . . ?
C19 C20 C21 120.4(3) . . ?
C21 C20 H20 119.8 . . ?
C20 C21 H21 120.0 . . ?
C22 C21 C20 120.0(3) . . ?
C22 C21 H21 120.0 . . ?
C21 C22 H22 120.0 . . ?
C21 C22 C23 120.0(3) . . ?
C23 C22 H22 120.0 . . ?
C22 C23 H23 119.9 . . ?
C22 C23 C24 120.1(3) . . ?
C24 C23 H23 119.9 . . ?
C19 C24 H24 119.9 . . ?
C23 C24 C19 120.1(3) . . ?
C23 C24 H24 119.9 . . ?
C26 C25 P1 122.6(3) . . ?
C30 C25 P1 118.8(3) . . ?
C30 C25 C26 118.6(4) . . ?
C25 C26 H26 119.6 . . ?
C27 C26 C25 120.8(4) . . ?
C27 C26 H26 119.6 . . ?
C26 C27 H27 120.1 . . ?
C28 C27 C26 119.8(4) . . ?
C28 C27 H27 120.1 . . ?
C27 C28 H28 120.1 . . ?
C29 C28 C27 119.7(4) . . ?
C29 C28 H28 120.1 . . ?
C28 C29 H29 119.7 . . ?
C28 C29 C30 120.6(5) . . ?
C30 C29 H29 119.7 . . ?
C25 C30 C29 120.6(4) . . ?
C25 C30 H30 119.7 . . ?
C29 C30 H30 119.7 . . ?
O1 C31 C2 109.0(3) . . ?
O1 C31 C7 105.8(3) . . ?
O1 C31 C13 109.2(3) . . ?
C7 C31 C2 108.4(3) . . ?
C13 C31 C2 112.1(3) . . ?
C13 C31 C7 112.1(3) . . ?
C33 C32 Au1 124.0(3) . . ?
C33 C32 C37 114.9(3) . . ?
C37 C32 Au1 121.1(2) . . ?
C32 C33 H33 118.8 . . ?
C32 C33 C34 122.3(3) . . ?
C34 C33 H33 118.8 . . ?
C33 C34 H34 119.5 . . ?
C35 C34 C33 121.0(3) . . ?
C35 C34 H34 119.5 . . ?
C34 C35 H35 120.8 . . ?
C36 C35 C34 118.4(4) . . ?
C36 C35 H35 120.8 . . ?
C35 C36 H36 119.8 . . ?
C35 C36 C37 120.4(3) . . ?
C37 C36 H36 119.8 . . ?
C32 C37 H37 118.5 . . ?
C36 C37 C32 123.0(3) . . ?
C36 C37 H37 118.5 . . ?
H38A C38 H38B 107.8 . . ?
Cl1A C38 H38A 109.1 . . ?
Cl1A C38 H38A 109.1 2_656 . ?
Cl1A C38 H38B 109.1 . . ?
Cl1A C38 H38B 109.1 2_656 . ?
Cl1A C38 Cl1A 112.5(4) 2_656 . ?
Cl1A C38 Cl1B 67.6(8) 2_656 . ?
Cl1A C38 Cl1B 105.9(6) . . ?
Cl1B C38 H38A 47.1 . . ?
Cl1B C38 H38B 142.8 . . ?
C38 Cl1B H38B 33.8(5) . 2_656 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P1 C1 C2 -49.3(3) . . . . ?
Au1 P1 C1 C6 127.2(2) . . . . ?
Au1 P1 C19 C20 158.1(2) . . . . ?
Au1 P1 C19 C24 -28.5(3) . . . . ?
Au1 P1 C25 C26 148.1(3) . . . . ?
Au1 P1 C25 C30 -31.3(3) . . . . ?
Au1 C32 C33 C34 -178.4(3) . . . . ?
Au1 C32 C37 C36 177.6(4) . . . . ?
P1 C1 C2 C3 174.4(3) . . . . ?
P1 C1 C2 C31 -3.5(5) . . . . ?
P1 C1 C6 C5 -175.9(3) . . . . ?
P1 C19 C20 C21 172.6(3) . . . . ?
P1 C19 C24 C23 -173.2(3) . . . . ?
P1 C25 C26 C27 -179.6(3) . . . . ?
P1 C25 C30 C29 179.7(3) . . . . ?
C1 P1 C19 C20 22.6(3) . . . . ?
C1 P1 C19 C24 -164.0(2) . . . . ?
C1 P1 C25 C26 -84.0(3) . . . . ?
C1 P1 C25 C30 96.7(3) . . . . ?
C1 C2 C3 C4 1.4(5) . . . . ?
