# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2022

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_platon_pl
_audit_block_doi                 10.5517/ccdc.csd.cc2d1rv2
_database_code_depnum_ccdc_archive 'CCDC 2206234'
loop_
_audit_author_name
_audit_author_address
'Jiawei Lin'
;University of Science and Technology Beijing
China
;
_audit_update_record             
;
2022-09-09 deposited with the CCDC.	2022-11-08 downloaded from the CCDC.
;
_audit_creation_date             2022-09-09
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
#Alert level B: PLAT342_ALERT_3_B Low Bond Precision on C-C Bonds ............... 0.056 Ang.#
#Response: We performed single crystal X-ray diffraction at room temperature (293 K), and discorder is present in the organic cations, resulting in a high thermal temperature factor for the C atoms.#
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'Ag Bi2 Br14, 1.67(Br3), 2(C4 H10 N), 8(C4 H12 N)'
_chemical_formula_sum            'C40 H120 Ag Bi2 Br19 N10 O0.25'
_chemical_formula_weight         2789.57
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   32.453(2)
_cell_length_b                   8.0862(6)
_cell_length_c                   36.082(3)
_cell_angle_alpha                90
_cell_angle_beta                 106.856(3)
_cell_angle_gamma                90
_cell_volume                     9061.9(12)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9893
_cell_measurement_temperature    293
_cell_measurement_theta_max      26.875
_cell_measurement_theta_min      2.344
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    12.496
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    2.045
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             5240
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0974
_diffrn_reflns_av_unetI/netI     0.0732
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       42
_diffrn_reflns_limit_l_min       -42
_diffrn_reflns_number            48211
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        24.998
_diffrn_reflns_theta_max         24.998
_diffrn_reflns_theta_min         2.359
_diffrn_ambient_temperature      293
_diffrn_detector                 'CCD area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'Bruker SMART CCD 1K area detector'
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  Bruker
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'sealed X-ray tube'
_diffrn_source_target            Mo
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5491
_reflns_number_total             7933
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v8.37A (Bruker, 2015)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v8.37A (Bruker, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         2.046
_refine_diff_density_min         -1.497
_refine_diff_density_rms         0.225
_refine_ls_extinction_coef       0.00046(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     257
_refine_ls_number_reflns         7933
_refine_ls_number_restraints     69
_refine_ls_R_factor_all          0.1179
_refine_ls_R_factor_gt           0.0812
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0999P)²+167.2776P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1990
_refine_ls_wR_factor_ref         0.2234
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups, All N(H,H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C4-C3
 1.54 with sigma of 0.02
 C11-C10
 1.54 with sigma of 0.02
 C2-C3
 1.54 with sigma of 0.02
 C10-C9
 1.54 with sigma of 0.02
 C5-C6
 1.54 with sigma of 0.02
 C7-C8
 1.54 with sigma of 0.02
 C14-C15
 1.54 with sigma of 0.02
 C14-C13
 1.54 with sigma of 0.02
3. Rigid bond restraints
 N5, C17, C18, C19, C20
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
N5 \\sim C17 \\sim C18 \\sim C19 \\sim C20: within 2A with sigma of 0.04 and
sigma for terminal atoms of 0.08
Uanis(C17) \\sim Ueq, Uanis(C18) \\sim Ueq, Uanis(C19) \\sim Ueq, Uanis(C20)
\\sim Ueq, Uanis(N5) \\sim Ueq: with sigma of 0.1 and sigma for terminal atoms
of 0.2
Uanis(N4) = Uanis(C16) = Uanis(C15) = Uanis(C14)
Uanis(N4) = Uanis(C16) = Uanis(C15) = Uanis(C14) = Uanis(C13)
Uanis(N1) = Uanis(C4) = Uanis(C3) = Uanis(C2) = Uanis(C1)
Uanis(C9) = Uanis(C10) = Uanis(C11) = Uanis(C12) = Uanis(N3)
5.a Secondary CH2 refined with riding coordinates:
 C14(H14A,H14B), C16(H16A,H16B), C10(H10A,H10B), C11(H11A,H11B), C12(H12A,
 H12B), C6(H6A,H6B), C7(H7A,H7B), C8(H8A,H8B), C2(H2D,H2E), C3(H3D,H3E), C4(H4A,
 H4B), C18(H18A,H18B), C19(H19A,H19B), C20(H20A,H20B)
5.b Me refined with riding coordinates:
 N4(H4C,H4D,H4E), N3(H3A,H3B,H3C), C9(H9A,H9B,H9C), N2(H2A,H2B,H2C), C5(H5A,
 H5B,H5C), N1(H1A,H1B,H1C), C1(H1D,H1E,H1F), N5(H5D,H5E,H5F), C17(H17A,H17B,
 H17C)
5.c Idealised Me refined as rotating group:
 C13(H13A,H13B,H13C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Bi1 Bi 0.28433(2) 0.75705(5) 0.12128(2) 0.0534(2) Uani 1 1 d . . . . .
Ag1 Ag 0.2500 0.2500 0.0000 0.0678(5) Uani 1 2 d S T P . .
Br1 Br 0.37360(7) 0.7000(2) 0.13372(6) 0.0899(6) Uani 1 1 d . . . . .
Br2 Br 0.28433(7) 0.5105(2) 0.17722(5) 0.0825(6) Uani 1 1 d . . . . .
Br3 Br 0.30316(7) 1.01678(19) 0.17675(5) 0.0805(5) Uani 1 1 d . . . . .
Br4 Br 0.28191(7) 0.9876(2) 0.06107(5) 0.0833(6) Uani 1 1 d . . . . .
Br5 Br 0.19462(6) 0.8155(2) 0.10905(5) 0.0776(5) Uani 1 1 d . . . . .
Br6 Br 0.26258(7) 0.51121(19) 0.06226(4) 0.0799(5) Uani 1 1 d . . . . .
Br7 Br 0.17037(7) 0.2072(2) 0.00040(6) 0.0913(6) Uani 1 1 d . . . . .
Br8 Br 0.41714(17) 0.2952(6) 0.22451(13) 0.2135(19) Uani 1 1 d . . . . .
Br9 Br 0.5000 0.2931(5) 0.2500 0.1504(16) Uani 1 2 d S T P . .
Br1A Br 0.18938(7) 0.2270(2) 0.21259(5) 0.0826(6) Uani 1 1 d . . . . .
N4 N 0.2077(11) 0.245(3) 0.1141(10) 0.200(8) Uani 1 1 d . . . . .
H4C H 0.2300 0.3132 0.1179 0.240 Uiso 1 1 calc R . . . .
H4D H 0.2095 0.1894 0.1358 0.240 Uiso 1 1 calc R . . . .
H4E H 0.2079 0.1738 0.0953 0.240 Uiso 1 1 calc R . . . .
C13 C 0.0573(11) 0.235(3) 0.0803(12) 0.200(8) Uani 1 1 d D . . . .
H13A H 0.0683 0.1246 0.0821 0.300 Uiso 1 1 calc GR . . . .
H13B H 0.0355 0.2497 0.0560 0.300 Uiso 1 1 calc GR . . . .
H13C H 0.0451 0.2550 0.1012 0.300 Uiso 1 1 calc GR . . . .
C14 C 0.0936(11) 0.357(3) 0.0830(11) 0.200(8) Uani 1 1 d D . . . .
H14A H 0.0954 0.4421 0.1023 0.240 Uiso 1 1 calc R . . . .
H14B H 0.0927 0.4058 0.0583 0.240 Uiso 1 1 calc R . . . .
C15 C 0.1285(12) 0.225(4) 0.0961(13) 0.200(8) Uani 1 1 d D . . . .
C16 C 0.1699(14) 0.335(4) 0.1035(12) 0.200(8) Uani 1 1 d . . . . .
H16A H 0.1686 0.3968 0.0802 0.240 Uiso 1 1 calc R . . . .
H16B H 0.1703 0.4136 0.1239 0.240 Uiso 1 1 calc R . . . .
N3 N 0.2219(7) 0.829(3) 0.2168(6) 0.139(4) Uani 1 1 d . . . . .