C1 C2 C31 O1 -25.4(5) . . . . ?
C1 C2 C31 C7 -140.1(3) . . . . ?
C1 C2 C31 C13 95.6(4) . . . . ?
C2 C1 C6 C5 0.8(5) . . . . ?
C2 C3 C4 C5 0.5(6) . . . . ?
C3 C2 C31 O1 156.7(3) . . . . ?
C3 C2 C31 C7 42.0(4) . . . . ?
C3 C2 C31 C13 -82.3(4) . . . . ?
C3 C4 C5 C6 -1.7(5) . . . . ?
C4 C5 C6 C1 1.1(5) . . . . ?
C6 C1 C2 C3 -2.0(5) . . . . ?
C6 C1 C2 C31 -179.9(3) . . . . ?
C7 C8 C9 C10 -1.4(6) . . . . ?
C8 C7 C12 C11 -0.4(5) . . . . ?
C8 C7 C31 O1 -42.4(4) . . . . ?
C8 C7 C31 C2 74.4(3) . . . . ?
C8 C7 C31 C13 -161.3(3) . . . . ?
C8 C9 C10 C11 0.2(6) . . . . ?
C9 C10 C11 C12 0.9(6) . . . . ?
C10 C11 C12 C7 -0.8(6) . . . . ?
C12 C7 C8 C9 1.5(5) . . . . ?
C12 C7 C31 O1 141.9(3) . . . . ?
C12 C7 C31 C2 -101.3(4) . . . . ?
C12 C7 C31 C13 23.0(4) . . . . ?
C13 C14 C15 C16 0.0(5) . . . . ?
C14 C13 C18 C17 0.0(5) . . . . ?
C14 C13 C31 O1 123.0(3) . . . . ?
C14 C13 C31 C2 2.1(4) . . . . ?
C14 C13 C31 C7 -120.1(3) . . . . ?
C14 C15 C16 C17 -0.3(5) . . . . ?
C15 C16 C17 C18 0.5(5) . . . . ?
C16 C17 C18 C13 -0.3(5) . . . . ?
C18 C13 C14 C15 0.2(5) . . . . ?
C18 C13 C31 O1 -55.5(4) . . . . ?
C18 C13 C31 C2 -176.3(3) . . . . ?
C18 C13 C31 C7 61.5(4) . . . . ?
C19 P1 C1 C2 83.2(3) . . . . ?
C19 P1 C1 C6 -100.3(3) . . . . ?
C19 P1 C25 C26 28.7(3) . . . . ?
C19 P1 C25 C30 -150.7(3) . . . . ?
C19 C20 C21 C22 0.2(5) . . . . ?
C20 C19 C24 C23 0.5(5) . . . . ?
C20 C21 C22 C23 0.4(5) . . . . ?
C21 C22 C23 C24 -0.6(5) . . . . ?
C22 C23 C24 C19 0.1(5) . . . . ?
C24 C19 C20 C21 -0.7(5) . . . . ?
C25 P1 C1 C2 -169.9(3) . . . . ?
C25 P1 C1 C6 6.6(3) . . . . ?
C25 P1 C19 C20 -86.8(3) . . . . ?
C25 P1 C19 C24 86.6(3) . . . . ?
C25 C26 C27 C28 0.4(6) . . . . ?
C26 C25 C30 C29 0.3(6) . . . . ?
C26 C27 C28 C29 -0.7(6) . . . . ?
C27 C28 C29 C30 0.8(7) . . . . ?
C28 C29 C30 C25 -0.6(7) . . . . ?
C30 C25 C26 C27 -0.2(5) . . . . ?
C31 C2 C3 C4 179.4(3) . . . . ?
C31 C7 C8 C9 -174.4(3) . . . . ?
C31 C7 C12 C11 175.3(3) . . . . ?
C31 C13 C14 C15 -178.3(3) . . . . ?
C31 C13 C18 C17 178.5(3) . . . . ?
C32 C33 C34 C35 -0.1(7) . . . . ?
C33 C32 C37 C36 -0.9(7) . . . . ?
C33 C34 C35 C36 0.8(7) . . . . ?
C34 C35 C36 C37 -1.6(7) . . . . ?
C35 C36 C37 C32 1.7(8) . . . . ?
C37 C32 C33 C34 0.1(6) . . . . ?

# end Validation Reply Form
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.400
_oxdiff_exptl_absorpt_empirical_full_min 0.735
# start Validation Reply Form
_vrf_PLAT420_ltm_auph_revision_cold2_retryagain 
;
PROBLEM: D-H Bond Without Acceptor  O1       --H1       .     Please Check 
RESPONSE: Au1 serves as the hydrogen bond acceptor
;