H3A H 0.2444 0.8374 0.2378 0.166 Uiso 1 1 calc R . . . .
H3B H 0.2306 0.7906 0.1972 0.166 Uiso 1 1 calc R . . . .
H3C H 0.2101 0.9287 0.2107 0.166 Uiso 1 1 calc R . . . .
C9 C 0.0826(8) 0.763(3) 0.1534(8) 0.139(4) Uani 1 1 d D . . . .
H9A H 0.0634 0.8524 0.1424 0.208 Uiso 1 1 calc R . . . .
H9B H 0.0899 0.7041 0.1330 0.208 Uiso 1 1 calc R . . . .
H9C H 0.0687 0.6892 0.1668 0.208 Uiso 1 1 calc R . . . .
C10 C 0.1251(8) 0.835(3) 0.1828(7) 0.139(4) Uani 1 1 d D . . . .
H10A H 0.1413 0.9057 0.1704 0.166 Uiso 1 1 calc R . . . .
H10B H 0.1198 0.8906 0.2047 0.166 Uiso 1 1 calc R . . . .
C11 C 0.1445(9) 0.671(3) 0.1925(7) 0.139(4) Uani 1 1 d D . . . .
H11A H 0.1489 0.6167 0.1700 0.166 Uiso 1 1 calc R . . . .
H11B H 0.1270 0.6008 0.2037 0.166 Uiso 1 1 calc R . . . .
C12 C 0.1906(10) 0.718(3) 0.2244(8) 0.139(4) Uani 1 1 d . . . . .
H12A H 0.1835 0.7618 0.2468 0.166 Uiso 1 1 calc R . . . .
H12B H 0.2054 0.6142 0.2324 0.166 Uiso 1 1 calc R . . . .
N2 N 0.3506(8) 1.277(2) 0.1176(9) 0.155(11) Uani 1 1 d . . . . .
H2A H 0.3353 1.2206 0.1301 0.185 Uiso 1 1 calc R . . . .
H2B H 0.3578 1.3752 0.1290 0.185 Uiso 1 1 calc R . . . .
H2C H 0.3350 1.2925 0.0931 0.185 Uiso 1 1 calc R . . . .
C5 C 0.4714(16) 1.281(7) 0.0722(18) 0.31(3) Uani 1 1 d D . . . .
H5A H 0.4961 1.2307 0.0674 0.468 Uiso 1 1 calc R . . . .
H5B H 0.4502 1.3034 0.0480 0.468 Uiso 1 1 calc R . . . .
H5C H 0.4797 1.3827 0.0861 0.468 Uiso 1 1 calc R . . . .
C6 C 0.452(2) 1.164(7) 0.096(2) 0.32(3) Uani 1 1 d D . . . .
H6A H 0.4424 1.0609 0.0829 0.379 Uiso 1 1 calc R . . . .
H6B H 0.4724 1.1414 0.1215 0.379 Uiso 1 1 calc R . . . .
C7 C 0.4179(17) 1.271(6) 0.0982(13) 0.23(2) Uani 1 1 d D . . . .
H7A H 0.4014 1.3014 0.0721 0.278 Uiso 1 1 calc R . . . .
H7B H 0.4298 1.3709 0.1119 0.278 Uiso 1 1 calc R . . . .
C8 C 0.3879(16) 1.190(4) 0.1185(12) 0.194(17) Uani 1 1 d D . . . .
H8A H 0.3795 1.0821 0.1068 0.233 Uiso 1 1 calc R . . . .
H8B H 0.4040 1.1711 0.1453 0.233 Uiso 1 1 calc R . . . .
N1 N 0.1840(9) 0.798(3) 0.0027(8) 0.179(6) Uani 1 1 d . . . . .
H1A H 0.2007 0.7758 -0.0124 0.215 Uiso 1 1 calc R . . . .
H1B H 0.1805 0.9067 0.0037 0.215 Uiso 1 1 calc R . . . .
H1C H 0.1964 0.7594 0.0264 0.215 Uiso 1 1 calc R . . . .
C1 C 0.0453(12) 0.770(3) 0.0133(11) 0.179(6) Uani 1 1 d . . . . .
H1D H 0.0146 0.7664 0.0019 0.268 Uiso 1 1 calc R . . . .
H1E H 0.0536 0.6888 0.0334 0.268 Uiso 1 1 calc R . . . .
H1F H 0.0534 0.8782 0.0240 0.268 Uiso 1 1 calc R . . . .
C2 C 0.0685(10) 0.733(4) -0.0188(10) 0.179(6) Uani 1 1 d D . . . .
H2D H 0.0631 0.6230 -0.0296 0.215 Uiso 1 1 calc R . . . .
H2E H 0.0628 0.8159 -0.0392 0.215 Uiso 1 1 calc R . . . .
C3 C 0.1128(10) 0.752(4) 0.0113(10) 0.179(6) Uani 1 1 d D . . . .
H3D H 0.1172 0.8633 0.0219 0.215 Uiso 1 1 calc R . . . .
H3E H 0.1169 0.6729 0.0322 0.215 Uiso 1 1 calc R . . . .
C4 C 0.1412(11) 0.717(4) -0.0136(11) 0.179(6) Uani 1 1 d D . . . .
H4A H 0.1278 0.7573 -0.0396 0.215 Uiso 1 1 calc R . . . .
H4B H 0.1450 0.5981 -0.0151 0.215 Uiso 1 1 calc R . . . .
N5 N 0.3779(6) 0.718(3) 0.2323(6) 0.140(8) Uani 1 1 d . U . . .
H5D H 0.3683 0.7576 0.2083 0.168 Uiso 1 1 calc R . . . .
H5E H 0.3808 0.6088 0.2314 0.168 Uiso 1 1 calc R . . . .
H5F H 0.3593 0.7425 0.2454 0.168 Uiso 1 1 calc R . . . .
C17 C 0.5021(10) 0.739(6) 0.3434(14) 0.29(2) Uani 1 1 d . U . . .
H17A H 0.5314 0.7763 0.3496 0.438 Uiso 1 1 calc R . . . .
H17B H 0.4882 0.7890 0.3606 0.438 Uiso 1 1 calc R . . . .
H17C H 0.5017 0.6206 0.3460 0.438 Uiso 1 1 calc R . . . .
C18 C 0.4809(10) 0.782(6) 0.3061(13) 0.249(15) Uani 1 1 d . U . . .
H18A H 0.4839 0.9005 0.3045 0.299 Uiso 1 1 calc R . . . .
H18B H 0.4973 0.7337 0.2901 0.299 Uiso 1 1 calc R . . . .
C19 C 0.4388(9) 0.747(5) 0.2878(11) 0.213(13) Uani 1 1 d . U . . .
H19A H 0.4358 0.6285 0.2893 0.256 Uiso 1 1 calc R . . . .
H19B H 0.4224 0.7955 0.3036 0.256 Uiso 1 1 calc R . . . .
C20 C 0.4180(12) 0.789(5) 0.2509(11) 0.205(13) Uani 1 1 d . U . . .
H20A H 0.4371 0.7651 0.2353 0.246 Uiso 1 1 calc R . . . .
H20B H 0.4141 0.9085 0.2503 0.246 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Bi1 Br1 2.838(2) . ?
Bi1 Br2 2.8371(15) . ?
Bi1 Br3 2.8427(15) . ?
Bi1 Br4 2.8466(15) . ?
Bi1 Br5 2.8547(19) . ?
Bi1 Br6 2.8485(14) . ?
Ag1 Br4 3.0177(15) 1_545 ?
Ag1 Br4 3.0177(15) 7_565 ?
Ag1 Br6 3.0237(14) 7 ?
Ag1 Br6 3.0236(14) . ?
Ag1 Br7 2.612(2) 7 ?
Ag1 Br7 2.612(2) . ?
Br4 Ag1 3.0176(15) 1_565 ?
Br8 Br9 2.578(5) . ?
Br9 Br8 2.578(5) 2_655 ?
N4 C16 1.38(4) . ?
C13 C14 1.513(18) . ?
C14 C15 1.528(19) . ?
C15 C16 1.57(5) . ?
N3 C12 1.44(3) . ?
C9 C10 1.586(18) . ?
C10 C11 1.465(18) . ?
C11 C12 1.64(3) . ?
N2 C8 1.40(5) . ?
C5 C6 1.529(19) . ?
C6 C7 1.43(6) . ?
C7 C8 1.524(19) . ?
N1 C4 1.50(4) . ?
C1 C2 1.58(4) . ?
C2 C3 1.537(19) . ?
C3 C4 1.488(18) . ?
N5 C20 1.40(4) . ?
C17 C18 1.37(5) . ?
C18 C19 1.36(4) . ?
C19 C20 1.35(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Br1 Bi1 Br3 90.44(6) . . ?
Br1 Bi1 Br4 91.61(6) . . ?
Br1 Bi1 Br5 179.74(6) . . ?
Br1 Bi1 Br6 91.43(6) . . ?
Br2 Bi1 Br1 89.07(6) . . ?
Br2 Bi1 Br3 93.60(5) . . ?
Br2 Bi1 Br4 175.99(5) . . ?
Br2 Bi1 Br5 90.92(6) . . ?
Br2 Bi1 Br6 89.44(5) . . ?
Br3 Bi1 Br4 90.35(5) . . ?
Br3 Bi1 Br5 89.31(6) . . ?
Br3 Bi1 Br6 176.46(6) . . ?
Br4 Bi1 Br5 88.42(6) . . ?
Br4 Bi1 Br6 86.59(5) . . ?
Br6 Bi1 Br5 88.82(6) . . ?
Br4 Ag1 Br4 180.00(6) 7_565 1_545 ?
Br4 Ag1 Br6 89.73(5) 1_545 7 ?
Br4 Ag1 Br6 90.27(5) 7_565 7 ?
Br4 Ag1 Br6 90.28(5) 1_545 . ?
Br4 Ag1 Br6 89.72(5) 7_565 . ?
Br6 Ag1 Br6 180.0 . 7 ?
Br7 Ag1 Br4 88.08(6) 7 1_545 ?
Br7 Ag1 Br4 91.92(6) 7 7_565 ?
Br7 Ag1 Br4 91.92(6) . 1_545 ?
Br7 Ag1 Br4 88.08(6) . 7_565 ?
Br7 Ag1 Br6 89.48(6) . 7 ?
Br7 Ag1 Br6 90.52(6) . . ?
Br7 Ag1 Br6 90.52(6) 7 7 ?
Br7 Ag1 Br6 89.48(6) 7 . ?
Br7 Ag1 Br7 180.0 7 . ?
Bi1 Br4 Ag1 160.99(8) . 1_565 ?
Bi1 Br6 Ag1 173.61(8) . . ?
Br8 Br9 Br8 179.2(3) . 2_655 ?
C13 C14 C15 93(2) . . ?
C14 C15 C16 100(3) . . ?
N4 C16 C15 113(3) . . ?
C11 C10 C9 93.5(19) . . ?
C10 C11 C12 101.5(19) . . ?
N3 C12 C11 124(2) . . ?
C7 C6 C5 96(5) . . ?
C6 C7 C8 112(5) . . ?
N2 C8 C7 116(3) . . ?
C3 C2 C1 91(2) . . ?
C4 C3 C2 100(3) . . ?
C3 C4 N1 110(3) . . ?
C19 C18 C17 125(4) . . ?
C20 C19 C18 125(4) . . ?
C19 C20 N5 120(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C13 C14 C15 C16 -176(3) . . . . ?
C14 C15 C16 N4 -177(3) . . . . ?
C9 C10 C11 C12 -179(2) . . . . ?
C10 C11 C12 N3 -57(3) . . . . ?
C5 C6 C7 C8 176(5) . . . . ?
C6 C7 C8 N2 -173(4) . . . . ?
C1 C2 C3 C4 179(2) . . . . ?
C2 C3 C4 N1 155(3) . . . . ?
C17 C18 C19 C20 -180(5) . . . . ?
C18 C19 C20 N5 166(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
